TW408489B - The manufacture method of DRAM - Google Patents
The manufacture method of DRAM Download PDFInfo
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- TW408489B TW408489B TW088108041A TW88108041A TW408489B TW 408489 B TW408489 B TW 408489B TW 088108041 A TW088108041 A TW 088108041A TW 88108041 A TW88108041 A TW 88108041A TW 408489 B TW408489 B TW 408489B
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- 238000000034 method Methods 0.000 title claims abstract description 68
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 44
- 239000004020 conductor Substances 0.000 claims abstract description 79
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- 230000005669 field effect Effects 0.000 claims abstract description 13
- 238000000059 patterning Methods 0.000 claims abstract 6
- 229910052751 metal Inorganic materials 0.000 claims description 61
- 239000002184 metal Substances 0.000 claims description 61
- 230000004888 barrier function Effects 0.000 claims description 49
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 33
- 229920002120 photoresistant polymer Polymers 0.000 claims description 28
- 239000000463 material Substances 0.000 claims description 23
- 238000005530 etching Methods 0.000 claims description 21
- 229910021417 amorphous silicon Inorganic materials 0.000 claims description 16
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 14
- 229910052710 silicon Inorganic materials 0.000 claims description 13
- 239000010703 silicon Substances 0.000 claims description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 12
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 claims description 11
- 229910021332 silicide Inorganic materials 0.000 claims description 11
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims description 11
- 230000002079 cooperative effect Effects 0.000 claims description 10
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 238000007639 printing Methods 0.000 claims description 2
- PCTMTFRHKVHKIS-BMFZQQSSSA-N (1s,3r,4e,6e,8e,10e,12e,14e,16e,18s,19r,20r,21s,25r,27r,30r,31r,33s,35r,37s,38r)-3-[(2r,3s,4s,5s,6r)-4-amino-3,5-dihydroxy-6-methyloxan-2-yl]oxy-19,25,27,30,31,33,35,37-octahydroxy-18,20,21-trimethyl-23-oxo-22,39-dioxabicyclo[33.3.1]nonatriaconta-4,6,8,10 Chemical compound C1C=C2C[C@@H](OS(O)(=O)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2.O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C=C/C=C/C=C/[C@H](C)[C@@H](O)[C@@H](C)[C@H](C)OC(=O)C[C@H](O)C[C@H](O)CC[C@@H](O)[C@H](O)C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 PCTMTFRHKVHKIS-BMFZQQSSSA-N 0.000 claims 2
- 239000003990 capacitor Substances 0.000 abstract description 38
- 239000003989 dielectric material Substances 0.000 abstract 7
- 239000010410 layer Substances 0.000 description 246
- 229910052581 Si3N4 Inorganic materials 0.000 description 13
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 13
- 238000003860 storage Methods 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
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- 125000006850 spacer group Chemical group 0.000 description 5
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- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 238000001459 lithography Methods 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
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- 229910052770 Uranium Inorganic materials 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 3
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- 238000001039 wet etching Methods 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910004205 SiNX Inorganic materials 0.000 description 1
- 229910008814 WSi2 Inorganic materials 0.000 description 1
- QSQSQJSJMSMRCA-UHFFFAOYSA-N [N].O=[Si]=O Chemical compound [N].O=[Si]=O QSQSQJSJMSMRCA-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
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- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
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- 229910021341 titanium silicide Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
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- Semiconductor Memories (AREA)
Abstract
Description
4445twf.d〇c/00 經濟部智慧財產局員工消費合作社印製 P8489 at B7 五、發明説明(I ) 本發明是有關於一種積體電路的製造方法,且特別是 有關於一種動態隨機存取記憶體(Dynamic Random Access Memory,DRAM)的製造方法。 當電腦微處理器功能逐漸增強、軟體所進行的程式.與 .運算愈來愈龐大時,記憶體的電容需求也就愈來愈高。而 .隨著動態隨機存取記憶體積集度的增加,目前所發展之記 憶胞係由一個轉移場效電晶體與一個儲存電容器所構 成。 由於電容器爲DRAM藉以儲存訊號的心臟部位,當電 容器所儲存的電荷愈多,讀出放大器在讀取資料時受雜訊 的影響也就愈小。通常用以增加儲存電荷能力的方法可以 藉由增加電容器的面積、使用高介電常數的介電膜層、或 是減少介電膜層的厚度以達到目的。 目前已發展的高介電常數之介電膜層有五氧化二钽 (Ta205 )、Pb(Zr,Ti)03’即 PZT 以及(Ba,Sr)Ti03,即 BST。 而增加電容器表面積的方法則隨著積體電路元件的高度 積集化,已需要利用三度空間的電容器來實現,例如所謂 的堆疊型(Stacked Type)或溝槽型(Trench Type)電容 器。而在目前更爲高度積集化的記憶體元件中,例如,64M 位元容量的DRAM,則是將電容器的電極與介電膜層向水 平延伸,並且向上堆疊而形成所謂的鰭型(Fin Type)的 堆疊電容器,或是將電容器的電極與介電膜層延伸成垂直 狀結構,而形成所謂的柱型(Cylindrical Type)堆疊電容 器以達成增加電容量之目的。 本紙張尺度適用中國國家標準(CNS ) A4規格(2I0X297公釐) (請先聞讀背面之注意事項再填寫本f4445twf.d〇c / 00 P8489 at B7 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the Invention (I) The present invention relates to a method for manufacturing integrated circuits, and more particularly to a dynamic random access Manufacturing method of memory (Dynamic Random Access Memory, DRAM). As the functions of computer microprocessors gradually increase and the programs and calculations performed by software become more and more large, the capacitance requirements of memory will become higher and higher. With the increase of the dynamic random access memory volume concentration, the currently developed memory cell system consists of a transfer field effect transistor and a storage capacitor. Since the capacitor is the heart of the DRAM where the signal is stored, the more charge the capacitor stores, the less the sense amplifier will be affected by noise when reading data. The methods generally used to increase the charge storage capacity can be achieved by increasing the area of the capacitor, using a dielectric film layer with a high dielectric constant, or reducing the thickness of the dielectric film layer. Currently developed dielectric films with high dielectric constants include tantalum pentoxide (Ta205), Pb (Zr, Ti) 03 ', PZT and (Ba, Sr) Ti03, BST. The method of increasing the surface area of the capacitors is accompanied by the high accumulation of integrated circuit components, which has been required to use three-dimensional capacitors, such as the so-called Stacked Type or Trench Type capacitors. In today's more highly integrated memory devices, for example, DRAM with a capacity of 64M bits, the electrodes of the capacitor and the dielectric film layer are extended horizontally and stacked up to form a so-called fin type (Fin Type) stacked capacitors, or the electrodes and dielectric film layers of the capacitors are extended into a vertical structure to form a so-called cylindrical type stacked capacitor to achieve the purpose of increasing capacitance. This paper size is applicable to Chinese National Standard (CNS) A4 (2I0X297mm) (Please read the precautions on the back before filling in this f
4 4 4 5 t wf . d> i/^2489 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明(1) 第1圖爲習知一種柱狀電容器之動態隨機存取記憶體 的剖面圖。動態隨機存取記憶體之電容器的製作’係在已' 形成隔離區102的基底100上形成場效電晶體104’之後,' 先在基底1⑻上覆蓋一層介電層110 ’並在介電層U0中 形成裸露出源極/汲極區108的接觸窗開口 112。其後,再. 於基底1〇〇上形成一層非晶矽層114 ’以覆蓋介電層110 之表面並將接觸窗開口 112塡滿。接著’以微影成像與貪虫4 4 4 5 t wf. D > i / ^ 2489 A7 B7 Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (1) Figure 1 shows the dynamic random access memory of a cylindrical capacitor. Sectional view. The fabrication of a capacitor for a dynamic random access memory is 'formed after a field effect transistor 104' is formed on a substrate 100 having an isolation region 102 formed thereon, 'and a substrate 110 is first covered with a dielectric layer 110' and a dielectric layer is formed. A contact window opening 112 is formed in U0 to expose the source / drain regions 108. Thereafter, an amorphous silicon layer 114 'is formed on the substrate 100 to cover the surface of the dielectric layer 110 and fill the contact window opening 112. Next ’lithography and the worm
\ I 刻程序定義覆蓋於介電層no上方之導體層114的圖案, 以作爲電容器之下電極主體結構。其後,再於定義後的非 晶矽層114上形成選擇性半球型矽晶粒(HSG)(未繪示. 出),以增加下電極的表面積’接著再覆蓋一層介電層膜 116與另一層複晶矽層118,以作爲電容器之上電極。 爲了因應目前高密度之動態隨機存取記憶體的需求, 習知的作法係增加上述之非晶矽層114的厚度,以藉由厚 度的增加來增加下電極的表面積’提昇電容器的電荷儲存 里。 然而,非晶矽的沉積速率非常低,以目前所製作的動 態隨機存取記憶體爲例,非晶矽層Π4的厚度高達8000 埃,沉積非晶矽層114必須長達16小時以上。因此,以 增加非晶矽層Π4的厚度來達到提昇儲存電容的方式,不 但會耗費較長的沉積時間,減少製造的產能 (Throughput),而且易會使得爐管的操作成本提高。此外, 過厚的非晶矽層114其在定義圖案的過程中,則會增加蝕 刻的困難度。 本紙張尺度適用中國國家標準(CNS ) A4规格(210X297公釐) -β in (請先聞讀背面之注意事項再填寫本頁)The I-cut procedure defines the pattern of the conductor layer 114 overlying the dielectric layer no as the main structure of the electrode under the capacitor. Thereafter, a selective hemispherical silicon grain (HSG) (not shown.) Is formed on the defined amorphous silicon layer 114 to increase the surface area of the lower electrode, and then a dielectric layer film 116 and Another polycrystalline silicon layer 118 is used as an electrode on the capacitor. In order to cope with the current demand for high-density dynamic random access memory, a conventional method is to increase the thickness of the above-mentioned amorphous silicon layer 114 to increase the surface area of the lower electrode by increasing the thickness, thereby increasing the charge storage of the capacitor. . However, the deposition rate of amorphous silicon is very low. For example, the currently manufactured dynamic random access memory has a thickness of 8000 angstroms and the amorphous silicon layer 114 must be deposited for more than 16 hours. Therefore, increasing the thickness of the amorphous silicon layer Π4 to increase the storage capacitance will not only take a long time to deposit, reduce manufacturing throughput, but also easily increase the operation cost of the furnace tube. In addition, the excessively thick amorphous silicon layer 114 may increase the difficulty of etching during the process of defining the pattern. This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm)-β in (Please read the precautions on the back before filling this page)
ς 408489 Α7 4445twf . doc/002 .........Β7_____ 五、發明説明(,) 緣此,本發明提供一種動態隨機存取記憶體的製造 法,可以增加電容器的儲存電容量。 本發明提供一種動態隨機存取記憶體的製造法’可以 增加電容器之下電極的表面積,以提昇電容器的儲存電容 •量。 本發明提供一種動態隨機存取記憶體製造法’可以減 少製造的時間,提高製造的產能。 本發明提供一種動態隨機存取記憶體的製造法’可以 減少爐管的操作成本。 本發明提出一種動態隨機存取記憶體之電容器的製造 方法,此方法之簡述如下:在已形成場效電晶體的基底上 形成一層介電層,並在介電層中形成裸露出源極/汲極區的 接觸窗開口,其後在基底上覆蓋一層厚度足以將介層窗開 口塡滿的導體層,接著,再定義導體層,並去除未被圖案 化之導體層覆蓋之介電層的一部份,使介電層中彫成一個 環繞導體層的凹槽,然後,在凹槽的側壁以及位於介電層 上方之導體層的側壁形成導體間隙壁’以使其與上述之導 體層共組電容器之下電極主體架構。接著再於上述之導體 層與導體間隙壁形成一層介電膜層與另一層導體層。 依照本發明實施例所述,上述定義導體層以及在介電 層中形成一個環繞導體層的凹槽的步驟,係在導體層上形 成一層氮化矽與一層光阻層,之後’先將氮化矽層與光阻 層圖案化,再以氮化矽爲蝕刻的硬罩幕層,蝕刻導體層與 介電層,然後,再將氮化矽層與光阻層去除。 5 本紙張尺度適用中國國家標準(C.NS ) M規格(210><297公釐) (諳先聞讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製 經濟部智慧財產局員工消費合作社印製 4445twf.d〇c/002 A/ _._ B7 __ — 五、發明説明(f) 由於氮化矽層與導體層之間以及與介電層之間均具有 良好的蝕刻選擇比,可以在触刻的程序中作爲硬罩幕層, 所以,本發明並不需要形成過厚的光阻層,因此,可以避 免光阻層過厚所衍生的問題。 而且,上述之導體層與導體間隙壁之厚度很薄,用於 非晶矽下電極的製作非常適合,可以減少沉積多晶矽層的 時間、增加產能、並且可以降低爐管的操作成本。 此外,上述之方法可以在導體層與導體間隙壁所架構 之下電極主體上形成半球型矽晶粒層,以增加下電極的表 面積,進而提昇電容器之儲存電容。 本發明提出另一種動態隨機存取記憶體之電容器的製 造方法,此方法之簡述如下:在已形成場效電晶體的基底 上形成一層介電層,並在介電層中形成裸露出磾極/汲極區 的接觸窗開口。其後,在基底上覆蓋一層厚度足以將介層 窗開口塡滿的複晶矽層,再於複晶矽層上形成第一阻障層 與第一金屬層。接著,定義複晶矽層、第一阻障層與第一 金屬層。其後,將未被第一金屬層覆蓋的介電層部分去 除,以在介電層中形成一個環繞複晶矽層的凹槽。然後, 在基底上形成第二阻障層與第二金屬層,並進行回蝕刻程 序,以在複晶矽層、第一阻障層、第一金屬層與凹槽之側 壁形成一導體間隙壁。接著,在第一金屬層與體間隙壁上 形成一層介電膜層,並於介電膜層上覆蓋一層導體層。 依照本發明實施例所述,上述定義複晶矽層、第一阻 障層與第一金屬層以及在介電層中形成一個環繞複晶矽 6 本紙張尺度適用中國國家標準(CNS > A4規格(210X297公釐> (請先聞讀背面之注$項再填寫本頁)ς 408489 Α7 4445twf. doc / 002 ......... B7_____ 5. Description of the Invention (,) Therefore, the present invention provides a method for manufacturing a dynamic random access memory, which can increase the storage capacity of a capacitor. The present invention provides a method for manufacturing a dynamic random access memory, which can increase the surface area of the electrodes under the capacitor to increase the storage capacity of the capacitor. The present invention provides a method for manufacturing a dynamic random access memory, which can reduce manufacturing time and increase manufacturing capacity. The present invention provides a method for manufacturing a dynamic random access memory, which can reduce the operation cost of the furnace tube. The present invention provides a method for manufacturing a capacitor of a dynamic random access memory. The method is briefly described as follows: a dielectric layer is formed on the substrate on which a field effect transistor has been formed, and an exposed source electrode is formed in the dielectric layer. / Drain region contact window opening, then cover the substrate with a conductive layer thick enough to fill the dielectric window opening, and then define the conductor layer and remove the dielectric layer not covered by the patterned conductor layer A part of the dielectric layer is engraved with a groove surrounding the conductor layer, and then a conductor gap wall is formed on the side wall of the groove and the side wall of the conductor layer above the dielectric layer so that it is in line with the above conductor. The electrode body structure under the layer group capacitor. Then, a dielectric film layer and another conductor layer are formed on the above-mentioned conductor layer and the conductor gap wall. According to the embodiment of the present invention, the steps of defining the conductor layer and forming a groove surrounding the conductor layer in the dielectric layer are to form a layer of silicon nitride and a photoresist layer on the conductor layer, and then 'the nitrogen The silicon layer and the photoresist layer are patterned, and then the silicon nitride is used as an etching hard mask layer, the conductor layer and the dielectric layer are etched, and then the silicon nitride layer and the photoresist layer are removed. 5 This paper size applies the Chinese National Standard (C.NS) M specification (210 > < 297 mm) (谙 Please read the notes on the back before filling out this page) Order the Intellectual Property Bureau of the Ministry of Economic Affairs and the Consumer Cooperatives to print the economy Printed by the Consumer Cooperatives of the Ministry of Intellectual Property Bureau 4445twf.d〇c / 002 A / _._ B7 __ — V. Description of the invention (f) Because the silicon nitride layer and the conductor layer and between the dielectric layer have A good etching selection ratio can be used as a hard mask curtain layer in the etching process. Therefore, the present invention does not need to form an excessively thick photoresist layer, and therefore, problems caused by excessively thick photoresist layers can be avoided. In addition, the thickness of the above-mentioned conductor layer and the conductor gap wall is very thin, which is very suitable for the fabrication of the electrodes under the amorphous silicon, which can reduce the time for depositing the polycrystalline silicon layer, increase the production capacity, and reduce the operation cost of the furnace tube. In addition, the above method can form a hemispherical silicon grain layer on the electrode body under the conductor layer and the conductor gap wall to increase the surface area of the lower electrode, thereby improving the storage capacity of the capacitor. The present invention proposes another method for manufacturing a capacitor of a dynamic random access memory. A brief description of this method is as follows: a dielectric layer is formed on a substrate on which a field effect transistor has been formed, and an exposed layer is formed in the dielectric layer. Contact window opening in the pole / drain region. Thereafter, a polycrystalline silicon layer is coated on the substrate to a thickness sufficient to fill the openings of the interlayer window, and a first barrier layer and a first metal layer are formed on the polycrystalline silicon layer. Next, a polycrystalline silicon layer, a first barrier layer and a first metal layer are defined. Thereafter, the portion of the dielectric layer not covered by the first metal layer is removed to form a groove in the dielectric layer surrounding the polycrystalline silicon layer. Then, a second barrier layer and a second metal layer are formed on the substrate, and an etch-back process is performed to form a conductor gap wall on the polycrystalline silicon layer, the first barrier layer, the first metal layer and the sidewall of the groove. . Next, a dielectric film layer is formed on the first metal layer and the bulk gap wall, and a conductive layer is covered on the dielectric film layer. According to the embodiment of the present invention, the above-mentioned definition of the polycrystalline silicon layer, the first barrier layer and the first metal layer, and the formation of a surrounding polycrystalline silicon in the dielectric layer 6 The paper size is applicable to Chinese national standards (CNS > A4 Specifications (210X297mm > (Please read the note on the back before filling in this page)
A7 B7 五、發明説明(會) 層的凹槽的步驟,係在第一金屬層上形成一層氮化矽與一 層光阻層,之後,先將氮化矽層與光阻層圖案化’再以其 爲鈾刻罩幕,蝕刻第一金屬層、第一阻障層、複晶矽層與 介電層,然後,再將氮化矽層與光阻層去除。 由於氮化矽層與第一金屬層、第一阻障層、複晶彳夕層 之間以及與介電層之間均具有良好的蝕刻選擇比’可以在 鈾刻的程序中作爲硬罩幕層,所以,本發明並不需要形成 過厚的光阻層,因此,可以避免光阻層過厚所衍生的問 題。 而且依照本發明實施例所述,上述方法可以使用二氧 化釕作爲下電極,以提昇電容器之效能,而且由於接觸窗 開口中係塡入複晶矽,因此,可以避免金屬層與源極/汲極 區接觸所衍生的漏電現象。此外,本發明可以使用具有高 介電常數的介電膜層,包括五氧化二钽、BST與PZT ’以 增加電容器之儲存電容。 爲讓本發明之上述目的、特徵、和優點能更明顯易懂, 下文特舉較佳實施例,並配合所附圖式,作詳細說明如 下: 圖式之簡單說明= 第1圖爲習知一種柱狀電容器之動態隨機存取記憶體 兀件的剖面圖, 第2A圖至第2E圖,其繪示依照本發明第一較佳實施 例之一種動態隨機存取記憶體的製造流程剖面圖;以及 第.3A圖至第3G圖,其繪示依照本發明第二較佳貫施 (請先聞讀背面之注意事項再填寫本買)A7 B7 5. The step of the invention description (meeting) layer is to form a layer of silicon nitride and a photoresist layer on the first metal layer. After that, first pattern the silicon nitride layer and the photoresist layer. Using it as a uranium mask, the first metal layer, the first barrier layer, the polycrystalline silicon layer and the dielectric layer are etched, and then the silicon nitride layer and the photoresist layer are removed. Since the silicon nitride layer has a good etching selection ratio between the first metal layer, the first barrier layer, the polycrystalline silicon layer, and the dielectric layer, it can be used as a hard mask in the uranium etching process Therefore, the present invention does not need to form an excessively thick photoresist layer, and therefore, the problems caused by excessively thick photoresist layers can be avoided. Furthermore, according to the embodiment of the present invention, the above method can use ruthenium dioxide as the lower electrode to improve the performance of the capacitor, and because the polycrystalline silicon is implanted in the opening of the contact window, the metal layer and the source / drain can be avoided. Leakage from pole contact. In addition, the present invention can use a dielectric film layer having a high dielectric constant, including tantalum pentoxide, BST, and PZT 'to increase the storage capacity of the capacitor. In order to make the above-mentioned objects, features, and advantages of the present invention more comprehensible, the preferred embodiments are described below in detail with the accompanying drawings as follows: A brief description of the drawings = FIG. 1 is known Cross-sectional view of a dynamic random access memory element of a columnar capacitor, FIG. 2A to FIG. 2E, which are cross-sectional views illustrating a manufacturing process of a dynamic random access memory according to the first preferred embodiment of the present invention ; And Figures .3A to 3G, which show the second best practice according to the present invention (please read the precautions on the back before filling in this purchase)
T Η 經濟部智慧財產局員工消費合作社印製 4 4 4 5 twf doc/002 . A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明(A )例之一種動態隨機存.取記憶體的製造流程剖面圖。圖式標記說明: 100、200、300 基底 102、202、302 隔離區 104、204、304 場效電晶體 108 ' 208 源極/汲極區 110' 210 ' 310 介電層 112、212、312 接觸窗開口 114 非晶矽層 116、234、334 介電膜層 118 ' 314 複晶砂層 206 閘極 214、236、336 導體層 220、320 硬罩幕層 222、322 光阻層 223 ' 323 凹槽 230、330 導體間隙壁 23 2 半球型砂晶粒層 315 金屬矽化物層 316、324 阻障層 318、326 金屬層 實施例一請參照第2A圖至第2F圖,其繪示依照本發明一較佳 實施例的一種柱狀電容器之動態隨機存取記憶體的製造 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CMS ) A4規格(210X297公釐)T 印 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 4 4 4 5 twf doc / 002. A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. A description of the invention (A), a kind of dynamic random storage. Sectional view of the manufacturing process. Description of graphical symbols: 100, 200, 300 substrates 102, 202, 302 isolation regions 104, 204, 304 field effect transistors 108 '208 source / drain regions 110' 210 '310 dielectric layers 112, 212, 312 contact Window opening 114 Amorphous silicon layer 116, 234, 334 Dielectric film layer 118 '314 Complex crystal sand layer 206 Gate 214, 236, 336 Conductor layer 220, 320 Hard cover curtain layer 222, 322 Photoresist layer 223' 323 Groove 230, 330 Conductor gap wall 23 2 Hemispherical sand grain layer 315 Metal silicide layer 316, 324 Barrier layer 318, 326 Metal layer Example 1 Please refer to FIGS. 2A to 2F, which shows a comparison according to the present invention. Manufacturing of a kind of columnar capacitor dynamic random access memory in the preferred embodiment (please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CMS) A4 specification (210X297 mm)
4 4 5 twf . do I 錄84 8g /002 A7 B7 五、發明説明(q) 流程剖面圖。 首先,請參照第2A圖’在棊底200表面,例如是p 型矽基底,形成隔離區202以定義元件之主動區,續再於 主動區上形成動態隨機存取記憶體的場效電晶體2〇4與位 .元線(未繪示出)。隔離區202的形成方法例如爲淺溝渠隔 離法(STI)或是局部區域氧化法(LOCOS)。場效電晶體204 包括閘極206以及源極/汲極區208。閘極206可例如由厚 度分別約爲100埃、1000埃、1000埃以及1〇〇〇埃的閘極 氧化層、摻雜複晶砍層、矽化金屬層,例如,砂化鎢(WSi2 ) 以及頂蓋層,例如’氮化矽(SiNx)所組成。此外,在閘 極206之側壁形成有間隙壁,其材質包括氮化矽,形成的 方法可以在基底200上沈積厚度約爲1500埃的氮化矽 層,續再進行回蝕刻以製備之。 接著,請繼續參照第2A圖,在基底200上形成一層介 電層210,其厚度約爲3微米。介電層210之材質例如是 化學氣相沉積法沉積之氧化矽、硼磷矽玻離(BPSG)、或是 以塗佈方式形成之旋塗式玻璃(SOG)。之後,再以化學機 械硏磨法(CMP)將介電層210平坦化,使介電層210具有 較爲平坦的表面,以利後續製程的進行,平坦後之介電層 210的厚度距離位元線約爲2微米左右。 接著,請參照第2B圖,以微影成像與蝕刻程序定義介 電層210,以在介電層210中形成裸露出源極/汲極區208 的接觸窗開口 212。然後,於基底200上形成一層厚度足 以將接觸窗開口 212塡滿的導體層214 ’使其與源極/汲極 9 ^^1適用中國國家標準(€邶)八4規格(210乂297公釐厂 ' (請先聞讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工湞費合作社印製 _48d A7 4445twf . doc/002 __ B7__ 五、發明説明(?) 區208耦接。導體層214之材質例如爲具有摻雜的複晶矽 或非晶矽,其形成的方法例如爲化學氣相沉積法’厚度約 爲1000埃至3000埃。接著,在導體層214上形成一層硬 罩幕層220與一層光阻層222。硬罩幕層22〇之材質係與 .介電層210以及導體層214具有良好之蝕刻選擇比者,其 料睹苞仆访,联命的方法例如爲化學氣相沉積法, (請先閲讀背面之注也 4 4 4 5 twf . doc /〇 〇 2 經濟部智慧財產局員工消費合作社印製 五、發明説明(7) 於基底200上,之後,進行回蝕刻程序,使留在導體層214 以及凹槽223側壁的複晶矽層或非晶矽層形成上述之導體 間隙壁230 ° 然後,請參照第2E圖,去除硬罩幕層22〇 ’以裸露出 .由導體層214以及導體間隙壁230所架構之下電極主體。 去除硬罩幕層220的方式包括濕式蝕刻法,例如是以熱磷 酸爲蝕刻溶液。接著,在導體層以及導體間隙壁230 的表面上形成一層半球型矽晶粒(Hemispherical-Grained Silicon,HSG-Si)層232,以增加下電極的表面積’提昇 電容器的儲存電容。半球型砂晶粒層232的形成方式可以 以化學氣相沉積法,或是以選擇性半球型矽晶粒的技術形 成之。 由於本發明之導體層214其厚度可以縮減至將接觸窗 開口 212塡滿即可,而且製作導體間隙壁230所需的厚度 亦不需太厚,因此本發明非常適合於非晶矽下電極的製 作,可以減少沉積非晶砂層的時間、增加產能、並且可以 降低爐管的操作成本。 此外,由於導體間隙壁230係以回蝕刻的方式形成, 而不需要以典型的微影成像與蝕刻程序定義其圖案,因此 可以減少製程的困難度與成本,並且可以避免導體層的厚 度過厚,在蝕刻的過程中容易斷裂的問題。 最後,請繼續參照第2E圖,在半球型矽晶粒層232 上形成一層介電膜層與另一層導體層236 ^介電膜層 234之材質例如爲氧化矽層、氮化矽餍/氧化矽層(N〇)結 (請先閲讀背面之注意事項再填寫本頁) -7^· 訂 114 4 5 twf. Do I Record 84 8g / 002 A7 B7 V. Description of the invention (q) Process sectional view. First, please refer to FIG. 2A. On the surface of the substrate 200, for example, a p-type silicon substrate, an isolation region 202 is formed to define an active region of the device. Then, a field effect transistor of a dynamic random access memory is formed on the active region. 204 and bit line (not shown). The isolation region 202 is formed by, for example, a shallow trench isolation (STI) method or a local area oxidation method (LOCOS). The field effect transistor 204 includes a gate electrode 206 and a source / drain region 208. The gate electrode 206 may be, for example, a gate oxide layer, a doped polycrystalline layer, a silicided metal layer, such as tungsten alumina (WSi2), and a thickness of about 100 Angstroms, 1000 Angstroms, 1000 Angstroms, and 1000 Angstroms, respectively. The capping layer is composed of, for example, silicon nitride (SiNx). In addition, a gap wall is formed on the sidewall of the gate electrode 206, and the material thereof includes silicon nitride. The formation method can deposit a silicon nitride layer with a thickness of about 1500 angstroms on the substrate 200, and then perform etch-back to prepare it. Next, referring to FIG. 2A, a dielectric layer 210 is formed on the substrate 200 with a thickness of about 3 μm. The material of the dielectric layer 210 is, for example, silicon oxide deposited by chemical vapor deposition, borophospho-silicon glass separation (BPSG), or spin-on-glass (SOG) formed by coating. After that, the dielectric layer 210 is planarized by a chemical mechanical honing method (CMP), so that the dielectric layer 210 has a relatively flat surface, so as to facilitate subsequent processes. The element line is about 2 microns. Next, referring to FIG. 2B, a dielectric layer 210 is defined by a lithography imaging and etching process to form a contact window opening 212 in the dielectric layer 210 to expose the source / drain regions 208. Then, a conductive layer 214 'is formed on the substrate 200 with a thickness sufficient to fill the contact window opening 212 with the source / drain electrode 9 ^^ 1. Applicable to the Chinese National Standard (€ 邶) 8 4 specifications (210 乂 297 mm) Li Factory '(Please read the precautions on the back before filling this page) Order printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and printed by the co-operative cooperative _48d A7 4445twf. Doc / 002 __ B7__ V. Description of the invention (?) Area 208 coupling The material of the conductor layer 214 is, for example, doped polycrystalline silicon or amorphous silicon, and the method of forming the conductor layer 214 is, for example, a chemical vapor deposition method with a thickness of about 1000 angstroms to 3000 angstroms. Next, a layer is formed on the conductive layer 214. The hard cover curtain layer 220 and a photoresist layer 222. The material of the hard cover curtain layer 22 and the dielectric layer 210 and the conductor layer 214 have a good etching selection ratio. For example, for the chemical vapor deposition method, (please read the note on the back 4 4 4 5 twf.doc / 〇〇2 printed by the staff consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. The invention description (7) on the substrate 200, and then To carry out an etch-back process so that the conductor layer 214 and the recess remain A polycrystalline silicon layer or an amorphous silicon layer on the side wall of 223 forms the above-mentioned conductive spacer 230 °. Then, referring to FIG. 2E, remove the hard cover curtain layer 22 ′ to expose it. The conductive layer 214 and the conductive spacer 230 The electrode body under the structure. The method for removing the hard cover curtain layer 220 includes wet etching, such as using hot phosphoric acid as an etching solution. Next, a layer of hemispherical silicon grains is formed on the surface of the conductor layer and the conductor spacer 230 ( Hemispherical-Grained Silicon (HSG-Si) layer 232 to increase the surface area of the lower electrode to increase the storage capacitance of the capacitor. The hemispherical sand grain layer 232 can be formed by chemical vapor deposition or selective hemispherical silicon The technology of crystal grains is formed. Since the thickness of the conductor layer 214 of the present invention can be reduced to fill the contact window opening 212, and the thickness of the conductor spacer 230 is not required to be too thick, the present invention is very suitable The fabrication of electrodes under amorphous silicon can reduce the time to deposit the amorphous sand layer, increase the production capacity, and reduce the operating cost of the furnace tube. In addition, due to the conductor gap wall 23 0 is formed by etch-back, and does not need to define its pattern by typical lithography imaging and etching procedures, so it can reduce the difficulty and cost of the process, and can avoid the thickness of the conductor layer being too thick. During the etching process The problem of easy fracture. Finally, please continue to refer to FIG. 2E to form a dielectric film layer and another conductive layer 236 on the hemispherical silicon grain layer 232. The material of the dielectric film layer 234 is, for example, a silicon oxide layer, nitrogen Silicon Dioxide / Silicon Oxide (N〇) Junction (Please read the precautions on the back before filling this page) -7 ^ · Order 11
JU 本紙張尺度通用中國國家標準(CNS ) A4規格(210X297公釐) 408489 4445twf.doo/002 A7 B7 五、發明説明(/£;) 構、氧化矽/氮化矽/氧化矽層(0N0)。導體層236之材質例 如爲複晶矽,形成的方法例如爲化學氣相沉積法。 第3A圖至第3G圖’其繪示依照本發明弟一較佳貫施 例之一種動態隨機存取記憶體的製造流程剖面圖15 請參照第3Λ圖,依照上述實施例一的方式在基底300 上形成隔離區202、場效電晶體304、位兀線(未繪7K出) 與介電層310。 接著,請參照第3B圖,然後,以微影成像與蝕刻技術 定義介電層310,以在介電層310中形成接觸窗開口 312。 再於基底300上形成一層厚度足以將接觸窗開口 312塡滿 的複晶矽層314,使其與源極/汲極區308耦接。複晶矽層 314具有摻雜,例如爲砷或磷,其形成的方法例如爲化學 氣相沉積法,其厚度例如1000埃至3000埃。其後,在複 晶矽層314上形成一層金屬矽化物層3 15、一層阻障層316 與一層金屬層318。金屬矽化物層315例如爲矽化鈦,以 作爲複晶矽層314與阻障層316之接觸層(Contact Layer)阻障層316之材質例如爲氮化鈦,或是由氮化鈦 與釕(Ru)金屬層所組成者。氮化鈦層係作爲金屬之擴散阻 障層(Metal Diffusion Barrier),釕金屬層則是作爲氧化阻 障層(Oxidation Barrier)。金屬層3 18係作爲下電極之一部 份’其材質例如爲二氧化釕(Ru02)。 接著,請參照第3C圖,在金屬層318上形成一層硬罩 幕層32〇與一層光阻層322。硬覃幕層320之材質係與介 本紙張尺度逋用中國國家標準(CNS } A4規格(210x297公楚) (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消費合作社印製JU The paper size is in accordance with the Chinese National Standard (CNS) A4 specification (210X297 mm) 408489 4445twf.doo / 002 A7 B7 V. Description of the invention (/ £;) Structure, silicon oxide / silicon nitride / silicon oxide layer (0N0) . The material of the conductive layer 236 is, for example, polycrystalline silicon, and a method of forming the conductive layer 236 is, for example, chemical vapor deposition. FIG. 3A to FIG. 3G are diagrams showing a manufacturing process of a dynamic random access memory according to a preferred embodiment of the present invention. FIG. 15 Please refer to FIG. An isolation region 202, a field effect transistor 304, a bit line (not shown in 7K), and a dielectric layer 310 are formed on 300. Next, referring to FIG. 3B, the dielectric layer 310 is defined by lithography and etching techniques to form a contact window opening 312 in the dielectric layer 310. Then, a polycrystalline silicon layer 314 is formed on the substrate 300 so as to fill the contact window openings 312 so as to be coupled to the source / drain regions 308. The polycrystalline silicon layer 314 has a dopant, such as arsenic or phosphorus, and is formed by, for example, a chemical vapor deposition method, and has a thickness of, for example, 1000 angstroms to 3,000 angstroms. Thereafter, a metal silicide layer 315, a barrier layer 316, and a metal layer 318 are formed on the polycrystalline silicon layer 314. The metal silicide layer 315 is, for example, titanium silicide, and is used as a contact layer of the polycrystalline silicon layer 314 and the barrier layer 316. The material of the barrier layer 316 is, for example, titanium nitride, or titanium nitride and ruthenium ( Ru) composed of a metal layer. The titanium nitride layer is used as a metal diffusion barrier (Metal Diffusion Barrier), and the ruthenium metal layer is used as an oxidation barrier (Oxidation Barrier). The metal layer 3 18 is a part of the lower electrode ', and the material is, for example, ruthenium dioxide (Ru02). Next, referring to FIG. 3C, a hard mask layer 32 and a photoresist layer 322 are formed on the metal layer 318. The material of the hard Qin curtain layer 320 is based on the Chinese paper standard (CNS) A4 size (210x297). (Please read the precautions on the back before filling this page.) Order the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Print
40B48S 4445twf.d〇c/002 pj ----:---- B7 五、發明説明(//) (请先閲讀背面之注意事項再填寫本頁) .電層310以及金屬層318、阻障層3U、複晶矽層314具 有良之蝕刻培擇比者,其材質例如爲氮化矽,形成的方法 例如爲化學相沉積法,厚度約爲1⑻埃至1〇〇〇埃。 然後’請參照第3ϋ圖,將光阻層322圖案化。圖案化 .之光阻層322係對應於接觸窗開口 3 12的上方,其面積略 .大於接觸窗開口 3U。_,再以圖案化的光阻層322爲 罩幕,蝕刻硬罩幕層320。接著,以圖案化的光阻層322 與硬罩幕層320爲蝕刻罩幕,鈾刻複晶矽層314、金屬矽 化物層315、阻障層316、金屬層318與介電層31〇,以使 複晶砂層314、金屬矽化物層3 15、阻障層3 16與金屬層 31S圖案化’並在介電餍310中形成一個環繞複晶矽層3 I4 的凹槽323 ’其深度約爲5〇〇〇埃至ι.5微米。 由於氮化砂層320與複晶矽層3〖4、金屬矽化物層 315、阻障層316、金屬層318之間,或與介電層21〇之間 均具有良好的蝕刻選擇比,可以在蝕刻複晶矽層314、金 屬矽化物層315、阻障層316、金屬層318與介電層310 的程序中作爲硬罩幕層,所以,本發明並不需要形成過厚 的光阻層322,因此,可以避免光阻層322過厚所衍生的 經濟部智慧財產局員工消費合作社印製 問題。 其後’請參照第3E圖,將光阻層322去除。然後,在 基底300上形成另—層阻障層3〗4與另一層金屬層326。 阻障層324之材質例如爲氮化鈦,或是由氮化鈦與釕金屬 層所組成者。氮化鈦層係作爲金屬之擴散阻障層,釕金屬 層則是作爲氧化阻障層。金屬層326係作爲下電極之一部 13 本紙張尺度適用中國國家榡隼(CNS ) A4規格(210X297公釐) A7 B7 4445twf .doc^g^g^ 五、發明説明(/2) 份,其材質例如爲二氧化釕。 然後,請參照第3F圖’進行非等向性回蝕刻,以去除 覆蓋於介電層310上的阻障層324與金屬層326,使留在 複晶矽層314、金屬矽化物層3 I5、阻障層316、金屬層 318以及凹槽323之側壁的阻障層324與金屬層326形成 一導體間隙壁330。 之後’請參照第3G圖,去除硬罩幕層320,以裸露出 由複晶矽層314、金屬矽化物層315、阻障層316、金屬層 318以及導體間隙壁330所架構之下電極主體。去除硬罩 幕層320的方式包括濕式蝕刻法,例如是以熱磷酸爲蝕刻 溶液。接著,在基底300上形成一層介電膜層334,再形 成一層導體層336,以作爲電容器之上電極。介電膜層334 之材質例如爲五氧化二鉅(Ta205)、Pb(Zr, Ti)03,即PZT 以及(Ba,Sr)Ti03,即BST等高介電常數的材料。導體層 336之材質例如爲鋁,較佳的在形成鋁之前會先形成一層 氮化鈦以作爲阻障層。金屬鋁以及氮化鈦的形成方法例如 爲濺鍍法。 本發明第二實施例所述之電容器爲金屬-絕緣-金屬 (Metal-Insulator-Metal,MIM)結構,具有低介面反應(Low Interfacial Reaction)的特性,因此能提昇電容器之效能。 而且,由於接觸窗開口中係塡入複晶矽’因此’可以避免 金屬層與源極/汲極區接觸所衍生的漏電現象。此外’本發 明可以使用具有高介電常數的介電膜層,包括五氧化二 鉅、BST與PZT,以增加電容器之儲存電容° 本紙張尺度適用中國國家標準(CNS ) A4規格(210X2,97公釐) {請先閱讀背面之注意事項再填寫本頁) 訂 經濟部智慧財產局員工消费合作社印製 4 44 5 twf . doc^oQP ^'6 9 A7 B7 五、發明説明(P ) 綜合以上所述,本發明具有下列優點: 1. 本發明運用凹槽的形成,而並不需要形成很厚的 非晶矽層,因此可以減少沉積非晶矽層的時間,提高製造 的產能,並且可以減少爐管的操作成本,以及蝕刻厚非晶 T矽層的困難度。 2. 本發明可以增加電容器之下電極的表面積,以提 昇電容器的儲存電容量。 3. 本發明可以可用於製造具有高介電常數之介電膜 層的電容器。 4. 本發明之電容器爲金屬-絕緣-金屬結構可以增進 提昇電容器之效能。 雖然本發明已以一較佳實施例揭露如上,然其並非用 以限定本發明,任何熟習此技藝者,在不脫離本發明之精 神和範圍內,當可作各種之更動與潤飾,因此本發明之保 護範圍當視後附之申請專利範圍所界定者爲準。 (請先聞讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐)40B48S 4445twf.d〇c / 002 pj ----: ---- B7 V. Description of the invention (//) (Please read the precautions on the back before filling this page). Electrical layer 310 and metal layer 318, resistance The barrier layer 3U and the polycrystalline silicon layer 314 have a good etching selectivity ratio. The material is, for example, silicon nitride, and the formation method is, for example, a chemical phase deposition method, and the thickness is about 1 Angstrom to 1,000 Angstroms. Then, referring to FIG. 3 (a), the photoresist layer 322 is patterned. The patterned photoresist layer 322 corresponds to the contact window opening 312, and its area is slightly larger than the contact window opening 3U. Then, the patterned photoresist layer 322 is used as a mask, and the hard mask layer 320 is etched. Next, using the patterned photoresist layer 322 and hard mask layer 320 as an etching mask, uranium is etched with a polycrystalline silicon layer 314, a metal silicide layer 315, a barrier layer 316, a metal layer 318, and a dielectric layer 31. So that the polycrystalline sand layer 314, the metal silicide layer 3 15, the barrier layer 3 16 and the metal layer 31S are patterned 'and a groove 323' surrounding the polycrystalline silicon layer 3 I4 is formed in the dielectric 餍 310, the depth of which is about It is 5000 angstroms to 1.5 μm. Since the nitrided sand layer 320 and the polycrystalline silicon layer 3, 4, the metal silicide layer 315, the barrier layer 316, the metal layer 318, or the dielectric layer 21 have a good etching selection ratio, it can be The process of etching the polycrystalline silicon layer 314, the metal silicide layer 315, the barrier layer 316, the metal layer 318, and the dielectric layer 310 is used as a hard mask layer. Therefore, the present invention does not need to form an excessively thick photoresist layer 322. Therefore, it is possible to avoid the printing problem of the consumer co-operatives of the Intellectual Property Bureau of the Ministry of Economics, which is caused by the photoresist layer 322 being too thick. Thereafter, please refer to FIG. 3E to remove the photoresist layer 322. Then, another barrier layer 3 and a metal layer 326 are formed on the substrate 300. The material of the barrier layer 324 is, for example, titanium nitride, or is composed of a titanium nitride and a ruthenium metal layer. The titanium nitride layer is used as a metal diffusion barrier, and the ruthenium metal layer is used as an oxidation barrier. The metal layer 326 is used as a part of the lower electrode. 13 The paper size is applicable to the Chinese national standard (CNS) A4 (210X297 mm) A7 B7 4445twf .doc ^ g ^ g ^ 5. Description of the invention (/ 2), The material is, for example, ruthenium dioxide. Then, referring to FIG. 3F, perform anisotropic etch-back to remove the barrier layer 324 and the metal layer 326 covering the dielectric layer 310, so that the polycrystalline silicon layer 314 and the metal silicide layer 3 I5 are left. The barrier layer 324, the barrier layer 316, the metal layer 318, and the sidewall of the groove 323 and the metal layer 326 form a conductor gap 330. Afterwards, please refer to FIG. 3G, remove the hard mask layer 320 to expose the electrode body under the structure of the polycrystalline silicon layer 314, the metal silicide layer 315, the barrier layer 316, the metal layer 318, and the conductive spacer 330. . The method for removing the hard mask layer 320 includes wet etching, such as using hot phosphoric acid as an etching solution. Next, a dielectric film layer 334 is formed on the substrate 300, and a conductive layer 336 is formed as an electrode on the capacitor. The material of the dielectric film layer 334 is, for example, pentoxide (Ta205), Pb (Zr, Ti) 03, that is, PZT and (Ba, Sr) Ti03, that is, high dielectric constant materials such as BST. The material of the conductive layer 336 is, for example, aluminum, and it is preferable to form a layer of titanium nitride as a barrier layer before forming aluminum. The method for forming metal aluminum and titanium nitride is, for example, a sputtering method. The capacitor according to the second embodiment of the present invention has a metal-insulator-metal (MIM) structure, and has a characteristic of low interfacial reaction, so the performance of the capacitor can be improved. Moreover, since the polycrystalline silicon is implanted in the opening of the contact window, the leakage phenomenon caused by the contact between the metal layer and the source / drain region can be avoided. In addition, the present invention can use a dielectric film layer with a high dielectric constant, including pentoxide, BST and PZT, to increase the storage capacity of the capacitor ° This paper size applies the Chinese National Standard (CNS) A4 specification (210X2,97 Mm) {Please read the notes on the back before filling this page) Order printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 4 44 5 twf .doc ^ oQP ^ '6 9 A7 B7 V. Description of Invention (P) As mentioned, the present invention has the following advantages: 1. The present invention utilizes the formation of grooves without the need to form a very thick amorphous silicon layer, so the time for depositing the amorphous silicon layer can be reduced, the production capacity can be improved, and Reduced furnace tube operating costs and difficulty in etching thick amorphous T silicon layers. 2. The present invention can increase the surface area of the electrodes below the capacitor to increase the storage capacity of the capacitor. 3. The present invention can be used for manufacturing a capacitor having a dielectric film layer having a high dielectric constant. 4. The capacitor of the present invention has a metal-insulation-metal structure, which can improve the performance of the capacitor. Although the present invention has been disclosed as above with a preferred embodiment, it is not intended to limit the present invention. Any person skilled in the art can make various modifications and decorations without departing from the spirit and scope of the present invention. The scope of protection of the invention shall be determined by the scope of the attached patent application. (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper applies the Chinese National Standard (CNS) A4 specification (210X297 mm)
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