TW388714B - Low silicone hair conditioning shampoo and non-silicone hair conditioning/style control shampoo - Google Patents

Abstract

A hair conditioning shampoo comprising an aqueous dispersion of a water-insoluble lipid phase, an anionic hair-cleansing surfactant and at least one hair conditioning, film-forming, polycationic polymer soluble in the aqueous disper-sion and 0-6% by weight, based on the weight of the shampoo, of a water-insoluble, non-volatile hair conditioning silicone, the water-insoluble lipid phase comprising at least one lipid-soluble, emulsifiable, monocationic, quaternary ammonium com-pound or amine solubilized in a water-insoluble long chain lipid compound, the weight ratio of moncationic compound to the lipid compound in the lipid phase being in the range of from about 5:1 to about 1:10 and the molar ratio of anionic surfactant to water-insoluble cationic compound is greater than 2:1 The shampoo having no silicone possesses a high degree of style control properties. The shampoo containing silicone has a high degree of hair conditioning properties.

Description

Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperative, A7 B7 V. Description of the Invention (1) The relevant application I The animal case was established on December 3, 1992, and is in the United States queue No. 07 / 984,786 under trial After the mining part, the latter was read after the American queue number No. 07 / 507,335, which was built on April 9, 1990. The current American queue number 5,213,716 was broadcasted on the American queue number on January 21, 1989. Ν〇 · 07 / 369,361 (abandoned) after the mine part, Jianye US serial number on January 21, 1989 No. 07 / 369,389 (abandoned), built on November 7, 1989 US serial number No. 07 / 432,644, the current US patent 5,051,250, and the US serial number No. 07 / 432,952 (released) of Jianye on November 7, 1989. The invention is related to a kind containing a small amount Or shampoo for hair that does not contain water-insoluble silicon _ hair conditioner. > The so-called "two-in-one" product of Yifengfangxiong's Jiefeng can simultaneously moisturize and cleanse the hair has been formulated. It has been used for a long time to separate the composition onto the hair. Disadvantages of achieving this type of purpose; previously, one shampoo was used to clean the hair, and another separate conditioner was used to condition the hair.巳 Some phosphonium compounds and polymers have been found to be excellent hair conditioners. However, when mixing these agents with anionic surfactants, which is known to be the most effective at removing sebum, sludge, and other atmospheric pollutants, into these shampoo formulas, these two types of agents can be ineffective. Compatibility issues arise. As soon as the negatively charged anionic surfactant and positively charged cationic surfactant are in contact, they will precipitate or cause the anion to interact with the male compound 3 — This paper size applies to the Chinese National Standard (CNS) A4 specification (210 × 297 mm) Pretend to be a ^ line (please read the notice on the back \! ^ Fill in this page > 丨 printed by A7 ___B7___ of the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Description of the invention (2) Interactions have significantly reduced their differences Cleansing and moisturizing properties. The decrease in detergency and moisturizing effect can be clearly seen even in compositions whose anions and ion-limiting compounds do not sink from the composition but remain in solution or suspension. This type of incompatibility between anionic surfactants and Yangweizi Lake compounds is well known to those working in the bank. For example, in the harmfulness of Cosmetics (New York, Interscience Publishers, Inc., published, No. P. 538), the author Sagarin stated that the anions and the male compound must not be used together because they will form insoluble salts. Part of the incompatibility problem is to use a partial solution in this shampoo formula for hair, replacing non-ionic, amphoteric or zwitterionic surfactants in conventional shampoos containing cationic conditioners. Anionic surfactants. See, for example, U.S. Pat. No. 3,849,348 (Hewitt); 3,990,991 (Gerstein); and 3,822 · 312 (Sato). Another difficulty in formulating hair conditioners with a hair conditioning effect is when water-insoluble The instability problem caused by the conditioner when it is added to the shampoo composition, for example, the case of adding non-volatile silicones, which is well known in the art to soften the hair to a certain degree. The substance that puts the sugars in the shampoo composition has been disclosed in many of the previous foods, such as the United States and the United States (J: 2,826,551 (Green); 3,964,500 (Drakoff); 4,364,837 ( Pader); 4,741,855 (Grote et al); 4.788,006 (Bolich, Jr. et al); 4,902,499 (Bolich, Jr. et al); 4,704,272 (Oh et a 1); and UK No. 849, 433 (Woolston ) ° —4 — This paper is applicable to national standards (CN S) A4 size (210X297 mm) (please read the note on the back first and fill in this page) 7, outfit: hard copy 1T- printed by male labor consumer cooperative of Central Ladder Bureau of the Ministry of Economic Affairs A7 _'_ B7_ V. Invention Explanation (3) The particular difficulty in overcoming silicone-containing conditioner shampoos is to maintain a stable, suspended state of a dispersed, insoluble, non-volatile silicon rhenium material while maintaining this. The cleansing and conditioning properties of hair shampoo. As mentioned above, in a shampoo for wine hair containing an anionic surfactant and a hair conditioner, it is particularly difficult because of their tendency to interact with each other. For the purpose of thickening or stabilization, various materials have been proposed for use in silicon shampoo-containing shampoos, such as xanthan gum, long bond derivatives, long bond amidine Oxides, and long-dimensional fermenting glycosamines, such as those disclosed in the aforementioned U.S. Patent Nos. 4,788,006, 4,704,272 and 4,741,855. The use of silicones has been tested by environmental researchers because they are less susceptible to biodegradation. In addition, there are handling problems when using silicones, especially due to the high viscosity of silicones. Finally, silicone is difficult to remove from the hair, reducing the effectiveness of ironing and dyeing. Many alfalfas want to provide the "three-in-one" shampoo composition, that is, to provide a shampoo formula that after shampooing and rinsing, not only has the effect of cleaning the hair, but also has a moisturizing effect and control Styling or leaving hair wavy and curly. The hair conditioning effect usually means that the hair can be softened and smoothed after shampooing, no stickiness, easy combing, no hard or rough feeling after shampooing, no static electricity and easy handling. Hair styling, that is, maintaining the wavy and curly state of the hair after blowing, can be achieved in two ways. First, the hair is subjected to a permanent chemical treatment to achieve the desired shape. Secondly, temporarily change the shape of the hair, usually at -5-(Please read the precautions on the back V and fill in this page to bind " thread paper X degree, using Chinese National Standard (CNS) A4 specifications (210X297 mm) Printed by A7 _B7__ of the Industrial and Commercial Cooperatives of the Central Bureau of Standards and Commerce of the Ministry of Economic Affairs 5. Description of the Invention (4) After shampooing and / or moisturizing the hair, use the third composition M to achieve this. The materials for temporary styling control are traditionally used resins, gums, etc., and mousse, gel, lotion or spray, etc. that are usually added to the hair that has been washed and / or conditioned, and will be treated. After the headwear is dried, the resin or gum material is fixed in a rigid state to temporarily maintain the hair in the desired shape. This temporary styling agent is different from the permanent styling treatment in the subsequent shampooing operation. The permanent styling is limited and the temporary agent will be completely washed away. After each shampoo, you need to apply it again to maintain the desired hairstyle. One type of temporary hair control agent is a viscous polymer. Usually includes Water-based solvent, and a rigid polymer with a glass transition temperature higher than the reachable setting operation (that is, the temperature of hair styling), etc. Examples of fluorene polymers are listed in U.S.A. 3,743,715, 4,165,367 and 4,223,039 Disclosed. Other previously recommended polymers for temporary modeling are multi-component polymers that include up to four or more monomers. This type of modeling polymer system is disclosed in US Patent J3 , 222,329, 3,577,517, 4,012,501 and 4,272,511. Block copolymers with various glass transition temperatures can also be used as styling agents, such as U.S. Patent Nos. 3,907,984, 4,030,512 and 4,283,384. U.S. Patent 5,104,642 discloses one application. The polymer in the hair styling composition includes the first polymerizable hydrophilic monomer up to 50 × and the remaining one. 6 — This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm). 1T- (Please read the notes on the back ^ F% first write this page) 、 Printed by the Shellfish Consumer Cooperative of the Central Government Bureau of the Ministry of Economic Affairs «. A7 _I__B7_ V. Description of the invention ( 5) a second polymerizable hydrophilic monomer, the obtained polymer has a molecular weight of 5,000 to 1,000,000, a glass-ring state temperature · Tg, which is greater than -20 X: and a solubility parameter, which is 8.5 to 12.0. The international application number is PCT / USQl / 02170, published on October 17, 1991. A polymer of this type is added to the shampoo formula. Canadian Patent No. 2,033,626 discloses a method that provides Type shampoo composition that maintains curliness and includes at least one anionic surfactant, a film-forming copolymer (eg, polymers JR, GAFQUAT 755, MERQUAT 550, chitin or its derivatives, CROQUAT S, LAMEQUAT L or Methyl Ethyl Brand_Sickle Gas / Ethyl Btfc Pyrrolidone Copolymer and a Large Amount of Citric Betulinic Acid to Improve the Effect of Film-forming Polymers. This article does not mention that such shampoo formula has the characteristics of hair conditioning. The object of the present invention is to provide a shampoo with a moisturizing effect, which can solve various problems of the aforementioned documents. Another object of the present invention is to provide a shampoo with high hair conditioning effect and a shampoo for full hair which can control the shape. The invention of Long's invention is capable of achieving various purposes according to the present invention. What the present invention relates to is an aqueous dispersion containing an insoluble lipid phase, an anionic surfactant for cleaning hair, and at least one moisturizing agent. Hair-forming, film-forming, polyionic polymer with 0-6 «Inner meter (M shampoo weight is based on weight) insoluble, non-volatile silicone hair turbidity agent, The cationic polymer is dissolved in the aqueous solution of the detergent; the water-insoluble lipid phase includes at least one lipid-soluble, emulsifiable, monofluoride-based * -7-(Please First read the note on the back of $ 4 to complete this page.) Binding, the size of the paper is applicable to the Chinese National Standard (CNS) A4 (210X297 mm). Printed by the Central Labor Bureau of the Ministry of Economic Affairs. (6) a quaternary ammonium compound or an amine dissolved in a water-insoluble long-bond lipid compound, the weight ratio of the monocationic compound to the lipid compound in the lipid phase is from about 5: 1 to about 1:10, And anionic surfactants are relatively The mole ratio of the water-soluble male seed compounds is greater than 2: 1, preferably about 2: 1 to about 50: 1, and most preferably about 5: 1 to about 30: 1. The invention is based on the discovery of an oil-filled sharp shampoo. The present invention is based on the discovery of a water-containing shampoo for hair conditioner, which contains a female surfactant and a polyionic hair conditioner that can be dissolved in a cleaning agent and a relatively low amount of insoluble in water. Non-volatile silicone conditioner, which is present in the water-insoluble lipid phase of shampoo, has a single ion-dissolving, lipid-soluble conditioner, and the resulting shampoo has better condition Hair effect and cleansing hair characteristics, while avoiding the many shortcomings of qualitative and reduced effectiveness that occur with the traditional two-in-one shampoo formula. Unexpectedly, in the shampoo for hair conditioner of the present invention, the effect of the monocationic compound dissolved in the lipid provides synergy rather than competition for the water-soluble polycationic polymerizable agent, although With only a few Dong-Kong-hair conditioners, the effect provided by the conditioner is also stronger than that provided by traditional shampoos. In addition, it is generally believed that the presence of the lipid phase will greatly reduce the anxiety of the anionic surfactant / cationic conditioner mixture by limiting the contact between the oppositely charged individual ingredients in the formulation. The lipid phase of the single-agent-containing agent appears to function as a water-insoluble hair conditioner, much like silicone, but without the disadvantages associated with typical water-insoluble hair conditioners, such as instability, There is a tendency for uneven coating on the hair. 8 8 This paper size is in accordance with Chinese National Standard (CNS) A4 * l (210X297 mm) ---------_ Ί ^-(Please read the Note $ item on the back '^ write this page) 1Τ- • n I If A7 __B7_ V. Description of the Invention (7) The most unexpected is "" It has been found that if water-insoluble and non-volatile xanthone conditioner is not used in the above formula, Shampoo has the function of hair styling. It is also not expected that the shampoo formula of the present invention which does not contain ketones has a high degree of repair of damaged hair, including the effect of split ends, K and a high degree of styling durability. The critical feature of the present invention lies in the lipid / lipid-soluble monocationic conditioner phase of such a shampoo for conditioner. Suitable lipid-soluble mono-positive compounds that can be included in the lipid phase of the shampoo are any long-chain aliphatic, mono-ion, quaternary ammonium compounds, or amines having at least one long-chain aliphatic group Is preferably an alkyl group, and it is preferably one having about 16 to about 40 carbon atoms on average. Amines have a suitable pKa value, i.e., at least about 7.5. In shampoos with a pH of 6 or less, they are partially protonated and provide the necessary cationic charge to act as a haze. The shampoo for hair conditioners of the present invention may include any auxiliary substances conventionally used in such shampoos, such as those disclosed in U.S. Patent No. 5,078,990. For example, amphoteric or amphoteric chickling surfactants can be used as co-surfactants. In some preferred shampoo formulations (see Examples 1, 5 and 7 below), amphoteric surfactants are the main cleaning agents. Suitable such amphoteric surfactants include those having the following formula:

Ri

I R ——H + — RX00 a

I

Ri -9 A paper size using the Chinese National Standard (CNS) A4 size (210X297 mm) (Please read the precautions on the back first ^ i ^ i ^^ 1 I write this page) Order the Central Bureau of the Ministry of Economic Affairs Printed by Shelley Consumer Cooperative, printed by the Central Standards Bureau of the Ministry of Economic Affairs, Shelley Consumer Cooperative, printed A7 _____B7__ V. Description of Invention (8) Among them, R is Ce-Cl 8 fluorenyl or C8 -Cl 8 burned amine, C2 -C3 An alkyl group, Ri is a Cl-C3 alkyl group, R2 is a Ci-C4 alkenyl group or a Cl-C4 diradical group, and X is C or SiO. When X is C, this detergent is called lactam, and when X is SiO, this type of detergent is called thioindicator. These zwitterionic detergents can be broadly defined as containing C8- Ci 8 is a straight or branched aliphatic group and an anionic group containing an aliphatic saddle or a tertiary sulfur compound derivative. The preferred inner strong and thio inner saddle cleaners are coconut aminopropyl propyl betaine, dodecyl dimethyl is stronger than acetic acid, tetradecyl dimethyl mesyl acetate, c8 -Ci 8Aromatic propyl dimethyl diacetate S8 1- (tetradecyl dimethyl ammonium) -propane-3-sulfonate and 1- (tetradecyl dimethyl protyl) -2 -Propidium-3-sulfonate. The reference material of the present invention is U.S. Pat. No. 5,078,990 (Martin et al), which states that a long-chain sulfanyl sulfate and / or a long-chain alkyl sulphate-containing surfactant and an ionic donor The water-soluble shampoo of bis-long-chain alkyl quaternary ammonium nitrogen compounds has an unexpectedly increased ability to (1) add a water-insoluble hair conditioner, especially a non-volatile silicon tincture material, and (2) Remove the previously applied conditioner and other solid conditioners and dirt on the hair. However, this product must contain a water-insoluble hairspray and specifically requires that the mole ratio of the female surfactant to the long-chain quaternary ammonium compound should be at least about 85: 1, and the ratio is higher and better. Any of the long-season single saddle seedling compounds disclosed in U.S. Patent No. 5,078,990 can be practically used in the present invention. Among the monocationic compounds, distearylmethyldimethylammonium, second-line fluorenyldimethyl saddle, trimethylsulfonylmethyl saddle, fluorenyltrimethylsulfanyl, -10 _ paper Zhang scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) ~ (Please read the note on the back to write this page-installation · ΪΤ- A7 B7 V. Description of the invention (9) Grafted trimethyl ammonium, Hexadecyl trimethyl saddle, stearyl benzyl dimethyl saddle, gueryl tentacles such as gaseous compounds, bromides, etc. Suitable amines include distearylamine, distearyl Glycosylmethylamine, fluorenyldialkylamine, fluorenyldifluorenylmethylamine, fluorenyldimethylamine, dicetylamine, difluorenylmethylamine, tricetylamine, etc. Tongdang lipids include long-chain aliphatic C2 0-C50 fermentations with an average of 28 to 42 carbon atoms, long-distanced aliphatic fermentation ingredients, for example, with at least one more than about 16 carbon atoms in length The enzymes and amidines of the bond, that is, adipic acid distearate, glyceryl tristearate, peak peak, isosteareth-2, isosteareth-10, mill fat, isostearyl lactic acid , Isopropyl isostearate, isocetyl stearic acid, ethoxylated enzymes, for example, those with a chain length of 16 carbon atoms or more, of which ethoxylated Change up to a maximum of about 40, with long-chain aliphatic acids, for example, complete acids with a length of about 16 to about 40 carbon atoms. This lipid component is preferably the C20-C50-alcohol or ethyl A mixture of diol distearate and an ethoxylated enzyme. More preferably, the lipid is a mixture of the long-acting yeast and isosteareth-2. The weight of the monocationic compound to the lipid compound in the hair extract formula The ratio is in the range of about 5: 1 to about 1:10. However, this shampoo should contain at least about 0.7% by weight of a monocationic compound M to ensure a sufficiently high degree of hair conditioning effect. It has been found that using less than About 0.7% by weight of the monocationic compound of the shampoo can not achieve sufficient hair conditioner to avoid problems, such as "fly away" phenomenon. Generally, the lipid phase is equivalent to about 1 ¾ to about 1 16¾ This paper size applies to China National Standard (CNS) A4 (210X297 mm) ） Loading — (Please read the note on the back first < 5 ^ 5% write this page to order printed by the Ministry of Economic Affairs Central Standards Bureau Zhengong Consumer Cooperative Printed by the Central Government Bureau of the Ministry of Economic Affairs Printed by Shellfish Consumer Cooperative Cooperative A7 __ ^ __ B7_ 五Description of the invention (10), preferably in an amount of about 4% to about 10%. The customary anionic surfactant can be used in the shampoo of the present invention. A typical type of surfactant is U.S. It is disclosed in No. 4,554,098, the entire contents of which are also incorporated herein by reference. Suitable anionic surfactants of this type include 1 mole of Ci o-Ci 6 alcohol and 5-12 mole of ethyl oxide. The water-soluble salt of the sulfated product of the reaction product. These detergents have the following structural formula, which are called alkyl ether sulfates in the literature before M: R (0C2 H4) n0S03 Μ where R is an alkane containing about 10 to about 16 carbon atoms The average value of η is 5 to 12 and M is a cation. Generally, this cation can be selected from the group consisting of sodium, potassium, ammonium, and mono-bis- and tri-acetammonium. Preferably, the alkyl phosphonium sulfates will contain 12-14 carbon atoms in the alkyl portion and can be used in the form of sodium or ammonium salts. Suitable alkynyl sulfates are (: 12-(: 14 alkoxyethoxy (6.5) sodium sulfate, (: 12-〇14 alkoxyethoxy (6.5) ammonium sulfate, (: 12-(: 14 Alkenyl ethoxy (9.5) sodium sulfate, Ci 2 -Ci 4 fluorenyl ethoxy (11.4) sodium sulfate, Ci 2 -Ci β alkenyl ethoxy (6.5) potassium sulfate, Ci 2 -Ci 3 alkenyl Ethoxy (6.5) ammonium sulfate and Ci 2 -Ci 6 fluorenyl ethoxy (7) ammonium sulphate. The preferred alkyl ether sulfates are Ci 2 -Ci 3 or Ci 2 -Ci 4 alkylethoxy (6.5-9) Sulfate of sodium or sulphate. The other female cleaner contains C7-C2 2 thiol group in its molecular structure, -12-(Please read the Note V on the back and fill in it first. [Writing Page). Binding, binding, thread_ This paper size is applicable to China National Liang Zhun (CNS) A4 specification (210X297 mm) The Central Government Bureau of the Ministry of Economic Affairs of the Bayer Consumer Cooperatives Co., Ltd. Imprint A7 B7 V. Description of invention (U) Dilute base Or water-soluble, non-soap, anionic cleaners of the type hydrazone and vinegar nitrate, heterosulfate or sulfonium sulfonium groups. These detergents, water-soluble salts are used and heterocations are usually selected from Includes the following types of ions: sodium, potassium, ammonium and mono -And tri-C2 -C3 alkanes, etc. Among them, M nano and ammonium ions are preferred. Suitable anionic cleaners of this type include: 1. C8 -Ci β-carbyl sulfate, which is usually animal fat Or coconut oil triglycerin is used to produce C8-Ci β roasted fermented by sulfonation. The preferred roasted sulfates are those whose fluorenyl moiety contains 10 to 16 carbon atoms. 2. C9 -Ci 5 nitrobenzyl nitrates, in which the fluorenyl group is a straight bond or a branched chain, which is better because the straight chain has better biodegradability. 3. Ce _C2 2 olefin sulfonic acid Salts can be obtained by sulfating appropriate olefins. Preferred olefin sulfonates are those whose alkyl portion contains 14 to 16 carbon atoms and which are obtained by sulfonating an α-olefin. 4. (: 8-Ci β fluorenyl ether ethoxylated sulphates, R (0C2 H4) n0S03 Μ where η is 1 to 4. This type of sulfates and primary alkyl ether sulfates The difference between cleaning agents is the ethylene oxide number (1-4) of ethylene oxide which reacts with a mole of alcohol to form ethoxylated alcohol (which is then sulfated and neutralized to form this anionic detergent). Alkyl ether ethoxylates contain 10 to 16 carbon atoms in their alkyl moiety and 2 to 3 ethoxylated oxides per mole of fermented -13-(Please read the notes on the back first to fill in (This page) / 1 -Item νβ -Pack. 1Τ- · This paper size is applicable to China National Standards (CNS) Α4 specifications (2 丨 0 > < 297 mm) Printed by the Central Government Standards Bureau of the Ministry of Economic Affairs A7 _B7__ V. Description of the invention (12) Group. 5. Ci o-C 2 O hydrocarbons can be obtained, for example, by reacting alpha-olefins with bisulfites. The preferred fumes are those whose carbyl group contains 13 to 17 carbon atoms. 6. It is also possible to use C6-Ci 2 benzyl ether polyvinyloxy sulfates containing 2 to 6 moles of ethylene oxide in the molecule. The amidine cleaning agent is prepared by reacting an alkylbenzene age with 2 to 6 moles of ethylene oxide, and sulfating and neutralizing the resulting ethoxyfluorenyl age. Preferred cleaning agents of this type contain 8 to 12 carbon atoms in the fluorene group and contain about 4 ethyl oxide groups in the molecule. 7. Ce-Ci 8-methyl thioacetates with the formula: ROOCCHz S03 M where R is a C8-Ci 8 alkyl group, and an enzyme can be esterified with acetic acid or acetamyl chloride. M sodium bisulfite or potassium chloride sulfite reacts with this chloroester. Preferred thioacetates are those in which the alkyl portion contains 12 to 16 carbon atoms. Ν-mono-CS-C2 2 alkyl (including those with an ether or amido group interposed between them) thiosuccinic acid Salts can be obtained, for example, from a mole of C8-Ci 8 alkanol or C8 -Ci 8 alkoxy C 2 -C 3 alkanol or Ce-Ci 8 alkamino amine C 2 -C 3 alkanol, and Malay Acid reaction, and the resulting product is reacted with the testa bisulfite to form N-mono-C8-C2 2 alkylthio shoper acid salt. It should be known that the sulphur base of products made from N-fluorenyl amines is based on the intermediates containing fluorenamine. Similarly, if the alkyl ether alcohol or ethyl ester of ethylene glycol and MA-14-(Please read the precautions on the reverse side β first to complete this page)-Binding-Binding 'This paper size applies to Chinese national standards ( CNS) A4 specification (210X2.97 mm) A7 __B7____ 5. Description of the invention (13) If the acid reaction occurs, the firing chain may be interrupted by the brewing chain or bond. The preferred thiosulphonate salts are N-mono-C8-Ci 8-isopropionylaminothio-nonanoic acid, and dodecylthio-anion ΪΘ acid dinaline and N-monoolein. Isopropyl alcohol amine thiol is a sulfonium salt. 9. N-Cs -Ci 8 base sarcosinates can be obtained by neutralizing the reaction product of C 8 -Ci 8 base enzymes with N-methylglycine. The preferred sarcosinates are those having 12-14 carbon atoms in the hydrazone base, which are obtained from hydrazone coconut oil. 10. N-C8 -Ci 8 fluorenyl taurine, which can be obtained by neutralizing the reaction product of Ce -Ci 8 fermenting acid and amino ethyl ceramic acid. Similarly, the preferred taurates are those whose fluorenyl group contains 12-14 carbon atoms, which are obtained from hydrazone coconut oil. 11. 0-C8 -Ci 8 -yl hydroxyethane sulfonic acid can be obtained by neutralizing the reaction product of C8 -Ci 8 alkyd acid with 2-acetylacetic acid. Similar to sarcosinates and bovine mineral salts, the preferred acetyl sulfonates are those whose fluorenyl group contains 12-14 carbon atoms, which are obtained from hydrazone coconut oil. The amount of feminine surfactant in the shampoo formulation is usually about 3-25% by weight, preferably about 7-14% by weight. Any polycationic hair conditioner for turbid hair that is conventionally used in typical previous shampoo formulations for shampooing, which can be dissolved in the aqueous surfactant phase of the composition, can be practically applied to the present invention. Invented. Examples of these agents are Polyquatern ium_10, Poly qua tern ium-7 (e.g. Merquat-550) and mixtures thereof. In general, polycationic quaternary saddle polymers constitute from about 0.2 to about 3% of the total weight of the shampoo formula By weight. The size of this paper is in accordance with the Chinese National Standard (CNS) A4 (210X2.97 mm). Please read the notes on the back and write on this page. Order · Central Standards Bureau, Ministry of Economic Affairs Printed by Standard Bureau Shelley Consumer Cooperatives A7 __ ^ _____ B7___ V. Description of the Invention (14) Any suitable water-insoluble, non-volatile, traditional xanthone hair turbidity agent can be used in the present invention and includes, for example, polymer Dioxane-based oxadiazine, polyfluorene-based arylsiloxane or polyethersiloxane copolymer. Mixtures of these fluids can also be used. Silicone should also be insoluble in shampoos. The main non-volatile poly-sand-based sand oxidizers that can be used include, for example, polydimethyl sand-based sinters (dimethicones) with a viscosity ranging from about 5 to about 100,000 centistocks (at 25TC). These silicones are available, for example, from the Vicasil series by General Electric Company and the Dow Conning 200 series from Dow Corning. 0 Viscosity is according to Corning Corporate Test Method CTM0004 (July 20, 1970 Method), using a glass capillary viscometer. The main non-volatile polyalkenyl aryl sintered products that can be used include, for example, polymethylphenyl-synthetic phenyltrimethicones, with viscosity ranging from about 15 to about 85 centimeter stokes ( 25C). This ketone is available from, for example, SF-1075 methylphenyl fluid from General Electric Company or 558 Cosmetic Grade fluid from Corning Corporation. The main non-volatile polyether sand oxygen copolymers that can be used include, for example, polydimethylsiloxane polyoxyalkylene ether copolymer fluids with a viscosity of about 1,200-1,500 centistock (25C) under). These ketones are available, for example, from SF-1066 organic silicone surfactants by General Electric Company. The preferred compounds of this type are polyoxypropylene modified dimethylpolysiloxanes (for example, Dow Corning DC-1248 by Corning). Ethylene oxide or ethylene oxide can also be oxidized with propylene. Mixture of things. -16 A paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back ^; write this page) Order, line --- Central Consumers Bureau of the Ministry of Economic Affairs Printing A7 __'__ B7_ V. Description of the invention (K) It is also possible to use the ketones with amine functional groups in the composition of the present invention, for example, Dow Corning's X2-8107 material. Classes include those disclosed in the following patents: 2,828,551, 3,964,500 and 4,364,837, all of which are reference materials of the present invention. The preferred silicone is polymethicone. The role of the aqueous solution phase of the surfactant of the shampoo and the polycationic polymer in the lipid phase of the composition is the main stabilizer of the shampoo dispersion. Neutral polymers, such as via ethyl cellulose, can be mixed with this polycationic polymer to enhance the stabilization of the dispersion. The unique advantage of the present invention is that in addition to stabilizing the dispersion, the polycationic polymer can also improve the moisturizing properties of the shampoo. The amphoteric surfactants which can still be used in the shampoo of the present invention include amine oxides, such as C8-Ci 8 alkyl dimethylamine oxides. Examples of other auxiliary substances are solubilizers, such as sodium citrate, sodium xylitol, sodium benzoate and sodium hexyl sulfate. In addition, the following examples illustrate the present invention, but the present invention is not limited thereto. Please read the precautions on the back & fill in this page first) • Packing · 1T-, Line-17-This paper size applies Chinese national standard (€?) 8 4 ^ grid (210 > < 297 mm) V. Invention Explanation (16) A7 B7 Example 1 Preparation of shampoo for conditioner with the following formula: Part of m 1 deionized water Ten: Deceth-3 sulfur mmm Na4 EDTA Na2HP〇4 "Supplier" Henkel's Standapol A, 2 %% Vista's Novel 10-44 ES Na, 30¾ Stepaor 8 Stepanate SCS, 43X rajone-Poulenc * s CSxeelox BF-78 13.750 16.000 15.000 7.000 ± 0.100 0.200 Total coconut propyl I # 3 Goldschnidt 'S Tego Betaine L-7, 30X 30.000 Deionized water Polyquatern iun-10 Polyquaterniun-7 Isosteareth-2 + compound 909 yellow cord (1 total solution) anti-surface, 50X aqueous solution mm

Aaerchor s Polyner JR-30M Calgon * s Merquat-550, 8¾ Sierex ’s Varonic 66-E2 (1.5 E0) Petrolite * s C-7138 Polymer Sierex * s Arosurf TA-100

Stepan's Stepanate SCS, 43% 5.000 0.500 2.500 2.000 4.000 1.000 0.250 1.200 1.000 ± 0.500ΜΛ " ΐ (Please read the notes on the back and fill in this page first) Pack. Ir- Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs + Isosteareth-2 is a kind of acetylated isostearate marinated yeast (1.5 EO units). * ^ -Sc2〇-c4〇mmm -18-This paper uses China's national standard (CNS > Μ specifications (210X297) (Public address) A7 __'_ B7__, a consumer consumer cooperative of the Central Government Bureau of the Ministry of Economic Affairs __'_ B7__ 5. Description of the invention (17) The main mixing container is a stainless steel container with a variable speed Lightnin 'mixer and heating and heating equipment. Stainless steel or plastic container is used for pre-mixing of part 2. Additional heat equipment and stainless steel container with minimum speed for mixing are used for mixing the oily phase of part 4. Fill the main part of the formula 1 with deionized water. Start mixing in the mixing container. Add part 1 formula of dodecylsulfate, sodium deceth sulfate, sodium disulfide, Na4 EDTA, sodium monohydrogen scale and coconut aminopropylpropylammonium salt. After joining Allow sufficient time for the ingredients to completely dissolve before being ingredients and be careful not to cause foaming. This batch should be mixed for at least 15 minutes before proceeding to the next batch. Stir the mixture and heat it to 85-87Ό 〇 In addition Take a dry and clean container and fill it with part 2 formula devitrified water. After mixing, disperse part 2 formula amount of Polyquaternitm-10 into deionized water and mix thoroughly to make it non-caking, but do not exceed five Minutes to avoid gel formation. Add the premix of Part 2 into the main mixing container while stirring and be careful not to cause foaming. Before proceeding to the next batch, this batch should be mixed for at least 15 minutes. Mix and heat it to 85-87. Add part 3 Polyquaternium-7 to the main mixing container, being careful not to cause foaming. Before proceeding to the next batch, this batch should be mixed At least 15 minutes. Stir the mixture and heat it to 85 -87¾ ° into a third, separate, heatable container, and fill in part 4 oily phase-19-This paper uses China National Standards ( CNS) A4 size (210X2 97 mm) Please read the notes on the back '^ write this page) • Packing · 1T-Printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A7 __B7_ V. All the ingredients of the invention description (18) start heating. Mix all ingredients thoroughly at a temperature of 90-92 ° C until all materials are in a homogeneous molten state. When the liquid is liquid, the mixture need not be clarified, but may be transparent. When the batch temperature is 85-87TC, add the premix of Part 4 to the main mixing container under high speed mixing, being careful not to cause foaming. Intermittent heating is maintained at this temperature. This batch should be mixed for at least 15 minutes and then allowed to cool while stirring. Part 5 pigments can be added at any time during the cooling process. When cooled to 52 * 0, add part 5 of the formula's fragrance, mix and cool. When it cools to 381 or below, add the preservative in part 5 of the formula, then mix and cool. After the sample is cooled to 25 ° C, inspect its properties. If necessary, add sodium pinenesulfonate M to the main mixing container to reduce its viscosity. In the formulation of Example 1, two polyfluoride surfactants were used, wherein the total active substance concentration was 0.6% by weight [0.3% Polyquaternium-10 (Amerchol's Polymer JR-30M) and 0.3% Poly-quaternium-7 (Calgon's Merquat-550, 8¾)] ° In the following test, a variety of polyyang broccoli hair sprays were used in the formulation of Example 1, and the concentration of the active substance was 0.6% by weight. Polycations and test results are stated as follows: This paper size is applicable to China National Standards (CNS) A4 specifications (210X297mm) Please read the gutter A7 B7 on the back of the back. V. Description of the invention (19) Example of polycations 1 Polyion ion 0.6¾ Merquat-550 0.6 »Polymer JR-30M 0.6¾ Polymer JR-400 0.6¾ Merquat-100 Relative wet combing score * * The higher the wet combing score, the higher the conditioner 》 Person rated 4.5, its effect is about the same as that of a commercially available silicone-containing conditioner 2-in-1 shampoo. Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Shelley Consumer Cooperative, changed the formula of Example 1 to contain the same amount of monofunctional cationic hair conditioner, and replaced the original stearyl dimethyl dimethyl ammonium compound. Relative wet carding scores distearyldimethylammonium 4.5 tricetylmethylammonium 4.0 dicetearyldimethylammonium 3.5 trisdialkyltrimethylammonium 3.5 cetyltrimethylammonium 3, 0 Result of changing the formula of Example 1 to replace the original polyoxyethylene stearyl alcohol-2 (isosteareth-2) with other lipids: Relative lipid carding score of polyoxyethylene isostearyl alcohol-2 4.5 Polyoxyethylene isostearyl alcohol-1 〇4.0 Phospholipid 4.5 Isostearosyl lactate 4.5 Isopropyl isostearate 4.5 Isocetyl stearate 4.5 -21-This paper is for China National Ladder Standard (CNS) A4 specification (210X297mm) Please read the note on the back and fill in this page-installation, line V. Description of invention (20) Example A7 B7 According to the method of Example 1, prepare the following formula shampoo:

Ingredients Part A has been detoxified water, Hydroxyethyl, "Viso, Part B mmm Coconutyl propyl internal interest dark c

Product name Natrosol 250-HHR Staodapol A, 28XNaH2P〇4 Na2HP〇4 Naxooate SC, 98X supplier

AquaIon Heokel J.T. Baker J.T. Baker Reutgers-Nease QS0.200

Tego Betaine L-7.30X Goldschnidt 67.8580.2000.200 ± 1.000 13.334 (Please read the notes on the back to write this page) The Central Bureau of Standards of the Ministry of Economic Affairs and the Industrial Cooperatives Co., Ltd. printed the malonase USP PolyquaterniuB-10 quaternary ancient gelatin DiiS® 128T c20-40 Fermented mmtm II «SSKSz: Symphony II C22 ~ Quat Laureth-4 Hydroponic Seed Oil Part E Anti-Pay Blue Pigment (1 Association Solution) Blue Pigment (1 Total Solution)

Propylene Glycol USP Polyaer JR-30M Cosnedia Guar C-261

Boler 1070 Uni 1 in 425 Adol 62 TC-90-F Arosurf TA-100 Genaiin KDH-F Brij-30 Crenophor RH-40 22-This paper size applies to China National Standard (CNS) A4 (210X297 mm) 1.000 Anerchol Henkel 0.300 0.300

Boler Petroleum Petrolite Sierex Sherex Sierex BASF ICI BASF oo oooo oo oo oo oo 00 0005 55 1-40 ^ css2 · 2 · 0 · 0 · 0 · 1.200 0.750 0.021 0.168 Total amount 100.000 5. Description of the invention (21) Examples follow the example 1 Method to prepare the following formula: Partial Charm 1 Sickle Water Deceth-3 iSKifi Laureth-2 EO Laureth-13 atssnj ^ ii Na4 EDTA Trideceth

A7 B7 Vendor > Trade name Vista's Novel 10-44 ES Na, 30¾ Henkel's Staodapol £ S-2 LV.25X SaodoZT 8 Sandopan L-24, 70X Hanp ^ iire, s Haivosyl C-Acid, 100X Wione-Poalenc * s Qieelox BF-78 Rhone-Ptmlenc * s Rhodopex EST-30, QS 6.000 6.518 2.750 0.820 0.090 30% 11.900 Miranors C2M NP, 38X 9.200 L-7, 30 »13.750 3 peg-80 PolyquatemiuB-10 Polyquaterniua-7 4 Isosteareth-2 Compound 909 Ershi KHlin 5 pigment anti-face, 50X aqueous solution

ICr s Atlas G-4280 Anerchor s Polyner JR-30M Stepan's Stepanate SCS, 43X

Sherex's Varonic 66-E2 (1.5 E0) Petrolite's Polymer C-7138 aierex's Arosurf TA-100 9.000 0.275 3.000 2.500 3.450 1.850 4.100 0.900 QS1.200 1.000 100.000 ----------- Ί ^ ---- ^- -1Τ ------- ^ line (please read the precautions on the back V to fill out this page) ί Printed by the Central Bureau of the Ministry of Economic Affairs of the Shellfish Consumer Cooperative Co., Ltd. Example 4 Prepare the following formula and test it as described above- 23 This paper uses Chinese National Standards (CNS) Α4 specifications (2 丨 0 × 297 mm) 5. Description of the invention (22)

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Printed by the Consumer Cooperatives of the Central Bureau of Procurement, SM Ministry of Economic Affairs $ i -i scy i 0 < SQSSKM 00 > 606i ¥ > 00 · ί s 醵 alsi 廉 ς. · U ^ BnbxJod OST (% 5? ) ss οεοo-TumiuwlBnbytllod οσε «is sow (% 0 £) ζ, -i kane 0-0 Vla3i οοώ (% δ swas 00.91 (% K) STV scy« iw i 装 i 05 ^-里 i 劁 Documents « II ^ ii --------- Ί ^ .---- ^-ΐτ ------ (Please read the notes on the back first & fill in this page) (4 2 This paper size applies China National Standard (CNS) A4 specification (210X297 mm) A7 B7 V. Description of the invention (2 3) Those formulas that can keep the shape highly durable, such as those in Example 4, numbered 4, 8 and 9, also found It has the effect of repairing damaged hair. Example 5 Prepare the following shampoo composition according to the method described above: (Please read the precautions on the back first & fill in this page) -Packing-Shellfish Consumer Cooperative, Central Standards Bureau, Ministry of Economic Affairs Printing-25-This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210X297mm) V. Description of invention (24) 〇 〇 1-1 UT3 0 > CV3 Si cv3 ιη ο «ο ο 〇I» — · CO + | co ο ο ο ο οα MGSC ^ iri OlOO ^ QP »-H CO + | A7 B7

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I Binding-ί. 8t asIssia (S > rKrxiaiussnSIS) printed by Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ϊ-10 i ^ in + "ON Su Tan lisKIl! Meng Ling Ling Zhen SI Erben paper size applicable to Chinese National Standard (CNS) A4 specifications (210X297 mm) v 388714 A7 B7 V. Description of the invention (25) found according to each formula The formulated shampoo can make it have the effect of styling and controlling the shape. It is printed by the Central Government Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives.

Claims (1)

388714 VI 、 Scope of patent application Patent Application No. 84104960 ROC Patent Appln. No. 84104960 Amended Claims in Chinese-Enel. (I) (8 films in the Republic of China in 88 years > Daily Fantasy) (August, 1999) (Please read the notes on the back before filling out this page) 1. A shampoo composition for conditioning hair, which contains an aqueous dispersion (weight ratio) with the following components: a) 1% To 16% of the water-insoluble lipid phase comprising a long-chain aliphatic alcohol having an average number of 24 to 50 carbon atoms and 0 to 40 ethoxy units; b) at least 0.7% of the lipid phase soluble in the lipid phase A water-insoluble monocationic conditioner compound selected from alkylamines having a pKa value of at least 7.5 selected from the group consisting of distearylamine, distearylmethylamine, behenylamine, diamine Dodecylmethylamine, behenylmethylamine, dicetylamine, dicetylmethylamine and tricetylamine; c) 3 to 25% water-soluble anion for clean hair Use organic surfactants; printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs d) Amphibian or sulfosulfate飨 Surfactant, its molecular structure contains C8-C18 alkyl or C8-C18 alkanol, amine C2-C3 alkenyl, and it contains at least 0.75 per part by weight of the anionic surfactant in the dispersion To 1.25 parts by weight; e) from 0 to 6% of a water-insoluble and non-volatile silicone hair conditioner; and f) at least one hair-conditioning, water-soluble and film-forming polycationic polymer from 0.2% to 3% The weight ratio of the single ion conditioner compound to the lipid compound in the lipid phase ranges from 5: 1 to -28-r5UmWr% Tlaim. This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) ) 388714 Patent Application No. 84104960 ROC Patent Appln. No. 84104960 Amended Claims in Chinese-Enel. (I) (8 films in the Republic of China in 88 years > Daily Fantasy) (August, 1999) (Please read the notes on the back before filling out this page) 1. A shampoo composition for conditioning hair, which contains an aqueous dispersion (weight ratio) with the following components: a) 1% To 16% of the water-insoluble lipid phase comprising a long-chain aliphatic alcohol having an average number of 24 to 50 carbon atoms and 0 to 40 ethoxy units; b) at least 0.7% of the lipid phase soluble in the lipid phase A water-insoluble monocationic conditioner compound selected from alkylamines having a pKa value of at least 7.5 selected from the group consisting of distearylamine, distearylmethylamine, behenylamine, diamine Dodecylmethylamine, behenylmethylamine, dicetylamine, dicetylmethylamine and tricetylamine; c) 3 to 25% water-soluble anion for clean hair Use organic surfactants; printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs d) Amphibian or sulfosulfate飨 Surfactant, its molecular structure contains C8-C18 alkyl or C8-C18 alkanol, amine C2-C3 alkenyl, and it contains at least 0.75 per part by weight of the anionic surfactant in the dispersion To 1.25 parts by weight; e) from 0 to 6% of a water-insoluble and non-volatile silicone hair conditioner; and f) at least one hair-conditioning, water-soluble and film-forming polycationic polymer from 0.2% to 3% The weight ratio of the single ion conditioner compound to the lipid compound in the lipid phase ranges from 5: 1 to -28-r5UmWr% Tlaim. This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) ) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A8 B8 38S71 * _m_ 6. The scope of patent application is 1:10 and the molar ratio of anionic surfactant to water-insoluble monocationic compound is 2: 1 to 50: 1. 2. The shampoo composition according to item 1 of the scope of patent application 'is free of silicone hair conditioner and has high hair conditioning and damaged hair repair properties. 3. The shampoo composition according to item 1 of the patent application scope, which contains the silicone in a weight ratio of 0.2% to 6% (based on the weight of the shampoo composition) and has high hair-controlling properties. 4. The shampoo composition according to item 1 of the scope of the patent application, wherein the anionic surfactant is an alkyl sulfate, an alkyl ether sulfate, an alkyl ether sulfonate, an alkphenoxy polyoxyethylene ethanol Sulfates, sulfonates, / 3-alkoxyolefin sulfonates, alkylaryl sulfonates, sulfated monoglycerides, fatty acid amino polyoxyethylene sulfates, or combinations thereof. 5. The shampoo composition according to item 1 of the Shenshen patent, wherein the anionic hand surfactant is ammonium dodecyl sulfate. 6. The shampoo composition according to item 1 of the scope of the patent application, wherein the anionic surfactant is poly (ethylene oxide decethsulfate). 7. 'The shampoo composition according to item 1 of the scope of the patent application, wherein the anionic surfactant is a mixture of dodecane, ammonium sulphate and polyoxyethylene decyl alcohol thiol. Sodium acid. 8. The shampoo composition according to item 1 of the scope of the patent application, wherein the anionic surfactant is sodium lauret ^ isulfate 0 -29- This paper size applies to Chinese national standards ( CNS) A4 specification (210 X 297 mm) < Please read the notes on the back before filling out this page) Installation · ——I *-——Order —— Scope of patent application 9. According to the scope of patent application The shampoo composition of item 1, wherein the lipid phase is the long-chain aliphatic alcohol having an average of 24 to 50 carbon atoms. 10. The shampoo composition according to item i of the application, wherein the The monocationic compound for conditioning the hair comprises 0.7 to 3% by weight of the shampoo composition. The shampoo composition according to item 4 of the patent application, wherein the amphoteric surfactant is coconut aminopropylpropyl betaine. 12. The shampoo composition according to item 1 of the scope of the patent application, further comprising a compatibilizer selected from the group consisting of sodium cumene sulfonate, sodium xylene sulfonate, sodium benzene sulfonate, and hexamethylene thiosulfate. U. The shampoo composition according to the application in the Bailey scope, wherein the water-soluble cationic polymer comprises an acetamidine salt which is reacted with a substituted epoxide trimethylammonium. 14. The shampoo composition according to item 1 of the scope of the patent application, wherein the water-denatured cationic polymer comprises a copolymer of acrylamide and vaporized dimethyldiallylammonium. 15. The shampoo composition according to item 2 of the scope of the patent application, wherein the anionic surfactant is selected from the group consisting of CrCi8 sulphuric acid vinegar, crc18 silk ether ethoxylated sulphate containing H vinyloxy groups, and The mixed group is present in an amount of 7% to 14% by weight; the boundary of the series:, the active agent is beet test ^ and the water-insoluble lipid phase is present in an amount of 4% to secret weight. It is believed that the shampoo composition according to item 15 of the scope of patent application, wherein the polycationic polymer is selected from the group consisting of ethyl cellulose androgen salt reacted with the substituted epoxide trimethyl K. SBS714_g_ Copolymers of acrylamide and vaporized dimethyldiene and their mixtures. 17. The shampoo composition according to item 6 of the patent application, wherein the lipid plate comprises a mixture of the long-chain alcohol and isostearyl alcohol ethoxylate. 18. The shampoo composition according to item 1 of the application, wherein the lipid phase comprises ethoxylated isostearyl alcohol. (Please read the precautions on the reverse side before filling out this page) '· Packing --- II --- Order --- I --- I Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economy -31- National Standard (CNS) A4 specification (210 X 297 mm)