TW323232B - - Google Patents

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Publication number
TW323232B
TW323232B TW084103103A TW84103103A TW323232B TW 323232 B TW323232 B TW 323232B TW 084103103 A TW084103103 A TW 084103103A TW 84103103 A TW84103103 A TW 84103103A TW 323232 B TW323232 B TW 323232B
Authority
TW
Taiwan
Prior art keywords
weight
parts
center
golf ball
wire
Prior art date
Application number
TW084103103A
Other languages
Chinese (zh)
Original Assignee
Sumitomo Rubber Ind
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Sumitomo Rubber Ind filed Critical Sumitomo Rubber Ind
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Publication of TW323232B publication Critical patent/TW323232B/zh

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Classifications

    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003Golf balls
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003Golf balls
    • A63B37/0038Intermediate layers, e.g. inner cover, outer core, mantle
    • A63B37/0039Intermediate layers, e.g. inner cover, outer core, mantle characterised by the material
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003Golf balls
    • A63B37/0004Surface depressions or protrusions
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003Golf balls
    • A63B37/005Cores
    • A63B37/0051Materials other than polybutadienes; Constructional details
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003Golf balls
    • A63B37/005Cores
    • A63B37/0051Materials other than polybutadienes; Constructional details
    • A63B37/0053Thread wound
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003Golf balls
    • A63B37/005Cores
    • A63B37/006Physical properties
    • A63B37/0064Diameter
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003Golf balls
    • A63B37/005Cores
    • A63B37/006Physical properties
    • A63B37/0065Deflection or compression
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003Golf balls
    • A63B37/007Characteristics of the ball as a whole
    • A63B37/0072Characteristics of the ball as a whole with a specified number of layers
    • A63B37/0075Three piece balls, i.e. cover, intermediate layer and core
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003Golf balls
    • A63B37/007Characteristics of the ball as a whole
    • A63B37/0077Physical properties
    • A63B37/0094Rebound resilience

Description

A7 B7 五、發明説明(3 ) 經濟部中央標準局員工消費合作社印製 發明節釀 本 發 明 係 關 於 一 種 線 繞 式 高 爾 夫 球 0 更 特 別 地 0 疋 關 於 保 持 線 繞 式 高 爾 夫 球 中 存 在 之 固 有 地 良 好 擊 球 感 且 達 到 長 的 飛 行 距 離 之 線 繞 式 高 爾 夫 球 0 發 明 背 景 線 繞 式 咼 爾 夫 球 係 經 由 將 線 狀 橡 膠 捲 繞 在 固 jam m 或 液 體 之 橡 膠 中 心 形 成 線 狀 橡 膠 層 t 且 Μ 被 覆 物 質 (例如, 離 子 鍵 聚 合 物 , 巴 拉 塔 樹 脂 等 等 )被覆於線狀橡膠層上而製 得 0 線 繞 式 高 爾 夫 球 在 擊 球 感 及 控 制 性 質 上 係 優 於 使 用 固 體 心 之 兩 片 式 高 爾 夫 球 0 妖 而 J 與 兩 片 式 高 爾 夫 球 比 較 1 因 為 旋 轉 量 大 > 且 飛 射 角 度 小 而 無 法 達 到 長 的 飛 行 距 離 0 因 此 與 線 繞 式 高 爾 夫 球 比 較 J —. 般 之 業 餘 m 爾 夫 球 均 較 喜 好 可 達 到 長 的 飛 行 距 離 之 兩 片 式 局 爾 夫 球 且 兩 Η 式 高 爾 夫 球 近 來 獨 佔 於 市 場 上 Q 發 明 且 的 本 發 明 係 為 了 解 決 傳 統 之 線 繞 式 高 爾 夫 球 僅 可 達 到 相 對 短 的 飛 行 距 離 之 問 題 且 本 發 明 之 主 要 的 係 提 供 一 種 保 有 線 繞 式 高 爾 夫 球 固 有 的 良 好 擊 球 感 j 且 可 達 到 相 等 於 兩 片 式 高 爾 夫 球 可 達 到 之 長 的 飛 行 距 離 之 線 繞 式 高 爾 夫 球 此 巨 的 及 本 發 明 之 其 他 巨 的 及 優 點 由 下 列 之 敘 述 及 參 昭 附 圖 5 對 於 熟 習 本 技 術 者 將 變 得 顯 而 易 見 的 0 圖 式 簡 要 説 明 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4規格(210X:m公釐) A7 B7 五、發明説明(4 ) 圖1係說明本發明之線繞式高爾夫球一具體例之剖面 圖 <·-, 發明概要 依據本發明,上述之目的已藉由增加線嬈式高爾夫球 之中心直徑,且使中心變更,Μ控制欲形成之旋轉量,及 增加飛射角度Μ增加飛行距離而達成。 亦即,本發明提供一種包括由橡膠組成物之硫化模製 物件組成之中心,在該中心上形成之線狀橡膠層,且在該 線狀橡膠層上被覆被覆材之線繞式高爾夫球,其中該中心 之直徑為30至35min,且初負荷為10kg及終負荷為30kg間之 應變量為].2至2.5mm。 發明^詳細紗沭 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 此中心可經由,例如,調配5至8 0 (較好1 5至5 0 )重量 份之熱塑性樹脂當作填充料用於調整硬度,2至1 2 (較好 8至1 0 )重量份之硫,1至4 (較好1至2 )重量份之硫化加 速劑及10至150(較好50至120)重量份之重量調整劑,及若 需要,3至1 0 (較好5至9 )重量份之硫化肋劑(K上均K ]0 0重量份之橡膠為準),Μ得到橡膠組成物,且使此橡膠 組成物進行硫化模製而得。 本發明中,經由調整中心之直徑為30至35mm,及初負 荷(1 0 k g )及終貪荷(3 0 k g )間形成之應變量為1 . 2至2 . 5 m m , 而達到線繞式高爾夫球之大飛行距離,同時維持良好之擊 球感之原因目前並不清楚,但認為係如下: 其係認為經由調整中心之直徑為30至35mm,且初負荷 本紙張尺度適用中國國家橾準(CNS ) A4規格(210 X 2Θ7公釐) 4 A7 B7 經濟部中央標準局員工消費合作社印製 五、 發明説明( 5 ) ·- 1 1 (1 0 k g )及終貪荷 (3 0 k g〉間 形 成 之 應 變 量 為 1 . 2至 2 · 5 m m 1 則 1 1 擊 球 時 高 爾 夫 球 之 變 形 形 態 iti. 變 得 類 似 於 兩 片 式 高爾 夫 球 > 1 I 且 結 果 t 可 控 制 擊 球 時 形 成 之 旋 轉 量 且 飛 射 角變 大 y 因 'S 請 1 此 增 加 飛 行 距 離 0 先 閲 讀 1 1 再 者 線 繞 式 局 爾 夫 球 可 保 持 線 繞 式 局 爾 夫球 中 保 有 背 面 之 1 1 之 固 有 特 性 之 良 好 擊 球 感 而 與 上 述 之 飛 行 距 離 之改 善 無 關 意 拳 1 1 之 理 由 認 為 係 線 狀 橡 膠 層 之 張 力 與 傳 統 之 線 繞 式高 爾 夫 球 再 填 1 4 比 較 係 較 小 之 故 0 寫 本 頁 I 當 中 心 之 直 徑 小 於 3 0 si ία 時 Ϊ 線 狀 橡 膠 層 變 厚, 結 果 飛 [ I 射 角 度 變 小 且 旋 轉 量 變 大 0 換 之 » 田 中 心 之 直徑 大 於 1 1 I 3 5 m m 時 線 狀 橡 膠 層 變 薄 t 且 在 張 力 形 成 前 已 捲繞 線 狀 橡 1 1 訂 1 膠 ) 因 無 法 得 到 高 爾 夫 球 之 適 當 硬 度 0 再 者 當 中 心 之 應 變 量 在 上 逑 條 件 下 大 於 2.5m ΠΙ時, 1 1 線 狀 橡 膠 必 需 緊 密 地 捲 繞 1 K 得 到 適 當 之 球 硬 度 結 果 t 1 I 線 狀 橡 膠 層 之 張 力 變 大 且 擊 球 時 之 變 形 無 法 輕易 地 產 生 1 ; 因 此 •frrr 雛 法 得 到 所 需 之 技 術 性 效 果 0 換 言 之 I 當中 心 之 旋 1 轉 量 在 上 述 條 件 下 小 於 1 . 2 1 ffi時, 擊球感變得不良 5 1 1 再 者 J 較 好 當 使 茼 爾 夫 球 白 2 5 4 c m之高度掉在水泥板 1 1 上 時 中 心 之 回 3d» 局 度 為 120 c ffl或更高, 特別是1 4 0至 1 I 2 4 0 c m ( -亦即, 中心具有大的回彈高度之事實顯示中心之 1 I 撞 擊 回 彈 力 大 J 且 當 中 心 具 有 大 的 撞 擊 回 彈 力 時, 擊 球 時 1 1 球 的 初 速 變 大 因 此 可 得 到 良 好 的 飛 行 效 能 0 換g 之 > 當 1 1 中 心 之 回 彈 .. C3 问 度 小 於 上 述 之 现 圍 時 » 球 的 初 速 度變 小 且 1 1 因 此 y 無 法 輕 易 的 得 到 長 的 飛 行 距 離 1 1 本紙張尺度適用中國國家標準(CNS ) A4規格(210Χ297公釐) A7 B7 五、發明説明(6 ) 如上所述,當中心係由經由調配5至8 0 (較好1 5至5 0 ) 重量份之熱塑性樹脂當作镇充劑用K調整硬度,2至12( 較好8至1 0 )重量份之硫,1至4 (較好1至2 )重量份之硫 化加速劑,及10至]50(較好50至120)重量份之重量調整劑 ,及若需要,3至1 0 (較好5至9 )重量份之硫化肋劑(K 1 0 0重量份之橡膠為準)所得之橡膠組成物之硫化模製物件 所構成。硫化通常化在壓力下,於1 4 0至1 7 0 υ (較好1 5 0至 1 6 0 )下加熱5至3 0分鐘(較好1 0至2 0分鐘)下進行。 用作中心之橡膠並未特別限制,且具有高回彈性能之 聚丁二烯(特別是高的順式聚丁二烯)係較佳者。較好使用 高的順式聚丁二烯或含有高的順式聚丁二烯之橡膠於用作 中心之橡膠組成物之製備。 熱塑性樹脂並未特別限制,且較好使用高分子量聚烯 烴,如高苯乙烯樹脂,高分子量聚乙烯,高分子量聚丙烯 ,等等,或其混合物。 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 上述用作中心之橡膠組成物與一般用作中心之橡膠組 成物不同處在於調配當作填充料用於調整硬度之熱塑性樹 脂。 熱塑性樹脂係用於調整中心之硬度,且其量為上述之 Κ100重量份之橡膠為準為5至80重量份,較好為15至50 重量份。當熱塑性樹脂之量少於上述之範圍時,中心之硬 度無法充份的增加。因此,硬度變成與一般的中心相同, 因而無法提供所需之效果。另一方面,當熱塑性樹脂之量 大於上述之範圍時,硬度變得太高,且因此,擊球感變得 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) 6 A7 32S232 — B7 五、發明説明(7 ) 不良,且橡膠捏合時之加工性亦變得不良。 (請先閱讀背面之注意事項再填寫本頁) 如上所述,硫之量Μ〗0 0重量份之橡膠為準為2至1 2 重量份,較好為8至1 0重量份。當硫之量小於上述之範圍 時,硫化程度變低,且因此,無法輕易地得到中心所需之 硬度。另一方面,當硫之量大於上述之範圍時,中心之硬 度變得太高,且因此,無法得到所需之效果。 硫化肋劑之實例包含金屬氧化物(例如氧化鋅,氧化 鎂,等等)及高级脂肪酸(例如,硬脂酸,棕櫊酸,油酸, 月桂酸,等等)。此硫化肋劑較好係用於使硫化順利的進 行,但並非必要。 硫化加速劑可為可用作一般硫硫化之硫化加速劑之任 一種,其典型實例包含趣唑硫化加速劑,如2 -氫硫基苯並 噬唑,二苯並1« _基二硫化物,等等;二S荒胺醯硫化加 速劑,如四甲基二烴荒胺醯單硫化物,四甲基二烴荒胺醯 二硫化物,等等;亞磺醯胺硫化加速劑,如Ν -環己基-2 -苯並β唑基亞磺酿胺,等等,但並不限於上述者。 經濟部中央標準局員工消費合作社印製 硫化肋劑與硫化加速劑可依照欲調配之硫之量調配。 硫化助劑之量Μ 1 0 0重量份之橡膠為準,較好為3至】0重 量份,特別是5至9重量份,硫化加速劑之量Μ 1 0 0重量 份之橡膠為準,較好為1至4重量份,特別是〗至2重量 份:·當其量小於上述之範圍時,硫之硫化無法充份的進行 。另一方面,當其量大於上述之範圍時,中心之硬度變得 太高,導致擊球感不良。 重量調整劑之實例包含硫酸鋇、黏土、碳酸鈣、氧化 7 本紙張尺度適用中國國家標準·( CNS ) Α4規格(210X297公釐) A7 B7 五、發明説明(8 ) 矽填充劑等等,且其量如上所述,以1 0 0重量份之橡膠為 準,較好為]0至1 5 0重量份,特別是5 0至1 2 0重量份。 當重量調整劑之量小於上述之範圍時,中心之重量變 小,且無法得到高爾夫球之適當重量。另一方面,當重量 調整劑之量大於上述之範圍時,中心之重量變大,且因此 ,球重量超過標準值。 對於用作中心之橡膠組成物,除了上述之成份外,可 添加抗氧化劑等等。 本發明高爾夫球之構造將參照附圖說明。圔1係說明 本發明之線繞式高爾夫球之一具體例之剖面圖。圖】中, 1為中心,2為線狀橡膠層,且3螽被覆材。 中心1係由橡膠組成物之硫化模製物件組成,且中心 之直徑為3 0至3 5 m πι。再者,初貪荷(1 0 k g )及終負荷〇 0 k g ) 之間形成之中心之應變量係在1 . 2至2 . 5 m πι之範圍中。 線狀橡膠層2係藉由使線狀橡膠捲繞中心丨,且所謂 的線繞S係由中心〗及線狀橡膠層2組織組成c 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 至於用於形成線狀橡膠層2之線狀橡膠,可使用迄今 為止已使用之線狀橡膠。例如,可使用經由使橡膠組成物 (其中硫,碕化肋劑,硫化加速劑,抗氧化劑,等等調配 於天然橡膠,或天然橡膠及合成聚異戊間二烯中)硫化而 製得者- 線狀橡膠層2係Μ被覆材3被覆,且3 a係該置於被覆 材3上之凹洞,且若需要,依照所需之特性可設置適當數 量之凹洞3 a。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) A7 B7 經濟部中央標準局員工消費合作社印製 五、 發明説明( 9 ) 至 於 被 覆 材 3 , 可使用含有離子鍵聚合物當作主要物 質 之 離 子 鍵 聚 合 物 被 覆 材 及 巴 拉 塔 樹 脂 被 覆 材 二 者 > 但 由 飛 行 距 離 之 m 點 來 看 離 子 鍵 聚 合 物 係 較 佳 者 0 Μ 被 覆 材 被 覆 芯 之 方 法 Μ 未 特 別 限 制 j 且 歡 覆 係 Μ 一 般 之 方 法 進 行 0 例 如 » 可 使 用 包 括 預 先 模 製 兩 片 具 有 半 球 形 形 狀 之 半 殼 > 使 用 該 半 段 被 覆 芯 且 在 1 3 0 至 1 70 V, 下 進 行 壓 力 模 製 1 至 15分 鐘 之 方 法 1 或 包 括 使 用 作 被 覆 材 之 組 成 物 直 接 射 擊 模 製 於 芯 上 } Μ 被 覆 此 心 之 方 法 〇 被 覆 材 之 厚 度 一 般 約 為 1 至 4 m ΠΪ 1 =然而, 凹洞可在被覆材模製之時, 任 -tr. 思 地 在 高 爾 夫 球 之 表 面 上 形 成 0 再 者 j 被 覆 材 模 製 後 可 任 意 地 提 供 漆 料 修 飾 > 作 標 記 等 等 C 依 據 本 發 明 t 經 由 增 加 中 心 之 直 徑 1 且 使 中 心 變 得 比 傳 統 之 線 繞 式 高 爾 夫 球 硬 1 可 提 供 逹 到 長 的 飛 行 距 離 1 同 時 維 持 如 線 繞 式 高 爾 夫 球 之 特 性 般 之 良 好 擊 球 感 之 線 繞 式 高 爾 夫 球 0 宵 例 下 列 之 實 例 與 比 較 例 更 詳 細 的 說 明 本 發 明 J 但 並 非 用 於 限 制 其 範 圍 0 實 例 1 至 5 及 比 較 例 1 至 7 用 作 中 心 之 橡 膠 組 成 物 具 有 表 及 2 中 所 示 之 配 方 > 且 所 得 之 橡 嘐 組 成 物 注 入 用 於 中 心 之 模 具 中 且 在 1 c 5 °C 下 分 別 進 行 壓 著 模 製 /硫化20分鐘, 得到中心 所 得 中 心 之 直 徑 » J I S - Α硬度 Η J I S - Α硬度測試機測 量 ), 應變量, 回彈高度, 及重量均示於表] 及2 中 二> 本紙張尺度適用中國國家搮準(CNS ) A4規格(210X297公釐) 請A7 B7 Fifth, the invention description (3) The Ministry of Economic Affairs, Central Standards Bureau, Employee Consumer Cooperative printed invention invention brewing This invention is about a wire-wound golf ball 0 More specifically 0 疋 About maintaining the inherent nature of the wire-wound golf ball Wire-wound golf ball with good hitting feeling and long flying distance 0 BACKGROUND OF THE INVENTION A wire-wound ball is formed by winding a linear rubber around a solid jamm or a liquid rubber center to form a linear rubber layer t and Μ Coated substances (for example, ionomers, Balata resins, etc.) are coated on the linear rubber layer to produce a 0-wound golf ball that is superior to the solid core in terms of impact and control properties One-piece golf ball 0 monster and J compared with two-piece golf ball 1 Because of the large amount of rotation & small flying angle, it is impossible to achieve a long flying distance 0 Therefore Compared with wire-wound golf ball J. General amateur m golf balls are more like two-piece round golf balls that can achieve a long flying distance and two Η golf balls have recently been exclusively on the market. The invention is to solve the problem that the traditional wire-wound golf ball can only achieve a relatively short flying distance and the main purpose of the present invention is to provide a wire-wound golf ball with a good hitting j and equal to two pieces. The long flight distance of the golf ball can be achieved. The huge and other advantages and advantages of the wire-wound golf ball of the present invention are described in the following and refer to FIG. 5. FIG. 0 will become apparent to those skilled in the art Brief description of the formula (please read the precautions on the back before filling this page) This paper size is applicable to the Chinese National Standard (CNS) A4 Grid (210X: mmm) A7 B7 V. Description of the invention (4) Figure 1 is a cross-sectional view illustrating a specific example of the wire-wound golf ball of the present invention < ·-, Summary of the invention According to the present invention, the above purpose has been By increasing the center diameter of the linear golf ball and changing the center, M controls the amount of rotation to be formed, and increases the flying angle M to increase the flying distance. That is, the present invention provides a wire-wound golf ball including a center composed of a vulcanized molded article of a rubber composition, a linear rubber layer formed on the center, and a coating material coated on the linear rubber layer, The diameter of the center is 30 to 35min, and the initial load is 10kg and the final load is 30kg. Invention ^ Detailed Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) This center can be used, for example, to allocate 5 to 8 0 (preferably 15 to 50) weight Parts of thermoplastic resin are used as fillers to adjust the hardness, 2 to 1 2 (preferably 8 to 10) parts by weight of sulfur, 1 to 4 (preferably 1 to 2) parts by weight of vulcanization accelerator and 10 to 150 (Preferably 50 to 120) parts by weight of the weight modifier, and if necessary, 3 to 10 (preferably 5 to 9) parts by weight of the vulcanized rib agent (K on K) 0 0 parts by weight of the rubber shall prevail , M to obtain a rubber composition, and this rubber composition is obtained by vulcanization molding. In the present invention, the diameter of the center is adjusted to 30 to 35mm, and the strain formed between the initial load (10 kg) and the final greedy load (30 kg) is 1.2 to 2.5 mm, and the wire winding is achieved The reason for the large flying distance of the golf ball while maintaining a good sense of hitting is not clear, but it is considered as follows: It is believed that the diameter of the center through the adjustment is 30 to 35mm, and the initial load of this paper size is suitable for the Chinese national skid Standard (CNS) A4 specifications (210 X 2Θ7 mm) 4 A7 B7 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of invention (5) ·-1 1 (1 0 kg) and final charge (3 0 kg 〉 The dependent variable formed is 1.2 to 2.5 mm 1 and then 1 1 the shape of the golf ball deformed when hitting iti. It becomes similar to a two-piece golf ball> 1 I and the result t can control when hitting the ball The amount of rotation formed and the flying angle become larger y because of 'S please 1 increase the flying distance 0 first read 1 1 and then the wire-wound round golf ball can maintain the wire-wound round golf ball mediator The good hitting feeling with the inherent characteristics of 1 1 on the back side has nothing to do with the improvement of the above-mentioned flight distance. The reason for Yi Quan 1 1 is that the tension of the linear rubber layer is compared with that of the traditional wire wound golf ball. 1 4 Smaller reason 0 Write this page I When the diameter of the center is less than 3 0 si ία, the linear rubber layer becomes thicker, and as a result fly [I The angle of incidence becomes smaller and the amount of rotation becomes larger 0 In exchange »The diameter of the center of the field is greater than 1 1 I 3 At 5 mm, the linear rubber layer becomes thinner and the linear rubber has been wound before the tension is formed. 1 1 Order 1 glue) Because the appropriate hardness of the golf ball cannot be obtained 0 Furthermore, when the center strain is under the upper condition When it is greater than 2.5m ΠΙ, 1 1 linear rubber must be tightly wound by 1 K to obtain an appropriate ball hardness result t 1 I The tension of the linear rubber layer becomes larger and the deformation when hitting the ball cannot easily produce 1; therefore • frrr Young The method obtains the desired technical effect. 0 In other words I. When the rotation of the center 1 is less than 1.2 1 ffi under the above conditions, the hitting feeling becomes poor 5 1 1 and J is better. When the height of white 2 5 4 cm falls on the cement board 1 1, the center returns to 3d »The locality is 120 c ffl or higher, especially 1 4 0 to 1 I 2 4 0 cm (-that is, the center has a large The fact that the rebound height of the center shows that the center 1 I has a large impact resilience J and when the center has a large impact resilience, the initial velocity of the 1 1 ball becomes larger when hitting the ball, so you can get good flight performance. 0 for g> When the rebound of the center of 1 1 .. C3 is less than the above-mentioned current circumference »The initial velocity of the ball becomes smaller and 1 1 so y can not easily get a long flight distance 1 1 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210Χ297mm) A7 B7 V. Description of invention (6) As mentioned above, when the center is adjusted by 5 to 8 0 (preferably 15 to 50) Parts of thermoplastic resin are used as stabilizers to adjust the hardness with K, 2 to 12 (preferably 8 to 10) parts by weight of sulfur, 1 to 4 (preferably 1 to 2) parts by weight of vulcanization accelerator, and 10 to ] 50 (preferably 50 to 120) parts by weight of the weight modifier, and if necessary, 3 to 10 (preferably 5 to 9) parts by weight of the vulcanized rib agent (K 1 0 0 parts by weight of the rubber) The rubber composition is composed of vulcanized molded articles. The vulcanization is usually carried out under pressure, under heating at 140 to 170 ° (preferably 150 to 160) for 5 to 30 minutes (preferably 10 to 20 minutes). The rubber used as the center is not particularly limited, and polybutadiene (especially high cis-polybutadiene) with high resilience performance is preferred. It is preferable to use high cis polybutadiene or a rubber containing high cis polybutadiene in the preparation of the rubber composition used as the center. The thermoplastic resin is not particularly limited, and high molecular weight polyolefins such as high styrene resin, high molecular weight polyethylene, high molecular weight polypropylene, etc., or mixtures thereof are preferably used. Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling in this page) Thermoplastic resin to adjust hardness. The thermoplastic resin is used to adjust the hardness of the center, and the amount of the rubber is 5 to 80 parts by weight, preferably 15 to 50 parts by weight, based on the above-mentioned K100 parts by weight of rubber. When the amount of the thermoplastic resin is less than the above range, the hardness of the center cannot be increased sufficiently. Therefore, the hardness becomes the same as that of a general center, and thus cannot provide the desired effect. On the other hand, when the amount of the thermoplastic resin is greater than the above range, the hardness becomes too high, and therefore, the hitting feeling becomes the paper standard applicable to the Chinese National Standard (CNS) Α4 specification (210X297 mm) 6 A7 32S232 — B7 5. Description of the invention (7) Defective, and the processability during rubber kneading also becomes poor. (Please read the precautions on the back before filling in this page) As mentioned above, the amount of sulfur M 0 0 parts by weight of rubber shall be 2 to 12 parts by weight, preferably 8 to 10 parts by weight. When the amount of sulfur is smaller than the above range, the degree of vulcanization becomes low, and therefore, the hardness required for the center cannot be easily obtained. On the other hand, when the amount of sulfur is larger than the above range, the hardness of the center becomes too high, and therefore, the desired effect cannot be obtained. Examples of vulcanizing rib agents include metal oxides (e.g. zinc oxide, magnesium oxide, etc.) and higher fatty acids (e.g. stearic acid, palmitic acid, oleic acid, lauric acid, etc.). This vulcanization rib agent is preferably used for smooth vulcanization, but it is not necessary. The vulcanization accelerator can be any of the vulcanization accelerators that can be used for general sulfur vulcanization, and typical examples thereof include thiazole vulcanization accelerators, such as 2-hydrothiophenyl benzophazole, dibenzo 1 «_yl disulfide , Etc .; bis sulfonamide vulcanization accelerators, such as tetramethyl dihydrocarbon sulfonamide monosulfide, tetramethyl dihydrocarbon sulfonamide disulfide, etc .; sulfenamide sulfide accelerators, such Ν-cyclohexyl-2-benzoxazolylsulfenamide, etc., but not limited to the above. Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy. The curing rib agent and curing accelerator can be formulated according to the amount of sulfur to be formulated. The amount of vulcanization aid Μ 1 0 0 parts by weight of rubber shall prevail, preferably 3 to】 0 parts by weight, especially 5 to 9 parts by weight, the amount of vulcanization accelerator Μ 1 0 0 parts by weight of rubber, It is preferably from 1 to 4 parts by weight, especially from 2 to 2 parts by weight: When the amount is less than the above range, sulfur vulcanization cannot proceed sufficiently. On the other hand, when the amount is larger than the above range, the hardness of the center becomes too high, resulting in a poor hitting feeling. Examples of weight adjusters include barium sulfate, clay, calcium carbonate, and oxide. 7 The paper size is applicable to the Chinese National Standard (CNS) Α4 specification (210X297 mm) A7 B7 5. Invention description (8) Silicon filler, etc., and The amount is as described above, based on 100 parts by weight of rubber, preferably 0 to 150 parts by weight, particularly 50 to 120 parts by weight. When the amount of the weight adjusting agent is smaller than the above range, the weight of the center becomes small, and an appropriate weight of the golf ball cannot be obtained. On the other hand, when the amount of the weight adjusting agent is larger than the above range, the weight of the center becomes large, and therefore, the weight of the ball exceeds the standard value. For the rubber composition used as the center, antioxidants and the like can be added in addition to the above-mentioned components. The structure of the golf ball of the present invention will be described with reference to the drawings. Fig. 1 is a cross-sectional view illustrating a specific example of the wire-wound golf ball of the present invention. In the figure], 1 is the center, 2 is the linear rubber layer, and 3 is the covering material. The center 1 is composed of a vulcanized molded article of a rubber composition, and the diameter of the center is 30 to 35 m πι. Furthermore, the strain of the center formed between the initial greedy load (10 k g) and the final load 〇 0 k g) is in the range of 1.2 to 2.5 m πι. The linear rubber layer 2 is made by winding the linear rubber center, and the so-called wire winding S system is composed of the center and the linear rubber layer 2c. Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy Note on the back and then fill out this page) As for the linear rubber used to form the linear rubber layer 2, the linear rubber that has been used so far can be used. For example, those obtained by vulcanizing a rubber composition (in which sulfur, ribbed rib agent, vulcanization accelerator, antioxidant, etc. are formulated in natural rubber, or natural rubber and synthetic polyisoprene) can be used -The linear rubber layer 2 is covered by the cladding material 3, and 3a is a cavity placed on the cladding material 3, and if necessary, an appropriate number of cavities 3a can be provided according to the required characteristics. This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm) A7 B7 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Invention description (9) As for the coating material 3, polymers containing ionomers can be used As the main material, both the ionomer polymer coating material and the Balata resin coating material > but from the point of flight distance m, the ionomer polymer is preferred. 0 Μ The method of coating the core of the coating material Μ is not particularly limited j And the coating is carried out by the general method 0 For example »Can be used including pre-moulding two half-shells with a hemispherical shape> Using this half-section coated core and carrying out a pressure die at 1 3 0 to 1 70 V, Method 1 for 1 to 15 minutes or include direct shot molding of the composition used as a coating material on the core} Μ Method for coating this core 〇The thickness of the coating material is generally about 1 to 4 m ΠΪ 1 = However, the cavity Can be molded on the coating material At the time, Ren-tr. Thought to form 0 on the surface of the golf ball. Furthermore, after the molding, the coating material can be optionally provided with paint modification> for marking, etc. C. According to the present invention, the diameter of the center is increased by 1 and Makes the center harder than traditional wire-wound golf balls1 Provides a long flying distance1 While maintaining a good shot like the characteristics of a wire-wound golf ball Examples and Comparative Examples illustrate the present invention in more detail but are not intended to limit its scope. 0 Examples 1 to 5 and Comparative Examples 1 to 7 The rubber composition used as the center has the formulation shown in Table 2 and the obtained The rubber composition is injected into the mold used for the center and compression molded / vulcanized at 1 c 5 ° C for 20 minutes to obtain the center The diameter of the obtained center »JIS-Α hardness Η JIS-Α hardness testing machine measurement), the amount of strain, rebound height, and weight are shown in the table] and 2 in the two > This paper scale is applicable to the Chinese National Standard (CNS) A4 size (210X297mm) please

A 閱 讀 背 之 注 意 事 項 再 填 寫 本 頁 訂 2 S 2 3 3A Read the notes on the back and fill in this page. Order 2 S 2 3 3

AA

7 B 五、發明説明( 表1及2中顯示之欲調配之各別配方量之量係以重量 份表示。所得中心之直徑,J I S - A硬度(M J I S - A硬度測試 機測童),應變量,回彈高度及重量係列於表1中,除了 實例1至5之組成物以外。比較例1至7之上項性質列於 表2中。 再者,應變量及回彈高度之測量方法如下。配方成份 之說明將敘述於表2之後。 應礬畺 測量初負荷(1 〇 k g )及終貪荷(3 0 k g )間形成之應變量。 冋强高度 中心之回彈高度係測量自2 5 4 c m之高度掉至水泥板上 時回彈之高度。 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 _1 貝 施 编 號 1 2 3 4 5 RB-11 *1 100 100 100 100 100 Nippol 2007J *2 30 30 30 40 0 Miperc.n XM-220 *3 0 0 0 0 30 硫 10 10 10 10 10 硫化助劑 14 7 7 7 7 7 硫化加速劑 *5 1.5 1.5 1. 5 1.5 1.5 重量調整劑 本6 90 80 70 75 90 中心 直徑(M) 30.0 31.3 32. 4 32.3 31.2 JIS-A硬度 86 87 87 90 86 應變量() 1.95 1.98 2. 00 1.78 1.90 回彈高度(C1D) 200 198 196 190 210 重量(g) 20.4 22. 1 23 2 23.2 22.1 本紙張尺度逋用中國國家梯準(CNS ) A4规格(210X297公釐) 10 經濟部中央標準局員工消费合作社印製 A7 B7 五、發明説明(u ) 表2 比 較 例 编 :kVPI 號 1 2 3 4 5 6 7 RB-11 *1 100 100 100 100 100 100 |0 0 Nippol 2007J 本2 0 0 0 0 85 0 40 硫 10 10 10 15 10 10 1 硫化肋劑 *3 7 7 7 7 7 7 7 硫化加速劑 *4 1.5 1.5 1.5 1.5 1.5 1.5 1.5 重量調整劑 本5 83 70 65 65 90 33 77 中心 直徑(M) 28.2 30.2 31.3 31.3 32.3 35.5 32.3 JIS-A硬度 76 75 74 85 99 73 84 應變量(M) 3.17 3.20 3.25 2.65 1.18 3.35 2.20 回彈高度(《) 216 215 214 210 ISO 205 118 重量(g) 17.5 20.5 22.0 22.0 23.2 29.1 23.1 *]:商標名稱,由Nihon Gosei Gomu Co. Ltd製造之高順 式聚丁二烯(1,4 -順式聚丁二烯之量:9 6 % ) *2:商標名稱,由Nihon Zeo n Co Ltd製造之高苯乙烯樹 脂0 -Η- 本紙張尺度逋用中國國家樣準(CNS ) Α4規格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁)7 B 5. Description of the invention (The amount of each formula shown in Tables 1 and 2 is to be expressed in parts by weight. The diameter of the center obtained, JIS-A hardness (MJIS-A hardness tester tester), strain The quantity, rebound height and weight series are listed in Table 1, except for the compositions of Examples 1 to 5. The above properties of Comparative Examples 1 to 7 are listed in Table 2. In addition, the measurement methods of the dependent variable and rebound height The description of the formulation ingredients will be described after Table 2. The strain between the initial load (10 kg) and the final greedy load (30 kg) should be measured. The rebound height of the strong height center is measured from 2 5 4 cm The height of the rebound when falling to the cement board. (Please read the notes on the back before filling this page) Printed by the Employees Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs _1 Bei Shi No. 1 2 3 4 5 RB-11 * 1 100 100 100 100 100 Nippol 2007J * 2 30 30 30 40 0 Miperc.n XM-220 * 3 0 0 0 0 30 sulfur 10 10 10 10 10 Vulcanization aid 14 7 7 7 7 7 Vulcanization acceleration Agent * 5 1.5 1.5 1. 5 1.5 1.5 Weight adjuster book 6 90 80 70 75 90 Center Diameter (M) 30.0 31.3 32. 4 32.3 31.2 JIS-A hardness 86 87 87 90 86 Strain () 1.95 1.98 2. 00 1.78 1.90 Rebound height (C1D) 200 198 196 190 210 Weight (g) 20.4 22. 1 23 2 23.2 22.1 The size of this paper adopts China National Standards (CNS) A4 specification (210X297mm) 10 Printed by the Consumer Standardization Bureau of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of invention (u) Table 2 Comparative example compilation: kVPI No. 1 2 3 4 5 6 7 RB-11 * 1 100 100 100 100 100 100 | 0 0 Nippol 2007J Ben 2 0 0 0 0 85 0 40 Sulfur 10 10 10 15 10 10 1 Sulphurized Rib Agent * 3 7 7 7 7 7 7 7 Vulcanization accelerator * 4 1.5 1.5 1.5 1.5 1.5 1.5 1.5 Weight regulator 5 83 70 65 65 90 33 77 Center diameter (M) 28.2 30.2 31.3 31.3 32.3 35.5 32.3 JIS-A hardness 76 75 74 85 99 73 84 Dependent variable (M) 3.17 3.20 3.25 2.65 1.18 3.35 2.20 Rebound height (") 216 215 214 210 ISO 205 118 Weight (g) 17.5 20.5 22.0 22.0 23.2 29.1 23.1 *]: trade name, manufactured by Nihon Gosei Gomu Co. Ltd Of high cis-polybutadiene (amount of 1,4-cis-polybutadiene: 96%) * 2: trade name It is said that the high styrene resin manufactured by Nihon Zeo n Co Ltd 0 -Η- This paper uses the Chinese National Standards (CNS) Α4 specification (210X297mm) (please read the precautions on the back before filling this page)

經濟部中央樣準局貝工消费合作社印製 A7 B7 五、發明説明(】2) * 3:商標名稱,由三井石油化學工業股份有限公司(Printed by Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A7 B7 V. Description of invention (】 2) * 3: Trademark name, by Mitsui Petrochemical Industry Co., Ltd. (

Mitsui Petroleum Chemical Industries Co. Ltd) 製造之高分子量聚乙烯。 本4 : 5重量份之鋅白,G 1 N R E I R (商標名稱,由T o h o A e η C ο . L t d製造)及2重量份之硬脂酸(由Ν i h ο η Υ u s h ί C ο L t d 製造)。 *5: 0.25重量份之Noxxelar JT (商標名稱,由OhuchiHigh molecular weight polyethylene manufactured by Mitsui Petroleum Chemical Industries Co. Ltd). This 4: 5 parts by weight of zinc white, G 1 NREIR (trade name, manufactured by Toho A e η C ο. L td) and 2 parts by weight of stearic acid (by Ν ih ο η Υ ush ί C ο L td manufacturing). * 5: 0.25 parts by weight of Noxxelar JT (trade name, by Ohuchi

Shinko Kagaku Kogyo Co. Ltd製造之四甲基二烴胺 荒醯二硫化物)及1 . 2 5重量份之Ν o x x e 1 a r C Z - G (商標 名,由Ohuchi Shinko Kagaku Kogyo Co Ltd製造之 N -環己基-2-苯並噬唑基亞磺醯胺)。 *6:硫酸鋇(由 Sakai Kagaku Kogyo Co. Ltd製造)c 接著,當作基底橡膠之包括天然橡膠/低-順式合成聚 異戊間二烯(5 0 : 5 0 ,重量比)[S h e 1 1 I R - 3 0 9 (商標名稱), 由蜆殼化學股份有限公司製造]之線狀橡膠環繞値各如上 述製得之中心,Μ形成線狀橡膠層,因此製備外徑為 3 9 . 5 m m之線繞式芯。 上述之芯Μ —對由用作被覆材之組成物模製之半球形 半殼被覆,接箸使其在球之模具中,於1 5 0 °C下進行壓箸 模製3分鐘,得到線繞式高爾夫球。所得之高爾夫球Μ漆 料塗佈,Μ修飾外徑為4 . 2 7 m m之高爾夫球。被覆材之組成 物係經由使2重量份之二氧化鈦調配於H i ί i 1 a n e U 0 5 ( 商標名稱)及Hi-milalnel760(商標名稱(50:50,重量化)[ 分別為由三井杜邦高分子化學股份有限公司(M i t s u i D u 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) (請先閱讀背面之注意事項再填寫本頁)Shinko Kagaku Kogyo Co. Ltd's tetramethyldihydrocarbylamine disulfide) and 1.2 5 parts by weight of N oxxe 1 ar CZ-G (trade name, N-made by Ohuchi Shinko Kagaku Kogyo Co Ltd Cyclohexyl-2-benzophazolyl sulfenamide). * 6: Barium sulfate (manufactured by Sakai Kagaku Kogyo Co. Ltd) c Next, as the base rubber including natural rubber / low-cis synthetic polyisoprene (50:50, weight ratio) [S he 1 1 IR-3 0 9 (trade name), manufactured by Shell Chemical Co., Ltd.] linear rubber surrounds the center of each of the above-prepared centers, M forms a linear rubber layer, so the outer diameter is prepared 3 9. 5 mm wire wound core. The above-mentioned core Μ—covers the hemispherical half-shell molded by the composition used as the coating material, and connects it to the ball mold, and then presses and molds it at 150 ° C for 3 minutes to obtain a wire Wrap golf. The resulting golf ball was coated with M paint, and the M modified golf ball with an outer diameter of 4.2 mm. The composition of the coating material is prepared by mixing 2 parts by weight of titanium dioxide in H i ί i 1 ane U 0 5 (brand name) and Hi-milalnel760 (brand name (50:50, weight)) [respectively by Mitsui DuPont High Molecular Chemistry Co., Ltd. (M itsui Du) This paper standard is applicable to China National Standard (CNS) Α4 specification (210X297mm) (Please read the notes on the back before filling this page)

、1T A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明( 1 ^ 1 1 Po n t P ο 1 y _ Chemical C 0 . L t d )製造之Μ納離子中和之離 1 1 子 鍵 聚 合 物 j 及 由 三 井 杜 邦 高 分 子 化 學 股 份 有 限 公 司 製造 1 1 之 Η 鋅 離 子 中 和 之 離 子 鐽 聚 合 物 ]中製得 * /— 請 1 先 1 檢 測 所 得 高 爾 夫 球 之 重 量 壓 縮 t 飛 行 效 能 與 擊 球感 閱 讀 1 背 1 0 飛 行 效 能 係 如 當 Μ 1 m 木 桿 擊 球 之 情 形 (飛行效能1)及 面 之 1 注 I Μ 5 號 鐵 桿 擊 球 時 之 情 形 (飛行效能2 )檢測 意 本 1 例 項 I 實 1 至 5 之 高 爾 夫 球 之 重 量 j 壓 縮 飛 行 效 能 1)及 再 填 Λ 2)及擊球感 之 評 估 結 果 列 於 表 3 中 0 比 較 例 1 至 4 之 高爾 寫 本 頁 1 夫 球 之 此 等 性 質 係 列 於 表 4 中 » 且 比 較 例 5 至 7 之 此 等性 1 I 質 係 列 於 表 5 中 0 1 1 | 再 者 * 壓 著 * 飛 行 效 能 1 及 飛 行 效 能 2 之 測 量 方 法, 1 1 訂 Μ 及 擊 球 感 之 評 估 方 法 及 評 估 標 準 如 下 0 1 赌縮 1 1 將 初 負 荷 (10k S) 施 於 局 爾 夫 球 上 且 接 著 負 荷 逐 漸增 1 | 加 至 終 負 何 (13 0kg) ! 高爾夫球之初貪荷與終負荷間形成 1 Μ 之 m VU»、 變 量 係 依 P G A条統測量 1 敗..行效能丄 1 1 由 T r u e T e in P r t Co .製造之自動擺動機裝置1 號木桿, 1 且 在 桿 頭 速 约 4 5 m /秒 下 擊 球 » 測 量 飛 行 效 能 1 ' 旋轉量係 1 | 經 由 拍 攝 打 擊 之 高 爾 夫 球 之 照 Η 測 定 射 程 係 Γί~ι" 阿 爾 夫 球落 1 I 地 之 點 之 距 離 ° 全 程 係 射 程 及 局 爾 夫 球 白 落 地 之 點 滾 動之 1 1 | 距 離 之 和 〇 1 1 版 行 效 能 ? 1 | T r u e T e πι P e r Co .製造之自動擺動機裝置5 號鐵桿, 1 1 1 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) 13 經濟部中央梂準局員工消費合作社印製 323232 ‘ A7 _B7__ 五、發明説明(1 ί 且Κ桿頭速約3 8 m /秒打擊高爾夫球,測量飛行效能2。 盤球感評估方法及評估德進 此高爾夫球經由十位頂尖之職業高爾夫球員Ml號木 旱實地的擊球,K評估擊球感。評估標準如下。表3至5 中顯示之結果係Μ不低於8至10位高爾夫球員Μ相同之標 準評估所得之事實為準。 0 : 與使用巴拉塔樹脂之標準線繞式高爾夫球相似之擊球 感。 X Η :重且不良。 XS:軟且重的感覺,不良。 Μ_a (請先閱讀背面之注意事項再填寫本頁) ,1Τ Μ ! 實 施 編 號 1 2 3 4 5 球 重量ω 45.4 45.4 45.5 45.3 45.3 壓縮 86 87 87 86 86 飛行效能1Π號木捍) 飛射角度(度) 11.2 11.3 11.4 11.5 11.4 旋轉(rpm) 3150 3130 3080 3050 3120 射程(碼) 227.0 227.3 228.0 228.2 227.2 全程(碼) 233.5 233.9 234.5 234.7 234.0 飛行效能2(5號鐵桿) 飛射角度(度) 14.7 14.8 15.0 15.2 14.9 旋轉(rpm) 4800 4750 4730 4700 4730 射程(碼> 187.3 187.5 187.9 188.0 187.6 全程(碼) 189.5 189.8 190.0 190.5 189.7 擊球感 0 0 0 0 0 本紙張尺度適用中國國家標準(CNS ) Μ规格(210 X 297公釐) 經濟部中央樣準局員工消費合作社印製 A7 B7 五、發明説明(]5 ) II__4、 1T A7 B7 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of invention (1 ^ 1 1 Po nt P ο 1 y _ Chemical C 0. L td) Neutralization of 1 mn sub-bond manufactured by Mn nano-ions Polymer j and manufactured by Mitsui Dupont Polymer Chemical Co., Ltd. 1 1 Zn-neutralized ion-neutralized polymer of H Zn ion] * / — Please 1 first 1 Check the weight compression of the resulting golf ball t Flight performance and impact Ball sense reading 1 Back 1 0 The flight performance is like the situation when the Μ 1 m wood hits the ball (Flight Effectiveness 1) and the surface 1 Note I The situation when the Μ 5 iron hits the ball (Flight Effectiveness 2) Example I The weight of golf balls 1 to 5 j Compressed flight performance 1) and refill Λ 2) and the evaluation result of hitting feeling are listed in Table 3 0 Gower of Comparative Examples 1 to 4 write this page 1 The series of these properties of the ball are shown in Table 4 »and the equivalence of the comparative examples 5 to 7 1 The qualitative series are shown in Table 5 0 1 1 | Furthermore * the compression * the measurement methods of flight performance 1 and flight performance 2, 1 1 Set the evaluation method and evaluation criteria for Μ and the sense of hit as follows 0 1 Gamble 1 1 Apply the initial load (10k S) to the golf ball and then the load gradually increases by 1 | Add to the final loss (13 0kg )! Between the initial load and the final load of the golf ball is formed 1 m of m VU », the variable is measured according to the PGA system. 1 failure .. the performance is 1 1 1 automatic pendulum manufactured by True T e in P rt Co. Motivation device No. 1 wooden pole, 1 and hits the ball at a head speed of about 4 5 m / sec »Measure flight efficiency 1 'Rotation amount system 1 | The shot of the golf ball shot by shooting Η Measure range Γί ~ ι " Al The distance of the point where the ball falls 1 I to the ground ° Cheng and Juerlf Ball White Landing Point Rolling 1 1 | Sum of Distance 〇 1 1 Version Performance? 1 | Automatic swing machine device No. 5 iron manufactured by True Te e Per Co., 1 1 1 copy The paper size is in accordance with the Chinese National Standard (CNS) A4 specification (210X 297 mm). 13 Printed by the Consumer Entrepreneur Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economics 323232 'A7 _B7__ V. Description of invention (1 ί and the speed of the club head is about 38 m / Strike a golf ball in seconds and measure flight efficiency 2. Evaluation Method of Dribbling Sense and Evaluation of Dejin. This golf ball is hit by ten top professional golfers Ml. The evaluation criteria are as follows. The results shown in Tables 3 to 5 are based on the fact that M is not less than the same standard evaluation of 8 to 10 golfers M. 0: Similar to the standard wire wound golf ball using Balata resin. X Η: Heavy and bad. XS: Soft and heavy feeling, bad. Μ_a (please read the precautions on the back before filling in this page), 1Τ Μ! Implementation number 1 2 3 4 5 Ball weight ω 45.4 45.4 45.5 45.3 45.3 Compression 86 87 87 86 86 Flight efficiency 1Π wooden defend) Flying angle ( Degrees) 11.2 11.3 11.4 11.5 11.4 rotation (rpm) 3150 3130 3080 3050 3120 range (yards) 227.0 227.3 228.0 228.2 227.2 full range (yards) 233.5 233.9 234.5 234.7 234.0 flight performance 2 (iron 5) angle of flight (degrees) 14.7 14.8 15.0 15.2 14.9 Rotation (rpm) 4800 4750 4730 4700 4730 Range (yards> 187.3 187.5 187.9 188.0 187.6 Full range (yards) 189.5 189.8 190.0 190.5 189.7 Sense of hit 0 0 0 0 0 This paper size applies to the Chinese National Standard (CNS) Μ Specifications (210 X 297 mm) A7 B7 printed by the Employee Consumer Cooperative of the Central Prototype Bureau of the Ministry of Economic Affairs 5. Description of the invention (] 5) II__4

比 較 例 编 號 1 2 3 4 球 重量U) 45.4 45.4 45.5 45.3 壓縮 86 86 86 8 7 飛行效能Η1號木桿) 飛射角度(度) ]〇. 7 11.0 10.9 11.1 旋轉(r p m) 3400 3300 3310 3280 射程(碼) 224.0 225.0 224.8 225.2 全程(碼) 229.5 2 3 0.2 230.0 230.4 飛行效能2(5號鐵桿) 飛射角度(度〉 14.0 14.5 14.4 14.5 旋轉(r p m) 5150 5020 5030 5000 射程(碼) 18 4.3 185.0 ]8 4 8 18 5.2 全程(碼) 186.5 187.3 187.0 187.2 擊球感 XH XH XH XH (請先閱讀背面之注意事項再填寫本頁)Comparative Example No. 1 2 3 4 Ball weight U) 45.4 45.4 45.5 45.3 Compression 86 86 86 8 7 Flight performance Η1 wooden pole) Flying angle (degrees)] 〇. 7 11.0 10.9 11.1 Rotation (rpm) 3400 3300 3310 3280 Range (yards) 224.0 225.0 224.8 225.2 Full range (yards) 229.5 2 3 0.2 230.0 230.4 Flight performance 2 (No. 5 iron) Flying angle (degree> 14.0 14.5 14.4 14.5 Rotation (rpm) 5150 5020 5030 5000 Range (yards) 18 4.3 185.0] 8 4 8 18 5.2 The whole process (code) 186.5 187.3 187.0 187.2 Sense of hitting XH XH XH XH (Please read the precautions on the back before filling this page)

、1T 本紙張尺度速用中國國家揉準(CNS ) A4規格(210X2.97公釐1)5、 1T The standard speed of this paper is the Chinese National Standard (CNS) A4 specification (210X2.97mm1) 5

AA

7 B 五、發明説明(】6) 轰7 B 5. Description of the invention (】 6) Boom

經濟部中央標準局員工消费合作社印I 比 較 例 編 號 5 6 7 球 重量(g) 45.4 45.3 45.5 壓縮 8 6 65 8 6 飛行效能Η 1號木捍) 飛射角度(度) 11.2 11.5 11.0 旋轉(r P m ) 3 3 2 0 3 100 3 3 5 0 射程(碼) 225.5 2 2 3.5 2 2 2.5 全程(碼) 2 3 0.5 2 2 9.0 2 2 8.0 飛行效能2 ( 5號鐵桿) 飛射角度(度) 14.3 15.1 14.1 旋轉< 1* P m ) 5 0 3 0 4 8 0 0 5 100 射程(碼) 184.7 18 4.0 18 3.0 全程(碼) 1 S 7 . 1 18 7.5 186.5 擊球感 XH XS 0 (請先閲讀背面之注意事項再填寫本頁)Printed by the Consumer Standardization Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. Comparative Example No. 5 6 7 Ball weight (g) 45.4 45.3 45.5 Compression 8 6 65 8 6 Flight performance Η 1 Muhang) Flying angle (degrees) 11.2 11.5 11.0 Rotation (r P m) 3 3 2 0 3 100 3 3 5 0 Range (yards) 225.5 2 2 3.5 2 2 2.5 Full range (yards) 2 3 0.5 2 2 9.0 2 2 8.0 Flight performance 2 (iron 5) Flight angle (degrees) ) 14.3 15.1 14.1 Rotation < 1 * P m) 5 0 3 0 4 8 0 0 5 100 Range (yard) 184.7 18 4.0 18 3.0 Full course (yard) 1 S 7.1 18 7.5 186.5 Sense of impact XH XS 0 ( (Please read the notes on the back before filling this page)

、1T -I. 本紙張尺度適用中國國家揉準(CNS ) A4規格(210 X 297公釐) 16 325232 五、發明説明(n) 表 由 R3 i 出 看 地 顯 明 可 較 比 果 結 之 示 顯 中 5 及 大較 均均 度較 角比 射球 飛夫 且爾 , 高 小 之 均 7 量 至 轉 1 旋例 , 較 球比 夫與 爾離 高 距 之 行 5 飛 至 -1 者 例再 實且 於 , 球了式 擊可片 桿 ,兩 木此於 號因等 1 且且 Μ , , 球碼大 夫α均 爾 3 離 高 ? 距體择行 固 5 飛 2 一 片 2 之 兩為球 準般夫 標一爾 之 } 高 程 Kif之 體(15 固離至 用距 1 使行例 。 飛實 大之解 之變 4 將 至轉 丨旋 例 -實 時 之硬 宿 較 οηπ -ίΕ-ι· 樹 得 性變 塑心 熱中 同且 相大 用變 使徑 在直 -.之 者心 再中 〇 當 球 , 夫中 爾估 高 評 均 心 中 球 夫 ο 爾 離 高 距之 行 6 飛及 的 3 大 至 致 1 導例 » --Hit 大比 變於 將關 度 , 角地 射 對 飛相 且 且 , 亦此 ο 因 離且 距 , 行大 飛量 的變 大 應 到 之 得心 法中 無 , , 球 此夫 因爾 a高 , 之 大 4 均例 量較 變比 應 於 且 關 軟 , £於 中關 I 〇 球離 夫距 爾行 高飛 之的 5 大 例到 較達 比法 於無 關此 。 因 離且 距 , 行小 飛量 的變 大應 到其 得 , 法硬 無太 乂- 、 夫變 爾度 高 速 之始 7 起 例 , 較此 比因 且 足 不 性 單 擊 撞 且 小 度 高 pi 回 0 距 行 飛 的 小 到 達 此 因 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央樣準局員工消費合作社印製 , 相 太 感球均 球夫球 擊爾夫 之 高 爾 好式高 良 繞些 持線某 保準之 球標中 夫之球 爾材夫 高 覆 爾 之 被高 5 脂之 至 樹 6 1 塔 至 例拉 1 較巴伊 比 阿較 , 用 比 者使在 再與但 係 其 似 良 不 均 此 因 軟 太 或 硬 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐)、 1T -I. This paper scale is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 16 325232 V. Description of the invention (n) The table is clearly shown by R3 i and can be compared with the results The average of 5 and the average of the larger than the angle is higher than the shot of the fly, and the average of the height is 7 to the rotation of 1 rotation. The case of flying from the ball to the high distance of 5 and -1 is better. Moreover, the ball hits the flick, and the two woods are due to the number 1 and Μ,, the ball yard doctor α Juner 3 is high? From the body to choose the line 5 to fly 2 to a piece of 2 is the ball quasi-hufu marked one} of the body of the elevation Kif (15 fixed away to use the distance 1 to make the routine. The change of the solution of Fushida 4 will be transferred to turn 丨Rotating example-Real-time hard accommodation is more οηπ -ίΕ-ι · Trees become deformed, the heart is the same and the same, and the diameter is straight-. Those who are in the heart will be the ball again. The golfer ’s trip from the high distance to 6 and the flight from 3 to 3 to 1 lead case »--Hit ratio is changed to the level, the angle of the shot is opposite to the flight phase, and the same is true due to the distance and distance. The increase in the amount of fly should be in the right way,, the ball is higher than the ball, and the maximum is 4. The average amount of change is better and softer, £ 10 in Zhongguan. The five major examples of Gao Feizhi have nothing to do with the Darby method. Due to the distance and distance, the increase in the small flying amount should be due to it. The law is not too bad. Compared with this cause, it is not enough to click and hit, and the degree of pi is high, and the pi returns to 0. Read the notes on the back and fill out this page) Printed by the Employee Consumer Cooperative of the Central Bureau of Samples of the Ministry of Economic Affairs. The ball of the husband, the material of the husband, the high of the cover, the high of the fat, the tree of the fat, the tower of 6, the tower of 1 to the shell, 1 is better than that of Baibiya, and it is not good or uneven because it is too soft or hard. This paper scale is applicable to China National Standard (CNS) A4 specification (210X297mm)

/t L/ t L

Claims (1)

5282 A8 B8 C8 D8 申請專利範圍 1 一種線 物件構 覆於該 中該中 負荷為 2 .如申請 心係包 脂組成 3 .如申請 心係包 脂,2 及10至 製物件 繞式高爾夫球,包括由橡膠組成物之硫化模製 成之中心,在該中心上形成之線狀橡膠層及被 線狀橡膠層上之被覆材之線繞式高爾夫球,其 心之直徑為30至35mm,且在初負荷為l〇kg及終 3 0 k g之間形成之應變量為1 . 2至2 . 5 m πι。 專利範圍第1項之線繞式高爾夫球,其中之中 括1 0 0重量份之橡膠及5至8 0重量份之熱塑性樹 之橡膠組成物之硫化模製物件。 專利範圍第]項之線繞式高爾夫球,其中之中 括1 0 0重量份之橡膠,5至8 0重量份之熱塑性樹 至1 2重量份之硫,]至4重量份之硫化加速劑 1 5 0重量份之重量調整劑之橡膠組成物之硫化模 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 4 .如申請專利範圍第1至3項任一項之線繞式高爾夫球, 其中中心之橡膠為高順式聚丁二烯或主要含有高順式 聚丁二烯者。 5.如申請專利範圍第2或3項任一項之線繞式高爾夫球, 其中之熱塑性樹脂為高苯乙烯樹脂或高分子量聚烯烴 或其混合物。 6 .如申請專利範圍第丨項之線繞式高爾夫球,其中當中 心自2 5 4 c πι之高度掉下時,中心之回彈高度為1 2 0 c m或 更高。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 185282 A8 B8 C8 D8 Patent application scope 1 A wire object covered in the middle load is 2. For example, apply for cardiolipid composition 3. For example, apply for cardiolipid, 2 and 10 to make the object winding golf ball, Including a center made of a vulcanization mold of a rubber composition, a linear rubber layer formed on the center and a wire-wound golf ball coated with a coating material on the linear rubber layer, the diameter of the core is 30 to 35 mm, and The strain between the initial load of 10 kg and the final 30 kg is 1.2 to 2.5 m πι. The wire-wound golf ball of the first item of the patent scope includes vulcanized molded articles of 100 parts by weight of rubber and 5 to 80 parts by weight of a rubber composition of a thermoplastic tree. Patent scope item] wire wound golf ball, which includes 100 parts by weight of rubber, 5 to 80 parts by weight of thermoplastic tree to 12 parts by weight of sulfur,] to 4 parts by weight of vulcanization accelerator 1 5 0 parts by weight of the vulcanization mold of the rubber composition of the weight adjuster (please read the precautions on the back before filling in this page) Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 4. If applying for patents, items 1 to 3 Any one of the wire-wound golf balls, wherein the rubber in the center is high cis polybutadiene or mainly contains high cis polybutadiene. 5. The wire-wound golf ball according to any of items 2 or 3 of the patent application, wherein the thermoplastic resin is a high styrene resin or a high molecular weight polyolefin or a mixture thereof. 6. The wire-wound golf ball as claimed in item 丨 of the patent scope, in which the center rebounds to a height of 120 cm or more when the center falls from a height of 2 5 4 c πι. This paper scale is applicable to China National Standard (CNS) A4 specification (210X297mm) 18
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EP (1) EP0674923B1 (en)
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AU (1) AU687511B2 (en)
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Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2299275B (en) * 1995-03-31 1999-04-07 Sumitomo Rubber Ind Thread wound golf ball
JP3625231B2 (en) * 1995-12-07 2005-03-02 住友ゴム工業株式会社 Thread wound golf ball
JPH09248352A (en) * 1996-03-15 1997-09-22 Sumitomo Rubber Ind Ltd Golf ball
JPH09271537A (en) * 1996-04-04 1997-10-21 Sumitomo Rubber Ind Ltd Golf ball
US6210291B1 (en) 1996-04-04 2001-04-03 Sumitomo Rubber Industries, Ltd. Golf ball
US7244384B1 (en) 1998-02-04 2007-07-17 Taylormade-Adidas Golf Company Method for manufacturing two and three piece golf balls constructed from polyurethane material
US7223181B2 (en) 1998-02-04 2007-05-29 Taylormade-Adidas Golf Company Polyurethane material for two and three piece golf balls and method
US6196937B1 (en) 1998-02-04 2001-03-06 Sanjay M. Kuttappa Three piece golf ball
US6719646B2 (en) 2000-01-25 2004-04-13 Dunlop Slazenger Sports Polyurethane covered three-piece golf ball

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1520254A (en) * 1974-12-30 1978-08-02 Uniroyal Ltd Golf balls
JPS59129072A (en) * 1983-01-12 1984-07-25 住友ゴム工業株式会社 Yarn wound golf ball
CA1230355A (en) * 1983-10-24 1987-12-15 William Gobush Low trajectory long distance golf ball
JP3169287B2 (en) * 1992-06-09 2001-05-21 住友ゴム工業株式会社 Wound golf ball
JP2664857B2 (en) * 1993-07-30 1997-10-22 住友ゴム工業株式会社 Thread wound golf ball

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AU687511B2 (en) 1998-02-26
CA2145783A1 (en) 1995-10-01
DE69506930T2 (en) 1999-05-27
KR950031136A (en) 1995-12-18
DE69506930D1 (en) 1999-02-11
AU1620295A (en) 1995-10-12
EP0674923B1 (en) 1998-12-30
EP0674923A1 (en) 1995-10-04

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