TW384553B - Process for recovering organic hydroxides from waste solutions - Google Patents

Description

Printed by the Central Standards Bureau of the Ministry of Economic Affairs® C Industrial Consumer Cooperative A7 B7 V. Description of the Invention (\) Fangjie Oven This invention is a method for recovering organic hydrogen compounds from waste solutions. In particular, the present invention is a W-type method for recovering organic argon oxides. Including the step of the battery and the salt sinking beach. The step of removing the gold sacrifice "or including > 4 size optional partitions or sizes. «Waist-in-steps" one of the famous medical quaternary ammonium hydroxides such as Tetramethylammonium (TMAH) and Tetraethylammonium Oxide (TEAH) are strong organic compounds. ; ≫ Various uses of the quaternary ammonium hydroxide have been discovered, including as a titrant of the acid in organic solvents # as a branch in polarography »« Solution of quaternary ammonium 丨 aqueous solution of quaternary ammonium fi oxide丨 TMAH solution in particular: It has been widely used as a photoresist developer for printed circuit boards and micro wafers. For various reasons, I hope to minimize all of the color chips used in printed circuit boards and microchips. One method of minimizing the total amount of hydride developer is to reuse the waste developer / however, the waste developer contains these including falconium and non-dipper impurities. Ion androgenic substances include gadolinium ions such as sodium, potassium, zinc, and calcium, and deionizing agents such as halides, nitrates, carbonates, carboxylates, sulfates, and non-ionic males. Agents, amines, and a large number of other organic molecules, r waste development fl! Also contains a lower concentration of hydrogenated developer η. Therefore, it is still necessary to effectively recover the fi gas development in a usable manner so that it can be used. Reuse • to minimize the amount of filming agents used in the printing of "road boards and" «sub-chip manufacturing. This paper size is applicable to China National Standard (CNS) A4 specification (2 丨 〇 X 297 mm) )

V * ϋ 上 二 — …… < ·· ^ ‘· j—-’. ~~ ^ ― (Please read the note on the back before filling this page)

, 1T

丨 thorn. C Printed by the Central Bureau of Standards, Ministry of Economic Affairs, Shellfish Consumer Cooperative, printed A7 ΒΊ_5. Description of the invention (>) Beautiful Circle No. 4,714,53 0 »(Hale and his research colleagues) describe a method of preparing high-quality According to the "solution method" of tritium oxide: it uses a cathode containing a cathode separated by a separator exchange membrane «solution solution 酽,» and »electrode solution M 霣 pond f. This method involves the quaternary ammonium hydroxide Aqueous solution is fed to the electrolyte solution compartment; water is added to the catholyte solution compartment, and the DC power is used to decompose the battery, and the fourth stage of the relatively pure purity is recovered after generation of tritium in the electrolyte compartment. Press hydroxide. > The '530' also describes an improvement 'which comprises heating the quaternary ammonium hydroxide at a high temperature before feeding the radon gas to the radon polar interval of the tritium bath. Meipu No. 4,9 38,854 (Sharifian and colleagues in his research) also described a method for purifying quaternary ammonium argon oxide by reducing the content of potential compounds. The decomposing bath is divided into the 隈 electrode liquid interval by a separator plaque which can be an anion or hidden ion selective membrane, and the cathode 霣 solution interval t is divided by the cathode 锌 液 cadmium, v tin ,, lead, ytterbium or titanium., Or its alloys, li or recorded? Japanese Public Lecture No. 60-13198 5 (1985) (1 & 1 ^ 810 and its research colleagues) describes a method of manufacturing in an electrolytic cell that is exchanged by a stupid child @ divided into »a pole chamber and a pole chamber A method for high-intensity tetraammonium argon oxide. . Feed the quaternary ammonium phosphonium oxide solution containing tribute to the dysprosium chamber and supply DC dysprosium between the two dysprosiums after the water is fed into the hibiscus chamber? Obtained purified quaternary ammonium argon oxide from the hibiscus chamber? The purified fourth-grade technical hydroxide contains a reduced amount of _Jin Yang · _ Tujin, yin_zi and so on. * '«» Economy 110 Woben Binding. Binding-This paper size is applicable to China National Standards (CNS) Α4 size (210X297 mm). Printed by A7 B7, Cooper Cooperative of Central Bureau of Standards, Ministry of Economic Affairs. Explanation of the invention (,) In one example, the present invention is a method for recovering organic hydroxide from a solution containing organic hydroxide and impurities / including: Complete (Ala-Alb) One of (A2) and (A3), (Ala) precipitates organic argon oxide from the waste cable solution as an insoluble salt, and (Alb) removes the insoluble salt from the waste cable solution and places the salt in a liquid solvent To form a second solution ^ (A2) or (A2al) feed the waste solution into a first tritiated cell including at least two intervals, a cathode, a pole, and a size-selective separator, * and The flow is passed through the first chemical cell. By this, impurities are migrated through the size-selective separator (A2a2) to recover the second solution containing eaves ions from the first electrochemical cell or (A2bl) to form The first solution of gun salt and miscellaneous solution (A2b2) Membrane contact, · At least a part of the impurities are selected by a size-selective membrane, and a second solution containing a tungsten salt and a reduced amount of impurities is provided; (A3) The waste solution is brought into contact with the gold embroidery 淸In order to remove the impurities of the golden eagle, where steps "(A3) in steps" (B) and (C) are completed before or after 9 (B) the second solution obtained from (Alb) is obtained from (A2a2) Or the second solution of (A2b2) or the waste solution obtained from (A3) is fed to a paper size containing at least two papers, using Chinese National Standard (CNS) A4 specifications (21 OX 297 mm) (please read the back first) Please fill in this page for the $ item) oi Assembling and ordering 丨 —Line A7 B7 _ V. Description of the invention (w) Separate * * a cathode '-Separate the first electrochemical cell in the hibiscus and the separator, and pass it through. The first electrochemical cell is then regenerated with tritium hydroxide, and (C) the eaves hydroxide is recovered from the first cell. In another example, the present invention is a method for recovering organic radon gas from a waste cord solution containing organic hydroxide and radon, which includes the following steps: The hydroxide is used as an insoluble SR to remove the salt from the waste solution and place the salt in a liquid solution to form a second solution; the second solution is fed to a solution containing at least two intervals Neutralization of the electrochemical cell with the separator and separator will pass tritium to the side cell, thereby regenerating the organic hydroxide / and recovering the organic argon oxide from the cell. In another example, the present invention is a method of recovering rust hydroxide from a waste solution containing gun argon gas # and impurities / including the following steps: Osmic acid was added to the waste cable solution while the beach water-insoluble fin cricket was removed; the osmium salt was removed from the sleeping solution and the gun was placed in a liquid «to form a second solution. At least three intervals •, a cathode • a methane cell with a single electrode and two plutonium separators and a plutonium circulation tank, a regenerative gun hydrogenate; and a gun argon gas recovery from the plutonium tank Compound ... In still another embodiment, the present invention relates to a method for recovering quaternary tritium oxide from a waste solution containing tetrahydroxide hydroxide and tritium, including the following steps. In the precipitation of four, grade hydroxide as water-insoluble 鼸 彳 will be obtained from the waste cable solution of the quaternary 鼸 added to a liquid "in this way to form a second solution i feed the second solution to contain at least two intervals. , A paper size applies to the China Solid State Standard (CNS) A4 specification (210X297 mm) (please read the note on the back before filling in this purchase) Printed by the Consumer Cooperatives. Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives. A7 _B7_ V. Description of the Invention (s) Cathode ·,》, and the separator and the decontamination of the pond and the flow through the pond., Here Regeneration of quaternary hydroxides in hyenas and recovery of quaternary hydroxides from batteries. In another example, the present invention relates to a method for recovering from a contaminated solution containing organic argon oxide and impurities. Method for recovering organic argon oxide, including the following steps: will be polluted The solution is fed to the first electrochemical cell containing at least two valence intervals. One cathode: one hibiscus and size β volatile matter. The first battery will meet the first battery: the toad will migrate through Volatile separators; from the first electrochemical "recovering a second solution containing organic chicks and feeding the second solution to a solution containing at least a bivalent barrier · a cathode * a" hibiscus and * «the second separator Neutralization of the electrochemical cell will pass through the second electrochemical cell, thereby purifying the argon oxide; and recovering the organic argon oxide from the second electrochemical cell. · In another embodiment > The present invention is a method for recovering gun hydroxide from a contaminated solution containing iridium argon gas and impurities including the following steps: t feed the contaminated solution to a At least two separators, * one pole, one pole, and one size-selective ion, "the first ion-selective ionizer" that neutralizes the battery and passes the current through the first cell: _ This metal ion is mixed through the large and small electrodes. Selective ion-selective membranes; recover the second solution containing tungsten chicks from the first tritium m pool and feed the second solution to at least two intervals t, a negative stage, a carved stage and a separator The second «Chemical Pond and Circulation» No. «Second Dimensional Chemical Plutonium Pond to purify the surface hydroxide; and the gun hydroxide was recovered from the second Chemical Plutonium Pond. % This paper size is in accordance with Chinese National Standard (CNS) A4 specification (2 丨 0X297mm) (Please read the note f on the back before filling out this page) V. Description of the invention (t) In still another embodiment, the present invention is a method for recovering fin argon gas from a contaminated solution containing thorium oxide and impurities / including the following steps: The first solution of gun salt and toadstool is formed from the contaminated itch solution; the first solution is contacted with the size "volatile film of which at least under room force"

A part of the maggots has a large size «Effectiveness» This provides a second solution containing rust H and a reduced amount of arsenic .; The second solution is fed to contain at least two interlayers. Hurricanes and separators in the galvanic cell and through the cell • This way tungsten tungsten thorium oxide is recovered; and the table is recovered from the battery * Hydrogenation 丨 In a solid salting example: the present invention The invention relates to a method for recovering eaves hydroxide from a waste solution containing eaves oxide and impurities / including the following steps :, followed by "removal of waste solution and metal chicks to remove metal ion species; 1. Dispose the waste cable solution to a tank containing at least two compartments, one to remove the four poles, one to the poles and the separator, and the rolls to pass through the pools, and then regenerate the eaves fi oxide I And «hydroxide ... In another embodiment, the present invention relates to a method for recovering gun argon gas from a waste solution containing gun hydroxide and thoron containing gold ion impurities. The method includes the following steps: contacting the waste solution and the ring Ether compounds, so as to reduce the amount of metal __ in the waste solution; feed the waste cleaning solution to an electrochemical cell containing at least two intervals and a depolarizer: Γ and neutralization of the electrochemical cell Pass the current through the pond. This tungsten ion is passed through the 1A hurricane sickle, the volatile film and the regenerating gun hydroxide; and the hydrogen hydride is recovered from the battery. -10- This paper size applies to Chinese national standards (CNS > A4 size (210X297 mm) (please read the note on the back before filling in this page) Preparation of A7 B7 V. Description of the invention (q) is still in another specific example. The present invention has "a method for recovering the hydrogenated supply from a waste cord solution containing eaves hydroxide and impurities." Including the following steps "丨 Waste Waste" liquid material to contain at least two M-a cathode, t-anode and the rest of the waste cell and pass the battery, the box of this organic chick through the separator And regenerating susceptible hydroxides; and recovering organic argon gas from batteries. Still in another specific embodiment * The present invention has a 从The method for recovering gun hydroxide in a high-quality waste solution includes the following steps: Including the following steps: 1. Disposing the waste solution into a tritium battery containing at least two spacers, a hibiscus, a separator, and a separator to neutralize Roll the plutonium through the plutonium. This gun ion will encounter the particles and Regenerate gun hydroxide; and recover fin-fi oxide from the limulus pond to contact the iridium hydroxide solution and cyclic ether compound K to remove gold yang sickle impurities; and recover male argon oxide. Result of the method of the present invention > Regeneration solution of regenerated organic hydroxide can be obtained, where the concentration and concentration are increased. The waste solution of regenerated organic rhenium gas not only provides cost savings, but also provides a solution for removing new synthetic hydroxide «compound solution and associated capital Purification method and environmental benefits required to reduce the toxicity of the effluent of the 8-line solution. After the organic hydroxide is removed from the solution, an increased amount of water can be recovered. In addition, there is no need to store large suspended chemicals. Via the present invention The organic hydroxide solution obtained at a relatively low concentration and purity can be effectively used in many applications in which the compound solution is important. (Please read the note f on the back before filling out this Page) d. · The size of the paper is applicable to the Chinese National Standard (CNS) A4 (210X297 mm). Printed by the Zhengong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A7 __B7__ V. Description of the invention (8 ) _1 is a kind of "E to garden display" containing one unit «Chi No. 2 interval electrochemical battery according to the present invention; _2 is a paper to display three battery cells according to the present invention. _3 is a type containing two army single cells戆 ister _2 of the unit of the unit of the unit of the unit of the unit of the unit of the unit «To show / _4 is a four 1« electrically isolated unit according to the present invention "To show 0 5 is another The “K” of a four-cell battery is illustrated. _6 is a schematic plaque of a unit battery containing two β_5 units according to the present invention. Boxing 7 is a bipolar sister cell containing two troops. The outline of the electrochemical cell stacked in the unit m pool of the face 2 / 鼷 8 is a kind of «Transformation of the Pool» to show the two units in the bipolar sister unit 霣 池. _9 is the "remark" of the other / one-three-three-dimensional electric-restricted electrochemical cell according to the present invention. Draw 10 is the «remark" of the present invention that includes a two-waisted unit Ao pond. _11 is a schematic illustration of a stacked electrochemical pool that includes a two-pronged tanning pool in a bipolar system. _1 2 is a schematic illustration of another tetramerization pond according to the present invention. -12- The standard of this paper is applicable to the standard of China and China (CNS > A4 specification (2 丨 OXW7mm i '' (please read the note on the back before filling in this page)). Order A7 B7_ V. Description of the invention (1) The eaves hydroxide can usually be represented by the special emblem A (OH) x (I) where A is a fluorene or an inorganic group and x is an integer equal to the valence of A; > "In the Examples" Rhenium hydroxide should be fully soluble in solution

For example, water, yeast, or organic liquid crocodile, or a mixture thereof M allows an effective recovery. In another embodiment, the present method is used to prepare «purified organic rhenium oxides such as quaternary argon oxide, quaternary phosphonium oxide and tertiary hydrazone hydroxide? Can these organic hydrides be collectively referred to as surface hydrides? In this and other specific examples, A is the androgen compound in the above formula (I), and formula (I) represents a tungsten hydride, and quaternary ammonium and tetrafluorene argon oxide can be represented by the following formula _ R2 +

I

RrA-R3 OH * Sichuan)

I R4 _ where A is nitrogen or "atom, Rt ,, R2, * R3 and Rt are alkyl groups containing 1 to about 20 carbon atoms, respectively. Hydroxyalkyl groups containing 2 to about 20« sulfonic atoms Or alkane alkyl. Aryl 圏 ·, japonica aryl groups: IU and 112 and A can form a 雑 «group together with A, but only if the 雑 · group contains C = A group \ -13 -_-Vi-. '·: .. This paper size applies to Chinese National Standard (CNS) A4 Circle (^^ x297mm). V. (Please read the note on the back before filling in this page)装 Ordering and printing printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7 5. Description of the invention (丨 G), then R3 is the second key. Examples include straight octyl, iso-titanium, and other different types, such as hydroxyalkane. Butane examples include more methods, or branching, including methyl, ethyl isooctyl, Nonyl, .hexadecyl alkyl groups and the like. Thai contains one to ten radicals. Alkylmethyl, butoxyphenyl, benzylhydroxyl group is derived or purified and contains 1 to 20 groups, propyl, butyl, decyl., Isodecyl and octadecyl plaque / such as Hydroxyethyl and hydroxypropane are preferably t-butyl and the like having an alkyloxyalkyl radical with a solid atom. Various Fang >, and equivalent base generation. Four-stage argon oxide

The special alkyl groups of the alkyl Ri to the IU ore atom, pentyl \ hexyl, heptyl \ *, dodecyl, tridecyl, R i 9 Rz, R3 and R4 are also methyl \ hydroxybutyl, In the case of hydroxypentyl, .R 1-IU radicals and special cells containing two to three carbon atoms include implementations of ethyl ethyl and hydroxyaryl rings * where the benzene ring has been * These can be represented by K in formula III according to the present invention.

RrN-R3 OH- (III) Printed by Crying Consumer Cooperatives, Central Bureau of Standards, Ministry of Economic Affairs R4 where Ri-R4 are as defined in Formula II. In a preferred embodiment, Ri reef -R4 is an alkyl group containing 1 to about 4 sulfonic atoms and a hydroxyalkyl group containing 2 or 3 valence broken atoms? Tetraammonium cyanide oxide most commonly converted in accordance with the method of the present invention 5 This paper is in accordance with Chinese national standards (CNS > A4 specification (2ί〇χ297 公 4 A7 B7) V. Description of the invention (\\ Specific examples of methylammonium (TMAH) or hydroxide include, trifluoroammonium gasification, trimethylhydroxyethyl tetrahydrogenation, tridihydroxyethylammonium hydroxide, Phenyltriethyl hydroxide, argon oxidation, f, dimethylpyrrole oxyoxidation, m-diisopropyl oxazoline gun, tritium quaternary scale hydroxide of type II which can be used according to the present invention The method is to purify tetraethyl ether, argon oxidation of tetrapropane, hydroxyethyl », argon oxidation of dimethyl dicyanocyanide to oxidize phenyltrimethylammonium hydroxide, cast hydrogen hydroxide, etc. 、 Hydroxymethylmethoxyethoxyethyl according to 丨 Hydroxybenzyltrimethyl »represented by N-alkylpyridine dimethyl hydroxide), including hydrogen peroxide oxidation of tetrabutyl ethyl scale, hydroxyphenyltriethyl and« (TEAH) .Ammonium, argon hydratium tetra-n-octylammonium, hydrazine oxidized phenyl trioxide, argon oxidized benzyl hexahydropyridine, etc. For example, where A 4 is oxidized during the casting phase of tetramethyl chloride, trimethylhydroxyl hydroxide and benzyl hydrogen are other tetraethylammonium hydroxide, dimethyldimethylammonium hydroxide, trimethylethyl, tritium gas = P (,, Trimethyl ethyl hydroxide scale, trimethyl methoxide (Please read the note on the back before filling in this page)

OI- 装. Order In another M embodiment 丨 these arsenic argon oxides can be purified according to the method of the present invention can be expressed by the following formula.

RrS * OH * (IV)

I r3 where Ri: R2 and Rs are alkyl groups containing 1 to about 20 valent carbon atoms, respectively.-This paper size applies to China National Standard (CNS) A4 specifications (21 (^ X297 Central Bureau of Standards of the Ministry of Economics and Work Printed by Consumer Cooperatives

A7 B7 Printed oxygen by the Central Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperative, 5. Description of the invention () 9 Contains 2 to about 20 carbon atoms of hydroxyalkyl to alkoxyalkyl %% aryl ring or hydroxyaryl group \ Or Ri and R2 and S can form an androyl group $ only if the m ring H contains a C: S group and Rs is the second bond. Examples of grade VIII hydrides represented by Formula IV include hydrogenated trimethylsalmonium triethyl hydroxide * tripropyl hydroxide, etc. 0 »These are m-liquids that are normalized or regenerated in the method according to the present invention (B dye (Solution) is a mixture, preferably solution m, containing oxidizable liquid rhenium and about 0.01% to about 50% by weight of phosphonium hydroxide and usually will contain varying amounts of one or more unwanted impurities, such as anions such as Halides, carbonates, formazan, nitrite% «nitrate salt 〇 thio acid 81 and so on some ions such as zinc and calcium • Na N \ potassium gold 翳 and some neutral species • * For example Photoresistance • Formazan λ amine, etc. 〇 Gasifiable liquid Η Can be a mixture of water and water-a type of solvent such as _ and so on. 〇 In a specific example «The method of the present invention effectively reduces Quaternary hydroxide The solution and the non-ionic impurities in the solution are further described in the following examples: • The method of the present invention generates a gold ion ions M and organic ions in a solution that reduces organic hydroxides such as quaternary ammonium hydride. The result is that organic hydroxides are commercially available. In addition, t • Organic hydroxides can be equivalent from 榇 m. For example, there are equivalent organic halides. * 鼸 鼸., Formate \ sulfuric acid H, etc. Preparation 0 Various preparation methods are described in U.S.A. No. 4,911,781 (Sha rifi an and his colleague) and No. 5,286,354 (Bard and his research colleague) 螫 therefore incorporated here for Reference 18- The paper size of the edition applies to the Chinese national standard (CNS > A4 size (210X297 mm)

The Central Government Bureau of the Ministry of Economic Affairs, Printed Oxygen A7, B7_, Shellfish Consumer Cooperatives V. Description of Invention (Λ). There are no particular restrictions on how to obtain or prepare organic hydrides4. In the method according to the present invention, an organic gaseous substance such as the above is purified or reconstituted from a waste solution in a method including at least one of three applicable steps. Although in most cases it is actually one of three «» steps that can be taken *. But more than one of the three change steps »can be implemented,. The first three steps include the precipitation step. The second one of the three steps includes the use of large and small spacers or the size of the film. Three available steps: The third puppet includes contact with the waste solution and the golden pupae scavenger. After being used in a method, the waste solution can be a solution of eaves hydrogen »oxides, especially in the development method with printed circuit boards and micro« sub-wafer manufacturing »due to the results of the pass. Impurities enter and contaminate the solution. In other words, can the waste solution be a waste solution with tritium hydroxide? In addition to suspected hydroxides, the waste solution may contain any of the above-mentioned substances and / or eaves and / or other particles equivalent to eaves hydroxide. Before completing at least one of the three available steps, at least one of the waste solutions containing tritium hydroxide and tritium is optionally concentrated. That is, the concentration of the organic hydride in the waste solution can be increased before the three applicable steps. In most of the examples, it is preferable to concentrate the waste solution before implementing the present invention. Concentrated step "The person who knows this technique in the box is known and includes evaporation, ion exchange, tritium dialysis, and reverse osmosis. *% The first step of the" available steps "includes the immersion step. Step "Includes argon oxide lining as insoluble in splattered waste Qin solution as insoluble 鼸 t • and better water -17- (Please read the note ^ I- on the back before filling this page)

OI • Binding. Binding: The size of the paper is suitable for the Chinese National Standard (CNS) A4 (210X297 mm) A7 B7_ 5. Description of the invention The term "water-insoluble", which is insoluble, means that the water is completely or partially insoluble in water. Although it is preferred to form M that is substantially insoluble and / or water-insoluble, others are not necessarily required. What is needed is that M is at least partially insoluble

It is hydrolyzed (and / or water-insoluble). The solubility of insoluble salts preferably changes depending on the temperature. Therefore, it is preferred to reduce or decrease the pan of the rejection solution while precipitating insoluble salts. Add osmium or acid to the abandon solution to produce a heavy insoluble 膻. ♦. At least part of the insoluble 鼸 is composed of compounds containing organic «ions derived from quasi-hydroxide) and Yinzi · (from the added osmium or acid). The insoluble salt may contain other compounds. The added »or acid is preferably non-stigmatizing or eucalyptus. Examples of rhenium that produces precipitated insoluble salts include ammonium, sodium, potassium, and other gold perchlorate, ML; ammonium, sodium, and potassium and other gold hexafluoroaluminate; ammonium / nano, Potassium and other gold hexafluorophosphonate M. Ammonium • Na, Potassium and others • · ♦ # Printed by the Central Labor Bureau of the Ministry of Economic Affairs, Consumer Cooperatives (Jing first read the note on the back and then fill out this page) Metal Hexafluoroarsenate .; Ammonium, .Na, Potassium and other metals rhenium hexafluorophosphate; ammonium, sodium, potassium and other gold hexafluorosilicates; ammonium, sodium: potassium and other gold hexafluorotitanates; ammonium, sodium · Potassium and other metals hexafluorophosphonates; ammonium., Sodium, potassium and other gold sulfonates and sulfonic acids. Ammonium: sodium •, potassium and other gold salts »acid salts: > ammonium, sodium. · Potassium and other gold sulphate, ammonium sulphate, sodium sulphide and other gold sulphide bromide; technical • sodium, potassium and other stilbene glycosides, sodium sulphate and other gold sulphate into manganese Examples of acids that cause precipitation of insoluble salts include perazoic acid, .IS iodic acid •• Fluorine including tetrafluoroacetic acid | acid, hexafluorophosphate k, hydrobromic acid < aglycone Acid · .Acidic acid and anything—generally equivalent to -18—this paper size is free to use ^^ Country ^ 橾 standard (CNS M4 specification 1210X297 mm) 'A7 B7 Λ, the acid of the salt listed in the description of the invention (β), . The precipitated insoluble hydrazones include salts consisting of uranium ions and any of the equivalent anions listed above. Specific examples include perchloric acid, hydrazone salts, and fluorinated salts (including fluorine atoms). Yin Yinzi), · For example, any one of the above listed "Hexafluoride: Suspected of bromine": There is cyclic acid salt. · Organic hydrazone acid, or any of the cymbals of the above-mentioned Yin sculpture, . The salt or acid to be added to the waste solution is selected based on a number of factors including the specific definition of organic rhenium vapors, the relative solubility of the resulting salt that does not dissolve osmium and any gold ions, and rhenium. Once the insoluble salt has been loaded, it can be isolated by any method known to anyone skilled in the art; including, but not limited to, decantation; and / or centrifugation. , And then washed by Qin Li ’s insoluble salt and placed in a liquid bath. This will form a new solution. The liquid hip may be water-based and water-based. * For example: water and a kind of « Solvents such as mixtures of yeast or ethylene glycol. 2. Because the insoluble salt only needs to be slightly dissolved in the new solution, so can the insoluble particles be present in the new solution? The new solution is then fed into the electrochemical cell. Printed by the Central Laboratories of the Ministry of Economic Affairs, Shelley Consumer Cooperatives (please read the note on the back, and then fill out this page) Before feeding the new solution to the battery, the thickness of the solution can be thinned «加Solubility of insoluble salts in it. For insoluble salts, complete dissolution in the new solution is not required but instead only at least @ 微 地 soluble. At a point of ν solubility, pegasus can also be added to a new solution to increase the apparent solubility of insoluble plutonium. In a practical example, • If the solution is water, add a small amount of _ · * For example, formazan or acetic fermentation can add insoluble -19- This paper is applicable to Chinese national standards (CNS) ) Α4 ^ (2 丨 0X297 mm) A7 B7 printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention () Solubility. Or, and / or in addition / new solution can be heated, agitated to place K under the K force, then add the solubility of insoluble ,. The second step that can be used in the three-step method includes the use of size-dependent features or size-selective measures. , Waste cable solution, * it can be evacuated to soil, and with size-selective separators, such as size-selective «difficult sub-selective membranes *, or size-selective membranes, such as nanometer Chip contact ,. Size «Selective concealment or film allows certain sickles to meet:% includes size, molecular weight, and many sizes and types depending on the material" In general, v in a specific embodiment The medium waste cable solution is subjected to one of two steps before being fed into the tritium tank. The first "step" consists of feeding the waste cord solution to the containing separator. • and the first electrification "selective ion selective membrane of a better size" in the pond; and the second step "including the formation of organic salts. Gun salt, followed by contact with an organic tritium solution and a size-selective membrane, such as a nano-filtration membrane. "Although the two steps can be carried out before the waste solution is sent to the tritium tank, it is better to perform only two steps." One of them. In a specific example. • Before contacting the waste solution with a size-selective separator or membrane \ «Restoring the waste solution M to form an organic compound containing an organic substance from a β waste solution» (of Solution? Better. * Before contacting the waste cable solution with a size-selective filter, such as a nanofiltration membrane. In the preferred example, • You suspect "is polymer # 枪 鼸》 Organic M can be dissolved in or completely or partially insoluble in solution? The solubility of organic tritium is preferably changed depending on the temperature% in which the solution is in contact with a size-selective membrane. With the example / newly formed organic 臁 -20- This paper size is applicable to China National Standards (CNS) Α4ίΙ (2 丨 0X297 mm) (Please read the note $ on the back before filling in this I)- Equipment. Printed by A7 B7 of the Central Working Group of the Ministry of Economic Affairs, Shellfish Consumer Cooperative. 5. Description of the invention (θ) It is not easy to select the size of the volatile film. In a case with β, E. Add salt or acid to the waste solution to form Molecular weight organic β. The phosphonium or acid added is preferably non-cyclic salt or non-phosphonic acid. Examples of phosphonium-forming salts include ammonium, sodium, potassium, and other gold perchlorate; and ammonium: sodium: Potassium and other gold rhenium hexafluorophosphonates; ammonium .. Na · «鲆 and other gold rhenium hexafluorophosphonates? Ammonium; Na,. Qing and other gold hexafluoroarsenate! I; Ammonium., Na • Potassium and other gold hexafluorophosphamide;, ammonium, sodium potassium and%% 'other metals hexafluorosilicate; ammonium, • sodium, • potassium and other gold hexafluorotitanates; ammonium * sodium ., Ammonium and other gold hexafluorosuccinates M; Ammonium Na., Ammonium and other gold iodides and iodine iodate; Ammonium., Na .. Potassium and other Jin Yangbian __ 臞; Ammonium · • Potassium and other Jinyang Fengyan acids: ammonium, sodium, potassium and other metal bromides ·; ammonium •, sodium, potassium and other metal fluorides and phosphonium compounds; press, sodium • potassium and other metal picric acid 》; Ammonium., Na., Samarium and other gold saccharic acid 馥: Ammonium ~ Na: Potassium and other gold osmium ammonium nitrate., Na •• Potassium and other gold osmium sulfonate etc.? Examples of acids include Including fluoric acid including tetrafluoro acid, hexafluorophosphoric acid, hydrofluoric acid, nitric acid, * · 9 $ * phosphoric acid •, phosphorous acid, polyphosphoric acid, hydrochloric acid, phosphonium bromide: picric acid; over Perylene acid and any acid generally equivalent to those listed above. In another suspected embodiment, 榇 M is formed via ion exchange technology using an ion exchange system. Ion exchange can occur in a column. Organic Salt is made up at least in part of compounds containing transporting ions (from argon oxide) and anions (from adding salt to acid or from ion exchange). -21- This paper applies to China National Standard (CNS) Α4 Specification (2 丨 0X297 mm) (Please read the note f on the back before filling this page) -58 A7 ^ __ B7__ V. Description of the Invention (β) Neutralization of Organic Kappa Dioxide To form. In the embodiment of the anthracnose method • Because the equivalent is too carbonic acid ”and bicarbonate complicate the process, (please read the note ^^ on the back before filling this page) • Selective size reduction Divided into "materials and sizes" Volatile membranes and / or electrochemical reactors • The formation of tritium bicarbonate and tritium disulfide is unwanted. Such eaves include such crocodile composed of organic «hungry sons and any one of the above-listed sows, special examples include eaves gaseous 鼸. * 榇 榇 遇 cyanic acid", 籣 籣 籣Compound 蘧 * · Organic fluorene (anion containing fluorine atom) such as any of the hexafluoride fluorene, organic bromide * ♦ · Eucalyptus gluconate: Eucalyptus acetic acid, Eucalyptus nitrate Or any equivalent of the 馥 listed above. The anion with a phosphonium salt is selected based on a number of factors including the relative solubility of the organic salt obtained and the salt of any gold ionic impurity impurity. In another specific embodiment, after the selective concentrated depletion solution and «after the formation of salt, the waste solution can be brought into contact with the size« volatile hydrazone »under pressure in a preferred embodiment Medium. • Size-selective membranes are, for example, microfiltration membranes with nanofiltration membranes. The applied pressure is usually at least about 100 ps, and preferably about 200 to about 1,000 psi: and more preferably about 300 to about 800 psi. Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs in another preferred example of funding * * especially after organic brewing has been formed 5 wt% blue solution. The size of the volatile membrane is usually in the form of a pressure tank distinguished from the cartridge. The waste cable solution is in contact with the size selective membrane under sufficient scraping force. This gold ions ion impurity can pass through the size selective. In a typical work: a part of the waste solution .. For example, a quarter •, half # • or three quarters •, forced to wear «-22- This paper is scaled to the standards of the Chinese family (CNS } A4 size (210X297 mm) A7 printed by the Central Standard of the Ministry of Economic Affairs, Shellfish Consumer Cooperative Co., Ltd. Ⅴ. Description of the invention (θ) The size of the selective membrane and the impenetrable size are left. The organic thin film containing organic rhenium solution contains a small amount of metal ion impurities and / or tungsten ions to gold ions impurity ratio is greater than the ratio before the large volatile film contact. The osmium salt is obtained from the large and small volatile membranes by solvent engraving and recovery technology, and a solution containing organic tritium is then fed to a tritium tank to purify and / or regenerate organic tritium oxide. Examples include MPF-3 4 nanometers from Kinyat-Weiz «iann; Desal-5 from LCI; and ESNA nanometers filter 4 from Hydronautics. Other nanomembrane filters In order to be obtained from Dow and Fil · Tec, in another embodiment, the waist is abandoned. Liquid .. It has been selectively concentrated, and it is fed to the first electrochemical cell containing the selected material. In specific examples, the method of the present invention includes the use of two chemical compounds. Battery. In one embodiment, the first cell includes at least one electrode and a cathode, and optionally a separator a, and the first cell further includes a bipolar membrane. In a preferred embodiment, the t • separator is a male engraved volatile residue, and more preferably a male-sized ion-limiting ion-selective membrane. The waste solution is fed to the first electrochemical cell, Therefore, metal ion ions such as lithium, sodium, and potassium, leave the waste liquid with the p-side sized spacer κ due to the result of current flow through the galvanic cell. A In all of the present invention, The description of the electrochemical cell used in the crocodile cockroach example (after the time) can be applied to the first electrochemical cell with actual examples, and it is not included in this section for short reasons. This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) HM. (Please read the note on the back before filling in (This page) • Equipment. Printed by A7 B7, Shellfish Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs 5. Description of the invention (w) In the case of «Real Example», the chemical tank contains at least two overseas Chinese, ie V The feed-recovery interval and the waste liquid interval, and the selective water interval ffi and / or the pass interval. In some cases of crocodile marinated cases / according to one of the first exemplified cases Have two preparations or the above intervals on κ ". For example, ** In a" example with real examples * according to a first embodiment of the first chemical tank, there may be two feeds and a recovery multiple interval , A pour water interval, and two waste liquid barriers. The solution was poured into each interval. The solution may be a water-based > fermentation or secondary fermentation as a substrate, or other circulating solutions or a combination thereof. In the preferred alligator embodiment, the solution fed into each interval is an aqueous solution. The solution that is fed to the feed-recovery interval contains organic hydroxides and impurities that are to be regenerated or purified to a certain concentration, such as, for example, gold ions. The concentration of the hafnium oxide in the initial feed-to-feed-recovery interval ranges from about 1% to about 20% by weight, and more preferably from about 2% to about 10% by weight. In most cases, the solution also contains metal ions, such as lithium ion, lithium ion, sodium ion, potassium ion, magnesium ion, and calcium ion. The waste solution interval is initially fed with a solution, and preferably an aqueous solution. The solution fed to the waste solution interval may or may not contain ionic compounds. After the flow passes through the first electrochemical cell, the organic hydroxide may be removed from the solution. Recycling interval of material one. The degree of eaves hydroxide recovered from the feed-recovery interval may be the same or higher than the starting concentration of the organic hydroxide in the solution initially fed into the feed-p collection interval. Once applied, a “flow” of “gold ions” is moved through the separator / and in a preferred embodiment, it is moved through the size 遘 遘 隈 ions male film _ 2 4 _ This paper size applies to China CNS A4 Grid (210X297mm) (please read the "$" on the reverse side before filling out this page) .q ·

• IT i! Printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A7 _B7_ V. Description of Invention (vl) • Enter the interval between waste solutions. As a result, the solution recovered from the feed-recovery interval accidentally contained less µgolden ion impurities. Examples of selective membranes include the CNS ion membranes from Tokuyaia Soda and the CSV membranes from Asahi Glass. The membranes can be used in accordance with one embodiment. The first embodiment of the first battery is described with reference to the formula. Two specific embodiments of the first battery are described in the following formula. It can be seen that many other examples that are not explicitly described in the _ formula exist in the scope of the present invention, "A tool for the first battery cell described in circle 1" in the embodiment * _ 1 is An outline of an electrochemical cell 1Q / The electrochemical cell 10 includes an anode 11i cathode 12 and a starting at the anode 11: separator 13 (which is a size S volatile film in the implementation of the "better") "* It is better A unit having a sequence of «selective membrane of size S selective limit ion» in the embodiment. The tritiated tank 10 includes two intervals, namely, a feed-recovery interval 14 and a waste liquid interval 15. In the operation of the electrochemical cell 10 illustrated in Fig. 1, a solution containing an organic hydroxide and an Au ion is fed to a feed-recovery interval 14. Feed water to the waste interval 15. Establish and maintain a potential between the anode and the cathode to generate a flow across the battery ** so at least some metal ion species are attracted towards the cathode and enter the waste liquid through the separator 13 in the interval 15. There are `` oxides '' Retention at the feed-recovery interval M produces the required hydroxide solution containing less ft of metal ion impurities (compared to the solution originally fed into it). "Recycling from the feed-recycling interval 14 to the metal containing the fewest metal -25-This paper size applies to Chinese National Standard (CNS) A4« L «· (210X297 mm) (Read the f note on the back before filling (This page) d -pack. -Β, line A7 B7__ printed by the Central Bureau of Standards and Quarantine Bureau of the Ministry of Economic Affairs of the People ’s Republic of China, the fifth edition of the invention (/) a new solution of impurities. The embodiment of the «Another Pond» of the 霣 说明 is described in the garden 12 / it is a type of 霣 尔 尔 池 180 180 containing two 悝 units 霣 / / Although it may contain more units 霣 霣. The tritium battery 180 contains tritium pole 181 ... yin hibiscus 182 and starts at yang * 181 ·, the first size «volatile intestinal ion« selective film 183, bipolar film 184; and the second size 遘The order of ion selectivity 臜 185. The bipolar salamander 184 has its yin sickle facing the gull pole 181 (not shown) and the diarrhea facing the road pole 182. The male is optional (not shown). Four β 閜 compartments, namely: the first feed-recovery compartment B1ΐβδ, the first waste liquid interval 187. · the second waste liquid-recovery interval 188, and the second waste liquid interval 189. During the operation of the battery 180 • A solution containing organic argon oxide and metal ion species is fed to the feed-recovery intervals 186 and 188. Water was fed to the mash solutions at intervals 187 and 189. Establish and maintain a niche between the cathode and the cathode to create a flow across the cell. * Therefore at least some of the gold ion impurities are attracted to the cathode and pass through the first or second size selective isolator-selective membrane 183 or 185 enter the «fluid interval 187 or 189 respectively. The organic hydroxide is maintained in the feed-recovery interval M to produce the desired argon oxide solution (compared to the original feed to it) containing a smaller amount of gold sulfide ion impurities. From a feed cycle of 186 or 188, a new solution of osmium hydroxide containing a small amount of golden cymbal sickle is recovered. The κ cord solution containing less metal sickle materials recovered from the feed-recovery interval can be fed to the second electrochemical cell, and then the hydroxide can be -2 6 * This standard is applicable. Gujia Standard (CNS) Α4 specification (210X297 mm) (Please read the note f on the back before filling in this purchase) Order

J Central Bureau of Standards and Quarantine, Ministry of Economic Affairs, Consumer Cooperatives, Ben Ben A7 B7 V. Description of Invention (4) Purification and / or regeneration. The third step that can be used, the third involves contacting the waste cord solution with Jin Yang's ions. After the waste liquid containing organic argon oxide and impurities is volatile, it is contacted with a metal ion scavenger to remove gold ions. This is a reaction with gold ions in the presence of tetraammonium ions « Reactive or incompatible compounds. In the context of 埴, 4 羼 gold ions include _ 羼 羼 表 surface soil Jin Yang, Tung Bo 靥 靥 and other young metal 纟 more specifically, gold 羼 艨 包括 includes lithium k, sodium, potassium: •. Absolute •• Beryllium, Magnesium f: Calcium: Barium • Barium: Titanium • Titanium, Vanadium, Chromium ··· ♦ • Niobium •, Molybdenum • Soft I., Rhodium,. Palladium “Silver” Cadmium • Tungsten, Suspect ♦ • Iridium, • Platinum, Gold · # »Aluminum • Cat, Tin, Lead • Antimony Bismuth, 铊, and other sickles. In a preferred embodiment, the gold layer sickle scavenger comprises a cyclic ether compound I. In a more preferred embodiment, the golden pheasant herb comprises at least one crown ether or cryt and. In another example, the gold ion ion scavenger contains a polymer containing an ether moiety: and more specifically a polymer containing a cyclic ether moiety or a cavity-shaped cross-linking moiety? Specific examples of cyclic ether compounds include crown ethers such as 12-crown ether-4 (1,4,7,10-tetraoxycyclododecane); 15-crown bond-5 (1,4,7,10, 13-pentaoxycyclopentadecane); 18-crown ether-6 (1,4,7, 10,13,16-hexafluorenyl ring ten% octane; (12-crown ether-4) -2- Formazan (2- (hydroxymethyl)> Γ12-crown ether-4-) .; (+)-(18-crown ether-6) -2,3, 11,12-tetracarboxylic acid, 4'-amine Benzo-15-¾ 黼 -5; 4 · -amine Benzo-18-crown_-6; 2- (Amine methyl > -15-Crown ether-5; 2- (Amine methyl) · 18- Η_-6; 4'-Amino-5 * .- Nitrobenz-15-S ether-5; 1- -27- (Please read the note f on the back before filling this page) d Binding

This paper size applies to China's national standard (CNS > A4 specification (210X297mm) --- ·-»· — β Printed by the Shell Sample Consumer Cooperative of the Central Sample Bureau of the Ministry of Economy A7 ___B7_ V. Description of the invention (> ♦ ) Acryl-12-crown ether-4; 1-acyl-15-S_-5; 1-acyl-18-S ether-6; benzot '-'12_crown ether_4; benzo-15-crown Ether-5J Benzo-18-crown B-6 pyrene bis [(benzo-15-crown ether-5) -15-ylmethyl] pyrene pivalate; 4'-bromobenzo-18-crown ether -6; dibenzyl-18-crown ether-6; dibenzyl-24-crown ether-8 / dibenzo-30-¾ ether-10; ar, ar'-di-tertiary-butyl di Benzo-18-S ether-6; '4 Dicyclohexano-18-crown ether-6 ;, Dicyclohex-24-S ether-8; 4'-Methylfluorenylbenzo-15- Crown »-5; 2- (dimethylol) -12-crown ether-4; 2- (dimethylol) -15-crown ether-5; · 2- (dimethylol) -18-crown Pyrene-6; 4'-¾ylbenzo-15-crown ether-5; 4-vinylbenzo-18-H ether-6; 1,8-dihydroxy% -dibenzo-14-crown ether- 4; 1,11-diol-20-H ether-6; poly [(dibenzo-18-B ether-6> -co-formaldehyde], and 2-methyl-2-dodecyl propane Acid bis [* 12-crown ether-4) -2-methyl]; various formulas and formulas for preparing cyclic ether compounds An example is described in U.S. Patent No. 5,393,892, (: "1 [〇1 ^ & 1 [et al., Which is hereby incorporated herein by reference, < Cyclic ether compounds that additionally contain nitrogen atoms in the ring structure, such as 2.2.2-cryptate and 2 ^ 2.1-cryptate. In one embodiment, the gold ion ion scavengers can be prepared without further steps. Is used. ≫ In another «embodiment, the gold ion ion scavengers are incorporated into the polymer, and the K polymer contains a cyclic ether moiety, and in particular« a crown ether moiety: a special example is Monomer polymer product of formaldehyde and dibenzof 18-crown ether-6. In another specific embodiment * the gold tincture is eliminated «* agent is attached to a polymer containing a metal ion scavenger is attached To the brace »The brace% can be polymer beads, membranes, compounds containing silicon gallium, or can be connected in order. -28- This paper is a Chinese national standard (CNS) A4 specification (210X297) Li) (Please read the note on the back before filling in this page) d-Binding · Ordering-Printed by the Central Laboratories of the Ministry of Economic Affairs, Off-line Consumer Cooperatives A 7 _B7_ V. Description of the invention (/) The silicon sulfide compound or its polymer that has received 9S to remove 9S · t sand 4, silicon condensate waist, glass, glass fiber, aluminum oxide, gasification, · Gasification test, or oxidized peptide. * Or other media containing gold ions elimination agent. % Waste solution M is contacted with metal sickle scavenger in many different ways. It usually depends on the state of the gold scavenger ion scavenger. For example, 1, the waste solution can be combined with the gold ion ion scavenger in the container. The waste solution can be passed through the column containing the metal ions contained in the support. • The waste solution can include metal sickle. The medium of the sterilizer, etc .: the waste solution and the metal ions are eliminated. The method of contact is not particularly limited. In a preferred embodiment of the crocodile I. When the golden eagle eagle eagle owl is attached to the polymer beads / the polymer beads themselves are contained in a column, and then the waste solution is passed through the column ~ Carving scoops are attached to the haze on the polymer beads that are present in the container. In Example 4, the waste solution is added, and the container can be optionally shaken or otherwise stirred. ♦ The polymer beads and solution are then separated. ? In a preferred embodiment, it is essential that the contact between the waste solution and the gold ion scavenger is performed before the step involving the electrochemical cell. The result / actual amount of gold ions was not introduced into the "chemical bath". Because, in some embodiments, the actual mass of metal ions in the waste solution can reduce the effectiveness of the steps involving the electrochemical cell: it is important. In the broader point, the solid gold dipper may contaminate the recovered organic hydroxide. In another example, the waste solution was fed into an electrochemical cell, and the solution recovered from the electrochemical cell was later brought into contact with the gold ion removing surface. * In the third available -29-sheet The scale is applicable to China National Standard (CNS) Α4 specification (210X297 mm) (Please read the note on the back before filling this page) 4. Order

A A7 __B7_ 5. In the specific example of the step of the invention description, in other words, before or after contact with the metal ion scavenger, it contains organic hydroxides such as those described above. The waste barren liquor is added to the «chemical battery * in the method according to the invention 丨 eaves argon oxide such as those described above in a step including a step including a« chemical battery purification or reformation step including Xiaohuan pond It can be carried out by dialysis in the dialysis or by dialysis in the dialysis dialysis tank. The galvanic "pool> generally / contains at least one» pole, a cathode, and a separator and / or one or more devices for use with K positioning operation between the separator and the cathode "pool Many electrolytic and dialysis cells containing various unit and multi-unit cells are described herein. They are used in the method of the present invention. A multi-unit cell can be defined by a number of cells between the separator and the cathode (see, for example, _6), or a multi-cell cell can be defined by a number of intervals including the limit and the cathode (see, > For example, _3). A multi-unit battery including a pole and a pole can be military-grade (see », for example, or a bipolar configuration (see, for example, _7). There are no special restrictions on the number of units that can be used. In a modified embodiment, i is used in accordance with the present invention. The «chemical battery contains 1 to about 2 5« military position «pool and preferably 1 to about 10 unit pools.« These unit pools may contain Two or more intervals defined by the exposed electrode • depolarized: and its separator or separator: The separator can be divided into two parts: (U Controlled pore size or pore size distribution allows or disallows a certain These carvings pass through the non-inserted microporous expansion array of partitions or isolates, such as screens, filters, diaphragms, etc. > Paper size applies to China National Standards (CNS) A4 specification (210X297 male shovel) (Please read the note on the back before filling out this page) d-Packing. Order · Printed by the Central Standard of the Ministry of Economics 扃 Printed by Male Workers' Cooperatives 5;

Printed by the Central Laboratories of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives, "Invention Description" (霣) and »ion-implanted membranes; because their use usually produces higher inertness and relative in the preparation of organic rhenium oxides High yield • So it is better than «. The various partitions used in the trickle ponds of the present invention are more fully described below. The electrochemical cell according to the present invention contains at least two intervals i, i.e., a feed parameter interval and a recovery interval. Optionally, the electrochemical cell according to the present invention may include at least one water interval, a communication interval, and / or an OM-free or acid-free recovery compartment. In some embodiments of the crocodile, the 霣 霣 pond according to the present invention may have two or the above-mentioned intervals on other K. In other embodiments, the 霣 轚 pond may have two or 上The intervals listed above on a β or M / For example *. In a practical example; a chemical tank can have one entrance interval * two water intervals and a recovery interval solution are entered into each interval. The solution may be a water matrix or a second enzyme matrix or another organic solution or a combination thereof. In a preferred embodiment, the solution fed into each interval is an aqueous solution. The solution fed into the feeding interval contains a concentration of eaves hydroxide (water insoluble) to be regenerated or passivated. Salt, organic krypton, and / or organic argon gas). , Water insolubility within the initial feed-to-feed interval "\ Eaves" and / or a range of organic hydroxides with a concentration of about 0.1 Μ to about 2 Μ *. In a preferred embodiment, the concentration is from about 0.2M to about 1M. In a dehydration tank containing two or more feed intervals / concentrations can be the same or different for each feed interval / fed to the "water-insoluble water in the solution of the water", organic water and water Concentrations are about 1% by weight to about 20% by weight and more often 2% by weight and 10% by weight. Feeding interval -31- This paper size applies Chinese National Standard (CNS) Α4ϋ 格 (210X297mm).. T- '' ·. ^ · Τ = -one by one: (Please read the note on the back first (Fill in this page again)

M The Central Standards Bureau of the Ministry of Economic Affairs, a separate consumer cooperative, A7 B7 V. Description of the invention (β), as indicated by the surgery box, V remains to contain suspected hydroxides that are intended to be reprocessed and processed in the form of self-waste liquid by the present invention « The solution (. The recovery interval is initially fed with a solution and is preferably an aqueous solution. The solution fed to the recovery 'interval may or may not contain the chick compound #. After the plutonium is circulated through the «battery, the The eaves hydroxide A recovered or obtained at a certain concentration after circulating the water through the galvanic pond. The concentration of the organic argon oxide in the recovered water is usually higher than the organic hydrogen initially fed into the feed room. Concentration of oxides 丨 In one example, the degree of eaves ammonia oxide in the recovery chamber is about 0.1 MM. ≫ In another case, the organic in the recovery interval The concentration of radon gas is about 0.2M or more. In a preferred embodiment, the concentration of the organic hydroxide in the recovery interval is about 1 MM. T In the electrochemical cell containing two or M recovery intervals «in the pool / Solvents recovered from these recovery intervals The degree of eaves hydroxide in can be the same or different at each recovery interval. The water interval (if present) contains a solution of the young compound at a certain concentration, and the water interval containing ionic compounds is maintained by 専 霣It can reduce the pressure of the operation and the pressure of the pond. ≪ i Si compound is an ionized compound in the solution, such as the electrolyte * ion compounds. Examples include 类, 羼 salts and acids or any when dissolved in Compounds that form anions and sulfonium ions in water. In the preferred embodiment, the compound of the eagle and the hydride fed into the feed interval of phase f are the same. "I is in another preferred embodiment" 2 «The female compound or ytterbium ion of the child compound is the same as the organic ion of the organic ion hydroxide in the feed-to-feed interval. In another« Cell example-32- This paper size Applicable to China National Standard (CNS) A4 specification (2 丨 OX297) 漦 (Please read the “$” on the back side before filling out this page); Pack. Order 4! Α7 Β7 Printed by the Bayou Consumer Cooperative of the Central Automobile Bureau of the Ministry of Economic Affairs «. 5. In the description of the invention (β), The ionic compound is not different from the hydrazone hydroxide fed into the feed room. The concentration of the refractory compound in the solution fed to the water is between about * 0.1M to about 5H. In a preferred embodiment, the concentration is from about 0.3M to about 3M. And in a preferred embodiment, the concentration is about 0.5M to about a% 2M. The concentration of ionic compounds in the solution in the water interval. · The concentration of ionic compounds in the solution fed to the water interval may be the same or different for each water interval. ≪? The interval (if present) is initially fed with the solution and Preference is given to aquatic fluids. The solution to which the through edge is spaced may or may not contain sickle compounds. The sickle compound, if present •, may be the same as or different from the chick compound in the water; >; In the practical example of using the pass-through method / after the pass-through pass through the passivation tank} organic hydroxide pass-through meeting interval "" because most of the unwelcome callouts do not pass through壜 Intervals • The organic hydroxides can be further oxidized by γ. The recovery interval of non-salt salt or inorganic acid ~ If there is a knot t, the solution which is initially fed with the solution and preferably an aqueous solution% is fed to the inorganic salt or non-acid recovery interval may or may not contain a refractory compound. Ionic compounds: If there is a junction, they can be the same as or different from the ionic compounds separated by water. In the case where an inorganic salt or an acid-free acid recovery interval is used, «Example I After the flow through the electrochemical cell, there is a suspected ion migration. At the same time, the anions from the water-insoluble crocodile pass through from the feed interval to the phosphonium-free salt or inorganic acid recovery interval. .Because most of the undesired impurities do not pass into the non-susceptible or non-seeded acid recovery interval, all unsupported or unsupported acids can be recovered and used •, especially «9 -33- d. (Please Please read the precautions on the back before writing this page)-Binding. The paper size of the binding thread applies to the Chinese National Standard (CNS) A4 (210X297 mm) 4! Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7_ V. [Explanation of the Invention] () It is read in series. When salt or acid is added to the waste solution / when the waste solution is water-insoluble. References will be given to explain some examples of chemical conversion pools that can be used in the present invention. Although many practical examples of various various chemical conversion pools are described in the formulas, the box-heater artist shows It is easy to know that many others are not explicitly described in the formulas in the present invention within the scope of the present invention. • The description of the “Electrical Cell” in Example 1 is shown in circle 1 / which is a general outline of the “Electric Cell” 10. The electric cell 1Q contains the electrode ut, the cathode 12 and the anode 11 ′. Separator 13; it is preferably a sequence of limited-chamber selective membrane units «pool. The chemical tank 10 contains two intervals; 1 is the \ feed interval 14 and the recovery interval 15 «This tank can be used in conjunction with one of the three available steps4. In the operation of the chemical tank 10 described in _1, a solution containing a water-insoluble solvent such as sodium perchlorate, an organic salt, and / or an organic hydroxide is fed to the feed interval 14. Feed water to recovery interval 15 ,. Establishing and maintaining a potential M between the hibiscus and the depolarizing electrode generates a horizontal «« pool of the roll • so the gun »The ions or organic embroidery are attracted to the depolarizing electrode and pass through the partition 13 into the recovery interval 15. Tungsten thorium ions or organic exposure ions are combined with hydroxide ions during the recovery interval to produce the desired male argon oxide. Impurities are not attracted to the cathode or pass through the separator and therefore remain in the feed cell. Regenerated hafnium hydroxide is formed and recovered from the recovery interval 15. Another specific example of the chemical conversion tank is described in · 2, * _2 is a general illustration of the chemical conversion tank 20, which contains »台 21: 播 -3 4-This paper is applicable to the standard China National Standard (CNS > Α4 specification (2 丨 QX297 male thin) (Please read the precautions on the back before filling in this tile) d Pack · Order 41 Printed by the Shellfish Consumer Cooperative of the Central Sample Bureau of the Ministry of Economic Affairs «. A7 B7 V. Description of the invention Ui) Hibiscus 2 2 and a unit cell containing the order starting from the exposure electrode 21, deionized thinner town 23, and the selective membrane 24. "Huaxiao Pool 20 contains three intervals; that is, no salt or organic acid recovery interval 2 5 / relic interval 26 and recovery interval 27. This pond is better than three possible steps." It will be used together by the sisters in the operation of the "Chemical Pond" described in the garden 2 / will be contained in water-insoluble 酦 丨 organic 81 and / or organic hydrogen hydride solution feed to the feed 閟 隈 26 » Expected inorganic salt or eucalyptus acid limit recovery 25 and recovery room 1127. Establish and maintain a niche between the anode and the negative stage to generate the flow of water across the pond, so water-insoluble salts, and the nuclei cations of the eaves and / or organic tritium oxide are attracted to the cathode and pass through The ion selective membrane 24 enters the recovery interval 27 ,. The "榇" ions are combined with hydroxide ions in the recovery room W to produce the required 榇 hydroxides 丨 impurities are attracted to the platform and / or they will not be attracted to the cathode and / or they will not The selective membrane 24 and / or remain in the feed interval, and the regenerated organic hydroxide is formed and recovered from the recovery interval 27; > At the same time, water-insoluble radon, eaves salt and / or organic radon The anion of the oxide is attracted to the anode, and it is selective through yin and yang. It enters the non-ortho- or non-ortho-acid recovery interval 25. The combination of anion and cymbal f. Produces acid or 鼸 _. The acid or ρ can then be recovered from the canopy or inorganic acid recovery chamber, which can be reused when using the flail method to precipitate additional water-insoluble salts. »In another practical example, one of the two types of« Chemical Ponds »and 2« Chemical Ponds », except for the two units used in the unipolar sisterhood-35- This paper is suitable for China National Standard (CNS) Bagu 1 grid (210 × 297 mm) ------- d {read the note f on the back before filling in this purchase)-printed by the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (from) «Beyond the pool •• Description in circle 3 ·, _3 is a kind of 霣 池 30« To show, the 霣 霣 30 contains the first pole 31 ·, the Two poles 32: Dipole 35 and two poles contain Yang starting from the first female platform 31, the first anion is thinly selective 臜 33, »* The first insulator is thin and thin 腆 34 ,,» pole 35, the second " The unit of the order of the ore-selective film 36 'and the second quarantine _37 is 挥. The tritium battery 3 0 described in the circle 3 contains six «intervals; that is, the first inorganic salt or non-phosphonic acid * · Recovery interval 38, first feed interval 39, first recovery interval 40: second recovery interval 41 · The second advanced battery 4 2 and the second free battery or the free acid recovery room to make 43 batteries are preferably used with any of the three steps that can be used. In "Operation of chemical tanks" explained in Figure 3> "Into the inorganic solution of the aqueous solution" or non-acetic acid recovery and recovery room will contain water-insoluble salts, with and / or with gaseous compounds The port liquid is fed to the feed scent. β establishes and maintains a potential between the carved pole and the depolarized pole, κ generates a current t across the pond, so insoluble salts, organic tritium, and / or organic hydroxide ions are attracted to the hibiscus box. Through the first or second ion-limiting ions, 34 and 36, enter recovery intervals 40 and 41. At this time, "Water-insoluble salts": Anions with osmium salts and / or hydrazones are attracted to individual broadcast poles to pass through the first or the second larvae and enter the inorganic M 3 or 3 7 Or recover acid within recovery intervals 38 and 43. _Combined with eaves ions and argon oxide to produce the desired organic tritium oxide in the recovery intervals 40 and 41 / then recover the organic hydrogen hydride from the non-titanium ion 4 0 and 41 "The anion and the counter ion Acids or salts are generated in starvation K or inorganic acid recovery intervals 38 and 43. , And then recycle from inorganic thorium or -36- This paper size applies the Chinese National Standard (CNS) Α4Λ lattice (210 > < 297 mm): · * '' + ·-til Pan + V ^ · ___ ·. ». ........... 1 Ι.Β--1ί ~ 11. M J-.J-«11 ^ ·»-. _ (Please read the notes on the back before filling this page)-装_ Order 111 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs and Consumer Cooperatives for printing A7 _ B7 V. Description of the invention (Vi) Inorganic acid recovery interval 3 8 and 4 3 Recovery of acid or "> It has been reused in Shen's "Extra Water-Insoluble Electrochemical« Another Specific Example of a Pond Distinguished from the Garden '/ 4 "is a summary of an electrochemical cell 50_shows that this chemical cell 50 contains Yang 51 / Cathode 5 2 and the beginning of the order "51: Yin Dizi Selective_5 3f • First Exposure Ion Implantation_54 and Second Emperor Sculpture Male Order 55 in order. • Tritiated pond 50 contains four intervals j, namely: inorganic tritium or inorganic acid recovery interval 56, feed interval 57, through edge interval 58; and the second recovery interval 59 / three Used in conjunction with any of the three available steps in the operation of the "Pond 50" described in circle 4, will include water-insoluble 酦 •, 酦 salts and / or 榇 hydroxides The solution was fed to feed room ffi 57. Feed water to the inorganic rhenium or inorganic acid Recovering 56: through the space 58 and the recovery 嗝 59 < establish and maintain a position M between the separator and the cathode to generate a current across the battery / therefore Water-insoluble », the erect salty and / or organic hydride of the eye-catching sickle is attracted to the depolarizing and pass-through first and second cation selective membranes 5 4 or 5 5 and enters the recycling through the space 5 8 Within interval 59. The organic cations are combined with the hydroxide ions in the recovery methane to produce the desired mobile hydroxide. The capsules are attracted to the cuckoo poles and / or they are not attracted to the cormorants, and / or they do not pass through the first and second «Ion S selective membranes 5 4 and 5 5 and / or remain in During the feed interval. Regenerated organic hydroxides are formed and recovered from these recovery intervals 59; > At the same time, water-insoluble tritium, yin sculptures that are suspected of salt and / or tritium hydroxide are attracted to the positive seeding "this through anion Optional film 5 3 enters the recovery interval of inorganic salt or acid-free acid within 56 -37- This paper size applies to Chinese National Standard (CNS) Α4 specifications (2 丨 0X297 public envy) {Please read the note on the back before reading (Fill in Benja) d Pack. * • 11

»-Printed by the Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description () φ). Yin sickle and osmium ions generate acid or sulfonium in phosphonium-free salt or inorganic acid recovery interval 56. Then the acid or hydrazone is recovered from the suspicion or suspicion acid recovery interval 56, so when the continuous method is used, it can be used to splash water insoluble 顗 outside 顗 〃 The embodiment is described in Shui 5> _5 is an outline of an electrochemical cell 60. The electrochemical cell includes an anode 61, a cathode 62, and a starting electrode 隈 61, a double-planted membrane 63 ·, and a soy stalk. Selective Membrane 64 • Sequential unit with selective ion exposure. The bipolar 臜 6 3 has an anion selective side (not shown) facing the separator 61 and an ion-selective side (not shown) facing the blind electrode 6 2. Tritium pond 60 contains four intervals, namely, water interval 66; no salt or no eucalyptic acid recovery interval 67, feed interval 68 and recovery interval 69 ^ > Any combination of steps that can be used 丨 In the operation of "Chemical Pool 60" described in 圔 5, feed a solution containing water-insoluble # nature salt V osmium salt and / or eaves hydroxide To feed 閜 皤 68 丨 feed water to the non-seeded or inorganic acid recovery interval 67 and recovery interval 69. Water and ionic compounds enter the water interval 66. The establishment and maintenance of a unitary position between the tritium pole and the tritium pole generates a flow V across the battery, so water-insoluble salts. ♦ Tritium cations with tritium salts and / or tritium oxides are attracted to the depolarizer. And through the cation-selective membrane 6 5 into the recovery chamber 皤 6 9 々 榇 饥 饥 饥 饥 饥 饥 饥 饥 饥 饥 饥 饥 饥 饥 饥 饥 饥 饥 饥 饥 饥 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 雕 in a recovery interval to produce the desired organic hydride They are not attracted to the cathode and / or they are not retained in the feed through the meteorological ion-implanted membranes 6-5 and / or into the feed 尺度 -3 8 This paper is suitable for China ^ Ladder Standard (CNS) Λ4 specification (210X297 & i) (Please read the note on the back before filling in this page) οί Binding and ordering A7 B7 Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives. V. Invention Description (β) 皤 中 #. Regenerated osmium hydroxide is formed and recovered from these recovery intervals 69. At the same time, the water-insoluble crocodile * organic osmium and / or organic osmium oxide ion is attracted to the seed so as to selectively pass through the female chick 64 enters the inorganic radon or manganese acid recovery interval 67. Anions and sulphur ions are combined to generate acids or salts in the hydration-free or inorganic acid recovery solution 67, and then recover the acid or salt from the hydration-free or non-acid recovery interval 67, so when using the construction method It can be used in water-insoluble materials other than MEMS. Another example of the funded Xiaochi Pool is shown in Figure 6. Circle 6 is a "remark" of an electric pool 70 containing two units of the same unit as the tumor 5. • «Hua" Pond 70 contains sowing pole 71 · Depolarization 7 2 and one starting from "pole 71 * the first bipolar 缜 73: the first anion 遘 volatile film 74 · the first meteorite Qin ·« selective film 75; a unit cell of the second pair of diaphragms 76, the second yin sickle selective viscera 77, and the second double cricket optional membrane 78. These double hibiscus membranes 73 and 76 have ion selectivity (not shown) of the shaded furnace facing the pole 71 (volatile side (not shown) and facing hibiscus 72). The electrochemical cell 70 includes 1: a free space; that is, a water interval 79; a first hafnium-free salt or inorganic acid recovery interval 80, a first feed interval 81; a first recovery interval 82, a second inorganic thorium or no The acid recovery interval 83; the second feed interval 84 and the second recovery interval 85f are preferably used in combination with any of the three available steps. In the operation of «Chemical Battery 70" described in _6, v will contain water-insoluble 溶 •, organic 鼸 and / or hydroxide-containing solutions to the feed intervals 81 and 84. Feed the water into the hydrazone-free or inorganic acid recovery compartment and the hydration compartment. Water and ionic compound feed water interval 79 is established between the anode and the depolarizer -39- (Please read the precautions on the back before filling this page)

-56

X This paper size is in accordance with the Chinese National Standard (CNS) A4 specification (210X297 mm). Printed by the Central Government Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives. A7 _B7_ V. Description of the invention (from) and keeping one position M across the "pool" «潦 •, so water-insoluble salts / organics with 榇 鼸 and / or 榇 hydroxide» ions are attracted to the first and second septa of the polar and through edges selective 镰 7 5 or 78 Into individual collection rooms M 82 and 85. The "榇" ions are combined with the argon ions in the recovered 閜 ffi to produce the required 榇 hydride >. Substances are attracted to the exposure platform, and / or they are not attracted to the cathode ** and / or other ion-selective membranes are passed through and / or retained in the feedstock, and the generated organic hydrogen compounds are Formed and recovered from these recovery intervals 82 and 85. At the same time, water-insoluble crocodile. · Organic chicks and / or females with truncated oxides are attracted to the hibiscus to meet the first or second anion 遘 臜 4 7 4 or 7 7 into the individual inorganic The crocodile or manganic acid recovery interval within 80 or 83 is a combination of f anions and cationic ions. In the no-supply or acetic acid recovery interval, acid is generated or then recovered from the inorganic tt or inorganic acid recovery intervals 80 and 83 When using the continuous feed method, it can be reused to precipitate additional water-insoluble salts. In another example, "An example of an electrified battery with the same battery type t, except for the second multi-unit military pool which is used in the military position pool of the bipolar sister state." Described in HB7 ; Draw 7 is a kind of electrochemical battery 90 "To be displayed" < • Children's battery 90 contains the first limit 91 · the first Yin plant 92 and starts at the first station »91 · the first anion S selective Membrane 93 ·· The first ionic selectivity _ 94, the second 険 pole 95 ·, the second hibiscus 96 ·, the second yin-selective membrane 97, and the second Ν »selectivity» 198 The unit of order is 霣 池. It is explained that the battery 90 of _ 7 contains six intervals; that is, the first recovery interval of no salt or acid. -40 · This paper Λ degree is applicable to the Chinese national standard (CNS > A4 size (210X297 mm) ) (Please read the note f on the back before filling this page). Assemble and order the seal of the Central Ministry of Economic Affairs and the Seal of the Shellfisher Consumer Cooperative *. A7 £ 7_ V. Description of the Invention (VI) 99 {第一 进 料 闰 PR100 ·, The first recovery compartment 101 ·, the second inorganic salt or inorganic acid recovery compartment 102, and the second feed compartment 103 and the second recovery compartment 104 S batteries are preferably used with three Use any one of the steps in combination. · In the operation of the electrochemical cell described in circle 7, · Dispense the aqueous solution into the eaves or eucalyptus recovery and recycling. The water insoluble curtain will include water-insoluble curtains.-Organic鼸 and / or organic hydroxide solution is fed to the feed HI.

Establishes and maintains a stream of K-shaped cross-border ponds between the I and depolarization poles / therefore insoluble salt •, susceptible larvae with radon and / or argon oxide are attracted to the radon and When the first or second NR selective membranes 94 and 98 enter the recovery intervals 101 and 104, they are simultaneously water-insoluble, and the deionization of susceptible salts and / or tritium hydroxide is attracted to This is through the first or the second negative insert selective membrane 93 or 9 7 into the inorganic rhenium or osmotic acid-free recovery interval 9 9 and 102. The organic ions and hydroxide ions are combined in the recovery intervals 101 and 104. The desired organic argon gas f is generated and the organic hydroxide is recovered from the recovery chambers 101 and 104. > The combination of anion and curcumin M produced acids or bribes in the recovery intervals 99 and 102 of inorganic gadolinium or eucalyptic acid; and then recovered the acids or gadolinium from the inorganic gallium or non-acidic acid recovery compartment 99 and 102 When using the continuous ore method, it can be reused for additional water insolubility of the CK sink. In another «embodiment · # A type of multi-military battery unit included in the dual configuration battery / description in circle 8« · 8 is a summary of a type of battery 11Q 酾Indicated · "The 霣 霣 110 110 contains the first carving pole m • The first 捶 捶 112 and begins with the first« 111 ·, the first male Yang Zixiong-4 1-Chinese paper standard applicable to the paper scale ( CNS) A4 specification Τ210χ297 ^ | Γ) (Please read the note ^^ on the back before writing this page) d Binding. 4! Λ Printing policy of the Central Consumer Samples Office of the Ministry of Economic Affairs, Consumer Cooperatives A7 __B7_ V. Description of the invention (彳) Selective membrane 113 ·, the second ion selective membrane 114, the second negative ion 115, the first 4 second anode 116 > the third positive song 遘 volatile membrane 7 and the fourth limiting ion 遘Sequence of optional _118. 》 As explained in _8, the Xiaohua Xiaochi 110 contains six Confucianisms; that is, the first feeding interval 119 ', the first meeting interval 120, the first recovery interval 1 * 121, and the second feeding interval 122 · The second communication interval 12 3 and the second recovery interval 124. The third step of «A better tank, a better tank, and a lower one" can be used in combination in the operation of the 霣 8 霣 Chemical Tank. • Feed the aqueous solution to the through edge and the feed room. 丨A solution containing krypton or argon-like gas is fed to the feed interval. Establishing and maintaining a potential M between the N1 electrode and the cathode produces a current across the cell / so there is a hydrazone salt or organic hydroxide. The starvation is attracted to the cathode to pass the first or second Ion volatile membranes U4 and 118 enter the individual recovery intervals 121 and 124. The ions are ionized and merged with the hydride sickle in recovery intervals 121 and 124 to produce the required erbium oxide. Then there is a specific embodiment of the «Plutonium oxide is recovered from these recovery intervals 121 and 124 * < > Electrochemical« pool. The _9 in / Sleep 9 is a general formula of the fluorinated Xiaochi 130: The tritium pond 130 contains a hibiscus 131, a depolarizer 13 2 and a unit which starts at the anode 131; the first positive Sickle selective membrane 133 and the second positive cation selective membrane 134 «Chem« 130 Contains three intervals & namely, feed interval 135, open interval 136, and recovery interval 137. · A large pool can be used in combination with the third step of the three available steps. __ 4 2 _ This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) — (please first (Read the Note $ on the back and fill out this page)

Order m. A7 _B7_ V. Description of the invention (M) In the description of "9" in the work of "Pond 130", ν will feed the solution containing organic 81 or tritium hydroxide to the feed room and broadcast 135 « Water is fed into the pass interval 136 and the recovery interval 1370. Establishing and maintaining a square position between the cathode and the cathode generates a current flowing across the pond, and therefore the organic refractory with salt or thorium hydroxide is attracted to the meridian and the passivation ion The selective membrane enters the recovery interval 137, and thorium ions are merged with the radon gaseous ions in the recovery interval. The organic thorium oxide impurities required for production are attracted to the separator; and / or they are not attracted to the cathode and / Or they can't pass through the ion selective supply "and / or remain in the feed interval, the purified bound hydroxide is formed and recovered from this recovery interval 137 / tritium« another of the pool «embodiment Explained in 10/10 is a kind of electrification «pool 140" containing two units 罨 池. The tritiated battery 140 includes an anode 141, #cathode 14 2 and starts at the cathode 141, the first polar film 143¾, the first meteoselective membrane 144, the second bipolar membrane 145, and the second cation selectivity. Sequence of the films 146. The bismuth fluorenes 14 3 and 14 5 have an anion selective surface facing the anode 141 (not shown) and a cation selective surface facing the cathode 142 (not shown). The electrochemical cell 140 includes five intervals, that is, the water interval 147 > the first feed interval 148, and the first recovery interval 149 9 Ψ

I, the second feed interval 150 and the second withdrawal interval 151. It is better to use the "three-step" third step of the three available steps. "Combined use in the operation of" Hua «Pond 140" of awakening 10, feed the solution containing organic hydroxide To these feed intervals 148 and 150 / feed water to the recovery booth. , Feed water and ionic compounds into the water _ ·. In the anode and -4 3-This paper size applies Chinese National Standards (CNS) M specifications (2 丨 0X297 mm) (Please read the note on the back before filling this page) oi Packing. Order the central standard of the Ministry of Economic Affairs Industrial and consumer cooperative printing 4 A7 B7 V. Description of the invention (V) Establishing and maintaining a bit K between the depolarizers generates a current across the pond, so the Liyang carving of organic hydroxide is attracted to The cathode and the pass through the first or second I »ion are selectively 嫫 14 4 or 14 6 into the decantation recovery interval 14 9 or 151. The shovel-limited shovel is used to collect the argon oxide ions in the recovery broadcast 150 to produce the entrained hydride γ impurities that are attracted to the hidden electrode and / or they are not attracted to the cathode, and / or they do not pass Cationic volatile membranes pass through the edge and / or remain in the admission interval. Regeneration is "Argon oxide formed and recovered from these recovery intervals 15 2 and 155," In another example, The electrochemical cell containing the multi-unit Xiao pond of the second-stage unit cell that K bipolar sister should use is described in _11, circle 11 is-spike contains the first anode 161, and the first depolarization is 16 2 and starts at At the first cathode 161, the first bipolar waist 163, the first cation selective membrane 164: the second cathode 165, the second I »pole 166 / the second bipolar 臜 167, and the second ridge selectivity membrane. The main illustration of the sequence 168 of the battery 160 is shown. These bipolar membranes have a volatile side (not shown) facing the anode, and an erbium ion-selective side facing the cathode (not shown). Six intervals, ie, the first water interval 169, the first feed interval 170 i printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs «., The first recovery interval 171, and the second water interval 172 i the second feed interval 173 and the second recovery interval 174 «One battery can be used with three available materials. The solution is built into the solution containing the water solution. The water will be 0, anion 1 and 丨.搡 Into the separated room 丨 Pond mixture ° »霣 Inject the chemist to the sum of the electric carving material into the group 11. The water and liquid circle will be dissolved. • The individual partitions of the three-story interstitials are in the gaseous hydrogen returning to the eaves -------- 0 ^ — — (please read and read the note on the back before writing this page) -44 -This paper size is applicable to Chinese National Standard (CNS) A4 specification (2 丨 0 × 297mm) 41 Printed by the Sheller Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs «. A7 B7 V. Description of the invention (IV,) Establish and maintain a potential Μ generated Current across the battery • The organic meteorological sickle with eaves hydroxide is therefore attracted to the broadcast pole where it passes through the first or second meteorological ion selective membranes 164 and 16 8 into the individual recovery intervals 171 and 172. 》 The ions are combined with the hydroxide sculptures to produce the organic hydroxide that is required in the recovery limits 171 and 174 / and then recover the plutonium oxide from the recovery limits 171 and 174. · Because the desired product is an organic osmium oxide; the recovery interval contains water / ferment, or liquid with a liquid solution or a mixture of water and yeast and / or organic solvents, but only if the recovery interval contains sufficient Water so that the desired hafnium oxide can be formed or regenerated. The word regeneration uses M to indicate that the organic ions and argon oxide ions from the circulating argon oxide are present in the solution. Can the operation of the method of the present invention be continuous or batch? The operation of the method according to the invention can usually be flail and some intervals can be looped without interruption. The cycle is generated by the pump 10 and / or by gas venting. Various materials can be used as the electrochemical seeding in the pond. , For example / limited 榧 can be made of metal (such as 呔) coated electrodes, giant, 雎, 绐 or alloys of these gold 羼 • * 丨 usually #, these 隈 electrodes will have non-passivable and catalyst films Precious metals such as platinum, iridium, or alloys thereof, which may contain metals, or mixtures of at least one precious metal such as platinum t, iridium, ruthenium; oxides of palladium or rhodium, or oxides of mixed gases . # 在 一个 佳佳 《In the Example • «Extremely dimensionally stable electrodes such as a titanium substrate with ruthenium oxide and / or vaporized iridium on it > > 巳 is used as an electrode in an electrochemical cell Various materials can be included in use (Write this page)

• 1T, line

• I Printed by the Consumer Cooperatives of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs A7 B7 V. Description of the invention (A) In the fans of this invention and other legally qualified pools. The materials of Chen Li include susceptible, susceptible, stainless steel, titanium-plated, titanium *, graphite *, carbonaceous (susceptible), or alloys thereof. Term: "alloy" is used in a wide range of Changxiong and includes a homogeneous mixture M of Jin Yang or M and one gold tincture coated on another gold tincture. Combination with the three possible steps * of the method of the present invention The used electrochemical cell contains at least one separator ~ for example, hunger 挥; and at least one bi-sexuality as needed _ Ϋ interval is defined as a region between two or less j partition and / or bipolar membrane And / or anode and / 成 阴 檷. 分 «物 和

I / or bipolar membranes can be used as expansion barriers and / or gas separators. The separators that can be used in the present invention can be selected from a wide range of microporous expansion arrays, screens, filters, membranes, etc. It contains pores of the required size to allow the ions of organic plutonium oxides (such as fins) to migrate to the pole. The microporous separator can be made from a variety of materials; including plastics such as polyethylene, polypropylene, and Teflon * ceramics, etc.% For example, in addition to the separators listed in the illustration • Microporous separators can be used For example, non-ionic separators. Specific examples of microporous separators that can be used on commercial dishes include / Cel-anese Celgard and Norton Zitex. The microporous fraction is particularly effective when the method of the present invention is used to purify higher molecular weight organic phosphonium oxides such as n-tetrabutyl hydroxide and tetra-n-butylammonium hydroxide. · The ion-selective membrane used in the cell and method of the present invention may be any of those that have been used in the chemical purification or regeneration of rhenium hydroxide. Better: Suspected ion-exchange catalysts should contain highly durable materials such as membranes based on fluorocarbons or less expensive from polystyrene or polypropylene queues. 4 6 _ This paper applies Chinese national standards (CNS > Α4 size (210 × 297) ((Please read the note on the back before filling in this page); Binding and ordering A7 ___B7___ V. Substance of invention description (β). However, *, better, used in The invention of the "ionistic volatile bag

I includes fluorinated membranes containing optional ion-limiting groups; for example, perfluorosulfonic acid and perfluorinated sulfonic acid and / or perfluorocarboxylic acid. Kffl_ "Nafion ", such as DuPont's cationic Nafion 902 waist seller. Other covalent cationic selective films include styrene divinylbenzene copolymer films Base

I, Louate * and other Raipore Cationic R1010, (available from Pall RAI), and NEOSEPTA CMH and NE-OSEPTA CM1 membranes from Tokuyama Soda, particularly useful for higher molecular class IV compounds The preparation and structure of subselective membranes are described in the encyclopedia of chemical technology (E π cyc 1 〇pedia 〇f C hebica 1 T echn ο 1 〇gy) entitled "Membrane Technology (M e ai brance T ech η ο 1 ogy) * in the chapter, K irk-01 her, third edition, volume 15, pages 92-131, father and son · Weiss, 1 985. Therefore I »* * The number of pages is incorporated here for Reference is made to a variety of osmium ion S selective membranes which can be used in the method of the present invention. It is preferred to use at least one cation selective membrane 9 in a chemical tank. The membrane includes such membranes that are used in the micro-water removal method. It is better that the membrane should be in the pond according to the phase.

% I Special anion (such as * halide ion) selective eliminator. The preparation and structure of the selective membrane are described in the chapter of the encyclopedia of chemical technology {| 1 for "membrane technology". * er · Third Edition, Volume 15, Pages 92-131. Fence & Sons, New York · 1985 丨 This page is hereby incorporated by reference for the various anions shown which can be used in the method of the present invention Optional film-4 7-This paper size applies Chinese National Standard (CNS) Α4 specification (210 × 297 mm) (锖 first read the note on the back and fill in this I)-Pack.

Printed by the Central Bureau of Standards of the Ministry of Economic Affairs and the Industrial and Consumer Cooperatives 44 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs and Industrial Cooperation Du printed A7 B7 V. Description of the invention (0) It can be used in chemical batteries and is commercially available as follows: AMFLOH, 糸 310, M quaternary ammonium group-substituted fluorinated polymer produced by the United States eaves and 锢 造 company as the matrix , I0HAC ΜΑ 3148, ΜΑ 3236, ΜΑ 3475, Μ are derived from Ritter- Qin ·

The quaternary ammonium-substituted polymer of Heterogeneous Polyvinyl Chloride produced by Pfaulder's Synthetic Zeolite Division is based on rhenium, Tosflex IE-SF34 or IE-SA 48v manufactured by Tosoh Corporation. Stable

臌;, NEOSEPTA AMH, NEOSEPTA ACM, NEOSEPTA AFH or NEOSEPTA ACLE-SP from Tokuyaaa Soda; and Selenion AMV and Selenion AAV from Asahi Glass. In a specific embodiment *, Tosflex IE-SF34 and NEOSEPTA AMH (R) seed exchange membranes are preferred because they are in a residual solution (such as a hydroxide-containing solution formed in the method of the present invention). ) Stability #. The bipolar membranes used in these chemical baths are composite membranes, which include three parts: the cationic selective side or region, the yin zongzi, the two or the region parameters, and The interface between the two regions. . When the DC flow crosses the polar film, it is cationic and lateral or facing the depolarization. • By H + and OH — ions (which can be produced by hydrolysis at the interface under the influence of the field). The transmission is achieved > Bipolar membranes are described in / example of the United States, 2,82 9,095, 4,024,043 (single-film bipolar membrane) and 4,116,889 (flat extrusion bi-layer membrane). The double-sex films used in the method of the present invention include NEOSEPTA BIPOLA 1 'WSI BIPOLAR and Aq- 4 8-¥ of Tokuya ^ a Soda. The paper size is applicable to China's national standard (CNS > A4 size (210X297 mm) j ------- d (please read the note f on the back before filling this page)-装. Order # Α7 Β7 V. Description of the invention (β) ualytics dual-layer film. It is the direct current that is generated by the application of a current between the anode and the cathode (usually a direct current), which is the direct current of the design and performance indicators of the pond. (It is known in the art as (Easy to know and / or can be determined by routine experimentation). Generally "flow density is between about 0.1 and about 50 amps per square inch, and preferably electric density is about 1 and Between about 10 amps., Higher or lower "flow density can be used for certain special applications < >« flow density "is added to the battery for a time sufficient to form the desired amount or concentration of organic argon gas, In the period including the step of electrolysis "the pond," it is usually hoped that: The degree can be maintained within the range of about 5 * 0 to about 75 * C, * preferably about 25X3 to about 45Ό, and the special good degree is maintained at about 35 * Ct. It is also during the step including the battery 霣. It is generally expected that the pH of the liquid in the battery is salty or * acidic. In one embodiment, the pH of the feed interval is about 1 to about 13, preferably about 4 to about 10, and the water interval The pH is about 0 to about 14: the recovery interplanting pH is about 12 to about 14%. The pH of the pass interval is about 12 to about 144, and the pH of the inorganic acid or salt recovery interval is about 0 to about 4. The method of plutonium is a purification method that includes argon oxide ions and / or acid ions. • The pH changes when the method is carried out. • Especially when the method is carried out .. PH usually «

Add ,. V Although not willing to be limited by any theory, according to the present invention, the operation of chemical batteries is based on (in part) the occurrence of tritium gas due to the application of tritium. interval. . -49- This paper size applies to China's national standard (CNS > A4 size (210X297 mm) -li ........——_ _____________________-------- ------ -(Please read the note on the back before filling out this page) σ Pack. Order printed by the Shellfish Consumer Cooperative of the Central Elevator Bureau of the Ministry of Economic Affairs

Printed by the Central Standard of the Ministry of Economic Affairs and Consumers' Cooperatives I A7 B7____ V. Description of the Invention (Red) The following examples illustrate the method of the present invention. Unless indicated otherwise, in the following examples and elsewhere in the description and in the application, * All All parts and percentages are measured by a house scale. All irrigation degrees are in degrees Celsius. And the pressure is at or near atmospheric pressure. Fenbian Li 1 Add peroxyacid to 1M aqueous TMA, 7.04 PP * sodium, 33 ρρ · «Potassium and various tetrakimonium ammonium chlorate-producing waste liquids that produce sunk. Glycerol tetramethylammonium perchlorate is collected by filtration and added to water to form a second solution (tetramethylammonium is not completely dissolved in water with chlorate). The second solution was fed into the feed interval of the cell according to · 2. The salient pole is made of titanium coated with ruthenium oxide, and the cathode is made of chain / water is fed to the recovery interval and the inorganic acid or non-interval interval plus a bit to thereby cause the top four The ammonium cations move to the hibiscus, and the concentration of tetramethylammonium hydroxide in the recovery interval is reduced by the amount of tetramethylammonium hydroxide in the recovery interval. The concentration of tetramethylammonium hydroxide in the recovery interval is 1.18ΜΜ. 〇.65ρρ · sodium and less than 0.28ρρ · potassium and there is no non-TMAH suspected gold ions. Fenque 2 Add hydrogen acid to a waste liquid containing 1M aqueous TMAB, 7.04 ρρ · sodium, 33 PP · potassium and various organic substances that produce precipitated tetramethylammonium iodide, and collect the solid by purging. Tetramethylammonium iodide was added to the sound and a second solution was formed (the tetramethylammonium sulfide was not completely dissolved in water). The second solution was fed into the feed interval of the electrochemical cell according to circle 5. t The anode is made of titanium coated with ruthenium oxide, and the cathode is fed back to -50 with water that is formed into the water.-This paper size applies to China National Standard (CNS) A4 specification (2 丨 OX297) ) (Please read the note ^^ on the back before filling in this page)-Packing. Thread A7 ____B7_ V. Description of the invention (called) Within the interval between the free space and the inorganic acid to form an inorganic salt 丨 Dilute the sulfuric acid The aqueous solution is fed to the water and 嗝 ξ 雎 plus one bit to thereby cause tetramethylammonium »to move the cathode to the cathode. In the recovery compartment, argon oxidized tetramethylammonium with reduced gold content is generated. The concentration of tetramethylammonium hydride in the recovery interval is 1.18 M or more, the recovery interval also contains less than 0.6 5ρρ · nano and less than 0.28ρρ · potassium, and there is substantially no non-TMA non-fluorene metal.

For the IS, the 1M tetramethylammonium aqueous solution (mixed with tritium oxide and gaseous) containing 6 · 3 ρρ · n '0.93 ppi potassium was fed to the feed-recovery interval of the tritium pond according to _1 The inner spacer is made of titanium coated with ruthenium oxide and / or the pole is made of nickel. 0.1M HC1 solution is fed to the waste solution space. Apply 11 Α 霣 flow for 11 hours. From the feed 1 recovery room, the recovered solution contains 0.9 6M argon oxidized tetramethylammonium and chlorine; 3.2ρρ · nano and 0.34ρρ · potassium. The "卩" pole is made of titanium coated with ruthenium oxide, and the depolarizer is made of nickel. Water is fed into the recovery and pass-through interval; a megamechanical position is used to cause tetramethylammonium ions to the cathode. Move; thin to produce tetramethylammonium hydroxide with reduced metal and organic in the recovery compartment. The concentration of tetramethylammonium argon oxide in the recovery interval is 1.2 MK. The recovery interval also contains less than 3 PP · nano and less than 0.3 PP · potassium and there is substantially no non-TMA organic metal. Hydrogen acid is added to the waste solution of the fourth-stage hydroxide, thereby forming a fourth-stage chloride solution. The solution contains 1.0 5% quaternary ammonium gasified and 0.91 ρρ · -5. The paper size is applicable to China's national standard (CNS > 乂 4 ^ (210 × 297 mm)) (Please read the note f on the back before filling (This page)

Order the seal of the shelling consumer cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs A7 __B7_ of the Central Bureau of Standards of the Ministry of Economic Affairs. The pressure tank was equipped with MPF-34 nanometer lift filter. One and a half of the quaternary ammonium chloride solution was forced through the membrane at a pressure of 450 psig. The portion of the solution without 15 membranes contained 1.7% quaternary ammonium vapor and 0.92 pp · »^. This solution was fed into the feed cell of a chemical tank according to _2. The emitter is made of ruthenium oxide-coated hafnium and the cathode is made of hafnium. Water is fed into the recovery interval and within the eucalyptus or inorganic K interval. Applying a nib to thereby cause the tetramethylammonium-restricted sculpture to move toward the pole, and by using M to produce tetramethylammonium hydroxide with reduced «less gold 羼 and mixed 霣 ，, in the recovery. The concentration of tetramethylammonium hydroxide in recovery m was 1.2 MM. The recovery interval also contains less than 0.5 ρρ · •. Sodium and is substantially free of non-TMAH ferrous metals.

Fen Li Li added hydrogen argon acid to the waste solution tank of the quaternary ammonium hydroxide to form a tetraphosphonium ammonium chloride solution. The solution contained 4.7 7% of quaternary ammonium chloride and 1.77 ρρ ·% nano. The pressure cell was equipped with a Desa 5 nanometer filter membrane. One-half of the solution of quaternary ammonium chloride% 4 was forced to pass through the membrane at 450 psig. The portion of the solution without a through-membrane contains 6.35% tetraammonium chloride and 1.77 ρρ · ,. This solution was fed into the feed chamber of a chemical tank in accordance with country 2. "The pole is made of titanium coated with vaporized ruthenium, and the pole is made of suspicion. "Water is fed into the recovery interval and between the inorganic acid or the inorganic ions, and a potential is applied. This causes the tetramethylammonium isolator to move to the cathode. The hydrogen is used to reduce the metal and organic impurities during recovery and sowing Tetramethylammonium technology, the concentration of tetramethylammonium hydroxide in the recovery interval is 1.8 HK. The recovery interval also includes organic golden rats less than 1 ρρ · nanometer and substantially free of non-TMAΤ. -52- This paper size applies to Chinese National Standards (CNS > Α4 size (2 丨 0X297mm) (please read the note on the back before filling in this page)-installed _-, 11 Central Bureau of Standards, Ministry of Economic Affairs A7 B7 printed by the Industrial and Commercial Cooperatives Fifth, the description of the invention (M) Fen Li ft added sodium bicarbonate to the waste solution of the quaternary ammonium hydroxide to form a quaternary carbon ammonium solution. The solution contains 0.095 % Ammonium quaternary ammonium carbonate and 0.91 ρρ · nano. The pressure cell is equipped with an MPF-3 4 nm pass membrane. One and a half of a four's ammonium bicarbonate solution is forced through the membrane at a pressure of 4 50 psig. • None The part of the solution that passes through the membrane contains 0.149% of quaternary ammonium bicarbonate and 1.75 ppb nanometers. This solution is fed into the feed interval of the 霣 5 chemical tank, the anode is coated with ruthenium oxide It is made, and the hydrazone is made with the susceptible 'water feed to the recovery interval and the inorganic acid or inorganic salt, and the TMAH solution is fed to the water interval to apply a potential to thereby cause the tetramethylammonium limit. As the ions move towards the depolarizer, Ping Yi produces hydroxides with reduced metal and organic impurities in the recovery interval. Tetramethylammonium. The concentration of tetramethylammonium hydroxide in the recovery interval is 1MM. The recovery interval also contains less than 0.5ρρ · nano and there is no non-TMAH organic gold tincture. 瞀 妩 利 7 The sodium bicarbonate Add it to the waste solution of quaternary ammonium hydroxide to form a quaternary ammonium bicarbonate solution 4. This solution contains 4.01% quaternary ammonium bicarbonate and 0.6 9 buckles) "Nano \ Pressure battery pack 〇88 88 1 -5 nanometer filter membrane. One-half of the four-stage broken% ammonium bicarbonate solution was forced to pass through the plutonium at 450 psig. The part of the solution without a membrane is composed of 5.8 3% quaternary carbon ammonium hydrogen and 1.28 PP. This solution is fed into the feed interval of the tritium tank according to _4. The separator is made of ruthenium oxide. The coated peptide is made of hydrazine, which is made of suspicion, and the water is fed to the recycling, through the interval with inorganic acid or eaves. Imposition -53- (Please read Note 11 ^ on the back before filling out this page) • Binding. The size of the paper is applicable to the Chinese National Standard (CNS) A4 (210X297 mm). Printed by the Consumer Cooperative A7 __B7_ V. Description of the Invention (0) A box of four places caused the four-year-old prostitutes to move to the danger station t • 台 to produce argon oxidation with reduced gold ions and organic male ions in the recovery compartment. Tetramethylammonium. The tetramethylammonium hydroxide splash in the recovery interval was 1.5MM. Recycling booths also contain organic gold badges that are less than 1.1 PP · N and are not non-TMAH qualified. Fen_ 锎 8. A waste solution containing water-based 2.5% TMAH, 3.75PP · potassium and various organic substances will be commercially available and a polymer containing crown brew (a formamidine and dibenzo 18-S ether-6 The product) was pushed through 'separating the solution from the polymer and collecting it by Yu. The second solution is fed into the feeding interval of the electrochemical cell according to · 8. The electrode is made of a peptide coated with ruthenium oxide: and the cathode is fed to Within the recovery and communication interval. The application of one site caused the tetramethylammonium ion to transfer to the yin, and I used the K to generate a regenerated hydrogenated tetramethylammonium hydrogen recovery chamber in the recovery interval with reduced gold ions and reduced susceptible ions. The concentration of tetramethylammonium hydroxide is 8% M. The recovery interval also contains less than 0.58 ρρ · potassium and is substantially free of non-TMA fluorinated metal. «Fen Yan Li 9 · A waste solution containing 2.5% water-based TMA, potassium 340 ppb and various kinds of suspected gadolinium and a commercially available crown ether-containing polymer (a formaldehyde gallium dibenzo 18-crown ether- The product of 6) shoved 4. Separate the chick solution from the polymer and collect it by side filtration to feed the second solution into the feed compartment of the electrochemical cell according to the garden 8. Rhenium is made of ruthenium oxide-coated rhenium, and He Luji is made of unbelievable. Water and sculpture compounds are fed into the recovery and communication facilities. Shi

I -54- This paper's flt scale is applicable to China National Standard (CNS) Α4 specification (2 丨 0X297mm) -------- OI package— (Please read the “Notes on the back side” before filling this page) Order A7 B7__ V. Description of the invention (θ) A potential is added to cause the tetramethylammonium ion to move to the hibiscus, and by using the tritium in the recovery interval, the regeneration of argon oxidized tetramethylammonium with reduced metal and eaves quality is achieved. Ammonium. The concentration of tetramethyl hydroxide in the recovered W partition is above. The commercial collection M also contains less than 17 ppb potassium and there is no organic metal other than TIMA, and the present invention has been explained in the related preferred embodiment. Its t will be understood to be its various modifications to Those who are familiar with this technique are obvious and easy to understand when reading the instructions. Therefore: it will be understood that:

• I The additional claims of the present invention contain the amendment>. (Please read the note on the back before filling in this page)

OI-Outfit ·

. • IT, line Printed by the Central Government Bureau of the Ministry of Economic Affairs of the Bayan Consumer Cooperatives -55- This paper size applies to the China National Standard (CNS > A4 size (210X297 male thin))

Claims (1)

Printed by the Central Government Bureau of the Ministry of Economic Affairs of the EC Industrial and Consumer Cooperatives *. A8 B8 C8 ______ D8 'Patent Application Scope · A method for recovering eaves gas from a waste solution containing thorium hydroxide and impurities, including: : Completion of one of (ash 1 & -ash 11 >), (ash 2) and (ash 3), (Ala) impregnating the organic hydroxide from the waste cable solution as insoluble tritium; and 9 (Alb) from Remove the insoluble plutonium from the solution and place the plutonium in a liquid to form a second solution; (A2) or (A2al) feed the waste cord solution to include at least two plutonium intervals, a cathode, a pole, and The first chemically-separated battery, and the current is passed through the first chemically-suppressed battery / thus the impurities are transferred to the size of the volatile separator; 4 (A2a2) is recovered from the first chemically-suppressed battery and contains A second solution of organic chicks; or (A2bl) forms a first solution (A2b2) containing waste and impurities from the waste solution. The first solution is brought into contact with the selective sulfonium under pressure, where # at least a portion of the impurities pass through Size-selective membrane, thereby providing a second solution (A3) containing guns and reduced impurities The waste solution is contacted with the gold ion ion scavenger K to remove the gold ion ion substance * where step (A3) is before or after steps (B) and (C) »成 成; · (B) will be obtained from (Alb) The second solution, the second solution obtained from (A2a2) or (A2b2), or the waste cable solution obtained from (A3) is fed to a first solution containing at least two compartments, a cathode *, a stand, and a separator. Battery (% please read the note on the back before writing the match) ο Binding, binding line, and paper size in use "National Standards (CNS) A4 (210X297 mm)) Printed by Zhengong Cooperative Cooperative A8 B8 C8 _ D8 VI. In the scope of patent application and the «circulation through the first« chemical tank to regenerate the hydrogenated hydrocarbons; and (C) the recovery of tritium oxide from the first battery Things. 2 · —A method for recovering organic «oxides from a waste solution containing thorium hydroxide and thallium hydroxide: including: (A) immersing thorium hydroxide as insoluble thorium from the waste solution; and 4 (B ) Remove the salt from the waste solution and place the mash in a liquid mash to form a second solution;% (C) Feed the second solution to a solution containing at least two interlayers, a cathode, and a * «separator Neutralize the galvanic cell with the separator and pass m through the battery to regenerate the organic argon oxide; and (D) recover the tritium hydroxide from the battery. % 3. The method according to item 2 of the Shenyang Patent Fanyuan, wherein the insoluble salt precipitated in step (A) is at least one hydrazone, hydrazine, and sulfonium salt. Good 4. The method according to item 2 of the Shenyang Patent Fanyuan, wherein the eaves hydrogenate in step (A) is obtained by adding a non-water or inorganic acid to the waste solution. 5. According to the application Two methods, in which the tritium cell includes at least four intervals, a cathode, a limit, and the order from the pole to the cathode is, bipolar membrane, yin sickle selective membrane, and The ion-selective membrane / second solution is fed into the space formed by the deionized and ion-restricted membrane, and the hafnium hydroxide is recovered from the space formed by the cationic-selective membrane and vulva . tr This paper size is applicable to China • Furniture Ratio (CNS) A4 specification (210X297mm) --------- II (please read the note f on the back and fill in the cold copy) Order 41 R2 IR 、 N-R3 I R4 A8 B8 C8 ^ ___ VI. Application for patent scope β. According to the method of applying for Lifan _ Item 5, in which the inorganic salt is formed from the bipolar membrane and the Yin sickle «selective The space formed by the film is recovered. 7. According to the method of patent application No. 2 >, "The cell contains at least three compartments, a cathode, ν-anode, and the order from separator to depolarization is / anion-selective ion. The second solution is fed into the barrier formed by the anion and ion-selective ion, and the argon oxide is formed from the ion-selective ion and the cathode. Recovered from the intermediate ffi 0. 8. According to the method of the patent application Fanyuan Item 2, in which «% of the solution solution * the organic oxide is quaternary ammonium hydroxide OH represented by the following formula: (III) R 1, R2, R3, and R4 are alkyl groups containing 1 to about 10 carbon atoms,% aryl groups: or R1 and R2 are alkyl groups that together with nitrogen atoms can form aromatic or non-aromatic fluorene rings, but their Provided that if the heterocyclyl contains C = N- · R3 is a second bond. \ 9. A method for recovering quaternary hydroxide from a waste cable solution containing quaternary hydroxide and impurities 丨 including: (A) Caching the quaternary hydroxide as water insoluble from the waste cable solution "; (B) Add quaternary salt from the waste solution to one solution * »This paper size is in accordance with China National Standard (CNS) A4 (210X297 mm) -------- ------ TT ------ om (Please read the note on the back before filling in this page) The Central Rubbing Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperative, printed oxygen 'Apply for a patent solution to solidify the second solution;% (C) Divide the second solution to contain at least two intersects, one cathode and one (please first read the note $ Item on the back and then #write this page) I neutralize the hydrangeas and separators in the plutonium tank and pass the current through the cell t to thereby regenerate the fourth-level hydroxide in the battery; and (D) recover the fourth-level argon oxide from the plutonium P according to the application The method according to item 9 of the patent, wherein the quaternary argon oxide is precipitated in step (A) by adding an inorganic plutonium or an inorganic acid to the waste solution. ♦ Π. Method according to Patent Application _ Item 9 where «Batteries include at least three intervals, one cathode, one hibiscus, and the order from attention to cathode is \ The second solution is fed into the membrane formed by the female membrane and the ion-selective membrane, and from the ion-selective membrane and the cathode. Recovery of Tetrahydroxide Hydroxide from the Ladder Formed by Seeding 12. 12. A method for recovering eaves hydroxide from waste solutions containing organic hydroxides and impurities% includes: Printing by industrial and consumer cooperatives (A) Feed the waste solution to a tank containing at least two compartments; a cathode, a hibiscus, and a large and small volatile separator in the first tank and pass the electricity to the tank , So that the impurities migrate through the size-selective separator t ♦ t (B) recover the second solution containing thallium ions from the first «chemical« cell and feed the second solution to at least two compartments, One depolarization. One anode and separator of the second electrochemical cell and the second paper A Xiao uses the Chinese National Standard (CNS) A4 specifications (210x297). J | ..... --- A8 B8 C8 ----- D8 VI. Patent application for chemical treatment of chemical tanks, to purify cyclic hydroxide and (c) Recovery of organic hydroxide from the second chemical reaction tank; 13. Method according to item 12 of patent application 'Further includes increasing the concentration of radon gas in the contaminated solution before step (A) I. 14 · According to the method of applying for the benefit of the project No. 13 _ which includes the hydroxide splash plus steps including at least one evaporation f, electroosmosis or reverse osmosis / 15. According to the application of the project Method 4 • In which the organic hydroxide is a quaternary ammonium hafnium oxide: a quaternary ammonium halide oxide or a tertiary hafnium hydroxide / 16. According to the method of application No. 12 of Lilifan, • the first of which The size-selective separator of the cell is a cation-entangled membrane. 17. The method according to item 12 of the patent application: where the first puppet «pool includes at least three compartments, a cathode, a limit pole, and the order from the broadcast pole to the hibiscus is, double-sex, and size Selective membrane-limiting ion s-volatile membranes. * In step (A), feed the waste solution into the space formed by the bipolar europium and size S-selective ion-selective membranes, and in step » (B) The second solution is recovered from the gap formed by the bipolar membrane and the size-selective ion-limiting selective membrane. 18. The method according to item 12 of the application patent application * wherein the second tritiated battery pack Include at least three intervals *, one cathode, one hibiscus, and * the order of% from the anode to the cathode is •, the first cationic selective film and the second sickle "selective film in step» ( In step (B), the second solution is fed into the space formed by the balcony and the first cation-selective volatile film and / or in step (C) from the space formed by the second positive-electrode volatile film and the cathode. Organic hafnium oxide is recovered. Turtle-5 'This paper size uses China National Standard (CNS) Α4 size (210 X 297 mm) -------- Q ^ .-- (Please read the note on the back side first. ## Manuscript X) Order the patent scope A8 B8 C8 D8 of the Central Government Bureau of the Ministry of Economic Affairs in the printing of the patent scope A8 B8 C8 D8 Ministry of Economic Affairs t Central Government Bureau Λ Industrial Consumer Cooperative Association's Seal 19 · —A kind of waste from guns containing hydrogen and impurities Method: (A) forming a second solution containing rust from a waste cable solution and (B) contacting the first solution with a portion of the sizing agent under pressure «size selectivity» and reducing the amount of male substance (C) feeding the second solution to a tritiated cell containing at least two meteorites and a separator to neutralize the purified epihydroxide; and (D) recovering the tritium argon oxide from the cell. »2〇 · According to the method of the 19th patent application, neutralize the waste solution with inorganic acid or inorganic rhenium. «21. According to the method of the patent application No. 19 *, the contaminated solution meets the ion exchange system. 22. According to the method of the 19th patent application, the selective membrane is a nanofiltration membrane. 23. According to the method of the patent application No. 19,% 0.1 resuspension from about 20% to about 20 weight jealous salt. 24. According to the method of Shenchai Yuli Fanyuan's item 19 •• Among which ® there are three less intervals • One cathode, one yang sowing, and 2 from 除 to depolarize, • Anion-selective membrane and anode furnace In step (C), the second solution is fed into the space formed by the selective selective ridge of the sculptors: and in step K (D > in the -6- solution, the first gun oxyhydroxide is recovered. Solutions. Selective membranes, liquids :: Confucian interstitial fluids pass through the pond / boring membrane / where at least this offer contains a gun depolarization / a where step (A) includes M where step (A) includes where The size in step (B) in which the second solution contains a reduction tank, including a sequential membrane to the depolarization / the membrane and the dysprosium are buried in the step by the cuckoo _ subselect (please read the note on the back side first) (Floor this page) ---- Installation ---- 11 orders α This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) Printed by A8 E84553 by the Bayou Consumer Cooperative of the Central Automobile Bureau of the Ministry of Economic Affairs! S _____ D8 _ 'The scope of the patent application is to recover iridium hydroxide in the space formed by the volatile film and the cathode. 25. According to the application The method of item 24 of Limeipu, wherein the method is submerged and recovered from the space formed by an anion-selective membrane and a soot-free or inorganic acid is used in step (A) to form K First solution 26 · A method for recovering eaves hydroxide from a grind solution containing eaves hydroxide and impurities including impurities of golden eagle carvings includes: (A) contacting a waste solution to remove the golden worms ffiM removes metal ions ♦ 9 I (B) feed the waste solution from A3 to a tank containing at least two 僩 intervals * one eliminator t, one limiter and separator, and circulate 霣埵 霣 池 ', regenerate 榇 hydroxide and / or (C) recover the hydrated hydroxide from the 霣 pond? 27. According to the method in item 26 of the Shen patent patent plaque, in step (A) Prior to increasing the concentration of the hydroxide in the waste solution, 28. According to the application of the method of Lifan painting item 27, which has the concentration of hydroxide, the step includes at least one "evaporation or reverse osmosis 29. According to The method of applying for patent No. 26, wherein the Jintang ion-eliminating agent includes at least one tritium Ether compound: a polymer containing an ether moiety and a polymer containing a crown moiety. 30. The method according to item 26 of the patent application circle, wherein the separator is a cryptic compound and obtained from (A The waste solution of) was fed to the space formed by the selective film of osmium and yangyangzi, and the organic argon oxide solution was recovered from the space formed by the selective ion and depolarization of osmium ion ... Applicable to Central China Kneading Rate (CNS) M specifications (210X297 mm) -------------- 1T ------ QI (please read the note f of 1 ^ face first) (Fill in this page) 384553 Α8 Β8 C8 D8 77, scope of patent application 31. According to the method of item 26 of Shenchai Lifanpu, where the organic argon oxide in the waste solution is quaternary ammonium cyanide oxidation represented by the following formula物 R, 3-R2— · Ν · 丨 R4 + ΟΗ- The Central Government Bureau of the Ministry of Economic Affairs, R & D, R2, R2,. R3 and R4 are alkyl groups containing 1 to about 10 valent carbon atoms, respectively. Group: or R1 and R2 are _ nature groups, which together with the nitrogen atom can form aromatic or non-aromatic heterocyclic rings, but the condition is that if the _ ring group contains C = N- *, then R3 is the second 鐽 32 . The method according to item 26 of the patent application; wherein the waste solution further contains an organic salt equivalent to an organic hydroxide. 33. A method 1 for recovering thorium hydroxide from a waste solution containing organic hydrogen hydride and impurities including gold rhenium impurities, including: (A) feeding the thorium solution to at least two compartments 丨A cathode a, a cathode and a separator in an electrochemical cell neutralize the thallium current, and there is a thorium ion passing through the separator and the thallium oxide is regenerated. (B) The organic hydroxide is recovered from the battery. Solution ,; (C) contacting the osmium hydroxide solution and the gold ions scavenger M to remove gold ions ions; ^ (D) recovering organic rhenium oxide. 34. According to the method of applying for 専 利范 园 item 3 3 •• Among them, gold ions ion scavenger-8-(please read the note on the back before filling in this page) Order-ο This paper is applicable to «Country 梂Standard (CNS) Α4 (210x297). E84 & 53 μ ___ D8 'patent application scope of the Central Government Bureau of the Ministry of Economic Affairs includes at least one cyclic ether compound and a polymer containing an ether moiety. 35. The method according to item 3 of Shen Lili Fan Guo | • wherein the separator is a cationic volatile film and the rejection solution is fed into the space formed by the anode and the separator 遘 volatile film, and the organic The argon oxide solution is recovered from the gap formed by cation-selective tritium and depolarization. 36. The method according to claim 33, wherein the ammonium hydroxide in the waste solution is a tetraammonium hydroxide R1 Γ-Ν-—R4 R3 + ο R 1: R2 ν · R3 and R4 are respectively a radical or aryl group containing 1 to about 10 涸 carbon atoms, or R1 and R2 test groups, which are _ (性 基 #, which together with gas atoms can form aromatic or non-aromatic groups Heterocyclic ring 丨 But if the heterofluorene group contains C = Ν-, then R3 is the second 鐽. · --------- 0 »^ .------ Order ---- --ο (Please read the note on the back of the item before buying in «copies») This paper size is based on the Chinese national rubbing rate (CNS > Α4 size (210X297 mm)