TW400237B - Air freshener dispenser device with combustible taper strand feature - Google Patents
Air freshener dispenser device with combustible taper strand feature Download PDFInfo
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- TW400237B TW400237B TW87113504A TW87113504A TW400237B TW 400237 B TW400237 B TW 400237B TW 87113504 A TW87113504 A TW 87113504A TW 87113504 A TW87113504 A TW 87113504A TW 400237 B TW400237 B TW 400237B
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M1/00—Stationary means for catching or killing insects
- A01M1/20—Poisoning, narcotising, or burning insects
- A01M1/2022—Poisoning or narcotising insects by vaporising an insecticide
- A01M1/2061—Poisoning or narcotising insects by vaporising an insecticide using a heat source
- A01M1/2066—Poisoning or narcotising insects by vaporising an insecticide using a heat source burning insecticide, e.g. impregnated candles, burning coils
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/02—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air by heating or combustion
- A61L9/03—Apparatus therefor
Abstract
Description
B7 五、發明說明(i) 發明背景 本發明係有關一種可蒸發性介質之散發裝置。更特 別言之,本發明係有關一種用於密閉環境之清淨空氣之以 蒸氣形式散發香料或除臭劑之裝置。 錯由臭味之掩敝或驅除而有效對抗家裡及密閉公共 建築物内之空氣°惡臭之需求已被建立。不同種類之蒸氣散 發裝置已因此目的而被使用之。最普遍之此等裝置係喷霧 劑容器,其將細微之空氣清香劑組成物之液滴推進於空氣 中。另一種普遍形式之散發裝置係含有或支撐膠質體之盤 形物,當其乾燥及縮收時會將蒸氣化之空氣處理組成物釋 於大氣中。其它諸如塊狀除臭劑之產物亦被用以藉由蒸發 將空氣-處理蒸氣散發於大氣内。另一類蒸氣散發裝置係使 用以可络發之組成物浸潰或塗覆之諸如紙板之負載材料。 最近之數種發展包含密閉器内之液態空氣處理組成 物,其所有或部份係由聚合物膜形成,經由此,空氣處理 組成物可移動而於外表面以蒸氣釋出。使用此種可滲透之 聚合物膜可控制空氣處理蒸氣之散發且易於除去產物壽命 期間散發速率之大量變化。 蕊裝置係已知之用以將蒸發液體(諸如,香水、除 臭;=1(1、殺窗劑或驅蟲活化劑)散發至大氣令。典型之蕊裝 置係使用蕊及散發區域之結合,以便自液體儲存器散發蒸 發之液體。 與本發明相關之背景同業之出版物包含美國專利第 2,090,297、2,379,250、2,818615、2,829,511、3,332,428 本紙張尺度適用中國國家標準(CNS)/U規格(2〗〇 χ ?97公发) Φ--- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 --線!^------------------ 1· n n (, 4 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明(2 )' 3,499,425 > 3,560,122 ' 3,705,890 ' 3,898,039 ^ 4,092,988 、4,568,270、5,538,018 及 5,569,779 號案,其等被併入以 供產考用。 美國專利第2,818,615號案描述一種除臭劑裝置,其 中可燃燒之芯以空氣清香劑浸潰,且當芯被點燃時,空氣 清香劑被釋出。 美國專利第2,829,511號案描述一種蠟燭蕊結構,其 係由與之棉花纖維結合之纖維之外棉網素乙酯之核線料組 成。 美國專利第5,538,018號案描述一種芳香劑釋放添加 劑’其係一種纖維素衍生物,其被併入香煙包裝紙内。 有·關於本發明之特殊興趣係香味燃燒器型式之裝 ’其係藉由緩慢之煙燻燃燒方式使香料蒸氣化。香味燃% 器型式之裝置被描述於美國專利第4,〇99,916、4,155 979、4,324,763、4,334,853 及 5,215,719 號案,其等案被併 以作參考用。 ^ 某些空氣清香劑散發裝置之製備係昂貴的。其它 氣清香劑散發裝置之製備雖不昂貴,但是易於具有較差 結構及功能。 仍存有一種結構良好之空氣清香劑散發裝置之需个 ,其可被具經濟性地大量製造且其可於長時間以—受控制 之均勻速率傳送蒸氣介質。 又工 因此,本發明之目的係提供一種用以於密閉環境内 傳送香味劑及/或除味劑蒸氣之改良式空氣清香劑散發裝 置 燒 入 空 之 求 (請先閱讀背面之注意事項再填寫本頁) .©· 表紙張尺度適用中國國家標準(CNS)A-l規格(21〇 X 297公釐)B7 V. Description of the invention (i) Background of the invention The present invention relates to a device for emitting a vaporizable medium. More particularly, the present invention relates to a device for emitting perfume or deodorant in the form of vapor for clean air in a closed environment. The need to effectively combat the stench of air in homes and enclosed public buildings by masking or dispelling it has been established. Different types of vapor emission devices have been used for this purpose. The most common of these devices are spray containers, which propel droplets of fine air perfume composition into the air. Another common form of distribution device is a disc that contains or supports colloids and releases the vaporized air treatment composition to the atmosphere when it is dried and retracted. Other products such as block deodorants are also used to disperse air-treatment vapors into the atmosphere by evaporation. Another type of vapor emitting device is a load material such as cardboard impregnated or coated with a composition that can be expanded. Several recent developments include a liquid air treatment composition in an enclosure, all or part of which is formed of a polymer film, through which the air treatment composition can be moved and released as vapor on the outer surface. The use of such a permeable polymer film can control the emission of air-treated vapors and easily remove large variations in the emission rate during the life of the product. Kernel devices are known to emit evaporated liquids (such as perfume, deodorant; = 1 (1, window killer or insect repellent activator) to the atmosphere. Typical Kernel devices use a combination of kernels and emission areas, To evaporate the liquid from the liquid reservoir. Background related publications related to the present invention include U.S. Patent Nos. 2,090,297, 2,379,250, 2,818615, 2,829,511, 3,332,428 The paper dimensions are applicable to Chinese National Standard (CNS) / U specifications (2 〖〇χ? 97 issued) Φ --- (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-line! ^ ---------- -------- 1.nn (, 4 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of Invention (2) '3,499,425 > 3,560,122' 3,705,890 '3,898,039 ^ 4,092,988, 4,568,270, 5,538,018 and 5,569,779 Case No., which was incorporated for production testing. US Patent No. 2,818,615 describes a deodorant device in which a combustible core is impregnated with an air deodorant, and when the core is ignited, the air deodorant is Released US Patent No. 2 No. 829,511 describes a candle core structure composed of a core material of cotton web ethyl acetate other than the fibers bound to cotton fibers. US Patent No. 5,538,018 describes a fragrance release additive 'which is a fiber The derivative is incorporated into cigarette wrapping paper. There is a special interest in the present invention is the flavor burner type package, which is used to vaporize the fragrance by a slow smoke combustion method. The flavor burner type is The device is described in U.S. Patent Nos. 4,099,916, 4,155,979, 4,324,763, 4,334,853, and 5,215,719, which are incorporated by reference. ^ Certain air fragrance dispensers are expensive to prepare. Others Although the preparation of the air freshener emitting device is not expensive, it is easy to have poor structure and function. There is still a need for a well-structured air freshener emitting device, which can be economically manufactured in large quantities and can be used for a long time The vapor medium is delivered at a controlled, uniform rate. Therefore, the object of the present invention is to provide a fragrance agent and / or remover in a closed environment. Modified air deodorant emitting device for scented steam is required to burn into the air (please read the precautions on the back before filling this page). © · The paper size applies the Chinese National Standard (CNS) Al specification (21〇X 297) %)
-*-r»J n n H ϋ n n I I I ^ n - -- i - I n I I I - n I - n I - I n - I - I 5 五、發明說明(3 ) 置。 本發明之另一目的係提供具有主要結構為塑材組件 之空氣清香劑散發裝置’該塑材組件可以熱成形裝置經濟 性地製備之。 θ 本發明之另一目的係提供一種空氣清香劑散發裝置 ’其特徵在於具有一含量之空氣清香劑組份之可燃性細長 形股條。 本發明之另一目的係提供一種空氣清香劑散發裝置 ,其藉由緩慢之煙燻燃燒蒸發空氣清香劑。 本發明之目的及優點可由附圖及範例而變得明顯。 發明之綜诚 本發明之目的係藉由提供一種空氣清香劑散發裝置 而達成之,此裝置包含: (a)具有内部健存腔室之容器; (b )可燃性細長形股條,其包含具有一含量之化學 性結合之空氣清香劑組份之纖維素基材,且該細長形股條 被置於該容器儲存腔室内; ' (c )推閉裝置,其形成橫過該容器頂部區段之隔板 :及 (d )乍孔管,其係以垂直延伸位置以該隔板支撐之 ,且其具有經該隔板至該容器儲存腔室之通道; 其中’該垂直管係用以自該容器儲存腔室接授及導 引該細長形股條之通過’且用以支撐自該管向上延伸之該 股條之外露端區段,且其中該細長形股條係用以在該細 A7-*-r »J n n H ϋ n n I I I ^ n--i-I n I I I-n I-n I-I n-I-I 5 5. Description of the invention (3). Another object of the present invention is to provide an air deodorant emitting device having a main structure of a plastic material component. The plastic material component can be economically prepared by a thermoforming device. θ Another object of the present invention is to provide an air fragrance dispersing device ′, which is characterized by a flammable elongated strand having a content of an air fragrance component. Another object of the present invention is to provide an air deodorant emitting device which evaporates the air deodorant by slow smoke combustion. The objects and advantages of the present invention will be apparent from the accompanying drawings and examples. Summary of the invention The object of the present invention is achieved by providing an air fragrance dispersing device, which device comprises: (a) a container having an internal health-saving chamber; (b) a flammable elongated strand, comprising Cellulose substrate with a content of chemically bound air deodorant component, and the elongated strands are placed in the container storage chamber; '(c) a push-close device that forms across the top area of the container Section of the partition: and (d) the first hole tube, which is supported by the partition in a vertically extended position, and which has a passage through the partition to the container storage chamber; where 'the vertical tube is used to Receiving and guiding the passage of the elongated strands from the container storage chamber and used to support the open-end section of the strands extending upward from the tube, and wherein the elongated strands are used to Fine A7
經濟部智慧財產局員工消費合作社印制衣 形股條被燃燒時將該化學性結合之空氣清香劑組份釋放至 大氣中。 圖示簡要說明 第1圖係本發明之具有封蓋之空氣清香劑散發裝置之 立面圖。 第2圖係第1圖之空氣清香劑散發裝置無封蓋時之上 視圖。 第3圖係第2圖之空氣清香劑散發裝置延線3_3所取得 之截面圖。 第4圖係第3圖之空氣清香劑散發裝置之該垂直管之 放大立面圖。 故佳實施例之描沭 第1圖係本發明之空氣清香劑散發裝置1〇於操作模式 前之立面圖。 如所例示者,第1圖之散發裝置10係由模製之塑膠容 器12及圓頂形封蓋14所構成。容器12及封蓋14可由聚合物 (諸如,聚乙烯、聚丙烯、聚苯乙烯、聚氣乙烯、聚乙酸 乙烤酯、乙酸纖維素酯' 聚醯胺、聚甲基丙烯酸酯等)注 射成型或熱成型模製而成。 各器12及封蓋14一般於空氣清香劑散發功能已被完 成後可被棄置。若容器12及封蓋14被設計成具有可再填充 空氣清香劑之延伸使用,其可由玻璃、金屬、木材、熱塑 性樹脂等構成之。 第1圖之空_氣清香劑散發裝置1〇,典型上具有環狀截 本紙張尺度適用中國國豕標準(CNS)A‘l規格·(21〇 X 297公爱) ------ο. — ----- 訂—· (請先閱讀背面之注意事項再填寫本頁) 五、發明說明(5 ) 面,其具有約6-12公分之高度尺寸及約2_5公分之侧面尺 寸。 第2圖係第1圖之空氣清香劑散發裝置ι〇於圓頂形封 蓋14被移除後之上視圖。隔板15與垂直管以及灰爐儲存裝 置19結合而呈—體。細長形股冑16被置於垂直管^内。 第3圖係第2圖之空氣清香劑散發裝置延線所取 得之截面圖。細長形股條16自容器儲存腔室導引·且以垂 直管18支撐。 細長形股條16可具有環狀截面,其具有約2-8毫米之 直备及至少約20公分之長度。細長形股條16典型上由纖 維素纖維(其係繞捲狀、摺狀、編織狀、編飾狀)組成。 訂 細長形股條16之纖維素基材可由諸如綿花、麻、亞 麻、麻纖維、木漿等來源獲得之。纖維素基材亦可為諸如 人造絲、烷基纖維素或酯化纖維素之纖維素衍生物之形式 此處所用之”纖維素”一辭係意指相對應於化學式為 [C6H7〇2(〇H)3]n 之/3 -纖維素聚糖, 其中,η係提供約1〇〇,0〇〇_2,〇〇〇〇〇〇之平均分子量之 整數。 第3圖之空氣清香劑散發裝置1〇例示用以當其於適當 位置時容納封蓋14之凹槽20。封蓋14亦可被可移動地固: 於容器12’如此可在未脫離下打開。 第3圖之散發裝置1〇之内部延伸緣22係固定並支撐隔 本紙張尺度適用中國國家標準(CNS)A4規格 (210 χ 297公釐_)The printed clothes of the employee cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs will burn the chemically bound air freshener component into the atmosphere when the strands are burned. Brief Description of the Drawings Fig. 1 is an elevational view of an air fragrance dispersing device with a cover according to the present invention. Fig. 2 is a top view of the air fragrance dispersing device of Fig. 1 without a cover. FIG. 3 is a cross-sectional view taken on line 3_3 of the air fragrance dispersing device of FIG. 2. FIG. 4 is an enlarged elevational view of the vertical tube of the air fragrance dispersing device of FIG. 3. FIG. Description of the preferred embodiment Fig. 1 is a front elevational view of the air fragrance dispersing device 10 of the present invention before the operation mode. As exemplified, the distribution device 10 of FIG. 1 is composed of a molded plastic container 12 and a dome-shaped cover 14. The container 12 and the lid 14 can be injection-molded from a polymer (such as polyethylene, polypropylene, polystyrene, polyethylene gas, polyethylene acetate, cellulose acetate, polyamide, polymethacrylate, etc.) Or thermoformed. Each of the containers 12 and the cover 14 may be disposed of after the air fragrance dispersing function has been completed. If the container 12 and the lid 14 are designed for extended use with a refillable air fragrance, they may be made of glass, metal, wood, thermoplastic resin, or the like. Picture 1 of the air_air freshener dispersing device 10, typically has a circular cut-off paper size applicable to China National Standard (CNS) A'l specifications · (21〇X 297 public love) ------ ο. — ----- Order — · (Please read the notes on the back before filling in this page) 5. Description of the invention (5) The surface has a height dimension of about 6-12 cm and a side dimension of about 2_5 cm . FIG. 2 is a top view of the air fragrance dispersing device of FIG. 1 after the dome-shaped cover 14 is removed. The partition plate 15 is integrated with the vertical pipe and the ash furnace storage device 19 to form a unitary body. The elongated femoral condyle 16 is placed in a vertical tube. Fig. 3 is a cross-sectional view taken from an extension line of the air fragrance dispersing device of Fig. 2. The elongated strand 16 is guided from a container storage chamber and is supported by a vertical tube 18. The elongated strands 16 may have a circular cross-section, having a straight length of about 2-8 mm and a length of at least about 20 cm. The elongated strands 16 are typically composed of cellulose fibers (which are wound in a rolled shape, folded shape, knitted shape, and braided shape). The cellulose substrate of the elongated strands 16 can be obtained from sources such as cotton, hemp, hemp, hemp fiber, wood pulp and the like. The cellulose substrate may also be in the form of a cellulose derivative such as rayon, alkylcellulose, or esterified cellulose. As used herein, the term "cellulose" means corresponding to the chemical formula [C6H7〇2 ( OH) 3] n / 3-cellulose, wherein η is an integer providing an average molecular weight of about 100,000 to 20,000. The air fragrance dispersing device 10 of Fig. 3 illustrates the groove 20 for receiving the cover 14 when it is in place. The lid 14 can also be movably secured to the container 12 'so that it can be opened without being detached. The internal extension edge 22 of the dispersing device 10 shown in Figure 3 is fixed and supported. The paper size is in accordance with China National Standard (CNS) A4 (210 χ 297 mm_)
I 五、發明說明(6) 板15。如第3圖所示’與垂直管18及灰燼儲存裝置19結合 之隔板15係可取回之單元。通道裝置促進具有細長形股條 16之儲存腔室之再填充。 隔板15、垂直管18及灰燼儲存裝置19可由相同或不 同之材料形成。灰燼儲存裝置19係一種選擇性特徵,因為 隔板15可作為收集殘留之灰燼。 隔板15、垂直管18及灰燼儲存裝置19之結合可為單 一結構’其係由玻璃、金屬或塑膠形成之》因為當垂直管 18於燃燒相時與細長形股條;[6接觸,垂直管1 8較佳係非 可燃性或熱阻性主體。 於細長形股條16之延伸端被點燃後,其以緩慢煙燦 向下燃燒至垂直管18之開口端,其間細長形股條16自己 媳滅。 第4圖係第3圖之垂直管18之放大立面圖。第4圖中之 縫21及是侧(未示出)上之另一縫21 一起提供細長形股條 16之前進裝置,其係由容器1〇之儲在腔室而經由垂直管18 。一對縫21使細長形股條16於垂直管18内呈手指狀操作 經濟部智慧財產局員工消費合作社印1 本發明一獨特處在於提供可燃性細長形股條16,其 係由具有一含量之化學性結合之空氣清香劑組份之纖維素 纖維所組成。 此處所用之”化學性結合”一辭係意指纖維素聚合物鏈 與空氣清香劑分子間之共價鍵,諸如,醚或酯鍵結。取代 度(D.S.)可為約0.05-3之間。 本纸張尺度適用中國國家標準(CNS)A.丨規格(210 X 297公釐) 9 A7 A7 經濟部智慧財產局員工消費合作社印製 B7 五、發明說明(7) 处所用《空氣清香劑辭係指包含諸如香 香料、諸如香茅油之驅蟲劑及諸如薄荷之治療劑。…之 本發明細長形股條之空氣清香劑成份可 =被共價鍵結至纖維細之任何潛在揮發性::: 適當之揮發性空氣清香劑化合物包含醇,諸如,十 —院醇、4-異丙基環己醇、葉香醇、里哪醇、香茅醇、法 尼醇薄何醇、3-反式-異莰基環己醇、苯甲基醇、苯 基乙基醇、3_苯基丙醇、3_甲基5_苯基戊醇、肉桂醇、昇 水片百里酚、丁子香酚、異丁子香酚、茴香醇、甲基 揚酸酯等。 其它適當之空氣清香劑化合物包含醛或酮,諸如, 己醛、癸醛、2-甲基癸醛、反式_2_己醛、3_羥基_2_ 丁酮 、一乙醯、香葉醛、香茅醛、甲氧基二氩_香茅醛、薄荷 網、香芽㈤、樟腦、詩酮、里香酮、甲基定香酮、大馬酮 '柏木基曱基酮、麝香酮、靈貓酮、2,4_二曱基_3_環己烯 羧基醛、2-庚基環戊酮、順-茉莉酮、二氫茉莉酮、環十 五烷酮、笨并酮、苯基乙醯醛、二氫肉桂醛、肉桂醛、α -戊基肉桂醛、乙醯苯酮、苯并丙酮、苯并苯酮、胡椒醛 等。 其它適當之空氣清香劑化合物包含醋,諸如,反式_2_ 己烯基乙酯、烯丙基3-環己基丙酯、曱基肉桂酯、苯甲基 肉桂酯、苯基乙基肉桂酯等。 醇空氣清香劑(諸如’香葉醇或薄荷醇)與纖維素 本紙張尺度適用中國國家標準(CNS)A-l規格(210 X 297公爱)I. Description of the invention (6) Plate 15. As shown in Fig. 3 ', the partition plate 15 combined with the vertical pipe 18 and the ash storage device 19 is a retrievable unit. The channel device facilitates the refilling of the storage chamber with the elongated strands 16. The partition 15, the vertical tube 18, and the ash storage device 19 may be formed of the same or different materials. The ash storage device 19 is an optional feature because the partition 15 can be used to collect residual ash. The combination of the partition plate 15, the vertical tube 18, and the ash storage device 19 can be a single structure 'It is formed of glass, metal or plastic' because when the vertical tube 18 is in the combustion phase, it contacts the elongated strands; [6, vertical The tube 18 is preferably a non-flammable or thermally resistive body. After the extended end of the elongated strand 16 is ignited, it burns down with a slow smoke to the open end of the vertical tube 18, during which the elongated strand 16 annihilates itself. FIG. 4 is an enlarged elevation view of the vertical pipe 18 of FIG. 3. The slit 21 in FIG. 4 and another slit 21 on the side (not shown) together provide an elongated strand 16 forward feeding device, which is stored in a chamber by a container 10 and passes through a vertical tube 18. A pair of slits 21 make the elongated strands 16 finger-shaped in the vertical tube 18 to operate the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 1 A unique feature of the present invention is the provision of flammable elongated strands 16 which have a content of It is composed of cellulose fibers which are chemically combined with air freshener components. As used herein, the term "chemically bonded" means a covalent bond between a cellulose polymer chain and an air freshener molecule, such as an ether or ester bond. The degree of substitution (D.S.) can be between about 0.05-3. This paper size applies Chinese National Standard (CNS) A. 丨 Specifications (210 X 297 mm) 9 A7 A7 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs B7 V. Description of the Invention (7) Means include perfumes such as fragrances, insect repellents such as citronella, and therapeutics such as mint. ... the air freshener component of the elongated strands of the present invention may = any potential volatility that is covalently bonded to the fiber fine ::: A suitable volatile air freshener compound contains an alcohol such as, -Isopropylcyclohexanol, geraniol, linalool, citronellol, farnesol bohol, 3-trans-isofluorenylcyclohexanol, benzyl alcohol, phenylethyl alcohol, 3 _Phenylpropanol, 3-methyl 5-Pentylpentanol, cinnamyl alcohol, thymol, eugenol, isoeugenol, anisyl alcohol, methyl salicylate, etc. Other suitable air fragrance compounds include aldehydes or ketones, such as hexanal, decanal, 2-methyldecanal, trans-2_hexanal, 3_hydroxy_2_butanone, monoacetam, geranal , Citronellal, methoxy diargyrene_citronellal, mint net, citronella, camphor, styrone, saponone, methyl levulone, damascenone's cypress ketone, musk ketone, civet Ketone, 2,4_difluorenyl_3_cyclohexene carboxyaldehyde, 2-heptylcyclopentanone, cis-jasmone, dihydrojasmone, cyclopentadecanone, benzone, phenylacetamidine Aldehydes, dihydrocinnamaldehyde, cinnamaldehyde, α-pentylcinnamaldehyde, acetophenone, benzoacetone, benzophenone, piperonal and the like. Other suitable air fragrance compounds include vinegar, such as trans-2-hexenylethyl, allyl 3-cyclohexylpropyl, fluorenylcinnamate, benzylcinnamate, phenylethylcinnamate, and the like . Alcohol air deodorant (such as ‘geraniol or menthol) and cellulose This paper size applies the Chinese National Standard (CNS) A-l specification (210 X 297 public love)
#--------"訂·|丨I——ί-^1ψ. (請先間讀背面之注意事項再填寫本頁)# -------- " Order · | 丨 I——ί- ^ 1ψ. (Please read the precautions on the back before filling this page)
-III-III
— — II 10 五、發明說明(8 ) A7 B7 聚合物之化學性鍵結可藉由形成碳酸酯鍵結而完成 之 O Cj R-0(!!ci+ 纖維食-►r-OCO- 纖維素 反應於諸如氫氧化鈉或有機胺之鹼性試劑存在中進 行快速。纖維素礙酸酯之製備被描述於諸如美國專利第 3,705,890及5,068,321號案,其等被併人以供參考。 另一於醇空氣清香劑與纖維素聚合物間形成鍵结之 化學方式係藉由於鹼反應條件下使用環氧氣丙燒。 0/ \ R-O-CK^CU 一 0¾ 十織維素二^ 0H. 織維素 ©-----—訂-------—線.!. (詩先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印制衣 諸如香茅經之酸或諸如葑酮之酮與纖維素聚合物之 化學鍵結可藉由於酸性條件下形成半縮醛(縮酮)及/或縮 搭(縮酮)而達成之: 適用令固"iii^NS)A4規格⑵ο X 297公爱) u B7五、發明說明(9 ) 0Η +「纖維素—纖雎ΐ素 H+— — II 10 V. Description of the invention (8) Chemical bonding of A7 B7 polymers can be accomplished by forming carbonate bonds O Cj R-0 (!! ci + fiber food-►r-OCO- cellulose The reaction proceeds quickly in the presence of a basic reagent such as sodium hydroxide or organic amines. The preparation of cellulose phytoesters is described in, for example, US Pat. Nos. 3,705,890 and 5,068,321, which are incorporated herein by reference. The chemical method for forming a bond between an alcohol air deodorant and a cellulose polymer is through the use of epoxy gas under the conditions of an alkaline reaction. 0 / \ RO-CK ^ CU-0¾ ten oryzanol ^ 0H. Oryzanol © -----— Order -------— Line.!. (Read the notes on the back of the poem before filling out this page) The Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives, printed clothes such as lemongrass Or the chemical bonding of ketones such as fluorenone with cellulose polymers can be achieved by the formation of hemiacetals (ketals) and / or ketals (ketals) under acidic conditions: Applicable order solids " iii ^ NS) A4 specifications (⑵ο X 297 public love) u B7 V. Description of the invention (9) 0Η + "cellulose-cellulose H +
K^GO·®·2 + 纖維素. ITK ^ GO · ® · 2 + cellulose. IT
諸如笨基乙基肉桂酯空氣清香劑之酯與纖維素聚合 物之化學鍵結可藉由於鹼性條件下之麥可加成反應而達成 之: -------------Q-----------訂 (請先閱讀背面之注意事項再填寫本頁)The chemical bonding of esters such as benzyl ethyl cinnamyl air deodorant with cellulose polymers can be achieved by the addition reaction of wheat under alkaline conditions: ------------- Q ----------- Order (Please read the notes on the back before filling this page)
線 I 經濟部智慧財產局員工消費合作社印製Line I Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs
麥可加成反應被描述於諸如美國專利第2,415,〇4〇及 5,569,779號案等文獻内,其等被併入以作參考用。 本發明細長形股條中之空氣清香劑組份與纖維素基 材之化學性鍵結提供習知技術未達成之明顯優點。 二氣μ香劑成份僅於細長形股條被燃燒時釋出。办 虱清香劑係以保持之固定速率之熱解而釋放之。The Michael addition reaction is described in documents such as U.S. Patent Nos. 2,415,040 and 5,569,779, which are incorporated by reference. The chemical bonding of the air freshener component in the elongated strands of the present invention with the cellulose substrate provides significant advantages not achieved by conventional techniques. The two-gas μ fragrance is released only when the elongated strands are burned. Lice deodorants are released at a constant rate of pyrolysis.
本紙張尺度適用中國國家標準(CNSM4規格⑵〇 X 297公茇)' 12 A7 五、發明說明(10) 人以化學性鍵結之空氣清香劑組份之量可藉由選用之 σ成條件於D.S.範圍約0.05-3内被預先決定之。 “因為空氣清香劑組份被化學性鍵結,其無因移動及 黑·發而造成空氣清香劑之過早損失。 本發明之空氣清香劑散發裝置可由便宜之材料輕易 組成,且使用後可安全地棄置。 二 本發明之空氣清香劑散發裝置較家用之蠟燭具較少 之毐性,因細長形股條係以煙燻,而非以開放火焰燃燒之 ’且不具有小池狀之會溢出之熔融蠟。 因為細長形股條燃燒之緩慢燃燒性質,本發明空氣 清香劑散發裝置之細長形股條之儲在供應器可作為延長使 用期之頻繁使用。 下列範例係進一步例示本發明。組份及特殊成份係 如典型般表示之,且各種不同改良可於本發明範圍内基於 前述揭露而衍生之。 範例1 此範例例示香葉醇環氧丙醚。 經濟部智慧財產局員工消費合作社印製This paper size applies the Chinese national standard (CNSM4 specification ⑵〇X 297 公 茇) '12 A7 V. Description of the invention (10) The amount of the air deodorant component chemically bonded by the person can be determined by using σ as the condition. The DS range is predetermined within about 0.05-3. "Because the air freshener components are chemically bonded, there is no premature loss of the air freshener due to movement and darkening. The air freshener emitting device of the present invention can be easily composed of cheap materials and can be used after use. Dispose safely. 2. The air fragrance dispersing device of the present invention is less susceptible than domestic candles, because the elongated strands are smoked instead of burning with an open flame and do not have a small pool shape. The molten wax. Due to the slow burning properties of the elongated strands, the storage of the elongated strands of the air fragrance dispersing device of the present invention in the dispenser can be used frequently for prolonged use. The following examples further illustrate the present invention. Group And special ingredients are represented as typical, and various improvements can be derived based on the foregoing disclosure within the scope of the present invention. Example 1 This example illustrates geraniol propylene oxide. Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs system
香葉醇(100克)被滴入攪拌之50%氫氧化鈉水溶液 m--------Ϊ 訂------.---線 —φ----------------------- (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A.l規格(210 X 297公釐) 13 經濟部智慧財產局員工消費合作社印製 ___B7___ 五、發明說明(U) (300¾升)、環氧氯丙烧(300克)及四丁基錄氫硫酸鹽 (60克)之混合物,且冷卻以保持20EC之溫度。 於18小時之反應期後,混合物被倒入水中(1公升) ’水性介質以氯仿萃取。萃取層以水清洗,於硫酸納上乾. 燥並過渡之,於蒸發溶劑後回收油狀產物。NMR及IR端 認其結構。Geraniol (100 g) was dropped into a stirred 50% aqueous sodium hydroxide solution m -------- Ϊ Order ------.--- line—φ -------- --------------- (Please read the notes on the back before filling out this page) This paper size is applicable to China National Standard (CNS) Al specification (210 X 297 mm) 13 Ministry of Economic Affairs Printed by the Intellectual Property Bureau's Consumer Cooperative ___B7___ V. Mixture of Invention Description (U) (300¾ liters), epichlorohydrin (300 g), and tetrabutyl hydrosulfate (60 g), and cooled to keep 20EC temperature. After a reaction period of 18 hours, the mixture was poured into water (1 liter) 'and the aqueous medium was extracted with chloroform. The extraction layer was washed with water, dried over sodium sulfate, dried and transitioned, and the oily product was recovered after the solvent was evaporated. The structure was confirmed by NMR and IR.
範例II 此範例例示依據本發明製備空氣清香劑取代之細長 形股條。 配置以迴流冷凝器及攪拌器之反應器被注以己烷(i 公升)、荷性溶液(20克之50%之氫氧化鈉水溶液)及飾 帶狀槔花線料(30克)。混会物於25EC之氮氛圍下攪拌3〇 分鐘。 香葉醇環氧丙醚(50克)被添加至漿料内,所形成 之反應混合物於80EC加熱8小時。然後,混合物被冷卻至 室溫,以冰醋酸中和,並過渡之。 回收之棉花線料以丙酮清洗,然後以水清洗β乾燥 後’固態NMR顯示棉花線料之纖維素基材具有〇362D.s 〇 綿花線料一端被點燃,其係以無火焰生成而煙燦之 。線料之燃燒释放出玫瑰花香,其係香葉醇之特性。Example II This example illustrates the preparation of an elongated strand replaced by an air freshener in accordance with the present invention. The reactor equipped with a reflux condenser and stirrer was filled with hexane (i liters), a charging solution (20 g of 50% aqueous sodium hydroxide solution), and a ribbon-shaped linden thread (30 g). The mixture was stirred under a nitrogen atmosphere of 25EC for 30 minutes. Geraniol glycidyl ether (50 g) was added to the slurry, and the resulting reaction mixture was heated at 80EC for 8 hours. The mixture was then cooled to room temperature, neutralized with glacial acetic acid, and transitioned. The recovered cotton thread was washed with acetone, and then washed with water. After β-drying, the solid state NMR showed that the cellulose substrate of the cotton thread had 0362D.s. One end of the cotton thread was ignited. Of it. The burning of the strands releases the fragrance of roses, which is the characteristic of geraniol.
範例III 此範例例示以香水混合物替代之本發明細長形股條 之製備。 (請先閱讀背面之注意事項再填寫本頁)Example III This example illustrates the preparation of an elongated strand of the invention replaced by a perfume blend. (Please read the notes on the back before filling this page)
-------丨訂---------線 II------- 丨 Order --------- Line II
14 A7 B7 五、發明說明(12) 經濟部智慧財產局員工消費合作社印製 依據範例I之一般程序,環氧丙醚以香油之組份形成 之: 份數 經基香茅醇 18.0 肉桂醇 1.7 $占品醇 8.0 苯甲基醇 18.0 . 苯乙基醇 20.0 里哪醇 2.0 以相同於範例π所述之方式 ,飾帶狀之棉花股條以 環氧丙醚混合物處理,以使香水組份化學性鍵結至飾帶狀 棉花之-纖維素基材(D.S.為0.6)。 棉花股條點燃後釋出紫丁香之味道。 範例IV 此範例例示製備以香水混合物替代之本發明細長形 股條。 依據範例I之一般程序,環氧丙謎以香油之組份形成 之: 份數 羥基香茅醛 50.00 苯曱基醇 4.0 香葉醇 3.0 香茅醇 3.0 里哪醇 3.0 (請先閱讀背面之注意事項再填寫本頁} 訂----;.!線 ΙΦ---------------------- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公爱) 15 經濟部智慧財產局員工消費合作社印制^ A7 _____B7 五、發明說明(13) 以相似於範例Π所述之方式’飾帶狀之棉花股條以 環氧丙醚混合物處理,以使香水組份化學性鍵結至飾帶狀 棉花之纖維素基材(D.S.為1.8)。二曱基甲醯胺及氯化鐘 於反應處理中作為額外之成份’以增加纖維素基材中之 D.S.。 棉花股條點燃後釋出百合花之味道。 範例V , 此範例例示薄荷基氯曱酸酯之製備。 乾冰/丙酮浴(-75EC)内之反應器被注入液態之光氣 (117克)》溶於120毫升環戊烷内之薄荷(130克)被滴入 光氣内並攪拌之9反應介質於室溫迴流6小時。 過_量之光氣及環戊烷於.減壓下移除。移除之薄荷基 氣曱酯被溶於二乙基醚(60mL ) ’且溶液以水性二碳酸鈉 清洗,然後以蒸餾水清洗。液態介質於硫酸鈉上乾燥,且 溶劑於減壓下移除而產生純化之甲基氣甲酯。14 A7 B7 V. Description of the invention (12) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs in accordance with the general procedure of Example I, glycidyl ether is formed from the components of sesame oil: the parts are based on citronellol 18.0, cinnamyl alcohol 1.7 $ 占 品 醇 8.0 Phenyl alcohol 18.0. Phenyl alcohol 20.0 Linalol 2.0 In the same manner as described in Example π, the ribbon-shaped cotton strands are treated with a glycidyl ether mixture to make the perfume component Chemically bonded to the cellulose substrate of the ribbon-like cotton (DS 0.6). The cotton strands ignite and release the smell of lilac. Example IV This example illustrates the preparation of an elongated strand of the present invention replaced with a perfume blend. According to the general procedure of Example I, the propylene oxide puzzle is formed from the components of sesame oil: parts of hydroxycitronellal 50.00 benzyl alcohol 4.0 geraniol 3.0 citronellol 3.0 linalol 3.0 (please read the note on the back first) Please fill in this page again for the order} Order ----;.! Line ΙΦ ------------------------ This paper size applies to China National Standard (CNS) A4 (210 X 297 public love) 15 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ^ A7 _____B7 V. Description of the invention (13) In a manner similar to that described in Example Π ', the ribbon-shaped cotton strands are propylene oxide The mixture is processed to chemically bond the perfume components to the cellulose substrate of the ribbon-like cotton (DS 1.8). Dimethylformamide and chlorinated bellies are used as additional ingredients in the reaction treatment to increase the fiber. DS in a plain substrate. The cotton strands ignite and release the smell of lilies. Example V, This example illustrates the preparation of menthol chloroacetate. The reactor in a dry ice / acetone bath (-75EC) is filled with liquid Phosgene (117 g) "mint (130 g) dissolved in 120 ml of cyclopentane was dropped into the phosgene and stirred. The medium was refluxed at room temperature for 6 hours. The excess amount of phosgene and cyclopentane were removed under reduced pressure. The removed menthol-based phytostilbene ester was dissolved in diethyl ether (60 mL) and the solution was water-based. It was washed with sodium carbonate and then with distilled water. The liquid medium was dried over sodium sulfate, and the solvent was removed under reduced pressure to produce purified methyl gas methyl ester.
範例VI 此範例例示依據本發明製備薄荷基碳酸酯取代之細 長形股條。 400克之多纖維人造絲(North American Rayon, 4321 絲)被懸浮於吼咬(1 800克)與笨(3公升)所成之摻合 物,混合物於室溫攪拌20小時。 1200克之薄荷基氯甲酸酯於室溫被滴入授拌之反應 介質。於80EC之反應溫度攪拌持續1 〇小時。冷卻過濾後 ,回收之股條產物以苯清洗’然後以異丙醇及水清洗。股 本纸張尺度適用中國國家標準(CNS)A.l規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁)Example VI This example illustrates the preparation of menthol carbonate-substituted thin elongated strands according to the present invention. 400 grams of multi-fiber rayon (North American Rayon, 4321 silk) was suspended in a blend of roaring bites (1,800 grams) and stupid (3 liters), and the mixture was stirred at room temperature for 20 hours. 1200 grams of menthol chloroformate was dropped into the stirred reaction medium at room temperature. Stir at a reaction temperature of 80EC for 10 hours. After cooling and filtering, the recovered strand product was washed with benzene 'and then with isopropanol and water. The size of the equity paper is applicable to the Chinese National Standard (CNS) A.l specification (210 X 297 mm) (Please read the precautions on the back before filling this page)
Ϊ--------r ^ · 111---1I 16 ! A7 B7 五、發明說明(14) 條產物具有0.9之薄荷基碳酸酯D.S.。 細長形股條之煙燻燃燒釋出之可輕檢測出之薄荷味 於大氣中。 範例YU 此範例例示依據本發明製備香茅縮醛取代之細長形 股條。 反應益被配置授掉gg及具有水移除單元之迴流冷凝 器。反應器被注入苯(500毫升)、對_曱苯磺酸(5〇毫克 )、香茅油(50克)及飾帶狀棉花股條(3〇克)。 混合物被迴流加熱並攪拌之,至無水以共沸物夾雜 出。冷卻後,酸催化劑以氫氧化銨中和。混合物被過濾, 且回收之棉化股條以水清洗。乾燥後,固態NMR顯示棉 花股條之纖維素基材具有約〇.2之d.s。 細長形股條之煙燻燃燒將溫和之香茅油味釋入大氣中。 (請先間讀背面M江意事頌與填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS)A-l規格(210 X 297公髮)Ϊ -------- r ^ · 111 --- 1I 16! A7 B7 5. Description of the invention (14) The product has 0.9 of menthol carbonate D.S. The lightly detectable mint flavor released by the smoky combustion of the elongated strands is in the atmosphere. Example YU This example illustrates the preparation of citronellal-replaced elongated strands according to the present invention. The reaction benefit is configured to grant gg and a reflux condenser with a water removal unit. The reactor was charged with benzene (500 ml), p-toluenesulfonic acid (50 mg), citronella oil (50 g), and ribbon-shaped cotton strands (30 g). The mixture was heated at reflux and stirred until no water was included as azeotrope. After cooling, the acid catalyst was neutralized with ammonium hydroxide. The mixture was filtered and the recovered cotton strands were washed with water. After drying, solid state NMR showed that the cellulose substrate of the cotton strands had a d.s of about 0.2. The smoky burning of the elongated strands releases the mild citronella flavor into the atmosphere. (Please read the tribute to M Jiang on the back and fill in this page first) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper size applies to China National Standard (CNS) A-l specifications (210 X 297)
I 1^— - n I - -*-p°J_ _n n I ϋ n ! I I I I--.1 HI ϋ 11 1 n - n - - - - - I - - n n I I 17 4002Sr/ A7 _B7_ 五、發明說明(15) 元件標號對照 10 散發裝置 18 直管 12 塑膠容器 19 灰燼儲存裝置 14 圓頂形封蓋 20 凹槽 15 隔板 21 缝 16 細長形股條 22 内部延伸緣 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 -I - — — III 1' I^OJ*1! — — — — — — I — — — — — — — — — — — — — — — — — — — — — I. 本紙張尺度適用中國國家標準(CNS)A-l規格(210 X 297公釐) 18I 1 ^--n I--*-p ° J_ _n n I ϋ n! III I-. 1 HI ϋ 11 1 n-n-----I--nn II 17 4002Sr / A7 _B7_ V 、 Description of the invention (15) Comparison of component numbers 10 Dispersion device 18 Straight tube 12 Plastic container 19 Ash storage device 14 Dome-shaped cover 20 Groove 15 Partition 21 Slot 16 Slim strand 22 Internal extension edge (please read the back Please fill in this page again for attention) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy -I-— — III 1 'I ^ OJ * 1! — — — — — — I — — — — — — — — — — — — — — — — — — — — — I. This paper size applies to China National Standard (CNS) Al specification (210 X 297 mm) 18
Claims (1)
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US91285297A | 1997-08-19 | 1997-08-19 |
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TW400237B true TW400237B (en) | 2000-08-01 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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TW87113504A TW400237B (en) | 1997-08-19 | 1998-09-18 | Air freshener dispenser device with combustible taper strand feature |
Country Status (3)
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AU (1) | AU8912198A (en) |
TW (1) | TW400237B (en) |
WO (1) | WO1999008721A1 (en) |
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EP1774982A1 (en) * | 2005-10-14 | 2007-04-18 | Fritz Altmann | A phial for a perfuming and/or deodorising device |
PT105270B (en) | 2010-08-26 | 2012-05-31 | Domino Ind Ceramicas S A | LAYER OF SILICA WITH SLOW RELEASE OF FRAGRANCE, CERAMIC TILE AND RESPECTIVE PRODUCTION PROCESS |
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FR732458A (en) * | 1932-02-29 | 1932-09-21 | Device for the evaporation of a liquid and the absorption of bad odors, fumes, etc. | |
GB2199246B (en) * | 1987-12-07 | 1990-02-14 | Ki Yip Chemical Works Limited | Wax air freshener |
US5690484A (en) * | 1996-01-26 | 1997-11-25 | S. C. Johnson & Son, Inc. | Candle wick holder |
-
1998
- 1998-08-18 WO PCT/US1998/017079 patent/WO1999008721A1/en active Application Filing
- 1998-08-18 AU AU89121/98A patent/AU8912198A/en not_active Abandoned
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WO1999008721A1 (en) | 1999-02-25 |
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