TW386096B - Polyphenylene ether resin composition - Google Patents

Description

A7 B7 V. Description of the invention (1) Background of the invention The invention relates to a thermoplastic resin, which includes a polyphenylene ether resin and an amorphous thermoplastic resin, and has improved process stability and thermal stability in practical use. Of characteristics. Relevant technical description._ A polyphenylene ether resin is a thermoplastic resin, which is better in many characteristics, such as mechanical properties, heat resistance and dimensional stability. However, it is used for coloring and deteriorates during high temperature molding, such as crosslinking. Especially in the presence of oxygen, gelation caused by heat causes serious deterioration, increasing molecular weight or sometimes black spots. In addition, polyphenylene ether resins are prone to discoloration due to light. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). In order to overcome the shortcomings of this resin, different additives have been proposed. For example, Japanese patent Kokoku 44-2075 1 proposes a phosphorous additive, and Japanese patent Kokoku 4 6-2 4 7 8 2 proposes a phenolic additive. In addition, many attempts have been made mainly to suppress photofading, such as the use of stabilizers containing little hindered amines or stabilizers containing hindered amines and phenolic additives, which are disclosed in Japanese Patent Kokai 60-14964 6 No. 60-203150, U.S. patents 4232131, 423 3 4 10, 42334 12 * 4234699, 4260689, 426069.1 and 4299926, EP09 4 048A2, EP 134523A1, EP14 6 879A2, EP146878A2, this paper size applies to Chinese National Standards (CNS) A4 specifications (210X297 mm) A7 B7 V. Description of the invention (2) EP151961A1, EP 1 49454A2, EP233153A2, EP240723A2, EP229363A2 and EP313118A1. Many of these trials have helped to improve the evaporation resistance of stabilizers during processing or in actual use 'and proposed different compounds containing sterically hindered amines alone or copolymers (oligomers) with other components. However, none of these proposals provides a sufficient effect of suppressing deterioration when heated. Summary of the Invention The present invention relates to a thermoplastic resin composition including a polyphenylene ether resin and an amorphous thermoplastic resin, which suppresses heat during processing, especially heat Caused by deterioration. The inventors of the present invention have found that by adding a sterically hindered amine compound having a special structure to a composition including a polyphenylene ether resin and an amorphous thermoplastic resin, the deterioration due to heat can be effectively suppressed. The present invention relates to a thermoplastic resin composition comprising: (a) 1 to 99% by weight of polyphenylene ether resin, printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling in this guide) ) (b) 99 to 1% by weight of at least one amorphous thermoplastic resin consisting of an alkenyl aromatic resin, an amorphous aromatic polyester resin, a methacrylic resin, a polyetherimide resin, and An aromatic polymer resin is selected and includes (C) 0. 0 0 1 to 15 parts by weight per 100 parts by weight of the sum of (a) and (b) at least one of the following formula (1) or (2) 4—Amine—2,2,6,6 — This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) ~ A7 B7 V. Description of the invention (3) Tetramethylpiperidine Compound R2N- R. c, c CH, I i CH. CH. (1) R, n (Please read the precautions on the back before installing

R 彳 · / 'CH3s.l CH, /, N〆 3 I R ......,) Plant 1 C 1 .CH, CH, < 3 3, CH3 CH3 1 ^ Λ (2)

, 1T •• Wherein 1 represents a hydrogen atom, an oxygen atom (containing oxygen). 'A hydroxyl, an alkyl, a cycloalkyl, an allyl, a benzyl'-an aryl, an alcohol Group, an alkenyl group, an alkoxy group, or a cyclooxyl group. R 2 represents a hydrogen atom, ~ a radical or a group represented by the following chemical formula (3), 0

II r4c + x + r5 where X represents a direct chain, 10- or NH- 'R4 represents a direct bond, a straight-chain or branched alkylene, an alkylene or -arylene, 115 represents One hydrogen atom, one alkyl group, one aryl group or — a group represented by the following chemical formula (4) or (5) 'This paper size applies to Chinese national standards (CNS> Α4 specifications (210 × 297 mm) \ \ Ministry of Economy Printed by the Consumer Standards Cooperative of the Central Bureau of Standards (3) A7 B7 V. Description of the invention (3) Tetramethylpiperidine compound:

/ \ 3 1 CHCH

CHCH η NIC.'M OcT * c — c, \ 3, K H c c

CH rt (c \ ^ c

\ 丨, c ”w * · // 3 Ί CHCH Printed by the Consumers Cooperative of the Standards Bureau of the Ministry of Economic Affairs (3) R 4 represents; where 111 represents a hydrogen atom, an oxygen atom (containing oxygen), and a hydroxyl group, An alkyl group, a cycloalkyl group, an allyl group, a fluorenyl group, an aryl group, an alcohol group, an alkenyl group, an alkoxy group, or a cycloalkoxy group. 112 represents a hydrogen atom 'an alkyl group or a group represented by the following chemical formula (3), 0

II -r4c ten x + r5 where X represents a direct bond,-or an NH, a direct bond, a straight or branched alkylene group, an arylene group, or an alkylene group, and R 5 represents a hydrogen atom, An alkyl group, an aryl group or a group represented by the following chemical formula (4) or (5) 'This paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) 5. Description of the invention (4

-CH * CHCOH A7 B7 ¢ 4) 3 3 Η Hc c

, C—c 丨 c NIR \ / CIC 33 Η Ηc c 5 where η represents an integer from i to 4 and p represents an integer from 2 to 6 '113 represents an n-valent organic group. A detailed description of the polyphenylene ether resin (a) of the present invention is a polymer obtained by oxidative polymerization using at least one phenol compound represented by the following chemical formula and oxygen or an oxygen-containing gas using an oxidative coupling catalyst; (Please read the precautions on the back first Again ^! # This page) • The order is printed by the Consumer Cooperative of the China Standards Bureau of the Ministry of Economic Affairs

RiK. OH t…) 丨 1 Ris " where R is · R 1 * 1 Rl7 ί β, RlT ·, RlS and Rl9 each represent a hydrogen atom, a halogen atom or a substituted or unsubstituted hydrocarbon group, and where At least one is a hydrogen atom. Examples of R15, Rle, R17, Rle and Rie are hydrogen, chlorine, and bromine. The paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) -line-7-A7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Preparation of the fifth, description of the invention (5) 1 fluorine > iodine > methyl > ethyl n- or iso-propyl P ri — 9 zero one or-1 1 1 second butyl chloroethyl hydroxyethyl phenethyl Benzylhydroxymethylcarboxyl-1 1 ethyl 9 methoxy v / jfr m yl ethyl cyanoethylphenyl chlorophenyl tolyl 9 1 read 1 1 xylylethylphenyl and M propyl 0 read 1 I read 1 The compound represented by the above formula is an example of a phenol 0 — m 1 of 1 or 1 P-cresol 2 6 — 2 5 — 2 4 — or 3 5 — Note 1 dimethylphenol 9 2 monomethyl — 6 —phenol 9 2 6 —di-phenol 2 ψ term 1 9 6 diethylphenol 2 monomethyl-6 — ethyl Phenol 2 3 5 — > Με =-m page 4 1 9 2 3 6 — or 2 4 > 6 — trimethylphenol 3 — methyl-1 1 — t-butylphenol thymol and 2 — Methyl-6 monoallylphenol 0 1 1 The phenol compound of the above chemical formula may also be copolymerized with other phenolated α compounds. Example 1 1 Such as a polyhydroxy aromatic compound such as bisphenol A tetrabromobisphenol A resorcinol 1 phenol Hydroquinone and novolac resin 0 1 I A preferred example of the polyphenylene ether resin (a) may be 2 6 —dimethyl 1 1 homopolymer of phenol 2 6 — homopolymer of diphenol 1 1 .. 2 6 1 —. Methyl phenol and a smaller amount of 3 — methyl — 6 — t — butyl phenol or I 2 3 6 — dimethyl phenol copolymer can be prepared as long as it has polymerization ability can be used Any oxidative coupling catalyst to oxidize 1 1 to polymerize the phenol compound 0 1 1 The present invention The crystalline resin (b) is a thermoplastic resin composition having a crystallinity of 5% or higher I, which uses conventional injection molded articles to measure f with a differential scanning calorimeter (DSC) and preferably at least- Polyethylene tree 1 1 I Lipid polypropylene resin Polyamide resin poly (alkylene dicarboxylate) tree 1 1 Lipid polyacetal tree my Polyarylene sulfide resin and polyether ketone resin Choose 1 1 Paper size applies to Chinese national standard (cns) μ size (ηοχ297 mm) A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (6) 1 of which 0—-1 1 Polyethylene resin used in the present invention Including-1 kind of ethylene homopolymer, 1 1-an ethylene-a-olefin copolymer such as-* a kind of ethylene-propylene copolymer 1 1 J-a kind of ethylene-butene-1 copolymer a kind of ethylene-4-methylpentyl Please read 1 1 1 1 Copolymer type ethylene-hexene-1 copolymer—type ethylene-synthetic copolymer 1 1 ene copolymer and an ethylene-decene-1 copolymer 〇The polyethylene resin can be noticed 1 I classified into low density polyethylene (LDPE) Its density is 0 9 14 Matters again-. · I 1 to 0 • 9 2 5 g / C m 3 1 Medium density polyethylene (MDPE) > Substitute 4 has a density of 0 9 2 5 to 0 9 4 g / C m 3 and HDPE 1 1 Ethylene (Η DPE) with a density of 0 9 4 to 0 9 6 g / 1 C m 3 | It is based on Japanese Industrial Standards_J [SK6760 Class 1 Special 1 1 Special 9 In LDPE, the ethylene-a-olefin copolymer can be referred to as linear low-density polyethylene (LLDPE) 〇1 I In addition, the ethylene-a-olefin copolymer also includes lower density, 1 1 I such as very low density The density of polyethylene is 0 9 0 to 1 1 0 9 1 4 g / C m 3 (VLDPE) and the density of ultra-low density polyethylene is 0 8 8 to 0 9 0 S / C m 3 (1 1 ULDPE) 〇The melting point of both VLDPE and ULDPE is 1 1 8 0 X or higher. At this point, it can be distinguished from 1 with the same density range | Ethylene — a — olefin copolymer rubber 〇I The polyethylene resin may be a modified polyethylene onto which a 1 | kind of monomer having at least — functional groups > such as a β — unsaturated acid, 1 1 I Aliphatic carboxylic acid and its derivatives 0 1 1 The polypropylene resin of the present invention includes:-a kind of crystalline polypropylene such as a 1 1 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) B7 5 、 Explanation of invention (7) (Please read the notes on the back first, and then the page) Crystalline propylene homopolymer and a crystalline propylene_α-olefin copolymer, which contains 30% by mole or less of ethyl acetate and / or At least one α-olefin different from Bing Can. It includes a crystalline propylene α-olefin block copolymer 'which is a first step polymerizing propylene or copolypropylene with 6 mole% or less ethylene and / or at least one α-olefin (such as butene-1) , And then in a second step prepared by copolymerizing propylene with 10 mol% or more of ethylene and / or at least one α-olefin, and a crystalline propylene_α_olefin random copolymer, which is composed of propylene and 6 Molar% or less is prepared by copolymerization of ethylene and / or at least one alpha-olefin such as butene-1 and hexene-1. -* ·-— * 一 — ~ __ The cold amines used in the present invention are one or more polyamidoamine resins, which are made from a homopolyamidoamine, which is made by polymerizing an endoamine or an aminocarboxylic acid. And a copolyamide, such as an aliphatic polyamidoamine, which is a saturated diresidual acid having 4 to 12 carbon atoms and a 2 to 12 carbon atom It is prepared by copolymerizing aliphatic diamine. The content of amine end groups in the copolymerized amines is not necessarily greater than the content of carboxy end groups in the use of excess diamine. In the reaction ', the content of the carboxyl end group is larger than that of the amine end group when an excessive amount of dicarboxylic acid is used. Printed by the Consumers' Cooperative of the China Standards Bureau of the Ministry of Economics. Similarly, the polyamide resin can be prepared using derivatives of the acids and amines, such as esters, acid chlorides and amine salts. The aliphatic dicarboxylic acid from which the polyamide resin is prepared may include adipic acid, pimelic acid, azelaic acid, suberic acid, dodecanedioic acid. On the other hand, the aliphatic diamine includes hexamethylene Diamine and Octamethyldiamine. In addition, the polyamide resin can be prepared by self-condensation of lactam. Examples of the aliphatic polyamine include polyhexamethylene hexamethylene diamine (resistance to this paper is subject to the Chinese National Standard (CNS) A4 specification (210X297 mm) -10-B7 V. Description of the invention (8) Polyamide 66), polyhexamethylene nonylamine diamine (Nylon 69), polyhexamethylene decanediamine diamine (Nylon 610), polyhexamethylene dodecylamine t (Nylon 612 ) 'Poly-bis- (P-aminocyclohexyl) methanedodecylamidoamine, polytetramethylene adipamide diamine copolymer (Nylon 4 6, Nylon 6' Nylon 10, Nylon 11 , Nylon 12, nylon 6/6 6) and optionally use two or more of this nylon. Nylon 4 6, nylon 6, nylon 6 6 ′ nylon 11 and nylon 12 are preferably used in the crystalline polyamide resin. It is better to use nylon 6, nylon 66 ', and any mixture of nylon 6 and nylon 66. Among the terminal functional groups of the polyamide resin, those having excessive amine end groups', those having excessive carboxyl end groups, those having an equilibrium number of the two, and mixtures of any ratio thereof are more suitable. Aromatic copolyamides with crystallinity are also included. For example, it includes a copolymer polyamide containing an aromatic component such as polyhexamethylene isophthalamide (Nylon 6 1). The aromatic copolymer polyamide mainly contains an aromatic amino acid and / or an aromatic amino acid. Aromatic dicarboxylic acids, such as P-aminomethyl benzoic acid, P-aminoethyl benzoic acid, terephthalic acid and isophthalic acid, which can also be prepared by melt polymerization. Two of the aromatic copolyamides used Amines include hexamethylenediamine, deca-methyldiamine, dodecamethyldiamine, 2,2,4-a / 2,4,4_trimethyl_hexamethylenediamine, partial Dixylyldiamine, p-xylyldiamine, bis (P-aminocyclohexyl) methane, bis (P-amino-cyclohexyl) propane, bis (3-methyl-4-amino) Cyclohexyl) methane, 1,3-bis- (aminomethyl) cyclohexane, and 1,4-bis- (aminomethyl) _cyclohexane. In addition, isocyanates can be used in China for this paper size National Standard (CNS) Α4 Specification (210 × 297 mm) Please read the note on the back * Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 11 A7 _____B7___ V. Invention (9) Substituted diamine. For example, it includes 4,4 diisocyanate > -diphenylmethane ester and tolyl diisocyanate. The copolymerization component selectively used in the polyamide resin is No particular limitation and derivatives of lactam, ω-amino acids having 4 to 12 carbon atoms, aliphatic dicarboxylic acids having 4 to 12 carbon atoms, and 2 to 12 carbons can be used Atomic aliphatic diamines, such as caprolactam, omega-laurylamine '1 1-amino undecanoic acid, limonamine and 12-aminododecanoic acid, amino acids and the different diamines described above and Molar salts such as aliphatic acids, azelaic acid or sebacic acid, etc. A mixture of an amorphous polyamine and a crystalline polyamine resin in any ratio is selectively used. '' The poly (alkylene dicarboxylate) of the present invention ) Resin is produced by polycondensation of a dicarboxylic acid or a functional derivative and an alkylene dioxy compound or a functional derivative thereof. Examples of the dicarboxylic acid printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs include an aromatic Dicarboxylic acids, such as terephthalic acid, isophthalic acid 'and 2,6-amidine dicarboxylic acid, a nuclear substituted aromatic dicarboxylic acid' which The hydrogen atom of the aromatic ring is substituted by methyl, ethyl or phenyl, an aliphatic dicarboxylic acid having 2 to 20 carbon atoms, such as fatty acids, sebacic acid and dodecanedicarboxylic acid, and aliphatic A cyclodicarboxylic acid, such as cyclohexanedicarboxylic acid. Functional derivatives of a dicarboxylic acid include an acid chloride of the above compound and an ester such as methyl carboxylate and phenyl carboxylate. Examples of the compound include an aliphatic diol and an alicyclic diol such as ethylene glycol, 1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, 1 ， 10-decanediol This paper is in accordance with Chinese National Standard (CNS) A4 specification (210 × 297mm) 'A7 __. _B7_ V. Description of the invention (10) and 1,4-cyclohexanediol. An example of a functional derivative of an alkylene dioxy compound is a diacetate. Two or more of the above compounds can be used, and a copolymer containing P-oxybenzoic acid or polyethylene glycol can also be used. Polyarylene sulfide resin is a polymer composed of recurring units represented by the following chemical formula (1 2) (wherein A r represents a divalent aromatic residue) "i -6Ar — (12)

I

.. I Examples of this Ar include a divalent aromatic residue and the following chemical formulae (13) to (22) represent nuclear substituted residues. General Moore (1 3) (14) (15) 丨:-(〇) -s〇2 — < ^ >-(16) (17) (18) (19) This paper size applies Chinese national standards ( CNS) A4 specification (210X297 mm) (Please read the notes on the back before _ repairing this page) Order A7 B7 printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (11)-(〇) -C (CH3) 2— (20) (21)

Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs In addition, Ar also includes a small amount of trifunctional energy bases represented by the following chemical formula (2 3).

I (23)

Examples of the polyarylene sulfide resin represented by the chemical formula (12) include poly (phenylene sulfide), poly (1,4-phenylene carbonyl-1,2,4-phenylene sulfide), and poly (1, 4_phenylenesulfonyl-1,4-phenylene sulfide), and poly (bisphenylene sulfide). Among them, the polyarylene sulfide resin is preferably a polyarylene sulfide having 50 mol% or more of a recurring unit represented by the following chemical formula (2 4). Preferably, a polyphenylene sulfide having a crystallization temperature at a falling temperature of 2 5 ° C or lower is most preferred. Therefore, the crystallization temperature at the falling temperature is the crystallization temperature measured at the falling temperature after melting, and its value is measured as D S C and the temperature drop rate is 10 ° C / min. This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) 5. Description of invention (12. General A7 B7

S (2 4) In general, there are two types of resins in these polyarylene sulfide resins, such as a linear type and a cross-linked type, which include partial cross-linkers. Both can be used in the present invention, and a linear type is preferred. A 4-amino group-2,2,6'6-tetramethylpiperidine compound (c) having a sterically hindered amine group as a basic skeleton is represented by the following compound (1) or (2): RN ... .. / i I c / C, cΉ〆% CH3〆, CH: R, R. (1) Please make a note of the first item to print RH-- 2I 〆 [, cc CH3 , 1 CH3 /, N〆, CH: R.-Η P 1 c " S ch7 > 1 1 J CH- ·, vc 1 R, ^ CH. (2) where Ri represents a hydrogen atom and an oxygen atom (including (Oxy group), one hydroxyl group, one alkyl group, one cycloalkyl group, one allyl group, and one benzyl group. The paper size applies to the Chinese National Standard (CNS.) A4 specification (210X297 mm) -15-five A7 B7, Description of the invention (13)-an aryl group, an alcohol group, a methyl group, a oxo group or a cyclic oxo group. R2 represents a hydrogen atom 'a courtyard or an alkyl group represented by the following chemical formula (3), 0 II r4c + x + r5 (3) where X represents a direct · chain, —0' or -N__H — 'R4 represents A direct bond, a linear or branched alkylene, an alkylene or an arylene 'represents a' hydrogen atom ', a alkynyl group, an aryl group, or one of the following chemical formula (4) or' (5) (C4)

-CH ^ CHCOH (Please read the precautions on the back first—v r this page). Equipment · 33 Η H c c

, C * c f \ f cN \ -CIC 33 Η Η c c 5

R Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. The number is shown in the table. The number is shown in the table. The whole number is 1 in 14. 6 in 2. Tables show that there are valuable η units.

Under 6 V glisamide, 1 is as good as 4 examples, which is better than the 2 compounds (combination or chemistry)> 1 piperyl group. Formula A shows the 2 to [I] when η is 1 and R3 is 1 Hydrogen atom, one alkyl group, one ring group, one storage group, one narrow group, one aryl group or one of the following chemical formulas. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (2 丨 0X297 mm) -16 -When printed by A7 B7___ in the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs V. The group represented by the invention description (14) (6); 0 Η-R6C 十 Υ γκ7 (6), where γ represents a direct bond, 1 —Or an nr8—, Re represents a direct bond, a straight or branched alkylene, an alkylene or an arylene, and Rt and Rs individually represent a hydrogen atom 'a shoky'-an alkyl or an More preferably, when η is 1, Ri and R 2 each represent a hydrogen atom or an alkyl group having 1 to 18 carbon atoms, 113 represents a hydrogen atom, _ a courtyard group, a cyclic group A 'cannyl' or a group represented by the chemical formula (6), where Y represents a direct chain 'a0—' or —nr8 _ Re represents a direct bond, a straight or branched alkylene group having 1 to 10 carbon atoms, an alkylene group or an arylene group, R 7 and R 8 each represent a hydrogen atom, and one has 1 to 1 8 A carbon, atomic alkyl group 'is an aryl group with 6 to 21 carbon atoms or a group represented by the chemical formula (4) or (5). [Π] When η is 2, R 3 is an alkylene group Or a group represented by the following chemical formula (7); a '(Please read the precautions on the back first ¾ r this page)-binding · binding

one 9 ROMC 7 .ί-link straight 1 shown in Table 9 R the alkane extension branch or chain straight this paper standard applicable Chinese national standards (2 like gifts) _ 1? _ A7 £ 7_. 5 2. Description of the invention (15) alkylene or an arylene. More preferably, η is 2, 111 and 112 each-represents a hydrogen atom or an alkyl group having 1 to 18 carbon atoms, R 3 represents an alkylene group or a group represented by the chemical formula (7), Wherein 119 represents a direct bond, a linear or branched alkylene group having 1 to 10 carbon atoms, an alkylene group or an alkylene group. For the compound in the chemical formula (1), when η is 2, R2 represents a group represented by the chemical formula (· 3), where X represents a direct bond, -0_, or NH_, and R4 represents a direct bond, a A straight or branched alkylene group, an alkylene group or an alkylene group, R5 represents a hydrogen atom, an alkyl group, an aryl group, or a group represented by the following chemical formula (4) or (5), In addition, R 3 represents an alkylene group, which is more preferable. [Dish] When η is 3, R 3 is a group represented by the following chemical formula (8); (Please read the precautions on the back first and then this page) Ρ • 装. Order

Ηc Η H 丨 o 丨 c r CH ο

Hi ο Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

NIC o 丨 sc〆

lCH

CH 丨 CHC r CH 1/8 Γ \ >! Or when group 4 is η, it means when the table \ ly V ο

* 钂 CH ot HR type academic list consists of one sheet and one sheet of paper. M λ— / Ns c / 1 \ quasi-standard home country one country I-China use suitable centimeter 7 9 2 / A7B7 V. Description of the invention ( 16 〇u CHa C * Ο «CHC- O Μ CHC- (9) (Please read the notes on the back first O tl CH. C- O < 1 (10) this page). Equipment-Set the central standard of the Ministry of Economic Affairs Printed by the Consumer Cooperative of the Bureau [V] In addition, the compounds represented by the following chemical formula (1) are also more than-% R_N ....... -R3 2i _ / CNr CH3, JpH3 ⑴ ⑶ /, 〆, CH3. _ Rl-Ω In the chemical formula (1), 'represents a gas atom, an oxygen atom (containing an oxygen group), a hydroxyl group, an alkyl group having 1 to 8 carbon atoms, a cycloalkyl group, an allyl group, and a benzyl Group 'an aryl group, an alcohol group, an alkyl group', a alkoxy group, or a cyclooxy group 'and η is an integer in' 1 '2 or 4; when η is 1, R2 represents a hydrogen Atom 'Paper New Zealand Financial Standards (⑽) A4 · (210X297 mm) _ A7 B7 V. Description of the invention (17) — an alkyl group with 1-8 carbon atoms or

-C-(p)-(Q)-C- OH

II II 〇〇 ′ where P and Q represent a selected group consisting of an alkylene group, an alkylene group, a vinyl group, and a vinylidene group, and R 3 represents a hydrogen atom, an alkyl group, and a cycloalkane Group, an alkenyl group, a fluorenyl group, an aryl group or a group represented by the following chemical formula (6); 0 I! -R «C 十 Y ^ R7 (6) where 'Y represents a direct bond A, 0 —, a NRs — 'Re represents a direct bond, a straight chain or branched alkylene, an alkylene or an alkylene, 117 and 8 each individually show a hydroxyl group, an alkyl group' a An aryl group or a group represented by the following chemical formula (4) or (5) '

-CH ^ CHCOH

u C (Please read the note on the back π "This page". Binding and ordering _ Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 3 3 Η Ηc c

CIC 丨 c c ·

-丨 R 33 Η Ηc c Time-base 2 alkane is the η atom; carbon

Each of the original hydrogen is shown in Table 2 R 8 1 1X has one or this paper size applies Chinese National Standard (CNS) A4 specification (21〇 × 297 mm) _ A7 B7 V. Description of the invention (18) -C-( P)-(Q)-C-OH II II 0 〇, where P and Q represent a member selected from the group consisting of an arylene group, an alkylene group, an ethylene group and a vinylidene group, R 3 Representation — one alkylene group or one group represented by the following chemical formula (7), one 9 Rone

T (Please read the precautions on the reverse side before printing. 装 It is printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, where 119 represents a direct bond, a linear or branched alkylene, an alkylene or an alkylene; When η is 4, 114 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and R 3 represents a group represented by the following chemical formula (9) or (10), 〇 II CHaC- 〇 < 1 CHC- 〇 (9) 丨 π CHC- Ο η CH, C- 〇c—ecH, occh, (ι 〇) This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) Π1 -21-order A7 B7 V. Description of the invention (19) Even better, in formula (1), R ^ and R 2 each represent a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and (i) when η is At 1, R3 is a hydrogen atom, an alkyl group, a cyclofluorenyl group, an alkenyl group or a group represented by the chemical formula (6), wherein Y represents a direct bond, a 0-or a NR8-, and Re represents A direct bond, a straight or branched alkylene group with 1 to 10 carbon atoms, an alkylene group or an alkylene group, 117 Heji 8 each represents a hydroxyl group, an alkyl group having 1 to 18 carbon atoms, an aryl group having 6 to 21 carbon atoms, or a group represented by the chemical formula, (4) or (.5) And (i.i) when η is 2, R 3 represents an alkylene group or a group represented by the chemical formula (7), wherein R 9 represents a direct bond, and one having 1 to 10 carbon atoms Linear or branched alkylene, one alkylene or one arylene. In addition, at least one compound represented by the following formulae (i) to (iv) is also preferred; (Please read the precautions on the back before reading (ιρί page)

P. Install. Order

N [H

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Η C Η c

H / c 'c Η c ruler | ^ > Paper standard 1 country I country one country I one use one centimeter 97 2 2 2 V. Description of invention (20)

c \ NIC R

1 It R H c 3 H c c

H

N R 3 H c A7 B7 2 Rlc-c \ NIC / c-c \, / 3 3 Η H c c Η Η c c

Ho 0? 丨 &RM; RMi

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, 10 NR c c c c / \

H

H This paper size is applicable to Chinese National Standard (CNS) A4 (210X297 mm), printed by A7 B7, consumer cooperation of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention (21) where Rio represents a hydrogen atom, an alkyl group, or An alkoxy 'Rii represents an alkylene group, R12 represents an alkyl group, and r13 and R i 4 each represent a hydrogen atom or a methyl group. In the preferred formula (i), R10 represents a hydrogen atom, a hydroxyl group, an alkyl group having 1 to 10 carbon atoms or an alkoxy group having 1 to 10 carbon atoms, and Rn represents one having 2 — An alkylene group of 8 carbon atoms is more preferred, R1 (J represents a hydrogen atom or a methyl group, and Rli represents a hexamethylidene group. In the chemical formula (ii), the better one, Ri. Represents one A hydrogen atom, a hydroxyl group, an alkyl group having 1 to 10 carbon atoms, or an alkoxy group having 1 to 10 carbon atoms, representing a radical group having 2 to 8 carbon atoms, R12 represents An alkyl group with 1 to 18 carbon atoms, more specifically, Ri. Represents a hydrogen atom or a methyl plug. In the formula (iii), preferably, R α. Represents a hydrogen atom 'a hydroxyl group, a An alkyl group having 1 to 10 carbon atoms or an alkoxy group having 1 to 10 carbon atoms, Rn represents an alkylene group having 2 to 8 carbon atoms, and more preferably, Ri. Represents a hydrogen atom Or a methyl group. In the formula (iv), preferably, R: represents a hydrogen atom, one hydroxyl group, and one having 1 to 1 0. An alkyl group with carbon atoms or an alkoxy group with 1 to 10 carbon atoms represents an alkylene group with 2 to 8 carbon atoms, and more preferably, Ri. Represents a hydrogen atom or a methyl group. [VI] This compound is represented by the following chemical formula (1); This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -24-(Please read the precautions on the back before this page)

P Order V. Description of Invention (22)

C / C, C CH. CH- IR,, ch3, CH. A7 B7 R- η (1) where Ri represents one hydrogen atom, one oxygen atom (containing oxygen), one hydroxyl group, one with 1 -8 carbons Atom alkyl, a cycloalkyl, a quaternary group, a hexyl group, an aryl group, an .alcohol group, a alkoxy group, an alkoxy group or a cycloalkoxy group, R2 represents a hydrogen atom or an alkane And (i) when η is 1, R 3 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, a benzyl group, an allyl group or one represented by the following chemical formula (6) Group, ------: ---: —— ^-(Please read the notes on the back first and then this page) Order the printout of the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 0 Re cy Rt where y represents A direct bond, a 0 (6) NR a_, R β represents a direct bond, a straight or branched alkylene, an alkylene, or an arylene, R 7 and R 8 each represent a hydroxyl group, a Alkyl group, an aryl group or a group represented by the following chemical formula (4) or (5), this paper size applies to China National Standard (CNS) A4 specification (210 × 297 mm) -25-A7 B7 V. Description of the invention (23

-CH = »CHCOH 0 / CH.? ^ ^ CH C4) 3 3

CH 3 N ίΗ

CH 5) 3 1 (Please read the notes on the back before this page) (i i) When n is 2, R 3 represents a group represented by the following chemical formula 7), one 9 Rone

, TT printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, where rule 9 represents a direct bond, a linear or branched alkylene group, an alkylene group, or an arylene group, and (iv) when η is 4, R 3 Represents a group represented by the following chemical formula) or (10), CHC- CH &-The standard of this paper is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) -26-A7 B7 V. Description of the invention (24) CIO ) Printed by the Consumer Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs 〇

(I moreover, in formula (1), Ri represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and R2 represents a hydrogen atom or an alkyl group having 1 to 18 carbon atoms; And when η is 1, R3 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group or a group represented by the chemical formula (6), wherein Y represents a direct bond, and a 0—or—NR8 —, Re represents a direct bond, a straight or branched alkylene group with 1 to 10 carbon atoms, an alkylene or alkylene group with 1 to 10 carbon atoms, R 7 and R 8 Individually represents a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an aryl group having 6 to 21 carbon atoms, or a. Group represented by chemical formula (4) or (5), and when When N is 2, R3 represents a group represented by the chemical formula (7), wherein R 9 represents a direct bond, a straight or branched alkylene group having 1 to 10 carbon atoms, and one having 1 to 1 〇 An alkylene group of one carbon atom or an arylene group.

V] Compound represented by the following chemical formula (2): C C CH3s '' Λ,, ch3

CH

P CH3 '' • CH. (2) where Ri represents a hydrogen atom and an oxygen atom (containing oxygen) 'This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm)-FREE f ^ Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 Β7__ 5. Description of the Invention (25) Hydroxyl, an alkyl group with 1 to 8 carbon atoms, a cycloalkyl '-an allyl group, a benzyl group, an aromatic group Group, an alcohol group, an alkenyl group, an alkoxy group, or a cycloalkoxy group 'R 2 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, η is an integer of 3, and P is 2 An integer up to 8, R 3 represents a group represented by the following chemical formula (8)

Examples of [ϊ], [V] and [VI] of [η = 1] of the compound (C) of the present invention include 4-amino-2,2,6'6-tetramethyl-piperidine, 4-methyl Monoamino-2,2,6,6-tetramethyl 4-piperidine, 4-ethylamino-2,2,6,6-tetra-methylpiperidine '4-propylamino 2,2,6,6-tetramethylpiperidine, 4-butylamino-2,2,6,6-tetra-methylpiperidine, 4-hexylamino-2,2,6,6 — Tetramethylpiperidine, 4-octylamino-2,2,6,6-tetra-methylpiperidine, 4-dodecylmonoamino-2,2,6,6-tetramethyl- Piperidine, 4-diethylamino-1,2,6 This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) _ 28 _ (Please read the precautions on the back first and then the page) Order A7 B7 V. Description of the invention (26), 6-tetramethylpiperidine, N- (2,2,6,6-tetramethyl-4-naphthalene), N- (2,2,6,6-tetramethyl) N- (4-piperidine) acetamide and N- (2,2,6,6-tetramethyl-4-eridine) stearylamine. In addition, the compounds represented by the following chemical formulas (2 9) to (4 7) can also be taken as examples. 〇 6 HJ " C18H37 FREE 〇 Η Η CH, NCH 3

Μ ch3 CK3 "! L ~ C ** C17H35 ο

Please read the note first

I

I equipment (27) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 11 (25) (26) (28)

N ί CH3 (35) The paper size applies to Chinese National Standard (CNS) A4 (21 〇 × 297 mm) -29-5 A7 B7 Printed by the Consumers' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (27

(36) ο tr

ch3 (37)

Ν 'Η Η (42) (Please read the notes on the back before ΐ

HN Ο ij

This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) nn-30-, ιτ-(ch2) 3 (43)

1 OH Printed by the Consumers' Cooperative of the Central Government Bureau of the Ministry of Economic Affairs ^ ------- B7____ V. Description of the Invention (28) [II], [v] and [VI] of the present invention [n = n] Examples of the compound (c) include the following compounds. In the chemical formulae (1) and (2), Ri includes, for example, a hydrogen atom, a hydroxyl group, an alkyl group having 1 to 10 carbon atoms, such as methyl, ethyl, or propyl, or 1 to 10 The alkoxy group of a carbon atom, when the carbon number is 3 or more, includes a cyclic group such as a cyclohexylmethyl group and a cyclohexylethyl group in addition to a linear or branched group. Ri is preferably a hydrogen atom or a methyl ^ R 2 is preferably an alkyl group having 1 to 18 carbon atoms or an alkoxy group having 1 to 18 carbon atoms, such as methyl ethyl , Propyl, isopropyl, n-butyl, isobutyl, t-butyl, zero-butyl, η-phenyl, η-hexyl, 2-ethylhexyl, η-octyl, 1, 1, 3 , 3-tetramethylbutyl, η-decyl, η-dodecyl, η .-octadecanyl_, cyclohexyl_, 3. '3,5 trimethyl-cyclohexyl, cyclooctyl and "Cyclodecyl" R 3 includes an alkylene group having 2 to 8 carbon atoms and an alkylene group represented by a CnH2n_, such as ethylene, 1, 2- or 1, 3-propyl, 1, 2—, 1, 3—or 1,4—butylene, pentamethyl, 2,2-dimethyl-1,3-methylpropyl, hexamethyl and octamethyl, and cycloethylene Hexyl and cyclohexyldimethyl "R 3 is preferably a hexamethyl group having 6 carbon atoms. In Chemical Formula (3), R4 is a hydrogen atom or an alkyl group having 1 to 18 carbon atoms, such as methyl, ethyl, propyl, isopropyl, η-butyl, isobutyl, t a Butyl, zero-butyl, η-phenyl, η-hexyl, 2-ethylhexyl, η-octyl, 1,1,3,3-tetramethylbutylfluorene, η-decyl, η-dodecyl , Η-octadecanyl, cyclohexyl, 3, 3, 5-trimethylcyclohexyl, cyclooctyl and cyclodecyl. Chemical formula (7) This paper size is in accordance with Chinese national standard (〇 Chan) 8 4 specifications (210 parent 297 mm) — ~~ -.i I-(Please read the precautions on the back before this page) Order A7 __ B7 5 In the description of the invention (29), R9 represents a direct bond, a straight or branched alkylene group having 1 to 10 carbon atoms, an alkylene group or an alkylene group such as, for example, ethylidene, 1, 2_, 1,3 —, or 1,4-propanyl, 1,2,1'1,3 — or 1,4-butanyl'pentamethyl, 2,2-dimethyl-1,3 _Propyl, hexamethyl, octamethyl, cyclohexyl and cyclohexyl-dimethyl. Specific examples of this compound include N, N bis (2,2, .6, 6-tetra-methyl-4-natane) -1,6-hexanediamine, N, N ^ -bis (2,2 , 6,6-tetra-methyl-4-piperidine) ethylenediamine, N, N, bis (2,2,6,6-tetra-methyl-4-piperidine)-1,8 —Octane diamine and compounds represented by the following chemical formulae (4 4) to (4 9). (Please read the notes on the back before this page) 0 Order Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 〇

〇 0

Η (45) Η

0 〇 C · CH2CH2-C-ΝΗ 0 c-(CH Hill-(47)

The scale of this paper applies the Chinese National Standard (CNS) A4 specification (21〇 > < 297mm). 5. Description of the invention (30

(48) A7 B7

CH «CH-C-KH

0 B

(49) C) [I I I] and 1 [Compound V 1 1 of the present invention [η = 3] Examples include the following compounds. In the chemical formula (2), R 3 is a group represented by the δ ib scientific formula (8). Specific examples of the compound include compounds represented by the following chemical formulae (5 4) and (5 5). Ηζ >

OH, ^ HC KHCH2fcHCH2, Jl ^ 〆 Ο HCH ^-, -HH— (Please read the notes and notes on page 1¾ first and then page (50) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

O

OH I

• CHCH HO < (51) Examples of [I] and [IV] to [V I] of the compound (c) of the present invention [n = 4] include the following compounds. In the chemical formula (1) or (2), R 3 is a group represented by the chemical formula (9) or (10). The dimensions of this paper are in accordance with Chinese National Standards (Oyang) 8-4 (210 乂 297 mm) _33_ A7 B7 V. Description of the invention (31) Specific examples of this compound include compounds represented by the following chemical formulas (5 2) to () . CHa —NH — * / NH O NV CHaCNH — / NCH, CH-C-NH— ^ NH CHCNH- ^ NCH, CH-i bottle ^ ~ ^ SlCH, CHS CH, < 5hH ~ (52) (53) « ./ 一 · \ C — (-CH, OCCH, CH, -NH — / (54) (Please read the notes on the back before filling in-

Set the quantity ratio of components (a) and (b) printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs; (a) 1 to 99% by weight of polyphenylene ether resin and (b) 99 to 1% by weight of the A crystalline thermoplastic resin, preferably (a) 10 to 90% by weight of a polyphenylene ether resin and (b) 90 to 10% by weight of the crystalline thermoplastic resin, more preferably; (a) 10 to 80% by weight of the Polyphenylene ether resin and (b) 90 to 20% by weight of the crystalline thermoplastic resin, the best; (a) 15 to 60% by weight of the polyphenylene ether resin, and (b) 85 to 40% by weight of the crystalline Thermoplastic resin · The quantity of component (c) is (a) polyphenylene ether resin and (b) crystal. The paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) — " -34-Ministry of Economic Affairs Standards Bureau's consumer cooperation Du printed A7 B7_ V. Description of the invention (32) The total thermoplastic resin accounts for 0.00 parts by weight of 0.15 to 15 parts by weight, and 0.1 to 10 parts by weight Better. When it is less than 0.01 parts by weight, there is no effect of suppressing gelation. When it is more than 15 parts by weight, problems such as blistering due to volatile substances are caused in actual handling. In the present invention, the thermoplastic resin composition additionally contains a certain amount of (d) a mutual solvent, which is beneficial for the mutual compatibility of components (a) and (b). The present invention is used for mutual compatibility (a) of polyphenylene ether and (B) The compatibilizer (d) of the crystalline thermoplastic resin is at least one selected from the following (d 1) to (d 1 0). (d1): an epoxy compound without ethylenic and alkyne unsaturated bonds "(d2):-a molecule having (i) at least one unsaturated group, such as a carbon-carbon double bond and a carbon-carbon triple bond, And (ii) a compound of at least one polar group "(d3): a silane compound having (i) a carbon atom crosslinked with oxygen in the molecule, and (ii) at least one olefinic carbon-carbon double bond , Carbon-carbon triple bond, one selected from an amine group and a fluorenyl group, and the functional group having a silicon atom does not have a direct bond. (d 4):-a compound having at least two functional groups which are the same or different in the molecule, which is composed of (i) (OR) (wherein R is a hydrogen atom, an alkyl group, an aryl group, A fluorenyl group or a carbonyldioxy group) and (ii) a carboxylic acid, a fluorenyl halide group, an acid anhydride, a fluorenyl halide anhydride, an acid ester, an acid amine, an imine, and salts thereof Paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) -35-(Please read the notes on the back before filling |? ^ Page)-Order 2 or more amine groups. The mutual container A7 B7 selected by (d 1), (d3), (d4) ^ I (d5) -------------- 5. Description of the invention (33). (d 5): a compound having (.i) a fluorenyl halide group and (ii) at least one selected from a carboxyl group, a carboxylic anhydride group, ~~ acid ester group, and a hydrazine group Group. (d 6): a copolymer of a vinyl aromatic compound and an α, / 3-unsaturated dicarboxylic acid or a dicarboxylic anhydride, or a vinyl aromatic compound and an αΘ-unsaturated dicarboxylic acid Copolymer of imine compounds. (d 7): An organic compound having no alkenyl group or odorous unsaturated bond in the molecule and having two or more isocyanate groups and / or isothiocyanate groups. '(d 8):-a compound * which has no alkenyl and alkynyl unsaturated bonds in the molecule, and (OR) (where R is a hydrogen atom, an alkyl group, an aryl group, a fluorenyl group, or a carbonyl group ) Has (d 9): a polyphenylene ether functionalized with at least one (d 2). Please read the note at the back first and then print the page printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. D10): A copolymer of an alkenyl aromatic compound and a crystalline thermoplastic resin (b) a mutual compatibility compound. Compatibilizers (d 1) used in the present invention include substances such as bisphenol A, tetrabromobisphenol A, and condensation products with epichloroethylene glycol, such as propylene glycol and ethylene glycol. The compatibilizer (d 2) used in the present invention refers to the condensation of polyhydric phenol to produce hydroquinone and a compound with epichlorohydrin. The paper size is applicable to Chinese National Standard (CNS) A4 specification (2丨 0X297mm) -36-A7 B7 V. Description of the invention (34) The molecule has (i) at least one unsaturated group and (ii) at least one polar group, in other words, a functional group, which is shown and contained in Polyamine resins have amine bonds, affinity and chemical reactivity of carboxyl and amine end groups. The functional group includes a carboxylic acid group, a group derived from a carboxylic acid, in which a hydrogen atom of a carboxyl group or a hydroxyl group is passed through, such as a salt, an ester, an amidine, an acid anhydride, an imine, and an amidine Substituted by azido and a dentate, an eye group, an oax.aziline group, an epoxy group, an amine group, a hydroxyl group and an isocyanate group. The compatibilizer (d 2) includes an unsaturated carboxylic acid, an unsaturated carboxylic acid derivative, an unsaturated epoxy compound, an unsaturated alcohol, an unsaturated amine, and an unsaturated isocyanate. Examples of the compatibilizer (d 2) include maleic acid, maleic anhydride, fumaric acid, maleic acid diamine, maleic acid hydrazine * by the following chemical formulae (5 5) and (5 6 ) Is the reaction product of cis-butene dihydrazine and diamine. 0 0 (Please read the precautions on the back before reading ΐ

Page A) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs

This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -37-A7 〇 5. Description of the invention (35) Γ. ,, NH R N Η-, c, II, 0 Η HO-ll 〇 〇 (where R represents an aliphatic group or an aromatic group). Examples of the compatibilizer (d 2) also include methyl dianhydride, dichloromaleic anhydride 'maleic acid diamine, itaconic acid, itaconic anhydride; natural fats and oils such as soybean oil, tung oil , Ramie oil, linseed oil, cottonseed oil, sesame oil, sesame oil, rapeseed oil, peanut oil, tea oil, palm oil * coconut oil and sardine oil; epoxidized natural fats and oils; an unsaturated carboxylic acid such as acrylic acid, butadiene Enoic acid, crotonic acid, ethylene acetic acid, methacrylic acid, pentenoic acid 'angelica acid, tic acid, 2-pentenoic acid, 3-pentenoic acid, α-ethyl acrylic acid, yS-methyl crotonic acid, 4 --Pentenoic acid, 2-heptenoic acid, 2-methyl-1 2-pentenoic acid, 3-methyl-2 2-pentenoic acid, α-ethylcrotonic acid, 2,2-dimethyl-1-3- Butenoic acid, 2-heptenoic acid '2-octenenoic acid, 4-decenoic acid, 9-undecenoic acid, 10-tenth Mono-acrylic acid printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, 4-twelve Enoic acid, 5-dodecenoic acid '4-tetradecanoic acid, 9-tetratetracarboxylic acid, 9-{-heptaic acid, 2-h octacanic acid' 9-h octaene , Pinenoic acid, phenadienoic acid, erucic acid, pantetraenoic acid 'mycolic acid, 2,4 pentadienoic acid, 2,4-hexadienoic acid, diallylic acid group, geranic acid, 2 , 4decadienoic acid, 2,4 dodecadienoic acid, 9 '12 —h hexadienoic acid, 9,12 —octadecadienoic acid, hexadecadienoic acid, linoleic acid Acid, linoleic acid, octadecadienoic acid 'carbadienoic acid, carbatrienoic acid, docosatraenoic acid, ramie acid, tungstic acid, oleic acid, pentene This paper is in accordance with Chinese national standards (.CNS) M specifications (210X 297 mm) A7 B7 Printed by the Consumers' Cooperative of the China Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (36) 1 I Acid dicarbonate dicarbonate dicarbonate dicarbonate four carbon Unsaturated fluorene /, carbon_ 1 1 Unsaturated hexadecadienoate, octadecenoic acid, and tetraconic acid are unsaturated * 1 1 of carboxylic acids • ~ * esters-phosphonium amines and-. Species Wild; — a kind of unsaturated alcohol 1 1 please 1 I such as allyl alcohol crotonyl alcohol methyl vinyl Methanol Allyl Methanol > Read First 1 | Glycol Methyl Acetyl Methanol 4 — Extender 1 — Alcohol 1 0 One Ten — Group 1 Back Λ 1 1 Alcohol Phenyl Alcohol 1 3 Diene 1 3 Alcohol »1 4 — Hexadiene 1 | Ethene — 3 — Alcohol 3 5 — Hexadiene — 2 — Alcohol 2 4 — Hexadiene Matter I — 1 — Alcohol — Specified by the chemical formula C nH 2 η — sO Η C η Η 2 η -7 0 Η A or C nH 2 η — 9 0 Alcohol represented by Η (Γ1 is a mono-integer) 3--butene-page. 1 1 1 2 — diol 2 5 — dimethyl — 3 —hexene — 2 9 5 — __. 1 1 alcohol 1 5 hexadiene — 3 4 — diol and 2 6 — octadiene — 1 1 4 5 — diol * * — * unsaturated amines t of which The 0 之 radical 1 of this unsaturated alcohol is substituted with a N Η 2 radical (meth) glycidyl acrylate and allyl 1 1 based glycidyl ether 0 1 1 I In addition to butadiene or isoprene Oligomer( For example, the average molecular weight is 1 1 and the molecular weight is about 5 0 to 1 0 0 0 0) or a high molecular weight polymer (for example, the average molecular weight is 1 0 0 0 0 or higher) t will be butadiene 1 1 anhydride phenol — · Amino groups and 1 carboxylic acid group— · A hydroxyl group or an epoxy group is combined with 1 1 thereof, and an isocyanate can also be included in the compatibilizer (d 2 1 I) of the present invention. 0-I In addition 9 the present invention The mutual compatibilizer (d 2) also includes a compound containing two or more types of unsaturated groups and two or more polar groups (same or different). 1 or two special compounds may also be used. 0 1 1 These compounds 9 maleic anhydride maleic acid »fumaric acid» 1 1 This paper size applies to China National Standard (CNS) A4 (210X297 mm) -39-Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 5. Description of the invention (37) Itaconic acid and (meth) acrylic acid shrink Preferably, oily esters, maleic anhydride used and more preferably fumaric acid. The compatibilizer (d 3) used in the present invention includes a silane compound having (i) a carbon atom crosslinked by oxygen and (ii) at least one functional group in a molecule, which is composed of a susceptible carbon- Carbon double bond, a carbon-carbon triple bond, selected from an amine group and a fluorenyl group, and the functional group with a silicon atom is different from the direct bond, for example, r-aminopropyltriethoxysilane, and 2— (3 —Cyclo-hexyl) -ethyltrimethoxysilane is included. The compatibilizer (d 4) used in the present invention includes an aliphatic polycarboxylic acid represented by a chemical formula, its esters and its amines; (R10) mR (C0 〇R2) n (CONR3R4) 1; where R represents A linear or branched unsaturated aliphatic hydrocarbon having 2 to 20 carbon atoms preferably having 2 to Γ0 carbon atoms; Rt represents a hydrogen atom; a hydroxyl group, an allyl group, a fluorenyl group, or a carbonyldioxy group A hydrogen atom is preferred; R2 represents a hydrogen atom, a hydroxyl group or a allylic group with 1 to 20, and 1 to 10 carbon atoms, and 3 to 114 represents a hydrogen atom, a hydroxyl group, or a An allyl group having 1 to 10, preferably 1 to 6, and more preferably 1 to 4 carbon atoms; m is 1; (n + 1) is an integer of 2 or more, with 2 or 3 Preferably, 1 is an integer of 0 or greater, which is substituted at the α position or the iS position into a carbonyl group, wherein there are 2 to 6 carbon atoms between the two carbonyl groups. For example, it means a saturated aliphatic polycarboxylic acid ester and its amines, anhydrides, hydrates and salts. The partially aliphatic polycarboxylic acids include citric acid, maleic acid and agaric acid. This compound is detailed in Japanese Patent Bulletin Sho 61- This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) _ (Please read the precautions on the back before this page) -s A7 B7 V. Description of the invention ( 38) 5 0 2 1 9 5. The mutual compatibilizer (d 5) used in the present invention includes a compound represented by the chemical formula [(I) —z— (H)]; wherein (I) represents a group having the chemical formula (X—C0) — (where X Represents a fluorine, a chlorine, a boron, an iodine, a hydroxyl group, an OR group or -〇-CO-R, and R represents a hydrogen atom, an alkyl group or an allyl group), and (Π) represents a carboxyl group An acid group, an anhydride group, an amido group, an imine group, a carboxylate group, an amine group or a hydroxyl group, and the groups (I) and (Π) are covalently bonded via a divalent hydrocarbon Z Together. Examples include chloroformamidine succinic anhydride, chloroethanol succinic anhydride, fluorenyl chlorotrimellitic anhydride, trimellitic anhydride acetic anhydride, and chlorinated terephthalic acid. The mutual compatibilizer (d 6) used in the present invention includes a copolymer of a vinyl aromatic compound and an α, / 5-unsaturated dicarboxylic acid or a dibasic anhydride, and a vinyl aromatic compound and an α , A copolymer of an imine compound of an unsaturated dicarboxylic acid, including, for example, an alkenyl aromatic compound such as styrene and α-methylstyrene, and maleic anhydride, maleic acid, Copolymer of fumaric acid, N-methyl maleimide or N-phenyl maleimide. The compatibilizer (d 7) used in the present invention includes a compound having no alkenyl and alkynyl unsaturated bonds in the molecule and having two or more isocyanate groups and / or isothiocyanate groups, for example, it includes Aromatic polyisocyanates, such as m-phenylene diisocyanate, 2,4-tolyl diisocyanate, 2''6-tolyl diisocyanate, 4,4 diphenylmethane diisocyanate 'diisocyanate 4,4 -_Diphenylpropane ester, 棻 -1, This paper size is applicable to China National Standard (CNS) 8-4 (210X297 mm) 'λ 1 (Please read the precautions on the back before

、 1Τ f Printed B7 by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (39) ~ 5 ~ 'Diisocyanate' bisphenyl-4,4 > — 3,3-diisocyanate , Dimethyl diphenyl methane diisocyanate, diphenyl ether 1 4 4 —diisocyanate, diphenyl hydrazone-4,4 diisocyanate 'triisocyanate triphenylmethane and xylyl diisocyanate ; An aliphatic polyisocyanate, such as diisocyanate 4,4 / monocyclohexane, dicyclohexylformamidine-4,4 --- diisocyanate, isopropyl diisocyanate, diisocyanate 1, 1 2-dodecyl ester, hexamethylene diisocyanate, 2 '4,4-trimethylhexamethylene diisocyanate, and mixtures thereof; a compound having an isocyanate group corresponding to the polyisocyanate A polymer of the polyisocyanate and polythioisocyanate, such as a dimer and a trimer; a modified carbodiimide of the polyisocyanate and a polythioisocyanate; and a modified polyisocyanate, such as a block Class, where the isocyanate group is masked by phenol or lactam. Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before this page) The compatibilizer (d 8) used in the present invention includes a compound whose molecules do not have susceptible and bulk unsaturated bonds And (OR) (where R is a hydrogen atom, an alkyl group, an aryl group, a fluorenyl group, or a carbonyldioxy group) and has 2 or more amine groups, for example, it includes a saturated aliphatic diamine and Polyamines such as ethylenediamine, propylenediamine, diaminobutane, diaminopentane, 2-methylpentamethylenediamine, hexaethylethylamine, octaethylenediamine, diaminodecane and diamine Aminododecane; and an aromatic polyamine, such as P-xylenediamine, m-xylenediamine, tris (3-aminopropyl) amine, a carbon dioxide adduct of the amine, p —Phenylenediamine, m —phenylenediamine, toluene diamine, 4,4 diamino diphenyl ether, 4, 4 > —diamino diphenyl sulfide, and 3,3 diamino diphenyl sulfide . ^ The paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) ~~~: " —AV — A7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (40) 1 1 In the present invention The compatibilizer (d 1 0) used includes an alkenyl aromatic-λ 1 1 compound and a copolymer having a compatibility with the crystalline thermoplastic resin (b) < a copolymer of a polyolefin such as a polymer When vinyl resin and polypropylene resin are used as the crystalline thermoplastic resin (b), they include an alkenyl aromatic compound. Please first listen to 1 I compounds (such as styrene and a-methylstyrene). Ctsx and a monoolefin Copolymer, read back 1 1 -1 〇 Note 1 I However, the mutual compatibilizer (d) of the present invention is not limited to the compounds listed above. Ί 〇 Any polyphenylene ether resin (a) and the crystal can be used. Thermoplastic resin (b) a compound of mutual compatibility. Page 1 In the present invention, when the mutual compatibilizer (d) is used, the effective amount of the mutual compatibility of the components (a) and (b 1 1) is 100 parts by weight of the array component (a) of the polyphenylene ether 1 I resin and (b) The total amount of the crystalline thermoplastic resin contains 0 • 0 1 to 3 0 Order I parts by weight is 0 • 0 5 to 2 5 parts by weight is preferred 0 1 to 1 | 1 0 parts by weight is even better when it exceeds 0 It is not preferable when it is 30 parts by weight. One is that the mechanical strength deteriorates due to heat and stability degradation and decomposition 1 1 effect. In addition, when using a mutual compatibilizer (b), a group 1 initiator may be used together. 〇1 | In the present invention, in order to improve the mechanical properties such as strength inflexion and hardness 1 I degree> fillers can be added to the thermoplastic resin composition Q 1 1 I The fillers include-* calcium carbonate, magnesium carbonate, aluminum hydroxide, 1 I magnesium Zinc oxide, titanium oxide, magnesium oxide, sulfur Magnesium Silicate Aluminum Magnesium Silicate 1 > Calcium Silicate Calcium Silicate Calcium Silicate Hydrate Aluminum Silicate Hydrate Mineral Fiber 1 1 Dimension Zonnotr it e Titanate Whiskers Magnesium Oxide Sulfate, Glass Ball Glass 1 1 Glass Fiber glass bead inorganic filler, such as carbon fiber stainless steel fiber 1 1 This paper size is applicable to China National Takaoka Standard (CNS) A4 specification (210 x 297 mm) 43 A7 B7 V. Description of the invention (41) Aluminum fiber and ar amide fiber, carbon Black, inorganic fillers such as a metal whisker, silica 'alumina, talc, mica, clay, kaolinite, Ti 02, Z η 0, and S b203. These fillers can be blended in one or more. In addition, the filler used in the present invention is not limited to this. The thermoplastic composition of the present invention can be prepared by blending and melt-kneading components (a), (b) and (c) in a conventional manner. And components (b) and (c) can be added during the polymerization of component (a). The thermoplastic resin composition of the present invention can be molded in many methods, such as injection molding, extrusion molding, blow molding, sheet molding, and film molding, which are the most suitable, because the composition can be Highly avoid heat-induced deterioration. In addition, the molded articles proposed by the present invention can be widely used as packaging materials, household goods, exterior materials and interior decoration materials of automobile parts, such as automotive decoration parts. Examples The embodiments of the present invention are based on the following examples and Comparative examples are illustrated in detail, but these are simple examples, and the present invention is not limited thereto. Each of the examples and comparative examples was prepared by blending the compositions shown in Tables 1 to 3. That is, this component is extruded at a calcination temperature of 2 60 ° C with a double-screw kneader (TME-50A manufactured by Toshiba Machine Co. Ltd.), and granulated by a fiber cutter, and the mixture The composition was obtained after cooling. The obtained pellets were dried under vacuum drying at 130 ° C for 2 hours, and then an injection molding machine (Toshiba Machine Co.

Ltd.'s I S2 20EN) calcined at 2 90 ° C, the paper size of the injection pressure is in accordance with the Chinese national standard ((CNS) A4 specification (210 X 297 mm) "" -44-(Please read the Note again on this page) * Word. A7 B7 printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (42) The force is 12 000 kg / cm2 and the molding temperature is 80. (: A sample is prepared next. The obtained particles and the sample are evaluated by the following method and the result is obtained. [Molecular weight of the polyphenylene ether resin] The obtained particles are dissolved in chloroform and coagulated with Gel Permeation Chromatograph (GPC) (Toso Co. Ttd's 111 ^ (:-802 0; 仄 -806, K-805, K-804, and K-803 columns; UV wavelength 290 nm detector) Temperature: 40 ° C: flow rate 1.0 mi? / Min), and determine the molecular weight converted to the molecular weight of standard polystyrene. [Yellowness index of the resin composition after melt-kneading] Trial made by the aforementioned injection molding The sample-like yellow index is measured with CC Μ (Color Eye 2020 (Macbeth)) manufactured by Sumika Color Company Ltd. [Heat resistance and stability] The thermal hysteresis is transmitted to a 3.2 mm thick sample (which is used for Izod impact resistance) It is made by injection molding as described above and made separately at 100 and 500 hours at a fixed temperature of 120 ° C.) After nicking according to ASTM 0 2 5 6 and I z 0 d impact resistance at 2 3 ° C Test. Prepare the materials listed below to get the composition of the examples and comparative examples. This paper is sized to the Chinese National Standard (CNS) A4. Grid (21〇Χ297 public Ling) _ 45 (please read the Notes on the back of reloading *

Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of Invention (43). (Polyphenylene ether; PPE) The polyphenylene ether (PPE) is prepared by the homopolymerization of 2,6-dimethylphenol and has a logarithmic viscosity of 0 in a 30 ° C chloroform solution (0.5 g / dj?). 46. The molecular weight (Mw) of PPE before kneading was 46 10 0. (This crystalline thermoplastic resin composition) PA-1: Nylon 66 having a number-average molecular weight of 17000. P P is a product manufactured by Sumitomo Chemical Company Ltd. Sumitomo Noblen HDIOOO P B T: A product Tafpet manufactured by Mi. tsubishi Rayon Company Ltd. is used. P P S: A product manufactured by Toray / Phil l.ips Corporation Μ 2 880 was used. Impact modifier: Carif lex TRllOl, a product manufactured by Shell Chemical Company Ltd. was used. (Compatibilizer) Compatibilizer 1: Maleic anhydride compatibilizer 2: Diaminododecane compatibilizer 3 ·· Products manufactured by She 11 Chemical Company ^ Paper size applies Chinese National Standard (CNS) A4 specifications (210 X 297 mm) ~ (Please read the precautions on the back before ipf this page) Order A7 B7 V. Description of the invention (44)

Kraton G1701K. 4 > Diphenylmethane diisocyanate Compatibilizer 4: 4 (Additive) Additive 1: Commercial product Sanol LS-770 manufactured by Sankyo Co. Ltd. It is represented by the following chemical formula (5 7).

(5 7) Additive 2: Commercial product Tinuvin .6 22 manufactured by Ciba-Ceigy Corp., which is represented by the following chemical formula (5 8). Η

η Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

This paper size applies Chinese national standard f CNS) A4 specification (210X297 mm) Additive 3: Chimasorb 944, a product manufactured by Gba-Geigy Corp., which is represented by the following chemical formula (5 9): (59) -47-A7 B7 Fifth invention description (45) Additive 4: Adekastab PEP-36, a product made by Asahi Denka Kogyo KK. It is represented by the following chemical formula (60). t-Bu t-Bu

Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs The compounds used in the examples were prepared according to the following reference examples. In addition,% in the reference example is weight% unless otherwise defined. Reference Example 1 Preparation of Ν, Ν-bis (2,2,6,6-tetramethyl-4piperidine) -1,6-hexanediamine (compound 1) was filled in a 5 male booster 981g (6.32 mole) of 2,2,6,6-tetramethyl-4-piperidine, 350g (3.01 mole) of hexamethylene diamine, 1,500g of methanol and 5 0 g contains 5% carbon and the temperature is maintained at 45 to 55 ° C. The autoclave is pressurized to 40 bar with hydrogen and heated to 70-80 ° C for hydrogenation. The hydrogenation is completed after 4 to 5 hours. The catalyst was removed under reduced pressure at 2 to 3 bar at 70 to 80 ° C, and 1070 g of N, N-1,2- (2,2,6,6-tetramethyl-1,4-piperone) were prepared by distillation. Pyridine) -1,6-hexanediamine (compound 1). Yield · 90%. Boiling point: 188 to 190 ° C / 0.8 mbar. This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) _48 A7 —________ B7 _ 5. Description of the invention (46) Reference Example 2 Preparation of N 'N / —bis (2-methoxycarbonylethyl) —N, — Bis (2 '2' 6 '6-tetramethyl-1 4-piperidine) -1,6-hexane% diamine (Compound 2) In a 1 liter four-necked flask was charged 80 g (0.20 Moore) N, N, a bis (2,2,6,6-tetramethyl-4-piperidine) -1,6-hexanediamine (compound 1), and 2 obtained in Reference Example 1 and 2 00 g of methanol, which was completely dissolved. A solution was added dropwise at room temperature, which was prepared by dissolving 35 g (0.41 mole) of methyl acrylate in 0 g of methanol. Then, the reaction was carried out under reflux for 12 hours. After completion of the reaction, the solvent was distilled, and the residue was recrystallized from hexane to obtain 9.8 g (0.17 mol) of Compound 2 as a white solid. Yield: 85%. Melting point: 50-52 ° C. Reference Example 3 Preparation of N, N —_bis (2-octadecyloxycarbonylethyl) —N, N—bis (2,2,6,6-tetramethyl—4-piperidine) —1,6 -Hexanediamine (Compound 3) A four-necked flask with a stirrer and a reflux condenser was charged with 20 g (35 m moles) of N, N — double (2 —Methoxycarbonylethyl) —N, —bis (2,2,6,6-tetramethyl-4-piperidine) —1,6-hexanediamine (Compound 2), 21 g (77 m Mol) ) Of stearyl alcohol and 200 μm of toluene, followed by stirring under reflux. A solution is added dropwise to this paper. The paper size is applicable to the Chinese National Standard (CNS) M specification (210X297 mm) -ZLQ-(Please read the precautions on the back before this page) Order the staff of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the Consumer Cooperative V. Description of the invention (47) 3 g of methanol contains 0.1 g (4 m Molar) of lithium ammonium. Thereafter, toluene was added to distill off the solvent, and the reaction was completed. The reaction was allowed to proceed for 4 hours, toluene was added, and then cooled to room temperature. The organic layer was washed three times with water, and then concentrated to obtain 23 g (22 m moles) of Compound 3. Yield: 63%. Melting point: 45-46 ° C. Reference Example 4 Preparation of N, N < —bis (ethoxycarbonyl) _N, N < —bis (2, 2, 6, 6-tetramethyl-4 piperidine) -1,6-hexanediamine ( Compound 7) At 0 ° C or lower, 22.8 g (0.21 mol) of ethyl chlorocarbonate was added to 39.4 g (0.1 mol) of N, N, prepared in Reference Example 1 (2,2,6,6-tetramethyl-1,4-piperidine) -1,6-hexanediamine (compound 1) at 200mj? 1,2-dichloroethane (which is cooled to a temperature of 10 ° C) ) In solution. Then, 8.4 g of sodium hydroxide dissolved in 50 m1 of water was slowly added thereto. Printed by the Central Standards Bureau of the Ministry of Economy.

, Maintain the temperature at 0 ° C. Then, the temperature was raised to 20 ° C, the reactant was separated into an aqueous layer and an organic layer, and the organic layer was washed with water, and dried over anhydrous sodium sulfate to remove the solvent. The residue was then crystallized from octane to obtain 44. lg compound 4. Yield: 82%. Melting point: 125 ° C Reference Example 5 Preparation of compound 8 [Chemical formula (6 1)] The paper size is applicable to Chinese National Standard (CNS) M specification (210X297 mm) -50-V. Description of the invention (48) Η co «cc \ NIC H / c H c H c A7 B7 K ο ohc Η c H c

A c (6

NHH c A 4-necked flask with a thermometer and a stirrer was charged with 156 g of 4-monoamino-2,2,6,6-tetramethylpiperidine, 40 toluene and 9 8 g of maleic anhydride, and the gas in the flask was replaced with nitrogen, followed by stirring at 60 ° C for 6 hours. After the reaction was completed, white crystals generated were filtered and washed with toluene to obtain 2 4 3 g of compound 8. Printed by Zhengong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economics Reference Example 6 Using 2,2,6,6-tetramethyl-4 piperidinylamine as the compound 6 was used. Examples 1 to 11 and Reference Examples 1 to 10 The blending ratios of Examples and Comparative Examples, and the molecular weights of polyphenylene ethers in the obtained resin compositions are shown in Tables 1 and 2. Example 12 ′ 13 and Comparative Examples 11, 12 This paper scale is applicable to China National Standards (CNS) 8-4 specifications (210X29 * 7 public directors) _ -51-, words (please read the precautions on the back first)

A7 _______B7 V. Description of the invention (49) The yellow index of the resin composition is shown in Table 3. Examples 14, 15 and Comparative Example 13 The heat resistance stability of the resin composition is shown in Table 4. Effects of the invention Adding a special sterically hindered piperidine compound to a composition including polyphenylene ether and the crystalline thermoplastic resin can significantly improve the deterioration of polyphenylene ether due to heat during processing. Please read the precautions below before ordering the pages printed by the Central Consumers ’Bureau of the Ministry of Economic Affairs’ Consumer Cooperatives. This paper is printed in accordance with the Chinese National Standard (CNS) A4 (210X297 mm) -52-A7 B7 Staff ’s consumption by the Central Bureau of Standards Cooperative printing 5. Description of invention (so) Table 1 Molecular weight of composition PPE Mw PPE PA-1 Compatibilizer 1 Compound 1 Example 1 50 50 0.8 0.5 49,800 PPE PA-1 Compatibilizer 1 Compound 2 Example 2 50 50 0.8 0.5 49,900 PPE PA-1 Compatibilizer 1 Compound 3 Example 3 50 50 0.8 0.5 49,500 PPE PA-1 Compatibilizer 1 Compound 3 Compound 4 Example 4 50 50 0.8 0.5 48,900 PPE PA-1 Compatibilizer 1 Compound 5 Example 5 50 50 0.8 0.5 50,000 PPE PA-1 Compatibilizer 1 Compound 6 Example 6 50 50 0.8 0.5 50, 000 PPE PA-2 Compatibilizer 1 Compound 1 Example 7 50 50 0.8 0.5 49,900 PPE PA-1 Compatibilizer 1 Comparative Example 1 50 50 0.8 59,000 PPE PA-1 Compatibilizer 1 Additive 1 Comparative Example 2 50 50 0.8 0.5 58, TOO PPE PA-1 Compatibilizer 1 Additive 2 Comparative Example 3 50 50 0.8 0.5 59,200 PPE PA-1 mutual compatibilizer 1 Tim Agent 3 Comparative Example 4 50 50 0.8 0.5 57,500 PPE PA-1 Compatibilizer 1 Additive 4 Comparative Example 5 50 50 0.8 0.5 58,900 PPE PA-2 Compatibilizer 1 Comparative Example 6 50 50 0.8 59,300 (Please read the note on the back first Matters to be reprinted) This paper size is in accordance with Chinese National Standard (CNS) A4 specification (2 丨 0X297 mm) -53-A7 B7 Printed by the Consumer Cooperatives of the Central Standardization Bureau of the Ministry of Economic Affairs 5. Description of the invention (51) Table 2 Composition Molecular weight of PPE Mw PPE PP Compatibilizer 1 Compatibilizer 2 Compound 3 Example 8 50 50 1 1 1 46, 500 PPE PP Compatibilizer 3 Compound 1 Example 9 50 50 10 1 47,200 PPE PBT Compatibilizer 4 Compound 1 Example 10 50 50 3 1 47, 900 PPE PPS Compatibilizer 4 Compound 1 Example 11 50 50 3 1 51,200 PPE PP Compatibilizer 1 Compatibilizer 2 Comparative Example 7 50 50 1 1 56, 000 PPE PP Mutual Capacitor 3 Comparative Example 8 50 50 10 63, 200 PPE PBT Compatibilizer 4 Comparative Example 9 50 50 3 64,100 PPE PPS Compatibilizer 4 Comparative Example 10 50 50 3 66, 500 (Please read the notes on the back before filling (Page) bound paper size for China Home Standard (CNS) A4 specification (210X297 mm) r, 54- 5. Description of the invention (52) A7 B7 Table 3 Composition ΥΙ PPPE PA-1 Compatibilizer 1 Compound 1 Example 12 50 50 1 1 16 PPPE PP Compatibilizer 1 Compatibilizer 2 Compound 3 Example 13 50 50 1 1 1 15 PPPE PA-1 Compatibilizer 1 Comparative Example 11 50 50 1 23 PPPE PP Compatibilizer 1 Compatibilizer 2 Comparative Example 12 50 50 1 1 20 (Please read the notes on the back before this page) Yita

, 1T printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs

Izod impact strength at 23Ϊ notch starts at 120 ° C and starts at 100hrs 500hrs. Please read and read the precautions of © before PPE PA-1 intercapacitor 1 impact modifier 1 Example 14 40 50 0.6 10 1 42 35 31 PPE PA mutual compatibilizer 1 Na Na improver chemical modification 6 Example 15 40 50 0,6 10 1. 38 33 29 PPE PA-1 mutual compatibilizer 1 Na Na improver Comparative Example 13 40 50 0.6 10 44 24 16 Ordered by the Ministry of Economic Affairs, 4-Central Bureau of Standards, Consumer Cooperatives, printed paper scales applicable to Chinese National Standard (CNS) A4 (210X25) 7 mm) -56-

Claims (2)

A8 B8 C8 D8 6. Scope of patent application • --Annex I (A): No. 85101987 Patent Application Chinese Application Patent Scope Amendment October 1988 Amendment 1. A polyphenylene ether-fat composition, which Including: (a) 10 to 90% by weight of polyphenylene charm resin, -r ..... ''. (≫ a) 90 to 10% by weight of crystalline thermoplastic resin, which is at least one species It is selected from polyethylene resin, polypropylene resin 'polyacid' amine resin, poly (alkylene diamine) resin, polynonyl resin. 0 0 The sum of (a) and (b) after weight contains at least one of (c) 0/0 0 1 to 15 parts by weight represented by the following-V " Chemical formula (1) or (2) 4 Monoamine-2,2,6,6 ...., (_ Tetramethylpiperidine compound: Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs τ! 3 3-w-\ clc ^ 1veil / \ 3 3 CHCH; / f ··,-/ R1 Tifs; / \ ·-H3H3 -P 0 C 2 This paper size applies to China National Standard (CNS) A4 specifications (210x297 mm > -1 _-— — — — ΐ.-i III «— 111 III ill — — — — — — (Please read" Notes on the back "first Things! Know this page > A8 B8 C8 D8 6. Scope of patent application • --Annex I (A): No. 85101987 Patent Application Chinese Application Patent Range Amendment October 1980 Revision 1. A kind of polyphenylene ether -Fat composition comprising: (a) 10 to 90% by weight of polyphenylene charm resin, -r ..... ''. (≫ a) 90 to 10% by weight of crystalline thermoplastic Resin, which is at least one selected from polyethylene resin, polypropylene resin 'polyacid' amine resin, poly (alkylene diamine) resin, poly Nongxia resin. Ether M resin, and the sum of the numbers (a) and (b) after every 100 weights contains at least one of (c) 0/0 0 1 to 15 weight parts by the following-V " Chemical formula (1) Or (2) 4 -Amine-2,2,6,6 ...., (_ Tetramethylpiperidine compound: Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs τ! 3 3-w-\ clc ^ 1veil / \ 3 3 CHCH; / f ··,-/ R1 Tifs; / \ ·-H3H3 -P 0 C 2 This paper size applies to China National Standard (CNS) A4 specifications (210x297 mm > -1 _-— — — — ΐ.-i III «— 111 III ill — — — — — — (Please read" Notes on the back "first Things! Know this page > A8B8C808 (3) Six, apply for profit: 1 ^ means a hydrogen atom X oxygen source in _ (oxygen-containing fluorene), a sequester group 'alkyl group, a cycloagrochemical group , One allyl group, one benzyl group, one aryl group, two alcohol groups, one alkoxy group, one alkoxy group and one cyclo ^ oxy group 'R 2 represents a hydrogen atom, an alkyl group, or one as shown in the following chemical formula (3) a group represented by 0 II • RiC X X + R5 where 'X represents a direct chain, .- 0-or -N Ή-, R 4 represents a direct bond, a straight chain or branch: alkylene , An arylene group or an arylene group, Rs represents an proud hydrogen atom, a courtyard group 'an aryl group or a group represented by the following chemical formula (4) or (5)' -CH = CHCOH ^, it C 4) > tmm n * i ti n 1— Mmm »1_ I pack. 1 — p ^ 1¾ (Please read the precautions on the back before HI this page) Order: Warp Intellectual Property Office employees consumer cooperatives printed Where η is an integer from 1 to 4 and ^ is an integer from 2 to 6, R 3 is an η-valent organic group β-this paper size applies to China National Standard (CNS) A4 (210 x 297 public love) _ 2-A8B8C8D8 VI. Applying for profit-seeking Fanyuan 2 · For example, the polyphenylene ether resin composition in the scope of application for item j, in chemical formula (1) or (2), when η is 1 and R3 is a hydrogen atom, an alkane Group, one cycloalkyl group, one sham group, one benzyl group, ^ aryl group or a group represented by the following chemical formula (6): \ 0 十 Y (6), where Y represents a direct bond, 〇- OR, -N Η 8-, R β represents a direct bond, a straight or branched alkylene, an alkylene or an arylene, R 7 and R 8 each represent a hydrogen atom, One hydroxyl group, one .synthetic group or — ·, one aryl group. 3. For the application of the polyphenylene ether resin of composition 1 of Weng Weiwei—composition, its \ ...........-In the chemical formula (1) or (2), R 3 represents a Alkyl group or a group represented by the formula (7) in the second column; Μ Read the note on the back-1] E f Binding Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Where R / represents a direct chain, a straight chain or a branched alkylene, an alkylene or an alkylene. 4. If the polyphenylene ether resin composition of item 1 in the scope of the patent application 'wherein in the chemical formula (1) or (2), π is 3 2 and R 3 is tilted, the Chinese paper standard (CNS) applies A4 specification (210 X 297 mm) Application range for specific applications> Table 6 of the six-group radical Γν Chemical formula Η CH 1? CH r CH ort ·-2 Ni c .N ο A8B8C8D8 Η CH 丨 OI.CH2 CH 丨 Λ 丨 N] / 8 -fv 2 CH 2 ο 丨 Η 5. The polybenzoic acid resin composition according to item 1 of the patent application scope, wherein η in the chemical formula (1) or (2) is 4 and R 3 It is a group represented by the following < Chemical formula (9) or (10); 〇II CH, C- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 〇 IICHC- Ο «« CHC- C9) Ⅱ IIt.c- 〇η C—eCHt OCCH * CK,-^ = (10) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -4-A8— 6. Applying for a profit-seeking range 6. For example, the polyphenylene ether resin composition in the scope of patent application item 1, wherein in the formula (1), R 1 and Ge 2 each represent a hydrogen atom or a compound An alkyl group of 18 carbon atoms, and 11 is 1 or 2, where (I) when η is 1, R 3 represents a hydrogen atom, an alkyl group, a cycloalkyl group, a candyl group, or by the chemical formula (6) A group represented by Υ, where Υ represents a direct chain, a 0-, or -MR 8 R β represents a —Ji direct bond, a straight or branched chain with 1 to 10 carbon atoms _______ 〆 alkyl, a sub-group Alkyl or aryl-aryl, R 7 and trans 8 each represent a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, and an aromatic group having 6 to 21 carbon atoms. Or a group represented by the chemical formula (4) or (5) and [when η is I -R 3 is one of the following northern formula (7)-illlllillljlln ^ i < please read the precautions on the back of it first Then © this page: Order · . Line] Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, where R β represents r-direct chains, one with 1 to 10 carbon atoms. Or an arylene. Seven people, such as the polyphenylene ether resin, and the composition of the first item of the patent scope, wherein in the chemical formula (1), η is 2, and R 3 is a monoalkylene group. 8. The polyphenylene resin composition according to item 1 of the patent application scope, wherein the chemical formula (in which η. Is 2 ′ .. Rs is ._ ammonia. Proto ... The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 5 A8B8C8D8 6. Application for profit scope 9 _For example, the polyphenylene resin composition of the first scope of the patent application, where the chemical formula (1) In the formula, η is 2, R ^ is a dihydro atom or a methyl group, R2 is a nitrogen atom ', and R3 is -_-........ ~~ ..... 1 0聚 The polymer resin composition of item 1, wherein in the chemical formula (1), Π— is J, r 2- is a fluorenyl group and R 3 is a fluorinated group. 1 1 ′ as in the polymerized polymer of item 1 A phenyl ether resin composition, wherein in the chemical formula (1), η is 2, R 2 is a group represented by the chemical formula (3), wherein X represents a direct bond, or -N Η —, and R 4 represents a direct bond , A straight-chain or branched alkylene, an alkylene or an aromatic, R 5 represents a hydrogen atom, an alkyl group, an aryl group or a group represented by the chemical formula (4) or (5), R3 1 2 · As claimed, please apply for a polyphenylene ether resin composition in item 1 of the patent scope, wherein the crystalline thermoplastic resin (b) is a polyamidamine resin. 1 3 · If item 1 in the scope of patent application The polybenzoic acid resin composition, wherein the resin composition additionally contains a certain amount of (d) a mutual compatibilizer which is helpful for the mutual compatibility of the components (a) and (b). The polybenzoic acid resin composition of 3 items, wherein component (d) is at least one selected from the following (d 1) to (d 1 〇), (d 1) _: a species that is not suspected and acetylene unsaturated Bonded epoxy compounds, (d 2):-molecules with (i) at least one unsaturated group, such as carbon-carbon double bonds and carbon-carbon triple bonds' and (ii) at least one paper size applicable to China National Standard (CNS) A4 Specification (210 X 297 mm)-— — — — I — injin · II (please read the notice on the back before ^^ this page) Preparation of A8B8C8D8 VI. Application for profit-seeking polar compounds, (d 3) A: a silicon compound Its molecule has (i) carbon atoms cross-linked with oxygen, and (ii) at least; a Zen selected from the group consisting of a carbon-carbon double bond, a carbon-carbon triple bond, a seed, an amine group, and a thinner. And the functional group having a silicon atom does not have a direct bond, (d 4): a compound having at least two kinds of the same or different official skeletons in the molecule, which is composed of (i) (OR) (wherein, R is a hydrogen atom, an alkyl group, an aryl group, a fluorenyl group or a dioxo group) and (ii) a carboxylic acid,-* fluorenyl halide group, an acid anhydride, a fluorenyl halide anhydride'a Ester, an acid amine, an imine, and salts thereof, (d 5): a compound having (i) a halogen halide group and (ii) at least one carboxyl group, one Carboxylic anhydride group — an acid ester group and an amino group selected by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (d6): a vinyl aromatic compound and an unsaturated dicarboxylic acid or Copolymer of a dicarboxylic anhydride, or a vinyl aromatic compound and an imine compound of an a, yS-unsaturated dicarboxylic acid Copolymer, (d 7): an organic compound having no alkenyl or alkynyl unsaturated bonds in the molecule and having two or more isocyanate and / or isothiocyanate groups, (d 8-a compound , There are no alkenyl and alkynyl unsaturated bonds in the molecule, and (OR) (where R system, a hydrogen atom, a proton. 'A courtyard, an aryl, a fluorenyl or a fluorenyl) has 2 Or more amine groups, this paper size applies to Chinese National Standard (CNS) A4 specifications (210 X 297 mm) _ 7 A8 B8 C8 D8 VI. Application for profit scope (d 9): — a kind of polyphenylene ether, based on Functionalization of at least one mutual container selected from (d1), (d2), (d3), (d4), and (d5), (d1〇); a aryl aromatic compound and a crystalline thermoplastic resin '(B λ mutual capacity 4 ^ combination-thing_'s common green thing. 1 5 · As described in the first patent application of the poly-stupid resin product, wherein the 4-amino group 2 ″ 2 .._, 6, 6-tetramethyl erbium compound (c) is one Compounds represented by the chemical formula (1): R 卞 ... CH, 〆, CH, CH, R3 (1) * I n * ϋ Kt Mat —mw Qf el na ^ MW · I t I equipment • > 1 tM9 n {Please read the price on the back page before this page) tmm Λ§ Λ§ at n Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, where R Wei represents a hydrogen atom, one # oxygen atom_ (containing oxygen), one Hydroxyl, an alkyl group with 1 carbon atom,-a cycloalkyl group, an allyl group, a benzyl / an aryl group, an alcohol group 'an alkenyl group,-an alkoxy group,-or an Cycloalkoxy, and η is an integer of 1, 2, or 4; when η is 1, R2 represents a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, or a C- (P)-(Q ) -C—OH „^ 〇〇, where P and Q represent a selected group consisting of an alkylene, an alkylene, a vinyl and a vinylidene group, and R 3 represents a hydrogen atom, An alkyl group, a cycloalkyl group, an alkenyl group'—a benzyl group, an aryl group, or a group represented by the following chemical formula (6.); Order --------- line-; !! The paper size of the table applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) A8B8C8D8 6. Application for profit-seeking range 0-R6 ?: Ten Y in ^ 7 (.6) where γ represents a direct key—a direct key Bond, _ 0 a ', R β —, R β represents — a straight or branched fluorenyl group — — an arylene group — or an arylene group, R 7¾ R-8 each represents a meridian group — a courtyard Group, an aryl · > * group, or a group represented by the formula (4) or (5) in column f -CH = CHCOH 4 -111111 ^ 111111— · II {Please read the “Notes on the back page before you read this page.” Order .: When η is 2, R2 represents a hydrogen atom, an alkyl group with 1 to 8 carbon atoms, or —C 一 (P)-(Q) _ C _ 0H II II 〇〇, where P and Q represent a set consisting of an arylene group, a sub-group, a sub-group, a vinyl group and a vinylidene group Among the selected ones, R3 represents an alkylene group or a group represented by the following chemical formula (7) 'The private paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm)-line: Bureau of Intellectual Property, Ministry of Economic Affairs A8SD8 printed by the employee consumer cooperative (7) 6. Application for profit-seeking scope 〇C r9 c where R 9 represents a direct bond, a straight or branched alkylene, an alkylene or an alkylene; when η is At 4 o'clock, R4 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and R 3 represents a group consisting of the following chemical formula (9 or (1 Ο X 表 # 的 碁 团, -1 > | > 1 n 1 · * ί ϋ .1 '^ ϋ I equipment * _ < Please read the precautions on the back first, then β this κ C-tCHa OCCH, α 0) Order · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 16. For example, the polyphenylene acid resin product of the 15th patent application scope, where the chemical formula (1) is in ' R l · and R 2 -Bie-epi_ bearing a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and η is 1 or 2, (i,) _ when η is 1, R3 represents a hydrogen Atom ,, an alkyl ,! A cyclofluorenyl group, an alkenyl group or a group represented by the following chemical formula (6) 'This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -j〇- 6. The scope of patent application A8B8C8DS 0 I! C Ten Y Ten · r7 (6) 0 NR R β means one-to-one direct transition to a true chain or branched alkyl group with 1-1 〇 light carbon star, one sub-hidden group hides two Aryl, R 7 and R 8 each represent a perylene group, an alkyl group having 1 to 18 carbon atoms, an aryl group having 6 to 21 carbon atoms, or an aryl group having the following chemical formula (4) or (5) A group represented by -CH = * CHCOH < S C4) CH c / Cvc 3 • C 3 NI R. CH 5 3 — — — — — ΙΪΙΙΙΙ — — · 1111111 I — — — — — — — — — (Please read the notes on the back before reading this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (ii) When η is 2, R 3 represents a group represented by the following Bei Xue formula (7), Among them, Re represents a direct bond, a straight bond or branched dynein group having 1 to 10 carbon atoms, an arsenic or an arylene group. This paper size is applicable to China National Standard (CNS) A4 specification (210x 297 mm) _ η _ A8B8C8D8 VI. Application for profit margins 17. For example, the polyphenylene chain and resin composition of item 15 in the patent scope, where the chemical formula In (1), η is 2, and R 3 represents an alkylene group. For example, in the case of the patent-preferred poly-I resin I product of item 15, the chemical formula (1), 11 is 2 _112 represents a hydrogen atom, r and R 3 represents an alkylene group. 1 9 As in the polyphenylene ether resin composition of the 15th patent application scope, in the formula (1) in the ear, η is 2, and Ri represents a A hydrogen atom or a methyl group, 112 represents a hydrogen atom, and R3 represents a hexamethylidene group. The polyphenylene ether resin composition of item 15 in the patent application scope, wherein in the chemical formula (1), η is 2, R2 represents an alkyl group, and R3 represents an alkylene group. 21. The polyphenylene ether resin composition according to item 15 of the patent application scope, wherein the compound (b) represented by the chemical formula (1) is at least one of the following: Compounds represented by chemical formula (i)-(iv): • I · 1 ^ 1 1 at —vv · 1 I ii n Amew I installed.! (Please read "Notes on the back«-then m this page) -Line-Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper size applies to China National Standard (CNS) A4 specifications (210 * 297 mm) -12-VI. Application for profit-seeking scope A8 B8 C8 D8 0 R ， 'Rit 〇it II π B〇-CC = C -CN CR n 0 Rl * R | 4 0 II II II NC-C = C -C-OH IC (Please read the precautions on the back before @ (This page) Install CC C \ C C C H, C CCH 10 CH Order · Rio (iii) R-Line · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 0 Ru Ru Ο II 1 I II HO-CCC -CN HH iccc H s I 1 8 / CH 3 N Rio Ί 1 R c .0H I o UC 4-R · 丨 c ΗRI 丨 -CH one 4 .NIC. C H c 3 H c H c 3 E c c 10, NR1 ε c H c This paper size is applicable to Chinese National Standard (CNS) A4 specification (210 χ 297 mm) -13-A8B8C8D8 Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 6. Application for profit-seeking fan park where Rio indicates a A hydrogen atom, a meridian group, an academy group, or a oxo group 'Rll represents an extrinsic group' Rl2 represents a fluorenyl group, and R 13 and R i4 each represent a hydrogen atom or a methyl group 2 2. As requested The polyphenylene coagulation resin composition of the 21st item of the patent, wherein in the chemical formula (i.), R10 represents a dihydrogen atom, one carboxyl group, and one with 1-10 carbon atoms. Fluorenyl or = alkoxy plug with 1 —, .10 carbon atoms, R ai represents a #alkyl group with 2 to 8 carbon atoms — 2 The polybenzoic acid-resin composition of the item, wherein iR, in the chemical formula (i). Represents a hydrogen-avoiding atom or a methyl group, and Ru represents a hexamethylidene group. 24. For example, in the polyphenylene ether resin composition of item 21 of the scope of patent application, the chemical formula (i i) of Luzhong is 1 ^. Represents a hydrogen atom, a hydroxyl group, a radical with 1 to 10 carbon atoms or an alkoxy radical with 1 to 10 carbon atoms, Rn represents a shoulder radical with 2 to 8 carbon atoms, R ί2 represents an alkyl group having 1 to 18 carbon atoms. 25. For the polyphenylene ether resin composition according to the scope of the patent application No. 21, in the chemical formula (ii), R10 represents a hydrogen atom or a methyl group. The polyphenylene ether resin composition, wherein in the chemical formula (iii), R i. Represents a hydrogen atom, a hydroxyl group, an alkyl group with 1 to 10 carbon atoms, or an alkoxy group with 1.1 to 10 carbon atoms, and Rii refers to an alkylene group with 2 to 8 carbon atoms · .. Private paper size applies to China National Standard (CNS) A4 (210 x 297 mm) _ 14 _ --------------- installed • · 1 ft— nn Order 1! !! Line J < Please read the notes on the back «-then ® this page) A8B8C8D8 6. Apply for a patent scope 2 7. If you apply for a patent, where the chemical formula (iii) is methyl β 2 8. Among them, in the chemical formula (iv), a fluorenyl group having 1 to 10 carbon atoms, R η represents a group. 2 9. As claimed in the patent application, wherein the chemical formula (i ν) is a radical. 3 0. In the patent application, where 4-amino group-2, 2) is composed of the polyphenylene chain resin composition of the following chemical formula (1) item 21, R10 represents a hydrogen atom or a Item of polyphenylene ether resin composition, R i. Represents a hydrogen atom, an alkyl group of a hydroxyl atom, or a polyphenylene ether resin composition having 1 to 10 and an alkylene having 2 to 8 carbon atoms. Item 21 * Rio represents a hydrogen atom or A polyphenylene ether resin composition of No. 1 item, 6,6, tetramethylpiperidinium compound (c means: Please read I »Read the note on the back I pkI i Order printed by the Intellectual Property Bureau's Consumer Cooperative 3 Ri R η 1) where R ^ represents two hydrogen atoms ", an oxygen atom (containing an oxygen group), a 4-amino group, 2 a pseudo group having 1 to 8 carbon atoms, a cycloalkyl group, an Allyl, one benzyl, one aryl, one -alkenyl, one-/ alkylalkoxy or one cycloalkyloxy, r2 represents a hydrogen atom or an alkyl group; and η is 1, 2 or An integer of 4, this paper size applies to Chinese national standards (CNS> A4 specification (210 X 297 mm) 15 A8B8C8D8 VI. Application for profit-seeking fan park (I ') When n = 1, R3 represents a hydrogen atom, an alkyl group , A cyclofluorenyl group, a storage group, a fluorenyl group ~,-an allyl group or one-a group represented by the following chemical formula (6), 0U (6) where X represents a direct bond, -0- , NR β-, R β represents a direct bond, a straight or branched alkylene group, an alkylene group or an aryl group, and R 7 and R 8 each represent a hydroxyl group, an alkyl group, and an aryl group. Or a group represented by the following chemical formula (4) or (5), -CH = CHCOH 4 c. Ic 3 Consumer Cooperatives of Intellectual Property Bureau, Ministry of Economic Affairs Printed Γ c * c 3 3 Η Η cci · — — — — — — 1 — IJ --- · M ml — ^ illn-- (Please read the notes on the back «'then © this page) The group} I of the base I is shown in Table C. Table 2 is shown in Table 3. R type is listed by one 9 R one. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm). -16-Intellectual Property of the Ministry of Economic Affairs S86096 printed by the Bureau ’s Consumer Cooperatives § __§ VI. Applying for a profit-seeking fan park where R β table τκ is for sale. Direct _ key one, .. .. a direct key .. _ or — .. branch extension base, an Asian An alkyl group or an arylene group, and j IV) When η = 4, R 3 represents a group represented by the following chemical formula (9) ά (1〇), 〇II CH * C— 〇 II CHC- 〇 Μ CHC * (9) Ο tl [* C · Ο C—K: H, OCCH, CH «-^ S (10) 3 1 · As in the application for the polyisocyanate resin composition in the scope of the patent application No. 30, where the chemical formula In (1), R: represents one hydrogen atom or one alkyl group having 1 to 8 carbon atoms, and R 2 represents one hydrogen. Proton-proton- or one ~ with -1 ...- 18 carbons焼 -base of an atom, and η is an integer of 1 or 2; when 11__ 枭 _._ 1 ..._ , R 3 represents a hydrogen atom, a fluorenyl group, a cycloalkyl group, an alkenyl group, or a basic group represented by the following Northern Formula (6): 11-R € C ten Y (6) Paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm > _ 17 _ Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 6. Application for profit-seeking scope. Among them, Y represents a direct bond, 0—or NH, R β represents a direct bond, and a straight chain of 1_10 carbon atoms. Or branched alkylene '-one alkylene group with 1 to 10 carbon atoms, or extended aryl / r 7 and R 8 each represent a hydrogen atom, and one with 1 to 18 carbon atoms Alkyl 'an aryl group having 6 to 2 carbon atoms or a group represented by the chemical formula (4) or (5), -CH = CHCOH, & C〇'3 N-IR. 3 5: When When η is 2, R3 represents a group represented by the following chemical formula (7), Wherein 119 represents a direct bond, a straight or branched alkylene group of 1 to 10 carbon atoms, an alkylene group of 1 to 10 carbon atoms, or an alkylene group. 32. The polyphenylene ether resin composition according to item 1 of the scope of patent application, in which 4-monoamino-2,2,6, tetramethylmeridine compound (c This paper size applies the Chinese National Standard (CNS) A4 specification ( 210 χ 297 mm) _ 1 «II ^ 1 ϋ n ia« «I ^ > i > 1 I · n ^ I— > 1 ϋ ^ 5 't · 1 n 1 · n I; * ref ( Please read the precautions on the back before reading this page) Θ 9 ΰ s 8 3 A8B8C8D8 6. Apply for a profit-seeking range) is a compound represented by the following chemical formula (2): «3 ch3. CC .CH, P N > R3 CH C c, 'CH. 3 \: 3 R1 I * R, (2) where 111 represents a hydrogen atom, an oxygen atom (containing an oxygen group), a hydroxyl group, and one with 1 to 8 carbons Atomic alkyl group, one cycloalkyl group, one allyl group, p fluorenyl group ~ one aryl group, one alcohol group, one alkenyl group, one alkoxy group or one cycloalkoxy group, and η is an integer of 3 ―; Wherein R 2 represents 〆 ′ hydrogen atom or an alkyl group having 1 to 8 carbon atoms, and P is an integer of 2 to 8 and R 3 represents a group represented by the following chemical formula (8); ¾ H 丨 0 丨 8 2 CH ο > § n t— ϋ Eh ί in I equipment. 丨 — (Please read the notes on the back first and then the page) Order-· Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs o \ 〆NIC HIOIS 2 CH < 丨 CH CH r CH ο I Η This paper size is in accordance with Chinese national standard (CNS > A4 size (210 * 297 mm) _ J 9-· line · N— / 8 Γ \