TW426594B - Biodegradable material composition, containers made of which and the preparation - Google Patents

Biodegradable material composition, containers made of which and the preparation Download PDF

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Publication number
TW426594B
TW426594B TW89101907A TW89101907A TW426594B TW 426594 B TW426594 B TW 426594B TW 89101907 A TW89101907 A TW 89101907A TW 89101907 A TW89101907 A TW 89101907A TW 426594 B TW426594 B TW 426594B
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Taiwan
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biodegradable
manufacturing
scope
container
mixed
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TW89101907A
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Chinese (zh)
Inventor
Hisashi Kanaya
Hideaki Suemasu
Yoji Kai
Norio Matsuo
Yusuke Kubota
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Seibu Electric & Amp Machinery
Fukuoka Kasei Kogyo Kabushikig
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Priority claimed from JP3342099A external-priority patent/JP2000229312A/en
Priority claimed from JP3337899A external-priority patent/JP2000229311A/en
Priority claimed from JP11169495A external-priority patent/JP2000355008A/en
Priority claimed from JP25536099A external-priority patent/JP2001079816A/en
Application filed by Seibu Electric & Amp Machinery, Fukuoka Kasei Kogyo Kabushikig filed Critical Seibu Electric & Amp Machinery
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Publication of TW426594B publication Critical patent/TW426594B/en

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L93/00Compositions of natural resins; Compositions of derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • C08L101/16Compositions of unspecified macromolecular compounds the macromolecular compounds being biodegradable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L93/00Compositions of natural resins; Compositions of derivatives thereof
    • C08L93/04Rosin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/06Biodegradable
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W90/00Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
    • Y02W90/10Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics

Abstract

This invention relates to a biodegradable material composition, which contains mainly plant materials of rice husks, and biodegradable binder. The container made of the above biodegradable composition will be decomposed by microbes or degraded by sunlight or ultraviolet ray after use and then be reused as soil modifier. The rice husks can mix with rice straw and paper pulp or other plant fibers. The binder contains rosin, dammar, copaiba, gelatin, starch, shellac, calcium carbonate, biodegradable plastics and others. The biodegradable container is produced by: first impregnating sheet-like textile and non-woven sheets with the slurry contains plant fiber powder, shellac, titanium dioxide, biodegradable wax and calcium carbonate; then drying/consolidating the impregnates into sheets; finally laminating at least two sheets of the above consolidate into formality by applying heat and pressure.

Description

-426 594 五、發明說明(1) 發明背景 發明領域 本發明係關於以稻殼等 構成之生物分解性材料組成 物製成之生物分解性材料製 製容器之製法。 前案技藝之說 向來用完即丟棄的容器 樹脂添加稻样等之枒料所製 和8-151027號公報。 植物原料和生物分解性物質所 物’由該生物分解性材料組成 容器’以及該生物分解性材料 ’已知有在發泡笨乙烯系合成 成’例如參見特開平8 - 1 4 3 6 9 5 另外’特開平1 0-3238 1 0號公報揭示之生物分解性成 型材料,係51至70重量%的紙粉和3〇至49重量%的生物分 解性脂族聚酯樹脂所構成,可形成耐熱溫度高、利用蒸汽 滅菌而用完即吾棄的餐具、餐盤 '苗木等缽逐一移植土中 之植生蛛。該生物分解性成型材料具有耐水性,在使用後 廢棄時’於一定期間内即可崩解消滅。 又,特開斗' 7-205120號公報所揭示之可分解性容器製 法,係以榖類稈和稻殼為基本原料,不因廢棄而引起環境 污染’將穀稈和稻殼高溫殺菌消毒,乾燥後預先切斷成纖 維或粉碎,另方面將含水殿粉加熱糊化,將二者混合撲掉 而成之混合材料,利用成型模加熱加壓成型,接著塗佈塑 膠膜形成被覆層。 再者’搬運食品或陳列於展示櫃的食品用托盤或盒子 等,由生物分解性不織布製成用完即丟棄的容器,已見於-426 594 V. Description of the invention (1) Background of the invention Field of the invention The present invention relates to a method for manufacturing a container made of a biodegradable material made of a biodegradable material composition composed of rice hulls and the like. The technique of the previous case is a container made of rice, etc., which has been discarded in the past. Plant materials and biodegradable substances 'containers made of the biodegradable material' and the biodegradable materials 'are known to be synthesized in foamed styrene based systems' See, for example, JP 8-1 4 3 6 9 5 In addition, the biodegradable molding material disclosed in Japanese Unexamined Patent Application Publication No. 10-3238 10 is composed of 51 to 70% by weight of paper powder and 30 to 49% by weight of a biodegradable aliphatic polyester resin. Disposable tableware, dinner plates, seedlings, and other pots that are high in heat-resistant temperature and sterilized by steam are transplanted one by one in the soil. This biodegradable molding material has water resistance and can be disintegrated and destroyed within a certain period of time when it is discarded after use. In addition, the method for producing a decomposable container disclosed in Japanese Patent Application Laid-Open No. 7-205120 uses stalks and rice husks as basic raw materials, and does not cause environmental pollution due to waste. After drying, it is cut into fibers or pulverized in advance. On the other hand, the water-containing powder is heated and gelatinized. The mixed material formed by mixing the two powders is heated and pressurized with a molding die, and then coated with a plastic film to form a coating layer. Furthermore, 'food trays or boxes used to carry food or displayed on display cases are made of biodegradable non-woven fabrics and discarded after use.

第5頁 - 4 26 5 94 五、發明說明(2) 例如特開平4- 1 89740號公報□該食品用托盤係由纖維素系 的天然纖維或纖維素系的再生或半合成織維,或其混合纖 維,所構成之布輻,利用殼質之脫乙炔化物塩為主體之織 維間結合劑粘著,相對於該纖雉1 0 0重量份,附著撥水劑 以固體份計為1至10重量份,單位面積在200g/iri以上之生 物分解性不織布所製成,壓縮成型為表觀密度在0. 2g/cm3 以上。 可是,向來用完即丟棄的容器,由於成型時流動性良 好,添加有少量不能生物分解的樹脂材料,故此等容器在 廢棄處理時,會引起環境污染。又,習知分解性容器之缺 點是,使用時不具有充分的剛性、強度、形狀保持性等機 械物性,而利用上述分解性容器之製法所製成之成型體, 可保持設被覆層時之初期形狀。 此外,習知用完即丟棄的容器,製品強度不足,例如 用做食品容器時,在食品容器内裝入液體或佐料搬動中, 不能保持容器本身形狀,會膨潤,保形性不佳,容器本身 會吸收水份,以致表面變色,問題很多。 為強化容器,採用含片材的生物分解性材料成型時, 是在片材上方塗佈非片材,於非片材的中間成型體表面配 置片材加以成型等,片材和非片材不能一體成型,在減輕 減薄方面產生問題,並造成生產性不佳的問題。 發生概要 本發生之目的,在於解決上述課題,提供一種生物分 解性材料組成物,及由該組成物製成之容器,令構成容器Page 5-4 26 5 94 5. Description of the invention (2) For example, Japanese Patent Application Laid-Open No. 4- 1 89740 □ The food tray is made of cellulose-based natural fiber or cellulose-based recycled or semi-synthetic fabric, or The mixed fibers and the fabric spokes are adhered by a woven interdimensional bonding agent mainly composed of deacetylated fluorene of chitin. Relative to 100 parts by weight of the fiber, the water-repellent agent is 1 on a solid basis. To 2 parts by weight, made of a biodegradable non-woven fabric having a unit area of 200 g / iri or more, and compression molding to an apparent density of 0.2 g / cm3 or more. However, containers that have been discarded when used up have good fluidity during molding and a small amount of non-biodegradable resin materials are added. Therefore, when these containers are disposed of, they will cause environmental pollution. In addition, the disadvantage of the conventional degradable container is that it does not have sufficient mechanical properties such as rigidity, strength, and shape retention during use, and the molded body produced by the method for manufacturing the degradable container can maintain the same characteristics as when the coating layer is provided. Initial shape. In addition, conventionally used disposable containers have insufficient product strength. For example, when used as a food container, liquids or condiments are placed in the food container during transportation. The shape of the container cannot be maintained, and it will swell and have poor shape retention. , The container itself absorbs water, which causes the surface to change color, which causes many problems. In order to strengthen the container, when using a biodegradable material containing a sheet to form a sheet, a non-sheet is coated on top of the sheet, and a sheet is placed on the surface of the non-sheet intermediate formed body to be molded. Sheets and non-sheets cannot be used. Integral molding creates problems in reducing thinning and causes poor productivity. Summary of occurrence The purpose of this occurrence is to solve the above-mentioned problems, and provide a biodegradable material composition, and a container made of the composition, so as to constitute a container.

第6·頁 :426594 五、發明說明(3) ' 等物品之材料,於該物品廢棄處理後,物品枒料可在短期 内利用微生物的分解作用,或以陽光、紫外線等崩解=分 解成無害之土,分解物質可做為土壤改良材料等,同時: 使用時剛性、強度、形狀保持性等機械物性均優。 未發生之另一目的,在於提供一種生物分解性材料製 容器及其製法,係將植物原料和生物分解性物質分別粉碎 之原料混合材料均勻混合,或於該原料混合材料添加由生: 物分解性物質製成之片狀織布和/或不織布,视情況轉化 為漂白殺菌、耐水性、耐熱性等材料’利用加熱加壓以壓 縮成型,容易製成容器,而經成型加工構成容器之组成物 不必焚化,在廢棄處分後,容器材料在短期間即利用微生 物的分解作用’或藉陽光、紫外線等分解成H2〇、(:02等而 崩解’由此分解成無害之土,分解物質可用做土壤改良材 料等’同時可增進容器本身之輕薄和生產性,而使用時具 有優良之剛性、強度、形狀保持性、耐水性、耐熱性等機 械物性。 本發明係關於由稻殼為主成份之植物原料粉末,與含 粘合劑的生物分解性物質混合而成的混合材料所構成之生 物分解性材料组成物。 該混合材料之混合比例為,該植物原料粉末6 0至9 0 % ,而該生物分解性物質1〇至40%。又,前述浪合材料亦可 添加水。 又’前述生物分解性物質包括虫膠、松香 '達瑪 (Dammar)樹脂、科巴(Copal)樹脂、明膠、澱粉、碳酸鈣Page 6: 426594 V. Description of the invention (3) The materials of articles such as '3' can be decomposed by microorganisms in a short time after disposing of the article, or disintegrated by sunlight, ultraviolet rays, etc. = decomposed into Harmless soil, decomposed materials can be used as soil improvement materials, etc. At the same time, mechanical properties such as rigidity, strength and shape retention are excellent when used. Another object that has not occurred is to provide a container made of biodegradable materials and a method for preparing the same. The raw material mixed material is pulverized by plant raw materials and biodegradable materials separately, or added to the raw material mixed materials to decompose the raw materials. Sheet-like woven and / or non-woven fabrics made of sexual materials are converted into materials such as bleaching, sterilization, water resistance, and heat resistance as appropriate. 'Compression molding using heat and pressure makes it easy to make containers. The material does not need to be incinerated. After being disposed of, the container material uses the decomposition of microorganisms in a short period of time, or breaks down into H2O, (: 02, etc. by sunlight, ultraviolet rays, etc., and disintegrates. It can be used as soil improvement materials, etc. At the same time, it can increase the lightness and productivity of the container itself, and has excellent rigidity, strength, shape retention, water resistance, heat resistance and other mechanical properties when used. The present invention relates to rice husks. Ingredients of plant raw material powder, mixed with biodegradable material containing binder Composition of decomposable material. The mixing ratio of the mixed material is 60 to 90% of the plant raw material powder and 10 to 40% of the biodegradable material. Moreover, the aforementioned Langhe material can also be added with water. Biodegradable substances include shellac, rosin 'Dammar resin, Copal resin, gelatin, starch, calcium carbonate

ί 426594 五、發明說明(4) 、生物分解性塑膠,或其混合粉末。該生物分解性物質中 的粘合劑,係由虫膠、松香、達瑪樹脂、科巴樹脂、明膠 、澱粉、或其混合粉末所構成。 此生物分解性材料組成物,與日常所用容器等物品之 製造原料相較,價格與市場價格相同,經生物分解歸土時 ,即轉變成無害土壤,故製成容器等時,在使用後可節省 焚化、再循環等手續,而且可利用做農作物之土壤改良材 料,可提供整體低成本之容器或瓶等。 於前述混合材料可混合氧化防腐劑和/或漂白劑。尤 其是於前述混合材料可混合生物分解性物質製成的織布和 /或不織布。 另外,本發明又關於生物分解性材料製容器,使用上 述生物分解性材料組成物,將該生物分解性材料組成物藉 加熱加壓而壓縮成型所製成。 再者,本發明還關於生物分解性材料製容器之製法, 包括步驟為,將稻殼為主成份的植物原料粉碎所得植物原 料,與含枯合劑的生物分解性物質粉碎所得生物分解性原 料粉末均勻混合,製成混合原料粉末,其次,將該混合原 料粉末經加熱加壓,壓縮成型為容器形狀。 此生物分解性材料製容器之製法,是將前述混合原料 粉末加熱加壓成型,製成中間成型體,其次,在該中間成 型體表面上,配置生物分解性物質所製成之織布和/或不 織布,製成成型體,再將該成型體加熱加壓,壓縮成型為 預定之形狀。ί 426594 V. Description of the invention (4), biodegradable plastic, or its mixed powder. The binder in the biodegradable substance is composed of shellac, rosin, dammar resin, coba resin, gelatin, starch, or a mixed powder thereof. This biodegradable material composition is compared with the raw materials for the daily use of containers and other items. The price is the same as the market price. When biodegraded and returned to the soil, it is transformed into harmless soil. Therefore, when it is made into a container, it can be used after use. Save incineration, recycling and other procedures, and can be used as soil improvement materials for crops, can provide overall low-cost containers or bottles. An oxidizing preservative and / or a bleaching agent may be mixed with the aforementioned mixing material. In particular, a woven fabric and / or a non-woven fabric made of a biodegradable substance may be mixed with the aforementioned mixing material. The present invention also relates to a container made of a biodegradable material. The biodegradable material composition is used, and the biodegradable material composition is heat-pressed and compression-molded. Furthermore, the present invention also relates to a method for manufacturing a container made of biodegradable materials, comprising the steps of: pulverizing a plant raw material containing rice husks as a main component; and pulverizing a biodegradable raw material powder obtained by comminuting a biodegradable material containing a cumulant. They are uniformly mixed to form a mixed raw material powder. Next, the mixed raw material powder is heated and pressurized, and compression-molded into a container shape. The method for manufacturing a container made of biodegradable material is to heat and press the mixed raw material powder to form an intermediate molded body. Next, on the surface of the intermediate molded body, a woven fabric made of a biodegradable substance and / Or a non-woven fabric is formed into a molded body, and then the molded body is heated and pressurized and compression-molded into a predetermined shape.

第8頁 五、發明說明(5) 又,此生物分解性材料製容器之製法,是將前述混合 原料粉末製成之泥漿,塗佈於生物分解性物質所製成之織 布和/或不織布,經乾燥製成片材,將該混合材料積層於 該片材一體加熱加壓而壓縮成型為預定形狀。 本發明又關於生物分解性材料製容器之製法,將至少 含有稻殼為主成份的植物纖維粉末材料、虫膠粉末和/或 虫膠溶液及生物分解性蠟之泥漿,塗佈或含浸於生物分解 性物質製成之片狀織布和/或不織布後,經乾燥製成片材 ,其次將前述片材加熱加壓,壓縮成型為具有預定形狀之 容器。 前述泥漿可添加氧化鈦和碳酸鈣、滑粉和/或雲母等 無機質填料。 前述虫膠粉末和/或虫膠溶液,至少有粘合劑和耐水 性材料的功用。前述氧化鈦至少有除臭劑和漂白殺菌劑的 功用,而前述生物分解性蠟至少有耐水性材料、離型材料 和撥水材料之功用。例如容器做為餐具等使用時,添加氧 化鈦做為除臭劑或殺菌劑,可有效消除稻殼等的臭味,並 加以殺菌。 壓縮成型之前述片材係由一片或積層之複數片所構成 。在該片材積層步驟中,將含前述植物纖維粉末材料、前 述片材織布和/或不織布等生物分解性材料之填料,適度 介置於該片材間,即可調節容器之隔熱性、耐熱性、厚度 和強度。例如將該填料構成多孔體時,多孔部形成空氣層 ,可大為改善隔熱性=5. Description of the invention (5) The method for manufacturing a container made of biodegradable material is a slurry made of the aforementioned mixed raw material powder and applied to a woven and / or non-woven fabric made of a biodegradable material. After being dried, a sheet is formed, and the mixed material is laminated on the sheet to be integrally heated and pressurized to be compression-molded into a predetermined shape. The present invention also relates to a method for manufacturing a container made of biodegradable material, which comprises coating or impregnating a slurry of plant fiber powder material, shellac powder and / or shellac solution and a biodegradable wax at least containing rice husk as a main component. The sheet-like woven and / or non-woven fabric made of decomposable material is dried to form a sheet, and the sheet is then heated and pressurized, and then compression-molded into a container having a predetermined shape. The slurry may be added with inorganic fillers such as titanium oxide and calcium carbonate, slip powder, and / or mica. The shellac powder and / or the shellac solution have at least the functions of a binder and a water-resistant material. The titanium oxide has at least a function of a deodorant and a bleaching fungicide, and the biodegradable wax has at least a function of a water-resistant material, a release material, and a water-repellent material. For example, when the container is used as tableware, adding titanium oxide as a deodorant or bactericide can effectively eliminate the odor of rice husks and the like and sterilize it. The aforementioned compression-molded sheet is composed of one sheet or a plurality of laminated sheets. In the sheet lamination step, a filler containing the aforementioned plant fiber powder material, the aforementioned sheet woven and / or non-woven biodegradable material is appropriately interposed between the sheets, and the heat insulation of the container can be adjusted. , Heat resistance, thickness and strength. For example, when the filler constitutes a porous body, the porous portion forms an air layer, which can greatly improve the heat insulation property =

第9頁 426 594 五、發明說明(6) 在前述片材加熱加壓成型之前述容器表面,塗佈前述 生物分解性蠟和矽塗劑。 前述植物纖維粉末材料係由粉碎到5 0至350網目的細 粉所構成。前述片材經加熱加壓而壓縮成型的條件,設定 在例如溫度為100至250。(:,壓力30至2 0 0kg/cm2,成型時 間3至6 0秒間之範圍。 前述泥漿係由前述植物纖維粉末材料40至90%、前述 虫膠溶液5至40%、前述氧化鈦1至30% '前述生物分解性 蠟1至40%、前述碳‘酸鈣1至20%,其餘為水或有機溶劑, 混合製成。 在前述植物纖維中,可於前述稻殼添加選自竹、甘蔗 、稻草 '椰殼、蔗渣、木屑、洋麻、綿屑、紙漿等植物材 料’及其二種以上的混合材料之原料等植物纖維材料。又 ,前述稻殼可用藉乾稻殼摩擦而與糙米分離之稻殼。 前述泥漿可添加選自科巴樹脂、松香、蒸餾妥爾油、 妥爾油脂肪酸、萜烯聚合物、澱粉、明膠、酪朊、達瑪樹 脂、阿拉伯膠、硬遞青,及其二種以上遇合材料之結合 劑。 前述泥漿於前述片材含浸之步麻’可令從筒管抽出的 前述片材以浸入裝在槽内的前述泥漿之狀態通過而達成。 此容器之製法係將至少包含以箱殼為主成份的植物纖 維粉末材料、虫膠粉末和/或虫膠溶液’及生物分解性蠟 之泥漿,加以乾燥製成片材,其次將該片材加熱加壓,壓 縮成型為具有預定形狀的容器。Page 9 426 594 V. Description of the invention (6) The surface of the container formed by heating and pressing of the sheet is coated with the aforementioned biodegradable wax and silicon coating agent. The aforementioned plant fiber powder material is composed of fine powder pulverized to 50 to 350 mesh. Conditions for compression-molding the sheet by applying heat and pressure are set at, for example, a temperature of 100 to 250. (: The pressure ranges from 30 to 200 kg / cm2, and the molding time ranges from 3 to 60 seconds. The slurry is composed of the plant fiber powder material 40 to 90%, the shellac solution 5 to 40%, and the titanium oxide 1 to 30% 'the aforementioned biodegradable wax 1 to 40%, the aforementioned carbon' calcium acid 1 to 20%, and the balance is water or an organic solvent, which is made by mixing. In the aforementioned plant fiber, the rice husk can be added by selecting from bamboo, Plant fiber materials such as sugarcane, straw 'coconut shells, bagasse, wood chips, kenaf, kenaf, cotton chips, pulp and other plant materials' and raw materials of a mixture of two or more materials. The aforementioned rice husks can be rubbed with dry rice husks to Rice husks separated from brown rice. The aforementioned mud can be selected from the group consisting of coba resin, rosin, distilled tall oil, tall oil fatty acid, terpene polymer, starch, gelatin, casein, dammar resin, gum arabic, and hard green And the binding agent of two or more meeting materials. The step of impregnating the aforementioned slurry with the aforementioned sheet material allows the aforementioned sheet material extracted from the bobbin to pass through the state of being immersed in the aforementioned slurry contained in the tank. This container The legal system will include at least The plant fiber powder material, shellac powder and / or shellac solution 'and the slurry of biodegradable wax as the main components are dried to form a sheet, and then the sheet is heated and pressurized and compressed into a predetermined shape. container.

第10頁 f 4 26 ^ 五、發明說明(7) 由泥漿製造片材之步驟是,把篩浸入於裝在槽内的泥 漿,使該泥漿在篩上擴散,把篩從槽内取出,將該泥漿乾 燥而達成。 於此所用稻殼不必進行洗淨或乾燥消毒處理,於前述 混合材料加熱成型時,即可充分殺菌處理,以後即和通常 的餐具等同樣處置。 再者,前述容器在強度和使用上,厚度以0.5min以上 為佳,傾斜角度宜在15°以上,亦可成型為平板狀。 此生物分解性材料製容器之製法係例如,將前述混合 材料製成的泥漿塗佈於前述織布和/或不織布,乾燥製成 片材,把該混合材料積層於該片材所得素材,加壓成型為 預定之形狀。 此生物分解性材料組成物,完全以分解性材料構成, 尤其是藉織布和/或不織布之作用,可構成具有強度之製 品。 此容器在極簡單之製造步驟中,以稻殼為主成份,藉 織布和/或不織布加強,利用生物分解性材料之粘合劑粘 結製成。 由前述片材加熱加壓成型之容器表面,塗佈前述生物 分解性蠟和矽塗劑。該生物分解性蠟亦可添加選自動植物 蠟、礦物蠟、石油蠟等天然蠟,及其二種以上混合材料。 該生物分解性蠟一般對高溫不具有耐熱性,但為提高容器 使用領域之耐水性,宜塗佈於容器之表面。 此容器之製法中,由前述泥漿製造前述片材之步驟,Page 10 f 4 26 ^ V. Description of the invention (7) The step of manufacturing sheet from mud is to immerse the sieve in the mud installed in the tank, make the mud spread on the sieve, remove the sieve from the tank, and The mud was dried to reach it. The rice husks used here do not need to be washed or dried and disinfected. When the aforementioned mixed materials are heated and formed, they can be fully sterilized, and they will be disposed of in the same manner as ordinary tableware. Furthermore, in terms of strength and use, the thickness of the aforementioned container is preferably 0.5 min or more, and the inclination angle is preferably 15 ° or more, and it can also be formed into a flat shape. The manufacturing method of the container made of the biodegradable material is, for example, applying the slurry made of the mixed material to the woven and / or non-woven fabric, drying it to form a sheet, and stacking the mixed material on the sheet. Compression molding into a predetermined shape. This biodegradable material composition is composed entirely of degradable materials, and in particular, can be made into a product having strength by the action of woven and / or non-woven fabrics. In a very simple manufacturing step, this container is made of rice hull as the main component, reinforced with woven and / or non-woven fabric, and bonded with an adhesive of a biodegradable material. The surface of the container formed by heating and pressing from the sheet was coated with the biodegradable wax and the silicon coating agent. The biodegradable wax may be added with natural waxes such as automatic plant waxes, mineral waxes, petroleum waxes, and a mixture of two or more kinds thereof. This biodegradable wax generally does not have heat resistance to high temperatures, but in order to improve water resistance in the field of container use, it is suitable to be coated on the surface of the container. In the manufacturing method of the container, the step of manufacturing the aforementioned sheet material from the aforementioned mud,

第11頁_ 4 26 5 94 五、發明說明(8) 係將篩浸於裝在槽内之前述泥漿,令泥漿在該篩上擴散, 將篩從槽内取出,使該泥漿乾燥,即告完成。 前述片材含浸泥漿之步驟,係令筒管抽出的前述片材 ,以浸入裝在槽内的泥毁之狀態通過而達成。 此生物分解性材料製容器之製法,因係由上述構成, 因虫膠(虫膠粉末和/或虫膠溶液)具有耐水性或耐熱性 ,且生物分解性蠟具有耐水性,用做食品容器時,容器不 會因吸收水份而膨潤、變色或變質,故可提供良好容器。 又,由含浸生物分解性材料製成的泥漿所得片材至少 二片以上積層時,可製成良好容器,確保容器之保形性和 強度。 即由於可將片材一片或二片以上積層製成容器,故可 視容器用途調節材積層數,即可調節容器之強度或耐水 性情況。此外,亦可在積層的片材間夾持生物分解性材料 ,藉夾持而使容器具有厚度,可視所夾持材料之性質,使 容器具有其他功能,例如隔熱性、财熱性。 此外,此容器之製法可添加具有漂白殺菌劑和除臭效 果之氧化鈇,改善離型性、撥水性、流動性或光澤之生物 分解性蠟,做為生物分解性村料,以改進容器特性。 此容器之製法如上述構成,係於片材含浸生物分解性 材料製成的泥漿,製成片材,或將泥漿本身過濾而製成片 材,該片材則經加熱加壓而壓縮成型,製成容器,故與習 知物品相較,可提高強度,達成容器之輕、薄化,又因容 器製造有處理上的方便性,可得生產性改進效果。 第12-頁 426594 五、發明說明(9) 此容器可用做餐器、餐盤、植缽、容納各種材料之器 具等,用做食品容器後,容器本身放置或丟棄時,構成容 器之材料本身會被微生物等分解,受到陽光,‘尤其是紫外 線崩解歸土,即轉換為無害土壌、水或二氧化碳,故不必 進行容器焚化、回收等,可以節省處理費,而且生物分解 過的土壤,可用做農作物的土壌改良劑。 按照此項製法製成的容器,容器本身價格與市場價格 相同,具有上述功用,故可提供整體極為廉價之容器。 圖式簡單說明· 第1圖為本發明生物分解性材料製容器之製法中容器 製造步驟方塊圖; 第2圖為本發明生物分解性材料製容器之製法中所用 製造裝置概略說明圖; 第3圖為本發明生物分解性材料製容器之製法中容器 製造步驟另一實施例方塊圖; 第4圖為本發明生物分解性材料製容器之製法中織布 和/或不織布所構成容器製造步驟說明圖; 第5圖為在第2圖製造裝置設有控制器的實施例概略說 明圖, 第6圖為本發明生物分解性材料製容器之製法中容器 製造步驟次一實施例方塊圖; 第7圖為本發明生物分解性材料製容器之製法中容器 製造步驟又一實施例方塊圖; 第8圖為本發明生物分解性材料製容器之製法所用製Page 11_ 4 26 5 94 V. Description of the invention (8) The sieve is immersed in the aforementioned slurry installed in the tank, the slurry is diffused on the screen, the screen is taken out of the tank, and the slurry is dried. carry out. The step of impregnating the slurry with the sheet material is achieved by passing the sheet material extracted from the bobbin in a state of being immersed in the mud filled in the tank. The method for manufacturing a container made of biodegradable material is composed of the above. Because shellac (shellac powder and / or shellac solution) has water resistance or heat resistance, and the biodegradable wax has water resistance, it is used as a food container. In this case, the container does not swell, discolor or deteriorate due to absorption of water, so a good container can be provided. In addition, when at least two or more sheets obtained from a slurry made of impregnated biodegradable materials are laminated, a good container can be made to ensure the shape retention and strength of the container. That is, since one or more sheets can be laminated into a container, the strength of the container or the water resistance can be adjusted by adjusting the number of laminated layers according to the purpose of the container. In addition, the biodegradable material can also be sandwiched between the laminated sheets, and the container can be made thick by clamping. Depending on the nature of the material being clamped, the container can have other functions, such as heat insulation and financial properties. In addition, this container can be made by adding bleaching fungicides and deodorizing osmium oxide to improve release, water repellency, fluidity or gloss of biodegradable waxes as biodegradable village materials to improve container characteristics . The manufacturing method of this container is as described above. It is based on the sheet impregnated with a slurry made of biodegradable materials, made into a sheet, or the slurry itself is filtered to form a sheet. The sheet is compressed and molded by heating and pressing. It is made into a container, so compared with the conventional article, it can increase the strength, achieve the lightness and thinness of the container, and because the container has the convenience of handling, the productivity improvement effect can be obtained. Page 12-426594 V. Description of the invention (9) This container can be used as a tableware, dinner plate, planting bowl, utensils containing various materials, etc. After being used as a food container, when the container itself is placed or discarded, the material constituting the container itself It will be decomposed by microorganisms and exposed to sunlight, especially the ultraviolet rays disintegrate and return to the soil, that is, it will be converted into harmless soil, water, or carbon dioxide, so there is no need to incinerate and recycle the container, which can save processing costs, and the biologically decomposed soil can be used. Soil improvement agent for crops. Containers made according to this manufacturing method have the same price as the market price and have the above functions, so they can provide extremely low-cost containers as a whole. Brief description of the drawings. Figure 1 is a block diagram of a container manufacturing process in a method for manufacturing a container made of a biodegradable material according to the present invention; Figure 2 is a schematic explanatory diagram of a manufacturing apparatus used in a method for manufacturing a container made of a biodegradable material according to the present invention; The figure is a block diagram of another embodiment of the container manufacturing steps in the method for manufacturing a container made of biodegradable materials according to the present invention. FIG. 4 is a description of the manufacturing steps of the container made of woven and / or non-woven fabric in the method for manufacturing a container made of biodegradable materials according to the present invention. FIG. 5 is a schematic explanatory diagram of an embodiment in which a controller is provided in the manufacturing apparatus of FIG. 2, and FIG. 6 is a block diagram of a second embodiment of a container manufacturing step in a method for manufacturing a container made of a biodegradable material according to the present invention; FIG. 8 is a block diagram of another embodiment of a container manufacturing step in a method for manufacturing a container made of biodegradable materials according to the present invention; FIG. 8 is a chart for a method used for manufacturing a container made of biodegradable materials according to the present invention

ll^|- I 第13頁 五、發明說明(ίο) 造裝置實施例概略說明圖: 第9圖為本發明生物分解性材料製容器之製法製造裝 置内的加熱加壓裝置實施例概略說明圖; 第10圖為本發明生物分解性材料製容器之製法所用不 同素材的製造步驟實施例概略說明圖; 第11圖為本發明生物分解性材料製容器之製法另一實 施例之製造步驟說明圖。 具體例之詳細說明 茲分別就實施例說明本發明生物分解性材料組成物, 以及由該組成物成型之容器如下。 本發明生物分解性材料組成物先是用於餐具、收容器 、包裝箱、罐、袋,亦可用做植缽、花盆等植物栽培用容 器,係由稻殼為主成份的植物原料粉末6 0至9 0 %、混合含 粘合劑的生物分解性物質1 0至4 0 %而得混合材料,視原料 加水而成之混合材料所構成。構成生物分解性材料組成物 之主原料材料,因微生物的分解作用,陽光、紫外線等而 崩解,轉化為無害土壌,可利用為土壤改良材料。 植物原料可於稻殼添加選自竹、甘蔗、稻草、紙漿, 及其二種以上混合原料之植物纖維材料等原料。即植物原 料可單純由稻殼構成,亦可於稻殼混配稻草、紙漿等植物 纖維。 生物分解性物質可用松香、達瑪(天然樹脂)、科巴 (天然樹脂)、明膠、澱粉、虫膠、生物分解性塑膠、碳 酸鈣,或其混合粉末,其中,松香、達瑪、科巴、明膠、ll ^ |-I Page 13 V. Brief description of the embodiment of the manufacturing device: Figure 9 is a schematic illustration of the embodiment of the heating and pressurizing device in the manufacturing device of the method for manufacturing a container made of a biodegradable material according to the present invention. Figure 10 is a schematic illustration of a manufacturing method of different materials used in the method for manufacturing a container made of biodegradable materials according to the present invention; Figure 11 is a schematic illustration of the manufacturing steps of another embodiment of a method for manufacturing a container made of biodegradable materials according to the present invention; . Detailed description of specific examples The examples of the biodegradable material composition of the present invention and the containers formed from the composition are described below with reference to the examples. The biodegradable material composition of the present invention is firstly used in tableware, containers, packing boxes, cans, bags, and can also be used as a container for plant cultivation, such as planting pots, flower pots, etc. It is a plant raw material powder mainly composed of rice husks. 60 To 90%, and 10 to 40% of the biodegradable substance containing the binder is mixed to obtain a mixed material, which is composed of a mixed material made by adding water to the raw material. The main raw material constituting the biodegradable material composition disintegrates due to the decomposition of microorganisms, sunlight, ultraviolet rays, etc., and is converted into harmless soil, which can be used as a soil improvement material. Plant materials can be added to the rice husk with materials selected from bamboo, sugarcane, straw, pulp, and two or more kinds of mixed plant fiber materials. That is, the plant raw material can be simply composed of rice husks, and plant fibers such as straw and pulp can also be mixed with rice husks. Biodegradable substances can be rosin, dammar (natural resin), coba (natural resin), gelatin, starch, shellac, biodegradable plastic, calcium carbonate, or their mixed powders, among which rosin, dammar, coba ,gelatin,

第14頁 五 '發明說明(11) 殿粉、虫移,有粘合劑的功用。 此外,由植物原料和生物分解性原料構成之混合材料 ,亦可混合氧化防腐劑和/或漂白劑。稻殼可用乾稻經輾 米,而從糙米分離之稻殼,可節省另行乾燥處理等。 稻殼係構成容器等物品之增量劑,本身為生物分解性 ,為降低成本,含量可多達60至90%,以65至85%為佳。 生物分解性材料組成物所含碳酸的,具有自然崩解性 ,可降低成本,同時改進容器之耐熱性,可提高硬度,但 成型時流動性不良s故添加量必須視製品而調節,並無限 度。 構成生物分解性材料組成物之生物分解性塑膠,係由 生物分解性脂族聚醋、生物分解性脂族聚謎等構成,例如 由1,4-丁二醇等多元醇,與丁二酸 '己二酸等二羧酸,聚 縮合反應所得脂族聚酯。 虫膠為天然樹脂之一種,具有熱固性之特性,可自然 崩解,同時具有生物分解性,以粉末使用,俾可與植物原 料均勻混合,虫膠可溶於酒精,同時可熱熔,可配成酒精 溶液(25至50%)或水溶液(25%),以液狀使用。 用做粘合劑之松香係天然樹脂,具有自然崩解性,但 轴結力和耐熱性低,必須考慮此點來調節添加量。 明膠為動物性蛋白質之一種,具有生物分解性,但粘 結力、耐熱性低,必須考慮此點來調節添加量。 殿粉具有生物分解性,可以低廉成本取得,但粘結力 、耐熱性低,必須考慮此點來調節添加量。Page 14 5 'Explanation of the invention (11) Temple powder, insect migration, with the function of an adhesive. In addition, mixed materials composed of plant materials and biodegradable materials can also be mixed with oxidative preservatives and / or bleaching agents. Rice husks can be rolled through dried rice, and rice husks separated from brown rice can save additional drying treatments. Rice husks are bulking agents that make up containers and other items. They are biodegradable. To reduce costs, the content can be as high as 60 to 90%, preferably 65 to 85%. The carbonic acid contained in the biodegradable material composition has natural disintegrability, which can reduce the cost, and at the same time improve the heat resistance and hardness of the container. However, the flowability during molding is poor. Therefore, the amount of addition must be adjusted depending on the product and is unlimited. degree. The biodegradable plastic constituting the biodegradable material composition is composed of a biodegradable aliphatic polyacetate, a biodegradable aliphatic polymystery, and the like, for example, a polyhydric alcohol such as 1,4-butanediol and succinic acid 'Dicarboxylic acids such as adipic acid, aliphatic polyesters obtained by polycondensation reaction. Shellac is a kind of natural resin, which has the characteristics of thermosetting, can disintegrate naturally and biodegradable at the same time. It is used as a powder, and can be mixed with plant raw materials uniformly. Shellac is soluble in alcohol and can be hot melted. It can be used as liquid solution (25 to 50%) or aqueous solution (25%). The rosin-based natural resin used as a binder has natural disintegrability, but has low axial cohesion and heat resistance. This must be considered to adjust the amount of addition. Gelatin is an animal protein that has biodegradability, but has low adhesion and heat resistance. You must consider this point to adjust the amount of gelatin. Dianfen has biodegradability and can be obtained at a low cost, but its cohesive force and heat resistance are low. This must be considered to adjust the amount of addition.

第15頁 426 534 五、發明說明(12) 關於此生物分解性材料紐成物,在第一實施例中’植 物原料與生物分解性物質之混合比例,係由植物原料之箱 殼80%,和生物分解性物質之澱粉2〇%所構成β第二實施 例中’植物原料與生物分解性物質之混合比例,係由植物 原料之稻殼70%、生物分解性物質之澱&2〇%,和碳酸釣 10%所構成。第三實施例中,植物原料與生物分解性物質 之混合比例,係由植物原料之稻殼8〇 %,和生物分解性物 質之虫膠2 0 %所構成。在第四實施例中,植物原料與生物 分解性物質之混合比例,係由植物原料之稻殼8 5 % '生物 分解性物質之虫膠5%,和碳酸鈣等物質1〇%所構成。於 此所用虫膠,係溶於酒精内之虫膠溶液,可用來塗佈於稻 殼成型體之表面。第五實施例令,植物原料與生物分解性 物質之混合比例,係由植物原料之稻殼8〇%,生物分解性 物質之松香2 0 %所構成。第六實施例中,植物原料與生物 分解性物質之混配比例,係由植物原料之稻殼8 〇 %,和生 物分解性物質之明膠20%所構成。再者,在第七實施例中 ’植物原料與生物分解性物質之現配比例,係由植物原料 之稻殼70% ’和生物分解性物質之脂族聚酷2〇%,另含粘 合劑之碳酸纟3 1 0 %所構成° 其次,參見第1圖和第2圖琯日日士改叫丄 闺說明本發明生物分解性材料 製容器製法之一實施例。 由此製法製成之容器1原先用枥赵s — 7九用做餐具、容納器、句奘 植物栽培用容器 主要利用上述生物分解性材料組成物製成。構;容器; 箱、罐、袋等,亦可用做植蛛' 花盆等 之Page 15 426 534 V. Description of the invention (12) Regarding the new biodegradable material, in the first embodiment, the mixing ratio of the "plant material and the biodegradable material" is 80% of the shell of the plant material, Β in the second embodiment, which is composed of 20% of starch of biodegradable material and biodegradable material. The mixing ratio of plant material and biodegradable material is 70% of rice husk of plant material, biodegradable material & 2. % And carbonated fishing 10%. In the third embodiment, the mixing ratio of the plant material and the biodegradable material is composed of 80% of rice husk of the plant material and 20% of shellac of the biodegradable material. In the fourth embodiment, the mixing ratio of the plant material and the biodegradable material is composed of 85% of rice husk of the plant material, 5% of shellac of biodegradable material, and 10% of calcium carbonate and other materials. The shellac used here is a shellac solution dissolved in alcohol, which can be used to coat the surface of the rice husk shaped body. In the fifth embodiment, the mixing ratio of plant material and biodegradable material is composed of 80% of rice husk of plant material and 20% of rosin of biodegradable material. In the sixth embodiment, the mixing ratio of the plant material and the biodegradable material is composed of 80% of rice husk of the plant material and 20% of gelatin of the biodegradable material. Furthermore, in the seventh embodiment, "the current ratio of the plant material to the biodegradable material is 70% of the rice husk of the plant material" and 20% of the aliphatic polymer of the biodegradable material. The composition is composed of osmium carbonate 3 10%. Second, referring to Fig. 1 and Fig. 2, the Japanese name is renamed to 丄 女 to explain one embodiment of the method for manufacturing a container of the biodegradable material of the present invention. The container 1 made by this method was originally used as a tableware, container and sentence container for plant cultivation. It was mainly made of the above biodegradable material composition. Structure; container; box, can, bag, etc., can also be used as a spider's flower pot, etc.

第16頁 426594 ---------------------- 五、發明說明(13) 主要材料’係利用微生物之分解作用,或藉陽光、紫外線 等崩解,轉化成無害的土壤。 容器1之製法包括步驟為’抱稻殼為主成份之植物原 料粉碎所得植物原料粉末’與含粘合劑的生物分解性物質 粉碎所得生物分解性原料粉末,加以均勻混合製成混合原 料粉末,接著利用壓機將該混合原料粉末加^加壓,歷縮 成型為谷器。首先,選用含稻殼為主之植物原料(步驟j〇) ’將選定的植物原料以粉碎機等粉碎到5〇至3〇〇網目(步驊 ]),製成植物原料·粉末(步驟12)。另方面,選用含粘合 物分解性物質(步驟13),將選用之生物分解性物質 ^ Ϊ =機等粉碎到5 〇至3 〇 〇網目(步驟1 4 ),製成生物分解 往原料粉末(步騨1 5)。 一其次,將植物原料粉末和生物分解性原料粉末,按預 驟1 6广/W混合裔等均勻混合’製成混合原料粉末(步 控括札此時,混合原料粉末就容器形狀保持觀點言,可 j原料60至90%和生物分解性物質1〇至4〇%之混配比 ,而以植物原料65至85%和生物分解性物質15至35 思合比例混合為佳。 於=合原料粉末利用成型裝置加熱加壓以壓縮成型時, 水作:合原料粉末之際’彳視選擇原料’添加預定量的 ^ 。此時’當然也有因選用材料,而不必加水份者。其 Ϊ成! ΐ合原料粉末,使用預定成型裝置’例如第2圖所、 下裝置’充填於上模2和下模3之間’對設於上模2和 卜棋d之加熱器4通電’同時作動壓機5,施加負荷p,將混Page 16 426594 ---------------------- V. Description of the invention (13) The main material 'is the use of the decomposition of microorganisms, or collapse by sunlight, ultraviolet rays, etc. Decompose and transform into harmless soil. The method for manufacturing container 1 includes the steps of 'plant material powder obtained by pulverizing plant material containing rice husk as a main component' and biodegradable material powder obtained by pulverizing a biodegradable material containing a binder, and uniformly mixing them to obtain a mixed material powder. Then, the mixed raw material powder is pressurized by a press, and then shaped into a trough. First, select a plant material containing rice husks (step j0) 'pulverize the selected plant material to a 50 to 300 mesh (step 骅) with a pulverizer or the like to prepare a plant material · powder (step 12) ). On the other hand, a binder-containing degradable material is selected (step 13), and the selected biodegradable material is crushed to a mesh of 50 to 300 (step 14) to prepare a biodegradable raw material powder. (Steps 1 5). Secondly, the plant raw material powder and the biodegradable raw material powder were uniformly mixed according to Step 16 and the mixed raw material powder to prepare a mixed raw material powder (step control includes that at this time, the mixed raw material powder is maintained in terms of container shape. The mixing ratio of 60 to 90% of the raw material and 10 to 40% of the biodegradable material can be mixed, and it is better to mix the ratio of 65 to 85% of the plant raw material and 15 to 35 of the biodegradable material. When the raw material powder is heated and pressurized by the molding device for compression molding, the water is used: when the raw material powder is mixed, a predetermined amount of ^ is added to the 'despise selection of raw materials'. At this time, of course, there are also materials that do not need to be added. Ϊ 成! The raw material powder is mixed, using a predetermined molding device such as the second figure, the lower device is filled between the upper mold 2 and the lower mold 3, and the heater 4 provided on the upper mold 2 and the mold 4 is energized. Operate the press 5 at the same time, apply the load p, and mix the

426594 五、發明說明(14) 合原料粉末加熱加壓,而壓縮成型(步驟17)。此時,成型 裝置之壓縮成型條件,宜設定在成型溫度100〜200 °C,成 型壓力2 0〜8 0 kg / cm 2,成型時間在3〜3 0秒間之範圍。混 合原料粉末利用壓縮成型所形成之容器1厚度,可有各種 設定,以成型厚度在0.5 mni以上為佳,對容器I的強度、形 狀保持等機械物性有利(步驟1 8)。 容器1可製成平板狀,用做餐具時,其傾斜角度以成 型例如1 5 °以上,在強度和實用方面較佳。 製造容器1之植‘物原料,以及含钻合劑之生物分解性 物質,與上述組成物之材料相同。 稻殼等植物原料於此為構成容器1之增量劑,具有生 物分解性,為降低成本,含量宜多達60至90%,以65至85 %為佳。 容器1製法所用原料具體例,可用上述生物分解性材 料組成物之第一實施例至第七實施例所列。 其次參見第3圖至第5圖,說明本發明生物分解性材料 組成物,由該組成物製成之生物分解性材料製容器,及其 製法之其他實施例。 此實施例之生物分解性材料組成物,包括以稻殼為主 成份之植物原料粉碎所得植物原料粉末,由生物分解物質 構成之粘合劑,以及由生物分解性物質構成之織布和/或 不織布。生物分解性物質之粘合劑,可用上述實施例同樣 之物質。 此實施例之容器1,係使用上述生物分解性材料組成426594 V. Description of the invention (14) The raw material powder is heated and pressed, and compression-molded (step 17). At this time, the compression molding conditions of the molding device should be set at a molding temperature of 100 to 200 ° C, a molding pressure of 20 to 80 kg / cm 2 and a molding time in a range of 3 to 30 seconds. The thickness of the container 1 formed by the compression molding of the mixed raw material powder can be variously set, and the molding thickness is preferably 0.5 mni or more, which is advantageous for the mechanical properties such as the strength and shape retention of the container I (step 18). The container 1 can be made into a flat plate shape, and when used as tableware, its inclination angle is shaped, for example, 15 ° or more, which is preferable in terms of strength and practicality. The raw materials of the plant 1 and the biodegradable material containing the drilling agent are the same as those of the above composition. Plant husks and other plant materials are used here as an extender for container 1. It has biodegradability. In order to reduce costs, the content should be as high as 60 to 90%, and preferably 65 to 85%. Specific examples of the raw materials used in the method for manufacturing the container 1 can be listed in the first to seventh embodiments of the above-mentioned biodegradable material composition. Next, referring to Figs. 3 to 5, the biodegradable material composition of the present invention, the container made of the biodegradable material made of the composition, and other examples of the manufacturing method will be described. The biodegradable material composition of this embodiment includes a plant raw material powder obtained by crushing a plant raw material mainly composed of rice husks, a binder composed of a biodegradable substance, and a woven fabric and / or a biodegradable substance. Not woven. As the binder of the biodegradable substance, the same substances as in the above embodiments can be used. The container 1 of this embodiment is composed of the above-mentioned biodegradable material

第18頁 426 594Page 426 594

物製成。 容 度減薄 松香等 達成容 箱、罐 此 的植物 製成之 之織布 預定之 ,仍可竑=—布。和/或不織布而提高強度’即使厚 組成的,飞I ί器的充分強度,因此可減少稻殼等和 器之輕二I材料本身之使用量,而降低容器重量, 、代楚 谷荔丨耳先用於餐具、容納器、包裝 衣 亦可用做植味、。 生物分解性材料製完哭Λ t ^ ....χ ή何针裂合器之製法,係於稻殼為主成份 二1制,所得植物原料粉末,添加生物分解性物質 口形成之混合材料7,加生物分解性物質製成 和/或不織布8,製成素材,將該素材加壓成型為 形狀,而製成容器。 容器1係在例如第4圖(Α)所示織布和/或不織布8,按 第4圖(Β )所示’塗佈混合材料7構成之泥漿,經加壓成型 、乾燥,製成片材9。其次,如第4圖(C)所示,將混合材 料7積層於片材9,加熱加廢成型為預定形狀,製成第4圖 (D)所示容器1。 容器1之製法包括,於稻殼為主成份的植物原料粉碎 所得粉碎材料之植物原料粉末6 0至9 0 % ’混合生物分解性 物質之粘合劑1 0至4 0 %,所得原料粉末之混合材枓7所構 成,視情況於混合材料7加水成泥衆。構成容器1的主要材 料,因微生物之分解,或因陽光、紫外線等而崩解,轉化 為無害土壤、Η20、C02。 此實施例的植物原料粉末和加熱加壓之壓縮成型條件 ,與上述實施例相同。物 制。 Made of. The woven fabric made of plants, such as rosin, which has a reduced capacity, can reach containers and cans. And / or non-woven fabrics to increase the strength 'even with thick composition, the full strength of the fly I ί device, so can reduce the use of rice hulls and other light materials I material itself, and reduce the weight of the container, Ears are first used for tableware, containers, and packaging clothes. Biodegradable material production method Λ t ^ .... χ 何 He needle splitter manufacturing method, based on rice hull main component 21, the obtained plant raw material powder, added biodegradable material mouth formed mixed material 7. Add a biodegradable substance and / or non-woven fabric 8 to make a material, and press the material into a shape to form a container. The container 1 is, for example, a woven fabric and / or a non-woven fabric 8 as shown in FIG. 4 (A), and the slurry composed of the mixed material 7 is applied as shown in FIG. 4 (B), and then pressure-molded and dried to form a sheet.材 9。 Material 9. Next, as shown in Fig. 4 (C), the mixed material 7 is laminated on the sheet 9 and heated and waste-molded to form a predetermined shape to form a container 1 shown in Fig. 4 (D). The manufacturing method of the container 1 includes: pulverizing plant material powder obtained by pulverizing plant raw materials with rice husk as the main component, 60 to 90% of the raw material powder, and mixing the biodegradable material with a binder of 10 to 40%; The mixed material 7 is composed of water, and the mixed material 7 is mixed with water to form mud. The main materials constituting the container 1 are disintegrated by microorganisms, or disintegrated by sunlight, ultraviolet rays, etc., and are converted into harmless soil, radon 20, and C02. The plant raw material powder and the compression molding conditions under heat and pressure in this embodiment are the same as those in the above embodiment.

426 594426 594

其次’參見第3圉說明容器1之製造步驟。 、此製法包括步驟為’將稻殼為主成份的楂物原 成植物原料粉末,和生物分解性物質的粘合劑粉所$碎 物分解原料粉末’均勻混合製成混合原料粉末,接得生 加壓裝置將該混合原料粉末加熱加壓,壓縮成型為容^用 首先’準備以含稻殼為主的植物原料(步驟2〇),將^準備 的植物原料以粉碎機等粉碎成50〜300網目(步驟21),製 成植物原料粉末(步驟22)。另方面,準備生物分解性物質 之粘和劑(步驟23),將所準備的生物分解性物質以粉碎機 等粉碎成50〜300網目(步驟24),製成生物分解性原料粉 末(步驟25) 〇 其次,將植物原料粉末和生物分解性粘合劑,按預定 比例混配,以混合器等混合均勻,製成混合材料7 (步驟2 6 )。此時,混合原料粉末的混合材料中’稻殼的植物原料 粉末與粘合劑的原料粉末之混配比例’從形狀保持的觀點 ,宜由植物原料60至90%和粘合劑1〇至40%所構成’而以 植物原料6 5至8 5 %和粘合劑1 5至3 5 %構成為佳。又’在此 製法中,將混合原料粉末加熱加壓以壓縮成型時’於製造 混合原料粉末之際’可視選擇的原料’添加預定量的水份 ,^成泥紫。此時,當然可視選定材料之含水量’不必加 。另方面,準備生物分解性物質製成之織布和/或積層 不織布8(步驟27),於此’如第4圖(Α)所示’將織布和/ 稽層之不織布8例如配置於下膜3。如第4圖(Β)所示,於Next, referring to 3), the manufacturing steps of the container 1 will be described. 2. The production method includes the steps of: 'Hawthorn raw material consisting of rice husks is made into plant raw material powder and crushed material decomposed raw material powder obtained from binder powder of biodegradable substances' are uniformly mixed to obtain a mixed raw material powder. The raw material pressing device heats and presses the mixed raw material powder, and compresses it into a container. First, prepare a plant raw material containing rice husks (step 20), and pulverize the prepared plant raw material into 50 with a pulverizer or the like. ~ 300 mesh (step 21) to make plant material powder (step 22). On the other hand, a biodegradable substance adhesive is prepared (step 23), and the prepared biodegradable substance is pulverized into a mesh of 50 to 300 mesh by a pulverizer or the like (step 24) to prepare a biodegradable raw material powder (step 25). ) 〇 Second, the plant raw material powder and the biodegradable binder are mixed at a predetermined ratio, and mixed evenly with a mixer or the like to prepare a mixed material 7 (step 2 6). At this time, the "mixing ratio of the plant material powder of rice husk to the raw material powder of the binder" in the mixed material of the raw material powder is preferably 60 to 90% of the plant raw material and 10 to 10 of the binder from the viewpoint of shape maintenance. It is preferably composed of 40%, and is preferably composed of 65 to 85% of a plant material and 15 to 35% of a binder. In this method, when the mixed raw material powder is heated and pressurized for compression molding, a predetermined amount of water is added to the raw materials that can be selected depending on the production of the mixed raw material powder to form mud purple. At this time, of course, depending on the water content of the selected material, it is not necessary to add. On the other hand, a woven and / or laminated nonwoven 8 made of a biodegradable substance is prepared (step 27), and the woven and / or laminated nonwoven 8 is disposed as shown in FIG. 4 (A).下 膜 3。 Under film 3. As shown in Figure 4 (B),

' 426594 五、發明說明(17) 織布和/或積層的不織布8塗佈均勻混合的混合材料7之泥 漿,接著對塗佈混合材料7之織布和/或積層的不織布8作 動加壓裝置5,在上模2施加負荷p,藉加壓進行加壓成型 ’將加壓成型的片材9乾燥而定型(步驟28)。其次,於乾 燥的片材9積層由植物原料和松香構成之混合材料7,將此 配置於下模3上,對上模2和下模3所設加熱器通電,同時 作動加壓裝置5,於上模2施加負荷p,藉加熱加壓成型(步 驟29),製成生物分解性材料製容器步驟 使用生物分解性物質之松香為祐合劑時,因松香的耐 熱性低’為防止因熔解而延長成型時間,乃利用控制器6 控制加壓時間和成型溫度。 成型溫度利用控制器6 ’例如把金屬模具的上模2加熱 溫度設定於160〜170 °c,而下模3的加熱溫度設定於150〜 160C。此實施例雖然把上模2設定溫度高於下模3’但在 混合材料7加熱加壓成型時,在低溫方面之模漤有殘留成 型品之現象’故在此實施例中,成型品殘留於下模3。上 模2和下模3溫度設定在〗5 〇 °c以下時,利用松香使稻殼粒 彼此點著反應遲緩’引起成型時間加長的現象’同時,稻 殼的站結性惡化,成型品可能成為不良品。而上模2和下 模3的溫度設定在! 7 〇 t以上時,成型時間稍有延長,即會 發生成型品焦化的現象。因此,成型時間在3 〇秒左右時, 成型溫度以1 5 0〜1 7 〇 t左右為佳。 另外’成型壓力在金屬模塑的成型溫度或成型時間之 關係上,以10〜8〇kg/cm2左右為佳。再者,混合材料1因 426 594 五、發明說明(18) ' =壓成型、所形成的容器1厚度,可有各種設定,而以成型 0, 5mm以上之厚度為佳因有利於容器1之強度、形狀 持等機械特性。 n ^ ’稻殼等植物原料為構成容器之增量劑’可用上 =組=之同樣村料,具有生物分解降低成 量宜=6〇〜90% ’而以65〜85%為佳。 击 二二二參見第6圖說明此生物分解性材料製容器製法 中,:盗製造步驟之另一實施例。 ,故其說明在實施例:9步,26為止的製造步驟相同 分解性轴合劑,::。於步驟26,將植物原料粉末和生物 得混合材•斗,紙Ξ r定比例混配,以混合器等混合均句所 。另方面 車二…加壓成型’製成中間成型體(步驟31) 之不織布步驟備3么生物分解性物質製成之織布和/或積層 體配置於下模3卜)。於此,例如第5圖所示’將中間成型 之不織布,製成/於中間成型體上配置織布和/或積層 器4通電,同B#\成型體。其次,對上模2和下模3所設加熱 或積層之不織布:加壓裝置5 ’料間形型體及織布和/ 製成生物分解柯Ϊ加負荷P,經加熱加壓成型(步驟33), 以 解丨生材料製容器1(步驟34)。 料製圖至第1〇圖,說明本發明生物分解性材 此生物分艇f—實施例。 少準備將稻殻性材料組成物之製法,如第7圓所示,至 耐水性村料4碎所得植物纖維粉末材料、粘合劑、做為 材料和耐熱性材料之虫移粉末和/或'426594 V. Description of the invention (17) The woven and / or laminated nonwoven 8 is coated with the slurry of the mixed material 7 uniformly, and then the pressing device is operated on the woven and / or laminated nonwoven 8 coated with the mixed material 7 5. A load p is applied to the upper mold 2 and press-molded by pressurization. 'The press-molded sheet 9 is dried and shaped (step 28). Next, the dry sheet 9 is laminated with a mixed material 7 composed of plant materials and rosin, and this is arranged on the lower mold 3, and the heaters provided on the upper mold 2 and the lower mold 3 are energized, and the pressing device 5 is operated at the same time. A load p is applied to the upper mold 2 and heated and press-molded (step 29) to form a container made of a biodegradable material. When the rosin of a biodegradable material is used as a mixture, the heat resistance of the rosin is low. To extend the molding time, the controller 6 is used to control the pressing time and the molding temperature. The molding temperature is controlled by the controller 6 ', for example, the heating temperature of the upper mold 2 of the metal mold is set to 160 to 170 ° C, and the heating temperature of the lower mold 3 is set to 150 to 160C. In this embodiment, although the upper mold 2 is set to a temperature higher than the lower mold 3 ', when the mixed material 7 is heated and pressurized, there is a phenomenon that a molded product remains at a low temperature. Therefore, in this embodiment, the molded product remains于 下 模 3。 Under the mold 3. When the temperature of the upper mold 2 and the lower mold 3 is set to below 50 ° C, the husk grains react slowly with rosin 'causing the phenomenon of prolonged molding time'. At the same time, the stagnancy of the rice husk deteriorates, and the molded product may be damaged. Become defective. And the temperature of upper mold 2 and lower mold 3 is set at! If it is more than 70 t, the molding time is slightly prolonged, and coking of the molded product may occur. Therefore, when the molding time is about 30 seconds, the molding temperature is preferably about 150 to 170 t. In addition, the molding pressure is preferably about 10 to 80 kg / cm2 in relation to the molding temperature or molding time of the metal molding. In addition, the mixed material 1 has a thickness of 0, 5 mm or more, which is good for container 1 because of the 426 594 V. Description of the invention (18) '= the thickness of the container 1 formed by compression molding. Mechanical properties such as strength and shape retention. n ^ 'Plant raw materials such as rice husks are used as the bulking agent for the container.' The same materials as the group = can be used, and the biodegradation reduction amount should be 60 ~ 90%, and 65 ~ 85% is preferred. FIG. 22 illustrates another embodiment of the manufacturing process of the container made of biodegradable materials with reference to FIG. 6. Therefore, the description is in the embodiment: 9 steps, the manufacturing steps up to 26 are the same. Decomposable shaft mixture ::. In step 26, the plant raw material powder and the bio-derived mixed material • bucket, paper Ξr are mixed in a certain proportion, and mixed with a mixer or the like. On the other hand, the second car ... press molding is used to make an intermediate molded body (step 31), and the non-woven fabric is prepared in step 3 with a woven fabric and / or a laminated body made of a biodegradable material disposed in the lower mold 3b). Here, for example, as shown in FIG. 5 ′, a non-woven fabric formed in the middle is made / arranged with a woven fabric and / or a laminator 4 on the middle formed body, which is the same as B # \ formed body. Next, for the non-woven fabrics heated or laminated in the upper mold 2 and the lower mold 3: a pressurizing device 5 'a material shape and a woven fabric and / or made into a biodegradable keel load P, which is heated and press-molded (step 33). The container 1 is made of decomposed material (step 34). The material drawing to FIG. 10 illustrate the bio-degradable material of the present invention. The preparation method of the rice husk material composition is not prepared as shown in the seventh circle, and the plant fiber powder material obtained by crushing the water-resistant village material, the binder, the insect migration powder as the material and the heat-resistant material, and / or

426594 -- —---------------- 五、發明說明(19) 及改善耐水性所用生物分解性蠟(步驟41〜43),按預定量 混配製成泥漿1 4 (步驟4 6 )。在此情況下,可於泥漿14添加 除臭劑和渫白殺菌之氧化鈦’以及增量劑之碳酸鈣(步驟 44、45)。另方面,準備生物分解性物質製成的片狀織布 和/或不織布製成的片材(步驟47),片材以浸塗或喷塗等 塗佈泥漿14(步驟48),製成於片材含浸生物分解性材料的 泥漿14之片材11(步驟49)。其次,將片材11乾燥(步驟5〇) ’乾燥之片材11以一片或二片以上積層(步驟51)。接著, 將積層的片材11加熱加壓成型為預定形狀(步驟52),製成 預定的生物分解性材料製容器18(步驟53)。 又’片材11積層步驟,如第10圖(C)所示,填料19適 度介置於片材11之間’可調節容器1 8之隔熱性、耐熱性、 厚度和強度。填料1 9可例如由楂物纖維粉末材料、片狀織 布和/或不織布等生物分解性材料,或碳酸鈣、氫氧化鈣 、氧化鈣、氧化鈦、雲母粉末等礦物原料所製成。 片材11加熱加壓之壓縮成型條件,因材料混配比例或 材料含水率而異,例如可設定加熱溫度〜t,加壓 壓力30〜20 0kg/cm2、成型時間3〜60秒範圍’亦可設定和 上述實施例相同。 混合材料構成的泥漿1 4係按此等原料之混配比例,將 植物纖維粉末材料40〜90%、虫膠溶液的粘合劑5〜4〇% 氧化欽之除臭、漂白殺菌劑1〜、生物分解性蠟1〜 4〇%、碳酸鈣,其餘為水,加以混合製成。 植物纖維粉末材料係由粉碎至5 〇〜3 5 〇網目的細粉所426594------------------- V. Description of the invention (19) and biodegradable wax for improving water resistance (steps 41 to 43). Mud 1 4 (step 4 6). In this case, a deodorant, a white sterilized titanium oxide ', and an extender calcium carbonate may be added to the slurry 14 (steps 44 and 45). On the other hand, a sheet made of a biodegradable material and / or a non-woven sheet is prepared (step 47), and the sheet is coated with the slurry 14 by dip coating or spray coating (step 48), and is prepared in The sheet is impregnated with the sheet 11 of the slurry 14 of the biodegradable material (step 49). Next, the sheet 11 is dried (step 50). The dried sheet 11 is laminated in one or two or more sheets (step 51). Next, the laminated sheet 11 is heat-pressed into a predetermined shape (step 52), and a predetermined biodegradable material container 18 is formed (step 53). In the step of laminating sheet 11, as shown in FIG. 10 (C), filler 19 is appropriately interposed between sheets 11, and the heat insulation, heat resistance, thickness and strength of container 18 can be adjusted. The filler 19 can be made of, for example, a biodegradable material such as a hawthorn fiber powder material, a sheet-like woven fabric and / or a non-woven fabric, or a mineral raw material such as calcium carbonate, calcium hydroxide, calcium oxide, titanium oxide, and mica powder. The compression molding conditions for the heating and pressing of the sheet 11 vary depending on the material mixing ratio or the material moisture content. For example, the heating temperature can be set to t, the pressure can be set to 30 to 20 kg / cm2, and the molding time can range from 3 to 60 seconds. It can be set to be the same as the above embodiment. Based on the mixing ratio of these raw materials, the slurry 14 is composed of 40 to 90% of plant fiber powder material and 5 to 40% of the binder of shellac solution. 1. Biodegradable wax 1 ~ 40%, calcium carbonate, the rest is water, and it is made by mixing. Plant fiber powder material is made from fine powder crushed to 50-35 mesh.

-4 26 5 9 4 五、發明說明(20) 構成。稻殼可 屑、绵絮、洋 材料。此等植 ,亦可呈較粗 虫膠可添 肪酸、結稀聚 、硬遞青,及 搆成片材 器等將纖維互 解性樹脂、絹 。亦可添加沸 為提1¾耐 植物堪、礦物 物之材料。生 以上之物即可 的用途。在容 劑更好。而且 料。 椰殼、蔗渣、木 混合 添加選自竹、 麻、紙进 、甘蔗、稻草、椰殼、席/旦 物村料it ί植物材料,⑨其二種以上之混合 的粉碎拉ή碎成粉末為佳,視容器1 8的用途 加選自. 合物、 、松香、蒸餾妥爾油、妥爾油^ 其二羸粉、明膠、酪朊、達瑪、阿拉伯膠 之Η 4以上之混合物等材料,做為粘合劑。 相總八織布和/或不織布,係由例如以噴水 :之棉材、木綿、麻材、苧麻、生物分 i或天然材料等,或碳纖、玻纖等所製成 居性炭等做為除臭劑或漂白殺菌劑》 所用生物分解性蠟’可添加例如選自動 壤、石油蠟等天然蠟,及其二種以上的混合 物刀解性蠟一般耐熱性弱,例如觸及10 〇 c 能熔解,塗於容器18表面時,必須考慮容器 器1表面塗佈生物分解性壤時,以使用矽塗 在泥毁14添加滑粉和/或雲母等無機質填 一上述製成的泥漿U於片材η含浸之步驟,如第8圖所 不,係將從捲取片材U的筒管12拉出的片材η,以浸入槽 13内所裝泥漿μ之狀態通過而達成。又,浸於槽13内泥漿 的片材11 ’係利輪送輥1 6送出,送到設有加熱器2 7之乾 躁,15。另外,在輸送輥16前方等附近可設刮板2〇等,以 調節片材11的厚度。片材U通過乾燥機15,即可將含浸於-4 26 5 9 4 V. Description of Invention (20) Composition. Rice husks can be crumbs, cotton, and foreign materials. These plants can also be thicker shellac, which can add fatty acids, agglomerate, harden green, and form a sheet device to dissolve fibers, resins, and silk. It is also possible to add boiling materials that are resistant to plants and minerals. It can be used for all the above things. Better in containers. And expected. Coconut husk, bagasse, and wood are added and selected from bamboo, linen, paper feed, sugar cane, straw, coconut husk, mat / danwu village material it ί plant material, ⑨ two or more kinds of mixed pulverized and crushed into powder as Good, depending on the purpose of the container 18, plus materials selected from the group consisting of compounds, rosin, distilled tall oil, tall oil ^ the second powder, gelatin, casein, dammar, gum arabic, etc. 4 or more mixtures and other materials As a binder. The woven fabric and / or non-woven fabric are made of, for example, water-sprayed cotton, wood wool, linen, ramie, bio-based or natural materials, or carbon fiber, glass fiber, etc. Deodorant or bleaching bactericide "The biodegradable wax used can be added, for example, natural waxes, petroleum wax and other natural waxes, and mixtures of two or more of them. Knife-dissolving waxes generally have low heat resistance, for example, they can melt when they reach 10 ℃. When coating on the surface of the container 18, it is necessary to consider that when the surface of the container 1 is coated with biodegradable soil, a silicon coating is used to add mud and / or mica and other inorganic substances to the mud. The η impregnation step, as shown in FIG. 8, is performed by passing the sheet η pulled out from the bobbin 12 of the winding sheet U in a state of being immersed in the slurry μ contained in the tank 13. In addition, the sheet 11 'immersed in the mud in the tank 13 is sent out by a sharp roller 16 and sent to a dry 15 provided with a heater 27. In addition, a squeegee 20 or the like may be provided near the front or the like of the conveying roller 16 to adjust the thickness of the sheet 11. The sheet U can be impregnated by passing through the dryer 15

426594 五、發明說明(21) 片材11之泥漿14乾燥定型。含浸泥漿14的片材11,係例如 在乾燥機3内,於100 °C左右進行乾燥1 一 2小時。乾燥過的 片材11如第9圖所示,利用上模21和下模22所構成具有加 熱器24之加熱成型壓機17,利用控制器26把加熱器24的溫 度或加壓裝置25之施壓力,控制在例如1〇〇〜250 °C、30〜 2 00kg/cm2和3〜60秒範圍的條件,壓機重複1〜3次成型, 接著對成型體的容器18修邊等,容器18即告完成。此時, 谷器18成型取出後剩餘的片材n,可廢棄或捲取於筒管。 容器18製造時,片材11不加以積層,如第1〇圖(人)所 示,將片材11加熱加壓成型以製成容器18。再者,在此生 物分解性材料製容器之製法中’對要求強度等用途所用容 器18’如第10圖⑻所示,將片材11至少二片以上(圖示為 層之片材11加熱加壓成型為具有預定 :狀二:益18。片材積層月數’因所製造容器18之種類而 異。例如可積層5片片材。或者在此生 器之製法中,製造要求耐熱性、隔熱:等刀解Λ材料/容 第圖(c鴻示,將具有該項功能之/料等做之二器18時 片材11間’即可將積層之片材^和填 為填科配置在'426594 V. Description of the invention (21) The slurry 14 of the sheet 11 is dried and shaped. The sheet 11 impregnated with the slurry 14 is, for example, dried in a dryer 3 at about 100 ° C for 1 to 2 hours. As shown in FIG. 9, the dried sheet 11 uses a heating molding press 17 having a heater 24 constituted by an upper mold 21 and a lower mold 22, and a controller 26 is used to control the temperature of the heater 24 or the pressure device 25. Apply pressure to control conditions such as 100 ~ 250 ° C, 30 ~ 200kg / cm2, and 3 ~ 60 seconds. The press repeats the molding process 1 ~ 3 times, and then trims the container 18 of the molded body, etc. 18 is now complete. At this time, the sheet n remaining after the shaper 18 is taken out can be discarded or taken up in a bobbin. When the container 18 is manufactured, the sheet 11 is not laminated. As shown in FIG. 10 (person), the sheet 11 is heated and press-molded to form the container 18. In addition, in the method for manufacturing a container made of biodegradable materials, as shown in FIG. 10 (a), the container 18 used for applications requiring strength and the like is used to heat at least two or more sheets 11 (the sheet 11 shown as a layer is heated) The pressure molding has a predetermined shape: shape 2: benefit 18. The number of months of laminated sheets varies depending on the type of container 18. For example, five sheets can be laminated. In the production method of this device, heat resistance, Insulation: wait for the solution of the Λ material / capacity picture (c), and use the material / material with this function to make the second device at 18 o'clock and 11 sheets can be used to fill the laminated sheets ^ Configured in '

型。另外,填料19以纖維材料等構成多孔二吐加熱加壓成 孔:之空氣即形成隔熱層,λ為提高隔埶、’存在於多 體等裝入容器18内時,容器18外側 ;t。例如將熱液 J器18可例如先用於餐具:太匕處理方便。 !二::做植蛛、花盆等植物栽上 1§18的素村會因微生物玷厶銥此田.各 五、發明說明(22) 11圖說明本發明生物分解性材料製容器 0 是不用月狀織布和/或不織布,而是以 法,把泥槳本身抄成片狀而成型為片材 分解性材科製容器之製法,主要是將至 成份的植物纖維粉末材料、虫膠粉末和 生物分解拉蝶之泥漿14乾燥,製成片材 熱加壓成炎為具有預定形狀之容器。此 容器之製造步帮’例如第11圖所示,把 (步驟Η ),把篩目小的篩3 1浸於裝泥漿 ),搖動篩31,使泥漿14 一部份在篩31 (步驟J )。取出篩3 1,把篩3丨上泥漿i 4 片村30(步驟K)。從定著於篩31上 定型(步驟L),把篩31倒轉’使片材3〇 材20乾燥’製成片材η。片材30按第1〇 型容器18。 10圖(C)所示,可將片材3〇乾燥所得片 器18。積1步驟係將至少含有植物纖維 解性材料之填料19,適度介置於片材11 1 8之隔熱性、耐熱性、厚度及強度。 崩解’轉化為無害的土壌、HW'CO2’或在自然界回歸為 痛物。 其次,參照第 製法之其他實施例 本實施例製法 例如抄纸之同樣方 30。亦即,此生物 少含有以稻殼為主 /或虫膠溶液,及 30,再將片材30加 生物分解性材料製 泥漿14裝入槽13内 14的槽13内(步驟I 上呈擴散狀態移動 定著呈片狀,製成 材3 0過濾水份加以 從篩3 1脫落。將片 圖所示同樣方法成 此實施例如第 材11積層,製成容 粉末材料的生物分 間,即可調節容器 第26,頁 426594 圖式簡單說明 第1圖為本發明生物分解性材料製容器之製法中容器 製造步驟方塊圖; ' 第2圖為本發明生物分解性材料製容器之製法中所用 製造裝置概略說明圖; 第3圖為本發明生物分解性材料製容器之製法中容器 製造步驟另一實施例方塊圖; 第4圖為本發明生物分解性材料製容器之製法中織布 和/或不織布所構成容器製造步驟說明圖; 第5圖為在第2圖製造裝置設有控制器的實施例概略說 明圖; 第6圖為本發明生物分解性材料製容器之製法中容器 製造步驟次一實施例方塊圖; 第7圖為本發明生物分解性材料製容器之製法中容器 製造步驟又一實施例方塊圖; 第8圖為本發明生物分解性材料製容器之製法所用製 造裝置實施例概略說明圖; 第9圖為本發明生物分解性材料製容器之製法製造裝 置内的加熱加壓裝置實施例概略說明圖; 第10圖為本發明生物分解性材料製容器之製法所用不 同素材的製造步驟實施例概略說明圖; 第11圖為本發明生物分解性材料製容器之製法另一實 施例之製造步驟說明圖。type. In addition, the filler 19 is made of a fibrous material and formed into a porous two-tube heating and pressure hole: the air forms a heat insulation layer, and λ is to increase the barrier, 'is present in the multi-body, etc., when placed inside the container 18, the outside of the container 18; t . For example, the hydrothermal device 18 can be used for tableware, for example: it is easy to handle. Two :: Planting spiders, flowerpots and other plants and planting 1§18 in the village will be due to microorganisms 玷 厶 iridium in this field. Each 5. Description of the invention (22) 11 Figures illustrate the container made of biodegradable materials of the present invention 0 Yes Instead of using a moon-shaped woven fabric and / or a non-woven fabric, the method is to make the mud paddle itself into a sheet shape to form a sheet-decomposable material scientific container, which is mainly composed of plant fiber powder material and shellac. The powder and the biodegradable mud 14 of the butterfly are dried, and the sheet is heat-pressed into a container having a predetermined shape. For example, as shown in FIG. 11, the manufacturing steps of this container are immersed (step Η) and the small sieve 31 into the slurry), and the sieve 31 is shaken so that a part of the slurry 14 is on the sieve 31 (step J ). Take out the sieve 31 and put the sieve 3 into the mud i 4 piece 30 (step K). From the set on the sieve 31 (step L), the sieve 31 is inverted and the sheet 30 is dried to make the sheet η. The sheet material 30 is a 10th type container 18. As shown in FIG. 10 (C), the sheet 30 can be dried to obtain the tablet 18. The product 1 step is a method in which a filler 19 containing at least a plant fiber decomposable material is appropriately interposed in the heat insulation, heat resistance, thickness and strength of the sheet 11 1 8. Disintegration 'turns into harmless soil, HW'CO2', or returns to pain in nature. Next, reference is made to other embodiments of the manufacturing method. The manufacturing method of this embodiment is, for example, the same method as paper making. That is, this organism contains less rice husks and / or shellac solution, and 30, and then the sheet 30 plus the biodegradable material slurry 14 is filled into the tank 13 in the tank 13 (diffusion in step I) The state of movement is in the shape of a sheet, and the finished material 30 is filtered and detached from the sieve 31. The same method shown in the sheet diagram is used to form this example. The material 11 is laminated to make a biological compartment containing powder material. Conditioning container No. 26, p. 426594 Brief description of the drawing Figure 1 is a block diagram of the container manufacturing steps in the method for manufacturing a container made of biodegradable materials according to the present invention; 'Figure 2 is the manufacturing method used in the method for manufacturing a container made of biodegradable materials according to the present invention A schematic illustration of the device; FIG. 3 is a block diagram of another embodiment of a container manufacturing step in a method for manufacturing a container made of a biodegradable material according to the present invention; and FIG. 4 is a woven fabric and / or in the method for manufacturing a container made of a biodegradable material according to the present invention. An explanatory diagram of the manufacturing steps of a container made of a non-woven fabric; FIG. 5 is a schematic explanatory diagram of an embodiment in which a manufacturing device is provided with a controller in FIG. 2; and FIG. 6 is a container manufacturing step in a method for manufacturing a container made of a biodegradable material according to the present invention. Block diagram of the next embodiment; FIG. 7 is a block diagram of another embodiment of a container manufacturing step in a method for manufacturing a container made of a biodegradable material according to the present invention; and FIG. 8 is an implementation of a manufacturing apparatus used for a method for manufacturing a container made of a biodegradable material according to the present invention Example is a schematic illustration; FIG. 9 is a schematic illustration of a heating and pressurizing device in a manufacturing method of a biodegradable material container manufacturing method according to the present invention; and FIG. 10 is a different material used in a method of manufacturing a biodegradable material container according to the present invention FIG. 11 is a schematic explanatory diagram of an embodiment of a manufacturing process of the present invention; FIG. 11 is an explanatory diagram of a manufacturing process of another embodiment of a method for manufacturing a container made of a biodegradable material according to the present invention.

第27頁Page 27

Claims (1)

^" 426 59 4 六、申請專利範圍 1. 一種生物分解性材料組成物,係由稻殼為主成份的 植物原料粉末,與含粘合劑之生物分解性物質混合而成之 混合材料所構成者。 2. 如申請專利範圍第1項之生物分解性材料組成物, 其中該混合材料之混配比例,係該植物原料粉末6 0〜9 0 % 和該生物分解性物質10〜40%者。 3. 如申請專利範圍第1項之生物分解性材料組成物, 其中對該混合材料加水者。 4. 如申請專利範圍第1項之生物分解性材料組成物, 其中該植物原料係於稻殼混配選自竹、甘蔗、稻草、紙漿 ,及其二種以上的混合原料之植物纖維者。 5. 如申請專利範圍第1項之生物分解性材料組成物, 其中該生物分解性物質係由松香、達瑪樹脂、科巴樹脂、 明膠、澱粉、虫膠、碳酸鈣、生物分解性塑膠,或其混合 粉末所構成者。 6. 如申請專利範圍第1項之生物分解性材料組成物, 其中該生物分解性物質中的該粘合劑,係由松香、達瑪樹 脂、科巴樹脂、明膠、澱粉、虫膠,或其混合粉末所構成 者。 7. 如申請專利範圍第1項之生物分解性材料組成物, 其中於該混合材料混合氧化防腐劑和/或漂白劑者。 8. 如申請專利範圍第1項之生物分解性材料組成物, 其中該稻殼係使用乾燥稻經轘米而從糙米分離之稻殼者。 9. 如申請專利範圍第1項之生物分解性材料組成物,^ " 426 59 4 VI. Scope of patent application 1. A biodegradable material composition, which is a mixed material made of rice husk-based plant raw material powder and a biodegradable material containing a binder Constructor. 2. For example, the biodegradable material composition of the scope of application for the patent, wherein the mixing ratio of the mixed material is 60 ~ 90% of the plant raw material powder and 10 ~ 40% of the biodegradable material. 3. If the biodegradable material composition of item 1 of the patent application scope, wherein the mixed material is watered. 4. The biodegradable material composition according to item 1 of the patent application scope, wherein the plant raw material is a rice husk mixed with plant fiber selected from bamboo, sugarcane, straw, pulp, and two or more mixed raw materials. 5. If the biodegradable material composition of item 1 of the patent application scope, wherein the biodegradable material is made of rosin, dammar resin, coba resin, gelatin, starch, shellac, calcium carbonate, biodegradable plastic, Or its mixed powder. 6. The biodegradable material composition according to item 1 of the application, wherein the binder in the biodegradable material is made of rosin, dammar resin, coba resin, gelatin, starch, shellac, or It consists of mixed powder. 7. The biodegradable material composition according to item 1 of the patent application scope, wherein an oxidation preservative and / or a bleaching agent is mixed with the mixed material. 8. The biodegradable material composition according to item 1 of the application, wherein the rice husk is a rice husk separated from brown rice by drying rice with indica. 9. If the biodegradable material composition of item 1 of the patent application scope, 第28頁 4 26 59 4 六、申請專利範圍 其中於該混合材料混合生物分解性物質製成之織布和/或 不織布者。 1 0. —種生物分解性材料製容器,係將申請專利範圍第 1至9項之生物分解性材料組成物加熱加壓而壓縮成型者。 11. 一種生物分解性材料製容器之製法,包括步驟為, 將稻殼為主成份的植物原料粉碎所得植物原料粉末,與含 粘合劑的生物分解性物質粉碎所得生物分解性原料粉末, 均勻混合以製成混合原料粉末,再將該混合原料粉末加熱 加壓而壓縮成型為容器形狀者。 1 2.如申請專利範圍第11項生物分解性材料製容器之製 法,其中於該混合原料粉末加水者。 1 3.如申請專利範圍第1 1項生物分解性材料製容器之製 法,其中該植物原料粉末和該生物分解性原料粉末,係分 別粉碎至5 0〜3 0 0網目之細粉者。 1 4.如申請專利範圍第1 1項生物分解性材料製容器之製 法,其中該混合原料粉末之壓縮成型條件係溫度1 0 0〜2 0 0 °C、壓力20〜80kg/cm2、成型時間3〜40秒間範圍者。 1 5.如申請專利範圍第1 1項生物分解性材料製容器之製 法,其中該混合原料粉末經壓縮成型形成之該容器厚度, 在0.5ιηπι以上者。 16. 如申請專利範圍第11項生物分解性材料製容器之製 法,其令該混合原料粉末經壓縮成型形成之該容器傾斜角 度在1 5 °以上者。 17. 如申請專利範圍第11項生物分解性材料製容器之製 426594 六、申請專利範圍 法,其中該混合原料粉末係由該植物原料6 0〜9 0 %和該生 物分解性物質1 0〜4 0 %混合而得者。 1 8.如申請專利範圍第1 1項生物分解性材料製容器之製 法,其中該植物原料係於稻殼混配選自竹、甘蔗、稻草、 紙漿,及其二種以上的混合原料之植物纖維者。 19. 如申請專利範圍第11項生物分解性材料製容器之製 法,其令該生物分解性物質係由松香、達瑪樹脂、科巴樹 脂、明膠、澱粉、虫膠、碳酸鈣、生物分解性塑膠,或其 混合粉末所構成者〇 20. 如申請專利範圍第11項生物分解性材料製容器之製 法,其中該生物分解性物質中的該枯合劑,係由松香、達 瑪樹脂、科巴樹脂、明膠、澱粉、虫膠,或其混合粉末所 構成者。 2 1.如申請專利範圍第1 1項生物分解性材料製容器之製’ 法,其中於該混合原料粉末混合氧化防腐劑和/或漂白劑 者。 2 2.如申請專利範圍第1 1項生物分解性材料製容器之製 法,其中該稻殼係使用乾燥稻經輾米而從糙米分離之稻殼 者。 2 3.如申請專利範圍第11項生物分解性材料製容器之製 法,包括將該混合原料粉末加熱加壓成型,製成中間成型 體,接著,於該中間成型體表面上配置生物分解性物質製 成的織布和/或不織布,製成成型體,再將該成型體加熱 加壓而壓縮成型為預定形狀者。Page 28 4 26 59 4 VI. Scope of patent application Where woven and / or non-woven fabrics made of biodegradable substances are mixed with the mixed material. 1 0. A container made of a biodegradable material, which is formed by heating and pressing the biodegradable material composition in the range of claims 1 to 9 of the patent application. 11. A method for manufacturing a container made of a biodegradable material, comprising the steps of: pulverizing a plant raw material powder obtained from a rice husk as a main component; and pulverizing a biodegradable raw material powder obtained by pulverizing a biodegradable material containing a binder; Those who mix to make a mixed raw material powder, and then heat and press the mixed raw material powder to compression-mold into a container shape. 1 2. The method for manufacturing a container made of a biodegradable material according to item 11 of the scope of patent application, wherein water is added to the mixed raw material powder. 1 3. The method for manufacturing a container made of a biodegradable material according to item 11 of the scope of patent application, wherein the plant raw material powder and the biodegradable raw material powder are pulverized to a fine powder of 50 to 300 mesh. 1 4. The method for manufacturing a container made of biodegradable materials according to item 11 of the scope of the patent application, wherein the compression molding conditions of the mixed raw material powder are temperature 100 to 2 0 0 ° C, pressure 20 to 80 kg / cm2, and molding time. Those with a range of 3 to 40 seconds. 1 5. The method for manufacturing a container made of a biodegradable material according to item 11 of the scope of the patent application, wherein the thickness of the container formed by the compression molding of the mixed raw material powder is more than 0.5 μm. 16. For the method for manufacturing a container made of biodegradable materials according to item 11 of the scope of patent application, the inclination angle of the container formed by compression molding of the mixed raw material powder is more than 15 °. 17. For example, the scope of application for patent No. 11 for the manufacture of containers made of biodegradable materials 426594 6. The method of applying for patent scope, wherein the mixed raw material powder is 60 ~ 90% of the plant raw materials and the biodegradable material is 10 ~ 40% mixed winner. 1 8. The method for manufacturing a container made of biodegradable materials according to item 11 of the scope of the patent application, wherein the plant material is a plant made of rice husk mixed with bamboo, sugarcane, straw, pulp, and two or more mixed materials Fiber. 19. If the method for manufacturing a container made of biodegradable materials according to item 11 of the patent application, the biodegradable substance is made of rosin, dammar resin, coba resin, gelatin, starch, shellac, calcium carbonate, and biodegradability. Plastics, or their mixed powders. 20. For the method for manufacturing containers made of biodegradable materials under the scope of application for patent No. 11, wherein the cumulant in the biodegradable substances is made of rosin, dammar resin, coba Resin, gelatin, starch, shellac, or mixed powders. 2 1. The method for manufacturing a container made of a biodegradable material according to item 11 of the scope of patent application, wherein an oxidizing preservative and / or a bleaching agent is mixed with the mixed raw material powder. 2 2. The method for manufacturing a container made of a biodegradable material according to item 11 of the patent application scope, wherein the rice husk is a rice husk separated from brown rice by rolling dried rice. 2 3. The method for manufacturing a container made of a biodegradable material according to item 11 of the scope of the patent application includes heating and pressing the mixed raw material powder to form an intermediate molded body, and then disposing a biodegradable substance on the surface of the intermediate molded body. The finished woven fabric and / or non-woven fabric are formed into a molded body, and the molded body is then heated and pressurized to be compression-molded into a predetermined shape. 第30頁 426594 六、申請專利範圍 24.如申請專利範圍第11項生物分解性材料製容器之製 法,包括將該混合原料粉末製成的泥漿,塗佈於生物分解 性物質製成的織布和/戒不織布,乾燥而製成片材,於該 片材積層該混合材料,一體加熱加壓而壓縮成型為預定形 狀者。 2 5. —種生物分解性材料製容器之製法,包括將至少含 有稻殼為主成份之植物纖維粉末材料、虫膠粉末和/或虫 膠溶液,及生物分解性蠟之泥漿,利用塗佈或浸潰以含浸 於生物分解性物質製成的片狀織布和/或不織布後,乾燥 而製成片材,接著將該片材加熱加壓而壓縮成型為具有預 定形狀之容器者。 2 6.如申請專利範圍第2 5項生物分解性材料製容器之製 法,其中於該泥漿添加氡化鈦和碳酸鈣等無機質填料者。 2 7.如申請專利範圍第2 6項生物分解性材料製容器之製 法,其中該虫膠粉末和/或虫膠溶液至少有粘合劑和耐水 性材料之功用,該氧化鈦至少有除臭劑和漂白殺菌劑之功 用,而該生物分解性蠟至少具有耐水性材料、離型材料和 撥水材料之功用者。 2 8.如申請專利範圍第2 5項生物分解性材料製容器之製 法,其中壓縮成型之該片材,係由一片或積層之複數片所 構成者。 2 9.如申請專利範圍第2 8項生物分解性材料製容器之製 法,其中該片材之積層步驟,係將含有該植物纖維粉末材 料、該片狀織布和/或不織布等生物分解性材料之填料,Page 30 426594 VI. Application for Patent Scope 24. The method for manufacturing a container made of biodegradable materials such as the scope of patent application No. 11 includes applying a slurry made of the mixed raw material powder to a woven fabric made of a biodegradable material. And / or non-woven fabric, dried and made into a sheet, and the mixed material is laminated on the sheet, and is integrally heated and pressurized to be compression-molded into a predetermined shape. 2 5. —A method for manufacturing a container made of biodegradable materials, comprising applying a plant fiber powder material containing at least rice husk as a main component, shellac powder and / or shellac solution, and a slurry of biodegradable wax, using a coating Or it is impregnated with a sheet-like woven fabric and / or a non-woven fabric made by being impregnated with a biodegradable substance, and then dried to form a sheet, and then the sheet is heated and pressed to be compression-molded into a container having a predetermined shape. 2 6. The method for manufacturing a container made of biodegradable materials according to item 25 of the scope of patent application, wherein an inorganic filler such as titanium halide and calcium carbonate is added to the slurry. 2 7. The method for manufacturing a container made of biodegradable materials according to item 26 of the patent application, wherein the shellac powder and / or shellac solution has at least the function of a binder and a water-resistant material, and the titanium oxide has at least deodorization. And bleaching fungicide, and the biodegradable wax has at least the functions of water-resistant materials, release materials and water-repellent materials. 2 8. The method for manufacturing a container made of a biodegradable material according to item 25 of the scope of the patent application, wherein the compression-molded sheet is composed of one sheet or a plurality of laminated sheets. 2 9. The method for manufacturing a container made of biodegradable material according to item 28 of the scope of the patent application, wherein the step of laminating the sheet is to contain the biodegradability of the plant fiber powder material, the sheet-like woven fabric and / or non-woven fabric. Filler of material, 第31頁 ^" 426 5 94 六、申請專利範圍 適度介置於該片材間,以調節容器之隔熱性、耐熱性、厚 度和強度者。 3 〇.如申請專利範圍第2 5項生物分解性材料製容器之製 法,其中在該片材加熱加壓成型之該容器表面,塗佈該生 物分解性蠟和矽塗劑者。 31.如申請專利範圍第25項生物分解性材料製容器之製 法,其中該植物纖維粉末材料係由粉碎至5 0〜3 5 0網目之 細粉所構成者。 3 2.如申請專利範圍第2 5項生物分解性材料製容器之製 法,其中該片材之加熱加壓成型條件係:溫度100〜250 °C 、壓力30〜2 0 0 kg/cm2、成型時間3〜60秒間範圍者β 33.如申請專利範圍第25項生物分解性材料製容器之製 法,其中該泥漿係由該植物纖維粉末材料4 0〜9 0 %、該虫 膠溶液5〜40%、該氧化鈦1〜30%、該生物分解性蠟1〜 4 0 %、該碳酸鈣1〜2 0 %,其餘為水或有機溶劑,混合製 成者。 3 4.如申請專利範圍第2 5項生物分解性材料製容器之製 法,其中於該稻殼添加選自竹、甘蔗、稻草、椰殼、蔗渣 、木屑、洋麻、棉絮、紙漿等植物材料,及其二種以上混 合材料者。 3 5.如申請專利範圍第1 5項生物分解性材料製容器之製 法,其中於該泥漿添加選自科巴樹脂、松香、蒸餾妥爾油 、妥爾油脂肪酸、萜烯聚合物、澱粉、明膠、酪朊、達瑪 樹脂、阿拉伯膠、硬瀝青,及其二種以上混合材料之粘合Page 31 ^ " 426 5 94 6. Scope of patent application Those that are moderately placed between the sheets to adjust the heat insulation, heat resistance, thickness and strength of the container. 30. The method for manufacturing a container made of a biodegradable material according to item 25 of the scope of the patent application, wherein the surface of the container formed by heating and pressure molding of the sheet is coated with the biodegradable wax and a silicon coating agent. 31. The method for manufacturing a container made of a biodegradable material according to item 25 of the application, wherein the plant fiber powder material is composed of a fine powder pulverized to a mesh of 50 to 350 mesh. 3 2. According to the method for manufacturing a container made of biodegradable materials according to item 25 of the scope of the patent application, the heating and pressing molding conditions of the sheet are: temperature 100 ~ 250 ° C, pressure 30 ~ 200 kg / cm2, molding Time within the range of 3 to 60 seconds β 33. For example, the method for manufacturing a container made of biodegradable materials in the scope of application for patent No. 25, wherein the slurry is made from the plant fiber powder material 40 ~ 90%, and the shellac solution 5 ~ 40 %, The titanium oxide 1 to 30%, the biodegradable wax 1 to 40%, the calcium carbonate 1 to 20%, and the balance is water or an organic solvent, which are prepared by mixing. 3 4. The method for manufacturing a container made of biodegradable materials according to item 25 of the scope of patent application, wherein the rice husk is added with a plant material selected from the group consisting of bamboo, sugar cane, straw, coconut husk, bagasse, wood chips, kenaf, cotton wool, and pulp. , And two or more mixed materials. 3 5. The method for manufacturing a container made of biodegradable materials according to item 15 of the scope of patent application, wherein the mud is added with a material selected from the group consisting of Cobar resin, rosin, distilled tall oil, tall oil fatty acid, terpene polymer, starch, Gelatin, casein, dammar resin, gum arabic, hard asphalt, and the bonding of two or more mixed materials 第32頁 4265^4 六、申請專利範圍 劑者。 36. 如申請專利範圍第25項生物分解性材料製容器之製 法,其中於該泥i添加沸石和/或活性炭之除臭殺菌劑 者。 37. 如申請專利範圍第25項生物分解性材料製容器之製 法,其中該生物分解性蠟添加選自動植物蠟、礦物蠟、石 油蠟等天然蠟,及其二種以上混合材料者。 3 8.如申請專利範圍第2 5項生物分解性材料製容器之製 法,其中於該泥漿添加滑粉和/或雲母等無機質填料者。 3 9.如申請專利範圍第2 5項生物分解性材料製容器之製 法,其中該泥漿對該片材之含浸步驟,係令筒管抽出的該 片材,以浸入槽内所裝該泥漿之狀態通過而達成者。 4 0.—種生物分解性材料製容器之製法,包括將至少含 有稻殼為主成份之植物纖維粉末材料、虫膠粉末和//或虫 膠溶液,及生物分解性蠟之泥漿,加以乾燥製成片材,再 將該片材加熱加壓而壓縮成型為具有預定形狀之容器者。 4 1 .如申請專利範圍第40項生物分解性材料製容器之製 法,其中該片材積層步驟係將至少含有該植物纖維粉末材 料的生物分解性材料之填料,適度介置於該片材間,以調 節容器之隔熱性、耐熱性、厚度和強度者。 4 2.如申請專利範圍第40項生物分解性材料製容器之製 法,其中由該泥漿製造該片材之步驟,係將篩浸入槽内所 裝之該泥漿,令該泥漿在該篩上擴散,從該槽取出該篩, 將該泥漿乾燥而達成者。Page 32 4265 ^ 4 VI. Patent applicants. 36. The method for manufacturing a container made of a biodegradable material according to item 25 of the patent application, wherein a zeolite and / or activated carbon deodorant fungicide is added to the mud. 37. For example, the method for manufacturing a container made of biodegradable materials according to the scope of application for patent No. 25, wherein the biodegradable wax is added with natural waxes such as automatic vegetable wax, mineral wax, paraffin wax, and two or more kinds of mixed materials. 3 8. The method for manufacturing a container made of biodegradable materials according to item 25 of the scope of patent application, wherein an inorganic filler such as slip powder and / or mica is added to the slurry. 3 9. According to the method for manufacturing a container made of biodegradable materials according to item 25 of the scope of the patent application, wherein the step of impregnating the sheet with the slurry is to make the sheet withdrawn from the bobbin to immerse the slurry in the tank. Those who pass the state. 4 0. A method for manufacturing a container made of biodegradable material, comprising drying plant fiber powder material containing at least rice husk as a main component, shellac powder and / or shellac solution, and slurry of biodegradable wax, and drying the same Those who make a sheet, and then heat and press the sheet and compressively mold it into a container having a predetermined shape. 41. The method for manufacturing a container made of a biodegradable material according to item 40 of the scope of the patent application, wherein the step of laminating the sheet is to appropriately place a filler of the biodegradable material containing at least the plant fiber powder material between the sheet material In order to adjust the thermal insulation, heat resistance, thickness and strength of the container. 4 2. The method for manufacturing a container made of biodegradable material according to item 40 of the scope of patent application, wherein the step of manufacturing the sheet from the slurry is to immerse the sieve into the slurry contained in the tank, so that the slurry spreads on the sieve , Take out the sieve from the tank, and dry the slurry to achieve it. 第33頁Page 33
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CN111117273A (en) * 2019-11-25 2020-05-08 东莞市凯成环保科技有限公司 Antibacterial oleophobic plant fiber tray and preparation method thereof
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WO2007079648A1 (en) * 2006-01-10 2007-07-19 Rich Cup Bio-Chemical Technology Co., Ltd. Method for producing paper or plastic container of heat insulation, heat preservation and scald prevention and the same container obtained thereby
TWI496828B (en) * 2012-05-16 2015-08-21 Cheng Pang Chong Preparation of a Rice Fiberglass Synthetic Resin Powder and Rice Husk Fiber Product

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KR20000057885A (en) 2000-09-25

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