4614pif doc/〇〇6 A7 ^21678 _ _____B7_ 五、發明說明（/) 本發明是有關於一種含有少量添加物之聚酯纖維和 纖絲及其製造方法。 通常含有少量添加物的纖維或纖絲於經過與拉線速 率大約相同的熔融抽絲（melt spinning)過程時，如所形成的 產物爲不具延展性的紗線，則很容易導致斷裂。例如歐洲 專利0 041 327 B1所描述添加液晶物質(LC聚合物）之聚酯 混合物，其添加的液晶物質極爲昂貴，且可能會導致抽絲 過程產生問題，並且可能會產生紗線的不規則性與纖維的 斷裂等問題。 歐洲專利0 080 274 Bi描述對纖維形成聚合物聚對苯 二甲酸乙二醇醋（polyethylene terephthalate)添加聚己二酿己 二胺（polyhexamethylene adipamide)和衆艺二醇（polyethylene glycol) ’但其會導致致斷伸長性（elongation at break)增力口， 使對其混合物進行抽絲時會產生問題。因此纖維斷裂之情 況經常發生，參考第1表與第2表（添加物AS2503、A3和 A4)。歐洲專利0 080 274 B1中描述除了例如爲聚乙烯 (polyethylene)和聚丙稀（polypropylene)和聚烯烴（polyolefin) 外，連同聚£-己內醯胺（poly-epsilon-caproamide)均爲無法 與聚對苯二甲酸乙二醇酯相混合的聚合物。根據其實施例 與申請專利範圍得知，除了聚乙二醇外，如以聚己二醯己 二胺當作添加物，則會使習知技藝中所述聚醯胺 6(polyamide 6)之抽絲特性與產物性質比聚醯胺 66(polyamide 66)差，因此不會考慮將其當作添加物。 “不互融聚合物（immiscible polymer)”一詞於本發明中 4 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面V注意事項再填寫本頁) 10裝—4614pif doc / 〇〇6 A7 ^ 21678 _ _____B7_ V. Description of the invention (/) The present invention relates to a polyester fiber and filaments containing a small amount of additives and a method for manufacturing the same. Generally, fibers or filaments containing a small amount of additives undergo a melt spinning process at about the same drawing speed. If the product formed is a non-stretchable yarn, it is easy to cause breakage. For example, the European patent 0 041 327 B1 describes a polyester mixture containing a liquid crystal substance (LC polymer). The added liquid crystal substance is extremely expensive and may cause problems in the spinning process and may cause irregularities in the yarn. Problems with fiber breakage. European Patent 0 080 274 Bi describes the addition of polyethylene terephthalate to the polymer polyethylene terephthalate and polyhexamethylene adipamide and polyethylene glycol 'but it will This results in elongation at break booster openings, which can cause problems when spinning the mixture. Therefore, fiber breakage often occurs. Refer to Tables 1 and 2 (additives AS2503, A3, and A4). European Patent 0 080 274 B1 describes that except for polyethylene and polypropylene and polyolefins, together with poly-epsilon-caproamide, it is not possible to combine with poly-epsilon-caproamide. Polymer blended with ethylene terephthalate. According to the examples and the scope of the patent application, it is known that, in addition to polyethylene glycol, if polyhexamethylene hexamethylene diamine is used as an additive, the polyamine 6 (polyamide 6) described in the conventional art will be used. The spinning properties and product properties are inferior to polyamide 66, so it will not be considered as an additive. The term "immiscible polymer" is used in the present invention. 4 The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). (Please read the V precautions on the back before filling this page.) 10 pack —
^^1 0ΒΚ fM 經濟部智慧財產局員工消費合作社印製 1 46 I 4pif.doc/006 42167 Rd7 J\t ___B7__ 五、發明說明（1) (請先閱讀背面之注意事項再填寫本頁) 係指聚合物於抽絲溫度下會產生具有形成纖維之熱塑性聚 合物的二相熔融物，對熔融物所做微觀的調查與其照片可 以發現其爲二相的系統，於此二相系統中精細切割過之不 互融聚合物會連續性地於纖維形成聚合物主體之中擴散。 於前述的條件下，不互融聚合物位於纖維形成聚合 物之主體中’基本上與同溫度範圍下所形成之非等向性融 化物不同’而此溫度下熱塑性聚合物可能形成融絲。成立 此些非等向性條件之情況爲對例如歐洲專利〇 041 327所 描述之液晶物質添加聚酯抽絲聚合物，然後加熱與進行剪 力所設定的條件。 J. Appl. Polym. Sci·, vol. 55, 57-67(1995) Aslan et al.描 述聚對苯二甲酸乙二醇酯和nylon 6混合物的抽絲情況， 其聚醯胺6之重量百分比濃度爲5%時，抽絲率爲 3600m/rmn，與未含修正物質之情況相比，可降低致斷伸 長性。 經濟部智慧財產局員工消費合作杜印製 於 J. Appl. Polym, Sci., vol.67，723-737(1998) Evstatiev et aL硏究當PET/PA6混合物之重量比爲40/60時分子之交 互作用，以尋求混合物之相容性，而佔有60%之PA6之聚 酯所產生的纖維完全沒有經濟價値。^^ 1 0ΒΚ fM Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1 46 I 4pif.doc / 006 42167 Rd7 J \ t ___B7__ 5. Description of the invention (1) (Please read the precautions on the back before filling this page) Refers to a polymer that produces a two-phase melt with a thermoplastic polymer that forms fibers at the spinning temperature. A microscopic investigation of the melt and its photos can reveal that it is a two-phase system. Fine cutting in this two-phase system Excessively immiscible polymers will continuously diffuse through the fiber-forming polymer body. Under the aforementioned conditions, the immiscible polymer is located in the body of the fiber-forming polymer ' substantially different from the anisotropic melt formed at the same temperature range, and the thermoplastic polymer may form a fuse at this temperature. The case where these anisotropic conditions are established is a condition set by adding a polyester spinning polymer to a liquid crystal substance described in, for example, European Patent 0 041 327, and then heating and performing a shear force. J. Appl. Polym. Sci., Vol. 55, 57-67 (1995) Aslan et al. Described the spinning of a mixture of polyethylene terephthalate and nylon 6, and the weight percentage of polyamide 6 When the concentration is 5%, the drawing rate is 3600m / rmn, and the elongation at break can be reduced compared with the case where no correction substance is contained. Consumption Cooperation between Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by J. Appl. Polym, Sci., Vol. 67, 723-737 (1998) Evstatiev et aL. In order to seek the compatibility of the mixture, the fiber produced by the polyester that occupies 60% of PA6 has no economic value at all.
Aslan et d.弓I用很多將聚酉旨與聚ϋ月安相混合的日本 文獻來當作基礎背景的一部份，J61266616-A(採用Derwent 公司編號）描述降低於高濃度關係下之聚酯/聚醯胺的纖維 性質。·Ι56015414-Α(採用Derwent公司編號）描述添加10〜30% 之聚酯到耐倫6(nylon 6) ’歐洲專利0 047 464 B1描述將 5 本紙張尺度適用中國國家標準（CNS)A4蜆格（210><297公釐） 46 1 4pif-doc/〇〇6 A7 !. 42代飞來 B7 玉、發明說明（g) 很多種的丙烯聚合物，以及特別是聚對苯二甲酸乙二醇酯 之添加物-聚甲基丙嫌酸酯（polymethacrylie acid ester)。 歐洲專利〇 047 464 B1和歐洲專利0 631 638 Bl-後者 描述含亞胺化添加物使抽絲過程可信度受限之較新專利， 使用此些物質表纖維斷裂之情況會增加。 歐洲專利〇 631 638 B1描述纖維聚合物包含有重量百 分比約0.1%~5%之50〜90%亞胺化聚甲基丙烯酸酯。雖然 其並未提供實驗數據，但此種聚合物比歐洲專利047 464 B1 所描述的纖維聚合物更具有良好的抽絲效果。聚甲基丙烯 酸酯添加物具有價格昂貴之缺點，此種亞胺化聚甲基丙烯 酸酯的高成本無法達到經濟上的效應。並且此種添加物也 無法得到大量的供應，使用此種添加物亦即只能仰賴很少 的供應商。 歐洲專利0 631 638 B1並沒有提及所製造的絲被部份 延伸以配合的拉線織造（draw-texturing)製程並避免相關問 題，然後再進行後續程序，因此其提供抽絲速率爲3500、 6000、7000和8000m/min下之致斷伸長性。然而，其致斷 伸長性的數値不適合進一步進行織造製程（texturing process)。因此例如其於抽絲速率爲6000m/min情況下的破 斷伸長約爲65%，具有此種致斷伸長性之紗線並不適合進 行拉線織造製程，如果使用此種紗線可能會出現異於一般 規則之例外情況，適用於拉線織造製程的致斷伸長性約爲 120%，工業與紡織原料使用之高延伸（oriented)紗線具有超 過3500m/min抽絲速率時的致斷伸長性。 6 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁)Aslan et d. Bow I uses a lot of Japanese literature that mixes Juji and Juyuean as part of the basic background. J61266616-A (using Derwent company number) describes the reduction of aggregation under high concentration relationships. Fiber properties of esters / polyamides. · I56015414-A (using Derwent company number) describes adding 10 to 30% of polyester to nylon 6 (nylon 6) 'European patent 0 047 464 B1 describes applying 5 paper sizes to the Chinese National Standard (CNS) A4 grid (210 > < 297 mm) 46 1 4pif-doc / 〇〇6 A7!. 42 generation flying B7 jade, description of the invention (g) many kinds of propylene polymers, and especially polyethylene terephthalate Addition of alcohol ester-polymethacrylie acid ester. European patent 0 047 464 B1 and European patent 0 631 638 Bl-the latter describes newer patents containing imidized additives that limit the credibility of the spinning process, and the use of these substances increases the occurrence of fiber breakage. European patent 0 631 638 B1 describes that the fibrous polymer comprises 50 to 90% of imidized polymethacrylate in an amount of about 0.1% to 5% by weight. Although it does not provide experimental data, this polymer has a better spinning effect than the fiber polymers described in European Patent 047 464 B1. Polymethacrylate additives have the disadvantage of being expensive, and the high cost of such an imidized polymethacrylate cannot achieve economic effects. In addition, such additives cannot be supplied in large quantities, and the use of such additives can only rely on a small number of suppliers. European patent 0 631 638 B1 does not mention that the manufactured yarn is partially extended to cooperate with the draw-texturing process and avoid related problems, and then the subsequent procedures are performed, so it provides a spinning rate of 3500, Elongation at break at 6000, 7000 and 8000 m / min. However, its breaking elongation number is not suitable for further texturing processes. Therefore, for example, its elongation at break at a drawing speed of 6000 m / min is about 65%. A yarn with such a break elongation is not suitable for a draw-string weaving process. If this yarn is used, abnormalities may occur. In the exception of the general rule, the elongation at break applicable to the drawstring weaving process is about 120%, and the high-oriented yarns used in industrial and textile raw materials have a break at elongation at a spinning rate exceeding 3500m / min. . 6 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)
裝-------J 訂---------J 經濟部智慧財產局員工消費合作社印製 4 6 1 4pif.d〇c/0 06 A7 42,飪了 a 4 6 1 4pif.d〇c/0 06 A7 42,飪了 a 經濟部智慧財產局員工消費合作社印製 五、發明說明（十） 於歐洲專利0 530 652 B1中需要抽絲速率6000m/min 之特別的抽絲裝置，其記載噴絲頭下方的空心管（perforated tube)可以延遲冷卻並穩定抽絲過程，此種方法係透過纖絲 移動產生空氣抽送效果而達到被動冷卻的目的，因此抽絲 的過程極爲複雜，此種裝置主要的缺點在於抽絲過程中的 撓性（flexibility)極低。 但歐洲專利〇 530 652 B1中之範例中並未對範圍 4000〜6000m/min之臨界抽絲率作任何評論。而此範圍下抽 絲結晶（spmcrystailizaUon)扮演極爲重要的角色，因爲於此 速率範圍下需使用到橫斷吹氣(transverse blowing)法，而此 極爲重要的速率範圍卻沒有被提及，並且高速率下所需使 用到被動冷卻技術並不適用於高困難之抽絲速率與/或難以 抽絲的聚合物。抽絲速率小於6000m/min之抽絲過程會有 不良情形產生，於此情況下橫斷吹氣法可能僅運用到上述 聚合物混合物的有限範圍，因此易對整個製程造成限制。 雖然過去的文獻述及一些適用於纖維製造的聚合物 混合物，但於歐洲專利0 631 638 B1中爲了確保良好的抽 絲特性，必需使用具有特定抽絲速率之抽絲裝置（請參照 歐洲專利〇 530 652 B1)。 然而，歐洲專利〇 631 638 B1之習知技藝並沒有提及 包含聚顚和聚己一酿己—胺的混合物（歐洲專利〇 〇8〇 274)。 本發明之發明人發現習知技藝並沒有考慮到聚醯胺 和聚對苯二甲酸乙二醇酯的混合物會使溶融物顏色變黃的 7 本紙張尺度適用中國國家標準（CNS>A4規格（210 x 297公釐） (請先閱讀背面之注意事項再填寫本頁)Packing ------- J Order --------- J Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 4 6 1 4pif.d〇c / 0 06 A7 42, cooked a 4 6 1 4pif.d〇c / 0 06 A7 42, printed by a Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of invention (ten) Special drawing of wire drawing speed 6000m / min in European patent 0 530 652 B1. Silk device, which records that the hollow tube (perforated tube) under the spinneret can delay the cooling and stabilize the spinning process. This method achieves the purpose of passive cooling by the air pumping effect through the movement of the filaments, so the spinning process is extremely Complex, the main disadvantage of this device is the extremely low flexibility during the drawing process. However, the example in European Patent 0 530 652 B1 does not make any comment on the critical drawing rate in the range of 4000 to 6000 m / min. And spmcrystailizaUon plays a very important role in this range, because the transversal blowing method is used in this rate range, and this extremely important rate range is not mentioned, and it is high The passive cooling technology required at the rate is not suitable for high difficult spinning speeds and / or polymers that are difficult to spin. The spinning process with a spinning speed of less than 6000 m / min may cause undesirable situations. In this case, the cross-flow blowing method may only be applied to a limited range of the above polymer mixture, and therefore it is likely to limit the entire process. Although the previous literature describes some polymer blends suitable for fiber manufacturing, in order to ensure good spinning characteristics in European Patent 0 631 638 B1, it is necessary to use a spinning device with a specific spinning rate (please refer to European patents). 530 652 B1). However, the conventional art of European patent 0 631 638 B1 does not mention a mixture containing polyfluorene and polyhexamethylene amine (European patent 20080 274). The inventors of the present invention have found that the conventional technique does not take into account that the mixture of polyamidamine and polyethylene terephthalate can cause the melt to turn yellow. 7 210 x 297 mm) (Please read the notes on the back before filling out this page)
I I--I--訂---I I--I 42167 8 A7 B7 46 1 4pif.d〇c/006 五、發明說明（y ) 問題，而此種具有黃色污點的紗線往往不合要求而無丨去使 用。 (請先閲讀背面之注意事項再填寫本頁) 本發明之目的在於製造聚合物混合物以生產纖維及 纖絲，所生產的纖維及纖絲具有良好的抽絲特性，並且所 包含的聚醢胺添加物含量少於5%。由於本發明所使用的 添加物少、致斷伸長性增加、黃色污點減少、因此本發明 具有很高的經濟價値。 .. 令人出乎意料的是纖維及纖絲的製備可以藉由聚對 苯二甲酸乙二醇酯和添加少量聚e -己內醯胺（聚醯胺6)、 聚醯胺丨2或聚醯胺6I/6T而形成高致斷伸長性’特別是當 以高抽絲速率生產時具有極佳的抽絲效果。雖然聚對苯二 甲酸乙二醇酯和聚醯胺6之混合物已屬習知技藝’但造成 其致斷伸長性增加並且抽絲特性良好的原因卻不爲人所 知。除此之外，碁至在添加物的相對濃度很低的情況下’ 依然可以維持致斷伸長性，使纖絲於後續的拉線織造 (draw-texturing)製程可以順利進行，但添加聚醯胺12和聚 醯胺6I/6T的原因到目前爲止並不是很淸楚。· 煜濟部智慧射產扃具工消費合作社印梨 本發明之另’一個特徵在於聚合物混合物包含有由含 亞磷酸化合物之族群所選擇.出的有機磷穩定劑’用以降低 黃色污點。. 、 , 本發明之聚合物混合物可以於高抽絲速率的抽絲過 程中使用傳統的橫斷吹氣法而不會有任何的困難。 本發明可使用傳統的冷卻裝置來進行冷卻，例如快 速移、動纖維而擾動空氣的被動冷卻裝置或引導空氣流向纖 & 本纸張又度適用中國國家標準（CNS>A4規格（210 X 297公Μ ) A7 B7 46 1 4pif.doc/〇〇6 五、發明說明（6) 維之裝置，而後者係置於纖維陣列的中間。 聚對苯二甲酸乙二醇酯/聚醯胺6、聚對苯二甲酸乙 二醇酯/聚醯胺12、聚對苯二甲酸乙二醇酯/聚醯胺6I/6T 混合物於商抽絲速率時有高的致斷伸長性，使得產能提高 的原因並不是很淸楚。而且除了高致斷伸長性外，混合物 的抽絲效果極佳，並且，特別是聚醯胺6和聚醯胺6I/6T 比歐洲專利〇 631 638 B1之聚甲基丙烯酸酯便宜而且更容 易取得。 特別是商業聚廳胺6產品例如由位於瑞士，Ems，CH-7013 Domat 的 EMS-CHEMIE AG 公司所生產 Grilon®型號 F34、F40、F47和F50即爲很好的添加物，較佳的情況特 別是於攝氏20度之濃硫酸中其濃度爲1%時之相對黏度 2.5〜5.2時，可實質增加其致斷伸長性。 \ 考慮提升致斷伸長性的效應時，添加物聚醯胺6之相 對黏度於一個很大的範圍皆對致斷伸長性無大影響，傳統 聚醯胺6相對黏度之較佳範圍爲2.5~5.2。當聚醯胺6相對 黏度爲2.8〜4.1時，有較佳的抽絲效果，特別是聚醯胺6 相對黏度爲2.8〜3.7時的抽絲效果更好。 特別適用於聚醯胺12之添加物爲由EMS-CHEMIE AG 公司所製造GHlamid®型號L20之商業產品，於攝氏20度 之間甲酚（m-cresol)中濃度0.05%之此種添加物所量測到的 相對黏度爲1.85〜1.95，相對黏度1.6〜2.3之聚醯胺12較合 適，而較佳的相對黏度範圍爲1.8~2.0。 第三種形式的聚醯胺爲聚醯胺6I/6T，其爲部份芳香 9 (請先閱讀背面之注意事項再填寫本頁) 01 裝--------訂----！ I ' 經濟部智慧財產局員工消費合作社印製 本纸張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 42167 8 46 1 4pif.doc/006 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明（q) 性的共聚醯胺（copolyamide)，由其命名的方式可以知道其 爲 1，6-己二胺（hexamethylenediamine)、間苯二甲酸 (isophthalic acid)和對苯二甲酸（terephthalic acid)單體所組 成。配合本發明的使用發現如果聚醯胺6I/6T具有非結晶 結構，則不同組成範圍（間苯二甲酸比對苯二甲酸）的聚醯 胺6I/6T皆可產生良好的結果。.此基團由較低範圍相對黏 度的各個單體所組成，出乎意料地，其與考慮耐倫（nylon) 添加入PET的習知技藝（歐洲專利〇 080 274 B1，第9頁， 範例8，第30和31行）間有完全相反的現象。 攝氏20度下於間甲酚中有0.5%濃度之聚醯胺6I/6T 量測到的最大相對黏度爲1.50,其較佳的相對黏度約爲 1.34〜1.45，極爲適用之商業化產品爲EMS-CHEMIE AG公 司的產品Gnvory®型號G16，此商業化產品爲非晶系、其 中間苯二甲酸與對苯二甲酸比例爲70:30，而相對黏度約 1.42。 爲了穩定聚合物混合物以防止黃色污點產生，需要 有下述的亞磷酸化合物：3-亞磷酸基丙酸（3-phosphono propionic acid)(=2-carboxyethanephos phonic acid)、乙氧鑛基 -甲基亞鱗酸二乙基醋（ethoxycarbonyl-methanephosphonic add diethyl ester)和Irganox® 1222。因爲此些化合物可以降 低聚醋的分子量，甚至於聚醋聚縮合（polycondensation)的 過程也可以添加此些化合物，並且亦可能配合聚醯胺添加 物一起添加。 根據本發明所使用的亞磷酸化合物的濃度範圍爲重 10 本紙張尺度適用中國囤家標準（CNS)A4規格（210 X 297公釐） ---T----Γ----®裝--------訂---------崎' (請先聞讀背面之注意事項再填寫本頁) A7 B7 4614pif,d〇c/006 五、發明說明（Y ) 量百分比0.02〜1.0%，較佳的情況爲0.05〜0.6%。 將聚釀1女添加物加入聚對苯二甲酸乙二醇醋的過程 可以例如使用所明的溶融g周節，’(melt conditioning)法以連 續調整聚合物熔融物（德國專利4,039,857 C2)。本發明將德 國專利4,039,857 C2所揭露的內容當作參考，於此德國專 利中，部份的熔融物由熔融物流體中被抽離，而此被抽離 出的部份熔融物被注入輔助噴流器（subsidiary flow extruder)，細粒、珠狀、或較佳的粉末狀添加物加入輔助 噴流器，添加物於部份熔融物中擴散。此含有添加物之部 份熔融物流回到主熔融物導管，然後被稀釋到最終的濃 度。 在lieu所謂的”熔融調節”方法例如亦可以使用注塑機 (preplasticator)/壓出機（extruder)來製造純添加物的溶融物 並將其注入主熔融物流體中，即對混合裝置進行安排以確 保添加物與主聚合物聚對苯二甲酸乙二醇酯（polyethylene terephihalate=PET)兼有良好的同質性與擴散性。 當起使產物爲PET微粒時其溶入抽絲壓出機。而抽 絲壓出機可以進一步量測添加入PET微粒的添加物 '添加 物擴散至聚對苯二甲酸乙二醇酯後、再對熔融混合物進行 抽絲，爲了達到令人滿意的擴散效果，較佳的情況爲使用 粉末形式的添加物。 添加物可以以純物質形式或母料（master batch)形式進 行添加，也可以再添加另外的添加物（例如本發明所述之 穩定劑）而和其他物質一起進行抽絲’根據本發明之聚對 ---：---Τ----0^ 裝--------訂-------- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 421R7ft 46 !4pif.doc/006 A7 __B7 ___ 五、發明說明（q ) 苯二甲酸乙二醇酯可以包含有例如去光澤試劑（二氧化 鈦）、穩定劑（特別是本發明所需要的穩定劑）和催化劑等添 加劑。本發明所述之”聚對苯二甲酸乙二醇酯”或”聚酯”意 指聚酯包含至少80%的聚對苯二甲酸乙二醇酯和20%由乙 二醇例如二甘醇（diethylene glycol)、l,4- 丁二醇 (teiramethyleneglycol)以外的雙醇或例如間苯二甲酸、六氫 化對苯二甲酸（hexahydroterephthalic acid)和二苯甲酸 (dibenzoic acid)以夕f的酸所开多成的成分。 如欲修改聚對苯二甲酸乙二醇酯，亦可加入具有3到 4個醇或酸官能基的分枝試劑（branching agent)，例如爲三 甲醇丙焼（trimethylopropane)、 三甲醇乙院 (trimethyloethane)、季戊四醇（pentaerythritol)、丙三醇 (glycerol)、均苯甲酸（trimesic acid)、偏苯三酉菱（trimellitic acid)、或均苯四甲酸（pyromellitic acid)。 可以對初始聚酯添加已知的試劑來避免顔色污染’ 例如 3,5-二幾基苯磺酸鈉（sodium-3,5-dicarboxybenzene sulfonate) 〇 於熔融物導管中，亦可以使用例如動態和/或靜態混 合器，而此動態和/或靜態混合器可直接放置於噴絲器的上 游。 特別値得注意的是於本發明聚對苯二甲酸乙二醇酯 主體中的聚醯胺6顆粒大小約爲250〜400nm ’即小於 m，但歐洲專利0 080 274 B1中的顆粒大小爲〇.5~3 /im。 其可以假設如果主體中含有切割較精細的顆粒時’聚合物 (請先閱讀背面之注意事項再填寫本頁) Θ裝 訂---------岣、 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 經濟部智慧財產局員工消費合作社印製 46 1 4pif.doc/006 A7 42167 8 _______^7______ 五、發明說明（/〇) 混合物會有較好的抽絲特性。而於相同濃度下，大顆粒之 間的距離較大，無法達到均勻分佈的效果。顆粒大小的量 測是使用未進行抽絲的熔融混合物中所取得之顆粒當作樣 本來進行量測，其顆粒依然是圓球形，所有顆粒的大小限 制在J.5em以下= 下述本發明較佳實施例係用以詳細解本發明，而非 用以限定本發明， 習知技藝所使用之傳統抽絲裝置揭露於例如 Ullmann^ Encyclopedia of Industrial Chemistry, vol. 10, Fibers, 3，General Production Technology, page 535, Figure 26 o 實施例一 第1表係顯示於4950m/min之捲繞速率（Vwick)下所 做的抽絲測試。於使用PA6情況下的抽絲溫度約攝氏292， 於使用Gnlamid®型號L20與Grivory®型號G16和G21情 況下的較佳抽絲溫度約攝氏280〜295。纖絲的冷卻係使用 橫斷吹氣法，當通過橫斷氣流後，紗線被纏繞在冷卻雙繞 線管（cold dual bobbin)，而繞線管或拉線（draw-off)速率皆 爲5000m/nun，傳統製造紗線所使用去光澤後的聚對苯二 甲酸乙二醇酯係使用紡織工業常用到EMS-CHEMIE AG公 司所出產的型號M764產品。聚e -己內醯胺添加物係使用 EMS-CHEMIE AG 公司所出產型號 A23、F34、F40、F47 ' F50產品，聚己二醯己二胺爲BASF公司型號AS2503、A3、 A4、A5產品。粉末狀的添加物被送入微粒狀聚對苯二甲 酸乙二醇酯。於PA6和PA66的情況下，PA6和PA66於聚 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ---------------I ! I--訂· I ------I .· (請先閱讀背面之注意事項再填寫本頁) A7 B7 46l4pif. doc/0 五、發明說明（π ) 對苯二甲酸乙二醇酯中的濃度皆約重量百分比1.25%。於 PA12和PA6I/6T的情況下，PA12和PA6I/6T於聚對苯二 甲酸乙二醇酯中的濃度1皆約重量百分比3%，且PA12和 PA6I/6T以片狀形式加入聚對苯二甲酸乙二醇酯。 比較不同添加物的各種情況可以發現使用A23、F34、 F40、L20和G16時，可以避免很多問題並有良好的抽絲 特性，然而使用聚己二醯己二胺時會使纖維容易斷裂，於 混合聚對苯二甲酸乙二醇酯和A5的情況下，所形成的纖 維甚至在接觸捲線軸時斷裂，因此無法纏繞任何絲線。於 使用G21之情況下，其黏度比G16大，並沒有增加致斷伸 長性。 實施例二 第2表係顯示六條絲線製造單位的測試結果。抽絲溫 度爲攝氏288度’纏繞速率（Vwick)爲4950m/min，除了 於”zei-o 2”的零速率測試（zero rate test)外，捲繞速率爲 5000m/min，而於”zero 2”測試（傳統上不含添加物）時的捲 繞速率爲3225m/min。於使用熔融調節的情況下，亦即使 用與抽絲裝置直接相連的連續聚酯縮合裝置之情況時，添 加物F34、F40、AS2503的重量百分比濃度爲1.5和2%， 其中使用F34、F40時具有優良的抽絲校果，然而使用 AS2503卻很容易造成絲線的斷裂。聚醯胺6顆粒的大小爲 250〜400nm。而第一實施例中所有聚己二醯己二胺中，雖 然AS2503有最好的效果，但依然低於標準。 第3表顯示紗線的織品（textile)資料。修正過的聚酉旨 本紙張尺度適用中國國家標準（CNS)A4規格（210x 297公g ) (請先閱讀背面之注意事項再填寫本頁) ---- ---丨訂 ---------"- 經濟部智慧財產局員工消費合作社印製 421678 A7 B7 46 i 4pif.doc/006 五、發明說明（/之.） 的品質與傳統優良紗線的品質一樣，主要爲抽絲效果大爲 改進，POY紗線通常使用約3200m/min的速率進行抽絲。 習知所進行的熔融抽絲程序較慢，延展（stretch)變大 (如 Ullmann’s Encyclopedia of Industrial Chemistry； vol, 10, Fibers, 3, General Production Technology, page 550〜561， Figure 26)。本發明之所以提生產率的原因，不僅由於溶融 抽絲的產能高，而且也因爲纖維生產線上提升纖維的延伸 比例。 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 ί 5 本紙張尺度適用中國國家標準（CNS)A4規格（210x 297公釐） A2 Α7 Β7 五、發明說明（丨>) 第1表至第3表説明 第1表至第3表中各代號所代表之意義I I--I--order --- I I--I 42167 8 A7 B7 46 1 4pif.d〇c / 006 V. Description of the invention (y), and this kind of yarn with yellow stains is often not satisfactory Nothing to use. (Please read the precautions on the back before filling this page) The purpose of the present invention is to produce polymer mixtures to produce fibers and filaments. The fibers and filaments produced have good spinning properties and contain polyamines. Additive content is less than 5%. Since the additive used in the present invention is small, the elongation at break is increased, and the yellow stain is reduced, the present invention has a high economic value. .. Surprisingly, the preparation of fibers and filaments can be achieved by polyethylene terephthalate and a small amount of poly-e-caprolactam (polyamide 6), polyamine 2 or Polyammonium 6I / 6T has a high breaking elongation, especially when produced at a high spinning rate, and has excellent spinning effect. Although a mixture of polyethylene terephthalate and polyamide 6 is a conventional technique ', the reasons for its increased elongation at break and good drawing properties are unknown. In addition, even when the relative concentration of the additive is very low, it can still maintain the elongation at break, so that the filament can be smoothly used in the subsequent draw-texturing process, but the addition of polyfluorene The reasons for amine 12 and polyamide 6I / 6T are not very clear so far. · The Ministry of Yuji's Smart Shooting Production Cooperative Consumer Cooperative, Pear Printing Co., Ltd. Another feature of the present invention is that the polymer mixture contains an organic phosphorus stabilizer selected by the group containing phosphorous acid compounds to reduce yellow stains. The polymer mixture of the present invention can use the traditional cross-flow blowing method in the spinning process at a high spinning rate without any difficulty. The present invention can use conventional cooling devices for cooling, such as a passive cooling device that quickly moves and moves the fibers to disturb the air, or guides the air to the fibers. The paper is also applicable to Chinese national standards (CNS > A4 specifications (210 X 297) (M) A7 B7 46 1 4pif.doc / 〇〇6. Description of the invention (6) device, which is placed in the middle of the fiber array. Polyethylene terephthalate / polyamide 6, Polyethylene terephthalate / polyamide 12 and polyethylene terephthalate / polyamide 6I / 6T mixtures have high breaking elongation at the rate of commercial drawing, which makes the capacity increase. The reason is not terribly clear. Besides the high breaking elongation, the silk-drawing effect of the mixture is very good, and especially the polyamide 6 and polyamide 6I / 6T are better than the polymethyl group of European Patent 0631 638 B1. Acrylic esters are cheaper and easier to obtain. Especially commercial polyamine 6 products such as Grilon® models F34, F40, F47 and F50 produced by EMS-CHEMIE AG in Domat, CH-7013 Domat, Switzerland. Additives, preferably at 20 ° C When the relative viscosity of the acid is 2.5% to 5.2 when its concentration is 1%, it can substantially increase its elongation at break. When considering the effect of improving the elongation at break, the relative viscosity of the additive polyamide 6 is at a large The ranges have no great influence on the elongation at break. The preferred range of the relative viscosity of traditional polyamide 6 is 2.5 to 5.2. When the relative viscosity of polyamide 6 is 2.8 to 4.1, there is a better drawing effect, especially Polyamide 6 has a better spinning effect when the relative viscosity is 2.8 ~ 3.7. The additive especially suitable for polyamide 12 is a commercial product of GHlamid® model L20 manufactured by EMS-CHEMIE AG, at 20 degrees Celsius. The relative viscosity measured in m-cresol (0.05%) of this additive is 1.85 ~ 1.95. Polyamide 12 with a relative viscosity of 1.6 ~ 2.3 is more suitable, and the preferred range of relative viscosity is 1.8 ~ 2.0. The third form of polyamide is polyamide 6I / 6T, which is partially aromatic 9 (Please read the precautions on the back before filling this page) 01 Packing -------- Order ----! I ”Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, this paper is printed in accordance with Chinese National Standard (CNS) A4 regulations (210 X 297 mm) 42167 8 46 1 4pif.doc / 006 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (q) Copolyamide of the nature, named by it It is known that it is composed of hexamethylenediamine, isophthalic acid, and terephthalic acid monomers. According to the use of the present invention, it has been found that if the polyamide 6I / 6T has an amorphous structure, all of the polyamide 6I / 6T with different composition ranges (isophthalic acid to terephthalic acid) can produce good results. This group consists of individual monomers with a relatively low range of relative viscosities, which, unexpectedly, is related to the conventional technique of considering the addition of nylon to PET (European Patent 080 274 B1, page 9, example) 8, lines 30 and 31). The maximum relative viscosity measured by polyamidamine 6I / 6T with 0.5% concentration in m-cresol at 20 ° C is 1.50, and its preferred relative viscosity is about 1.34 ~ 1.45. The most suitable commercial product is EMS. -Product of Gnvory® Model G16 from CHEMIE AG. This commercial product is amorphous, with a ratio of isophthalic acid to terephthalic acid of 70:30 and a relative viscosity of about 1.42. In order to stabilize the polymer mixture to prevent yellow stains, the following phosphorous compounds are required: 3-phosphono propionic acid (= 2-carboxyethanephos phonic acid), ethoxylate-methyl Ethoxycarbonyl-methanephosphonic add diethyl ester and Irganox® 1222. Because these compounds can reduce the molecular weight of polyacetate, they can be added even in the process of polycondensation of polyacetate, and may also be added together with polyamine additives. The concentration range of the phosphorous acid compound used according to the present invention is 10 weights. The paper size is applicable to the Chinese Standard (CNS) A4 (210 X 297 mm) --- T ---- Γ ---- ® equipment -------- Order --------- Saki '(Please read the notes on the back before filling in this page) A7 B7 4614pif, doc / 006 V. Description of the invention (Y) The amount percentage is 0.02 to 1.0%, preferably 0.05 to 0.6%. The process of adding the poly (vinyl terephthalate) additive to the polyethylene terephthalate can continuously adjust the polymer melt, for example, using the known melt conditioning method (German Patent 4,039,857 C2). In the present invention, the content disclosed in German Patent 4,039,857 C2 is taken as a reference. In this German patent, part of the melt is extracted from the melt fluid, and the extracted part of the melt is injected into the auxiliary jet. Subsidiary flow extruder, fine-grained, bead-like, or better powdered additives are added to the auxiliary jet, and the additives diffuse in a part of the molten material. This portion of the melt stream containing the additive is returned to the main melt conduit and is then diluted to the final concentration. In Lieu's so-called "melt conditioning" method, for example, it is also possible to use a preplasticator / extruder to make a melt of pure additives and inject it into the main melt fluid, that is, to arrange the mixing device to Ensure that the additive and the main polymer polyethylene terephihalate (PET) have good homogeneity and diffusivity. When the product is made of PET microparticles, it is dissolved in a drawing extruder. The wire drawing extruder can further measure the additives added to the PET particles. After the additives have diffused to polyethylene terephthalate, the molten mixture can be drawn. In order to achieve a satisfactory diffusion effect, It is preferred to use additives in powder form. Additives can be added in the form of pure substances or master batches, or additional additives (such as the stabilizers described in the present invention) can be added to perform spinning with other substances. ---: --- T ---- 0 ^ Loading -------- Order -------- (Please read the notes on the back before filling this page) Intellectual Property Bureau of the Ministry of Economic Affairs The paper size printed by the employee consumer cooperative is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 421R7ft 46! 4pif.doc / 006 A7 __B7 ___ V. Description of the invention (q) Ethylene glycol phthalate can It contains additives such as a delustering agent (titanium dioxide), a stabilizer (especially the stabilizer required by the present invention), and a catalyst. The term "polyethylene terephthalate" or "polyester" as used herein means that the polyester contains at least 80% of polyethylene terephthalate and 20% of ethylene glycol such as diethylene glycol Diols other than (diethylene glycol), 1,4-butanediol (teiramethyleneglycol) or acids such as isophthalic acid, hexahydroterephthalic acid, and dibenzoic acid Add more ingredients. If you want to modify polyethylene terephthalate, you can also add a branching agent with 3 to 4 alcohol or acid functional groups, such as trimethylopropane, trimethylopropane ( trimethyloethane, pentaerythritol, glycerol, trimesic acid, trimellitic acid, or pyromellitic acid. Known reagents can be added to the initial polyester to avoid color contamination ', such as sodium-3,5-dicarboxybenzene sulfonate, in a melt tube. Dynamic and And / or a static mixer, and this dynamic and / or static mixer can be placed directly upstream of the spinneret. It is particularly noticeable that the particle size of the polyamide 6 in the polyethylene terephthalate body of the present invention is about 250 to 400 nm, that is, less than m, but the particle size in European Patent 0 080 274 B1 is 0. .5 ~ 3 / im. It can be assumed that if the main body contains finely cut particles, the polymer (please read the precautions on the back before filling this page) Θ Staple --------- 岣, Consumer Consumption Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs The paper size for printing is applicable to China National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 46 1 4pif.doc / 006 A7 42167 8 _______ ^ 7______ 5. Description of the invention (/ 〇) The mixture will have better spinning properties. At the same concentration, the distance between large particles is large, and the effect of uniform distribution cannot be achieved. The particle size is measured by using the particles obtained from the molten mixture without drawing as a sample. The particles are still spherical, and the size of all particles is limited to less than J.5em = The preferred embodiment is used to explain the present invention in detail, but not to limit the present invention. The conventional wire drawing device used in the conventional art is disclosed in, for example, Ullmann ^ Encyclopedia of Industrial Chemistry, vol. 10, Fibers, 3, General Production Technology. , page 535, Figure 26 o Example 1 The first table is a drawing test performed at a winding speed (Vwick) of 4950 m / min. The drawing temperature is about 292 ° C when using PA6, and the best drawing temperature is about 280 ~ 295 ° C when using Gnlamid® model L20 and Grivory® models G16 and G21. The cooling of the filaments uses a cross-flow blowing method. After passing through the cross-flow, the yarn is wound around a cold dual bobbin, and the bobbin or draw-off rate is 5000m / nun, the matte polyethylene terephthalate used in the traditional manufacturing of yarns is a model M764 product commonly used in the textile industry by EMS-CHEMIE AG. Poly-caprolactam additive uses the models A23, F34, F40, F47 'F50 produced by EMS-CHEMIE AG, and polyhexamethylene diamine is BASF's model AS2503, A3, A4, A5. The powdered additive is fed into particulate polyethylene terephthalate. In the case of PA6 and PA66, PA6 and PA66 apply the Chinese National Standard (CNS) A4 specification (210 X 297 mm) to the aggregate paper size. I! I --Order · I ------ I. · (Please read the notes on the back before filling this page) A7 B7 46l4pif. Doc / 0 V. Description of the invention (π) In ethylene terephthalate The concentration is about 1.25% by weight. In the case of PA12 and PA6I / 6T, the concentration 1 of PA12 and PA6I / 6T in polyethylene terephthalate are both about 3% by weight, and PA12 and PA6I / 6T are added in the form of tablets. Diethylene glycol dicarboxylate. Comparing the various conditions of different additives, it can be found that when using A23, F34, F40, L20, and G16, many problems can be avoided and good spinning properties, however, the use of polyhexamethylene dihexamethylene diamine will cause the fiber to break easily. When polyethylene terephthalate and A5 are mixed, the resulting fiber breaks even when it comes into contact with the spool, so no filament can be wound. In the case of using G21, its viscosity is greater than that of G16 without increasing the elongation at break. Example 2 Table 2 shows the test results of the six yarn manufacturing units. The drawing temperature is 288 ° C. The winding rate (Vwick) is 4950m / min. Except for the zero rate test in "zei-o 2", the winding rate is 5000m / min, and in "zero 2" "The winding speed at the test (traditionally without additives) was 3225 m / min. In the case of using melt adjustment, that is, when using a continuous polyester condensation device directly connected to the spinning device, the weight percentage concentration of the additives F34, F40, and AS2503 is 1.5 and 2%, of which, when using F34, F40 It has excellent drawing results, but it is easy to cause the thread to break using AS2503. The size of the polyamide 6 particles is 250 to 400 nm. Of all the polyhexamethylene adipamide in the first embodiment, although AS2503 had the best effect, it was still below the standard. Table 3 shows the textile information of the yarn. Revised Poly Paper Purpose This paper size applies the Chinese National Standard (CNS) A4 specification (210x 297 g) (Please read the precautions on the back before filling this page) ---- --- 丨----- "-Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 421678 A7 B7 46 i 4pif.doc / 006 V. The quality of the invention description (/ 之.) is the same as the quality of traditional fine yarns, mainly for The drawing effect is greatly improved. POY yarns are usually drawn at a rate of about 3200 m / min. The melt-drawing procedure performed by the conventional is slower and the stretch becomes larger (such as Ullmann ’s Encyclopedia of Industrial Chemistry; vol, 10, Fibers, 3, General Production Technology, pages 550 ~ 561, Figure 26). The reason why the present invention improves productivity is not only because of the high production capacity of melt-drawing, but also because of the increase of the fiber extension ratio on the fiber production line. (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5 This paper size is applicable to China National Standard (CNS) A4 (210x 297 mm) A2 Α7 Β7 V. Description of the invention (丨 >) Tables 1 to 3 explain the meanings of the codes in Tables 1 to 3.
商標名 1 職商丨 高分子 A23 Grilon® A23 Ems-Chemie FA6 F34 Grilon® F34 Ems-Chemie ?A6 F40 Grilon® F40 Ems-Chemie ?A6 F47 Grilon® F47 Ems-Chemie PA6 F50 Grilon® F50 Ems-Chemie ?A6 L20 Grilamid® L20 Ems-Chemie ?A12 G16 Grivory® G16 Ems-Chemie ΡΛ6Ι/6Τ (70/30) G21 Grivoiy® G21 Ems-Chemie ΡΑ6Ϊ/6Τ (70/30) AS2503 Ultramid® BASF PA66 AS2503 1 f j A3 Ultramid<S> A3 BASF ! PA66 A4 Ultramid® A3 BASF |PA66 Zero： * Grilene® M764 Ems-Chemie ;PET Zero-1 ： k Grilene® M764 Ems-Chemie 丨PET Zero-2： * Grilene® M764 Ems-Chemie ；PET 相對黏度(於濃 流酸中估有1 % 之浪度） 2.40-2.53 3.35 — 3.50 3.60-3.75 4.00 - 4.20 5.00-5.40 1.85-1.95 1.42*** 1.52 … 2.5 2.5 2.5 (請先聞讀背面之注意事項再填寫本頁) --------訂---------線. 經濟部智慧財產局員工消費合作社印製 *:主體高分子=偈統織品應用之未修飾之PET:已去光灌） PET顆粒之相對黏度=Ί .64於間一甲齡洽液中濃度1 %時所測量 ***:攝氏20度下於間一甲酚'濟液中濃度1 %写所量測之相對黏度 太紙張尺度適用中國阁定嫂准 - r 份 * C / ' 1 V 「 1 Μ A2^678 A7 B7 五、發明說明（I +) 第1表(中間試驗裝置） 添她種類 A23 F34 R〇 F47 F50 ϋ A3 A4 咖 L20 GJ6 G21 (%) 1.25 1.25 1.25 L25 1.25 1.25 Ϊ.25 1.25 !- ! 5.0 ' 3.0 3.0 Stab.·* (%) - 0.15 ' - - 1- 0.3 0.3 0.3 EB(%)- 69.6 103.S 106 \063 107,1 101.9 Ϊ 14.& 123.9 64.7 t55.fi 141.2 39』 TS (cN/dtex) 2.89 2 63 2.5 2.47 2.49 2.4 2.3 U1 3.07 1.64 1.54 Ϊ.Ί5 鷉量 126.4 126.8 126.5 126.2 126,5 127,1 126.2 Ϊ25.2 124.9 126.1 125.1 125.1 ·'， (τπ/min) 4950 4950 4950 4950 4950 4950 4950 4950 4950 4950 . 4950 4950 驗速率 2.475 3.425 3.675 ΑΛ 5.2 2.5 2.6 1 3.4 - j 1.90 1 M2 1.52 抽絲特性 丨極佳 極佳 極佳 佳 中等 差 差 極差 佳 極佳 诖 中等 顔色Γ黃 ώ 黃 黄 黃 黄 黄 白 白 白 白 ' *: P A添力_相難度係於濃纖中當其濃度為1 %時所量測L 2 0，G1 6, G 2 Ί c 像於間一甲酚中當其濃度為0.5%時所量測 **:亞 | ([巳=破隨申長量，丁2二張力） 經濟部智慧財產局員工消費合作社印.楽： 第2表(六條絲線製造裝置) F34 F34 F40 F40 AS 2503 AS 2503 > Zero-l Zero-2 r才量 1.5 2 1.5 2 1.5 2 - - EB (%). 121.6 151.0 122,9 153 1203 137.5 65.8 !21.2 TS (cK/dtcx) 2.Π 1.84 2.1 1,81 2.14 1.9S 3.1 ，tJ 2*3.4 谪定量 latex; 124.1 124.3 124 124,9 124.6 124.9 124.1 125,1 繼跡 (m/min) 4950 4950 4950 4950 4950 4950 4950 13170 1 _ 柚絲特Ιΐ 雛” 雛** 極佳" 極佳” 佳… 佳”* .佳 1 丨極佳 |顔fe 黃 黃 黃 黄 黃 黃 白 ! ^ 1 ，**:運轉240分鐘無問題産生 ***:平均每1 3分鐘出現問題 η 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） --------------*—,------------—訂---------線./.—---------------.________(請先閱讀背面之注意事項再填寫本頁) 4? 1RJQ A7 B7 五、發明說明（/y) 第3表(拉線織造) 添力fffel種類 F34 F40 Zero-2 爸量(%) 1.5 L5 - EB (%) 26.9 26.1 21.2 TS (cN/dtex) 3.92 3.96 4.05 谪定量（dtex) 75.1 75,4 75.9 Vlex (rn/min) 800 800 §00 延仲比例 L7 L705 1,695 一運作幡兄 極佳 極佳 極佳 250-400 250*400 *· ----,---B-----*0^裝--------訂---------竣"~^ (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 I? 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）Trade name 1 Trader 丨 Polymer A23 Grilon® A23 Ems-Chemie FA6 F34 Grilon® F34 Ems-Chemie? A6 F40 Grilon® F40 Ems-Chemie? A6 F47 Grilon® F47 Ems-Chemie PA6 F50 Grilon® F50 Ems-Chemie? A6 L20 Grilamid® L20 Ems-Chemie? A12 G16 Grivory® G16 Ems-Chemie ΡΛ6Ι / 6Τ (70/30) G21 Grivoiy® G21 Ems-Chemie ΡΑ6Ϊ / 6Τ (70/30) AS2503 Ultramid® BASF PA66 AS2503 1 fj A3 Ultramid < S > A3 BASF! PA66 A4 Ultramid® A3 BASF | PA66 Zero: * Grilene® M764 Ems-Chemie; PET Zero-1: k Grilene® M764 Ems-Chemie 丨 PET Zero-2: * Grilene® M764 Ems-Chemie; Relative viscosity of PET (estimated 1% in concentrated acid) 2.40-2.53 3.35 — 3.50 3.60-3.75 4.00-4.20 5.00-5.40 1.85-1.95 1.42 *** 1.52… 2.5 2.5 2.5 (Please read the back first Please note this page before filling in this page) -------- Order --------- line. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs *: The main polymer = the unfinished fabric application Modified PET: de-irradiated) Relative viscosity of PET particles = Ί .64 measured at 1% concentration ***: The relative viscosity measured at 1% in m-cresol 'solution at 20 degrees Celsius is written. The relative viscosity measured is too large for paper scales. Applicable to China Pavilion Standards-r serving * C /' 1 V 「1 Μ A2 ^ 678 A7 B7 V. Description of the invention (I +) Table 1 (Intermediate test device) Tim type A23 F34 R〇F47 F50 ϋ A3 A4 Coffee L20 GJ6 G21 (%) 1.25 1.25 1.25 L25 1.25 1.25 Ϊ.25 1.25!- ! 5.0 '3.0 3.0 Stab. ** (%)-0.15'--1- 0.3 0.3 0.3 EB (%)-69.6 103.S 106 \ 063 107,1 101.9 Ϊ 14. & 123.9 64.7 t55.fi 141.2 39 『TS (cN / dtex) 2.89 2 63 2.5 2.47 2.49 2.4 2.3 U1 3.07 1.64 1.54 Ϊ.Ί5 Volume 126.4 126.8 126.5 126.2 126,5 127,1 126.2 Ϊ25.2 124.9 126.1 125.1 125.1 · ', (τπ / min) 4950 4950 4950 4950 4950 4950 4950 4950 4950 4950 4950 4950. 4950 4950 Test rate 2.475 3.425 3.675 ΑΛ 5.2 2.5 2.6 1 3.4-j 1.90 1 M2 1.52 Drawing characteristics 丨 Excellent Excellent Excellent Excellent Medium difference Very poor Excellent Excellent 极Medium color, yellow, yellow, yellow, yellow, yellow, yellow, white, white, white and white '*: PA added power_phase difficulty is measured in thick fiber when its concentration is 1% L 2 0, G1 6, G 2 Ί c Measured in m-cresol when its concentration is 0.5% **: Asia | ([巳 = breaking the long-term application amount, Ding Li tension) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 印: Table 2 (Six-wire manufacturing equipment) F34 F34 F40 F40 AS 2503 AS 2503 > Zero-l Zero-2 r Capacity 1.5 2 1.5 2 1.5 2--EB (%). 121.6 151.0 122,9 153 1203 137.5 65.8! 21.2 TS (cK / dtcx) 2.Π 1.84 2.1 1,81 2.14 1.9S 3.1 ， tJ 2 * 3.4 谪 Quantitative latex; 124.1 124.3 124 124,9 124.6 124.9 124.1 125,1 Relay track (m / min) 4950 4950 4950 4950 4950 4950 4950 4950 13170 1 _ Yuciste Iΐ Chick "Chick ** Excellent " Excellent" Good ... Good "* .Good 1 丨 Excellent | Yanfe yellow yellow yellow yellow yellow yellow white! ^ 1 **: No problem during 240 minutes of operation ***: Problems occur every 13 minutes on average η This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) --------- ----- *-, -------------- Order---------line./.---------------- -.________ (Please read the precautions on the back before filling this page) 4? 1RJQ A7 B7 V. Description of the invention (/ y) Table 3 (Drawstring weaving) Timfffel Class F34 F40 Zero-2 Dad volume (%) 1.5 L5-EB (%) 26.9 26.1 21.2 TS (cN / dtex) 3.92 3.96 4.05 谪 Quantity (dtex) 75.1 75,4 75.9 Vlex (rn / min) 800 800 §00 Yanzhong ratio L7 L705 1,695 One operation 幡 Excellent Excellent Excellent Excellent 250-400 250 * 400 * · ----, --- B ----- * 0 ^ Installation -------- Order --------- End " ~ ^ (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, I? This paper size applies to Chinese National Standards (CNS) A4 size (210 X 297 mm)