TW323308B - - Google Patents
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- TW323308B TW323308B TW84107827A TW84107827A TW323308B TW 323308 B TW323308 B TW 323308B TW 84107827 A TW84107827 A TW 84107827A TW 84107827 A TW84107827 A TW 84107827A TW 323308 B TW323308 B TW 323308B
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3-23308 A7 B7 五、發明説明(') 本發明像鼷於一種用於染色非-编維性有機材料(例如耐 陵、聚酯、乙酸酯、阿克利綸(acrilan)、黏謬纖維( viscose)、聚烯烴類、聚胺基甲酸酯類和聚芳族醯胺類) 之方法。其也鼷於已染色材料•特別是指新穎之已染色 非-纖維性有機材料,其具有藉由染色方法可獲得改良之 性質者。 鐘濟部中央梂準局貝工消费合作社印装 (請先閲讀背面之注$項再填寫本頁) 當傳统惯用之邇原染料染色(vat dyeing)法使用於合 成饑物(例如刷睡和聚酯)是無法提供令人谋意的耐光牢 度(1 i g h t f a s t n e s s)和耐洗牢度(w a s h f a s t n e s s )是眾所 皆知的。當在商.業上施用此等染料郅合成材料時,會造 成難題。汽車内部物舆室内裝璜、在家、火車與船中之 窗簾舆裝飾經常包含將長期曝露於明亮日光之合成鐵物 β耐磨合成地毯,特別是指在商業區,需要良好之耐光 牢度者,仍然時常是包含淸潔時會被沖洗掉之為提离耐 光牢度之以金屬為基質之化合物。此外,現代的合成嫌 物〔例如撤繼維耐陵〕、聚胺基甲酸酯類〔例如萊克拉 (lycra)(RTM)〕和聚芳族醯胺類〔例如飢夫拉爾(Kevlar) (RTM}〕和諾梅克斯(Noiex)(RTM)是有名的不易加以染色 者。對例如萊克拉材料之纖維,傳统慣用的是將彼等摻 合以更易染色材料之纗維,例如纗維素纖維(例如原棉) ,以使可獲得令人滿意的染色。 施用邇原染色到具有耐光牢度與耐光牢度之預期的合 成材料(例如耐隆、凱夫拉爾(RTM)、諾梅克斯(RTM)、 聚燔烴類、聚胺基甲酸酯類和聚酯)於此藉中已經減少 本紙張尺度逍用中國國家橾準(CNS > A4规格(210X297公釐) 艟濟部中央梂率局貝工携费合作社印製 323308 ^ A7 __B7 _五、發明説明(v )了:參閲例如、使用克力登(Caledon)、杜茚酮藍( Durindone)曬麗登(Soledon)染料之紡鐡品印刷花、 ( 1 96 1 ) 3 9 1頁,第17.9段和"合成离分子舆乙酸酯纖維之 染色〃,D . M . N u η η 编輯,D y e r s C 〇 昼 p a n y P u b 1 i c a t i ο II Trust 1979〇 合成材料之染色在特殊領域(譬如用於提供服務人貝 之衣服)也是重要的。在此領域也將材料藉由降低在某 些大氣'窗'波長之反射率以改良彼等之近红外線掩飾待 性而加以染色。在原棉和纖維素摻合之纖錐嫌物中,笛 遢原染料傜包含大量之給與正確反射性質之共轭琛结構 時,此可藉由運原染色法而容易地進行。然而,當能有 效地將彼等著色之染料偽包含較小之分子時,其總是難 以輿合成材料(例如耐陲舆聚酯)迪成近红外線反射掩供ίβ 在原棉上使用少曇之黑色邇原染料是足以控制近红外 線性質。然而,使用標準運原染料和邇原染料染色條件 ,當染耐睡時,其迄今無法《得Β光牢度為大於5 (英國 檫準測試BS1006: (1978)Β01: Β02),同時在60-C之耐 洗牢度已限制在4至5(美國標準測試BS1QQ6: (1978): C06)。在 Thoaas Vickerst.a ff" The Physical Chemistry of Dyeing" (1968)第 2 販 Edition, 479頁表 125中顯示: 對一範圃之色彩而言,經運原染料染色之附陲之耐光牢 度為不優於2至3,而相醑的原棉具有堅牢度為5至8。 欲提供耐隆絲雜物之近紅外線掩飾,已經施用數種技 術。此等技術之第一種係併用磺黑顔料到印花漿料中。 ' -4 - (請先閱讀背面之注^^項再埃寫本頁) h 裝· 訂 r 本纸張尺度適用中國國家揉準(CNS > 格(210X297公釐) 鐘濟部中央揉準局員工消费合作社印製 A7 ________B7__五、發明説明(今) 然而,硝黑是不易施用且低反射堅牢度不佳。在更受限 之應用之第二種方法中,顔料像間接地藉由併用高分子 塗覆或膜到織物中。第三種方法係包含一比例之經染黑 色之耐隆纱線到織造構造物中,因此霈要仔細地紡鑼以 在最终産品中将彼等完全遮蔽。所有的此等技術會在製 造上造成難題且不方便。 待殊的染色材料已經被製得,如敘述於日本專利第 0 3 0 7 6 8 8 0號中者,雖然所敘述之方法並不可一般性地應 用,且僅少數之待定材料可根據方法來染色。B染料之 材料之耐光牢度也β經藉由如掲述於德固專利第9011668 號之再汽蒸方法來改善。然而,此需要添加會增加複雜 性且涉及成本之額外的步篇到染色方法中。 因此目前需要一種染色方法,其可應用染料,特別是 指邇原染料到合成纗物,且可提供優良或特優之«光牢 度或酎洗牢度,和在軍事領域之低紅外線反射性。特定 言之,彼等箱要此等方法容易進行且可一般性地應用到 合成材料。術語"還原染料"對熟諳此g者將是眾所皆知 的,但是通常包括邇原染料例如靛藍和蒽匿類,其在被 .再氣化之前必須被還原成彼等之皤色體形態且從中性或 鹹性基質(亦邸一種溶液或漿料)施用,以提供彼等之箸 色效果β此等染料可用於浴染(亦即將纗物浸沒於水性 染料溶液中)和用於呈漿料形態之印花。 本發明人等目前已經提供一種新穎方法用於施用染料 ,且僳呈較佳之還原染料之形態者,當施用到非-繼維 (請先《讀背面之注$項再4寫本頁) '裝· *訂 r 本纸張又度適用中國國家橾準(CNS ) Α4規格(210X297公釐) 經濟部中央揉準局—工消费合作社印*. A7 B7 五、發明说明(4 ) 索有機材料(待別是纖維)時,其會導致改良之耐光牢度 與耐洗牢度,且因此提供一種藉由簡單的印花或浸沒步 驟而K予適當的紅外線反射值到此等材料上。此外,彼 等之發明提供一種新穎之方法用於已染色(較佳為邐原 染料染色)之非-«維性有機材料其具有比先前所獲得之 值較提高之爾光牢度和/或耐洗牢度值者,在較佳的具 鑛實例中耐光牢度為5或更多(根鐮英固標準瀏試BS 1006 B01和B02(1978)和5或更多之耐洗牢度(根據英國槺準 澜試 BS1006 C06.C2(1981))« 因此,在本發明之第一特黏為提供一種方法用於將非 -鑛雒素有機材料以染料加以染色,换包含: (a) 將材料在通原劑和麯之存在下以染料予以處理,和 (b) 將在步《(a)所製得之經處理過之材料予以氣化; 其特微為:在步*(a>中所使用之逦原_之濃度和/或 蓮原潜力(potential)和鹼之義度是增加到离於傳統惯 用之蓮原染料所使用者,如此使得所獲得之已染色材料 之附光牢度為5或更多(藉由BS1006B01和/或802(1378) 所测得)和/或耐洗牢度為5或更多(藉由英國標準搜I試 BS1006 C06.C2所测得)和/或已染色材料具有波長400 奈米U·)光之反射率為20%或更少,較佳為1596或更少 ,更佳為1096或更少且最佳為5%或更少。更佳的是已 染色材料對在波長範園為從至700奈米之光線具有此 低反射性質。本方法能在材料之’己染色’狀態播得此等 性質,亦卽不痛要進一步處理(譬如汽蒸處理)。藉由本 本紙張尺度逋用中國«家梯率(CNS > A4规格(210X297公釐) (婧先《讀背面之注$項再填寫本I ) 、17 A7 _B7__ 五、發明説明(^ ) 方法所提供之材料可在使用之前選擇性地進一步以任何 傅統愼用之方法加以典理β 其將了解到黑色染料之反射率將少於其他色彩,特別 是指少於明亮的色彩例如黃色,且恃別是指窜反射光之 波長增加時。對軍事用途而言,本發明待別提供較佳的 已染色非-戧維素有檐材料,當染料是卡其黃時,其在 7 0 0舆1200奈米之間的反射率為6596或更少;當染料是 錄色時,在7 0 0舆1200奈米之間的反射率為50%或更少 ,•當染料是棕色時,在7Q0舆1200奈米之間的反射率.為 2+.5%或更少;而當染料是黑色時,在與120 0奈米 之間的反射率為12.5%或更少。 較佳的是在步驟(a)中所使用之染料是一種還原染料 ,但是本發明者已經確定:本技術將提供使用其他染料 之染色,例如甚至是酸性染料,即使此等染料並不是被 使用於彼等之正常pH介質。使用於本發明之較佳的邐原 染料是一種通原黑色染料。 鑪濟部中央揉準局貝工消费合作社印轚 -----_-----户 --- (婧先閱讀背面之注$項再填寫本頁) Λ1Γ 本發明可適當地藉由浸沒於鐮和還原劑之溶液中,在 fi度為介於90*0舆100 »C之間的溫度下來進行。染色步 «(a)也可使用染料、鐘與邇原_在溶液中或呈適用於 印花之漿料形態下來進行,且步骤(a)僳方便地在升高 之溫度下進行。.當组成物是一種漿料,所使用之升髙的 溫度将視漿料成分而定,例如可使用在1〇〇«〇至140°C之 蒸汽。酋在步《(a)中僳使用溶液時,較佳的是在介於 90°C與120°C之間來進行,更佳為在95°C至110T:之間來 本紙張尺度適用中國國家梂準(CNS ) A4规格(210X297公釐) 323308 ΑΊ _Β7_ 五、發明説明(ί» ) 進行。 «化步骤(b)可拜由傅统憤用之運原染色《化技術來 進行。例如,當步嫌(a)是在溶液中進行時•步糠(b)可 方便地藉由使用氣化剤之水性溶液來進行(例如二絡酸 鉀/乙酸之混合物),在升离之溫度下(例如對此混合物 約6 5*0)»也可使用空氣或氣氣諝介之氣化作用。 氣化作用較佳的是在將步《(a)所提供之纖雄性材料 淸洗後來進行。在《化作用之後,較佳的是將材料在水 中淸洗,然後在水性皂液中皂洗(較佳為加以沸煮)以移 除過量之染料。此等步隳之各所需要之遇期將視所使用 之材料和條件而定,但是對»隆而言,步驟(a)可在約 95*0下進行4 5至75分鐘,步K (b)可在65°C下進行15至 45分鐘,且在沸騰下進行皂洗處理為期5至15分鐘。 Λ濟部中央揉準局員工消费合作社印装 (請先《讀背面之注$項再填寫本頁) 將嫌物浸沒於溶液中之傅統惯用的溶液類型之遍原染 料组成物傜典型地包含約〇.〇1至〇.〇 2奠耳之氫《化銷和 0.3莫耳之連二亞硫酸《 (sodiu· dithionite)或等效的 邏原劑(例如雕白粉(Rongalite))。(參閲例如Ciba Geigy 汽巴能(Cibanone)染料製造商之説明窨)。使用於本溶掖 方法的齡(例如氫氣化鈉)之較佳的莫耳數是超遇〇·5莫耳 ,更佳為1莫耳或更多,且最佳為介於1與4莫耳之間。 鐮之最大濃度将主要視受限於要被染色之特定材料對 得柔軟之敏成性而變化,但是在浸没染色法中傅统供用 的是通常須不多於2莫耳,且在印花漿料中為不多於4 奠耳。對《隆而言,使用浸沒法用於步思(a)之典型的氳 . -8 - 本紙張尺度逋用中國國家橾率(CMS > Α4规格(210X297公釐} — mu· * A7 B7 五、發明説明(r ) 氣化納強度是1.3 3荚耳,且在用於印花法之漿料中為約 3某耳。因此,傅統供用之邇原染色法使用PH為12-13,本發 明卻使用PH為高於PH13,更佳為約pH14,结果可獲得更 持久之耐光牢度與耐洗牢度之染色。 當連二亞硫酸納是使用於本方法之步*(a)畤,呈溶掖 形態之還原劑之較佳的莫耳湯度是0.015莫耳或更多,更 佳為fl.3其耳且最佳為高於0.6契耳或更多。傳统懦用的 是可使用离至2契耳之連二亞硫酸納或其等效董,但是 並無可預見到之特定的上限,因為材料抵抗此等程度之 能力可能會有變化。 在步《 (a)中運原劑對鐮之比率較佳為大於0.001荚耳 缠二亞硫酸銷(毎莫耳氫《化銷(之邇原當*或等效 _對0 . 1至10克邇原染料。 Λ濟部中央橾準局員工消费合作社印装 |卜丨|——勹:·!II丨丨1rrl——— (請先閏讀背面之注$項再f本I) 其將了解到所需要之邇原劑之類型或用量可能會随着 其所使用之染料之功效(亦即邇原潛力)、其預期染色之 _雒材料和印花法或锶染色法而變化。因此,對1.5克 塔斯鎢(Taslan)耐隆鐵物而言,其已經發現:利用3莫 耳氫氧化納和全部7克CI邇原黑色染料、3克連二亞硫 酸銷(0.0124莫耳)於80毫升中是可適酋地用於製造本發 明之材料,如同3克之雕白粉C、雕白粉HT、雕白粉DP、 _白粉FD、雕白粉PS91、和雕白粉HT91之任何一種以類似的髏積可 製得者》然而,在使用此等條件之5克濃度下,雕白粉Η 液體、雕白粉ST液釀、和雕白粉2ΡΗ-A/ Β是比其他較無 效果。利用上述之典型的條件,本發明者已經能將耐陲 本紙張尺度逋用中國國家標準(CNS ) A4此格(210X297公釐) A7 _ _B7 _ 五、發明説明(ί ) 以酸性染料加以染色,與利用酸性染色技術所製得者相 比較,雖然所提供之色彩是改變了的。 對使用於印花法,需要將增加之籲置和S择性的邇原 剤併用室印花漿料中。當連二亞《酸納是邇原劑時,其 能以漿料添加入,例如於歟洲専利第0140 21 8號中所敘述 者,偽以連二亞硫酸銷之置增加至將可容易地藉由簡單 的實驗室實驗方法來拥定而然。對熟諳此β諳者將會出 現其他適用之邇原染料/蓮原劑/ _性漿料形態;例如 參閲 W 0 9 4 0 6 9 6 1、W 0 9 2 0 9 7 4 0、日本專利 6 3 1 8 2 4 8 2、曰本 専利63159586、·歐洲専利0162018(發泡漿狀)、英國専利2152037、曰本專利1 92001118、瑞 士専利 CH662695、日本専利 87008556B、 徳固專利4206929、歐洲專利0162018、日本專利58060084 、日本専利85030792和歃洲專利0021432。 漿科可以包含染料(例如蓮原染料)呈»色臁-鹽形贐, 例如掲述於日本専利第9 4 0 3 5 7 1 5號者,加以改質使得_ (請先W讀背面之注$項再填寫本頁} 訂 组 , 花料 印材 他用 其併 。之 果花 效印 之網 得篩 欲之 所嫌 到眼 逹形 以隠 足如 烈譬 強許 分允 成如 劑例 原, a 物 和成 Λ «濟部t央梯準局貝工消费合作杜印衷 1 增 第含 利包 專料鉀 本漿化 日的氣 如佳氳 譬較如 ϊ(。* 質 } { 改號 的19 此47 如26 以63 加第 可利如 也専例 鹼 ' 料 染 原 還 納 或 衣料 ϋ 染% 曰 WM* 和包ί aKlti) 4 且-ϊ 82_ 88两 原 邇 和 之 紫 維 m 於 對 且 料 材 素 維 0 於 朗用 種被 一 地 或知 銷皆 酸所 硫眾 亞葆 二料 連漿 ο R ΛΙ\ 爾 等 此 ° )/ 粉 白 雕 或 於 述 掲 是 料 漿 於 用 蓮 泛 廣 色 染。 原者 還中 S 和 9 4 ο 本紙張尺度逍用中困國家揉準(CNS ) A4規格(210X297公釐) 經濟部中夹樣準局負工消费合作社印装 323308 五、發明説明(9 ) 本發明方法較佳的是用於染合成有機材料,較佳為一 種落自聚芳族發胺(凱夫拉爾或諾梅克斯(RTMs)、耐隆 、聚_、聚丙烯、聚胺基甲酸酯、乙酸酯、2° -乙酸酯 、三乙酸酯和阿克利綸。在本發明之較佳的具體實例中 的方法是用於染一棰耐睡橄纖雜材料》 本發明人已通成功地將纖維和/或下列材料之鐡物加以染 色,其傜利用本發明之較佳的組成物用於進行邇原步» (a>而然者:耐陵、聚酯、二级乙酸酯、三乙酸酯、凱 夫拉爾、阿克利鎢、聚丙烯、聚胺基甲酸酯(萊克拉)和 黏®雄維。原棉也將利用本方法染色,但是當然此方法 並不是本發明之部分。若使用超高含量之齡時,該方法 會溶解羊毛和軟化乙酸酯、阿克利编、黏繆繼維和三乙 酸酯。使用最適化方法結果導致對各原棉、聚酯、凱夫 拉爾和酎隆之耐洗牢度具有完美的BS1 0 0 6'5’得分(參閲 下面);甚至對於晒隆纖維,其像熟知的具有此傳统》 隆較差之酎洗牢度,其後者仍被提供。 從在此之後所提供之實施例將容易地看見:本發明人 已經提供一種可根本改變已染色非-纖維素産品之待性 之方法,特別是指已染色之合成織維材料(例如還原染 色材料),使得彼等之酎洗牢度、耐光牢度 和反射率 可全部從通常與染色且特別是指邇原染色有醑之性質發 生變化》當在染色後之産品纖維/染料之精確的化學特 性在目前並不熟知,其清楚的是彼等己經提供新穎的己 染色材料,例如具有先前並未提供之性質的鑛維和繼維 . -11- 本纸張尺度適用中困國家橾率(〇«>入4^格(210><297公釐) i.>丨_L—!Λ;----.!訂卜—l·——^ γ (請先閲讀背面之注意事項再填寫本頁) 經濟部中央揉準局貝工消费合作社印簟 A7 ___B7___ 五、發明説明(β ) 材料。 因此,本發明之進一步觀點是一種經邇原染料色之非 •嚴維素有機材料具有耐洗牢度為至少5 (根據英固禳準 拥試BS1006 C06:C2(19 81))和/和酎光牢度為5或更多 (根據英國標準拥試BS1006B01和B02(1978))。更佳的是 材料具有附光岸度為7或更多 < 根據英國標準SI試BS1006 B 0 1和B 0 2 ( 1 9 7 8 ) ) 〇本發明也提供可藉由新穎方法獲得 之材料。 此外,本發明提供轚雒和嫌物,且包羅此等之項目包 括:地毯、汽車内部的裝餘舆覆蓋、室内裝璜、窗簾兒 舆窗簾和微繼維嫌物項目,具有此等三種耐洗牢度、耐 光牢度與低反射率性質之一種或更多之性質。其將了解 到除了鑛維和鎇物以外之材料也可利用本發明之方法加 以染色,例如隆汽車内部的裝飾舆配件例如儀錢板等。 本方法之特殊的優黏和本發明之已染色産品是:彼等 允許某些較新穎之材料例如將被採用於染色條件之聚芳 族醒胺類、聚胺基甲酸酯類舆耐睡撖纖維類並不需要包 含彼等固有之持擻(藉由將彼等舆其他材料例如纖雒素 材料摻合者)。 本發明之方法和材料現在將進一步藉由參考下列僅作 例證用之非限制性實施例來加以敘述。本發明之進一步 具體實例將使熟諳此蕤者瞭然於造些觀黏。 奮施例 實施例1 :利用朗茄爾Η T葡庖88 |[] Γ V蒱商染料里色2 7 -12- 本纸張尺度逋用中國國家揉準(CNS ) A4规格(210X297公釐) (請先閲讀背面之注$項再填寫本頁) 、1Τ 經濟部中央橾率局貝工消费合作杜印簟 A7 B7 五、發明説明(“) .Clii原染料畜色和CT薄鹿染料嫌色染耐降雄扭之方法 將耐皤鐵物(1.5克)在95 °c下於包含CI還原染料黄色( 1豪升之1.6%水性溶液)、CI還原染料黑色27(10毫升之 5%水性溶液丨和CI還原染料嫌色(1毫升之1.6%水性溶 液)舆1?毫升之4Mg氧化納水溶液、4.5克朗茄爾HT(BASF) 和水(6 0毫升)之浴掖中進行染色為期4 5分鐘。氫氣化納 最終濃度為約0.6莫耳。 在此遇期之末將鐵物以水淸洗,並使用75«升之二鉻 酸押(1.5克)舆_酸(15克)之水溶液在65°C下加以氣化 為期30分鐘。將已氣化之继物在氷中淸洗並在75毫升之 含有皂Μ (3.75克)沸騰之水溶液中皂洗為期10分鐘。結 果錄色試樣之红外線反射率足夠低,可符合NATO(STANAG) 錄色红外線反射率標準,且在介於400奈米與680奈米波 長之間為1096或更少,且在介於680奈米與1000奈米波長 之間為少於4 7 · 5 %或更少。 胃掄俐2:刹用舫笳爾HT薄庖_和(^薄鹿染料薈色.33 如Πν«鹿染料黑fa. 27染耐膝嫌物夕方法 將耐皤嫌物(1.5克)在95eC下於包含CI邇原染料黄色 33(1毫升之3%水性溶液)、CI還原染料黑色2 7 ( 2 5毫升 之5%水性溶液)舆13毫升之4M氳氣化銷水溶液、4·5克 朗茄爾ΗΤ和水(60亳升)之浴液中進行染色為期45分鐘。 氫《化銷最終濃度為約0.5莫耳。 在此週期之末将嫌物以水清洗,並加以氣化與皂洗, 如掲述於實施例1。結果綠色試樣之紅外線反射率足夠 -1 3- 本纸張尺度逍用中國國家揉準(CNS > Α4规格(210X297公釐) (請先閱讀背面之注意事項再填寫本頁)3-23308 A7 B7 V. Description of the invention (') The present invention resembles a kind of organic material used for dyeing non-woven fabrics (such as Nailing, polyester, acetate, acrilan, viscous fiber) (Viscose), polyolefins, polyurethanes and polyaromatic amides). It also applies to dyed materials. Especially refers to novel dyed non-fibrous organic materials that have improved properties that can be obtained by dyeing methods. Printed by the Beiji Consumer Cooperative of the Central Bureau of Central Economic Affairs of the Ministry of Economic Affairs (please read the $ item on the back and then fill in this page). When the traditional vat dyeing method is used for synthetic hunger (such as brushing and sleeping) Polyester) is not known to provide interesting light fastness (1 ightfastness) and washfastness (washfastness). When applying these dye-zhi synthetic materials in business, it will cause difficulties. Automotive interiors, interior decoration, curtains and decorations in homes, trains, and ships often include synthetic iron β-resistant synthetic carpets that will be exposed to bright sunlight for a long time, especially those in commercial areas that require good light fastness It is still often a metal-based compound that will be washed away when cleaned to improve light fastness. In addition, modern synthetic suspects [e.g., withdrawing Veraline], polyurethanes [e.g., lycra (RTM)] and polyaromatic amides [e.g., Kevlar (Kevlar) ( RTM} and Noiex (RTM) are well-known people who are not easy to dye. For the fiber such as Lycra material, the traditional custom is to blend them to more easily dye the material, such as dimensional Plain fibers (eg raw cotton) to achieve satisfactory dyeing. Apply Hojihara dyeing to expected synthetic materials with light fastness and light fastness (eg Nylon, Kevlar (RTM), Nomeck) (RTM), Polyoxanes, Polyurethanes and Polyesters) have been used to reduce the size of this paper and use the Chinese National Standard (CNS> A4 specifications (210X297mm) Central Ministry of Economy 323308 ^ A7 __B7 _ Printed by the Beigong Carrier and Cooperative Cooperative Society of the Bureau of State Development and Development (v): See, for example, the use of Caledon and Durindone Soledon dyes Printed flowers of textiles, (1 96 1) 3 9 1 page, paragraph 17.9 and " synthetic ion molecule Dyeing of acetate fiber, edited by D.M.Nu η η, D yers C 〇day pany P ub 1 icati ο II Trust 1979. Dyeing of synthetic materials in special fields (such as the use of service providers Clothing) is also important. In this area, materials are also dyed by reducing the reflectance at certain atmospheric 'window' wavelengths to improve their near infrared ray masking properties. Fiber cones blended with raw cotton and cellulose Among the suspects, the diziyuan dye contains a large number of conjugated structures that give correct reflection properties. This can be easily done by the Yunyuan dyeing method. However, when the dyes that they colored can be effectively faked When it contains smaller molecules, it is always difficult to use synthetic materials (such as polyester and polyester) to form a near-infrared reflection mask for Ιβ. Using a few black black raw dyes on raw cotton is sufficient to control the near-infrared properties. However, The standard dyeing conditions of the original dye and the original dye are used. When it is dyed to sleep, it has not been able to obtain a light fastness of more than 5 (British Standard Test BS1006: (1978) Β01: Β02), and at 60-C Fastness to washing It is prepared in 4 to 5 (American Standard Test BS1QQ6: (1978): C06). It is shown in Table 125 of Thoaas Vickerst.a ff " The Physical Chemistry of Dyeing " (1968) Edition, page 479: For a model nursery In terms of color, the light fastness of the attached dyed with Yunyuan dyes is not better than 2 to 3, while the raw cotton has a fastness of 5 to 8. Several techniques have been applied to provide near-infrared masking of tolerant to silk. The first of these technologies is the combined use of sulphur black pigments in printing pastes. '-4-(Please read the note on the back ^^ first and then write this page) h Binding · Order r This paper size is applicable to the Chinese National Standard (CNS > grid (210X297mm) Central Department of Central Standards A7 ________B7__ printed by the Bureau ’s Consumer Cooperatives 5. Description of the invention (present) However, nitric oxide is not easy to apply and has poor low-reflective fastness. In the second method of more limited applications, the pigment image is indirectly It is coated or filmed with a polymer into the fabric. The third method consists of a proportion of dyed black nylon yarn into the woven structure, so the centipede must be carefully spun to complete them in the final product. Masking. All these techniques will cause difficulties and inconvenience in manufacturing. The dyeing material to be special has been prepared, as described in Japanese Patent No. 0 3 0 7 6 8 8 0, although the method described It is not generally applicable, and only a few of the pending materials can be dyed according to the method. The light fastness of the material of the B dye is also improved by the re-steaming method as described in Degu Patent No. 9011668. However, this need to add will increase the complexity and And cost additional steps to the dyeing method. Therefore, there is currently a need for a dyeing method, which can apply dyes, especially from raw dyes to synthetic materials, and can provide excellent or excellent «light fastness or rinsing Fastness, and low infrared reflectivity in the military field. In particular, these boxes require these methods to be easily carried out and can be applied to synthetic materials in general. The term " reduced dye " It is well known, but usually includes pyrogen dyes such as indigo and anthracene, which must be reduced to their morphology before being regasified and from a neutral or salty matrix (also a solution Or paste) to provide their choppy effect β. These dyes can be used for bath dyeing (that is, immersing the stain in an aqueous dye solution) and for printing in the form of paste. The inventors have already Provide a novel method for applying dyes, and those in a better form of vat dyes, when applied to non-secondary dimensions (please read "Notes on the back of the back $ item and then write 4 pages") Paper is again suitable for China Standard (CNS) Α4 specification (210X297mm) Printed by the Central Bureau of Economic Development of the Ministry of Economic Affairs-Industry and Consumer Cooperatives *. A7 B7 5. Description of the invention (4) When requesting organic materials (if not fiber), it will lead to improvements Light fastness and fastness to washing, and therefore provide a suitable infrared reflectance value to these materials by simple printing or immersion steps. In addition, their inventions provide a novel method for dyeing (Preferably dyed with virgin dyes) Non- «dimensional organic materials with higher light fastness and / or wash fastness values than those previously obtained are among the preferred examples of minerals Light fastness of 5 or more (Fujian Yinggu standard test BS 1006 B01 and B02 (1978) and 5 or more wash fastness (according to the British quasi-lan test BS1006 C06.C2 (1981)) « Therefore, in the first special stick of the present invention is to provide a method for dyeing non-mineralocyanine organic materials with dyes, including: (a) Treating the materials with dyes in the presence of the original agent and koji , And (b) gasify the processed material prepared in step (a); The special feature is: the concentration and / or the potential of the lotus root and the meaning of alkali used in the step * (a > are increased to be away from the users of traditional lotus dyes, so that The light fastness of the obtained dyed material is 5 or more (as measured by BS1006B01 and / or 802 (1378)) and / or the fastness to washing is 5 or more (by the British Standard Search I BS1006 C06.C2) and / or the dyed material has a wavelength of 400 nm U ·) The reflectance of light is 20% or less, preferably 1596 or less, more preferably 1096 or less and The best is 5% or less. Even better is that the dyed material has this low reflection property for light in the wavelength range from 700 nm to 700 nm. This method can broadcast these properties in the "dyed" state of the material, and it does not hurt to be further processed (such as steaming). Use the Chinese «Home Stability Rate (CNS> A4 specification (210X297 mm) (Jing first" read the note $ item on the back and then fill in this I), 17 A7 _B7__ V. Description of invention (^) method The materials provided can be selectively further refined by any conventional method before use. It will be understood that the reflectance of black dyes will be less than other colors, especially less than bright colors such as yellow, and Don't refer to the increase in the wavelength of the channel reflection light. For military applications, the present invention will provide better dyed non- 戗 维素 eaves materials, when the dye is khaki yellow, it is in 700 0 1200 The reflectance between nanometers is 6596 or less; when the dye is recorded, the reflectance between 700 and 1200 nanometers is 50% or less, • when the dye is brown, it is 7Q0 The reflectance between 1200 nm. Is 2 + .5% or less; and when the dye is black, the reflectance between 12000 nm and 12.00 nm is 12.5% or less. The dye used in (a) is a vat dye, but the inventor has determined that this technology will provide Dyeing with other dyes, for example, even acid dyes, even if these dyes are not used in their normal pH medium. The preferred Lüyuan dye used in the present invention is a black dye of Tongyuan. Printed by the Pengong Consumer Cooperative Society -----_----- Huo --- (Jing first read the $ item on the back and then fill in this page) Λ1Γ The invention can be properly submerged in the sickle and In the solution of the reducing agent, the fi degree is between 90 * 0 and 100 »C. The dyeing step« (a) can also use dyes, clocks and 賩 原 _ in solution or in the form suitable for printing The slurry form is carried out, and step (a) is conveniently carried out at an elevated temperature .. When the composition is a slurry, the temperature of the elevated temperature used will depend on the slurry composition, for example, it can be used Steam at 100 ° C to 140 ° C. When the chief uses the solution in step (a), it is preferably carried out between 90 ° C and 120 ° C, more preferably at 95 ° C to 110T: The paper size is applicable to China National Standards (CNS) A4 specifications (210X297 mm) 323308 ΑΊ _Β7_ V. Invention (Ί ») to carry out.« Chemical step (b) can be carried out by Fu Tongyang ’s Yunyuan dyeing chemical technique. For example, when step suspect (a) is carried out in solution • Step bran (b) can It is conveniently carried out by using an aqueous solution of gasifier (eg potassium di complexate / acetic acid mixture) at elevated temperature (eg about 65 * 0 for this mixture) »air or gas can also be used The gasification effect of 慞 介. The gasification effect is preferably carried out after washing the fibrous male material provided in step (a). After the chemical action, it is preferable to wash the material in water and then Soap in an aqueous soap solution (preferably boiling) to remove excess dye. The required duration of each of these steps will depend on the materials and conditions used, but for »Long, step (a) can be carried out at about 95 * 0 for 4 5 to 75 minutes, and step K (b ) It can be carried out at 65 ° C for 15 to 45 minutes, and the soaping treatment is carried out for 5 to 15 minutes under boiling. Printed by the Employee Consumer Cooperative of the Central Ministry of Economic Development of the Ministry of Economic Affairs (please read "Notes on the back" and then fill in this page) Fu Tong's customary solution type that immerses the suspect in the solution is typical of the original dye composition. Contains about 0.01 to 0.02 mol of hydrogen "sales and 0.3 mol of dithionite" (sodiu dithionite) or equivalent logic agent (such as Rongalite). (See, for example, Ciba Geigy Cibanone dye manufacturer's instructions). The preferred mole number for the age used in the dissolution method (such as sodium hydroxide) is 0.5 moles, more preferably 1 mole or more, and most preferably between 1 and 4 moles. Between ears. The maximum concentration of the sickle will vary mainly depending on the sensitivity of the specific material to be dyed to the softness, but in the immersion dyeing method, it is usually necessary to use no more than 2 moles, and in the printing paste No more than 4 ears in the middle. For "Long, use the immersion method for step (a). Typical 氲. -8-This paper scale uses the Chinese national rate (CMS> Α4 specification (210X297mm} — mu · * A7 B7 V. Description of the invention (r) The strength of vaporized sodium is 1.3 3 pods, and it is about 3 ears in the paste used in the printing method. Therefore, the pH of the original dyeing method used by Fu Tong is 12-13, In the present invention, the pH is higher than PH13, more preferably about pH14, and as a result, more durable light fastness and washing fastness dyeing can be obtained. When sodium dithionite is used in the step of the method * (a) The preferred molarity of the reducing agent in the dissolving form is 0.015 molar or more, more preferably fl.3 its ear and the best is higher than 0.6 chil or more. Traditional Cowardly It is possible to use Lithium disulfite or its equivalent to 2 kels, but there is no specific upper limit that can be foreseen, because the ability of the material to resist these levels may change. In step "(a) The ratio of Zhongyun original agent to sickle is preferably greater than 0.001 pod entangled disulfite pin (Every mole of hydrogen sulfide (the original pin * or the equivalent _ to 0.1 to 10 grams of the original dye Λ Printed by the Employees ’Consumer Cooperative of the Central Department of Economic Affairs of the Ministry of Economic Affairs | 卜 丨 | —— 勹 : ·! II 丨 丨 1rrl ———— (please read the note $ item on the back and then f this I) It will understand what it needs The type or amount of the original agent may vary depending on the efficacy of the dye used (that is, the potential of the original agent), the expected dyeing method and the printing method or strontium dyeing method. Therefore, for 1.5 g As far as Taslan Nylon iron is concerned, it has been found that: using 3 mol sodium hydroxide and all 7 grams of CI black black dye, 3 grams of dithionite (0.0124 mol) in 80 ml is It can be used in the manufacture of the materials of the present invention, as any of 3 grams of Carabinite C, Caramelite HT, Caramelite DP, White Powder FD, Caramelite PS91, and Caramelite HT91 can be prepared with similar cross product "However, at a concentration of 5 grams using these conditions, Diao White Powder H Liquid, Diao White Powder ST Liquid Brew, and Diao White Powder 2PH-A / B are less effective than others. Using the typical conditions described above, the present invention The author has been able to use the standard of the paper resistant to the Chinese National Standard (CNS) A4 (210X297mm ) A7 _ _B7 _ V. Description of the invention (ί) Dyeing with acid dyes, compared with those made using acid dyeing technology, although the colors provided are changed. For the printing method, it needs to be increased It can be used in the room printing paste of the selective combination of the original and the original. When Lian Erya "acid sodium is the original agent, it can be added as a paste, for example, in No. 0140 21 8 The narrator, the pseudo-dithiosulfite sales will be increased to be easily achievable by simple laboratory experiments. Those who are familiar with this beta will have other suitable pyrogen dyes / lotus roots. Agent / _slurry morphology; for example, see W 0 9 4 0 6 9 6 1, W 0 9 2 0 9 7 4 0, Japanese patent 6 3 1 8 2 4 8 2, Japanese specialty 63159586, European specialty 0162018 (foamed paste), British Kelly 2152037, Japanese Patent 1 92001118, Swiss Kelly CH662695, Japanese Kelly 87008556B, Dekol 4206929, European Patent 0162018, Japanese Kelly 58060084, Japanese Kelly 85030792, and Pai Patent 0021432. Pulpaceae may contain dyes (such as lotus root dyes) in the form of 懁-salt form, such as those described in Japan's No. 9 4 0 3 5 7 1 5 and modified to make _ (please read the back side first Note $ item and then fill out this page} Ordering group, he used the material printing materials to combine them. The fruit flower is effective in printing the net, and it is suspected that the eyes are in the shape of the eye, as strong as strong, strong, and powerful. Originally, a thing and a success «The Ministry of Economic Affairs and the Central Bureau of Pyongyang's Beigong Consumption Cooperation Du Yinzhong 1 added the first package containing the special package of potassium, and the pulp of the day was as good as 抲 (. * Quality} { Changed the number of 19, such as 47, 26, 63, 63, plus Kelly, as well as alkali, the raw material is dyed or the cloth is dyed% WM * and the package is aKlti) 4 和 -ϊ 82_ 88 The dimension m is correct and the material dimension is 0. The material used in the plant is known to be used in one place or known to be sour. The thiodithiol compound is a continuous slurry. R ΛΙ \ 尔 等等 °) / Powder white carving or Yushu It is used for dyeing with pan-wide color. The original is also in the S and 9 4 ο This paper standard is easy to use in troubled countries (CNS) A4 specifications (210X297 mm) Printed by the Ministry of Economic Affairs, the quasi-bureau of negative labor consumption cooperatives 323308 V. Invention description (9) The method of the present invention is preferably used for dyeing synthetic organic materials, preferably a polyaromatic amine (Kevlar or Nomex (RTMs), nylon, poly, polypropylene, polyamine group) Formate, acetate, 2 ° -acetate, triacetate and acryl. The method in the preferred embodiment of the present invention is used for dyeing a sleeping-resistant olive fiber composite material. The inventors have successfully dyed the fibers and / or the following materials, and they used the preferred composition of the present invention to carry out the original step »(a > and those: Nailing, polyester, Secondary acetate, triacetate, Kevlar, Akryl Tungsten, Polypropylene, Polyurethane (Lycra) and Visco® male dimension. Raw cotton will also be dyed using this method, but of course this method It is not part of the present invention. If you use a very high age, this method will dissolve the wool and soften the acetate, Acrylic, Nimiaojiwei and triacetate. The results of using the optimized method resulted in a perfect BS1 0 0 6'5 'score for the wash fastness of each raw cotton, polyester, Kevlar and Suulong (see (Below); even for the sun-long fiber, which is known to have this tradition, "Long's poor wash fastness, the latter is still provided. The examples provided after this will be easily seen: The inventor has provided A method that can fundamentally change the waitability of dyed non-cellulose products, especially dyed synthetic textile materials (such as reduced dyed materials), so that their fastness to washing, light fastness and reflectance can be All changes from the nature of dyeing and especially the dyeing of the original raw dyeing. When the exact chemical properties of the product fiber / dye after dyeing are not well known at present, it is clear that they have provided novel Dyed materials, such as mineral and secondary dimensions that have properties not previously provided. -11- This paper scale applies to the rate in the middle-sleepy countries (〇 «> into 4 ^ grid (210 > < 297 mm) i . > 丨 _L—! Λ; ---- .! 定 卜 —l · —— ^ γ (Please read the precautions on the back before filling in this page) Ministry of Economic Affairs Central Bureau of Accreditation Beigong Consumer Cooperatives Inquiry A7 ___B7___ Fifth, the invention description (β) material. Therefore, this A further aspect of the invention is that a non-Yan Wei Su organic material has a wash fastness of at least 5 (according to Ingusco BS1006 C06: C2 (19 81)) and / or the light fastness is 5 or more (BS1006B01 and B02 (1978) according to the British standard). It is better that the material has a gloss shore of 7 or more < according to the British standard SI test BS1006 B 0 1 and B 0 2 (1 9 7 8)) 〇 The present invention also provides materials obtainable by novel methods. In addition, the present invention provides Zuo and suspects, and includes such items as: carpets, car interior decoration coverage, interior decoration, curtains and curtains and Wei Jiwei suspect items, with these three kinds of resistance One or more properties of washing fastness, light fastness, and low reflectance properties. It will be understood that materials other than minerals and minerals can also be dyed using the method of the present invention, for example, decorative interior parts such as car money plates and the like inside the car. The special superior adhesion of this method and the dyed products of the present invention are: they allow certain newer materials such as polyaromatic amines, polyurethanes and naphthalene to be used in dyeing conditions Fibers do not need to contain their inherent support (by blending them with other materials such as cellulosic materials). The methods and materials of the present invention will now be further described by reference to the following non-limiting examples for illustration only. Further specific examples of the present invention will make those who are familiar with this knowledge more obvious. Fenshi Example Example 1: Use of Long Eggplant Η ΤΤ 庖 88 | [] Γ V 蒱 商 dye color 2 7 -12- The paper size is based on the Chinese National Standard (CNS) A4 specification (210X297 mm ) (Please read the note $ item on the back and then fill out this page), 1T Ministry of Economic Affairs, Central Bureau of Consumer Affairs, Beigong Consumer Cooperation Du Yinmu A7 B7 V. Description of the invention (“). Clii original dye animal color and CT thin deer dye The method of discoloring and resisting torsion resistance is to dissolve the resistant iron (1.5 g) at 95 ° C in a yellow containing CI vat dye (1.6% aqueous solution of 1 liter), a black vat dye 27 (5 in 10 ml) % Aqueous solution 丨 and CI vat dyes (1 ml of 1.6% aqueous solution) and 1? Ml of 4Mg sodium oxide aqueous solution, 4.5 kronol HT (BASF) and water (60 ml) bath dyeing The duration is 45 minutes. The final concentration of hydrogen hydride is about 0.6 mole. At the end of this period, the iron is washed with water, and 75 liters of dichromic acid (1.5 g) and acid (15 g) are used. ) The aqueous solution was vaporized for 30 minutes at 65 ° C. The vaporized secondary was washed in ice and dissolved in 75 ml of boiling water containing soap M (3.75 g) Medium soaping takes 10 minutes. As a result, the infrared reflectance of the color recording sample is low enough to meet the NATO (STANAG) color infrared reflectance standard, and it is 1096 or more between 400 nm and 680 nm wavelength Less, and less than 47.5% or less between 680 nm and 1000 nm wavelength. Stomach 2: The use of Fang Lier HT thin _ and (^ thin deer dye color .33 Such as Πν «Deer Dye Black fa. 27 dyeing knee-resistant susceptible evening method. The refractory-resistant susceptor (1.5g) is contained at 95eC in CI containing original dye yellow 33 (1ml of 3% aqueous solution), CI reduction Dye black 2 7 (25 ml of 5% aqueous solution) and 13 ml of 4M aqueous solution of vaporized pin, 4.5 Krona egg HT and water (60 ml) were dyed for 45 minutes. Hydrogen "The final concentration of the chemical pin is about 0.5 mole. At the end of this cycle, the suspect is washed with water, and then vaporized and soaped, as described in Example 1. As a result, the infrared reflectance of the green sample is sufficient -1 3- The size of this paper is in accordance with Chinese National Standard (CNS & Α4 specifications (210X297mm) (please read the precautions on the back before filling this page)
B7__ 五、發明説明(^ ) 低,可符合U Κ Μ o D反射率規格,在介於4 0 Q奈米輿6 8 0奈 米之間為10%或更少,且在介於680奈米與1QOO奈米波 長之間為少於47.5%或更少^ 窨掄例3:利用朗笳爾ΗΤ蒱鹿薄I和CT蒱原染料黑色27 染酎除继物以靱得卡其番色載夕雄物 本方法利用相同黑色染料以製造不同色彩和澤之能力 ,偽藉由將耐隆鏃物(1 . 5克)在9 5 °C下於包含C I邇原染 料黑色27(2毫升之5%水性溶液)、氫氣化納(10毫升之 4 Μ水溶液)、朗茄爾HT(BASF)(3克)和水(60毫升)之水 溶液中進行染色為期4 5分鐘來作説明。 將經處理過之試樣加以清洗、《化和皂洗,如掲述於 實施例1。在70G奈米舆12QQ奈米之間的反射率發現為60% 或更少且適用於DKMoD之用途。 奮旃例4:利用朗茄爾HT蒱鹿酬和CT箱鹿棕色:Π染料 將耐降染色 經濟部中央標準局属工消费合作社印装 (請先閲讀背面之注$項再填寫本頁) 將酎隆継物(15克)在95°C下於包含CI邇原棕色染料33 (4.5克)、氫氣化納(25毫升之8^水性溶液中)、朗茄爾訂 (BASF)(5.5克)和水(50立方公分)之水溶液中進行染色為 期45分鐘。氫氣化鈉最終濃度為約2.7莫耳。將經處理過 之試樣加以清洗、氣化和皂化,如掲述於實施例1者, 且發現暗棕色産品之紅外線反射率符合UK MoD反射率規 格,在400奈米與1200奈米之間的反射率為25%或更少。 奮施例5:刺用朗笳爾HT潭原酬和CI溴鹿染料黑色30 和CI潭庖染料黑色25將耐咯染色 -14-本紙張尺度適用中蠲國家標準(CNS ) A4規格(210X297公釐) 經濟部中央揉準局貝工消f合作社印装 A7 ____B7___ 五、發明説明( 將酎隆纗物(1.5克)在95-C下於包含CI邇原染料黑色 30(4克)、CI邇原染料黑色.25(2.5克)、氳氧化銷(3〇立 方公分之8M水性溶液)、朗茄爾HT(5克)和水(5()之方公 分)之水溶液中進行染色為期45分鐘。氳氣化鈉最终濃 度為約3某耳。 將經ίΤ理過之試樣加以淸洗,氣化和皂洗,如掲述於 實施例1,且發明所《得之黑色産品之红外線反射率符 合UK MOD反射率規格;在400奈米舆1200奈米之間的反 射率為1 0 %或更少。 啻掄例6:刹a璩二邸砝酴纳》τπτ箱Μ染料孱隹Μ和 谶鹿染料黑色20将琪斯给鏃物染色. 將塔斯綸耐睡嫌物(1.5克)在95-C下於包含CI邇原染 料黑色30 (4.5克)、CI還原染料黑色25(2. 5克)、氫氣化 鈉(30立方公分之8Μ水性溶液)、連二亞硫酸銷(B7__ Fifth, the invention description (^) is low, it can meet the U Κ Μ o D reflectance specifications, between 4 0 Q nanometers and 6 8 0 nanometers is 10% or less, and between 680 nanometers The wavelength between rice and 1QOO nanometers is less than 47.5% or less ^ Example 3: Use Langjier HT 蒱 thin I and CT 蒱 原 dye black 27 dyeing and removing the follower to get khaki color This method uses the same black dye to produce different colors and lustres. This is achieved by containing the Nylon (1.5 g) at 95 ° C. in a CI black dye (27 ml) 5% aqueous solution), hydrogen hydride (10 ml of 4 M aqueous solution), Longanol HT (BASF) (3 g) and water (60 ml) aqueous solution were stained for 45 minutes to illustrate. The treated samples were washed, chemically and soaped, as described in Example 1. The reflectivity between 70G nanometers and 12QQ nanometers was found to be 60% or less and is suitable for DKMoD applications. Endeavour Example 4: Use Longhorn HT Kulu Deer Pay and CT Box Deer Brown: Π Dye will be printed by Naijiang Dyeing Industry and Consumer Cooperative Cooperative (Ministry of Economic Affairs, Central Standard Bureau) (please read the note $ item on the back and fill in this page) Elongate (15g) at 95 ° C in a CI containing brown dye 33 (4.5g), sodium hydroxide (in 25ml of 8 ^ aqueous solution), Longanerding (BASF) (5.5g) Dye with an aqueous solution of water (50 cm3) for 45 minutes. The final concentration of sodium hydroxide is about 2.7 moles. The processed samples were washed, gasified and saponified, as described in Example 1, and the infrared reflectance of the dark brown product was found to meet the UK MoD reflectance specifications, between 400 nm and 1200 nm The reflectivity is 25% or less. Fenshi Example 5: Lang Langer HT Tanyuanfu and CI bromine dye black 30 and CI Tanbu dye black 25 will be resistant to dyeing 14-This paper scale is applicable to the Chinese national standard (CNS) A4 specification (210X297 Ali) Printed A7 ____B7___ in the Beigongxiao Cooperative of the Central Ministry of Economic Affairs of the Ministry of Economic Affairs. V. Description of the invention (including the Lozenge (1.5g) under 95-C, including the CI original dye black 30 (4g), CI It is dyed in an aqueous solution of black original dye black .25 (2.5g), oxidized pin (8M aqueous solution of 30cm ^ 3), Longaner HT (5g) and water (5 (cm)) for a period of 45 Min. The final concentration of vaporized sodium is about 3 ears. The conditioned sample is washed, vaporized, and soaped, as described in Example 1, and the infrared product of the black product obtained by the invention The reflectance meets the UK MOD reflectance specification; the reflectance between 400 nm and 1200 nm is 10% or less. Example 6: 電 a 璩 二 二 重 醴 纳》 τπτ 箱 Μ Dye 魹 Μ and Dawn deer dye black 20 dyes Kies to the yam. Tasilon sleep resistant substance (1.5 g) at 95-C contains CI original dye black 30 (4.5 ), CI vat dye Black 25 (2.5 g), sodium hydrogen of (8Μ 30 cc of an aqueous solution), dithionite pin (
Na2 S2 〇4 -Vickers Laboratory)(3克)及水(50立方公 分)之水溶液中進行染色為期45分鐘。氫«化銷最終« 度為3莫耳。經處理之樣品以如實施例1所述者淸洗, 氣化及皂洗,且發明所獲得之黑色産品之红外線反射$ 符合UK MoD反射率規格;在400奈米舆1200奈米之間的 反射率為1096或更少。 密淪拥7:泡丨用夂獯不固覇鹿酬逛奮旃例6之边料将耐睡— 嫌物1逛侍. 在1.5克附睡(塔斯编嫌物試樣重複實施例6之染色方 法,使用各種不同之BASF朗茄爾與雕白粉糸之還原劑以 -15- 本紙法尺度逍用中國國家標率(匸灿)八4规格(210父297公釐) (請先閲讀背面之注f項再填寫本頁) 訂 4 經濟部中央揉準局貝工消费合作社印装 A7 B7 五、發明説明(^ ) 取代連二亞硫酸銷β此等化學試薄之待性拂列在表1中。 運原劑 待性 雕 白 粉 Η液體 次 硫 酸 鹽 衍 生 物 雕 白 粉 ST液體 亞 磺 酸 鹽 衍 生 物 雕 白 粉 2ΡΗ-Β液醱 2ΡΗ- Α無機物 雕 白 粉 2PH-A液醱 2ΡΗ- B脂肪族磺酸衍生物 雕 白 粉 C 羥 甲 院 亞 磺 酸 鹽 雕 白 粉 ΗΤ 次 硫 酸 衍 生 物 雕 白 粉 DP 羥 甲 院 亞 磺 酸 鹽混合物 雕 白 粉 FD 次 硫 酸 衍 生 物 朗 in 爾 PS 9 1 次 硫 酸 衍 生 物 朗 描 爾 ΗΤ9 1 次 硫 酸 衍 生 物 從造值研究發現各雕白粉C、HT、DP、FD和朗茄爾PS91 與ΗΤ91在3克於80毫升中在95 °C下是足夠強的運原劑, 以産生在波長為400奈米與10GQ奈米之間所霈要的反射 率值為1096或更少者。雕白粉2PH-B液體(3克)混合以雕 白粉2PH-A固體者被發現其無法逹到軍事用途的反射率 (介於900奈米與1200奈米之間為超10%),如同雕白粉 ST與Η液體(5克於各個例中),但是會影轘根據本發明 之染色。 -1 6 - 本紙張XJt適用中國國家標率(CNS ) Α4规格(210X297公釐) ί !_ — l·---ο------訂,_| ---- (請先閲讀背面之注$項再蜞寫本頁) 經濟部中央揉準局貝工消费合作社印策 A7 _B7_ 五、發明説明() 窨旃例8:使用夂耱不固眚少薄原_夕耐膝染色 改變在實施例6中之連二亞硫酸鈉濃度之效應,僳對 1.5克耐隆微纖維試樣之染色參考藉由反射率光譜儀所 測得之色彩損失來澍定。結果顯示於如下表2。 Μ___2 連二亞硫 酸鹽(克) 4 0 0奈米反 射率(% ) 4 0 0奈米反射率在 C06 C2冲洗之後 差異 0.12 2 5.24 3 1.22 5 . 98 0.25 15.22 17.41 2.19 0.53 10.73 11.29 0.56 1.00 3.89 4.01 0.12 2.00 4.02 4.17 0.15 此等結果偽利用10毫升之8Μ氫氣化納和60立方公分水 所獲得,利用實施例6之染料,因此提供氫氣化鈉濃度 為約1.14莫耳,與典型的還原染料配方相比較則為約 0 . 0 1 5莫耳。 結果顯示當在70毫升之水液中之連二亞硫酸納是低於 1克時,在清洗時從織物上之色彩損失會變得顯著,所 以在此濃度會改變已染色鏃物性質的一些變化已經發生。 窨旃例9:使用各種不固鼉:>鹸(氳氮化納):>耐膝染色 改變氫氣化鈉濃度同時維持最適(2克於60-70毫升)之 -1 7 - 本紙張尺度適用中國國家橾準(CNS ) Α4规格(210X297公釐) __:___:____ft______丁:__^____f , ^ ί Λ i i ix (請先閲讀背面之注意事項再填寫本X ) OV 3Na2 S2 〇4 -Vickers Laboratory) (3 grams) and water (50 cubic centimeters) were dyed in an aqueous solution for 45 minutes. The degree of hydrogen «chemical sales» is 3 moles. The processed sample was washed, vaporized and soaped as described in Example 1, and the infrared reflection of the black product obtained by the invention complies with the UK MoD reflectance specification; between 400 nm and 1200 nm The reflectance is 1096 or less. Millionaire 7: bubble 丨 use the stubborn bucks to pay for the excitement of the side material of Example 6 will be resistant to sleep-suspect 1 to walk around. Sleep at 1.5 grams (Tass edited suspect sample repeat Example 6 The dyeing method uses various reducing agents of BASF Longanol and Rongalite to -15- the standard of Chinese paper standard (岸 灿) 84 specifications (210 father 297 mm) (please read first Note f on the back and then fill in this page) Order 4 A7 B7 Printed by Beigong Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs 5. Description of the invention (^) To replace the sales of β-thionite and other chemical test books In Table 1. The original agent is ready to be prepared. White powder H liquid hyposulfite derivative white powder ST liquid sulfinate derivative white powder 2PH-B liquid 2PPH-A inorganic powder white 2PH-A liquid 2PPH-B Aliphatic sulfonic acid derivative Rongalite C hydroxymethane sulfinate Rongalite HT Hyposulfuric acid derivative Rongalite DP hydroxymethane sulfinate mixture Rongalite FD hyposulfuric acid derivative Lang in Seoul PS 9 1st sulfuric acid derivative Lungsher ΗΤ9 1 time sulfur The acid derivative from the value research found that each of Rongalite C, HT, DP, FD, Longhorn PS91 and HT91 in 3 grams in 80 milliliters at 95 ° C is a sufficiently strong transport agent to produce at a wavelength of 400 The desired reflectance value between nanometers and 10GQ nanometers is 1096 or less. Carved white powder 2PH-B liquid (3 grams) mixed with carved white powder 2PH-A solid is found to be incapable of military use Reflectivity (over 10% between 900 nm and 1200 nm), just like Rongalite ST and H liquid (5 g in each case), but will affect the dyeing according to the invention. -1 6- This paper XJt is suitable for China National Standard Rate (CNS) Α4 specifications (210X297 mm) ί! _ — L · --- ο ------ order, _ | ---- (Please read the note on the back $ Xiang Zai wrote this page) Printed A7 _B7_ of the Beigong Consumer Cooperative of the Central Ministry of Economic Affairs of the Ministry of Economic Affairs. 5. Description of the invention () Example 8: Use of unconsolidated and unremarkable raw materials The effect of the concentration of sodium dithionite in 6 on the dyeing of 1.5 g Nylon microfiber samples is determined by reference to the color loss measured by the reflectance spectrometer. The results show Table 2 below. Μ ___ 2 dithionite (g) 4 0 0 nanometer reflectance (%) 4 0 0 nanometer reflectance difference after C06 C2 rinse 0.12 2 5.24 3 1.22 5.98 0.25 15.22 17.41 2.19 0.53 10.73 11.29 0.56 1.00 3.89 4.01 0.12 2.00 4.02 4.17 0.15 These results were obtained by using 10 ml of 8M hydrogen hydroxide and 60 cubic centimeters of water. The dye of Example 6 was used, thus providing a sodium hydroxide concentration of about 1.14 moles, and Typical vat dye formulations are about 0.015 moles compared. The results show that when the sodium dithionite in 70 ml of water is less than 1 gram, the color loss from the fabric during washing will become significant, so at this concentration will change some of the properties of the dyed noodles Change has already taken place. Example 9: Use of various non-fixed moles: > 鹸 (氰 nitride): > knee dyeing to change the concentration of sodium hydroxide while maintaining the optimum (2g in 60-70ml) -1 7-this paper The standard is applicable to China National Standard (CNS) Α4 specification (210X297mm) __: ___: ____ ft______ D: __ ^ ____ f, ^ ί Λ ii ix (please read the precautions on the back before filling in this X) OV 3
五 3308發明说明(a ) 連二亞硫酸《度之效應僳藉由利用如同實施例β所設定 之染料和其他條件來作研究。结果顙示於表3。 在各侮例中,此等數字相當於(約)〇、〇.32、Q·62與 1.14其耳氫氣化鈉。因此,其淸楚地顯示:若具有最適 之邇原角《度,氲氣化銷從〇·2增加至m契耳會在撤 _維之反射率提供顯著的變化,其中所提供之耐洗牢度 之BSl〇〇6 C〇6 C2分數為’5',具有在奈米之棰定的 1 反射率為低於596。 丟 .1 (请先Μ讀背面之注意事項再填寫本頁) Γ 8Μ氪氧化 納(¾升) 4 0 0奈米反 射率(% ) 400奈米反射率在 C 0 6 C 2冲洗之後 差異 0 33.54 50.20 16.66 1.25 9.65 14.49 4.99 2 . 5 3.61 3 . 7 0.09 5 3.45 3.67 0.22 10 4.02 4.17 0.15 Μ濟部中央搮準局貝工消费合作社印装 當在微繼維或原棉上像使用如上所設定之染色方法t ,測試污斑(stain)對鄰近的織物之轉移,發現其並不 顯著。在實施例8(〇_12舆0.25克連二亞硫酸)以橄缳維 所獲得之兩宿試樣和在實施例9(0與1.2毫升氫氧化納 以撤纖維所獲得之兩傾試樣在耐洗牢度試驗液中所産」 -18 本纸張尺度逍用中國國家揉準(CNS ) A4规格(210X297公釐) 經濟部中央標準局*C工消费合作社印策 A7 _B7_ 五、發明说明(·7 ) 之色彩損失並不顯著。無染料出現在任何其他試樣中。 窗掄俐10:塔舫綸酎降之染角.:皮射銮、耐泮庄庙甲 耐光牢度_ 使用於此研究的是塔斯繪酎陵,具有熔點為2 6 4°C和 熔融吸熱為90焦耳/克。將塔斯编(1.5克)在95T:下於 含有CI蓮原染料黑色30(4克)、CI還原染料黑色25(2.5 克)、30毫升之8M氳氣化鈉、朗茄爾HT(5克)和水(50毫 升)之溶液中加以染色為期45分鐘。氫氣化納之最終其耳 數為3莫耳。 在淸洗之後,將試樣在65eC之含有K2 Cr2 07舆醋酸 (15克)之75毫升水溶液中氣化為期30分鐘。在清洗之後 ,將試樣在沸騰之含有3.75克皂片之水溶液中清洗為期 10分鐘。試樣所提供之可見光與红外線反射率是顯示於 下表4β如下所述之耐光牢度試驗BS 1 0 0 6 ISO/R B01與 Β02所提供性能之評價為7 + ,且酎洗牢度試驗BS1006 ISO/R C06C2所提供性能之分數為5,因此證實根據本 ,發明之産品之獨特的特性。此耐陵是特別適用於若汽車 内部像存在需要耐光牢度黑色耐隆室内裝璜舆其他内部 的物品;目前經黑色染色之耐隆之駙光牢度分散僅為介 於4舆5之間。 -19- 本紙張尺度適用中國國家揉率(CNS > Α4规格(210X297公釐) (請先閱讀背面之注$項再填寫本頁) 、1Τ -ΜΗ : 五、發明説明(,?) 寿 4 A7 B7 經濟部中央揉準局貝工消费合作社印装 波長 反 射率 波 長 反 射率 400 奈 米 3 .01% 420 奈 米 3 .03% 440 奈 米 2 .97 % 460 奈 米 2 .94 % 480 奈 米 2 .94% 500 奈 米 2 .89 % 520 奈 米 2 • 90 % 540 奈 米 2 .90 % 560 奈 米 2 .94 % 580 奈 米 2 .92 % 600 奈 米 2 .95% 620 奈 米 2 .95 % 640 奈 米 2 .97% 660 奈 米 2 .95% 680 奈 米 2 .91% 7 0 0 奈 米 2 .26 % 7 2 0 奈 米 2 .27% 7 4 0 奈 米 2 .32 % 760 奈 米 2 • 34% 780 奈 米 2 .36% 800 奈 米 2 .37% 82 0 奈 米 2 .72% 84 0 奈 米 2 .66% 8 6 0奈 米 2 .86 % 880 奈 米 3 .28 % 90 0 奈 米 3 .21% 920 奈 米 3 .22% 9 4 0 奈 米 3 .31% 960 奈 米 3 .34 % 980 奈 米 3 .59% 1 0 0 0 奈 米 3 .66% 奮施例1. 1:使闲增加:>_ /增加箱庖酬方法於凯丰 爾、聚酷、笛二級7,酸酯、三Z酸酯、羊苯、阿克利 输、聚丙烯、黏暖繼維、耐膝铒鹿楠;屮較用 -20- 本紙張尺度適用中國國家揉準(CNS ) Α4规格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁) < .A 4 / / 0 A7 B7 五、發明説明(《9) (请先閱讀背面之注意事項兵填寫本頁) 下列之議定耆<protocol)傺利用15克之呈纖維形態 之各下列材料進行:飢夫拉爾、聚酯、二级乙酸酯、三 乙酸酯、羊毛、阿克利编、聚丙烯、黏謬鑛維與原棉。 將嫌物在95 °C下利用1克邇原染料棕色33、2克朗茄 爾HT、50毫升4U氳氧化納舆25毫升水進行染色為期45分 鐘,其獲得最終氫氣化銷濃度為2. 64契耳。將已染色試 樣在65 °°下利用一極含有20克/公升之二益酸鉀 U2 Ci>2 〇7 )與19〇克/公升之醱酸之溶液加以氣化為 期30分鏞。然後将已氣化之雄物在i〇(rc下含有75毫升 之水舆3·7 5克之皂Η之溶液中進行皂洗為期15分鑲。 上面所提到之全部嫌物被染色至某些程度除了羊毛以 外,因為其溶解於此等條件下β所有的嫌物視覺上已染 成棕色,除了被染成黑色的原棉以外。聚酯與聚丙烯繼 維利用此特殊配方舆使用柔軟的乙酸_、三乙酸酯、黏 謬鐵維和阿克利綸之條件僅被染成淡色澤;欲避免此情 .況是箱要降低驗瀑度。在凱夫拉爾、聚酯舆原棉上進行 W洗牢度試驗(BS1006 ISO C06 C02),且結果顙示於表5。 錢濟部中央梂準局貝工消费合作社印裝 -21- 本紙張尺度逋用中國國家橾率(CNS > A4规格(210X297公釐) 經濟部中央標準局負工消费合作社印装 A7 __ B7 五、發明説明(>« ) 鎇物 污斑/分數 污斑/分數 飢夫拉爾 原棉© 飢夫拉爾⑸+ 聚酯 原棉⑸ 聚酯⑸ 原棉 原棉® 原棉⑸ 耐隆 原棉⑸ 耐降⑸ 奮掄期Μ 利用声鹿染料薈色33之耐降撤繼雒垫色:5. Description of the invention of 3308 (a) The effect of dithionous acid was studied by using the dye and other conditions as set in Example β. The results are shown in Table 3. In each case, these figures are equivalent to (approximately) 〇, 〇.32, Q · 62 and 1.14 Qi'er sodium hydroxide. Therefore, it clearly shows that if the optimal angle of the original angle "degree, the increase of the gasification pin from 0.2 to m Chele will provide a significant change in the reflectance of the withdrawal dimension, which provides washability The BSlO6 C〇6 C2 score of fastness is '5', with a reflectance of 1 in nanometers below 596. Throw. 1 (please read the precautions on the back before filling this page) Γ 8Μ KrO3 (¾ litre) 4 0 0 nanometer reflectivity (%) 400 nanometer reflectivity difference after C 0 6 C 2 rinse 0 33.54 50.20 16.66 1.25 9.65 14.49 4.99 2. 5 3.61 3. 7 0.09 5 3.45 3.67 0.22 10 4.02 4.17 0.15 Μ Ministry of Economic Affairs Central Bureau of Customs and Crafts Consumer Cooperative Printed on micro-dimensional or raw cotton as set above The dyeing method t, testing the transfer of stains to adjacent fabrics, was found to be insignificant. In Example 8 (〇_12 and 0.25 g of dithionous acid) two-well samples obtained with carbamazepine and in Example 9 (0 and 1.2 ml of sodium hydroxide to remove fibers obtained from the two-inclined samples Produced in the washing fastness test solution "-18 This paper scale is easy to use the Chinese National Standard (CNS) A4 specification (210X297 mm) Central Bureau of Standards of the Ministry of Economic Affairs * C Industrial and Consumer Cooperative Institution A7 _B7_ V. Description of invention (· 7) The color loss is not significant. No dye appears in any other samples. Window Luli 10: Tafanglun's lowered dyeing angle .: Leather Shek Luang, Naopanzhuang Temple Armor Lightfastness_ Use What we are studying here is Tassin Souling, which has a melting point of 264 ° C and a melting endotherm of 90 Joules / gram. The tassian (1.5 grams) is prepared at 95T: under the CI lotus dye black 30 (4 G), CI Vat Dye Black 25 (2.5 g), 30 ml of 8M NaOH vaporized solution, Longcon HT (5 g), and water (50 ml) were dyed for 45 minutes. The number of ears is 3 moles. After washing, the sample is vaporized in 65 ml of 75 ml aqueous solution containing K2 Cr2 07 and acetic acid (15 g) for a period of 30 After cleaning, the sample is washed in a boiling aqueous solution containing 3.75 grams of soap flakes for 10 minutes. The visible and infrared reflectances provided by the sample are shown in the following table 4β Light fastness test BS as described below 1 0 0 6 The performance provided by ISO / R B01 and Β02 is evaluated as 7 + and the scouring fastness test BS1006 ISO / R C06C2 provides a performance score of 5, thus confirming the unique characteristics of the product according to the invention . This Nailing is especially suitable for the interior of the car if there is a need for light fastness. Black Nailong interior decoration and other internal items; currently the black light dyed Nailon's light fastness dispersion is only between 4 and 5. -19- This paper scale is applicable to China's national rubbing rate (CNS> Α4 specifications (210X297mm) (please read the $ item on the back and then fill in this page), 1Τ -ΜΗ: Fifth, invention description (,?) Shou 4 A7 B7 Printed Wavelength Reflectance 400 nm 3.01% 420 nm 3.03% 440 nm 2.97% 460 nm 2.94% 480 nm 2.94% 500 nm 2.89% 520 Nano 2 • 90% 540 Nano 2.90% 560 Nano 2.94% 580 Nano 2.92% 600 Nano 2.95% 620 Nano 2.95% 640 Nano 2.97% 660 Nano Rice 2.95% 680 nm 2.91% 7 0 0 nm 2.26% 7 2 0 nm 2.27% 7 4 0 nm 2.32% 760 nm 2 • 34% 780 nm 2 .36% 800 nm 2.37% 82 0 nm 2.72% 84 0 nm 2.66% 8 6 0 nm 2.86% 880 nm 3.28% 90 0 nm 3.21% 920 nanometers 3.22% 9 4 0 nanometers 3.31% 960 nanometers 3.34% 980 nanometers 3.59% 1 0 0 0 nanometers 3.66% Endeavour Example 1. 1: Increase idleness : ≫ _ / Increase the box payment method for Kaifenger, Juku, Flute Grade 7, Ester, Tri-Z-ester, Sheep Benzene, Acrylic, Polypropylene, Sticky Warm, and Knee-Er Deer Nan; Bijiao -20- This paper scale is suitable for China National Standardization (CNS) Α4 specification (210X297mm) (please read the precautions on the back before filling this page) < .A 4 / / 0 A7 B7 5 1. Description of the invention ("9" (please read the precautions on the back and fill in this page first) The following agreement 〈protocol〉 Ye use 15 grams of fiber Forms of the material for the following: hungry Fula Er, polyester, two acetate, tris acetate, wool, Ackerly ed., Polypropylene, cotton and sticky Paradox ore dimension. The suspect was dyed at 95 ° C for 1 minute with 1 gram of original dye brown 33, 2 kronasol HT, 50 ml of 4U sodium oxide and 25 ml of water, and the final hydrogenation concentration was 2.64. Cheer. The dyed sample was vaporized at 65 ° using a solution containing 20 g / liter of potassium dibirate (U 2 Ci> 2 〇7) and 190 g / liter of citric acid for 30 minutes. Then the vaporized male is soaped in a solution containing 75 ml of water and 3.7 g of soap H under rc (rc for 15 minutes). All the above mentioned suspects are dyed to some Except for wool, because of its dissolution in these conditions, all the suspects of β have been visually dyed brown, except for raw cotton that has been dyed black. Polyester and polypropylene use this special formula and use soft acetic acid The conditions of _, triacetate, viscous iron and acryl are only dyed to a light color; to avoid this. The case is to reduce the test degree. W washing on Kevlar, polyester and raw cotton Fastness test (BS1006 ISO C06 C02), and the results are shown in Table 5. Qianji Ministry of Central Bureau of Industry and Commerce Beigong Consumer Cooperative Printed -21- This paper scale uses the Chinese national rate (CNS > A4 specification ( 210X297 mm) A7 __ B7 printed by the Consumer Labor Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (> «) Smudge / fractional stain / fractional Hungarian raw cotton © Hungry Lar⑸ + Poly Ester Raw Cotton ⑸ Polyester ⑸ Raw Cotton Raw Cotton® Raw Cotton ⑸ Nylon Raw Cotton ⑸ Resistance to Drop ⑸ During the Fen period Μ Use the sound deer dye color 33 to withstand the drop of the Luo pad color:
It洗牢庶研弈 進一步在此等雜物(酎陵撤纖雒是熟知的具有比傳统 憤用酎皤較差之耐洗牢度)利用:0.1克運原染料黃色33 、2克朗茄爾Η T舆1〇毫升8M氫氧化納於60毫升水中進行 染料;最終氫氣化銷濃度為h14莫耳。在經先前所敘述 之《化與皂洗之後,將嫌物進行BS1006 ISO C06 C2耐洗 牢度試驗且分數為完美1'。 啻旃例H眭畀邐鹿割;利用朗茄爾HT與氳氲化 鹼夕hh蜜:甜笳爾麝度_ 其預期隨著色澤深度增加,在耐洗牢度試驗中之鄰近 的織物之污斑增加。此使得狀況後雜化,因為當還原薄* 濃度減少時,鐡物染成較淡色澤,雖然污斑也變更壞。 下面表6清楚地展示降低朗茄爾HT爨度會影鬱到染料黏 合到纖維;^方式。 -22- 本紙張尺度遑用中國困家標率(CNS > A4规格(210X297公釐) i:_丨l·——η:. —.!訂 . (請先W讀背面之注$項再填寫本頁) A7 B7 五、發明説明(X ) 酎隆微纖雒(1.5克)是在95Ό下利用0.1克還原染料黃 色33、10毫升之8 Μ氳氣化銷與60毫升水和不同量之朗茄 爾ΗΤ加以染色為期45分鐘;最終氫氣化鈉濃度為1.14其 耳。氧化、淸洗與若洗像如先前所敘述地進行。 表6 :朗茄爾HT#耐路榭繼維夕酎洗牢庠夕放· 朗茄爾 (克) %反射率 4 0 0奈米 耐隆污 斑分數 原棉污 斑分數 降低之耐 隆色彩 0.012 3 3.83 3/4 5 4 0.12 3 9.65 3/4 5 4/5 0.27 2 5 · 04 4/5 5 4 0 . 5 14.52 4/5 5 4 1,0 6.59 5 5 4 2 . 0 3.60 5 5 4 經濟部中央揉準局貝工消費合作社印装 (請先閲讀背面之注f項再填寫本頁) Λ 最敏越的指示計是鄰近的耐隆撤纖雒之污斑。其可看 出:在低含量之朗茄爾ΗΤ,在鏃物上之染料數量是非常 低,且耐洗牢度也是低。欲確保用於此實施例之耐隆微 鑛維之優良耐洗牢度,則朗茄爾ΗΤ應該使用含量為14克 /公升。 奮掄例1 4 :臨界潭鹿酬;伸闲朗笳爾Η Τ斑M S仆.納^ 赫夕屮率氳氲化納澹麻 耐隆徹缕維(1.5克)是在95 °C利用0.1克還原染料黃色 -23-本紙張尺度逍用中國國家揉準(CNS > A4規格(210X297公釐) 經濟部中央揉準局員工消费合作社印裂 A7 _B7_五、發明説明(>>) 33、2克之朗茄爾HT舆60毫升之水加以染色為期45分鐘; 未加入齡。所提供之耐洗牢度如下:耐隆污斑分數為3 .,原棉污斑分數為4/5,降低之耐隆色彩為4。 找出描述準確性質之任何決定性的鹼舆還原劑之間的 比率是困難的。因為在固定的鹺濃度下,減少朗茄爾HT 之濃度會降低在鍇物上色彩産率,且結果導致較低之耐 洗牢度分數。對所提供之朗茄爾HT瀑度,若鹺之濃度減 少,則相同的事會發生。除了決定性的比率以外,具有 一加工窗(processing window),其中各種不同鹺對朗 茄爾HT组合可産生類似的結果。此外,此等窗是染料之 特性。 窗施例15:以減少畺:> 箱鹿勘料黑色7((K1克):> 耐膝 擻繼雒之染色 重後如上所述同一實驗,但是使用10毫升8Μ氫氧化鈉 舆還原染料黑色7(0.1克)與各種朗茄爾ΗΤ;結果提供於 下表7〇 (請先閲讀背面之注意事項再填寫本頁) f -'Φ; λ / 寿7 :朗笳爾ΗΤ在耐膝榭继維^效座 朗茄爾 %反射率 耐隆污 原棉污 減少之耐 (克) 4 0 0奈米 斑分數 斑分數 隆色彩 0.5 9.93 3/4 4/5 4/5 1.0 5.71 4 4/5 4/5 2 . 0 3.34 5 5 5 -24- 本紙張^尤逍用中國國家標準(匚呢)八4*1;格(210/297公釐> A7 B7 五、發明説明(y) 枏墟太發明所勘色夕铒獼鹿勘料黑色7染色夕煤舫淦 嫌物的柃伸強庶 利用本發明方法以較搔端的條件染色之塔斯编織_之 拉伸強度的測試以證實織物並未被加工而柔軟化。 所使用之染色處理是實施例1之方法,但例外的是所 使用之配方係由邇原染料黑色7(4克)、水{50毫升)、氫 «化納(8M、30毫升)、雕白粉C(5克)和1克之塔斯编 織物所組成。 物 鎇 綸 斯 塔 之 色 染 未 和 線 纱 之 綸 斯 塔 之 色 染 所 上 如 將 *4%> 1 ---------一 -- (請先閲讀背面之注^^項再填寫本頁) 時測強 裂之伸 斷線拉 在纱之 之十身 樣之本 試得條 試取物 測所嫌 所物量 示嫌測 展各tb 〇〇 從是 表,驗 下度試 。 長 此. 度伸 C 強與分 #力公 拉裂10 各銜是 其均度 量平 測之 長更 試度 法 方 的 慼 敏 更 之 性 軟 柔 試 於 用 為 該 應 且 便 方 經濟部中央梯準局負工消费合作社印It 試樣 平均 伸長度 % 伸長度 變化 在斷裂時 之平均力 c N 變化 在斷裂 時之最 大力 未染色 3 2 . 9 4 X 8.73¾ 510 . 40 2.96 5 3 2 · 7 I 染色 3 4 . 0 8 X 7.36¾ 526.07 2.89 5 5 8 . I 0 隆 化強 軟較 柔得 生變 發維 未纖^ ± 丨際 實 酸 (I驗 编試 斯的 塔殊 在特 示此 顯同 地如 楚示 清顯 像 跡 有 具 Μ 本紙張尺度適用中國國家標準(CNS ) A4规格(210X297公釐) A7 323308_B7__ 五、發明説明(-) 太兹明方法夕印芘夕奮掄例 將如下所述之印花漿料以標準圔樣應用方法來施用, 然後在讓其乾燥之前在115-C加以汽蒸為期15分鐘。謓 乾燥之印花《化,然後以如同敘述於上面實施例之還原 染料染色方法加以皂洗和清洗。 協fflMfi:刹用蘀鹿勘料級fel摒酎路(垅舫淦)印花 一種印花漿料傜由還原染料錄色1 (〇·6克)、雕白粉 C(0.5克)、β «化納(8Η、3毫升)、水(5毫升)舆 Polyprint(RTM)增拥薄(可獲自 Rudolph Chemicals, Derbyshire, UK)所混合而成。將所混合之漿料施用到塔 斯编嫌物,並利用如上所述和還原染料染色之實施例中 所敘述之汽蒸、乾燥、氣化、皂洗與淸洗条統加以處理。 所獲得之染色織物具有反射率值在400與8 0 0奈米之間 為20%或更低,在1〇〇〇奈米處上升至46%。 經濟部中央揉準局男工消费合作社印装 (請先閲讀背面之注意事項再填寫本頁) 啻掄俐17:刹用镧原染料碁色33將耐除(琪舫淦)印花 一種印花漿料傺由還原染料黃色33(0. 6克)、雕白粉C (0.5克)、氫氧,化鈉(8M、3毫升)、水(5毫升)舆Polyprint (RTM)增稠劑所混合而成。將所混合之漿料施用到塔斯编 嫌物,並利用如上所述和還原染料染色之實施例中所敘 述之汽蒸、乾燥、氣化、皂洗與淸洗糸統加以處理。 所獲得之染色嫌物是明亮的黃色,且具有反射率值在 4 0 0與4 6 0奈米之間為10%或更低,在4 8 0奈米為低於15% ,在500舆1〇〇〇奈米之間升為約50%。 窗掄俐18:刹用蒱原垫料軽色耪耐咯(琪舫脍) . -2 6- 本纸張尺度逍用中國國家橾準(CNS ) A4规格(210X297公釐) A7 -----B7 五、發明説明( 一種印花褒料偽由運原染料g色(〇 6克)雕白粉c( 0.5克)、氣氣化納(8M、3毫升)、水(5毫升)_p〇lyprint (RTtl)增稠劑所混合而成。将所混合之漿料施用到塔斯繪 嫌物,並利用如上所述和邇原染料染色之實施例中所敘 逑之汽臻、乾燥、氧化、皂洗與淸洗糸統加以處理。 所獲得之染色織物是蠡色/紫色色彩,且具有反射率 值在4 0 0與660奈米之間為12%或更低,在660舆7 2 0奈米 之間為低於3 0 %,在7 2 0舆1 Q 〇 〇奈米之間上升至約4 4 %。 宣施例19·♦迴用涅原染料黑色7除酎膝印扣 一種印花黎料俗由邇原染料黑色7 (〇 . 6克)、雕白粉c (0.5克)、.氫氣化納(8M、3毫升)、水(5毫升)舆Polyprint (RTM)增稠劑所混合而成。將所混合之漿料施用到塔斯鑰 嫌物,並利用如上所述和邇原染料染色之實施例中所.敘 述之汽蒸、乾燥、氣化、皂洗與淸洗糸統加以處理。 所獲得之染色鎇物是強黑色色彩,且具有反射率值在 400與700奈米之間為5 %或更低,在7fl〇與820奈米之間 為低於10%,在820與1000奈米之間上升至約15%。 置施例20:利用酸染料#太發明之鰱趂ft:卞雎煤舫綸 | 丨 — IJ----D------訂^-I ^——<1, (請先閱讀背面之注^'項再填寫本頁) 色 染 潯 以 加 路 耐 經濟部中央揉準局貝工消费合作社印装 κ - 2 定 { 設色 所黑 1 酸 例由 施是 實方 用配 利之 係液 綸溶 斯料 塔染 光.是 耐的 舆外 洗例 0 , 之供 色提 棕所 染嫌 經步 之 克)、朗茄爾HT(5克)、氫氣化納(8M 30奄升)、水(50毫 升)、塔斯编(1克)所組成β W掄例2 1 :剎用邐原染料以太兹昉方法為边i封料潘籀Γ -27- 本紙張A度逍用中國國家揉準(CNS ) A4规格(210X297公釐) B7 五、發明説明(d ) 色夕浔沿染色 將阻燃性聚芳酵胺諾梅克斯加以染色,以提供一種橄 欖色適用於軍事的偽裝用途,如同在實施例5中所設定 之條件,利用下面之配方以沸騰溫度為135 °C為期45分 鐘;配方:CI邇原染料黑色7 (0.5克)、CI還原染料綠色 1 (20克)、Cljg原染料黑色27(ϋ·5克)、水(40毫升)、 氫《化納(8Μ、20毫升)、朗茄爾ΗΤ(3.0克)、諾梅克斯 i (1.0克)。所製得之已染色之鐵物具有藉由ISO C06 C2 所澜得之耐洗牢度如下:污斑鄰近的原棉-5;污斑鄰近 的諾梅克斯-5;色澤之變化-5。所測得之耐光牢度6。 産品之紅外線反射率在高至680奈米時為低於12%且在 高至1 0 0奈米時為低於3 5 % ^ 奮槲例22:萊克拉:>浔沿恐色 將聚胺基甲酸酯鏃物萊克拉藉由本發明實施例5之方 法加以染色,鏃物是市售商品级呈聚酯-萊克拉摻合物 之形態者。使用兩種溫度值(l〇Q°C與110-C )用於邇原劑 之步驟,利用於下所提供之配方;配方:CI還原染 料棕色33(2克)、朗茄爾HT(5克)、氫氣化納(8H、30 毫升)水(50毫升)、聚酯-萊克拉(3克)。 經濟部中央樣準局員工消费合作社印製 (請先閱讀背面之注意事項再填寫本頁) 利用l〇〇°C於還原劑/齡步驟會提供ISO C06 C2附洗 牢度值為:鄰近原棉污斑為5;鄰近萊克拉污斑為5和 色澤變化為5β紅外線反射率在高至68G奈米時為低於20% 且高至100奈米時為低於30% ^將還原劑/鹼步驟之溫度 增加至110 °C也可提供所霈要之高耐洗牢度,但晕把然會 , -2 8 - 本紙張尺度適用中國國家樣準(CNS ) A4規格(210X297公釐) A7 323308 B7 五、發明説明(勹) 進一步減少紅外線反射率,使得在离至7 2 0奈米時反射 (請先閱讀背面之注意事項再填寫本頁) 率為20%或更少且高至100奈米時為低於1QQ-C值。在兩 值例中之耐光牢度均為大於5%。 用於幼鏃a斑皮茧尚試夕箱國棟進方法:Bsioofi 此等_試是更完全地解獮於可獲自英國樣準機構之文 獻中,但是在此提供簡單的概述。 BS 1 0 0 6 ISO B 0 1 : 1 9 78此方法是預期用於澜定所有的 類別和呈所有的形態之紡纗品和皮革之色彩對日光作用 之抵抗力。澜試之原則是將紡嫌品或皮革之試樣片連同 8種已染色之羊毛標準一起曝露於日光,且藉由比較舆 此等之色彩變化來評估堅牢度。 可使用兩組藍色標準,但是並不是可相互轉變,此等 為CI標準1至8(歐洲)或L標準2至9(美國):將在&洲 所顯色舆裂造之藍色標準分別以下列各八棰染料加以染 色:1:CI酸藍色104,2:CI酸藍色109, 3:CI酸藍色83,It is further researched in this study (the Lingling fiber-removing compound is well known to have poorer washing fastness than the traditional one): 0.1 g Yunyuan dye yellow 33, 2 Krone egg Η T and 10 ml of 8M sodium hydroxide were used for dye in 60 ml of water; the final hydrogenation pin concentration was h14 mole. After the chemical and soaping described previously, the suspects were subjected to BS1006 ISO C06 C2 wash fastness test and the score was perfect 1 '. Example H Sui Qi deer cut; use Lang egg HT and 氲 氲 alkali alkali hh honey: sweet mushyness_ It is expected that as the color depth increases, the stains of adjacent fabrics in the wash fastness test increase. This makes the situation post-hybrid, because when the concentration of reduced thin * is reduced, the dye is dyed lighter, although the stains are also changed. Table 6 below clearly shows that lowering the Angstall HT Cuan degree will affect the adhesion of the dye to the fiber; ^ way. -22- The standard of this paper does not use the standard rate of China's sleepy (CNS & A4 specifications (210X297 mm) i: _ 丨 l · ——η :. —.! Order. (Please read the note item on the back first (Fill in this page again) A7 B7 V. Description of the invention (X) Suolong Microfibre Luo (1.5g) is used at 95Ό with 0.1g of vat dye yellow 33, 10ml of 8 Μ gas vaporization pin and 60ml of water and different The amount of Longanol HT was dyed for 45 minutes; the final sodium hydroxide concentration was 1.14. Earrings, oxidation and washing were carried out as previously described. Table 6: Longaner HT # Nelute Xi Xian Xiu Xiu Xi Yu Lang Langer (g)% reflectance 4 0 0 nanometer Nylon stain score Raw Nylon stain score reduced Nylon color 0.012 3 3.83 3/4 5 4 0.12 3 9.65 3/4 5 4/5 0.27 2 5 · 04 4/5 5 4 0. 5 14.52 4/5 5 4 1,0 6.59 5 5 4 2. 0 3.60 5 5 4 Printed and printed by Beigong Consumer Cooperative, Central Bureau of Economic Development, Ministry of Economic Affairs ( Please read Note f on the back and then fill in this page) Λ The most sensitive indicator is the stains of the nearby Nailon Fiber Removal Lobe. It can be seen that: at a low content of Long Eggplant ΗΤ, on the 镞 物The number of dyes is very low, Moreover, the washing fastness is also low. To ensure the excellent washing fastness of the Nailong micro-mineral used in this example, the content of Langegall HT should be 14 g / L. Example 1 4: Critical tank Deer remuneration; Shen Xian Lang Shui Η Τ spot MS servant. Na ^ Hershine rate of 氲 氲 氲 化 Na Dan Ma Nylon Long Zhewei (1.5 g) is used at 95 ° C with 0.1 g of vat dye yellow-23-ben For paper size, the Chinese National Standard (CNS > A4 size (210X297mm) is printed by the Ministry of Economic Affairs, Central Bureau of Standardization and Employee Consumer Cooperatives A7 _B7_ V. Invention description (> >) 33, 2 grams of Langal HT and 60 ml of water are dyed for 45 minutes; no age is added. The wash fastness provided is as follows: the stain resistance score is 3., The raw cotton stain score is 4/5, the reduced color is 4 It is difficult to find out the ratio between any decisive alkali and reducing agents that describe the exact nature, because at a fixed concentration of tartar, reducing the concentration of Langall HT will reduce the color yield on the corona, and the result Lower washing fastness score. For the provided Langel HT waterfall degree, if the concentration of the owl decreases, the same thing Occurred. In addition to the decisive ratio, there is a processing window (processing window), where a variety of different combinations of Langer HT can produce similar results. In addition, these windows are the characteristics of dyes. Window Example 15: to reduce畺: > Box deer survey material black 7 ((K1 g):> The same experiment as described above after the knee-stained dyeing weight was repeated, but using 10 ml of 8M sodium hydroxide and vat dye black 7 (0.1 g) With all kinds of Longanol HT; the results are provided in the following table 7 (please read the precautions on the back before filling in this page) f -'Φ; λ / Shou 7: Langjier HT in the knee-resistant knee ^ effect seat Longanol% reflectance resistance to cotton stain reduction resistance (grams) 4 0 0 Nano speckle fraction speckle fraction color 0.5 9.93 3/4 4/5 4/5 1.0 5.71 4 4/5 4/5 2. 0 3.34 5 5 5 -24- This paper ^ You Xiao uses the Chinese National Standard (匚 呢) 8 4 * 1; grid (210/297 mm)> A7 B7 5. Description of the invention (y) Survey of the Taixu Tai invention Sei erbium cervus survey material black 7 dyeing and stretching of the dyed coal susceptor using the method of the present invention to dye the Tas knitting_staining under the condition of the more end Test to confirm the degree of fabric has not been processed and softening. The dyeing treatment used is the method of Example 1, except that the formulation used is composed of the original dye black 7 (4 g), water {50 ml), hydrogen hydride (8M, 30 ml), carving It is composed of white powder C (5g) and 1g Tas braid. The color of the dyestuff of the yarn is not as good as that of the yarn of the yarn of the yarn * 4%> 1 --------- 一-(please read the note on the back ^^ Please fill in this page again) When the tensile strength of the tensile crack is pulled on the tenth body of the yarn, the test strip is obtained. The amount of the suspected substance is measured. The suspected tb is displayed. test. Long time. Degree extension C 强 与 分 # 力 公 拉 裂 10 Each title is its average measurement length. The test method of Qi Mingen is soft and soft. It should be used as a response and convenient for the central government of the Ministry of Economic Affairs. It is printed by the National Bureau of Standards, Consumer Cooperatives, It. Average elongation of the sample% Average elongation change at break c N Change Maximum force at break Unstained 3 2. 9 4 X 8.73¾ 510. 40 2.96 5 3 2 7 I dyeing 3 4. 0 8 X 7.36¾ 526.07 2.89 5 5 8. I 0 swelling is strong and soft and becomes soft and fibrinous ^ ± 丨 real acid (I test editor's Tashu in special This clearly shows that the image traces are clear. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) A7 323308_B7__ 5. Description of the invention (-) Taizming method Xiyin Xifen For example, the printing paste described below is applied in a standard application method, and then steamed at 115-C for 15 minutes before allowing it to dry. The dried printing is chemical, and then described as in the above example. The dyeing method of vat dyes is soaped and washed. Mfi: For the brakes, the deer grade material fel squeezes the road (垅 舫 淦) to print a printing paste. The color is recorded by vat dye 1 (0.6g), carved white powder C (0.5g), β «Hua Na ( 8Η, 3 ml), water (5 ml) and Polyprint (RTM) thinner (available from Rudolph Chemicals, Derbyshire, UK). The mixed slurry is applied to the TASS suspect, and Use the steaming, drying, gasification, soaping and washing as described in the examples of dyeing with vat dyes as described above. The dyed fabric obtained has reflectance values between 400 and 800 nm Between 20% or lower, rising to 46% at 1000 nanometers. Printed by the Men ’s Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) 17: The original lanthanum dye 碁 色 33 will be used for the removal of resistance (Qi Fang Gan) to print a printing paste. The dye is made from a reduction dye yellow 33 (0.6 g), carved white powder C (0.5 g), hydroxide, sodium hydroxide ( 8M, 3 ml), water (5 ml) and Polyprint (RTM) thickener. Mix the mixed slurry to the TASS suspect, and use The steaming, drying, gasification, soaping and washing processes described in the examples of vat dyeing as described above and the dyeing process are processed. The obtained dyeing suspect is bright yellow and has a reflectance value of 4 It is 10% or less between 0 0 and 460 nm, less than 15% at 480 nm, and rises to about 50% between 500 and 1000 nm. Window Lili 18: Koga Mats for brakes are color-resistant (Qi Fang). -2 6- The size of this paper is easy to use China National Standards (CNS) A4 specifications (210X297 mm) A7 --- --B7 V. Description of the invention (A printing material pseudo-Yunyuan dye g color (〇6g) carved white powder c (0.5g), gasification sodium (8M, 3ml), water (5ml) _p〇 lyprint (RTtl) thickener is mixed. The mixed slurry is applied to the Tass paint, and the steaming, drying, and oxidation described in the examples of dyeing with the original dye as described above 、 Soaping and washing are processed together. The dyed fabric obtained is calyx / purple color, and has a reflectance value between 400 and 660 nanometers, 12% or lower, at 660 and 7 2 Between 0 nm and below 30%, it rises to about 4 4% between 7 2 0 and 1 Q 〇〇 Nanometer. Xuan Shi Example 19 · The nigella dye black 7 is used to remove the knee buckle A kind of printing Li material is composed of the original dye black 7 (0.6g), carved white powder c (0.5g), hydrogen hydride (8M, 3ml), water (5ml) and Polyprint (RTM) thickener It's made by mixing. The slurry is applied to the Taskey suspects and processed using the steaming, drying, gasification, soaping, and washing systems described above as described in the examples of dyeing with the original dyes. The dyeing obtained The matte is a strong black color, and has a reflectance value between 400 and 700 nm of 5% or less, between 7fl〇 and 820 nm is less than 10%, between 820 and 1000 nm Increased to about 15%. Zhi Shi Example 20: The use of acid dye # Tai invention of silver carp ft: Bianju coal ladle | 丨 — IJ ---- D ------ 定 ^ -I ^ —— < 1, (please read the note ^ 'on the back before filling in this page) The color is dyed with the print of KL-2, the Ministry of Economic Affairs, Central Bureau of Economic Development, Beigong Consumer Cooperative Society κ-2 {set color black 1 acid example Shi Shishi is dyed with a liquid-liquid-dissolving material tower of Pali. It is a durable example of foreign washing. Β W 抡 Example 2 1: Bumper for the original material used for the brake, and the sealing material is Panzi Γ -27 -This paper A degree is used Chinese national standard CNS) A4 specification (210X297mm) B7 V. Description of the invention (d) Stain dyeing flame retardant polyarylamide Nomex to provide an olive color suitable for military camouflage purposes, as In the conditions set in Example 5, the following formula was used for a boiling temperature of 135 ° C for 45 minutes; Formula: CI Pyrene Black 7 (0.5 g), CI Vat Green 1 (20 g), Cljg Original Dye Black 27 (ϋ · 5g), water (40ml), hydrogen sulfide (8M, 20ml), Longaner HT (3.0g), Nomex i (1.0g). The dyed irons obtained had the wash fastness obtained by ISO C06 C2 as follows: raw cotton adjacent to stains-5; Nomex-5 adjacent to stains; change in color-5. Measured light fastness 6. The infrared reflectance of the product is less than 12% at up to 680 nanometers and less than 35 percent at up to 100 nanometers. ^ Fenque Example 22: Lycra: > The lykla of carbamate is dyed by the method of Example 5 of the present invention. The yam is a commercially available grade in the form of a polyester-lykla blend. Use two temperature values (10Q ° C and 110-C) for the step of the original agent, use the formula provided below; formula: CI vat dye brown 33 (2 grams), Lang egg HT (5 grams) ), Hydrogen hydride sodium (8H, 30 ml) water (50 ml), polyester-Lycra (3 g). Printed by the Employees ’Consumer Cooperative of the Central Bureau of Samples of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page). Use l〇〇 ° C in the reducing agent / age step will provide ISO C06 C2 with a washing fastness value: near raw cotton The stain is 5; the neighboring Lekra stain is 5 and the color change is 5β. The infrared reflectance is less than 20% at up to 68G nanometers and less than 30% at up to 100 nanometers. The temperature of the step is increased to 110 ° C to provide the required high fastness to washing, but it will be flat, -2 8-This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) A7 323308 B7 V. Description of the invention (Yi) Further reduce the infrared reflectance, making it reflect at 7 to 20 nanometers (please read the precautions on the back before filling this page) The rate is 20% or less and up to 100 Nanometer is below 1QQ-C value. In both cases, the light fastness is greater than 5%. It is used for young cocoon a spotted cocoon is still trying to get into the box. The method is: Bsioofi. This is a more complete solution to the literature available from the British Prototype Agency, but here is a brief overview. BS 1 0 0 6 ISO B 0 1: 1 9 78 This method is expected to be used to determine the resistance of the colors of textiles and leathers of all categories and in all forms to sunlight. The principle of the Lanshi test is to expose the test piece of textiles or leather together with the 8 dyed wool standards to the sun, and to evaluate the fastness by comparing these color changes. Two sets of blue standards can be used, but they are not interchangeable. These are CI standards 1 to 8 (Europe) or L standards 2 to 9 (United States): the blue color created by & Chau The standard is dyed with the following eight dyes: 1: CI acid blue 104, 2: CI acid blue 109, 3: CI acid blue 83,
4:CI酸藍色121, 5: CI酸藍色47, 6:CI酸藍色23, 7:CI 娌濟部中央樣準局貝工消费合作社印褽 溶解型邇原染料藍色5, 8: CI溶解型邇原染料藍色8。所 有的此等染料和那些使用於實驗1至15者是列示於 Society of Dyers and Colourists (P 0 Box 244,Perkin House,82 Grattan Road,Bradford BD12JB,West Yorkshire,.United Kingdoa)所出販之染料索引(The Colour Index)(譬如,第三版)e L2至L9染料傺藉由將 各種不同比例之以CI媒染劑藍色1(染料索引,第三販, 4383Q)染色之羊毛和以CI溶解型還原染料藍色8(染料索 . -29- 本紙張尺度_適用中國國家標準(CNS ) Λ4規格(210X297公釐) A 7 · B7 五、發明説明(4 ) . 引,第三版,738(31)加以摻合所製得,所以使得各較离 编號之稼準比前面的榡準緊牢大約兩倍。 (請先閲讀背面之注意事項再填寫本頁) 所箱要之設備包括:面對太陽之曝光架(在北半球朝 向南方,在南半球朝向北方),從水平線傾斜角約等於 81試位置之緯度。較佳的是架應該設置於免於撖麋與汽 車排氣煙之非-居住和非-工業區域,其中陰彩並不會落 在紡織品上者。纺織品應該以在380奈米舆70 0奈米之間 的透明度為至少9 Q %,在3 1 0奈米舆3 2 0奈米之同為消減 為〇%之窗玻璃加以覆蓋。在紡織品後邊應該提供空氣 通氣。介於ί»璃與試樣片之間的最小容許距雛為5公分 ,且可使用之曝光區域是受限在玻璃覆蓋在各侧所減少 之區域從覆蓋至試樣片距離之兩倍。 需要不透明硬紙板或其他薄材料例如鋁箔者;需要用 於堆稹鏃物時避免緊壓之覆蓋◊也需要用於評估色彩變 化之灰色分级卡(Grey scale.)。 視是否醮用BSI方法1或2,所製得之測試試樣片為不 少於1公分X6公分或ΐχΐϋ公分,且藍色樣準是類似之 成比例化 曝光:試樣Η是曝露於日光下毎天24小時。在使用於 超濟部中央揉準局貝工消费合作社印裝 此之方法2中,試樣Η是排列成毗連標準之條料,且兩 倕間隔五分之一區域之各試樣Η是同時以不透明材料加 以覆蓋。當掀起覆蓋在標準3或L2之變化是察覺到灰色 # 分级卡為等於4-5時,檢査試樣片評價和耐光牢度,且 與標準1至3或L2相比較。將覆蓋放回,且斷鑲磁光, -30-本紙張尺度適用中國«家揉率(CNS > Α4规格(210X297公釐) 323308 A7 B7_ 五、發明说明(θ ) (請先聞讀背面之注$項再填寫本頁) 直到察覺到在標準4或L3之變化,在此時將一額外的覆 蓋重叠置於第一次覆蓋者之一和各試樣片之某些上,直 到察覺到在標準6到L5之變化,等於灰色分级卡4-5,傜 在最終覆綦是重叠在第二覆蓋上之前而然者。經四次覆 蓋之後,繼鑛曝光直到在標準7或L7之對比度等於顯示 於灰色粉级卡4;或在最具抵抗之試樣片提供對比度等 於灰色分鈒卡等级為3:以首先發生者為依據。 在數值評價上之最終評估是根據試樣Η介於曝光舆未 曝光部分之間的對比度為等於灰色分级卡4和/或3。 将所有的覆蓋移除以掲露在標準與己經曝露不同次數之 試樣片之三區域,連苘至少一未曝光之區域。將標準在 6001 X或更多落在45°舆試樣之變化相比較;耐光牢度 是在色彩上之變化符合標準者。色彩之變化可能是色諝 、深度、明亮或此等之任何組合。 使用於本實施例之藍色羊毛標準可以播自英國標準機 構(10 Blackfriars Street, Manchester M3 5 D T,U K) 經濟部中央樣準局貝工消费合作社印製 ;Beuth-Vertrieb, Burggrafenstr. 4-7.D-1000 Berlin 3 0 Germany and Japanese Standard Association, 1-24 .Akasaka 4,Minatoku Tokyo Japan.L 藍色羊毛榡準是 可獲自 American Association of. Textile Chai^sts and, P. Ο· Box 12215, Research Triangle Park, North Carolina 2 7 7 0 9 , USA0 BS1 006 ; TSn B02 Π 978 ) • ·· ·. - 此方法是意欲利用上面所施用之檫準評估對人工光線 • -31- 本纸張尺度適用中國困家橾準(CNS > A4规格(210X297公嫠) Α7 Β7 323308 五、發明説明(w )' 之耐光牢度。 所使用之設備包括充分通氣之曝光箱和相朗於溫度 5500 K至6500K之氙弧燈,介於光源與試樣片之間具有 濾光器,以棰定地降低紫外光光譜。所使用之玻璃醮該 具有在3 8 0奈米與7 5 0奈米之間的透遇率為至少9 0 %,且 在3 10奈米舆3 2 0奈米之間消減為0% ^紅外線輻射也需要 以一種黑色嵌板最大為45*C加以過濾。在曝露之表面上 Ϊ 之光強度之變化應該不多於平均量之± 10%。 當在同一試樣片上並排地作若干曝光時,傜使用紡嫌 品之區域為不少於1公分X 4.5公分。 在本賁施例中僳使用方法2:試樣片是與標準排列在 一起用於ISO B01測試,但是僅具有一覆蓋,其延仲至 至各試樣片與標準之四分之一。當在標準3之變化晒剛 可被察凳到時(等於灰色分级卡4-5),檢査試樣Η且藉 由舆揉準1至3相比較而加以分级。放回覆蓋,直到標 準4刚剛等於灰色分级卡4-5為止,此偽當額外的覆蓋 是以重叠方式固定在所有的試樣Η與標準之一部分J:時 而然饉鑲曝光直到在樣準6之變化察覺到符合灰色分级卡上5為止,此偽當第三覆蓋 是被安置與第二和某些未被覆蓋之試樣Η與標準相互重叠時而然。逛鑲曝光直到在 標準7所産生之對比度是等於在灰色分级卡上如同4所例證之對比度,或在最能抵抗 i 之試樣Η上已經能産生對比度等於灰色分级卡3,以首先發生者為依據。 最終評估是根據試樣片之介於曝光與未曝光部分之對 比度等於灰色分级卡4和/或3。將所有的覆蓋移除,且 駙光牢度是在色彩上顯示類似變化之標準之數目。’ . -32- 本紙張尺度逍用中國國家標準(CNS ) A4规格(210Χ297公釐) __:__:____Λ1-______丁 Γ 丨^, ---------一 ------、ρ------^ Lr 1 (請先閲讀背面之注意"項再填寫本頁) 經濟部中央標準局負工消费合作杜印裝 S233Q8 A7 B7 五、發明説明(Μ ) RST OOB : TSfl 006(198 1) 構 機 準 標 國 英 ΌΠ 獲 可 是 節 細 之 驗 試 此 洗 漿 據 根 係 其 與 洗 清 燥 在 地' 之度 逑溫 上之 閲定 (#設 ί所 滑參 、由 絲藉 捻像 由化 藉變 係之 者彩 後色 ·, 0 下供 件提 條所 之擊 用衝 作起 損一 磨在 與球 白銷 漂多 、許 性舆 餘動 織物 之雜 置連 放毗 連有 毗具 到僳 移估 轉評 彩 ; 色物 其鏃 估樣 評試 物之 雜斑 將染 ,未 卡舆 。 级棉化 分原變 色如彩 灰例色 考物之 (請先閲讀背面之注^'項再填寫本頁) f4: CI acid blue 121, 5: CI acid blue 47, 6: CI acid blue 23, 7: CI Ministry of Economic Affairs, Central Bureau of Standards, Beigong Consumer Cooperative Society, printed dissolving type Porogen dye blue 5, 8 : CI Dissolve Porogen Dye Blue 8. All these dyes and those used in experiments 1 to 15 are listed in the Society of Dyers and Colourists (P 0 Box 244, Perkin House, 82 Grattan Road, Bradford BD12JB, West Yorkshire, United Kingdoa) The Colour Index (e.g., 3rd edition) e L2 to L9 dyes by using various ratios of wool dyed with CI mordant blue 1 (Dye Index, 3rd Vendor, 4383Q) and CI Dissolved vat dye blue 8 (dye cable. -29- This paper standard _ applicable to China National Standards (CNS) Λ4 specifications (210X297 mm) A 7 · B7 V. Description of the invention (4). Cited, third edition, 738 (31) is made by blending, so that the standard of each number is tighter than the previous standard by about two times. (Please read the precautions on the back before filling this page) The equipment required Including: the exposure frame facing the sun (facing the south in the northern hemisphere, and facing north in the southern hemisphere), the angle of inclination from the horizontal line is approximately equal to the latitude of the 81 test position. It is preferred that the frame should be installed to avoid the exhaust smoke of the moose and the car Non-residential and non-industrial areas, including shade Those who will not fall on textiles. Textiles should have a transparency between 380 nanometers and 70 nanometers of at least 9 Q%, and 3 10 nanometers and 3 200 nanometers should be reduced to 0% The window glass should be covered. Air ventilation should be provided behind the textile. The minimum allowable distance between the glass and the specimen is 5 cm, and the exposure area that can be used is limited to the glass covered on each side. The area of the reduction is twice the distance from the cover to the sample piece. Those who need opaque cardboard or other thin materials such as aluminum foil; need to be used to avoid compaction when stacking the wads ◊ also need to be used to evaluate the gray gradation of color changes (Grey scale.) Depending on whether the BSI method 1 or 2 is used, the test specimens prepared are not less than 1 cm X 6 cm or 1 cm x 1 cm, and the blue sample is similar to the proportional exposure: The sample Η is exposed to sunlight for 24 hours every day. In the method 2 used in the printing of this by the Beigong Consumer Cooperative of the Central Kneading Bureau of the Chaoji Ministry, the sample Η is arranged into a strip of adjacent standards, and two Each sample Η in the interval of one-fifth is impervious at the same time The material is covered. When the change of the coverage in standard 3 or L2 is noticed when the gray # rating card is equal to 4-5, the evaluation of the sample piece and the light fastness are checked and compared with the standard 1 to 3 or L2. Cover and put back, and magneto-optically broken, -30-This paper scale is suitable for China's home rubbing rate (CNS> Α4 specification (210X297 mm) 323308 A7 B7_ V. Invention description (θ) (please read the back side first Note $ item and then fill in this page) until the change in standard 4 or L3 is noticed, at this time an additional coverage overlap is placed on one of the first cover and some of the sample pieces until it is noticed The change from standard 6 to L5 is equal to the gray rating card 4-5, which is before the final overlay is overlaid on the second overlay. After four coverages, follow the mine exposure until the contrast at standard 7 or L7 is equal to that shown on the gray powder card 4; or provide the contrast in the most resistant sample piece equal to the gray sub-card level 3: whichever occurs first As a basis. The final evaluation on the numerical evaluation is based on the contrast of the sample H between the exposed and unexposed portions being equal to the gray scale cards 4 and / or 3. Remove all the cover to expose the three areas of the test piece that have been exposed to the standard and different times, and at least one unexposed area. Compare the change of the standard at 6001 X or more at 45 ° to the sample; the light fastness is the change in color that meets the standard. The change in color may be color, depth, brightness, or any combination of these. The blue wool standard used in this embodiment can be broadcasted by the British Standards Agency (10 Blackfriars Street, Manchester M3 5 DT, UK). Printed by the Beige Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs; Beuth-Vertrieb, Burggrafenstr. 4-7 .D-1000 Berlin 3 0 Germany and Japanese Standard Association, 1-24 .Akasaka 4, Minatoku Tokyo Japan.L Blue wool is available from the American Association of. Textile Chai ^ sts and, P. Ο · Box 12215 , Research Triangle Park, North Carolina 2 7 7 0 9, USA0 BS1 006; TSn B02 Π 978) • ···.-This method is intended to evaluate artificial light using the sassafras applied above • -31- This paper The standard applies to China ’s sleepy family standards (CNS & A4 specifications (210X297 gong)) Α7 Β7 323308 V. Description of invention (w) ’Light fastness. The equipment used includes a fully ventilated exposure box and a temperature of 5500 The xenon arc lamp from K to 6500K has a filter between the light source and the sample piece to reduce the ultraviolet light spectrum. The glass used should have a temperature between 3 800 nm and 7 50 nm The penetration rate between is at least 9 0 %, And reduced to 0% between 3 10 nm and 3 20 nm ^ Infrared radiation also needs to be filtered with a black panel up to 45 * C. The change in light intensity of Ϊ on the exposed surface should be No more than ± 10% of the average amount. When several exposures are made side by side on the same sample piece, the area of the textile suspects used by Tong is not less than 1 cm X 4.5 cm. Method 2 is used in this example : The test piece is arranged with the standard for ISO B01 test, but only has a coverage, which is extended to one quarter of each test piece and the standard. When the change in the standard 3 is just detected When the stool is up (equal to the gray grading card 4-5), check the sample Η and grade it by comparing with the standard 1 to 3. Put back the cover until the standard 4 is just equal to the gray grading card 4-5, This pseudo-overlay is fixed in an overlapping manner on all samples H and part of the standard J: from time to time exposure until the change in sample 6 is found to meet the 5 on the gray grading card. Three coverage is when the second and some uncovered samples H overlap with the standard. The exposure until the contrast produced on standard 7 is equal to the contrast as exemplified in 4 on the gray grading card, or the sample H that is most resistant to i has been able to produce a contrast equal to the gray grading card 3, which occurs first Based. The final evaluation is based on the fact that the contrast ratio between the exposed and unexposed parts of the test piece is equal to the gray scale cards 4 and / or 3. Remove all overlays, and the light fastness is the number of standards that show similar changes in color. '. -32- This paper scale uses Chinese National Standard (CNS) A4 specification (210Χ297mm) __: __: ____ Λ1 -______ 丁 Γ 丨 ^, --------- 一 ---- -、 Ρ ------ ^ Lr 1 (Please read the note on the back " item first and then fill out this page) The Central Standards Bureau of the Ministry of Economic Affairs, Negative Consumer Cooperation Du Printing S233Q8 A7 B7 V. Description of Invention (Μ) RST OOB: TSfl 006 (198 1) The standard of the construction machine is Guoying ΌΠ, but it is a detailed test of this washing pulp. It is based on its relationship with washing and drying and drying on the ground. (# 设 ί 所Slippery ginseng, twisted by silk, twisted by color, changed by color, color, and color. 0 Under the impact of the feed strip, it is used as a wear and tear. The miscellaneous complexes are connected and connected to the transfer to the color transfer to evaluate the color; the stains of the color sample and the sample evaluation sample will be stained, and the card is not stuck. The original color of the cotton grade is like the color gray. (Please read the note ^ 'on the back before filling this page) f
*1T κ 經濟部中央搮準局員工消費合作社印裝 本紙張尺度適用中國圃家標準(CNS ) Α4規格(210X297公釐)* 1T κ Printed by the Employee Consumer Cooperative of the Central Department of Economics of the Ministry of Economic Affairs. The paper size applies to the Chinese Nursery Standard (CNS) Α4 specification (210X297 mm)
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GB9415302A GB9415302D0 (en) | 1994-07-29 | 1994-07-29 | Novel dyed materials |
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TW323308B true TW323308B (en) | 1997-12-21 |
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TW84107827A TW323308B (en) | 1994-07-29 | 1995-07-28 |
Country Status (2)
Country | Link |
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GB (1) | GB9415302D0 (en) |
TW (1) | TW323308B (en) |
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1994
- 1994-07-29 GB GB9415302A patent/GB9415302D0/en active Pending
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1995
- 1995-07-28 TW TW84107827A patent/TW323308B/zh active
Also Published As
Publication number | Publication date |
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GB9415302D0 (en) | 1994-09-21 |
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