TW411311B - Manufacture method of recycling rubber shoe sole - Google Patents

Manufacture method of recycling rubber shoe sole Download PDF

Info

Publication number
TW411311B
TW411311B TW88114846A TW88114846A TW411311B TW 411311 B TW411311 B TW 411311B TW 88114846 A TW88114846 A TW 88114846A TW 88114846 A TW88114846 A TW 88114846A TW 411311 B TW411311 B TW 411311B
Authority
TW
Taiwan
Prior art keywords
waste
rubber
new
granular
mixing
Prior art date
Application number
TW88114846A
Other languages
Chinese (zh)
Inventor
Kuen-Jung Liou
Original Assignee
Liou Kuen Jung
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Liou Kuen Jung filed Critical Liou Kuen Jung
Priority to TW88114846A priority Critical patent/TW411311B/en
Application granted granted Critical
Publication of TW411311B publication Critical patent/TW411311B/en

Links

Landscapes

  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A manufacture method of recycling rubber shoe sole, which allows the recycling of discarded shoe sole, rubber waste produced during shoe-making and other rubber products. Rubber waste is granulated into pellets in a way that most of the physical properties of the original material is retained. The resultant pellets are mixed and blended with new rubber pellets in which a vulcanization agent is added, so that effective crosslink takes place in the blended mixture under heating and thus the product has physical properties as its original new material. Not only the production cost of rubber articles can be reduced significantly but also the waste management of the rubber industry can be solved and pollution of environment can be controlled in an optimal way by this method.

Description

B7 五、發明説明(1) 本發明係與一種橡膠鞋底材料有關,f 尺砰而言之,特 別是指一種可大量利用再生資源且可解決 么1屯問題之回收 橡膠鞋底之製造方法。 按,一般製鞋業在其生產過程中所產生廢料對環境造 成的污染問題,以及因生產方式所顯示之4 玍產效益問題, 為當前製鞋業界迫切需要解決之技術難題; ’艰τ鞋子在使 用材料上將依製程分成鞋底成型與鞋面成剖 取』兩部份,鞋底 材料有EVA、PVC.、橡膠、PU、TPR...等,宜由说咖 ~ -、甲橡勝鞋底在 製程中約產生I 5 %的廢料,在以往面臨橡膠廢料問題ρ 僅少數再生利罔將其磨成粉狀當作填充劑, 大部份以燒毁 或掩埋方式處理,這些所造成環境污染的情形八扣上 ’〆丁刀嚴重, 然至今幾乎也束手無策’且造成的材料浪費無法估叶 這些情形肇因於一般業界對橡膠廢料的特+ ^ 竹艮/又有清楚 的認識,因此未能有系統的分類 '研究分析, 了具物性亦 未能作有效的運用,致使對廢料處理方法的不當。 請參第一圖所示,首先探究橡膠鞋底之製程及其特 ,其中,該橡膠原料於目前多採用合成橡膠,而 J邊捏練作 經濟部智慧財產局員工涓費合作社印製 業係使原本堅硬的彈性橡膠原料因受熱受力變志 %年人化均勻 可塑狀'態’且該混合作業係使配合劑均勻分散於 、t碟結東 的橡膠中’再者,該配合劑係依橡膠原料種類及 八取品性能 決定成份配方,其最重要之主劑為硫化劑,其他 W令促進 劑、防陳化劑、填充劑、著色劑、軟化劑…等,,、? 此合完畢 之橡膠注入模具中硫化成型,所謂硫化係讓原本s 卞王鍵狀高 第3頁 本紙張尺度適用中國國家標準(€邓)六4说^(2】0父297公釐) 411311 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明(2 ) 分子的橡膠藉硫化劑作兩後,橡膠分子的不飽和 結、二硫結、聚硫結等互相交聯(或稱架橋)變 合的南分子橡膠聚合物,使橡膠由熱可塑性變成 如此,該橡膠性質即會變得安定且具良好彈性及 一般最常用的硫化劑為硫磺,其他有過氧化物、 物…等等,當橡膠中的硫化劑受熱達到反應溫度 有85%會產生不可逆的硫化作用,剩餘} 5%則仍 膠成品中,而這些殘留的硫化劑及部份尚未硫化 膠即為構成本發明之一關鍵技術點。 傳統以磨成粉末之方式處理橡膠廢料,會造 織斷裂,失去原有的物性,也只能當作次產品的 了 ’況且研磨的過程十分繁瑣,需消耗大量電力 有鑑於斯,本案發明人乃經詳思細索,並積. 專業研九開發經驗,終而有本發明之誕生。 即’本發明之主要目的在於提供一種回收橡 製造方法’係可有效並大量應用橡膠廢料回收資 可減少新特的使用,且達到環境保護之目的。 緣是’依據本發明.所提供之一種回收橡膠鞋 方法’係自廢棄物回收橡膠廢料,且將上述廢料 預定體積之顆粒狀廢料’促使顆粒狀廢料仍保有 物性及殘留硫化劑’再將上述顆粒狀廢料進行表 乾燥之,若硫化條件不同者則再加以塗佈接著劑 ,其中該接著劑主要為與橡膠新料同屬性之硫化 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 鏈利用硫 成網狀結 熱固性, 耐磨性, 金屬氧化 後,大約 殘留在橡 完成的橡 成硫結組 填充料罷 能源。 多年從事 膠鞋底之 源,不僅 底之製造 切製成具 原來交聯 面清潔後 後乾燥之 劑,然後 A7 B7 五、發明説明(3) 加入已捏練、混合完成的橡膠新料進行攪拌混練,顆粒狀 廢料會被均勾地被包覆在新料中,成為一新、廢料混合物 ,最後置入模具中,當其受高溫高壓硫化反應時,顆粒狀 廢料内部殘留的硫化劑會被引發出來,使原本未硫化完成 的橡膠與橡膠新料一起硫化產生交聯作用,進而重建一個 组織完好、物性更好的鞋底,待硫化完成後即可取出。 有關本發明所採用之技術、手段及其功效,茲舉二 較佳實施例並配合圖式詳細說明如后,相信本發明上述之 目的、構造及特徵,當可由之得一深入而具體的瞭解。 圖式之簡單說明: 第一圖係習用橡膠鞋底之製造流程圖。 第二圖係本發明較佳實施例之製造流程圖。 請配合參閱第二圖,本發明第一較佳實施例回收橡膠 鞋底之製造方法,大體上包含下列步驟: 一、 選用自廢棄物回收之橡膠廢料: 橡膠廢料可來自廢鞋底、製鞋過程中產生的廢料 ,或是廢橡膠輪胎,及其他橡膠製品的廢料。 二、 將上述橡膠廢料切製成具預定體積之顆粒狀廢 料: 該顆粒狀廢料仍保有其交聯組織(硫結、二硫結 、聚硫結等結構)而保有原物性,且殘留有少量 第5頁 本紙張尺度適用中國國家檩準(CNS ) A4規格(210X29?公釐) (請先閲讀背面之注意事項再填k本頁) -Φ 經濟部智慧財產局員工消費合作社印製 五、發明説明(4 ) ~^ ' ----- 的硫化劑;倘若廢料取自製鞋過程的毛邊胚料而 體積不大時’亦可不經切割直接視為顆粒使用。 三、對上述顆粒狀廢料進行表面清潔: 清潔方法可用酸鹼液以超音波清洗,或以溶劑(如 甲笨)直接清洗,以去除污垢、油潰及老化表層 四 五 將清潔過的顆粒狀廢料進行乾燥。 將乾燥完成的顆粒狀廢料加入橡膠新料中進行 攪拌混練: 該橡膠新料係已經過捏練作業、混舍配合劑(以 硫化劑為主劑)作業,攪拌混練後顆粒狀廢料會 被均勻地被包覆在新料中,成為一新、廢料混合 物。 六 置入模具内硫化成型: 經濟部智慧財產局員工消費合作社印製 可採溢壓、射出或押出等不同方式將新、廢料混 合物置入模具中’當.其受高溫高.壓硫化反應時, 顆粒狀廢料内部殘留的硫化劑會被引發出來,使 原本未硫化完成的橡膠與橡膠新料—起硫化產生 交聯作用,進而重建一個組織完好、物性更好的 鞋底,待硫化完成後即可取出。 上述製程適用於當橡膠廢料與橡膠新料之破化條件相 同時’亦即兩者的硫化劑成份、硫化反應溫度相同,倘若 兩者之硫化條件不同時’必須增加第二圖虛線所示之步顿 第6頁 錢張適用中國國家榡準(CNS )从規格(2!〇><297公瘦) 411311 A 7 B7 五、發明説明(δ ) ^ ’故本發明第二實施例整體步驟如下: 一、 選用自廢棄物回收之橡膠廢料: 橡膠廢料可來自廢鞋底、製鞋過程中產生的廢料 ’或是廢橡膠輪胎,及其他橡膠製品的廢料。 二、 將上述橡膠廢料切製成具預定體積之顆粒狀廢 料: 該顆粒狀廢料仍保有其交聯组織(硫結、二硫妗 、聚琉結等結構)而保有原物性,且殘留有少量 的硫化劑;倘若廢料取自製鞋過程的毛邊肱料而 體積不大時’亦可不經切割直接视為顆粒使用。 二、對上逆顆粒狀廢料進行表面清潔: 清沛方法可用酸驗液以超音波清洗,或以溶劑(如 甲苯)直接清洗’以去除污垢、油潰及老化表層 〇 四、 將清潔過的顆粒狀廢料進行乾燥。 五、 對清潔且乾燥完成的顆粒狀廢料塗佈接著劑: 該接著劑含有與橡膠新料屬性相同的硫化劑。 經濟部智慧財產局員工消費合作社印製 六、 將塗佈完成的顆粒狀廢料進行乾燥。 七、 將塗佈且乾燥完成的顆粒狀廢料加入橡膠新料中 進行攪拌混練: 該橡膠新料係已經過捏練作業、混合配合劑(以 硫化劑為主劑)作業,攪拌混練後顆粒狀廢料會 被均勻地被包覆在新料中,成為一新、廢料混合 第7頁 本紙浪尺度適用中國國家標CMS ) A4規格{ 210X297公楚:〉 Α7 Β7 經濟部智慧財產局員工消費合作社印製 五、發明説明 (6 ) 物 〇 : 八 > 置 入 模 具 内 硫 化 成 型 : 可 採 溢 壓 、 射 出 或 押 出 等. 不 同方 式將 新 、 廢 料 混 合 物 入 模 具 中 當 其 受 古 VJIIL 壓硫 化 反 應 時 ί 顆 粒 狀 廢 料 内 部 殘 留 的 硫 化 劑會 被引 發 出 來 使 原 本 未 硫 化 完 成 的 橡 膠 與 橡 膠新 料一 起 硫 化 產 生 交 聯 作 用 進 而 重 建 一 個 組 織完 好、 物 性 更 好 的 鞋 底 待 硫 化 完 成 後 即 可 取 出。 依 据 上 之 說 明 ) 可 知 本 發 明 之 技術 要點 如 下 1. 廢 料 製 ' J- 再 加 工 製 品 時 ,使其保有原材料之物性: 橡 膠 製 成 顆 粒 狀 仍 保 有 其 原 有 硫結 、二 石jil έ士 、 聚 硫 結 等 交 m 組 織 ,且大部份橡膠已完成硫化故保有其 原 來 物 性 0 2. 運 用 殘 留 在 廢 料 之 化 學 物 性 ; 原 不貝 粒 狀 橡 膠 廢 料 殘 留 之 硫 化 劑仍 具有 交 聯 性 i 因 、,拉 ΛΓ2. 壓 會 將 其 再 激 發 與 橡 膠新 料一 起 硫 化 4 士 合 經 再 疏 化 的 廢 料 成 為 "幾 近 完 全'硫 化的 橡 膠 新 、 廢 料 橡 膠 硫 化 結 合 後 5 其 物 性 可比 ¥新 料 橡 膠 鞋 底 更 佳 D 3. 由 於 回 收 橡 膠 廢 料 具 有 不 同 的 功能 屬性 於 加 入 橡 膠 新 料 時 可 依 成 品 的 功 能 需 求 加入 不同 物 性 比 例 的 廢 料 〇 為 驗 證 本 發 明 丨性提高之功效 ,採 用五 種 不 同 配 方 η ;8 頁 - 請 先 閱 讀 背 之 注 意 事 項 寫 本 頁 本纸張尺度適用中國國家標準(CNS ) Α4規格(2丨0X297公釐) 411313 A7 B7 發明説明(Ί) 製作鞋底後測試其耐磨性及硬度,其中耐磨測試係採德國 標準DIN53 5 1 6,硬度測試係採德國標準DIN53 505, 實驗數據採三次平均值: 配方 成份(重量比)及製程 磨耗度 腿3 硬度 shore a.c.d 1 1 〇 0 %橡膠新料,採習知 製程。 56 66 2 8 0 %橡膠新料加2 0 %橡膠 粉當填充劑,採習知製 程。 84 65 3 80%橡膠新料加20%橡膠 製鞋廢料,採本發明第 一製程。 50 64 4 8 0 %橡膠新料加2 0 %廢橡 膠輪胎胎紋面部位,採 本發明第一製程》 54 67 8 0 %橡膠新料加2 0%廢橡 膠輪胎胎側面部位,採 本發明第一製程。 5 1 64 (請先閲讀背面之注$項 『本頁) -裝. ,-=5 經濟部智慧財產局員工消费合作社印製 配方2添加橡膠粉會使成品耐磨性顯著變差,配方3 5依本發明添加顆粒狀廢料會提高成品对磨性;至於 笑則各配方差異不大a 經由以上之說明,可知本發明之廢料回收製造技術 令環境污染之降低,以及生產效益之提升將有莫大之幫 ,尤其所有橡膠製品之製程廢料以及使用後之廢料皆可 L述回收技術’再進行拆解分類後,進行回收再製,綜 >析其效益如下: (一)解決橡耀廢料所造成之環保問題。 第9頁 本纸張尺政適用中國國家標準(CNS ) A4規格(2]〇χ297公澄) 經濟部智慧財產局員工消費合作社印製 411311 _ A7 ____________B7 五、發明説明(8) (二)使用過的舊鞋子、舊輪胎也可依此技術回收。 (二)廢料生產方式簡便快速,對生產經濟效益大。 (四) 生產機械設備簡單、生產所消耗之能源少,可 降低其生產設備與能源之投資。 (五) 減少橡膠原料之使用,節省材料成本及資源。 ( ’、)可提甬部份橡膠物性,使製品可經久耐用。 猎由以上之說明可知’本發明不僅可大量利用橡膠廢 某物,並可減少新原料的使用,對於環境的保護產生極大 之助益,且極具產業上利用價值。 综上所述’本發明之技術思想確屬高度創作,同時查 遍國内外關於此類結構之技術資料、文獻中亦未發現有相 同的構造的技術存在在先,是以,本發明實已具備發明專 利要件,麦依法提出申請。 雖然本發明已關於被視為是最實同和最佳實施例來說 明’但是可瞭解的是本發明不被限制於所揭露之實施例中 ,而是用來涵蓋包括於本發明精神和最廣解釋範圍内的各 種設計,以便囊括所有此種的改良和同等設計α 第丨0買 本纸張尺度適用中國國家裙準(CNS ) Α4規格(210Χ297公釐) (請先閱讀背面之注意事項再填寫本頁)B7 V. Description of the invention (1) The present invention relates to a rubber sole material. In terms of f-foot bang, it particularly refers to a method for manufacturing a recycled rubber sole that can use a large amount of renewable resources and can solve the problem of 1 tun. According to the pollution problems caused by the waste produced by the general footwear industry in the production process, and the 4 production efficiency problems shown by the production methods, it is a technical problem that the current footwear industry urgently needs to solve; The materials used will be divided into two parts according to the manufacturing process: sole molding and upper cutting. The sole materials are EVA, PVC., Rubber, PU, TPR, etc., it should be said by the coffee ~-, nails and soles In the process, about 15% of waste is generated. In the past, it faced the problem of rubber waste. Only a few reclaimers used it as a filler, and most of them were burned or buried. They caused environmental pollution. The situation of Babao is “Severe knives are severe, but so far it is almost helpless” and the material waste caused cannot be estimated. These situations are due to the special nature of rubber waste in the general industry. Can be systematically classified 'research and analysis, the materiality has not been effectively used, resulting in improper waste disposal methods. Please refer to the first figure, first explore the manufacturing process and characteristics of rubber soles. Among them, the rubber raw material is currently mostly synthetic rubber, and J is working as an employee of the cooperative printing industry department of the Intellectual Property Bureau of the Ministry of Economic Affairs. The original hard elastic rubber raw material changes its orientation due to heat and stress. It is humanized and uniformly plasticized in the 'state', and the mixing operation is to make the compound uniformly dispersed in the rubber, and the compound is based on The type of rubber raw material and the properties of the eight ingredients determine the formulation of the ingredients. The most important main agent is the vulcanizing agent. The other W order accelerators, anti-aging agents, fillers, colorants, softeners, etc ... The finished rubber is injected into the mold and vulcanized. The so-called vulcanization system makes the original s 卞 king key shape high. Page 3 The paper size applies the Chinese national standard (€ Deng) 6 4 ^ (2) 0 parent 297 mm) 411311 Ministry of Economic Affairs Printed by the Intellectual Property Bureau employee consumer cooperative A7 B7 V. Description of the invention (2) After the molecular rubber is vulcanized as two, the unsaturated, disulfide, and polysulfide junctions of the rubber molecules are crosslinked (or bridged). The compounded South molecular rubber polymer makes the rubber from thermoplasticity to this. The properties of the rubber will become stable and have good elasticity. The most commonly used vulcanizing agent is sulfur, and other peroxides, substances, etc ... When the vulcanizing agent in the rubber reaches 85% of the reaction temperature when heated, it will produce irreversible vulcanization, and the remaining 5% is still in the finished rubber product. These residual vulcanizing agents and some of the vulcanizates have not been vulcanized. Technical point. The traditional treatment of rubber waste by grinding into powder will break the weaving and lose the original physical properties, and it can only be used as a secondary product. Moreover, the grinding process is very tedious and requires a lot of power. For this reason, the inventor of this case After careful consideration, and accumulated experience in professional research and development, finally the invention was born. That is, "the main object of the present invention is to provide a method for manufacturing recycled rubber", which can effectively and extensively use rubber waste recycling capital, reduce the use of new features, and achieve the purpose of environmental protection. The reason is that according to the present invention, a method for recovering rubber shoes is to recover rubber waste from waste, and the granular waste of a predetermined volume of the waste is used to 'promote the granular waste to retain physical properties and residual vulcanizing agent', and then the above The granular waste is surface-dried. If the vulcanization conditions are different, apply an adhesive. The adhesive is mainly vulcanized with the same properties as new rubber materials. The paper size is applicable to China National Standard (CNS) A4 specifications (210X297). C) The chain uses sulfur to form a network junction, thermosetting, abrasion resistance, and after the metal is oxidized, approximately the rubber-filled sulfur-forming junction filler material remaining in the rubber is removed. For many years, I have been engaged in the source of rubber shoe soles. Not only the manufacture of the sole is cut into the original cross-linked surface after cleaning and drying, and then A7 B7 V. Description of the invention (3) Add the new rubber material that has been kneaded and mixed and stir. The granular waste will be uniformly coated in the new material to become a new, waste mixture, and finally placed in the mold. When it is subjected to high temperature and high pressure vulcanization reaction, the vulcanizing agent remaining inside the granular waste will be triggered. Coming out, the original unvulcanized rubber is vulcanized together with the new rubber material to produce a cross-linking effect, and then a shoe with a good structure and better physical properties is rebuilt, which can be removed after vulcanization is completed. Regarding the technology, means and effects adopted by the present invention, two preferred embodiments will be described in detail with reference to the drawings. It is believed that the above-mentioned objects, structures, and characteristics of the present invention can be thoroughly and thoroughly understood. . Brief description of the drawing: The first drawing is a manufacturing flow chart of a conventional rubber sole. The second figure is a manufacturing flowchart of the preferred embodiment of the present invention. Please refer to the second figure. The manufacturing method of recycled rubber soles according to the first preferred embodiment of the present invention generally includes the following steps: 1. Selection of rubber waste recovered from waste: Rubber waste can come from waste soles and shoe making processes. Waste generated, or waste rubber tires, and other rubber products. 2. Cut the above rubber waste into granular waste with a predetermined volume: The granular waste still retains its cross-linked structure (sulphur, disulfide, polysulfide structure, etc.) and retains its original properties, with a small amount remaining Page 5 This paper size applies to China National Standards (CNS) A4 (210X29? Mm) (Please read the precautions on the back before filling in this page) -Φ Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Description of the invention (4) ~ ^ '----- vulcanizing agent; if the waste is taken from the raw material of the homemade shoe process and the volume is not large, it can also be directly used as granules without cutting. 3. Surface cleaning of the above-mentioned granular waste: The cleaning method can be ultrasonic cleaning with acid or alkali solution, or direct cleaning with solvent (such as methylbenzyl) to remove dirt, oil breakage and aging surface. The waste is dried. Add the dried granular waste material to the new rubber material for mixing and mixing: The new rubber material has been subjected to kneading operation and mixed compounding agent (based on vulcanizing agent as the main agent). After mixing, the granular waste material will be uniformly mixed. The ground is covered in new material and becomes a new, waste material mixture. Six placed in the mold vulcanization molding: The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs can print new and waste mixture into the mold in different ways, such as overflow pressure, injection or extrusion. When it is subjected to high temperature and high pressure. The residual vulcanizing agent inside the granular waste material will be triggered to make the original unvulcanized rubber and the new rubber material-play a role of cross-linking vulcanization, and then rebuild a shoe with a good structure and better physical properties, after the vulcanization is completed, Can be removed. The above process is applicable when the decomposing conditions of the rubber waste material and the new rubber material are the same, that is, the vulcanizing agent components and the vulcanization reaction temperature of the two are the same. If the vulcanization conditions of the two are different, it is necessary to increase the Buton on page 6 applies to the Chinese National Standards (CNS) from the specifications (2! 0 > < 297 male thin) 411311 A 7 B7 V. Description of the invention (δ) ^ 'The second embodiment of the present invention as a whole The steps are as follows: 1. Select the rubber waste recovered from the waste: The rubber waste can come from waste soles, waste generated during the shoe-making process, or waste rubber tires, and other rubber products. 2. Cut the above rubber waste into granular waste with a predetermined volume: The granular waste still retains its cross-linked organization (sulphur structure, disulfide structure, poly structure, etc.) and retains its original properties, and remains A small amount of vulcanizing agent; if the waste material is taken from the raw material of the self-made shoes and the volume is not large, it can also be directly used as granules without cutting. 2. Clean the surface of the upper inverse granular waste: The clear method can be cleaned by ultrasonic with acid test solution or directly washed with solvent (such as toluene) to remove dirt, oil breakage and aging surface. Granular waste is dried. V. Apply adhesive to clean and dry granular waste: This adhesive contains vulcanizing agent with the same properties as the new rubber material. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 6. Dry the coated granular waste. 7. Add the coated and dried granular waste material to the new rubber material and stir and knead: The new rubber material has been kneaded and mixed with a compounding agent (based on the vulcanizing agent). The waste material will be evenly wrapped in the new material, becoming a new, mixed waste material. Page 7 The paper scale is applicable to the Chinese national standard CMS) A4 specification {210X297 Gongchu:〉 Α7 Β7 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperative 5. Description of the invention (6) Object 0: Eight> Put into the mold for vulcanization molding: Overpressure, injection or extrusion can be used. Different ways to put new and waste materials into the mold when it is subjected to the ancient VJIIL pressure vulcanization reaction ί The vulcanizing agent remaining inside the granular waste will be triggered to vulcanize the rubber that has not been vulcanized together with the new rubber material to produce a cross-linking effect, thereby rebuilding a well-organized, better physical shoe sole after vulcanization is completed That can be taken out. According to the description above), the technical points of the present invention are as follows: 1. When made from waste materials, J- reprocessed products to retain the physical properties of the raw materials: rubber made of granules still retains its original sulfur knot, two stone jil, Polysulfide and other cross-linked structures, and most of the rubber has been vulcanized, so it retains its original physical properties. 0. Uses the chemical properties remaining in the waste; the vulcanizing agent remaining in the original granular rubber waste still has crosslinkability. ,, pull ΛΓ2. The pressure will re-excite it with the new rubber material. 4 Shihe re-dried waste material becomes " nearly completely 'vulcanized rubber new, waste rubber after vulcanization combined. 5 Its physical properties are comparable to ¥ new material. The rubber sole is better D 3. Because the recycled rubber waste has different functional properties, when adding new rubber materials, different types of waste materials can be added according to the functional requirements of the finished product. In order to verify the effectiveness of the invention, five different formulas are used. Page 8-Please read the notes on the back and write this page. The paper size is applicable to the Chinese National Standard (CNS) Α4 specification (2 丨 0X297 mm). 411313 A7 B7 Description of the invention (Ί) After making the soles, test the abrasion resistance and hardness. The abrasion test adopts the German standard DIN53 5 1 6 and the hardness test adopts the German standard DIN53 505. The average of the experimental data is three times: Formula composition (Weight ratio) and process abrasion degree 3 hardness shore acd 1 100% new rubber material, adopt the known process. 56 66 2 8 0% of new rubber material plus 20% of rubber powder as filler, adopt the known process. 84 65 3 80% rubber new material plus 20% rubber shoe waste, adopt the first process of the present invention. 50 64 4 8 0% new rubber material plus 20% waste rubber tire tread surface, using the first process of the present invention "54 67 8 0% new rubber material plus 20% waste rubber tire tire side, using the present invention First process. 5 1 64 (please read the note on the back of this page, "this page") -pack.,-= 5 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Formula 2 Addition of rubber powder will significantly worsen the abrasion resistance of the finished product. Formula 3 5 The addition of granular waste according to the present invention will improve the abrasiveness of the finished product; as for the smile, the formulas are not much differenta. From the above description, it can be known that the waste recycling manufacturing technology of the present invention will reduce environmental pollution and improve production efficiency. The great help, especially all the rubber product process waste and the used waste can be described in the recycling technology, and then disassembled and sorted, and then recycled. The comprehensive analysis of the benefits is as follows: Environmental issues caused. Page 9 This paper rule applies the Chinese National Standard (CNS) A4 specification (2) × 297 Gongcheng Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 411311 _ A7 ____________ B7 V. Description of the invention (8) (2) Use Used shoes and tires can also be recycled according to this technology. (2) The waste production method is simple and fast, and has great economic benefits to production. (4) The production machinery and equipment are simple and the energy consumed in production is low, which can reduce the investment in production equipment and energy. (5) Reduce the use of rubber raw materials and save material costs and resources. (′,) Can improve some rubber properties, so that the product can be durable. From the above description, it can be known that the present invention can not only use a large amount of waste rubber, but also reduce the use of new raw materials. It can greatly help the protection of the environment and has great industrial use value. In summary, the technical idea of the present invention is highly creative. At the same time, we have searched domestic and foreign technical data on such structures, and we have not found that the same structure technology exists in the literature. Therefore, the present invention With the elements of an invention patent, Mai filed an application in accordance with the law. Although the invention has been described in terms of what is considered to be the most similar and preferred embodiment, it is to be understood that the invention is not limited to the disclosed embodiments, but is intended to encompass the spirit and broadest scope of the invention. Explain the various designs within the scope, so as to include all such improvements and equivalent designs. Α # 丨 0 This paper size is applicable to China National Skirt Standard (CNS) Α4 specification (210 × 297 mm) (Please read the precautions on the back before (Fill in this page)

Claims (1)

411311 A8 B8 C8 D8 申請專利範圍 經濟部智慧財產局員工消費合作社印製 一種回收橡膠鞋底之製造方法,包含以下步驟: 一、 選用自廢棄物回收之橡膠廢料; 二、 將上述橡膠廢料切製成具預定體積之顆粒狀廢 料’使其保有其交聯組織而保有原物性,且殘 留有少量的硫化劑;倘若廢料取自製鞋過程的 毛邊胚料而體積不大時,亦可不經切割直接視 為顆粒使用; 二、對上述顆粒狀廢料進行表面清潔; 將清潔過的顆粒狀廢料進行乾燥; 將乾燥完成的顆粒狀廢料加入橡膠新料中進行 攪拌混練,該橡膠新料係已經過捏練作業、混 合配合劑(以硫化劑為主劑)作業,攪拌混練 後顆粒狀廢料會被均勻地被包覆在新料中,成 為一新、廢料混合物; 置入模具内硫化成型,硫化完成後即可取出。 L 一種回收橡膠鞋底之製造方法,包含以下步驟_· 一、 ia用自廢棄物回收之橡膠廢料; 二、 將上述橡膠廢料切製成具預定體積之顆粒狀廢 料,使其保有其交聯組織而保有原物性,且殘 留有少量的硫化劑;倘若廢料取自製鞋過程的 毛邊胚料而體積不大時,亦可不經切割直接視 為顆粒使用; 一、對上述顆粒狀廢料進行表面清潔.; 四 五 六 第11頁 本紙張尺度適用中國國家標準(CNS ) A4規格(210 X 297公笼) ————ο裝— t請先閲讀背面之注意事項再填寫本肓) 訂- 111311 C8 D8 六、申請專利範圍 四 . ,將 清 潔 過 的 顆 粒 狀 廢 料 進 行 乾燥 t 五, 、對 清 潔 且 乾 燥 完 成 的 顆 粒 狀 廢料 塗 佈 接 著 劑 9 該 接 著 劑 含 有 與 橡 膠 新 料 屬 性相 同 的 硫 化 劑 , 六 、將 塗佈 完 成 的 顆 粒 狀 廢 料 進 行乾 燥 J 七, 、將 塗 佈 且 乾 燥 完 成 的 顆 粒 狀廢料 加 入 橡 膠 新 料 中 進 行 攪 拌 混 練 ί 該 橡 膠 新 料係 已 經 過 捏 練 作 業 > 混 合 配 合 劑 ( 以 硫 化 劑 為主 劑 ) 作 業 攪 拌 混 練後 顆 粒 狀 廢 料 會 被 均 勻地被 包 覆 在 新 料 中 J 成 為 新 廢 料 混 合 物 ; 八. ,置 入 模 具 内 破 化 成 型 硫 化 完成 後 即 可 取 出 〇 丨丨-:丨衊— (請先聞讀背面之注意事項再填窝本頁) 3. 依據申請專利範園第1項或第2項所述之回收橡膠鞋 底之製造方法’其中該步驟三之表面清潔方法可用酸鹼液 以超音波清洗’以去除污垢、油潰及老化表層。 4. 依攄申請專利範圍第1項或第2項所述之回收橡膠 鞋底之製造方法,其中該步驟三之表面清潔方法可用溶劑 直接清洗,以去除污垢、油潰及老化表層。 訂: 經濟部中央標準局員工消費合作社印製 第12頁 本紙張尺度適用中國國家禚準(CNS ) A4規格(210X297公釐)411311 A8 B8 C8 D8 Patent application scope Intellectual Property Bureau of the Ministry of Economic Affairs employee consumer cooperative prints a manufacturing method of recycled rubber soles, including the following steps: 1. Selecting rubber waste recovered from waste; 2. Cutting the rubber waste into the above Granular waste with a predetermined volume 'enables it to retain its cross-linked structure and retain its original properties, and a small amount of vulcanizing agent remains; if the waste is taken from the raw material of the homemade shoe and the volume is not large, it can also be directly cut without cutting Treated as granules; 2. Surface cleaning of the above granular wastes; drying the cleaned granular wastes; adding the dried granular wastes to a new rubber material for mixing and kneading, the new rubber material has been kneaded Practice operation, mixing compounding agent (mainly vulcanizing agent) operation, after mixing, the granular waste will be evenly covered in new material to become a new, waste mixture; put into the mold to vulcanize and complete the vulcanization Then you can remove it. L A method for manufacturing recycled rubber soles, including the following steps: 1. ia rubber waste recovered from waste; 2. cutting the rubber waste into granular waste with a predetermined volume to keep its cross-linked organization It retains the original properties and has a small amount of vulcanizing agent. If the waste material is made of raw material of the homemade shoe process and the volume is not large, it can also be directly used as granules without cutting. 1. Surface cleaning of the granular waste material .; Page 4 of 556. The paper size applies to Chinese National Standard (CNS) A4 specification (210 X 297 male cage) ———— ο installed— tPlease read the notes on the back before filling in this card) Order-111311 C8 D8 VI. Application for patent scope 4. Dry the cleaned granular waste t 5. Apply the adhesive to the cleaned and dried granular waste 9 The adhesive contains vulcanizing agent with the same properties as the new rubber material , 6. Dry the coated granular waste J. 7. The dried granular waste is added to the new rubber material for mixing and mixing. This new rubber material has been kneaded. ≫ Mixing compounding agent (based on vulcanizing agent) After mixing and mixing, the granular waste will be uniformly treated. Wrapped in the new material J becomes the new waste mixture; 8. Put it into the mold, and it can be taken out after the curing and vulcanization is completed. 丨 丨-: 丨 蔑 — (Please read the precautions on the back before filling the page. ) 3. According to the method for manufacturing recycled rubber soles described in item 1 or 2 of the patent application park, 'where the surface cleaning method in step 3 can be performed by ultrasonic cleaning with acid and alkali solution' to remove dirt, oil breakage and aging surface layer. 4. According to the method for manufacturing recycled rubber soles described in item 1 or 2 of the scope of patent application, the surface cleaning method in step 3 can be directly cleaned with a solvent to remove dirt, oil breakage and aging surface layers. Revision: Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs Page 12 This paper size applies to China National Standard (CNS) A4 (210X297 mm)
TW88114846A 1999-08-30 1999-08-30 Manufacture method of recycling rubber shoe sole TW411311B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
TW88114846A TW411311B (en) 1999-08-30 1999-08-30 Manufacture method of recycling rubber shoe sole

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
TW88114846A TW411311B (en) 1999-08-30 1999-08-30 Manufacture method of recycling rubber shoe sole

Publications (1)

Publication Number Publication Date
TW411311B true TW411311B (en) 2000-11-11

Family

ID=21642104

Family Applications (1)

Application Number Title Priority Date Filing Date
TW88114846A TW411311B (en) 1999-08-30 1999-08-30 Manufacture method of recycling rubber shoe sole

Country Status (1)

Country Link
TW (1) TW411311B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI642490B (en) * 2017-06-30 2018-12-01 楊婇琳 Shoe cleaning and drying device
CN113844077A (en) * 2021-07-28 2021-12-28 福建智铭鞋业有限公司 Method for preparing shoe material by using waste EVA

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI642490B (en) * 2017-06-30 2018-12-01 楊婇琳 Shoe cleaning and drying device
CN113844077A (en) * 2021-07-28 2021-12-28 福建智铭鞋业有限公司 Method for preparing shoe material by using waste EVA

Similar Documents

Publication Publication Date Title
US4244841A (en) Method for recycling rubber and recycled rubber product
CN102190812B (en) Preparation method for environmental-friendly reclaimed rubber
TW411311B (en) Manufacture method of recycling rubber shoe sole
CN107236188A (en) A kind of modified waste rubber powder and pp intermingling materials and preparation method thereof
CN105602036A (en) Acrylonitrile-butadiene rubber powder and preparation method thereof
JP3638872B2 (en) Artificial turf recycling method and materials
CN105968460A (en) Method for preparing rubber by using onion essential oil as rubber regenerant
CN105949503B (en) A kind of environment-friendly type active hydrogenation butadiene-acrylonitrile-rubber vulcanized rubber powder and preparation method thereof
EP3562874B1 (en) Method of recycling rubber
CN104017223B (en) A kind of preparation method of sulfhydryl-lignin for regenerating waste or used rubber
CN101879786A (en) Method of making environment-friendly sole by waste shoe
CN108638549A (en) A kind of production technology of solid tyre
KR100424424B1 (en) Regeneration method of useless polyurethan resin
CN1032819C (en) Regeneration method of waste sulphurated rubber by chemical plasticizing machinery
TW406043B (en) The manufacture method of the recycled-rubber tire
JP4880129B2 (en) Injection molding boots recycling method
CN110577665A (en) reprocessed rubber and process for producing the same
CN216001164U (en) Rubber flat plate manufactured based on vulcanized rubber powder and footpath for body building
CN104017239B (en) A kind of preparation method of sulfhydryl modified activated carbon for regenerating waste or used rubber
KR20040018759A (en) Elastic block comprising waste block and waste ruber chips
Coran Vulcanization
CN108285563A (en) A kind of preparation method of compliant rubber powder
DE102018203965A1 (en) Method for permanently bonding vulcanised rubber components and vehicle tires
GB580051A (en) Improvements in or relating to the reclaiming of vulcanised synthetic rubber-like material
KR20130011226A (en) Manufacturing method of producing a regeneration rubber using waste synthetic rubber