TW323308B - - Google Patents

Description

3-23308 A7 B7 V. Description of the invention (') The present invention resembles a kind of organic material used for dyeing non-woven fabrics (such as Nailing, polyester, acetate, acrilan, viscous fiber) (Viscose), polyolefins, polyurethanes and polyaromatic amides). It also applies to dyed materials. Especially refers to novel dyed non-fibrous organic materials that have improved properties that can be obtained by dyeing methods. Printed by the Beiji Consumer Cooperative of the Central Bureau of Central Economic Affairs of the Ministry of Economic Affairs (please read the $ item on the back and then fill in this page). When the traditional vat dyeing method is used for synthetic hunger (such as brushing and sleeping) Polyester) is not known to provide interesting light fastness (1 ightfastness) and washfastness (washfastness). When applying these dye-zhi synthetic materials in business, it will cause difficulties. Automotive interiors, interior decoration, curtains and decorations in homes, trains, and ships often include synthetic iron β-resistant synthetic carpets that will be exposed to bright sunlight for a long time, especially those in commercial areas that require good light fastness It is still often a metal-based compound that will be washed away when cleaned to improve light fastness. In addition, modern synthetic suspects [e.g., withdrawing Veraline], polyurethanes [e.g., lycra (RTM)] and polyaromatic amides [e.g., Kevlar (Kevlar) ( RTM} and Noiex (RTM) are well-known people who are not easy to dye. For the fiber such as Lycra material, the traditional custom is to blend them to more easily dye the material, such as dimensional Plain fibers (eg raw cotton) to achieve satisfactory dyeing. Apply Hojihara dyeing to expected synthetic materials with light fastness and light fastness (eg Nylon, Kevlar (RTM), Nomeck) (RTM), Polyoxanes, Polyurethanes and Polyesters) have been used to reduce the size of this paper and use the Chinese National Standard (CNS> A4 specifications (210X297mm) Central Ministry of Economy 323308 ^ A7 __B7 _ Printed by the Beigong Carrier and Cooperative Cooperative Society of the Bureau of State Development and Development (v): See, for example, the use of Caledon and Durindone Soledon dyes Printed flowers of textiles, (1 96 1) 3 9 1 page, paragraph 17.9 and " synthetic ion molecule Dyeing of acetate fiber, edited by D.M.Nu η η, D yers C 〇day pany P ub 1 icati ο II Trust 1979. Dyeing of synthetic materials in special fields (such as the use of service providers Clothing) is also important. In this area, materials are also dyed by reducing the reflectance at certain atmospheric 'window' wavelengths to improve their near infrared ray masking properties. Fiber cones blended with raw cotton and cellulose Among the suspects, the diziyuan dye contains a large number of conjugated structures that give correct reflection properties. This can be easily done by the Yunyuan dyeing method. However, when the dyes that they colored can be effectively faked When it contains smaller molecules, it is always difficult to use synthetic materials (such as polyester and polyester) to form a near-infrared reflection mask for Ιβ. Using a few black black raw dyes on raw cotton is sufficient to control the near-infrared properties. However, The standard dyeing conditions of the original dye and the original dye are used. When it is dyed to sleep, it has not been able to obtain a light fastness of more than 5 (British Standard Test BS1006: (1978) Β01: Β02), and at 60-C Fastness to washing It is prepared in 4 to 5 (American Standard Test BS1QQ6: (1978): C06). It is shown in Table 125 of Thoaas Vickerst.a ff " The Physical Chemistry of Dyeing " (1968) Edition, page 479: For a model nursery In terms of color, the light fastness of the attached dyed with Yunyuan dyes is not better than 2 to 3, while the raw cotton has a fastness of 5 to 8. Several techniques have been applied to provide near-infrared masking of tolerant to silk. The first of these technologies is the combined use of sulphur black pigments in printing pastes. '-4-(Please read the note on the back ^^ first and then write this page) h Binding · Order r This paper size is applicable to the Chinese National Standard (CNS > grid (210X297mm) Central Department of Central Standards A7 ________B7__ printed by the Bureau ’s Consumer Cooperatives 5. Description of the invention (present) However, nitric oxide is not easy to apply and has poor low-reflective fastness. In the second method of more limited applications, the pigment image is indirectly It is coated or filmed with a polymer into the fabric. The third method consists of a proportion of dyed black nylon yarn into the woven structure, so the centipede must be carefully spun to complete them in the final product. Masking. All these techniques will cause difficulties and inconvenience in manufacturing. The dyeing material to be special has been prepared, as described in Japanese Patent No. 0 3 0 7 6 8 8 0, although the method described It is not generally applicable, and only a few of the pending materials can be dyed according to the method. The light fastness of the material of the B dye is also improved by the re-steaming method as described in Degu Patent No. 9011668. However, this need to add will increase the complexity and And cost additional steps to the dyeing method. Therefore, there is currently a need for a dyeing method, which can apply dyes, especially from raw dyes to synthetic materials, and can provide excellent or excellent «light fastness or rinsing Fastness, and low infrared reflectivity in the military field. In particular, these boxes require these methods to be easily carried out and can be applied to synthetic materials in general. The term " reduced dye " It is well known, but usually includes pyrogen dyes such as indigo and anthracene, which must be reduced to their morphology before being regasified and from a neutral or salty matrix (also a solution Or paste) to provide their choppy effect β. These dyes can be used for bath dyeing (that is, immersing the stain in an aqueous dye solution) and for printing in the form of paste. The inventors have already Provide a novel method for applying dyes, and those in a better form of vat dyes, when applied to non-secondary dimensions (please read "Notes on the back of the back $ item and then write 4 pages") Paper is again suitable for China Standard (CNS) Α4 specification (210X297mm) Printed by the Central Bureau of Economic Development of the Ministry of Economic Affairs-Industry and Consumer Cooperatives *. A7 B7 5. Description of the invention (4) When requesting organic materials (if not fiber), it will lead to improvements Light fastness and fastness to washing, and therefore provide a suitable infrared reflectance value to these materials by simple printing or immersion steps. In addition, their inventions provide a novel method for dyeing (Preferably dyed with virgin dyes) Non- «dimensional organic materials with higher light fastness and / or wash fastness values than those previously obtained are among the preferred examples of minerals Light fastness of 5 or more (Fujian Yinggu standard test BS 1006 B01 and B02 (1978) and 5 or more wash fastness (according to the British quasi-lan test BS1006 C06.C2 (1981)) « Therefore, in the first special stick of the present invention is to provide a method for dyeing non-mineralocyanine organic materials with dyes, including: (a) Treating the materials with dyes in the presence of the original agent and koji , And (b) gasify the processed material prepared in step (a); The special feature is: the concentration and / or the potential of the lotus root and the meaning of alkali used in the step * (a > are increased to be away from the users of traditional lotus dyes, so that The light fastness of the obtained dyed material is 5 or more (as measured by BS1006B01 and / or 802 (1378)) and / or the fastness to washing is 5 or more (by the British Standard Search I BS1006 C06.C2) and / or the dyed material has a wavelength of 400 nm U ·) The reflectance of light is 20% or less, preferably 1596 or less, more preferably 1096 or less and The best is 5% or less. Even better is that the dyed material has this low reflection property for light in the wavelength range from 700 nm to 700 nm. This method can broadcast these properties in the "dyed" state of the material, and it does not hurt to be further processed (such as steaming). Use the Chinese «Home Stability Rate (CNS> A4 specification (210X297 mm) (Jing first" read the note $ item on the back and then fill in this I), 17 A7 _B7__ V. Description of invention (^) method The materials provided can be selectively further refined by any conventional method before use. It will be understood that the reflectance of black dyes will be less than other colors, especially less than bright colors such as yellow, and Don't refer to the increase in the wavelength of the channel reflection light. For military applications, the present invention will provide better dyed non- 戗 维素 eaves materials, when the dye is khaki yellow, it is in 700 0 1200 The reflectance between nanometers is 6596 or less; when the dye is recorded, the reflectance between 700 and 1200 nanometers is 50% or less, • when the dye is brown, it is 7Q0 The reflectance between 1200 nm. Is 2 + .5% or less; and when the dye is black, the reflectance between 12000 nm and 12.00 nm is 12.5% or less. The dye used in (a) is a vat dye, but the inventor has determined that this technology will provide Dyeing with other dyes, for example, even acid dyes, even if these dyes are not used in their normal pH medium. The preferred Lüyuan dye used in the present invention is a black dye of Tongyuan. Printed by the Pengong Consumer Cooperative Society -----_----- Huo --- (Jing first read the $ item on the back and then fill in this page) Λ1Γ The invention can be properly submerged in the sickle and In the solution of the reducing agent, the fi degree is between 90 * 0 and 100 »C. The dyeing step« (a) can also use dyes, clocks and 賩 原 _ in solution or in the form suitable for printing The slurry form is carried out, and step (a) is conveniently carried out at an elevated temperature .. When the composition is a slurry, the temperature of the elevated temperature used will depend on the slurry composition, for example, it can be used Steam at 100 ° C to 140 ° C. When the chief uses the solution in step (a), it is preferably carried out between 90 ° C and 120 ° C, more preferably at 95 ° C to 110T: The paper size is applicable to China National Standards (CNS) A4 specifications (210X297 mm) 323308 ΑΊ _Β7_ V. Invention (Ί ») to carry out.« Chemical step (b) can be carried out by Fu Tongyang ’s Yunyuan dyeing chemical technique. For example, when step suspect (a) is carried out in solution • Step bran (b) can It is conveniently carried out by using an aqueous solution of gasifier (eg potassium di complexate / acetic acid mixture) at elevated temperature (eg about 65 * 0 for this mixture) »air or gas can also be used The gasification effect of 慞 介. The gasification effect is preferably carried out after washing the fibrous male material provided in step (a). After the chemical action, it is preferable to wash the material in water and then Soap in an aqueous soap solution (preferably boiling) to remove excess dye. The required duration of each of these steps will depend on the materials and conditions used, but for »Long, step (a) can be carried out at about 95 * 0 for 4 5 to 75 minutes, and step K (b ) It can be carried out at 65 ° C for 15 to 45 minutes, and the soaping treatment is carried out for 5 to 15 minutes under boiling. Printed by the Employee Consumer Cooperative of the Central Ministry of Economic Development of the Ministry of Economic Affairs (please read "Notes on the back" and then fill in this page) Fu Tong's customary solution type that immerses the suspect in the solution is typical of the original dye composition. Contains about 0.01 to 0.02 mol of hydrogen "sales and 0.3 mol of dithionite" (sodiu dithionite) or equivalent logic agent (such as Rongalite). (See, for example, Ciba Geigy Cibanone dye manufacturer's instructions). The preferred mole number for the age used in the dissolution method (such as sodium hydroxide) is 0.5 moles, more preferably 1 mole or more, and most preferably between 1 and 4 moles. Between ears. The maximum concentration of the sickle will vary mainly depending on the sensitivity of the specific material to be dyed to the softness, but in the immersion dyeing method, it is usually necessary to use no more than 2 moles, and in the printing paste No more than 4 ears in the middle. For "Long, use the immersion method for step (a). Typical 氲. -8-This paper scale uses the Chinese national rate (CMS> Α4 specification (210X297mm} — mu · * A7 B7 V. Description of the invention (r) The strength of vaporized sodium is 1.3 3 pods, and it is about 3 ears in the paste used in the printing method. Therefore, the pH of the original dyeing method used by Fu Tong is 12-13, In the present invention, the pH is higher than PH13, more preferably about pH14, and as a result, more durable light fastness and washing fastness dyeing can be obtained. When sodium dithionite is used in the step of the method * (a) The preferred molarity of the reducing agent in the dissolving form is 0.015 molar or more, more preferably fl.3 its ear and the best is higher than 0.6 chil or more. Traditional Cowardly It is possible to use Lithium disulfite or its equivalent to 2 kels, but there is no specific upper limit that can be foreseen, because the ability of the material to resist these levels may change. In step "(a) The ratio of Zhongyun original agent to sickle is preferably greater than 0.001 pod entangled disulfite pin (Every mole of hydrogen sulfide (the original pin * or the equivalent _ to 0.1 to 10 grams of the original dye Λ Printed by the Employees ’Consumer Cooperative of the Central Department of Economic Affairs of the Ministry of Economic Affairs | 卜 丨 | —— 勹 ： ·! II 丨 丨 1rrl ———— (please read the note $ item on the back and then f this I) It will understand what it needs The type or amount of the original agent may vary depending on the efficacy of the dye used (that is, the potential of the original agent), the expected dyeing method and the printing method or strontium dyeing method. Therefore, for 1.5 g As far as Taslan Nylon iron is concerned, it has been found that: using 3 mol sodium hydroxide and all 7 grams of CI black black dye, 3 grams of dithionite (0.0124 mol) in 80 ml is It can be used in the manufacture of the materials of the present invention, as any of 3 grams of Carabinite C, Caramelite HT, Caramelite DP, White Powder FD, Caramelite PS91, and Caramelite HT91 can be prepared with similar cross product "However, at a concentration of 5 grams using these conditions, Diao White Powder H Liquid, Diao White Powder ST Liquid Brew, and Diao White Powder 2PH-A / B are less effective than others. Using the typical conditions described above, the present invention The author has been able to use the standard of the paper resistant to the Chinese National Standard (CNS) A4 (210X297mm ) A7 _ _B7 _ V. Description of the invention (ί) Dyeing with acid dyes, compared with those made using acid dyeing technology, although the colors provided are changed. For the printing method, it needs to be increased It can be used in the room printing paste of the selective combination of the original and the original. When Lian Erya "acid sodium is the original agent, it can be added as a paste, for example, in No. 0140 21 8 The narrator, the pseudo-dithiosulfite sales will be increased to be easily achievable by simple laboratory experiments. Those who are familiar with this beta will have other suitable pyrogen dyes / lotus roots. Agent / _slurry morphology; for example, see W 0 9 4 0 6 9 6 1, W 0 9 2 0 9 7 4 0, Japanese patent 6 3 1 8 2 4 8 2, Japanese specialty 63159586, European specialty 0162018 (foamed paste), British Kelly 2152037, Japanese Patent 1 92001118, Swiss Kelly CH662695, Japanese Kelly 87008556B, Dekol 4206929, European Patent 0162018, Japanese Kelly 58060084, Japanese Kelly 85030792, and Pai Patent 0021432. Pulpaceae may contain dyes (such as lotus root dyes) in the form of 懁-salt form, such as those described in Japan's No. 9 4 0 3 5 7 1 5 and modified to make _ (please read the back side first Note $ item and then fill out this page} Ordering group, he used the material printing materials to combine them. The fruit flower is effective in printing the net, and it is suspected that the eyes are in the shape of the eye, as strong as strong, strong, and powerful. Originally, a thing and a success «The Ministry of Economic Affairs and the Central Bureau of Pyongyang's Beigong Consumption Cooperation Du Yinzhong 1 added the first package containing the special package of potassium, and the pulp of the day was as good as 抲 (. * Quality} { Changed the number of 19, such as 47, 26, 63, 63, plus Kelly, as well as alkali, the raw material is dyed or the cloth is dyed% WM * and the package is aKlti) 4 和 -ϊ 82_ 88 The dimension m is correct and the material dimension is 0. The material used in the plant is known to be used in one place or known to be sour. The thiodithiol compound is a continuous slurry. R ΛΙ \ 尔 等等 °) / Powder white carving or Yushu It is used for dyeing with pan-wide color. The original is also in the S and 9 4 ο This paper standard is easy to use in troubled countries (CNS) A4 specifications (210X297 mm) Printed by the Ministry of Economic Affairs, the quasi-bureau of negative labor consumption cooperatives 323308 V. Invention description (9) The method of the present invention is preferably used for dyeing synthetic organic materials, preferably a polyaromatic amine (Kevlar or Nomex (RTMs), nylon, poly, polypropylene, polyamine group) Formate, acetate, 2 ° -acetate, triacetate and acryl. The method in the preferred embodiment of the present invention is used for dyeing a sleeping-resistant olive fiber composite material. The inventors have successfully dyed the fibers and / or the following materials, and they used the preferred composition of the present invention to carry out the original step »(a > and those: Nailing, polyester, Secondary acetate, triacetate, Kevlar, Akryl Tungsten, Polypropylene, Polyurethane (Lycra) and Visco® male dimension. Raw cotton will also be dyed using this method, but of course this method It is not part of the present invention. If you use a very high age, this method will dissolve the wool and soften the acetate, Acrylic, Nimiaojiwei and triacetate. The results of using the optimized method resulted in a perfect BS1 0 0 6'5 'score for the wash fastness of each raw cotton, polyester, Kevlar and Suulong (see (Below); even for the sun-long fiber, which is known to have this tradition, "Long's poor wash fastness, the latter is still provided. The examples provided after this will be easily seen: The inventor has provided A method that can fundamentally change the waitability of dyed non-cellulose products, especially dyed synthetic textile materials (such as reduced dyed materials), so that their fastness to washing, light fastness and reflectance can be All changes from the nature of dyeing and especially the dyeing of the original raw dyeing. When the exact chemical properties of the product fiber / dye after dyeing are not well known at present, it is clear that they have provided novel Dyed materials, such as mineral and secondary dimensions that have properties not previously provided. -11- This paper scale applies to the rate in the middle-sleepy countries (〇 «> into 4 ^ grid (210 > < 297 mm) i . > 丨 _L—! Λ; ---- .! 定 卜 —l · —— ^ γ (Please read the precautions on the back before filling in this page) Ministry of Economic Affairs Central Bureau of Accreditation Beigong Consumer Cooperatives Inquiry A7 ___B7___ Fifth, the invention description (β) material. Therefore, this A further aspect of the invention is that a non-Yan Wei Su organic material has a wash fastness of at least 5 (according to Ingusco BS1006 C06: C2 (19 81)) and / or the light fastness is 5 or more (BS1006B01 and B02 (1978) according to the British standard). It is better that the material has a gloss shore of 7 or more < according to the British standard SI test BS1006 B 0 1 and B 0 2 (1 9 7 8)) 〇 The present invention also provides materials obtainable by novel methods. In addition, the present invention provides Zuo and suspects, and includes such items as: carpets, car interior decoration coverage, interior decoration, curtains and curtains and Wei Jiwei suspect items, with these three kinds of resistance One or more properties of washing fastness, light fastness, and low reflectance properties. It will be understood that materials other than minerals and minerals can also be dyed using the method of the present invention, for example, decorative interior parts such as car money plates and the like inside the car. The special superior adhesion of this method and the dyed products of the present invention are: they allow certain newer materials such as polyaromatic amines, polyurethanes and naphthalene to be used in dyeing conditions Fibers do not need to contain their inherent support (by blending them with other materials such as cellulosic materials). The methods and materials of the present invention will now be further described by reference to the following non-limiting examples for illustration only. Further specific examples of the present invention will make those who are familiar with this knowledge more obvious. Fenshi Example Example 1: Use of Long Eggplant Η ΤΤ 庖 88 | [] Γ V 蒱 商 dye color 2 7 -12- The paper size is based on the Chinese National Standard (CNS) A4 specification (210X297 mm ) (Please read the note $ item on the back and then fill out this page), 1T Ministry of Economic Affairs, Central Bureau of Consumer Affairs, Beigong Consumer Cooperation Du Yinmu A7 B7 V. Description of the invention (“). Clii original dye animal color and CT thin deer dye The method of discoloring and resisting torsion resistance is to dissolve the resistant iron (1.5 g) at 95 ° C in a yellow containing CI vat dye (1.6% aqueous solution of 1 liter), a black vat dye 27 (5 in 10 ml) % Aqueous solution 丨 and CI vat dyes (1 ml of 1.6% aqueous solution) and 1? Ml of 4Mg sodium oxide aqueous solution, 4.5 kronol HT (BASF) and water (60 ml) bath dyeing The duration is 45 minutes. The final concentration of hydrogen hydride is about 0.6 mole. At the end of this period, the iron is washed with water, and 75 liters of dichromic acid (1.5 g) and acid (15 g) are used. ) The aqueous solution was vaporized for 30 minutes at 65 ° C. The vaporized secondary was washed in ice and dissolved in 75 ml of boiling water containing soap M (3.75 g) Medium soaping takes 10 minutes. As a result, the infrared reflectance of the color recording sample is low enough to meet the NATO (STANAG) color infrared reflectance standard, and it is 1096 or more between 400 nm and 680 nm wavelength Less, and less than 47.5% or less between 680 nm and 1000 nm wavelength. Stomach 2: The use of Fang Lier HT thin _ and (^ thin deer dye color .33 Such as Πν «Deer Dye Black fa. 27 dyeing knee-resistant susceptible evening method. The refractory-resistant susceptor (1.5g) is contained at 95eC in CI containing original dye yellow 33 (1ml of 3% aqueous solution), CI reduction Dye black 2 7 (25 ml of 5% aqueous solution) and 13 ml of 4M aqueous solution of vaporized pin, 4.5 Krona egg HT and water (60 ml) were dyed for 45 minutes. Hydrogen "The final concentration of the chemical pin is about 0.5 mole. At the end of this cycle, the suspect is washed with water, and then vaporized and soaped, as described in Example 1. As a result, the infrared reflectance of the green sample is sufficient -1 3- The size of this paper is in accordance with Chinese National Standard (CNS & Α4 specifications (210X297mm) (please read the precautions on the back before filling this page)

B7__ Fifth, the invention description (^) is low, it can meet the U Κ Μ o D reflectance specifications, between 4 0 Q nanometers and 6 8 0 nanometers is 10% or less, and between 680 nanometers The wavelength between rice and 1QOO nanometers is less than 47.5% or less ^ Example 3: Use Langjier HT 蒱 thin I and CT 蒱 原 dye black 27 dyeing and removing the follower to get khaki color This method uses the same black dye to produce different colors and lustres. This is achieved by containing the Nylon (1.5 g) at 95 ° C. in a CI black dye (27 ml) 5% aqueous solution), hydrogen hydride (10 ml of 4 M aqueous solution), Longanol HT (BASF) (3 g) and water (60 ml) aqueous solution were stained for 45 minutes to illustrate. The treated samples were washed, chemically and soaped, as described in Example 1. The reflectivity between 70G nanometers and 12QQ nanometers was found to be 60% or less and is suitable for DKMoD applications. Endeavour Example 4: Use Longhorn HT Kulu Deer Pay and CT Box Deer Brown: Π Dye will be printed by Naijiang Dyeing Industry and Consumer Cooperative Cooperative (Ministry of Economic Affairs, Central Standard Bureau) (please read the note $ item on the back and fill in this page) Elongate (15g) at 95 ° C in a CI containing brown dye 33 (4.5g), sodium hydroxide (in 25ml of 8 ^ aqueous solution), Longanerding (BASF) (5.5g) Dye with an aqueous solution of water (50 cm3) for 45 minutes. The final concentration of sodium hydroxide is about 2.7 moles. The processed samples were washed, gasified and saponified, as described in Example 1, and the infrared reflectance of the dark brown product was found to meet the UK MoD reflectance specifications, between 400 nm and 1200 nm The reflectivity is 25% or less. Fenshi Example 5: Lang Langer HT Tanyuanfu and CI bromine dye black 30 and CI Tanbu dye black 25 will be resistant to dyeing 14-This paper scale is applicable to the Chinese national standard (CNS) A4 specification (210X297 Ali) Printed A7 ____B7___ in the Beigongxiao Cooperative of the Central Ministry of Economic Affairs of the Ministry of Economic Affairs. V. Description of the invention (including the Lozenge (1.5g) under 95-C, including the CI original dye black 30 (4g), CI It is dyed in an aqueous solution of black original dye black .25 (2.5g), oxidized pin (8M aqueous solution of 30cm ^ 3), Longaner HT (5g) and water (5 (cm)) for a period of 45 Min. The final concentration of vaporized sodium is about 3 ears. The conditioned sample is washed, vaporized, and soaped, as described in Example 1, and the infrared product of the black product obtained by the invention The reflectance meets the UK MOD reflectance specification; the reflectance between 400 nm and 1200 nm is 10% or less. Example 6: 電 a 璩 二 二 重 醴 纳》 τπτ 箱 Μ Dye 魹 Μ and Dawn deer dye black 20 dyes Kies to the yam. Tasilon sleep resistant substance (1.5 g) at 95-C contains CI original dye black 30 (4.5 ), CI vat dye Black 25 (2.5 g), sodium hydrogen of (8Μ 30 cc of an aqueous solution), dithionite pin (

Na2 S2 〇4 -Vickers Laboratory) (3 grams) and water (50 cubic centimeters) were dyed in an aqueous solution for 45 minutes. The degree of hydrogen «chemical sales» is 3 moles. The processed sample was washed, vaporized and soaped as described in Example 1, and the infrared reflection of the black product obtained by the invention complies with the UK MoD reflectance specification; between 400 nm and 1200 nm The reflectance is 1096 or less. Millionaire 7: bubble 丨 use the stubborn bucks to pay for the excitement of the side material of Example 6 will be resistant to sleep-suspect 1 to walk around. Sleep at 1.5 grams (Tass edited suspect sample repeat Example 6 The dyeing method uses various reducing agents of BASF Longanol and Rongalite to -15- the standard of Chinese paper standard (岸 灿) 84 specifications (210 father 297 mm) (please read first Note f on the back and then fill in this page) Order 4 A7 B7 Printed by Beigong Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs 5. Description of the invention (^) To replace the sales of β-thionite and other chemical test books In Table 1. The original agent is ready to be prepared. White powder H liquid hyposulfite derivative white powder ST liquid sulfinate derivative white powder 2PH-B liquid 2PPH-A inorganic powder white 2PH-A liquid 2PPH-B Aliphatic sulfonic acid derivative Rongalite C hydroxymethane sulfinate Rongalite HT Hyposulfuric acid derivative Rongalite DP hydroxymethane sulfinate mixture Rongalite FD hyposulfuric acid derivative Lang in Seoul PS 9 1st sulfuric acid derivative Lungsher ΗΤ9 1 time sulfur The acid derivative from the value research found that each of Rongalite C, HT, DP, FD, Longhorn PS91 and HT91 in 3 grams in 80 milliliters at 95 ° C is a sufficiently strong transport agent to produce at a wavelength of 400 The desired reflectance value between nanometers and 10GQ nanometers is 1096 or less. Carved white powder 2PH-B liquid (3 grams) mixed with carved white powder 2PH-A solid is found to be incapable of military use Reflectivity (over 10% between 900 nm and 1200 nm), just like Rongalite ST and H liquid (5 g in each case), but will affect the dyeing according to the invention. -1 6- This paper XJt is suitable for China National Standard Rate (CNS) Α4 specifications (210X297 mm) ί! _ — L · --- ο ------ order, _ | ---- (Please read the note on the back $ Xiang Zai wrote this page) Printed A7 _B7_ of the Beigong Consumer Cooperative of the Central Ministry of Economic Affairs of the Ministry of Economic Affairs. 5. Description of the invention () Example 8: Use of unconsolidated and unremarkable raw materials The effect of the concentration of sodium dithionite in 6 on the dyeing of 1.5 g Nylon microfiber samples is determined by reference to the color loss measured by the reflectance spectrometer. The results show Table 2 below. Μ ___ 2 dithionite (g) 4 0 0 nanometer reflectance (%) 4 0 0 nanometer reflectance difference after C06 C2 rinse 0.12 2 5.24 3 1.22 5.98 0.25 15.22 17.41 2.19 0.53 10.73 11.29 0.56 1.00 3.89 4.01 0.12 2.00 4.02 4.17 0.15 These results were obtained by using 10 ml of 8M hydrogen hydroxide and 60 cubic centimeters of water. The dye of Example 6 was used, thus providing a sodium hydroxide concentration of about 1.14 moles, and Typical vat dye formulations are about 0.015 moles compared. The results show that when the sodium dithionite in 70 ml of water is less than 1 gram, the color loss from the fabric during washing will become significant, so at this concentration will change some of the properties of the dyed noodles Change has already taken place. Example 9: Use of various non-fixed moles: > 鹸 (氰 nitride): > knee dyeing to change the concentration of sodium hydroxide while maintaining the optimum (2g in 60-70ml) -1 7-this paper The standard is applicable to China National Standard (CNS) Α4 specification (210X297mm) __: ___: ____ ft______ D: __ ^ ____ f, ^ ί Λ ii ix (please read the precautions on the back before filling in this X) OV 3

5. Description of the invention of 3308 (a) The effect of dithionous acid was studied by using the dye and other conditions as set in Example β. The results are shown in Table 3. In each case, these figures are equivalent to (approximately) 〇, 〇.32, Q · 62 and 1.14 Qi'er sodium hydroxide. Therefore, it clearly shows that if the optimal angle of the original angle "degree, the increase of the gasification pin from 0.2 to m Chele will provide a significant change in the reflectance of the withdrawal dimension, which provides washability The BSlO6 C〇6 C2 score of fastness is '5', with a reflectance of 1 in nanometers below 596. Throw. 1 (please read the precautions on the back before filling this page) Γ 8Μ KrO3 (¾ litre) 4 0 0 nanometer reflectivity (%) 400 nanometer reflectivity difference after C 0 6 C 2 rinse 0 33.54 50.20 16.66 1.25 9.65 14.49 4.99 2. 5 3.61 3. 7 0.09 5 3.45 3.67 0.22 10 4.02 4.17 0.15 Μ Ministry of Economic Affairs Central Bureau of Customs and Crafts Consumer Cooperative Printed on micro-dimensional or raw cotton as set above The dyeing method t, testing the transfer of stains to adjacent fabrics, was found to be insignificant. In Example 8 (〇_12 and 0.25 g of dithionous acid) two-well samples obtained with carbamazepine and in Example 9 (0 and 1.2 ml of sodium hydroxide to remove fibers obtained from the two-inclined samples Produced in the washing fastness test solution "-18 This paper scale is easy to use the Chinese National Standard (CNS) A4 specification (210X297 mm) Central Bureau of Standards of the Ministry of Economic Affairs * C Industrial and Consumer Cooperative Institution A7 _B7_ V. Description of invention (· 7) The color loss is not significant. No dye appears in any other samples. Window Luli 10: Tafanglun's lowered dyeing angle .: Leather Shek Luang, Naopanzhuang Temple Armor Lightfastness_ Use What we are studying here is Tassin Souling, which has a melting point of 264 ° C and a melting endotherm of 90 Joules / gram. The tassian (1.5 grams) is prepared at 95T: under the CI lotus dye black 30 (4 G), CI Vat Dye Black 25 (2.5 g), 30 ml of 8M NaOH vaporized solution, Longcon HT (5 g), and water (50 ml) were dyed for 45 minutes. The number of ears is 3 moles. After washing, the sample is vaporized in 65 ml of 75 ml aqueous solution containing K2 Cr2 07 and acetic acid (15 g) for a period of 30 After cleaning, the sample is washed in a boiling aqueous solution containing 3.75 grams of soap flakes for 10 minutes. The visible and infrared reflectances provided by the sample are shown in the following table 4β Light fastness test BS as described below 1 0 0 6 The performance provided by ISO / R B01 and Β02 is evaluated as 7 + and the scouring fastness test BS1006 ISO / R C06C2 provides a performance score of 5, thus confirming the unique characteristics of the product according to the invention . This Nailing is especially suitable for the interior of the car if there is a need for light fastness. Black Nailong interior decoration and other internal items; currently the black light dyed Nailon's light fastness dispersion is only between 4 and 5. -19- This paper scale is applicable to China's national rubbing rate (CNS> Α4 specifications (210X297mm) (please read the $ item on the back and then fill in this page), 1Τ -ΜΗ: Fifth, invention description (,?) Shou 4 A7 B7 Printed Wavelength Reflectance 400 nm 3.01% 420 nm 3.03% 440 nm 2.97% 460 nm 2.94% 480 nm 2.94% 500 nm 2.89% 520 Nano 2 • 90% 540 Nano 2.90% 560 Nano 2.94% 580 Nano 2.92% 600 Nano 2.95% 620 Nano 2.95% 640 Nano 2.97% 660 Nano Rice 2.95% 680 nm 2.91% 7 0 0 nm 2.26% 7 2 0 nm 2.27% 7 4 0 nm 2.32% 760 nm 2 • 34% 780 nm 2 .36% 800 nm 2.37% 82 0 nm 2.72% 84 0 nm 2.66% 8 6 0 nm 2.86% 880 nm 3.28% 90 0 nm 3.21% 920 nanometers 3.22% 9 4 0 nanometers 3.31% 960 nanometers 3.34% 980 nanometers 3.59% 1 0 0 0 nanometers 3.66% Endeavour Example 1. 1: Increase idleness ： ≫ _ / Increase the box payment method for Kaifenger, Juku, Flute Grade 7, Ester, Tri-Z-ester, Sheep Benzene, Acrylic, Polypropylene, Sticky Warm, and Knee-Er Deer Nan; Bijiao -20- This paper scale is suitable for China National Standardization (CNS) Α4 specification (210X297mm) (please read the precautions on the back before filling this page) < .A 4 / / 0 A7 B7 5 1. Description of the invention ("9" (please read the precautions on the back and fill in this page first) The following agreement 〈protocol〉 Ye use 15 grams of fiber Forms of the material for the following: hungry Fula Er, polyester, two acetate, tris acetate, wool, Ackerly ed., Polypropylene, cotton and sticky Paradox ore dimension. The suspect was dyed at 95 ° C for 1 minute with 1 gram of original dye brown 33, 2 kronasol HT, 50 ml of 4U sodium oxide and 25 ml of water, and the final hydrogenation concentration was 2.64. Cheer. The dyed sample was vaporized at 65 ° using a solution containing 20 g / liter of potassium dibirate (U 2 Ci> 2 〇7) and 190 g / liter of citric acid for 30 minutes. Then the vaporized male is soaped in a solution containing 75 ml of water and 3.7 g of soap H under rc (rc for 15 minutes). All the above mentioned suspects are dyed to some Except for wool, because of its dissolution in these conditions, all the suspects of β have been visually dyed brown, except for raw cotton that has been dyed black. Polyester and polypropylene use this special formula and use soft acetic acid The conditions of _, triacetate, viscous iron and acryl are only dyed to a light color; to avoid this. The case is to reduce the test degree. W washing on Kevlar, polyester and raw cotton Fastness test (BS1006 ISO C06 C02), and the results are shown in Table 5. Qianji Ministry of Central Bureau of Industry and Commerce Beigong Consumer Cooperative Printed -21- This paper scale uses the Chinese national rate (CNS > A4 specification ( 210X297 mm) A7 __ B7 printed by the Consumer Labor Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (> «) Smudge / fractional stain / fractional Hungarian raw cotton © Hungry Lar⑸ + Poly Ester Raw Cotton ⑸ Polyester ⑸ Raw Cotton Raw Cotton® Raw Cotton ⑸ Nylon Raw Cotton ⑸ Resistance to Drop ⑸ During the Fen period Μ Use the sound deer dye color 33 to withstand the drop of the Luo pad color:

It is further researched in this study (the Lingling fiber-removing compound is well known to have poorer washing fastness than the traditional one): 0.1 g Yunyuan dye yellow 33, 2 Krone egg Η T and 10 ml of 8M sodium hydroxide were used for dye in 60 ml of water; the final hydrogenation pin concentration was h14 mole. After the chemical and soaping described previously, the suspects were subjected to BS1006 ISO C06 C2 wash fastness test and the score was perfect 1 '. Example H Sui Qi deer cut; use Lang egg HT and 氲 氲 alkali alkali hh honey: sweet mushyness_ It is expected that as the color depth increases, the stains of adjacent fabrics in the wash fastness test increase. This makes the situation post-hybrid, because when the concentration of reduced thin * is reduced, the dye is dyed lighter, although the stains are also changed. Table 6 below clearly shows that lowering the Angstall HT Cuan degree will affect the adhesion of the dye to the fiber; ^ way. -22- The standard of this paper does not use the standard rate of China's sleepy (CNS & A4 specifications (210X297 mm) i: _ 丨 l · ——η :. —.! Order. (Please read the note item on the back first (Fill in this page again) A7 B7 V. Description of the invention (X) Suolong Microfibre Luo (1.5g) is used at 95Ό with 0.1g of vat dye yellow 33, 10ml of 8 Μ gas vaporization pin and 60ml of water and different The amount of Longanol HT was dyed for 45 minutes; the final sodium hydroxide concentration was 1.14. Earrings, oxidation and washing were carried out as previously described. Table 6: Longaner HT # Nelute Xi Xian Xiu Xiu Xi Yu Lang Langer (g)% reflectance 4 0 0 nanometer Nylon stain score Raw Nylon stain score reduced Nylon color 0.012 3 3.83 3/4 5 4 0.12 3 9.65 3/4 5 4/5 0.27 2 5 · 04 4/5 5 4 0. 5 14.52 4/5 5 4 1,0 6.59 5 5 4 2. 0 3.60 5 5 4 Printed and printed by Beigong Consumer Cooperative, Central Bureau of Economic Development, Ministry of Economic Affairs ( Please read Note f on the back and then fill in this page) Λ The most sensitive indicator is the stains of the nearby Nailon Fiber Removal Lobe. It can be seen that: at a low content of Long Eggplant ΗΤ, on the 镞 物The number of dyes is very low, Moreover, the washing fastness is also low. To ensure the excellent washing fastness of the Nailong micro-mineral used in this example, the content of Langegall HT should be 14 g / L. Example 1 4: Critical tank Deer remuneration; Shen Xian Lang Shui Η Τ spot MS servant. Na ^ Hershine rate of 氲 氲 氲 化 Na Dan Ma Nylon Long Zhewei (1.5 g) is used at 95 ° C with 0.1 g of vat dye yellow-23-ben For paper size, the Chinese National Standard (CNS > A4 size (210X297mm) is printed by the Ministry of Economic Affairs, Central Bureau of Standardization and Employee Consumer Cooperatives A7 _B7_ V. Invention description (> >) 33, 2 grams of Langal HT and 60 ml of water are dyed for 45 minutes; no age is added. The wash fastness provided is as follows: the stain resistance score is 3., The raw cotton stain score is 4/5, the reduced color is 4 It is difficult to find out the ratio between any decisive alkali and reducing agents that describe the exact nature, because at a fixed concentration of tartar, reducing the concentration of Langall HT will reduce the color yield on the corona, and the result Lower washing fastness score. For the provided Langel HT waterfall degree, if the concentration of the owl decreases, the same thing Occurred. In addition to the decisive ratio, there is a processing window (processing window), where a variety of different combinations of Langer HT can produce similar results. In addition, these windows are the characteristics of dyes. Window Example 15: to reduce畺: > Box deer survey material black 7 ((K1 g):> The same experiment as described above after the knee-stained dyeing weight was repeated, but using 10 ml of 8M sodium hydroxide and vat dye black 7 (0.1 g) With all kinds of Longanol HT; the results are provided in the following table 7 (please read the precautions on the back before filling in this page) f -'Φ; λ / Shou 7: Langjier HT in the knee-resistant knee ^ effect seat Longanol% reflectance resistance to cotton stain reduction resistance (grams) 4 0 0 Nano speckle fraction speckle fraction color 0.5 9.93 3/4 4/5 4/5 1.0 5.71 4 4/5 4/5 2. 0 3.34 5 5 5 -24- This paper ^ You Xiao uses the Chinese National Standard (匚 呢) 8 4 * 1; grid (210/297 mm)> A7 B7 5. Description of the invention (y) Survey of the Taixu Tai invention Sei erbium cervus survey material black 7 dyeing and stretching of the dyed coal susceptor using the method of the present invention to dye the Tas knitting_staining under the condition of the more end Test to confirm the degree of fabric has not been processed and softening. The dyeing treatment used is the method of Example 1, except that the formulation used is composed of the original dye black 7 (4 g), water {50 ml), hydrogen hydride (8M, 30 ml), carving It is composed of white powder C (5g) and 1g Tas braid. The color of the dyestuff of the yarn is not as good as that of the yarn of the yarn of the yarn * 4%> 1 --------- 一-(please read the note on the back ^^ Please fill in this page again) When the tensile strength of the tensile crack is pulled on the tenth body of the yarn, the test strip is obtained. The amount of the suspected substance is measured. The suspected tb is displayed. test. Long time. Degree extension C 强 与 分 # 力 公 拉 裂 10 Each title is its average measurement length. The test method of Qi Mingen is soft and soft. It should be used as a response and convenient for the central government of the Ministry of Economic Affairs. It is printed by the National Bureau of Standards, Consumer Cooperatives, It. Average elongation of the sample% Average elongation change at break c N Change Maximum force at break Unstained 3 2. 9 4 X 8.73¾ 510. 40 2.96 5 3 2 7 I dyeing 3 4. 0 8 X 7.36¾ 526.07 2.89 5 5 8. I 0 swelling is strong and soft and becomes soft and fibrinous ^ ± 丨 real acid (I test editor's Tashu in special This clearly shows that the image traces are clear. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) A7 323308_B7__ 5. Description of the invention (-) Taizming method Xiyin Xifen For example, the printing paste described below is applied in a standard application method, and then steamed at 115-C for 15 minutes before allowing it to dry. The dried printing is chemical, and then described as in the above example. The dyeing method of vat dyes is soaped and washed. Mfi: For the brakes, the deer grade material fel squeezes the road (垅 舫 淦) to print a printing paste. The color is recorded by vat dye 1 (0.6g), carved white powder C (0.5g), β «Hua Na ( 8Η, 3 ml), water (5 ml) and Polyprint (RTM) thinner (available from Rudolph Chemicals, Derbyshire, UK). The mixed slurry is applied to the TASS suspect, and Use the steaming, drying, gasification, soaping and washing as described in the examples of dyeing with vat dyes as described above. The dyed fabric obtained has reflectance values between 400 and 800 nm Between 20% or lower, rising to 46% at 1000 nanometers. Printed by the Men ’s Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) 17: The original lanthanum dye 碁 色 33 will be used for the removal of resistance (Qi Fang Gan) to print a printing paste. The dye is made from a reduction dye yellow 33 (0.6 g), carved white powder C (0.5 g), hydroxide, sodium hydroxide ( 8M, 3 ml), water (5 ml) and Polyprint (RTM) thickener. Mix the mixed slurry to the TASS suspect, and use The steaming, drying, gasification, soaping and washing processes described in the examples of vat dyeing as described above and the dyeing process are processed. The obtained dyeing suspect is bright yellow and has a reflectance value of 4 It is 10% or less between 0 0 and 460 nm, less than 15% at 480 nm, and rises to about 50% between 500 and 1000 nm. Window Lili 18: Koga Mats for brakes are color-resistant (Qi Fang). -2 6- The size of this paper is easy to use China National Standards (CNS) A4 specifications (210X297 mm) A7 --- --B7 V. Description of the invention (A printing material pseudo-Yunyuan dye g color (〇6g) carved white powder c (0.5g), gasification sodium (8M, 3ml), water (5ml) _p〇 lyprint (RTtl) thickener is mixed. The mixed slurry is applied to the Tass paint, and the steaming, drying, and oxidation described in the examples of dyeing with the original dye as described above 、 Soaping and washing are processed together. The dyed fabric obtained is calyx / purple color, and has a reflectance value between 400 and 660 nanometers, 12% or lower, at 660 and 7 2 Between 0 nm and below 30%, it rises to about 4 4% between 7 2 0 and 1 Q 〇〇 Nanometer. Xuan Shi Example 19 · The nigella dye black 7 is used to remove the knee buckle A kind of printing Li material is composed of the original dye black 7 (0.6g), carved white powder c (0.5g), hydrogen hydride (8M, 3ml), water (5ml) and Polyprint (RTM) thickener It's made by mixing. The slurry is applied to the Taskey suspects and processed using the steaming, drying, gasification, soaping, and washing systems described above as described in the examples of dyeing with the original dyes. The dyeing obtained The matte is a strong black color, and has a reflectance value between 400 and 700 nm of 5% or less, between 7fl〇 and 820 nm is less than 10%, between 820 and 1000 nm Increased to about 15%. Zhi Shi Example 20: The use of acid dye # Tai invention of silver carp ft: Bianju coal ladle | 丨 — IJ ---- D ------ 定 ^ -I ^ —— < 1, (please read the note ^ 'on the back before filling in this page) The color is dyed with the print of KL-2, the Ministry of Economic Affairs, Central Bureau of Economic Development, Beigong Consumer Cooperative Society κ-2 {set color black 1 acid example Shi Shishi is dyed with a liquid-liquid-dissolving material tower of Pali. It is a durable example of foreign washing. Β W 抡 Example 2 1: Bumper for the original material used for the brake, and the sealing material is Panzi Γ -27 -This paper A degree is used Chinese national standard CNS) A4 specification (210X297mm) B7 V. Description of the invention (d) Stain dyeing flame retardant polyarylamide Nomex to provide an olive color suitable for military camouflage purposes, as In the conditions set in Example 5, the following formula was used for a boiling temperature of 135 ° C for 45 minutes; Formula: CI Pyrene Black 7 (0.5 g), CI Vat Green 1 (20 g), Cljg Original Dye Black 27 (ϋ · 5g), water (40ml), hydrogen sulfide (8M, 20ml), Longaner HT (3.0g), Nomex i (1.0g). The dyed irons obtained had the wash fastness obtained by ISO C06 C2 as follows: raw cotton adjacent to stains-5; Nomex-5 adjacent to stains; change in color-5. Measured light fastness 6. The infrared reflectance of the product is less than 12% at up to 680 nanometers and less than 35 percent at up to 100 nanometers. ^ Fenque Example 22: Lycra: > The lykla of carbamate is dyed by the method of Example 5 of the present invention. The yam is a commercially available grade in the form of a polyester-lykla blend. Use two temperature values (10Q ° C and 110-C) for the step of the original agent, use the formula provided below; formula: CI vat dye brown 33 (2 grams), Lang egg HT (5 grams) ), Hydrogen hydride sodium (8H, 30 ml) water (50 ml), polyester-Lycra (3 g). Printed by the Employees ’Consumer Cooperative of the Central Bureau of Samples of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page). Use l〇〇 ° C in the reducing agent / age step will provide ISO C06 C2 with a washing fastness value: near raw cotton The stain is 5; the neighboring Lekra stain is 5 and the color change is 5β. The infrared reflectance is less than 20% at up to 68G nanometers and less than 30% at up to 100 nanometers. The temperature of the step is increased to 110 ° C to provide the required high fastness to washing, but it will be flat, -2 8-This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) A7 323308 B7 V. Description of the invention (Yi) Further reduce the infrared reflectance, making it reflect at 7 to 20 nanometers (please read the precautions on the back before filling this page) The rate is 20% or less and up to 100 Nanometer is below 1QQ-C value. In both cases, the light fastness is greater than 5%. It is used for young cocoon a spotted cocoon is still trying to get into the box. The method is: Bsioofi. This is a more complete solution to the literature available from the British Prototype Agency, but here is a brief overview. BS 1 0 0 6 ISO B 0 1: 1 9 78 This method is expected to be used to determine the resistance of the colors of textiles and leathers of all categories and in all forms to sunlight. The principle of the Lanshi test is to expose the test piece of textiles or leather together with the 8 dyed wool standards to the sun, and to evaluate the fastness by comparing these color changes. Two sets of blue standards can be used, but they are not interchangeable. These are CI standards 1 to 8 (Europe) or L standards 2 to 9 (United States): the blue color created by & Chau The standard is dyed with the following eight dyes: 1: CI acid blue 104, 2: CI acid blue 109, 3: CI acid blue 83,

4: CI acid blue 121, 5: CI acid blue 47, 6: CI acid blue 23, 7: CI Ministry of Economic Affairs, Central Bureau of Standards, Beigong Consumer Cooperative Society, printed dissolving type Porogen dye blue 5, 8 : CI Dissolve Porogen Dye Blue 8. All these dyes and those used in experiments 1 to 15 are listed in the Society of Dyers and Colourists (P 0 Box 244, Perkin House, 82 Grattan Road, Bradford BD12JB, West Yorkshire, United Kingdoa) The Colour Index (e.g., 3rd edition) e L2 to L9 dyes by using various ratios of wool dyed with CI mordant blue 1 (Dye Index, 3rd Vendor, 4383Q) and CI Dissolved vat dye blue 8 (dye cable. -29- This paper standard _ applicable to China National Standards (CNS) Λ4 specifications (210X297 mm) A 7 · B7 V. Description of the invention (4). Cited, third edition, 738 (31) is made by blending, so that the standard of each number is tighter than the previous standard by about two times. (Please read the precautions on the back before filling this page) The equipment required Including: the exposure frame facing the sun (facing the south in the northern hemisphere, and facing north in the southern hemisphere), the angle of inclination from the horizontal line is approximately equal to the latitude of the 81 test position. It is preferred that the frame should be installed to avoid the exhaust smoke of the moose and the car Non-residential and non-industrial areas, including shade Those who will not fall on textiles. Textiles should have a transparency between 380 nanometers and 70 nanometers of at least 9 Q%, and 3 10 nanometers and 3 200 nanometers should be reduced to 0% The window glass should be covered. Air ventilation should be provided behind the textile. The minimum allowable distance between the glass and the specimen is 5 cm, and the exposure area that can be used is limited to the glass covered on each side. The area of the reduction is twice the distance from the cover to the sample piece. Those who need opaque cardboard or other thin materials such as aluminum foil; need to be used to avoid compaction when stacking the wads ◊ also need to be used to evaluate the gray gradation of color changes (Grey scale.) Depending on whether the BSI method 1 or 2 is used, the test specimens prepared are not less than 1 cm X 6 cm or 1 cm x 1 cm, and the blue sample is similar to the proportional exposure: The sample Η is exposed to sunlight for 24 hours every day. In the method 2 used in the printing of this by the Beigong Consumer Cooperative of the Central Kneading Bureau of the Chaoji Ministry, the sample Η is arranged into a strip of adjacent standards, and two Each sample Η in the interval of one-fifth is impervious at the same time The material is covered. When the change of the coverage in standard 3 or L2 is noticed when the gray # rating card is equal to 4-5, the evaluation of the sample piece and the light fastness are checked and compared with the standard 1 to 3 or L2. Cover and put back, and magneto-optically broken, -30-This paper scale is suitable for China's home rubbing rate (CNS> Α4 specification (210X297 mm) 323308 A7 B7_ V. Invention description (θ) (please read the back side first Note $ item and then fill in this page) until the change in standard 4 or L3 is noticed, at this time an additional coverage overlap is placed on one of the first cover and some of the sample pieces until it is noticed The change from standard 6 to L5 is equal to the gray rating card 4-5, which is before the final overlay is overlaid on the second overlay. After four coverages, follow the mine exposure until the contrast at standard 7 or L7 is equal to that shown on the gray powder card 4; or provide the contrast in the most resistant sample piece equal to the gray sub-card level 3: whichever occurs first As a basis. The final evaluation on the numerical evaluation is based on the contrast of the sample H between the exposed and unexposed portions being equal to the gray scale cards 4 and / or 3. Remove all the cover to expose the three areas of the test piece that have been exposed to the standard and different times, and at least one unexposed area. Compare the change of the standard at 6001 X or more at 45 ° to the sample; the light fastness is the change in color that meets the standard. The change in color may be color, depth, brightness, or any combination of these. The blue wool standard used in this embodiment can be broadcasted by the British Standards Agency (10 Blackfriars Street, Manchester M3 5 DT, UK). Printed by the Beige Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs; Beuth-Vertrieb, Burggrafenstr. 4-7 .D-1000 Berlin 3 0 Germany and Japanese Standard Association, 1-24 .Akasaka 4, Minatoku Tokyo Japan.L Blue wool is available from the American Association of. Textile Chai ^ sts and, P. Ο · Box 12215 , Research Triangle Park, North Carolina 2 7 7 0 9, USA0 BS1 006; TSn B02 Π 978) • ···.-This method is intended to evaluate artificial light using the sassafras applied above • -31- This paper The standard applies to China ’s sleepy family standards (CNS & A4 specifications (210X297 gong)) Α7 Β7 323308 V. Description of invention (w) ’Light fastness. The equipment used includes a fully ventilated exposure box and a temperature of 5500 The xenon arc lamp from K to 6500K has a filter between the light source and the sample piece to reduce the ultraviolet light spectrum. The glass used should have a temperature between 3 800 nm and 7 50 nm The penetration rate between is at least 9 0 %, And reduced to 0% between 3 10 nm and 3 20 nm ^ Infrared radiation also needs to be filtered with a black panel up to 45 * C. The change in light intensity of Ϊ on the exposed surface should be No more than ± 10% of the average amount. When several exposures are made side by side on the same sample piece, the area of the textile suspects used by Tong is not less than 1 cm X 4.5 cm. Method 2 is used in this example : The test piece is arranged with the standard for ISO B01 test, but only has a coverage, which is extended to one quarter of each test piece and the standard. When the change in the standard 3 is just detected When the stool is up (equal to the gray grading card 4-5), check the sample Η and grade it by comparing with the standard 1 to 3. Put back the cover until the standard 4 is just equal to the gray grading card 4-5, This pseudo-overlay is fixed in an overlapping manner on all samples H and part of the standard J: from time to time exposure until the change in sample 6 is found to meet the 5 on the gray grading card. Three coverage is when the second and some uncovered samples H overlap with the standard. The exposure until the contrast produced on standard 7 is equal to the contrast as exemplified in 4 on the gray grading card, or the sample H that is most resistant to i has been able to produce a contrast equal to the gray grading card 3, which occurs first Based. The final evaluation is based on the fact that the contrast ratio between the exposed and unexposed parts of the test piece is equal to the gray scale cards 4 and / or 3. Remove all overlays, and the light fastness is the number of standards that show similar changes in color. '. -32- This paper scale uses Chinese National Standard (CNS) A4 specification (210Χ297mm) __: __: ____ Λ1 -______ 丁 Γ 丨 ^, --------- 一 ---- -、 Ρ ------ ^ Lr 1 (Please read the note on the back " item first and then fill out this page) The Central Standards Bureau of the Ministry of Economic Affairs, Negative Consumer Cooperation Du Printing S233Q8 A7 B7 V. Description of Invention (Μ) RST OOB: TSfl 006 (198 1) The standard of the construction machine is Guoying ΌΠ, but it is a detailed test of this washing pulp. It is based on its relationship with washing and drying and drying on the ground. (# 设 ί 所Slippery ginseng, twisted by silk, twisted by color, changed by color, color, and color. 0 Under the impact of the feed strip, it is used as a wear and tear. The miscellaneous complexes are connected and connected to the transfer to the color transfer to evaluate the color; the stains of the color sample and the sample evaluation sample will be stained, and the card is not stuck. The original color of the cotton grade is like the color gray. (Please read the note ^ 'on the back before filling this page) f

* 1T κ Printed by the Employee Consumer Cooperative of the Central Department of Economics of the Ministry of Economic Affairs. The paper size applies to the Chinese Nursery Standard (CNS) Α4 specification (210X297 mm)

Claims (1)

A. Applying for patent patent No. M107827 "New particle of dyed material" (July 88 amendment) A. Application for patent scope 1. A polyaromatic amine, nylon, poly-, polypropylene , Polyurethane, Acetate, Secondary Acetate, Triacetate or Acrylic reduction dyeing method, so that the finished dyed material has one or all of the following properties: (i) British Standard Test BS1 006 C06C2 (1981) is a wash fastness of 5, (ii) British painting standard test BS1 006 BΘ1 and B02 (1978) is a light fastness of 5 to 8, Uii) to 400 nm (η · > The light has a reflectivity of 5% to 20%. The method includes the following steps: (a) Select a raw dye, (ΓΓίΤ 包 Ίδ 连 二 sulfite «or its effective substance reduction_ and # in the presence of, Treat the material with the dye department. The concentration of the sickle is between 2 and 8 Μ. Please read the note I on the page first and install it. Printed by the Beige Consumer Cooperative Society of the Central Sample Bureau of the Ministry of Economic Affairs. _ In the material, the dyeing and dyeing, and the principles of the law and law \ u / IX (b 第 開 園 步 范 經 養 利 化 专 气 鰪} Shen (C Ru 2 4 Μ Fang 0's ΘΘ term 0 Yu Da 1 is 0 The first rate is better than the Fan II II 5 Specially for 0 Please please apply to Shen Yuanjie as in 3.2 or in \ ly a / ΙΛ ri The paper standard for thiodithiol thiol is applicable to China National Frame Rate (CNS) Α4 specification (210X297mm) V ® 23; {Weng Suben, patent application Printed by the Beigong Consumer Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs β · 01 (a certain amount of gas). The reduction equivalent or equivalent of the crocodile pair is from 0.1 to 10 grams. 4. The method as claimed in item 1 or 2 of the patent application, in which the dye is an original black dye. 5. If the scope of patent application is the first! Or the method of item 2, wherein the dye image is applied in the aqueous solution of Moweiling and Xuanyuan agent in step (a) at a temperature between 90t and 10010. 6. For example, the method of claim 1 or item 2 of the scope of patent application, in which the dye is printed by applying a paste containing a reactive dye, hydrogen hydride and reducing agent to the material in step (a), and then Apply steam between 100P and 140t :. 7. The method as claimed in item 1 or 2 of the patent scope, in which the dyed material obtained has a light reflectance of between 2% and 65% between 700 nm and 120Θ nanometers. 8. The method of item 7 of Shenzhao Patent Fan Circle, in which the material obtained is dyed khaki and has a light reflectance between 700 nm and 1 200 nm between 2% and 65%. 9. The method as claimed in item 7 of the patent application, in which the material obtained is a dyed edge color and has a light reflectance of between 2% and 50% between 700 nm and 1200 nm. 10. For example, the method of claim 7 of the patent scope, in which the obtained material is dyed and has a light in the range of 700 nanometers to 120,000 nanometers -2- Please read the note I first try hard ίτ (CNS) (210X297 ^ *) V. Printed by the Beigong Consumer Cooperative of the Central Dart Bureau of the Ministry of Economic Affairs. The reflectivity is between 2% and 27.5%. The method of item 7 of the patent patent garden, in which the obtained material is black dyed with B and has a light reflectance of between 2% and 12.5% between 700nm and 12000nm. 12. A kind of dyed non-ferrewicin organic material, which is split by the method of claim 1 and has a light junction reflectance of 400% to 680 nm of 10% or less, and The reflectance of light from 700 nm to 1 200 nm is between 2% and 65%. 13. If you apply for the material in item 12 of the Fanfan painting, it has a light reflectance of between 2% and 50% between 700nm and 1200nm. 14. For example, the material of item 12 of Shenzhanli Fanshuang has a light reflectance of between 2% and 27.5% between 700 nm and 12000 nm. 15. For example, the material in claim 12 of the patent application has a light reflectance of between 2% and 12.5% between 700nm and 1200nm. 16. If the material of the patent application is 12, 13, 14 or 15, the material is a material dyed with reduced black dye. 17. For example, the materials in items 12, 13, 14 or 15 of the patent application, which have a wash fastness of '5' as measured by the British Standard Test BS1006 C06C2 (1981). 18. For example, the patent application plaque Nos. 13, 14, or 15 materials, which have a K light fastness measured by British Standard Tests BS1006 B01 and B02U978), 5 'to 1'. -3- This paper music standard uses Chinese national frame rate (CNS) Α4 specification (210x297 mm) (please fill in the item $ on the back of Μ # 'before filling the nest) --------:- if · 82 this & and the patent application range is S3 D8 Spider JUll is a material that is filled in item 19 of the 19 · $ Π application scope, which has been tested by the British Sassafras test BS1006 Β01 and Β02 (1978) The obtained R light fastness is' 7, to .8 ,. 2Θ · 5ΠApplicants to the patent scope items 12, 13, 14 or 15 for g from: polyaromatic house amines (Hungryr or Nomex (RTMs)), Klong, Juku, Poly Propylene, polyurethane, acetate sugar, secondary acetate, triacetate, and Keli. ------------- I-\ ---- (please read the $ item on the back and then fill in this page,) The Central Bureau of Economics of the Ministry of Economic Affairs Beigong Consumer Cooperative Printing Co. \ 4 -The size of this paper is based on China National Standard (CNS) (210X297mm)