經濟部中央梂準局貝工消费合作社印製 ^07806 at ___87 五、發明説明（/ ) Γ業界之使用領域] 本發明係關於提供具有優異耐熱性之層合犓用之層壓 基材原料。 「習知技蓊〕 靥合物用之基材原料以酚樹脂、聚翻欄騰等處理，而 且主要條作為曆合物使用於印刷電路板。近年來•鼸箸 電子儀器之多功能化及高密度化，鍍_穿孔與塗画穿孔 已進步，而a對於使用紙基質之層合物亦漏要离可攤度 。特別地，對於刪熱性，因為焊接處璎之加速、電路之 离密度化、電子零件之增加熱放射等、，要求程度變為較 駸格。 目前，對於曆壓基材原料，由木頭産生之濯白牛皮紙 漿已廣泛地使用，但是對於如耐熱性之特嫩，尚来得到 滿足之品質。因此，有使用具有高α -纖維素含量、离 純化溶解紙漿或棉絨紙漿之方法！日本未審査專利特謂 昭60-7952與昭64 -1 4398)。然而，使用癯呰紙漿畤，可 得優異之耐熱性.但是因為顯然彎曲之纖雄：，尺寸安定 性顯著地不良。 亦有使用具有低彎曲纖維之_白牛皮紙擬之方法，其 中藉由難言牛皮紙漿之生産時.改善意燒條件而抑制低 的1 0 % Κ 0 Η溶解（日本未審査專利特開¥ 2 -- 1 7 5 9 9 6丨，但是 目前之狀況為，在猶熱性之改良對於其高純化無法稱為 足夠。 在上示之習知技藉，完f並未顯示層壓基材顒料之熱 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） I I I I I— I n ^ I II I n I I —1 n I n If— i* (請先閱讀背面之注意事項再填寫本頁) 307806 Λ7 B7 五、發明説明（ 由 _ c. 性 熱及 耐提 之未 物亦 合實 層事 連之 _ 性 何熱 如耐 為良 行改 解而 分漿 ί έ 顯 低 用 題壓 間層 之意 決注 解人 明明 發發 本本 與 為 視 被 其 量 之 解 起直 解«' 分性 熱熱 之耐 料之 原物 材合 基層 調*數 亦質指 ，木之 件酸索 條硫質 些之木 逋中餘 足漿殘 滿紙為 於之作 易得 ， 了而僳 為離關 ,分之 材 基 分外維 熱此 _ 及 ,以 度連予in 鼴關料gn 量 之 J 八、' Ί S 1.熱進低 法耐，不 方之實有 之物事具 題合之下 間靥偽氣 決意關大 解注切氣 r 密氡 與 性 材果 基結 壓的Printed by Beigong Consumer Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs ^ 07806 at ___87 V. Description of the invention (/) ΓIndustry use field] The present invention relates to the provision of laminated base materials for laminated enthalpy with excellent heat resistance. "Conventional Techniques" The base material used for the compound is treated with phenol resin, poly-barrel, etc., and the main strip is used as a compound for printed circuit boards. In recent years, the multifunctional and High-density, plating, perforation and painting perforation have been improved, and a is also necessary for the use of paper-based laminates. In particular, for heat removal, because of the acceleration of the solder joint and the separation density of the circuit The increase in thermal radiation of electronic components and electronic components has become more demanding. At present, for the base material that is pressed, the white kraft pulp produced from wood has been widely used, but for the special tenderness such as heat resistance, The quality is still satisfied. Therefore, there is a method of using high alpha-cellulose content, purified purified pulp or lint pulp! Japanese unexamined patents are specifically named Sho 60-7952 and Sho 64 -1 4398). However, Using 瑯 呰 紤 紤, you can get excellent heat resistance. But because of the obvious bending of the fiber: the size stability is significantly poor. There are also methods using _ white kraft paper with low bending fibers, in which During the production of pulp. Improving the firing conditions and suppressing the low 10% Κ 0 Η dissolution (Japanese Unexamined Patent Special Publication ¥ 2-1 7 5 9 9 6 丨, but the current situation is the improvement of the heat resistance For its high purification, it cannot be said to be sufficient. In the conventional technique shown above, the heat of the laminated substrate is not shown. This paper standard is applicable to the Chinese National Standard (CNS) A4 specification (210X 297 mm) IIIII — I n ^ I II I n II —1 n I n If— i * (please read the precautions on the back before filling this page) 307806 Λ7 B7 V. Description of the invention (by _ c. Sexual heat and endurance) Things are also in line with real things _ He He Ru Ru Ning Separate for good deeds. It is obvious that the purpose of using the interlayer is low. The note is clearly issued by the person and the direct solution is based on the amount of the solution. «'The original material and base layer adjustment of the heat-resistant refractory material also refer to the quality, the wood is sour, the sulfur is more, and the wood is full of more than enough pulp to make it easy to obtain. Su is off from the customs, the material is divided and the dimension of the heat is increased _ and, to the degree of the gn quantity in the 闹 关 料 J 八 、 'Ί S 1. The heat is low, the law is tolerant, and the real things are different. Under the title, the hypothetical qi is determined. The key is to explain the qi, r, the radon, and the sex.
Aff fi 高 不 0 V 有在起 為用解 行使分 解由熱 分藉之 熱现 P 之發70 料一 (請先閱讀背面之注意事項再填寫本頁) ·《丨裝. 大 氣 M 在 且 而為 ，率 度少 溫減 始解 超 不 至 ¾ V ο 懕 6 I. 2 曆 於之 下% 分 熱 之 鐘 分 ο 持 本 照 依 料 的之 目物 此 合 成曆 完良 效改 有了 可為 明 分 性 重耐 為之 色接 變焊 與經 泡偽 起性 之熱 時耐 熱之 加物 制合 抑層 及 41 ί 及 χ3 X ^ JTi 層的性 經濟部中央標準局員工消費合作社印袋 估 評26 而在 之用 述使 性 熱 之 氣 空 在 之Aff fi is not higher than 0 V. It is used for the purpose of decomposing and decomposing the heat that is borrowed from the heat. P is 70 (please read the precautions on the back and then fill out this page) · 《丨 装. Atmospheric M is in and In order to reduce the temperature and reduce the temperature, the initial solution will not exceed ¾ V ο 懕 6 I. 2 Experience below% of the minutes of heat In order to clearly distinguish the color-resistance welding and the heat resistance of the bubble pseudo-initiating heat, the combination of the suppression layer and the 41 ί and χ3 X ^ JTi layer of the Ministry of Economy Central Standards Bureau Employee Consumer Cooperative printed bag Appraisal 26 and use the narrative to make the sex hot
浴 錫 焊 之 P 層 於 * 對品 檐 之石 氣置 空測 在a 且並 而 ， *鐘 法分 方 5 之熱 音加 聲機 之燥 裂乾 燔風 到吹 聽在 〇 分 定熱 溯之 而物 度合 溫靥 高析 最分 之 素 所生’ 1由色 1 Ϊ. 性聲 i ί & 1 _1藉變 ^48illm» 0 二 Ξ® ® 分(0妾‘&溫起 熱Is接S熱成 J? I .E rf? If 份 域 性 發 掲 之 物 合 層 以 為 1了 41 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 訂----Μ •線_ A7 ___B7五、發明説明（> ) 層壓基材原料之半繼維素、接績為纖維素《最後為酚樹 脂之次序而迪成分解（Seni Gakkai之前稿，1994, (G) & >7 熱 之0 樹 酚 於 性纖 性半 熱之 耐料 之原 等材 錫基 焊壓 在層 鏍覺自 ).,感源 頁 .於 80實由 第事乃 ，之體 0 始 驗* 近蘅 附解熱 P 分之 70熱素 E3之維 二 j K 變41 α與 分 解 分 熱 之 料 原 材 基 壓 C 層 物知 産習 解 近 - P ο 3 為 0 0 始 發樹 本酚 在近 時接 間至 , 高 低提 «為 相度 為灑 度始 溫起 '?**· ?-始解 起分 解熱 分之 熱料 之原 脂材 樹基 酣壓 於曆 對 ， 其明 ο 3 3 於 低 。 不性 之熱 度耐 溫之 始高 起常 解非 分到 熱得 之可 脂此 不 材% 基]0 壓約 靥為 知認 習率 ，少 率減 少解 減分 之熱 解之 分時 熱鐘 於分 至10 持 1 些可 、一 這性 ot覺熱 26慼 _ 在且 r 地 效 有 而 an » 明 S59 本通 在超 時不 同至 ο ο 因至 原率 之少 等減 泡之 起解 為分 體熱 氣制 解抑 分由 熱藉 分 熱 P 32? 發 C 本 良在 改 大 氣0 在 析 分 之 為 i7 /»4« 實 下 (請先閱讀背面之注意事項再填寫本頁) 訂 經濟部中央樣準局員工消費合作社印製 樹條之 賺此性 之用熱 物使耐 合 C 之 層實料 入事原 嵌¾材 料再基 原 定 材件決 基條而 壓單法 層籣方 , 之之 r解性 件分現 條至再 氣熱好 厭加良 在且籍 為並可 因 ，. 乃脂件 β 件 燒 廉 物 頭 木 合 組 由 藉 明 發 本 C 現 圍實 範了 忍為 容 而 .VI/ 件 條 之 漿 紙 皮 0 耐 κ, I i低 0 有 逆具 迓 I 為i -減 件中 條當 白份 性 之 度 成的 料效 廳有 材為 -1 線--- 本紙張尺度逋用中國國家標準（CNS ) A4規格（2丨Ο X 297公釐} 經濟部中央樣準局員工消费合作社印裝 A7 __B7 五、發明説明（4 ) 雖然並無特别限制。特別地，半纖維素與非結晶纖維素 之熱分解起始溫度低至3 00ic,因此，為了實現不低於 330 之溫度為本發明之容忍範圃，降低遽些成份為重要 的。至於製造條件，提及如具有良好t燒力之木頭物種（ 例如，植林後1 0年内之油加利樹木頭）作為原料之龌擇、 藉由在相當低之溫度煮燒及离程度之ft,學加成、如半纖 維素之低分子量多糖藉由增強氣漂0等之拂餘等。其中 ,漂白條件之邏揮特別重要。 其次，本發明人已發現，藉由在層驅基材顧料遣留在 特定範麵之木質素量，易於製谁包含在》氣大氣下以2 0 t /分鐘之瀰度上升速度加熱時，興有不低於330 t至不 高於370T：之熱分解溫度，而且在氮氣大氣下於2601C離 持1 0分鐘之熱分解減少率為0 %至不超過5 %之硬木牛皮 紙漿之層壓基材原料。使用本發明之層騣基材原料，殘 餘木質素之置之指數的硫酸木質素量安排在不小於〇 . 2 % 至不超過1 . 2 %之範園，而得到离耐熱性，， 通常，在層壓基材原料之製迤，硬木牛皮紙漿經一条 列之多階段漂白而漂白，如使用氣、氯、次氯酸銷 與二氣化氯。然而，逭些方法之詳細鑣定之結果，顯然 在使用殘留一些含量之木質素之中闥廉物的紙漿畤，耐 熱性比漂白至一般L B K P之紙漿較诖t涵旦.潛心研究之 結果，己發現在將層壓基材原料予以繼維素分麵而得之 紙漿之殘餘木質素量鬭於硫酸木賨素為不小於〇 . 2 96至不 超過1 . 2 %時，可得具有最佳謝熱性之層釅基材顒料. 本紙張尺度適用中國國家標準（CNS ) A,4規格（210X297公釐） -------f丨裝------訂-----f -線 -* (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消费合作社印製 ^07806 A 7 __B7 五、發明説明（r ) 漂白方法為藉由在可於煮燒方法排除之紙擬纖維排除 木質素（_恃別是在第二而得到亮度之方法3在潔白之 起始階段，半纖維素輿相當低分子量非結晶纖維素水解 ,如此改良耐熱性，，然而，在進行潔白以進一步排除化 學地鍵結織維素之羥基與羧基之木質素畤，纖維緊之結 晶度損壊，生成降低之耐熱性所以•在本發明，使用 殘餘木質素之量調整在上示容忍範園内之顯白方法，使 其可增強耐熱性。 〔動作〕 依照本發明而改良靥合物之耐熱性，顧因在於.8由 增加靨壓基材原料之熱分解起始溫度ft抑刺熱分解減少 率為低，而防止加熱層合物畤之起始輿變色> 〔實例〕 在以T .使用資例而顯示本發明之效果然而•本發 明不限於這些實例。 (實例1) 在表1之條件下使用得自北海遵之硬木Η進行牛皮紙 煮燒，即，比較實例2為相當低之瀧度輿較高化學加成 程度之煮燒條件，以得到具有10之κ數之来漂白紙漿 < U Κ Ρ )。此ϋ Κ Ρ接受使用氣與：1氣化氣之低氱型灘白後， 以手動製紙機使用該漿而形成具有〗3 5克/平方公尺之 基本重量與0 . 5克/之方公分之密度之層顯基材原料紙 Μ。此層壓基材原料予以纖維分離以测定硫酸木質素之 量，其顯示為0.8%。 7 ~ 本紙張尺度逋用中國國家標準（CNS ) Α4規格（2丨Ο X 297公釐） (I裝------訂----1.線 * (請先閱讀背面之注意事項再填寫本頁) 經濟部中央樣準局貝工消费合作社印製 A7 __B7五、發明説明（b ) 在此基材原料，商業酵溶解酚樹腺（商樣名稱BLS-3122 ，得自昭和离聚合物有限公司）漫潰及在〗6 0 f之熱風乾 燥，以製造預漬醱。其次，8 Η預漬釀及興有附#之黏 著劑之鐧箔分層，其籍由在1 5 5 υ、1 0 0公Ff /平方公分 及60分鐘之條件下加熱及加壓，然浚在加廳狀態冷卻30 分鐘，而得具有50%之樹脂漫漬率及1. .6毫米之板厚度 之單侧銅層合物。 此方法所得之曆壓基材原料與層合物之特徽示於表1 如由表1所明顯，因為適鼉之殘餘木質素，饜壓基材 原料之耐熱性高，生成具有良好_熱姓之馨合物 (實例2) 使用得自南非之由加利樹Η ,在表〗所示之條件F進 行煮燒，卽，比實例1為相當高之溫度及較低程度之化 學加成，以得到具有1 2之Κ歟之ϋ Κ Ρ 紙嫌藉氣灌白而 灌白後.類似實例1使用此紙漿作為原料而得層壓基材 原料紙Η與層合物： 此方法所得之層壓基材原料輿層合钱I之特徽示於表1 。如由表1所明顯，因為適量之殘餘木質素，靥歷基材 原料之耐熱性离，生成具有良好耐熱性之層合物， (比較例1) 使用得自南非之由加利樹Η ,茌類似實例2之煮燒條 件下得到I) Κ Ρ 此ϋ Κ Ρ接受使用氣、氱、過氣化氳/ _、 次氱化鈉與二氣化氯之多階段灌白，函得BRP。類似實 例1使用此紙漿作為朦料而得層壓基材原料紙Η與層合 (請先閲讀背面之注意事項再填寫本頁) 裝· -a 丄·線· 本紙張尺度適用中國國家樣準（CNS ) Α4規格（210 X 2Q7公釐） 經濟部中央梂準局貝工消费合作杜印製 307S06 A7 _ B7 五、發明説明（T ) 物。 如由表1所明顯，此方法所得之曆壓基材原料之特嫩 因較少量之殘餘木質素而1現較高之亮度，但是低熱分 解起始溫度與高熱分解之減少率。結纖，_合物之耐熱 性亦比實例2與實例〗不良，、 <比較例2 ) 使用得自北海遒之硬木Η ,在類似霣例1之條件下進 行煮燒而得到υ Κ Ρ。無_白處《，類似窗例1使用此ϋ Κ Ρ 作為紙漿原料而得層壓基材原料紙Μ輿層合物《 如由表1所明顯，此方法所得之層廳基材原料之特微 呈現容忍範匾外之較高量殘餘木質素.低熱分解起始溫 度與1 0 %之特別高之熱分解減少率。因此s壩合物之_ 熱性亦比實例1與實例2不良， (比較例3 > 使用得自北海遒之硬木Η，在類似實例1之條件下進 行煮燒而得到U Κ Ρ。此ϋ Κ Ρ接受使用氣氯'«氣化氫/ 次氱化納與二氣化氯之多階段灘白，而得Β Κ Ρ。類 似實例1使用此紙鳆作為原料而得靥顧基材朦料紙片與 層合物。 如由表1所明顯，此方法所得之層廳基材塬料之特激 僅因較少量之殘餘木質素而呈琨較高之亮度.但是低熱 分解起始溫度與高熱分解減少率。結果.層合物之耐熱 性亦比資例1輿實例2不良。 ~~ g ~ 本紙張尺度適用中國國家標準（CNS ) A4規格（2.10〆297公釐） n. J...... - - 1 I ί -----观' m ------—i - - ........... i—- nil ...... - --1 .! I .......《 >* (請先閲讀背面之注意事項再填寫本頁) A7 __B7 五、發明説明（δ ) 經濟部中央標準局員工消費合作杜印製 表1 實例 比較例 1 2 1 2 3 煮燒條件： 原料Η 得自北海 遒之硬木 得自南非之 油加利樹 _自南非之 油加利_ 得自北海 遒之硬木 得自北海 遒之親木 溫度上升時間（分解） 90 90 90 90 90 煮燒溫度（tO 155 160 160 155 155 保持時間（分鐘） 50 50 50 50 50 有效鹸之加成程度 (%r 1 23 15 15 23 23 未漂白紙漿k數** 2 10 12 12 10 10 漂白條件： 0 ?階段氣(kg/cm 2 ) 4.5 4.5 4.5 4.0 * m(96) 3.0 3.0 2,0 - 2.0 C階段* 4氯(％> - 2,0 - L.5 E/P階段鹼<%) - 1,2 1.2 * 5過氣化氳(％) ~ - 1,0 — 1.0 Η階段"6次氱酸納龙 -* - 0.5 — 1,0 D階段** 7 0,2 一 0,2 "" 0.1 層壓基材原料與層合物之特嫩： 基材原料纖維分離後 之硫酸木質素"8 0.8 0,9 <0。2 2.0 <0.2 亮度 70 60 112 35 90 熱分解起始溫度β 9 (¾) 335 355 325 320 315 熱分解減少率* 10¾) 4.0 3.0 5,5 10,0 7,5 焊接之耐熱性11 1塊少) 40 55 30 15 20 在空氣之耐熱溫度 * 12 nn) 285 275 255 240 245 本紙張尺度適用中國國家樣準（CNS ) Α4規格（210 X 297公釐） ^-------1 —^-- (請先閲讀背面之注意事項再填寫本頁)The P layer of the solder bath is set to * and the stone gas of the eaves is empty and measured at a and the same, * the dry and dry wind of the hot sound phonograph of the clock method 5 to the sound is determined at 0 minutes. And the materiality and temperature are the highest and the most important element is born. 1 is made of color 1 Ϊ. Sex sound i ί & 1 _1 borrowed by ^ 48illm »0 two Ξ® ® points (0 concubine '& temperature rise heat Is Connect S to form J? I .E rf? If the localized hair layer is 1 layer, the paper size is 41 Chinese standard (CNS) A4 (210X297mm). ---- M • Line _ A7 ___B7 V. Description of the invention (>) The semi-substantial dimension of the raw material of the laminated base material, the succession is cellulose "The last is the order of the phenol resin and the composition of the solution (Seni Gakkai previous draft, 1994, (G) &; > 7 hot 0 phenols are made of tin-based solder of the original materials such as slender and semi-heat refractory materials, pressed in the layer of yinjue.), sensory page. In 80, the first thing is that the body 0 starts Test * Nearly attached heat-resolving P 70th pyrogen E3 dimension two j K change 41 α and decomposition heat-removing material base pressure C layer physical knowledge practice solution near-P ο 3 is 0 0 originating tree Phenol In the near time, the high and the low «is the phase degree as the starting temperature of the sprinkling degree '? ** ·?-The original fat tree base that starts to decompose the heat material that decomposes the heat is pressed against the historical pairs, which is clear. 3 3 is low. The temperature of the sex is high. The beginning of the temperature resistance is high. The common solution is not divided into the fat of the heat. This base is %%] 0. The pressure is about the knowledge rate, and the rate of reduction is reduced. At the time, the heat clock is between 10 and 10, and it can hold a certain amount of heat. This kind of ot feels hot 26 Qi _ in and r. The ground effect is effective and an »Ming S59 This pass is different in the timeout to ο ο Due to the lack of the original rate, etc. The starting point of the foam reduction is the split hot gas system, and the suppression is divided by the heat and the heat is P 32? Hair C Benliang is changing the atmosphere 0. The analysis is i7 / »4« Actually (please read the precautions on the back first (Fill in this page) Ordered by the Central Sample Bureau of the Ministry of Economic Affairs, the employee consumer cooperatives printed tree strips to make use of this material to make the C-resistant layer material into the original embedding ¾ The material is then based on the original material. Pressing the single-layer method, the r-dissolvable parts are divided into strips until the re-heating is good and good and can be attributed. The Shaoliang Wutoumuhe group is based on the Mingfa Ben C, and now it is practical and tolerant. VI / pieces of pulp paper 0 resistant to κ, I i low 0 there is an inverse with I I-minus middle When the whiteness is achieved, the material effect hall has a material of -1 line-this paper scale uses the Chinese National Standard (CNS) A4 specification (2 丨 Ο X 297mm) Employee consumption of the Central Bureau of Standards of the Ministry of Economic Affairs Cooperative cooperative printing A7 __B7 V. Description of invention (4) Although there are no special restrictions. In particular, the thermal decomposition starting temperature of hemicellulose and non-crystalline cellulose is as low as 300 ic. Therefore, in order to achieve a temperature of not less than 330, it is the tolerance range of the present invention, and it is important to reduce these components. As for the manufacturing conditions, mention is made of wood species with good t-burning power (for example, oil-bearing trees within 10 years after planting) as raw materials, by cooking at a fairly low temperature and the degree of separation , Learn addition, low molecular weight polysaccharides such as hemicellulose by enhancing the air drift 0 and so on. Among them, the logic of bleaching conditions is particularly important. Secondly, the present inventors have discovered that by considering the amount of lignin left in a specific area in the layer drive substrate, it is easy to prepare who is included in the gas atmosphere when heating at a density rise rate of 20 t / min , There is a layer of hardwood kraft pulp with a thermal decomposition temperature not lower than 330 t and not higher than 370T: and a thermal decomposition reduction rate of 0% to not more than 5% at 2601C for 10 minutes under nitrogen atmosphere. Press base material. Using the raw material of the layered base material of the present invention, the amount of residual lignin is set at an index of not less than 0.2% to not more than 1.2% of the lignin sulfate to obtain the heat resistance, usually, In the production of laminated base materials, hardwood kraft pulp is bleached through a series of multiple stages of bleaching, such as the use of gas, chlorine, hypochlorous acid, and digasified chlorine. However, as a result of the detailed determination of these methods, it is clear that the use of pulp residues with some residual lignin content is more heat-resistant than that of bleached to ordinary LBKP pulp. The results of intensive research have been It was found that when the residual lignin content of the pulp obtained by laminating the base material of the substrate following the surface separation of the vitamins is not less than 0.296 to not more than 1.2% with leptin sulfate, the best Xie Xie's layered base material. This paper scale is applicable to China National Standard (CNS) A, 4 specifications (210X297 mm) ------- f 丨 installation ------ order ---- -f-线-* (Please read the precautions on the back before filling out this page) Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ^ 07806 A 7 __B7 5. Description of the invention (r) The bleaching method is based on The paper-like fiber excluded by the burning method excludes lignin (_different is the second method to obtain brightness. 3) At the initial stage of whitening, hemicellulose and a relatively low molecular weight non-crystalline cellulose are hydrolyzed to improve heat resistance. However, whitening is carried out to further exclude the chemical bonding between the hydroxyl group and the carboxyl group of oryzanol The lignin residue, the tight crystallinity of the fiber is impaired, resulting in reduced heat resistance. Therefore, in the present invention, the amount of residual lignin is used to adjust the whitening method in the tolerance range shown above, so that it can enhance the heat resistance. 〕 According to the present invention, the heat resistance of the tantalum compound is improved. The reason is that by increasing the starting temperature of the thermal decomposition of the raw material of the tantalum pressure base material ft, the reduction rate of the thermal decomposition is low, and the rise of the heating laminate is prevented. Shiyu discoloration> [Examples] The effect of the present invention is shown in the case of T. However, the present invention is not limited to these examples. (Example 1) Using hardwood H obtained from Beihai Zun under the conditions of Table 1 for kraft paper Boiling, that is, Comparative Example 2 is a boiling condition with a relatively low degree of turbidity and a higher degree of chemical addition to obtain a bleached pulp with a number of κ of 10 (<U Κ Ρ). This ϋ Κ Ρ accepts the use of gas and: 1 low gas type white sand of gasification gas, using the pulp with a manual paper machine to form a basic weight of 35 grams / square meter and 0.5 grams / square The centimeter density layer shows the base material M. The raw material of the laminated base material was subjected to fiber separation to determine the amount of lignin sulfate, which showed 0.8%. 7 ~ The size of this paper uses the Chinese National Standard (CNS) Α4 specification (2 丨 Ο X 297mm) (I installed ------ ordered ---- 1. line * (please read the precautions on the back (Fill in this page again) A7 __B7 printed by the Beigong Consumer Cooperative of the Central Bureau of Samples of the Ministry of Economy V. Description of the invention (b) The raw material of this substrate, commercial fermented phenol tree gland (commercial name BLS-3122, obtained from Showa Li Polymer Co., Ltd.) and the hot air drying at 60 0 f to make pre-stained slush. Secondly, 8 Η pre-stained brewing and layering of the foil with the adhesive attached ##, its origin is in 1 5 5 υ, 100 cm Ff / cm 2 and heating and pressurizing under 60 minutes, then dredging and cooling in the state of adding hall for 30 minutes to obtain a 50% resin diffusion rate and 1. 6 mm plate The thickness of the single-sided copper laminate. The special emblem of the raw material and the laminate obtained by this method are shown in Table 1. As is obvious from Table 1, the residual lignin suitable for the raw material is used to press the raw material of the substrate. It has high heat resistance and produces a good compound with a good _ surname (Example 2). It is cooked by Yuri tree H obtained from South Africa under the condition F shown in Table〗, which is better than Example 1. A relatively high temperature and a relatively low degree of chemical addition to obtain a ϋ Κ Ρ paper with a κ of 1 2 after white filling by gas filling. Similar example 1 uses this pulp as a raw material to obtain a laminated substrate Raw material paper H and laminate: The special emblem of the laminated base material obtained by this method and the lamination money I are shown in Table 1. As is apparent from Table 1, because of the proper amount of residual lignin, the raw material of the base material Heat resistance, to form a laminate with good heat resistance, (Comparative Example 1) Use Yukari tree Η from South Africa, obtained under cooking conditions similar to Example 2 I) Κ Ρ This ϋ Κ Ρ accepts gas, Multi-stage whitening of 氱, over-vaporized _, _, sodium sub-vaporized sodium and di-vaporized chlorine, BRP was obtained. Similar example 1 Use this pulp as a matte material to obtain a laminated base material paper Η and laminate (please read the precautions on the back side and then fill out this page). Installation--a 丄(CNS) Α4 specification (210 X 2Q7mm) The Ministry of Economic Affairs, Central Bureau of Economics and Technology, Beigong Consumer Cooperation Co., Ltd. printed 307S06 A7_B7. V. Invention Description (T). As is apparent from Table 1, the extraneous raw material of the pressed substrate obtained by this method has a higher brightness due to a smaller amount of residual lignin, but the reduction rate of low thermal decomposition starting temperature and high thermal decomposition. Fibre formation, the heat resistance of the compound is also inferior to Example 2 and Example〗, < Comparative Example 2) using hardwood Η obtained from Beihai Qi, boiled under conditions similar to Example 1 to obtain υ Κ Ρ . No _ white place ", similar to window example 1 using this ϋ Κ Ρ as the pulp material to obtain a laminated base material paper M and a laminate" As is obvious from Table 1, the characteristics of the layer hall base material obtained by this method The micro-presentation tolerates a higher amount of residual lignin outside the fan plaque. Low thermal decomposition starting temperature and a particularly high thermal decomposition reduction rate of 10%. Therefore, the thermal properties of the s dam compound are also inferior to those of Examples 1 and 2. (Comparative Example 3 > Using hardwood H obtained from Beihai Qi and cooking under conditions similar to Example 1 to obtain U Κ Ρ. This ϋ Κ Ρ accepts the use of gas chlorine '«multi-stage whitening of hydrogen gas / sub-hydrogenation sodium and two gasification chlorine, and get Β Κ Ρ. Similar example 1 uses this paperfish as a raw material and obtains the base material and paper Laminates. As is apparent from Table 1, the ultra-high intensity of the substrate material obtained by this method is higher in brightness due to the smaller amount of residual lignin. However, the starting temperature of low thermal decomposition and high thermal decomposition Reduction rate. Results. The heat resistance of the laminate is also inferior to that of Case 1 and Case 2. ~~ g ~ This paper scale applies the Chinese National Standard (CNS) A4 specification (2.10〆297mm) n. J ... ...--1 I ί ----- guan 'm -------- i--........... i --- nil ......-- 1.! I ....... "> * (please read the precautions on the back before filling in this page) A7 __B7 V. Description of invention (δ) Employee consumption cooperation du printing of the Central Standards Bureau of the Ministry of Economic Affairs 1 Example Comparative Example 1 2 1 2 3 Cooking conditions: Material Η Hardwood from Beihai Qi from South Africa Oil Plus tree _Oil from South Africa Jiali from _ Hardwood from North Sea Qi from Beihai Qi's pro wood temperature rise time (decomposition) 90 90 90 90 90 Boiling temperature (TO 155 160 160 155 155 holding time (minutes) 50 50 50 50 50 Addition degree of effective emu (% r 1 23 15 15 23 23 unbleached pulp k number ** 2 10 12 12 10 10 Bleaching conditions: 0? Stage gas (kg / cm 2) 4.5 4.5 4.5 4.0 * m (96) 3.0 3.0 2,0-2.0 Stage C * 4 Chlorine (%>-2,0-L.5 E / P stage base <%) -1,2 1.2 * 5 Over-gasification (%) ~-1,0 — 1.0 Η stage " 6 times naronate-*-0.5 — 1,0 D stage ** 7 0,2 1 0, 2 " " 0.1 Special tenderness of the laminated base material and laminate: lignin sulfate after separation of the base material fiber " 8 0.8 0,9 < 0.2 2 2.0 < 0.2 Brightness 70 60 112 35 90 Thermal decomposition start temperature β 9 (¾) 335 355 325 320 315 Thermal decomposition reduction rate * 10¾) 4.0 3.0 5,5 10,0 7,5 Heat resistance of welding 11 Less 1) 40 55 30 15 20 in air Heat-resistant temperature * 12 nn) 285 275 255 240 245 paper Standards apply to China National Standards (CNS) Α4 specifications (210 X 297 mm) ^ ------- 1 — ^-(please read the notes on the back before filling this page)
、1T A7 307806 B7 五、發明説明（9 ) 在表中，** 1至· 1 2如下： * 1有效齡之加成程度：鹼之加成程度黼於HaOH + Na 2 S 而基於晶片。 * 2 K 數：K 數符合 J I S P 8 2 0 6 * 3 階段：氣漂白在lOOt)及非1〇%之紙擬一致性實 行60分鐘。 * 4 C階段：氯灘白在5 0 t及在3 %之紙凝一致性質 行30分鐘。 * 5 E / P階段：過氣化氳顯白在6 0 1C及在1. 〇 % 之紙聚一致性實行6 0分鐘。 ** 6 Η階段：次氯化納灘白在4 5 t〕段在1 0 96之紙擬一 致性實行60分鐘。 * 7 D階段：二氣化氣_白在7 5 T： 在1 0铋之紙擬—‘ 致性實行1 2 0分_。 *硫酸木質素之置：符合T a ρ ρ ί標_方法Τ 2 2 2 ~ * 8 3 „ * 9熱分解之起始鵝度：熱分解之起始灑度使用得自 R i g a k u公司之熱平衡器而測量。 (测量條件）大氣：氮氣，流速2 0 0毫升/分鏞 I I 1▲ I 裝—— — II 訂 II 線 .* (請先閲讀背面之注意事項再填寫本頁) 經濟部中央棣準局貝工消費合作社印製 P ο 2 克·’ *幸 10速 : 升 量上 品度 樣瀨 室 由 鐮 分 之 水 附 暖 有 具 不 品 櫟 在 由 P ο ο 5 至 溫 布 分 量 重 S· 燒 煆 I 了 0 , _度 廳溫 反始 饗起 ΐ 之 之解 應分 反熱 解為 分作 熱度 經溫 -始 點起 叉之 交插 之外 線成 曲完 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ 297公釐） 307S06 A7 __B7 五、發明説明（W ) * 1 0熱分解之減少率：熱分解之減少率使用得自R丨g a k U 公司之熱平衡器而圈量。 (測鼉條件）大氣：氰氣，流速2 0 0毫升/分鐘 樣品量：丨0 *兒 溫度上升速率：Μ度往5分鐘自室 i:升蚕2 6 Ο υ ,然後樣品在2 6 0 V保持1 0分鏞。測嫌保持 1 0分鐘前後之重量差，以完成熱分解之減少率。 * 11焊接之耐熱性：符合Jis C6481 * 1 2在空氣之_熱性：在吹風乾燥.器麵加熱而不遒 成起泡與變色之最离溫度。 [發明之效果] 如表1所顯示，在本發明之各實例，使用興有組合特 定原料、煮燒條件與漂白條件之層壓*材灝料作為基層 之單側銅層合物之耐熱性非常良奸·:；結果•提供良好品 質之靥合物變成可能的， (請先閲讀背面之注意Ϋ項再填寫本頁) α.1 裝-- ---./ I flu— ϋ^— ^ imw§ · -1-餐 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家揉準（CNS ) Λ4規格（210Χ297公釐）, 1T A7 307806 B7 V. Description of the invention (9) In the table, ** 1 to · 1 2 are as follows: * 1 The degree of addition of effective age: the degree of addition of alkali is based on HaOH + Na 2 S and is based on the wafer. * 2 K number: K number is in accordance with J I S P 8 2 0 6 * 3 stage: air bleaching at 100 t) and non-10% paper to be consistent for 60 minutes. * 4 Stage C: Chlorine beach white at 50 t and 3% paper consistency for 30 minutes. * 5 E / P stage: Over-gasification of whitening at 60 1C and 1.0% paper polymerization consistency for 60 minutes. ** 6 Η stage: hypochlorite sodium white at 4 5 t] paragraph 1 0 96 paper to be implemented consistently for 60 minutes. * 7 D stage: two gasification gas _ white in 7 5 T: in the paper of 10 bismuth-"consistently implement 1 2 0 points_". * Placement of sulfate lignin: in accordance with T a ρ ρ ί standard_method Τ 2 2 2 ~ * 8 3 „* 9 The initial degree of thermal decomposition: The initial degree of thermal decomposition uses the thermal balance obtained from R igaku company (Measurement conditions) Atmosphere: Nitrogen, flow rate 200 mL / min Yung II II 1 ▲ I Pack-— II Order II line. * (Please read the precautions on the back before filling this page) Central Ministry of Economic Affairs Printed by the Ministry of Industry and Fisheries Cooperatives Co., Ltd. P ο 2 g · '* Fortunately, 10-speed: the quality of the sample is increased by the water divided by the sickle. There is a quality oak from P ο ο 5 to the temperature cloth. S · 煆 煆 I got 0, _The solution of the temperature of the beginning of the temperature should be divided into antipyrolysis into the temperature of the temperature-the starting point of the intersection of the outer line and the curve is completed. The paper size is suitable for China. Standard (CNS) Α4 specification (210Χ 297mm) 307S06 A7 __B7 V. Description of the invention (W) * 1 0 Reduction rate of thermal decomposition: The reduction rate of thermal decomposition is measured using the thermal balancer obtained from R 丨 gak U (Measurement conditions) Atmosphere: cyanide gas, flow rate 200 mL / min Sample volume: 丨 0 * Child temperature Degree rise rate: Μ degree to 5 minutes from the room i: raise silkworm 2 6 Ο υ, and then the sample is kept at 2 6 0 V for 10 minutes. The weight difference before and after 10 minutes is suspected to be completed to reduce the rate of thermal decomposition * 11 Welding heat resistance: in line with Jis C6481 * 1 2 in the air _ heat: in the air drying. The surface of the device is heated without becoming the most away temperature of blistering and discoloration. [Effect of the invention] As shown in Table 1 In each of the examples of the present invention, the use of lamination * materials that combine specific raw materials, cooking conditions and bleaching conditions as the base side of the single-sided copper laminate has very good heat resistance. Quality compounds are possible, (please read the note Ϋ on the back before filling in this page) α.1 装----./ I flu— ϋ ^ — ^ imw§ · -1- Meal Ministry of Economy The standard of the paper printed by the Central Bureau of Standards and Staff's Consumer Cooperative is applicable to China National Standard (CNS) Λ4 specification (210Χ297mm)