經濟部中央標隼局員工消費合作社印裝 嬸⑽652 ab] 五、發明説明() 發明背景 1. 發明領域 本發明係關於在鹼性紙漿化過程中以鹼性牛皮紙之 紙漿化液,或硫酸根,將木質纖維物質,例如木材,去 木質化過程中的一種改良添加物組成物及其方法。更特 別的是,本發明係關於一種以含有環狀酮基化合物(以 蒽醌為較佳)的牛皮紙紙漿化液將木質纖維物質去木質 化,使產率提高。更明確的來說,本發明係關於所述添 加物組成物及方法之改良,其中所述產率之提高係藉著 添加内含至少一烷氧化之烷基醇與至少一以聚亞烷氧基 二醇醚與選自篦麻油酸與十二羥基硬脂酸之一所組成酯 類之界面活性混合物,於較低之葸醌含量下所達成的。 2. 先前技藝敘述 在1970年代中期,因發現在鹼性紙漿化液中加入蒽 醌作為紙漿化添加物之效益,因此使製造木材紙漿之木 質纖維物質的去木質化過程明顯的往前邁進。在美國第 3,888,727號專利案件中最早公開揭露蔥醌之此種用途’ 其中揭橥了以含蒽醌磺酸之鹼性紙漿化液處理木質纖維 物質後,再以氧去木質化。然而更顯著的是’在美國第 4,012,280號專利案件中指出,較環保之鹼法紙漿化過程 其較差之經濟效益可藉著將蒽醌併入紙漿化添加物而獲 得改善,並能與較不環保(依氣味之觀點而言)之牛皮 紙紙漿化過程競爭。雖然前者具增加纖維紙漿之產率與 第4頁 _ ___—' 本紙張尺度適用中國國家摞準(CNS ) A4規格(210/ 297^¾ ) ---------^裝------訂--<-----A-------- : ' - * -- - - {請先閲讀背面之注意事項再填寫本頁} A7 B7 403652 五、發明説明(Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 652 ab] V. Description of the invention () Background of the invention 1. Field of the invention The present invention relates to a pulping solution using alkaline kraft paper or sulfate in the process of alkaline pulping. An improved additive composition and method for removing lignocellulosic materials, such as wood, in the process of delignification. More specifically, the present invention relates to a method for de-lignifying lignocellulosic materials with a kraft pulp slurry containing a cyclic ketone compound (preferably anthraquinone is preferred) to increase the yield. More specifically, the present invention relates to the improvement of the additive composition and method, wherein the improvement of the yield is achieved by adding an alkyl alcohol containing at least one alkoxylate and at least one polyalkylene oxide. An interfacial active mixture of an alkyl glycol ether and an ester selected from one of ramie oleic acid and dodecyl hydroxystearic acid was achieved at a lower fluorenone content. 2. Description of previous techniques In the mid-1970s, the benefits of adding anthraquinone as a pulping additive were found in alkaline pulping liquors, so the process of delignification of wood fiber material for making wood pulp was significantly advanced. U.S. Patent No. 3,888,727 was the first to disclose the use of onionquinone ’, which disclosed the treatment of lignocellulosic materials with an anthraquinone sulfonic acid-containing alkaline pulp liquefaction, followed by oxygen delignification. However, what is more significant is that 'in the US Patent No. 4,012,280, it is pointed out that the poorer economic benefits of the more environmentally friendly alkaline pulping process can be improved by incorporating anthraquinone into the pulping additive, and can be compared with less Environmentally friendly (in terms of smell) kraft pulping processes compete. Although the former has an increase in the yield of fiber pulp and page 4 _ ___ — 'This paper size is applicable to China National Standard (CNS) A4 specifications (210/297 ^ ¾) --------- ^ pack- ---- Order-< ----- A --------: '-*---{Please read the notes on the back before filling this page} A7 B7 403652 V. Invention Description (
増進去木質化之速率(使銥甚、A ^ 〈使能量消耗降低並提高產量)的 優點’但此經改良,污染潜士 来脣力較低之鹼法製紙漿方法之 n t \ - . ι^ϋ I nn - 、ν6 '1 (請先閱讀背面之注意事項再填寫本頁) 使用卻未提升。第一,為了热‘ ΑTake advantage of the rate of lignification (making iridium, A ^ <reducing energy consumption and increasing yield) 'but this modified, polluting the potential of the lip strength of the alkaline pulp pulp method nt \-. Ι ^ ϋ I nn-, ν6 '1 (Please read the precautions on the back before filling in this page) The use has not improved. First, for the heat ‘Α
能在產量上與不用蒽越之各L 酸鹽製紙漿法不相上下,驗法制α ^ ^ 决I紙漿方法中需使用相* 昂貴的蒽酸,如此會降低立細% _ 陣低其經濟上之競爭力。第二,蒽 醍的益處亦可由其他(商χ 两業上已較常使用)製紙漿万法 達到,例如那些採用牛古Μ , 干皮紙紙漿化液或多硫化紙漿化液 之過程。 -如美國帛4,213,821號專利案件中所揭露的,在中 性之硫酸根紙聚化液中美國帛5>ΐ39,6ΐ7號專利中所 經濟部中央標隼局貝工消費合作社印f 發現的特殊案例),或是於驗性紙槳化液中熬煮木屑, 很快就能發現蒽醍的效益。將葱醌之效益推廣至極至之 ,法則可見於美國丨 4,127,439 ; 4,178,861 ;與 4,310,383 號專利案件中。同時,有鑑於蒽醌之難以處理、不溶於 水、細粉末形式的特性,美國第4 248 663,4,384 921與 4,574’032號專利案件中揭露了加速蒽醌分散於紙漿化液 中之方法。使用蔥醗的一缺點為易在蒸煮容器中形成復 垢之問題。在美國第4,481〇73與4 56^35號專利案件中 對此問題提出了解決之道。最後,鑑於蒽醌相當高的售 價’美國第4,197,168與4,31〇,383號專利案件中提出對於 此化合物的回收與再利用之方法。 儘管有前述之進展,但仍亟需增進蒽醌紙漿化(主 要在增進產量的同時降低能量與的化學物之需求量)之 效益並減少其缺點(主要為成本與量產之儀器設備)。 第5頁 本紙張尺度適用中國國家標準(CNS > A4規格(210X297公# )Can be comparable to the production method of each L acid salt pulp without anthracene. The method of making α ^ ^ is determined in the pulp method. Phase * expensive anthracene acid is needed, which will reduce the percentage of fineness. Competitiveness. Second, the benefits of anthracene can also be achieved by other methods (usually used in the Shang and X industries) for making pulp, such as those using Niu Gu M, dry skin pulp pulp or polysulfide pulp pulp. -As disclosed in the US Patent No. 4,213,821, the special solution found in the neutral sulfate paper polymerization solution of the US Patent No. 5 > No. 39, 6 No. 7 by the Central Bureau of Standards, Ministry of Economic Affairs, Shellfish Consumer Cooperative Co., Ltd. Case), or cooking wood chips in a test paper paddle liquid, the benefits of anthracene will soon be discovered. The benefits of onionquinone can be extended to the extreme, the rules can be found in the United States, 4,127,439; 4,178,861; and 4,310,383 patent cases. At the same time, in view of the characteristics of anthraquinone that is difficult to handle, insoluble in water, and in the form of a fine powder, U.S. Patent Nos. 4 248 663, 4,384 921, and 4,574'032 disclose methods for accelerating the dispersion of anthraquinone in a pulping liquid. One disadvantage of using shallots is the problem of easy formation of scale in the cooking vessel. A solution to this problem was proposed in U.S. Patent Nos. 4,481,073 and 4,56 ^ 35. Finally, in view of the relatively high selling price of anthraquinone, U.S. Patent Nos. 4,197,168 and 4,31,0,383 propose methods for the recovery and reuse of this compound. Despite the aforementioned progress, there is still an urgent need to improve the benefits and reduce the disadvantages of anthraquinone pulping (mainly reducing the energy and chemical requirements while increasing yield) (mainly cost and mass production equipment). Page 5 This paper size applies to Chinese national standards (CNS > A4 size (210X297 公 #)
^02652 〜---- 五、發明説明( 二-:決<道即為將部分之蔥醌以—種具有葱醌某㈣ 點但使用時卻無龙& r热具缺點之添加物來取代。 因此,本發昍、 <目標為在木質纖維天然原料之去4 質化過程中提供—1、 、改艮之紙漿化添加物組成物與方法, 此過程乃是以具酋 、‘、輥足紙漿化液作為製造預定產率之痛 維紙漿,此纖錐缸妝、 以 ,、及漿芯組成與過程可達所述之產率,万 則述之效益,並,试 減少至少10%蒽釅需求量。 I明概述及i» 1 上述目標可组< 丄 太㈣地 由現今之發明而達成,此發明為改良 木質纖維天然原料,1士昆 如木屑,去木質化過程以生產製備 紙張或厚紙板所φω 夂纖維紙漿之初步助劑組成物與方 法,其中木屑係认 ^ 、 ' 达、閉反應容器中與一内含可達成既^ 02652 ~ ---- V. Description of the invention (II-: Decided that the onion quinone is a kind of additive which has a certain point of onion quinone but does not have a dragon & r heat defect when used. Therefore, the purpose of this hairpin, < is to provide -1, and to improve the pulping additive composition and method in the process of degrading the natural raw materials of wood fiber. This process is based on 'The roller foot pulp liquid is used as a pain-reducing pulp to produce a predetermined yield. The composition and process of the fiber cone cylinder makeup, pulp, and pulp core can achieve the stated yield, the benefits described in 10,000, and try to reduce At least 10% of anthracene demand. I. Overview and i »1 The above goals can be achieved by the present invention, which is a natural raw material for improving lignocellulosics. The process is to produce the preliminary auxiliary composition and method of producing φω 夂 fiber pulp made of paper or cardboard. Wood chips are recognized in a closed reaction container and can be reached with an inclusion.
疋紙裝產率之含I 環狀酮基化合物,例如蒽醌,之鹼性 紙衆化液作用,1 士、 , 、中疋改良包括藉著添加一内含至少一 燒氧化之烷基醇與、 至/一以聚亞烷氧基二醇醚與選自篦 麻油酸輿+ -银甘 t 一工基硬脂酸之一所組成之酯類之界面活性 混合物至此鹼性蚯骓 、漿化液中,以降低可達到上述產率所 需之蔥醌量。 施例之描诂 本發明 < 改良方法至少包含下述步驟(1)在一密 反應容器中,讓木質纖維原料與一含有環狀酮基化合 添加物之鹼性紙漿化液作用,此化合物可擇自下列之 第6頁 本紙張尺度適用中國國家標隼(CNS ) Λ4規格(210X2们公^ > ----------¾衣-----^----------^ (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印" A7 B7 醇與 幾基 經濟部中央標隼局貝工消费合作社印裝 硬脂酸之一所組成之酯 由上述二步驟所製造之去木質化之纖維原料不 步又處理即可使用或可直接用於傳統之漂白步進 當欲處理之纖維原料為木㈣,需先將其形成 而W纖維原料已經是纖維狀時則不需此步驟。 纖維原料可於步驟(1)與(2)之間予以切細。切細可 使用已知之機器進行,如一單碟或雙碟之切細機。可 本發明方法可用於毬果類或落葉性之木材。此中越 果類意指如松樹’雲杉,與香樅。落葉性意指如樺樹, 白楊,東方白楊,楓樹,杉毛櫸,與橡樹。 界面活性物質混合物之烷氧化之烷基醇成分較好是 C4 C3。碳鍵之燒氧化燒基醇,此燒氧化之燒基醇可由一線 402652 五、發明説明( 醒,葱醒’葱辆,菲艇,此類醒類之㈣ 與氨基之衍生物,M1-二酮1H 栳乳基 蓁吖啶酮,7,12·二嗣曾* ,蒽鲲-1么 fn 1()亞甲基^ -氣處'[1,2帅比味,a" 。興10-亞甲基葱酮,此反應在最高溫度自 并 ?〇:作用約。·5至料鐘以達既定之 S〇c r)木質纖維原料中之紙莱化液以水或一種不與=與 既定產率,其中=替代達到去木質纖維原料之 、 作疋改良包括加入鹼性紙漿化液Φ 界面活性混合物以降低為達到上述之產率所窝、 嗣基化合物添加物的量,除了環狀綱基化合物=狀 外,'此界面活性混合物係由至少含—燒氧化之境基低 至少一以聚亞燒氧基二醇酸與選自萬麻油酸與十 第7頁 本紙張尺度適用中國國家標準(CNS ) Μ規格(210X297公釐) ___Ί.-------裝-------^訂一I 線 •--N請先閲讀背面之注意事項再填、寫本頁) __ 40265£ A7 經濟部中央標準局貝工消費合作社中製 五、發明説明( 形或支鏈且可以是'級或二級醇,與約5莫 耳選自環氧乙烷、嫌银 00莫 環氧丙烷、環氧丁烷及其任一组人 環氧化物作用而ά ° ^ 作用而成。其中尤佳疋烷氧化烷基醇 氧化物與23莫耳之環氧乙缔反應製備而來。‘ 聚亞烷氧基二醇瞇與選自萬麻油酸與十 酸之-所组成之锻是由選自甘油,新戍二酵, 乙烷,三羥甲其石降 .^ τ * 甲基丙烷,季戍四醇與其聚合物, 山梨糖醇之乙二醇酿與約5莫耳至,。。莫耳選 烷、環氧丙燒、播 衰軋丁烷及其任一組合之環氧化物作 而成由於篦麻油酸是篦麻油之主要成分(9〇%), 麻油酸雖然是以三酸甘油醋而非自由酸之形式存在, 可直接坑氧化形成所需之萬麻油酸聚亞燒基二醇酿。 此較佳(成員是由篦麻油酸甘油酯乙氧化而成。 在美國第5,298,120與5,501,769號專利案件中揭露 以脂肪酸聚亞燒氧基二醇酯來製造木材紙漿可增進紙 化之均勻度與紙漿的產率。雖然這些酯類可賦予所需 性能’但在強鹼溶液中與加熱至高溫之情況下它具有 潛在之弱點。這些酯類可被斷裂而形成一脂肪酸皂和 亞娱:基二醇。因此,它不再是所聲稱之酯類。並且, 發現化合物也無法產生效益,事實上,分解所得之產 反會減低前述之效益。 申請專利範固之烷基酵聚亞烷基二醇醚與(篦麻 的)篦麻油酸甘油醇之聚亞烷基二酵醚則與上述不同, 乙 用 篦 因 了 漿 之 聚 所 油 ----------^------1T|_^-----0 (請先W'讀背Φ-之注意事項Ϊ寫本頁).-' 第8頁 本紙張尺度適用中國國家樣準(CNS )八4胁(加幻97公兼 經 榡 準 局 貝 合 作 杜 40265^ 、發明说明 A7 B7 (y 於製造木材紙漿的高溫,強鹼溶液中具有極佳之 性能。當篦麻油酸甘油酵之聚亞烷基二醇醚中之酯分解 時,所得之分子為篦麻油酸甘油醇之聚亞烷基二醇趟之 鈉鹽,它是一種界面活性物且在紙漿化溶液中具有功能。 當紙漿化過程完成時,篦麻油酸甘油醇之聚亞烷基二醇 ::麵鹽的存在有助於统基醇聚亞燒基二醇鍵在高溫、 強鹼溶液中之溶解度。 由—本發明組成物為一較佳之微細乳化液,此乳化液是 4 -種油哮乙氧化物與蒸麻油酸三酸甘油酿乙氧化物以 能與1Γ1:4之重量比(約1:2為佳)组合而成。為了 與用於鹼性紙漿化液中之蒽醌一起 總重 巧忧用,組成物與佔 透明、hO到3〇% (約㈣為較佳)#水混合而得一 :稠之溶液。此溶液依序以水稀釋並加入分散於 溶液=艇而得具約10至30% (約125%較佳)活性之 親油平衡Γ月之界Γ活性劑组成物具有約5至2°之親水 劑組成物、出又以約8 i 16之值為較佳。當與界面活性 粒之平於; 吁微細乳化液,其中顆 鸣大小為約0·5至10微米, 而又以丨# 木以約1至4微米較佳 人以小於2微米尤佳。 具適當平均顆粒大小之乳化液斑 之加強伖™, 孔化履與蒽醚可達成所陳述 用之證據如下,在週遭環境、'〇电、 分混八,_ 杜迥埂塚境溫度之下將二種成 ° 可形成—透明溶液,並Η ^ (180。 ή並且’當加熱至82t )時,洛液轉成一混濁之藍色。 環狀_基化合物, 以蒽醌為佳,在加入蒸煮容器之 它 在用 第9頁 本紙張尺度朝巾關轉準(CNS > A4規格(210X297公釐) ---Ί.--Ί----- I 裝----^ /訂 (請先閲讀背面之注項再填寫本頁) ___ 402652 五、發明説明( A7 B7 前與所發明之界面活性化合物混合而可製成—水性 :。葱酸的分教可藉由加入一種分散劑與藉由源性研磨 或磨粉將葱醌磨成、約…0冑米之帛粒以降低水中蒽醗 义平均顆粒大小而達成。磺化木質納 劑。 為較佳义分散 雖然界面活性物組成成分與蔥醌分散液可分別加入 蒸者容器中,但在加人之料將:者混合再以其水溶液 混合物加人為較佳。界面活性物乳化液可將蔥醒之顆粒 包覆且可令蒽醌與紙漿化液之混合物快速地滲入木屬中 且將其更有效率地,完全地浸潤。可推想即是此種藉著 使用非常少量的蔥醖之機轉而獲得欲求之K a p p a值與低 棄率。 所發明之方法與組成物之效益見於下列諸實施例 中 。 請 先 閲疋 Paper-containing yields of I-containing cyclic ketone compounds, such as anthraquinone, are used as alkaline paper solvents, and the improvement of 疋, ,, and 疋 includes the addition of an alkyl alcohol containing at least one oxidized alkyl alcohol. And, to / an interfacial active mixture of polyalkylene oxide glycol ethers and esters selected from one of ramie oleic acid ++-glyceryl t-stearic acid To reduce the amount of onionquinone required to achieve the above yield. Description of the Example The present invention < The improved method includes at least the following steps (1) In a dense reaction container, the lignocellulosic raw material is allowed to react with an alkaline pulping liquid containing a cyclic ketone compound additive. This compound Can be selected from page 6 of the following. This paper size is applicable to China National Standard (CNS) Λ4 specification (210X2men ^ > ---------- ¾ clothing ----- ^ ---- ------ ^ (Please read the notes on the back before filling out this page) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs " A7 B7 The ester composed of one of the fatty acids is made from the above-mentioned two steps. The delignified fiber raw material can be used without further processing or can be directly used in the traditional bleaching step. This step is not necessary when the W fiber material is already fibrous. The fiber material can be shredded between steps (1) and (2). The shredding can be performed using a known machine, such as a single dish or double Dish shredder. The method of the present invention can be used for capsules or deciduous wood. Class means pine such as pine, spruce, and cedar. Deciduous means means birch, aspen, oriental aspen, maple, cedar, and oak. The alkoxylated alkyl alcohol component of the mixture of surfactants is better It is C4 C3. Carbon-bonded oxidized alkynyl alcohol. This burned oxidized alkynyl alcohol can be described by the first line of 402652. V. Description of the invention , M1-dione 1H 栳 lactyl 蓁 acridinone, 7,12 · di 嗣 zene *, anthracene -1 mol fn 1 () methylene ^-气 处 '[1,2, handsome taste, a " 10-methylene allium ketone, the reaction at the highest temperature is self-contained. The effect is about 5 to 5 minutes to reach the established Socr) lignocellulose solution in wood fiber raw materials with water or a kind of And = with a given yield, where = replaces the raw material for delignification, and the improvement includes adding an alkaline pulping solution Φ interfacial active mixture to reduce the amount of fluorenyl compound additives to achieve the above yield, In addition to the cyclic group compounds, this' Interactive mixture is composed of at least one-lower than the Oxyglycolic acid and selected from sesame linoleic acid and tenth page 7 This paper size applies the Chinese National Standard (CNS) M specification (210X297 mm) ___ Ί .---------------------- ^ Order an I line • --N Please read the notes on the back before filling and writing this page) __ 40265 £ A7 Central Bureau of Standards, Ministry of Economic Affairs, Shellfish Consumer Cooperatives, China System V. Description of invention (shaped or branched and can be 'Class or secondary alcohol, and about 5 moles selected from the group consisting of ethylene oxide, arsenic 00 mole propylene oxide, butylene oxide and any group of human epoxides. Among them A particularly preferred alkylene oxide is prepared by reacting an alkylene oxide with 23 moles of ethylene oxide. '' Polyalkylene glycol 眯 and selected from the group consisting of sesame linoleic acid and decanoic acid-the forging is composed of glycerol, neodymium di-enzyme, ethane, trimethylol sulphate. ^ Τ * methyl Propane, quaternary tetrol and its polymers, sorbitol in ethylene glycol and about 5 moles. . Morsethan, propylene oxide, butane and any combination of epoxides made of ramie oleic acid is the main component of ramie oil (90%), although linoleic acid is a triacid Glycerol vinegar exists instead of free acid, and can be directly oxidized to form the desired sesame linoleic acid polyalkylene glycol. This is better (members are ethoxylated from glyceryl linseed oleate. U.S. Patent Nos. 5,298,120 and 5,501,769 disclose that the use of fatty acid polyoxymethylene glycol to make wood pulp can improve papermaking Uniformity and pulp yield. Although these esters can impart the desired properties, it has potential weaknesses in strong alkaline solutions and when heated to high temperatures. These esters can be cleaved to form a fatty acid soap and Asia Entertainment: Glycol. Therefore, it is no longer the claimed ester. Moreover, it was found that the compound could not produce benefits. In fact, the yield obtained from the decomposition would reduce the aforementioned benefits. Polyalkylene glycol ethers and (ramie) polyalkylene dimer ethers of ramie oleic acid glycerol are different from the above. -^ ------ 1T | _ ^ ----- 0 (please read the precautions of Φ-read this page first) .- 'page 8 This paper standard is applicable to Chinese national standards ( CNS) 8 4 threats (plus 97 magical and quasi-examination board cooperation cooperation 40265 ^, invention description A7 B7 (y for making wood pulp High temperature, excellent performance in strong alkaline solution. When the ester in the polyalkylene glycol ether of ramie oleic acid glycerol is decomposed, the obtained molecule is the polyalkylene glycol of ramie oleic acid glycerol. Sodium salt, which is a surfactant and has a function in the pulping solution. When the pulping process is completed, the presence of polyalkylene glycol of glycerol glycerol :: face salt helps the base alcohol Solubility of polyalkylene glycol bond in high temperature, strong alkali solution. The composition of the present invention is a preferred fine emulsion. This emulsion is 4 kinds of oleyl ethoxylate and linoleic acid triglyceride. Ethylene oxide is combined with a weight ratio of 1Γ1: 4 (about 1: 2 is preferred). In order to be used together with anthraquinone used in alkaline pulping liquid, the composition is transparent , HO to 30% (about ㈣ is better) # water mixed to obtain a: a thick solution. This solution was diluted with water in order and added to the solution = boat to obtain about 10 to 30% (about 125%) Better) Active lipophilic balance. The boundary of the month. The active agent composition has a hydrophilic agent composition of about 5 to 2 °. The value of 8 i 16 is better. When it is equal to that of the interface active particles; call for a fine emulsion, in which the size of the particles is about 0.5 to 10 microns, and It is better to be less than 2 microns. Emulsion reinforcement with proper average particle size ™, pores and anthracene ether can achieve the stated evidence as follows, in the surrounding environment, '0 electricity, mixing and mixing, Under the temperature of the graveyard, two kinds of ° can be formed-a transparent solution, and ^ (180.) and 'when heated to 82t, the Luo liquid turns into a turbid blue. Cyclic compound, Anthraquinone is preferred. When it is added to the cooking container, it is used in the paper on page 9. The paper size is turned toward the towel (CNS > A4 size (210X297 mm) --- Ί .-- Ί ----- I Equipment ---- ^ / Order (please read the note on the back before filling out this page) ___ 402652 V. Description of the invention (A7 B7 can be made by mixing with the invented surface-active compound-water-based :. The division of onion acid can be achieved by adding a dispersant and grinding onion quinone into source particles of about 0 胄 m by source milling or milling to reduce the average particle size of anthracene in water. Sulfonated lignin. Dispersion for better meaning Although the composition of the surfactant and the onionquinone dispersion can be separately added to the steamer container, it is better to mix the ingredients and add the aqueous solution mixture. The surfactant emulsion can coat the onion particles and quickly infiltrate the mixture of anthraquinone and the pulping liquid into the wood genus and infiltrate it more efficiently and completely. It can be inferred that this kind of onion is used to obtain the desired K a p p a value and low rejection rate. The benefits of the invented method and composition are found in the following examples. Please read
fL 3 頁 訂 實施例 為了相互比較,將59,090公斤(濕重65噸)之針葉 木屑填置入紙漿化蒸煮器之中,在此紙漿化蒸煮器申含 有硫酸鹽鹼性紙漿化液,此液中具有平均約為4 9〇9公斤 (約Μ,βοο磅)的活化鹼且此液與木材之重量比約為 3.45 ’再加入22 7公斤(濕重55磅)之5〇%蒽醌分散液 (佔總重量之0.08%,以烘箱乾燥之木屑重量為基礎)β 所·蒸煮之内容物加熱至最高溫IgfC ,然後木 屑再蒸衆79分鐘直至Kappa值為91。蒸煮過程其最終產 第10頁 本紙張尺度適用中國國家揉準(CNS ) A4规格(210X297公釐) 線 經 濟 部 t 標 隼 局 貝 工 消 t 合 作 社 印 / 402652 A7 B7 五、發明説明() 率為54%,而廢棄率為10%。 實施例2 為了作為能增進蒽醌效益之額外消化助劑,製備了 數種本發明界面活性劑之,樣本並對其細微乳化作用做一 評估。在不同的比例下,將由23莫耳環氧乙烷所製備之 乙氧基化油醇與乙氧基化之篦麻油酸三酸甘油酯和水混 合。在各案例中,當將各組成物攪拌混合後可形成一透 明、黏稠之溶液。 樣本A : 乙氧基化油醇一 23莫耳環氧乙烷 乙氧基化物之篦麻油酸三酸甘油酯 水 總重中之20份 總重中之60份 總重中之20份 (請先聞讀背面之注意事項再填寫本頁) 丨裝· 樣本B : 乙氧基化油醇一23莫耳環氧乙垸 乙氧基化之篦麻油酸三酸甘油酯 水 總重中之40份 總重中之40份 總重中之20份 經濟部中央標準局員工消費合作社印製 JI. 樣本C : 乙氧基化油醇_ 23莫耳環氧乙烷 乙氧基化之篦麻油酸三酸甘油酯 水 總重中之60份 總重中之20份 總重中之20份 第11頁 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) 經濟部中央標準局員工消費合作社印裝 402652 A7 ______ B7 五、發明説明() 各個樣本均以水稀釋至其重量之12.5 %並加熱至82 C(18〇°F)。在週遭環境之溫度下所有稀釋的樣本均呈 透明 < 溶液’而在82t ( 180。F )時各個樣本轉呈混濁之 藍色。 實施你丨3 重複實施例1中之過程;除了,在蒸煮器中加入木 屑與系入白色液體的同時’於此白色液體中加入以烘 箱乾燥木屑所得重量為基準所計算出之〇 %由實施例2 樣本A界面活性混合物及蒽醌所組成之消化助劑以取代 0.08%之蒽醌。消化循環完成後,可得Kappa值為9〇之紙 漿而其廢棄率低於1 〇 %。 實施例1中蒽醌之性能相較下,當分解輔助能力降 低25%時(使用本發明之紙漿化添加物)Kappa值與廢棄 率會顯著降低。並且,當依各個消化助劑中其相對蔥醌 含量來進行比較時,本發明界面活性組成物可降低至少 5〇%之蒽醌需求量。 使用蒽醒含量較低之消化助劑之其他益處尚包括: 1_在蒸餾管路與管路塞子上較不易形成覆垢;並且 2.降低紙漿原始浮油之污染,因而減少浮油提煉麻之 問題與降低浮油初分餾時之污染。 即便本發明於參考文獻中就各種特定之原料、步驟 與實施例已有描述,本發明並不僅侷限於特定之原料, 原料之组合與就其目的所選用之程序。上述細節可作許 第12頁 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公嫠) (請先閱讀背面之注意事項存填寫本頁) _装· fr A7 經濟部中央標準局員工消費合作社印製 402Q52 B7 五、發明説明() 多變化’並為本領域中熟悉技藝之人士所能理解的。 第13頁 n- HI n^l n I ^^^1 il^i n^i m« ^ > HI mL • ^ « J / ^ · · 、t 销 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐)fL 3 pages Example For comparison, 59,090 kg (65 tons wet weight) of softwood sawdust is filled into a pulping cooker, where the pulping cooker contains a sulfated alkaline pulping liquid. The liquid has an average of about 4 909 kg (about M, βοο lbs) of activated alkali and the weight ratio of the liquid to the wood is about 3.45 ', and then 22 7 kg (55 lb wet weight) of 50% anthraquinone are added. The dispersion (0.08% of the total weight, based on the weight of the wood-dried oven-dried wood) β The contents of the cooking are heated to the highest temperature IgfC, and then the wood-dried wood is steamed for another 79 minutes until the Kappa value is 91. The final product of the cooking process page 10 This paper size is applicable to China National Standards (CNS) A4 (210X297 mm) Ministry of Economic Affairs t Standardization Bureau Shellfisher t Cooperative Press / 402652 A7 B7 V. Description of the invention () Rate It is 54%, and the rejection rate is 10%. Example 2 In order to serve as an additional digestive aid that can enhance the benefits of anthraquinone, several surfactants of the present invention were prepared, and samples were evaluated for their fine emulsification. In different ratios, ethoxylated oleyl alcohol prepared from 23 mol ethylene oxide was mixed with ethoxylated linseed triglyceride and water. In each case, when the components are stirred and mixed, a transparent and viscous solution is formed. Sample A: 20 parts by weight of ethoxylated oleyl alcohol 23 mol ethylene oxide ethoxylate ramie oleate triglyceride 60 parts by weight (please first Please read the notes on the back of the page and fill in this page) 丨 Packing · Sample B: 40 parts by weight of the total weight of ethoxylated oleyl alcohol-23 mol epoxy ethoxylated ramie oleate triglyceride in water 40 of the top 20 parts of the total weight 20 printed by the Ministry of Economic Affairs Central Standards Bureau Consumer Cooperatives. Sample C: ethoxylated oleyl alcohol_ 23 mol ethylene oxide ethoxylated linseed triglyceride 60% of total weight of ester water 20% of total weight 20% of total weight Page 11 This paper applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 402652 A7 ______ B7 V. Description of the invention () Each sample was diluted with water to 12.5% of its weight and heated to 82 C (18 ° F). All the diluted samples were transparent < solution ' at ambient temperature and each sample turned cloudy blue at 82t (180 ° F). Implement your practice 3 Repeat the process in Example 1; except that when you add wood chips to the cooker and tie the white liquid, add 0% of the white liquid calculated based on the weight of the oven-dried wood chips in the cooker. Example 2 Sample A was a digestive aid composed of an interfacial active mixture and anthraquinone to replace 0.08% of anthraquinone. After the digestion cycle is completed, pulp with a Kappa value of 90 can be obtained and its rejection rate is less than 10%. Compared with the performance of anthraquinone in Example 1, when the decomposition assisting capacity is reduced by 25% (using the pulping additive of the present invention), the Kappa value and the rejection rate will be significantly reduced. In addition, when compared with the relative onionquinone content of each digestion aid, the interfacial active composition of the present invention can reduce the demand for anthraquinone by at least 50%. Other benefits of using digestive aids with lower anthracene content include: 1_ less fouling on distillation pipes and pipe plugs; and 2. reducing the pollution of the original oil slick in the pulp, thus reducing the slick oil refining The problem is to reduce the pollution during the initial fractionation of oil slick. Even though the present invention has been described in the references with regard to various specific raw materials, steps and examples, the present invention is not limited to specific raw materials, the combination of raw materials and the procedures selected for their purpose. The above details can be made on page 12. This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297). (Please read the precautions on the back and fill in this page first.) _Installation · fr A7 Staff Consumption of the Central Bureau of Standards, Ministry of Economic Affairs Cooperative printed 402Q52 B7 V. Description of the invention () Many changes' and can be understood by those skilled in the art. Page 13 n- HI n ^ ln I ^^^ 1 il ^ in ^ im «^ > HI mL • ^« J / ^ · ·, t pin (Please read the precautions on the back before filling this page) This Paper size applies to China National Standard (CNS) A4 (210X297 mm)