TW385232B - Fungicidal active compound combinations - Google Patents

Abstract

The novel active compound combinations consisting of a halogeno-benzimidazole of the formula (I) in which Z represents chlorine or bromine and the active compound groups (1) to (25) listed in the description have very good fungicidal properties.

Description

I A7 ----- B7 V. Description of the invention h) The Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs of the People's Republic of China printed the present invention relates to a novel active compound composition containing a known halogen-benzimidyl and further known to kill Fungal active compounds, and their high suitability for controlling phytopathogenic fungi. 1- (3-5-dimethyl-isohumidazole_4_continyl) _2-mo_6,6_difluoro- [1,3] -dihumopeno- [4, Succinylbenzimidazine and dimethylisoxazol-4-acryl) -2-gas-6,6-difluoro- [1,3] _dioxanyl_ [4,5f] _ Benzimidazole has fungicidal properties (refer to WO 97-06171) »The activity of these compounds is good; however, at low dosages, it is not satisfactory in some cases. In addition, it is also known that most triazole derivatives, aniline derivatives, dicarboximide derivatives, and other heterocycles can be used for fungal control (see EP_A 0040 345, DE-A2 201 063, DE-A2 3240 0 10, Pesticides Handbook, 9th edition (1991), pages 249 and 827, EP-A 0 382 375 and EP-A 0 515 901). Likewise, the activity of these compounds is not always satisfactory at low dosages. Finally 'now also known that 1-[(6-qi_3 · pyridinyl) -methyl] nitro-2-tetrahydroimidimine can be used to control animal pests, such as insects (see the pesticide manual '9th edition (1991), p. 491 However, the fungicidal properties of this compound have not been described so far. The novel active compound composition has now been discovered, which consists of

This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) (谙 Please read the precautions on the back before filling this page) Order A7 B7 (II), (Please read the precautions on the back before filling in this tribute) Print the Fan Cooperative Staff Cooperative of the Ministry of Economics and Standards of the Ministry of Economic Affairs of the People's Republic of China. 5. Description of the invention (2 where Z stands for gas or bromine and (1) has the following formula: 3) derivatives XΌ ^ 0- 广 丫 -c (ch3) 3 1; > wherein X represents a gas or a phenyl group, and u, * —C— —CH-Y represents 丨 丨 or 〇 and / or (2) a triazole derivative having the formula

OH CH0 and / or (3) benzylamine derivatives of the following formula (ill), (tebutine) 5. Description of the invention (3)

s-cci2f so-N (CH3) 2 where R1 represents hydrogen or methyl and / or A7 B7 (IV), (4) N- [l- (4-Gas-phenyl) -ethyl] -2,2-Digas-1-ethyl-3-methyl · cyclopropane · carboxamide

CH-NH-C-I II

Cl, CI

-Η c2h5 ch3 (V) CH. 3 and / or (5) propylene-1,2-bis (dithiouric acid) zinc S CH, SII I II-(Zn—S—C— NH—CH2—CH——NH—-CS]-(VI) n > = Indian Union Consumers ’Cooperative Press (Proupperone) and / or (6) at least one thiamine with the formula Acid salt S,

H S ： Me (VII), (Please read the notes on the back before filling this page)

This paper size applies to Chinese national standards (CNS> A4 specification (210X297 mm). Reading 5. Description of invention (4) A7 B7

Me = Zn or Mn or a mixture of Zn and Mn and / or (7) an aniline derivative of the formula

Gate_Π —C-NH CH,

ΟΗ Cl CI (VIII) (fenproxamine) and / or (8) a compound of the formula fj ^ H (CH3) 2 (CH3) 2CH-〇-C-NH-CH-C-NH-CH- ~ \ —II | 〇ch3 and / or (9) benzothiodifluorene derivative CH, (IX) h3cs-c

N II N S- (X) (benzene dicarbamate) and / or the Central Consumers Bureau of the Ministry of Economic Affairs of the Consumer Cooperatives Cooperative Seal (10) with the following formula: 8-Second-butyl-2- (N-ethyl-N -N-propyl-amino) -methyl-1,4-dihumo [5,4] -decane〇, (CH3 > 3C- < X ~ · (X 丨) (spirosamin)

C3H7-n 6 (Please read the precautions on the back before filling this page)

This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) L. Invention description (and / or (π) compounds with the following formula

OCH, and / or (12) a compound of the formula

And / or (13) a compound of the formula A7 B7 (XII) (azostobin oxide) (XIII) (crisoxime-methyl) printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

And / or (14) Cyanoxime derivatives with the following formula 7 The paper size is applicable to Chinese National Standard (CNS) A4 (210X297 mm) (XIV) (Read the precautions on the back before filling in this page)

5. Description of the invention (6 A7 B7 〇CNII II I CH3—CH—NH—C-NH—CC = NOCH3 (XV) (Sermosani) and / or (15) a pyrimidine derivative CH having the following formula, (XVI), N: wherein R2 represents methyl or cyclopropyl and / or (16) an aniline derivative CH having the formula:

CH, / CH-COOCH3 'C-CH2-〇—CH3 〇 (XVII) (Miracil) Employees of the Central Standards Bureau of the Ministry of Economic Affairs, Consumer Cooperatives and / or (17) morpholine derivatives with the formula: 0 and /or

〇V II N-C-CH = C

(XVIII) (Dimethoxymorph) 8 (Read the precautions on the back before filling in this page)

This paper size applies Chinese National Standard (CNS) A4 specifications (210X297 mm) 5. Description of the invention (7 A7 B7 (18) Phthaloimine derivatives of the following formula 0Cn-s, II 0 and / or (19 ) Phosphite compound (XIX) (Fupert) h5c2o,: p \ and / or (20) hydroxyethyl-triazole derivative (XX) (filled ethyl-A1) with the formula Ministry of Central Standards Bureau staff consumer cooperatives

And / or (21) l-[(6-air bite) -methyl] -N_wall-based-2 · Weifeng Entertainment * imine 9 This paper size applies to Chinese National Standard (CNS) A4 Specifications (210X29? Mm) (Please read the precautions on the back before filling this page)

A7 B7 V. Description of Invention (8)

CH. / ~ \ 2, N NH Η N—NO, cr n (XXII) (middapril) and / or (22) humazolidinedione having the formula

(XXIII) (Cutting, sitting and biting) (Please read the precautions on the back before filling in this page)

1T (23) benzamidine derivative CI h3c

〇 II C-NH-CC——CH2CI Cl CH, c2h5 ϋ (XXIV) κ, ιν-- printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs and / or (24) a guanidine derivative of the following formula R—N— (CH2) 8- [N— (CH2) 8] -NH (XXV) Π

χ (2 + m) CH-COOH This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) V. Description of the invention (9 where m represents an integer from 0 to 5 and J · R3 represents hydrogen (17 to 23%) or free radical ~ C = NH NH, please read the note on the back (77 to 83%)

I and / or (25) a triazole derivative of the formula? Η2

Cl · (XXVI) t Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

(Comprised of Penkang ο 'and has good fungicidal properties β Unexpectedly, the fungicidal activity of the active compound composition according to the present invention is considerably higher than the sum of the activities of the individual active compounds. Therefore, there is an unexpected synergistic effect And not just an active addition. Formula (I) includes — 1- (3-5-dimethyl-isohumazole-4-sulfonyl) -2-bromo-6,6- Difluoro- [1,3] -di-Hentamyl- [4,5f] -benzimidazole (la) This paper size is applicable to China National Standard (CNS) A4 (210X297 mm) 5. Description of the invention ( 10) and A7 B7 have the following formula: 1- (3-5-dimethyl-isofluoren-4-sulfonyl) -2-azine, 6,6-difluoro- [1,3] -dihum Pentamido- [4,5fj-benzimidazole

(lb). The halogen-benzimidazoles of the formulae (la) and (lb) are known (see WO 97-06171). Formula (II) includes compounds having the formula 1- (4-Gas-phenoxy) -3,3-dimethyl-1- (1,2,4-triazol-1-yl) -but- 2-ketone

Cl ^ >. 〇II 一 CH—C—C (CH3) 3 (lla)-(Please read the notes on the back before filling out this page) Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 1- (4-Gas-phenoxy) -3,3-dimethyl-1- (1,2,4-triazol-1-yl) -but-2-ol OH CI ~~ Ο- CH—CH—C (CH3) 3 Ο (Mb) (Quatraminol) 12 This paper size applies to China National Standard (CNS) A4 (210X297 mm)

And 1- (4-phenyl · phenoxy) -3,3 · dimethyl_1- (1,2,4-trifluoren-1 · yl) -but-2-ol having the formula

OH O-CH-CH—. (. Go I (He) (Bittanol). Formula (IV) includes aniline derivatives of the following formula ----------- (Please read the precautions on the back before filling out this page ) And CCI, ~~ SO-N (CH3) 2 (IVa) (difluorofluoride)

H3C S〇2-N (CH3) 2 (IVb) Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (Tolufluranide). Obviously, for the chemical formula of the active compound of formula (v), the compound has two Asymmetrically substituted carbon atom. The product can therefore exist as a mixture of different isomers or as individual components. Particularly preferred is a compound given by N- (R)-[1_ (4-Gas-phenyl) ethyl Kls > Propane Carboxamide 13 A7 B7

V. Description of the invention (12) (Va) and N- (R)-[l- (4-gas-phenyl) -ethyl]-(lR) -2,2-digas-1- Ethyl-3t-methyl-lr-cyclopropanecarboxamide (Please read the precautions on the back before filling this page)

(R) -CH—CI (Vb) Order (s) (R) in3 The compound of formula (VII) includes several compounds, the Ministry of Economic Affairs, the Central Standards Bureau, the staff consumer cooperative, Yinfan (Vila), Me = Zn (代 森 Zn) (Vllb ) Me = Mn (Morocene) (Vile) (Vila) and (Vllb) mixture (Morocene). The compound of formula (XVI) includes several compounds (XVIa) r2 = ch3 (methylbenzirimidine) (XVIb) R2 = ~ <] (cyclopropanyl). In the formula (XXI), the ethyl-triacetate can be stored in the form of "thionine" in the following formula. The paper dimensions are applicable to the Chinese National Standard (CNS) A4 specifications (2 丨 0X297 mm) A7 B7 5. Description of the invention ( )

ΟΗ CH-C- ^ C | CH,

IVs -NH (XXI) or exist in tautomeric "filament" form

(Please read the notes on the back before filling out this page) $ Ding Simplified Printing of the Consumers' Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs , Is a substance commonly known as a mixture of ancient azines. Not only the halogen-benzimidazole of formula (I), but also the ingredients present in the active compound composition according to the present invention. In particular, several active compounds are described in the following publications. (1) Compound of formula (II) DE-A2 201 063 DE-A 2 324 010 (2) Compound of formula (III) EP-A 0 040 345 15 This paper size applies Chinese National Standard (CNS) A4 specification (2 丨 0x297 (Concurrently) A7 B7 V. Description of the invention (14) (3) Manual of pesticides for compounds of formula (IV), 9th edition (1991), pages 249 and 827 (4) Compounds of formula (V) and their derivatives EP-A0 341 475 (5) Handbook of Insecticides for Compounds of Formula (VI), 9th Edition (1991), Page 726 (6) Handbook of Insecticides for Compounds of Formula (VII), 9th Edition (1991), Chapter Pages 529, 531 and 866 (Compound of Formula (VII) Ep-A 0 339 418 (8) Compound of Formula (IX) Ep-A 0472 996 (9) Compound of Formula (X) Ep-A 0 313 512 (10) Compound of formula (XI) EP-A 0 281 842 (11) Compound of formula (XII) EP-A0 328 375 (12) Compound of formula (XIII) is printed and printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Distillation (please read the note on the back first) (Please fill in this page again) ΕΡ-Α0 515 901 / (13) Compound of formula (XIV) DE-A 196 02 095 (14) Manual of compounds of formula (XV) pesticides, 9th edition (1991), p. 206 16 This paper size applies to Chinese National Standard (CNS) Α4 size (210X297 mm) A7 B7 (15) Description of the invention (15) Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (15) Compound of formula (XVI) EP-A0 270 111 EP-A 0 310 550 (16) Manual of compounds of formula (XVII) Pesticides, Section 9th edition (1991), p. 554 (17) Compound of formula (XVIII) EP-A 0 219 756 (18) Manual of compounds of formula (XIX) Pesticides, 9th edition (1991), p. 431 (19) Formula (XX) Handbook of Compound Pesticides, 9th Edition (1991), p. 443 (20) Compound of Formula (XXI) WO 96-16048 (21) Handbook of Pesticide Compounds of Formula (XXII), 9th Edition ( 1991), p.491 (22) Compound of formula (XXIII) Ep-A0 393 911 (23) Compound of formula (XXIV) Ep-A 0 600 629 (24) Manual of insecticidal stab of substance of formula (XXV), 9th edition ( 1991), page 461 (25) Handbook of pesticides for compounds of formula (XXVI), 9th edition (1991), page 654 Not only active compounds of formula (I), active compound combinations according to the invention 17 This paper is applicable to China National Standard (CNS) Α4 specification (210X297 male) (read the notes on the back first and then fill out this page)

A7 B7 The consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ’s consumer cooperatives is 0.1 to 20 parts by weight, more than 1 to 150 parts by weight, and preferably 0.1 to 10 parts by weight. It is preferably 1 to 150 parts by weight, preferably 1 to 150 parts by weight, preferably 0.1 to 50 parts by weight, and preferably 0.1 to 50 parts by weight. Parts, preferably by weight of 0.02 to 50 parts by weight, preferably by weight 5. Description of the invention (Yu Wu, contains at least one active compound from several compounds of groups (1) to (25). In addition They may further comprise a fungicidal active ingredient. When the active compound in the active compound slave compound according to the present invention is present in a specific weight ratio, their synergistic effect is particularly significant. However, the active compound weight ratio in the active compound composition It can be changed in a wide range. The active compound of the general group (1) is 0.1 to 20 parts by weight, preferably 0.2 to 10 parts by weight. The active compound of the group (2) 0.2 to 10 parts, active compound of group (3) is 1 100 parts, the active compound of group (4) is 0.2 to 5 侩, the active compound of group (5) is 5 to 100 parts, the active compound of group (6) is 5 to 100 parts, and the active compound of group (7) is The active compound counts from 1 to 20 parts, the active compound count from group (8) is from 0.2 to 20 parts, and the active compound count from group (9) is from 0.1 to 10 parts. 18 This paper size applies to Chinese National Standard (CNS) A4 specifications (210 ×: 297 mm) (Please read note f on the back before filling out this page) Order five. Description of the invention (17 Active compound printed by Group A7 B7 (10) printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, by weight 0.1 to 20 parts by weight, preferably 0.5 to 10 parts by weight * active compound of group (11), 0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight, group ( 12) The active compound is 0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight, and the active compound of group (13) is 0 to 50 parts by weight, preferably by weight. 0.2 to 20 parts, active compound of group (14), 0.1 to 50 parts by child, preferably 0.2 to 20 parts by weight, 4L of active compound of group (15), The amount is 0.2 to 50 parts, preferably 1 to 20 parts by weight. The active compound of group (16) is 0.1 to 50 parts by weight, preferably 0.2 to 0 parts by weight. The group ( 17) The active compound is 0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight. The active compound of group (18) is 1 to 150 parts by weight, preferably 5 by weight. To 100 parts, the active compound of iridium (19) is 0.1 to 150 parts by weight, preferably 1 to 100 parts by weight, and the active compound of group (20) is 0.02 to 5 parts by weight. 0.20.2 to 10 parts by weight, active compound of group (21), 0.05 to 20 parts by weight, preferably 0.1 to 10 parts by weight, 19 Chinese paper standard (CNS) A4 specification (2 丨 0X297mm) (Please read the precautions on the back before filling in this page)

Employees' cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs, A7, B7. 5. Description of the invention (18) Group (22) of the active compound is 01 to 50 parts, preferably 0.2 to 20 parts by Tong Dong. The active compound of (23) is 0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight, and the active compound of group 4) is 0.02 to 50 parts by weight, preferably 0.04 to 10 parts by weight of the active compound of group (25), 0.2 to 50 parts by weight, preferably 1 to 20 parts by weight are applied per part by weight of the active compound of formula C0. The active compound composition according to the present invention has good fungicidal properties and can be applied to control phytopathogenic fungi, such as rhizobium, oomycete, chytrid, zygote, ascomycete, and basidiomycete g nets, semi-known bacteria steel and so on. The active compound composition according to the present invention is particularly suitable for controlling cereal diseases, such as powdery mildew, Puccinia, and Fusarium, and for controlling diseases required for viticulture, such as Lepus , Uniaxial emblem and Botrytis, and also in dicotyledonous crops suitable for controlling white powder and downy mildew fungi and organisms that cause leaf spots. The present active compound composition has good to good results for the plant at the concentration required for controlling plant diseases, allowing treatment of above-ground parts of the plant, breeding crosses and seeds, and soil. The active compound composition according to the present invention is suitable for use in leaves, otherwise it is a fertilizer for seeds. The active compound of the present invention can be converted into conventional formulations, such as solutions, emulsifiers, suspending agents, powders, foaming agents, pastes, granules. This paper size applies Chinese National Standard (CNS) A4 specifications ( 210X297 mm) (Please read the notes on the back before filling out this page) Order A7 _ B7 V. Description of Invention (l9) Employees of the Central Standards Bureau of the Ministry of Economic Affairs, Consumer Cooperatives, printed granules, gas-soluble and stored in polymers Substances and microcapsules coated in the composition for use in seeds, as well as ULV formulations. These formulations are manufactured in a known manner, for example by combining the active compound or active compound composition with an extender, i.e. a liquid solvent , Liquefied gas under pressure «, and / or solid 艟 loading and mixing, and if necessary, use surfactants, that is, emulsifiers and / or dispersing 及, and / or foam forming 剤. If the expansion agent used is water, It is also possible to use, for example, organic solvents as auxiliary solvents. Basically, suitable liquid solvents include: aromatics such as xylene, toluene or alkylnaphthalene, chlorinated aromatic or gasified aliphatic hydrocarbons, such as gaseous benzene, Hexene or dichloromethane, aliphatic hydrocarbons, such as cyclohexane or paraffin, such as petroleum fractions, yeasts, such as butyrate or oxalase, and their ethers and islands, ketones, such as acetone, methyl 6-based amine, methyl isobutyl ketone or cyclohexanone, strong polar solvents, such as dimethylformamide and dimethyl sulfenamide, otherwise it will be water. Liquefied gaseous extenders or carriers are known as meaning Liquids that are gaseous at ambient temperature and atmospheric pressure, such as propellants such as butane, propane, nitrogen, and carbon dioxide. Suitable ship carriers are ground natural ores, such as white clay, clay, talc, white Minerals, quartz, green slope, montmorillonite, and diatomaceous earth, as well as milled artificial ore, such as finely divided silica, aluminum halide and silicate. Suitable for solid loading of granules «for example: Crushed and classified natural rocks, such as calcite, marble, pumice, sepiolite, and dolomite, or coarse inorganic and organic stone powders, and organic particles, such as wood chips, coconut, maize cobs, and tobacco handles. Suitable emulsifiers and / or foam forming: Non-ionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty group ethers, such as alkylaryl polyethylene glycols, alkyl sulfonates, alkanes (please read the notes on the back first (Fill in this page again)

, 1T 21 paper > ^ Shicaiguan) Six 4 threats (210X297 mm) V. Description of invention (2) A7 B7 Printed base sulfate and aryl sulfonate by the Consumer Cooperatives of the Central Standardization Bureau of the Ministry of Economic Affairs , Otherwise it is a protein hydrolysate. Suitable dispersants are, for example, lignin-sulfite waste liquid and methyl oryzanol. Gummy sticks, such as carboxymethyl cellulose and natural and artificial polymers in the form of powders, granules, or milk crusts, such as gum arabic, polyvinyl acetate, and polyvinyl acetate, or else natural phospholipids, such as phospholipids and sea bass Lipids, and artificial phospholipids that can be used in the formulation. Other additives can be mineral and vegetable oils. Possible colorants, such as inorganic pigments, such as iron oxide, titanium dioxide, and Prussian tincture, and organic dyes, such as alizarin, argon, and metal phthalocyanine dyes, and micronutrients, such as iron, shovel, Boron, steel, cobalt, surface and zinc SI. General gratitudes include active compounds between 0.1 and 95% by weight, preferably between 0.5 and 90%. In this formulation, the active compound composition according to the present invention can be used as other known active compounds, such as fungicides, insecticides, acaricide steels and herbicidal steels, and as fertilizers or plant growth Mixture of conditioners. The active compound compositions can be used in the form of, for example, their own formulations or prepared therefrom, such as ready-to-use solutions, emulsifiable concentrates, emulsifiers, suspended dishes, wettable powders, soluble powders, and granules Agents "are used in conventional ways, such as by wetting, spraying, spraying, scattering, coating, and as a powder for dry seed treatment, as a solution for seed treatment, as a water-soluble powder for seed treatment, as a water-soluble Sex powders are used in aging plasma treatments, or by gifting. When using the active compound composition according to the present invention, depending on the type of application 22 This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297), (please read the precautions on the back before filling this page)-· 香 五、 Explanation of the invention (21) A7 B7 Printed by the Central Ministry of Economic Affairs, the Ministry of Economic Affairs and the Consumers' Cooperatives ", and its application level can be changed in a relatively wide range. When treating plant parts > Generally the active compound The dosage of the composition is between 0.J and 10,000 g / m, preferably between 10 and 1000 g / ha. When treating seeds, the dosage of the active compound composition is generally between 0.001 and 50 grams per kilogram of seed, and more preferably between 0.01 and 10 grams per kilogram of seed. In the treatment of soil, the dosage of the active compound composition is generally between 0 and 1 and 10,000 grams per hectare, preferably between 1 and 5000 grams per hectare. From the examples below, it is clear that the active compound combination according to the present invention Good fungi fungicidal activity. However, the respective active compounds exert weak effects on fungicidal activity, and the activity of their compositions exceeds that of a simple addition. When the fungicidal activity of the active compound composition exceeds the combined activity of the active compounds for the respective monuments, the synergistic effect of the fungicide must occur. The expected activity for a given combination of two active compounds can be calculated as follows (cf. Colby, SR "Calculating Synergistic and Antagonistic Responses to Herbicide Shot Compositions", Weed 15_, (1967), 20-22 ) »If X is the effect when the active compound A is applied at a dosage of 1 g / ha, Y is the effect when the active compound A is applied at a dose of rick / ha, and E is when the dosage is up to And the effectiveness of the application of active compounds A and B in grams per hectare, then standard 23 (CNS) A4 (210X297 mm) --------- ^ # 4 ^ .------ order- ----- Guang, (please read the note # ^ on the back before filling this page) A7 ____ B7 V. Description of the invention (22) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs = Ⅹ + +-^- 1 100 potency is calculated in%. 0% is the potency corresponding to the control group, while 100% potency means that no infection was found. If the actual fungicidal activity exceeds the calculated value, the activity of the composition is Super-addition, ie there is synergy. In this example, the actual observed effect must be greater than the one calculated from the above formula Periodic Efficacy Value (E). The following examples illustrate the invention. Implementation "Phytophthora test (tomato) / Protective solvent: 47 parts emulsifier by weight of acetone, and 3 weight by alkylaryl polyethylene glycol ether 3 Parts are for the preparation of suitable active compounds, 1 part is mixed with the promising solvent and emulsified glucose content by the weight of the active compound or active compound, and the concentrate is diluted with water to the required concentration, or commercially active The compound or the compound composition is diluted with water to the required concentration. In order to test the protective activity, the young plant is sprayed with the dosage of the active compound mentioned above, and after being spray-dried and dried, the plant is inoculated An aqueous spore suspension of Phytophthora infestans. This plant was then placed in an incubator at about 20 t and 100% relative atmospheric humidity. "To be evaluated after 3 days of inoculation" 0% means the efficacy corresponding to the control group 100% efficacy means that no infection was found. Active compounds, dosages, and test results are shown in the table below. 24 This paper is sized to the Chinese National Standard (CNS) A4 210X297 gong) (please read the note f on the back before filling out this page), order A7 B7 V. Description of the invention (23) Table 1 Phytophthora test (tomato) / Protective active compound Active compound dosage per gram / Hectare effectiveness is known in%

0.2 6514

10.2 76 37

.S—CCLF S〇-N (CH3) 2 (IVa) Printed by H3C (IVb) ~ Qn · ', s—cci2f' S〇2-N (CH3) 2 26 S ' .Mn (VHc) 's' One: Zn 17

H S (Please read the notes on the back before filling this page)

This paper size applies to China National Standard (CNS) A4 (210X297 mm) A7 B7 V. Description of Invention (24) Table 1 (continued) Phytophthora test (tomato) / Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Protection Active compound dosage of active compound per g / ha potency 96 s CH, s [[Zn_s | NH_CH2—iH3_NH— (VI) 2 58 ο (Q ^ Jn-s-cc.3 II 〇 (XIX) 2 12 L〆 \ 〇 」3 Al (XX) 2 36 ch3 ch3 (XVIa) 1 0 ch3 cw 疋 (XVIb) 1 0 CN H3CO A ^ OCH3 (XII) ° 0.2 51 ____26_ This paper size applies to Chinese national standards (CNS> A4 specifications ( 210X297 mm) II —I II Order II i 11 V ~ (Please read the notes on the back before filling this page) A7 B7 Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (25) Table 1 ( Performance) Phytophthora test (tomato) / protection

Active compound dosage of active compound per g / ha potency%% h3co, c / ^ n / 〇ch3 (XIII) 0.2 0 ％ (XIV) 1 27 / -Λ Π / 0 ~ C, 〇NC-CH two C v_y \ < ^ \-〇ch3 (XVIII) OCH3 0.2 0 〇〇CN CH 「CH「 NH 」-nhXUCH3 (XV) 0.2 0 pul CH, WCH3 iH-COOCH3 (v < c-ch2-o-ch3 ch3 ( xvi i) 0.2 0 — 7T (Please read the notes on the back before filling this page) Order K.). This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) A7 B7 V. Description of the invention (26 Table 1 (Performance) Phytophthora Test (Tomato) / Protection

Active compound effectiveness application rate by% in g / ha 0.2 (XXIV) (Please read the precautions on the back before filling this page)

1 0.2 0 0 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 0 CH (CH Hill II I 32 (CH3) 2CH-〇-C-NH-CH-C-NH-CH 0 CH. (IX) l! \ ~ If \ -〇-CH—CH—C (CH3) 3 — 4 (lie) N 0.2 24 OH Cl — ^ ~ y-CH2-CH2-C —C (CH3) 3 (j: H2 0.2 0 (, < x jrx fi Cl — 《〉 — 〇—CH (CC3) 3 0.2 0 (»a) \ l 1 J2 & _ The size of the paper is applicable to Chinese National Standard (CNS) A4 (21 OX297 mm)

Employees 'Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs of the People's Republic of China II A7 B7 V. Description of the invention (27) Table 1 (continued) Phytophthora test (tomato) / protective active compound active combination' Dosage by g / ha Effectiveness by% c, -〇- (llb) OH 〇- CH—CH— & 0.2 0 Cl CHrC- ^ Z-CI CH0 1 2 0.2 0 (XXI) < VS LNH (CH3) 3C-/ _ (XI) C3H7-n 0.2 5 Q c II _ ^ γλ —C-NH—T OH ^ C | HC | 5 0 (VIII) (Please read the precautions on the reverse side before filling out this page) 29- This paper size applies to China National Standards (CNS ) A4 specification (210X297 mm) A7 B7 V. Description of the invention (28) Table 1 (continued) Test of Phytophthora (Tomato) / Protective active compound

CI > dosage of active compound per g / ha potency per% 〇

} _ (Please read the notes on the back before filling this page) Order CH, (Vb) (1: 1-mixture)

Experimental value Calculated value *) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs According to the present invention:

(1:10)

(1:10)

54 14

55 37 This paper size applies to Chinese national standard (CNS > A4 size (210X297mm) i A7 B7 V. Description of invention (29) Table 1 (continued) Phytophthora test (tomato) / Ministry of Conservation and Economics Central Standard Rate Bureau Consumer Consumption Cooperative

(Read the precautions on the back before you fill in this page) This paper size applies Chinese National Standard (CNS) A4 specification (210X297 male thin) Order " A7 B7 V. Description of invention (30) Table 1 (continued) Phytophthora Test (Tomato) / Protection | Active Compound The active compound dosage is in grams per hectare of Efficacy in% (Xl ^ OJ (1:10) 〇1 \ 'Poor test value calculated *) 71 45 (IbTl 〇ΞΊ +) + > 83 60 (XX) J (1:10) 2J — 69 37

(1: 5)

(Please read the notes on the back before filling this page)

, 1T

Employees' cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs of the People's Republic of China printed A7 B7 V. Description of the invention (31) Table 4 (continued) Epidemic test (tomato) / protective active compound : 1) 〇 £ J Experimental value 75 Calculated value *) 37 (.aTl 〇Ξ \ +) +〉 73 37 (XIV) J (1: 5) ~ I (lb) l 02! +) + ≫ 75 54 (XINOJ (1: 5) OaTl 0Τ21 +) + > 46 14 (XVIII) '[0.2 j (1: 1) (IbTl (λ2ΐ + > +) 81 37 (XVIII) j 0.2 [(1: 1) -1 —] (la) l 0.2 I +) + > 56 14 (XVOJ ° II I (1: 1) (Please read the notes on the back before filling this page) Order f: _; _ 33_ This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) A7 B7 V. Description of the invention (32) Table 1 (Performance) Test of Phytophthora (Tomato) / Protective Active Compound

(乃 (X ^ J (1: 1)

(1: 1) Active compound dosage per gram / ha

Effectiveness Calculated as% experimental value 67 37 73 (Please read the precautions on the back before filling in this page)

_; _ 34 This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) Employees' Cooperatives Cooperative Printing Co., Ltd. A7 B7 of the Ministry of Economic Affairs 5. Description of the invention (33) Table 1 (Performance) Phytophthora test (tomato )/protection

(Please read the notes on the back before filling this page) Order _; _15_ This paper size applies to China National Standards (CNS) A4 specifications (210X297 mm) A7 B7 Printed by the Employees' Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs

V. Description of the invention (34) Table 1 (Performance) Phytophthora test (tomato) / protection Please read the precautions of S before filling in ^ Birds The dosage of active compounds of this active compound is in grams per hectare, and the efficacy is in% ( IbH (II ^ J (1: 1) ° ii Experimental value calculated *) 75 37 | (Ia7! 0.2 1 ί 1 I + S + > 51 14 1 I (XXI) ί 〇ii 1 1 (1: 1 ) 1 | (ib) l 〇Tl order +) + > 69 37 1 I (xxoj 0.2 f 1 |. (1: 1) 1 I (laTl 〇ΐ \ 1 1 + > +) 67 18 product (XLJ 0.2 [Ί I (1: 1) 1 1 1 (lb) ~ l 〇 " ΤΙ 1 1 + > 87 40 I ° ^ J 1 1 (1: 1) 1 1 (laTl Η 1 I + >- > 90 65 1 I (VIII) J 1 1 (1: 5) 1 1 16 I This paper size applies to China National Standard (CNS) A4 (210X 297 mm) Employees' Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs, Consumer Cooperatives, India and India A7 B7 V. Description of the invention (35) Table 1 (continued) Phytophthora test (tomato) / protection

Experimental value = calculated value of experimental result = calculated value using Colby formula (#Read the precautions on the back before filling this page) _; _π_ This paper size applies to China National Standard (CNS) A4 (210X 297) (%) \ A7 _B7 V. Description of the invention (36) 耆 Example 2 Snow rot test (triticale) / seed treatment The active compound is applied as a coating for dried seeds. These Russian systems produced minerals in the form of crushed powder by healing the expanded active ensemble of the respective active compounds 4 and grinding them to obtain a crushed powdery waterfall compound to ensure that they can be evenly distributed on the seed surface. To coat the seeds, shake the infected seeds together with the seed coating in a sealed glass Erlenmeyer flask for 3 minutes. Triticale 2x100 was sown in standard soil with a depth of 1 cm, and cultivated in a greenhouse and a seed shallow box at a temperature of about 10 ° c and about 95% relative atmospheric humidity, and received a light specification of 15 hours a day-ready for sowing About 3 weeks later * the plant signs are evaluated. 〇% means the efficacy corresponding to the control group, while efficacy means that no infection was found. The active compounds, dosages and test results are shown in the table below. (锖 Please read the note $ on the back before filling in this f) Customs Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs printed a suitable standard M 38 I centimeter 97 2 Β7 V. Description of the invention (37) Table 2 Snow rot sickle Spore test (tritical wheat) / seed treatment Active consumer compound printed by the Central Bureau of Standards of the Ministry of Economic Affairs. The amount of active compound printed is mg / kg of seed I. The potency is 96. Known: (la) 100. 26 (lb) 500 0 100 0 (XXII) 100 0 (IX) 500 0 (Vile) 100 0 (IVb) 100 3 Mixture of Roots Wood Invention: (la + Vile) (1: 1) 50 + 50 66 (Ib + XXII) (1: 1 ) 50 + 50 36 (Ib + IX) (l: l) 250 + 250 43 (Ib + Vile) (1: 1) 50 + 50 32 (Ib + IVb) (l: l) 50 + 50 75 (please first (Read the notes on the back and fill out this page)

> 1T quasi-staircase country and middle school with moderate ruled paper on paper centimeters 97 > 2 Α7 Β7 V. Description of the invention (38) f application 3 Fusarium test (Sfe bean) / seed treatment Apply the active compound as dry Seed coating. These are prepared by expanding the respective active compounds into active compounds / 6 ## 余 合 教 with ground minerals to obtain a finely divided powdery mixture to ensure that it can be evenly distributed on the seed surface. To coat coriander seeds, shake the infected seeds together with the seed coating in a sealed glass Erlenmeyer flask for 3 minutes. Seeds of 2x50 were planted in a pile with a depth of 2 cm. The soil was naturally infected by Pythium and was grown in a shallow box of seeds in a greenhouse at a temperature of about 20 ° C. Each day received a light specification of 15 hours. Evaluation will take place after 14 days. 0% means the efficacy corresponding to the control group, while 100% means that no infection was found. The active compound, dosage and test results are shown in the table below. (Please read the note on the back before filling out this page), ιτ Printed by the Central Bureau of Standards of the Ministry of Economic Affairs, Printed by the Cooper ’s Cooperative, 40 This paper size applies to the Chinese National Standard (CNS) A4 (210X297 mm) Central Standards Bureau of the Ministry of Economic Affairs Employee Consumer Cooperative Cooperative A7 B7 V. Description of the invention (39) Table 3 Humus test (pea) / seed treatment active compound Active compound dosage per mg / kg seed potency in% Known: (la) 500 1 (lb ) 1000 4 (Vile) 1000 8 (IVb) 1000 42 500 37 The mixture according to the invention: (Ia + IVb) (l: l) 250 + 250 55 (Ib + VIIc) (l: l) 500 + 500 38 ( Ib + IVb) (l: l) 500 + 500 59 (Please read the notes on the back before filling in this page) τ-- °-疒 ___ 41- This paper size applies to China National Standard (CNS) A4 specifications (2 丨0'〆297 mm)

Claims (1)

Scope of patent application 〇-CH-Y-C < CH3) 3 A8 B8 rc Patent Application No. 87105036, ROC Patent Appln. No. 8710503 Amended Claims in Chinese-Encl. I (戾 国 _ Submitted on November 18th, 2010) Submitted on November 5, 1999 ^ ^ 1. A fungicidal composition characterized by containing a halogen-benzimidazole of the formula z where Z represents gas or bromine, and (1) a triazole derivative (II) having the formula: where X represents gas or phenyl, and n I nnnn _ nn — > m · n It 1 iBi ϋ IV Jf (Please read M. Please read the notes on the reverse side before filling out this page.) Y representative or-CHO or (2) a triazole derivative with the following formula 42 —CH-l OH is printed by the Intellectual Property Bureau of the Ministry of Economic Affairs ’Consumer Cooperatives. Applicable to Chinese National Standards (CNS > A4 specifications (210 * 297 mm) OH CH2—CH2—C—C (CH3) 3 CH, (III> · or (toconazole) (3) Aniline derivative of the formula R , S-CCI2F 'SO—N (CH3) 2 CV). 1 ..___ »__ II ------IIC (Please read the note on the back before filling this page) where R1 represents hydrogen or methyl, Or (4) N- [1 · (4-Gas-phenyl) -ethyl] with the following formula: -2,2--3-methyl-cyclopropane · carboxamidine · c 丨 ~ ^ ^- CH- NH-C-II CH, 〇 Cl, Cl -Η c2h5 ch3 (V). Line · Printed by the shellfish consumer cooperation of the Intellectual Property Bureau of the Ministry of Economic Affairs or (5) propylene_1,2-bis (dithiouric acid) with the formula Γ3 ^ —C —NH—CH ^ bCH * ~ NH —C—SJ— (VI) η > (Propinabine) 43 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 6. Apply for a patent Range or Revelation 0808 (6) At least one thiamine formate S / Me (VII), HS Me = Zn or Mn or Zn and Mn (zeolite or (7) aniline derivative with the following formula物 c-NH—ν y— CH, Μ Cl Cl (VIII) (fenproxamine) (Please read the precautions on the back before filling out this page) or (8) a compound of the formula 〇〇ch < ch3) 2 (CH3) 2CH-〇-C-NH-CH-C-NH—CH— ^ / —CH3 II 〇I CH, (IX) or (9) Benzothiadiazole derivatives with the formula Printed by property consumer cooperatives or NUN (X) (benzene dicarbide) 44 This paper size is applicable to China National Standard (CNS) A4 (210 * 297 mm) A8SC8D8 6. Application scope (10) 8-Third-Butyl- 2- (N-ethyl-N-n-propyl-amino) -methyl-1,4-dihumo [5,4] -decane (CH3) 3c ° CH, —N:, c2h5, C3H7-n (XI) (spirosamin) or (11) a compound of the formula f — If! ) (XII) 〇 Called (Sulfurized Azo Division Consuming Bin) 1SJ. Or (12) Compounds with the formula , 〇CH, or (13) Compound 45 (XIII) (Krisme-Methyl) with the following formula: This paper is applicable to National Standard (CNS) A4 (210 X 297 mm) Range A8 B8 C8 D8 Cl (XIV) or (ii) an oxime derivative of the formula: IIII CH3-CH-NH-C-NH-C CN -C = NOCH (XV) (Sermosani) or (15) with the formula Pyrimidine derivative CH, where N: R2 represents methyl or cyclyl (XVI), ulilr — — — — — — — — — — — — II > — — — — — I < Please M (Please read the note on the back and fill in this page) or printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (16) Aniline derivative CH with the following formula, N: XH—COOCH, CH, CH3 'C-CH5-O—CH, II 〇 (XVII) (malacil) 46 This paper size applies to the Chinese national standard < CNS > A4 (210 X 297 mm) 385232 A8B8C8D8 6. Does the scope of patent application or (17) have the following formula? Forest derivatives 〇II 〇 'N-C-CH (XVIII) (dimethoxymorph) or (18) a phthaliminoimide derivative having the formula 〇 -C〇3 (X / X) (Fupert) or (19) Phosphorous acid compound HsC2〇, • ο Ό (XX) Economy, Ministry of Intellectual Property Bureau, consumption cooperation, printed by (Ethyl-A1) or (20) Hydroxyethyl-triazole derivative 47 This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 male «) 3B5332 A8B8C8D8 VI. Patent application scope ch2 < VS (XXI) or _NH (21) with the following formula l-[(6- 气- 3-Methylpyridyl) -methyl] -N-nitro-2-imidazolidinimine Cl N ϊ-Ν〇, (XXII) (Mida Gas Pride) aBB ·-·· 1 n amae ϋ I 0 a ^ in (please read the notes on the back before filling this page) or (22) Humazolidinedione (XXIII) (Cumin today " Ming) · " ---- Line · Printed by employee consumption cooperation of Intellectual Property Bureau of the Ministry of Economic Affairs or (23) Phenylamine derivative CI Η3φΐ Cl NH-CC— CH2CI c2h5 Ο (XXIV) -1. Or 48 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 2 3 2 5 8 3 A8SC8D8 VI. Application scope (24) Guanidine with the following formula Derivative R ° N— (CH2) 8— [N —— (CH2) eJ—N—Η Π χ (2 + m) CH3COOH (XXV) where m represents an integer from 0 to 5 and R3 represents hydrogen (Π To 23%) or a free radical of the formula -C diNΗI ΝΗ, (77 to 83%) or (25) a triazole derivative having the formula (XXVI) (Please read the notes on the back before filling in this page)-Packing, Γν Order: 〇 Line. Active compound combination printed by Pengcong Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs Thing. 2. The composition according to item 1 of the scope of patent application, characterized in that the active compound composition has a weight ratio of the active compound of formula (I) to the group ⑴ active compound of 1: 0.1 to 1:20, and the group (2) The weight ratio of the active compound is 1: 0.1 to 1:20, the weight ratio of the active compound in group (3) is 1: 1 to 1: 150, and the weight ratio of the active compound in group (4) is 1: 0.1 to 1: 10, 49 This paper uses national standards (CNS) A4 specifications (210 χ 297 mm) A8 B8 C8 D8 3S5232 6. Application scope-Group (5) weight ratio of active compounds is 1: 1 to 1 : 150,-The weight ratio of the active compound of group (6) is 1: 1 to 1: 150,-The weight ratio of the active compound of group (7) is 1: 0.1 to 1:50 ''-of the active compound of group (8) The weight ratio is 1: 0.1 to 1:50,-the weight ratio of group (9) active compounds is 1: 0.02 to 1:50 '-the weight ratio of group (10) active compounds is 1: 0.1 to 1:20,- The weight ratio of the group (11) active compound is 1: 0.1 to 1:50, the weight ratio of the group (12) active compound is 1: 0.1 to 1:50, and the weight ratio of the group (13) active compound is kO. l to 1:50,-group (14) live The weight ratio of the compounds is 1: 0.1 to 1:50, the weight ratio of the group (15) active compounds is 1: 0.2 to 1:50, and the weight ratio of the group (16) active compounds is 1: 0.1 to 1:50 -The weight ratio of the active compound of group (17) is 1: 0.1 to 1:50, the weight ratio of the active compound of group (18) is 1: 1 to 1: 150, the weight ratio of the active compound of group (19) is 1: 0.1 to 1: 150,-the weight ratio of the active compound in group (20) is 1: 0.02 to 1:50, • the weight ratio of the active compound in group (21) is 1: 0.05 to 1:20, • group (22 ) The weight ratio of the active compound is 1: 0. 〖To 1:50,-the weight ratio of the group {23) active compound is 1: 0.1 to 1:50 '-the weight ratio of the group (24) active compound is 1: 0.02 To 1:50, the weight ratio of group (25) active compounds is 1: 0.2 to 1:50. 3. A method for controlling fungi, characterized in that the active compound composition according to item 1 of the scope of patent application is applied To the fungus and / or its habitat. 50 This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) Liju ΓΙΙΓ! — — — — IIII-✓fv (Please read the notes on the back before filling this page) Ministry of Economy Intellectual Property Bureau employee consumer cooperation number 385232 0q0Q88 AKCD VI. Patent application scope 4. A method for preparing a fungicidal composition, which is characterized by combining an active compound combination with a synergist and / or according to item 1 of the patent application scope Surfactant mixing. Please read the note on the back first and then on this page)-Install kSJ • Line · Ministry of Economic Affairs, Intellectual Property Bureau, Tooling and Consumer Cooperation X 297 mm)