TW354320B - Process for preparing organophosphorus ester compound and reactive flame retardant the invention relates to a simple process for preparing organophosphorus ester compound with high yield - Google Patents
Process for preparing organophosphorus ester compound and reactive flame retardant the invention relates to a simple process for preparing organophosphorus ester compound with high yieldInfo
- Publication number
- TW354320B TW354320B TW084100638A TW84100638A TW354320B TW 354320 B TW354320 B TW 354320B TW 084100638 A TW084100638 A TW 084100638A TW 84100638 A TW84100638 A TW 84100638A TW 354320 B TW354320 B TW 354320B
- Authority
- TW
- Taiwan
- Prior art keywords
- ester compound
- organophosphorus ester
- carbon atoms
- preparing
- preparing organophosphorus
- Prior art date
Links
Abstract
A process for preparing organophosphorus ester compound featuring: esterifying the reaction mixture (M1) obtained from the reaction of dichlorphosphine derivative (a) shown in formula (1) (where R1 is hydrcarbyl having 1 to 18 carbon atoms) and (methyl)acrylic acid (b) by monohydric alcohol; neutralizing the reaction mixture (M2) with the solid or aqueous solution of alkali metal of hydrogen peroxide or alkali earth metal of hydrogen peroxide (d), the amount of (d) used keeps the equivalent ratio of [hydrochloric acid in (M2) +(b)]/(d) in the range of 1/(0.8 ~ 1), and refining the mixture by filtering or separation to obtain organophosphorus alkyl ester compound represented by formula (2) (wherein R1 is hydrocarbyl having 1 ~ 18 carbon atoms; R2 is hydrogen or methyl; R3 is hydrogen or alkyl having 1 ~ 4 carbon atoms; R4 is alkyl having 1~4 carbon atoms).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30722893 | 1993-11-12 | ||
| JP6026068A JP2686908B2 (en) | 1993-11-12 | 1994-01-27 | Process for producing phosphinyl carboxylic acid ester |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW354320B true TW354320B (en) | 1999-03-11 |
Family
ID=17966591
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW084100638A TW354320B (en) | 1993-11-12 | 1995-01-25 | Process for preparing organophosphorus ester compound and reactive flame retardant the invention relates to a simple process for preparing organophosphorus ester compound with high yield |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP2686908B2 (en) |
| KR (1) | KR100344493B1 (en) |
| TW (1) | TW354320B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100429313B1 (en) * | 1996-11-11 | 2004-07-05 | 삼성아토피나주식회사 | Tetrakis(dichloropropyl)meta-phenylene diphosphate having excellent flame resistance useful for polyurethane foam |
| KR100696080B1 (en) * | 2001-09-18 | 2007-03-19 | 주식회사 코오롱 | Flame retardant agent and Non-combustible thermoplastic resin composition containing it |
| DE102006012879A1 (en) * | 2006-03-21 | 2007-09-27 | Clariant International Limited | Phosphorus-containing mixtures, a process for their preparation and their use |
| DE102006012881A1 (en) * | 2006-03-21 | 2007-09-27 | Clariant International Limited | Phosphorus-containing mixtures, a process for their preparation and their use |
| DE102006012878A1 (en) | 2006-03-21 | 2007-09-27 | Clariant International Limited | Phosphorus-containing mixtures, a process for their preparation and their use |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2236036C3 (en) * | 1972-07-22 | 1982-02-04 | Hoechst Ag, 6000 Frankfurt | Diphosphinic acid ester |
| JPS6021600A (en) * | 1983-07-15 | 1985-02-02 | 三菱電機株式会社 | Method of mounting coaxial connector |
| JPH0565339A (en) * | 1991-07-10 | 1993-03-19 | Sanyo Chem Ind Ltd | Production of flame-retardant polyester |
| JP2990953B2 (en) * | 1991-08-09 | 1999-12-13 | 堺化学工業株式会社 | Method for producing phosphinylcarboxylic acid derivative |
-
1994
- 1994-01-27 JP JP6026068A patent/JP2686908B2/en not_active Expired - Fee Related
-
1995
- 1995-01-25 KR KR1019960703907A patent/KR100344493B1/en not_active IP Right Cessation
- 1995-01-25 TW TW084100638A patent/TW354320B/en active
Also Published As
| Publication number | Publication date |
|---|---|
| KR100344493B1 (en) | 2002-11-30 |
| JPH07179482A (en) | 1995-07-18 |
| JP2686908B2 (en) | 1997-12-08 |
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