TW318168B - - Google Patents
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- TW318168B TW318168B TW085109876A TW85109876A TW318168B TW 318168 B TW318168 B TW 318168B TW 085109876 A TW085109876 A TW 085109876A TW 85109876 A TW85109876 A TW 85109876A TW 318168 B TW318168 B TW 318168B
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- Prior art keywords
- film
- layer
- thin
- resin
- allyl
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/18—Handling of layers or the laminate
- B32B38/1825—Handling of layers or the laminate characterised by the control or constructional features of devices for tensioning, stretching or registration
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/21—Anti-static
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/514—Oriented
- B32B2307/52—Oriented multi-axially
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
- B32B2307/7246—Water vapor barrier
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/746—Slipping, anti-blocking, low friction
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
- B32B2323/04—Polyethylene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
- B32B2323/10—Polypropylene
Landscapes
- Laminated Bodies (AREA)
- Wrappers (AREA)
Description
318168 A7 B7 經濟部中央櫺準局工消費合作社印製 五、發明説明( 3 ) 1 I 本 發 明 有 一 種 呈 現 改 良 之 m 氣 陣 壁 及 加 強 之 櫬 械 性 質 1 Γ 之 κ聚 丙 烯 為 主 之 多 層 薄 m 0 1 許 多 工 業 應 用 中 使 用 聚 合 物 薄 膜 0 一 特 別 重 要 之 應 用 /-—S 請 先 閱 讀 1 1 I 為 食品 包 装 工 業 0 食 品 包 裝 工 粟 中 所 使 用 之 薄 m 係 經 選 擇 1 1 I 及 /或設計Μ提供壤合之食品包裝(f〇 〇 d C on t a i η m e nt)所 背 面 之 1 1 1 需 之性 質 0 此 種 性 質 包 含 水 蒸 氣 陣 m 性 質 氧 氣 及 氣 體 陣 注 意 事 1 1 壁 性霣 Μ 及 風 味 與 芳 香 陣 壁 性 質 0 項 再 4 裝 I 聚 丙 烯 係 一 般 製 造 用 於 食 品 包 裝 工 業 之 薄 m 所 使 用 之 本 頁 聚 合物 0 在 多 曆 膜 之 例 子 中 聚 丙 烯 係 用 於 基 底 或 芯 層 之 1 1 1 聚 合物 0 通 常 將 聚 丙 烯 層 改 霣 9 獲 得 非 未 經 改 質 之 聚 丙 1 1 1 烯 所固 有 之 所 希 望 的 特 性 0 例 如 t 可 將 樹 脂 改 質 劑 、 添 加 1 · 1 訂 r 劑 及/或第二聚合物與聚丙烯播和。 改 變 聚 丙 烯 特 性 之 嘗 試 通 常 針 對 改 良 由 此 種 聚 合 物 所 1 1 形 成之 薄 膜 所 提 供 之 m 氣 陣 垩 0 對 於 此 巨 的 $ 已 知 將 聚 丙 1 | η 與樹 脂 改 霣 劑 摻 和 1 會 改 進 所 得 薄 膜 之 m 氣 陣 壁 性 霣 〇 U 一 般, 必 須 添 加 約 1 0 ^ 至 約20〆 之 樹 脂 改 % 劑 至 薄 m * 以 1 I 達 成所 希 望 之 水 蒸 氣 傳 送 之 減 低 0 1 I 然 而 f 樹 脂 改 霣 劑 以 前 述 範 _ 内 之 最 添 加 並 非 無 其 1 1 缺 點。 特 別 是 , 在 此 技 藝 中 典 型 使 用 之 用 董 範 _ 會 使 聚 1 丙 烯之 尺 寸 安 定 性 顯 著 減 底 0 此 黏 又 姐 礙 所 得 薄 膜 之 可 加 'V I X 性及 及 可 搡 作 性 導 致 增 加 η 造 成 本 及 /戎品 Ά 租 1, I 薄 _。 I 1 1 聚 合 物 薄 m 之 機 械 性 m 為 此 種 m m (特 §|J 1 對 如 香 1 1 I m 產品 包 裝 之 此 類 應 用 之 薄 謓 之 另 一 簠 要 特 性 〇 具 加 強 機 1 1 本紙張尺度適用中國國家橾準(CNS ) A4規格(210X297公釐) 9 1267 318168 A7 B7 經濟部中央揉準局貝工消费合作社印装 五、發明説明(4 ) 械性質之薄膜有肋於處理及包裝,因為此種薄禊更易於配 合典型之工菜機械之故。曾苜試藉著增加薄瞋之定向及/ 或添加添加劑來改菩聚合物薄膜之櫬械性質,如:櫬械方 向(MD)模數及横向方向(TD)棋數。然而.所坩加的定向通 常增加薄縝在製造期間破裂的可能性,而添加添加劑一般 提供襪械性質之加強有限,但舍負面影響其他薄膜性質, 如澄淸度。 因此,此技β中需要圼現改良濕氣陣壁性霣及加強機 械性質而維持尺寸安定性、可加工性、可搡作性及®清度 之經樹脂改質之以聚丙烯為主的薄膜。 指出先前技8之需要的本發明係有闞具改良湄氣陣壁 特性之聚合物薄膜。此薄膜包含具有等現立體規則性大於 93〆之高结晶性聚丙烯以及含量為至多基底層之8重量〆 之樹脂改霣劑的該基底1。 在一較佳具«實施例中·高结晶性聚丙烯具有至 98〆之等規立體規則性。基底1較佳包含3至6重董〆之樹 脂改質劑。較佳,樹脂改質劑為氫化烴樹脂或飽和脂環族 烴樹脂。 在另一較佳具體賁腌例中,薄_包含至少一暦鲇著至 基底層的表曆(skin layer),較佳在其上具有塗覆臛。表 層較佳由乙烯-丙烯無規共聚物或乙烯-丙烯-1-丁烯三聚 物所形成。 本發明亦有Μ製慯《溉度陣壁之定向聚丙烯薄_之方 法,包含下列步驟:(a)將(1)等規立體規則性大於93〆之 i. (請先閱讀背面之注意事項再填寫本頁) • - f nn n m dn . -裝· 訂' ί 本紙張尺度逍用中國國家梯準(CNS ) Α4規格(210X297公釐) 4 91267 經濟部t央標準局負工消费合作社印策 A7 B7五、發明説明(5 ) 高结晶性聚丙烯及(2)含量至多為8重量涔之樹脂改霣劑摻 和以形成基底層先疆物;(b>將該基底層先驅物形成薄膜, 較佳搞壓基底曆先驅物W形成基底層以及將片材(sheet) 在縱向及横向方向定向,Μ獲得雙袖定向之薄膜。 在一較佳具體霣拖例中,高结晶度聚丙烯具有94涔至 98涔之等規立體規則性。基底曆較佳包含3至6重量〆之樹 脂改霣劑。較佳樹脂改質劑為氫化烴樹脂飽和脂環族烴樹 脂。 在另一較佳具體霣豳例中,基底曆先驅物與至少一曆 表層共擠壓。表層可由乙烯-丙烯無規共聚物或乙烯-丙烯 -1-丁烯三聚物形成。較佳基底曆係與在兩側的表曆共摒 Κ 0 本發明進一步有闞具有改良湄氣陣壁特性及加強之機 械性質的聚合物薄膜结構。薄膜结構包含具有等規立體規 則性大於93〆之高结晶性聚丙烯Μ及含量為基底層之至多 8重量涔之樹脂改質劑之該基底基。薄膜结構進一包含至 少一層黏著至基底雇的表»。表曆包含有效*之抗粘结銷 以減低薄膜在捲编時之黏结,Μ及包含有效量之矽酮油Μ 維持其曝》表面上之低摩擦係數。薄臢结構較佳包含鲇著 於基底層之各側的對立表雇,該表《係由乙烯-丙烯-1-丁 烯三聚物所形成。 结果,本發明提供呈琨改良瀰氣陣壁性«及加強機械 性霣之以聚丙烯為主之薄膜。此等改良性質之獲得不會使 所得薄_損失尺寸安定性且在其他薄膜特性如澄濟度方面 ih. (請先閱讀背面之注意事項再填寫本頁) _______f 裝 訂318168 A7 B7 Printed by the Ministry of Economic Affairs, Central Bureau of Industry and Consumer Cooperatives V. Description of the invention (3) 1 I The present invention has an improved m air barrier and enhanced mechanical properties Thin m 0 1 Polymer film used in many industrial applications 0 A particularly important application / -S Please read 1 1 I for the food packaging industry 0 The thin m used in the food packaging industry is selected 1 1 I and / Or design Μ to provide the back of the food packaging (f〇〇d C on tai η me nt) 1 1 1 Required properties 0 This property includes water vapor array m Properties oxygen and gas array Note 1 1 Wall霣 霣 Μ and flavor and aroma barrier properties 0 items and 4 packs I Polypropylene is generally manufactured for the thin m in the food packaging industry Used on this page polymer 0 Polypropylene is used as a substrate in the case of multi-calendar film Or the core layer of 1 1 1 polymer 0 Usually the polypropylene layer is modified 9 to obtain the desired properties inherent in the unmodified polypropylene 1 1 1 alkene 0 For example t resin modifiers can be added, 1 · 1 order r agent and / or second The polymer is blended with polypropylene. Attempts to change the properties of polypropylene are usually aimed at improving the m gas craze provided by the film formed by this polymer 1 1 0 For this huge $ it is known that blending polypropylene 1 | η with a resin modifier 1 will improve The m film of the resulting film has a gas barrier property. Generally, a resin modification agent of about 10 ^ to about 20 〆 must be added to the thin m * 1 I achieves the desired reduction in water vapor transmission. 0 1 I but f resin The modification agent is not without its shortcomings with the most added within the aforementioned range. In particular, the use of Dong Fan_, which is typically used in this technique, will significantly reduce the size stability of poly 1 propylene. This viscosity also hinders the addition of VIX and the workability of the resulting film, resulting in an increase in η. This and / Rongpin Ά rent 1, I thin _. I 1 1 The mechanical m of the polymer thin m is this type of mm (Special § | J 1 is another essential feature of thin application for such applications as Ruxiang 1 1 I m product packaging. The paper scale is applicable to China National Standard (CNS) A4 (210X297 mm) 9 1267 318168 A7 B7 Printed by the Beigong Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs V. Description of the invention (4) The mechanical properties of the film are ribbed for processing and Packaging, because this kind of thin food is easier to match with the typical Gongcai machinery. Zeng Mu tried to change the mechanical properties of the polymer film by increasing the orientation of the thin film and / or adding additives, such as: MD) modulus and transverse direction (TD) chess number. However, the orientation of the crucible usually increases the possibility of thinning during manufacturing, and the addition of additives generally provides limited reinforcement of the properties of the hosiery, but negatively affects other films. Properties, such as the degree of clarity. Therefore, in this technique β, it is necessary to improve the moisture barrier properties and strengthen the mechanical properties to maintain the dimensional stability, processability, workability and resin clarity of resin modification Polypropylene-based film. Pointing to the need of the prior art 8, the present invention is a polymer film with improved Membrane barrier characteristics. This film contains highly crystalline polypropylene with isotactic regularity greater than 93〆 And the substrate 1 with a content of up to 8 weights of the resin modifier of the substrate layer. In a preferred embodiment, the highly crystalline polypropylene has an isotactic stereoregularity of up to 98〆. The substrate 1 is preferred Contains 3 to 6 heavy resin modifiers. Preferably, the resin modifier is a hydrogenated hydrocarbon resin or a saturated alicyclic hydrocarbon resin. In another preferred specific example of pickling, thin_ contains at least one catfish The skin layer to the base layer preferably has a coating on it. The skin layer is preferably formed of an ethylene-propylene random copolymer or an ethylene-propylene-1-butene trimer. There is also a method made by Μ "Directional Polypropylene Thin Films for Irrigation Arrays", which includes the following steps: (a) i) (1) The isotactic stereoregularity is greater than 93〆i. (Please read the precautions on the back first (Fill in this page) •-f nn nm dn. -Installed and ordered 'ί This paper size is easy to use Chinese country Standard (CNS) Α4 specification (210X297mm) 4 91267 Ministry of Economic Affairs t Central Standards Bureau Negative Consumer Cooperatives printed policy A7 B7 V. Description of invention (5) Highly crystalline polypropylene and (2) The content is at most 8% by weight The resin modifier is blended to form the base layer precursor; (b > the base layer precursor is formed into a thin film, preferably the base layer precursor is formed to form the base layer and the sheet is formed in the longitudinal and lateral directions Orientation, M obtains a double-sleeved orientation film. In a preferred embodiment, high crystallinity polypropylene has an isotactic stereoregularity ranging from 94 ° to 98 °. The base calendar preferably contains 3 to 6 weight 〆 of resin modifier. The preferred resin modifier is a hydrogenated hydrocarbon resin saturated alicyclic hydrocarbon resin. In another preferred embodiment, the base calendar precursor is co-extruded with at least one calendar layer. The surface layer may be formed of an ethylene-propylene random copolymer or an ethylene-propylene-1-butene terpolymer. The preferred substrate calendar is co-exclusive with the calendars on both sides. K 0 The present invention further has a polymer film structure with improved Membrane barrier characteristics and enhanced mechanical properties. The film structure includes the substrate base having a highly crystalline polypropylene M with an isotactic stereoregularity greater than 93 〆 and a resin modifier containing up to 8 weight percent of the substrate layer. The film structure further contains at least one layer adhered to the substrate table ». The calendar contains an effective anti-sticking pin to reduce the film's adhesion during winding, and M contains an effective amount of silicone oil M to maintain a low coefficient of friction on the exposed surface. The thin lamella structure preferably includes catfish on opposite sides of the base layer, which is formed of ethylene-propylene-1-butene trimer. As a result, the present invention provides a polypropylene-based film that exhibits improved air barrier properties and enhanced mechanical properties. Obtaining these improved properties will not make the resulting thin _ lose size stability and other film characteristics such as clarity ih. (Please read the precautions on the back before filling this page) _______f Binding
K 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 5 9 1267 318168 A7 經濟部中央標準局負工消费合作杜印裝 B7五、發明説明(6 ) 不會有負面銜擊。甚且,所得薄隞維持高度可加工性及可 操作性,產生更佳品質之薄膜及/或減低製造成本。 第1圔僳顯示經由各種百分率之樹脂改質劑改質之聚 丙烯薄膜之水蒸氣傳輪速率(WVTR)之變化_。 本發明係賴著將高结晶性聚丙烯(HCPP)與樹脂改霣劑 摻和形成基底層先驅物而製成。HCPP具有大於93涔,較佳 自94〆至98〆之等規立體規則性),。基底餍包含高至3重 垦涔之樹脂改霣劑,較佳自3至6重量涔之樹脂改質劑。 適合之HCPPs(薄模等级)包含Amoco9117及Amoco9U9( 可自伊利諾州芝加哥市的Aboco化學公司獲得);Chisso HF5010及Chisso XP2805(可自日本東京之Chisso化學有限 公司獲得)。遘合之HCPPs亦可自歐洲薩爾未(Solvay)獲得 。HCPP具有高等規立體則規性,導致高於習用聚丙烯聚合 物之结晶性,呈現較高剛性、表面硬度、高溫時折射較低 及較佳之蠕變性霣。美國專利第5,063,264號中揭示有闞 HCPP之進一步黄枓,包含其製備方法。 就本發明之目的而言,可《由如應用聚合物科學雜誌 (Journal of Applied Ployner Science)卷 9,第 359〜 367頁(1965)J.L.Koenig及 A.Van Roggen所著之”聚丙烯中 立體規則度之積分紅外線薄強度測量(I n t e g r a t e d Infrared Band Intersity Measureaent of Stereoregularity in Polypropylene)及紐約、其卻 斯特(Chichester)、布里斯班(Brisbane)、多檐多之 JohnWiley and Sons公司 Wiley-Inerscience發行之 Jack (請先閱讀背面之注意事項再填寫本頁) -裝_ 訂- / 级 本紙佚尺度逍用中國國家棣準(CNS ) A4规格(210X297公釐) 6 9 1267 A7 B7 經濟部中央標準局只工消費合作杜印S- 五、發明説明(7 ) L. Koenig所著之”聚合物鐽之化學微结構”中所述步驟之 IR光譜測定立體規則度。亦可賴由十氫化萘(萘烷)溶解度 及核磁共振光譜(NMR)測定立體規整度。 HCPP成分與含量至多為8重量〆,較佳3至6重量〆之 樹脂改質劑摻和。較佳樹脂改霣劑包含氫化烴樹脂及飽和 脂環族樹脂。其他適合之樹脂改質劑實例為石油烴、瀝靑 、烴樹脂如石油樹脂與煤樹脂、松香、松香衍生物、及苯 乙烯樹脂。 較佳具有低分子量之樹脂改霣劑具有以氣相滲透壓力 測量法所測之數目平均分子量通常少於5000,較佳少於 2000,例如500至1000。樹脂改質劑可為天然或合成者。 石油樹脂可由自深裂解石油所衍生之單體混合物之觸 媒聚合或熱聚合所獲得,該單《主要為單-或二-烯烴。此 種混合物之觸媒聚合一般在低溫使用Friede卜C「afts觸媒 進行之。可將石油樹脂氫化K降低其不飽和度、使其顔色 變淡、及改菩其性質等等。 本發明中有用的一種烴樹脂為不飽和煤焦油副產物之 聚合物,如聚茚樹脂及香豆酮茚樹脂。已知如苯乙烯-二 烯烴共聚物之烴樹脂亦為有用。 根據本發明,可使用任何一般種類之松香,如木松香 、膠松番、焦油松香、及改質松香.如部分或大體上氳化 之松香、去氫松香、歧化松香、聚合松香,K及松香醉及 烴热處理之松香。 «合之松番亦可包含松香、氳化松香、聚合松香等之 em·— _ (請先閲讀背面之注意事項再填寫本頁) ___f -裝.K This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 5 9 1267 318168 A7 Duplicate printing and packaging of the Central Standards Bureau of the Ministry of Economic Affairs B7 5. The invention description (6) will not have a negative impact. Moreover, the resulting thin lamellas maintain a high degree of processability and operability, resulting in better quality films and / or reduced manufacturing costs. Section 1 shows the change in water vapor transmission rate (WVTR) of polypropylene films modified with various percentages of resin modifiers. The present invention is made by blending highly crystalline polypropylene (HCPP) with a resin modifier to form a precursor to the base layer. HCPP has an isotactic stereo regularity greater than 93 °, preferably from 94〆 to 98〆). The substrate contains up to 3 weights of resin modifiers, preferably from 3 to 6 weights of resin modifiers. Suitable HCPPs (thin mold grades) include Amoco9117 and Amoco9U9 (available from Aboco Chemical Company in Chicago, Illinois); Chisso HF5010 and Chisso XP2805 (available from Chisso Chemical Co., Ltd., Tokyo, Japan). The combined HCPPs can also be obtained from Solvay in Europe. HCPP has high isotactic stereoregularity, resulting in higher crystallinity than conventional polypropylene polymers, showing higher rigidity, surface hardness, lower refraction at high temperatures and better creep properties. U.S. Patent No. 5,063,264 discloses a further product of Kan HCPP, including its preparation method. For the purposes of the present invention, "Polypropylene in three dimensions" by "Journal of Applied Ployner Science" Volume 9, pages 359 to 367 (1965) JL Koenig and A. Van Roggen Issued by I ntegrated Infrared Band Intersity Measureaent of Stereoregularity in Polypropylene and New York, Chichester, Brisbane, and John Wiley and Sons, Wiley-Inerscience Jack (please read the precautions on the back before filling in this page) -Installation_ Order- / Grade-level papers are not used in the Chinese National Standards (CNS) A4 specifications (210X297 mm) 6 9 1267 A7 B7 Central Standards of the Ministry of Economic Affairs Bureau Veritas Consumer Cooperation Du Yin S- V. Description of the invention (7) L. Koenig's "Chemical Microstructure of Polymers" The IR spectroscopy measures the stereoregularity. The decahydronaphthalene can also be used (Decalin) solubility and nuclear magnetic resonance spectroscopy (NMR) to determine the stereoregularity. The HCPP component is blended with a resin modifier up to 8 weight 〆, preferably 3 to 6 weight 〆 Preferred resin modifiers include hydrogenated hydrocarbon resins and saturated alicyclic resins. Examples of other suitable resin modifiers are petroleum hydrocarbons, asphalt, hydrocarbon resins such as petroleum resins and coal resins, rosin, rosin derivatives, and styrene Resin. It is preferred that the resin modifier with a low molecular weight has a number average molecular weight measured by a gas-phase osmotic pressure measurement method is usually less than 5000, preferably less than 2000, for example 500 to 1000. The resin modifier may be natural or Synthesizer. Petroleum resins can be obtained by catalyst polymerization or thermal polymerization of monomer mixtures derived from deep cracked petroleum. The single is mainly mono- or di-olefins. Catalyst polymerization of such mixtures is generally used at low temperatures. Friede Bu "afts catalyst. It can hydrogenate petroleum resin K to reduce its unsaturation, lighten its color, and change its properties, etc. A hydrocarbon resin useful in the present invention is a by-product of unsaturated coal tar Polymers such as polyindene resins and coumarone indene resins. Hydrocarbon resins such as styrene-diene copolymers are also known to be useful. According to the present invention, any general kind of rosin can be used, Wood rosin, gum rosin, tar rosin, and modified rosin. Such as partially or substantially rosin rosin, dehydrogenated rosin, disproportionated rosin, polymerized rosin, K and rosin drunk and hydrocarbon heat-treated rosin. «合 之 松Fan can also contain rosin, rosin rosin, polymerized rosin, etc. — _ (please read the precautions on the back before filling this page) ___f -installed.
•IT ί 本紙伕尺度適用中國國家標準(CNS ) A4規格(210 X 297公釐) 91267 A7 B7 經濟部中央櫺準局Λ工消费合作社印製 五、發明説明(8 ) 多元酵酗,如:木松香之甘油酯及季戊四酵_、氫化松香 之乙二酵酷、甘油酯及季戊四酵 特別適合之可後績被氫化之樹脂為烴樹脂、酮樹脂、 聚釀胺樹脂、松香、香豆酮樹脂、秸烯樹脂、氯化脂族或 氡化芳族烴樹脂。烴樹脂之實例為焦爐氣、裂化石腦油、 粗柴油(g a s 〇 i 1 )及秸烯油。 較佳S化樹脂為氫化石油樹脂。此等通常由觸媒氫化 熱聚合裂解石油之蒸龌部分的蒸氣而製得。亦可能藉著觸 媒聚合不飽和烴生產氫化樹脂。 適用於本發明之商業可得之氫化烴樹脂為彼等以 Hercules公司之商檷REGALREZ及REGALITE所出售者。 本發明所用較佳飽和脂環族樹脂係由芳族烴樹脂氫化 而獲得者。芳族樹脂本身係由聚合反«性不飽和烴所獲得 ,此反應性不飽和烴含有其中反應性雙鍵一般在俩鐽的芳 族烴作為主成分。脂環族樹腊係拜由將芳族樹脂氫化至所 有,或幾乎所有之不飽和處(包含芳環中之雙鐽)消失而獲 得。 雖然製備脂瓖族樹脂時有用之芳族烴主要為在側_含 有反應性雙鍵之化合物,此芳族烴亦可包括在稠環糸中具 有反應性雙鍵之芳族煙。此等有用芳族煙之實例包含乙烯 基甲笨、乙烯基二甲苯、丙烯基苯、苯乙烯、對-甲基苯 乙烯、茚、甲基茚、及乙基茚。可使用數檷此等煙之混合 物。此等芳族焊之非常便利之工業來源為自重石油部分之 热裂解產物蒸鑲去除有用烯烴(如乙烯反丙烯)後所得之殘 __. (請先閲讀背面之注意事項再填商本頁) ,__________f- 裝- 訂 線 本紙張尺度逡用中國國家梂準(CNS ) A4規格(210 X 29"7公釐) 9 1267 31S168 A7 B7 五、發明説明(9 ) 餘物之沸點範園為20°至3 0 0 C,較佳為140°至3 0 0 C之 部分。反應性烴之聚合可在聚合觸媒如磺酸、磷酸、或兩 性金饜氫化物之存在下進行。 將所得芳族烴樹脂氫化,直至不胞和鍵(包含芳環内 之雙鍵)實質上完全飽和為止。一般在高溫及至少150kg/ cb2之氫氣®力下,在大量高度活性觸媒如雷iSUaney)鎳 戎鈀存在下進行氫化。芳族雙鍵之篦化可藉比較氪化前與 氫化後樹脂的紅外媒或紫外線吸收光譜而確定。芳環在紅 外線光譜中之700CB-1及750c·-1,及在紫外媒光譜中之 261.5bU及274.5au具有特激吸收,此吸收在芳瓌氫化成 脂環時減小,而當所有環均飽和時則消失。所欲為獲得以 特激吸數之消失所測得之達到至少80涔及較佳至少90涔之 氫化者。 本發明所用之脂環族樹脂具有Μ球及環方法澜得為 85°至140它,較佳lOOt至140它之炊化點。遘合用於本 發明之商業可得之脂瑁族樹腊實例為彼等Μ日本Arakawa 森林化學工業股份有限公司之商品名A RK0N-P出售者。• IT ί The size of this paper is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 91267 A7 B7 Printed by the Central Bureau of Economic Development of the Ministry of Economic Affairs ⑤Industry and Consumer Cooperatives 5. Description of inventions (8) Multiple enzymes, such as: Glycerol ester and pentaerythritol of wood rosin_, Glycerol ester of hydrogenated rosin, glyceride and pentaerythritol are particularly suitable. The resins that can be hydrogenated are hydrocarbon resin, ketone resin, polybromoamine resin, rosin , Coumarone resin, straw resin, chlorinated aliphatic or radonized aromatic hydrocarbon resin. Examples of hydrocarbon resins are coke oven gas, cracked naphtha, gas oil (g a s 〇 i 1) and straw oil. The preferred S resin is hydrogenated petroleum resin. These are usually prepared by catalytic hydrogenation and thermal polymerization to crack the steam of the steamed portion of petroleum. It is also possible to produce hydrogenated resins by polymerization of unsaturated hydrocarbons through catalysts. Commercially available hydrogenated hydrocarbon resins suitable for use in the present invention are those sold by Hercules Corporation, REGALREZ and REGALITE. The preferred saturated alicyclic resin used in the present invention is obtained by hydrogenating an aromatic hydrocarbon resin. The aromatic resin itself is obtained by polymerizing reactive unsaturated hydrocarbons. This reactive unsaturated hydrocarbon contains an aromatic hydrocarbon in which the reactive double bond is generally present in the two as the main component. The alicyclic tree wax is obtained by hydrogenating the aromatic resin to all, or almost all of the unsaturation (including the double arsenic in the aromatic ring) disappears. Although the aromatic hydrocarbons useful in the preparation of the fat-oil resin are mainly compounds containing a reactive double bond on the side, the aromatic hydrocarbon may also include aromatic smoke having a reactive double bond in the fused ring. Examples of such useful aromatic smokes include vinyl meth, vinyl xylene, propylene benzene, styrene, p-toluene, indene, methyl indene, and ethyl indene. Mixtures of several of these smokes can be used. The very convenient industrial source of these aromatic welds is the residues obtained by steaming and removing the useful olefins (such as ethylene anti-propylene) from the thermal cracking products of the heavy petroleum part. (Please read the precautions on the back and fill in this page ), __________ f- Binding-The paper size of the binding book is in accordance with China National Standard (CNS) A4 specification (210 X 29 " 7mm) 9 1267 31S168 A7 B7 5. Description of the invention (9) The boiling point of the residue is 20 ° to 3 0 0 C, preferably 140 ° to 3 0 0 C. The polymerization of the reactive hydrocarbons can be carried out in the presence of a polymerization catalyst such as sulfonic acid, phosphoric acid, or amphoteric gold hydride. The resulting aromatic hydrocarbon resin is hydrogenated until the cell and bond (including the double bond in the aromatic ring) are substantially completely saturated. Generally hydrogenation is carried out in the presence of a large amount of highly active catalysts such as Lei iSuaney) nickel palladium under high temperature and at least 150kg / cb2 of hydrogen® force. Grate formation of aromatic double bonds can be determined by comparing the infrared medium or ultraviolet absorption spectrum of the resin before kryptonization and after hydrogenation. The 700CB-1 and 750c · -1 of the aromatic ring in the infrared spectrum, and 261.5bU and 274.5au in the ultraviolet medium spectrum have ultra-excited absorption. This absorption decreases when the aromatic ring is hydrogenated into an alicyclic ring, and when all the rings When they are saturated, they disappear. Those who desire to obtain a hydrogenation of at least 80 ° C and preferably at least 90 ° C measured by the disappearance of the number of extra shocks. The alicyclic resin used in the present invention has an M-ball and a ring method with a cooking point of 85 ° to 140 °, preferably 100 t to 140 °. Examples of commercially available tallow tree waxes used in the present invention are the sellers of their trade name ARKON-P under the name of Arakawa Forest Chemical Industry Co., Ltd., Japan.
經濟部中央梯準局貝工消費合作社印IL -***. I 1— .....—^― - - - ^l -I —^― n (請先閲讀背面之注意事項再填寫本頁) 本發明之薄膜較佳包含黏著至基底暦之至少一價的至 少一層烯烴聚合物表層。表曆較佳與基底層共濟朦。在一 較佳具體實例中,表曆同時在基底«之兩側共擠懕。 在一較佳具應寘例中,表«之外表面敷有塗料。可將 提供改良可印刷性、可加工性及芳香陣垩特性的丙烯酸糸 塗料塗敷在表層中之一個。可將热封塗料如乙烯丙烯酸甲 _ (EMA)或乙》丙烯酸(EAA)之塗敷至另一表隳。其他遺合 本紙張尺度遑用中國國家標率(CNS ) Α4規格(210X 297公釐) 9 9 12 6 7 經濟部中央樣準局貝工消費合作杜印製 A7 B7 五、發明説明(1〇) 之塗包含聚儀氛二乙烯(PVDC)、聚乙烯酵(PV0H)及低溫熱 封塗枓,如一般癱有之美鼷專利第〜5,419,960號所揭示 者。 使用為表層之《合烯烴聚合物包含i)乙烯均聚物、 ii)乙烯及丙烯之共聚物、iii)乙烯或丙烯及丁烯或另一 具有5至10個碳原子之α-烯烴之共聚物、iv)乙烯、丙烯 及丁烯或另一具有5至10個碳原子之ex-烯烴之三聚物、及 v)前述各項之混合物。 特別宜作為表»之烯烴聚合物包含以丙烯為主要組成 及乙烯含量2至10里量〆(相對於共聚物之重董)之乙烯-丙 烯共聚物、Μ丙烯為主要組成及丁烯含量0.5至25重1涔( 相對於共聚物之重量)之丙烯-丁烯共聚物、及以丙烯為主 要組成及含0.5至7重董涔乙烯與5至30重量〆丁烯(各相對 於三聚物之重董)之乙烯-丙烯-丁烯三聚物,以及此等聚 合物之混合物。共聚物及三聚物係較佳之無規聚合物。 為進一步改菩所得薄膜之特定性質,可在基底餍及/ 或表層中含有有效量之添加劑,如抗鮎结劑、抗靜霣謂及 /或肋滑劑。 較佳抗黏结劑包含氧化矽、淆石、粘土、矽酸納鋁、 及習用無懺抗黏结劑。其他瘸合之抗黏结劑包含無機添加 如二氧化矽、碳酸鈣、矽酸鎂.、矽酸鋁及《酸鈣等, 及/或不相容之有櫬聚合物,如聚醢胺、聚_及聚碳酸酯 等。 較佳抗靜霣劑包含烷礤酸_金属及基本上直韃,而擁 本紙張尺度適用中國國家標準(CNS ) Α4规格(210X297公釐) 1〇 9 1267 (請先閱讀背面之注意事項再填葙本頁) _________r 装. 訂 線 318168 A7 B7 五、發明説明(11) 有具10至20饀碳原子之脂族基且被2 -羥烷基(CiMCd基團 取代之飽和脂族三级胺。較佳胺為在其烷基中具有1〇至 20,較佳12至18個碳原子之N,H -雙- (2 -羥乙基)-烷基胺。 抗靜電劑之有效量在相對於層重量之〇·〇5至3重量〆之範 麵内變動。 較佳肋滑劑包含較高级脂肪酸醢胺、較高趿脂肪酸酯 、蠟、金屬皂及矽嗣油如聚二甲基矽氧烷。潤滑劑之有效 添加董自0.1至2重悬〆變動。 本發明之一具體實例中,薄膜包鲇著至芯層之對側的 表層。各表層包含有效逢之抗黏结劑(如:氧化矽)以減低 捲缡薄膜之黏结及至少一層表層包含有效量之矽酮油(如: 聚二甲基矽氧烷)以維持表層之曝露表面的低摩擦係數。 抗黏结劑較佳存在悬為0.1至0.3重1〆。矽酮油存在量為 0 . 5至2 . 0重量〆,且較佳自0 . 8至1 . 2重霣涔,且具有3 5 0 至600,000厘斯(〇6〇1;丨5^;〇1^3)之黏度,及較佳10,000至 30,000之厘斯。若將矽酮油加至兩表層,則產生ΑΒΑ结構 。在僅將矽酮油加至一®表層(生成ABC结構)之彼等具體 實例中,油量仍可在捲编薄膜時,轉移至對側表《。在此 特別ABC结構中,不含油之側可在捲鲩之前以火焰或霣翬 處埋。 本發明之多層薄膜可使用共摘®樹脂所用之商業可得 系统而製得。如所述者,較佳將摻和的HCPP及樹脂改質劑 與至少一種形成表曆的第二聚合物共擠臛。可使聚合物至 熔融狀戆且自習用擠颳拥經由平板棋(flat sheet die)共 11 (請先閲讀背面之注意事項再填寫本頁) _________Γ 裝 、1Τ ί 經濟部中央橾準局貝工消費合作社印製 本紙伕尺度適用中國國家梂準(CNS ) Α4規格(21〇Χ 297公釐) 9 1267 經濟部t央橾準局員工消费合作社印袈 318168 A7 __B7 五、發明説明(12 ) 擠壓,諸熔融流在自横中擠)K之前在接頭(adapter)中结 合。在多層薄膜结構離開撗孔口後,將其驟冷。 本發明之薄_較佳經雙_定向。在一較佳聚體實拖例 中,將薄膜在櫬器方向(MD)拉伸4.5至6次,及在横向(TD) 拉伸 6至 13次。總定'向(overall orientation) (MDXTD)較 佳在25至80之範圍。定向之後.可修剪膜之邊緣且將膜捲 繞在芯上。 所形成之本發明之薄_结構具有l〇u至60u,較佳 1 5 w至50 w之厚度。 富例 Μ下列實例說明本發明。下列實例1〜4係說明先前技 __ —— ―一― »薄膜之混氣性質之比較例。》例5〜13說明本發明薄膜 所改良且意想不到之性霣。下列各實例之湖氣陣壁係在 37.8tMl〇〇°F)及90〆相對濕度(ASTM F372)下測得,且使 用轉換因子6.4516ci2/in2及四拾五入至千分之一而Mg/ 100c«2/天/密耳U/l〇〇in2/天/密耳)表示。»例14說明本 發明之薄膜所呈琨之加強櫬械性質。 奮例1 製造樣品1以說明習用Μ聚丙烯為主薄_之濕氣陣壁 。將厚度23.75微米之等規聚丙烯均聚物(Fina 3371)之芯 蘭熔融,然後與厚度各為0.6激米之乙烯-丙烯共聚物( Fina 8 5 7 3 HB)之表層共擠ffi。表靥含有1 0 0 0 PP·之包栝氧 化矽之_Sylobloc 48抗粘结劑(Grace Div丨son公司之產品) 〇__ 本紙張尺度it财關家料(CNS ) A4胁(21G X 297公廣) · 12 91267 (請先閲讀背面之注意事項再填寫本頁)Printed by the Beigong Consumer Cooperative of the Central Bureau of Economics of the Ministry of Economic Affairs IL-***. I 1— .....— ^ ―---^ l -I — ^ ― n (Please read the precautions on the back before filling in this The film of the present invention preferably includes at least one olefin polymer surface layer adhered to the substrate at least one valence. The calendar is preferably in harmony with the base layer. In a preferred embodiment, the calendar is co-extruded on both sides of the substrate. In a preferred example, the outer surface of the table is coated with paint. One of the surface layers can be coated with an acrylic paint that provides improved printability, processability, and aromatic chalk properties. Heat-sealing coatings such as ethylene acrylic acid methyl (EMA) or ethylene acrylic acid (EAA) can be applied to another watch. For other papers of this type, the Chinese standard rate (CNS) Α4 specification (210X 297 mm) is used. 9 9 12 6 7 The Central Sample Bureau of the Ministry of Economic Affairs, Beigong Consumer Cooperation Co., Ltd. prints A7 B7 V. Description of invention (1〇 ) Coatings include polystyrene divinylidene (PVDC), polyvinyl yeast (PV0H), and low-temperature heat-sealing coatings, as disclosed in the general US Patent No. 5,419,960. Copolymerization of olefin polymer containing i) ethylene homopolymer, ii) copolymer of ethylene and propylene, iii) ethylene or propylene and butene or another α-olefin having 5 to 10 carbon atoms Iv) ethylene, propylene, and butene or another ex-olefin terpolymer having 5 to 10 carbon atoms, and v) a mixture of the foregoing. The olefin polymer particularly suitable as shown in Table »contains an ethylene-propylene copolymer with propylene as the main composition and an ethylene content of 2 to 10 li (relative to the weight of the copolymer), M propylene as the main composition and butene content of 0.5 Propylene-butene copolymer with a weight of 25 to 1 weight (relative to the weight of the copolymer), and with propylene as the main composition and containing 0.5 to 7 weights of ethylene and 5 to 30 weights of butene (each with respect to trimerization) Heavyweight) ethylene-propylene-butene terpolymer, and mixtures of these polymers. Copolymers and terpolymers are preferred random polymers. In order to further modify the specific properties of the film obtained, an effective amount of additives, such as anti-catfish agents, anti-static agents and / or rib slip agents, may be included in the substrate and / or surface layer. Preferred anti-sticking agents include silicon oxide, quartz, clay, sodium aluminum silicate, and conventional non-stick anti-sticking agents. Other anti-adhesion agents that contain lamination include inorganic additives such as silica, calcium carbonate, magnesium silicate, aluminum silicate and calcium silicate, etc., and / or incompatible polymers such as polyacetamide and polysilicate _ And polycarbonate. The preferred anti-static agent contains alkanoic acid_metal and substantially straight, and the standard of this paper is applicable to China National Standard (CNS) Α4 specification (210X297mm) 1〇9 1267 (please read the precautions on the back first (Fill this page) _________r Packing. Stranding 318168 A7 B7 5. Description of the invention (11) Saturated aliphatic tertiary with an aliphatic group having 10 to 20 carbon atoms and substituted by a 2-hydroxyalkyl group (CiMCd group) Amine. The preferred amine is an N, H-bis- (2-hydroxyethyl) -alkylamine having 10 to 20, preferably 12 to 18 carbon atoms in its alkyl group. Effective amount of antistatic agent It varies within the range of 0.05 to 3 weight relative to the weight of the layer. Preferred rib slip agents include higher fatty acid acetamide, higher fatty acid esters, waxes, metal soaps and silicone oils such as polydi Methyl silicone. The effective addition of lubricants varies from 0.1 to 2 re-suspension. In one specific example of the present invention, the film is wrapped to the surface layer on the opposite side of the core layer. Each surface layer contains effective anti-stick Agents (such as silicon oxide) to reduce the adhesion of the rolled film and at least one surface layer contains an effective amount of silicone oil (such as: polydimethylene Siloxane) to maintain a low coefficient of friction of the exposed surface of the surface layer. The anti-sticking agent is preferably present in a suspension of 0.1 to 0.3 weight 1〆. The amount of silicone oil present is 0.5 to 2.0 weight〆, and preferably from 0.8 to 1.2 heavy weight, and has a viscosity of 3 5 0 to 600,000 centistokes (〇6〇1; 丨 5 ^; 〇1 ^ 3), and preferably 10,000 to 30,000 centistokes. When silicone oil is added to both surfaces, the ABA structure is produced. In the specific examples where only silicone oil is added to the surface layer (to produce the ABC structure), the amount of oil can still be transferred to the opposite side when the film is wound. Table ". In this particular ABC structure, the oil-free side can be buried in flames or squiggles before the carp is rolled. The multilayer film of the present invention can be made using commercially available systems for co-pick® resins. It is preferred that the blended HCPP and resin modifier be co-extruded with at least one second polymer that forms a calendar. The polymer can be melted and squeezed through a flat sheet (flat sheet) die) a total of 11 (please read the precautions on the back before filling out this page) _________ Γ outfit, 1Τ The size of the paper printed by the publisher is applicable to the Chinese National Standard (CNS) Α4 specification (21〇Χ 297 mm) 9 1267 Ministry of Economic Affairs t Central Central Bureau of Standards and Technology Employee Cooperative Printing Co., Ltd. 318168 A7 __B7 V. Description of invention (12) Pressure, the melt streams are combined in the adapter before the self-extrusion K). After the multilayer film structure leaves the opening, it is quenched. In the present invention, the thin_preferably double_oriented. In a preferred polymer drag example, the film is stretched 4.5 to 6 times in the direction of the MD (MD) and 6 to 13 times in the transverse direction (TD). The overall orientation (MDXTD) is preferably in the range of 25 to 80. After orientation, the edges of the film can be trimmed and the film wound on the core. The formed thin-structure of the present invention has a thickness of 10 u to 60 u, preferably 15 w to 50 w. Rich Examples M The following examples illustrate the invention. The following examples 1 to 4 illustrate the prior art __ —— ― 一 ― »Comparative example of the gas mixing properties of the film. "Examples 5 to 13 illustrate the unexpected and improved properties of the film of the present invention. The lake gas arrays of the following examples were measured at 37.8tM100 ° F) and 90〆relative humidity (ASTM F372), and using a conversion factor of 6.4516ci2 / in2 and four to one thousandths and Mg / 100c «2 / day / mil U / lOOin2 / day / mil). »Example 14 illustrates the enhanced mechanical properties of the film of the present invention. Practical Example 1 Sample 1 was manufactured to illustrate that the conventional M polypropylene is mainly used as a thin moisture barrier. The core of an isotactic polypropylene homopolymer (Fina 3371) with a thickness of 23.75 microns was melted, and then coextruded with the surface layer of an ethylene-propylene copolymer (Fina 8 5 7 3 HB) with a thickness of 0.6 mils each. The table contains 1 0 0 0 0 PP · Supplied Silica Oxide _Sylobloc 48 anti-binder (product of Grace Divson) 〇__ The paper standard it financial home materials (CNS) A4 threat (21G X 297 Public Broadcasting) · 12 91267 (Please read the precautions on the back before filling this page)
___K I 裝___K I installed
*1T 線 A7 B7 五、發明説明(13) 將ΑΒΑ擠懕物《冷,再加熱,且於104t(220T)至 143TM290°F)在襪器方向拉伸4〜6次。接著,將經MD定向 之基底片材於約15710 (315T)至193T: (380T)在横向拉伸 8〜12次。 (請先閱讀背面之注意事項再填寫本頁) --.JJ,----------裝_ 揉品 芯層 〆樹脂 周圍之WVTR 老化之 (水蒸氣傳输速率) W VTR 1 F i na 3 3 7 1 0 0.048 (.311) 0.048 (.311)* 1T line A7 B7 5. Description of the invention (13) The ABA extruded material is "cooled, reheated, and stretched 4 to 6 times in the direction of the hosiery at 104t (220T) to 143TM290 ° F). Next, the MD oriented substrate sheet is stretched from about 15710 (315T) to 193T: (380T) in the transverse direction 8 to 12 times. (Please read the precautions on the back before filling in this page)-. JJ, ---------- installation_ KV product core layer〆WVTR around the resin Aging (water vapor transmission rate) W VTR 1 F i na 3 3 7 1 0 0.048 (.311) 0.048 (.311)
2 例 V 0 ( 質烯 改丙 脂聚 樹用 之習 董得 同製 不 〇 有垩 含陣 明氣 說湄 以 之 C I 2 膜 及薄 2b主 、 為 a απ 2 0 品丙 樣聚 造以 製用 習 之 XC物 C ΕΧ和pi 的摻 Μ 頓之司 士物公 休合 e 州聚ui 斯烯rc 61秸Ke 克 〆 自 德wt可 自 2 得及其 可 谇 且 t II• W 31 2 ο B· 1 1 禽 6 -4 有 d η 含有 ΧΟ其含 ΕΧ及物 司 公 化 合 聚0 秸 1T, 經濟部中央揉準局負工消費合作社印製 脂 樹 加 添 式 方 之 和 播 融 熔 著 藏 ο 得 購 名 品 商 之 本紙張尺度適用t國國家標準(CNS ) Α4規格(2丨0>< 297公釐) 3 11 9 12 6 7 318168 Α7 Β7 Μ濟部中央樣隼局貝工消资合作杜印裝 五、發明説明(14) 樣品 芯層 涔樹脂 同園之 老化之 改霣劑 WVTR WVTR 2a Exxon 46 12 0 - 0.045(0.29) 2b Exxon 4612 10 - 0.039(0.25) 2c Exxon 46 1 2 20 - 0.037(0.24) 製造樣品3a、 3b及3c以說明含有不同量之改質劑之習 用K聚丙烯為主薄膜之湄氣陣坚。將習用聚丙烯(Fina 3371,可得自德克S斯州達拉斯的Fina石油及化學公司) 與以熔融摻和方式添加而含有10wt¥及2(Wt〆之包括d-蓽 铺之链烯聚合物(Piccolyte C-115,可得自Hercules公司 )之其摻和物輿?丨113 857 3共擠壓,?丨〇3 8573為含有3.5贸七 火乙》之乙烯-丙烯無規聚合物。將此姐合共擠壓並定向, Μ使之具有0.6微米之外表皮尺寸及20»米之芯層尺寸。 樣品 芯餍 〆樹脂 同園之 老化之2 cases of V 0 (Xin Dong used for the conversion of acrylic resin to acrylic resin trees. There is no chalk. There is a burst of vitality. The Mae Yi ’s CI 2 film and thin 2b are mainly produced by a απ 2 0 product. Preparation of the XC material C ΕΧ and pi doped with the princes of the princes, the public restoring e state poly ui sene rc 61 straw Ke 〆 from the German wt can be obtained from 2 and its can be assumed and t II • W 31 2 ο B · 1 1 poultry 6 -4 has d η contains ΧΟ its contains Εx 物 物 物化 聚聚 聚 Straw 1T, the Ministry of Economic Affairs Central Bureau of Accreditation Bureau of Consumer Labor Cooperatives printed fat tree plus the addition of the formula and sowing melting melting Collection ο The original paper standard of the famous brand is applicable to the national standard (CNS) Α4 specifications (2 丨 0> 297 mm) 3 11 9 12 6 7 318168 Α7 Β7 Μ テ テ ィ ー テ テ ィ フ テ ィ テ ィ テ ィ テ ィ テ ィ テ ィ テ ィ テ ィ テ ィ テ テ ィ テ ィ テ ィ テ ィ バ バ テ テ テ ィ バ テ テ テ ィ バ テ テ テ ィ バ テ テ テ ィ バ テ ィ バ テ テ テ ィ バ テ ズ of National Standards (CNS) Α4 specifications (2 丨 0> <297mm) 3 11 9 12 6 7 318168 Α7 Β7 Cooperation with Consumers in Du Printing 5. V. Description of the Invention (14) Sample core layer of aging resin in the same garden WVTR WVTR 2a Exxon 46 12 0-0.045 (0.29) 2b Exxon 4612 10-0.039 (0.25) 2c Exxon 46 1 2 20-0.037 (0.24) Manufacture samples 3a, 3b and 3c to illustrate the conventional K polypropylene based film containing different amounts of modifier Zhenjian. Combine conventional polypropylene (Fina 3371, available from Fina Petroleum and Chemical Company of Dallas, Texas) with melt blending to contain 10wt ¥ and 2 (Wt〆including d- 荜 铺 的Alkene polymer (Piccolyte C-115, available from Hercules), its blending materials? 113113857 co-extrusion, 8103 is an ethylene-propylene random containing 3.5 trade seven fire B " Polymer. Co-extrusion and orientation of this sister, M to make it have a skin size other than 0.6 microns and a core layer size of 20 »meters. The core of the sample is aged with resin
改霣劑 WVTR WVTR --------Γ -^----—ΪΤ-----^ 線 (请先閱讀背面之注意事項再填寫本頁) 3 a Pina 3 3 7 1 0 - 0.050 (0 . ,3 2 5 ) 3b F i n a 3 3 7 1 10 0.042 (0 . .27) 3c F i n a 3 3 7 1 20 - 0.039 (0 . ,25 ) 本紙浪尺度適用中國國家標準(CNS ) Α4洗格(210X297公釐)‘ 14 91267 A7 B7 五、發明説明(15) 奮例4 製造樣品4以說明HCPP薄縝之濕氣陣鑒。使用高结晶 性均聚物聚丙烯(Aaoco 9117)之芯層里覆實例1。Correction agent WVTR WVTR -------- Γ-^ ----— ΪΤ ----- ^ line (please read the precautions on the back before filling this page) 3 a Pina 3 3 7 1 0 -0.050 (0., 3 2 5) 3b F ina 3 3 7 1 10 0.042 (0. .27) 3c F ina 3 3 7 1 20-0.039 (0., 25) This paper wave scale applies the Chinese National Standard (CNS ) Α4 wash grid (210X297 mm) '14 91267 A7 B7 V. Description of the invention (15) Fen Example 4 Manufacture sample 4 to illustrate the HCPP thin moisture barrier. A highly crystalline homopolymer polypropylene (Aaoco 9117) core layer was used to cover Example 1.
樣品 芯屬 涔樹脂 同園之 老化之 改質劑 WVTR WVTR 4 Ancoc 9117 0 0.038 0.034 (.246) (.218) (請先閲讀背面之注意事項再填寫本頁) -裝- g例5 製造樣品5a、5b及5c。經由母煉製法添加钦化點為 115t:之胞環族樹脂,ARKON P-115。樣品5a、5b及5c中, 芯層之最终濃度各為3涔,6光及10〆之ARKON P-115。將 薄膜如下定向:MDX=5.0, TDX=9.0。 訂. 樣品 〆樹脂 改霣劑The sample core is the aging modifier WVTR WVTR 4 Ancoc 9117 0 0.038 0.034 (.246) (.218) (Please read the precautions on the back before filling in this page) -Package- gExample 5 Manufacturing sample 5a, 5b and 5c. Through the mother refining method, the addition point is 115t: the cell ring resin, ARKON P-115. In samples 5a, 5b, and 5c, the final concentration of the core layer was 3 A, 6 light, and 10 ARKON P-115. Orient the film as follows: MDX = 5.0, TDX = 9.0. Order. Sample 〆Resin Modifier
同圍之 W VTRT Wai Wai W VTR
老化之 W VTR 經濟部中央樣準局貝工消費合作社印裝 5 a A 疆 o c ο 9 117 3 0.035 0.030 (.2 2 7 ) (.194) 5 b A 通 o c ο 9117 6 0.032 0.027 (.2 0 6 ) (.1 76) 5 c A a o c o 9 117 10 0.032 0.027 (.2 0 5 ) (.1 73 ) 15 本紙乐尺度逍用中國國家標準(CNS ) A4規格(210X297公釐) 9 1267 318168 at Β7 五、發明説明(1 窗例fi 製造樣品6a及6b。經由母煉製法將钦化點為125它之 脂環族樹脂ARKON P-125添加至實例4之薄稱。樣品6a及 6b中,芯層之最終濃度各為3〆及6涔之ARKON P-125。將 薄膜如下列定向:MDX=5.0, TDX=9.0。 (請先閱讀背面之注意事項再填寫本頁) ,-1ΊΙ.ΤΤ__________Γ -裝- ΪΤ- 樣品 si 心靥 % 改 樹脂 質劑 同圍之 VVTR 老化之 WVTR 6 a Amoco 9117 3 0.036 0.032 (.2 3 0 ) (.2 0 7 ) 6b Aaoco 9117 6 0.033 0.033 (.214) (.210) «例7 製造樣品7a及7b。經由母煉製程將砍化酤為140T之 脂瓌族樹脂ARKON P-140添加至實例4之薄膜。樣品7a及 7b中.芯雇之最终濃度為3涔及6涔之ARKON P-140。將薄 膜如下定向:MDX = 5 . 0 . TDX = 9.0。 經濟部中央揉準局員工消費合作杜印«. 樣品 ++ Μ 心層 樹 脂 同園之 老化之 改 質劑 y vtr W VTR 7a Affloco 9117 3 % 0.035 0.033 (.2 2 3 ) (.210) 7 b A醒oco 9117 6 % 0.033 0.030 (· 214) (.196) 1 6 本紙張尺度適用中國國家標準(CMS ) Α4规格(210Χ 297公釐) 91267 經濟部中央櫟準局貝工消費合作社印製 A7 B7 五、發明説明(17 ) 窖例8 製造樣品8a、8b及8c。經由母煉製法將氫化烴樹脂 REGALITE 101添加至實例4之薄顏。樣品8a、8b及8c中, 芯阐之最终濃度為1.5涔、3〆及6〆之Regalite 101。將 薄膜如下定向:MDX=5.0, TDX=9.0。 ---------裝------1Τ------《線 (請先閲讀背面之注意事項再填寫本頁) 樣品 芯層 知樹脂 改質劑 同圍之 WVTR 老化之 W VTR 8a Aaoco 9117 1.5 0.036 0.034 (.2 32 ) (.217) 8b Amoco 9117 3 0.034 0.031 (.219) (·20 0 ) 8c Aaoco 9117 6 0.032 0.030 (.2 0 8 ) (.193) 苜例 9 製造樣品9a 及9b。經由母煉製 法將 氫化烴樹脂 REGAL ITE 1 0 9 4添加至實例 4之薄膜 〇樣 品9a及9b中,S層 之鼉 终瀰度為3〆及6〆之R e g a 1 i t e 1094。將薄糗如下定丨 :MDX = 5 . 0 , TDX = 9 . 0 〇 本紙張尺度適用中國國家梂準(CNS ) Α4规格(210Χ297公釐) 17 9 1267 318168 A7 B7 五、發明説明(18 )Aging W VTR Printed by the Beige Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5 a A Xinjiang oc 9 117 3 0.035 0.030 (.2 2 7) (.194) 5 b A Tong oc 9117 6 0.032 0.027 (.2 0 6) (.1 76) 5 c A aoco 9 117 10 0.032 0.027 (.2 0 5) (.1 73) 15 This paper music standard uses the Chinese National Standard (CNS) A4 specification (210X297 mm) 9 1267 318168 at Β7 V. Description of the invention (1 Window example fi Manufacture samples 6a and 6b. The alicyclic resin ARKON P-125 with a chlorination point of 125 is added to the thin name of Example 4 through the master refining method. Samples 6a and 6b The final concentration of the core layer is ARKON P-125 of 3〆 and 6 抔. Orient the film as follows: MDX = 5.0, TDX = 9.0. (Please read the precautions on the back before filling this page), -1ΊΙ .ΤΤ __________ Γ -installed- ΪΤ- sample si heart %% modified resinous agent with the surrounding VVTR aged VVTR 6 a Amoco 9117 3 0.036 0.032 (.2 3 0) (.2 0 7) 6b Aaoco 9117 6 0.033 0.033 (. 214) (.210) «Example 7 Manufacture samples 7a and 7b. Add the ARKON P-140 resin, which is chopped to 140T, to the thickness of Example 4 through the mastering process Membrane. In samples 7a and 7b. The final concentration of the core is ARKON P-140 of 3 and 6. Orient the film as follows: MDX = 5.0. TDX = 9.0. Employee consumption cooperation印 «. Sample ++ Μ core layer resin aging modifier of the same garden y vtr W VTR 7a Affloco 9117 3% 0.035 0.033 (.2 2 3) (.210) 7 b A wake oco 9117 6% 0.033 0.030 ( · 214) (.196) 1 6 The size of this paper is in accordance with Chinese National Standard (CMS) Α4 specification (210Χ 297 mm) 91267 Printed A7 B7 by the Beiqi Consumer Cooperative of the Central Oak Quasi Bureau of the Ministry of Economic Affairs 5. Invention Instructions (17) Example 8 Samples 8a, 8b, and 8c were manufactured. The hydrogenated hydrocarbon resin REGALITE 101 was added to the thin color of Example 4 via a master refining method. In samples 8a, 8b, and 8c, the final concentration of the core was Regalite 101 at 1.5, 3, and 6〆. Orient the film as follows: MDX = 5.0, TDX = 9.0. --------- Installed ------ 1Τ ------ "Wire (please read the precautions on the back before filling in this page) The sample core layer knows the resin modifier WVTR Aging W VTR 8a Aaoco 9117 1.5 0.036 0.034 (.2 32) (.217) 8b Amoco 9117 3 0.034 0.031 (.219) (· 20 0) 8c Aaoco 9117 6 0.032 0.030 (.2 0 8) (.193) Alfalfa Example 9 Manufacture samples 9a and 9b. The hydrogenated hydrocarbon resin REGAL ITE 1 0 9 4 was added to the film 〇 samples 9a and 9b of Example 4 through a master refining method, and the final density of the S layer was 3 〆 and 6 〆 R e g a 1 i t e 1094. The thin rice is determined as follows: MDX = 5.0, TDX = 9.0. The paper size is applicable to China National Standards (CNS) Α4 specifications (210Χ297 mm) 17 9 1267 318168 A7 B7 5. Description of the invention (18)
樣品 芯層 樹脂 同園之 老化之 改質劑 WVTR WVTR 9a Aboco 9117 3〆 0.036 0.032 (.234 ), ( . 2 0 9 ) 9 b Aioco 9117 6 % 0.0 3 4 0.030 (.218) ( . 193) --------^ -裝-- (請先閱請背面之注意事項再填寫本頁) 奩例1 0 製造樣品l〇a及10b。經由母煉製法將另一氫化烴樹脂 REGAL ITE 1128添加至»例4之薄_。樣品10a及10b中•芯 鼷之最终濃度為3〆及6〆之Regalite 1128。將薄_如下 定向:MDX=5.0, TDX=9.0。Aging modifier WVTR WVTR 9a Aboco 9117 3〆0.036 0.032 (.234), (. 2 0 9) 9 b Aioco 9117 6% 0.0 3 4 0.030 (.218) (.193) -------- ^ -installation-- (Please read the precautions on the back before filling in this page) Example 10 0 Manufacturing samples l〇a and 10b. The other hydrogenated hydrocarbon resin REGAL ITE 1128 was added to the thin film of Example 4 through the master refining method. The final concentrations of cores in samples 10a and 10b are Regalite 1128 at 3〆 and 6〆. Orient the thin as follows: MDX = 5.0, TDX = 9.0.
、1J 線, 1J line
樣品 芯層 樹脂 同圃之 老化之 改質劑 WVTR WVTR 經濟部中央標準局負工消費合作社印製 10a Aioco 9117 3 0.0 3 5 0.0 3 4 (.2 2 7 ) (.2 1 7 ) 10b Aaoco 9117 6 % 0.0 3 5 0.0 3 1 (.2 2 8 ) (.202) 奮例1 1 本紙張尺度適用中國國家橾準(CNS ) A4规格(210X 297公釐) 18 91267 A7 B7 五、發明説明(19) 製造樣品11a及Ub。經由母煉製法將另一氫化烴樹脂 REGALITE 1139添加至實例4之薄膜。樣品11a及Ub中,芯 層之 下定 最终濃度各 向:M D X = 5 . 為3外及6〆之Regal ite 0, TDX = 9 . 0 〇 1139。將薄_如 樣品 芯 層 樹 脂 同圃之 老化之 改質劑 WVTR W VTR 11a A a 〇 c 〇 9117 3 % 0.037 0.034 (.2 40 ) (.217) lib Amoco 9117 6 % 0.037 0.033 (.2 37 ) (.210) --------^ .^-----^——訂 (請先閲讀背面之注意Ϋ項再填寫本頁) 經濟部中央樣準局属工消費合作社印装 奮例1 2 製造樣品12a、12b、12c及12d。將高结晶性聚丙烯( A»oco 9117,可得自伊利諾州,芝加哥布的Aaoco化學公 司)及其W熔融摻和方式添加而含有5以火、10wt外及 20wt〆之包括d-擎烯之秸烯聚合物(Piccolyte C-115,可 得自Hercules公司)之摻和體與Fina 8573共擠JK。將此組 合共擠颳及定向,Μ使之具有0.6微米之外表艚尺寸及20 微米之芯層尺寸。 本紙張尺度適用申國國家標準(CNS ) A4規格(210Χ2ίΠ公釐) 19 9 1267 318168 A7 B7 五、發明説明(20) 樣品 芯層 〆樹脂 改霣劑Sample core layer resin and aging modifier WVTR WVTR Printed by the Consumer Labor Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 10a Aioco 9117 3 0.0 3 5 0.0 3 4 (.2 2 7) (.2 1 7) 10b Aaoco 9117 6% 0.0 3 5 0.0 3 1 (.2 2 8) (.202) Endeavour 1 1 This paper size is applicable to China National Standard (CNS) A4 specification (210X 297 mm) 18 91267 A7 B7 V. Description of invention ( 19) Manufacture samples 11a and Ub. Another hydrogenated hydrocarbon resin REGALITE 1139 was added to the film of Example 4 via the master refining method. In samples 11a and Ub, the final concentration of the core layer is determined in each direction: M D X = 5. It is 3 outer and 6 〆 Regal ite 0, TDX = 9. 0 〇 1139. The thinner aging modifier WVTR W VTR 11a A a 〇c 〇9117 3% 0.037 0.034 (.2 40) (.217) lib Amoco 9117 6% 0.037 0.033 (.2 37 ) (.210) -------- ^. ^ ----- ^-order (please read the note Ϋ on the back first and then fill out this page) Printed by the Industrial and Consumer Cooperative Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Pretend example 1 2 Manufacture samples 12a, 12b, 12c and 12d. Highly crystalline polypropylene (A »oco 9117, available from Aaoco Chemical Company, Chicago, Illinois) and its W-melt blending method are added to contain 5 to fire, 10 wt and 20 wt, including d-engine A blend of olefinic straw polymer (Piccolyte C-115, available from Hercules) co-extruded with Fina 8573 JK. This combination was co-extruded and oriented so that M had a surface size of 0.6 micrometers and a core size of 20 micrometers. The scale of this paper is applicable to the national standard (CNS) A4 specification (210Χ2ίΠmm) 19 9 1267 318168 A7 B7 5. Description of the invention (20) Sample Core layer 〆Resin Modifier
同園之 W VTRW VTR of the same garden
老化之 WVTR 12a Aboco 9 117 0 - 0 . 0 3 9 ( 0 . 2 5 ) 12b A a o c ο 9117 5 - 0.0 3 1 ( 0.2 0 ) 12c A i o c o 9 117 10 - 0.031(0.20) 1 2d Aboco 9117 20 - 0.0 3 1 ( 0.2 0 ) 實例1 3 (請先閲讀背面之注意事項再填寫本頁) ------Γ -等 訂 製造樣品13a、13b及13c。將高结晶性聚丙烯(“oco 9117,可得自伊利諾州,芝加哥市的Aioco化學公司)及其 以熔融摻和方式添加而含有及6Wt〆之包括d-蓽烯之 枯稀聚合物(Piccolyte C-115,可得自Hercules公司)之 摻和«共擠臛及定向,Μ使之具有20»米之芯«尺寸。 樣品 芯層 經濟部中央標率局負工消費合作社印装 米樹脂 改霣爾Aging WVTR 12a Aboco 9 117 0-0. 0 3 9 (0. 2 5) 12b A aoc ο 9117 5-0.0 3 1 (0.2 0) 12c A ioco 9 117 10-0.031 (0.20) 1 2d Aboco 9117 20 -0.0 3 1 (0.2 0) Example 1 3 (please read the precautions on the back before filling in this page) ------ Γ-Order to manufacture samples 13a, 13b and 13c. A highly crystalline polypropylene ("oco 9117, available from Aioco Chemical Company, Chicago, Illinois) and its melt-blended addition containing 6 Wt 〆 of the dilute polymer including d-xylene ( Piccolyte C-115, available from Hercules) blending «co-extrusion and orientation, M to have a core size of 20» meters. Sample core layer printed by the Ministry of Economic Affairs, Central Standardization Bureau, negative work consumer cooperatives printing rice resin Change
同_之 WVTRSame as the WVTR
老化之 WVTR 13a A 〇 c 〇 9117 13b Aboco 9117 13c Ao c o 9117 0.034(0.22) 0.026(0.17) 0.026(0.17) 本纸張尺度適用中國國家橾準(CNS ) A4規冰(210X297公釐) 20 9 1267 318168 A7 __B7_ 五、發明説明(21) 製造搛品14a、 14b、 14c及14d,及澜量此等薄瞋之懺 器方向(HD)模數。各薄膜包括21微米厚之共擠SABA结構, 其芯«為19.5微米厚,係由[1{:15?(&道〇(:〇9218)形成且含 Arkon P-115樹脂改良劑者。該结構進一步包含一對相對 面之乙烯-丙烯-1-丁烯三聚物所形成之熱可密封表層( Chisso 7 5 0 4 )。表層包含 2 3 0 0 ppb 之 Sylobloc 44(—種包 括氧化砂之抗黏结劑)及8000ppb之_Dow Corning 200(—棰 聚二甲基矽氧烷)。各薄膜结構如下定向:MDX =參見下表, TDX = 9.0。樣品14a至14d之MD及TD镆數與類似之ΑΒΑ薄膜结 構(即,具有不含樹脂改質劑之定向習用聚丙烯之芯層的 樣品14e)之MD及TD模數。 --------C -裝— (請先閱讀背面之注意事項再填寫本頁) 經濟部中央樣準局貝工消費合作杜印裝 揉品 芯 改 樹脂 質劑 HDX MD横數 lOOOkPA TD模數 (IQOOps i) 14a A 鼸 o c ο 92 18 6 4,3 2 9 9 9 5 7 9 2 ( 4 3 5 ) ( 8 40 ) 14b A o c o 92 18 6 5 3 0 8 9 5 5 9 9 ( 448 ) (8 1 2 ) 14c A 通 o c o 92 18 3 5 29 37 5419 ( 4 2 6 ) ( 7 8 6 ) 1 4d A 圈 o c o 9 2 18 3 4.3 2 7 7 9 5 5 5 0 ( 4 0 3 ) (8 0 5 ) 1 4e F i n a 3 3 7 1 0 4 . 3 2 5 4 4 4 8 47 ( 36 9 ) ( 7 0 3 ) 本紙張尺度逍用中國11家橾準(CNS ) Α4规格(210Χ 297公釐) 21 91267 訂 318168 A7 B7 五、發明説明(22 ) 實例1〜13之结果綜合如下 經濟部中央揉率局員工消費合作社印袈 樣品 芯蘑 樹 脂 改質劑 同圍之 WVTR 老化之 WVTR 1 F i n a 3 37 1 0 % .048 .048 2a Exxon 46 12 0 % --- • 0 45 2b Exxon 4612 10 C-1 1 5 — .039 2c Exxon 4612 20 C-1 15 — .0 37 3a F i n a 3 3 7 1 0 — .050 3b F i n a 3 3 7 1 10 C - 11 5 — .0 42 3c F i n a 3 3 7 1 20 C-115 — .039 4 A i o c o 9117 0涔 .038 .034 5 a A i o c o 9117 3 % P - 11 5 .035 .030 5b A 釀 o c o 9117 6 % P-115 .032 .027 5 c A o c o 9117 1 0 % P - 1 1 5 .032 .027 6 a A B 0 C 0 9 117 3 % P - 1 25 .036 .032 6b A i o c o 9117 6 % P-125 .033 .033 7a A a o c o 9117 3 % P - 1 40 .035 .033 7b A o c o 9 117 6 ^ P - 1 40 .033 .030 8 a A π o c o 9117 1.5^ R - 1 0 1 .0 36 .034 8b A 臟 o c o 9 117 3〆 R - 1 0 1 .034 ,031 8c A a o c o 9 117 6 % R-101 .032 .0 30 9 a A o c o 9 117 3 % R - 1 094 .036 .032 本紙伕尺度適用中國團家梯準(CNS ) A4規格(210X297公釐) (請先閱讀背面之注意事項再填寫本頁) 22 9 1 2 6 7. mm 修正 附件二 曰 A7 B7 經濟部中央裸準局員工消費合作社印製 五、發明説明(23 ) 1 9b A 0 C 0 9117 6 % R -1094 • 034 .030 »1 I 10a Αι 0 C 0 9117 3 % R -1128 • 035 .034 、·ι 1 10b A B 0 C 0 9117 6〆 R -1128 • 035 .03 1 /--V 請 先 閱 讀 背 Λ 之 1 1 I 11a A » 0 C 0 9117 3〆 R -1139 • 037 .034 1 1 1 lib A 0 C 0 9117 6〆 R -1139 • 037 .033 1 1 12a A 0 C 0 9117 0 % ---- .039 V王 意 事 項 再 填 1 1 12b A 0 C 0 9117 5〆 C -115 — .031 1 ΛΙ 12c A 0 C 0 9117 10知 C -115 — .031 寫 本 頁 1 12d A n 0 C 0 9117 20〆 C -115 — .031 1 I 13a A雇 0 C 0 9117 0〆 — .034 1 1 1 13b A B 0 C 0 9117 3 % C -115 ——— .026 ϊ 1 1 13c A 0 C 0 9117 6 % C -115 ——— .026 訂 ♦ 為了 説 明 之 目的 » 将實 例 1、3, 5、 8及 12之WVTR對 % 樹 脂 改質 m 作 画 飨於 第 1園中。 如 所 示 ,當 改 質劑 之 百分比 白 0〆增至20〆時, 實例 Ai 2及3(兩者均代表先前技e)之層形基本上 保 持 直線 0 園 形 1 一般 呈 現 負 斜度 I 此表 示 當将改 質 劑添 加 至 樹 脂時 使 水 蒸 1 1 1 氣之 傳 输 減 少。 為 獲得 敢 大濕氣 障 壁, 必 須 添 加多 於 20〆 1 1 之改 質 m 至 樹脂 〇 然而 > 如上述 » 含大 ft 改 質 爾之 樹 脂 經 1 :| 常曾 減 少 尺 寸安 定 性、 可 加工性 及 可操 作 性 0 1 實 例 5、 8及 12之圈 形 説明本 發 明HCPP樹脂/改 質 m 摻 1 I 和醱 所 呈 現 之意 想 不到 之 待性。 更 明確 的 説 » 睡 諸_ 形 説 明 1 I 添加 少 置 改質剤至HCPP樹脂意想不到地大大減 低水 蒸 氣 之 1 1 I 傅输 0 此 點 顯示 在 園形 斜 度之初 始 陡度 0 當 更 多之 改 質 劑 1 1 本紙張尺度適用中國國家標準(CNS ) A4規格(2I0X297公釐) 23 (修正頁) 91267 .7 —— ¥ (况搞- 五、發明説明(24 ) 添加至HCPP樹脂,例如接近8外時,園形之斜度平坦下來 至實質上為零,顯示VVTR無進一步之減小。 述及另一方面,本發明之摻和醱以相對低量之改質_ ,即至多8重量〆及較佳3至6重量〆之改質劑逹到最小 WVTR。結果,可形成呈現實質上最大濕氣障壁之以聚丙烯 為主之薄膜,而不損失尺寸安定性、可加工性及可操作性 0 如實例14中所述,本發明之薄膜結構亦呈現比具有習 用之以OPP為主之芯層的薄膜結構意想不到之增加的M D及 TD棋數。很明顯地,此等MD及TD棋數之增加偽在相對低定 (請先閲讀背面之注意事項再填寫本頁) r 裝 響 影 面 負 無 度 清 例澄 實如 持例 雜性 而特 , 膜 成薄 所他 下其 向對 且 質 性 壁 障 氣 濕 良 改 之 示 所 之 率 效 造 製 > 0C 身 結 ,ιτ 加 增 由), 經質 滅 --- 5 的 1少 間 時 造 製 性 械 機 的 強 加 〇 生加 産增 下而 HD裂 低破 對的 相能 在可 可少 ί減 及 本 成 經濟部中央揉準局員工消費合作社印装 本紙張尺度逋用中國國家橾準(CMS ) Μ規格(210Χ297公釐〉 24 (修正頁) 91267Aging WVTR 13a A 〇c 〇9117 13b Aboco 9117 13c Ao co 9117 0.034 (0.22) 0.026 (0.17) 0.026 (0.17) This paper scale is applicable to China National Standards (CNS) A4 ice (210X297 mm) 20 9 1267 318168 A7 __B7_ V. Description of the invention (21) Manufacture of 14a, 14b, 14c and 14d, and the amount of thin-walled module (HD) modulus. Each film includes a 21-micron-thick co-extruded SABA structure with a core of 19.5 micron-thickness, which is formed of [1 {: 15? (&Amp; Door 〇 (: 〇9218) and contains an Arkon P-115 resin modifier. The structure further includes a pair of opposite heat-sealable skin layers (Chisso 7 5 0 4) formed by ethylene-propylene-1-butene trimer. The skin layer contains 2 3 0 0 ppb Sylobloc 44 (-including oxidation Sand anti-adhesive agent) and 8000ppb of _Dow Corning 200 (-dimethicone). The structure of each film is oriented as follows: MDX = see table below, TDX = 9.0. MD and TD of samples 14a to 14d The MD and TD modulus of the ABA film structure similar to that of the ABA film structure (ie, the sample 14e with a directional conventional polypropylene core layer without resin modifier). -------- C-装 — (Please Read the precautions on the back first and then fill out this page) Ministry of Economic Affairs Central Bureau of Samples and Accessories Beigong Consumer Co., Ltd. Du Printing and Kneading Product Core Modification Resin Agent HDX MD Horizontal Number lOOOkPA TD Modulus (IQOOps i) 14a A 鼸 oc ο 92 18 6 4,3 2 9 9 9 5 7 9 2 (4 3 5) (8 40) 14b A oco 92 18 6 5 3 0 8 9 5 5 9 9 (448) (8 1 2) 14c A pass oco 92 18 3 5 29 37 5419 (4 2 6) (7 8 6) 1 4d A circle oco 9 2 18 3 4.3 2 7 7 9 5 5 5 0 (4 0 3) (8 0 5) 1 4e F ina 3 3 7 1 0 4. 3 2 5 4 4 4 8 47 (36 9) (7 0 3) The paper size is easy to use 11 Chinese standards (CNS) A4 specifications (210 297 mm) 21 91267 order 318168 A7 B7 V. Description of the invention (22) The results of Examples 1 to 13 are summarized as follows: Central Ministry of Economic Affairs, Bureau of Consumers ’Cooperatives, Consumer Cooperatives, Printed Samples, Core Mushroom Resin Modifier, WVTR, Aging, WVTR 1 F ina 3 37 10%. 048 .048 2a Exxon 46 12 0% --- • 0 45 2b Exxon 4612 10 C-1 1 5 — .039 2c Exxon 4612 20 C-1 15 — .0 37 3a F ina 3 3 7 1 0 — .050 3b F ina 3 3 7 1 10 C-11 5 — .0 42 3c F ina 3 3 7 1 20 C-115 — .039 4 A ioco 9117 0 涔 .038 .034 5 a A ioco 9117 3% P-11 5 .035 .030 5b A brewed oco 9117 6% P-115 .032 .027 5 c A oco 9117 1 0% P-1 1 5 .032 .027 6 a AB 0 C 0 9 117 3% P-1 25 .036 .032 6b A ioco 9117 6% P-125 .033 .033 7a A aoco 9117 3% P-1 40 .035 .033 7b A oco 9 117 6 ^ P-1 40 .033 .030 8 a A π oco 9117 1.5 ^ R-1 0 1 .0 36 .034 8b A dirty oco 9 117 3〆R -1 0 1 .034, 031 8c A aoco 9 117 6% R-101 .032 .0 30 9 a A oco 9 117 3% R-1 094 .036 .032 The paper size standard is applicable to China Tuanjia Standard (CNS ) A4 specification (210X297mm) (Please read the precautions on the back before filling in this page) 22 9 1 2 6 7. mm Amendment Attachment 2: A7 B7 Printed by the Employees ’Consumer Cooperative of the Central Bureau of Nursing of the Ministry of Economic Affairs (23) 1 9b A 0 C 0 9117 6% R -1094 • 034 .030 »1 I 10a Αι 0 C 0 9117 3% R -1128 • 035 .034, ι 1 10b AB 0 C 0 9117 6〆R -1128 • 035 .03 1 /-V Please read the first 1 I 11a A »0 C 0 9117 3〆R -1139 • 037 .034 1 1 1 lib A 0 C 0 9117 6〆R -1139 • 037 .033 1 1 12a A 0 C 0 9117 0% ---- .039 V Wang Yi matter and then fill 1 1 12b A 0 C 0 9117 5〆C -115 — .031 1 ΛΙ 12c A 0 C 0 9117 10 know C -115 .031 write this page 1 12d A n 0 C 0 9117 20〆C -115 — .031 1 I 13a A employed 0 C 0 9117 0〆— .034 1 1 1 13b AB 0 C 0 9117 3% C -115 — —— .026 ϊ 1 1 13c A 0 C 0 9117 6% C -115 ——— .026 For the purpose of illustration »The WVTR of examples 1, 3, 5, 8 and 12 are painted on% resin modified m In the first garden. As shown, when the percentage of modifier is increased from 0〆 to 20〆, the layer shape of Examples Ai 2 and 3 (both represent the prior art e) basically maintains a straight line. 0 Round shape 1 generally exhibits a negative slope I This means that when the modifier is added to the resin, the transmission of water vapor is reduced. In order to obtain a large moisture barrier, it is necessary to add more than 20 〆 1 1 of modified m to the resin. However, as described above »The resin containing the modified ft of large ft 1: | often has reduced dimensional stability and can be processed And operability 0 1 The circles of Examples 5, 8 and 12 illustrate the unexpected hospitality presented by the HCPP resin / modified m-doped 1 I and XI of the present invention. To be more specific »睡 诸 _ Shape description 1 I Adding less modification to the HCPP resin unexpectedly greatly reduces the water vapor 1 1 I Fu lose 0 This point shows the initial steepness of the slope of the circle 0 when more Many modifiers 1 1 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (2I0X297mm) 23 (Amendment page) 91267.7 —— ¥ (Condition-V. Description of invention (24) Added to HCPP resin For example, when it is close to 8, the slope of the circle is flattened to substantially zero, indicating that there is no further reduction in VVTR. On the other hand, the blending compound of the present invention is modified with a relatively low amount_, that is Up to 8 weight 〆 and preferably 3 to 6 weight 〆 modifiers to the minimum WVTR. As a result, a polypropylene-based film that exhibits a substantially maximum moisture barrier can be formed without loss of dimensional stability and processability Performance and operability 0 As described in Example 14, the film structure of the present invention also exhibits unexpectedly increased MD and TD numbers compared to the film structure with a conventional OPP-based core layer. Obviously, this Wait for the increase in the number of MD and TD For low setting (please read the precautions on the back and then fill in this page) r The negative surface of the sound pretends to be indefinitely clear, and the case is as complicated as the case. The film is thin and the opposite is the qualitative barrier. The efficiency and effectiveness of the demonstration of good gas and humidity improvement> 0C body knot, ιτ increase and increase), the quality of the extinction --- 5 of the time of the mechanical machine made by the time of forced production and production increase The HD energy is low and the corresponding energy is reduced in cocoa and the cost is printed in the Cooperative Staff Cooperative Association of the Ministry of Economic Affairs of the Ministry of Economy. The paper size is based on the Chinese National Standard (CMS) M specification (210Χ297mm) 24 (Amendment page ) 91267
Claims (1)
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US49008195A | 1995-06-13 | 1995-06-13 | |
US54220995A | 1995-10-12 | 1995-10-12 |
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TW318168B true TW318168B (en) | 1997-10-21 |
Family
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TW085109876A TW318168B (en) | 1995-06-13 | 1996-08-14 |
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JP (1) | JPH11507605A (en) |
KR (1) | KR19990022828A (en) |
AU (1) | AU697293B2 (en) |
CA (1) | CA2223547A1 (en) |
TW (1) | TW318168B (en) |
WO (1) | WO1996041718A1 (en) |
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US6844078B2 (en) † | 2002-02-06 | 2005-01-18 | Toray Plastics (America) Inc. | Polyolefin oil resistant film using high isotactic content polypropylene |
AU2003228218A1 (en) * | 2002-02-21 | 2003-09-09 | Toray Plastics (America), Inc. | Biaxially oriented polypropylene high barrier metallized film for packaging |
EP2428357A4 (en) * | 2009-05-06 | 2012-10-17 | Extrusion De Resinas Vinilicas S A | Method for producing biaxially oriented polypropylene film for hot lamination without a coating phase |
CN102673060A (en) * | 2012-05-24 | 2012-09-19 | 海宁市粤海彩印有限公司 | Highly-smooth polyethylene film and manufacturing method thereof |
WO2021140382A1 (en) | 2020-01-06 | 2021-07-15 | Flint Hills Resources, Lp | Polymeric substrate including a barrier layer |
KR20230123782A (en) | 2022-02-17 | 2023-08-24 | 주식회사 디엔솔루션즈 | Wireless communication control device and control method of detachable tool holder |
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GB8613161D0 (en) * | 1986-05-30 | 1986-07-02 | Exxon Chemical Patents Inc | Sealable films |
US5489473A (en) * | 1994-04-07 | 1996-02-06 | Borden, Inc. | Biaxially and monoaxially oriented polypropylene cold seal release film |
US5500282A (en) * | 1994-07-15 | 1996-03-19 | Mobil Oil Corporation | High moisture barrier OPP film containing high crystallinity polypropylene and terpene polymer |
-
1996
- 1996-03-28 CA CA002223547A patent/CA2223547A1/en not_active Abandoned
- 1996-03-28 JP JP9503035A patent/JPH11507605A/en not_active Ceased
- 1996-03-28 KR KR1019970709297A patent/KR19990022828A/en not_active Application Discontinuation
- 1996-03-28 AU AU53818/96A patent/AU697293B2/en not_active Ceased
- 1996-03-28 WO PCT/US1996/004444 patent/WO1996041718A1/en not_active Application Discontinuation
- 1996-08-14 TW TW085109876A patent/TW318168B/zh active
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JPH11507605A (en) | 1999-07-06 |
WO1996041718A1 (en) | 1996-12-27 |
AU697293B2 (en) | 1998-10-01 |
AU5381896A (en) | 1997-01-09 |
CA2223547A1 (en) | 1996-12-27 |
KR19990022828A (en) | 1999-03-25 |
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