TW418239B - Red reactive dyes, their composition and dyeing method empolying them - Google Patents

Abstract

A red reactive dye having the following formula (I), in its free acid form: wherein X is -CH=CH2 or -C2H4W (wherein W is -OSO3H or halogen), A is a C2-3 alkylene group or a C2-3 alkylenoxy C2-3 alkylene group, E is a hydrogen atom, a C1-3 alkyl group or -A-SO2X(wherein A and X are as defined above), n is 0 or 1, l is 1 or 2, m is 0 or 1, and R is a hydrogen atom, -OH, -CN, -CH3, -CF3, -SO3H, -COOH, -CH2SO3H or -CH2SO2X (wherein X is as defined above), provided that when R is a hydrogen atom, each of m and n is 0, l is 1, and -SO2X is -SO2C2H4W which is boned at the ortho position to the azo group, and when each of m and n is 0 and l is 1, R is not -SO3H.

Description

.418239

V. Inventions (1) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs This invention is about water-soluble monoazo-based reactive dyes, which are used for materials containing hydroxyl or amido groups such as cellulose fibers, Dyed or printed with natural or synthetic synthetic fibers, polyurethane fibers or leather, or a mixture of these fibers. More specifically, this relates to a reactive dye capable of dyeing a particular cellulose fiber to become red and being fixed in light and excellent in leveling property, a composition thereof, and a dyeing method using the same. Reactive dyes are widely used for the dyeing of different materials, especially cellulose fibers, because of their bright colors and their excellent gripping properties. On the other hand, in the field of dye industry, the demand for better dyes is also increasing. In recent years, the red type of reactive dyes are excellent in light fixation, and their demand is much higher than before. Conventional reactive dyes are usually at the level of level 4 and no dyes are known to be superior to level 5 (after exposure to carbon arc light for 80 hours). In order to meet the above requirements, the present invention has conducted extensive research to develop a red reactive dye which is excellent in light fixation, color fixation to light and sweat, and color fixation to chlorine , Especially in terms of light fixation. As a result, the present invention has been completed. The present invention provides a red reactive dye which has the following formula (I) and is in free acid form, and its composition and dyeing method: (Please read the precautions on the back before filling this page) -tl --------- line. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -4-A7 B7 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Instructions (2)

Where X is a ch = ch2 or a c2h4w (where W is -0S03H or halogen ratio), A is C2-c3 alkylene or C2_3 alkylalkoxy C2_3 alkylene, E is hydrogen atom, Chs alkyl Or -A-S Ο 2-X (where A and X are as defined above), 11 is 0 or 1, and 1 or 2, m is 0 or 1, and R is a hydrogen atom, —OH, — CN, -CH3, a CF3,-so3h, -c Ο Ο Η, a CH2S03H or a CH2S02X (where X is as defined above), but if R is a hydrogen atom, m and η are 0, 芡 is 1_, S02X is _S02C2H4W It is bonded to the ortho position of the azo group. In addition, if m and η are both 0 and 5 is 1, R is not -S Ο 3 Η. Now, the present invention will be described in more detail with reference to this more specific part. In the above formula (I), X is a ch = ch2 or -C2H4W, where W is a base which can be split by 鹸 "Under the action of this base, -c2h4w splits so that it will be converted into a CH = CH2 however separates W-H. When this group is cleaved under the action of a certain base, _0S03H, SS03H '— OPO3H2, _〇C〇CH3, or a " dentin ^^ standard is applicable to China National Standard (CNS) A4 specifications (210 x 297 mm) ------------: ^ -------- Order --------- line (Please read the precautions on the back before filling this page) 418239 A7 B7 V. Description of the invention (3) (Please read the notes on the back before filling this page) Atoms are usually referred to. Particularly preferred is 0 s0sH. This C 2-3 alkylene group or C 2-3 alkylene oxide C 2-3 alkylene group may be, for example, ethyl, propyl, ethoxy, or propyl Examples of oxy-propyl-specific A-so2x include chloro- (cold-chloroethylsulfonyl) ethyl, -r-(y5 -chloroethylsulfonyl) propyl, -r- (Θ —Ethylsulfonylsulfate) propyl, —Θ — (ethenylsulfenyl) ethyl, mono-> 9 [Lu — (Θ —chloroethylsulfonyl) ethoxy] ethyl, —r One [r — (point monoethylsulfonylsulfonyl) propoxy] propyl group, and one / 3— [point one (vinylsulfonyl) ethoxy] ethyl group. Particularly preferred are, for example, C2H4S 〇2CzH4〇S O3H, -C3HeS 〇2C2H40 S 03H and -c2h4〇 C2H4S 02C2H40 s 03H. The Ci_3 alkyl group of E may be, for example, methyl, ethyl or propyl. Particularly preferred are methyl or ethyl β and 1 ^ is preferably a sulfonic or carboxyl group. From the viewpoint of light fixation and color fixation to light and sweat, the reactive dye in formula (I) is preferably a reactive dye, which is printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs. Clothing

η is 0 or 1, J? is 1, X is a C2H4SO3H, the ruler is a sulfonic acid group or a carboxylic acid, and m is 0. Furthermore, the reaction of formula (I)

E

I-type dyes in which (C — N_A) nS02X or R is located on para-azo

II 〇 If it is an adjacent location, it is also excellent in color fixation to chlorine. This paper is applicable to the national standard (CNS) A4 specification '(210 x 297 mm) -6 1 4 1 82? 9 ί_I 散 Α7 j Α ,. Β7 丨. V. Description of the invention (4) The reactive dyes of the present invention can be prepared as follows. That is, a compound of formula (A):

Among them, X, A, E 'R' η and p are as defined above. This is diazotized according to a conventional method, and then a compound of the following structural formula (B) is used to couple with it.

---------------- Install --------- Order ---------- Line®. ≪ Please read the notes on the back before filling (This page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, where m is as defined above, and is performed in a water-soluble medium at a temperature of 0 to 5 ° (: 2 to 3 with mouth water), and then chlorinated Sodium is added to the reaction solution, and the formed precipitate is collected by filtration. With this type of reactive dye, it is possible to improve the leveling property and to combine it into a composition by 2 or more dyes to enhance Such a dye composition can be a composition including a dye of formula (I), where X is a ch = ch2 and a dye of formula (I) where X is -C 2 H 4W, which is a composition containing The dyes of the following formula (I-A) and the dyes of the following formula (I-B): This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 418239 A7 B7 Announcement

5. Description of the invention (

F

(I-A)

(IB) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs or a composition containing a dye of formula (I) where ten f — IjJ-A + ns 〇2X is an adjacent position bonded to an azo group, and DE A dye of the formula (I) and wherein the same base is bonded at the para position, that is, the unitary composition contains a dye of the following formula (I-C) and a dye of the following formula (I_D):

工 -C) ------------- Installation -------- Order --------- < Please read the precautions on the back before filling this page) This scale is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -8 ~ 4 1823 ^ 丨 5 A7 B7 L ·. 5. Description of the invention (II E 0

[X〇2SfA-N-C ^ < P > R

(ID) or a composition containing a dye of formula (I) where m is 0 and a dye of formula (I) and _ where m is 1, that is a composition is a dye comprising the following formula (I_E) and the following formula (I-F) dye: f

(IE) ----------- t -------- Order · --------- M (Please read the notes on the back before filling this page) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperation

(I-F) In the above formulae (I-A) to (I-F), 'the X, A, E R, η, m and ί are as defined above. A preferred example of this dye containing such a composition is to include the following formula (η This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -9--4 1 823 V. Description of the invention (7) ) To (V): A7 B7

X〇2S

II so3h

(III) (Please read the notes on the back before filling this page)

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (IV) (V) In the above formulas (Π) to (V), X is as defined above. When the dyes of the above formulas (Π) to (V) are combined to form a composition, a known formula (VI) (see Japanese Examined) is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297). (%) Order ---------- 4y -10-418239 / a ·: -K- y- A7 V. Description of Invention (8) Patent Publication No. 1 6 4 3/1 9 5 6) The dye can then be incorporated into:

(VI) Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs In the present invention, the dyes of the formulae (π) to (v) can be arbitrarily combined to obtain a dye composition. The ratio of the respective dyes varies depending on the composition of the dye composition. For example, if a composition contains dyes of the formulae (π) and (π), the weight ratio of (n) :( m) is usually from 100: 30 to 100: 300, preferably from 100: 70 to 100: 130; if a composition contains dyes of formulae (π) and (IV), then the weight ratio of (Π) :( IV) is usually 100: 10 to 100: 200, preferably 100. : 20 to 100: 150 'more preferably 100: 30 to 100: 100; and if a composition contains a dye (VS) where X is -ch = ch2 and a dye (ES) where X It is a C2H4w, and the weight ratio of (vs) :( ES) is usually 100: 1 to 100: 50, preferably 100 3 to 100: 4. Q is better: 100: 5 to 1 0 0: 3 0 »The dyes of the formulae (I) to (VI) of the present invention may exist in the form of their free acids or their salts, respectively. In its _ form towel, it can be applied to the national standard (CNS) A4 specification (210 X 297 mm) of the metal paper scale (please read the precautions on the back before filling this page). ~ 11

418239 5. Description of the invention (9) Salts and alkaline earth metal salts, especially sodium, potassium and lithium salts are preferred. However, in order to obtain a liquid composition having a high concentration, a lithium salt is particularly preferable. In order to prepare the reactive dye composition in the present invention, the dyes of the formulae (Π) to (IV) may be mixed by synthesizing them simultaneously. Otherwise, they can synthesize and mix them separately. Alternatively, it can be mixed at the time of dyeing. However, by combining the condensation products of monosulfonic acid or alkylphosphonium sulfonic acid with formaldehyde and a pH buffering reagent, it can show that the buffering effect is in the range of ρΗ4 to 7, and The above composition can improve the solubility and the stability of the solution in water or an alkaline aqueous solution. In the present invention, the alkyl fruit sulfonic acid may be a low alkyl sulfonic acid, such as a methyl sulfonic acid, an ethyl sulfonic acid, a propyl sulfonic acid, or a butyl sulfonic acid. A sulfonic acid may be not only a monoalkyl compound but also a polyalkyl compound such as a dialkyl compound or a mixture thereof. The alkyl group may be a single type or a mixture of two or more types, and may be a mixture with fruit sulfonic acid. This buffering agent exhibits a buffering effect in the range of ρ Η 4 to 7 and includes an acid such as sodium dihydrogen phosphate, Sodium monohydrogen phosphate, potassium dihydrogen phosphate, potassium monohydrogen phosphate, sodium hydrogen phthalate, potassium hydrogen phthalate, acetic acid, tartaric acid and citric acid, and their sodium, potassium and ammonium salts. It can be used alone or as a mixture. When the sulfonic acid or alkyl sulfonic acid and the condensation product of formaldehyde and the PF buffering agent are mixed into the above composition, the weight ratio is to apply the Chinese National Standard (CNS) A4 specification for this paper scale (210 X 297 mm) —--------- ^ -------- Order --------- (Please read the notes on the back before filling this page) Economy Printed by the Consumer Cooperatives of the Ministry of Intellectual Property Bureau ~ 12-4 1 823 9%, Α7 Β7 bulletin board

5. Description of the invention (10) The material composition is 20 to 85 parts by weight, the condensation product is 3 to 50 parts by weight, and the P (R) buffer reagent is 1 to 25 parts by weight. The dye composition of the present invention may contain a solubilizer such as urea or ε-caprolactam. It may also include sodium chloride or sodium sulfate, or incorporate anti-dust agents such as mineral oil emulsions, and its acceptable range is based on the fact that there is no adverse effect on the solubility of this dye composition. The amount of such additives can be arbitrarily selected, and is preferably per 100 parts by weight of the above-mentioned dye composition. The total amount of the condensation product of a certain sulfonic acid or alkyl sulfonic acid with formaldehyde and the P Η buffer is It can be as high as 70 parts by weight. In a preferred specific part * the present invention provides a red reactive dye composition comprising 100 parts by weight of a dye having formula (I >) and in its free acid form:

SO.XR where X is -ch = ch2 or a C2H4W (where W is -0S03H or halogen) 'R1 is a hydrogen atom, a S02X, -CH2S02X (where X is -ch = ch2i-c2h4w (where w is _oso3h or Halogen)), halogen atom, low alkyl, low alkoxy, —S02x or a CH2S02X and m is σ or 1 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) ---- ------- .. Install -------- Order --------- < Please read the precautions on the back before filling out this page) Intellectual Property Bureau, Ministry of Economic Affairs, Consumer Consumption Cooperative Printing-13-Printing by Employee Consumer Cooperatives, Bureau of Intellectual Property, Ministry of Economic Affairs 4

, Slave 2 CHO-is in Q

3

R where R2 is a hydrogen atom or _ prime atom, R3 is a hydrogen atom or low alkyl 'R4 is a hydrogen atom, halogen atom, low alkyl or _so2x and where X is ~ CH = CH2 or —C2H4W (W is —0S03H Or halogen), and z is a halogen atom, a hydroxyl group, -In or R5 ί Ν

R ------------ load / V '(Please read the notes on the back before filling out this page) COOH (where R5 is a hydrogen atom or a low alkyl group, and R8 is a hydrogen atom or a halogen atom , Carboxyl, sulfonic or a so2x (where X is as defined above), Y is a hydroxyl group, a ch = ch2 or —CH2CH2W (where W is as defined above), and P is 0 or 1 in the above formula (— 0 S 0 3 Η. For each R 1 and (X), W is preferably a tr-line ridge-

The low alkyl groups of R, R4 and ruler 3 are for one-kilometer paper, and apply the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 14-418239 r). A7 B7 V. Description of the invention (l2)

Ci-4 alkyl groups are, for example, methyl'ethyl, n-propyl or n-butyl, and are generally as described above. For each Z, R1, R2 ,: R4 and R6, the halogen atom is usually a chlorine atom, a fluorine atom or a bromine atom. In particular, Z is preferably a chlorine atom or a fluorine atom 'and each of R1, R2, R4 and R6 is preferably a chlorine atom or a bromine atom. In the above formula (I >), it is particularly preferred that R1 is a hydrogen atom 'and S 02X is an ortho position of the azo group in the benzene ring. As far as the selectivity of each group in the above formula (X.) is concerned, it is not necessary to consider the selectivity as necessary, so that at least one reactive group is present in the reactive dye. These dyes exist in free acid form or in their salt form. If it is in the form of a salt, it may be an alkali metal salt or an alkaline earth metal salt such as a lithium salt, a sodium salt, a potassium salt or a calcium salt. Of the above formulas (I /) and (x >), The water-soluble reactive dye can be prepared by a conventional method, and the production method is not particularly limited. In the present invention, the dye of the formula (X) is usually combined in an amount of 10 to 300 parts by weight, and It is preferably 30 to 120 parts by weight, and is determined per 100 parts by weight of the dye of the formula (1 >). If the amount of the dye of the formula (X) is too little or too much, it is difficult to obtain a dye with good balance of color fixation to light and sweat, color fixation to chlorine and dyeing properties, And this is what the present invention wants. These dyes can be mixed in advance, or they can be mixed at the time of dyeing; the A-scale is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) M, -------- Order * --- 1 ---- Yuan y / ΐ. Y / ί ^ (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -15-A 1 8239 A7 B7 '5 2. Description of the invention (η) The fibers to be dyed by the dye and the dye composition of the present invention may be, for example, cellulose fibers such as cotton, slime, copperamine, and hemp, and nitrogen-containing fibers such as polyamide. Fiber, wool and silk. However, the cellulose weave is particularly excellently dyeable. These fibers can be mixed with fibers such as polyester taps, weave triacetate fibers, or polypropylene fibers. When the cellulose fibers are thoroughly dyed with the dye or dye composition of the present invention, an acid-binding agent composed of an inorganic alkali metal such as sodium bicarbonate or sodium carbonate, or an organic base such as triethylamine can be used. , And dyeing is performed by the addition of a neutral salt such as thenardite or sodium chloride. In particular, dyeing can usually be done at a temperature of 50 to 60 ° C and the use of thenardite at 20 to 50 g / 5. When the cellulosic fabric is dyed by the pressure suction method, the pressure suction method is performed at room temperature or a high temperature, and after drying, the fiber is steamed or dried and heated to fix it. When printing and dyeing cellulose fibers, it is printed in a single phase, a printing paddle such as sodium bicarbonate or other acid binders, and then heated by steam at a temperature of 100 to 160 ° C. , Or in two phases, for example-neutral or weak acid printing paddles, and then weaving to introduce and pass through a high-temperature bath containing electrolyte, or pressurization with alkaline electrolyte The feed solution is used for the feed effect, and the treatment is performed by heating with steam or drying. In this connection, the printing and dyeing paste can be incorporated with a thickener such as sodium glutamate or starch ether, or an emulsifier, and if necessary, an ordinary printing auxiliary such as urea, or a dispersant. This paper size is applicable to China Gujiazheng (CNS) A4 grid (21〇 × 297 public attack) _ _ (read the notes on the back first and then fill out this page)

Α7 Β7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 418239 'Λ 5. Description of the invention fu) The dyeing of this synthetic or natural polyamide or polyurethane fiber is first performed by an acid or weak The acid dye bath is thoroughly impregnated under a controlled p Η value, and then the ρ Η value is changed to neutral, or in some cases to be fixed in an lye. This dyeing is usually performed at a temperature of 6 0 ° 匸 to 120 ° <: Finished below. When cellulose fibers are dyed with the dye or dye composition of the present invention, particularly excellent light fixation, color fixation to light and sweat, and color fixation to chlorine can be obtained. When the above-mentioned red reactive dyes and dye compositions are used for dyeing, by using specific yellow dyes and / or blue dyes in combination, they can obtain particularly excellent light fixation and color against light and sweat. Fixation. As such a yellow dye, one or more dyes of the following formulae (i) to (iv) can be used. (i) where m1 is an integer of 2 or 3, R7 is a hydrogen atom or a lower alkyl group, E1 is an amine group or a COCH3, and A1 is a substituted or extended phenyl group, a fluorenyl group, a fluorenyl group, or a oxonyl group. Yenyl, Y1 is a halogen atom, -NHC2HdS 03H or N-A1-S02X (where R 7 A1 and R7 are as defined above, X is -CH = CH2 or this paper size applies Chinese National Standard (CNS) A4 specifications ( 210 X 297 mm) I ------------ 1. · ------- Order --------- line ^ (Please read the precautions on the back first (Fill in this page)

(SO, H) m -17-α 1 823 86. 8 Α7 Β7 Ⅴ) —c2h4w (where W is —0S03h or halogen), and X1 is X or hydroxyl as defined above) ’

ch3 9 CO I N = — Cll OCH: (ii) COHli

、、 S03H uh3 {Please read the precautions on the back before filling out this page) -pack. Where R8 is low alkyl or low alkoxy, R9 is low alkyl.oxy, and X is as defined above, (S03H ),

ca3 I CO I -CH SO I COiNH

.Then K. t 11 (iii) Order _ Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economics, where is low alkyl, R11 is a hydrogen atom or low alkyl, and A1, X1 and Y1 are as defined above,

41823.i A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (〖6) where η1 is 0 or 1, m2 is 1 or 2, R12 is methyl or carboxyl, and X and X1 are such as The above definition. As the blue dye, one or more dyes of the following formulae (v) to (v i i) can be used.

Ο HH

Where m3 is 0 or 1, and X is as defined above,

Cl 50, Η (vi) SQ2H Cl, where Z1 is an amine group or NH-R14_NHQ2, R13 and R14 are both low alkyl groups, each Q1 and Q2 is 15 (where Y 2 is a halogen atom, 1 or a sulfonic group The size of the benzene paper is applicable to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) ------------ ". 装 -------- Order --- ---- Line (Please read the notes on the back before filling in this page)

Bu if see NH-q1

Ο N -19-418239 A7 B7 V. Description of the invention (17) Amino group 'R15 is a hydrogen atom or a lower alkyl group, and A1 and X1 are as defined above] or r3 · (where Y3 is a halogen atom or 0 C0GK number 1 to 3), and η 3 is a whole

CI t2-nh

Vll S02x Cl----------- II * IIIIIII ί I! I / 1. (Please read the notes on the back before filling out this page) where T1 and T2 are low alkyl and they can Is substituted, and X is as defined above. Β A1 for each of the above formulae (i), (iH), and (vi) represents phenyl or phenyl and may be substituted, and The substituent may be a halogen atom such as a bromine atom or a chlorine atom, a nitro group, a sulfonic group, a carbonyl group, a Cl-4 fluorenyl group, a Ci-4 alkoxy group, or a -c h2s o2c2h4o s o3h. Specific examples include the following groups (where the symbol * indicates that the bond is connected to a nitrogen atom and it is bonded to a triple well ring): This paper size applies to Chinese national standards (CNS > A4 specifications (210 X 297) Line Θ · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -20-41 8239 Λ7 Α7 Β7 V. Description of the Invention (is)

ch2so2c2h4〇so3h

-21-(Please read the precautions on the back before filling in this page) -Installation '' Order-Q-line paper wave scale is applicable to China National Standard (CNS) A4 (2 丨 0X297 mm) 4 1 8 2.3 & ----------- 丨 Jh / A7: r:?: Umbrella "β7 V. Description of the invention (19

Furthermore, as for the alkylene and alkyleneoxyalkylene groups of A 1, Calkylene and Calkyloxyalkylene groups may be as described above. Specific examples of A1—SOsX1 include a jS— (jS-chloroethylsulfonyl) ethyl group, a r— (point-chloroethylsulfonyl) propyl group, and a < 5— (million chloride Ethylsulfonyl) butyl, r- (Ethylsulfonylsulfonyl) propyl '-/ S — (vinylsulfonyl) ethyl, — [Luchlorochlorosulfonyl) Ethoxy] ethyl, r-[[tau]-(stone-ethylsulfonylsulfonyl) propoxy] propyl, and-[[fluorene- (vinylsulfonyl) ethoxy] ethyl]. Particularly preferred is 可 〇2ίΪ4, δ 0 2 ^ ZH 4. 0 S Ο3Η, printed by the Consumers ’Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs ~ ^ -i — ^-^^ 1 I —i I ^ m I (Please read the note on the back before filling in this page>> CaHeS O2C2H4O S Ο3Η and —C2H4O C2H4S. O2C2H4O S O3H. For each R7, R8 'R1.,! ^ 11 and R15, the lower alkyl is It may be methyl, ethyl, straight-chain or branched propyl, or straight-chain or branched butyl, which may be as described above. Particularly preferred is methyl or ethyl. For each R8 and R9 The lower alkoxy group can be as above, such as methoxy group, ethoxy group, straight bond or branched propoxy group or straight chain or branched butoxy group. This paper is applicable to China National Standard (CNS) A4 specifications ( 210X297 mm) -22-.———— IW gas "J R7 — One 1, —7 .. :: ....) ------ i- 5. Description of the invention (—20)! 1 i Is particularly preferred is methoxy. _...._______----------------- For each Y1, Y2, and Y3 halogen atom, it may be as described above. A fluorine atom, a chlorine atom or a bromine atom. Particularly preferred is a fluorine atom or a chlorine atom ^ These reactive dyes are separable In the free acid form or in its salt form, while in the salt form, it can be an alkali metal salt or earth metal salt 'such as lithium, sodium, potassium or calcium salts are usually preferred — Or one or more members selected from the group consisting of yellow dyes of the formulae (i) to (iv) and / or one or more members selected from the group consisting of blue dyes of the formulae (v) to (vii) The amount used is in the range of 0.01 to 100 times the weight, preferably 0 to 1 to 50 times the weight, and this is relative to the red dye. Moreover, for color adjustment For the purpose, other dyes as the third component can be incorporated within the dosage range that does not detract from the effect of the present invention, for example, in an amount not exceeding 1 Ow t% * Now the present invention refers to the following examples It will be described in further detail. However, it should be understood that the present invention is not intended to be limited to the following examples only. Example 10.2g has the following structural formula in its free acid form (Π_ 1 ) Dyes to dissolve in 20 OinJ? Water: This standard is applicable to Chinese National Standard (CNS ) A4 size (210 X 297 mm) (Please read the notes on the back before filling out this page). Binding --- Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -23-418239 · ...... ....... 〆. ..! Years S., I A7 --r _q -¾ .1 B7…. :: 乂 卜 > > ya twenty two one-one-one of five, Description of the invention (21)

so3h H0350H4 C202 s (Please read the notes on the back before filling this page) Η〇 Then add 10g of thenardite. Then, 10 g of unmercerized cotton cloth was impregnated therein, and the temperature was raised to 50 eC for about 30 minutesa. Then, 4 g of sodium carbonate was added thereto, followed by dyeing at 50 ° C for 1 hour. Thereafter, it was washed with water, then with soap, and then washed with water and completed drying to obtain a ruby red dyeing product with good leveling property. This light fixation is level 5 (40 hours of radiation), the color fixation to light and sweat is level 4+, and the color fixation to chlorine is level 4 _ β Employees, Bureau of Intellectual Property, Ministry of Economic Affairs The light fixation of printed clothing by consumer cooperatives is evaluated in accordance with JISL-0842, and the color fixation of light and sweat is evaluated in accordance with JISL-0888 (Method A, using alkaline artificial sweating). And the color fastness to chlorine is evaluated according to Jf ISL — 0884 (test solution: available chlorine 10 mg / i2, temperature: 25 ± 2 ° C).眚 例 2 1 0 0 g has the following structural formula in its free acid form (E — This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 Gongchu) — 24-4 18239 A7 B7 clothing 5. Description of the invention (22) Ο-SO;

(II-l) and 30 g have the following structural formulas in free acid form (m— i, c = hco, s

so3h

(III-1) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs for blending to obtain a dye composition. 0-lg, 0.2 g, and 0.4 g of this composition were separately dissolved in 20 Omj? Of water, and 10 g of thenardite were added to each solution. Immerse non- mercerized cotton cloth in each solution and increase the temperature to 60 ° C for about 30 minutes. Then, 4 g of sodium carbonate was added thereto, followed by dyeing at 60 ° C for about 1 hour. Thereafter, washing with water, washing with soap, washing with water, and finishing drying are performed to obtain a ruby red dyed product, which has excellent reinforcing properties and excellent leveling property. The light fixation of cloth dyed with 0.2g of composition is grade 5 (40 hours of radiation exposure), and the color fixation to light and sweat is equal to ------------ -------- tr ------- '! 线 # (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) Centimeters) -25-418239

Im aa " b: -9 -Μ- Α7 Β7 丨 Announcement V. Description of the Invention (23) Grade 4+ 'and its color fixation to chlorine is Grade 4 (Examples) [Example 2] In this case, the dyeing was carried out as in Example 1 and it was carried out using reactive dyes of the formula (Dish-1) of 0.1 g, 0.2 g, and 0.4 g. As a result, the enhanced properties obtained were inferior to the dyed products obtained in Example 2. Consumption cooperation between employees of the Intellectual Property Bureau of the Ministry of Economic Affairs, Du printed Example 3 in 2.5 g of hot water and 5.5 g of glass with 50 ° 1 0 0 0 g (padding to wind the water for 20 hours. After that, In boiling soap and 50 g of the dye composition of Example 2 were separately dissolved in this solution and cooled to 25 ° C. »In each solution, 2. 2% sodium hydroxide aqueous solution and 150 g Water glass Baling, and then add water to make the total amount at 25 ° C »Immediately after that, each solution was used as a padding solution solution) and saturated with cotton fibers. This cotton fiber is then sealed in a polyethylene film and stored at 20 ° C. Each dyed product is washed with cold water and hot water and then washed, and then soaped in solution. Then washed with cold water once and finally dried. To obtain a ruby red dyeing product, which has excellent reinforcing properties. Examples 4-1 to 4-20 The reactive dye used in Example 1 was changed to the dye in Table 1, and the dyeing was performed according to Example 1. As a result, the dyed product has the color of the paper and is suitable for Chinese National Standard (CNS) A4 (210 X 297 mm) --- 1 II Ϊ I ----- ^ ---- I --- order-- --- y —... (Please read the precautions on the back before filling this page) Line ©. -26-4 1 823 & A7 B7 V. Description of the invention (24) The color is obtained as indicated in Form 1. , Its light fixation is level 5 (40 hours of exposure), the color fixation to light and sweat is level 4 and the equivalent is the color fixation of chlorine I- B ^ i ^-^^ ^^ 1 In 'τ · ~ ΙΒ In n (Please read the notes on the back before filling in this page) Ordering the C-line The paper size is applicable to China National Standards (CNS) Rule 8 < Grid (210 × 297 mm) ^ 18239 A7 B7 V. Description of the invention ()

Printed by soih No. • —K | -N-AtnS〇2XJi …… 0 E 、, m warp color of the cloth 4-1 S 0 2 C 2 H 4 0 S 0 3 H ho3 s- ^ Q- 0 .. 2 Crimson 4 — 2 S03 H " 302 (: 2 ^ 〇S03 H 0 1 Red 4-3 C 0 OH. ..... 0- _.. . so2c2h4 oso3 h 0 / —Red ij — 4 so2c2h, oso3 h >-<. H ◦〇Q 0. Job X 4-5 S〇2C2H4〇-S〇3 h H 0 —, 0 Red basket 4- 6 S 0 3 HC J.- H ^ C 2 ° .2 S 0 Crimson 4-7 S 0 2 C, H ^ 0 S 0.3 H 0-S 03 H 0 Specifications. (210X297mm) _ — (Please read the precautions on the back before filling out this page) Central Industry Standards Bureau of the Ministry of Economic Affairs, monthly consumer cooperation fi print 4 1823 9 A7 B7 V. Description of the invention (26) Table 1 & lt Outline: >

No. 11 1 v 7-U 0 E j '-R m The color of the dyed cloth is 4-8 f. 2〒2〒 严 3H S 〇3 Η '丄 0 Red 4-9 / 2WAC1-^^ n \ c2h4s〇2c2h4ci S 0 3 Η-0 ―Red 4-10 H〇3s〇H4c2〇2SH4c2N〇c X Η- -h〇3soh4c2〇2sh4c2noc W Η 1 Crimson 4-11 h〇3soh4c2〇2sh2c ^, H〇3S〇H4C2〇2S ^^ r Lion Worker 4 ~ 12 g 02c2h4〇s〇3h 0- H〇3S〇H4C2 ° 2S 1 Crimson 4-13 .conc3h6〇c3h6s〇2c2h4〇s〇3h: 0 Red 4-14 1-CONC9 ~ S〇? CH = CH2-h〇3s- < ^ '0 Red ------ install —------ Order ------ 'line (please read the notes on the back before filling in this education) The paper scale is applicable to China National Standards (CNS) M specifications (210X297 cm) Economic Lang Central华 笱 贝 X Consumer cooperation fiii-catch 4 18239 •. A7 B7 V. Description of invention (27) Table 1 (缡) No, R —HC NA ^ so ^], -Λ 0 E · * J- m The color of the cloth 4-15 S〇2C2H4〇3〇3H H〇33〇H4C2 ° 2SH2C-〇- '0 —Fresh_ 4-16 BrH4C2〇2SH5C3x ^ 3 »woc ^ J >-BrH4C2〇2SH6C3 0 —Weighing ——— 4-17 .CN H〇3s〇H4c2〇2s ^^-'0 —Chief Engineer 4-18 CF. 0- H〇3s〇H4c2〇2SH4c2〇H4c2N〇c. H 1 Crimson 4-19 S〇 2〒4〇S〇3h I., S〇2C2H4〇S〇3H '1 Crimson 4-20 s〇2c2h4〇s〇3h h〇3sh2cH ^-.: 0 Crimson (Please read the notes on the back before filling this page) • Install-, ar This paper size Applicable to China National Ladder Standard (CNS) A4 specification (1I0X297 mm) 18239 I am supplementing A7 B7

V. Description of the invention (28) y Example 50. 2 g of the dye having the following structural formula (W-1) in free acid form is dissolved in 200 mj? Of water:

(iv-l) (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Then add 10 g of thenardite to it. Then 10 g of non- mercerized cotton cloth was impregnated. This temperature was raised to 50 ° C for about 30 minutes' followed by impregnation for 1 hour. After washing with water, soaping, washing and drying, a dyed product with a cyan red color is obtained, which has excellent leveling properties. The light fixation is level 5 (80 hours with carbon arc light), the color fixation of light and sweat is level 4+, and the color fixation of chlorine is level 4_. This evaluation method is carried out in Examples 6-1 to 6-3 using the same method as in Example 1. A dye having the following structural formula (IV-2) in the form of free acid. This paper applies the national standard of 1f1. (CNS) A4 size (210 X 297 mm) -31-1 8 23.9 ^ Revision · Zheng is A7 B7

SO 3 Η (IV-2); and a dye having the following structural formula (IV-3) in free acid form

(IV-3) 1 (Please read the notes on the back before filling out this page) SO ο Η Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs for blending, 0 · 1 g at 2 0 0 and then 1 degree higher Each solution is soaped, and the water has a good composition for 80 hours, and the amount is about 0.2 gj? 0 g non-60 eC in water, then wash and complete the dyeing cloth with enhanced properties) > G and 0 4 in Table 2, and adding 1 mercerized cotton for 20 minutes. "Drying at 60 ° C can get a good uniform light fixation. Light and sweat show to get every 0 g. After immersion in g, the lower dyeing band has cyan dyeability. It is a grade of color solids, a dye, a composition, thenardite to 4 g of carbon per solution for 1 hour. The red staining is 0.5 (the carbon composition is equal to the composition. To dissolve β in a solution separately, and add this warm sodium to the product washed with water, which has an arc of 2. g Light exposure level 4 +, and this paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) -32-418239 • Positive A7 Β7 Example 6 — 1 6-2 6-3 V. Description of the invention (3 〇) This color fixation to chlorine is grade 4. This evaluation was performed by the same method as described in Example 1. Table 2 Dye (IV-2) (g) Dye (IV-3 (g) 10 0 1 0 .10 0 5 1 0 0 2 5 Reference Example 2 Dyeing was performed in the same manner as in Example 6 but Example 6 using 0 · lg, 0.2g, and 0.4g was used. The dye of the formula (IV-2) used in the results. As a result, the product after dyeing is inferior to the product dyed with the composition of Example 6 in terms of enhancing properties. Example 7 2 5 g and 50 g of the dye composition of Example 6-1 was separately dissolved in hot water, and the solution was cooled to 7 5 ° C. To each solution was added 5.5 g of 32.5% sodium hydroxide water-soluble And 150g of water glass with 50 ° BaumS, and then add water to make the total weight reach 100 g at 25 ° C. Immediately after that, each solution was used as a padding solution to impregnate the cotton fabric. Fiber. Then | this fiber is wrapped with twisted water and then sealed in a polyethylene film and stored in a 20 ° C room for 20 hours. Thereafter, the paper produced after this dyeing is compliant with China National Standard (CNS) A4 specifications ( 210 X 297 mm) ----------------------- Order ----- (Please read the notes on the back before filling this page) line. }, Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -33-418239

A7 B7

5. Description of the invention (31) The object is washed with cold water and hot water, and then soaped in a boiling soap bath. The dyed product was washed with cold water, and finally dried to obtain a cyan red dyed product, which had excellent reinforcing properties. Examples 8-1 to 8-3-A dye having the following structural formula (E-1) in free acid form

(工 ι-ΐ) and a dye having the following structural formula (VI)

2 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

(VI) Blend and use the amounts as shown in Table 3 to obtain a dye composition of 0.1 g, 0.2 g, and 0.4 g of each of the compositions, each dissolved in 200 m $ of water. Then, add; 10 g of thenardite is in accordance with the Chinese National Standard (CNS) A4 specifications (210 X 297) for each paper size. ------------------------ --Order --------- line 'J (please read the precautions on the back before filling this page) -34-4 j 8239

The employees of the Intellectual Property Bureau of the Ministry of Economic Affairs consumed the printed solution in the cooperative to prepare a dye solution. 10 g of non- mercerized cotton cloth was immersed in each solution, and the temperature was raised to 60 ° C for about 30 minutes. Then, 4 g of sodium carbonate was added thereto, followed by dyeing at 60 ° C for 1 hour. Then, it was washed with water, soaped, washed with water, and dried to obtain a red dyed product having excellent reinforcing properties. The degree of light fixation of the cloth dyed with each composition of 0.2 g was level 5 and the degree of light fixation to light and sweat color was level 4 to 5. It is worth noting that = metal-free reactive dyes have never before seen such excellent color fixation to pre-sweating and are of interest as far as red dyes are concerned. Table 3 Example Dye (nl) (g) Dye (vi) (g) 8-1 100 10 8 — 2 100 5 8-3 100 2 5 Comparative Example 1 The dyeing was performed in the same manner as in Example 8. However, 0.1 g, 0.2 g, and 0.4 g of the reactive dye of structural formula (VI) used in Example 8 were used. However, the dyeing product obtained in this way was inferior in enhancement properties and uniform in dyeability. It is not good. Example 9 This paper size applies the China National Standard (CNS) A4 specification (210 X 297 mm) ----------- installed, --I ---- ordered ------ --- line (Please read the precautions on the back before filling this page) -35-418239

A7 R7 • ~ n I J-\ ft '1 V. Description of the invention

Mu is 70 parts by weight of a dye composition which is a dye of the 8 t configuration (π-1) and a dye. Sodium phosphate (crystal) having a degree of sulfonation of 1 2 0 and a weight of 1 to 20 are added. Mineral oil emulsifier composition. 100 parts by weight of hot water, and 20 parts by weight of anhydrous mirabilite, and then added to the water bath immediately after the pressure rate of 6 5% into the olefin film, and let After 2 the product is washed with cold water to clean the cleaning reagent and rewashed with water at a temperature of 9 and the product is dried. No padding of the dye was observed even when the padding was performed as described above, and thus a product was obtained. The parts by weight are 14% by weight, and the thus obtained liquid-cooled sodium sulphate is made up to the total amount of bath liquid for pad dyeing5. . Room and hot water from 5 to 9 to obtain% of the above-mentioned aldehyde condensation product of structural formula (VI), 5 parts by weight and 5 wt% of the above-formed methyl sulfonic acid and methyl formaldehyde have a degree of condensation of 1.8 parts by weight of sodium sulfate (Anhydrous) and 1 are completely mixed to obtain (please read the precautions on the back before filling this page) ό 装 · — order --------- line. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The dye set is rolled up to 2 5 3 8 ° up to 10, then stored and then washed to dissolve in ° C. Then, Baumg and 300 parts by weight of the dyeing bath were wound with water for 15 hours. A powdery dyeing weight of 50,000 is added to it by 0 parts by weight. The dyed cotton cloth was squeezed and sealed in polyethylene at 8 ° C to make the soaping place dark red without extremes. Then this dyeing was done in a bath, and the dyeing solution of the stain was left at 25 °. Precipitation under C. More specifically, Maoge cotton was dyed using this uniform dark-stainless extreme dark red 60-minute padding solution. Example 10 This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm>- 36-418239 A7 B7 Order of the Central Government Bureau of the Ministry of Economic Affairs ®: Industrial and Commercial Cooperatives Co., Ltd. V. Invention Description (34) Add 70 parts by weight to the dye mixture used in Example 9, and quickly add 15 parts by weight. A condensation product of a sulfonic acid and formaldehyde (Demo 丨 N, made by Kao Corporation), 14 parts by weight of sodium phosphate (crystal) and 1 part by weight of mineral oil emulsion, and then thoroughly stirred to obtain a Powdery dye composition: 80 parts by weight of the obtained dye composition, 50 parts by weight of urea, 5 50 parts by weight of thickener (~ low viscosity glutamic acid 8% pulp), 30 parts by weight The hot water and 20 parts by weight of sodium bicarbonate were mixed together to obtain a printing and dyeing paste. The obtained printing and dyeing paste was stored at 25 ° C for 12 hours, and then printed and printed on cotton cloth by traditional methods. Then steam heat treatment at 100 ° C for 5 minutes. Washed with water, then washed with hot water, rinsed, washed with hot water, washed with water, and finished drying to obtain a uniform and extremely dark red dyeing product. Refer to Example 3 at 70 parts by weight for the dye used in Example 9. To the mixture, add 29 parts by weight of sodium sulfate (anhydrous) and 1 part by weight of an oil-breaking emulsion, and thoroughly mix to obtain a powdery dye composition. 100 parts by weight of the obtained dye composition is used. According to the dyeing method of Example 9, a pressure-absorbing dye solution was prepared, so that a part of the dye precipitate can be observed. Using this pressure-absorbing dye solution, the cold-pressing dyeing of the cotton cloth was performed as in Example 9 In the same situation to complete, and the result is-stain-like red dyed product. This paper size applies to China National Standard (CNS) A4 specifications (2 丨 0X297 mm)-(Please read the note on the back first (^ Items, then fill out this page)

4 18239 A7 B7 V. Description of the invention (Reference Example 4 The dye composition obtained in Reference Example 3 was used. A printing paste was prepared in accordance with Example 10, and the dye was precipitated. " The color rate is low, and a stain-like and particularly useless dyeing product is obtained. Examples 1 1 to .1 1 1 Γ) and Reference Examples 5 to 7 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The dyeing is as red as possible. This is used as a reference, the compound is 0 2 g. Example 1 1 — In the example, 1 1 — 1 is shown in the example of the table. Color and dyeing is 0.2. Grade 5 The test implementation is as shown in the table or 0 · 1 to 1 for enhancement. 0-1 in case 4 of the product of 1 and its g, and the example, 4 in gram 4 of the 1-1 dye to 8-to enhance the appearance of other components of sweat, the amount shown in the above formula to 0 medium phase The leveling properties and fruit are poor. According to the same square property of Table 4-3 and the color fixation degree of the dyed material is (m) and (), it is used alone, and the same method is used to complete the quality than to use the amount method to complete the properties. All grades 4 W) are 0 · 1 and dyed, mixed from Example 1 1, and finished, which are both excellent and have light to 5. The g in the compound is as follows in every one to one (please read the precautions on the back before filling in this purchase) This paper size applies to Chinese national standards (CNS> A4 specification (210 X 297 mm) _ 38 — Economy Zou Zhongyang Sample Bureau Shellfish Consumption Co., Ltd. Seal 4 18239 A7 …… B7 V. Description of Invention (36) Table 4 No. ne2 / s〇2X ', ..V' fj ~ V \ * kj—-fj , ίβ ~ N_N V '/ so3h • (II) X g Example 11-1 " C2H4〇S〇3H 100 Example 11-2-c2h4oso3h 7 0 Real_Example 11-3 —. One CsHqOSOjH .... .... 30 Example 11-4 -ch = ch2 100 Example cell 11-5 -C2H4C € 100 Example 11-6 -c2h4oso3h. 100 Example 11-7 -c2h4oso3h 100 Example 11-11 -c2h4oso3h 100 implementation of ten columns 11-9 -ch = ch2, 100 mmn 11-10 -c2eac ^ 100 Compare column 5 Compare 6 Compare teeth-Example 7 -c2h4oso3h '1 (Please read the note on the back ^ before filling this page) -. Φ The size of this paper is applicable to China National Standard (CNS) A4 (.210X297 mm), -3y 4 \ 82 3 9 A7 B7 V. Description of the invention (37 Table 4 cm)

No, nh7 .... C ir /-\ n // \\ VJ // (工 II) x02s \ ^ 7 N ~ N X_7 h〇-C ^ ΞΟ-, Η -—, 3 X g 11-1 -c2h4oso3h 100 Example 11-2 -c2h4oso3h 30 Example 11-3 -c2h4oso3k 70 Case Award 11-4 -c2h4oso3h 100 11-5 -ch = ch2 100 Case example J. 11-6 丨 w— Example 11 -7 II — Examples of real cells 11-8. — — Example 11-9 Example 1 — Examples of her '.. 11-10 A comparative example of cells 5-Comparative column 6 "C2H4〇S〇3H; Comparative examples Case 7 (Please read the precautions on the back before filling in this page) Installation · This paper size applies to China National Standard (CNS) A4 specification U10X297 mm) —40 4 V823 9

A B7 V. Description of the invention (38) Table 4 (Excitation) No. nh2 .s〇3h / s〇2x w // ~ \\-* kj — // ~ • (IV) \ _7 NN v_ / so3h X g 11-1-one embodiment 11-2-one embodiment 11-3 one-column 11-4--delete column " * 11-5 M-example 11-6… -c2h4oso3h ', _ 100 Example of window drag • 11-7 -c2h4oso3h 30 Real cell example 11-8 -c2h4oso3h 70 Real lion column. 11-9 -c2h4oso3.h 200 Temporary cell 11-10 '-c2h4〇so3h 100 Compare 5 — ratio Example of the window collision 6 r Comparative Example 1 7 -c2h4oso3h (please read the cautions on the back before filling in this page). The size of the paper is applicable to the Chinese national rubbing rate (CNS) A4C grid (210 X 297) %) TT 4 182 material

V. Description of the invention (39) Example 1 0.2 g of a dye mixture containing 50 parts by weight of a dye having the following formula (a) in free acid form:!

'SO 〇H and 20 parts by weight have the following free acid form (Dye: ------------ ο loading (please read the precautions on the back before filling this page) ' 1 _

The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs of N I CH printed so2c2h4oso3h to dissolve in 20 Omi of water. 10 g of thenardite was added to this solution and dissolved to obtain a dye bath (glauber's salt concentration: 50 g / J2). In this dye bath, 10 g of non-mercerized cotton fibers were immersed, and the temperature was raised to 60 ° C for about 30 minutes. Then 3 g of sodium carbonate was added, and thorough staining was performed at the same temperature for 1 hour. After dyeing, the dyed cloth was washed with water, then soaped and dried by a conventional method to obtain a red dyed cloth with good leveling property. The light fixation of this cloth, the light and the paper size apply the national standard (CNS) A4 (210x 297 mm) -42-418239 A7 _B7 V. Description of the invention (40) The color of sweat is fixed Degrees, color fixation to chlorine and leveling properties were evaluated by the following methods, and the results obtained are shown in Table 5. ① Evaluation of light fixation. J I S L-0 8 4 2 8 0 hours. ② Evaluation of light and sweat color fixation. Such as J IS-〇 8 8 Method A, an alkaline method. (However, the amount of this histamine is changed by 10 times.) ③ The evaluation of the color fixation of chlorine is evaluated according to J IS — L-0884 (chlorine concentration: 2〇t) pm. Evaluation of Dyeing Properties This dyed cloth is substantially evaluated according to the following standards: Excellent: (evenly dyed) 0: Evenly dyed and practically acceptable △: Slightly poor X: Non-uniform dyeing, and irregularities are clearly visible . Examples 1 and 14 are compared to Examples 2 to 4. In the method of Example 12 by Yu Yin, the mixing ratio of this dye mixture is changed as shown in Table 5, and is the same as in Example 12. The test is done similarly. This result is shown in Table 5. As shown in Table 5, the light fixation provided by the dye mixture according to the embodiment of the present invention, the color fixation to light and sweat, and the color fixation to chlorine are applicable to the Chinese National Standard (CNS > A4 specification (210X297mm) _ 43 _ -------- I _ equipment-(please read the precautions on the back before filling this page) 418239 A7 B7 V. Description of the invention (41) Degrees are all excellent and at a level of 4 or higher, and the leveling properties of the dyed fabrics obtained in this way are without any problems ° (Read the precautions on the back before filling in this page ) Scripture book Qilang middle clip Pan X X Consumption paper 阼 ti print and capture paper music scale Applicable to Central China National Kneading Rate (CNS) A4 specifications (210X297 mm) 44 418239 A7 B7 V. Description of the invention (42) Table 5 Item Dye Mixing ratio (weight ratio) Light fixation (grade) Color fixation to light and sweat (grade) Color fixation to chlorine (grade) Leveling dye (a) Dye (a,) Implementation Example 12 71.4 28.6 5 r Example 13 50 50 4-5 + 4 * 4-5 Example 14 30 70 4 4 4-5 As in Example 2 100 0 5 4-5 3-4 X Comparative Example 3 0 100 3-4 3 5 " ◎ Comparative Example 4 95 5 5 4-5 '3-r Δ (Please read the Note: Please fill in this page again.) Binding. The size of the paper for this guideline is applicable to China National Standards (CNS), 8 and 4 (2i0 × 297 mm) 45 4182. Get: Amend! Add A7 B7 V. Invention Description (43) Example 15-Example 15-26 The method in Example 12 'The reactive dye of the formula (a /) was changed to the reactive dye of the free acid form shown in Table 6' and carried out The same test as in Example 12 * However, the obtained light fixation, color fixation to light and sweat, and color fixation to chlorine are all in the level 4 or higher, and may be Red dyed cloth with leveling property of 0 (please read the notes on the back before filling this page) 210 X 297 mm) -46-Α ^ δ2.39 Α7 Β7 5. Description of the invention (44)

This paper size applies to China National Standard (CNS) A4 specifications (.210X297 mm) · 47 _ (Please read the precautions on the back before filling out this page). Packing. Order A7 f 418239 _ B7 V. Description of invention (milk) ^

σ I

HsKas ~ · θν = 3

Hcrsus, 3-: 3

= i \ .if-\ ----.-- I--install-- (I first read the precautions on the back before filling out this page) (I) r Order

E < -〇

Hro S -9 line .i

C —LrsI ιοΐ T si This paper fff standard is applicable to China National Standard (CNS) A4 (210X297 mm) ’-48 418239 A7 B7 V. Description of the invention (46) (l) 9f

Hfo S t σι -0 / Ύη ^ -0 Jos, 1 / · _ΞΥ

. | 1§ ί, loWoS H ^ M! V

30s50crs ^. ^ Τ-ν 9 S, β of----I ί ml mu m ^ | j i-f- — (Please read the notes on the back before filling this page)

d (Λ⑺〇s) Wu

Has ύ

η 〔〇s

Printed by Shellfish Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs

CJN

A —LnT co—ιοΐ The standard of this paper is applicable to the Chinese National Standard {CNS) A4 specification (21 〇X297 public; ¢.) 4 18239 A7 B7 V. Description of the invention (47) (1_) S Feed 〇1 1. O CJ ς / Ξ 3 ^^ X〇co% 1 σ > * IL〇τ-Η (Please read the precautions on the back before filling this page)

The size of the paper is applicable to the Chinese national standard (€ yang). 6 See ^ (210 father 297 mm) 418239 A 7 B7 V. Description of the invention (48)

—.----- 5Γ — Assembling-(Please read the precautions on the reverse side before filling out this page) The paper's dimensions apply to Chinese national standards (CNS > A4 (210X297 mm) -51-4 1 8239 A7 B7 i £ · ^ Lang lost *-^-tiGT member ν-ί goods 16ar ^ work.fi-, = p £ 8i V. Description of the invention (49) 9 Move

(Please read the notes on the back before filling out this page) --Ί r J— 装 -------- Order ------ line ------.---.—— 1 paper The standard is applicable to China National Standards (CMS) A4 specification (210X297 public love), 52 _ [Into the fifth, the description of the invention (50) (I) 9f A7 B7 Economic Lang t central government bureau shell X consumer cooperatives printed

(Please read the precautions on the back before filling out this page) -------------------, ιρ installed -------- order ------ line ------ ,! This paper size applies to China National Sample Vehicle (CNS) A4. (21 OX 297 mm) MS239: B7

Zhang Hr 1 ^ ssoiCVJos ΗΝ ϊ, θγ ~ *) §β 13-1-0S ^ ~ ΗΝ

(Please read the notes on the back before filling this page)

装. ，-口

MiroS

Hoos

llcrs ^ licrcoos

j-oos si = ros§

... saiCJos CJH.

GI_SI 075:

Applicable to quasi-standard home country I country 4 I 4 A s N c X o 4 5 r 418239 Λ-7 B7 V. Description of the invention (52) ''

I --------- 0 Wide Pack ------ Order ---- II-Line (Please read the precautions on the back before filling out this page). This paper size is applicable to Chinese national standards ( CNS) A4 specification (2 丨 0 father 297 mm) 418239 A7 B7 V. Description of invention (53) (i) 9 nitrate

D:-0 S = c-Joso = crCJos σι

J V

Ι! Ν, ogll = c, os ° Hcrcrs (Please read the notes on the back before filling this page).

Ilsan ◦ S --a-

H " 0 ° HCVI3OJ0s

Η-0 S

l ^ ° ll-: os 丨 Line Frog Jilang Order Lost Sample Mou Bureau Moon Industry Consumers Cooperative Printing Yttrium-9751 This paper size applies to China National Kneading Rate (CNS) A4 (210X297 mm). 56 418239 S9. S- A7 B7! Public description of the invention (window examples 16 — 1 to 16 — 1 8) In the method of Example 12, the reactive dye of formula (a) was changed to the formula shown in Table 7. Reactive dye, and completed the same test as in Example 12, but this light fixation, color fixation to light and sweat, and color fixation to chlorine are all at level 4 _ or A higher level, and the resulting red dyed fabric has a leveling property of 0 ------------ install -------- order --------- Line} 1 (Please read the notes on the back before filling out this page) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives This paper is printed in accordance with China National Standard (CNS) A4 (210 χ 297 mm) -57-.418239 A7 A 7 B7 V. Description of the invention (55) A table 7

Economy Zou Shenyang Standard Soap Bureau employee consumer cooperatives printed Να S 0 2 X: iy 16-1 KO3S0K4C202S-^^ > — 16-2 / S02C2K40S03H. H3c_cj / h2c = cho2s, — 16-3 o ^-factory < B 「16-4 H〇3SOH4C2〇2S ^ / V- och3 16-5 ho3soh4c2o2s — < ^ ch3 16-6 C1H4C202S-// V- (Please read the note on the back before filling this page) ---- ------ j--installation ------ order ------- line ----------- ψ I · nn — ^ ϋ * This paper size applies to Chinese standards (CNS) A4 specifications (210 father 297 mm,) 418239 A7 B7 V. Description of invention (56) Table 7 (缋 :)

(Please read the notes and notes on the back before filling out this page) -0

This paper size is in use ® National Standard (CNS) A4 (2H), X 297 mm) _ .-. 59- 418239 Α7 Β7 V. Description of the Invention (57) __ Examples 1 A dye mixture comprising 0-1 g of a dye having the following formula (a) in the form of a free acid as a red component:

0.1 g of a dye having the following formula (b) in its free acid form is used as a yellow component:

Cl (Please read the phonetic on the back? Matters before filling out this page) One pack I · so3h

η = < NHCONH: HH (b)

S〇2C2Hii〇S03H Printed by the Qigong Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs and Q. 1 g of the dye with the following formula (c) in its free acid form as the blue component: This paper is applicable to countries in t country Standard (CNS) A4 specification (210 X 297 mm) —60-Α \ δ239 Α7 _; _ ___B7 Five 'invention description (58) 0 nh2

The Ministry of Economic Affairs, Central Bureau of Standards, Industrial Engineering and Consumers' Association, printed so2c2h4oso3h to dissolve in 20 Omi? Of water. With this solution, i 0 g of thenardite was added. Then, 15 g of cotton cloth was dipped therein, and the temperature was raised from room temperature (25 ° C) to 60 ° C for a period of about 30 minutes. More specifically, 4 g of anhydrous sodium carbonate was added thereto, followed by dyeing at 60 ° C for 1 hour. After that, it was washed with water, self-washed, washed with water, and dried according to the conventional method, so as to obtain a brown dyed product. The reactive fixing properties of the dyes of each color component to this fiber are excellent in this dyeing, and the leveling properties are also good. The light fixation and color fixation to light and sweat of the dyed cloth obtained in the above dyeing method were evaluated by the following methods, and the results are shown in Table 8. ① Light Fixing Degree According to J I S L-0 8 4 2 (40 hours of irradiation) ② Color Fixing Degree to Light and Sweating According to J I S — 0 8 8 8 Method A, make the alkaline artificial sweating. The first example 18 to 20 dyeing is done in the same way as in example 17 except for this dye (please read the precautions on the back before filling this page). Packing. The size of the paper is suitable for Chinese countries. (〇 阳) Six 4 rules ^ (210 father 297 mm) 'til-418239

V. Description of the invention (59l.) The mixing ratio is changed except that the dyeing products obtained are shown in Table 8. As shown in Table 8, the light fixation and the color fixation to light and sweat are good. Comparative Example 5 In Example 17 • Dyeing was done in the same way, except that the blue component dye was changed to the following dye of known structural formula (d), and the formula (d) was published in Japanese Unexamined Patent Publication No. 4 7 8 3/1 9 8 1 is particularly excellent in color fixation to light and sweat. As shown in Table 8, the color fixation to light and sweat is substantially poor. ------------ Install --- (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) Order ----- line, -62-1 418239 Printed by the Central Bureau of Standards, Ministry of Economic Affairs, Shellfish Consumer Cooperative, A7 B7 V. Description of the invention (6) Table 8 The mixing ratio of the reactive dyes The color light fixation of the dyed product to the light and sweat color fixation a:? B C d Example 17 0.1 0.1 0.1 Brown 5 4 Example 18 0.1 '-0.16-Fuchsia 5 4 Example 19 0.1 0.16 0.3-"Reveal 5 4 Example 20 0.05 0.015 "-Orange 5 4 Comparative Example 5 0.1 0.1-0.1 Brown 5 1-2-----J ---”:-I (please read the notes on the reverse side before filling out this page) • I — The paper size of the thread is applicable to the Chinese National Standard (CNS) A4 specification u 10 X 297 mm) 63 Form 9 A passing grade such as a light table has a change in production grade such as furniture and finished products, etc.} The color is C dyeing degree, and the fruit is solid. 丨 Light b 〇 有 〇 {External 4 dyeing and dyeing etc. What you have is a Chinese style with a degree of 7, shape, with 1. The acid color solid example is the color that is applied to the face of the real and the 9th sweat 418239 A7 B7 ______t __ _ -5. Description of the Invention (ei) Example 2 1 1 5 g of the dyes (a), (b) and (c) published in Example 17 were dissolved in hot water of 50 OmJ2, and This solution was cooled to 25 ° C. To this solution, 5.5g of 3 2 · 5% sodium hydroxide aqueous solution and 15 Og of 50 ° Baum4 water glass were added, and water was added to make the total amount at 2 100 g at 5 ° C. Immediately afterwards, this solution was used as a pressure-absorbing material solution and a cotton fiber as a pressure-absorbing material. This fiber was used as a twisting water and then sealed with a polyethylene Store in the film for 20 hours at 20 ° C. After that, the dyed product is washed with cold water and hot water and then washed, and then washed directly in a boiling self bath. It is washed with cold water and dried. To obtain an excellent brown dyeing product at a level of light fixation level 5 and a level of light and sweat color fixation level 4. Official Example 2 2 — 1 to 2 2 — 2 5 Dyeing is It is completed in the same way as in Example 17 except that the paper size is applicable to the Chinese national standard (CNS > A4 size (2 丨 〇χ 297 mm): 64 (please read the back first) (Notes for filling in this page)

418239 A7 B7 issued θ profile '^-Economy Zou Central Provincial Bureau of Staff eliminates cracks in cooperatives

This paper size applies to Chinese National Standard (CNS) A4C (210X297 mm.) 65 418239 A7 B7 V. Description of the invention (B) '' Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 51 Μ f θ if I pass, I ο : O o Bu KO v > C3 — Tone '»• Ί s a <« λ μ a 〇_ «= s Ο MC ^ J SC 3S t \: · ^ 3-. O =: ΪΕ ^ 5 a c >» SfZ oo CO (M p = Έ 1 ^ E. 1-*-^-1—1 1 C ^]. ^ Su XI 3 > 4 On S3 M wm.? C uc a nt cd = ^ (4 „r • SC o * yy C3 PC o • yt o-»> * _» o 'φ »i — Pi U., I 〇 "-· " -X% = c ◦ 0 VJ φ x. — Ac = U 1 9 > Λ I " Q! = C * 1 Ss: 〇vt port a: Cf »l_F ^ a * *.« Λ ζ / φ WK: κ X r Y 3C V, X ii T 9C S 3 «N •. O Table II a Si 1 CN fN Ln Ϊ ΓΝ ΓΝ UD 1 fN CN Γ '' 1 (Ν (Ν (Please read the notes on the back before filling out this page) The paper scale is applicable to Chinese national standards ( CNS) A4 specifications (210X297 mm) wide ^ g one five four 18239 A7 B7 6 / {, say 丨 Mingfa

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哉 N fiff I u CO I ZZΓ7 MJ. 銶 szhao-ιΗ ε iH, 't < N c ^ a — a rc = 1 s ^ ς (ί > ig ·, 3¾ 〇 · χ. 7S. Ο 旮ί Μ .U 1 ~ 1 «rq < NI m-1 ^ S i Λ ^. · TXv {n κ g. (\ s 5 3¾. Μ Γ3 兰 g _ 51 gc〇ir • Jiru cu Ξ YY 2 ri Μ O c • ···-SC = .1 η λ ι ι. ^ ». χ» · si SVY Oil i ii CD, €: ΐ ^ = 1 yy Φ4 < _ > ^ =: 〇yy il 拗Si VO r—i 1 tN fN r- • ~~ 1 1 (N (N 00 1 ~~ 1 1 (N ΓΝ < J \ r—i 1 CN fN (Please read the notes on the back before filling this page )

This paper size applies to China National Standard (CNS) A4 (210X297 mm) Λ A 823 9 A7 B7 V. Description of the invention (67

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0fN- (NCN τζ-ττ This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) A7 B7 V. Lu Ming's note f 68 Printed by China Industrial Standards Bureau, Ministry of Economic Affairs, China Industrial Cooperatives ¾

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I order I-丨 丨 The size of the paper is applicable to the Chinese National Standard (CNS) A4 specification (2 丨 OX 297 mm) A7 B7 V. Description of the invention (69) Official Example 2 3 — 1 to 2 3 — 1 3 Dyeing This was done in the same manner as in Example 17 except that the dye (a) used in Example 17 was changed to a dye in the free acid form as shown in Table 10. As a result, the obtained dyed product had a color as shown in Table 10, and had a light fixation level of 5 and a light fixation and sweat permeation level of 3 to 4 or higher. -1— I (please read the note $ on the back before filling out this page) Order • I 丨 Printed by the Ministry of Economic Affairs, Central Bureau of Standards, Bureau of Work and Consumer Cooperatives 72 This paper's standard is applicable to China National Standard (CNS) A4 specifications (210X297 mm) 418239 A7 B7 V. Description of the invention (70) Printed by the Central Government Bureau of the Ministry of Economic Affairs

iu3I 'fif— \, _ / Z: O π rc 0 cn cj ° c, vr Ξ to c? s .1 〇0 .. ·-., * Si ri m CN rs 1 m CN (Please read the (Please fill in this page again)

This paper size applies to China's National Standard (CNS) A4 specification (.210 X 297 mm) 4V8239 A7 B7 V. Description of the invention (71) (叆) ο I 褴 Economy Langzhong 夬 Chestnut 员 member X eliminates cooperation. Printed M ip SN liii i .i! I f \ V_f Ξ 2; II 2 =. — Cr > = QO CO o 〇αί c〇,-§ ΣΣ. | L CO 2 = < Si CD Csl '«ϊ * 5 U ~ i cn nr 〇 > o II φ? C〇 «-ξ. CNJ 1 ε s a-^ two: +》 = j〇cX s Σ × Z η α CO 3; cz > a ^ Τζζ ~ CnJ ο CJ Ό Ψ g Si m Λ < N 1 m CN in 1 ΓΊ C ^ i 1 (Please read the notes on the back before filling in this X)

The paper scale is applicable to China National Standard (CNS) A4 (210X297 mm) 4 \ 823 9 A7 B7 'V. Description of the invention (72) Forging i _ i N ii .ifi / -i Γ3 • v_ * CO CO CD O CO CO o ^ E; 〇CO of π * τ · ZΣ., »-R— i C ^ J: < -n Ό. 〇 " IE -〇CO CJ ^ Tj- CO 口 3 = To ¢ -3 C = 3 CO = ϊ〇φ CO SI • Cavities:-: 1 1 m Zr ^ · Ό rJ, < x / CD ZC c- »〇OO 5 = O tt Cvj C- * CVI CD < _n Ό II & 1 uo 1 Γ0 (N \ \ m Γ-) CO f CN j -------- —factory j—installation ------ order ------ line (please Read the notes on the back ^ before filling in this paper 1 ·) This paper size is applicable to the Chinese family kneading rate (CNS) A4 specification (2 〖0X297mm) 4 V8239 A7 B7. V. Description of the invention (73) Paper I

A S N C -ί 'Applicable to quasi-standard countries.

Centimeter 7 9 2 X 7 rnn i rn ϋ n *-^--I ϊ ~~ ϊ ', 1T (Please read the notes on the back before filling this page] I 丨 line 418239 A7 B7 V. Description of the invention ( 74) (I) Ο ΐ f

If system f .I _: — 一 t ί—V fa ^ 〇〇CO 1 〇〇 U3 2: uo M EU CN < NU CJ < N 〇〇W CO inch-tf K w < N < N ua \ x " 〇-- 丨 m 〇tn m ά ο 11 κ mfa 〇〆 \ 内 ο ο \ Ω ΙΟ CO W CN (Ν 〇〇 α υ β W II JJ α ο CN < Μ i 扣 as per N ϋ fN-«~ t 1 rn < N-m. Ι—JI m CN (Please read the notes on the back before filling this page)

The paper scale is applicable to the Chinese National Standard {CNS) A4 specification (2 丨 〇ΪχΜ7mm) 418239 A7 B7 V. Description of the invention (75) The present invention can dye and print with color fixation and the color of chlorine, especially, It can be used in a desired color to be excellent in wet fixation, and it is excellent in color fixation. It is used for sports clothes. As such, the present invention is an excellent weaving material for dyeing industrial colors in terms of light fastness, light fastness and sweat fastness. It is used to dye textile fibers, and its contribution not only to light fixation and to light and sweat, but also to provide dyed textile products is very durable under severe conditions. ------- Installation ------ Order ------- Line (please read and read the notes on the back before filling in this page) This paper size is applicable to China Gujia Standard (CNS) A4 U10X297 mm) 78

I

Claims (1)

8239 A8 B8 C8 D8 an. ‘见 See 6. Scope of Patent Application Annex A: Patent Application No. 83106376 Amendment to Chinese Patent Application Scope May 1998, a red reactive dye with the following free acid form: Ϊ) -----------_, @ 装 (Please read the precautions on the arm surface before filling out this page) where X is a CH = CH2 or a C2H4W (where W is —0S03H or halogen) , A is C2_3 alkylene or (: 2_3 alkylene oxide C2_3 alkylene, E is hydrogen atom, Ci_3 alkyl group or -A-S 0 2X (where Αχ is as defined above), η is 0 or 1, i ? Is 1 or 2, m is 0 or 1, and R is a hydrogen atom, 〇Η, —CN ′ — C Η 3, —CF3 ′ — S Ο 3 Η — — C Ο Ο Η, —CH2S03H or —CH2S02X ( Where X is as defined above), but if R is a hydrogen atom, m and η are both 0,]? Is 1, and -S 02χ is _ S 02C2H4W and is bonded to the ortho position of the azo group. In addition, if • When m and η are 0 and j? Is 1, R is not -0 S 〇3h. 2. As the red reactive dye in the scope of the patent application, the paper size of Thailand applies Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) _ Order -------- Line, member of the Ministry of Economic Affairs, Smart Time Production Bureau 31¾ Fei He Du printed A8BSC8D8 418239, the scope of patent application is in formula (I), X is a C2H40S03H, 11 is 0 or 1, R is-s〇3h — —Coon, —ch2so2x or —CH2S03H, 111 is 0, β is 1, and A is C2-3 alkylene or C 2_3 alkyloxy C 2_3 alkylene. 3. Composition of a red reactive dye It contains 20 to 8 5 parts by weight of a dye of formula (I) as defined in item 1 of the scope of the patent application. 13 to 50 parts by weight of a sulfonic acid or Ci-Cs alkyl sulfonic acid and formaldehyde Condensation product, and 1 to 25 parts by weight of p Η buffer. 4. A red reactive dye composition comprising at least two dyes of formula (I) as defined in item 1 of the patent application scope, wherein This dye composition contains 100 parts by weight of dyes of the formula (I-A) with the following free acid form: Please read it first, read the precautions of S, and then fill in this page to order The line economy is the Intellectual Property Bureau's 1-¾ fee < SDltfi printing and 1 to 50 parts by weight of the dyes of the formula (I-B) with the following free acid form: This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) _? 418239 A8 B8 C8 D8 VI. Patent application scope R (IB) where w is os03H or halogen, and is -c2_3 alkane, or C2-3 alkoxy, c2_3 alkane, E is a hydrogen atom, Ci-3 alkyl or -A-S02x (where A is as defined above, and X is -CH =: CH2 or C2h40S03H), n is 0 or 1, meaning 1 or 2 'm is 0 or] l, and the ruler is a hydrogen atom, _〇H, -CN »-C Η〇-CF —S 0 3 Η, — C 〇〇ΗCH2S03H or —CH2S02X (where X is as defined above). If item 4 of the scope of patent application (please read the precautions on the back before filling this page) --------- ^ --- Order ----- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, Among them, (I-A) and .. (-S03H or one COH 6-a kind of red reactive dyed parts by weight, as in the scope of the patent application, 3 to 50 parts by weight of the sulfonaldehyde condensation product ， And 1 to 2 5 7.—A kind of red reactive dyeing composition as defined in item 1 of the patent scope contains 100 parts by weight of I-B, η and the composition of 4 or 5 acid or C replacement parts In the composition formula (which has a red reaction), R m is all 0, and the 1-C 6 焼 P Η retarder, including I) is defined in the package item, and the composition is c hydrogen 1 Atom,, and 5 are 1. A dye composition containing 20 to 8 5 sulfonium sulfonic acid and methyl ester. At least two kinds of materials are required, of which the dyeing formula (I — this paper size applies the National Standard of China (CNS) A4 (210x297 mm 疒 3 丨-1 A8 B8 C8 D8 418239 VI. Dyes with patent application scope c): (IC) and 30 to 300 parts by weight of dyes with formula (I-D) in free acid form: Please read first. Please read the precautions of S before filling in this Page S〇3H) m E〇 R s〇3h (ID) The consumer cooperation agreement of the Intellectual Property Bureau of the Ministry of Economic Affairs, where X is a CH = -GH2, a C2H4W (W is -0S 0 3H or halogen), A is a C 2-3 extension Alkyl or C 2-3 alkylene oxide (: 2-3 alkylene, E is a hydrogen atom, Ci-3 alkyl or -A-S 0 2X (where A and X are as defined above), 11 is ◦ or 1, β is 1 or 2, m is 0 or 1, and R is a hydrogen atom, _OH, one CN, one CH3 >-CF 3, one S03H, -C Ο Ο Η > one CH2S03H Or a CH2S02X (where X is as defined above) 8. If the red reactive composition in item 7 of the scope of the patent application, the paper size of this paper applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -4 :. · 418239 A8 B8 C8 D8 6. In the scope of the patent application, in formulas (I-C) and (i-D), 'x is -CH = CH2 -C2H40S03H, -C2H4C 1 or -C2H4B r, m and η Both are 0, j? Is 1 'and R is a hydrogen atom. 9. — A red reactive dye composition' which contains 20 to 8 5 parts by weight as defined in the 7th or 8th of the scope of the patent application Dye composition, 3 to 50 parts by weight of a sulfonate Or 〇1 _ (^ 6 alkyl sulfonic acid condensation product with formaldehyde, and 1 to 25 parts by weight of pH buffering agent "1 0.-a red reactive dye composition 'comprising at least two The compound of formula (1) as defined in item 1, wherein the dye composition contains 100 parts by weight of a dye of formula (I-E) having a free acid form: -------------------- Order --------- Online (Please read the Weeping Matters on the Face before filling out this page) Investigator II Qi <ia; tfi, -fs and 20 to 200 parts by weight of dyes with free acid form (I: This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm > -5:-41823 9 as B3 CS D8 Ministry of Economic Affairs 1¾ member |-| Shao Fei ^ 阼? £ Printed where X is a ch = ch2 or a c2h4w (where W is -0 S 03H or halogen), A is C2_3 alkyl or C2_3 alkyl Oxygen C2_3 extends the radical, E is a hydrogen atom, Cl-3 fluorenyl or -A-S 0 2X (where A and X are as defined above), 11 is 0 or 1, J2 is 1 or 2, and R is One hydrogen atom, one 0H, one CN * — C Η 3 >-CF 3, one S03H, one C00H, —CH2S03H or one CH2S02X (where X is as defined above). 1 1. The red reactive dye composition according to item 10 of the application, wherein in the formulae (I-E) and (IF), X is —CH = C Η 2 1 — C2H4OS〇3H * ~ C2H4C1 or .- -c 2H 4B r, n is o and 1 again, and R is a hydrogen atom. 1 2. A red reactive dye composition comprising 20 to 85 parts by weight of a dye composition as defined in the scope of application for patents No. 10 or 11 and 3 to 50 parts by weight of sulfonium Acid or C:-a condensation product of Ce alkyl sulfonic acid and formaldehyde, and 1 to 25 parts by weight of p Η buffering agent 1 3.-A red reactive dye composition containing 100 parts by weight of Free acid form dyes (I-A >): (Please read the notes on the -t side before filling out this page) ---- I i III line 'This paper size applies to China National Standard (CNS) A4 Specifications (210 X 297 mm) _ 6.-418239 A8 88 C8 D8 6. Scope of patent application And 1 to 50 parts by weight of a dye of formula (VI) in free acid form: 1 4. A red reactive dye composition comprising 20 to 85 parts by weight of a dye composition as defined in the patent application range of item 13 of the term '3 to 50 parts by weight of a sulfonic acid or Ci-C e alkyl condensation product of a sulfonic acid and formaldehyde, and 1 to 25 parts by weight of a pH buffering agent. (Please read the precautions for noisy faces before filling out this page) Order --------- line, printed by member of Intellectual Property Bureau of the Ministry of Economic Affairs X. Consumption Co., Ltd. ο 1 Included: Material, Dye Into 3 groups of 'material I dyeing < trans-form-shaped red acid type according to nature. There are 5 units of 1 paper size applicable to Chinese National Standard (CNS) A4 specifications (210x 297 mm) — 7 to 8 C $ 008 ASSCD .S〇 (S0'2 Y) P Η 418239 VI. Patent application scope X ') where X is _ch = ch2 or a C2H4W (where W is ~ 〇S03H or halogen)' R1 is a hydrogen atom, a s〇2X '—CH2S02X (where X is as defined above) , _ Prime atom 'Ci-4 alkyl or C_1_4 alkoxy, and m is 0 or 1, and 10 to 300 parts by weight of a dye of formula (X) having a free acid form: (X)- ----------- I ------ Order --- III-'line (Please read the precautions on -f before filling out this page) Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by Consumer Cooperatives where Q is ZR cno or 4 where R2 is a hydrogen atom or a halogen atom; R3 is a hydrogen atom or a Ciy alkyl group; R4 is a hydrogen atom or a halogen atom * Ci_4 courtyard or —s 02x This paper size applies to China National Standard (CNS) A4 specifications (21〇 χ 297 芨)-\ < 8239 VI. Patent application scope, and z is a halogen atom, hydroxyl A8 B8 C8 D8 R or N. R 5 C 0 OH (where R5 is a hydrogen atom or an alkyl group, and R6 is a hydrogen atom, a halogen atom * a carboxyl group, a sulfonic group or a S02X), y is a hydroxyl group, —CH = CH2 or a CH2CH2W (where W is as The above definition) 'and P are 0 or 1. .16. A method for dyeing fibrous materials comprising using one or two red reactive dyes of formula (I) having the following free acid form as the red component: ------------ h) m -------- Order --- Factory.---(Please read the notes on the back before filling this page) where X is a ch = ch2 or a c2h4.w (where W is — OS〇3H or halogen), eight is (: 2-3 alkylene or 02-3 alkylene oxide C2_3 alkylene group, E is a hydrogen atom, Cl -3 Yuan Ji or -A-S 0 2 X (where A and X are as defined above) 'η is 0 or 1' 32 is 1 or 2, m is 0 or 1, and & R is a hydrogen atom,- 〇Η --CN >-C Η 3 1-CF 3, one S03H > -9'- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 418239 8888 ABCD, patent application scope _ c ο Ο Η, a ch2so3h or a ch2so2x (where X is as defined above) 'But if R is a hydrogen atom, η and m are 0, β 疋 1, a S 02X is a S O2C2H4W and is bonded to It is an ortho position for an azo group. In addition, if m and η are both 0, ^ is 1 ', and fj R is not a S 0 3 Η; one or more of the following formulae (i) to (iv) Dye as a yellow ingredient: Please read it first, and pay attention to Qin Xiang before filling in Φ- Page N = K NH H = < HHC0EJ, KAS〇zX (S0, R) a Economy Zou Intellectual Property Bureau 31 Consumer Printing Co., Ltd. where in: is an integer 2 or 3, R7 is a hydrogen atom or Ci_4 alkyl group, E1 is an amine Or C0CH3, A1 is a phenyl or fluorenyl group and may be a S03H, halogen, Ci-4 alkoxy, ~ CH2S〇2C2H40S03H substituted, C4 alkylene or alkyleneoxyalkylene , Υα is a halogen atom-NHC2H4S03H or one N — Ai-SOsX (where A1 and R? Are as defined above, X is — (: 11 = (: 112 or— C2H4W (where W is as defined above), and X1 is X or hydroxy as defined above), this paper size applies to Chinese National Standard (CNS) A4 specification (210 X 297 mm) —10;-A8 B8 C8 D8 418239 Where R8 is CP4 alkyl or Ci-4 alkoxy, 3RS is Ci_4 alkoxy, and X is as defined above: ca3 I ca, II..! NN-CH S〇3H Please read first-note of Si Please fill in this page again for 'w * (S03H) 3. HK' (iii) NA-SO- I „11 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (x'〇7Si» nn CS〇3HJsi: S0, X where Rla is a Cpi alkyl group, R11 · is a hydrogen atom or ¢: ^ 4 alkyl group, and A 1, X 1 and Y 1 are as defined above, -a.12 (iv; where n1 is 0 or 1, m2 is 1 or 2, R12 is methyl or carboxyl, and X and X1 are as defined above; and one or more dyes having the following formulae (v) to (vii) are used as a blueprint paper Standards are applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) _. 11 I 418239 A8 BS C8 D8 Six. Patent application scope Color composition: Q UK, ΜΗ -if i) Please read the precautions for Si first and then fill in this page. Z1 is amine or NH — R14 — NHQ2, R13 and R14 are both <: 1_4 alkylene, Q1 and Q2 are both 碜Printed by the Economic and Intellectual Property Bureau employee co-operative cooperative yz ί 15 'where Y2 is a halogen atom, _OC00H. Or sulfonyl substituted aniline group' RU is a hydrogen atom or Ci_4 alkyl group, and A1 and X1 are as above (Definition) or the size of this paper applies the Chinese National Standard (CNS) A4 specification (210 x 297 mm) _ 12. 418239 VI. Patent application scope A8B8C8D8 r1 (S03H) i where Y3 is-halogen atom or 1 to 3), And is an integer COOH (Please read the precautions for the noisy face before you fill out this page.) Printed by the Consumer Affairs Bureau of the Ministry of Economic Affairs and the Ministry of Economic Affairs, where Ding 1 and T2 are a 0S03H or a NHCO — ChA alkylene and COOH substituted C alkyl. , And X are as defined above. When the fiber is subjected to dyeing, it is performed in the presence of an inorganic salt and a neutral salt at a temperature of 50 to 60 ° C, and when the fiber is pad dyed, In the presence of caustic and sodium silicate, the reactive dye aqueous solution is pad-dyed onto the fibers at room temperature. 1 7. A reactive dye composition comprising one or two red reactive dyes having the following free acid form of Formula 1) as a red component: This paper size applies the Chinese National Standard (CNS) A4 specification ( 210x297 public friends) -13 丨 i 418239 A8 88 C8 D8 Patent application scope P (I) where X is _CH = CH2 or _C2H4W (where w is -0S03H or halogen), A is C2_3 alkylene or (: 2-3 alkylene oxide C2_3 alkylene, E is hydrogen atom, Ci_3 Alkyl or -A-S Ο 2 X (where A and X are as defined above) * η is 0 or 1, ί is 1 or 2, m is 0 or 1, and R is a hydrogen atom, -0Η, -CN >-C Η 3, a CF3-S03H, a COOH, -CH2S03H or a CH2S〇2X (where X is as defined above), but if R is a hydrogen atom, η and m are 0, β is 1,- S02X is —S02C2H4W and is bonded to the ortho position for the azo group. In addition, if m and η are both 0 and $ is 1, then R is not a S03 Η; please read the note first Fill in the matter again. I print the line printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The material i is dyed in the C color style. The red color is divided into the corresponding ones. The color is more than twice the amount of yellow. Medium Q. Material 1 dyed to I ") This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -14 4 1 8239 A8 B8 C8 D8 HA-SO ^ X (30, Η) α Scope of patent application (i) where m1 is an integer 2 or 3, R7 is a hydrogen atom or Ci_4 alkyl group, E1 is an amine group or _COCH3, and A1 is a phenylene group Or a certain group and it may be -S 03H, halogen, alkoxy,-<: 1 ^ 23〇2 (: 2 substituted by 40 3 031 ^, Ci-4 alkyl or Ci-4 alkyl Alkoxy CP4 alkylene, Υι is a halogen atom, —NH C2H4S O3H or ~ N — A 1 — S 0 2 X (where A1 and R7 are as defined above, X is a CH = CH2 or —C2H4W (where w (As defined above), and X1 is X or a hydroxyl group as defined above (please read the precautions of S before filling in this page) Printed by R · CH-I 'C0 (ii) where R 8 is C alkyl or C group, and X is as defined above:, alkoxy, R 9 is C, and the paper size of this paper applies the Chinese National Standard < CNS) A4 (210 x 297) Mm)-15i 418239 A8 B8 C8 D8 Patent scope CH: I 'CO (S03H); S03H V cohh-(^ 7-nh- < / 10 N = < [R10 NA-S02XIn (iii I where R1D is a Ci_4 alkyl group, is a hydrogen atom or Ci_4 alkyl group, and A1, X1 and Y1 is as defined above, 12 so, x (SCUH) n: where n1 is 0 or 1, m2 is 1 or 2, R12 is methyl or carboxyl, and X and X1 are as defined above; and G is relative to the red dye -. 1 to 1 Of blue components by weight which have one or more of the following formulas: ... 乂 v) to (vi〇 dye: ------------ 装- --1 ---- Order --------- Online, " '< Please read the note of noisy face before filling this page) SCM where m3 is 0 or 1, and X is as defined above. The paper size applies the Chinese National Standard (CNS) A4 (210 * 297 mm) —16; A8 B8 C3 D8 18 2 3 9 4ίθ239 t, patent application scope vi) where Z1 is an amine group or-NH-R14 ~ NHQ2, R13 and R14 are both Ci_4 alkyl groups I Q1 and Q2 are both «= <, Han-Aug-50 , I 2 p 15 ------------ install (please read the precautions on the -f side first and then fill out this page) where Y2 is a halogen atom ㊉ Ν'Ο) or sulfonate-substituted benzene COOH amine group, R15 is hydrogen atom or Ci_4 alkyl group, and A1 and X1 are as defined above) or Y3 line-Printed by Consumer Consumption Cooperation of Intellectual Property Bureau, Ministry of Economic Affairs < 2 ^ (S0, H) n where Y3 is a halogen atom or a @ 1 to 3), Ν Λοοη ;, and η 3 is an integer This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ~ 17 418239 § D8 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Attachment ·· Corrected Page of Chinese Specification for Patent Application No. 83106376 Submitted in U.S.A. 85, July 13, 1993 418239 Class ‧ Application Date 83106376 (The above columns are filled out by the Bureau.) Patent Specification Invention Type Name _ Invention, I. Creation of Chinese English Name Nationality Residence 'Name of Residence (Name) Red Reactive Dyes, Compositions Containing It, and Dyeing Method Using That Red reactive dyes, their composition and dyeing aethod empolying them ⑴ 桧 原 利夫 C2) High __ 介 (1) 本本 (2) Japan ⑴ said the country of Japan, Kurosaki Castle Stone, Hachiman West District, Kitakyushu City, Fukuoka Prefecture, Japan—No. Inside the Research Institute (2) Inside the Research Institute of Mitsubishi Kasei Yabu Niubi No.1, Kurosaki Castle Ichiban, Ichiban, Kita-Kyushu, Fukuoka Prefecture, Japan (1) Japan Destar Co., Ltd.肀 八 & Co., Ltd. Binding © Department of Economics and Economics, Xia Hui Called Zouzhuanzhuan, Bone Removal and Bone Cooperative Co., Ltd. Printed National Debit III. Applicant's Residence and Residence (Office) Name of Representative (1) Japan (1) Osaka Prefecture, Japan Osaka City Central Plaque, Atome, Ichimechiban, No. 20, Podolmel Kappa Paper Size Applies to Chinese National Standard (CNS) A4 Specification (210 X297 mm} .418239 V. Inventions (1) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs This invention is about water-soluble monoazo-based reactive dyes, which are used for materials containing hydroxyl or amido groups such as cellulose fibers, Dyed or printed with natural or synthetic synthetic fibers, polyurethane fibers or leather, or a mixture of these fibers. More specifically, this relates to a reactive dye capable of dyeing a particular cellulose fiber to become red and being fixed in light and excellent in leveling property, a composition thereof, and a dyeing method using the same. Reactive dyes are widely used for the dyeing of different materials, especially cellulose fibers, because of their bright colors and their excellent gripping properties. On the other hand, in the field of dye industry, the demand for better dyes is also increasing. In recent years, the red type of reactive dyes are excellent in light fixation, and their demand is much higher than before. Conventional reactive dyes are usually at the level of level 4 and no dyes are known to be superior to level 5 (after exposure to carbon arc light for 80 hours). In order to meet the above requirements, the present invention has conducted extensive research to develop a red reactive dye which is excellent in light fixation, color fixation to light and sweat, and color fixation to chlorine , Especially in terms of light fixation. As a result, the present invention has been completed. The present invention provides a red reactive dye which has the following formula (I) and is in free acid form, and its composition and dyeing method: (Please read the precautions on the back before filling this page) -tl --------- line. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -4-A7 B7 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Instructions (2) Where X is a ch = ch2 or a c2h4w (where W is -0S03H or halogen ratio), A is C2-c3 alkylene or C2_3 alkylalkoxy C2_3 alkylene, E is hydrogen atom, Chs alkyl Or -A-S Ο 2-X (where A and X are as defined above), 11 is 0 or 1, and 1 or 2, m is 0 or 1, and R is a hydrogen atom, —OH, — CN, -CH3, a CF3,-so3h, -c Ο Ο Η, a CH2S03H or a CH2S02X (where X is as defined above), but if R is a hydrogen atom, m and η are 0, 芡 is 1_, S02X is _S02C2H4W It is bonded to the ortho position of the azo group. In addition, if m and η are both 0 and 5 is 1, R is not -S Ο 3 Η. Now, the present invention will be described in more detail with reference to this more specific part. In the above formula (I), X is a ch = ch2 or -C2H4W, where W is a base which can be split by 鹸 "Under the action of this base, -c2h4w splits so that it will be converted into a CH = CH2 however separates W-H. When this group is cleaved under the action of a certain base, _0S03H, SS03H '— OPO3H2, _〇C〇CH3, or a " dentin ^^ standard is applicable to China National Standard (CNS) A4 specifications (210 x 297 mm) ------------: ^ -------- Order --------- line (Please read the precautions on the back before filling this page) 418239 A7 B7 V. Description of the invention (3) (Please read the notes on the back before filling this page) Atoms are usually referred to. Particularly preferred is 0 s0sH. This C 2-3 alkylene group or C 2-3 alkylene oxide C 2-3 alkylene group may be, for example, ethyl, propyl, ethoxy, or propyl Examples of oxy-propyl-specific A-so2x include chloro- (cold-chloroethylsulfonyl) ethyl, -r-(y5 -chloroethylsulfonyl) propyl, -r- (Θ —Ethylsulfonylsulfate) propyl, —Θ — (ethenylsulfenyl) ethyl, mono-> 9 [Lu — (Θ —chloroethylsulfonyl) ethoxy] ethyl, —r One [r — (point monoethylsulfonylsulfonyl) propoxy] propyl group, and one / 3— [point one (vinylsulfonyl) ethoxy] ethyl group. Particularly preferred are, for example, C2H4S 〇2CzH4〇S O3H, -C3HeS 〇2C2H40 S 03H and -c2h4〇 C2H4S 02C2H40 s 03H. The Ci_3 alkyl group of E may be, for example, methyl, ethyl or propyl. Particularly preferred are methyl or ethyl β and 1 ^ is preferably a sulfonic or carboxyl group. From the viewpoint of light fixation and color fixation to light and sweat, the reactive dye in formula (I) is preferably a reactive dye. Garment η is 0 or 1, J? Is 1, X is a C2H40SO3H, the ruler is a sulfonic acid group or a carboxylic acid, and m is 0. Furthermore, the reactive EI dye of the formula (I) in which (C — N_A) nS02X or R is located adjacent to the azo group II 〇 is also excellent in the color fixation of chlorine. The standard applies to the national standard (CNS) A4 specifications (210 x 297 mm) -6 1 4 1 82? 9 ί_I 散 Α7 j Α ,. Β7 丨. 5. Description of the invention (4) The reactive dye of the present invention ° can be prepared as follows, that is, a compound of formula (A): Among them, X, A, E 'R' η and p are as defined above. This is diazotized according to a conventional method, and then a compound of the following structural formula (B) is used to couple with it. ---------------- Install --------- Order ---------- Line®. ≪ Please read the notes on the back before filling (This page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, where m is as defined above, and is performed in a water-soluble medium at a temperature of 0 to 5 ° (: 2 to 3 with mouth water), and then chlorinated Sodium is added to the reaction solution, and the formed precipitate is collected by filtration. With this type of reactive dye, it is possible to improve the leveling property and to combine it into a composition by 2 or more dyes to enhance Such a dye composition can be a composition including a dye of formula (I), where X is a ch = ch2 and a dye of formula (I) where X is -C 2 H 4W, which is a composition containing The dyes of the following formula (I-A) and the dyes of the following formula (I-B): This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 418239 A7 B7 Announcement 5. Description of the invention (F (I-A) (IB) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs or a composition containing a dye of formula (I) where ten f — IjJ-A + ns 〇2X is an adjacent position bonded to an azo group, and DE A dye of the formula (I) and wherein the same base is bonded at the para position, that is, the unitary composition contains a dye of the following formula (I-C) and a dye of the following formula (I_D): 工 -C) ------------- Installation -------- Order --------- < Please read the precautions on the back before filling this page) This scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -8 ~ 4 1823 ^ 丨 5 A7 B7 L ·. 5. Description of the invention (II E 0 [X〇2SfA-NC ^ < P > R (ID) or a composition containing a dye of formula (I) where m is 0 and a dye of formula (I) and _ where m is 1, that is a composition is a dye comprising the following formula (I_E) and the following formula (I-F) dye: f (IE) ----------- t -------- Order · --------- M (Please read the notes on the back before filling this page) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperation (I-F) In the above formulae (I-A) to (I-F), 'the X, A, E R, η, m and ί are as defined above. A preferred example of this dye containing such a composition is to include the following formula (η This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -9--4 1 823 V. Description of the invention (7) ) To (V): A7 B7 X〇2S II so3h (III) (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (IV) (V) In the above formulas (Π) to (V), X is as defined above. When the dyes of the above formulas (Π) to (V) are combined to form a composition, a known formula (VI) (see Japanese Examined) is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297). (%) Order ---------- 4y -10-418239 / a ·: -K- y- A7 V. Description of Invention (8) Patent Publication No. 1 6 4 3/1 9 5 6) The dye can then be incorporated into: (VI) Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs In the present invention, the dyes of the formulae (π) to (v) can be arbitrarily combined to obtain a dye composition. The ratio of the respective dyes varies depending on the composition of the dye composition. For example, if a composition contains dyes of the formulae (π) and (π), the weight ratio of (n) :( m) is usually from 100: 30 to 100: 300, preferably from 100: 70 to 100: 130; if a composition contains dyes of formulae (π) and (IV), then the weight ratio of (Π) :( IV) is usually 100: 10 to 100: 200, preferably 100. : 20 to 100: 150 'more preferably 100: 30 to 100: 100; and if a composition contains a dye (VS) where X is -ch = ch2 and a dye (ES) where X It is a C2H4w, and the weight ratio of (vs) :( ES) is usually 100: 1 to 100: 50, preferably 100 3 to 100: 4. Q is better: 100: 5 to 1 0 0: 3 0 »The dyes of the formulae (I) to (VI) of the present invention may exist in the form of their free acids or their salts, respectively. In its _ form towel, it can be applied to the national standard (CNS) A4 specification (210 X 297 mm) of the metal paper scale (please read the precautions on the back before filling this page). ~ 11 418239 5. Description of the invention (9) Salts and alkaline earth metal salts, especially sodium, potassium and lithium salts are preferred. However, in order to obtain a liquid composition having a high concentration, a lithium salt is particularly preferable. In order to prepare the reactive dye composition in the present invention, the dyes of the formulae (Π) to (IV) may be mixed by synthesizing them simultaneously. Otherwise, they can synthesize and mix them separately. Alternatively, it can be mixed at the time of dyeing. By combining the condensation products of monosulfonic acid or alkylphosphonium sulfonic acid with formaldehyde and a pH buffering reagent, it can show that the buffering effect is in the range of ρΗ4 to 7, and The above composition can improve the solubility and the stability of the solution in water or an alkaline aqueous solution. In the present invention, the alkyl fruit sulfonic acid may be a low alkyl sulfonic acid, such as a methyl sulfonic acid, an ethyl sulfonic acid, a propyl sulfonic acid, or a butyl sulfonic acid. A sulfonic acid may be not only a monoalkyl compound but also a polyalkyl compound such as a dialkyl compound or a mixture thereof. The alkyl group may be a single type or a mixture of two or more types, and may be a mixture with fruit sulfonic acid. This buffering agent exhibits a buffering effect in the range of ρ Η 4 to 7 and includes an acid such as sodium dihydrogen phosphate, Sodium monohydrogen phosphate, potassium dihydrogen phosphate, potassium monohydrogen phosphate, sodium hydrogen phthalate, potassium hydrogen phthalate, acetic acid, tartaric acid and citric acid, and their sodium, potassium and ammonium salts. It can be used alone or as a mixture. When the sulfonic acid or alkyl sulfonic acid and the condensation product of formaldehyde and the PF buffering agent are mixed into the above composition, the weight ratio is to apply the Chinese National Standard (CNS) A4 specification for this paper scale (210 X 297 mm) —--------- ^ -------- Order --------- (Please read the notes on the back before filling this page) Economy Printed by the Consumer Cooperatives of the Ministry of Intellectual Property Bureau ~ 12-4 1 823 9%, Α7 Β7 bulletin board 5. Description of the invention (10) The material composition is 20 to 85 parts by weight, the condensation product is 3 to 50 parts by weight, and the P (R) buffer reagent is 1 to 25 parts by weight. The dye composition of the present invention may contain a solubilizer such as urea or ε-caprolactam. It may also include sodium chloride or sodium sulfate, or incorporate anti-dust agents such as mineral oil emulsions, and its acceptable range is based on the fact that there is no adverse effect on the solubility of this dye composition. The amount of such additives can be arbitrarily selected, and is preferably per 100 parts by weight of the above-mentioned dye composition. The total amount of the condensation product of a certain sulfonic acid or alkyl sulfonic acid with formaldehyde and the P Η buffer is It can be as high as 70 parts by weight. In a preferred specific part * The present invention provides a red reactive dye composition comprising 100 parts by weight of a dye having the formula (I >) and in its free acid form: SO.XR where X is -ch = ch2 or a C2H4W (where W is —0S03H or halogen) 'R1 is a hydrogen atom, a S02X, —CH2S02X (where X is —ch = ch2i-c2h4w (where w is _oso3h or halogen)), a halogen atom, low Alkyl, low alkoxy, —S02x or a CH2S02X and m is σ or 1 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -----------. .Install -------- Order --------- < Please read the notes on the back before filling out this page) Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-13 Printed by Property Consumer Employee Cooperatives 4 , Slave 2 CHO-is in Q 3 R where R2 is a hydrogen atom or _ prime atom, R3 is a hydrogen atom or low alkyl 'R4 is a hydrogen atom, halogen atom, low alkyl or _so2x and where X is ~ CH = CH2 or —C2H4W (W is— 0S03H or halogen), and z is a halogen atom, a hydroxyl group, -In or R5 ί Ν R ------------ install / V '(Please read the precautions on the back before filling this page) COOH (Where R5 is a hydrogen atom or a lower alkyl group, and R8 is a hydrogen atom, a halogen atom, a carboxyl group, a sulfonic group, or a so2x (where X is as defined above)), Y is a hydroxyl group, and ch = ch2 or —CH2CH2W ( Where W is as defined above, and P is 0 or 1 In the above formula (—0 S 0 3 Η. For each R 1 and (X), W is preferably a tr-line ridge-R, R4 and ruler 3 The lower alkyl group is a one-kilogram paper scale that applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 14-418239 r). A7 B7 V. Description of the invention (l2) Ci-4 alkyl group such as methyl 'Ethyl, n-propyl or n-butyl, and is usually as described above. For each Z, R1, R2 ,: R4 and R6, the halogen atom is usually a chlorine atom, a fluorine atom or a bromine atom. In particular, Z is preferably a chlorine atom or a fluorine atom 'and each of R1, R2, R4 and R6 is preferably a chlorine atom or a bromine atom. In the above formula (I >), it is particularly preferred that R1 is a hydrogen atom 'and S 02X is an ortho position of the azo group in the benzene ring. As far as the selectivity of each group in the above formula (X.) is concerned, it is not necessary to consider the selectivity as necessary, so that at least one reactive group is present in the reactive dye. These dyes exist in free acid form or in their salt form. If it is in the form of a salt, it may be an alkali metal salt or an alkaline earth metal salt such as a lithium salt, a sodium salt, a potassium salt or a calcium salt. Of the above formulas (I /) and (x >), The water-soluble reactive dye can be prepared by a conventional method, and the production method is not particularly limited. In the present invention, the dye of the formula (X) is usually combined in an amount of 10 to 300 parts by weight, and It is preferably 30 to 120 parts by weight, and is determined per 100 parts by weight of the dye of the formula (1 >). If the amount of the dye of the formula (X) is too little or too much, it is difficult to obtain a dye with good balance of color fixation to light and sweat, color fixation to chlorine and dyeing properties, And this is what the present invention wants. These dyes can be mixed in advance, or they can be mixed at the time of dyeing; the A-scale is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) M, -------- Order * --- 1 ---- Yuan y / ΐ. Y / ί ^ (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -15-Α7 Β7 Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Staff Consumer Cooperative 418239 'Λ 5. Description of the invention fu) The dyeing of this synthetic or natural polyamide or polyurethane fiber is performed by first performing a p or The value is completely dip down, and then the value of ρ is changed to neutral, or in some cases it is done by fixing in lye. This dyeing is usually at a temperature of 60 ° 匸 to 120 ° < : Finished. When cellulose fibers are dyed with the dye or dye composition of the present invention, particularly excellent light fixation, color fixation to light and sweat, and color fixation to chlorine can be obtained. When the above-mentioned red reactive dyes and dye compositions are used for dyeing, by using specific yellow dyes and / or blue dyes in combination, they can obtain particularly excellent light fixation and color against light and sweat. Fixation. As such a yellow dye, one or more dyes of the following formulae (i) to (iv) can be used. (i) where m1 is an integer of 2 or 3, R7 is a hydrogen atom or a lower alkyl group, E1 is an amine group or a COCH3, and A1 is a substituted or extended phenyl group, a fluorenyl group, a fluorenyl group, or a oxonyl group. Yenyl, Y1 is a halogen atom, -NHC2HdS 03H or N-A1-S02X (where R 7 A1 and R7 are as defined above, X is -CH = CH2 or this paper size applies Chinese National Standard (CNS) A4 specifications ( 210 X 297 mm) I ------------ 1. · ------- Order --------- line ^ (Please read the precautions on the back first (Fill in this page) (SO, H) m -17-α 1 823 86. 8 Α7 Β7 Ⅴ) —c2h4w (where W is —0S03h or halogen), and X1 is X or hydroxyl as defined above) ’ ch3 9 CO I N = — Cll OCH: (ii) COHli 、、 S03H uh3 {Please read the precautions on the back before filling out this page) -pack. Where R8 is low alkyl or low alkoxy, R9 is low alkyl.oxy, and X is as defined above, (S03H ), ca3 I CO I -CH SO I COiNH .Then K. t 11 (iii) Order _ Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economics, where is low alkyl, R11 is a hydrogen atom or low alkyl, and A1, X1 and Y1 are as defined above, 41823.i A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (〖6) where η1 is 0 or 1, m2 is 1 or 2, R12 is methyl or carboxyl, and X and X1 are such as The above definition. As the blue dye, one or more dyes of the following formulae (v) to (v i i) can be used. Ο HH Where m3 is 0 or 1, and X is as defined above, Cl 50, Η (vi) SQ2H Cl where Z1 is an amine group or NH-R14_NHQ2, R13 and R14 are both low-elongated alkyl groups, and each of Q1 and Q2 is 15 (where Y 2 is a halogen atom, 1 or a sulfonic acid-substituted benzene paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 χ 297 mm) ------------ " .Install -------- Order ------- line (Please read the precautions on the back before filling this page) Bu if see NH-q1 Ο N -19-418239 A7 B7 V. Description of the invention (17) Amino group 'R15 is a hydrogen atom or a lower alkyl group, and A1 and X1 are as defined above] or r3 · (where Y3 is a halogen atom or 0 C0GK number 1 to 3), and η 3 is a complete CI t2-nh Vll S02x Cl----------- II * IIIIIII ί I! I /1.· (Please read the precautions on the back before filling (This page) where T1 and T2 are both low alkyl and may be substituted, and X is as defined above β A1 represents, for each of the above formulae (i), (iH) and (vi), benzene Or a certain group and it may be substituted, and the substituent may be a halogen atom such as a bromine atom or a chlorine atom, a nitro group, a sulfonic acid group, a carbonyl group, a Cl-4 alkyl group, and a Ci-4 alkoxy group. Or -c h2s o2c2h4o s o3h. Specific examples include the following groups (where the symbol * indicates that the bond is connected to a nitrogen atom and it is bonded to a triple well ring): This paper size applies to Chinese national standards (CNS > A4 specifications (210 X 297) Line Θ · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -20-4 1 8 2.3 &----------- 丨 Jh / A7: r:?: Umbrella "β7 V. Description of the invention ( 19 Furthermore, as for the alkylene and alkyleneoxyalkylene groups of A 1, Calkylene and Calkyloxyalkylene groups may be as described above. Specific examples of A1—SOsX1 include a jS— (jS-chloroethylsulfonyl) ethyl group, a r— (point-chloroethylsulfonyl) propyl group, and a < 5— (million chloride Ethylsulfonyl) butyl, r- (Ethylsulfonylsulfonyl) propyl '-/ S — (vinylsulfonyl) ethyl, — [Luchlorochlorosulfonyl) Ethoxy] ethyl, r-[[tau]-(stone-ethylsulfonylsulfonyl) propoxy] propyl, and-[[fluorene- (vinylsulfonyl) ethoxy] ethyl]. Particularly preferred is 可 〇2ίΪ4, δ 0 2 ^ ZH 4. 0 S Ο3Η, printed by the Consumers ’Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs ~ ^ -i — ^-^^ 1 I —i I ^ m I (Please read the note on the back before filling in this page>> CaHeS O2C2H4O S Ο3Η and —C2H4O C2H4S. O2C2H4O S O3H. For each R7, R8 'R1.,! ^ 11 and R15, the lower alkyl is It may be methyl, ethyl, straight-chain or branched propyl, or straight-chain or branched butyl, which may be as described above. Particularly preferred is methyl or ethyl. For each R8 and R9 The lower alkoxy group can be as above, such as methoxy group, ethoxy group, straight bond or branched propoxy group or straight chain or branched butoxy group. This paper is applicable to China National Standard (CNS) A4 specifications ( 210X297 mm) -22-.———— IW gas "J R7 — One 1, —7 .. :: ....) ------ i- 5. Description of the invention (—20)! 1 i Is particularly preferred is methoxy. _...._______----------------- For each Y1, Y2, and Y3 halogen atom, it may be as described above. A fluorine atom, a chlorine atom, or a bromine atom. Particularly preferred is a fluorine atom or a chlorine atom. ^ These reactions Dyes can exist in free acid form or in their salt form. In the salt form, they can be alkali metal salts or earth metal salts, such as lithium, sodium, potassium or calcium salts. Generally preferred.-One or more members selected from the group consisting of yellow dyes of the formulae (i) to (iv) and / or one or more members selected from blue dyes of the formulae (v) to (vii). The basic group, the amount used is in the range of 0.01 to 100 times the weight, preferably 0 to 1 to 50 times the weight, and this is relative to the red dye. For the purpose of color adjustment, additional dyes as the third component can be incorporated within the dosage range that does not detract from the effect of the present invention, for example, in an amount not exceeding 1 Ow t% * Now the present invention is made by reference The following examples will be described in further detail. However, it should be understood that the present invention is not meant to be limited to the following examples only. Example 10.2g has the following structural formula in its free acid form (Π_ 1) dye to dissolve in water of 20 OinJ? National Standard (CNS) A4 Specification (210 X 297 mm) (Please read the notes on the back before filling out this page). Binding --- Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -23-418239 ·. ............ 〆. ..! Month S., I A7 --r _q -¾ .1 B7…. :: 乂 卜 > > ya 221——1—- · V. Description of the invention (21) so3h H0350H4 C202 s (Please read the notes on the back before filling this page) Η〇 Then add 10g of thenardite. Then, 10 g of unmercerized cotton cloth was impregnated therein, and the temperature was raised to 50 eC for about 30 minutesa. Then, 4 g of sodium carbonate was added thereto, followed by dyeing at 50 ° C for 1 hour. Thereafter, it was washed with water, then with soap, and then washed with water and completed drying to obtain a ruby red dyeing product with good leveling property. This light fixation is level 5 (40 hours of radiation), the color fixation to light and sweat is level 4+, and the color fixation to chlorine is level 4 _ β Employees, Bureau of Intellectual Property, Ministry of Economic Affairs The light fixation of printed clothing by consumer cooperatives is evaluated in accordance with JISL-0842, and the color fixation of light and sweat is evaluated in accordance with JISL-0888 (Method A, using alkaline artificial sweating). And the color fastness to chlorine is evaluated according to Jf ISL — 0884 (test solution: available chlorine 10 mg / i2, temperature: 25 ± 2 ° C).眚 例 2 1 0 0 g has the following structural formula in its free acid form (E — This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 Gongchu) — 24-4 18239 A7 B7 clothing 5. Description of the invention (22) Ο-SO; (II-l) and 30 g have the following structural formulas in free acid form (m— i, c = hco, s so3h (III-1) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs for blending to obtain a dye composition. 0-lg, 0.2 g, and 0.4 g of this composition were separately dissolved in 20 Omj? Of water, and 10 g of thenardite were added to each solution. Immerse non- mercerized cotton cloth in each solution and increase the temperature to 60 ° C for about 30 minutes. Then, 4 g of sodium carbonate was added thereto, followed by dyeing at 60 ° C for about 1 hour. Thereafter, washing with water, washing with soap, washing with water, and finishing drying are performed to obtain a ruby red dyed product, which has excellent reinforcing properties and excellent leveling property. The light fixation of cloth dyed with 0.2g of composition is grade 5 (40 hours of radiation exposure), and the color fixation to light and sweat is equal to ------------ -------- tr ------- '! 线 # (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Centimeter) -25-418239 Im aa " b: -9 -M- Α7 Β7 Announcement V. Invention Description (23) Level 4+ 'and its color fixation to chlorine is level 4 Example] In Example 2, the dyeing was performed as described in Example 1 and it used a reactive dye of the formula (Dai-1) of 0.1 g, 0.2 g, and 0.4 g. As a result, the enhanced properties obtained were inferior to the dyed products obtained in Example 2. Consumption cooperation between employees of the Intellectual Property Bureau of the Ministry of Economic Affairs, Du printed Example 3 in 2.5 g of hot water and 5.5 g of glass with 50 ° 1 0 0 0 g (padding to wind the water for 20 hours. After that, In boiling soap and 50 g of the dye composition of Example 2 were separately dissolved in this solution and cooled to 25 ° C. »In each solution, 2. 2% sodium hydroxide aqueous solution and 150 g Water glass Baling, and then add water to make the total amount at 25 ° C »Immediately after that, each solution was used as a padding solution solution) and saturated with cotton fibers. This cotton fiber is then sealed in a polyethylene film and stored at 20 ° C. Each dyed product is washed with cold water and hot water and then washed, and then soaped in solution. Then washed with cold water once and finally dried. To obtain a ruby red dyeing product, which has excellent reinforcing properties. Examples 4-1 to 4-20 The reactive dye used in Example 1 was changed to the dye in Table 1, and the dyeing was performed according to Example 1. As a result, the dyed product has the color of the paper and is suitable for Chinese National Standard (CNS) A4 (210 X 297 mm) --- 1 II Ϊ I ----- ^ ---- I --- order-- --- y —... (Please read the precautions on the back before filling out this page) Line ©. -26-18239 18-01 I am adding A7 B7 V. Description of the invention (28) y Example 50. 2 g of the dye having the following structural formula (W-1) in free acid form is dissolved in 200 mj? Of water: (iv-l) (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Then add 10 g of thenardite to it. Then 10 g of non- mercerized cotton cloth was impregnated. This temperature was raised to 50 ° C for about 30 minutes' followed by impregnation for 1 hour. After washing with water, soaping, washing and drying, a dyed product with a cyan red color is obtained, which has excellent leveling properties. The light fixation is level 5 (80 hours with carbon arc light), the color fixation of light and sweat is level 4+, and the color fixation of chlorine is level 4_. This evaluation method is carried out in Examples 6-1 to 6-3 using the same method as in Example 1. A dye having the following structural formula (IV-2) in the form of free acid. This paper applies the national standard of 1f1. (CNS) A4 size (210 X 297 mm) -31-1 8 23.9 ^ Revision · Zheng is A7 B7 SO 3 Η (IV-2); and a dye having the following structural formula (IV-3) in free acid form (IV-3) 1 (Please read the notes on the back before filling out this page) SO ο Η Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs for blending, 0 · 1 g at 2 0 0 and then 1 degree higher Each solution is soaped, and the water has a good composition for 80 hours, and the amount is about 0.2 gj? 0 g non-60 eC in water, then wash and complete the dyeing cloth with enhanced properties) > G and 0 4 in Table 2, and adding 1 mercerized cotton for 20 minutes. "Drying at 60 ° C can get a good uniform light fixation. Light and sweat show to get every 0 g. After immersion in g, the lower dyeing band has cyan dyeability. It is a grade of color solids, a dye, a composition, thenardite to 4 g of carbon per solution for 1 hour. The red staining is 0.5 (the carbon composition is equal to the composition. To dissolve β in a solution separately, and add this warm sodium to the product washed with water, which has an arc of 2. g Light exposure level 4 +, and this paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) -32-418239 • Positive A7 Β7 Example 6 — 1 6-2 6-3 V. Description of the invention (3 〇) This color fixation to chlorine is grade 4. This evaluation was performed by the same method as described in Example 1. Table 2 Dye (IV-2) (g) Dye (IV-3 (g) 10 0 1 0 .10 0 5 1 0 0 2 5 Reference Example 2 Dyeing was performed in the same manner as in Example 6 but Example 6 using 0 · lg, 0.2g, and 0.4g was used. The dye of the formula (IV-2) used in the results. As a result, the product after dyeing is inferior to the product dyed with the composition of Example 6 in terms of enhancing properties. Example 7 2 5 g and 50 g of the dye composition of Example 6-1 was separately dissolved in hot water, and the solution was cooled to 7 5 ° C. 5.5 g of 32.5% was added to each solution. Sodium hydroxide aqueous solution and 150 g of water glass with 50 ° BaumS, and further water was added so that the total weight reached 100 g at 25 ° C. Immediately thereafter, each solution was used as a padding solution to make It is saturated with cotton fibers. Then this fiber is wrapped with twisted water and sealed in a polyethylene film and stored in a 20 ° C room for 20 hours. After that, the paper produced after this dyeing is compliant with Chinese national standards (CNS ) A4 size (210 X 297 mm) ----------------------- Order ----- (Please read the precautions on the back before filling in this Page) line.}, Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -33-418239 A7 B7 5. Description of the invention (31) The object is washed with cold water and hot water, and then soaped in a boiling soap bath. The dyed product was washed with cold water, and finally dried to obtain a cyan red dyed product, which had excellent reinforcing properties. Examples 8-1 to 8-3-A dye having the following structural formula (E-1) in free acid form (工 ι-ΐ) and a dye having the following structural formula (VI) 2 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (VI) Blend and use the amounts as shown in Table 3 to obtain a dye composition of 0.1 g, 0.2 g, and 0.4 g of each of the compositions, each dissolved in 200 m $ of water. Then, add; 10 g of thenardite is in accordance with the Chinese National Standard (CNS) A4 specifications (210 X 297) for each paper size. ------------------------ --Order --------- line 'J (please read the precautions on the back before filling this page) -34-4 j 8239 The employees of the Intellectual Property Bureau of the Ministry of Economic Affairs consumed the printed solution in the cooperative to prepare a dye solution. 10 g of non- mercerized cotton cloth was immersed in each solution, and the temperature was raised to 60 ° C for about 30 minutes. Then, 4 g of sodium carbonate was added thereto, followed by dyeing at 60 ° C for 1 hour. Then, it was washed with water, soaped, washed with water, and dried to obtain a red dyed product having excellent reinforcing properties. The degree of light fixation of the cloth dyed with each composition of 0.2 g was level 5 and the degree of light fixation to light and sweat color was level 4 to 5. It is worth noting that = metal-free reactive dyes have never before seen such excellent color fixation to pre-sweating and are of interest as far as red dyes are concerned. Table 3 Example Dye (nl) (g) Dye (vi) (g) 8-1 100 10 8 — 2 100 5 8-3 100 2 5 Comparative Example 1 The dyeing was performed in the same manner as in Example 8. However, 0.1 g, 0.2 g, and 0.4 g of the reactive dye of structural formula (VI) used in Example 8 were used. However, the dyeing product obtained in this way was inferior in enhancement properties and uniform in dyeability. It is not good. Example 9 This paper size applies the China National Standard (CNS) A4 specification (210 X 297 mm) ----------- installed, --I ---- ordered ------ --- line (Please read the precautions on the back before filling this page) -35-418239 A7 R7 • ~ n I J-\ ft '1 V. Description of the invention Mu is 70 parts by weight of a dye composition which is a dye of the 8 t configuration (π-1) and a dye. Sodium phosphate (crystal) having a degree of sulfonation of 1 2 0 and a weight of 1 to 20 are added. Mineral oil emulsifier composition. 100 parts by weight of hot water, and 20 parts by weight of anhydrous mirabilite, and then added to the water bath immediately after the pressure rate of 6 5% into the olefin film, and let After 2 the product is washed with cold water to clean the cleaning reagent and rewashed with water at a temperature of 9 and the product is dried. No padding of the dye was observed even when the padding was performed as described above, and thus a product was obtained. The parts by weight are 14% by weight, and the thus obtained liquid-cooled sodium sulphate is made up to the total amount of bath liquid for pad dyeing5. . Room and hot water from 5 to 9 to obtain% of the above-mentioned aldehyde condensation product of structural formula (VI), 5 parts by weight and 5 wt% of the above-formed methyl sulfonic acid and methyl formaldehyde have a degree of condensation of 1.8 parts by weight of sodium sulfate (Anhydrous) and 1 are completely mixed to obtain (please read the precautions on the back before filling this page) ό 装 · — order --------- line. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The dye set is rolled up to 2 5 3 8 ° up to 10, then stored and then washed to dissolve in ° C. Then, Baumg and 300 parts by weight of the dyeing bath were wound with water for 15 hours. A powdery dyeing weight of 50,000 is added to it by 0 parts by weight. The dyed cotton cloth was squeezed and sealed in polyethylene at 8 ° C to make the soaping place dark red without extremes. Then this dyeing was done in a bath, and the dyeing solution of the stain was left at 25 °. Precipitation under C. More specifically, Maoge cotton was dyed using this uniform dark-stainless extreme dark red 60-minute padding solution. Example 10 This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm>- 36-4 18239 A7 B7 V. Description of the invention (Reference Example 4 The dye composition obtained in Reference Example 3 was used. A printing paste was prepared in accordance with Example 10, and the dye was precipitated. " 'Here, the color ratio is low, and a stain-like and particularly useless dyeing product is obtained. Examples 1 1 to .1 1 1 Γ) and Reference Examples 5 to 7 Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economy This coloration is as red as possible. The fixation is used as a reference, and the compound is 0 2 g. Example 1 1 — In the example, 1 1 — 1 is shown in the table example. Color Dyeing 0.2 Grade 5 As shown in the table or 0 · 1 to 1, which enhances the 0-1 of the product 0 in the case 4 and its g, and the example, the 4 in the case 4 of the 1-1 dye to 8-to enhance the composition of other sweat The amount shown in the formula above shows the phase-dyeing properties and results. Poor. According to the same square property of Table 4-3 and the color fixation degree of the dyed material is (m) and (), it is used alone, and the same method to complete the quality is better than the amount of method to complete the property. Cloth, grade 4 W) of 0 · 1 and dyed into, mixed from Example 1 1 and finished, and thus all are excellent is light to 5. The compound g, is as implemented in each of -1 to ( Please read the precautions on the back before filling in this purchase) This paper size is applicable to Chinese national standards (CNS> A4 size (210 X 297 mm) _ 38 — 4 182 materials V. Description of the invention (39) Example 1 0.2 g of a dye mixture containing 50 parts by weight of a dye having the following formula (a) in free acid form:! 'SO 〇H and 20 weight The portion has the following free acid form (dye: ------------ ο loading (please read the precautions on the back before filling this page) a '1 _ The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs of N I CH printed so2c2h4oso3h to dissolve in 20 Omi of water. 10 g of thenardite was added to this solution and dissolved to obtain a dye bath (glauber's salt concentration: 50 g / J2). In this dye bath, 10 g of non-mercerized cotton fibers were immersed, and the temperature was raised to 60 ° C for about 30 minutes. Then 3 g of sodium carbonate was added, and thorough staining was performed at the same temperature for 1 hour. After dyeing, the dyed cloth was washed with water, then soaped and dried by a conventional method to obtain a red dyed cloth with good leveling property. The light fixation, the light and the paper size of this cloth apply the national standard (CNS) A4 (210x 297 mm) -42-4182. Obtain: Amend! A7 B7 V. Description of the invention (43 ) Example 15-Example 15-26 The method in Example 12 'The reactive dye of this formula (a /) is changed to the reactive dye of the free acid form shown in Table 6' and The same test as in Example 12 was performed * However, the obtained light fixation, color fixation to light and sweat, and color fixation to chlorine were all at a level of 4 or higher, and Red dyed cloth with leveling property of 0 is available (please read the precautions on the back before filling this page) Line-Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper applies the national standard (CNS) A4 standard (210 X 297 mm) -46-418239 A7 B7 V. Description of the invention (57) ......_ Example 1 A dye mixture containing 0_ 1 g of the following formula in free acid form (A) The dye is used as the red component: 0.1 g of the dye having the following formula (b) in its free acid form is used as the yellow component: Cl (please read the note on the back? Matters before filling out this page) One pack I · so3h η = < NHCONH: HH (b) S〇2C2Hii〇S03H printed by Qigong Consumer Cooperative of Intellectual Property Bureau of Ministry of Economic Affairs and Q. 1 g of dye having the following formula (c) in its free acid form as blue Color composition: The size of this paper applies to the national standard (CNS) A4 (210 X 297 mm) —60-418239 V. Description of the invention (59l.) The mixing ratio is changed except that the dyeing products obtained are shown in Table 8. As shown in Table 8, the light fixation and the color fixation to light and sweat are good. Comparative Example 5 In Example 17 • Dyeing was done in the same way, except that the blue component dye was changed to the following dye of known structural formula (d), and the formula (d) was published in Japanese Unexamined Patent Publication No. 4 7 8 3/1 9 8 1 is particularly excellent in color fixation to light and sweat. As shown in Table 8, the color fixation to light and sweat is substantially poor. ------------ Install --- (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) Order ----- Line, -62-1 9: · _ * 3 2 β J 4 83 Section C: Pieces 9 8 Hu Yuemingfa / ft \ To extract Mingfa. Chinese 'Four natures should be reversed red: ϊ ζ species form acid by I Jirf .5:; ..: Please string, self-organize into groups, and} I I contain method {, the way the material is colored and dyed should have the opposite color, red and dyed Where X is ~ ch = ch2 or one (where W is 10S03H or bacteriocin) 'A is C2-3 alkene group or C2_3 alkoxy group c2_3 alkane group, E is argon atom' Ci-3 alkane Or -A-S Ο 2X. (Where A and X are as defined above), 11 is 0 or 1 and 1 or 2, Π1 is 0 or 1 'and R is a hydrogen atom, -0H, -C Ν >-C Η 3, one CF3, one S03H, one COOH, -c h2s O3H or one c h2s 02X, (where X is the abstract of the invention as defined above in English (the name of the invention: RED REACTIVE DYES, THEIR COMPOSITION AN :) 丨 DYEING METHOD EMPOLYING THEM; Λ red reactive dye having the following formula (I) in its free acid form: (Please read the precautions on the back before filling in the columns on this page) Member 4 Printed by a cooperative -OSO ^ H or halogen), A is a C2 ^ 3 alkylene group or a C2_j alkylenoxy c2-3 alkylene gcoup, Ξ is a hydrogen atom, a Cx, 3 alicyX group or -AS〇3X (vhereici A and X are as defined abov-), n is 0 or 1, / is 1 or 2 / a is 0 or 1, and R is a hydrogen Atom, -0E, -CN / -CZ3, -Ci * 3,-* 50 ^ 3 / -COOS / -CS3S〇3H or -CS2S〇2X (wherein X is aa defined above) t provided that when R is a hydrogen atom »each of m end ji is 0 * t is 1 · and -S〇2X is -SO ^ Cj ^ W which is banded at che ortho position to che λζο group „and when e & ch of nt and n is 0 and t ia l, ft is not -SO ^ H * This paper size applies to the Chinese National Standard (CNS) A4 specifications (2 丨 〇X297 mm) A 8 a year ^ ¾ buffalo is ortho, it is 1 group is not nitrogen R β even, right, ο in a _ is a knot is η chain 0 < and is, m and ο, 诃 is a child H4 are all M2HC hydrogen C and is 2m ο ^ R when S 若若 尙 > 彳 is. Yes ^ 外 i X Η But 2 other 3P, ◦, ο} S is set to S meaning I-(Please read the precautions on the back before filling in each page of this page) • Equipment · English Abstract of the Invention (Name of the Invention η Line Reference Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, the paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 2-1 8239 A8 B8 C8 D8 an. ‘见 See 6. Scope of Patent Application Annex A: Patent Application No. 83106376 Amendment to Chinese Patent Application Scope May 1998, a red reactive dye with the following free acid form: Ϊ) -----------_, @ 装 (Please read the precautions on the arm surface before filling out this page) where X is a CH = CH2 or a C2H4W (where W is —0S03H or halogen) , A is C2_3 alkylene or (: 2_3 alkylene oxide C2_3 alkylene, E is hydrogen atom, Ci_3 alkyl group or -A-S 0 2X (where Αχ is as defined above), η is 0 or 1, i ? Is 1 or 2, m is 0 or 1, and R is a hydrogen atom, 〇Η, —CN ′ — C Η 3, —CF3 ′ — S Ο 3 Η — — C Ο Ο Η, —CH2S03H or —CH2S02X ( Where X is as defined above), but if R is a hydrogen atom, m and η are both 0,]? Is 1, and -S 02χ is _ S 02C2H4W and is bonded to the ortho position of the azo group. In addition, if • When m and η are 0 and j? Is 1, R is not -0 S 〇3h. 2. As the red reactive dye in the scope of the patent application, the paper size of Thailand applies Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) _ Order --------- Line, member of the Ministry of Economic Affairs of the Ministry of Wisdom and Real Estate 31¾ fee printed