TW387791B - Composition for controlling insects and representatives of the order acarina comprising an oxadiazine and cypermethrin, profenofos, pymetrozine or thiocyclam - Google Patents

Description

A7 B7 V. Description of the invention (The present invention is related to a composition, which includes a pest-killing activity, a method for controlling a guest, a process for preparing the product, and its use. In K's Physics, Plants and Materials, and the use of compounds of formula (A) below to prepare the composition. Specific mixtures of active compounds have been proposed in the literature to control harmful compounds with K. However, some The biological properties of mixtures of known compounds are not entirely satisfactory in the field of pest control. • This is why there is a need to provide further mixtures with synergistic killing properties. Representative of Xin and Acarina. This object can be achieved according to the present invention by providing the composition. The present invention is accordingly based on a composition that controls the representative of Kunming and Acarina, which Include a combination * The sisterhood includes different forms of one or more compounds of the following formula «form or form, if combined, can be read as a tautomeric form Note page (IIIII Order Intellectual Property Bureau Staff consumption Printed by Cooperative

A

o wnx 〆 • N

T This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm). Printed by Shelley Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs. Or, depending on the possibility of substitution on the ring system, it is substituted by one to four, aromatic or non-aromatic monocyclic or bicyclic heterocyclic radical, wherein the substituent A is selected from the group consisting of One of the following substituents: Ct-C3 alkyl, "-C3 alkoxy, halogen, halo-C,-C3 alkyl, cyclopropyl, halocyclopropyl, C2-C3 alkenyl, Cz-C3 alkyne Group, halo-c2-C3 alkenyl, halo-C2_C3 alkynyl, halo_Ci-C3 alkyloxy, Ci-C3 alkylsulfur, Ct_C3 alkylsulfonium, allyl gas, propargyl Oxygen, allylthio, propargyl, haloallyloxy * haloallyl, cyano and nitro; R is fluorene, Ci-Ce alkyl, phenyl-Ci-C4 alkyl, C3-Ce cycloalkyl, C2-Ce alkenyl, or C2-Ce alkynyl; and X is N-I 2 or N-CN, and includes one or more of the following compounds: (I) nitrogen Phosphorus (az ^ ethiaphos); (II) (Chlorfenvinphos); (III) Cyper ^ ethrin >, cyperiethrin high-cis; (IV) cyroiazin; (V) diafenthiuron (VI) diazinon; (VII) dichlorvos; (VIII) dicrotophos; (IX) dicyclanil; (X > fenoxycarb ); (XI) fluazuron); (XII) furathiocarb; (XIII) isazofos; (XIV) rescued Uodfenphos; (XV) Jinnuopran ( -5- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) II I --- ^ 111 ---- πΓν ------- I ----- 1. · 谞 Please read the note on the back before filling in this purchase) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 _B7 _ V. Description of the invention (that is, ki η ο prene); (X VI) 霣 芬 狃 隆 （1 ufenur ο η); (X V11) lethacriphos; (XVIII) ethidathion; (XIX) lonocrotophos; (XX) Phospliaiidon; (XXI) Bufeisong (Pr 〇fe η 〇f 〇s); (X X11) di I? Forest (di 〇fe η ο ο 1 a η); (X Π 11) can be obtained from Bacillus t. Aureus (Bacillus tburingiensis) strain GC91 or a substance from NCTC11821; (XXIV) py ^ etrozine; (XXV) bromopropion; (XXVI) methoprene; (XXVII) disulfuton; (XXVIII) quinalphos : (XXIX) tan-fluvalinate; (XXX) thiocycla (thiocycla): or (XXXI) thioietqn and at least one adjuvant compound of formula (A) are described in EP -A— 580 553. (I) Boro-grade acid 0,0 —dimethyl S — 6 —chloro_2,3 —diargon — 2 —gas — 1,3 — “zolo [4,5 — b] pyridine —3 -yl Methyl sugar (az ^ ethiaphos), from The Pesticide Manual, 9th Ed · (1991), The British Crop Protection

Counc.il, London, p. 44; (II) Diethyl phosphate 2—Ammonia 1_ (2 · 4-dichlorophenyl) ethane-6-This paper size applies to China National Standard (CNS) A4 (210 X 297 males; * >. ---------- rw -------- 1 ----- r—ache ί. (_ Please read the precautions on the back before Fill out this purchase) Consumption cooperation by employees of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed A7 ___B7_ V. Description of the invention (if) Alkenyl esters (¾blófenvinphos), from The Pesticide Manual »10th Ed · (1 994)» The British C r ο p P rotection Counsi 1, L ond ο π, p. 17 4; (III) (IRS) — 顚 -trans- ~ 3 — (2, 2_dichloroethanyl) — 1 , 1-Dimethylcyclopropanecarboxylic acid (RS) — ct monocyano-3 —phenoxycarbyl ester (cyperiethrin »cypenethrin high-cis), from The

Pesticide Manual, 9th Ed * (1331), The British

Known by the Crop Protection Council, London, p. 208; (IV) N-cyclopropyl-1 * 3, triazine-2,4,6-triamine (cyroaazin), from The Pesticide Manual, 9th Ed. (1991), The British Crop Protection

Council, London »on page 217; (V) 1-Third-butyl_3_ (2,6-di-isopropyl-4-phenoxyphenyl) 醗 urea (diafenthiulon) ) · Learned from The Pesticide Manual »10th Ed 2-Isopropyl-6-methyl Otidine-4-yl-telluride This paper is sized to the Chinese National Standard (CNS) A4 (210 * 297 mm) < · «Read the precautions on the back first (Fill in *-this page) Γ: clothing -------- order ----- l · —printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 _ B7__ V. Description of the invention (f) Acid 0, 0-diethyl ester (diazinon), from The Pesticide Manual, 9th Ed · (1991) * The British

The Crop Protection Council, London, p. 243, (VII) Dimethyl 2,2-dichlorovinyl phosphate (dichlorvos), from The Pesticide Manual, 9th Ed · (1991), The British Crop Protection Council »

Known in London, p. 259; (VIII) Dimethyl (E) -2-dimethylaminomethylmethyl-1-methyl vinyl (dicrotophos), from The Pesticide Manual > 10th Edition (1994), The

British Crop Protection Council * London, page 322 ψ; (IX) 5-cyano-2-cyclopropylamino-4,6-diaminopyridine (dicyclanil) from ΕΡ-Α- 244 360 is known; (X) 2- (4- (phenoxyphenoxy) ethylaminoformate (fenoxycarb)) * From The Pesticide Manual, 9th Ed · ( 1991), The British Crop Protection

Learned from Council, London, 375 pages; -8- This paper size applies to the Chinese national standard (CNS > A4 size (210 X 297 mm) !. I --------------- ^ --------- (Please read the notes on the back before filling out this page) A7 —. __B7_ V. Description of the invention (〇 (XI) 1- 〔4 一 (3-chloro-1 5-trifluoro Methyl_2-pyridyloxy) phenyl] -3- (2,6-difluorobenzyl) [[Urea] urea (fiuazuron)), from The Pesticide Manual, 10th Ed · (1994), The British Crop Protection Council > L ondou. Learned on page 4 7 5; (XII) N, N '-Dimethyl-N, Γ-dihydroamido 2, 3 -dihydro-2,' 2-2 Methylbenzofuro- 7-ylbutyl ester (furathiocarb), from The Pesticide Manual > 9th Ed * (1991), The British Crop Protection

Known by Council, London, p. 448; (XIII) sulfoacids 0,0-diethyl 0-5 -chloro-1 -isopropyl-1H-1,2,4-trisalyl-3-yl Cool (isazofos), from The Pesticide Manual * 9th Ed · (1991) *

The British Crop Proteotion Council * London, page 502; Printed by Shelley Consumer Cooperative, Intellectual Property Bureau, Ministry of Economic Affairs • (Please read the precautions on the back before filling out this page) (XIV) 0,0—dimethyl coupling Phosphorothiosulfuric acid 0—2 * 5—dichloro-4—iodophenylcool (Rescue Fenfo Uodfenphos)) · From The

Pesticide Manual > 10th Edition (1994), The British Cr ο p Protecti ο n Counci 1 L ο nd ο n, learned on page 110 2;: 9- This paper size applies Chinese National Standard (CNS) A4 specifications (210 * 297 mm) Printed by the Shellfish Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 _____ Β7 _ V. Description of the invention (7) (XV) (+) (E, E) — 3, 7, 11 Dodecane-2,4-dienoate propyl-2-alkynyl ester (kinoprene), from The Pesticide Manual, 10th Edition (1994) *

The British Crop Protection Council * London, p. 1102; (XVI) (R, S) -l- [2,5-: it-4- (l, l, 2,3,3,3-hexafluoro Propanylphenyl] _ 3- (2,6-difluorobenzylfluorenyl) monourea (lufenuron), from The Pesticide Manual · 10th Edition (1994), The British Crop

Known by the Protection Council, London, p. 628; (XVII) (E) -3— (Dimethoxyphosphinofluorene) —2-methacrylic acid methyl mill (ethacripbos) ) ·From

The Pesticide Manual > 9th Edition (1991) »The

Known by the British Crop Protection Council, London, p. 562; (XVIII) 0,0-dimethylarsinosuccinic acid S-2,3-diarsine-5-methoxy-1 2-gas-1 , 3,4-androstadiazole- 3-methyl (Lethidathion, from The Pesticide Manual, 9th Edition (1991), The British Crop -10- This paper size applies to China National Standard (CNS) A4 specifications ( 210 X 297 mm > —: --------------------- Order --------- line ί- * (Please read the Please fill in this page for the note items) DuPont A7 B7__ Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs

Known by the Protection Council, London, p. 567; (XIX) «Acid (E) — 1-methyl-2- (methylaminoformamidine) vinyldimethylfluorene (lonocrotophos), From The Pesticide Manual > 9th Ed · (1991) »The British

Known by the Crop Protection Council, London, p. 597; UX) Dimethyl phosphate 2— «— 2-diethylaminomethyl 1-1 methyl vinyl ester (Phosphanidon) · From The The

Pesticide Manual > 9th Ed · (1991) »The British

Crop Protection Council * London, p. 679 Learned about (XXI) iodophosphate S-propyl 0-ethyl 0- 4-bromo- 2 -fluorenyl phenyl (profenofos) * from The Pesticide

Manual > 9th Ed (1991) * The British Crop

Known by the Protection Council, London, p. 705; (XXII) 50 to 80% (2RS, 4SR) — 4- (2-ethyl-1,3-difluoropentanyl-4 4-ylmethoxy) phenyl Mixture of phenyl ether and 50 to 20% (2RS, 4RS) — 4-mono (2-ethyl-1,3-dioxolane-4 monoylmethoxy) phenylphenyl ether (diofenolan )), From The Pesticide Manual, 10th Ed · (1 994), The British C r ο p Protecti ο n Counci 1, L ο nd ο π, page 3 6 3 -11-This paper size applies China National Standard (CNS) A4 specification (210 X 297 mm) --------------------- Order --------- line (please first «Read the note on the back and fill in this page again.] Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives. A7 B7__ 5. Description of the invention (1) Known; (XXIII) Available from Bacillus thuringiensis strain The substance of GC91 may be obtained from Bacillus thuringiensis strain N CT C1182 1 from The Pesticide Manual, 10th Ed * (1 994) »The

British Crop Protect ion Council * London · page 62; (XXIV) 2,3,4,5-tetrahydro-3-oxo-4 _ [(pyridine-3-yl) -methyleneamino] -6 —Methyl-1,2,4-triazine (pynetrozine ·), from Thq Pesticide Manual ♦ 10 'h Edition (1994), The British Grop Protection Counci 1, L ο nd ο n, section Known on pages 8 6 8; and (XXV) 4,4'-dibromobenzyl ilate isopropyl S (bromopropionate), from The Pesticide Manual, 9th Edition (1991), The British Crop Protection Council * London • Learned on page 99. (XXVI) (E, E) — (R, S) — 11-methoxy-1,3,7,11-trimethyldodecane-2,4-dienoic acid isopropyl Base ester (Methoprene), from The Pesticide Manual > 10th -12- This paper size applies to China National Standard (CNS) A4 (210 χ 297 male *) I ------- ---- 0 ^ -------- Order ------- •• Line (Dragon first reads the note on the back and then fills the book to buy it) A7 B7___ V. Description of the invention (( 4

Edition (1994) * The British Crop Protection

Council, London, p. 680. UXVII) Phosphonobithiophosphonic acid S-2-ethylthioethyl 0, 0-diethyl _ (disulf uton), from The Pesticide Manual · 10th Edition (1 994) * The British Crop

Protection Counsil »London, p. 37 2; (XXVIII) Pyridoxine 0-quinoline- 2-yl 0,0 —diethylpyrene (quinalphos), from The

Pesticide Manual, 10 th Edition (1994), The

British Crop Protection Council »London, p. 890, and (XXIX) N — (2-« — a, α, α -trifluoro-P-tolyl)-D-valine (RS)-α — Cyano 3-phenoxybenzyl ester (tau-fluvalinate) from The

Pesticide Manual »9th Ed · (1991)» The British

Known by the Crop Protection Council, London, p. 428; (XXX) N, N-dimethyl-1,2,3-trithian-5 -ylamine (thiocyc 1 a ·), from The Pesticide

Manual * 9th Edition (1991), The British Crop -13- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ------ ': ^ i — (Please wash it-it Note on the back, please fill out this page again) Order · Print · Printed by the Shellfish Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Shellfish Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed A7 — _B7____ V. Description of the Invention (U)

Protection Council * London, p. 816; and (XXXI) 偁 "Dithiotelluric acid 0,0 -dimethyl S-2 -ethylthioethyl% (thioieton), from The Pesticide Manual »9th Edition (1991), The British Crop

Protetion Council > London · page 819 〇 Compounds of formula (A) may be intermutated eaves in some cases. For example, when R is a hydrogen phase compound of formula (A), that is, a compound having 3 — Η — 4 — § 5 amino group β S — 1, 3, 5 — the structure of the two fluorene can be used with Concentrated tautomers of the partial structures of amine-1,2,5,6-tetrahydro-1,3,5-fluorene difluorene. The above-mentioned and the following compounds of the formula (A) can also be understood as meaning that, when combined, the tautomers of each other, even if the latter is not specifically mentioned each time. Compounds of formula (A) containing at least one diagnostic center can be formed by K, for example, acid addition hydrazones. The formation of these acid addition salts, for example, using strongly non-aqueous acids, such as mill acids, such as chloric acid, sulfonic acid, nitrous acid, nitric acid, monophosphoric acid or monomethyl halide acid, Acids, such as Ci_C4 alkanecarboxylic acids, which are unsubstituted via, for example, halosol, for example, acetic acid, such as diacids, which are saturated or non-harmonic, such as oxalic acid, malonic acid , Succinic acid, glutaric acid, fumaric acid or peptidic acid, such as hydroxycarboxylic acids, such as ascorbic acid • lactic acid • Ping-14-This paper size applies to China National Standard (CNS) A4 specifications ( 210 X 297 mm)! Τ— — — — — —r, 4 in — — — — — — — — — — (锖 Please read the notes on the back before filling this page) A7 B7 V. Description of the invention (丨γ) (Please read the notes on the back before filling this page) Fruit acid, tartaric acid or citric acid, or benzoic acid, or use sulfonic acid, such as Ci-C4 alkyl mono or aryl sulfonic acid • It is unsubstituted or substituted by, for example, halogen, plus K, such as methane or p— Acid. The compounds of formula (A) and at least one acid-based compound can further form salts with the test compound. The union with sickle! Classes are, for example, gold urn, such as sickle metal or sickle gold urn salts, such as sodium, potassium or magnesium salts, or hydrazones formed with fluorine or eavesamine, such as morpholinyl, pyridine Pyrrolidine, one-, two-, or three-smaller alkylamines, such as ethyl mono, diethyl mono-triethyl mono or dimethyl-propyl monoamine, or mono-, di- or Trisyl-a smaller fluorenylamine, such as Jun--, dione or triethylenylamine. When they are combined, they can further form salts within the line and phase. The content of the present invention is very favorable for the hydration of the Chinese medicaments "because the free form of the compounds of the formula (A) and their Chinese forms are closely related to each other. Conveniently and conveniently is understood to mean that, when entangled, the salts of the formula (A) and the refractory compounds. The same applies to the tautomers of compounds of formula (A) and their M form. In each case, the free-living form is usually employed. Printed by Shelley Consumer Cooperative, Bureau of Intellectual Property, Ministry of Economic Affairs, the subject matter of the present invention includes sister products in the free form of the compound of formula (A). The general terms used in the preceding and following sections have the following meanings, unless otherwise specified. -15- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) A7 A7 V. Description of the invention (b) B7_ $$$ Heterocyclic basic structure of radical R in the periodic table is in the periodic table All elements in W which can form two covalent bonds. N and S are preferred. It is a base plaque or as a structural element of other groups a and compounds 'If it is a haloalkyl, haloalkyl, haloalkoxy, halocyclopropyl, haloalkenyl' The structural requirements for oxygen and haloallyl sulfur are fluorine, chlorine, bromine or rhenium, especially fluorine, gas or bromine, especially fluorine or rhenium, especially chlorine. Unless otherwise defined Contains "groups and compounds containing in each case 1 to and 6 interfering atoms * Preferential to include 1 to and 3 interstitial atoms, especially 1 or 2« carbon atoms. The fluorenyl group is cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl, and cyclopropyl is preferred. Alkyl itself is a basic plaque or a structural element of other groups and compounds * If it is a phenylalkyl, haloalkyl, alkoxy, di alkoxy, alkyl and haloalkyl structure -In each case, it should be considered: the number of carbon atoms in the group or compound, which may be a straight bond, that is, methyl, ethyl, propyl, butyl, and pentyl to hexyl , Or branched * such as isopropyl, isobutyl, second-butyl * third-butyl 'isopentyl, neopentyl or isohexyl ° -16- This paper is applicable to national standards (CNS) A4 specifications < 210 x 297 mm): --------------- 1 ---------. (Please read the note $ on the back first (Fill in this page again) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by the Shellfish Consumer Cooperative, printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by the Consumer Consumption Cooperative of A7, B7 V. Description of the invention (丨) Alkenyl, haloalkenyl, alkynyl and haloalkynyl Straight or branched and in each case contains two or preferred carbon-carbon bonds. The double or triple bond of these substituents is preferred to separate at least one saturated carbon atom from the rest of its compound (A). Examples of sinus are allyl, methallyl-but-2-yl, butyl-1, 3-butyl, propyl, butyl-2, and butyl-3-alkynyl.

Carbon-containing groups and compounds with halogen substitution, such as halosoloalkyl, cycloalkenyl, or haloalkynyl * may be partially A or halogenated, and in the case of multiple halogenation * The halogen substituents may be the same or different. Examples of the halogenated alkyl group are as a base plaque in itself, or other groups and compounds * such as the structural element of a halogenated alkenyl group, a methyl group, its M fluorine, "and / or bromine, etc. One-to-three substitutions, such as CF 2 and CF 3; ethyl, its K fluorine, chlorine and / or bromine are mono- to five-take

Generation, such as CH2 CF3, CF2 CF3 'CFz CI3, CF2 CHCI2' CF 2 CHF2 f CF2 CFCI2 * CFz CHBR2 · CF2 CHC1F * CF2 CHBrF or CC1FCHC1F; propyl, or isopropyl 'its K 蕹' gas and / or bromine Carry out the military-to seven substitutions, such as CH2 CHBrCH2 Br, CF2 CHFCF3, CHz CF2 CF3 or CH (CF3) 2; and butyl or its isomers

First, it is substituted by one to nine with fluorine, chlorine and / or bromine, such as CF (CF 3) CHFCF3 or CH2 (CFz) 2 CF3. Examples of halogenated radicals are 2 * 2 _dioxanyl 1-based, 2,2-dichloroethanyl-1 1-based, 2-trimethylene-17- This paper applies Chinese national standards (CNS> A4) Specifications (210 X 297 Public Love) --------------------- Order ----- r --- line-, -----.-- ------------------ c Read the notes on the back before filling in this page) A7 B7_ V. Description of the invention (<) 1 1 1 1-3 , 2,3-Difluoropropanyl-1, 3-methyl, and 2 »3-dibromopropanyl-1-ene-3-yl. Examples of haloalkynyl groups are 2-chloropropanyl-1, acetylene-3, Radicals, 2 · 3-dichloropropanyl ~ 1-alkynyl-3-yl and 2,3-dibromopropanyl-1-alkynyl-3-yl. Examples from hydrazine are 2-chlorocyclopropyl, 2 , 2-difluorocyclopropyl and 2-chloro- 2-fluoro-cyclopropyl. Examples of allylic oxygen are 2-propane-1, 2-methyloxy, 2,3-dichloropropane 1-11ene-3-yloxy and 2,3-dibromopropene-1ene-3ene radical. An example of Ifi allylfluorene is 2-dichloroprop-1-ene-1-3-ene, 2,3-dichloropropan-1ene-3-sulfur and 2,3-dibromopropene-1-ene-3 substrate 0 In phenylalkyl, an alkyl group bonded to another group of the compound of formula (A) is substituted via a phenyl group plus K * The alkyl group is preferred to be straight-bonded and the phenyl group is preferred to be An alkyl group bonded to a position higher than c (especially at the omega position; examples are benzyl, 2-phenylethyl, and 4-phenylphenyl. The employee's cooperation in intellectual property bureau of the Ministry of Economic Affairs Printed * (please read the notes on the back before filling this page) Especially preferred compounds of formula (A) are among them

(1) R is hydrogen * "-C4 alkyl, C3-Ce cycloalkyl, Cz-Ce alkenyl or C2-Ce alkynyl, especially fl or, CH3 * (2) ring of compound of formula (A) Basic structure, including 2 to 4 tilts-1 8-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 _B7_ V. Description of the invention ( ifc), preference for common double slits, preference for two, preference for conjugated double bonds, and particular preference for aromatic characteristics. (3) Basic cyclic structure of compounds of formula (A) • It contains 1 to and Contains 4 钃 heteroatoms, especially 1 to and 3 俪 雑 atoms, especially 1 or 2 heteroatoms, especially 2 heteroatoms; (4) Basic cyclic structure of compounds of formula (A) • It contains 1, 2, or 3 sickle atoms. The male atom is selected from the group consisting of oxygen, sulfur, and nitrogen. In the basic structure of the ring, the sickle atom is not more than the oxygen or target atom. * At least There is a nitrogen atom; (5) A in the compound of formula (A) is mono- or di-substituted via a group consisting of halide and Ci-C 3 alkyl, especially From halogen, especially via chlorine; (6) a compound of formula (A), in which the basic structure of the hydrazone is pyridyl, 1-epoxy β-pyridinyl (ο X id 〇pyrinidini 〇) or androzolyl, «OK The basic structure of the compound of formula (A) is pyridin-3-yl-1, 1-epoxy-3-pyridyl (1-oxido-3_pyridindinio) or dozozol-5-yl, -19- Paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 11111111111111 · 111111 11111111 1 • (锖, please fill in the precautions on the back before filling this page > printed by Shelley Consumer Cooperative, Intellectual Property Bureau, Ministry of Economic Affairs Preparation of A7 B7__ V. Description of the invention ("]) In particular, the compound of formula (A) is pyridinyl 3-yl, 2-halopyridine 5-yl, and 2,3-dentate salyl 5-yl 》 2-Ci-C3 fluorenyl ttt cavity-5-group, 1-cyclic parent (1-oxido-3-pyrinidinio), 2-halo-1-epoxy-5-pyridyl (1-10xid 〇-5 — pyrinidinio) * 2,3-dihalo-l-oxo-5 ~ pyridyl (ι_oxido — 5-pyridindinio) or 2-halozolyl-5 —yl · of formula (A) Compounds in particular (ft-ol- 3-yl, 2-yuryl; qg-5-yl, 2-yellow 1-present oxygen-5-lit steep (1--0xid〇 ~ 5 — pyrinidinio) * 2 —Halomidazole-5 —yl, compounds of formula (A) are preferred to be 2-chloroKidine-5 —yl, 2-methyl Bt 唆 — 5 —yl * 1 — epoxy — 3 — oxido—3 — pyri π idi π i 〇), 2 _ chloro-1 —epoxy-5 pyridinyl (1-0 xid 〇 5-pyrini < iini ο) * 2 · 3 _ dichloro_ 1 —Epoxy-5 —pyridinyl (1 — οXid〇 — 5 — pyr inid ini〇) or 2-chlorosore-5 —yl, the compound of formula (A) is especially pyridin-3 —yl, 2 — Argon-pyridine- 5-yl, 2-gas- 1-epoxy-5-pyridyl (1-oxido ~ 5-pyridindinio) or 2-chloroazolyl-5-yl · Especially the compound of formula (A) is 2 -Pyridine-5-based or 2-dichloropyrazole-5-based; -20- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) — mini — i — — — — — — ^ * — — — — 1 —11 ^. * (Please read the notes on the back Complete this page)

A7 V. Description of the invention (/ (D (7) compound of formula (A) * where X is; U) compound of formula (A), where A is 2-Mβazole 5-yl or 2-chloropyridine-5 R is Ct-C4 alkyl and X is N—NO 2. The preferred compound of formula (A) in the context of the present invention is U.1) 5— (2-aminopyridinyl-5-ylmethyl )-3-methyl-4 4-bromoimide-perhydro-1,3,5-fluorene difluorene; (A.2) 5- (2-chloroβ-sialyl 5-ylmethyl) -3 —Ethyl-4 mononitroidene ~~ 1,3,5— 《Diazine; (please read “Precautions on the reverse side and fill in this purchase first”)

(A 3) 3-methyl_4-nitroimino- 5- (1-epoxy 3-pyridinemethyl) -1,1,3,5-K Diazine Intellectual Property Office, Ministry of Economic Affairs Consumption cooperation Du printed oxomethyl VH / 5 hydrogen through I-based aminoimine nitrate «I-based aminoimide nitromethazinyl dipyridinyl-methyl; methylazinyl di-hire 5-1 5 Azole, β 7 ambience 1 base 1 4 This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 public love) Printed A7 B7 by the shellfish consumer cooperation of Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention ((A · 6) 3-methyl ~ 5— (2-methylpyridine-5-ylmethyl) ~~ 4 mononitro limbyl group on one side, 1,3,5—hiring two_ ί (A, 7} 3 — (2-pyrimidinyl-5-ylmethyl) —4—nitroimino— “1,3,5—“ diazine; and (A. 8) 3— (2-chloroazolyl— 5-Methylmethyl> -4 mononitroimino group with one side fi — 1,3,5-B difluorene. Preferred composition In addition to compound K of formula (A), there is only one other harmful compound Active compounds (I) to (XXXI). Compositions also available 5— (2-chloroβazole—5-huamethyl) —3-methyl—4-nitroimino—fi—l, 3,5-—diazine is used as the active ingredient (A). Further preferred composition In addition to compounds K of formula (A), the classes include aziettiiaphos, cypenethrin high-cis, fenoxycarb, diofe η ο 1 a η ), Profe η ofos or py ^ etrozine. The active composition according to the invention comprises an active compound of formula (A) and one of the active compounds of (I) to UXXI) * preference is 100: 1 to 1 · 6000 ratio, especially 1: 50 to 50: 1 ratio, especially between 1: 20 and 20: 1 ratio, especially 10: 1 and 1: 10 ratio, especially 5 : 1 and -22- This paper size is applicable to China National Standard (CNS) A4 specifications (210 * 297 mm> ~ *! ΊΙ — ίί! 1 Order! ----- line, (Please read "Notes on the backside $" Please fill in this item again. A7 ____B7_ V. Description of the invention (> " °) 1: 5 rooms, especially 2: 1 and 1: 2 rooms, and 4: 1 and 2 ·· 1 rooms, especially Especially 1: 1 Or 5: 1, or 5: 2, or 5: 3, or 5; 4, or 4: 1, or 4: 2, or 4: 3, or 3: 1, or 3: 2, or 1: 5, Or 2: 5, or 3: 5, or 4: 5, or 1: 4, or 3: 4, or 1: 3, or 2: 3, or 1: 2 ratio, or 1: 600, or 1: 300, or 1: 150, or 1: 35, or 2: 35, or 4: 35 · or 1: 75, or 2: 75, or 4: 75, or 1: 6000, or 1: 3000, or 1: 1500, or 1: 350, or 2 · 350 > or 4: 350, or 1: 750, or 2: 750, or 4: 750. 〇 These ratios are to be understood as meaning, on the one hand, the weight ratio, and on the other hand, the molar ratio. Surprisingly, it has now been discovered that the combination of an active compound of formula (A) or its alligator and one of (I) to (XXXI) active compounds not only results in a synergistic effect on the pest to be controlled. Its principle It can be expected that it will induce a synergistic effect, which can extend the limitations of the two preparations from two perspectives: First, the compound of formula (A) and the compound (I) to The application of (XXXI) is lowered but still maintains an equally good activity. Second, the combination mixture also achieves a high degree of harm control, in which the two individual substances K have become completely ineffective when applied at very low rates. On the one hand, ft allows the controllable harm to be increased to a considerable extent, and on the other hand, it is used for safety. -23- This paper size applies to Chinese national standard (CNS > A4 size (210 297 mm) Please read the note on the back h page I v IIIIII Threading Ministry of Economic Affairs Temporary Property Bureau Shellfish Consumer Cooperatives Printing Ministry of Economy Wisdom Printed by A7 B7 of the Consumer Cooperative of the Property Bureau. V. Description of the invention (v |) In addition to the real synergistic effect with respect to the killing activity, the sister product according to the invention has other surprising advantages, They can also be broadly defined as synergistic: they allow, for example, control of harm S * which is not or is not controlled by the partial compounds (A) and (I) to (XXXI), and according to the invention Compositions are more tolerated by plants ", that is, they are less phytotoxic than individual compounds (A) and (I) to (XXXI). What's more, for example, * different developmental stages of Kunyu can be controlled, which In some cases, this is not the case for the compounds (A) and (I) to UXXI), because these compounds can, for example, be used only as a killer or only as a counteract to very specific intermediate periods Alas. In addition, for example, the sisters of compound (A) and specific compounds U) to (XXXI) have shown more beneficial effects in grinding * mixing • storage and storage. The composition according to the present invention is valuable for prevention and / or therapeutic treatment in the field of pest control even when applied at a low rate, and can be tolerated by warm-blooded animals * fish or plants and has a very favorable killing effect. Biological Fanhui. The composition according to the present invention can effectively combat normal susceptibility and resistance to animal damage in all or individual stages of development *, such as representatives of Kunming and Acarina. The bactericidal and / or acaricidal effects of the compounds according to the present invention can be directly added to the wish, that is, immediately or only after a certain period of time [bad, such as at hatching, or indirectly Demonstrate that, for example, by reducing the spawning rate and / or "Huahua", it is equivalent to at least 50 to 60% destruction rate-2 4-This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm>)- -— — Jlllllllc ^-— — — — I —I ^ il —I —I —V (Please read the note on the back * 9 ^ before writing this page > printed by the Shellfish Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs System A7 B7___ V. Good activity% of invention description rate (mortality). The animal pests mentioned above include * For example:

Kuni from Lepidoptera (L epid ο ptera), Acleris spp., Adoxophyes spp., SI JB (Aegeria spp.), Ground Tiger 91 (Agrotis spp ·) , Alabaia argil laceae »Any lois spp ♦. * Anticarsia geiiatalis, Archips spp., Argyrotaenia spp. * A utographaspp, B usseo 1 afusca, C adra cautella »Peach Snack ft (Carpo bow ina nipponensis)» Chilo spp., Choistoneura spp •, Grape Fruit IK Moth (Clysia aikiguel la), longitudinal sowing (C napha 1 ocrocisspp ·), C Nephasiasp ρ ·), Cochy 1 is spp. * 赖 娥 靥 (Co 1 eophora spp.) ·

Crocido 1 o 霣 ia binotalis »Cryptophlebia leucotreta ♦ Cydia spp ·, Diatraea spp, ·

Diparopsis castanea, Earias spp., Ephestia spp., Eucosaa spp., Eupoecilia aUiguella * Ji Ji (Euproctis spp ·) * Root S 羼 (Euxoa spp ·), Grapholita spp, Hedya nubiferana, fleliotbis spp · -25- This paper size applies to China National Standard (CNS) A4 (210 X 297 public love) ----- --------------- ^ ---------- ^ / L ('Please read the notes on the back before filling in this card) Staff of Intellectual Property Bureau, Ministry of Economic Affairs Printed by the Consumer Cooperative A7 _ B7___ 5. Description of the Invention (Clever), Hellula spp., American White «(Hyphantria cunea), Tomato 蠹 蠘 (Keif eria lycopersicel la), Leucoptera scitella , Fine lines

Lithocollethis spp ·), Lobesia botrana, Lymantriaspp · Ly net netiaspp · 'Curacao jff (Malacosoaa spp ·), Cabbage night moth (Maiestra brassicae) (Manduca sexta), Operophtera spp., Ostrinia nubilalis, Panelle spp ♦, Pandeisis spp., Panolis flaiiea spp., Phthoriiaea operculella, Mulberry powder suspicion (Pieris rapae) • Pink pupa J * (Pieris spp. ♦), Plutella xylostella, Prass spp ·) · White for Hi (

Scirpophaga spp ♦), Nocturnal layer (Sesaiia spp ♦), Leaf leaf moth (Sparganothis spp,), Night fli (Spodoptera spp.), Speroptera (Synanthedon spp ♦) »Thauietopoea spp Tortrix spp ·), Trich ο p 1 usiani and fll (Y p ο η ο neutaspp ♦); Kunxin from Coleoptera, for example, Agr iotes spp ·), Antiionoius spp · · Atoiaria linearis, Chaetocne ^ a tibialis * Cocos b ο po 1 itesspp.), Curcu 1 i 〇spp *) »ϋ SI (-26 " This Paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) < «Read ML first and then read $ on the back, then buy it in Yunnan manuscript) • 1

---- Order ---- κϋ n Line L Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 _ V. Description of the invention (νψ)

Denestes spp ♦), Diabrotica spp., Epilaclnia spp · >, Ereinus spp * * Horse 钤 If 袅 (Leptinotarsa decealineata), Lissorhoptrus spp · * Kettlelontha spp ·) »Orycaephilus spp., Otiorhynchus spp., Phlyctinus spp ,, Lijin it 靥 (P ο P i 11 iaspp ·), Pycnogenol (P sy 11 iodesspp *), Rhizopertha spp., Scaratbeidae , Sitophilus spp ·, Sitotroga spp ♦ > * Tenebrio spp., Triboliu spp · and Trogodersa spp · from Zhizhi Kunft ft of the order Orthoptera, for example, Blatta spp ·, Blattella spp · 'Gryllotalpa spp · Leucophaea aderae , Locusta spp., Big _ 羼 (

Periplaneta spp.) And grasshopper hires (Schistocerca spp ·); Kunstocks from the Isopt era, for example, Reticul itemes spp ♦; Kunstocks from Psocoptera, for example '軎®® (Liposcelis spp ·); -27- This paper size applies to China National Standard (CNS) A4 (210 X 297 male «) J --- ^ --------------- -Order ---------- line-f: ('Please note the item $ on the back of BIS before filling * page) A7 B7 V. Description of the invention (/) (please note $ on the back of M Jing first) Xiangdian transcript f) Kunming crickets from Anoplura, for example, Blind S top (Haenatopinus spp.), Long jaw lice fll (Linognathus spp.), Pediculus spp. Pe_phigus spp ♦) and root β aphids (Phylloxera spp.); Insects from the order Homophae (Mallophaga), for example, D aa 1 ineaspp · and genus Fll (T rich 〇dectesspp,); from the order Thysanoptera ), Such as' Thrips (F rank 1 inie 11 aspp ♦) »Hermaphrodites (Herci η 〇thripss ρ P.), Taeniotbrips spp., Th rips pal * i • Thrips tabaci and Scirtothrips aurantii; Kunyu from Heteroptera, such as' O 袅 fll (Ciguan ex spp.), Distantiella theobroaa, Red Pillar Like JR (

Dysdercus spp ·) · Euchistus spp. 'Chunxiang 臞 (printed by E μ rygastei * spp ♦) from the Intellectual Property Bureau of the Ministry of Economic Affairs and the Consumer Cooperative, the SI (Leptocorisaspp ·) and the Nezara spp. , Pseudosaurus sinensis SI (Piesia spp ·), Rhodnius spp. · Sahlbergel la singularis, Black stake elephant Ji (Scotinophara spp) and Triatoia spp. * -2 8 _ This paper is in accordance with Chinese national standards ( CNS) A4 size (210 x 297 gigabytes) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Bei Xiaoxiao Cooperative A7 B7_ 5. Description of the invention (> 4) Kuni from the same class (Boioptera), for example, suspected whitefly (

Aleurothrixas f 1 occosus), whitefly (Aleyrodes brassicae), Aonidiel la spp ·, aphid (

Aphididae), aphid 9i (Aphis spp ·), Cymbidium (A spidiotuss ρ p *), Bemisia tabaci (B eiisiatabaci), cricket (Ceroplaster spp.) * Cliryso ^ plialus aonidiui, Rose wheel chrysanthemum (Chrysoipl lalus dictyosperrni), mango brown pheasant (Coccus hesperidu ·), hupasca spp., Eriosoaa lari'genia * Erythroneura spp ♦ Gascardia spp · > Laodelphax spp · Lecaniu corni, Lepidosaphes. Spp ♦ Macrosiphua spp · Long tube fll (Myzus spp ·) ,

Nephotettix spp •, Nilaparvata. Spp., Paratona spp., Peiphigus spp. * Planococcus spp., Pseudaulacaspis spp. Pseudococcus spp.)

Psylla spp *), Pulvinaria aethiopica,

Quadraspidiotas spp), Rhopalosiphti · spp ·, Saissetia spp., Scaphoideus spp *, Schizaphis spp., Sitobion spp *, Greenhouse white powder Tick (Trialeurodes vaporarioru ·) ♦ Trioza erytreae and orange shield (Unaspis -29- This paper size applies to the national standard (CNS) A4 specification (210 X 297 mm) ---- ^ ------- -/ 1 ^ -------- ^ --------- ^ > i < 'Please fill in this page with the precautions on the back of the case) A7 B7 V. Description of Invention citri); Kun beta from the gastropod (Hyienoptera), for example, Acroiynex, Atta spp. * Cephus spp., Diprion spp. * Saw Diphonidae, Gi lpinia polyto ^ a, Boplocaipa spp., Lasius spp., Kitchen ants (Μοποβογiui pharaonis), Neodiprion spp ♦, fire (Solenopsis spp *) and Vespa spp · (please "note $ on the back of the stew first, then the Yunnan script f > • 1 · · 1 Bn —1 1 智慧 Intellectual Property of the Ministry of Economic Affairs Kung ft from Diptera, such as Aedes spp., Antherigooa soccata, Bibio hortulanus, Calliphora erythrocephala, VM (Ceratitis spp) ·), Chryso hired yia spp · * W. Cu (Culex spp ♦), Cuterebra spp (Cuterebra spp ♦), Jia _fl | (Dacus spp.) * Dangophila elanogaster, defeated (Fannia spp.) 'Gastrophilus spp *' Glossina spp. '' Hypoderbaspp ♦ ', Hypoposcasp P ·' Lirioeyza spp. ', Lucilia spp.' Melanagroiyza spp., Musca spp. 'Oestrus spp., Orseolia spp., Broadcast straw straw (-30- private paper size applies Chinese National Standard (CNS) A4 specifications (W. x 297 公 H) Order -----. Printed by the Shellfish Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs A7 ____B7___ V. Description of the invention (> < h

Oscinella frit), sweet paddle leaf calyx (Pegoiyia hyoscya), Phorl) ia spp. 'RhagoIetis poione 11 a), Sciara spp., Stoioxos spp.), Tabanus spp ·), Tannia spp · and giant mosquito if (Tipula spp *); Kun magpie from the order Sipbonaptera, for example, Ceratophy 11 usspp · (X enopsy 11 acheopis); quince from Thysanura's, such as Lepisna saccharina; and quince from Acarina, such as Acarus siro, Aceria sheldoni, Aculus schlechtendali, Aablyoia spp •), Argas spp ·, Boophilus spp *, short-scarred mite Brevipalpus spp *) '

Bryobia praetiosa), the upper three sections of the mite SI (Calipitriierus spp *), the pain period 羼 (Chorioptes spp *) ’S 剌

Deraanyssus gallinae) * Eottranychuscarpini (E ri ο P hyesspp.), Hyalo ** a spp., Ixodes spp., 'Grass claw-31- Paper size applies to China National Sample Standard (CNS) A4 (210 X 297 mm) 1 II —'1 I! II · 1111111 — — — — — — — II (锖 “Read the notes on the back side and then fill out this I ) Printed A7 ____B7_ by Shelley Consumer Cooperatives, Bureau of Intellectual Property, Ministry of Economic Affairs 5. Description of the Invention (4) Mite (0lygonychus pratensis), blunt nickel nickel (

Ornithodoros spp ·), Panonychus spp ·, Phyllocoptruta oleivora, Polyphagotarsone genus us latus, Psoroptes spp ·, Rhipicephalus spp ·, root mite fll (Rhozoglyphus spp · es), salamander spp ♦) • Tarsoneius spp ♦ and Tetranychus spp *). The mixture of active compounds according to the invention according to the invention can be controlled by M, that is, the above-mentioned species of pests that occur especially in plants, especially in agriculture, solid arts and forestry crops and landscape plants * Or a part of some plants, such as fruit, flowers, stalks, rosettes or roots, and even some parts of some plants that grow in later periods are also protected from some harmful effects. The killing loquat mixture according to the present invention can be conveniently applied to loquat species, such as corn or thin loquat; fruits, such as pears, nuts, and soft fruits, such as frequency fruits, pears, peaches, peaches, almonds Peach, or berry, such as coriander, raspberry, and berry; Polygonaceae, such as peas, lentil, nursery or soybeans; oil crops, Such as canola, mustard, poppy, basket, sunflower, coconut, castor plant, cocoa or peanut; cucurbits · such as pumpkin, cucumber, or melon; fibrous plants such as cotton • flax, hemp Or jute; -32- This paper size is applicable to the national standard (CNS) A4 specification (210 X 297 mm) ---- K ---------------- order-- ------- line V, '(please fill in the note of $ on the back before filling this I) printed by the staff of the Intellectual Property Bureau of the Ministry of Economy A7 B7___ Fifth, the invention description (> D) Citrus Citrus fruits, such as tangerines, lemons * grapefruit or limes; vegetable crops, such as spinach * lettuce · asparagus, stuffed oars, carrots, prickly pear , Tomatoes, horse yam or sweet bell peppers; Lauraceae plants such as avocado * cinnamon or coriander; or tobacco, walnuts, coffee • eggplant, sugar cane • tea • pepper, rattan , Hops, bananas, natural waist-milk plants or tribute plants, especially corn, sorghum * pears and nuts, beans, melons, cotton, citrus fruits, Vegetables, eggplants, vines, hops, or traditional plants, especially corns, stalks, fruits, pears, peaches, peaches, cowpeas, green beans, soybeans撖, 獒, 獒 日 獒, coconut, cocoa, peanuts, cucumbers, melon, citrus fruits • cabbage, tomatoes _ • stables, grapevines or cotton • particularly preferred grapes, oranges Orange fruit, Yan fruit • loquat, tomato and cotton damage control _. Other aspects of the mixture of active compounds according to the present invention are used to protect stored goods, stocks and materials, and also related to their hygiene standards, in particular to protect domestic animals and productive livestock against the harmful effects of the aforementioned species. According to the purpose of the present invention, according to the desired purpose and harmful to the popular Huanpu, emulsifiable Shanghai road species, suspended condensate, directly sprinkleable or directly dilutable solution, Can be coated with edibles, thinner -33- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ----------------- ---- Order · -------- Line-ίν- ('锖 Read tl · Note on the back before filling in this page) Printed by A7 — · _ B7__V. Description of the invention (> 7 丨) Release emulsifiers * soluble powders, separable powders, wettable powders * powders * particles or in polymerizable materials Encapsulated compounds, all of which include the compound of formula (A) or one of them and one of the other active compounds (I) to (XXXI) according to the present invention. In these compositions, the active compound is administered in a tritiated form j «E: for example, the solid active compound is administered at a specific particle size * or is preferentially administered with at least one Zol that is customarily used in the field of regulation technology, The adjuvant may be a diffusible compound, such as a cocoon-soluble or solid cocoon-containing • or a surface-active compound (a surfactant). Examples of combined solvents are: • Non-oxidized or partially hydrogenated aromatic hydroxys * Alkyl benzene moieties that prefer C 8 to Ci 2 * For example xylene mixtures, alkylated naphthalenes or tetraargon Cai, fatty or cyclic fatty acids, such as lycopene or cyclohexane, yeasts, such as acetic acid • alanine or butanase • ethylene glycols and their ethers and esters, such as malonyl Fermentation, Dipropanyl Ethionase, Ethionase · Ethione Monomethyl Ether or Ethione Monoethyl Ether, Ketones, such as cyclohexanone, isophorone or diacetone, strong polar solvents Noodles, such as N-methylpyrrolidine-2-one, dimethyl sulfoxide, dimethylformamide, water, unepoxidized or epoxidized vegetable oils, such as unepoxidized or epoxidized vegetable oil , Ramie oil, coconut oil or soy oil, K and silicon oils "used in the haze-fixing carrier, such as for dust or fusible powder-3 4-(Please read the note on the back of the price first Please fill in this purchase) -C. • 1 · l_i n ϋ I nn I. This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) Printed by Shellfish Consumer Cooperative, Intellectual Property Bureau, Ministry of Economic Affairs A 7 B7__ 5. Description of the invention / The last category is usually ground natural milling materials, such as calcite, talc * kaolin, montmorillonite (· οη.1; · 〇Γί11οιιΗβ) or American activated white clay (Attapulgite). In order to modify its physical properties, there are also «I use highly dispersed silicon compounds or highly absorbing polymers. The granular absorbent carrier grades for the granules are porous, such as puiice, brick grit, sepiolite, or bentonite. The non-absorbable haze-loading material is calcite or sand. In addition, a large amount of granular materials with no organic or organic characteristics can be used to make doloiite into crushed plant residues. The «Interactive Compounds» are based on the natural characteristics of the compound to be formulated, non-ionic, ionic and / or anionic surfactants or surfactants with good emulsification, tarnishing and maeam properties mixture. The following surfactants are intended to be examples only. Other surfactants that are customarily used in the field of dispensing technology and that are more useful for the purposes of the present invention are described in the related literature. Non-ionic interfacial activity of hydration_ Mainly polyethylene glycol ether derivatives of fatty or cyclic fatty enzymes, plum and unsaturated fatty acids and alkylphenols, which have 3 to 30 glyoxetyl ether groups, with 8 to 20 mill atoms on (fatty) hydroxyl radicals and 6 to 18 carbon atoms on alkyl-aged alkyl radicals. Polyurethane-35 is also added in this paper. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) I .--- ^ --------- ------- Order --------- Line If (^ Please read the precautions on the back of the page before filling in this page >> Printed by the Shelley Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7_ V. Invention Description 〇2 /), water-soluble polyoxyethylene adducts of ethylenediaminopolyethylene glycol and alkylpolypropylene glycol, which have 1 to ιοβ on the alkyl bond Atoms and include 20 to 250 ethylene glycol bases and 10 to 100 ethylene glycol bases. The above compounds usually have 1 to 5 ethylene glycol units per ethylene glycol unit. Examples that may be mentioned are nonylphenol polyethoxylates, sesame oil polyethylene__ * cyclopropene / ethylene oxide adducts, tributylphenoxypolyethoxylates * Polyethylene glycol and octylphenol polyethylene glycol. There are also fatty acid esters or polyoxyethylene sorbose such as trioleic acid polysorbate.隈 Ionic interfacial activity is mainly quaternary ammonium salts, which have at least one alkyl group with 8 to 22 carbon atoms, as a substituent, and have lower, halogenated or unhalogenated alkyl, benzyl Or lower hydroxyalkyl groups as further substituents. This amidine is preferred to be in the form of a halide, methylsulfate or ethylammonate. Examples are stilbene-trimethylmonoammonium sulfide and benzyl bis (2-aminoethyl) ethylammonium bromide. Suitable anionic interfacial activity radium can be water-soluble soaps K and water-soluble. Synthetic interface active compounds. Combined soaps are gold test salts, _ [earth metal scandiums or ammonium salts of substituted or unsubstituted higher fatty acids (CI 0_C2 2), such as oleic acid or stearic acid. Natrium or Potassium or Natrium or Potassium of natural fatty acid mixtures * It can be obtained from -36- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) II -------------------- Order --------- line-ί. ♦ (Please read «Notes on the back page before filling out this page) Α7 B7 V. Description of the invention h 10. Coconut oil or pine oil; furthermore, it must be mentioned fatty acids methylaminoethanesulfonic acid. However, the synthetic surfactants are more commonly used, especially sulfonic acids, cytokines, sulfonated benzimidazole derivatives, or alkyllaurate sulfonates. The fatty sulfonium sulfonium salts and fatty sulfonium salts are usually of the form of sickle tincture, sickle tincture or substituted or unsubstituted ammonium salts, and usually have 8 to 2 An alkyl radical of 2 carbon atoms. The alkyl group also includes alkyl groups of fluorenyl groups, such as lignin sulfonate, dodecyl sulfonate, or lipolytic acids made from natural fatty acids plus K. Sodium or calcium salts of rhenium mixtures. This group also includes lipases of lipase and sulfonates / cycloethane ethane adducts. The preferences for the derivative of benzimidazole derivatives include 2 sulfonium sulfonium groups and a fatty acid radical having approximately 8 to 22 carbon atoms. Alkyl laurate sulfonates are, for example, dodecylbenzenesulfonic acid or sodium sulfonate / methane release temple products, calcium, or triethyl ammonium. Combined phosphates, such as phosphate esters of p-nonylphenol / (4--14) -oxyethylene adducts, or phospholipids are also complex. Generally, the composition contains 0 to 1% to 93%, especially Q 1 to 95% of a mixture of the active compound of the formula (A) and the active compound (I) to (XXXI), and 1 to 99%. 9%, especially 5% to 99 ♦ 9% of at least one solid or liquid, possibly, usually 0% to 25% of the composition, especially Q · 1% to 20%, is the interface activity _ Class represents the percentage of repetition in each case). However, the composition of the sickle is more preferred to -37 'This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 male 3Π (please read the note $ on the back before filling this page) • fa ϋ — I — I order ·! · Printed by the Shellfish Consumer Cooperation Department of Intellectual Property Bureau of the Ministry of Economic Affairs Α7 Β7 ____ 5. Description of the invention {please note the precautions on the back of the transcript before writing this page) are available on the market, Usually the final consumer uses a composition of diluted rhenium, which has a relatively low concentration of active substance. Preferred composition is especially composed of κ = weight percentage): Emulsifiable concentrated mash species: Active compound mixture: 1¾ to 9096, preference is 5% to 20% Surfactant: 1% to 30%,㑩 10% to 20% sol: 5% to 98¾, preference is 7G% to 85% powders: active compound mixture: 0.1% to 10%, preference is 0.1% to solid carrier : 99.9% to 90%, preference is 93.9% to 99% Suspended suspicion: Active compound mixture printed by Shelley Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs: 5% to 75%, preference is 10% To 50% water: 94% to 24%, preference is 88% to 30%. Surfactant: 1% to 40%, preference is 2% to 30%. Mae Mi powders: -38- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) Printed by A7 of the Intellectual Property Bureau of the Ministry of Economic Affairs, A7 __B7__ 5. Description of the invention (>; (〇 Active compound mixture: 0 * 5% to 90% * Preference is 1% to 80%. Surfactant: 0 ♦ 5% to 20%, preference is 1% to 15¾. "Carrier · 5% to 99% * Employment is 15% to 98%. Granules: Active compounds mixture 0 ♦ 5% to 30%, preference is 3% to 15%. Solid carrier: 99 ♦ 5% to 70%, preference is 97¾ to 85%. The finished product according to the present invention may also contain other solid or liquid spirits. Adjuvants such as stable cocoons, such as ring-vaporized or non-oxidized vegetable oils (such as epoxidized coconut oil * rapeseed oil or soybean oil). • Viscosity, hydration and / or stress, and M materials or other active ingredients that can achieve specific effects * such as bactericides • fungicidal agents, insecticides • Snail-killing agents or herbicides. According to the conventional methods of the composition K of the present invention, for example, in the absence of an adjuvant *, by grinding, screening and / or a solid active ingredient or active ingredient mixture Manufactured, for example, to a specific particle size, M, and in the presence of at least one adjuvant, for example, prepared by intimately mixing or / and grinding the active ingredient or a mixture of the active ingredient and Zoran (class). Therefore, the preparation process of the adult product is a further subject matter of the present invention. Paper size applies to national standard (CNS) A4 specifications (210 X 297 public love) 1 —! 1 ------- r ----- t _! ---- line Please note this item and fill in this page again) A7 B7 V. Description of invention (/ |) Preference and adjustment of mixture of compound of formula (A) and one of compounds (I) to (XXXI) The adjuvants used in technology S are applied together and therefore processed in a manner known by K. For example, • emulsifiable concentrates • directly sprayable or directly dilutable solutions * dilutable emulsifiers, Wettable powders, soluble powders, powder powders, granules K and encapsulations, such as polymerizable powders. The method of application * such as 啧 Mi * atomization, soot, wetness, spreading or pouring, and the type of the adult product, choose the purpose and prevailing environment that M Xiao wants to achieve. The application method of the pupae, that is, the methods to prevent the above-mentioned harmful species, such as spraying, atomizing, soot, smearing, seed coating, spreading or pouring, the choice depends on the desired purpose and the prevailing environment Anyway, K and the use of the composition for preventing the above-mentioned kinds of harmful S are further subject matter of the present invention. Typical application ratios are between 0.1 to 100 ρρ ·, with active ingredients preferred between G · 1 to 5G0PP ·. The difference in the application ratio can be within a fairly wide limit and depending on the nature of the soil, the type of application (leaf application; seed treatment; used in field hoe), morning crops, the climate of the prevailing area of S * phase M to be controlled, And other factors determined by the form of application, the timing of the application, and the crops of the order. The application rate per hectare is usually 1 to 2Q00 g of active ingredient per hectare, in particular 10 to 1 QD0 g / ha, and the employment rate is 20 to 600 g / ha. -4 0 — (Please read the notes on the back before filling out this page) / -------- Order --------- line — .n 1 n ί ί ϋ It n- Zhang scale is applicable to China National Standard (CNS) A4 (210 x 297 mm) A7 B7_ V. Description of Invention (#) A preferred application method in the field of crop protection is to apply to the leaves of plants (for leaf μ 懕), The frequency and rate of application may be adjusted based on the risk of spreading the problem. Alternatively, the active ingredient can reach the plant through the root system (systemic activity) * which uses a liquid beta composition to irrigate the plant growth plaque field or embed a solid-type active ingredient into a plant growth area, such as a human soil, such as Types of κ particles (soil applications). In rice crops, this grain may be added to the irrigated rice field in calculated parts. Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs < 锖 Read the precautions on the back before filling in this page> The composition according to the present invention is also used ^ Protect plant propagation 霣 • For example, seeds, tubers or Glutens, or plant cuttings, are protected from animal pests. The propagules can be treated with the adult product plus M before planting: for example, the seeds can be applied before seeding, and the active ingredients according to the present invention can also be applied to the seed core (coating), or by M solution The product is soaked with nuts or coated with a solid product. Or * when the colony is planted, the composition can be applied to the implantation site, e.g. to the field when it is planted. The method for treating plant propagation material and the produced plant propagation material are other main contents of the present invention. The following examples are intended to illustrate the invention. They do not limit the invention. -4 1-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 5

Description of the Invention (VJ A7 B7 Formula Pickled Example (% = weight percent, active compound ratio = weight ratio) Example F1: emulsion condensate a) b) c) active compound mixture 25 X 40 ί Compound (A): Compounds (I) to (XXXI) = 1: 3I calcium dodecylbenzenesulfonate 5 X 8 X castor oil polyethylene glycol ether (36 EO) 5 X-tributylphenol polyethylene glycol ether (30 mol of EO)-12: Cyclohexane-15: Xylene mixture 6δX 25 * 50 20 20 Any desired concentration of milk α can be prepared by diluting it with water. (· «Read the note on the back before filling this page) Example F2: Solution active compound mixture a) 80 b) c) d) 10 95 [Compound (A ): Compounds (I) to (XXXI) = 1:10 Glyoxal monomethyl ether 20 3;--4 2-This paper size applies the national standard (CNS) A4 specification (210 X 297 mm) Economy Printed by the Consumer Cooperative of the Ministry of Intellectual Property Bureau A7 ___B7_ V. Description of the Invention (V) Polyoxan MW 400-*-N-methyl-2-pyrrolidine caries-20 X-Cyclic Gastric Gardenia Oil-- 1 ϊ Petroleum ether (boiling point Fanyuan 160-190 C) 94 X This solution is used in the form of PK microdroplets. ί (Read "Precautions on the reverse side before filling in this page")

Example F3: Granules a) b) c) d) Active compound mixture 5 X [Compound (A): Compound (I) to (XXXI) 10 X = 2: 1] 8% 21 \ Kaolin 94%-79 X 54% Highly-dispersed silica 1%-13 X 7 X American activated clay-90 X-18 X The active ingredients are dissolved together in methane, the solution is sprayed onto the carrier * and the cocoon is dissolved later This line volatilizes under the sky. Example F4: Fenoids a) b) Active compound mixture 2 96 5 [Compound (A): Compound (I) to (XXXI) = 1 ·· 1] -43- The paper size applies to the Chinese National Standard (CNS) A4 specifications (210 X 297 mm) > SJ · • Line-A7 ______B7 V. Description of the invention (+ 丨) The stomach content is 1% of silica 1% 5% Talc 97% — Liline _ 90 96 Stomach into powder house Hydrocarbons are obtained by intimate mixing with active ingredients. F5: wettable powder a) b) c) active compound mixture 25% 50% 75 9i [compound (A): compounds (I) to (XXXI) = 1:75] lignin milling sodium 5% 5% — Sodium Laurate Enzyme 3% — 5% Sodium Diisobutyl Chaisulfonate 1 696 10 9 ι octylphenol polyethylene glycol (7-8 Mol E0) — 2% — Highly Dispersible Silica 5% 10% 10 9 (Kaolin 62% 27% — ί ...---, · ---------------- order ------ ^ ί-line — (please first (Please read the notes on the back and fill in this page)) The active ingredients and additives printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs are mixed with the additives and fully ground in a combined mill. Use water plus K to dilute K to get any suspension with the desired concentration. Example 6: Milk cocoon concentrate-4 4-This paper size is applicable _ National Standard (CNS) A4 specification (2) 0 X 297 male %) A7 B7 V. Description of the invention 10% of active compound mixture [Compound (A) ♦ • Compounds (I) to (XXXI) = 1: 35 0] Octylphenol polyethylene glycol ether (4 to 5 moles of E0 ) 3% calcium dodecylbenzenesulfonate 3% castor Polyethylene glycol ether (36 mol E0) 4% cyclohex_ 30% xylene mixture 50% Any emulsion of desired concentration can be prepared from this concentration by dilution with water β (Please read the first Please fill in this page again.) Example F7 printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs: powder dust a) b) active compound mixture (2: 3) 5% 8% talc 95% kaolin 92% ready-made dust Classes are obtained by mixing the active ingredients with a carrier class and grinding them in a constitutional mill. -45- -nnk— «I n · This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) V. Description of the invention (year>) Α7 Β7 S & Example F8:» Presser particle activity Compound mixture 10% Compound (A): Compounds (I) to (XXXI) = 1: 4] #Sodium Sulfonate 2% _Methylmethyl Cellulose 1% 87% $ 14 Ingredients are mixed with added amidines, and The mixture was ground and hydrated. This mixture is extruded, granulated and then dried in an air stream. (Please read the precautions on the back before filling this page.> Order · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Example F9: Coated granule active compound mixture%% [Compound (A): Compound (I ) To (XXXI) = 1: 300] Polyoxan (MW 200) 3% Kaolin 94 96 In the mixer * the finely ground active ingredient is uniformly applied to kaolin, which has been wetted with polyethylene glycol Kft method, powder-free coated particles are obtained. -46- This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) A7 B7_____ V. Description of the invention (fewer f) Examples F10: suspension

Active compound mixture (2: 350) 40X

Glyoxal 10X Nonylphenol Polyglyoxyl Ether (15 Molar E0) 6X Lignosulphonic Acid Sodium 10 X Carboxymethyl Sulfate Vitamin It 37X Formaldehyde Aqueous Solution 0.22 75 × Water-based Milk Cocoon Siloxane Oil Q.8X Water 3? X (please read the precautions on the back of the collar before filling in this page) The active ingredients of fine grinding printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs are closely mixed with the additives. This gives a suspension splash insert from which a suspension of any desired concentration can be prepared by dilution with water and adding K. Usually, the active ingredient of the individual formula (Α) and one of the other ingredients (I) to (XXXI) are more convenient, and only a short time before application is required to mix the desired mixing ratio in the applicator and # in the water. "Mixed" forms merge them. Biological examples (% = percentage of weight ft, unless otherwise specified) -47- This paper size applies to Chinese national standards (CNS> A4 specification (210 X 297 mm) A7 _B7 _ V. Description of the invention (A The effect of the combination of the active ingredient and an active compound (I) to (XXXI) EA The effect of the individual application of the active compound The synergy effect exists: ΕΑι > Ϊ + Y (B) The expected killing activity of a given leg of a killing tincture can be calculated by the following formula (see COLBY, SR, "

Calculating synergistic and antagonistic response of herbicide coibinations *, Weeds 15, pages 20-22 · 1967): Y (100-X) ikz = X + -------- 100 In this formula: X = utilization formula (A) Compounds treated at an application rate of p kilograms per hectare compared to the percentage mortality of untreated control sisters (= 0%). -4 8-This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 public love) (-Please read the precautions on the back before filling in this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs.H 1 I n II (·-A7 B7____ V. Description of the invention (middle h < please note the $ on the back of sil before filling out this page) y = use (I) to UXXI) compound M q q kg per hectare The percentage of mortality when treated at a rate 'compared to the untreated control group (= 0.96). EA = Expected killing activity after treatment with one of the compounds of formula (A) and one of compounds (I) to (XXXI), K + hectares of P + q kg of active compound (compared to the percentage of death in untreated control ) Β A synergistic effect exists when positively observed activity exceeds the expected value EA. Example B1: Activity line against cotton whitefly (Byisia tabaci) · Printed dwarf legumes printed by the Shellfish Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs were placed in a golden salamander and spread the results of Beaisia tabac i After oviposition * all diagenesis is removed. After 10 days * Plant K and its larvae were sprayed with an aqueous suspension 混合物 mixture containing 50 ρρ · active compound mixture. After 14 additional days of hydrocarbons, the percentage of egg hatching rate was evaluated compared to the untreated control batch. In this experiment, the confluence of the active compound of formula (A) with one of the active compounds (I) to (XXXI) has a synergistic effect. In particular, suspensions containing 40 ppa compound (a. 1) and 10 ρρι compound (II) 嗔 -4 9 * This paper size applies the Chinese National Standard (CNS) A4 specification (21〇X 297 mm) Wisdom of the Ministry of Economic Affairs Printed by the Consumer Cooperative of the Property Bureau A7 ___B7_ V. Description of the Invention (Shishi 0) The sprinkled mixture has an activity exceeding 80%. Example B2: Active immature soybean plants against Spodoptera littoralis caterpillars Using an aqueous milk containing a mixture of 360 ρ · active compound _ spraying mixture for clear spraying "After the irrigated coating was dried on it, the cockroach plant M 10 Only three instar Spodoptera littoralis hairy pheasants are distributed and placed in plastic containers. The trial was evaluated after 3 days. The percentage reduction of each * group or the reduction percentage of eating damage (activity) is determined by comparing the number of dead hairy clams and feeding loss on the untreated plants with the untreated plants. In this experiment, the confluence of the active compound of formula (A) with one of the active compounds (I) to (XXXI) has a synergistic effect. In particular, * the mixture including 200 PP · compound (A) and 60 ρρ · compound (II) is sprayed with the mixture and the suspension leak mixture including 180 ρρ · compound (A · 3) and 180 PP · compound (XV) 80% active. . Example B3: Against the egg-killing activity of Lobesia botrana The Lobesiabotrana eggs laid on the filter paper were briefly immersed in a test solution including a mixture of 400 ρρ · active compound, and then the M was adjusted in the tune / -50. (CNS) A4 specification (210 X 297 mm) -Ί- ^ —— — — — — — — — II · 1111111 ^ 11111111 IC Please read the precautions on the back of the effect before filling out this page) -H ϋ / I .1 a— A7 B7__ V. Description of the invention (ff) The test is performed in water. After the test solution has dried on, the eggs are incubated in shallow Petri dishes. After 6 days, the percentage of o-Shuahua eggs was evaluated in comparison to the untreated control batch (% reduction in hatching rate). In this experiment, the confluence of the active compound of formula (A) with one of the active compounds (I) to (XXXI) has a synergistic effect. In particular, the floating liquid spray mixture M including 300 PPB compound (A · 5) and 100 ρρ · compound (III) and 200 PP · compound (A · 5) and 200 ρρ · compound (XVI) Suspension sprinkler mixture has an activity exceeding 80%. Example B4: Egg-killing activity against Heliothis virescens The eggs of Fleliothis virescens laid on paper were briefly soaked in a test solution including a 400 ρρ · active compound mixture in a Caries / water test. After the test solution dries thereon, the eggs are incubated in a shallow culture dish. After 6 days, the percentage of egg hatching rate was evaluated in comparison to the untreated control batch (% reduction in hatching rate). In this experiment, the confluence of the active compound of formula (A) with one of the active compounds (I) to (XXXI) has a synergistic effect. Especially * suspension containing 240 ρρ · compound (Α · 1) and 160 ppi compound (XII) -51-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read first. Read the notes on the reverse side and fill in this page again) Order: --line-printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 887791 Α7 Β7 V. Description of the invention (⑹) Sprinkle the mixture M and include 3GG ρρ · Compounds (A · 5 ) And 100 PP · Compound (V) Suspension Sprinkled Mixture Has Super * 80% Activity. Example B5: Activity against plutella xylostella hair II Immature cabbage plants were flooded with an aqueous emulsion spray mixture comprising a mixture of 440 ppi active compounds. After the coating was sprayed on the suspicion, the plants of Gan M were distributed with 10 Sangui small vegetables «(Plutella xylostella) hair ft and placed in plastic containers. The test was evaluated after 3 days. The percentage reduction of the collar group into the reduction percentage of feeding damage (% activity) is determined by comparing the number of dead hairs a on the plant material and the feeding damage with the situation of untreated plants. In this experiment, the confluence of the active compound of formula (A) with one of the active compounds (I) to XXXI) has a synergistic effect. In particular, including 400 <, please fill in the notes on the back before filling in this page) Printed PP · Compound (A * 5) and 40 PPB Compound Spilled Mixture M and included by the Intellectual Property Bureau of the Ministry of Economic Affairs and Shellfish Consumer Cooperatives 220 PP · Compound (

Suspension (VII) A ♦ 7) and 22Q PPH Compound (IV) Suspension spray mixture has 80% active makeup Example B6: Myzus persicae fli against large aphids 6 Capsicua Plant (Capsicu · annuua L ·) K water-5 2-This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) A7 ____ _B7___ V. Description of the Invention (C5) Emulsified liquid 顷Sprinkles * This liquid tincture includes individual compounds and compounds according to the table below. The plant was placed in a chamber until the activity was determined to be 0. The activity against Myzus persicae was swarmed in biological experiments. After 2-4 hours of application, the leaf K molds were taken in a drawing type "* The upper and lower faces were placed on the agar cells in Petri 磲 and the M. persicae mixed ethnic group was included, which included 40-50" 髗, Carry out a large number of infections. Nine leaf blades were used for each scale. Petri dish wool tracing paper is covered with M, covered with a plastic lid, and placed in a climate incubator for plants. 2 days after a large number of infections, the garden-shaped objects removed from the leaves were cleared into 蠹 * empty and 蟠, so that only 25 to 40 tadpoles kept in the night remained in each Huazi noodles. 4 days after a large number of infections Calculate mortality by counting death and survival. The test was performed 3 times. The results are shown in the table below as the test averages. Table •• Synergistic effect of the pesticide mixture: Μ · persicae — — — — — — — — 1 illllll ^ illlKi! ^ F ^ fv {锖 Read the notes on the back first and then fill out this page) I 1 · PPI effect of compounds / mixtures printed by employees' cooperatives in the Intellectual Property Bureau of the Ministry of Economy X ΕΑι X calc. Formula (B) EA2 X calc. Formula (c) A.5 0.1 5.9--A.5 0.2 35.0--- 53- This paper size is in accordance with Chinese National Standard (CNS) A4 (2ί0 x 297 public love) A7 B7 Bufeisong 35 12.3--Semexine high-cis 600 8.2--Piracetam 0.3 38.4--A.5 / Bufeisong 0.1 / 35 31.4 18.2 17.5 A.5 / Semexin high-cis 0.1 / 600 22.8 14.1 13.6 A.5 / Semexin high-cis 0.2 / 600 65.6 43.2 40.3 A. 5 / Pemex 0.1 / 0.3 53.1 44.3 42.0 (Please read first, read the notes on the back, then fill out this page)

LiJ line Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -54- This paper size is applicable to National Standards (CNS) A4 (2) 0 X 297 mm

Claims (1)

387791 、 Application for patent 谞 1 * A composition for controlling a representative of Kun Shou suspect (A ca rj na), which includes a sister compound, the composition includes different amounts of-one or more compounds of the following formula Free form or «form, if it can be a tautomer in free form or salt form when combined, CI Please first read the note I printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs and includes one or more of the following compounds: (111) ¾ cypeiiejthriii, cyperiethrin high-cis; cyperiethrin high-cis; (X? I) profen ofos; (XXIV) py ^ etrozine; or (xxx) thiocycla ·; and at least one adjuvant. 2 ♦ If the composition of the first item of the patent model is applied, it includes only one of the compounds (in), (hi), (χπυ or (XXX). 3. If the composition of the first item of the patent model is applied , Which includes cyperjlethrin, high-cis (cyperaethrin high-cis) 0 4. The composition of item 1 of the Shenyang Patent Model Group, which includes Bufeisong (... China National Standard (CNS) A4 (210x297 mm) 387791 、 Application for patent 谞 1 * A composition for controlling a representative of Kun Shou suspect (A ca rj na), which includes a sister compound, the composition includes different amounts of-one or more compounds of the following formula Free form or «form, if it can be a tautomer in free form or salt form when combined, CI Please first read the note I printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs and includes one or more of the following compounds: (111) ¾ cypeiiejthriii, cyperiethrin high-cis; cyperiethrin high-cis; (X? I) profen ofos; (XXIV) py ^ etrozine; or (xxx) thiocycla ·; and at least one adjuvant. 2 ♦ If the composition of the first item of the patent model is applied, it includes only one of the compounds (in), (hi), (χπυ or (XXX). 3. If the composition of the first item of the patent model is applied , Which includes cyperjlethrin, high-cis (cyperaethrin high-cis) 0 4. The composition of item 1 of the Shenyang Patent Model Group, which includes Bufeisong (... China National Standards (CNS) A4 specification (210x297 mm) 3S7791 ajC8 _ D8, scope of patent application P'rofenofos) 〇 5 if the composition of the patent application for the first item, which includes Pyrotroziue) 6. If applying for the composition of item 1 of the noodle soup, it includes the noodle planting poplar as the noodle soup. 7. A method for controlling the plug a *, which comprises applying the adult product of any one of items 1 to 5 of the application box patent garden to a pest or its puppet. 8 ♦ The method of applying for item 7 of “Profit” • It is used to protect plant propagation material, including the location of the plant propagation material or the plant propagation material. Dili Fanli Special Note: If you want to make a seed at a price, please note it on page I. The method is printed by the Intellectual Property Bureau Staff Consumer Cooperative of the Ministry of Economic Affairs. The mixture of ingredients is sufficient to cope with a supplementary agent, a supplementary agent, a supplementary agent, or a supplementary agent, and the combination of the supplementary and chemical properties will be included on the paper scale. (CNS) A4iUft. (210X297 ^ *)