316923 經濟部中央樣準局貝工消费合作杜印装 A7 五、發明説明（ 技術領域 本發明係關於清潔硬表面之液態組合物。 發明背景 液態硬表面清潔劑應有某些黏度的特性是技藝中所熟知 的。確實地當與較稀薄的產品比較時，黏度可以使產品在 使用時能控制處理，更能特別地分散。還有黏性可使產品 在非水平的表面上有更好的作用，如馬桶、浴缸及類似者 。那是因爲黏性避免了產品像稀薄液體一樣跑離該表面。 較佳地黏度是由所謂的自己增稠系統而非做爲此特別目的 之增稠化合物。確實增稠劑如膠或聚合物至少有一缺點即 其影響到配方的成本而只提供唯一増稠的好處。它們並不 參與實際表面的清潔因而可謂爲"鈍性"物質，還有某些增 稠劑不利於其所調製成產品之物理安定性。在技藝中調配 自己增稠組合物，其增稠非使用聚合物之增稠劑所達到者 見實例如歐洲專利第518401號和歐洲專利第21581號。 但是有某些缺點與黏性有關。而一主要缺點爲黏性產品 典型地較難沖掉，特別因爲黏性物質在表面上有好的黏性 目前的自己増稠系統會有穩定泡朱的調配物。因此黏性和 好沖洗多少有些衝突，但兩者在用於清潔硬表面的單一產 品中都是需要的。因此本發明之一目的爲提供一種硬表面 清潔組合物，其爲有由自己增稠系統而來的黏性且仍然容 易沖洗掉。 在應驗後我們發現此種組合物可藉著使用氧化胺、胺或 其混合物與二級或一級單鏈烷基硫酸塩或磺酸塩在溫和的 私紙張尺度適用中國國家標準（CNS ) Α4规格（210X297公釐） 裝-- (請先閲讀背面之注意事少為填寫本頁) 、?τ •IJ. A7 B7 經濟部中央揉準局貝工消費合作社印製 五、發明説明（2 酸性系統中更包括了助溶劑和檸檬酸。此外之一利益衍生 自該组合物者爲其是低泡沫、無論其爲使用時起初產生泡 沫量的感覺或是就泡沫安定性論均是。此益處增加易沖洗 的好處已經由衍生自組合物黏度得到"機械式"益處。 發明摘述 本發明爲一種水狀黏性組合物，含有氧化胺、胺或其混 合物與二級或一級單支鏈烷基硫酸垣或續酸垣在過量的該 氧化胺、胺或其混合物中，以及助溶劑和有機酸，該組合 物調配爲pH從0.5至7。 發明説明 根據本發明之組合物爲水性組合物。因此它們食有全部 组合物重量比90%到60%的水。本發明之一成就爲此後所 述黏度的建立可以用如此大量的水達到，即用少量的活性 物質。 做爲第二重要的成份本組合物包含了氧化胺、或胺，或 其混合物。根據本發明所用適合的氧化胺爲依據通式 R1R2R3NO，其中R1爲碳氫鏈含有6至18個碳原子，而 R2和R3爲獨立的碳氳鏈含有高至3個碳原子或爲其混合 物。用於此較佳之氧化胺其R1含8至14個碳原子，較佳地 爲C8-C10氧化胺或C12-C14氧化胺而R2和R3兩者爲甲 基。此種C8-C10氧化胺市場上可得者爲來自Lonza商品 名爲Barlox®10S。此種C12-C14氧化胺適用於此者爲 市上可得來自Hoechst商品名爲Genanimox®LA。另外 適合的氧化胺可用於此者爲市上可得來自AKZO ino 本紙張尺度逋用中國國家標準（CNS ) A4规格（210X297公釐） (請先聞讀背面之注意事少為填寫本頁) 裝· 訂-· -5- 經濟部中央標準局貝工消費合作社印製 ^16923 A7 — _ B7 五、發明説明（3 )316923 Ministry of Economic Affairs, Central Bureau of Standards, Beigong Consumer Cooperation Du Printing Pack A7 V. Description of the invention (Technical Field The present invention relates to liquid compositions for cleaning hard surfaces. BACKGROUND OF THE INVENTION Liquid hard surface cleaners should have certain viscosity characteristics. It is well known. Indeed, when compared to thinner products, the viscosity allows the product to be controlled during use and can be more specifically dispersed. The viscosity also allows the product to have a better surface on non-level surfaces Functions, such as toilets, bathtubs, and the like. That is because the viscosity prevents the product from running away from the surface like a thin liquid. Preferably, the viscosity is caused by the so-called self-thickening system rather than a thickening compound for this special purpose It is true that thickeners such as gums or polymers have at least one drawback, which affects the cost of the formulation and only provides the only thickening benefit. They do not participate in the cleaning of the actual surface and can be described as " passive " substances, and Some thickeners are not conducive to the physical stability of the products they are formulated. In the art, the thickening composition is prepared by itself, and its thickening is not achieved by the use of polymer thickeners. See examples such as European Patent No. 518401 and European Patent No. 21581. However, there are certain disadvantages related to viscosity. One major disadvantage is that viscous products are typically difficult to wash out, especially because the viscous substance is on the surface Good viscosity The current thickening system of your own will have a stable foam formulation. So there is some conflict between viscosity and good rinsing, but both are needed in a single product for cleaning hard surfaces. So this One of the objects of the invention is to provide a hard surface cleaning composition which is viscous from its own thickening system and is still easy to rinse off. After examination, we found that this composition can be used by using amine oxide, amine or The mixture of the mixture with the second-level or first-level single-chain alkyl sulfate or sulfonic acid is suitable for the Chinese private standard (CNS) Α4 specification (210X297mm) in the mild private paper standard-(please read the notes on the back first. (Fill in this page),? Τ IJ. A7 B7 Printed by the Ministry of Economic Affairs, Central Bureau of Economic Development, Beigong Consumer Cooperative V. Description of the invention (2 The acid system also includes co-solvents and citric acid. One of the benefits is derived from The composition is low foam, whether it is the feeling of the amount of foam generated at the time of use, or in terms of foam stability. This benefit of increased ease of washing has been derived from the viscosity of the composition " mechanical " Benefits Summary of the Invention The present invention is an aqueous viscous composition comprising an amine oxide, an amine or a mixture thereof and a secondary or primary single-branched alkyl sulfate or continuous acid in excess of the amine oxide, amine or In its mixture, as well as co-solvent and organic acid, the composition is formulated with a pH from 0.5 to 7. DESCRIPTION OF THE INVENTION The composition according to the invention is an aqueous composition. Therefore, they contain 90% to 60% by weight of the total composition Water. One of the achievements of the present invention is that the establishment of the viscosity described later can be achieved with such a large amount of water, that is, with a small amount of active substance. As the second most important ingredient, the composition contains amine oxide, or amine, or a mixture thereof. Suitable amine oxides for use according to the invention are according to the general formula R1R2R3NO, where R1 is a hydrocarbon chain containing 6 to 18 carbon atoms, and R2 and R3 are independent carbon chains containing up to 3 carbon atoms or a mixture thereof. For this preferred amine oxide, R1 contains 8 to 14 carbon atoms, preferably C8-C10 amine oxide or C12-C14 amine oxide and both R2 and R3 are methyl groups. This type of C8-C10 amine oxide is commercially available under the trade name Barlox® 10S from Lonza. This type of C12-C14 amine oxide is suitable for this and is commercially available from Hoechst under the trade name Genanimox® LA. In addition, suitable amine oxide can be used for this. It is commercially available from AKZO ino. This paper standard uses the Chinese National Standard (CNS) A4 specification (210X297mm) (please read the notes on the back side to fill out this page) Binding · Order--5- Printed by Beigong Consumer Cooperative of Central Bureau of Standards of Ministry of Economics ^ 16923 A7 — _ B7 V. Description of invention (3)
Aromox®DMMCO-W。適合的胺根據本發明可用者爲依 照通式R1R2R3N，其中R1爲含6至18個碳原子之破氫鏈 ，而R2和R3各自獨立地爲氫或含高至3個碳原子的碳氫 鏈或其混合物。用於此之較佳的胺爲其R1含8至12個碳原 子而R2和R3獨立地爲甲基或氫。 根據本發明組合物中較佳地氧化胺或胺或其混合物全部 的量爲全部組合物重量比的0.3 %至5.0%，更佳地爲 0.5 % 至 1.2 %。 做爲第三個重要成份本組合物包含了二級或一級單支鏈 烷基硫酸造或磺酸迄或其混合物。二級烷基硫酸造或續酸 塩意謂在此之烷基硫酸塩或磺酸塩其烷基鏈含1〇至16個 碳原子，較佳地爲12至14個，且其中此烷基鏈在任一端 點均未硫酸化或碟酸化。而一級的支鏈硫酸造或續酸迄， 意謂在此之烷基硫酸迄或續酸迄其坑基鏈含有1〇至16個 碳原子，較佳地爲12至14個，且其中此烷基鏈爲支鏈含 有烷基取代基’至少一個碳離開硫酸基或磺酸基，即從硫 酸基或磺酸基编號在烷基鏈上第2或更多的位置上。我們 發現有支鏈烷基是很重要的，即使用直鏈烷基並不能提供 根據本發明之益處，但其顯示那一支鏈在烷基鏈中並無關 係。使用含全部12個碳原子之烷基鏈的烷基硫酸塩-乙·丁 基辛基硫酸鈉我們得到良好的結果^此種烷基硫酸迄市場 上可得者來自Condea之商品名Isofol®12S。烷基磺酸 垣之實例爲來自Hoechst之Hostapur®SAS。二級或一 級單支鏈烷基硫酸塩或磺酸塩在本組合物中的量視其他在 本紙張尺度適用中國困家榡準（CNS ) A4規格（210X297公釐） ~Aromox®DMMCO-W. Suitable amines according to the invention are available according to the general formula R1R2R3N, where R1 is a hydrogen-breaking chain containing 6 to 18 carbon atoms, and R2 and R3 are each independently hydrogen or a hydrocarbon chain containing up to 3 carbon atoms Or mixtures thereof. The preferred amine for this is that R1 contains 8 to 12 carbon atoms and R2 and R3 are independently methyl or hydrogen. The total amount of amine oxide or amine or a mixture thereof in the composition according to the present invention is preferably 0.3% to 5.0% by weight of the total composition, more preferably 0.5% to 1.2%. As the third important ingredient, the composition contains secondary or primary single-branched alkyl sulfate or sulfonic acid or a mixture thereof. Secondary alkyl sulfuric acid or continuous acid salt means that the alkyl sulfate salt or sulfonic acid salt here has an alkyl chain containing 10 to 16 carbon atoms, preferably 12 to 14, and wherein this alkyl The chain was not sulfated or dish acidized at either end. The first-level branched-chain sulfuric acid production or acid renewal means that the alkyl sulfuric acid or acid renewal here contains 10 to 16 carbon atoms in the pit base chain, preferably 12 to 14, and wherein this The alkyl chain is a branched chain containing an alkyl substituent 'at least one carbon leaving the sulfate group or sulfonic acid group, that is, numbered from the sulfate group or sulfonic acid group at the second or more positions on the alkyl chain. We have found that it is important to have a branched alkyl group, that is, the use of a linear alkyl group does not provide the benefits according to the present invention, but it shows that the branch in the alkyl chain is irrelevant. Using alkyl sulfates containing all 12 carbon atoms in the alkyl sulfate-ethyl · butyl octyl sodium sulfate we have obtained good results. ^ This type of alkyl sulfuric acid is available on the market from Condea under the trade name Isofol® 12S . An example of an alkylsulfonic acid is Hostapur® SAS from Hoechst. The amount of secondary or primary single-branched alkyl sulfate or sulfonate in this composition depends on the others. The paper standard is applicable to China's Standards for Confinement (CNS) A4 (210X297mm) ~
A (請先閲讀背面之注意事+為填寫本頁) 裝. Λ 916923 A7 B7 五、發明説明（4 ) 組合物中物質氧化胺或胺或其混合物的量而定，但在此二 級或一級單支鏈烷基硫酸塩或磺酸塩一般含有全部組合物 重量比的3%至20%之間，較佳地在4%和7%之間。重要 的是本組合物應含有該二級或一級單支鏈垸基硫酸迄或續 酸逸超過氧化胺’胺或其混合物即在本組合物中燒基硫 酸塩或磺酸逡的量應大於氧化胺'胺或其混合物的量。 作爲第四種重要成份，本組合物包含了有機酸或其混合 物。用於此較佳之有機酸之pK値低於6。適合的這種有機 酸爲選自包括檸檬酸、乳酸、乙二醇酸、琥珀酸、戊二酸 和己二酸及其组合物。適用於此之該酸的組合物市場上可 得者爲來自BASF之商品名Sokalan®DCS者。用於此較 佳的酸爲檸檬酸。此種酸已被發現能在黏度的組成上及組 合物的安定上提供所需之益處。我們已發現在檸檬酸下2〇 °C時至少30天沒有相分離發生，甚至高至5(TC也有3 0天 。在此有機酸的量可以視這裏其他成份的量而定，但此酸 適當的量一般含全部組合物重量比的1%和20 %之間，較 佳地在4 %和8 %之間，特別地當使用檸檬酸時。 在此第五項重要成份爲助溶劑。助溶劑在此意謂一種幫 助溶解組合物中疏水性成份的試劑。我們發現助溶劑參與 黏度的構成且增加組合物的安定性。用於此之適當助溶劑 包括非離子界面活性劑和有機溶劑及其混合物。用在這裏 之適當非離子爲烷氧化醇類一般含6至16個碳原子於醇的 燒基鏈部份。典型的烷氧化基爲乙氧基和丙氧基。此種化 合物以Shell之Dobanol®系列或BASF之Lutensol®含 本紙張尺度適用中國國家榇準（CNS ) A4规格（210X297公釐） (請先聞讀背面之注意事^ 裝-- ?填寫本頁) 訂 經濟部中央揉準局炎工消費合作社印製 A7 ______B7 五、發明説明（5 ) 廣大範園的鏈長和烷氧化程度者爲市場上可得。用於此較 佳之非離子界面活性劑爲依據通式反（父）1111者，其R爲含6 至16個碳原子的烷基鏈，較佳地爲6至1〇個，X爲烷氧基 ，較佳地爲乙氧基或乙氧基和丙氧基的混合物，11爲4至 30的整數，較佳地爲5至8 ,用於此之適當溶劑爲有機溶 劑’較佳地爲醇類或其醚類，或爲其混合物。一般可得適 用於此之溶劑爲包括正·丁氧基丙氧基丙醇（n_Bpp)、丙 二醇和丁基二乙二醇鼓（BDGE)。助溶劑的量可視其中其 他成份的量而疋，但此中助溶劑適當的量一般含全部組合 物重量比的1 %和10%之間，較佳地爲2 %和4 %之間。 此中第六項重要特性爲pH，其要從〇.5至7。但我們發 現當本組合物調配到接近此pH範圍的更高端點，組合物 的全部溶解度更低，因此要合併疏水性成份更困難，典型 地爲香水。還有在pH7之後不能提供所需的黏度。在相對 的端點，當pH低時則在此之前所需氧化胺的量更多。在 此較佳的pH範圍約爲2至6，最佳地爲3至4。 本組合物可由混合所有成份一起而製造，保持氧化胺、 或胺或其混合物，或二級或一級單支鏈烷基硫酸塩或磺酸 迄爲最後一項。直到此最後成份加入前沒有或只有一點點 黏度可見。到加入氧化胺、胺或其混合物或二級或一級單 支鏈坑基硫酸塩或磺酸塩則形成不透明溶液，其在所有成 份加入後被增稠。此不透明溶液在增稠後變得較透明。且 在某些例子中已得到透明產物。在光學顯微鏡下可見不透 明趙，我們推測是由於雙連續相，其在增稠上導致緊密包 心張从適用中國躅家梂準（CNS)八4胁（210χ297公着） _ n^i HI a (請先聞讀背面之注意Ϋ填寫本頁) 裝------訂.--；---- 經濟部中央揉準局貝工消费合作社印製A (please read the precautions on the back + fill in this page first). Install. Λ 916923 A7 B7 5. Description of the invention (4) The amount of amine oxide or amine or its mixture in the composition depends on the amount of The first-stage single-branched alkyl sulfate or sulfonate generally contains between 3% and 20% by weight of the total composition, preferably between 4% and 7%. It is important that the composition should contain the secondary or primary single-branched alkyl sulphuric acid until or after the acid surpasses the amine oxide 'amine or its mixture. The amount of amine oxide 'amine or a mixture thereof. As the fourth important ingredient, the composition contains an organic acid or a mixture thereof. The pK value for this preferred organic acid is less than 6. Suitable such organic acids are selected from the group consisting of citric acid, lactic acid, glycolic acid, succinic acid, glutaric acid and adipic acid, and combinations thereof. A commercially available composition of the acid suitable for this is available under the trade name Sokalan® DCS from BASF. The preferred acid for this is citric acid. Such acids have been found to provide the desired benefits in terms of viscosity composition and stability of the composition. We have found that at 20 ° C under citric acid there is no phase separation for at least 30 days, even as high as 5 (TC also has 30 days. The amount of organic acid here can depend on the amount of other ingredients here, but this acid Appropriate amounts generally contain between 1% and 20% by weight of the total composition, preferably between 4% and 8%, especially when citric acid is used. The fifth important ingredient here is a co-solvent. Co-solvent here means an agent that helps to dissolve hydrophobic components in the composition. We found that the co-solvent participates in the composition of viscosity and increases the stability of the composition. Suitable co-solvents for this include nonionic surfactants and organic solvents And mixtures thereof. Suitable non-ions used herein are alkoxylated alcohols which generally contain 6 to 16 carbon atoms in the burnt chain portion of the alcohol. Typical alkoxylated groups are ethoxy and propoxy. Applicable to China's National Standard (CNS) A4 (210X297mm) based on Shell's Dobanol® series or BASF's Lutensol® containing paper standard (please read the notes on the back ^ Pack-? Fill in this page) order economy Printed by Yangong Consumer Cooperatives System A7 ______B7 V. Description of the invention (5) The chain length and the degree of alkane oxidation of the majority of Fanyuan are available on the market. The preferred nonionic surfactant for this is based on the general formula (Father) 1111, whose R Is an alkyl chain containing 6 to 16 carbon atoms, preferably 6 to 10, X is alkoxy, preferably ethoxy or a mixture of ethoxy and propoxy, 11 is 4 Integer to 30, preferably 5 to 8, suitable solvents for this are organic solvents, preferably alcohols or their ethers, or mixtures thereof. Generally available solvents suitable for this include positive · Butoxy propoxy propanol (n_Bpp), propylene glycol and butyl diethylene glycol drum (BDGE). The amount of co-solvent can be determined according to the amount of other ingredients, but the appropriate amount of co-solvent generally contains all The weight ratio of the composition is between 1% and 10%, preferably between 2% and 4%. The sixth important characteristic is pH, which is from 0.5 to 7. But we found that when this combination The composition is adjusted to the higher end of this pH range, the overall solubility of the composition is lower, so it is more difficult to incorporate hydrophobic ingredients, typically perfume . There is also a failure to provide the required viscosity after pH 7. At the opposite end, when the pH is low, the amount of amine oxide required before then is greater. The preferred pH range here is about 2 to 6, the most It is preferably 3 to 4. This composition can be manufactured by mixing all the ingredients together, keeping the amine oxide, or amine or mixture thereof, or the secondary or primary monobranched alkyl sulfate or sulfonic acid as the last item. No or only a little viscosity is visible before the addition of this last ingredient. To the addition of amine oxides, amines or mixtures thereof, or secondary or primary single-chain pit sulfate or sulfonate, an opaque solution is formed, which is added after all ingredients are added Thickening. This opaque solution becomes more transparent after thickening. And in some cases, transparent products have been obtained. Opaque Zhao can be seen under an optical microscope. We speculate that it is due to the bicontinuous phase, which leads to a dense core in the thickening. From the application of the Chinese Family Housing Standard (CNS) Ba 4 threat (210χ297 public) (Please read the note on the back first and fill in this page) Installed ------ ordered.-; ---- Printed by Beigong Consumer Cooperative of Central Bureau of Economic Development of the Ministry of Economic Affairs
π I—------------- I -8 - 916923 A7 _ B7 五、發明説明（6 ) 覆的流體其提供所需的黏度。其顯示有不溶性的成份存在 。本組合物最後達到黏度從5 〇釐泊至5 0 0 〇釐泊在6 0轉每 分鐘切速率下以Brooke field黏度計2號軸所做，較佳地 達到1 0 0釐泊至3 0 0釐泊。 在此系統中咸信氧化胺和/或胺被質子化這是由於酸性 pH’並且形成離子對與二級烷基硫酸塩或磺酸塩於系統 中。此離子對構成疏水物質。我們推測二級烷基硫酸塩過 量地與助溶劑/親水物質及有機酸結合形成擴大的/網狀的 結構於水相中。這導致組合物的稠化以提供所需的黏度。 此外疏水離子對的存在本身顯示賦予了抗泡沫性質，因此 有沖洗掉的益處。 作爲選用但極爲佳的成份，本組合物含有香水成份，通 常爲此種成份的混合物。確實地香水成份典型地爲疏水性 物質已發現對黏度建立上的貢獻也許是藉由其支持產品的 相結構，且其増進產品全部的安定性。香水在此意謂其構 成只因或基本上爲其在嗅覺上的貫獻而加入。香水成份可 爲天然之產物如精油、絕對的事物、樹脂類、樹脂、凝結 物等，而合成的香水成份如破氫化物、醇類、接類、明類 、醚類、酸類、乙縮醛、縮酮、腈等，包括飽和和不飽和 化合物、脂肪族、碳環族和雜環化合物。此種香水成份的 實例爲；香葉醇、醋酸香葉酯沉香醇、醋酸沉香酯、四 氫沉香醇、香茅酯、醋酸香茅酯、二氫香葉烯醇、醋酸二 氫香葉烯酯、四氫香葉烯醇、帖品醇、醋酸帖品酯、諾甫 醇、醋酸諾甫酯、2-苯基乙醇、醋酸-2-苯基乙酯、苯甲 本紙張尺度適用中國國家揉準（CNS ) A4规格（210X297公釐） (請先聞讀背面之注π I —------------- I -8-916923 A7 _ B7 5. Description of the invention (6) The covered fluid provides the required viscosity. It shows the presence of insoluble ingredients. The composition finally achieves a viscosity from 50 centipoise to 5000 centipoise at a cutting speed of 60 revolutions per minute using Brookfield viscosity meter No. 2 shaft, preferably reaching 100 centipoise to 3 0 0 centipoise. In this system, the amine oxide and / or amine are protonated due to the acidic pH 'and form an ion pair with the secondary alkyl sulfate or sulfonate in the system. This ion pair constitutes a hydrophobic substance. We speculate that secondary alkyl sulfates excessively combine with co-solvents / hydrophilic substances and organic acids to form an expanded / reticulated structure in the aqueous phase. This causes the composition to thicken to provide the desired viscosity. In addition, the presence of hydrophobic ion pairs itself is shown to impart anti-foaming properties, and therefore has the benefit of being rinsed off. As an optional but extremely good ingredient, the composition contains perfume ingredients, usually a mixture of such ingredients. It is true that perfume ingredients are typically hydrophobic substances. It has been found that the contribution to viscosity establishment may be through its support for the phase structure of the product and its increase in the overall stability of the product. Perfume here means that its composition is added only or basically for its olfactory dedication. Perfume ingredients can be natural products such as essential oils, absolute things, resins, resins, coagulum, etc., while synthetic perfume ingredients such as hydride dehydration, alcohols, joints, brights, ethers, acids, acetals , Ketals, nitriles, etc., including saturated and unsaturated compounds, aliphatic, carbocyclic and heterocyclic compounds. Examples of such perfume ingredients are; geraniol, geranyl acetate linalool, geranyl acetate, tetrahydrolinalool, citronellate, citronellyl acetate, dihydrogeraniol, dihydrogeraniol acetate Ester, Tetrahydrogeraniol, Tipinol, Tipinate Acetate, Novopropanol, Norfolate Acetate, 2-phenylethanol, 2-phenylethyl acetate, benzoic acid Kneading (CNS) A4 specification (210X297mm) (Please read the note on the back first
經濟部中央揉準局貝工消费合作社印製 裝------訂.--；----"%冰---；--------------- 填寫本頁) -9 - A7 B7 經濟部中央橾準局貝工消費合作社印製 五、發明説明（7 ) 醇、酷酸苯甲酯、水楊酸苯甲酯、苯甲酸苯甲脂、 Styrallyl Acetate、水楊酸戊酯、二甲基苯甲基甲醇、 醋酸三氣甲基苯甲基甲酯、醋酸對特丁基環己酯、醋酸異 壬酯、醋酸印鬚酯、印鬚芒醇、α·正-戊基肉桂醛、α_ 己基肉桂醛、2 -甲基- 3- (對特丁基苯基丙醛、2_甲基· 3-(對異丙基苯基）丙搭、3-(對特丁基苯基）丙遂、醋酸三 環癸缔酯、丙酸三環癸烯酯、4-(4-羥基-4_甲基戊基）· 3 -環己晞搭' 4-(4 -甲基-3-戊基）-3 -環己締搭、4 -乙磁 氧基-3-戊基-四氫吡喃、二氳茉莉酸甲酯、2_正庚基-環 戊酮、3 -甲基-2-戊基-環戊明、正癸搭、正十二搭、9_癸 烯-1-醇、異丁酸苯氧基乙酯、苯基乙醛二菫基乙縮醛、 苯基乙搭二乙基乙縮越、香葉腈、香茅腈、醋酸雪松酯、 3 -異龍腦基環己醇、雪松醚、異長葉闞、茴香醛腈、茴香 趁 '向日葵醛、香豆素、丁香酚、香草醛、二苯基氧化物 、幾基香茅酸、紫羅酮、甲基紫羅酮、異甲基紫羅酮、馬 蘭根素、順己晞醇和其酯類、茚滿磨香、萘滿麝香、 異色滿麝香、巨環酮類、巨内酯麝香、次乙基巴西基酸、 芳香族硝基麝香。本組合物典型地含有全部組合物重量比 0 . 1 °/。至2 %之香水成份或其混合物，較佳地爲〇丨％至 1.0% 〇 本組合物可以含有各式其他成份，包括更多的活性物和 只有美感上成份如染料及相似者。特別地本組合物之流變 學會適合懸浮粒子於組合物中，如實例研磨的粒子。 實例-實驗教據 (請先聞讀背面之注意事爭姜填寫本頁) Γ4 裝- ΗPrinted and printed by the Beigong Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs ------ Ordered .--; ---- "% 冰 ---; -------------- -Fill in this page) -9-A7 B7 Printed by the Central Bureau of Economic Affairs of the Ministry of Economic Affairs Beigong Consumer Cooperative V. Description of the invention (7) Alcohol, benzyl acrylate, benzyl salicylate, benzyl benzoate, Styrallyl Acetate, amyl salicylate, dimethyl benzyl methanol, trimethyl benzyl acetate, p-tert-butyl cyclohexyl acetate, isononyl acetate, ursin acetate, ursin Alcohol, α · n-pentylcinnamaldehyde, α_hexylcinnamaldehyde, 2-methyl-3- (p-tert-butylphenylpropanal, 2-methyl · 3- (p-isopropylphenyl) propan , 3- (p-tert-butylphenyl) propionate, tricyclodecenyl acetate, tricyclodecenyl propionate, 4- (4-hydroxy-4_methylpentyl) · 3-cyclohexyl '4- (4-Methyl-3-pentyl) -3 -cyclohexylidene, 4-ethoxyoxy-3-pentyl-tetrahydropyran, methyl dihydroxide jasmonate, 2-n-heptane -Cyclopentanone, 3-methyl-2-pentyl-cyclopentamine, n-decane, n-dodecane, 9-decen-1-ol, phenoxyethyl isobutyrate, phenylethyl Aldehydes acetal, phenyl Ethylene diethyl ethylidene, geranile, citronellol, cedar acetate, 3-isoborneolyl cyclohexanol, cedar ether, isobaric, anisaldehyde nitrile, anise while sunflower sunflower aldehyde, incense Beans, eugenol, vanillin, diphenyl oxide, chiral citronellic acid, ionone, methyl ionone, isomethyl ionone, malanin, cis-colloxol and its esters, Indane milling, naphthalene musk, heterochromic musk, macrocyclic ketones, macrolactone musk, hypoethyl brasilyl acid, aromatic nitro musk. This composition typically contains 0.1% by weight of the total composition ° /. To 2% of perfume ingredients or mixtures thereof, preferably 0% to 1.0%. This composition may contain various other ingredients, including more active ingredients and only aesthetically pleasing ingredients such as dyes and the like ．In particular, the rheological society of this composition is suitable for suspending particles in the composition, such as the particles ground in examples. Examples-experimental teaching (please read the notes on the back and fill in this page) Γ4 equipment-Η
本紙張nt財s 8家搮準(CNS -10- A7 316923 B7 五、發明説明（8 ) 本發明更進一步由下列實例及數據説明。下列組合物是 依下表所列順序加入各成份混合所製。 (請先閲讀背面之注意事ΐ 裝-- ?填寫本頁) ,ιτ- •f 經濟部中央標準局貝工消費合作社印裝 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -11 - 五、發明説明（9 ) A7 B7 經濟部中央標準局員工消費合作社印製 配方 成份 1 2 3 4 5 6 7 8 9 擰檬酸 5.50 5.50 5.50 5.50 5.50 5.50 9.50 4.00 乳酸 5.50 Isofol 12S® 2.00 烷基硫酸塩 2.00 (以Lial醇爲基礎） 烷基硫酸塩（以4.00 4.00 4.00 4.00 4.00 7.50 4.00 Isalchem 123® 醇 爲基礎） Hostapur SCS® 4.00 氨(如 NH40H) 0.75 0.20 0.50 0.50 0.50 0.40 1.65 0.80 0.33 丙二醇 1.30 1.30 1.30 1.30 2.40 Dobanol 79-6® 3.00 3.00 3.00 3.00 3.00 5.60 Lutensol AO30® 3.00 n-BPP 3.00 2.50 香水 0.60 0.60 0.60 0.60 0.60 0.60 0.60 1.12 0.50 C8-C10 二甲基胺 0.90 1.10 0,80 1.10 0.45 4.40 0.30 1.50 氧化物 C12烷基胺 1.10 pH 4.0 3.0 3.2 3.2 3.2 3.2 6.0 3.2 3.7 黏度、董泊 140 300 170 185 140 350 135 940 140 (Brookfield 20°C下、2號針，每分鐘60轉） 所有上面之調配物所指爲％重量比而剩餘之部份爲水。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閲讀背面之注意事< 裝-- ί：填寫本頁) 訂. f -12- ^16023 A7 A7 B7 五、發明説明（10 ) 所有上述調配物爲安定的。在上述實例中，Lial醇（來自 丑1^(；1^111)爲€12-15醇，50%支鍵和50%直鏈。我們用 硫酸的鈉塩做成此物質。Isalchem 123®(來自Enichem) 爲（：12-13其94%爲支鏈。此物質可以描述爲（：113· (CH2)m-CH(CH20S03Na)-(CH2)n-CH3，其 n + m = 8.9。 Isofol 12S®(來自Condea)爲2-丁基辛基硫酸鈉。 Hostapur SAS®爲 C12-16鏈燒烴續酸納。Lutensol® AO30爲C13-15醇與平均每莫耳醇30莫耳環氧乙烷乙氧 化。 容易沖洗是在實驗室的條件下藉著測量產品在水中 (1.2 %重量比）的晞釋溶液所產生的泡沫而模擬的。泡沫 高度所產生者是在溶液中由海綿吸收且擠出十次後記錄並 記錄泡沫破裂的速率。根據本發明上述組合物1至8與市上 可得自己增稠的組合物比較，其含下列成份； 一級的C12-14烷基硫酸鈉 3.40% 檸檬酸 5.5 0% 氳氧化銨 0.30% 經濟部中央揉準局貝工消费合作社印装This paper has 8 financial standards (CNS -10- A7 316923 B7. V. Description of the invention (8). The invention is further illustrated by the following examples and data. The following compositions are added in the order listed in the table below. (Please read the precautions on the back first-install this page-? Fill in this page), ιτ- • f printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. The paper size is in accordance with the Chinese National Standard (CNS) A4 specification (210X297 )-11-V. Description of the invention (9) A7 B7 Formulation ingredients printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 1 2 3 4 5 6 7 8 9 Citric acid 5.50 5.50 5.50 5.50 5.50 5.50 9.50 4.00 Lactic acid 5.50 Isofol 12S ® 2.00 Alkyl sulfate 2.00 (based on Lial alcohol) Alkyl sulfate (based on 4.00 4.00 4.00 4.00 4.00 7.50 4.00 Isalchem 123® alcohol) Hostapur SCS® 4.00 Ammonia (eg NH40H) 0.75 0.20 0.50 0.50 0.50 0.40 1.65 0.80 0.33 Propylene glycol 1.30 1.30 1.30 1.30 2.40 Dobanol 79-6® 3.00 3.00 3.00 3.00 3.00 5.60 Lutensol AO30® 3.00 n-BPP 3.00 2.50 Perfume 0.60 0.60 0.60 0.60 0.60 0.60 0.60 1.12 0.50 C8-C10 dimethylamine 0.90 1.10 0,80 1.10 0.45 4.40 0.30 1.50 oxide C12 alkylamine 1.10 pH 4.0 3.0 3.2 3.2 3.2 3.2 6.0 3.2 3.7 Viscosity , Dong Bo 140 300 170 185 140 350 135 940 140 (Brookfield at 20 ° C, 2nd needle, 60 revolutions per minute) All the above formulations refer to the weight ratio and the remaining part is water. This paper size Applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) (Please read the notes on the back < outfit-ί: fill out this page) to order. F -12- ^ 16023 A7 A7 B7 V. Description of invention (10 ) All the above formulations are stable. In the above example, Lial alcohol (from Ugly 1 ^ (; 1 ^ 111) is € 12-15 alcohol, 50% branched and 50% straight chain. We made this substance with sodium sulfate sulfate. Isalchem 123® ( From Enichem) (: 12-13, 94% of which are branched. This substance can be described as (: 113 · (CH2) m-CH (CH20S03Na)-(CH2) n-CH3, where n + m = 8.9. Isofol 12S® (from Condea) is sodium 2-butyloctylsulfate. Hostapur SAS® is sodium C12-16 paraffinic acid. Lutensol® AO30 is C13-15 alcohol with an average of 30 moles of ethylene oxide per mole of alcohol. Ethoxylation. Easy rinsing is simulated under laboratory conditions by measuring the foam produced by the release solution of the product in water (1.2% by weight). The height of the foam is absorbed and squeezed by the sponge in the solution Record and record the rate of foam burst after ten times. According to the present invention, the above compositions 1 to 8 are compared with commercially available self-thickening compositions, which contain the following ingredients; First grade C12-14 sodium alkyl sulfate 3.40% Citric acid 5.50% ammonium oxide 0.30% Printed by the Beigong Consumer Cooperative of the Ministry of Economic Affairs
Dobanol®23 -3 0.8 5 % 1.90% 0.40% 爭衡 裝— (請先閎讀背面之注意事t填寫本頁) (C12-13醇與每莫耳醇平均3莫耳環氧乙烷乙氧化） 三乙醇胺 香水 次要者及水 本紙張尺度逍用中國國家揉準（CNS ) A4規格（210X297公釐） -13- A7 B7 五、發明説明（n ) 經濟部中央樣準局貝工消费合作社印製 結果如下； 產品 泡沫高度(公分） 泡沫破滅速率(平均公分，分） 參考 4.5 0.25 1 4.0 1.40 2 3.5 1.50 3 4.0 1.00 4 3.5 1.50 5 3.0 1.40 6 3.5 1.50 7 4.0 1.20 8 5.5 1.30 上面的結果顯示對每個及每 一上面實例所調配組合物產 生較少泡沫 ’且產生之泡珠破滅得更快，整個提供了更容 易的沖洗性 (請先閲讀背面之注意事巩馮填寫本頁) 裝· i Η 本紙張尺度遥用中國國家標準（CNS ) A4规格（2丨〇χ297公釐） -14 -Dobanol®23 -3 0.8 5% 1.90% 0.40% Balancing the equipment — (please read the precautions on the back first t fill in this page) (C12-13 alcohol and ethoxylation of 3 moles of ethylene oxide per mole of alcohol) Triethanolamine perfume minors and water-based paper standards are used in China National Standard (CNS) A4 (210X297 mm) -13- A7 B7 V. Description of Invention (n) Printed by Beigong Consumer Cooperatives, Central Bureau of Standards, Ministry of Economic Affairs The results are as follows; product foam height (cm) Bubble burst rate (average cm, min) Refer to 4.5 0.25 1 4.0 1.40 2 3.5 1.50 3 4.0 1.00 4 3.5 1.50 5 3.0 1.40 6 3.5 1.50 7 4.0 1.20 8 5.5 1.30 The above results show For each and every composition formulated in the above example, less foam is generated and the bubbles generated burst faster, and the whole provides easier rinsability (please read the notes on the back of Gong Feng to fill in this page) · I Η This paper scale uses the Chinese National Standard (CNS) A4 specification (2 丨 〇χ297mm) -14-