〔九丄一’. ；m nr h . ; — __7 v - v. ；( 五、發明説明（25) 加工部，並無塗敷上離模劑，结果就不必經過從來之先前 技術中之所利用之相當複雜之製造作業，而能夠製造出該 具有離模功能之包裝材料。 此外，本發明之包装材科，於進行密封加工處理之時* 在可K對於包装材料而附加上該與進行拉伸處理時之相同 外力的狀態下，由於可Μ同時地進行該在離模劑層上形成 有龜裂部之作業、Μ及密封加工處理，因此，並不需要預 先地對於包裝材料，進行拉伸處理，結果，能夠更進一步 地提高該密封加工處理之作業效率。 【元件編號之說明】 1 基材χ . < 2 離模劑層 3 黏著劑層 Α 包裝材料 B 衛生棉 C 密封加工部 P 龜裂部 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) S 拉伸方向 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公# ) _ 〇〇 _ 修正頁 A7 B7 ' 五、發明説明（1 ) 【技術領域】 本發明係關於一種具備有該能夠直接地包裝住各種之黏 著性物品並且還可以在由前述之物品上而將所包裝上之包 裝材料剝離掉之離模功能的包裝材料；若說得更加詳细一 點，即本發明係關於一種可以在離模劑層之表面，進行密 封加工（黏著加工）處理，而且遷擁有維持住離模功能的包 装材料。 【背景技術】 該作為用κ附加所謂之黏著功能至各種物品上的簡便之 手段，係大多利用黏著劑。例如衛生棉（M下則稱為紙巾） ，為了防止在使用該衛生棉時之偏雛現象產生，因此，在 該衛生棉之表面上，形成有黏著劑層。通常，像這樣之衛 生棉，在使用該剝離用紙而來保護前述之黏著劑層之捧， 再利用塑膠薄膜等之包裝材料，而個別地密封及包裝住整 個之衛生棉。在這樣之狀態下，藉由熱密封方式及沖壓密 封方式等之各種之密封加工方式，而密封該包裝住衛生棉 後之包裝材料的開口部。 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 另一方面，在最近，就該附加有黏著劑的衛生棉而言， 並不是使用該剝離用紙而來保護住該衛生棉之黏著劑層的 方式，而是使用該在表面上具備有離模功能之包裝材料而 來直接地包裝住衛生棉的方式；然而前述之方式，已經變 成為目前之主流方式。並且，該作為具有離模功能之包裝 材料，一般係使用該在由塑膠薄膜等之所組成之基材之表 面上而塗敷上矽酮糸等之各種之離模劑而構成之包裝材料。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公簸） -4 - B7 五、發明説明（2) 在使用像這樣之具有離模功能之包裝材料的狀態下，由 於並不需要該用Μ保護住前述之黏著劑層之剝離用紙，因 此，在使用衛生棉時，所產生之垃圾會變得比較少，結果 就經濟面而言，這樣之具有離模功能之包裝材料，也會變 得相當有利。 但是，在其基材表面上而形成有離模劑層的包裝材料之 狀態下，當企圖對於像這樣之包裝材料，進行密封加工處 理之時，由於該加工面係為塗敷上離模劑之表面（離模劑 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 ，因此，就不可能 性的密封加工處理。 此外，為了可Μ達成該具 加工處理，因此也提議有一 在基材上，僅在離模劑和黏 上離模劑，然而，在密封加 但是，由於像這樣之包裝材 為圖案狀，因此/比起該並 案狀之製造作業，前述之製 结果，就製品良品率等之觀 本升高之問題。 本發明係有鑒於前述之問 ，係為提供一種在其基材表 具備有離模功能的包裝材料 模劑層之表面，也可Κ進行 封加工處理，並且還具備有 行該具備有足夠之密封維持 備有足夠之密封維持性的密封 種包裝材料，而該包裝材料係 著劑層之相接觸之部份，塗敷 工面上，並無塗敷上離模劑。 料，必須要將離模劑，塗敷成 不需要將離模劑來塗敷成為圖 造作業，會變得比較複雜化，. 點來看的話，會發生有所謂成 題而構成的；即本發明之目的 面上而形成有離模劑層並且堪 之中，即使其密封加工面為離 該具備有足夠之黏著強度的密 離模功能的包裝材料。 本紙張尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐） 5 B7 Γ 五、發明説明（3 ) 【發明之揭示】 本發明人們，為了解決前述之問題，因此全心全力地進 行研究，結果就發現到：在可進行拉伸之基材之表面上， 形成有離模劑層，而製造出包裝材料，同時，在該包裝材 料進行拉伸處理之時，前述之離模劑層會發生有龜裂，而 且，在該包裝材料進行拉伸處理之後，該離模劑層之每單 位表面積之龜裂部的面積比率，係在特定之範圍內，藉此 就能夠解決前述之問題，因此而完成了本發明。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 也就是說，本發明之具有離模功能之包裝材料，係為在 可進行拉伸之基材之表面上而形成有離模劑層的包裝材料 ，其特徵為：在該包裝材料進行拉伸處理之時，前述之離 模劑層會發生有龜裂，而且，在該包裝材料進行拉伸處理 之後，該離模劑層之每單位表面積之龜裂部的面積比率， 係為10〜80% (實施形態1)。並且，本發明之具有離模功 能之包裝材料，其特徵為：該在包裝材料之密封加工部上 之離模劑層之每單位表面積之龜裂部的面積比率，係為10 %以上（實施形態2)。此外，本發明係關於一種使用前述 之實施形態1或實施形態2之具備有離模功能之包裝材科， 來作為該黏著性物品之個別之包裝材料（實施形態3)。 【圖式之簡單說明】 圖1係為顯示出本發明之具有離模功能之包裝材料的剖 面圖。 圖2係為在對於本發明之具有離模功能之包裝材料而進 行拉伸處理之後，再使用掃描型電子顯微鏡（SEM)，觀察 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 6 A7 經濟部中央標準局員工消費合作社印製 五、發明説明 (4 ) 1 1 1 離 模 劑 層 表 面 時 之 電 子 顯 微 鏡 照 片 (放大倍率300倍 ) 5 1 ! 1 圖 3 a 係 為 在 對 於 本 發 明 之 具 有 離 模 功 能之 包 裝 材 料 而進 1 | 行 熱 密 封 加 工 處 理 之 後 再 使 用 掃 描 型 電子 顯 微 鏡 (SEM) 請 1 閲 1 > 觀 察 該 密 封 加 工 部 之 離 模 劑 層 表 面 時 之電 子 顯 微 鏡 照片 1 買 背 I 面 !· y 而 該 電 子 顯 微 ΛτΛί 鏡 昭 片 之 放 大 倍 率 為 1 00倍 而圖3 b係為 之 注 1 意 I 在 對 於' 本 發 明 之 具 有 離 模 功 能 之 包 裝 材 料而 進 行 熱 密 封加 事 項 1 I 再 1 1 工 處 理 之 後 再 使 用 掃 描 型 電 子 顯 微 鏡 (SEM) 觀察該密 寫 d 本 封 加 工 部 之 離 模 劑 層 表 面 時 之 電 子 顯 微 鏡照 片 而 該 電子 頁 、〆 I I 顯 徽 鏡 照 片 之 放 大 倍 率 為 3 0 0倍 > 1 1 I 圖 4係為用Μ顯示出該使用本發明之具有離模功能之包 1 1 裝 材 料 而 作 為 該 附 加 有 黏 著 劑 之 衛 生 棉 之個 別 的 包 裝 材料 1 訂 時 之 概 略 狀 態 的 全 體 擴 大 剖 面 圖 〇 1 1 [ 實 施 發 明 之 最 佳 形 態 ] 1 I Μ 下 就 根 據 圖 式 來 說 明 本 發 明 0 1 1 | 圖 1係為顯示出本發明之具有離模功能之包裝材料（Μ下 > 僅 稱 為 包 裝 材 料 0 )之拉伸處理前之狀態的剖面圖 在 I 1 基 材 1之單面之整個面上 "係形成有離模劑層2 而 構 成該 [ I 包 裝 材 料 0 1 I 在 本 發 明 中 該 形 成 於 基 材 表 面 上 之 離模 劑 層 係 在基 1 1 I 材 表 面 塗 敷 有 離 模 劑 並 且 在 施 加 硬化 或 者 乾 燥 處理 1 1 之 後 例 如 就 像 圖 1所顯示的 馬上在基材表面之大約整 1 1 個 面 上 形 成 有 連 續 之 離 模 劑 皮 膜 〇 然 後， 藉 由 對 於 前述 1 1 之 構 造 之 所 組 成 之 包 裝 材 料 進 行 拉 伸 處理 Μ 便 於 使得 1 I 離 模 劑 層 產 生 有 龜 裂 現 象 9 而 成 為 並 不 連續 之 離 模 劑 皮膜。 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 7 A7 B7 五、發明説明（5 ) 於本發明中，所謂在對於包裝材料進行拉伸處理時而在 離模劑層上之所產生之龜裂現象，通常係是指：藉由利用 掃描型電子顯微鏡（SEM)，而Ml 00〜1000倍之放大倍率， 觀察該進行過拉伸處理後之包裝材料之離模劑層表面，而 能夠被確認出之程度之微细的龜裂現象。例如，該作為垂 直於拉伸方向上之垂直方向之龜裂現象之直徑，係為該具 有大約ΐό,ΟΟΟΑ〜6,50.0,000A(angstrom:埃）左右之龜裂。 該在離模劑層上之產生有龜裂現象的部份（龜裂部），係 形成在該曝露出底材之基材表面之部份上，或者形成於該 離模劑之塗敷量比起其他部分都還來得更少之部分上。本 發明之包裝材料，係可Μ藉由該生成於離模劑層上之龜裂 部，而使得該離模劑層之表面，成為密封加工面。 圖2係為顯示出在對於本發明之包裝材料而進行拉伸處 理（100%之拉伸處理）之後，再使用掃描型電子顯微鏡 (SEM)，観察該離模劑層表面時之電子顯微鏡照片（放大倍 率300倍）。 經濟部中央標準局員工消費合作社印裂 (請先閲讀背面之注意事項再填寫本頁) 由此可Κ得知：於圖2之包裝材料之狀態下，就在該離 模劑層，在幾乎垂直於包裝材料之拉伸方向（S)的垂直方 向上，係生成有無數個之龜裂部（Ρ)。 本發明之包裝材料，就正如前面所敘述的，在對於包装 材料進行拉伸處理之時，則必須在雛模劑層上，生成有龜 裂現象，並且，若由所謂能夠同時維持住該包裝材料之離 模劑層表面中之密封加工性及離模功能之觀點來看的話， 藉由後面所敘述之方法，而測定出該進行拉伸處理後之包 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） _ 8 一 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明 ( 6 ) 1 1 | 裝 材 料 之 離 模 劑 層 之 每 單 位 表 面 積 之 龜 裂 部 的 面 積 比 率 9 1 1 1 係 必 須 為 10 80 % 而 最 好 為 30 70 % 0 /-—S 1 | 當 離 橫 劑 層 之 龜 裂 部 的 面 積 比 率 係 為 低 於 10 % 之 時 > 請 1 閲 1 則 該 在 對 於 包 裝 材 料 之 離 模 劑 層 表 面 進 行 密 封 加 工 處 理 時 讀 背 1 » 面 之 密 封 強 度 (黏著強度） 會 變 得 不 夠 充 分 而 使 得 該 作 為 之 注 1 1 意 1 包 裝 材 料 之 密 封 維 持 性 變 得 比 較 差 0 此 外 當 離 模 劑 層 項 I 再 1 I 之 龜 裂 部 的 面 積 比 率 係 為 高 於 80 % 之 時 則 會 導 致 其 離 | d 本 模 功 能 降 低 而 無 法 從 包 裝 材 料 上 相 當 順 利 地 剝 離 掉 該 黏 頁 、"W〆 I 1 著 性 物 品 0 1 1 I 在 本 發 明 中 所 謂 之 離 模 劑 層 之 每 單 位 表 面 積 之 龜 裂 部 1 1 的 面 積 比 率 係 為 藉 由 利 用 電 子 線 微 分 析 儀 而 對 於 該 進 1 訂 行 過 拉 伸 處 理 後 之 包 裝 材 料 之 離 模 劑 層 表 面 進 行 分 析 處 1 1 理 得 到 一 彩 色 測 繪 影 像 而 進 行 圖 像 解 析 處 理 之 所 求 出 1 I 之 面 積 比 率 〇 在 該 離 模 劑 層 係 由 矽 酮 % 離 模 劑 氟 % 離 模 1 劑 Μ 及 長 鐽 烷 基 % 離 模 劑 所 組 成 之 狀 態 下 使 用 電 子 線 θ 微 分 析 儀 而 分 S!! 地 測 定 出 Si -K α 線 F- K α 線 Κ 及 0- \ 1 K C(線之強度 然後再對於所得到之彩色測繪影像 進行 1 圖 像 解 析 處 理 而 求 出 該 離 模 劑 層 之 每 單 位 表 面 積 之 龜 裂 1 I 部 的 面 積 比 率 〇 1 1 下 在 該 Μ 離 模 劑 層 係 由 矽 m 糸 離 模 劑 所 組 成 之 狀 態 1 1 作 為 例 子 而 就 該 離 模 劑 層 之 每 單 位 表 面 積 之 龜 裂 部 的 面 1 1 積 比 率 之 測 定 方 法 來 作 更 加 詳 细 之 說 明 0 1 1 1) 使 用 電 子 線 微 分 析 儀 (EPM -810 島 津 製 作 所 股 份 有 1 I 限 公 司 製 ) 測定出該進行過拉伸處理後之包裝材料之離 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 9 經濟部中央標準局員工消費合作社印製 ΑΊ Β：/ ; 五、發明説明（7 ) 模劑層表面的Si-Κα線之強度，而得到Si-Κα線強度之彩 色測繪影像。 電子線微分析儀之分析條件，正如Κ下所敘述的。 *加速電壓：15kv、試料電流：lONa •電子束範圍（面積）：IOOjU mX 1.4〇w.ib、 電子束直徑：lwm必 2)使用圖像處理裝置（Image Command、5098型號TMN-1528-01、日本肮空股份有限公司（Japan Avionics co.)製），而對於所得到之Si-Kot線強度之彩色測繪影像 之單位表面積（lOOwniXlOOwm)，進行圖像解析處理，Μ 便於測定出該離模劑層之每單位表面積之龜裂部的面積比 率。此時，係將Si-JCc(線之強度為40cpsM下之部份，作 為龜裂部，而Si-Kcc線之強度為大於40cps之部份，作為 離模劑層，Μ進行圖像解析處理，而測定出該離模劑層之 每單位表面積之龜裂部的面積比率。 本發明之包裝材料，由於係在基材表面上，形成有離模 劑層之後，再對於包裝材料，進行拉伸處理，而在離模劑 層上，形成有龜裂部，因此，必須要使用該可進行拉伸之 材料，來構成基材本體。 在本發明中，所謂之可進行拉伸之基材，就正如前面所 敘述的*如果具備有該為了滿足其在雛模劑層上形成有龜 裂部之拉伸處理之所需要的拉伸性，同時，在進行過拉伸 處理之後，遷具備有足夠之作為包裝材料之所需要之機械 強度之材料的話，基本上，並沒有特別限定該材料種類及 本紙張尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁)[九 丄 一 '.; M nr h.; — __7 v-v.; (V. Description of the invention (25) The processing section is not coated with a release agent, so the result does not have to go through the place of the previous technology The rather complicated manufacturing operation can be used to produce the packaging material with a mold release function. In addition, when the packaging material section of the present invention is subjected to a sealing process, the packaging material can be added to the packaging material. In the state of the same external force during the stretching process, the operation of forming a crack portion on the release agent layer, the M, and the sealing process can be performed simultaneously, so it is not necessary to perform the packaging material in advance. As a result of the stretching process, the working efficiency of the sealing process can be further improved. [Explanation of the component number] 1 Base material χ. ≪ 2 Release agent layer 3 Adhesive layer A Packaging material B Sanitary cotton C Seal processing Printed by the Ministry of Economic Affairs. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) S Stretch direction This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 公 #) _ 〇〇_ Correction page A7 B7 'V. Description of the invention (1) [Technical Field] The present invention relates to a kind of article which can be directly packed with various adhesive articles and can also be used in the aforementioned articles. The packaging material with a mold release function that peels off the packaging material on the package; if it is more detailed, the present invention relates to a sealing process (adhesive processing) on the surface of the release agent layer. [Background technology] As a simple means to add the so-called adhesive function to various articles with κ, most of them use adhesives. For example, sanitary napkins (M below is called Paper towel), in order to prevent the phenomenon of chicks when using the sanitary napkin, an adhesive layer is formed on the surface of the sanitary napkin. Generally, such sanitary napkins use the peeling paper to protect the aforementioned. In the state of the adhesive layer, the packaging material such as plastic film is used to individually seal and pack the entire sanitary napkin. In this state, by heat Sealing method and stamping sealing method, etc., and seal the opening of the packaging material after packing the tampon. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling in this (Page) On the other hand, recently, for the tampon to which the adhesive is added, instead of using the release paper to protect the tackifier layer of the tampon, the surface provided with The method of packing the tampon directly from the packaging material with mold release function; however, the aforementioned method has become the current mainstream method. And, as a packaging material with mold release function, the plastic film is generally used. The surface of the base material composed of the substrate is coated with various mold release agents such as silicone tincture. This paper size is in accordance with Chinese National Standard (CNS) A4 (210X 297 male dust) -4-B7 V. Description of the invention (2) In the state of using such packaging material with mold release function, it is not necessary Use M to protect the release paper of the aforementioned adhesive layer. Therefore, when using sanitary napkins, less waste will be generated. As a result, in terms of economics, such a packaging material with a mold release function will also Become quite favorable. However, in the state of a packaging material having a release agent layer formed on the surface of the base material, when an attempt is made to perform sealing processing on such a packaging material, the processing surface is coated with a release agent. Surface (Releasing agent (please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, so it is impossible to seal processing. In addition, in order to achieve the processing Processing, so it is also proposed to have a release agent on the substrate, only on the release agent and stick, but in the seal plus, because the packaging material like this is patterned, so / compared to the case Operation, the result of the aforementioned manufacturing process, and the problem of an increase in the yield of the product, etc. The present invention is made in view of the foregoing problems, and aims to provide a mold layer of a packaging material having a mold release function on a substrate surface thereof. The surface can also be sealed and processed, and it also has a kind of packaging material that has sufficient seal maintenance and sufficient seal maintenance, and the packaging material is an agent layer. The part that is in contact with it is not coated with a release agent on the coating surface. It is necessary to apply the release agent so that the release agent does not need to be applied as a drawing operation. It is more complicated. From the point of view, there will be a so-called problem formation; that is, a release agent layer is formed on the target surface of the present invention and it is acceptable, even if the sealing processing surface is sufficient. Packaging material with close-mold function for adhesive strength. This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 5 B7 Γ 5. Description of the invention (3) [Disclosure of the invention] The inventor, In order to solve the aforementioned problems, a thorough research was conducted, and as a result, it was found that a mold release agent layer was formed on the surface of a substrate that can be stretched to produce a packaging material. When the stretching process is performed, cracks may occur in the release agent layer, and after the packaging material is stretched, the area ratio of the cracked parts per unit surface area of the release agent layer is in Within a specific range In this way, the aforementioned problems can be solved, and the present invention has been completed. Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) That is, the invention has a mold release A functional packaging material is a packaging material having a release agent layer formed on a surface of a substrate that can be stretched, and is characterized in that when the packaging material is stretched, the aforementioned release agent layer is Cracking may occur, and after the packaging material is stretched, the area ratio of the cracked portion per unit surface area of the release agent layer is 10 to 80% (Embodiment 1). The packaging material with mold release function of the invention is characterized in that the area ratio of the cracked portion per unit surface area of the mold release agent layer on the sealing processing portion of the packaging material is 10% or more (Embodiment 2) . In addition, the present invention relates to a packaging material section having a mold release function using the aforementioned embodiment 1 or embodiment 2 as an individual packaging material for the adhesive article (embodiment 3). [Brief description of the drawings] Fig. 1 is a sectional view showing a packaging material having a mold release function of the present invention. Figure 2 is a drawing of the packaging material with a mold release function of the present invention, and then using a scanning electron microscope (SEM) to observe that the paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) ) 6 A7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention (4) 1 1 1 Electron micrograph of the surface of the release agent layer (300x magnification) 5 1! 1 Figure 3 a The packaging material with a mold release function of the present invention is further processed by a scanning electron microscope (SEM) after heat sealing processing, and the electron microscope is used to observe the surface of the mold release agent layer of the sealing processing portion. Photo 1 I buy the back side! · Y The magnification of the electron microscope ΛτΛί mirror Zhao film is 100 times and Figure 3 b is the note 1 Note I is for the packaging material with a mold release function of the present invention After the heat sealing is added 1 I 1 1 After the processing, the scanning electron microscope (SEM) is used to observe the secret d. The electron micrograph of the surface of the release agent layer of the sealed processing part is taken. The magnification of the photograph of the emblem mirror is 300 times > 1 1 I Figure 4 shows the use of the packaging material 1 1 with the release function of the present invention as the material for the tampon with the adhesive added. Individual packaging material 1 Enlarged cross-sectional view of the general state at the time of ordering 〇1 1 [Best Mode for Implementing the Invention] 1 I will explain the present invention with reference to the drawings 0 1 1 | FIG. 1 shows the present invention The cross-sectional view of the state of the packaging material with a mold release function (under M > just referred to as the packaging material 0) before the stretching treatment is on the entire surface of the single side of the I 1 substrate 1 " Agent layer 2成 I [I packaging material 0 1 I In the present invention, the release agent layer formed on the surface of the substrate is coated with a release agent on the surface of the substrate 1 1 and after hardening or drying treatment 1 1 is applied, for example As shown in FIG. 1, a continuous release agent film is immediately formed on approximately the entire 11 surface of the substrate surface. Then, the packaging material composed of the aforementioned 1 1 structure is stretched. It is convenient for the 1 I release agent layer to have a cracking phenomenon 9 and become a discontinuous release agent coating. 1 1 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 7 A7 B7 V. Description of the invention (5) In the present invention, when the packaging material is stretched, it is released from the mold. The cracking phenomenon on the agent layer usually refers to: by using a scanning electron microscope (SEM) at a magnification of 100 to 1000 times, observe the separation of the packaging material after the stretching process On the surface of the mold layer, a minute cracking phenomenon can be confirmed to the extent. For example, the diameter of the cracking phenomenon which is perpendicular to the stretching direction is the cracking which has about ΐ〇〇〇Α ～ 6,50.0,000A (angstrom: angstrom). The part (cracked part) on the release agent layer that has a cracking phenomenon is formed on the part of the surface of the substrate that exposes the substrate, or it is formed on the application amount of the release agent. There are fewer parts than the others. The packaging material of the present invention can make the surface of the release agent layer into a sealed processing surface by the cracks formed on the release agent layer. FIG. 2 is an electron microscope photograph showing the surface of the release agent layer after the packaging material of the present invention is stretched (100% stretched), and then the surface of the release agent layer is observed using a scanning electron microscope (SEM). (300x magnification). Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). From this, we can know that: in the state of the packaging material in Figure 2, it is in the release agent layer, almost There are numerous cracks (P) in the vertical direction perpendicular to the stretching direction (S) of the packaging material. As described above, when the packaging material of the present invention is stretched, it is necessary to generate cracks on the mold agent layer, and if the packaging can be maintained at the same time by the so-called From the viewpoint of the seal processability and the mold release function on the surface of the release agent layer of the material, the dimensions of the coated paper after the stretching process are determined by the method described later in accordance with the Chinese national standard (CNS ) A4 specification (210 × 297 mm) _ 8 A7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (6) 1 1 | The ratio 9 1 1 1 must be 10 80% and preferably 30 70% 0 / -— S 1 | When the area ratio of the cracked part from the horizontal agent layer is less than 10% > Please read 1 1 then read the back when sealing the surface of the release agent layer of the packaging material 1 »The sealing strength (adhesive strength) of the surface will be insufficient to make this note. 1 1 Note 1 The sealing maintainability of the packaging material becomes poorer. In addition, when the release agent layer item I then 1 I cracks When the area ratio is higher than 80%, it will cause its separation | d The mold function is reduced and the sticky sheet cannot be peeled off from the packaging material quite smoothly, " W〆I 1 adhesive article 0 1 1 I In the present invention, the area ratio of the cracked portion 1 1 per unit surface area of the release agent layer is the separation of the packaging material after the stretching process is performed by using an electron beam microanalyzer. Analyze the surface of the mold layer 1 1 to obtain a color mapping image and perform the image analysis to obtain the 1 I surface The product ratio 〇 is divided into S using an electron beam θ microanalyzer under the condition that the release agent layer is composed of silicone% release agent fluorine% release agent 1 agent M and long alkyl alkyl% release agent! The Si-K α line F- K α line K and 0- \ 1 KC (strength of the line are then measured, and then the obtained color mapping image is subjected to 1 image analysis processing to obtain each unit of the release agent layer. The surface area of the crack 1 is the area ratio of the part I. The release agent layer in the M state is composed of silicon m and the release agent 1 1 as an example. The method of measuring the surface area ratio of the cracked part 1 1 will be described in more detail. 0 1 1 1) Using an electronic wire microanalyzer (EPM-810 Shimadzu Corporation 1I Co., Ltd.) to measure the stretch The separation of the processed packaging materials 1 1 This paper size applies to Chinese National Standards (CNS) Specification A4 (210X 297 mm) 9 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs ΑΊ Β: /; V. Description of the invention (7) The strength of the Si-Kα line on the surface of the mold layer, and the strength of the Si-Kα line is obtained. Color mapping image. The analysis conditions of the electron microanalyzer are as described below. * Acceleration voltage: 15kv, sample current: lONa • Electron beam range (area): 100jU mX 1.4〇w.ib, electron beam diameter: lwm must 2) Use image processing device (Image Command, 5098 model TMN-1528-01 (Made by Japan Avionics co.), And the unit surface area (lOOwniXlOOwm) of the color mapping image of the obtained Si-Kot line intensity is subjected to image analysis processing, so that it is convenient to measure the release mold The area ratio of the cracked portion per unit surface area of the agent layer. At this time, the part where the strength of the Si-JCc line is below 40 cpsM is used as the cracked part, and the strength of the Si-Kcc line is more than 40 cps as the part of the release agent layer. The area ratio of the cracked part per unit surface area of the mold release agent layer is measured. The packaging material of the present invention is formed on the surface of the substrate, and after the mold release agent layer is formed, the packaging material is pulled. In the present invention, a crack portion is formed on the release agent layer, so it is necessary to use the stretchable material to constitute the substrate body. In the present invention, the so-called stretchable substrate As described above, * If it has the stretchability required to satisfy the stretching process in which cracks are formed on the mold layer, and after the stretching process, If there is sufficient material with the required mechanical strength as the packaging material, basically, there is no particular limitation on the type of material and the paper size applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read first Note on the back Then fill out this page)
-10 — A7 B7 五、發明説明（8 ) 構造等。 此外，因為本發明之包裝材料，在離模劑層上，形成有 龜裂部之後，還進行密封加工處理，因此，基材本體，必 須要具備有該熱密封方式及沖壓密封方式等之所需要之密 封加工性。 本發明之包裝材料之所使用之基材，若可κ滿足前述之 特性的話，則並沒有特別之限制，但是，最好使用該由κ 聚烯烴糸之熱塑性樹脂為主成分之塑膠薄膜而組成之基材。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 該作為像這樣之聚烯烴糸之熱塑性樹脂，可以使用例如 聚乙烯、聚丁烯、聚己烷、及聚辛烷等之單獨一種成分或 者混合物，特別是最好使用聚乙烯。該作為聚乙烯，則可 Μ使用超低密度、低密度、線狀低密度、中密度、及高密 度之單獨一種成分或者混合物中之任何一種，特別是最好 使用線狀低密度聚乙烯及/或低密度聚乙烯之含有量為15 重量％ Μ上者，或者使用高密度聚乙烯之含有量為80重量 % Μ上者。此外，遨可以配合著需要，而添加入該比起低 密度聚乙烯之熔點而還來得更高之材料，Μ便於提高其耐 熱性。該作為這樣之材料，係為熔點185 °C Μ上之材料， 最好為110 °C〜180 °C之材料。 此外，例如最好添加入4 0重量％ K下之苯乙烯糸、聚烯 烴系、及聚酯系等之彈性物成分，也能夠提高其品質及數 量。 在這裡|該作為用以構成為熱塑性塑膠薄膜之聚合物的 具體例子，例如可Μ由超低密度、低密度、線狀低密度、 本紙張尺度適用中國國家標隼（CNS ) Α4規格（210 X 297公釐） -11 - ΑΊ Β7_____ 五、發明説明（9 ) 中密度、及高密度之聚乙烯、聚丙烯、乙烯-醋酸乙烯共 聚物、乙烯-（甲基）丙烯酸酯共聚物、乙烯-（甲基）丙烯甲 酸酯共聚物、乙烯-(甲基）丙烯乙酸酯共聚物、聚乙唏-丙 烯共聚物、烯烴系彈性物、乙烯系彈性物、聚異丁烯、K 及丁基系橡膠中之所選擇出之單獨一種或者2種Μ上之複 合樹脂而構成的。 在這裡，該作為烯烴系彈性物，則可以列舉出乙烯-丙 烯橡膠（ΕΡΤ)、乙烯-丙烯-二烯橡膠（EPDM)、Κ及乙烯-丙 熥系和乙烯-丁烯糸之彈性物等；至於該作為苯乙烯糸彈 性物，則可Μ列舉出苯乙烯-異戊二烯-苯乙烯成塊共聚物 (SIS)、Κ及苯乙烯-丁二烯-苯乙烯成塊共聚物（SBS)等、 或者前述這些成塊共聚物之添水物。 在本發明中，就正如前面所敘述的，基材係可K為單層 構造；但是，例如最好由至少2層以上之層體，而構成該 基材，並且，在1層之單邊或者雙邊上，具備有比起該層 體之熔點遨降低5 °C以上之熱密封層，因此可Μ相當簡便 並且確實地進行熱密封處理。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 也就是說，在進行熱密封處理之時，當單層中之熱能， 變得比較強之時，則很可能在基材上，形成有孔洞，因此 ，並不容易控制住該熱密封處理；但是，在2層Μ上之基 材中，因為有專用之熱密封層存在著，所Μ具備有所謂能 夠得到相當容易地控制住該熱密封處理之條件的效果。 該作為像這樣之基材，則可Κ列舉出例如該由用以作為 熱密封層之低密度聚乙烯（熔點100 °C)所組成之層體以及 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） —12 - A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明 (10 ) 1 1 I 該 由 高 密 度 聚 乙 烯 (熔點120C )等之所組成之層體而構成2 1 1 1 層 Μ 上 之 基 材 等 0 在 這 樣 之 狀 態 下 9 於 成 為 熱 密 封 層 之 低 1 I 請 1 密 度 聚 乙 烯 部 份 上 係 設 置 有 離 模 劑 層 〇 先 閱 1 I 此 外 該 作 為 本 發 明 之 基 材 則 最 好 為 熱 塑 性 塑 膠 薄 膜 讀 背 面 1 ! 和 不 織 布 之 層 合 體 nsL Μ 及 熱 塑 性 塑 膠 薄 膜 和 織 布 之 層 合 體。 之 注 f 1 意 1 並 且 在 本 發 明 中 藉 由 混 合 入 前 述 之 聚 合 物 9 也 可 Κ 事 項 1 I 使 得 基 材 之 表 面 被 粗 糙 成 為 像 梨 子 皮 表 面 或 者 壓 印 浮 雕 再 填 寫 本 花 紋 面 藉 由 .x.t. 刖 述 之 處 理 能 夠 消 除 掉 外 觀 上 之 光 澤 9 而 頁 1 I 製 造 出 該 作 為 包 裝 材 料 之 所 需 要 之 高 鈒 品 味 0 而 且 還 因 1 1 1 為 其 動 摩 擦 係 數 變 得 比 較 小 所 以 能 夠 得 到 所 仝田 明 可 提 高 1 1 該 生 產 線 之 行 進 效 率 之 效 果 〇 前 述 之 基 材 表 面 被 認 為 .係 1 訂 由 於 在 其 互 溶 性 並 不 太 良 好 之 成 分 間 之 狀 態 下 藉 由 像 1 1 這 樣 之 混 合 處 理 K 及 利 用 該 溶 解 時 之 各 個 成 分 間 之 表 面 1 I 張 力 之 差 異 性 而 Μ 相 互 分 離 之 形 式 混 合 在 一 起 因 此 1 1 I 9 無 法 得 到 呈 均 勻 混 合 之 表 面 狀 態 並 不 能 夠 成 為 平 滑 之 G> 表 面 狀 態 而 成 粗 糙 面 之 狀 態 所 Μ 該 基 材 之 表 面 9 1 1 會 成 為 像 梨 子 皮 表 面 或 者 壓 印 浮 雕 花 紋 面 之 表 面 〇 該 基 材 ! 1 之 表 面 之 粗 糙 度 通 常 為 0 . 2 〜30 1 Π1 最 好 為 2〜5 U m 1 I 但 是 在 藉 由 後 面 所 敘 述 之 滾 筒 等 而 形 成 像 壓 印 浮 雕 花 紋 I 1 1 面 或 者 梨 子 皮 表 面 之 表 面 之 狀 態 下 則 該 基 材 之 表 面 之 粗 1 1 糙 度 9 最 好 在 薄 膜 之 1/ 2 之 厚 度 以 內 〇 此 外 t 還 可 藉 由 1 1 混 合 入 該 具 有 不 同 特 性 之 聚 合 物 而 製 造 出 該 僅 具 備 有 相 1 1 互 之 優 點 的 混 合 物 所 謂 之 新 功 能 1 係 指 例 如 所 謂 可 Μ 得 1 I 到 該 同 時 具 備 有 柔 軟 性 及 良 好 腰 部 之 兩 種 功 能 之 等 功 能 之 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公犛） -13 - Μ Β7 經濟部中央標準局員工消費合作社印製 五、發明説明 (' Π ) 1 1 I 聚 合 物 之 效 果 〇 1 1 1 此 外 就 正 如 前 面 所 敘 述 的 藉 由 混 合 入 比 較 柔 軟 之 聚 1 I 請 1 I 合 物 及 彈 性 物 而 在 由 黏 著 性 物 品 上 剝 離 掉 該 包 裝 材 料 之 先 閲 1 I 時 則 可 Μ 減 小 該 剝 雛 時 之 所 發 出 之 聲 音 因 此 也 具 備 讀 背 Λ 1 1 | 有 所 謂 並 不 會 讓 別 人 察 覺 到 該 包 裝 材 料 之 使 用 狀 況 的 效 果。 之 注 | 意 I 並 且 該 作 為 比 較 積 極 之 梨 子 皮 表 面 或 者 壓 印 浮 雕 花 紋 事 項 I 再 1 I 面 之 表 面 的 形 成 方 法 則 除 了 前 述 之 聚 合 物 混 合 法 之 外 9 寫 0 本 1 另 外 在 進 行 該 薄 膜 之 製 造 作 業 之 時 例 如 也 可 以 藉 由 該 頁 1 1 接 觸 到 Τ型式模具擠壓成形機上之滾筒面 而形成梨子皮 1 1 1 表 面 或 者 壓 印 浮 雕 花 紋 面 之 表 面 〇 在 本 發 明 中 於 形 成 有 1 1 壓 印 浮 雕 花 紋 面 之 表 面 之 狀 態 下 則 最 好 使 用 後 者 之 藉 由 1 訂 接 觸 到 Τ型式模具擠壓成形機上之滾筒面而形成該壓印浮 1 1 雕 花 紋 面 之 表 面 之 方 法 0 1 I 此 外 該 作 為 本 發 明 之 基 材 則 可 使 得 該 由 至 少 2層 1 1 I Μ 上 之 層 體 所 構 成 之 多 層 熱 塑 性 塑 膠 薄 膜 之 至 少 1個單面 Q 9 成 為 刖 述 之 該 由 聚 合 物 混 合 物 所 組 成 之 梨 子 皮 表 面 或 者 1 壓 印 浮 雕 花 紋 面 0 像 這 樣 藉 由 前 述 之 多 層 構 造 而 成 為 ! • 聚 合 物 混 合 物 便 於 能 夠 綜 合 及 複 合 化 各 個 之 層 體 之 聚 1 I 合 物 薄 膜 之 特 性 而 具 備 有 所 謂 附 加 新 功 能 之 效 果 例 如 I 1 I 可 Μ 同 時 地 附 加 上 前 述 之 熱 密 封 性 Μ 及 抗 拉 強 度 之 提 升 1 1 和 良 好 之 觸 感 等 之 共 同 存 在 之 附 加 功 能 〇 1 1 該 作 為 本 發 明 之 基 材 之 其 他 之 具 體 的 實 施 形 態 例 如 也 1 1 可 以 使 得 該 熱 塑 性 塑 膠 薄 膜 之 至 少 1個單面 ，成為例如具 1 I 備 有 薄 膜 厚 度 之 1 / 2左 右 以 下 之 表 面 粗 犍 度 (Ra) 之 梨 子 皮 I 1 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） -14 - A7 B7 ' 五、發明説明（丨2) 表面或者壓印浮雕花紋面，並且在該熱塑性塑膠薄膜之另 1個單面上，設置有離膜劑層，然後藉由像這樣之構造， 而能夠達到所謂觸摸時之柔軟感、眼睛看到之高品味感覺 、Μ及生產線之行進效率改善（動摩擦係數之減少）等之效 果0 此外，該作為其他之實施形態，也可Μ使得該熱塑性塑 膠薄膜之至少1個單面，成為該具備有薄膜厚度之1/2左 右以下之表面粗糙度（Ra)之梨子皮表面，並且在該熱塑性 塑膠薄膜之梨子皮表面上，設置有離膜劑層。 在這樣之狀態下，該進行離膜處理過之梨子皮表面或者 壓印浮雕花紋面的靜摩擦係數，係為未滿1.5，但是最好 為0 . 2〜1 .·0;至於其動摩擦係數，係為未滿1 . 2，但是最 好為0 . 1〜1 . 0。藉由在前述之摩擦係數之範圍內*則可Μ 使得該在生產線上之行進效率，獲得改善*而具備有所謂 能夠達到在基材和滾筒接觸時之並不容易發生有皺摺、蛇 行、及切斷等現象之效果。 基材之厚度，並沒有特別之限制，通常為ImmM下，但 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 是，若從柔軟性、K及優美性之觀點來看的話，最好為10 〜5〇w m，特別是最好為20〜40« m。 並且，在本發明中，若從基材之生產線上之搬運的觀點 來看的話，則基材必須要具備有某個程度之強度，通常， 基材之MD方向上之抗拉強度（測定溫度231C)，係為300gf 上，特別是最好為300〜lOOOgf/lOram，而基材 之TD方向上之抗拉強度（測定溫度231C)，係為200gf/ 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -15 - A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明 (13) 1 1 I 10 mm Μ 上 特 別 是 最 好 為 300〜1000g f/ 10m m c 1 1 在 本 發 明 中 該 用 Μ 構 成 其 離 膜 劑 層 之 材 料 9 就 正 如 .1, /·. 刖 1 | 請 1 1 面 所 敘 述 的 如 果 在 對 於 該 包 裝 材 料 進 行 拉 伸 處 理 之 時 9 閲 1 I 於 離 模 劑 層 上 會 發 生 有 龜 裂 規 象 9 然 後 > 再 將 像 這 樣 之 讀 背 1 1 面 離 模 劑 層 之 龜 裂 部 的 面 積 比 率 調 整 在 特 定 之 範 圍 内 的 話 之 注 | μ ， 則 並 沒 有 特 別 之 限 制 即 可 以 m 當 地 選 擇 及 使 用 該 能 夠 事 項 1 再 1 I 滿 足 像 這 樣 之 特 性 而 且 具 備 有 雛 膜 功 能 的 材 料 而 用 Μ 構 填 寫 Q 本 1 成 該 離 膜 劑 層 〇 頁 *—^ 1 I 該 用 Μ 構 成 其 離 膜 劑 層 之 材 料 可 Μ 戚 週 當 地 選 擇 及 使 用 1 I 例 如 熱 硬 化 型 、 紫 外 線 硬 化 型 及 電 子 線 7?BS 嫂 化 型 等 之 矽 酮 1 1 % 離 膜 劑 和 氟 系 離 膜 劑 、 或 者 長 鏈 烷 基 系 離 膜 劑 (一般來 1 訂 說 係 是 指 在 碳 數 巨 12 (C 12 )κ上之長鏈烷基丙烯酸酯 1 1 之 聚 合 物 長 鏈 院 基 丙 烯 酸 酯 和 其 他 之 乙 烯 單 體 間 之 共 聚 1 I 物 或 者 聚 乙 烯 醇 之 中 而 與 長 鏈 烷 基 異 氰 酸 等 之 長 鏈 烷 1 I 基 成 分 發 生 反 應 而 得 到 之 反 π» 悪 物 〇 )等之習知之離膜 q 劑 中 之 可 Μ 滿 足 前 述 之 特 性 的 任 何 一 種 材 料 0 並 且 於 .1·'· 月U \ 1 逑 之 材 料 中 在 基 材 係 由 熱 塑 性 塑 膠 薄 膜 所 構 成 之 狀 態 下 1 1 9 則 1st 取 好 使 用 該 在 形 成 其 離 膜 劑 層 時 之 並 不 需 要 進 行 加 熱 1 I 處 理 的 紫 外 線 硬 化 型 及 電 子 線 硬 化 型 之 矽 酮 糸 離 膜 處 理 劑 1 I 0 特 別 是 最 好 使 用 陽 離 子 聚 合 型 之 紫 外 線 rffi 嫂 化 型 之 矽 酮 % 1 1 離 膜 劑 〇 1 1 該 形 成 於 基 材 表 面 上 之 離 膜 劑 層 之 厚 度 9 並 沒 有 特 別 之 1 1 限 制 t 通 常 t 該 形 成 於 基 材 表 面 上 之 離 膜 劑 層 之 厚 度 9 係 1 1 為 0 . 05 〜 4 . 0 i m 最 好 為 0 . 1〜4 .0 U m ，更理想的話 ，則 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） 16 - B7 五、發明説明（14) 最好為0.3〜1.5w m。 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 於本發明中，不論是在基材 塗敷上該離模劑。並且，也可 僅是在基材之一部份之面上， 該作為在基材上而塗敷其離 限制，例如可K使用多支滾筒 (gravure roll)方式等之適當 本發明之包裝材料*係藉由 離模劑，接著，再進行乾燥處 如紫外線照射及電子線照射等 之後，對於該包裝材料，進行 層上，形成有龜裂部。 像這樣之拉伸處理方法，並 Μ適當地選擇及利用該能夠被 伸處理上之拉幅寬拉伸法Κ及 處理方法。 即使就拉伸條件而言，並沒 配合著基材之種類，而適當地 而使得該藉由拉伸處理所形成 率，能夠滿足本發明中之所規 本發明之包裝材料，就正如 行密封加工處理之前，預先地 理；例如，可Μ在使用該並無 ，包裝住該黏著性物品之後， 之單面或者兩面上，皆可Μ Μ在基材之整個面上，或者 來塗敷上該離模劑。 模劑之方法，並沒有特別之 方式、或者錯位·凹印滾筒 的塗敷裝置。 在基材之表面上，塗敷上該 理或者各種之硬化處理（例 方法），而形成有離模劑層 拉伸處理，Μ便於在離模劑 沒有特別之限制，但是，可 使用在通常之塑膠薄膜之拉 滾筒拉伸法等之習知之拉伸 有特別之限制，但是，可以 設定出該拉伸處理之條件， 之離模劑層龜裂部之面積比 定之特定範圍。 前面所敘述的，也可Κ在進 對於包裝材料，進行拉伸處 進行拉伸處理過之包裝材料 僅在密封加工部，進行拉伸 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） 17 A7 B7 丨 五、發明説明（15) 處理，而在離模劑層上，形成有龜裂部。 此時，該密封加工部中之離模劑層之每單位表面積之龜 裂部之面積比率，則必須為1 0 % Μ上，最好為1 5. %〜9 5 % 〇 當該密封加工部中之離模劑層之每單位表面積之龜裂部 之面積比率，低於10%之時，則該密封.加工部之黏著強度 ，會變成為相當不足夠，而使得該作為包裝材料之密封維 持性，變得比較差。 此外，在這裡，所謂密封加工部中之雛模劑層之每單位 表面積之龜裂部之面積比率，係藉由與前面之敘述相同之 條件，而測定出該密封加工部中之離模劑層表面之S i -Κ α 線之強度，然後，再藉由與前面之敘述相同之條件，而對 於所得到之彩色測繪影像，進行圖像解析處理，而求出該 離模劑層之每單位表面積之龜裂部的面積比率。在該密封 加工部之離模劑層上形成有龜裂現象之狀態下，也可Μ在 進行密封加工處理時，進行該用以形成龜裂部之拉伸處理 。也就是說，本發明之所利用之包裝材料，係為了在離模 劑層上，形成有龜裂現象，因此，在進行密封加工處理時 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) ，可Μ對於包裝材料，附加上外力。 該作為這種狀態下之密封加工方法，並沒有特別之限制 ，例如可Μ使得包裝材料之密封加工部（該包裝材料相互 重疊之部份），通過該Μ不同之旋轉速度之狀態而相互接 觸的2根滾筒之間（至少某一邊之滾筒係為用Κ進行熱密封 之加熱滾筒。），而能夠同時地進行該包裝材料之拉伸處 理及密封加工處理。在這樣之狀態下，可>乂藉由利用滾筒 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） —18 — B7 五、發明説明（1G) 間之剪力，而在包裝材料之離模劑層上，形成有龜裂現象。 此外，可Μ藉由利用該具備有其在表面上形成有凸出部 (突起部）之熱密封桿的熱密封機，而同時地進行該包装材 料之拉伸處理及密封加工處理。在這樣之狀態下*於進行 熱密封加工處理之時，則藉由熱密封桿之凸出部，而對於 包裝材料，進行拉伸處理，而能夠在包裝材料之離模劑層 上，形成有龜裂現象。 除了前述之方法Μ外，於進行密封加工處理之時，為了 在包裝材料之離模劑層上，形成有龜裂現象，而可Μ對於 包裝材料，附加上外力之狀態下，也能夠同時地對於包裝 材料，進行拉伸處理及密封加工處理。因此，在這樣之狀 態下，並沒有需要預先地對於包裝材料，進行拉伸處理， 所Μ，能夠更進一步地提高該密封加工處理之生產效率。 圖3a係為在對於本發明之包裝材料而進行熱密封加工處 理之後，剝離掉該密封加工部，再使用掃描型電子顯微鏡 (SEM) *觀察該包裝材科之離模劑層表面時之電子顯微鏡 照片，而該電子顯微鏡照片之放大倍率為100倍；而圖3b 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 係為在對於本發明之包裝材料而進行熱密封加工處理之後 ，剝雛掉該，密封加工部，再使用掃描型電子顯微鏡（SEM) ，觀察該包裝材料之離模劑層表面時之電子顯微鏡照片， 而該電子顯微鏡照片之放大倍率為300倍。 可以得知：在圖3a及圖3b之包裝材料之狀態下，於進行 熱密封加工處理之時，該包装材料會受到與拉伸處理相同 之作用（該包裝材料受到拉伸作用），而僅在該密封加工部 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -19 - A7 B7 ' 五、發明説明（〗7 ) 之離模劑層上，形成有無數之龜裂部。 本發明之包裝材料，也可Μ提供該預先地對於包裝材料 進行有拉伸處理之狀態，也就是說，本發明之包裝材料， 也可Μ提供該在離模劑層上形成有龜裂部而能夠進行密封 加工處理之狀態；例如，就正如前面所敘述的*也可Μ在 提供該並無進行有拉伸處理之狀態的包裝材料，而利用像 這樣之包裝材料，包裝住該黏著性物品之後，於進行密封 加工處理之時，進行著拉伸處理，而在離模劑層上，形成 有龜裂部。 圖4係為用Μ顯示出該使用本發明之包裝材料而作為該 附加有黏著劑之衛生棉之個別包裝用的包裝材料（個別裝 之薄片）時之概略狀態的全體擴大剖面圖。利用該並無進 行有拉伸處理之狀態的包裝材料A，包装住衛生棉Β之後， 接著，僅在該由包裝材料之離模劑層表面之所組成之密封 加工部C上，進行著拉伸處理，而形成有離模劑層之龜裂 部，Μ便於進行番封加工處理。此外，在圖1中，1係代表 著基材，2代表著離模劑層，而3係代表著黏著劑層。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 在本發明中，該作為對於其拉伸處理過之包裝材料而進 行密封加工處理之方法，並沒有特別之限制，例如可以使 用熱密封（熱黏著）法Κ及沖壓密封法。本發明之包裝材料 ，係以該形成有龜裂部之雛模劑層之表面，作為密封加工 s 面0 在這樣之龜裂部中，由於.曝露出該底材之基材層，或者 離模劑之塗敷量比較少之關係，因此，即使離模劑層之表 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） -20 - A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（18) 1 1 I 面 為 密 封 加 工 面 也 可 以 得 到 實 用 上 之 足 夠 之 密 封 強 度 ( 1 * I 黏 著 強 度 ) >並且 在本發明中 該包裝材料之密封加工 1 I 面 可 由 包 裝 材 料 之 離 模 劑 層 表 面 所 形 成 但 是 也 可 Μ 請 先 1 1 Μ | 由 離 模 劑 層 表 面 和 基 材 表 面 (例如形成有雛模劑層之表面 讀 § | 面 的 相反面）所形成 之 注 1 I 在 本 發 明 中 若 從 該 密 封 加 工 處 理 後 之 內 容 物 之 密 封 維 意 事 項 1 I 持 性 的 觀 點 來 看 的 話 其 用 Μ 表 示 出 該 密 封 加 工 部 份 之 黏 再 填 寫 著 力 的 密 封 強 度 (測定溫度2 3 t：) 係 最 好 為 2 g /25mm 上 本 頁 ^ 1 1 9 而 上 限 為 基 材 之 rdj 敝 壞 強 度 Μ 下 ) 但 是 比 較 理 想 之 密 封 1 1 強 度 (測定溫度2 3 °C ) 係 最 好 為 5 g / 25 m m 1000 g / 2 5 in ΏΙ 1 1 Μ 上 〇 在 這 裡 所 謂 基 材 之 破 壞 強 度 係 是 指 於 測 定 該 訂 1 I 密 封 強 度 之 時 在 並 far 從 密 封 部 份 上 剝 離 掉 基 材 而 基 材 發 生 有 破 裂 之 狀 態 下 之 強 度 也 就 是 指 該 密 封 部 份 之 黏 1 1 I 著 強 度 係 相 當 強 大 之 狀 態 0 當 密 封 強 度 小 於 2 g / 25 m m 之 時 1 1 9 則 會 有 該 密 封 加 工 部 份 會 變 得 相 當 容 易 剝 離 而 使 得 内 容 1 物之密封維持性變得 比 較 差 之 傾 向 產 生 〇 Μ | 本 發 明 之 包 裝 材 料 除 了 被使用來作為圖4所示之附加 'r 1 有 黏 著 劑 之 衛 生 棉 的 個 別 包 裝 用 之 包 装 材 料 之 外 還 可 以 1 1 被 使 用 來 作 為 例 如 並 不 使 用 該 剝 離 用 紙 而 直 接 地 包 裝 住 該 1 1 附 加 有 黏 著 劑 之 m 爐 等 、 Μ 及 各 種 之 黏 著 性 物 品 的 包 裝 材 1 1 料 〇 1 I Μ 下 則 列 擧 出 具 體 之 實 施 例 來 說 明 本 發 明 但 是 t 1 I 本 發 明 並 不 僅 限 定 於 這 些 實 施 例 〇 1 1 1 參 考 例 1 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明（19) 在厚度30« ΙΠ之低密度聚乙烯薄膜之單面之整個面上， 塗敷上厚度0.7« m之該由100重量份之陽離子聚合型之紫 外線硬化型矽酮離模劑（TPR6500、東芝矽酮股份有限公司 製）及2重量份之光起始劑（UV — 9310C、東芝矽酮股份有限 公司製）所調整製造成之雛橫劑，然後再使用II V (紫外線） 光線，進行照射，而形成離模劑層，Μ便於製造出該拉伸 處理前之包裝材料。 參考例2 在厚度30« m之低密度聚乙烯薄膜之單面之整個面上， 塗敷上厚度0.3/im之該由100重量份之附加反應型之熱硬 化型矽画離模劑及2重量份之白金糸硬化用觸媒之所調整 製造成之離模劑，然後於熱風乾燥機中，形成離模劑層， K便於製造出該拉伸處理前之包裝材料。 實施例1 ， 使得該在參考例1中之所得到之拉伸處理前之包裝材料 (25mm幅寬X 100 'mm畏度），沿著基材之流動方向（MD方向） ，進行1 0 0 %之拉伸處理。此時，使用拉力試驗機，K及 拉伸速度為50mm/min，而進行拉伸處理。 在進行拉伸處理之後，於使用掃描型電子顯微鏡（SEM) ，觀察離模劑層表面（放大倍率3 0 0倍）之時，結果観察到 :在離模劑層上，產生有龜裂現象。並且，在進行拉伸處 理之後，該離模劑層之每單位表面積之龜裂部的面積比率 ，係為1 5 %。 實施例2 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） (請先閲讀背面之注意事項再填寫本頁) 、?τ 22 A7 B7 丨 五、發明説明（20) 使得該在參考例1中之所得到之拉伸處理前之包裝材料 (25mm幅寬X 100 mm長度），藉由與實施例1相同之方法， 而沿著基材之流動方向（M D方向），進行1 5 0 %之拉伸處理。 在進行拉伸處理之後，於使用掃描型電子顯微鏡（SEM) ，觀察離模劑層表面（放大倍率300倍）之時，结果觀察到 :在離模劑層上，產生有龜裂現象。並旦*在進行拉伸處 理之後，該離模劑層之每單位表面積之龜裂部的面積比率 ，.係為5 0 %。 實施例3 使得該在參考例1中之所得到之拉伸處理前之包裝材料 (25mm幅寬X lOOmra長度），藉由與實施例1相同之方法，而 沿著基材之流動方向（M D方向），進行2 0 0 %之拉伸處理。 在進行拉伸處理之後，於使用掃描型電子顯微鏡（SEM) ，觀察離模劑層表面（放大倍率3 00倍）之時，結果觀察到 :在離模劑層上，產生有龜裂現象。並且，在進行拉伸處 理之後，該離模劑層之每單位表面積之龜裂部的面積比率 ，係為7 5 %。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 實施例4 使得該在參考例1中之所得到之拉伸處理前之包裝材料 的離模劑層之表面，相互地重疊在一起，然後，藉由該具 備有其在表面上形成有凸出部之熱密封桿的熱密封機，而 進行熱密封加工處理。在本實施例之狀態下，於進行熱密 封加工處理之時，藉由該熱密封桿之凸出部，而對於該包 裝材料，進行拉伸處理，結果，在該部份上之離橫劑層， 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） -23 - 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（2 0 會 產 生 有 龜 裂 現 象 j 因 此 9 可 以 進 行 該 具 備 有 所 謂 實 用 上 之 足 夠 之 密 封 強 度 之 熱 密 封 處 理 0 在 進 行 熱 密 封 加 工 處 理 之 後 9 就 剝 離 掉 該 包 裝 材 料 之 密 封 部 份 f 並 且 對 於 另 一 邊 之 包 裝 材 料 之 密 封 加 工 部 中 之 離 模 劑 層 之 每 單 位 表 面 積 之 龜 裂 部 的 面 積 比 率 9 進 行 測 定 9 結 果 9 測 定 出 該 面 積 比 率 為 53 % 〇 比 較 例 1 使 用 該 在 參 考 例 1中之所得到之拉伸處理前之包裝材料 t 而 該 包 裝 材 料 並 無 進 行 有 拉 伸 處 理 9 仍 然 維 持 著 拉 伸 處 理 ‘!》·产· 刖 之 狀 態 〇 此 時 9 該 離 模 劑 層 之 每 單 位 表 面 積 之 龜 裂 部 的 面 積 比 率 1 係 為 0 ? ί < ) 比 較 例 2 使 得 該 在 參 考 例 1中之所得到之拉伸處理前之包裝材料 (2 5 in m幅寬X 100 m m 長 度 ) •藉由與實施例1 相 同 之 方 法 9 而 沿 著 基 材 之 流 動 方 向 (MD方向） * 進 行 50 % 之 拉 伸 處 理 〇 在 進 行 拉 伸 處 理 之 後 9 於 使 用 掃 描 型 電 子 顯 微 鏡 (SEM) » 觀 察 離 模 劑 層 表 面 (放大倍率300倍 )之時： >结果觀察到 在 離 模 劑 層 上 > 產 生 有 龜 裂 現 象 0 並 且 9 在 進 行 拉 伸 處 理 之 後 $ 該 離 模 劑 層 之 每 單 位 表 面 積 之 龜 裂 部 的 面 積 比 率 9 係 為 5 ? 、.ί ； 5 比 較 例 3 使得該在參考例1中之所得到之拉伸處理前之包裝材料 (2 518111幅寬\10〇111111長度），藉由與賁施例1相同之方法，而 沿著基材之流動方向（MD方向），進行300 %之拉伸處理。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁)-10 — A7 B7 V. Description of the invention (8) Structure, etc. In addition, since the packaging material of the present invention is formed with a cracked portion on the release agent layer, it is also subjected to sealing processing. Therefore, the base body must have a place such as the heat sealing method and the stamping sealing method. Required seal processability. The base material used for the packaging material of the present invention is not particularly limited as long as κ satisfies the aforementioned characteristics. However, it is preferable to use a plastic film mainly composed of a thermoplastic resin of κ polyolefin 糸Of the substrate. Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page). As a thermoplastic resin for polyolefins such as this, polyethylene, polybutene, polyhexane, and As a single component or mixture of polyoctane and the like, polyethylene is particularly preferably used. As the polyethylene, any one of a single component or a mixture of ultra-low density, low density, linear low density, medium density, and high density can be used. In particular, linear low density polyethylene and The content of low density polyethylene is 15% by weight, or the content of high density polyethylene is 80% by weight. In addition, rhenium can be added to meet the needs, and the material which is higher than the melting point of low density polyethylene is added, and M is easy to improve its heat resistance. As such a material, it is a material having a melting point of 185 ° C, preferably 110 ° C to 180 ° C. In addition, for example, it is desirable to add elastomer components such as styrene fluorene, polyolefins, and polyesters at 40% by weight of K to improve the quality and quantity. Here | This is a specific example of a polymer used as a thermoplastic plastic film. For example, it can be made from ultra-low density, low density, linear low density, and this paper is applicable to the Chinese National Standard (CNS) Α4 standard (210 X 297 mm) -11-ΑΊ Β7 _____ 5. Description of the invention (9) Medium density and high density polyethylene, polypropylene, ethylene-vinyl acetate copolymer, ethylene- (meth) acrylate copolymer, ethylene- (Meth) acrylic acid ester copolymer, ethylene- (meth) propylene acetate copolymer, polyethylene-propylene copolymer, olefin-based elastomer, ethylene-based elastomer, polyisobutylene, K, and butyl-based The rubber is selected from one or two kinds of composite resins on M. Here, examples of the olefin-based elastomer include ethylene-propylene rubber (EPT), ethylene-propylene-diene rubber (EPDM), K, and ethylene-propylene-based and ethylene-butylene-based elastomers. As for the styrene-elastomer, M can be listed as styrene-isoprene-styrene block copolymer (SIS), K and styrene-butadiene-styrene block copolymer (SBS ), Etc., or hydrates of the aforementioned block copolymers. In the present invention, as described above, the base material may have a single-layer structure; however, for example, it is preferable that the base material is composed of a layered body of at least two or more layers, and the single side of one layer is provided. Or on both sides, it has a heat-sealing layer that is 5 ° C or more lower than the melting point 该 of the layer. Therefore, the heat-sealing treatment can be performed relatively easily and reliably. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page). That is, when heat sealing is performed, when the heat energy in the single layer becomes stronger, then It is likely that holes are formed in the substrate, so it is not easy to control the heat-sealing treatment; however, in the substrate on the two layers of M, because a dedicated heat-sealing layer exists, all of the substrates are provided with so-called The effect that the conditions of this heat-sealing process can be controlled relatively easily can be obtained. As the substrate like this, for example, the layered body composed of low-density polyethylene (melting point 100 ° C) used as a heat-sealing layer and the paper standard applicable to China National Standard (CNS) A4 Specifications (210X 297mm) —12-A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (10) 1 1 I This layer is made of high-density polyethylene (melting point 120C) and so on. Composition 2 1 1 1 Base material on the layer M 0 In this state 9 is lower than the heat-sealable layer 1 I Please 1 The density polyethylene part is provided with a release agent layer 0 Read 1 I In addition As the base material of the present invention, it is preferable to use a laminate of thermoplastic plastic film reading surface 1 and non-woven fabric and a laminate of thermoplastic plastic film and woven fabric. Note f 1 means 1 and in the present invention, it is also possible to mix the aforementioned polymer 9 with K. Item 1 I makes the surface of the substrate rough like a pear skin surface or embossed relief, and then fills this pattern surface. The treatment described by xt can eliminate the gloss on the appearance 9 and page 1 I produces the high-grade taste required as a packaging material 0 and also because 1 1 1 has a smaller dynamic friction coefficient, it can obtain the same Tian Ming The effect of improving the traveling efficiency of the production line can be improved. The aforementioned surface of the substrate is considered to be the same. Because it is in a state where the mutual solubility is not very good, it is processed by mixing and using K such as 1 1 and utilization. The disparity of the surface 1 I tension between the various components at the time of the dissolution, and the forms separated from each other are mixed together, so 1 1 I 9 cannot be obtained. The surface state of uniform mixing cannot be a smooth G > surface state and a rough surface state. The surface of the substrate 9 1 1 will become a surface like a pear skin surface or an embossed relief surface. The substrate The roughness of the surface of 1 is usually 0. 2 to 30 1 Π1 is preferably 2 to 5 U m 1 I. However, an embossed relief pattern I 1 1 surface or pear skin is formed by a roller or the like described later. In the state of the surface, the thickness of the surface of the substrate is 1 1 and the roughness 9 is preferably within 1/2 of the thickness of the film. In addition, t can also be manufactured by mixing 1 1 with the polymer having different characteristics. This mixture, which has only the advantages of phase 1 1 each other, the so-called new function 1 refers to, for example, the so-called 1 I to 1 which has both functions of flexibility and good waist. 1 1 paper size Printed in Chinese National Standard (CNS) A4 (210X 297 cm) -13-Μ Β7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention ('Π) 1 1 I Polymer effect 〇1 1 1 Just as described above, when the relatively soft polymer 1 I, 1 I compound and elastomer are mixed and the first 1 I of the packaging material is peeled off from the adhesive article, the peeling can be reduced. The sound made by the time therefore has the effect of reading back Λ 1 1 | so-called does not make others aware of the use of the packaging material. Note | It means I should be the more active surface of the pear skin or embossed embossed matter I and 1 The method of forming the surface of the I side is in addition to the aforementioned polymer mixing method 9 Write 0 This 1 Also perform this film During the manufacturing operation, for example, the surface of the pear skin 1 1 1 or the surface of the embossed relief surface can be formed by contacting the roller surface on the T-type die extrusion molding machine on this page 1 1. In the state of 1 1 embossed relief surface, it is best to use the latter to form the surface of the embossed relief 1 1 relief surface by contacting the roller surface on the T-type die extrusion forming machine with 1 order. Method 0 1 I In addition, as the substrate of the present invention, the multilayer thermoplastic consisting of at least two layers on 1 1 I M At least one single side of the flexible plastic film Q 9 becomes the surface of the pear skin or the embossed embossed surface that is described by the polymer mixture. 0 It is made by the aforementioned multilayer structure like this! • The polymer mixture is convenient It can synthesize and compound the properties of the poly 1 I compound film of each layer and has the effect of so-called additional functions. For example, I 1 I can simultaneously add the aforementioned heat sealability M and the improvement of tensile strength. 1 1 and the additional functions that coexist with good touch, etc. 1 1 This other specific embodiment as the base material of the present invention, for example, also 1 1 can make at least one side of the thermoplastic plastic film into 1 I Pear skins with a surface roughness (Ra) of less than 1/2 of the film thickness I 1 This paper size is applicable to Chinese National Standard (CNS) Α4 size (210X297 (Mm) -14-A7 B7 'V. Description of the invention (丨 2) Surface or embossed relief surface, and on the other one side of the thermoplastic plastic film, a release agent layer is provided, and Such a structure can achieve the effects of so-called softness when touched, high taste sensed by eyes, and improvement in travel efficiency of M and production line (reduction of dynamic friction coefficient). In addition, it can also be used as another embodiment. Μ makes at least one side of the thermoplastic plastic film the surface of the pear skin provided with a surface roughness (Ra) of about 1/2 or less of the thickness of the film, and is provided on the surface of the pear skin of the thermoplastic plastic film There is a release agent layer. In this state, the coefficient of static friction of the peeled surface of the peeled surface or the embossed relief surface is less than 1.5, but preferably 0.2 to 1. .0; as for its dynamic friction coefficient, It is less than 1.2, but it is preferably 0.1 to 1.0. By being within the range of the aforementioned friction coefficient *, the traveling efficiency on the production line can be improved *, and the so-called can be achieved so that wrinkles, snakes, And cut off effects. The thickness of the substrate is not particularly limited. It is usually under ImmM, but it is printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). From a sexual point of view, it is preferably 10 to 50m, especially 20 to 40 «m. Furthermore, in the present invention, from the viewpoint of transportation on the production line of the substrate, the substrate must have a certain degree of strength. Generally, the tensile strength in the MD direction of the substrate (measurement temperature) 231C), which is 300gf, especially 300 ~ 100gf / lOram, and the tensile strength of the substrate in the TD direction (measurement temperature 231C) is 200gf / This paper standard is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) -15-A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (13) 1 1 I 10 mm Μ is particularly preferably 300 ~ 1000g f / 10m mc 1 1 In the present invention, the material 9 constituting the release agent layer with M is just like .1, / ·. 刖 1 | Please 1 1 If you stretch the packaging material, please see 9 I 1 A crack pattern 9 will occur on the release agent layer, and then > read the 1 1 side release agent layer like this again If the area ratio of the cracked part is adjusted within a specific range, note | μ, there is no special restriction, and you can select and use the local matter. 1 and 1 I Satisfy such characteristics and have a membrane function Fill in the Q structure with the ML structure. 1 Form the release agent layer. 0 pages * — ^ 1 I The material that forms the release agent layer with ML can be selected and used locally. 1 For example, heat curing type, ultraviolet light. Hardening type and electronic wire 7? BS halogenated type silicone 1 1% release agent and fluorine-based release agent, or long-chain alkyl-based release agent (generally 1 refers to the large carbon number Copolymer of long chain alkyl acrylate on 12 (C 12) κ 1 1 Copolymer between long chain alkyl acrylate and other ethylene monomers 1 I or polyvinyl alcohol Reverse π »悪 物 〇) obtained by reacting with a long-chain alkane 1 I-based component of a long-chain alkyl isocyanate and the like Any of the materials which can satisfy the aforementioned characteristics in a conventional film release agent q And in the material of .1 · '· month U \ 1 在 in the state that the substrate is made of thermoplastic plastic film 1 1 9 then 1st is taken and used when forming its release agent layer, it does not need to be carried out Heating 1 I-treated UV curing type and electron curing type silicone release coating treatment agent 1 I 0 Especially, it is best to use a cationic polymerized UV rffi curing type silicone% 1 1 Release agent 0 1 1 The thickness 9 of the release agent layer formed on the surface of the substrate is not particularly limited to 1 1 t. Generally, the thickness 9 of the release agent layer formed on the surface of the substrate is 9 to 1 to 0.05. 0 im is preferably 0.1 to 4.0 U m, more preferably , Then applies a scale paper China National Standard (CNS) A4 size (210X 297 mm) 16 - B7 V. description of the invention (14) is preferably 0.3~1.5w m. (Please read the notes on the back before filling this page) Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs In the present invention, regardless of whether the release agent is coated on the substrate. Moreover, it is also possible to apply the separation restriction on the substrate only on a part of the substrate. For example, a suitable packaging material of the present invention such as a gravure roll method can be used. * After the release agent is applied, and then a dry place such as ultraviolet irradiation and electron beam irradiation is performed, the packaging material is layered to form a cracked portion. For such a stretching treatment method, the wide-width stretching method K and the processing method capable of being stretched can be appropriately selected and used. Even in terms of stretching conditions, the type of the substrate is not matched, and the formation rate by the stretching process can appropriately meet the packaging material of the present invention in the present invention, just as it is sealed. Before processing, geography is performed in advance; for example, after the adhesive is used, the adhesive article may be packaged on one or both sides, and the substrate may be coated on the entire surface of the substrate, or coated on the substrate. Release agent. There is no special method for the molding method, or a coating device for offset and gravure cylinders. The surface of the base material is coated with the material or various hardening treatments (eg, methods), and the release agent layer is stretched. There is no particular limitation on the release agent, but it can be used in general The conventional stretching of the plastic film, such as the pull-roller stretching method, has special restrictions. However, the conditions of the stretching treatment can be set to a specific range of the area ratio of the cracked part of the release agent layer. As mentioned above, the packaging material that can be stretched at the place where the packaging material is stretched can be stretched only in the seal processing section. The paper dimensions are applicable to China National Standard (CNS) A4 specifications (210X 297). (Mm) 17 A7 B7 丨 5. Description of the invention (15), and a crack portion is formed on the release agent layer. At this time, the area ratio of the cracked portion per unit surface area of the release agent layer in the sealing processing portion must be above 10% Μ, preferably 15.5% to 95%. When the sealing processing is performed, When the area ratio of the cracked part per unit surface area of the release agent layer in the part is less than 10%, the seal. The adhesive strength of the processed part will become quite insufficient, which makes it suitable as a packaging material. The seal maintainability becomes worse. Here, the area ratio of the cracked portion per unit surface area of the mold layer in the seal processing portion is determined by measuring the mold release agent in the seal processing portion under the same conditions as described above. The intensity of the Si-Kα line on the surface of the layer, and then, under the same conditions as described above, the obtained color mapping image is subjected to image analysis processing to obtain each of the release agent layer. The area ratio of cracks per unit surface area. In a state where cracks are formed on the release agent layer of the sealing processing portion, the stretching processing for forming the cracks may be performed during the sealing processing. In other words, the packaging material used in the present invention is for the formation of cracks on the release agent layer. Therefore, it is printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs during the sealing process (please read first Note on the back, fill in this page again), you can apply external force to the packaging material. The sealing processing method in this state is not particularly limited. For example, the sealing processing portion of the packaging material (the portion where the packaging material overlaps with each other) can be brought into contact with each other through the state of the different rotation speeds. Between the two rollers (at least one of the rollers is a heating roller heat-sealed with K.), the packaging material can be stretched and sealed at the same time. In this state, you can use the paper size of the roller to apply the Chinese National Standard (CNS) A4 specification (210X 297 mm) —18 — B7 5. The shear force between the description of the invention (1G), and A cracking phenomenon is formed on the release agent layer of the packaging material. In addition, the heat-sealing machine provided with the heat-sealing rod having a projection (protrusion) formed on the surface thereof can be used to simultaneously perform stretching processing and sealing processing of the packaging material. In such a state * When heat-sealing processing is performed, the packaging material is stretched by the protruding portion of the heat-sealing rod to form a mold release agent layer on the packaging material. Cracking. In addition to the method M described above, in order to form a crack on the release agent layer of the packaging material during the sealing process, the packaging material can be simultaneously applied with an external force. The packaging material is stretched and sealed. Therefore, in such a state, it is not necessary to perform a stretching treatment on the packaging material in advance, so that the production efficiency of the sealing processing can be further improved. Figure 3a shows the electrons when the surface of the release agent layer of the packaging material department is observed after the sealing processing part is peeled off after the heat sealing processing is performed on the packaging material of the present invention. Micrograph, and the magnification of this electron microscope is 100 times; and Figure 3b is printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). After the heat-sealing process is performed, the chip is peeled off, the processed part is sealed, and then a scanning electron microscope (SEM) is used to observe the electron microscope photograph of the surface of the release agent layer of the packaging material, and the electron microscope photograph is enlarged. The magnification is 300 times. It can be known that in the state of the packaging material of FIGS. 3a and 3b, when the heat sealing processing is performed, the packaging material will be subjected to the same effect as the stretching treatment (the packaging material is subjected to the stretching effect), but only Countless cracks are formed on the release agent layer of this seal processing department in accordance with the Chinese standard (CNS) A4 specification (210X297 mm) -19-A7 B7 'V. Description of the invention (7) . The packaging material of the present invention can also provide the state in which the packaging material has been stretched in advance, that is, the packaging material of the present invention can also provide the formation of cracks on the release agent layer. It can be sealed and processed; for example, as described above, * can also be used to provide the packaging material without the stretched condition, and use such packaging materials to pack the adhesiveness After the article is subjected to a sealing process, a stretching process is performed, and a crack portion is formed on the release agent layer. Fig. 4 is an overall enlarged cross-sectional view showing a schematic state of the packaging material (individually packed sheet) using the packaging material of the present invention as an individual packaging of the tampon with the adhesive added. After using the packaging material A that has not been stretched to pack the sanitary napkin B, the sealing processing portion C composed of the surface of the release agent layer of the packaging material is then pulled. It can be stretched to form a cracked part of the mold release agent layer, and M is convenient for the sealing process. In addition, in Fig. 1, 1 represents the substrate, 2 represents the release agent layer, and 3 represents the adhesive layer. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) In the present invention, there is no special method for sealing processing the stretched packaging material. For example, heat sealing (heat-adhesive) method K and stamping sealing method can be used. The packaging material of the present invention uses the surface of the mold agent layer having the cracked portion as the sealing process s surface. In such a cracked portion, the base material layer of the substrate is exposed, or The relationship between the coating amount of the mold agent is relatively small. Therefore, even if the paper size of the surface of the mold release layer is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) -20-A7 B7 Employees' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Printed 5. Description of the invention (18) The 1 1 I surface is a sealing processing surface, and a practically sufficient sealing strength (1 * I adhesive strength) can be obtained. ≫ In the present invention, the sealing processing of the packaging material is 1 I surface. It can be formed by the surface of the release agent layer of the packaging material, but it can also be M 1 1 Μ | From the surface of the release agent layer and the surface of the substrate (for example, the surface on which the mold release layer is formed read § | Formed Note 1 I In the present invention, if the seal is added from Sealing content of the processed content 1 I From the standpoint of consistency, it is indicated by M to indicate the adhesion of the sealing processing part and then the sealing strength of the sealing force (measurement temperature 2 3 t :) is preferably 2 g / 25mm Previous page ^ 1 1 9 and the upper limit is the base material's rdj 敝 bad strength M) but the ideal seal 1 1 strength (measurement temperature 2 3 ° C) is best 5 g / 25 mm 1000 g / 2 5 in ΏΙ 1 1 Μ Above. The so-called breaking strength of the substrate here means that the substrate is peeled off from the sealing portion and the substrate is cracked when the sealing strength of the order 1 I is measured. The strength in the state refers to the adhesion of the sealing part. 1 1 I The strength of the sealing is quite strong. 0 When the sealing strength is less than 2 g / 25 mm, 1 1 9 will have the sealing processing part become equivalent. Ease of peeling makes comparison of sealability of content 1 Poor tendency to produce OM | The packaging material of the present invention can be used as a packaging material for individual packaging in addition to the 'r 1 adhesive-attached tampons shown in FIG. 4 as well as, for example, 1 1 Instead of using the release paper, directly package the 1 1 m-furnace with adhesive, etc., and various packaging materials for adhesives 1 1 and 0 1 I. Specific examples are listed below. Illustrate the invention but t 1 I The invention is not limited to these examples. 0 1 1 1 Reference Example 1 1 1 This paper size applies to Chinese National Standard (CNS) A4 (210X 297 mm) A7 B7 Central Bureau of Standards, Ministry of Economic Affairs Printed by the staff consumer cooperative V. Description of the invention (19) On the entire surface of one side of the low-density polyethylene film with a thickness of 30 «ΙΠ, apply a thickness of 0.7« m of the cationic polymerized ultraviolet light hard Silicone mold release agent (TPR6500, manufactured by Toshiba Silicone Co., Ltd.) and 2 parts by weight of a light initiator (UV — 9310C, manufactured by Toshiba Silicone Co., Ltd.), and then the horizontal cross-cutting agent manufactured by The light is then irradiated with II V (ultraviolet) light to form a release agent layer. M is convenient for manufacturing a packaging material before the stretching treatment. Reference example 2 On the entire surface of one side of a low-density polyethylene film with a thickness of 30 «m, a thickness of 0.3 / im of the heat-reactive type silicone paint release agent with an additional reactive weight of 100 parts by weight and 2 Part by weight of the release agent adjusted and manufactured by the platinum hardening catalyst, and then formed in a hot air dryer to form a release agent layer, K is convenient for manufacturing the packaging material before the stretching treatment. In Example 1, the packaging material (25mm width X 100'mm degree of fear) before the stretching treatment obtained in Reference Example 1 was performed along the direction of flow (MD direction) of the substrate. % Stretching treatment. At this time, a tensile tester was used, and K and a stretching speed were 50 mm / min, and the stretching treatment was performed. After the stretching process was performed, the surface of the release agent layer (300 times magnification) was observed using a scanning electron microscope (SEM). As a result, it was observed that cracks occurred on the release agent layer. . After the stretching treatment, the area ratio of the cracked portion per unit surface area of the release agent layer was 15%. Example 2 This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) (please read the precautions on the back before filling this page),? Τ 22 A7 B7 丨 Fifth, the invention description (20) makes this The packaging material (25 mm width X 100 mm length) before the stretching treatment obtained in Reference Example 1 was carried out along the flow direction (MD direction) of the substrate by the same method as in Example 1. 150% stretch treatment. After the stretching treatment was performed, when the surface of the release agent layer (300 times magnification) was observed using a scanning electron microscope (SEM), it was observed that cracks occurred on the release agent layer. After the stretching treatment, the area ratio of the cracks per unit surface area of the release agent layer after the stretching treatment is 50%. Example 3 makes the packaging material (25mm width X 100mra length) obtained before the stretching treatment obtained in Reference Example 1 along the flow direction of the substrate (MD) by the same method as in Example 1. Direction), and stretched by 200%. After the stretching treatment was performed, the surface of the release agent layer was observed using a scanning electron microscope (SEM) (300 times magnification). As a result, a crack was observed on the release agent layer. After the stretching treatment, the area ratio of the cracked portion per unit surface area of the release agent layer was 75%. Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). Example 4 Makes the release agent layer of the packaging material before the stretching treatment obtained in Reference Example 1 The surfaces are superimposed on each other, and then a heat-sealing process is performed by the heat-sealing machine provided with a heat-sealing rod having a protrusion formed on the surface. In the state of this embodiment, when the heat-sealing processing is performed, the packaging material is stretched by the protruding portion of the heat-sealed rod. As a result, the cross-cutting agent on the portion Layer, this paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) -23-Printed by A7 B7, Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (2 0 will produce a cracking phenomenon, j 9 It is possible to perform the heat-sealing treatment provided with a so-called practically sufficient sealing strength. 0 After the heat-sealing processing is performed, 9 the sealing portion f of the packaging material is peeled off and the sealing processing portion of the packaging material on the other side is peeled off. Area ratio of the cracked part per unit surface area of the mold release agent layer 9 Measurement 9 Result 9 The area ratio was determined to be 53%. Comparative Example 1 The tensile strength obtained before the stretching treatment obtained in Reference Example 1 was used. Packing material The packaging material has not been stretched. 9 The stretched state is still maintained! At this time, the area ratio of the cracked part per unit surface area of the release agent layer is 1 Is 0? Ί <) Comparative Example 2 The packaging material before the stretching treatment obtained in Reference Example 1 (2 5 in m width X 100 mm length) is the same as in Example 1 Method 9 Along the flow direction of the substrate (MD direction) * 50% stretching treatment is performed. 0 After the stretching treatment is performed, the surface of the release agent layer is observed using a scanning electron microscope (SEM) (magnification 300) Times): > As a result, cracks were observed on the release agent layer > 0 and 9 After the stretching treatment was performed, the area ratio of the cracks per unit surface area of the release agent layer was 9 Department is 5?, .Ί; 5 Comparative Example 3 The packaging material (2 518111 width \ 10〇111111 length) obtained before the stretching treatment obtained in Reference Example 1 was obtained, and the same direction as in Example 1 was used to follow the flow direction of the substrate ( MD direction), and 300% stretching. This paper size applies to China National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page)
-24 - A 7 B7 . ' 五、發明説明（22) 在進行拉伸處理之後，於使用掃描型電子顯微鏡（SEM) ，觀察離模劑層表面（放大倍率3 00倍）之時，结果觀察到 :在離模劑層上，產生有龜裂現象。並且，在進行拉伸處 理之後，該離模劑層之每單位表面積之龜裂部的面積比率 ’係為8 5 %。 比較例4 使得該在參考例1中之所得到之拉伸處理前之包裝材料 (25mm幅寬XlOOmra長度），藉由與實施例1相同之方法，而 沿著基材之流動方向（M D方向），進行1 0 0 %之拉伸處理。 在進行拉伸處理之後，於使用掃描型電子顯微鏡（SE Μ) ，觀察離模劑層表面（放大倍率300倍）之時，结果観察到 :在離模劑層之任何一個之部份上，並無產生有龜裂現象。 比較例5 使得該在參考例2中之所得到之拉伸處理前之包裝材料 的離模劑層之表面，相互地重疊在一起，然後，藉由'與實 施例4相同之方法，而進行熱密封加工處理，但是，並無 達到熱密封之效果。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本可s ) 就該在實施例1〜3及比較例1〜4中之所得到之樣本，進 行Μ下之評價作業。 [熱密封強度] 使得各個樣本之離模劑層之表面，相互地重疊在一起， 然後再利用熱密封機（TP-701S HEAT SEAL TESTER: ΤΡ- 701S熱密封測試機、TESTER SANGYO CO.LTD)，而在Μ下 之條件下，進行熱密封加工處理。在進行熱密封加工處理 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） -25 - 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（23) 之後，利用拉力試驗機，而在拉伸速度300mm/ in ίη(Τ型剝 離試驗）之條件下，測定出該熱密封強度。 並且，在該評價作業中，所使用之熱密封機之熱密封擇 之表面形狀，係為扁平形狀。 •熱密封溫度：1 3 0 °C •壓接時間：2秒鐘 •壓接條件：4kg /平方公分 •壓接面積：10mfflX30niffl [剝離力] 藉由2kg之滾筒，往復地進行蓮動，而使得黏著用帶子（ 商品名稱：F-140BK、日東電工股份有限公司製）貼合在樣 本（10·幅寬）之離模劑層之表面上，接著，將前述之樣本 ，於室溫下，靜置30分鐘之後，再利用拉力試驗機，而在 拉伸速度300mm/inin(180°之剝離）之條件下，測定出該 黏著用帶子由樣本（包裝材料）部份被剝離掉時之剝離力。 其結果，係顯未在衷1中。 表1 龜裂部之面 積比率（5S) 熱密封強度 [S / 25mm ] 剝離力 [g / 1 0 m κι] 實施例1 15 310 44 實施例2 50 400 85 實施例3 75 5 30 98 比較例1 0 0 4 比較例2 5 <1 8 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） (請先閲讀背面之注意事項再填寫本頁)-24-A 7 B7. 'V. Description of the Invention (22) After performing the stretching treatment, using a scanning electron microscope (SEM) to observe the surface of the release agent layer (300 times magnification), the results are observed. To: On the release agent layer, cracking occurs. After the stretching treatment was performed, the area ratio 'of the cracked portion per unit surface area of the release agent layer was 85%. Comparative Example 4 The packaging material (25 mm width X 100 mra length) before the stretching treatment obtained in Reference Example 1 was made to follow the flow direction of the substrate (MD direction) by the same method as in Example 1. ), 100% stretching treatment is performed. After performing the stretching treatment, when using a scanning electron microscope (SE M) to observe the surface of the release agent layer (300 times magnification), it was observed that: on any part of the release agent layer, No cracking occurred. Comparative Example 5 The surface of the release agent layer of the packaging material before the stretching treatment obtained in Reference Example 2 was superimposed on each other, and then was performed by the same method as in Example 4. Heat-sealed processing, however, did not achieve the effect of heat-sealing. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling in this document). The samples obtained in Examples 1 to 3 and Comparative Examples 1 to 4 were evaluated under M. operation. [Heat seal strength] The surface of the release agent layer of each sample is overlapped with each other, and then a heat sealer (TP-701S HEAT SEAL TESTER: TP-701S heat seal tester, TESTER SANGYO CO.LTD) is used. , And under the conditions of M, heat sealing processing. After heat-sealing processing, the paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) -25-Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 5. After the description of the invention (23), use the pull force The tester measured the heat seal strength at a tensile speed of 300 mm / in (T-peel test). In this evaluation, the surface shape of the heat-sealing option of the heat-sealing machine used was a flat shape. • Heat-sealing temperature: 130 ° C • Crimping time: 2 seconds • Crimping conditions: 4kg / cm² • Crimping area: 10mfflX30niffl [Peeling force] A 2kg roller is reciprocated in a lotus motion, and Adhesive tape (trade name: F-140BK, manufactured by Nitto Denko Corporation) was attached to the surface of the release agent layer of the sample (10 · width), and the sample was then placed at room temperature. After standing for 30 minutes, the tensile tester was used to measure the peeling of the adhesive tape from the sample (packaging material) at a tensile speed of 300 mm / inin (180 ° peeling). force. As a result, the system was not in the first place. Table 1 Area ratio of cracked part (5S) Heat seal strength [S / 25mm] Peeling force [g / 10 m κι] Example 1 15 310 44 Example 2 50 400 85 Example 3 75 5 30 98 Comparative Example 1 0 0 4 Comparative Example 2 5 < 1 8 This paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)
26 - 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（24·) 比較例3 85 560 210 比較例4 0 0 10 就正如表1所明白顯示的，而可Μ得知：實施例1〜3之 包裝材料，係調整該藉由拉伸處理而形成之離模劑層之每 單位表面積之龜裂部的面積比率，而使得該離模劑層之每 單位表面積之龜裂部的面積比率在本發明所規定之特定範 圍內，因此，即使該密封加工面為離模劑層之表面，也會 具備有足夠之密封強度，同時，該離模劑層，對於黏著用 帶子*具備有相當之剝離性。 另一方面，由於比較例3之包裝材料，其龜裂部的面積 比率，超過本發明之所規定之80 % ，因此，會降低該離模 劑層對於黏著用帶子之剝離性。 此外，遷可Μ得知：由於比較例1、2、及4之包裝材料 ，在離模劑層上，形成有龜裂部，或者即使形成有龜裂部 而該龜裂部的面積比率也比起本發明之所規定之10 %遷來 得更低，因此，無法進行熱密封加工處理，结果，其密封 強度就變成為相當地低。 【產業上之可利用性】 本發明中之具有離模功能之包裝材料，係藉由具備有前 面所敘述之構造，因此，即使是在該密封加工面為離模劑 層之表面的狀態下，也可Κ進行該具備有足夠之黏著強度 的密封加工處理，同時，該離模劑層，對於各種之黏著性 物品，也能夠維持住足夠之剝離性。 因此，藉由使用本發明之包裝材料，則雖然僅有該密封 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁)26-Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the Invention (24 ·) Comparative Example 3 85 560 210 Comparative Example 4 0 0 10 As clearly shown in Table 1, we can know that: The packaging materials of Examples 1 to 3 are those in which the area ratio of the cracked portion per unit surface area of the mold release agent layer formed by the stretching process is adjusted so that the cracked portion per unit surface area of the mold release agent layer is adjusted. The area ratio is within the specific range specified in the present invention. Therefore, even if the sealing processing surface is the surface of the release agent layer, it will have sufficient sealing strength. At the same time, the release agent layer is suitable for adhesive tapes * Has considerable peelability. On the other hand, since the packaging material of Comparative Example 3 has an area ratio of cracked portions exceeding 80% prescribed by the present invention, the release property of the release agent layer to the adhesive tape is reduced. In addition, it can be seen that, due to the packaging materials of Comparative Examples 1, 2, and 4, a crack portion was formed on the release agent layer, or the area ratio of the crack portion was formed even if the crack portion was formed. Compared with the 10% specified in the present invention, the migration is lower. Therefore, heat sealing processing cannot be performed, and as a result, the sealing strength becomes relatively low. [Industrial Applicability] The packaging material having a mold release function in the present invention is provided with the structure described above. Therefore, even when the sealing processing surface is the surface of the mold release agent layer, It is also possible to perform the sealing processing with sufficient adhesive strength, and at the same time, the release agent layer can maintain sufficient peelability for various adhesive articles. Therefore, by using the packaging material of the present invention, although only the seal is used, the paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling this page)
-27 - 〔九丄一’. ；m nr h . ; — __7 v - v. ；( 五、發明説明（25) 加工部，並無塗敷上離模劑，结果就不必經過從來之先前 技術中之所利用之相當複雜之製造作業，而能夠製造出該 具有離模功能之包裝材料。 此外，本發明之包装材科，於進行密封加工處理之時* 在可K對於包装材料而附加上該與進行拉伸處理時之相同 外力的狀態下，由於可Μ同時地進行該在離模劑層上形成 有龜裂部之作業、Μ及密封加工處理，因此，並不需要預 先地對於包裝材料，進行拉伸處理，結果，能夠更進一步 地提高該密封加工處理之作業效率。 【元件編號之說明】 1 基材χ . < 2 離模劑層 3 黏著劑層 Α 包裝材料 B 衛生棉 C 密封加工部 P 龜裂部 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) S 拉伸方向 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公# ) _ 〇〇 _ 修正頁-27-[九 丄 一 '.; M nr h.; — __7 v-v.; (V. Description of the invention (25) The processing section is not coated with a mold release agent, so the result does not have to go through the previous technology The relatively complicated manufacturing operations used in this method can produce the packaging material with a mold release function. In addition, when the packaging material section of the present invention is subjected to a sealing process, it can be added to the packaging material. In this state of the same external force as when performing the stretching treatment, the operation of forming a crack portion on the release agent layer, the M, and the sealing processing can be performed simultaneously, so there is no need to pre-package the packaging. The material is stretched, and as a result, the working efficiency of the sealing process can be further improved. [Explanation of the component number] 1 Base material χ. ≪ 2 Release agent layer 3 Adhesive layer A Packaging material B Sanitary cotton C Seal processing department P Cracking department Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) S Stretch direction This paper size applies Chinese National Standard (CNS) A4 specifications 210X297 male #) _ _ thousand and correction page