A7 經濟部智慧財產局員工消費合作社印製 ___B7_五、發明說明（1 ) 【產業上之利用領域】 此發明係關於無機氯化物及其無水物等之吸濕性或腐 蝕性強之粉粒體狀物藥品之輸送、保管及搬運上所使用之 具優異氣密性及耐藥品性之輸送用包裝材。 【先行技術】 一般，在工業用原料及製品之粉粒體狀藥品的輸送上 ，必須考慮該粉粒體狀藥品之物理、化學性質，並且，考 量其對使用狀況之適應，依此再選擇容器或輸出手段。 但，如此之粉粒體狀藥品具有強吸濕性或腐蝕性，對 相關之粉粒體狀藥品，一般而言，當以開放狀態放置於大 氣中，會吸收空氣中水分而溶解（解潮性），由於吸收水 分，主成份分解，除了發生氯化氫等腐蝕性瓦斯與造成純 度低下外，還出現強酸性*對容器或輸出手段產生腐蝕， 可能會減低其使用壽命。 於此，對於如此之吸濕性或腐蝕性強的粉粒體狀藥品 之輸送，一般是將該粉粒體狀藥品充塡於以具有防止空氣 或分子狀水分侵入之具優異氣密性及耐蝕性之容器內。 例如，由於如無水氯化鋁、無水氯化鐵等之無水氯化 物，便是具有如此性質之物質’至今對其之充塡、保管、 輸送已做過非常多的檢討’例如，採用了使用可以杜絕分 子狀水分侵入，並且對氯化氫瓦斯具優異耐蝕性之塑膠等 材料爲其對策。 例如，做爲輸送如此物質之容器1使用厚鋼板製之數 <請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）-4 - A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明（？) 頓用鐵容器（鐵櫃）爲眾所皆知，此鐵櫃，依使用者之不 同其規格亦不同，具備有充塡口、排出口，全體堅固地製 成，且具備有充塡口、排出口之蓋，有優異之氣密性’對 於輸送時之不測之事故也不容易損壞。並具有內容物排漏 出之可能性小，在安全上等有其優異性還有可以重複使用 之優點。 但是’近年之趨勢傾向於，爲防止製品品質劣化或容 器之腐蝕、並且除謀求輸送之安全性外再加上使物流能有 效率地大量進行，又，對海外之輸送量也大，故謀求排出 作業時之作業手續不會繁雜之容器。所以，先行之鐵櫃， 容器本身之重量佔了很大之輸送重量，回收空容器時，也 由於容積過大而造成效率不佳等問題。又，即使對於國內 之平常的製品輸送上，爲配合客戶之接受狀況，容器之種 類很多而難以共用，而且，鐵櫃於在使用之際.，爲了確保 下一次充塡製品之品質，有必要對內部施以淸掃、乾燥、 高濕度空氣之置換等麻煩之洗淨作業。 再加上'於輸出之際，將鐵櫃當做容器來使用並不十 分適宜’其理由是由於上述所述之相同問題會更爲顯著a 例如’對空容器之回收需要花費時間，所以必須以增加容 器數量來應付，因而可預測到對多數量之容器，在管理上 將變得繁雜，而此原因會造成成本之上昇。 又’做爲輸送如此之物質之另一容器，有周知之施以 樹脂披覆內層（lining)之桶〔俗稱汽油桶），該桶之容器 重量比較輕，除外部形成有金屬之強度保護材料外，內部 (請先Μ讀背面之注意事項再填寫本頁} .! I — I I I 訂---- ---綠 本紙張尺度適用中國國家標準（CNS)A4蜆格<210 X 297公釐〉,5 - A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明<?) 爲樹脂披覆內層，有耐腐蝕性。解除鐵櫃之問題點。· 而且’如此之桶，比較輕量’具優異之耐腐蝕性和防 濕性，並且，被當作爲國內外之共通容器來使用，由於有 一般之流通性，所以可以以所謂一次性來使用，因此除了 有不必增添回收手續之物流面上之優點外，尤其適合被採 爲當作輸出用。 但是，此桶由於爲一次性使用，使得包裝費用增加， 充塡作業以每桶約2 0 0公斤，則每單位重量之作業次數 爲鐵櫃之4〜5倍，而且於使用時，必須要有專用之容器 反轉裝置，作業性還是較低，也使製品成本受影響而上昇 〇 再者，做爲防濕性高的包裝材料有周知之各式各樣的 多層樹脂薄膜，但多被利用於食品、攜帶用暖具（一次性 懷爐）等之數百公克之少量包裝上。然而，對於以這些多 層樹脂薄膜來做包裝時，其有必須考量薄膜的厚度、強度 、柔軟性是否有製袋之可能性、且難以以所要求之尺寸， 來取得做爲包裝材料之薄片等等實用上的諸課題。因此， 僅使用於少量’雖具優異防濕性能，但難以使用於以噸爲 單位之大型包裝‘輸送，以致不能滿足所有之相當於習知 之輸送容器之性能·機能。 又’做爲用於將吸濕性高之數十K g爲單位之粉粒製 品予以包裝’則有優異防濕性中型包裝材，如周知之在聚 '聚氯乙烯等之樹脂薄膜上，將具有瓦斯防護（遮斷 )瓦斯機能之聚偏二氯乙稀（polyvinyhdene chloride )或 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）-6 - 經濟部智慧財產局員工消費合作社印製 __B7__五、發明說明（4 ) 是鋁箔和紙貼合成多層薄膜之紙袋（特開昭5 5 -19522號' 特開昭62 — 7859，及特開昭63-178949號之公報等）。然而’使用鋁箔之此種紙袋 ，由於聚乙烯、聚偏二氯乙烯等之樹脂薄膜會使氯化氫等 穿透，因此鋁箔並不能用來當作腐蝕之相關物質的包裝材 料。又，使用聚偏二氯乙烯此種紙袋’雖防濕性高’但由 於袋子本身之強度低，所以即使能使用於2 0〜3 OKg 之包裝，也無法承受其以上之重量’例如不能當作1〜2 噸之容器使用，除此之外，於排出時，將袋開封之投入作 業要藉由人力、故不適用於吸濕後會發生瓦斯之物質。 【發明所欲解決之課題】 於是，本發明者，對於應該開發出具優異之氣密性及 耐藥品性、而且對塡充、排出等操作上之方便牲，同時也 適用於大量輸送無機氯化物及其無水物等之吸濕性及腐蝕 性強之粉粒體狀藥品之輸送、保管及搬運所使用之輸送用 包裝材潛心進行檢討之結果，將此輸送用包裝材由瓶罐型 內袋及軟質集裝外袋形成雙重構造，使瓶罐型內袋顯現出 氣密性及耐藥品性之同時，再藉由附加以軟質集裝外袋來 承受保管及搬運等操作時之強度，找到了可以達成目的之 包裝材，完成了本發明。 因此，本發明之目的，係在於提供一種具優異氣密性 及耐藥品性，適合於無機氯化物及其無水物等之吸濕性及 腐蝕性強的粉粒體狀藥品之輸送、保管及搬運之輸送用包 --I I I 1 I ----F t --J I I I I I 訂-J Ϊ I ---i^ (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中a國家標準（CNS)A4規格（210 X 297公釐） -7- k A A7 經濟部智慧財產局員工消費合作社印製 ______ B7 ___ 五、發明說明（？) 裝材。 又1本發明之目的，係在於提供一種每單位之塡充量 大之包裝，容器之回收再利用容易，且對製品之重量容器 之佔有重量小，亦可適於大量輸送之輸送用包裝材。 【用以解決課題之手段】 亦即，本發明，其特徵爲：由具優異防濕性、耐酸性 及瓦斯防護性之以多層樹脂薄膜形成之瓶罐型內袋、及收 容此瓶罐型內袋同時有優異強度之軟質集裝外袋所組合構 成之具有優良氣密性及耐藥品性之輸送用包裝材。 於本發明中，瓶罐型內袋，係以從袋中央部到下部排 出部漸漸地收縮之形狀，使內容物之全部量圓滑地排出， 爲防止空氣中分子狀水分致使內容物劣化或產生氯化氫瓦 斯向外部擴散，對於形成此瓶罐型內袋之多層樹脂薄膜， 必須至少具優異耐酸性及瓦斯防護性之樹脂薄膜層（A ) 。而，做爲此樹脂薄膜層（A )，例如，可舉出以聚偏二 氯乙烯、高密度聚乙烯、聚乙烯醇、聚丙烯等，而對防止 空氣中分子狀水分之侵入的防濕性這一點上1其中尤其是 聚偏二氯乙烯、高密度聚乙烯、及聚乙烯醇爲適宜。 又•關於形成瓶罐型內袋之多層樹脂薄膜，在上述樹 脂薄膜層（A)之兩面上以熱封等之封緘爲目的，貼合有 封緘用之樹脂薄膜層（B )來構成 > 再者，位於外側之封 碱用樹脂薄膜層（B )之外側面上，構成有以多層樹脂薄 膜全體之補強爲目的，亦可貼合有補強用樹脂層（C )。 ---I ! ! ·裝 i ί I 訂.J ---_# (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -8- A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明（6 ) 雖然用在吸濕性較低且很快用盡之少量內容物用之包裝材 的使用情況下，沒有封緘用之樹脂薄膜層（B )也行，但 如要做到具有完全防濕性，完全防止由吸濕產生瓦斯，則 以設有封緘用之樹脂薄膜層（B )較佳，再者，爲防止破 損，則最好設有補強用之樹脂薄膜層（C )。 做爲形成如此之封緘用之樹脂薄膜層（B )之樹脂者 ，例如，有低密度聚乙烯，聚氯乙烯、聚丙烯等，從與其 他薄膜之多層化的觀點，尤其以低密度聚乙烯或聚氯乙嫌 爲佳。又，對於構成多層樹脂薄膜之2種樹脂薄膜層（B )’可以相互爲同種類之樹脂，又亦可相互爲不同種類之 樹脂皆宜。又，做爲構成上述補強用之樹脂薄膜層（C ) 之樹脂，例如，可以舉出P E T樹脂（polyethylen terephthalate resin )等。 又’對於上述樹脂薄膜層（A )，從防濕.性之觀點， 理想爲以3 0〜1 0 Ovm之厚度爲佳，又，對於封緘用 之樹脂薄膜層（B)以能簡單地做熱封之厚度的2 ◦〜 1 0 0 之厚度爲佳’再者，對於補強用之樹脂薄膜層 (C )則以袋子的強度和開閉之難易等做考量，適當地決 定即可。 又’本發明所使用之軟質集裝外袋，基本上是將被充 塡有內容物之瓶罐型內袋包容入，有可支撐內容物重量之 形狀，於其上面部或底面部具備有貫通瓶罐型內袋之塡充 口部或排出口部之上面貫通孔或底面貫通孔，又，具有於 運送或注入時所使用之吊具，以聚丙烯、橡膠等之強韌材 ---1IIII--!-裝— ----訂.！|!!-梦 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 * 297公楚〉-9- iv\9^3' A7 -- B7 經濟部智慧財產局員工消費合作社印製 五、發明說明《) 質所形成，收容上述瓶罐型內袋，於輸送、操作、製品排 出等之作業時，雖具有承受將此瓶罐型內袋吊起等作業之 強度即可’但較適宜的是，可以從開放之上部容易地裝入 於瓶罐型內袋，同時於底部有瓶罐型內袋之排出口用之開 □部’由此開口部使瓶罐型內袋之排出口露出於底部下方 ’從此排出口能將充塡於瓶罐型內袋內之無機氯化物及其 無水物等之粉粒體狀藥品排出者即可。 本發明之輸送用包裝材，例如構成瓶罐型內袋之多層 樹脂薄膜具有封緘用之樹脂薄膜層（B )之情形下，首先 ’將此瓶罐型內袋之排出口部熱封住，其次將瓶罐型內袋 組入於軟質集裝外袋內，讓瓶罐型內袋之排出口部突出於 軟質集裝外袋之底面貫通孔之外部，於此狀態，以設於底 面貫通孔之開口緣部之細繩或絨釦件（velvet fastener)等 所成之繫綁具，將此底面貫通孔之開口緣部捆.挪於瓶罐型 內袋之排出口部，將這些瓶罐型內袋與軟質集裝外袋之間 予以固定後，從瓶罐型內袋之充塡口部充塡內容物，再將 此充塡口部熱封密閉住，再者，與排出口部相同地使充塡 口部突出於軟質集裝外袋之上面貫通孔之外部，並以設於 其開口緣部之繫綁具將瓶罐型內袋和軟質集裝外袋之間予 以固定。藉由做如此之構成，在讓內容物排出之際，即使 切斷瓶罐型內袋之排出口部的熱封部份，藉由繫綁具，內 容物不會從排出口部立刻排出，而能夠進行更安全之排出 作業。 ------裝.！---- 訂-----1_梦 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）-10- A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明@ ) 【發明實施形態】 以下’依據添附圖面所示實施形態之一例，具體說明 本發明之輸送用包裝材。 第1〜4圖係顯示關於本發明實施形態之輸送用包裝 材P。此輸送用包裝材P，係由有優異防濕性、耐酸性及 瓦斯防護性之多層樹脂薄膜所形成之瓶罐型內袋1、及收 容此瓶罐型內袋丨之軟質集裝外袋2所構成。 上述瓶罐型內袋1，如第2圖所示，係具備有：於約 中央部處形成有比較大直徑筒狀之容納部3、及突出於此 容納部3之上部以筒狀形成之充塡口部4、及突出於上述 容納部3之下部以筒狀形成之排出口部5，全體被以具有 均一厚度及柔軟性之多層樹脂薄膜所形成。 又’上述軟質集裝外袋2，如第1、3及4圖所示，於 內部係具備有，大小（即，與容納部3之直徑大略相同之 大小）使上述瓶罐型內袋1之容納部3大約剛剛好可以套 入之內袋收容部6 ’此內袋收容部6之上面部7形成有貫 通上述瓶罐型內袋1之充塡口部4之上面貫通孔8，又， 在此內袋收容部6之底面部9形成有貫通上述瓶罐型內袋 1之排出口部5之底面貫通孔10，將上述瓶罐型內袋1 收容於此軟質集裝外袋2，於瓶罐型內袋1內充塡無機氯 化物及其無水物等之粉粒狀藥品時，瓶罐型內袋1可緊緊 收容於內袋收容部6內，瓶罐型內袋1之充塡口部4與排 出口部5分別從軟質集裝外袋2之上面貫通孔8及底面貫 通孔1 0突出而露出來。 I — — 1 — I,·· · I I I I! I 訂------- —--梦 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）-11 . 五、發明說明p ) (請先閱讀背面之注意事項再填寫本頁) 於此實施形態，在軟質集裝外袋之外面，設有於輸送 、操作、製品排出等之作業時，用以進行吊取等作業之由 吊帶1 1 a及吊繩1 lb所成之吊具1 1 ，又，在上面貫 通孔8及底面貫通孔其開口邊緣部上，設有繫綁住貫通上 面貫通孔8及底面貫通孔1 0之瓶罐型內袋1之充塡口部 4及排出口部5，使瓶罐型內袋1與軟質集裝外袋2之間 固定之繫綁具1 2。 【實施例】 實施例1 如第5圖所示，係將具有熱封性（heat seal )之厚度 4 m之低密度聚乙烯層a爲內側、其外側以具優異瓦 斯防護性之厚度1 0 2 之聚偏二氯乙烯b、有接著性 之厚度2 0 之低密度聚乙烯層c、及有優異強度之厚 度1 2 # m之補強用P E T樹脂層d順次積層，調製爲多 層樹脂薄膜，用此多層樹脂薄膜製成如第2圖所示之瓶罐 型內袋1 a 經濟部智慧財產局員工消費合作社印製 將此瓶罐型內袋1裝入如第3及第4圖所示之軟質集 裝外袋2內，將瓶罐型內袋1之排出口部5之下端予以熱 封使之密閉，製造成輸送用包裝材P。 從如此所製得之輸送用包裝材P之瓶罐型內袋1的充 塡口部4，充塡以無水氯化鋁（99 7%) 1000 Kg，並將該瓶罐型內袋1內之空氣抽引排去，接著將充 塡口部4熱封密閉住。 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）-12- A7 經濟部智慧財產局員工消費合作杜印製 B7_____五、發明說明（1Q ) 之後，藉由吊車利用設於軟質集裝外袋2之吊具1 1 將之吊起，承載於平台貨架以起重機搬運至室內倉庫，置 於密閉之屋內保管3個月，保管時定期檢查周圍之氯化氫 臭，同時於3個月後割斷排出口部5將內部之無水氯化銘 排出於其他容器，測定了該時之排出性、無水物純度。 結果，除具有吊取搬運之搬運性外，於保管中全無感 知氯化氫臭，又’其排出時之排出性，係以2〜3分鐘排 出，而排出後之瓶罐型內袋1內幾乎沒有無水氯化鋁附著 ，其排出性極爲良好。純度亦與充塡時不變而斷定無吸濕 (請先閱讀背面之注意事項再填寫本頁) 實施例2 如第6圖所示，將具優異瓦斯防護性之厚度6 0 // m之高密度聚乙烯層e爲中心，分別於內側與外側積層 以具有熱封性之厚度4 0 /zm之低密度聚乙烯層a ，調製 爲多層樹脂薄膜，除製造成瓶罐型內袋1之外，與上述實 施例1相同地製造了輸送用包裝材P。 對此實施例2之輸送用包裝材P，進行與上述實施例 1完全相同之測試，其結果與實施例1相同可得到良好之 結果。 並以該無水氯化鋁做爲觸媒來使用，進行投入於反應 器之投入作業。將2 0 0 OKg吊起投入所需要之時間爲 ，每一袋2 0分鐘合計共4 0分鐘。 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 4 4 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明（11 ) 比較例1 將無水氯化鋁做爲觸媒來使用，進行對反應器之投入 作業，以先行之充塡2 5 OKg之桶（汽油桶）進行。 以該桶之情形爲，打開蓋，安裝吊具後吊起至反應器 之投入口，使其反轉進行投入。此時需要之投入時間爲每 桶2 5分鐘，投入2 0 0 0 K g合計需要3小時2 0分鐘 【發明之效果】 本發明之輸送用包裝材，係對於無機氯化物及其無水 物等之吸濕性或腐蝕性強的粉粒狀藥品之輸送、保管及搬 運等，其無水分透過性、不會發生內容物之分解或發生酸 性氯化氫瓦斯等，而且，包裝材料之重量輕、外袋容易回 收利用、廉價、且輸送效率佳、亦可使用於向海外之輸出 ，再者，製品之充塡·排出之作業效率也好。 【圖面之簡單說明】 第1圖係關於本發明實施形態之輸送用包裝材的立體 說明圖。 第2圖係於第1圖之輸送用包裝材所使用之瓶罐型內 袋的立體說明圖。 第3圖係於第1圖之輸送用包裝材所使用之軟質集裝 外袋的平面說明圖。 第4圖係顯示第3圖之軟質集裝外袋的底面說明圖。 本紙張尺度適用中國國家標準（CNS)A4規格（21〇χ 297公釐） ------------------!----訂·---------姨 (請先閱讀背面之注意事項再填寫本頁)A7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs _B7_ V. Description of the Invention (1) [Industrial Use Field] This invention is a powder that is highly hygroscopic or corrosive to inorganic chlorides and anhydrous substances Packaging materials for transporting, storing, and transporting granular medicines with excellent airtightness and chemical resistance. [Advanced technology] In general, when transporting powdered and granular medicines for industrial raw materials and products, the physical and chemical properties of the powdered and granular medicines must be considered, and their adaptation to use conditions must be considered, and then selected Container or output means. However, such powder and granular medicines are highly hygroscopic or corrosive. Generally speaking, related powder and granular medicines, when placed in the open state in the atmosphere, will absorb moisture in the air and dissolve (dissolve moisture) ), Due to the absorption of moisture and decomposition of the main components, in addition to the occurrence of corrosive gas such as hydrogen chloride and low purity, a strong acidity * will also cause corrosion of the container or output means, which may reduce its service life. Here, for the transportation of such hygroscopic or corrosive powdered medicines, the powdered medicines are generally filled with excellent airtightness and prevent air or molecular moisture from entering. Corrosion resistant container. For example, since anhydrous chlorides such as anhydrous aluminum chloride and anhydrous ferric chloride are substances with such properties, 'a lot of reviews have been made on their filling, storage, and transportation so far.' For example, the use of Materials such as plastic that can prevent the intrusion of molecular water and have excellent corrosion resistance to hydrogen chloride gas are countermeasures. For example, the number of thick steel plates used as the container 1 for transporting such materials < Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)- 4-A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the Invention (?) The iron container (iron cabinet) is well known. This iron cabinet has different specifications and has different specifications according to users. It has a filling port and a discharge port, and is made sturdy as a whole. It has a cover with a filling port and a discharge port. It has excellent air tightness. It is not easy to be damaged for accidents during transportation. In addition, it has a low possibility of leakage of contents, and has the advantages of safety and the like, and the advantage of being able to be reused. However, in recent years, in order to prevent the deterioration of product quality or the corrosion of containers, in addition to the safety of transportation, the logistics can be efficiently carried out in large quantities, and the amount of overseas transportation is also large. Containers that do not require complicated procedures during discharge. Therefore, in the leading iron cabinet, the weight of the container itself occupies a large amount of conveying weight. When recovering empty containers, it also causes problems such as poor efficiency due to the large volume. In addition, even in the ordinary domestic product transportation, in order to meet the customer's acceptance situation, there are many types of containers and it is difficult to share, and the iron cabinet is in use. In order to ensure the quality of the next filling product, it is necessary to The inside is cleaned by cleaning, drying, and replacing with high humidity air. In addition, 'at the time of output, it is not very suitable to use the iron cabinet as a container.' The reason is that the same problem described above will be more significanta. For example, 'Recycling of empty containers takes time, so it must be used. Increasing the number of containers to cope with, so it can be predicted that for a large number of containers, management will become complicated, and this reason will increase costs. Also, as another container for transporting such materials, there is a well-known resin-lined barrel (commonly known as a gasoline barrel). The container weight of the barrel is relatively light, except for the strength protection of the metal formed on the outside. Material outside, inside (please read the precautions on the back before filling this page}.! I — III Order ---- --- Green paper size is applicable to China National Standard (CNS) A4 grid < 210 X 297 Mm>, 5-A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention <?) The resin-coated inner layer has corrosion resistance. Remove the problem of the iron cabinet. · 'This barrel is relatively lightweight' has excellent corrosion resistance and moisture resistance, and is used as a common container at home and abroad. Due to its general circulation, it can be used as a disposable container. Therefore, in addition to the advantages of not having to increase the logistics surface of the recovery process, it is particularly suitable for being used as an output. However, this barrel is a one-time use, which increases the packaging cost. The filling operation is about 200 kg per barrel, and the number of operations per unit weight is 4 to 5 times that of the iron cabinet. There is a special container reversing device, the workability is still low, and the cost of the product is affected. Moreover, as a packaging material with high moisture resistance, there are various multilayer resin films known, but many It is used in small packages of hundreds of grams for food, heating appliances (disposable stoves), etc. However, when these multilayer resin films are used for packaging, it is necessary to consider whether the thickness, strength, and flexibility of the film are possible for bag making, and it is difficult to obtain a sheet as a packaging material in a required size, etc. And other practical issues. Therefore, although it is used only in a small amount ', it has excellent moisture-proof performance, but it is difficult to use it in large-scale packaging in ton's transportation, so that it cannot meet all the performance and functions equivalent to conventional transportation containers. Also, as a packaging material for powder and granules with a high hygroscopicity of several tens of kilograms, there are medium-sized packaging materials with excellent moisture resistance, such as well-known resin films such as polyvinyl chloride, Polyvinyhdene chloride with gas protection (interrupting) gas function or (Please read the precautions on the back before filling this page) This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) -6-Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs__B7__ V. Description of the Invention (4) is a paper bag made of aluminum foil and paper laminated with a multilayer film (Japanese Patent Laid-Open No. 5-51952) — 7859, and JP-A-63-178949, etc.). However, 'paper bags made of aluminum foil, because resin films such as polyethylene and polyvinylidene chloride can penetrate hydrogen chloride, etc., therefore, aluminum foil cannot be used as a packaging material for corrosive related substances. In addition, the use of paper bags such as polyvinylidene chloride is 'high in moisture resistance', but because the strength of the bag itself is low, even if it can be used in a package of 20 to 3 OKg, it cannot bear more than its weight. It can be used as a container of 1 to 2 tons. In addition, when it is discharged, the opening operation of the bag must be performed by manpower, so it is not suitable for substances that cause gas generation after moisture absorption. [Problems to be Solved by the Invention] Therefore, the inventors should develop an air-tightness and chemical resistance that are excellent, and be convenient for operations such as filling and discharging, and also suitable for large-scale transportation of inorganic chlorides. The packaging materials used for transportation, storage, and transportation of hygroscopic and corrosive powdery and granular medicines, such as anhydrous materials, etc., were carefully reviewed, and the packaging materials used for this transportation were bottle-type inner bags. And the soft container outer bag has a double structure, which makes the bottle-can inner bag show airtightness and chemical resistance. At the same time, the soft container outer bag is added to bear the strength during storage and transportation. The packaging material which can achieve the purpose completes the present invention. Therefore, the object of the present invention is to provide a powdery and granular medicine with excellent airtightness and chemical resistance, which is suitable for the transportation, storage, and storage of powdery and granular medicines that are highly hygroscopic and corrosive to inorganic chlorides and anhydrous substances. Conveying package for carrying --III 1 I ---- F t --JIIIII order -J Ϊ I --- i ^ (Please read the precautions on the back before filling this page) This paper applies the national standard of a (CNS) A4 specification (210 X 297 mm) -7- k A A7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ______ B7 ___ V. Invention Description (?) Packing materials. Another object of the present invention is to provide a packaging material with a large filling capacity per unit, which is easy to recycle and reuse the container, and has a small weight of the product. The container can also be suitable for a large number of transportation packaging materials. . [Means to solve the problem] That is, the present invention is characterized by a bottle-can type inner bag formed of a multilayer resin film having excellent moisture resistance, acid resistance and gas protection, and a container type The inner bag also has a combination of a soft container outer bag with excellent strength, which is a packaging material for transportation with excellent air tightness and chemical resistance. In the present invention, the inner shape of the bottle-can type is a shape that gradually shrinks from the central portion of the bag to the lower discharge portion, so that the entire amount of the contents is smoothly discharged, in order to prevent molecular moisture in the air from deteriorating or generating the contents Hydrogen chloride gas is diffused to the outside. For the multilayer resin film forming the bottle-can inner bag, it must have at least a resin film layer (A) with excellent acid resistance and gas protection. As the resin film layer (A), for example, polyvinylidene chloride, high-density polyethylene, polyvinyl alcohol, polypropylene, and the like can be used to prevent moisture from entering the molecular moisture in the air. Among these, 1 is particularly suitable for polyvinylidene chloride, high-density polyethylene, and polyvinyl alcohol. Also, regarding a multilayer resin film forming a bottle-can inner bag, a resin film layer (B) for sealing is formed on both sides of the resin film layer (A) for sealing purposes such as heat sealing > In addition, the outer side of the alkali-sealing resin film layer (B) is formed on the outer side thereof for the purpose of reinforcing the entire multilayer resin film, and a reinforcing resin layer (C) may also be bonded. --- I!! · Install i ί I order. J ---_ # (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ) -8- A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention Description (6) Although it is used in packaging materials with low hygroscopicity and a small amount of content that is quickly used up, there is no The resin film layer (B) for sealing is also acceptable, but if it is to have complete moisture resistance and prevent gas generation from moisture absorption, it is better to provide a resin film layer (B) for sealing. Furthermore, In order to prevent damage, it is preferable to provide a resin film layer (C) for reinforcement. As a resin for forming such a resin film layer (B) for sealing, there are, for example, low-density polyethylene, polyvinyl chloride, polypropylene, etc. From the viewpoint of multilayering with other films, especially low-density polyethylene Or polyvinyl chloride is better. The two types of resin film layers (B) 'constituting the multilayer resin film may be resins of the same type or resins of different types. Moreover, as a resin which comprises the said resin film layer (C) for reinforcement, P E T resin (polyethylen terephthalate resin) etc. are mentioned, for example. The resin film layer (A) is preferably a thickness of 30 to 10 Ovm from the viewpoint of moisture resistance, and the resin film layer (B) for sealing can be easily formed. The thickness of the heat-sealed layer is preferably from 2 ◦ to 100 °. Furthermore, the strength of the resin film layer (C) for reinforcement is determined by considering the strength of the bag and the ease of opening and closing. Also, the soft container outer bag used in the present invention basically contains a bottle-shaped inner bag filled with contents, and has a shape capable of supporting the weight of the contents. The upper face or the bottom face is provided with The top through hole or the bottom through hole of the filling and discharging part of the inner bottle-shaped inner bag has a spreader used for transportation or injection, and strong materials such as polypropylene and rubber- -1IIII-!-Equipment ------ Order.! | !!-Dream (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 * 297 Gongchu) -9- iv \ 9 ^ 3 'A7-B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention ") Formed by the quality organization, to house the bottle-inner-type inner bags. The strength of the operation such as lifting is sufficient, but it is more suitable that it can be easily loaded into the bottle-type inner bag from the open upper part, and at the same time, there is an opening part for the discharge port of the bottle-type inner bag at the bottom. This opening allows the outlet of the bottle-shaped inner bag to be exposed below the bottom. From this outlet, it is possible to discharge powdered and granular medicines such as inorganic chlorides and anhydrous substances filled in the bottle-shaped inner bag. . In the case of the packaging material for conveyance of the present invention, for example, when the multilayer resin film constituting the bottle-can inner bag has a resin film layer (B) for sealing, first, the outlet of the bottle-can inner bag is heat-sealed. Secondly, the inner bottle-shaped inner bag is assembled into the soft outer container, so that the discharge port of the inner bottle-shaped inner bag protrudes from the outside of the through hole of the bottom surface of the soft outer container. The straps made of string or velvet fastener at the opening edge of the hole are bundled with the bottom edge through the opening edge of the hole. Move them to the outlet of the bottle-shaped inner bag and bind these bottles After fixing between the can-shaped inner bag and the flexible container outer bag, fill the contents from the filling mouth of the bottle-shaped inner bag, and then heat-seal the filling mouth and seal it. The same filling part protrudes outside the through hole of the upper surface of the flexible container outer bag, and fixes between the bottle-shaped inner bag and the flexible container outer bag with a binding device provided at the opening edge portion. . With such a structure, when the contents are discharged, even if the heat-sealed portion of the discharge port portion of the bottle-shaped inner bag is cut, the contents are not discharged from the discharge port portion immediately by binding the straps. This enables safer discharge operations. ------ install.! ---- Order ----- 1_Dream (Please read the notes on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -10- A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention @) [Inventive Embodiments] The following will specifically describe the packaging materials for transportation of the present invention based on an example of the embodiment shown in the attached drawing. Figures 1 to 4 show the packaging material P for transportation according to the embodiment of the present invention. The packaging material P for transportation is a bottle-can inner bag 1 formed of a multilayer resin film having excellent moisture resistance, acid resistance and gas protection, and a soft container outer bag containing the bottle-can inner bag 丨2 is composed. As shown in FIG. 2, the bottle-can inner bag 1 is provided with a relatively large-diameter cylindrical receiving portion 3 formed at about the central portion, and a cylindrical portion protruding above the receiving portion 3 and formed in a cylindrical shape. The filling opening portion 4 and the discharge opening portion 5 formed in a cylindrical shape protruding from the lower portion of the accommodating portion 3 are all formed by a multilayer resin film having a uniform thickness and flexibility. Also, as shown in Figs. 1, 3 and 4, the above-mentioned soft outer container 2 is provided inside with a size (that is, approximately the same size as the diameter of the accommodating portion 3) to make the above-mentioned bottle-can inner bag 1 The accommodating portion 3 can be fitted into the inner bag accommodating portion 6 approximately. The upper surface portion 7 of the inner bag accommodating portion 6 is formed with an upper through hole 8 penetrating the filling mouth portion 4 of the bottle-shaped inner bag 1. A through-hole 10 is formed in the bottom surface portion 9 of the inner bag accommodating portion 6 and penetrates the bottom opening portion 5 of the bottle and can type inner bag 1, and the bottle and can type inner bag 1 is accommodated in the soft container outer bag 2. When the bottle-shaped inner bag 1 is filled with powdered and granular medicines such as inorganic chlorides and anhydrous substances, the bottle-shaped inner bag 1 can be tightly stored in the inner-bag storage portion 6 and the bottle-shaped inner bag 1 The filling opening portion 4 and the discharge opening portion 5 protrude from the upper through hole 8 and the lower through hole 10 of the flexible container outer bag 2 and are exposed. I — — 1 — I, ·· · IIII! I order ------- --- Dream (please read the precautions on the back before filling out this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -11. V. Description of the invention p) (Please read the precautions on the back before filling this page) In this embodiment, the outer surface of the soft container is provided for transportation, operation, When discharging products, etc., a sling 11 made of a sling 1 1 a and a lifting rope 1 lb is used for lifting and other operations, and on the opening edge of the upper through-hole 8 and the bottom through-hole, The bottle-and-canister inner bag 1 is provided with a filling opening 4 and a discharge port 5 which tie the through-hole 8 and the bottom-hole through hole 10, so that the bottle-and-canner inner bag 1 and the flexible container outer bag 2 The fixed tie 1 2. [Example] Example 1 As shown in FIG. 5, a low-density polyethylene layer a having a heat seal thickness of 4 m is used as the inner side, and its outer side is provided with a thickness of 10 which is excellent in gas protection. 2 polyvinylidene chloride b, a low-density polyethylene layer c with a thickness of 20, and a PET resin layer d with a thickness of 1 2 # m having excellent strength are sequentially laminated to prepare a multilayer resin film. Use this multilayer resin film to make a bottle-shaped inner bag 1 as shown in Figure 2. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Put this bottle-shaped inner bag 1 into Figures 3 and 4. In the soft container outer bag 2, the lower end of the outlet 5 of the bottle-shaped inner bag 1 is heat-sealed to seal it, and a packaging material P for transportation is manufactured. From the filling mouth portion 4 of the bottle-can inner bag 1 of the packaging material P for transportation thus prepared, 1,000 kg of anhydrous aluminum chloride (99 7%) was filled and the bottle-can inner bag 1 was filled. The air is evacuated and exhausted, and then the filling mouth portion 4 is heat-sealed and sealed. This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -12- A7 Printed by the consumer cooperation of the Intellectual Property Bureau of the Ministry of Economic Affairs B7 _____ 5. After the invention description (1Q), the equipment is used by crane Lift the sling 1 1 in the soft container outer bag 2 and lift it, carry it on the platform shelf and carry it to the indoor warehouse by crane, store it in a closed room for 3 months, and periodically check the surrounding hydrogen chloride odor during storage. After 3 months, the discharge port 5 was cut off, and the anhydrous chloride in the inside was discharged to another container, and the discharge property and the purity of the anhydrous substance at that time were measured. As a result, in addition to the transportability of lifting and conveying, there was no perceived hydrogen chloride odor during storage, and its dischargeability at the time of discharge was discharged in 2 to 3 minutes, and the bottle-shaped inner bag 1 after discharge was almost There is no adhesion of anhydrous aluminum chloride, and its discharge property is extremely good. The purity is also the same as when it is filled. It is determined that there is no moisture absorption (please read the precautions on the back before filling this page). Example 2 As shown in Figure 6, the thickness of the gas with excellent gas protection 6 0 // m The high-density polyethylene layer e is centered, and a low-density polyethylene layer a having a heat-sealing thickness of 40 / zm is laminated on the inside and the outside, respectively, and prepared into a multilayer resin film. A packaging material P for transportation was produced in the same manner as in Example 1 described above. The packaging material P for transportation in Example 2 was subjected to the same tests as in Example 1 above, and the results were the same as in Example 1 and good results were obtained. The anhydrous aluminum chloride was used as a catalyst, and the reactor was put into the reactor. The time required to lift the 2 0 OKg into is 20 minutes for each bag of 20 minutes. This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 4 4 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (11) Comparative Example 1 Anhydrous aluminum chloride as The catalyst is used and the reactor is put into operation. It is carried out with a barrel (gasoline barrel) filled with 2 5 OKg. In the case of the barrel, the lid is opened, and after being installed with a spreader, it is lifted to the inlet of the reactor, and it is put in reverse. At this time, the input time is 25 minutes per barrel, and it takes 3 hours and 20 minutes for the total input of 2000 kg. [Effect of the invention] The packaging material for transportation of the present invention is for inorganic chlorides and anhydrous substances, etc. The hygroscopic or corrosive powdered and granular medicines are transported, stored, and handled. They have no moisture permeability, do not decompose the contents, or generate acidic hydrogen chloride gas. Also, the packaging materials are light in weight and The bag is easy to recycle, cheap, and has good transportation efficiency. It can also be used for export to overseas. Furthermore, the efficiency of filling and discharging the product is also good. [Brief description of the drawing] Fig. 1 is a perspective explanatory view of a packaging material for transportation according to an embodiment of the present invention. Fig. 2 is a perspective explanatory view of a bottle-can type inner bag used in the conveying packaging material shown in Fig. 1; Fig. 3 is an explanatory plan view of a flexible container outer bag used in the conveying packaging material of Fig. 1; FIG. 4 is an explanatory diagram showing the bottom surface of the soft container outer bag of FIG. 3. This paper size applies the Chinese National Standard (CNS) A4 specification (21〇χ 297 mm) ------------------! ---- Order · ----- ---- Aunt (Please read the notes on the back before filling this page)
五、發明說明（12 ) 第5圖係用以製造本發明實施例之輸送用包裝材瓶罐 型內袋的多層樹脂薄膜的斷面說明圖。 第6圖係用以製造另一實施例之輸送用包裝材瓶罐型 內袋的多層樹脂薄膜的斷面說明圖。 經濟部智慧財產局員工消費合作社印製 【圖號說明】 F :輸送用包裝材 1:瓶罐型內袋 2 :軟質集裝外袋 3 :容納部 4 :充塡口部 5 :排出口部 6 :內袋收容部 7 :上面部 8 :上面貫通孔 9 :底面部 1 0 :底面貫通孔 1 1 :吊具 1 2 :吊帶 1 3 :吊繩 1 4 :繫綁具 a ，c :低密度聚乙烯層 b :聚偏二氯乙烯層 d : P E T樹脂層 -I---11!!裝— — —訂-----------餘 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -15- 41943^ 經濟部智慧財產局員工消費合作杜印製 A7 _B7 五、發明說明（13 ) e :高密度聚乙烯層 Ϊ i -----------裝--------訂--- (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -16 ·V. Description of the invention (12) FIG. 5 is a cross-sectional explanatory view of a multilayer resin film used to manufacture a bottle-and-can inner bag of a packaging material for transportation according to an embodiment of the present invention. Fig. 6 is a cross-sectional explanatory view of a multilayer resin film used for manufacturing a packaging container bottle-type inner bag for conveying in another embodiment. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs [Illustration of drawing number] F: Packaging materials for transportation 1: Bottle-shaped inner bag 2: Soft container outer bag 3: Storage section 4: Filling mouth section 5: Discharge outlet section 6: Inner bag storage section 7: Upper surface portion 8: Upper surface through hole 9: Bottom surface portion 1 0: Bottom surface through hole 1 1: Sling 1 2: Sling 1 4: Sling 1 4: Fastener a, c: Low Density polyethylene layer b: polyvinylidene chloride layer d: PET resin layer-I --- 11 !! Packing — — — Order ----------- I (Please read the precautions on the back first (Fill in this page again) This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) -15- 41943 ^ Intellectual Property Bureau, Ministry of Economic Affairs, Consumer Consumption Du printed A7 _B7 V. Description of Invention (13) e : High-density polyethylene layer Ϊ i ----------- Packing -------- Order --- (Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 Specification (210 X 297 mm) -16 ·