TW322448B

TW322448B -

Info

Publication number: TW322448B
Application number: TW086100124A
Authority: TW
Original assignee: Toyo Koban Kk
Priority date: 1995-12-22
Filing date: 1997-01-06
Publication date: 1997-12-11
Also published as: JPH09174757A; CN1207704A; WO1997023349A1; CN1084673C; JP2971382B2; KR100404158B1; KR19990076613A; AU1172497A

Description

522448 B7 經濟部中央標準局員工消費合作社印製五、發明説明（ 1 i ) 1 1 I r 1 技術領域 J 1 1 1 本發明係有闞一種具有高硬度 9 且耐壓痕性、耐 if 出 1 I 性 ( 可塑劑 ) 優異 9 同時加工性式 m 性良好之覆聚氯乙請先 1 閣 1 烯鋼板之製法 0 讀背 1 面 I 之 1 注 | 意 I C m 景技術事項 1 I 再 1 I 覆聚氯乙烯鋼板具有優異之加工性耐腐蝕性、耐填 1 裝寫本候性及式漾性等之特性 9 適用於建材電氣機器 \ 車輛 Λ 頁 1 1 傢俱等廣泛之領域 0 1 1 覆聚氯乙烯鋼板之製法大致可分為塑性溶膠法及薄 1 1 膜層合法 Ο 塑性溶膠法係將聚氯乙烯樹脂、可塑劑安 1 訂定劑 > 顔料等所構成之塑性溶解介接著劑層在鋼板上 1 1 塗裝 *. 定厚度後再 W 加熱將塗膜凝膠化而後再於皮膜 1 1 I 上進行壓花加工而完成製造〇 1 1 然而 9 K 塑性溶膠法所製造之覆聚氯乙烯 ΛΚΤΤ 鋼板 - 般 1 線上其塗膜為軟質與薄膜層合法所製造之覆聚氯乙烯 m 板 1 I 比較 9 塗膜之 CS 嫂度 Λ 耐壓痕性、耐遂出性等之特性不佳 Ο 1 I 於塑性溶膠法中係將由聚氛乙烯澍脂可塑劑、安定劑 1 1 、顔料稀釋劑等所構成之塑性溶膠 Μ 輥式被覆器等之方 1 1 法塗裝於鋼板上 9 因此 9 有必要將塑性溶膠粘度 9 維持於 1 1 一之範圍 0 是 Μ i — 般係使用相對聚氛乙烯樹脂 1 0 〇 1 I 重量份 ) 配合 4 〇 6 0 重量份可塑劑之塑性溶膠 » 與薄 1 1 | 膜層合法相較 » 塗膜中之可塑 3- 劑增多 » 塗膜會雯成軟質〇 1 1 1 1 本纸張尺度適财ii^^~CNS M4規丨五、發明説明（) A7 B7 經濟部中央標準局員工消費合作社印製壓可由，特可紫、} 粉或4法在之此乙題板耐 , 之是面，性射號等物化 1 方，板決氯問鋼、時中的層是合照 8 號合硬.3 等劑鋼解聚其烯性力膜。討的但聚後 13 聚.熱一此合烯為與有乙痕壓塗題研等，之化 89 系加 5, 配乙作係上氯壓之-問已用膠狀硬 13 力可平而之氯，均濟聚耐大又之界使溶液在 39 克及公然倍聚又，經覆、較，面業之性合是 I I 壓末特。數覆。種在之度有題方，劑塑配或47 合粉丨}至之點一 -造硬面問性點釋的中，45 配物法等價造缺何法製膜表之出缺稀度膠法昭昭中合方號高製之任方所塗膜性滲之及粘溶方公公膠聚之 7 用所種是之法種塗痕耐法擇之性的特特溶糸物 4 使法各管劑膠一對壓有膠選装塑化 {、性力合 7 係膠有不合溶供上耐而溶之塗在硬法 ο 塑克聚 6 均溶，，配性提其有，性劑可案熱方 8 在壓寡 7, 性質法價塑，於而面塑塑劑。提加之 5 案合、 I 較。塑软方高M成載，表等可塑限曾之化 2 提配體4相題M為之用決而積破至此或可界界時硬 2 曾及軍平脂問，係案使解發品壓移良脂低其業膠膜 I 邐以之公樹的述上提，為開製於轉改樹 Μ 有，凝塗 ο 界，化特烯大所般而較係題當易會為烯有善此 Μ 令 5 業法硬、乙有上 ~ 點相明問 - 案也作乙具改為，，昭，方線號氯上如，題脂發述此圖劑氮發之劑線公又之外 7 聚濟膜問澍本上如花塑聚開性塑外特。末紫 6 與經塗等烯。的 , - * -HI n n n I n I In _ _ I I n HI T/. US 、\s° (請先閱讀背面之注意事項再填寫本頁) 本紙悵尺度適用中國國家榡準（CNS ) Λ4規格（210Χ 297公釐） 322448 A7 經濟部中央標隼局員工消費合作社印製 B7五、發明説明（$ ) 滲出性等之特性優異，且經濟性佳之覆氯乙烯鋼板的製法。又，本發明復謀求塑性溶膠之低可塑劑量下的低粘度化 0 〔發明之概要] 針對此種課題，本發明之特徵係在於，在網板表面塗布習知之接著劑κ加熱進行烘烤後，被覆將具有持定粒徑分布之聚氮乙烯樹脂粉末及特定之可塑劑，相對聚氯乙烯樹脂粉末1 00重量份配合20〜40重量份，又配合習知顔料、安定劑而成之低可塑劑量及低粘度的塑性溶膠。具體言之，本發明覆聚氛乙烯鋼板之製法，其特徵係在：在鋼板上被覆相對95重量％以上為粒徑0·5〜4 ◦ wm ，且1 5〜40重量％為〇 · 5〜未達3wm ，在 1〜3wm具有尖峰*同時，55〜80重量％為3〜4 0«m，且8〜1 具有尖峰之二尖峰類型聚氯乙烯澍脂粉末1 0 0重量份，作為可塑劑配合由碳數目7〜9 之醇成分所構成的肽酸酯5〜2 5重量份及碳數目8〜1 0之醇成分所構成的己二酸酯5〜1 5重量份，配合缌量為2 0-4 0重量份，又再配合習知之顔料、安定劑而成之塑性溶膠。具體言之，本發明覆聚氛乙烯鋼板之製法*其特徵係在： -5- 本紙張尺度適用中國國家標率 s ) A4規格（21〇Χ37公釐） (請先閱讀背面之注意事項再填寫本頁) •裝. ，-° 線 A7 B7 經濟部中央標準局員工消費合作社印製五、發明説明（十） 1 i | 在鋼板上被覆相對 9 5重量％以上為粒徑 0 * 5 4 1 1 I 0 U m > 且 1 5 4 0 重量％為0 * 5 未達 3 U m 在 1 I 1 3 U m 具有尖峰 9 同時，5 5 8 0 重量 % 為 3 4 請先 1 1 閲 1 0 U m » 且 8 1 5 U m 具有尖峰之二尖峰類型聚氯乙烯讀背 I 面 I 樹脂粉末A 6 0 9 5 重量份與9 0 重量 % 以上為粒徑 1 冬 1 1 意 1 I 〇 6 0 U m 且在 2 〇 4 0 u m 具有尖峰之聚氯乙烯樹事項再 1 1 脂粉末 Β 5 4 〇重量份，而相對 A 與 B 之合計 1 〇 0 重填 1 寫本裝量份作為可塑劑配合由碳數目7〜 9 之醇成分所構成的狀頁 1 1 酸酯 5 2 5 重量份及碳數目8〜 1 0 之酵成分所構成的 1 1 己二酸酯 5 1 5 重量份，配合缌量為2 0 4 0 重量份 1 > 又再配合習知之顔料、安定劑而成之塑性溶膠 0 1 訂 1 〔實施發明之最佳形態 ] 1 1 於本發明方法中作為鋼板，可使用在冷延伸 m 板及 1 1 冷延伸鋼板上實施鍍鋅、鍍鉻、鍍錫、鍍 m 鍍鋁、鍍 1 線鉛或鍍此等金靥之合金 9 或作複層鍍敷而成之 m 板或是 1 I t 再於此種鍍金屬鋼板之上層，實施鉻酸塩處理、磷酸塩 1 ! 處理等之電化成形處理而成之鋼板 0 又，因應其百的 9 還 1 1 可選擇不 m 鋼板、鋁板等 0 1 I 依本發明方法，為了鋼板與聚氯乙烯塗膜之接著 9 可 1 I 使用 Μ 壓克力澍脂、聚酯樹脂、胺基甲酸酯樹脂、環氧澍 1 1 脂或壓克力掾膠為主成份之習知接著劑〇在網板表面被覆 1 1 成皮膜後 3 1 0 a m 後，Μ 1 6 0 2 5 〇作 1 分鐘 1 1 -6 - 1 1 本紙悵尺度適用中國國家標準（CNS ) A4規格（2丨OX 29?公釐） A7 522U8 _B7____ 五、發明説明（令）之加熱後•進行烘烤，而後再塗布塑性溶膠。本發明開發過程中，就塗布之塑性溶膠之組成及性狀 Μ及所獲得的鋼板之特性作詳细的試驗之结果發現* 一般之塑性溶膠法所製造之覆聚氯乙烯鋼板的塗膜之硬度、耐壓痕性、耐滲出性等之特性與薄膜層合法相較之下較差的原因是，塗膜中之可塑劑量的差異。薄膜層合法中所使用之薄膜，一般係以砑光加工法製造，可將薄膜中之可塑劑量，Κ大致任意的比例溫合，在覆聚氛乙烯鋼板之用途中 *相對聚氛乙烯樹脂1 00重量份係配合250〜40重量份，相對於此，若為塑性溶膠之場合，由於有必要將塑性溶膠以輥式被覆器等塗装一定之厚度，因此，有必要將塑性溶膠之粘度保持於一定以下，通常，相對聚氯乙烯樹腊1 00重量份，係配合可塑劑4 0〜60重量份。此一可塑劑量之差異，對於塗膜之特性有重大的影響。是以，本發明為了確立低可塑劑量之低粘度塑性溶膠 ’著眼於聚氯乙烯樹脂粉末之粒徑分布及可塑劑之選擇，再三研討之结果發現塗膜之硬度、耐壓痕性、耐滲出性等之特性優異，且經濟性亦佳之塑性溶膠。本發明塑性溶膠中所使用之聚氯乙烯樹脂粉末A，係 Μ乳化聚合物法或微懋浮法所製造之平均聚合度5 0 0〜 2 5 0 〇之澍脂粉末。此外，也可使用氮乙烯單體與乙烯 '两铺、乙酸乙烯酯、丙酸乙烯酯、烷基乙烯基醚、偏二氛乙稀、富馬酸二乙酯、或甲基丙烯酸酯共聚合所成之聚本纸张尺度適用中國國家標準（CNS ) Α4規格（2ΙΟΧ 297公痠） — I I I I I I ^ 線 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製經濟部中央標隼局員工消費合作社印製 A7 B7 五、發明説明（k) 氛乙烯系樹脂粉末。一般而言，Μ塑性溶膠法製造覆聚氯乙晞鋼板之場合，係使用圖1所示之平均粒徑1〜2 ，一尖峰之粒徑分布物。是Μ，為了 Μ低可塑劑量達成低粘度，就聚氯乙烯樹脂粉末之粒徑進行銳意之研究發現，為了獲得低可塑劑量之低粘度塑性溶膠，有必要提高塑性溶膠中聚氯乙烯樹脂之充填密度*為此，最好具有圈2中顯示其一例之二尖峰類型之粒徑分布。本發明聚氯乙烯樹脂粉末Α之粒徑，較佳的是，具有 95重量％以上為粒徑0 · 5〜40«Γη，且1 5〜40 重量％為0 · 5〜3/zm未達，在1〜3«m具有尖峰，同時，55〜80重量％為3〜40um，在8〜1 5« m具有尖峰之二尖峰類型的粒徑。當粒徑4 0 urriM上之粉末超過5重量％時，塑性溶膠塗装表面之完成狀態不佳，不令人滿意。為粒徑0 . 5〜3wm之粉末未達15重量％，且粒徑3〜40/zrTi之粉末超過80重量％時，塑性溶膠之凝膠化性能會降低，以致塗膜之強度降低，並不令人滿意。又，粒徑0.5〜3um之粉末在40重量％以上，且粒徑3〜40um之粉末未達55重量％時，塑性溶膠粘度會提高，塗装性變差，並不令人滿意。又，就可塑劑量20〜40重量份之塑性溶膠的低粘度化進行研討的结果發現，若配合如圖3中表示其一例之粗粒聚氯乙烯樹脂粉末B ,可進一步成為低粘度，使塗装 -8 * 本纸張尺度適用中國國家標準（CNS ) Λ4規格（210X 297公釐) I. . 裝訂線 (請先閱讀背面之注意事項再填寫本頁) A7 B7 經濟部中央標準局員工消費合作社印製 --- 五、發明説获 ( 7 ) 1 1 I 性進 — 步提高 0 1 1 1 本發明塑性溶膠中所使用之聚氯乙烯樹脂粉末 B ，係 1 | 由懸浮聚合法所製造之平均聚合度為 5 0 〇 2 0 〇 0 之請先閱 1 I 樹脂粉末 0 又 9 可使用氮乙烯單體與乙烯、丙烯、乙酸乙讀背 1 1 面 I 烯酯丙酸乙烯酯、烧基乙烯基醚、偏二氛乙烯富馬酸之注 1 1 二乙酯或甲基丙烯酸酯共聚合而成之聚氯乙烯系樹脂粉末悬事項 1 I 1 I 〇填 1 6 0 % 本裝聚氛乙烯樹脂粉末 B » 較佳的是 9 粒徑為 1 〇頁 1 | U m 1 且在 2 0 4 〇 U m 具有尖峰 0 又 t 更好的是 9 粒 1 1 徑 1 5 4 〇 U m 者在 7 0 重量 % 以上 0 當粒徑未達 1 1 1 〇 U m 之粉末超過 1 0 重量 % 時降低塑性溶膠的粘度之 1 訂 1 I 效果會降低並不令人滿意 0 又當粒徑 6 0 U m >λ 上者超過 6 〇重童 % 時塑性溶膠塗装表面之完工狀態會較劣 1 1 I 並不令人滿意 0 1 1 本發明塑性溶膠中聚氯乙烯樹脂 A 與 B 之比例當設 1 線聚氯乙烯樹脂 A 與 B 之合計量為 1 〇 0 重量份之場合較 1 I 佳的是聚氯乙烯樹脂 A 為 6 〇 9 5 重量份聚氮乙烯 1 1 I 樹脂 B 5 為 5 4 〇重量份 0 在聚氛乙烯樹脂 A 未達 6 0 1 1 重量份之狀況下 9 若聚氮乙烯樹脂 B 超過 4 〇重量份凝 1 1 膠化後之塗膠強度會降低因此不令人滿意 0 又在聚氛 1 | 乙烯樹脂 A 在 9 5 重量份以上之情況下 f 若聚氛乙烯樹脂 1 I B 未達 5 重量份時 > 看不到聚氛乙烯樹脂 B 配合之效果 9 1 1 因此不令人滿意〇 - 9- 1 1 1 1 本紙張尺度中家標率（CNS ) (21GX297公瘦） Z22U8 A7 B7 經濟部中央標準局員工消費合作社印製五、發明説明（ ) 1 1 其次於本發明方法 ♦ 就塑性溶膠中配合可塑劑此擧 1 1 I 研討之结果發現 > Μ 習知狀酸酯苯偏三酸酯 Λ 己二酸 1 1 1 等為首 » 可使用各種脂族酯、各種磷酸酯等之一次可塑劑請先 1 1 或二次可塑劑 9 但由塑性溶膠粘度、粘度之經時安定性 Λ Κ] 讀背 1 | 面 I 凝膠化性能及塗膜硬度 \ 耐壓痕性、加工性 > 耐滲出性等之注 1 I 意 1 I 之特性面觀之 * 宜為由碳數 7 9 之醇成份所構成之肽酸事項 1 I 1 I 酯與碳數 8 1 0 之醇成分所構成之己二酸酯的組合 0 填寫本 1 末重量裝就其配合比率 1 相對聚氮乙烯樹脂粉 1 〇 0 份頁 1 I » 作為可塑劑 t 宜配合由碳數 7 9 之醇成份所構成之肽 1 1 酸酯 5 2 5 重量份與由碳數 8 1 0 之醇成分所構成之 1 1 己二酸酯 5 1 5 重量份合計為 2 〇 4 〇重量份〇 1 訂 1 I 在由碳數 7 9 之醇成分所構成之肽酸酯未達 5 重量份之狀況下當由碳數 8 1 0 之酵成分所構成之己二酸 1 1 酷為 2 5 重量份 Μ 上時塗膜之耐滲出性會降低因此不 1 1 令人滿意 0 又當可塑劑之合計量為 4 〇重量份 Κ 上時 > 1 線塗膜之硬度會降低 > 耐壓痕性也會降低不令人滿意〇 1 I 作為可塑 m > 若使用碳數 S 未達 7 之醇成分所構成之 1 I 钛酸酯時 f 塑性溶膠之粘度的經時安定性會降低 9 且塗膜 1 1 之硬度會成為軟質 t 因此並不令人滿意〇又 ) 若使用碳數 1 1 1 0 以上之醇成分所構成之肽酸酯時 * 塑性溶膠之粘度會 1 1 增高 » 塗装性會降低 » 因此不令人滿意〇 1 I 又作為可塑劑，若使用由碳數百未達 7 之酵成分所 1 1 構成之己二酸酯時 f 塗膜之耐滲出性會降低 > 因此不令人 1 1 - 10 - 1 1 本紙掁尺度適用中國國家標準（CNS ) A4規格（210 κ 297公釐）經濟部中央標隼局員工消費合作社印製 A7 B7_____ 五、發明説明（/ ) 滿意。又，若使用碳數1 0K上之醇成分所構成之肽酸醋時，塑性溶膠之粘度會高，塗装性會降低*因此不令人滿意。又*於本發明方法中，可在塑性溶膠中配合習知之顏料、安定劑、各種添加劑及稀釋劑。就稀釋劑•相對聚氯乙烯樹脂1 00重量份，亘為未達1 0重量份。若為1 0 重量份Μ上時，塗膜會產生膨起，並不令人滿意。根摟本發明，將具有上述特激之塑性溶膠介以接著劑 M3 0〜5 0 wm之厚度塗布於鋼板表面上之後，藉由實施1分鐘之加熱，在將該塗膜凝膠化後，立刻施K一定之壓花加工，製造覆聚氯乙烯鋼板。塑性溶膠之塗装，可K刃式被覆器、輥式被覆器、桿式被覆器之任何一種方法塗裝。本發明塑性溶膠之物性及覆聚氯乙烯鋼板之特性，係以下述方法評估。 (1 )塑性溶膠之粘度 Μ東京計器公司製之BM型粘度計，在輥子No . 4 ，轉數6rpm之條件下測定。 (2 )塗装性及塗膜外觀之評估將塑性溶膠Μ刃式被覆器塗布於鋼板上之後，Μ加熱使其凝膠化，Κ目視評估該壓花加工前之塗膜的表面。〔評估基準〕 -1 1 - 本纸張尺度適用中國國家標準（CNS ) Α4規格（2丨0Χ297公釐） I---------批衣----^--，玎------線 (請先聞讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 A7 ^_ _BZ_ 五、發明説明（β) ◦:良好（表面平滑，無條狀或粒狀等之缺陷） Δ :稍好（稍有條吠或粒狀等之缺陷） X :不良（有全面性之條狀或粒狀等之缺陷） (6 )耐滲出性將覆氮乙烯鋼板切斷成1 5 cmx 1 5 cm之尺寸後，在覆聚氮乙烯網板與覆聚氯乙烯鋼板之間夾著二向延伸聚酯薄膜，重叠數片，在由其上施加荷重1 Oks/cm 2之狀態下，在50C下歷經10日。其後，取出試驗板 ’將與塗膜面相接之聚酯薄膜面，以目視覼察之。 C評估基準〕〇 :良好（完全沒有滲出） △:稍好（稍有疲狀物質） X :不良（全面有液狀物質）實陁例 K下，茲以實施例說明本發明。實施例1〜8 在鍍敷量2 0 g/m2之經施K鉻酸塩處理的板厚0 • 5 mm的電鍍鋅钃板上，將習知壓克力/環氧澍脂系之接著劑，Μ乾燥皮膜厚5 wm塗布後，K氣流式電爐實施 -12- 本纸浪尺度適用中國國家標率（CMS ) Α4規格（2丨Ο X 297公釐） ---------扣衣------1T------0 (請先閱讀背面之注意事項再填寫本頁) 五、發明説明（ A7 B7 2 V ~ ο 1 1 表 2 布 K 塗爐上電面式表流之氣。却M板冷再鋼於後烯再而乙後’氯然膠聚 , 溶覆烤性作烘塑製之之，下合化 P 配膠 ο 示凝 3 所熱 2 中加 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐）五、發明説明（ A7 B7 經濟部中央橾準局員工消費合作杜印製 C0 Μ 啻施例卡1汜萏襯 SS 璃卸翊茚 ΦΙΝ α> Nl Si 蹄密 -· y PS »—k CJ1 CJ CJI G co O · CD = CO K S c· s · · N · . 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Description of the invention (1 i) 1 1 I r 1 Technical field J 1 1 1 The present invention is a kind of Kan with a high hardness of 9 and resistance to indentation and resistance to if 1 I properties (plasticizer) excellent 9 Simultaneous workability formula m good properties of PVC coated please first 1 the manufacturing method of 1 vinyl plate 0 reading back 1 side 1 of 1 Note | Italian IC m King technical matters 1 I then 1 I PVC-coated steel sheet has excellent processability, corrosion resistance, and filling resistance. 1 Features such as copybook and weatherability. 9 Suitable for building materials, electrical equipment, vehicles, vehicles, etc. Page 1 1 Furniture and other wide fields 0 1 1 coating The manufacturing method of PVC steel plate can be roughly It is divided into plastisol method and thin 1 1 film layer method. Plastisol method is to apply plastic dissolving adhesive layer composed of polyvinyl chloride resin, plasticizer An1 fixative &pigment; on the steel plate 1 1 coating *. After a fixed thickness, the coating film is gelled by heating and then embossed on the film 1 1 I to complete the production. 1 1 However, the PVC coated ΛΚΤΤ steel plate produced by the 9 K plastisol method-generally 1 The coating film on the line is made of soft and thin-film laminated PVC-coated m-plate 1 I Comparison 9 The CS degree of the coating film Λ Indentation resistance, resistance to drawout and other characteristics are not good Ο 1 I in plastisol In the method, a plastisol composed of polyvinylidene resin plasticizer, stabilizer 1 1, pigment thinner, etc. M 1 Roller coater, etc. 1 1 method is applied to the steel plate 9 so 9 it is necessary to apply the plastisol Sticky 9 Maintained in the range of 1 1 1 0 is Μ i-generally used relative to the atmosphere of vinyl resin 1 0 〇1 I parts by weight) with 4 〇6 0 parts by weight of plasticizer plastisol »and thin 1 1 | Comparing »The amount of plasticizer 3-in the coating is increased» The coating will become soft 〇1 1 1 1 The size of the paper is suitable ii ^^ ~ CNS M4 regulations 丨 Five, invention description () A7 B7 Central Standard of the Ministry of Economic Affairs The bureau employees' consumer cooperatives can print and press, teco purple,} powder or 4 methods here. This is a plate resistance, it is the face, sex shots and other physical and chemical side, the plate is made of steel, and the middle layer is a group photo No. 8 Hehard. 3 equal-element steel depolymerizes its olefinic film. But after the polymerization, 13 poly. The thermal ene is used for the research of the pressure coating with B traces, etc., the 89 series is added with 5, and the B is used as the system of chlorine pressure. The chlorine, Junji Poly-Resistance and Boundary make the solution at 39 grams and blatantly re-accumulate, after a period of comparison and comparison, the performance of the noodle industry is II pressure. Several times. There is a problem in the degree of prescription, plastic or 47 compound powder to the point one-in the point of making a hard surface, the 45 compound method is equivalent to how to make a film. Zhao Zhao Zhonghe Fang No. of the high system of the side of the coating and the viscous side of the father and the son of the polymerization of 7 kinds of methods are used to paint the marks of the special resistance to the special dissolution of the material 4 to make each tube A pair of adhesives are available for optional plasticization with pressed adhesive {、 Synthetic 7 series adhesives are not compatible and can be coated on the hard method ο Plastic Gram 6 is soluble, and the compatibility is improved, the sexual agent can be Case hot side 8 in the widow 7, the nature of valence plastic, and the surface plasticizer. In addition, the 5 cases are combined and compared with I. The plastic soft square is high in M, and the plastic limit of the table and other plastics has been reduced. 2 The ligand 4 phase is used for the problem and it is broken up to this point or it can be hard when the boundary is reached. 2 Zeng and Jun Pingzhi asked. Good fat low its industry film I mentioned the description of the public tree, for the establishment of the transformation tree Μ Yes, solidified ο, the general qualities of the general and more difficult than the subject will be good for ene Μ Order 5 The law of practice is hard, and you have the right to do it. The case is also changed to B, and the name of the square line is chlorinated on the top. The Juji membrane asks for the original flower-like plastic and open plastic features. At the end of the purple 6 and coated with alkene. ,-* -HI nnn I n I In _ _ II n HI T /. US, \ s ° (please read the precautions on the back before filling in this page) This paper is suitable for China National Standards (CNS) Λ4 specifications (210Χ 297mm) 322448 A7 Printed by the Ministry of Economic Affairs, Central Standard Falcon Bureau Employee Consumer Cooperative B7 V. Description of Invention ($) The production method of vinyl chloride steel sheet with excellent characteristics such as exudability and good economy. In addition, the present invention seeks to reduce the viscosity at a low plasticizer dose of plastisols. [Summary of the Invention] In response to such a problem, the present invention is characterized in that a conventional adhesive κ is applied to the surface of the screen after heating and baking. ， Coated with 20-50 parts by weight of polyvinyl chloride resin powder with a fixed particle size distribution and specific plasticizer to 100 parts by weight of polyvinyl chloride resin powder, and with conventional pigments and stabilizers Plastic dosage and low viscosity plastisol. Specifically, the method for producing polyvinyl chloride-coated steel sheet of the present invention is characterized in that the coating on the steel sheet is 95% by weight or more with a particle size of 0.5-5 ~ 4 wm, and 15-40% by weight is 0.5. ~ Less than 3wm, with peaks in 1 ~ 3wm * At the same time, 55 ~ 80% by weight is 3 ~ 4 0 «m, and 8 ~ 1 has two peaks of peak type polyvinyl chloride resin powder 100 parts by weight, as The plasticizer is blended with 5 to 25 parts by weight of a peptide acid ester composed of an alcohol component with a carbon number of 7 to 9 and 5 to 15 parts by weight of an adipate ester composed of an alcohol component with a carbon number of 8 to 10, and is mixed The amount is 20-40 parts by weight, and then it is a plastisol made with conventional pigments and stabilizers. Specifically, the manufacturing method of the PVC-coated steel sheet of the present invention * is characterized by: -5- This paper standard is applicable to China ’s national standard rate s) A4 specification (21〇Χ37mm) (Please read the precautions on the back first (Fill in this page) • Installed.-° Line A7 B7 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Invention Instructions (X) 1 i | Coated on steel plates with a relative particle size of 9 5 wt% or more for particle size 0 * 5 4 1 1 I 0 U m > and 1 5 4 0 weight% is 0 * 5 less than 3 U m in 1 I 1 3 U m has a peak 9 At the same time, 5 5 8 0 weight% is 3 4 Please read 1 1 first 1 0 U m »and 8 1 5 U m The two-peak type of polyvinyl chloride with a sharp peak Read back I side I Resin powder A 6 0 9 5 parts by weight and 90% by weight or more is the particle size 1 winter 1 1 Italian 1 I 〇6 0 U m and a PVC tree with a peak at 2 〇4 0 um and then 1 1 fat powder B 5 4 〇 parts by weight, and 1 〇0 relative to the total of A and B refill 1 Write a large portion of this book as a plasticizer and mix it with a sheet composed of an alcohol component with a carbon number of 7 to 9 1 1 ester 5 2 5 parts by weight and a yeast component with a carbon number of 8 to 1 0 1 adipic acid ester 5 1 5 parts by weight, compounding amount is 2 0 4 0 parts by weight 1 > plastisol obtained by blending conventional pigments and stabilizers 0 1 Order 1 [Best form for carrying out the invention] 1 1 In the present invention As a steel plate in the method, it is possible to use galvanizing, chromium plating, tin plating, m-plating aluminum plating, 1-lead lead plating, or gold-plated alloy 9 or cladding on the cold-drawn m-plate and 1 1 cold-drawn steel plate The plated m-plate or 1 I t is then plated on this metal-plated steel plate and subjected to chromic acid treatment, phosphoric acid treatment 1! Treatment and other electroforming treatments. Also 1 1 can choose not m steel plate, aluminum plate, etc. 0 1 I according to the method of the present invention ， For the adhesion of steel sheet and PVC coating film 9 1 1 I use M acrylic resin, polyester resin, urethane resin, epoxy resin 1 1 resin or acrylic resin as the main component Conventional adhesives 〇 After coating 1 1 on the surface of the stencil, 3 1 0 am, Μ 1 6 0 2 5 〇 for 1 minute 1 1 -6-1 1 The standard of this paper applies the Chinese National Standard (CNS) A4 specifications (2 丨 OX 29? Mm) A7 522U8 _B7____ Fifth, the description of the invention (order) After heating • Bake, and then apply plastisol. During the development of the present invention, a detailed test was conducted on the composition and properties of the coated plastisol and the characteristics of the obtained steel sheet. It was found that the hardness of the coating film of the PVC coated steel sheet manufactured by the general plastisol method , The characteristics of indentation resistance, bleed resistance, etc. are inferior to the film lamination method because of the difference in the amount of plasticity in the coating film. The film used in the film lamination method is generally manufactured by calendering. The plasticizer in the film and K can be mixed at an almost arbitrary ratio. In the application of PVC coated steel sheets * relative to PVC resin 1 00 parts by weight is 250 ~ 40 parts by weight. On the other hand, in the case of plastisol, it is necessary to coat the plastisol with a roll coater or the like to a certain thickness. Therefore, it is necessary to maintain the viscosity of the plastisol at Below a certain level, usually, 100 to 100 parts by weight of polyvinyl chloride wax is mixed with 40 to 60 parts by weight of a plasticizer. This difference in plastic dosage has a significant influence on the properties of the coating film. Therefore, in order to establish a low-plasticity low-viscosity plastisol in the present invention, focusing on the particle size distribution of the polyvinyl chloride resin powder and the selection of plasticizers, the results of repeated studies have found that the coating film has hardness, indentation resistance, and bleed resistance. Plastic sol with excellent properties, such as good performance and economical efficiency. The polyvinyl chloride resin powder A used in the plastisol of the present invention is a powder of Shu made with an average degree of polymerization of 500 to 2500 manufactured by the M emulsion polymer method or the micro-float method. In addition, it can also be copolymerized with ethylene vinyl monomer, vinyl acetate, vinyl acetate, vinyl propionate, alkyl vinyl ether, vinylidene chloride, diethyl fumarate, or methacrylate. The size of the paper produced is applicable to the Chinese National Standard (CNS) Α4 specification (2ΙΟΧ 297 male acid) — IIIIII ^ line (please read the precautions on the back before filling out this page). The Ministry of Economic Affairs Central Bureau of Standards Employees Consumer Cooperative Printed Economy A7 B7 is printed by the Employee Consumer Cooperative of the Central Standard Falcon Bureau. V. Description of the invention (k) Atmospheric vinyl resin powder. Generally speaking, when the PVC coated steel sheet is manufactured by the M plastisol method, the average particle diameter of 1 to 2 shown in Fig. 1 and a sharp peak particle size distribution are used. It is M. In order to achieve a low viscosity with a low plasticizer dose, a keen study on the particle size of the polyvinyl chloride resin powder found that in order to obtain a low plasticizer with a low viscosity plastic sol, it is necessary to increase the filling of the polyvinyl chloride resin in the plasticizer Density * For this reason, it is preferable to have a particle size distribution of the two-spike type shown as an example in circle 2. The particle size of the polyvinyl chloride resin powder A of the present invention preferably has 95% by weight or more with a particle size of 0.5-5 ~ 40 «Γη, and 15-5-40% by weight is 0.5-5 ~ 3 / zm less than , With a peak at 1 ~ 3 «m, meanwhile, 55 ~ 80% by weight is 3 ~ 40um, and at 8 ~ 1 5« m, it has the particle size of the second peak type. When the powder on the particle size 40 urriM exceeds 5% by weight, the finished state of the plastisol-coated surface is unsatisfactory and unsatisfactory. When the powder with a particle size of 0.5 ~ 3wm is less than 15% by weight, and the powder with a particle size of 3 ~ 40 / zrTi exceeds 80% by weight, the gelation performance of the plastisol will be reduced, so that the strength of the coating film will be reduced, and Unsatisfactory. In addition, when the powder with a particle size of 0.5 to 3 um is 40% by weight or more, and the powder with a particle size of 3 to 40 um is less than 55% by weight, the viscosity of the plastisol will increase, and the coating property will be unsatisfactory. Furthermore, as a result of research on the lowering of the viscosity of plastisol with a plasticizing dose of 20 to 40 parts by weight, it was found that if it is combined with coarse-grained polyvinyl chloride resin powder B as shown in FIG. 3 as an example, the viscosity can be further reduced to make the coating -8 * This paper scale is applicable to China National Standard (CNS) Λ4 specification (210X 297mm) I.. Binding line (please read the precautions on the back before filling in this page) A7 B7 Employee Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs Printed --- V. Invention Obtained (7) 1 1 I The property is improved-0 1 1 1 The polyvinyl chloride resin powder B used in the plastisol of the present invention is made by suspension polymerization method 1 | The average degree of polymerization is 5 0 〇2 0 〇0 Please read first 1 I Resin powder 0 and 9 can use ethylene vinyl monomer and ethylene, propylene, ethyl acetate back reading 1 1 side I vinyl vinyl propionate, burned base Vinyl ether, vinylidene fluoride fumaric acid Note 1 1 Diethyl or methylpropyl Polyvinyl chloride-based resin powder obtained by copolymerization of enoate esters 1 I 1 I 〇 Fill 1 6 0% of this package of vinyl resin powder B »preferably 9 with a particle size of 1 〇 Page 1 | U m 1 with a peak at 2 0 4 〇U m 0 and t better still is 9 grains 1 1 diameter 1 5 4 〇U m is more than 70% by weight 0 when the particle size is less than 1 1 1 〇U m powder If it exceeds 10% by weight, the viscosity of the plastisol will be reduced. 1 I. The effect will be unsatisfactory. When the particle size is 60 U m > λ, the upper one will exceed 60% by weight. The finished state will be inferior 1 1 I is not satisfactory 0 1 1 The ratio of the polyvinyl chloride resins A and B in the plastisol of the present invention is to assume that the total amount of the first-line polyvinyl chloride resins A and B is 1 〇0 parts by weight The better place than 1 I is PVC Fat A is 6 〇9 5 parts by weight of polyethylene 1 1 I Resin B 5 is 5 4 〇 parts by weight 0 In the case that the polyvinyl resin A is less than 6 0 1 1 parts by weight 9 If the polyethylene resin B exceeds 4 〇 parts by weight of gel 1 1 The gel strength after gelation will be reduced and therefore unsatisfactory 0 Also in poly atmosphere 1 | vinyl resin A in the case of more than 9 5 parts by weight f If the poly vinyl resin 1 IB is not reached 5 parts by weight > The effect of blending with Polyvinyl Resin B is not seen 9 1 1 and therefore unsatisfactory 〇- 9- 1 1 1 1 The standard rate of the paper (CNS) (21GX297 male) Z22U8 A7 B7 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention () 1 1 Secondly in the method of the present invention ♦ The compounding of plasticizer in the plastisol 1 1 I The result of the study found > Μ Known ester benzene Trimellitic acid ester Λ adipic acid 1 1 1 etc. »Available for each For primary plasticizers such as aliphatic esters and various phosphate esters, please first 1 1 or secondary plasticizer 9 but the stability of the plastisol viscosity and viscosity over time Λ Κ] Read back 1 | Surface I Gelation performance and coating film Hardness \ Indentation resistance, workability > Exudation resistance, etc. Note 1 I meaning 1 I characteristics of the surface * It is preferably a peptide acid consisting of an alcohol component with carbon number 7 9 1 I 1 I ester and The combination of adipic acid esters composed of an alcohol component with a carbon number of 8 1 0 0 Fill in this book 1 The final weight of the blending ratio 1 Relative to the polyethylene resin powder 1 〇 0 copies Page 1 I »As a plasticizer t should be mixed by The peptide 1 1 consisting of the alcohol component with a carbon number of 7 9 5 2 5 parts by weight and the 1 1 adipate 5 1 5 consisting of the alcohol component with a carbon number of 8 1 0 are 2 〇4 〇 Parts by weight 〇1 Order 1 I When the peptide acid ester composed of an alcohol component with a carbon number of 7 9 is less than 5 parts by weight, when the adipic acid 1 1 composed of an enzyme component with a carbon number of 8 1 0 is 2 5 parts by weight M The bleed resistance of the coating film will be reduced, so it is not 1 1 satisfactory 0 and when the total amount of the plasticizer is 4 parts by weight Κ > 1 the hardness of the thread coating film will be reduced > the indentation resistance will also be reduced Unsatisfactory 〇1 I as a plastic m > If using 1 I titanate composed of an alcohol component with carbon number S less than 7 f, the time stability of the viscosity of the plastisol will decrease by 9 and the coating film 1 1 The hardness will become soft t, so it is not satisfactory.) If you use a peptide ester composed of an alcohol component with a carbon number of 1 1 1 0 or more * The viscosity of the plastisol will increase by 1 1 »Paintability will decrease» Therefore Unsatisfactory 〇1 I as a plasticizer, if When using adipic acid esters composed of enzymes with a carbon content of less than 7 1 1 f The bleed resistance of the coating film will decrease > therefore it is not acceptable 1 1-10-1 1 (CNS) A4 specification (210 κ 297 mm) A7 B7_____ printed by the Employee Consumer Cooperative of the Central Standard Falcon Bureau of the Ministry of Economic Affairs V. Invention description (/) Satisfied. In addition, if peptide acid vinegar composed of an alcohol component having a carbon number of 10K is used, the viscosity of the plastisol will be high, and the paintability will be reduced *, which is not satisfactory. In addition, in the method of the present invention, conventional pigments, stabilizers, various additives and diluents can be added to the plastisol. The diluent is less than 10 parts by weight relative to 100 parts by weight of polyvinyl chloride resin. If it is 10 parts by weight M, the coating film will swell, which is not satisfactory. Based on the present invention, after applying the above-mentioned plastisol with the thickness of the adhesive M3 0 ~ 50 wm on the surface of the steel plate, by heating for 1 minute, after gelling the coating film, Immediately apply a certain embossing process to manufacture PVC-coated steel plates. The coating of plastisol can be applied by any method of K-blade coater, roll coater and rod coater. The physical properties of the plastisol of the present invention and the characteristics of the PVC-coated steel sheet were evaluated by the following methods. (1) Viscosity of plastisol BM type viscometer manufactured by Tokyo Keiki Co., Ltd. was measured under the conditions of roller No. 4 and rotation speed 6 rpm. (2) Evaluation of paintability and coating film appearance After applying a plastisol M-blade coater to a steel plate, M was heated to gel it, and K was visually evaluated for the surface of the coating film before embossing. [Evaluation Criteria] -1 1-This paper scale is applicable to China National Standard (CNS) Α4 specification (2 丨 0Χ297mm) I --------- approved clothing ---- ^-, 玎- ----- Line (please read the precautions on the back and then fill out this page) A7 printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ^ _ _BZ_ V. Description of invention (β) ◦: Good (smooth surface, no strips Shape or granular defects) Δ: slightly better (slight bark or granular defects) X: poor (with comprehensive strip or granular defects) (6) The resistance to exudation will be covered with nitrogen After the vinyl steel plate is cut to a size of 15 cmx 15 cm, a two-way stretched polyester film is sandwiched between the polyvinyl-coated vinyl mesh plate and the polyvinyl chloride-coated steel plate, several pieces are overlapped, and a load is applied thereon 1 In the state of Oks / cm 2, it took 10 days at 50C. After that, the test board was taken out and the surface of the polyester film that was in contact with the coating film surface was visually inspected. Evaluation criteria of C] ○: Good (no bleed at all) △: Slightly good (slightly fatigued substance) X: Bad (liquid substance all over) Practical Example K Below, the present invention will be described with examples. Examples 1 to 8 On a plated plate with a plating amount of 20 g / m2 treated with K chromate, a plate thickness of 0 • 5 mm, an electro-galvanized strontium plate, followed by the conventional acrylic / epoxy resin series After the coating with Μ dry film thickness of 5 wm is applied, the K airflow electric furnace is implemented -12- This paper wave scale is applicable to the Chinese national standard rate (CMS) Α4 specification (2 丨 Ο X 297mm) -------- -Clothing ------ 1T ------ 0 (Please read the precautions on the back before filling in this page) V. Description of the invention (A7 B7 2 V ~ ο 1 1 Table 2 Cloth K coating furnace Electric surface-type surface flow. However, the M-plate is cold and then steeled, and then chlorinated, then coated and baked for bake molding. 2 China Canada (please read the precautions on the back before filling in this page) The paper standard printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) V. Description of invention ( A7 B7 The Ministry of Economic Affairs, Central Bureau of Prefectural Affairs Bureau, consumer cooperation, du printing C0 Μ 啻施例卡 1 搏萏 lined SS glass unloading indene ΦΙΝ α > Nl Si hoof dense-y y PS »—k CJ1 CJ CJI G co O CD = CO K S c · s · · N ·. KA S 0¾ CD O 〇Mam cs Touch Qing nmn Qing Lun translation mz »Shubin® Yi Yi Mu She ΦΙΝ 〇i > WS hanging debris ^ r PS C6 CO ΟΙ > »^ ^ ^; A 4 ^ > c〇 < = 5 · O ^ 3 DO 3 · * y ·· DC H— ^ CO 〇〇go [tmli O Urn» 卿 iimH Translated [Bfci 卿卡萏筠 s Musk mm reed Φ (Ν Π > Wi Xie Lishang-.-· S -r P- S? H- * 〇CJ CJ1 3 »H C3 3 ^ CO o-〇RP 二 3 CJ \ 3 ·· tt— ^ ^ OO cn CD 3 cn lljnll o limtl Qing Until Qing _ Guo_ = _ PVC resin plastisol compound composition 1_ .. ________. 1. …… G [NS 羿 S hun ghs 藤写众 ew ® Γ? 11 na t ^ g H ®) lffl g 7 gr'r gtHHgrtN Emm 〇〇nirr ® 〇〇 · «—» »t * ri t— * f— * CJ1 Q ◦ limit _ hmll 卿卿卿 _ _ igg s Yishun sPings Yi? t " It Γ? liE »Un» l ^ N- N · ΪΝΪ Si _ 1 ^ 1 1® »5 5 ς〇ς〇CJ1 CJTt C3 〇l limti liwii ΙΐΜ Ιιτη» pm [ΠΠΠ tnsn ιποη _ _ _ _ m 泽耷泽 sws yi g 丨 1Written by Bo Shishi ί t ΗΛ1- j I 4¾ do ro pil KgSs 〇〇Π3ΓΓ 〇〇5; 〇, limu liirm Qing Qing _ _ £ 1 stare Ba-Nn system 2 parts by weight Ba-Zn system 2 parts by weight J organotin system 3 parts by weight m titanium oxide 14 parts by weight oxidized olive 0.3 parts by weight carbon black 1.5 parts by weight carbon black 1.5 parts by weight Zhejiang One --------- approved clothing ------ ΪΤ ------. ^ (Please read the precautions on the back before filling out this page) This paper size is applicable to the Chinese National Standard (CNS) A4 size (210X 297 mm) B7 V. Description of invention ("Qiao") Printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 0Ί minus card 1 汇緇淇书汜 S 翊 S cut glass 麴銷保闼麴忊向 φίΝ 翔Indene Φ (Ν Φ W 鉼無醫繩 W 峢島駋商-Nian-g Ξ Sr PS I— * ζ * 1 CD i— * 0〇C * 3 cn > OS cn 05 ^ (gc = > 〇9 ^ oj 0 ί: ° R 3 H- * ^ 3 oo 5 · CO CO 00 0 0¾ ZJ \ 3 C3 UMt < 0 Itnfli Umji Hm | i Pm Innii 卿卿卿 _ 卿 »m _ = _ 卡 | 汜 mm 芷保握 Unlined indene Φ1Ν n > MS hang up-.-· Trace- ♦ Γ P m ►— 0〇oj cn 5 »· * 〇,? = Μ G s CO CD · C = 5 = e = s N g · · ^ · · CO t- * K 〇〇〇〇5 0 Μπηι ο iitmt Dfflu imm pn Μη pn s Bao Wei Wei Brewing ΦΙΝ α > Ν8 Gown Lishang-. Trace-r γ p S Η— · Co (CXI |> aa CO o · Qin 3 k H- »·· 3 ISD QO ·· y-. CD CS3 > — * ^ [»Aa 〇C3 sa qing_ c = 3 she translated itnm just _! Qingxiang m (N 33a mm 璲罗 Π > ΪΪΛ * cm S (NS game S game g U s circle write Wei Ea ^ Γ? [1 na i 1 ^ [1 Sitfflf ^ g, gcu Li 1S _. Chu circle 〇〇〇3ίΓ w os CO ^ H- * Η— * Η- »cn c = jc = > litrrfi Urnii iimli 卿卿卿 _ _ _ s cu s Yi 5 11¾¾, Miyu U ® itffl ^ N m chum thin eh— * O t— »Cs3 〇◦ Mirffl Hnrti Qingqing _ _ S0is 萍 S Yig US 薙写发-iisii ^ Li s Ϊ ^ 9 ^ S rr | m chug 鬵娌 mr 〇〇Sfr co 〇〇 < NM «· > —» PO cn 〇cn limit ltw »i linjn 卿卿卿 _ _ _ £ 1 眯 H? &Gt; -〇 limit ΡΒι _ 03 P t C ^ 3 = 3 DO Itwft _ ns ZjJ UlTTlI (non _ Xiemm 宁羿 P C5 ^ PO ◦ · CS3 η— * ►— * hmll Htm < Hmti ΙΠΙΙΠ 卿卿论 »wj 5 ^ ^ ^ m fine κ- C7I Hnni tn & nwmmm fine miscellaneous left P = > 羿 C3 CO t— * 1— »Cs3 limit Itm» (πηιι 卿卿卿 _ _ _ 杂 (please first Read the precautions on the back and fill in this page) This paper standard is applicable to the Chinese National Standard (CNS) A4 (210X297 mm) printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs fy 〇Ο Λ Λ ο Α7 Β7 V. Description of the invention (I heart) 0D Example card 1 汩 Emirates Underline Book 汏萏翊 S tired 鏡郷 S Bao mm Xiang Xiang ΦίΝ 翊向 Φ1Ν n > W ^ 15 π {> Μ 刼谣潮-·-· Banqi- · -· ^-· Zhao Er licking- · p ps) 03 t— C71 CO CJ1 >-CD 3 0¾ ^ 1 1 C3 G Ο 5 CO 1 = 3 r ^-53 r 3 ^ 5 〇3 said . · · 45 »CO C75 O CO CJ1 cn 3 G3 llnll CJ1 Uwrti h llwH Pel HthII Shi Qingyi Lunqing n_ Toze ^ s $ book) BS Xiangka i 汜 S 翊保闼閼儼 Is mm mm comparison Φ (Ν 翊 indene (Να > _ 汫丽昤 M ^ Ml hemp- *-· trace'man- * · * class- ^ S; Sr = fPS > — * f) C3 Η- 〇0 (CJ1 >-k (•, Office) Ο 3 CJ1 CD ^ CD < Ο C = > C3 S f CjJ 〇R ^-g RS Η_ »· · g ·· Γ〇〇〇 ·· Γ» C3 CO ς 〇csd ν iiafli 〇〇cn α Article _ Q Ιιτπ »Urn» jio * ii P5 · ίππίι nursery t〇nn EBfU 論卿 mm e = You polychloroethylene Vinyl resin plastisol composition s [U s 羿 s Deng gus Tibetan writing strong na ^ Γ? 1 1 na i 1 i [i 5: fgg cu Scuib 1 s 〇3 Seoul Island 〇〇 > «—« «οι ◦ Ο Ιιτπ »iimii ίllτπΐι Qing Qing • Na _ _ _ Φ Ze Φ g π 写薙 G3t ^ CT l ^ ΗΦ I j ΗΦ DO SiSfflSiN ® Chumrr ► Q〇CD ^ — / t— * CO O CD linrli limn tnon [ Π3Π _ m L ° 1 With 1 Ba-Zn series 2 parts by weight 1! | 1 1! Ί Ba-Zn series 2 parts by weight ί! Crmmmm Titanium oxide 14 parts by weight upsetting oxide 0.3 parts by weight carbon black 1.5 parts by weight 3 (Please read the precautions on the back before filling in this page) This paper scale is applicable to China National Standard (CNS) Α4 specifications (210 X 297 mm) A7 B7 printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (L <) Table 4 Viscosity (CPS) of plastisols in buttercups, film thickness (ul), coating properties and appearance of coating films, coating film properties, hardness of coating films, low temperature impact processability, indentation resistance, bleed resistance 1 8,500 80 〇96 〇〇〇2 7,000 100 〇95 〇〇〇3 6,500 150 〇93 〇〇〇4 6,500 200 〇93 〇〇〇5 6,000 150 〇95 〇〇〇6 4,300 200 〇93 〇〇〇7 4,000 150 〇95 〇〇〇8 5,800 150 〇93 〇〇〇-17-. --------- ^- ----- ir ------ # (Please read the precautions on the back first and then fill out this page) This paper scale is applicable to the Chinese National Standard (CNS) 84 specifications (2 丨 Ο X 297mm) Economy Printed by the Ministry of Standards and Labor ’s Consumer Cooperative of the Ministry of Standards A7 B7 V. Description of the invention (4,) Comparative Examples 1 to 1 1 Plated with a plating thickness of 2 0 s / m2 and treated with chromium acid treatment 0 · 5mm On the zinc steel plate, apply the conventional acrylic / epoxy resin adhesive * K dry film thickness 5 um, then bake at 230C in a gas flow electric furnace, and then coat the cooled surface in Table 5 The plastisol shown is compounded, and then the K-flow electric furnace is gelled with 2 1 Ot: heating * to produce a PVC-coated steel plate. The test results of the methods of Comparative Examples 1 to 7 are shown in Table 8. Comparative Example 1 is based on the use of 100 parts by weight of a peak-type polyvinyl chloride resin powder and a plasticizer amount of 30 parts by weight. The viscosity of the obtained plastisol is extremely high and cannot be applied. Comparative Example 2 is based on the use of a peak-type polyvinyl chloride resin powder at 100 parts by weight * with a plasticizer dose of 50 parts by weight. The obtained plastisol has a low viscosity and good paintability, but the coating film hardness is low. Poor resistance to indentation and bleeding. In Comparative Example 3, when using a two-spike type polyvinyl chloride resin powder with a particle size of 0.5 to 3wm, the compounding amount of the plasticizer is 30 parts by weight, the viscosity of the plastisol is high, and the paintability and resistance are high. Poor indentation 0 Comparative example 4 is a case where a two-peak type PVC powder with a particle size of 3 to 4 0 wm ratio of 90% is used. Although the viscosity of the plastisol is low, the low temperature impact processability and pressure resistance Poor traceability. -1 8-This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (2 丨 0 X 29? Mm) Binding line (please read the precautions on the back before filling this page) A7 S22448 B7 5. Description of invention ( ) In comparison, when 5 series uses a particle size of 0 * 5 ~ 3 wm, the ratio is 20% by weight, and the peak position is 0 · 8 «m of the second peak type of polyvinyl chloride resin powder, the viscosity of the plastisol is high , Poor paintability and indentation resistance. In Comparative Example 6, when the ratio of the particle size of 3 to 40 wm is 80% by weight and the peak position is 1 8 «type 2 polyethylene resin powder, the viscosity of the plastisol is low and the coating property is good, but the temperature is low The impact processability is not good. In Comparative Example 7, when a peak type polyvinyl chloride resin powder with a particle size of 3 to 4 0 um at a ratio of 80% by weight and a peak position as small as 5 wm is used, the viscosity of the plastisol is high, and the coating resistance and bleeding resistance are high. Not good. Comparative Example 8 is a plasticizer DBP (diisobutyl peptidate) and DIBA (diisobutyl adipate) with a carbon number of 4 as compared to the di-peak type polyvinyl chloride resin powder A of the present invention, and the carbon number of the alcohol component is 4, respectively. In the case of a total of 3 parts by weight, the viscosity of the plastisol is low and the paintability is excellent, but the hardness of the coating film is low, and the indentation resistance and bleeding resistance are not good. Comparative example 9 is the di-peak type polyvinyl chloride resin powder A of the present invention. * Plasticizers DI DP (diisodecyl peptidate) and DIDA (diisobutyl adipate) with a carbon number of 10 as the alcohol component are blended. ) In the case of a total of 30 parts by weight, the viscosity of the plastisol is high * The coating properties are poor and the indentation resistance is poor ° Comparative Example 1 0 50 parts by weight of the polystyrene urethane powder A of the two-peak type of the invention and the invention Polyethylene resin powder B5 ◦Heavy -1 9- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) Approved clothing line (please read the precautions on the back before filling in this education) Central Ministry of Economic Affairs A7 B7 of the Bureau of Standards and Staff ’s consumer cooperation. 5. Description of the invention (more) In the case of a large amount, the viscosity of the obtained plastisol is low. * Poor paintability. Low temperature impact processability and indentation resistance. Comparative Example 11 is based on the two-peak type polyvinyl chloride resin powder A of the present invention. In the case of blending coarse-grained polyvinyl chloride resin powder with a particle size of 80 to 120wM of 90% by weight and a peak position of 100 um, The obtained plastisol has a low viscosity, poor paintability, poor low temperature impact processability and indentation resistance. Approval of clothing line (please read the precautions on the back before filling in this page) Printed by Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs -20- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm)

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1.55S 1.5»1Φ a¾ 本紙伕尺度適用中國國家標準（CNS ) A4規格（2!〇κ 297公釐）經濟部中央標準局員工消費合作社印製 322448 A7 B7 五、發明説明（>c;) 00 cn η 卡t汜兹翔芷葆孩麯翊窃忒CN n> Wi 3f 15 商-， -* ^ -r f=S cn CO C7T >· V Η CD 3 CD · CD t h = 3 oj 5 ·· · · Cs5 i—* ^ CO O <=3 S Q Hmtt Q hrrm !S〇n hrmi P〇她卿书汜 mm 芷葆 mm 猓茚 Φ (N a> w 掛謠商-· -*班 -r p舔 t—* C71 C-〇 Ol H C3 5 ^ CO <=>·<=> = CJi^ 3 ^ H 二— 5 09 O C=) <0 OM O UflU P*« Itmti 卿論國 _罾》卡1凇 3翊芷葆 ®卸猓筘 y>cs Π> W 谢諉爾-* 迹 -r ps »—* 〇i co cn W l l G 3 ^ CO 〇二^ 〇〇 ^ s 3 ·· n · · CO ►—· S CO CS C3 O limti CD Dwii 卿 mnn 卿論卿 Wb^Wb s截 mm 猓筘玫(N a> WS 拼謠爾-* -·迹 -· P P w —0〇 Cs? cn i l C3 3 私 CO ° ^ ° co ^ 3 K ® ^ H- 5 OO G C3 ◦ [inn 〇 Uajti卿咖卿Intn卿 _ m m [N 迹 ass OT 瞪 H? m 翮 α> W ρπ a SCUS 浑 5 u宅蔵 5織ίά 1丨 8¾¾ i^mrn 薤楚娌 e 1—» CO O CD lirnli Itml» toon μ«Π _ 脚S m 洚 scus 萍 Ξ U写葳 -iii 薤馋® 娌 s ι—» G3 (—» Cs3 ^ CD C3 limli lijnll tcsn uion w m s cu S PP 5 U 写澴 1綠ii Sm g!(N m 's® 楚 s CD H-* hSfc C=> <=> Hffllt _ tssn 卿 _ Wa SQJS^ 5 U写菝 -s® ϋ Ι^|(Ν 菀浬® 薄 S h—» CD t—* CS3 ^ CS CS limli Inrtii toon μ〇3) _ _ m m 03 &3 1 OJ 象 DO Umli 卿 m ca W 1 OJ 3 矽 CO limti pn _ 03 &9 1 OJ CO _imti 卿昧 GO Ο 1 04 3 妒 ΙΝ3 limn 卿 _ 钳 w m 菊 lot ；fna 1—* CSi m _ 難 aia ；|R3 >—» C71 Hmti 卿 Mi 薤 ^1171 ；fta 1—* crt lunll pm » ；]12! ►—* cn limti 师 _ 雜 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐）五、發明説明（) A7 B7 經濟部中央樣隼局員工消費合作杜印製 Η-* ί1 H-* 〇 CD 實施例卡ι>β 萏翔卡ί汜 mm s葆菡激is葆闼卸襯筘 Φ㈧翊商 Φ1Ν a>w 3H；n>Pi 奇惑闽^ -· -·聲 -s gs-r °m OO CD ) K- cr\ CO C7T gR / 厶M 5 CS3 C3 S CO R S a 3 3 C>J 3 ·· OO CD CO ^ OO C3 00 <=> Q C3 5 CD tUffit CD hmH Ιίπτίΐ lim» llnffl ΡΒΠ hm 輝pm卿卿luin卿 mmm 卡翊卡酋翊芷葆葙卸芷葆 mm 縐茚ΦίΝ翔筘攻1Ν 卟W汫謠卟Ml 刼諮 W 班爾-- -· SS Γ Λ tJCU i_~* SB 一 S? 〇i OT，· · . err t—* ^ c〇 η-* cn co m 3» CD 3 CJ1 05 ^ C < C3 G O 3 ^ CO 〇 R 〇二 $ 公 3 C〇 K 3 ·· 3 ·· C〇 ^* ·· JSk CJ1 CJ1 a 0¾ G3 cn lumi 〇 O llM CD 卿!imn linm 卿 imjH 她卿卿她卿 5w mz» 书)b s葆闼卸锻向 Φ(Ν a>W 刼菡 j$i -· -* S£ -· r PS t—* CJ1 OJ W H O 3 ^ CO CO ^ 3 t· s ·· 〜·· fs〇一 3 OS 〇 C3 C3 UflUi 〇 Until P®» ΙίΜΙ W [η*. μ«Π wsSwd 聚氯乙烯樹脂 !_塑性爾配合組成_________ _____________________ — SCUS萍s萍s弈 s h s憩写薄宅薄 ·· η ® μ sa丨丨Ea脚通7基涵薤薤Sm» 浬楚营C3 CO cn cn cji cn _i 11½ limfi lunU 圃卿卿卿 _ _ 1Φ _ 耷 S Φ S scus 萍 s h写澴 lig 薤楚® 娌 a »—* O t—» Cs5 •w〇 <=5 IIWII IlffTll 卿卿 _ 邮 S Ws萍 Ξ II Ssa§[N m 楚 s O >—* CS3 ^*»·^ O C3 limit Until 卿 insn _ _ ㈢瞪 hi 有機錫系 2重量份 Ba-Zn系 2重量份 i i Ba-Zn系 2重量份坩 m m 氧化钛 10重量份氧化撖 0.8重量份碳黑 1.5重量份碳黑 1.5重量份溫 ---------1------ΐτ------α (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐）五、發明説明（分)1.55S 1.5 »1Φ a¾ The paper scale is applicable to the Chinese National Standard (CNS) A4 (2! 〇κ 297 mm) Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 322448 A7 B7 V. Description of the invention (>c;) 00 cn η card t 汜兹翔芷保 child's song stolen CN n > Wi 3f 15 quotient-,-* ^ -rf = S cn CO C7T > V Η CD 3 CD · CD th = 3 oj 5 · · Cs5 i— * ^ CO O < = 3 SQ Hmtt Q hrrm! S〇n hrmi P〇She Qing Shumei mm Zhi Zhi Bao mm 燓 indene Φ (N a > w Hang rumors-*-* 班- rp lickt— * C71 C-〇Ol H C3 5 ^ CO < = > · < = > = CJi ^ 3 ^ H II— 5 09 OC =) < 0 OM O UflU P * «Itmti Qing On the State _ 罾 "Card 1 凇 3 Yi Zhi Bao ® unloading reed y > cs Π > W Xie Huer-* trace-r ps» — * 〇i co cn W ll G 3 ^ CO 〇二 ^ 〇〇 ^ s 3 ·· n · · CO ►— · S CO CS C3 O limti CD Dwii 卿 mnn 卿论卿 Wb ^ Wb s cut-off mm 猓筘篘梅 (N a > WS 拼拼尔-*-· Trace- · PP w —0〇Cs? Cn il C3 3 Private CO ° ^ ° co ^ 3 K ® ^ H- 5 OO G C3 ◦ [inn 〇Uajti Qing Cafe Qing Intn Qing _ mm [N Trace ass OT 實 H? M 翮 α > W ρπ a SCUS muddy 5 u 蔔蔵 5woven ίά 1 丨 8¾¾ i ^ mrn 薤楚娌 e 1— »CO O CD lirnli Itml» toon μ «Π _ Feet S m 洚 scus 萍 Ξ U 写葳 -iii覤馋 ® 娌 s ι— »G3 (—» Cs3 ^ CD C3 limli lijnll tcsn uion wms cu S PP 5 U Write a green 1 Sm g! (N m 's® Chus CD H- * hSfc C = > < = > Hffllt _ tssn Qing_ Wa SQJS ^ 5 U 写菝 -s® ϋ Ι ^ | (Ν 菀浬 ® thin S h— »CD t— * CS3 ^ CS CS limli Inrtii toon μ〇3) _ _ mm 03 & 3 1 OJ elephant DO Umli Qing m ca W 1 OJ 3 silicon CO limti pn _ 03 & 9 1 OJ CO _imti Qing mei GO Ο 1 04 3 jealous ΙΝ3 limn Qing _ clamp wm chrysanthemum lot; fna 1— * CSi m _ difficult aia; | R3 > — »C71 Hmti Qing Mi 薤 ^ 1171; fta 1— * crt lunll pm»;] 12! ►— * cn limti division _ Miscellaneous (please read the notes on the back first Please fill in this page for details) This paper standard is applicable to the Chinese National Standard (CNS) A4 (210X 297mm). 5. Description of the invention () A7 B7 Duplicate printing by employees of the Central Sample Falcon Bureau of the Ministry of Economic Affairs H- * ί1 H- * 〇CD example card ι> β 萏翔卡 ί 汜 mm s 保菡激 is Bao Lin unloading reed Φ㈧翊 quotient Φ1Ν a > w 3H; n > Pi Qidumin ^-·-· sound-s gs-r ° m OO CD) K- cr \ CO C7T gR / 厶 M 5 CS3 C3 S CO RS a 3 3 C > J 3 · OO CD CO ^ OO C3 00 < = > Q C3 5 CD tUffit CD hmH Ιίπτίΐ lim »llnffl ΡΒΠ hm 辉 pm 卿卿 luin 卿 mmm Ka Yika Uygur葙释芷保 mm 谷銀 ind ΦίΝ 翔魘攻 1Ν 蓓 W 汫質醫 Ml 刼咨询 W Baner--· SS Γ Λ tJCU i_ ~ * SB 1S? 〇i OT, · err t— * ^ c〇η- * cn co m 3 »CD 3 CJ1 05 ^ C & C3 GO 3 ^ CO 〇R 〇 2 $ male 3 C〇K 3 · · 3 · · C〇 ^ * * · JSk CJ1 CJ1 a 0¾ G3 cn lumi 〇O llM CD Qing! Imn linm Qing imjH She Qing Qing she Qing 5w mz »Book) bs Bao Hun unloading forging direction Φ (Ν a > W 刼菡 j $ i-·-* S £-· r PS t— * CJ1 OJ WHO 3 ^ CO CO ^ 3 t · s · ~~ · fs〇一 3 OS 〇C3 C3 UflUi 〇Until P® »ΙίΜΙ W [η *. μ« Π wsSwd Polyvinyl chloride resin! _ Composition of plasticity _________ _____________________ — SCUS pings pings yishs rest write thin house thin η ® μ sa 丨丨 Ea Jiaotong 7 base culvert 薤薤 Sm »浬Chuying C3 CO cn cn cji cn _i 11½ limfi lunU Pu Qingqingqing _ _ 1Φ _ 耷 S Φ S scus pingsh write 澴 lig 薤楚 ® 娌 a »— * O t—» Cs5 • w〇 < = 5 IIWII IlffTll Qing Qing _ Post S Ws 萍 Ξ II Ssa § [N m Chu Chu O > — * CS3 ^ * »· ^ O C3 limit Until Qing insn _ _ ㈢資 hi organic tin system 2 parts by weight Ba-Zn system 2 parts by weight ii Ba-Zn series 2 parts by weight crucible titanium oxide 10 parts by weight oxide 0.8 parts by weight carbon black 1.5 parts by weight carbon black 1.5 parts by weight temperature --------- 1 ------ Ιτ ------ α (Please read the precautions on the back before filling out this page) This paper size is applicable to the Chinese National Standard (CNS) Α4 specifications (210 X 297 mm) V. Description of the invention (minutes)

A B 經濟部中央標準局員工消費合作社印製表8 t酬之粘度 (CPS) mm iun) wmsi 賴之離之麵性耐廳性賺出性 1 10M社一 X mmm — — — 一 2 8,000 200 〇 80 〇 X X 3 37,000 150 Δ 94 〇 Δ 〇 4 5,200 150 〇 94 X △ 〇 5 48,000 150 X 94 〇 X 〇 6 4,600 150 〇 94 X 〇〇 7 43,000 150 Δ 94 〇 Δ 〇 -24- 扣衣訂線 (請先閱讀背面之注意事項再填寫本頁) 本纸張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐）經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（>j) 表9 難獅之赌 (cps) mm (win) 雜之碰之毈低溫麵Π：性耐麵性酎凑出性 8 4,600 150 〇 88 〇 Δ X 9 20,000 200 Δ 94 〇 Δ 〇 10 3,600 150 X 94 X Δ 〇 11 3,000 200 X 94 X X 〇. -25- ---------私衣------ΐτ------^ (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) Α4規格（2丨ΟΧ 297公釐） ^^2ι1ύΒ Α7 ______ —_Β7五、發明説明（ >十）高儍為性膜特塗之造等製性地出價渗廉耐且及率性效痕有壓可耐 >' } 法性。性方 Η 板用之加鋼利明擊烯可發衝乙之本溫氯上據低聚業根且覆產度的 C 硬異分徑粒之末粉脂樹烯乙氯聚之型類 Ε- W ] 尖明一說用單習簡係之 1 面圖圖圖布粉脂樹烯乙氯聚型類峰尖二之〇法 X 方例明一發之本圖據布根分係徑 2 粒圈的 A 末本例據一根之係圖 3 布圖分徑粒的 B 末粉脂樹烯乙氛聚粒粗之法方明 (請先閱讀背面之注意事項再填寫本頁) •裝. 、ar 線經濟部中央樣準局員工消費合作社印製本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）AB Ministry of Economic Affairs Central Standards Bureau employee consumer cooperatives printed tables 8 t pay viscosity (CPS) mm iun) wmsi Lai Zhili's face resistance tolerance earning ability 1 10M company one X mmm — — one 2 8,000 200 〇 80 〇XX 3 37,000 150 Δ 94 〇Δ 〇4 5,200 150 〇94 X △ 〇5 48,000 150 X 94 〇X 〇6 4,600 150 〇94 X 〇7 43,000 150 Δ 94 〇Δ 〇-24- buckle (Please read the precautions on the back before filling out this page) The paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) A7 B7 printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of invention ( > j) Table 9 Difficult lion gamble (cps) mm (win) Miscellaneous hits low temperature surface Π: Sexual resistance and surface resistance 8 4,600 150 〇88 〇Δ X 9 20,000 200 Δ 94 〇Δ 〇 10 3,600 150 X 94 X Δ 〇11 3,000 200 X 94 XX 〇. -25- --------- private clothing ------ lτ ------ ^ (Please read the back of the first (Notes and then fill out this page) This paper standard is applicable to China National Standard (CNS) Α4 specification (2 丨 ΟΧ 297mm) ^^ 2ι1ύΒ Α7 ______ —_ 7 V. invention is described (> ten) is a special coating silly high film build like manner made an inexpensive price resistance and bleeding effect and whims marks pressurized resistant > '} of the method. The chlorinated chlorinated steel powder used in the production of chlorinated steel can be used for the production of chlorinated vinyl chloride. It is based on the oligomerization industry and the coverage is C. The hard powder with different diameters and the size of the powdered resin resin is chloroform type E- W] Jian Mingyi said to use the 1-face diagram of the single-practice simple system. The figure is a powdered resin resin. Ethyl chloride type peak-like two-point method X. The example of this picture is according to the root of the cloth. The diameter is 2 grains. Circle A at the end of this example according to a series of Figure 3 layout of the particle size of the powder B at the end of the powder resin resin ethoxylated coarse particles (please read the precautions on the back before filling this page) • Install. , Ar line The Ministry of Economic Affairs Central Prototype Bureau staff consumer cooperatives printed this paper standard is applicable to the Chinese National Standard (CNS) A4 specifications (210X297 mm)

Claims

A8 B8 C8 D8 Printed by the Central Business Bureau of the Ministry of Economic Affairs, Labor-only Consumer Cooperatives 6. Patent application scope 1 1 1 1 * A method of manufacturing a high-hardness film-coated polyethylene steel sheet 9 1 1 1 The special features are: 1 1 Please 1 1 Cover the steel plate with a relative size of 9 5 wt% or more for particle size 0 • 5 4 Read 1 1 〇U ΧΠ 1 and 1 5 4 0 wt% is 0. 5 Not up to 3 U m »Reading back 1 1 The surface I 1 3 U m has a peak f and f 5 5 8 0 wt% is 3 4 Note 1 I means I 0 U m > and 8 1 5 U m has a peak two peak type polyvinyl chloride matters 1 I then 1 | Resin powder 1 〇0 parts by weight% as a plasticizer blended with carbon number g 7 9 fill in the peptide acid ester 5 5 5 parts by weight and carbon hundreds 8 1 pages 1 I 〇 alcohol Adipate composed of ingredients 5 1 5 The amount of m in parts by weight is 1 1 1 to 2 0 4 0 parts by weight and is further compounded with a conventional pigment stabilizer to form a plastisol of I 1 0 1 2-a method for preparing a polyvinyl chloride-coated m plate with a high hardness film t 1 I is characterized by 1 1 1 coated on a steel plate with a relative particle size of 9 5 wt% K. The particle size is 〇5 4 1 1 0 U m and 1 5 4 0 wt% is 0 5 less than 3 U m in the 1 line 1 3 U m has a sharp peak and f 5 5 8 0 wt% is 3 4 1 1 0 U m 9 and 8 1 5 U m has a sharp peak two-spike type polyethylene II resin powder A 6 0 9 5 parts by weight and 9 0% by weight or more is the particle size of 1 1 1 0 6 0 U m and has a sharp peak at 2 0 4 0 U m 1 1 Fat powder B 5 4 0 parts by weight 9 and the total of A and B is 1 0 0 parts by weight 1 I As a plasticizer, a peptide composed of an alcohol component with a carbon number of 7 9 is added 1 | acid ester 5 2 5 parts by weight and carbon g 8 1 0 1 1 adipic acid ester composed of 5 1 5 adipic acid esters 5 1 5 parts by weight 9 with a total amount of 2 0 4 0 parts by weight 1 1 1 1 This paper wave is again suitable for China National Standards (CNS) ) A4 washing grid (210X297mm) S22448 VI. Patent application scope 0 Soluble plastic compounding agent Ding'an, Keyan Zhixi's combination is again --------- 1 -----: _ 丨ir ------ # (Please read the precautions on the back before filling out this page) The paper standard printed by the Consumer Labor Cooperative of the Central Standard Falcon Bureau of the Ministry of Economic Affairs is applicable to the Chinese National Standard (CNS) A4C grid (210X297 mm )