TW295604B - - Google Patents

Download PDF

Info

Publication number
TW295604B
TW295604B TW83100779A TW83100779A TW295604B TW 295604 B TW295604 B TW 295604B TW 83100779 A TW83100779 A TW 83100779A TW 83100779 A TW83100779 A TW 83100779A TW 295604 B TW295604 B TW 295604B
Authority
TW
Taiwan
Prior art keywords
weight
amount
over
brazing
quot
Prior art date
Application number
TW83100779A
Other languages
Chinese (zh)
Original Assignee
Furukawa Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP21237793A external-priority patent/JPH0790445A/en
Priority claimed from JP5214879A external-priority patent/JP2686037B2/en
Priority claimed from JP21801993A external-priority patent/JPH0797651A/en
Priority claimed from JP24056393A external-priority patent/JPH0790449A/en
Priority claimed from JP23897193A external-priority patent/JPH0790448A/en
Application filed by Furukawa Electric Co Ltd filed Critical Furukawa Electric Co Ltd
Application granted granted Critical
Publication of TW295604B publication Critical patent/TW295604B/zh

Links

Description

衣年 修 五、發明説明(l ) 本發明係關於一種用於製造汽車用之鋁合金熱交換器 的硬焊材料,一種用於鋁製熱交換器之構造成份的鋁合 金硬焊片,和一種使用上述物質來製造鋁製熱交換器的 方法。説的更清楚一點,它提供了一種藉硬焊技術製造 鋁合金熱交換器的硬焊材料和硬焊片,此熱交換器具有 優良的熱效率、高強度和優良的耐蝕性,以及使用它們 的硬焊方法。 汽車用的熱交換器包括一値散熱器、冷卻器、蒸發器 等。在其中的散熱器中,例如圖1中所示,在多倨扁平 管(1>之間,一體形成有加工波形之薄狀散熱片(2),且 此些扁平管(1)之兩端分別開口於由管集箱(3)及水箱(4) 所形成之空間β高溫之冷媒你從一倒水箱之空間餚入, 經由扁平管(1)而送至另一側水箱(4)之空間,因此在扁 平管(1)和散熱:Η (2)的部分產生熱交換,並且冷媒将變 得較低溫而再度循環使用β 對於此種熱交換器的管材和管集箱材料,常使用一種 硬焊片,其中包含,例如J I S 3 0 0 3合金(鋁-0 . 1 5重量% 的銅-1 · 1重量%的錳)之核心材料,在該核心材料的内倒 或者是永遠與冷媒接觸的一側,鍍上JIS 7072合金(鋁-1 重量%的鋅)做為内襯材料,並且該核心材料的外側, 通常是鍍上一層硬焊材料,如JIS 4045合金(鋁-10重量% 的矽);並且俗以硬焊的方式將和其波形的散熱片及其它 成份組合在 本紙張尺度逋用中困國家棋準(CNS)甲4規格(210X297公釐) .....................................................................................裝.......................玎.....................線 {請先閲讀背面之注意事項再填窝本頁) 經濟部中央樣準局員工消費合作杜印製 起 A6 B6 295604 五、發明説明(Z ) 此外,圖2傜顯示一種戀曲型的冷卻器,其中以熱擠 壓法或溫擠壓法而形成管狀的管材(5>被折成彎彎曲曲 的,並且包含硬焊Η之波形的熱熱片(6),係連結於管 材的開口之間。此外,數字(7)是表示一個連接器β對 於管材,可使用JIS 3003合金等,而對於散熱片而言, 刖可使用J I S 3 0 0 3合金或含鋅的合金等來做為核心材料 ,以逹到産生犧牲性效果的目的,並且在兩側同時鍍上 一層硬焊材料,如J I S 4 0 4 5合金或J I S 4 3 4 3合金(鋁-7 . 5 重量%的矽)。 而在圖3刖顯示了一値多層型的蒸發器。在這値蒸發 器中,散熱片(2 )以及形成冷媒路徑(8 )和(8 ·)並且包含 硬焊片的路徑形成薄Η (9}和(9’),偽交替地層叠,並 且以硬焊的方式使它們連接在一起《對於此種散熱片, 通常是使用大約0.08毫米厚的散熱Η材料,而對於冷媒 路徑形成薄片,則使用約0.4毫米厚的硬焊片。 在此種蒸發器中,為避免冷媒路徑的外部腐蝕現象, 將使用一種具犧牲性陽極效應的散熱片材料,而對於冷 媒路徑形成薄片,則使用一種硬焊片,包括一層Α1-1重 量%錳的合金之核心材料,一種摻有銅、鋅等之合金, 如有需要,可在其表面鍍上硬焊材料,如J I S 4 0 0 4合金 或是,丨I S 4 3 4 3合金。並且,所有的這些熱交換器皆是以 硬焊的方式組合,並加熱至接近6 Q (TC的溫度,而硬焊 技術則包括真空硬焊法、肋熔劑硬焊法,使用非腐蝕性 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公釐) 裝......................訂.....................線 {請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製Yi Nianxiu 5. Description of the invention (l) The present invention relates to a brazing material for manufacturing aluminum alloy heat exchangers for automobiles, and an aluminum alloy brazing sheet for structural components of aluminum heat exchangers, and A method for manufacturing an aluminum heat exchanger using the above substances. To put it more clearly, it provides a brazing material and brazing pieces for manufacturing aluminum alloy heat exchangers by brazing technology. This heat exchanger has excellent thermal efficiency, high strength and excellent corrosion resistance, and the use of them Brazing method. Heat exchangers for automobiles include a radiator, cooler, evaporator, etc. In the heat sink therein, for example, as shown in FIG. 1, between the multi-flat tubes (1 > Open separately in the space formed by the tube header (3) and the water tank (4). The high-temperature refrigerant you enter from the space of an inverted water tank, and send it to the other side water tank (4) through the flat tube (1) Space, so heat exchange occurs in the flat tube (1) and heat dissipation: Η (2), and the refrigerant will become lower temperature and reused again. For such heat exchanger tubes and tube header materials, often used A brazed sheet, which contains, for example, the core material of JIS 3 0 0 3 alloy (aluminum-0.15 wt% copper-1.1 wt% manganese), within the core material or is always with The side where the refrigerant contacts is plated with JIS 7072 alloy (aluminum-1% by weight of zinc) as the lining material, and the outer side of the core material is usually coated with a layer of brazing material, such as JIS 4045 alloy (aluminum-10 % By weight of silicon); and it is usually combined with its corrugated heat sink and other components by brazing Use the CNS Grade A 4 specifications (210X297mm) in this paper standard ................................. .................................................. ....... Pretend ...................................................... ... line {please read the precautions on the back before filling the nest page) The Central Consumers ’Bureau of the Ministry of Economic Affairs of the People ’s Republic of China Consumer Printing Co., Ltd. du printing from A6 B6 295604 V. Description of Invention (Z) In addition, Figure 2 shows a love Type cooler, in which a tube formed by hot extrusion method or warm extrusion method (5 > is folded into a curved shape, and contains a wave-shaped hot heat sheet (6), which is brazed Η), is connected to Between the openings of the pipe. In addition, the number (7) indicates a connector β. For the pipe, JIS 3003 alloy, etc. can be used, and for the heat sink, JIS 3 0 0 3 alloy or zinc-containing alloy, etc. can be used. As a core material, for the purpose of producing a sacrificial effect, and a layer of brazing material, such as JIS 4 0 4 5 alloy or JIS 4 3 4 3 alloy (aluminum-7. 5 wt% Of silicon). In Figure 3, a multi-layer type is shown In this evaporator, the fins (2) and the paths forming the refrigerants (8) and (8 ·) and the paths containing the brazed sheets form thin Η (9) and (9 '), alternately stacked , And connect them together by brazing. For this type of heat sink, usually about 0.08 mm thick heat dissipation H material is used, and for the refrigerant path formation sheet, about 0.4 mm thick hard solder is used. In this type of evaporator, in order to avoid external corrosion of the refrigerant path, a fin material with sacrificial anode effect will be used, and for the refrigerant path to form a thin sheet, a brazing sheet will be used, including a layer of A1-1 The core material of the manganese alloy is an alloy doped with copper, zinc, etc. If necessary, the surface can be plated with a brazing material, such as JIS 4 0 0 4 alloy or IS 4 3 4 3 alloy. Moreover, all these heat exchangers are combined by brazing and heated to a temperature close to 6 Q (TC, and brazing techniques include vacuum brazing, rib flux brazing, using non-corrosive The paper scale is in accordance with Chinese National Standard (CNS) A4 specifications (210x297mm) ................................................. ............ Line (Please read the precautions on the back before filling this page) Printed by Employee Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs

化 型 撤 及 輕 減 置 重 於 向 0 趨 等造 法製 焊的 硬韶 ck換 10交 C0熱 ο N , 的來 劑年 熔近 .助 統 傳 以 是 〇 果題 如問 , 多 而許 然生 ε11 Ο 産 的會 要則 需 , 是材 薄壁 變的 的薄 材變 壁造 ,製 故來 緣料 此材 為的 加 片增 薄要 成須 形必 徑 , 路時 媒低 冷降 於厚 用壁 當的 , 片 先熱 首散 及 材 管 如 度 強 以數 料有 材, 之此 )0 等 這加 0 旦 度一 強是 的但 夠, 足份 得成 未合 仍加 是添 但須 ,必 出度 提強 被善 金改 合 了 的為 度 , 強為 高因 種是 近 接 至 熱 加 焊 硬 在 致 導 而 低 降 會 就 點 熔 份 成 金 合 入 象 現 的 解 熔 生 産 時 度 溫 的 熱生 散發 至於 散向 擴傾 料 , 材時 焊少 硬減 和度 曲厚 扭 Η 的熱 Η 散 熱當 散成 時造 焊 會 硬 , 在象 ,現 外等 此中 片 此 I ο 因 1 ,為 象度 現厚 解限 熔極 言 而 片 熱 散 的 片 焊 fic 硬 於 對 的 薄 最 (請先閲讀背面之注意事項再填窝本頁) .装 刖 象 現 曲 杻 生 發 果 如 0 米 檝 通 為 發 開 明 發 本 0 * 率究 效研 熱的 器密 換列 交条 熱 I 低過 降經 而 , ,況 加情 增些 的這 力於 阻對 風 器和 換化 交型 熱檝 的且 性量 s ο 耐輕法 和滅製 度夠之 強能器 良種換 優一交 有及熱 具以金 仍,合 ,片鋁 後焊的 焊硬率 硬金效 經合熱 種鋁高 1 之有 出用具 .訂 經濟部中央標準局貝工消费合作社印製 焊 51 金 合 鋁 的 度 溫 焊 iy 硬 氐 14— 降 能 種 - 了 供 提 先 首 要明 概發 明本 發 徵重不 特5且 其0上 ,、以 矽 料% 材一S 量^ i S 硬0S05 金 2 0 合1 、 過 鋁 銅 aH s一 i % 且 於 量^ ^ S ^ % 8^00 k重超 且 7 # Arn j ,包i 料於 % 材在量 本紙張尺度適用中國國家標準(CNS)甲4规格<210X297公釐)The removal of the model and the reduction of the weight are more important than the welding method of welding to the 0 and the manufacturing method is changed to 10 for C0 heat ο N, the melting point of the coming year is close. It helps to pass the question. Ο The production needs to be required, it is made of thin-walled thin-walled materials, so the thinning of this material is necessary for the thinning of the material to be a must-have, and the low-temperature cooling of the medium is thicker. If the wall is right, the film will be hot first and the material will be as strong as the material, and so on) 0 etc. This plus 0 denier is enough but enough. , It must improve the degree changed by the gold, the strength is high, because the species is close to the heat and welding hard in the lead, and the low drop will be the melting point into the gold into the current melting production time. The warm heat dissipates to the spreading material, and the material is less hardened and the thickness is twisted. The heat dissipation of the heat is dissipated. When the heat is dissipated, the welding will be hard. In the image, it is waiting for this piece. 1, the sheet welding fic for the heat dissipation of the thickness of the image and the heat dissipation limit For the right thin most (please read the precautions on the back and fill in the nest page). The appearance of the elephant is like a Quqi fruit, such as 0 meters. It is an open encyclopedia. The heat of crossover I is lower than that of lowering the warp, and the situation is more increased. This force is for the resistance of the air heater and the exchange type heat. The light resistance and the system are strong enough. The delivery and heating tools are still in gold, and the welding hardness of the aluminum sheet is after welding. The gold alloy has a high value of 1. It is a high-quality aluminum alloy. It is printed by the Central Bureau of Standards of the Ministry of Economic Affairs. Degree temperature welding iy hard di 14-energy-reducing species-the first is to provide the first summary of the invention, the weight of the invention is not special, and its value is 0, with the silicon material% material-S amount ^ i S hard 0S05 gold 2 0 1. Over-aluminum copper aH s-i% and the amount ^ ^ S ^% 8 ^ 00 k is overweight and 7 # Arn j, including the material is at the%. Specification < 210X297mm)

經濟部t央標準局貝工消費合作社印製 五、發明説明(4 ) _過0.5重量%的鐵,以及更進一步含有至少一種自以 下元素之物質:0.5重量%以上且不超過5.5重量%的鋅 、0.0 0 2重量%以上且不超過0.3重量%的姻、和0.002 重量%以上且不超遇0.3重量%的錫,其餘的成份則為 鋁和一些無可避免的雜質。 此外,本發明的另一種硬焊材料是一種鋁合金硬焊材 料,其待擞在於包含7.0重量%以上且不超過12.0重量% 的矽、0.5重量欠以上且不超過3.0重量%的銅、0.05重 量%以上且不超過0.4重量%的鐵,1.0重量%以上且不 超過5 . 0重量%的鋅,或者是更含有一或兩種0 . 0 0 2重量% 以上且不超過0.05重量%的铟和0.002重量%以上且不 超過fl.05重量%的錫,其餘的成份則為鋁和一些無可避 免的雜質。 此外,本發朗經硬焊後仍具有雇良強度和耐蝕性之鋁 合金硬焊片,可用來做為如圖1所示之扁平管(1)和構 成散熱器之缝熔接管的管集箱(3),其特擞傜在此種熱 交換器用的鋁合金硬焊片中,具有三層結構,在鋁合金 所組成的核心材料的一側,鍍上含鋁合金的硬焊材料, 並且在另一側鍍上含鋁合金的犧牲性材料;有一種鋁合 金材料用來做為硬焊材料,其含有7.0重量%以上且不 超過12.0重量%的矽、0.5重量%以上且不超過8.0重量% 的銅、0.05重最%以上且不超過0.5重景%鐵,以及更 進一步含有至少一種選自以下元素之物質:0.5重量% -6 - 本紙張尺度逋用中國國家標準(CNS)甲4規格(210X297公釐> .....................................................................................裝.......................訂.....................線 (請先閲讀背面之注意事項再填窝本頁) 經濟部中央標準局員工消費合作社印製 A6 B6 五、發明説明(5 ) 以上且不超過5. 5重量%的鋅、0.002重量%以上且不超 過0.3重量%的洇、和0.0Q2重量%以上且不超過0.3重 量%的錫,其餘的成份則為鋁和一些無可避免的雜質; 還有一種鋁合金材料用來做為核心材料,其含有G . 6重 量%以上且不超過2. 5重量%的矽、0.5重量%以上且不 超過2. 5重量%的銅、0.05重量%以上且不超過2.0重量% 的錳,或者更進一步含有至少一種選自以下元素之物質 :0 . 0 3重量%以上且不超過0 . 5重量%的鎂、0 . 0 3重量% 以上且不超過〇 . 3重量%的鉻、0 . 0 3重量%以上且不超過 0.3重量%的銷、0.03重量%以上巨不超過0.3重量%的 鈦、0 . 0 3重量%以上且不超過1 . 5重量%的鎳,其餘的 成份則為鋁和一些無可避免的雜質;另外還有一種鋁合 金材料用來做為犧牲性材料,其含有至少一種選自以下 元素的物質:0.5重量%以上且不超過6.0重量%的鋅、 0.002重量%以上且不超過0.3重量%的絪、0.002重量% 以上且不超過0.3重量%的錫,或者是更含有一或兩種 0.05重量%以上且不超過2. 5重量%的鎂和0. 05重量% 以上fl不超過1 · 6重鼉%的錳,其餘的成份則為鋁和一 ◎無可避免的雜質。 本發明還有一種鋁合金硬焊片,可用來做為_3中所 示之多層型蒸發器的冷媒路徑形成薄片(9 )和(9 | ),或 者是圖2中所示之冷卻器的波形散熱Η ( 6 ),其特撖在 於包含一種核心材料,所使用的鋁合金包含0 . 6重量% -7 - 本紙張尺度適用中國國家標準(CNS)甲4规格(210x297公釐) 裝......................訂...................線 {請先閲讀背面之注意事項再填窝本頁) A6 B6 經濟部中央標準局員工消費合作社印製 五、發明説明(6 ) 以上且不超過2.5重量%的矽、0.5重量%以上且不超過 2. 5重量%的銅、0.05重量%以上且不超過2.0重量%的 錳,或者更進一步含有至少一種選自以下元素之物質: 0.03重量%以上且不超過0.5重量%的鎂、0.03重量% 以上且不超過0.3重蛋%的鉻、0.03重量%以上且不超 過0.3重量%的結、0.03重量%以上且不超過0.3重量% 的鈦,以及0 . 0 3軍最%以上且不超過1 . 5重量%的鎳, 其餘的成份則為鋁和一些無可避免的雜質,並且在其兩 側同時鍍上一層鋁合金硬焊材料,其包含7 . 0重量%以上 目不超過]2.0重量%的矽、重量%以上且不超過8.0 重量%的銅、0.05重量%以上且不超過0.5重量%鐵, 以及更進一步含有至少一種選自以下元素之物質:0.5 重量%以上且不超過5. 5重量%的鋅、0.002重量%以上 且不超過0.3重量%的絪、和0.002重量%以上且不超過 0.3重量%的錫,其餘的成份則為鋁和一些無可避免的 雜質。 還有,本發明有一種鋁合金硬焊Μ,可用來做為鋁合 金散熱Η,而製得重最輕S熱效率高的熱交換器,其特 徽在於含有一種使用鋁合金之核心材料,其包含0.03重 最%以上且不超過2 . 5重鼉%;的矽、0 . 0 5重量%以上且 不超過2 . 0重量%的鐵、0 · 0 5重最%以上且不超過2 . 0重 量%的銅、0 . 6重量%以上且不超過2 . 0重量%的錳,以 及更進一步含有至少一種選自以下元素之物質:().0 5重 裝.......................玎.....................線 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度逋用中國Η家搮準(CNS)甲4規格(210x297公釐) 205604Printed by the Beigong Consumer Cooperative of the Ministry of Economic Affairs and the Central Standards Bureau. 5. Description of the invention (4) _ More than 0.5% by weight of iron, and further containing at least one substance from the following elements: 0.5% by weight and not more than 5.5% by weight Zinc, 0.02% by weight and not more than 0.3% by weight, and 0.002% by weight and not more than 0.3% by weight of tin, the remaining components are aluminum and some inevitable impurities. In addition, another brazing material of the present invention is an aluminum alloy brazing material, which is composed of silicon containing 7.0% by weight or more and not more than 12.0% by weight, copper less than 0.5% by weight and not more than 3.0% by weight, 0.05 More than and not more than 0.4% by weight of iron, not less than 1.0 and not more than 5.0% by weight of zinc, or one or two of more than 0.02% by weight and not more than 0.05% by weight Indium and tin above 0.002% by weight and not more than fl.05% by weight, the remaining components are aluminum and some inevitable impurities. In addition, the aluminum alloy brazing sheet with excellent strength and corrosion resistance after brazing is used as a flat tube (1) as shown in FIG. 1 and a seam fusion tube that constitutes a radiator. Box (3), which is special in aluminum alloy brazing pieces for this kind of heat exchanger, has a three-layer structure, on one side of the core material composed of aluminum alloy, plated with aluminum alloy brazing material, And the other side is plated with sacrificial material containing aluminum alloy; there is an aluminum alloy material used as a brazing material, which contains more than 7.0% by weight and not more than 12.0% by weight of silicon, more than 0.5% by weight and not more than 8.0% by weight of copper, 0.05% by weight or more and not more than 0.5% by weight of iron, and further containing at least one substance selected from the following elements: 0.5% by weight -6-This paper scale uses the Chinese National Standard (CNS) A 4 specifications (210X297mm> ................................................... ...................................... Pretend ... ................................................ (Please read the precautions on the back first (Fill this page) Central Ministry of Economic Affairs A6 B6 printed by the Bureau ’s Consumer Cooperatives V. Description of invention (5) Zinc of 5% or more, 5% by weight or more, 0.002% by weight or less than 0.3% by weight, and 0.0Q2% by weight or more than 0.3 5% by weight of tin, the remaining components are aluminum and some inevitable impurities; there is also an aluminum alloy material used as a core material, which contains G. 6% by weight and not more than 2.5% by weight of silicon , 0.5% by weight or more and not more than 2.5% by weight of copper, 0.05% by weight or more and not more than 2.0% by weight of manganese, or further containing at least one substance selected from the following elements: 0.03% by weight or more and Magnesium not exceeding 0.5% by weight, chromium not exceeding 0.03% by weight and not exceeding 0.3% by weight, pins not exceeding 0.03% by weight but not exceeding 0.3% by weight, not exceeding 0.03% by weight More than 0.3% by weight of titanium, 0.03% by weight or more and not more than 1.5% by weight of nickel, the remaining components are aluminum and some unavoidable impurities; there is also an aluminum alloy material used as Sacrificial material containing at least one selected from Elemental substance: 0.5 wt% or more and not more than 6.0 wt% zinc, 0.002 wt% or more and 0.3 wt% or less, 0.002 wt% or more and not more than 0.3 wt% tin, or one or two more More than 0.05% by weight and not more than 2.5% by weight of magnesium and 0.05% by weight or more and fl not more than 1.6% by weight of manganese, the remaining components are aluminum and ◎ inevitable impurities. The present invention also has an aluminum alloy brazing sheet, which can be used as a refrigerant path forming sheet (9) and (9 |) of the multilayer evaporator shown in _3, or the cooler shown in FIG. 2. Wave heat dissipation Η (6), its special feature is that it contains a core material, the aluminum alloy used contains 0.6% by weight -7-This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210x297 mm). ..................... order ................... line {please read the notes on the back first (Refill this page) A6 B6 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of invention (6) Silicon above 2.5% by weight and copper above 0.5% by weight 2.5 0.05% by weight or more and not more than 2.0% by weight of manganese, or further containing at least one substance selected from the following elements: 0.03% by weight or more and not more than 0.5% by weight magnesium, 0.03% by weight or more and not more than 0.3% by weight Chromium, 0.03% by weight and no more than 0.3% by weight, 0.03% by weight and no more than 0.3% by weight of titanium, and 0.03% of the most No more than 1.5% by weight of nickel, the rest of the composition is aluminum and some inevitable impurities, and both sides are coated with a layer of aluminum alloy brazing material, which contains more than 7.0% by weight ] 2.0% by weight of silicon, more than 8.0% by weight and not more than 8.0% by weight of copper, 0.05% by weight and not more than 0.5% by weight of iron, and further containing at least one substance selected from the following elements: 0.5% by weight and not More than 5.5% by weight of zinc, 0.002% by weight and not more than 0.3% by weight, and 0.002% by weight and not more than 0.3% by weight of tin, the remaining components are aluminum and some inevitable impurities. In addition, the present invention has an aluminum alloy brazed Μ, which can be used as an aluminum alloy heat dissipation Η, and the heat exchanger with the lightest weight and high thermal efficiency is produced. The special emblem is that it contains a core material using aluminum alloy. Contains 0.03% by weight or more and not more than 2.5% by weight; silicon, 0.05% by weight or more and not more than 2.0% by weight of iron, 0.05% by weight or more and not more than 2. 0% by weight of copper, 0.6% by weight or more and not more than 2.0% by weight of manganese, and further containing at least one substance selected from the following elements: (). 0 5 reload ...... .............................................. (Please read the precautions on the back before filling in this Pages) This paper uses the standard of China National Standard (CNS) A 4 (210x297 mm) 205604

----------------- 1修正 ϋ4.9.2 9 年· q----------------- 1 correction ϋ 4.9.2 9 years · q

經濟部中央標準局貝工消費合作社印製 五、發明説明(7 ) 置以上且不超遇5.0重量%的鋅、0.002重置%以上且不 超過0.3重量%的絪、和0.002重量%以上且不超過0.3 重量%的鍚,或者是更進一步含有至少一種選自以下元 素之物質:0.03重量%以上且不超過0.5重量%的鎂、 0.05重量%以上且不超過2重量%的鎳、0.03重量%以 上且不超過〇 . 3重量%的鉻、G . 0 3重量%以上且不超過 0.3重董%的結和0.03重量%以上且不超過0.3重量%的 鈦,其餘的成份則為鋁和一些無可避免之雜質,並且在 其兩餹同時鍍上一層鋁合金硬焊材料,其包含7.fl重量% 以上且不超過12.0重量96的矽、0.5重量%以上且不超過 8.0重量%的銅、0.05重量%以上且不超過0.5重量%的 鐵,以及更進一步含有一至少一種選自以下元素之物質: 0.5重量%以上且不超過5.5重量%的鋅、0.002重量以上 且不超過0.3重量%的絪、和0.002以上且不超過0.3重 量%的錫,其餘的成份則為鋁和一些無可避免的雜質。 此外,本發明的另一種鋁合金硬焊片,可用來做為散 熱片材料,其待徵在於含有一種使用鋁合金之核心材料 ,其包含0.03重量%以上且不超過2.5重量%的矽、0.05 重量以上且不超過2.0重量%的鐵、0.05重量%以上且 不超過2.0重量%的銅,以及更進一步含有至少一種選自以 下元素之物質:0.05重量%以上且不超過5.0重量%的鋅 、0.002重量%以上且不超過0.3重量%的洇、和0.002重 本紙張尺度適用中國國家標準(CNS)甲4規格(210X297公釐) .....................................................................................裝..................…訂.....................線 (請先閲讀背面之注意事項再填窝本頁) A7 B7 經濟部中央標準局員工消費合作杜印製 1···扁平管 3…管集箱 5…管材 7…數字 8 五、發明説明( 置%以上且不超過0.3重量%的錫,或者是更進一步含 有至少一種選自以下元素之物質:0.03重量%以上且不 超過0.5重量%的镁、0.03重量%以上且不超過0.6重 量%的錳、0.05重量%以上且不超過2.0重量%的鎳、 0.03重量%以上且不超過0.3重量%的鉻、0.03重量% 以上且不超過0.3重量%的誥和0.03重量%以上且不 超過0 . 3重量%的鈦,其餘的成份則為鋁和一些無可 避免的雜質,並且在其兩側同時鍍上一層鋁合金硬焊材 料,其包含7.0重置%以上且不超過12.0重量%的矽、 0.5重量%以上且不超過8.0重量%的銅、0.05重量% 以上且不超過0.5重置%的鐵,以及更進一步含有至少 一種選自以下元素之物質:0.5重量%以上且不超過 5.5重量%的鋅、0.002重量%以上且不超過0.3重量% 的絪和0.002重量以上且不超過0.3重量%的錫,其餘的 成份則為鋁和一些無可避免的雜質。 本發明還關於一種用來製造鋁合金熱交換器的方法, 其待徵在於:在製造熱交換器的方法中,偽以硬焊的技 術來連接鋁合金成份,硬焊加熱偽以上述的硬焊材料或 硬焊Μ ,在5 7 0到5 8 5 3C的溫度下進行。 圖式之簡單說明 圖1係顯示散熱器的部分剖面斜視圖。 圖2係顯示彎曲型冷卻器的斜視圖。 圖3係顯示多層型蒸發器的部分剖面斜視圖。 符號之說明 2…薄狀散標熱Η 4…水箱 6…波形散熱Η 媒路徑 9…路徑形成薄Η 發明詳細説明 本發明的構成如前文中所述。以下將對每一項發明做 10 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) I:---^------批衣------1Τ------,,i (請先閲讀背面之注意事項再填寫本頁)Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of Invention (7) Zinc not exceeding 5.0% by weight, Zinc exceeding 0.002% and not exceeding 0.3% by weight, and 0.002% by weight or more No more than 0.3% by weight of thorium, or a substance further containing at least one element selected from the group consisting of: 0.03% by weight and more than 0.5% by weight of magnesium, 0.05% by weight and more than 2% by weight of nickel, 0.03% by weight % And more than 0.3% by weight of chromium, G. 0 3% by weight and not more than 0.3% by weight of the junction and 0.03% by weight and not more than 0.3% by weight of titanium, the remaining components are aluminum and Some inevitable impurities, and the two layers are coated with a layer of aluminum alloy brazing material at the same time, which contains 7.fl% by weight and not more than 12.0% by weight of 96 silicon, 0.5% by weight and not more than 8.0% by weight Copper, 0.05% by weight or more and not more than 0.5% by weight of iron, and further containing at least one substance selected from the following elements: 0.5% by weight or more and not more than 5.5% by weight of zinc, 0.002% by weight or more Generative force of over 0.3 wt%, and more than 0.002 and not more than 0.3% by weight of tin and the balance aluminum and some of the ingredients was inevitable impurities. In addition, another aluminum alloy brazing sheet of the present invention can be used as a heat sink material, which is characterized by containing a core material using aluminum alloy, which contains 0.03% by weight and not more than 2.5% by weight of silicon, 0.05 More than iron and not more than 2.0% by weight of iron, 0.05% or more and not more than 2.0% by weight of copper, and further containing at least one substance selected from the following elements: 0.05% or more and not more than 5.0% by weight of zinc, 0.002% by weight and not more than 0.3% by weight of 洇, and 0.002 copies of the paper size apply the Chinese National Standard (CNS) A 4 specifications (210X297 mm) ................ .................................................. ........................................... Order ... ........... Line (please read the precautions on the back before filling the nest page) A7 B7 Dumpling 1 of the Consumer Cooperation Cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs 1 ··· Flat tube 3… Tube header 5 ... Tube 7 ... Number 8 V. Description of the invention (set% or more and not more than 0.3% by weight of tin, or further contains at least one selected from the following elements Quality: 0.03 wt% or more and not more than 0.5 wt% magnesium, 0.03 wt% or more and not more than 0.6 wt% manganese, 0.05 wt% or more and not more than 2.0 wt% nickel, 0.03 wt% or more and not more than 0.3 wt% % Chromium, 0.03% by weight and no more than 0.3% by weight, and 0.03% by weight and no more than 0.3% by weight titanium, the remaining components are aluminum and some inevitable impurities, and in both The side is simultaneously coated with a layer of aluminum alloy brazing material, which contains 7.0 reset% or more and not more than 12.0 wt% silicon, 0.5 wt% or more and not more than 8.0 wt% copper, 0.05 wt% or more and not more than 0.5 reset % Iron, and further containing at least one element selected from the group consisting of: 0.5% by weight or more and not more than 5.5% by weight of zinc, 0.002% or more and not more than 0.3% by weight, and 0.002% or more and not more than 0.3 % By weight of tin, and the remaining components are aluminum and some inevitable impurities. The invention also relates to a method for manufacturing an aluminum alloy heat exchanger, which is to be characterized by: In the method, the aluminum alloy components are connected by pseudo brazing technology, and the brazing heating is preformed by the above brazing material or brazing M at a temperature of 5 7 0 to 5 8 5 3C. Brief description of the drawings Fig. 1 is a partial cross-sectional oblique view of a radiator. Fig. 2 is a perspective view of a curved cooler. Fig. 3 is a partial cross-sectional perspective view of a multi-layer evaporator. DESCRIPTION OF SYMBOLS 2 ... Thin bulk heat Η 4 ... Water tank 6 ... Wave heat dissipation Η Media path 9 ... Path forming thin Η Detailed description of the invention The structure of the present invention is as described above. The following will make 10 paper scales for each invention and apply the Chinese National Standard (CNS) A4 specifications (210X297mm) I: --- ^ ------ batch apparel ------ 1Τ --- --- ,, i (Please read the notes on the back before filling this page)

經濟部中央標準局員工消費合作社印製 五、發明説明(9 ) 吏詳细的説明β首先,所發明可用於管子和管集箱之硬 焊片,其具有三層結構,偽於核心材料的一供鍍上硬焊 材料,而在另一制鍍上犧牲性的材料,而此硬焊片組合 方式傜將硬焊材料的表面朝向外钥,犧牲性材料的表面 則是朝向冷媒路徑形成薄Η的那一脚。 同時,此種用於管子和管集箱之硬焊片的核心材料為 一種鋁合金,其包含0.6重量%以上且不超過2. 5重量% 的矽、0 . 5重量%以上且不超過2 . 5重董%的銅、0 . 0 5重 量%以上且不超遇2.0重量%的錳,或者是更進一步含 有至少一種選自以下元素之物質:0.03重量%以上且不 超過0.5重量%的镁、0.03重量%以上且不超過0.3重量% 的絡、0.03重量%以上且不超過0.3重量%的結、0.03 重置%以上且不超過0.3重量%的鈦和0.03重量%以上 且不超過1 .5重量%的鎳,其餘的成份則為鋁和一些無 可避免的雜質。 上述之各値添加成份所扮演的角色和用量限制的理由 ,將在下文中做一說明。 矽是用來改善強度的。然而,如果其用量不超過0.6 重量%時,無法獲得改善的效果。此外,在傳統的硬焊 溫度下,矽的最大添加量為1重量%左右,但是在本發 明中,因為硬焊溫度的降低而可提高矽的添加量。還有 ,如果添加量不超過1.2重量%時,矽對於改善強度的 效果與傳統的冷媒路徑組成成份之效果一樣好,但是經 本紙張尺度適用中國國家標準(CNS)甲4規格<210X297公釐) (請先閲讀背面之注意事項再填窝本頁) .裝 •訂 線. 五、發明説明(10 ) 明 説 中 文 下 ο在 加將 添這 時’ 同佳 由為Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (9) Detailed description of the β First, the invention can be used for the brazing pieces of pipes and headers, which has a three-layer structure, which is pseudo-core One is for brazing material, and the other is for sacrificial material, and this brazing plate combination method makes the surface of the brazing material facing the external key, and the surface of the sacrificial material is facing the refrigerant path to form a thin Η's foot. At the same time, the core material of such brazing pieces for pipes and headers is an aluminum alloy, which contains 0.6% by weight or more and not more than 2.5% by weight of silicon, 0.5% by weight or more and not more than 2 .5% by weight of copper, 0.05% by weight or more and not exceeding 2.0% by weight of manganese, or further containing at least one substance selected from the following elements: 0.03% by weight or more and not more than 0.5% by weight Magnesium, 0.03% by weight or more and 0.3% by weight or less, 0.03% by weight or more and 0.3% by weight or more, 0.03% by weight or more and 0.3% or less by weight of titanium, and 0.03% or more by weight and not more than 1 .5 wt% nickel, the remaining components are aluminum and some inevitable impurities. The above-mentioned roles of the added ingredients and the reasons for the limitation of dosage will be explained below. Silicon is used to improve strength. However, if the amount does not exceed 0.6% by weight, the improvement effect cannot be obtained. In addition, at the conventional brazing temperature, the maximum addition amount of silicon is about 1% by weight, but in the present invention, the addition amount of silicon can be increased because of the reduction in the brazing temperature. In addition, if the added amount does not exceed 1.2% by weight, the effect of silicon on improving strength is as good as that of the traditional refrigerant path components, but the Chinese standard (CNS) A4 specification < 210X297 mm ) (Please read the precautions on the back before filling the nest page). Binding • Binding. Fifth, the description of the invention (10) Explain clearly in Chinese ο will be added at this time 'Tongjia Youwei

時 % 量 Omil S 使卜更 ^ ^ ^,吧傳銅aofcb 的SB得 說 %中獲 量文能 重r 可 A6 B6 改 度 度果強強了 得佳 统 傳 比 至 過 超 量 加 度 程 善When the amount of Omil S is more than ^ ^ ^, it is said that the SB of the copper aofcb has to say that the percentage of the content obtained in the text is heavy r can be A6 B6 The degree of change is strong and the result is good good

性 蝕 附 時 % 量 S 合 化 矽 的 糙 粗 成 生 中 1.料 過材 超心 量核 加在 添為 的因 矽是 果這 如 0 ,低 外降 之 會 此時 除有 使 。 , 慮 免考 避入 來列 序序 程程 産産 生生 制將 控需 由故 0 , 須物 此合 因化 , 的 象糙 琨粗 的生 起産 引法 而無 物其When corrosive corrosion is added, the amount of S is the roughness of the silicon compound. 1. It is expected that the material's supercentric core is added to the Tianwei silicon. If this is like 0, the low drop will be caused at this time. , Consider avoiding the examination and avoid entering the order process. The production, production and production system will control the need for reasons.

時 % 量 S 掉 解 熔 會 也 料 2 材 過心 超核 量 , 加下 添度 果溫 如焊 6-!/ , 硏 果的 如明 ,發 且本 並在 是 使 ΕΠ 則 {請先閲讀背面之注意事項再填窝本頁) 中 金 合 於過 在超 存不 態量 狀含 的的 體銅 溶果 固如 以 0 係度 鋦強 , 的 次金 其合 善 可 且 並 強 則 % 量 S 5 -裝 過擻 超特 量項 用一 的的 銅量 。加 足添 不之 果銅 效中 的明 善發 改本 度為When the amount of S is off, the melting will also take the material into two cores, and add the extra core temperature, add the temperature of the fruit like welding 6-! (Notes on the back and fill in this page) The gold content in the super-existent state of the body is contained in the body of copper-soluble fruit solid. Quantity S 5-The amount of copper used to fill the super special quantity. If you add enough, you will be able to make a clear change in the copper effect.

況 情 的 % 量 S S 金 合 的 銅 含 用 使 當 BK- ap -I 焊〜間 在tt界 鋦 之 為 料 因ί材(* ^ 砠®核 stttftlf 料 性得Η 材S 0Β. 澍 , i 3 Ϊ 為 内中 因 ,層(C 時牲蝕 料犧泡 材至生 心散産 核擴且 為,並 做時 , 心 核 至 加 添 能 正一 真I 翬 此BS 用 因 卩使 K之 餍鋦 鋦的 缺度 層強 一 善 成改 生以 合E 用 近中 附料 的材 過 超 能 不 般 超忡 以牲 可犧 量和 用料 使材 的焊 銅硬 ,於 中對 明文 發下 本在 在將 , 由 地理 反其 相 , 。% % 量 量車 gl 一 5 5 ο ο過 -訂 經濟部中央標準局員工消費合作社印製 1使 過的 超銅 會果 不如 量 , 用而 使然 的 C 銅低 般降 一 的 , 點 外熔 此成 C 造 明會 説那 中為 述因 2 0 ,過 的%超 料最最 材重用The amount of% of the situation is that the copper content of the SS alloy is used when the BK- ap -I is welded between the tt boundary and the material is due to the material. 3 Ϊ is the internal cause, the layer (at C, the sacrificial material sacrifices the foam material to expand the core of the raw heart, and when it is done, the core is added to the core to be able to be true I. This BS uses K to cause K The lacking layer of 鋦 馦 is a good one, and it is regenerated to suit E. The materials used in the near-medium material are too good to be super. It can be sacrificed and the materials are used to make the copper of the material hard. Originally, the geography is reversed. %% of the volume of the car gl a 5 5 ο ο over-subscription-printed by the Ministry of Economic Affairs Central Standards Bureau employee consumer cooperative 1 printed super copper will not be as good as the amount used The C copper is as low as one, and it is melted out of the point to form C. It will be said that the reason is that the 20% is the most used material.

發 本 用 使 是 使 即 降 下 # 點 熔 刖 % 量 ϋιηι 一 S 本紙張尺度適用中國國家標準(CNS)甲4规格(210x297公釐) 經濟部中央標準局員工消費合作社印製 A6 B6 五、發明説明(11 ) 明的硬焊合金,也會導致在硬焊時産生熔解的現象。因 此,銅之使用量的上限為2 . 5重量%,特別是在添加量 介於0.8到1.5重量%之時間時,顯示出安定的特性。 錳將金膈間化合物分佈在合金,並且為改善強度的基 本元素,而不會降低耐蝕性。然而,如果其用量低於 0.05重量%,刖強度將不足,同時,如果添加鼉超過2.0 重量%時,塑模性會降低,而導致在加工時(如組裝), 硬焊Η破裂。 鎂傜以固溶體的狀態存在於合金中,並且為一種徽細 的矽化鎂沈澱相,以改善強度。然而,如果使用量低於 0 . 0 3重量%,刖無法獲得改善強度的效果,如果使用量 超過0.5重量96,刖當以一種非腐蝕性的助熔劑來進行 硬焊時,肋熔劑會和纟II進行反應,而使得硬焊無法成功。 銘、結和鈦皆形成徹細的金靨間化合物,並且可改善 合金的強度β然而,如果任何一種的用量低於0.03重量% 時,無法獲得強度改善的效果,同時,如果添加量超過 0.3重景%時,塑模性會降低,而導致在加工時如甜裝}, 硬焊片破裂。 鎳也是形成徹細的金驕間化合物,並&可改善合金的 強度。然而,如果其用景低於0.03重最%時,無法獲得 強度改善的效果,同時,如果添加量超過〗.5重量%時 ,塑模性胄降低,而導致在加工時(如組裝),硬焊片破 裂。 -1 3 - 本紙張尺度適用中國國家標準(CNS)甲4規格(210X297公釐) 裝.......................町.....................線 {請先閲讀背面之注意事項再填窝本頁)The use of the original version is to make the lowering # point melting rate% amount ϋιηι S This paper scale is applicable to China National Standards (CNS) A 4 specifications (210x297 mm) A6 B6 printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Note (11) The brazing alloy described also causes melting during brazing. Therefore, the upper limit of the amount of copper used is 2.5% by weight, and especially when the amount of addition is between 0.8 and 1.5% by weight, it shows stable characteristics. Manganese distributes the gold diaphragm compound in the alloy, and is an essential element for improving strength without reducing corrosion resistance. However, if the amount is less than 0.05% by weight, the strength will be insufficient. At the same time, if the added amount exceeds 2.0% by weight, the moldability will be reduced, resulting in cracking of the brazed solder during processing (such as assembly). Magnesium is present in the alloy as a solid solution and is a finely precipitated magnesium silicide phase to improve strength. However, if the amount used is less than 0.03% by weight, the strength improvement effect cannot be obtained. If the amount used exceeds 0.5% by weight 96, when the brazing is performed with a non-corrosive flux, the rib flux will Min II reacted, making brazing unsuccessful. Ming, knot, and titanium all form a fine intermetallic compound, and can improve the strength of the alloy. However, if the amount of any one is less than 0.03% by weight, the strength improvement effect cannot be obtained. At the same time, if the amount exceeds 0.3 At a double weight%, the moldability will be reduced, which leads to cracking of the brazing sheet during processing such as sweet packaging. Nickel also forms a fine intermetallic compound and can & improve the strength of the alloy. However, if its usage is less than 0.03% by weight, the effect of strength improvement cannot be obtained. At the same time, if the added amount exceeds 0.5% by weight, the moldability decreases, resulting in processing (such as assembly), The brazed piece is broken. -1 3-The size of this paper is in accordance with Chinese National Standard (CNS) Grade 4 (210X297mm) ............................... .................. Line (Please read the precautions on the back before filling this page)

經濟部中央標準局工消費合作杜印製 本發明的核心合金之成份如前所述β除此之外,在不 可避免的雜質之中,鐵是一種代表性的元素。如果含量 不超過1.2重量%時,鐵可包含在合金中。同樣的,如 果含量不超過5重量96,除了上述之外之元素(如硼) 也可分別包含在合金中,造些元素的加入,可使得簿塊 的紋理細緻β 此外,用於管子和管集箱之硬焊Η的硬焊材料,為一 種鋁合金(如前所述),其包含7.0重量%以上且不超過 12.0重量%的矽、0.5重董%以上且不超過8.0重置%的 銅、0.05重量%以上且不超過0.5重置%的鐵,以及更 進一步的含有至少一種選自以下元素之物質:0.5重量% 以上且不超過5.5重量%的鋅、0.002重量%以上且不超 過0.3重量%的絪、和0.002重量%以上且不超過0.3重 量%的錫,其餘的成份則為鋁和一些無可避免的雜質β 一般而言,當使用如本發明中之高強度‘核心材料合金 時,會産生熱交換器外部的附蝕性降低的問題,以及核 心材料因為低熔點而在硬焊時産生熔解的問題,因此使 用此類核心材料之硬焊Η,並未實際被使用。本發明的 硬焊材料合金已解決了這些問題,並且,當其與本發明 的核心材料一併使用時,它可發揮這些效果^亦即,經 由對熱交換器的外部耐蝕性做各種研究後,結果發現: 當將傳統上所使用的硬焊材料合金,與本發明的硬焊材 料合金結合時,加至核心材料合金中的銅,會在硬焊時 -14- 本紙張尺度逍用中困國家標準(CNS)甲4規格<210X297公釐) ....................................................................................裝.......................訂.....................線 (請先閲讀背面之注意事項再填寫本頁} 經濟部中央標準局員工消費合作社印製 A6 B6 五、發明説明(13) 擴散至硬焊材料中,而在硬焊材料和核心材料之界面間 的附近産生一塊低銅區域,並且那塊區域會最先産生腐 蝕現象,因而伴隨箸起泡而引發強烈的腐蝕。在本發明 中,在硬焊材料合金中加入銅,是為了避免銅由核心材 料擴散至硬焊材料中,並且不會在硬焊材料和核心材料 之界面間的附近産生低銅區域,因而改善了耐蝕性。並 且,如果硬焊可在接近5 8 (TC的溫度下進行,而非傳統 硬焊在接近60(TC的溫度下進行時,核心材料合金將不 會産生熔解,因此本發明開發出一種比傳統硬焊材料合 金之硬焊溫度為低的合金。 上述之各個添加成份所扮演的角色和用量限制的理由 ,將在下文中做一說明。 矽降低了合金的熔點,但是,如果其用量不超過7.0 重量%,則熔點的下降量會不足,並且硬焊不可能在低 於5 8 5 °C的溫度下進行。除此之外,如果使用量超過1 2 . 0 重量%,熔點反而上升,而使得硬焊不可能在低於585 °C 的溫度下進行。 銅降低了合金的熔點,並且改善了硬焊材料的流動性 。除此之外,當使用一種添加銅的合金做為冷媒路徑形 成成份時,銅可提高熱交換器之外部_蝕件。亦即,如 前所述,在硬焊材料和路徑形成成份之界而間的附近不 會産生低銅區域,因而改善了射蝕性。此時,如果銅的 用量不超過0 . 1重最%,則該效果並不充份,同時,如 -1 5 - 本紙張尺度適用中國國家標準(CNS)甲4规格(210X297公釐) 裝.......................玎.....................線 {請先閲讀背面之注意事項再填窝本頁}The industrial and consumer cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs du printed the core alloy of the present invention. The composition of the core alloy is as described above. In addition, iron is a representative element among the unavoidable impurities. If the content does not exceed 1.2% by weight, iron may be contained in the alloy. Similarly, if the content does not exceed 5 weight 96, elements other than the above (such as boron) can also be included in the alloy separately, and the addition of these elements can make the texture of the thin block fine. In addition, it is used for pipes and tubes. The brazing material of the header brazing Η is an aluminum alloy (as mentioned above), which contains 7.0% by weight and not more than 12.0% by weight of silicon, 0.5% by weight or more and not more than 8.0 reset% Copper, 0.05% by weight or more and not more than 0.5% replacement iron, and further containing at least one element selected from the following elements: 0.5% or more and not more than 5.5% by weight zinc, 0.002% or more and not more than 0.3% by weight, and 0.002% by weight and not more than 0.3% by weight of tin, the remaining components are aluminum and some inevitable impurities β In general, when using high-strength core materials as in the present invention When alloying, the problem of reduced corrosion resistance outside the heat exchanger and the problem of melting of the core material during brazing due to the low melting point, so it is not practical to use such core materials for brazing Η Use. The brazing material alloy of the present invention has solved these problems, and when it is used together with the core material of the present invention, it can exert these effects ^ That is, after various studies on the external corrosion resistance of the heat exchanger It was found that: when the traditionally used brazing material alloy is combined with the brazing material alloy of the present invention, the copper added to the core material alloy will be used during brazing Sleepy National Standard (CNS) Grade 4 Specification < 210X297mm) ......................................... ........................................... ....................................................................... (Please read first Note on the back and fill in this page} A6 B6 printed by the Employees ’Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Invention Description (13) Diffusion into the brazing material, and a block is produced near the interface between the brazing material and the core material Low copper area, and that area will be the first to produce corrosion, so it will cause strong corrosion along with blistering. In the present invention, copper is added to the brazing material alloy in order to Avoiding the diffusion of copper from the core material into the brazing material, and does not produce a low copper area near the interface between the brazing material and the core material, thus improving the corrosion resistance. And, if brazing can be close to 5 8 (TC It is carried out under the temperature of non-conventional brazing at a temperature close to 60 (TC, the core material alloy will not melt, so the present invention has developed an alloy with a brazing temperature lower than that of the traditional brazing material alloy The role of each of the above added ingredients and the reasons for the amount limitation will be explained below. Silicon reduces the melting point of the alloy, but if its amount does not exceed 7.0% by weight, the decrease in melting point will be insufficient, and It is impossible to perform brazing at a temperature lower than 585 ° C. In addition, if the usage exceeds 12.0% by weight, the melting point rises instead, making brazing impossible at a temperature lower than 585 ° C It is carried out at a temperature. Copper lowers the melting point of the alloy and improves the fluidity of the brazing material. In addition, when an alloy added with copper is used as the refrigerant path-forming component, copper can be lifted. The external eroded part of the heat exchanger. That is, as described above, no low copper area will be generated near the boundary between the brazing material and the path forming component, thus improving the erosion resistance. At this time, if the copper The dosage does not exceed 0.1% of the most weight, the effect is not sufficient, at the same time, such as -15-this paper scale is applicable to China National Standard (CNS) A 4 specifications (210X297 mm) ..... .................................... line {Please read the precautions on the back first Fill this page}

經濟部中央標準局員工消费合作社印製 果銅的用量超過8.0重量%時,則硬焊材料的電位將變 得太高而會先腐蝕冷媒路徑形成成份,而導致降低合金 的滾軋加工性,以及降低耐蝕性,使得其不適合做為熱 交換器用之硬焊片的硬焊材料。為此线故,所以鋦的用 量声為0.5重量%以上,且不超遇8.0重置%,但是待別 是在用里介於0.5到3.5重量%之間時,呈現出安定的待 性》除此之外,當用量為0.8重量%以上,且不超過3.0 重量%時,硬焊材料的流動性和滾軋加工性均優,這是 因為如果用量不超過0.8重量%時,母材的熔點變得較 高的縐故,並且如果用量超遇3.0重量%時,該項特性 就會降低。 鐵可藉箸在硬焊材料熔解之後,而進行固化的時候, 使得结晶顆粒變得細小,而提高硬焊條的強度。添加鐵 的目的就在於此。然而,如果用量未超遇D . 0 5重量%, 則效果並不夠,同時,如果用董超過0.5重量%,則會 在硬焊材料固化時,形成金颶間化合物,而使其成為腐 蝕的起源。特別是在用量不超過0.4重量%時,具有優 良的外部酮蝕性β 鋅的添加降低了合金的熔點。此外,如本發明中所述 ,若硬焊材料合金中添加銅時,由於外部腐蝕而産生發 泡的現象,將可被靨抑,但是硬焊材料的電位將變得比 核心材料要高,因此,在較高速度下,會衍生出形成類 似坑洞的外部的睬蝕的問題。為此緣故,鋅的添加是用 -1 6 - 本紙張尺度逍用中困Η家標準(CNS)甲4规格(210x297公釐) .....................................................................................^......................ΤΓ.....................^ (請先閲讀背面之注意事項再填寫本頁} 經濟部中央標準局員工消費合作社印製 A6 B6___ 五、發明説明(15 ) 來降低硬焊材料的電位,並且使得硬焊材料的電位能接 近核心材料的電位,因而改善_蝕性《然而,如果用量 在0.5重量%以下,刖此種效果不足,同時,如果闬量 超過5 . 5重量%,刖合金的滾軋加工性將會降低,而使 其不適合用來做為熱交換器之硬焊片的硬焊材料。除此 之外,考盧硬焊材料的流動性之後,建議使用量為1至 5重量%之間。 洇和錫的添加目的與鋅相同。也就是說,它們可使得 硬焊材料的電位變得較低,以改善冷媒路徑形成成份的 耐触性β然而,如果其用量不超過0.002重量%,則該 效果並不充份,同時,如果用量超過0.3重量%時,會 降低合金的滾軋加工性。 硬焊材料的合金組成如前文中所述。如果它們的含量 分別不超過0 . 〇 5重量%的話,其中可能含有無可避免的 雜質元素。 此外,這種用於管子和管集箱的硬焊Μ之犧牲性材料 ,如前所述,為一種鋁合金,其包含至少一種選自以下 元素之物質:0 . 5重量%以h.且不超過6 . 0重量%的鋅、 0.002重景%以上且不超過0.3重量%的洇和0.002重量% 以h目不超過0.3重量%的錫,或者是更含有一或兩種 0 . 0 5重量%以h Μ不超過2 . 5重量%的鎂和〇 . 〇 5重量% 以h Η不超過〗.6重量%的錳,其餘的成份則為鋁和一 些無可避免的雜質。 -1 7 - 本紙張尺度適用中《國家標準(CNS)甲4規格(210X297公釐) ............................................................ 裝_i-…— .訂— .……-線 {請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消費合作社印製 A6 B6_ 五、發明説明(认) JIS 7072合金是一種代表性的傳統犧牲性材料合金, 但是當將此種傳統的犧牲性材料合金與本發明之高鋦含 量的核心材料合金結合時,加至核心材料合金中的鋦將 在硬焊時,擴散至犧牲性材料中,而壓制了犧牲性材料 的犧牲效果。為此緣故,可在犧牲性材料中提高鋅的含 量,但是,如果鋅的含量提高時,犧牲性材料的熔點卻 降低了,而導致其在硬焊時熔解。然而,在本發明中, 由於使用了前述之低熔點的硬焊材料合金,所以可增加 鋅的含量。 鋅的添加可對合金提供犧牲效果。然而,如果用量低 於0 . 5重量% ,則此效果不足,同時,如果用量超過6 . 0 重量%時,熔點會降低,卽使是使用本發明的硬焊材料 合金,也會導致在硬焊時熔解。 絪和錫的添加也可對合金産生犧牲效果。然而,如果 用量低於0.002重量%,則此效果不足,同時,如果用 量超過0.3重量%,則合金的滾軋加工性會降低,使得 其不適合做為具三層結構之硬焊片的犧牲性材料。 铐的添加可使得犧牲性材料合金的強度變高,並且改 善整個材料的強度。然而,如果用量低於0.05重量%, 刖無法獲得改善強度的效果,同時,如果用景超過2.5 重最%時,熔點會降低,即使是使用本發明的硬焊材料 合金,也會導致在硬焊時熔解。 錳的添加也可使得犧牲性材料合金的強度變高,並目 -1 8 - 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公釐) ....................................................................................I.......................ΤΓ.....................線 (請先閲讀背面之注意事項再填窵本頁) A6 B6 295604 五、發明説明(17 ) 改善整値材料的強度。然而,如果用量低於〇.05重量% ,刖無法獲得改善強度的效果,同時,如果用量超過1.6 重量% ,則合金的滾軋加工性會降低,使得其不適合做 為具三層結構之硬焊Η的犧牲性材料》 在本發明之犧牲性材料中之合金成份如前文中所述。 在無可避免的雜質中,如果含罱不超過0.5重量%, 則矽可包含其中,但最好含量能不超過0.1重量%。如 果含量不超過0.8重量%,則鐵也可包含在其中,但最 好含量能不超過0.1重量%。同樣的,其它用於改善強 度而異於前面所述之元素,如鉻、結和鈦,也可包含在 雜質的成份中,只要其艏別的含量不超過0 . 0 5重量%。 接下來,本發明之用於冷媒路徑形成薄片(其偽在核 心材料的兩側同時鍍上硬焊片)之硬焊片的構成包括一 種鋁合金核心材料和鋁合金硬焊材料之組合,而該種鋁 合金核心材料包含0 . 6重量%以上且不超過2 . 5重量%的矽 、0.5重量%以上&不超過2.5重量%的銅、0.05重量% 以上目不超過2 · 0軍量%的錳,或者更進一步含有至少 一種選自以下元素之物質:0 . 0 3重詈%以h Η不超過0 . 5 重量%的纟S、 0 . 0 3重景%以h. Μ不超過0 . 3重量%的銘 、0 · 0 3重鼍%以h Η不超過0 . 3重鼉%的結、0 . 0 3重最% 以h Η不超過0 . 3重量%的鈦,以及0 . 0 3重量%以上且 不超過1 · 5軍暈%的鎳,其餘的成份則為鋁和一些無可 避免的雜質;該種鋁合金硬焊材料,則包含7 . 0重量% -1 9 - 本紙張尺度適用中國國家標準(CNS)甲4規格(210X297公釐) {請先閲讀背面之注意事項再填窝本頁) .裝 -訂 經濟部中央標準局員工消費合作社印製 經濟部中央標準局員工消費合作社印製 A6 B6_ 五、發明説明(18 ) 以上且不超過12.0重量%的矽、0.1重量%以上且不超 過8.0重量%的銅、0.05重量%以上且不超過0.5重量% 的鐵,以及更進一步含有至少一種選自以下元素之物質 :0.5重量%以上且不超過5.5重量%的鋅、0.002重量% 以上且不超過0 . 3重量%的絪、和0 . 0 0 2重量%以上且不 超過0.3重量%的錫,其餘的成份刖為鋁和一些無可避免 的雜質。 換句話說,這些核心材料和硬焊材料的合金組成,與 用於管子和管集箱之該種硬焊片之核心材料和硬焊材料 之組成相同,並目.添加元素所扮演的角色和限制的理由 也相同。 接箸將説明本發明之用於高強度鋁合金散熱片之硬焊 片β首先,將在下文中,針對其發展的思維做一説明。 當以上述的硬焊技術來製造鋁合金熱交換器時,通常 是在接近60(TC的溫度下進行加熱。由於60(TC對於散熱 片材料而言,是相當高的溫度,因此衍生出以下的三個 問題:亦即①在加熱時,散熱片彎曲,②在合金中的金 屬間化合物將該溶液重組,而降低散熱Μ的導熱度,以 及③低熔點和高強度的合金不能使用。When the amount of printed fruit copper in the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy exceeds 8.0% by weight, the potential of the brazing material will become too high and will first corrode the formation of the refrigerant path, which will reduce the rolling workability of the alloy. And reduce the corrosion resistance, making it unsuitable as a brazing material for brazing pieces for heat exchangers. For this reason, the dosage of Li is more than 0.5% by weight, and does not exceed 8.0 reset%, but when it is used between 0.5 and 3.5% by weight, it shows a stable waitability " In addition, when the amount is 0.8% by weight or more and not more than 3.0% by weight, the flowability and rolling processability of the brazing material are excellent, because if the amount does not exceed 0.8% by weight, the The melting point becomes higher, and if the amount exceeds 3.0% by weight, this characteristic will decrease. Iron can be used to solidify the crystalline particles after the brazing material is melted and solidifies, thereby increasing the strength of the brazing electrode. This is the purpose of adding iron. However, if the amount does not exceed D. 0 5% by weight, the effect is not enough, and at the same time, if the amount exceeds 0.5% by weight, when the brazing material solidifies, it will form a gold hurricane compound, making it corrosive origin. Especially when the amount is not more than 0.4% by weight, the addition of β zinc with excellent external ketone corrosion lowers the melting point of the alloy. In addition, as described in the present invention, if copper is added to the brazing material alloy, the phenomenon of foaming due to external corrosion will be suppressed, but the potential of the brazing material will become higher than the core material. Therefore, at higher speeds, the problem of the formation of pit-like external pits will arise. For this reason, the addition of zinc is used -1 6-This paper standard is used in the middle of the family standard (CNS) A 4 specifications (210x297 mm) ................... .................................................. ................... ^ ................ TΓ ....... .............. ^ (Please read the precautions on the back before filling in this page) A6 B6___ printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention Instructions (15) to reduce hard The potential of the welding material, and the potential of the brazing material can be close to the potential of the core material, thus improving the corrosion resistance. However, if the amount is less than 0.5% by weight, this effect is insufficient, and if the amount exceeds 5 By weight%, the rolling workability of the alloy will be reduced, making it unsuitable for use as a brazing material for brazing of heat exchangers. In addition, after the fluidity of the Kalu brazing material, it is recommended The use amount is between 1 and 5 wt.%. The purpose of the addition of 洇 and tin is the same as that of zinc. That is, they can make the potential of the brazing material lower to improve the contact resistance of the refrigerant path forming component. If the amount does not exceed 0.002% by weight, the effect is not sufficient, and at the same time, if the amount exceeds 0.3% by weight, the rolling workability of the alloy will be reduced. The alloy composition of the brazing material is as described above. If they If the content of each does not exceed 0.05% by weight, it may contain inevitable impurity elements. In addition, this sacrificial material for brazing of pipes and headers, as mentioned above, is a kind of Aluminum alloy, which contains at least one substance selected from the following elements: 0.5 wt% to h. And not more than 6.0 wt% zinc, 0.002 wt% or more and not more than 0.3 wt% 洇 and 0.002 wt% With tin mesh not exceeding 0.3% by weight of tin, or containing one or two of 0.05% by weight with h Μ not exceeding 2.5% by weight of magnesium and 0.05% by weight with h Η not exceeding〗 .6% by weight of manganese, the remaining components are aluminum and some inevitable impurities. -1 7-This paper scale is applicable to the "National Standard (CNS) A 4 specification (210X297 mm) ... .................................................. .... 装 _i-… —. — .......- line (please read the precautions on the back before filling in this page) A6 B6_ printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (recognition) JIS 7072 alloy is a representative traditional sacrifice Material alloy, but when this traditional sacrificial material alloy is combined with the core material alloy of high content of the present invention, the metal material added to the core material alloy will diffuse into the sacrificial material during brazing, and Suppresses the sacrificial effect of sacrificial materials. For this reason, it is possible to increase the zinc content in the sacrificial material, but if the zinc content is increased, the melting point of the sacrificial material is reduced, causing it to melt during brazing. However, in the present invention, since the aforementioned low melting point brazing material alloy is used, the zinc content can be increased. The addition of zinc can provide a sacrificial effect on the alloy. However, if the amount is less than 0.5% by weight, this effect is insufficient, and at the same time, if the amount exceeds 6.0% by weight, the melting point will be reduced, even if the brazing material alloy of the present invention is used, it will also lead to hard Melted during welding. The addition of 絪 and tin can also have a sacrificial effect on the alloy. However, if the amount is less than 0.002% by weight, this effect is insufficient, and at the same time, if the amount exceeds 0.3% by weight, the rolling workability of the alloy will be reduced, making it unsuitable as a sacrificial layer with a three-layer structure of brazing pads material. The addition of handcuffs can increase the strength of the sacrificial material alloy and improve the strength of the entire material. However, if the amount is less than 0.05% by weight, the effect of improving strength cannot be obtained. At the same time, if the usage exceeds 2.5% by weight, the melting point will be reduced. Even if the brazing material alloy of the present invention is used, it will lead to hard Melted during welding. The addition of manganese can also increase the strength of the sacrificial material alloy, and the head -1 8-This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210x297 mm) ......... .................................................. ....................... I .................... TΓ .. ................... line (please read the notes on the back before filling this page) A6 B6 295604 V. Description of the invention (17) Improve the strength of the whole material . However, if the amount is less than 0.05% by weight, the effect of improving strength cannot be obtained. At the same time, if the amount exceeds 1.6% by weight, the rolling workability of the alloy will be reduced, making it unsuitable as a hard with a three-layer structure Sacrificial Material of Welding H》 The alloy composition in the sacrificial material of the present invention is as described above. Among the unavoidable impurities, if the content does not exceed 0.5% by weight, silicon may be included, but the content is preferably not more than 0.1% by weight. If the content does not exceed 0.8% by weight, iron may be included, but the optimal content is not more than 0.1% by weight. Similarly, other elements that are used to improve the strength and are different from the foregoing, such as chromium, knot, and titanium, may also be included in the composition of impurities, as long as the content of the other does not exceed 0.05% by weight. Next, the composition of the brazing pads used in the refrigerant path forming sheet (which is simultaneously plated with brazing pads on both sides of the core material) includes a combination of an aluminum alloy core material and an aluminum alloy brazing material, and This kind of aluminum alloy core material contains 0.6 wt% or more and not more than 2.5 wt% silicon, 0.5 wt% or more & not more than 2.5 wt% copper, 0.05 wt% or more and no more than 2.0 military % Manganese, or further containing at least one substance selected from the group consisting of: 0.03 weight% with h Η not more than 0.5% by weight, S, 0.03 weight% with h. Μ 不More than 0.3% by weight of inscriptions, 0. 0 3% by weight of knots with h Η not exceeding 0.3% by weight, 0.03% by weight of most titanium with h Η not more than 0.3% by weight, And 0.03% by weight or more and not more than 1.5% of military halo% nickel, and the remaining components are aluminum and some inevitable impurities; this aluminum alloy brazing material contains 7.0% by weight- 1 9-This paper scale is applicable to China National Standard (CNS) A4 specifications (210X297mm) {Please read the notes on the back before filling This page). Binding-book printed by the Ministry of Economy Central Standards Bureau employee consumer cooperatives printed by the Ministry of Economics Central Standards Bureau employee consumer cooperatives A6 B6_ V. Invention description (18) Silicon not less than 12.0% by weight and 0.1% by weight And not more than 8.0% by weight of copper, 0.05% or more and not more than 0.5% by weight of iron, and further containing at least one substance selected from the following elements: 0.5% or more and not more than 5.5% by weight of zinc, 0.002% by weight % Or more and not more than 0.3% by weight of 絪, and 0.02% or more and not more than 0.3% by weight of tin, the remaining components are aluminum and some inevitable impurities. In other words, the alloy composition of these core materials and brazing materials is the same as the composition of the core materials and brazing materials of the brazing sheet used in pipes and headers, and the role of the added elements and The reason for the restriction is the same. Next, the brazing sheet β of the present invention for a high-strength aluminum alloy heat sink will be described. First, the development thinking will be explained below. When the aluminum alloy heat exchanger is manufactured by the above brazing technique, it is usually heated at a temperature close to 60 ° C. Since 60 ° C is a relatively high temperature for the fin material, the following is derived Three problems: namely, ① when heating, the heat sink bends, ② the intermetallic compound in the alloy reorganizes the solution, which reduces the thermal conductivity of the heat dissipation M, and ③ the low melting point and high strength alloy cannot be used.

本發明者浮過不斷的努力研究以解決這些問題,並巨 認為它將對於降低硬焊之加熱溫度將很有效。針對溫度 應為多少,或者是溫度應降至多少度才能解決這典問題 ,做了許多研究之後,結果發現:如果溫度不高於5 8 5 °C -2 0 - 本紙張尺度適用+國國家標準(CNS)甲4規格(210x297公釐) .....................................................................................f …….Ι.ΤΓ.....................線 (請先閲讀背面之注意事項再填窝本頁) 經濟部中央標準局貝工消費合作社印製 A6 B6 五、發明説明(19 ) ,則在硬焊時,散熱Η很難發生彎曲的現象,導熱度的 降低也變得很輕撤,並且藉由提高矽的添加量,可改善 合金的強度〇 這三點問題將做更詳細的解釋。 ① 大多數的情況下,散熱片彎曲現象的産生是因為散熱 片在高溫下所引起的高溫潛變現象,我們還發現,在 5 90 °c的附近形成一個界線,在溫度高於散熱Η開始變 得脆弱之溫度時,該種潛變現象會突然發生。為了谙個 理由,如果溫度不高於585 °C,刖由此而引起的胄曲現 象將不會發生。此外,有一種彎曲現象是由於硬焊材料 擴散至散熱片中而引起,但是我們發現,在5 9 5 °C附近 形成一値界線,在高於595 °C的溫度下,會突然發生硬 焊材料的擴散現象。為此緣故,如果溫度未高於585 °C ,則硬焊材料的擴散現象將變少,且散熱Η很難發生彎 曲的現象。 ② 由於沈澱在鋁合金中之金腸間化合物會在硬焊的加熱 時,重組固溶體,而造成進行硬焊之散熱片的導熱度降 低。並且,加熱溫度愈高,形成固溶體的限制愈高,以 及擴散速度愈快,因此而可使得固溶_的重組能輕易的 進行。為了這俩理由.我們發琨:將硬焊溫度降低可提 高導熱度,並Η ,如果溫度不高於5 8 5 °C ,則重組固溶 體的進行速度很低,並目在導熱度的降低方而也很少。 ③ 關於強度方而,為了製成高強度鋁合金而加入之元素 -2 1 - 本紙張尺度適用中國國家橾準(CNS)甲4規格(210x297公釐) 裝......................,ΤΓ..................…線 {請先閲讀背面之注意事項再填窝本頁) 經濟部t央標準局員工消#合作社印製 A6 _ B6_ 五、發明説明(20 ) 包括銅、鎂、矽等《但是,當鋁合金用來做為一種冷媒 路徑形成成份時,就須將耐蝕性和硬焊性列入考慮,並 且,當鋁合金用來做為散熱片時,刖須將犧牲效果、導 、 熱性和硬焊性列入考廉。因此,能夠改善合金強度而提 高添加量之元素須受到限制,且矽的添加確實是受到影 蜜的。在600°C的溫度下進行硬焊時,能添加之矽的用 量或是銅的用量,較好是能低至1重量%,但是在585 °C 或更低的溫度下,其用量可提高至2. 5重量%。 現在已知有一種可使得硬焊能在低於一般之硬焊溫度 下進行的方法,以及一種能在50(TC左右進行硬焊的方 法,它被稱為低溫硬焊(例如曰本未審專利公告案,第 平1-107961號)。這種方法有一個問題是:硬焊材料在 硬焊之後容易被腐蝕,因為鋁-鋅合金或是鋅含量不低 於20%的鋅合金,常被用來做為硬焊材料,因此它們實際 上並不會用於熱交換器的製造。此外,如果在鋁-鋅合 金中,鋅的添加鼍超過8%,則滾軋性質將礬得非常差 ,使得無法以靥賴的方法來製造硬焊Η ,因此至今還没 有可用來在穩定狀態下,τ業化生産低溫硬焊用之硬焊 Η的方法。因此,硬焊材料必須以片狀的硬焊材料來使 用,限制了可生産成份的型態。然而,本發明者已發現: 即使是在不高於5 8 5 °C (這俩溫度遠高於上述之低溫硬焊 溫度)的硬焊溫度下,也可以改善熱交換器的恃件,並 R開發出適合的散熱Η合金,因而衍生出本發明。 -2 2 - 本紙張尺度適用_國Η家標準(CNS)甲4規格(210x297公釐} .....................................................................................裝......................訂.....................線 (請先閲讀背面之注意事項再填寫本頁) A6 B6 五、發明説明(21 ) 至目前為止,己知有低熔點的鋁合金硬焊材料(例如 日本未審專利公告案第平3 - 5 7588號)。這些合金主要是 為了硬焊鋳件而開發的,並且因為其含有大量的銅或者 是添加了 8%以上的鋅,當進行滾軋加工時,它們會引起 裂紋的問題,而無法製造硬焊片。如果無法以硬焊Η來 使用,則用來工業化製造熱交換器的實用性將變得很差 ,而此種發明的方法將無法被實現。 至今所使用過,且在J I S中所規定之硬焊材料的型式 及代碼皆列於表一中,並且其化學組成偽列於表二中。 在表一中,列出了固相曲線溫度、液相曲線溫度和硬焊 溫度以為參考。 裝......................訂.....................線 {請先閲讀背面之注意事项再瑱窝本頁) 經濟部中央標準局員工消費合作社印製 -2 3 - 本紙張尺度適用肀國國家搮準(CNS)甲4规格(210x297公釐)The inventors have made continuous efforts to solve these problems and believe that it will be very effective for reducing the heating temperature of brazing. According to what the temperature should be, or how much the temperature should be reduced to solve this problem, after many studies, it was found that if the temperature is not higher than 5 8 5 ° C -2 0-This paper size is applicable to + country Standard (CNS) A 4 specifications (210x297 mm) ............................................ ................................................... f ...... .Ι.ΤΓ ..................... line (please read the precautions on the back before filling the nest page) Printed by Beigong Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs A6 B6 5. Description of the invention (19), during brazing, the heat dissipation H is difficult to bend, the reduction in thermal conductivity also becomes very light, and by increasing the amount of silicon added, the alloy can be improved Intensity 〇 These three issues will be explained in more detail. ① In most cases, the bending phenomenon of the heat sink is caused by the high temperature creep phenomenon caused by the heat sink at high temperature. We also found that a boundary line is formed near 5 90 ° C, and starts at a temperature above the heat dissipation Η When the temperature becomes fragile, this kind of creeping phenomenon will happen suddenly. For a reason, if the temperature is not higher than 585 ° C, the resulting phenomenon of cranking will not occur. In addition, there is a bending phenomenon caused by the diffusion of brazing material into the heat sink, but we found that a boundary line is formed near 5 9 5 ° C, and brazing will occur suddenly at a temperature above 595 ° C Material diffusion phenomenon. For this reason, if the temperature is not higher than 585 ° C, the diffusion phenomenon of the brazing material will be reduced, and the heat dissipation H will hardly bend. ② As the intergold compound precipitated in the aluminum alloy will recombine the solid solution during the brazing process, the thermal conductivity of the brazed heat sink will decrease. In addition, the higher the heating temperature, the higher the limit of forming a solid solution and the faster the diffusion speed, so that the reorganization of the solid solution can be easily performed. For these two reasons. We are keen: lowering the brazing temperature can increase the thermal conductivity, and if the temperature is not higher than 585 ° C, the speed of recombination of the solid solution is very low, and the focus is on the thermal conductivity There are very few reductions. ③ Regarding the strength, the elements added in order to make high-strength aluminum alloy-2 1-This paper scale is suitable for the Chinese National Standard (CNS) A 4 specifications (210x297 mm) ... ............., ΓΓ .................. line (please read the precautions on the back before filling this page) Economy A6 _ B6_ printed by the Ministry of Central Standards Bureau employee Xiao # Cooperative. V. Description of invention (20) Including copper, magnesium, silicon, etc. However, when aluminum alloy is used as a refrigerant path forming component, the corrosion resistance must be And brazeability is taken into consideration, and when aluminum alloy is used as a heat sink, the sacrifice effect, conductivity, heat and brazeability must be considered. Therefore, the elements that can improve the strength of the alloy and increase the amount of addition must be limited, and the addition of silicon is indeed affected by the honey. When brazing at a temperature of 600 ° C, the amount of silicon or copper that can be added is preferably as low as 1% by weight, but at 585 ° C or lower, the amount can be increased To 2.5 wt%. There is now known a method that enables brazing to be performed at a temperature lower than the general brazing temperature, and a method capable of brazing at around 50 ° C, which is called low temperature brazing (for example, Japanese unexamined Patent Bulletin, No. 1-107961). One problem with this method is that the brazing material is easily corroded after brazing, because aluminum-zinc alloys or zinc alloys with a zinc content of not less than 20% often It is used as a brazing material, so they are not actually used in the manufacture of heat exchangers. In addition, if the addition of zinc in aluminum-zinc alloy exceeds 8%, the rolling properties will be very alum Poor, making it difficult to manufacture brazing H by the method of lamination, so far there is no method that can be used to produce brazing H for low temperature brazing under stable conditions. Therefore, the brazing material must be in the form of a sheet The use of hard brazing materials limits the types of ingredients that can be produced. However, the inventors have found that: Even at temperatures not higher than 585 ° C (these two temperatures are much higher than the low temperature brazing temperature mentioned above) At the brazing temperature, the parts of the heat exchanger can also be improved, And R developed a suitable heat-dissipating H alloy, thus deriving the present invention. -2 2-This paper size is applicable _National H Family Standard (CNS) A 4 specifications (210x297 mm) .......... .................................................. ....................................................... Order. .................... Line (please read the precautions on the back before filling in this page) A6 B6 5. Description of the invention (21) Low-melting aluminum alloy brazing materials (such as Japanese Unexamined Patent Publication No. Hei 3-5 7588). These alloys were mainly developed for brazing brazing pieces, and because they contain a large amount of copper or are added 8 More than% of zinc, when rolling, they will cause cracking problems, making it impossible to manufacture brazed pieces. If they cannot be used with brazing H, the practicality of industrially used heat exchangers will become very high Poor, and the method of this invention will not be realized. The types and codes of the brazing materials that have been used so far and are specified in JIS are listed in Table 1, and their chemical compositions are pseudo-listed in Table 2. In table one In the list, the solid phase curve temperature, liquid phase curve temperature and brazing temperature are listed as a reference. Install ..................... Order ... ................ Line (Please read the precautions on the back before reading this page) Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs-2 3-This paper size is applicable China National Standard (CNS) Grade 4 (210x297 mm)

6 6 A B 五、發明説明(22 ) 表1 硬焊材料和表皮材料的型式及代碼Z 3 26 3 >6 6 A B V. Description of the invention (22) Table 1 Types and codes of brazing materials and skin materials Z 3 26 3 >

型 式 參考値 合金的 編號 形狀 代號… 代碼‘υ 间相曲 線溫度 rc) 液相曲 線溫度 cc) 硬焊溫度 Cc) 平板,條狀 ί)17 61S 60^-620 表皮材料 1 線狀 I3A4045W 川5 样狀 2 ΒΛ4ΙΜ5Β 590 59 卜 605 平板,條狀 ΒΛ4045Ρ 表皮材料 一 400Γ" // 3 一 559 591 〜605 4 005 ⑴ // 4 — // 582 585〜605 4⑴ // 5 一 // 579 580〜600 4104 m " 6 一 // 591 590〜605 4N43 // 7 — 576 609 600〜620 4N45 // 8 一 // 588 590〜605 4M5 桿狀 一 ΒΛ4Η5Β 520 585 570〜605 線狀 B A4047W 4047 捍狀 一 Β Α4047Β 577 580 580〜605 表皮村料 B A40UP ............................................................................ 裝.......................可.:::……….…線 {請先閲讀背面之注意事項再填寫本頁) 注意事項:⑴被用來做爲眞空硬焊之硬焊片的表皮材料。 經濟部中央標準局员工消費合作社印製 (2) 做爲表皮材料之硬焊材料的代號。 (3) 只用來做爲一種硬焊材料的代碼。 本紙張尺度適用中a國家標準(CNS)甲4规格(210X297公釐) 3 2For the type reference, refer to the alloy's number and shape code ... Code 'υ Interphase curve temperature rc) Liquidus curve temperature cc) Brazing temperature Cc) Flat plate, strip shape) 17 61S 60 ^ -620 Skin material 1 Linear I3A4045W Sichuan 5 samples Shape 2 ΒΛ4ΙΜ5Β 590 59 Bu 605 flat plate, strip-shaped Λ 4045P Skin material 400 Γ " // 3 559 591 ~ 605 4 005 ⑴ // 4 — // 582 585 ~ 605 4 ⑴ // 5 1 // 579 580 ~ 600 4104 m " 6 1 // 591 590 ~ 605 4N43 // 7 — 576 609 600 ~ 620 4N45 // 8 1 // 588 590 ~ 605 4M5 rod 1BΛ4Η5Β 520 585 570 ~ 605 linear B A4047W 4047 defend 1 Β Α4047Β 577 580 580 ~ 605 epidermal village material B A40UP ............................................ ................................ 装 装 .................. ............ may.:::...............line {please read the notes on the back before filling in this page) Notes: ⑴ is used as a hard soldering hole The skin material of the welding pad. Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (2) The code name of the brazing material used as the skin material. (3) Only used as a code for brazing materials. The size of this paper is applicable to China National Standard (CNS) Grade 4 (210X297mm) 3 2

6 6 A B 經濟部中央標準局員工消費合作社印製 發 雜浬趣豳雜W戡画3择-,呢萊雎_时3,純鸯忒筇。 、 五 套4047 一4145 1 ! 4N45 1 -1 4N43 1 1 -1 4104 4N04 4005 4004 4045 4343 合金 的编 號 11.0〜13.0 丨 1 1 CO Ού 1 Η-» CD -α CD Ο t—* H-* CD Oi CO i 0〇 PO CD 〇 l f—k o CJ\ 11.0〜13.0 9.5〜11·0 CO CD l 1—* 〇 CJ\ CO 0 1 * H-* o 6.8〜8.2 1 t_ CO 姻 a 5 k^P -<3 03 l 0.30 i 或更少1 _1 0.25 或更少 0.25 或更少 - 0.15 或更少 0.05 或更少1 _1 - - 0.05 或更少 0.10 或更少 3C 0.10 或更少1 0.15 ί 或更少i 0.05 1 或更少1 _1 1 = CO H-O ◦ l —〇 O CO o ? tS5 H- CD O ? 1 1 0.15 或更少 _1 1 1 1 1 1 1 1 1 0.20 或更少 = ts3 C=J cn cj\ l = = 0.20 或更少 0.20 或更少 _1 1 1 1 1 1 1 1 1 0.20 或更少 1 1 1 1 1 c=? o O CD 1 1 1 1 1 CD = 0.05 或更少 値別的量 丨奸物胃5I 0.15 或更少 雜1 ί衡 > H-* 谢2淘_过荖-13 Z 3263)3-儎路洚 (請先閱讀背面之注意事項再填寫本頁) .裝 -訂 本紙張尺度逋用中國Η家標準(CNS)甲4規格(210x297公釐) A6 B6 經濟部中央標準局員工消費合作社印製 五η發明説明(24) 在這裡所列出之硬焊溫度的下限是硬焊材料開始流動 的溫度,其為可用來暫時性硬焊小尺寸物件(如T型接 頭)的溫度。然而,熱交換器為大型的物體,當將它們 予以工業化硬焊時,各處的溫度將相差約5到1 0 °C。為 此緣故,在硬焊熱交換器時所需維持的溫度,要比這個 下限溫度稍高至少5到1 0 °C。 換句話説,首先可看出,4047合金和4N04合金看起來 似乎為可用於如本發明之硬焊材料的相同溫度範圍内之 硬焊材料合金,但是事奮上它們是不同的,並Μ尚未能 1:業化的使用本發明之硬焊材料合金進行硬焊的溫度下 完成硬焊。 雖然4145合金為一種可在本發明之硬焊材料合金進行 硬焊的溫度範圍内進行硬焊的硬焊材料,但它未曾被用 來做為熱交換器中所使用之硬焊Η的硬焊材料。詳細的 理由將在本發明之硬焊材料之組成限制的敘述中加以說 明,但是因為4145合金與本發明組成的不同點在於,其 與本發明之硬焊材料合金相比,具有較高的鐵含量上限 ,目未添加鋅、洇和錫,因此在外部耐蝕性方而不佳。 為此緣故,我們已經知道:使熱交換器的硬焊溫度不高 於本發明中所説的5 8 5 °C,#無什麽奸處。 此外,美國專利第3 , 9 ίΜ,6 9 5號傜關於一種硬焊Η, 但是軍點是放在核心材料合金的開發,該核心材料可以 鍍h任何一禪硬焊材料。這俩事菁可由申請書的例】到 -2 6 - 裝......................tr.....................^ (請先閲讀背面之注意事項再填窝本頁) 本紙張尺度適用中國國家標準(CNS)T4規格(210X297公釐) 295604 經濟部中央標準局員工消費合作社印製 五、發明説明(25 ) 例4中,完全沒有對於硬焊材料做任何敘述而可看出, 同時也可由其對於合金元素的添加理由沒有做任何說明 而看出。在這値發明中,對於硬焊材料的敘述只佔了 12 行,亦卽由第2頁第40行到第2頁第52行,並旦合金( 4 3 4 3,4 1 4 5,4 0 4 7,4 0 4 5和X 4 0 0 4 )之間的差異傺以實例來 加以描述,目本發明的硬焊材料如上所逑。除此之外, 在這個發明中所述的硬焊材料和本發明的硬焊材料有以 下幾點不同之處。 ① 有一點證實了鎂的添加方式與本發明不同。如果加人 m ,則助熔劑和iM會在硬焊時進行反應,而使得硬焊無 法進行。 ② 鋅的組成範圍較寬。當合金的鋅含量超過6%時,在 本發明的矽、銅和鐵之含量的情況下,其滾軋加工性不 良,而無法轉變成硬焊片。 ③ 鐵的含量沒有調整。因此,在滾軋加工性和外部耐蝕 性方面有問題D ④ R有敘逑硬焊材料的熔點,而沒有對硬焊溫度的敘述。 此時.存第一種用於鋁合金散熱片之本發明硬焊片之 核心材料為一種鋁合金,其包含0 . 0 3軍鼉%以h且不超 過2 · 5重最%的矽、0 . 0 5重最%以h R不超過2 . 0重量% 的鐵.0 . 0 5重最%以h巨不超過2 . 0重鼉%的銅、0 . 6重 屋%以1:且不超過2 . 0重景%的錳,以及更進一步含有 辛少一種選自以下元素之物質:0 . 0 5章鼉%以卜.且不超 -2 7 - ........................................................ 裝..................訂.....................線 {請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用t國國家標準(CNS)甲4规格(210x297公釐) A6 B6 經濟部中央標準局員工消費合作社印製 五、發明説明() 過5.0重量%的鋅、0.0ϋ2重量%以上且不超過0.3重量% 的綑、和0.002重量%以上且不超過0.3重量%的錫,或 者是更進一步含有至少一種選自以下元素之物質:0.03 重量%以上且不超過0.5重量%的鎂、0.05重量%以上 且不超過2.0重量%的鎳、0.03重量%以上且不超過0.3 重量%的絡、0.03重量%以上且不超過0.3重量%的結和 0.03重量%以上且不超過0.3重量%的鈦,其餘的成份 則為鋁和一些無可避免的雜質。 上述之各値添加成份所扮演角色和用量限制的理由, 將在下文中做一說明。 矽可用來改善強度。但是,如果用量不超過0.03重量% ,則無法獲得改善強度的效果。在傳統的硬焊溫度下,矽 的最大添加量為1重量%左右,但是,在本發明中,可因 為硬焊溫度的降低而提高矽的添加量。換句話說,如果 添加量不超過1.2重量%時,矽所具有改善強度的效果 與傳統的散熱Η —樣高,但是如果用量超過1.2重量% ,則可獲得比傳統散熱片更大的強度改善效果。此外, 當矽的添加量提高時,導熱度會降低,因此,在製造熱 交換器時,須同時考慮強度和導熱度之間的重要性,來 選擇其組成。此外,如果矽的添加量超過2. 5重量%時 ,即使是在本發明的硬焊溫度下,核心材料也會開始熔 解。 鐵形成金靨間化合物,且可改善強度,然而,若添加 -2 8 - ......................訂....................線 {請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家搮準(CNS)甲4规格(210X297公釐)6 6 A B Printed by the Employees ’Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. Miscellaneous, interesting, and miscellaneous W. Three choices of paintings, 篎 盎 _ 时 3, pure 魯 俒 筇. 5 sets of 4047 1 4145 1! 4N45 1 -1 4N43 1 1 -1 4104 4N04 4005 4004 4045 4343 alloy number 11.0 ~ 13.0 丨 1 1 CO Ού 1 Η- »CD -α CD Ο t— * H- * CD Oi CO i 0〇PO CD 〇lf—ko CJ \ 11.0〜13.0 9.5〜11 · 0 CO CD l 1— * 〇CJ \ CO 0 1 * H- * o 6.8 ~ 8.2 1 t_CO 婚 a 5 k ^ P-< 3 03 l 0.30 i or less 1 _1 0.25 or less 0.25 or less-0.15 or less 0.05 or less 1 _1--0.05 or less 0.10 or less 3C 0.10 or less 1 0.15 ί or less i 0.05 1 or less 1 _1 1 = CO HO ◦ l —〇O CO o? tS5 H- CD O? 1 1 0.15 or less _1 1 1 1 1 1 1 1 1 0.20 or less = ts3 C = J cn cj \ l = = 0.20 or less 0.20 or less_1 1 1 1 1 1 1 1 1 1 0.20 or less 1 1 1 1 1 c =? o O CD 1 1 1 1 1 CD = 0.05 or less, other amount 丨 Stomach stomach 5I 0.15 or less Miscellaneous 1 Heng > H- * Xie 2 Amoy _ Guolu-13 Z 3263) 3-Yan Luhuan (please read the note on the back first Please fill in this page for details.)-The size of the bound paper is in accordance with the Chinese Standard (CNS) A4 (210x297mm) A6 B6 The Ministry of Economy Central Standards Bureau Employee Consumer Cooperative printed the description of the five η invention (24) The lower limit of the brazing temperature listed here is the temperature at which the brazing material begins to flow, which can be used for temporary The temperature of brazing small-sized objects (such as T-joints). However, heat exchangers are large objects, and when they are industrially brazed, the temperature will vary by about 5 to 10 ° C everywhere. For this reason, the temperature to be maintained when brazing the heat exchanger is slightly higher than this lower limit by at least 5 to 10 ° C. In other words, first of all, it can be seen that the 4047 alloy and the 4N04 alloy seem to be brazing material alloys that can be used in the same temperature range as the brazing material of the present invention, but in fact they are different. Fail 1: Brazing is completed at a temperature where the brazing material alloy of the present invention is used for brazing. Although alloy 4145 is a brazing material that can be brazed in the temperature range where the brazing material alloy of the present invention is brazed, it has never been used as a brazing material for heat exchangers used in heat exchangers. material. The detailed reason will be described in the description of the composition limitation of the brazing material of the present invention, but the difference between the composition of the 4145 alloy and the present invention is that it has a higher iron than the brazing material alloy of the present invention The upper limit of the content is not added with zinc, blur and tin, so the external corrosion resistance is not good. For this reason, we already know that the brazing temperature of the heat exchanger is not higher than 5 8 5 ° C as mentioned in the present invention. In addition, U.S. Patent No. 3, 9 ί, 6 9 5 傜 relates to a brazing alloy, but the focus is on the development of core material alloys, the core material can be plated with any Zen brazing material. These two things can be selected from the application example] to -2 6-pretend ........................... tr ........... .......... ^ (Please read the precautions on the back before filling the nest page) This paper size is applicable to China National Standard (CNS) T4 specification (210X297 mm) 295604 Ministry of Economic Affairs Central Standards Bureau staff consumption Printed by the cooperative. V. Description of the invention (25) In Example 4, it can be seen that there is no description of the brazing material at all, and it can also be seen from the fact that the reason for the addition of alloy elements is not explained. In this invention, the description of brazing materials only occupies 12 lines, and also from page 40, line 40 to page 2, line 52, and alloys (4 3 4 3, 4 1 4 5, 4, The difference between 0 4 7, 4 0 4 5 and X 4 0 0 4) is described by an example, and the brazing material of the present invention is as described above. In addition to this, the brazing material described in this invention differs from the brazing material of the present invention in the following points. ① It is confirmed that the way of adding magnesium is different from the present invention. If you add m, the flux and iM will react during brazing, making brazing impossible. ② The composition range of zinc is wide. When the zinc content of the alloy exceeds 6%, in the case of the content of silicon, copper and iron of the present invention, the rolling workability is not good and it cannot be converted into a brazed sheet. ③ The iron content is not adjusted. Therefore, there are problems in rolling workability and external corrosion resistance. D ④ R has the melting point of the brazing material, but there is no description of the brazing temperature. At this time, the core material of the first brazed sheet of the present invention for aluminum alloy heat sink is an aluminum alloy, which contains 0.03% of the military and h and does not exceed 2.5% of the most silicon, 0.05% of the most heavy iron h R does not exceed 2.0% by weight of iron. 0.05% of the most heavy iron h does not exceed 2.0% of the heavy copper, 0.6% of the weight of the house 1: And no more than 2.0% of manganese, and further contains Xin Shao a substance selected from the following elements: 0.05% of Zhang Zu% to Bu. And not exceeding -2 7 -... ........................................... .................. order ............... line {Please read the notes on the back first (Fill in this page) This paper scale is applicable to National Standards (CNS) A4 specifications (210x297 mm) A6 B6 Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy V. Invention description () Zinc over 5.0% by weight, 0.0ϋ2 Bundles of not less than 0.3% by weight and not more than 0.3% by weight, and tin of 0.002% or more but not more than 0.3% by weight, or further containing at least one substance selected from the following elements: 0.03% by weight or more and not more than 0.5% by weight Magnesium, 0.05 wt% or more and not more than 2.0 wt% nickel, 0.03 wt% or more and not more than 0.3 wt% complex, 0.03 wt% or more and not more than 0.3 wt% junction and 0.03 wt% or more and not more than 0.3 wt% % Titanium, the remaining components are aluminum and some inevitable impurities. The reasons for the above-mentioned roles of the added ingredients and the limitation of the dosage will be explained below. Silicon can be used to improve strength. However, if the amount does not exceed 0.03% by weight, the effect of improving strength cannot be obtained. At the conventional brazing temperature, the maximum addition amount of silicon is about 1% by weight. However, in the present invention, the addition amount of silicon can be increased due to the reduction of the brazing temperature. In other words, if the added amount does not exceed 1.2% by weight, the effect of silicon on improving strength is as high as that of conventional heat dissipation H, but if the amount exceeds 1.2% by weight, a greater strength improvement than traditional heat sinks can be obtained effect. In addition, when the amount of silicon added increases, the thermal conductivity will decrease. Therefore, when manufacturing a heat exchanger, it is necessary to consider the importance between strength and thermal conductivity to select its composition. In addition, if the amount of silicon added exceeds 2.5% by weight, the core material will start to melt even at the brazing temperature of the present invention. Iron forms an intermetallic compound and can improve strength, however, if -2 8 is added -....................................... ............. Line {Please read the precautions on the back before filling out this page) This paper size is applicable to China National Standard (CNS) A 4 specifications (210X297mm)

經濟部中央楳準局貝工消费合作社印製 量未超過0.05重量%時,則效果並不足夠;而且若添加 量超過2.0重量%時,則散熱Η之再結晶粒會變撤小, 月硬焊材料之擴散變為顯著,致使該散熱片歷扁β 鏑可改善合金的強度。如果銅的含量不超過0.5重量% ,則無法捎得改善強度的效果,同時,如果網的用量超 過2.0重量%時,即使是在本發明的硬焊溫度下,核心 材料也會開始熔解。 錳在合金中形成微細的金鼷間化合物,並且不R是可 以改善強度,同時&可避免再结晶的頼粒在硬焊加熱時 變得微细β如果其用量未超過0.6重量%,刖無法獲得改 善強度的效果,同時,如果添加量超過2.0重量%時, 散熱Η的塑模性會降低,而使得其無法製成波浪狀的塑 模。 鋅、姻和錫是用來提供散熱Η犧牲性陽極效《Τ而添加 的元素β如果摻有銅的合金類似本發明之合金(如果這 些元素並未添加),刖散熱片的電位將變得比冷媒路徑 組成成份的電位要高,因而降低了耐蝕性。同時,如果 鋅的含量不超過0.05重量%,絪的用量不超過0.002重 量%,且錫的用量不超過0.002重量%時,該種效果將 不足,同時,如果鋅的添加量超過5.0重量%,朗的添 加量超過0.3重量%,且錫的用量超過0.3重量%時,導 熱度會降低。待別是在本發明中,銅的添加量較高的情 況,需要添加較多的鋅,但是因為鋅會降低合金的熔點 -2 9 - 本紙張尺度逋用中困國家標準(CNS)甲4規格(210x297公釐) .....................................................................................裝......................訂.....................線 (請先閲讀背面之注意事項再填寫本頁} A6 B6 經濟部中央標準局員工消費合作社印製 五、發明説明(28 ) ,它最多只能加至約2重量%。 轉、鎳、鉻、錯和钛為進一步改善強度而添加的元素ο 同時,如果鎂的含最不超過〇. 03重量%,鎳的用景不超 過0.05重量%,巨鍚的用量不超過0.03重量%時,將無 法獲得改善的效果。另一方面,鎂的添加量超過0.5重 量%時將會降低硬焊性,以及鎳的添加量超過2.0重量% ,且銘、結和钛的用量超過0.3重量%時,會降低塑模 性,而很難將散熱Η塑模成波浪狀。為了這値綠故,這 些元素的添加量設定在該範圍内。然而,對於鈦而言, 由於改善強度的作用,而使其添加的下限為0.3重*% ,但是有時為了使得_塊的紋理細緻,因此將下限設為 0 . 0 0】重量%。 至於無可避免的雜質方而,為了使得鑄塊的紋理細緻 ,所以可添加硼等元素,如果這些元素的個別含量不超 過0.03重鱟%時.它們可安全的包含在合金中。 此外,在第二種用於鋁合金散熱片之發明硬焊片之中 的核心材料為一種鋁合金,其包含0 . 0 3重量%以上巨不 超過2. 5重最%的矽、0.05重量%以上且不超過2.0重量% 的鐵、0 . 0 5重最%以卜.巨不超過2 . 0重量%的_,以及 更進一步含有至少一種選自以下元素之物質:0.05重最% 以卜目不超過5 . ϋ重翬%的鋅、0 . 0 0 2重最%以h Η不超 過0 . 3重最%的洇、和0 ·(] 0 2重量%以上日不超過0 . 3重 最%的錫,或者是更淮一步含有至少一種Ρ自以下元素 -3 0 - 裝......................訂....................線 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度逋用中國Η家標準(CNS)甲4規格(210x297公釐)When the printing volume of the Beigong Consumer Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs does not exceed 0.05% by weight, the effect is not sufficient; The diffusion of the solder material becomes significant, so that the flattened dysprosium of the heat sink can improve the strength of the alloy. If the content of copper does not exceed 0.5% by weight, the effect of improving strength cannot be achieved, and at the same time, if the amount of the net exceeds 2.0% by weight, the core material will start to melt even at the brazing temperature of the present invention. Manganese forms a fine intermetallic compound in the alloy, and not R can improve the strength, and at the same time & avoid recrystallized grains becoming fine when brazing heating. If its amount does not exceed 0.6% by weight, it cannot be At the same time, the effect of improving the strength is obtained. At the same time, if the addition amount exceeds 2.0% by weight, the moldability of the heat dissipation H will decrease, making it impossible to make a wavy mold. Zinc, indium, and tin are used to provide heat dissipation. The sacrificial anode effect. The added element β. If the alloy doped with copper is similar to the alloy of the present invention (if these elements are not added), the potential of the heat sink will become It has a higher potential than the components of the refrigerant path, thereby reducing corrosion resistance. At the same time, if the content of zinc does not exceed 0.05% by weight, the amount of 絪 does not exceed 0.002% by weight, and the amount of tin does not exceed 0.002% by weight, this effect will be insufficient, and if the amount of zinc exceeds 5.0% by weight, When the amount of Lang added exceeds 0.3% by weight, and the amount of tin exceeds 0.3% by weight, the thermal conductivity will decrease. It is to be noted that in the present invention, when the amount of copper added is high, more zinc needs to be added, but because zinc will reduce the melting point of the alloy-2 9-This paper standard is used in the national standard (CNS) A 4 Specification (210x297mm) .................................................. ....................................... pretend ... .............. Order ..................... line (please read the notes on the back before filling this page) A6 B6 Printed by the Consumers ’Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Invention Instructions (28), which can only be added up to about 2% by weight. Zinc, Nickel, Chromium, Chromium and Titanium are added elements to further improve strength. If the content of magnesium does not exceed 0.03% by weight, the use of nickel does not exceed 0.05% by weight, and the amount of giant thorium does not exceed 0.03% by weight, the improvement effect cannot be obtained. On the other hand, the amount of magnesium added When it exceeds 0.5% by weight, the brazing property will be reduced, and if the amount of nickel added exceeds 2.0% by weight, and the amount of Ming, knot, and titanium exceeds 0.3% by weight, the moldability will be reduced, and it will be difficult to mold the heat dissipation. Wavy. For this reason, the amount of these elements added is set within this range. However, for titanium, due to the effect of improving strength, the lower limit of its addition is 0.3 weight *%, but sometimes in order to make _ block The texture is fine, so the lower limit is set to 0.0 0% by weight. As for the inevitable impurities, in order to make the texture of the ingots fine, elements such as boron can be added, if the individual content of these elements does not exceed 0.03 weight Limulus%. They can be safely contained in the alloy. In addition, the core material in the second brazing sheet for aluminum alloy heat sink invention is an aluminum alloy, which contains 0.03% by weight or more Not more than 2.5% by weight of most silicon, 0.05% by weight or more and not more than 2.0% by weight of iron, 0.05% by weight of most yibu. Giant not more than 2.0% by weight of _, and further contains at least A substance selected from the following elements: 0.05 weight most% with a weight of not more than 5. ϋ heavy weight of zinc, 0.02 weight 2% of the most to h Η not more than 0.3 weight most of the 洇, and 0 · (] 0 2% by weight or more, no more than 0.3% tin, or more Huai One step contains at least one Ρ from the following elements-3 0-Pack ...................... Order ... ... line (please read the notes on the back before filling in this page) This paper uses the Chinese Standard (CNS) A4 specification (210x297 mm)

五、發明説明(29) 經濟部中央標準局貝工消费合作社印製 之物質:0 . 0 3重量%以上且不超過0 . 5重量%的鎂、0 . 0 3 重量%以上且不超過0.6重量%的錳、0.G5重量%以上 且不超過2.0重量%的鎳、0.03重量%以上且不超過0.3 重量%的鉻、0.03重量%以上且不超過0.3重量%的結 和0.0 3重量%以上且不超過0.3重量%的鈦,其餘的成 份則為鋁和一些無可避免的雜質β 關於上述之値別成份所扮演的角色和用景限制的理由 方面,做為基本元素的矽、鐵、鋦、鋅、洇和錫,和做 為選擇性元素的鎂、鎳、鉻、鈷和鈦,與在本發明第一 種用於散熱片之硬焊Η的核心材料中之情形的理由相同 。然而,在這種核心材料中,0 . 0 3重量%以上且不超過 0.6重量%的錳,可選擇性的成為添加元素《與其它選 擇性成份類似之處為:錳之添加是為了進一步改善該種 核心材料的強度,但是,如果用量不超過0.03重量%時 ,無法獲得改善強度的效果,同時,如果用量超過0.6 重量%時,則導電度會開始下降。此外,與第一種用於 散熱1=1之硬焊Η情形類似的是:如果傾別元素的含量不 超過0.03重量%,刖無可避免的雜質也可安全的包含在 核心材料中。 在本發明之第一揮和第二種用於散熱Η之硬焊Η中的核 心材料合金如前所述〇在另一方面,在其兩側所鍍之硬 焊材料為一種鋁合金,其包含7 ·(]重量%以上R不超過 12.0重量%的矽、0.5重量%以上目不超過8.0重量%的 -3 1 - 本紙張尺度遑用中國國家標準(CNS)f 4規格(210x297公釐) .....................................................................................#.......................訂.....................^ {請先Μ讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 ^ ό1 Β β Β6 五、發明説明(30 ) 銅,以及更進一步的含有至少一種選自以下元素之物質: 0.5重量%以上巨不超過5.5重量%的鋅,0.002重量% 以上且不超過〇 . 3重量%的絪和0 . 0 0 2重量%以上且不超 過fl. 3重量%的錫,其餘的成份則為鋁和一些無可避免 的雜質。這種硬焊材料在核心材料上的電鍍比率一般約 為3到20%。這種硬焊材料之組成與本發明中之該種其 它的硬焊片之硬焊材料合金的紐成相同,因此添加元素 所扮演的角色和用量限制的理由也相同β 接著將針對本發明之鋁合金熱交換器的製造方法做一説 明。 在本發明中,偽使用該種硬焊材料和硬焊Η,在5 7 0 到585 °C的溫度範圍内進行硬焊。這是因為:如果硬焊 溫度低於570 °C,有一部分的組成物不會熔解入本發明 的硬焊材料中,而無法進行硬焊。同樣的,如果溫度高 於585 °C,則散熱Η的導熱度會降低(如前文中所述U 並且在高溫時的彎曲性質也會降低,而導致更進一步的 熔解β此外,以這種方式來降低硬焊溫度,可延長硬焊 爐的壽命,並目.改善冷媒路徑形成成份的附蝕性。 雖然本發明的硬焊條件限制了溫度的範圍,但是其它 條件可與傳統的硬焊條件維持一樣。換句話說,熔接硬 焊法、使用非腐蝕件肋熔劑(氟化物型,絶型)的H 〇 c 〇丨〇 c k 硬焊法等,可以直接使用,而不需特別的限制。在進行 硬焊之前,如有需要,可依傳統的方式來進行邰装、清 -3 2 - 本紙張尺度逋用中國國家標準(CNS)甲4规格(210x297公釐) .....................................................................................裝…— ……訂! _ !.,線 (請先閲讀背面之注意事項再填窝本頁) 經濟部中央標準局員工消費合作社印製 A6 B6 五、發明説明(31 ) 洗、流動塗佈。在這個情形下,即使是使用一種肋熔劑 (例如绝型的肋熔劑),仍可在本發明的溫度範圍内進行 硬焊 此外,在本發明中,在加熱之後的處理程序,並未特 別的限制。亦即,進行至此,如加以處理、除去肋熔劑 和塗漆等程序皆可進行》 為製造本發明之散熱片,以半連鑛的鑲造方式來生産 鑄塊。然而,它可經由熱滾軋(多層滾軋)和冷軋-退火 的程序來製造,或者是也可經由連缠鑄造滾軋和冷軋-退火的程序來製造。 以下,將以這些啻例對於本發明做更具體的說明。 例 1 以本發明之具三層結構ί包括硬焊材料,核心材料和 犧牲性材料)的鋁合金硬焊片,用來做為散熱器的扁平 管和管集箱,以下面所述的方式來進行_試: 以表3到表9中所示之合金組成物,將核心材料、硬 焊材料和犧牲性材料接合在一起,並藉箸一般的方法來 製造具有三層結構巨厚度為〇 . 2 5毫米的硬焊片。硬焊材 料的電鍍卜b率為〗〇 % , Η犧牲性材料的電鍍比率為15% 。此外,在犧牲性材料中,鐵和矽為雜質元素,且其倨( 別的含最範圍介於0 . 0丨到0 . 2重最%之間„ 這®硬焊Η在表1 0到表1 2所示的溫度條件下,置於氮 氣中加熱„將硬焊Η的硬焊材料部分朝外,目撮牲件材 -3 3 - 本紙張尺度逋用中國Η家標準(CNS)甲4規格(210x297公釐) 裝......................訂.....................線 f請先閲讀背面之注意事項再填窝本頁) A6 B6 五、發明説明(32 ) 料部分朝内,而在硬焊Η加熱之後,進行張力測試、外 部耐蝕性測試及内部耐蝕性測試。 在外部耐蝕性潮試中,只有硬焊材料表面的中間部分 暴露,並且其它面皆予以密封,然後進行360小時的CASS (J I S Η 8 6 8 1 )測試,以檢査孔蝕産生的位置。 在内部耐蝕性的_試中,將以硬焊材料部分加以掩蔽 之硬焊片,浸入加有10 ΡΡβ之Cu2+鋦離子的自來水中 ,達5値月,並且谁行8 0 °C X 8小時及室溫X 1 6小時的 週期腐蝕測試。然後,在光學顯撤鏡下,以焦深度法來 決定在橇牲性材料之表而所生成之孔蝕的深度。 這些結果將列於表1 0到表1 2中。 (請先閲讀背面之注意事項再填窝本頁) .裝 訂 .線 經濟部中央標準局員工消費合作社印製 -3 4 - 本紙張尺度適用中國國家標準(CNS)f 4規格(210X297公釐) A6B6 五、發明説明(约 蛵濟部中央樣準局w工消费合作社印製 鴆 m t-o CO csa *Ό - 二 Ξ CD 00 --3 σ> cn Οί ro 1 编 硬焊片 % ii. 0 ii. δ % ·—· c^> ο ►—*· «n % «=» 11. 5 ! ί 55 % 爻 % ο in 硬焊材料合金的組成,重量% % ° % 二 : 二 % % : ·: % = % = 勺 a> c^s Ca> CT» C*» csa ϊ: €=> JO <=» 〇 仁 二 r^> 交 ro Ol - 二 «νβ c=> tSJ p t 1 1 1 1 1 a 〇 CO <=> tn 1 1 1 I 1 1 m D % % ί ί 5: w-mm > % 55 % ϊ % ί % % 55 l·-— CaJ (j) 核心材料合金的組成,重最% % % % % ί 金 % !: 二 二 ·: <zr> o c 爻 爻 令 令 % 令 % 令 % % % % % 二 z s 1 1 1 1 1 1 1 1 ί 1 e=> 1 s: OQ I 1 1 1 1 1 1 1 1 1 1 1 1 1 〇 <n 1 1 1 1 1 1 1 I i ι I 1 1 t 5=* Μ n 爻 欠 5: 55 爻 55 5i 令 令 爻 ι 0. 18 5s* H 1 1 1 1 1 1 ( ) I t t 1 1 1 1 1 〇〇 爻 % 爻 $ ί ί ί ί -n fD ί ί $ 平衡鼉 > ί : : : ί M P 揭抻件材料合余的纟Η成(审罱% ) 1 1 1 1 1 - 1 1 I 1 0. 01 1 1 1 1 ο. οι 1 1 f 1 1 1 1 1 1 i 1 1 1 I ί 1 1 1 1 1 1 1 1 1 1 1 1 1 1 cn Γ3 tO »—k 1 1 1 α 〇Q 1 1 1 1 1 t 1 1 1 Γ. 1 1 1 1 1 1 1 1 1 1 Γ3 $ % ί: 5: 5i i平衡詈 > (請先閲讀背面之注意事項再填寫本頁) .裝. 訂. 紙張尺度適用中國國家標準(CNS)甲4规格(210 X 297公釐) 82. 9. 6,000 五、發明説明(斗) 頫 s w β A6B6 - r>a Gk c*» .«> CAft 〇〇 c«a Ca* en «•η Ca* &>* CO o* cva Ck» *—» C*» G9 〇·» *·〇 CsA oo <sa —> rsa 〇« csa cn Cs» Ca» m 鷲 ί % % % % 55 ·—· ω : % % ί ί ί ί % % 5: 二 (H Γ'3 r^s «-Γ» rvs C^l CO ο c 交 % % 令 交 Ji ·*- Λ^- cxa &/I 1 - Μ p 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 CSt «s <=» a «-Γ» «=> «=d 〇> P 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I 1 1 i ω 口 ί 5ί ί ί % ί ί; 平衡· > 爻 •二 爻 爻 之 5; ϊί 匚 CO ΐ: % 爻 ί J5 % η c 爻 - % 之 之 爻 % 令 % 令 女 夸 55 々 r: Μη 1 1 Ο.ΊΟ 1 1 1 1 1 1 1 1 1 1 1 1 1 oq 1 ο 1 t l 1 1 1 1 1 i 1 ί 1 1 1 1 1 i 1 o »n t--s» <C3 1 - 1 1 1 1 1 1 1 1 1 1 I 1 1 1 1 1 1 1 1 1 IM •n t 0. 53 [- J=> 1 1 令 爻 1 爻 ϋ 爻 5ί ί % <=> oo H 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 ° 5: 丨0.3 :平衡ΐ i 0 Φ > 1 1 1 ί ί: ί t $ ,—, oo oo 1 1 1 : ESI p 1 1 t I 1 ! 1 1 1 <=> 1 1 1 <=» t=> 〇-» 1 I ο. oi j 一 | — 1 1 1 1 1 1 1 1 1 1 ! 1 1 P ί 1 5: 1 1 = 1 1 1 1 1 1 £=_> to : 1 CO P ·: = : 1 oq 1 - 1 1 1 t 1 1 1 ί 1 Ζ. 1 1 1 i - 1平衡景 P ί \ $ ί > s^ 谢 4 |裝· 訂· 36 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) H2. 6,000 5604 五、發明説明(^ ) A6 B6 濟部中-Λ樣準局Ri消费含作社邱轚 .宠 Μ 涅顆 θ'» er> cn «XI cr> C7> c*> en csa - cr* - *JF\ 00 &n e>n cr> &^1 «Π CO «•η «Α» «η CO - &Π tz 二 s: 硬焊片 1编號 *-· CS ·-· C3 GS % % % I 11.0 <Λ 硬焊材料合金的組成,重量% ° Ζ c=> ίί % 5: % ° 〇> Γ° e^rt = 二 爻 爻 4.Ό CZt 〇 C l, c; 5: :¾ 二 55 % 爻 爻 口 z 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Ρ :1 1 1 1 1 1 1 1 f 1 1 1 1 1 1 1 1 1 1 1 1 1 cn P 爻 5i ii ΪΪ 5; 5; 5: 女 % 平衡僵 _1 > % 令 : 爻 二 二 % 令 二 ω 核心材料合金的紐成,重量% 爻 ii % % % 5S % % % 1 ·: ο c: % % 令 爻 令 5: 爻 爻 C^t 〇> C*·» 〇 >=* CS Ca> C9 ,卜 <^Λ ,. 1 Μ η 1 1 1 1 1 1 1 1 1 1 1 1 1 1 C3 C^b <=> I 1 1 1 ο C^9 C3 C3 <jr\ (Ki 1 1 1 1 1 1 1 1 I 1 1 1 1 S 1 1 1 1 1 .β 1 1 0 •η 1 i 1 1 1 1 1 1 \ 1 1 1 *— «-Π 1 1 1 1 1 1 0. 10 ?=^ η - 5: % 55 爻 = ( 1 1 1 CX1 c=> α ►-· rm cn 1 Η 1 1 1 1 1 1 1 1 1 1 1 I 1 1 1 1 1 1 1 <=> 1 1 5ί G> C3 〇〇 G3 0·» α «〇 C=3 0 C^~3 1 ο. Γ平衡i i ί) Ο) 5: > C=3 «=> - Ρ is牲性材料合余的钳成(車單°/。) 1 1 1 1 1 1 1 1 0. 01 1 1 F3 1 1 1 1 1 1 1 I 1 1 1 1 Ρ 1 1 I 1 1 1 1 1 1 1 1 1 I 1 1 1 1 1 夂 1 1 1 LO Ρ oq 1 1 之 2.5 j -平衡最' 1 \ 1 : 1 1 1 1 1 1 1 1 1 1 1 1 1 Μ η ΐ; > -37 - (讀先閲讀背面之注意事項再塡寫本頁) —裝. 訂. 本紙張尺度適用中國國家樣準(CNS)甲4规格(210 X 297 :釐) 82. 9. 6,000 A6B6 五、發明説明(払) 經濟部中央標準局R工消费合作社印製 a Si 〇〇 〇〇 〇〇> 〇〇 〇% 〇〇 «_η oe oo 〇» oo rs» 〇〇 oo «〇 oo —*« —1 H —4 —4 en «〇 〇> e〇 σ> m 薄 硬焊片i 11.0 CO ο »— ►—· ca cs ►— ♦—· C3 «rt ►—» ►—» ►—* cn (Λ 硬焊材料合金的組成,重量% 5: CZJ r-o o <u» cs CO C3 ·—· C3 U1 c» c^s z 勺 Λ ΪΌ «-Π CO GS> cxi <^Λ o c_n o —1 C>3 5i % 5: €NS ο c - 1 1_ r«A r-«s .^. CV9 ►—· cn 5: 5ί % 爻 之 ii •b- Μ ρ 1 1 I I I I i I I 1 1 1 1 1 1 1 1 1 1 1 1 1 Ρ 〇 r〇 «S on I i I I I I . I 1 1 1 1 1 1 1 1 1 1 1 1 1 (Λ Ρ 爻 令 % 爻 爻 平衡量 > $ 55 55 : 二 ·: % 55 二 二 ⑺ 爻 >: 5: z L ez> 二 5S % = ο C % 令 ΐ 女 $ % 二 Z 二 二 二 ° Μ η 核心_料合金的組成,重量% 1 1 I I I I I I I 1 1 1 C=3 1 1 <=> 1 ! Γ 1 0Q 1 1 I I I I I I I 1 f 1 0. 10 f 1 1 1 1 1 1 1 1 ο -1 1 1 I I I I I I I 1 1 = 1 1 1 1 1 1 1 1 1 1 Ν -~t $ i: I I 爻 夂 5: 二 1 1 1 1 ί=· 1 : 1 Η 1 1 I I I I I 1 1 1 1 1 1 i 1 I 1 1 1 ί; < i: I 1 % $ 1 1 二. _书 s Λ Οι < < > ' ' < 、 十 cu to < < < < Ν ;J 犧杵性材料合余的組成(重量%) 1 I I I I { 1 1 1 1 1 1 1 1 1 1 1 τ—· ρ ν < ' 、 < *--rf 1 - < < < < ►w <» 2: oq 1 I i I I I I i 1 1 1 1 1 1 1 1 1 1 t 1 Ρ 平 iSif > -3 θ- 谢 6 (請先閲讀背面之注意事項再塡寫本頁) 裝. 訂. k紙張尺度適用中國國家標準(CNS)甲4规格(21〇 X 297公梦) 82. 9. 6,000 A6 B6 五、發明説明(^ ) 經濟部中失標準局R工消费合作社印製 m m s ^ 5 i s 5 ·-« <=» CO »-» es csa 5 CO «ο U9 oo CO «ο cr> «ο crt CO «〇 Ca» «〇 CSS «ο «ο Ο0 <〇 硬焊片 :職 ΪΪ !i % % % tn 硬焊材料合金的組成,重量% % % ° 夸 % Ϊ5 it 5¾ 爻 ° α % fsd οι % % f-a Cfl 〇Λ» ο c ί 爻 爻 : c^a c^t 1 二 Ν 1 1 1 I 1 1 1 1 1 1 1 1 1 1 1 1 % % (=> <=» (=> C3 Ρ 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 -ί平衡¥ 0. 8 in Ρ ί % $ % 爻 % > % : ° 二 5: % % % CO 核心材料合金的組成,重量% 1: % % 爻 % 爻 :¾ 之 二 ο C 爻 令 令 夂 令 爻 令 令 % 之 5: % 55 5: 55 匚 Μη 1 1 <=> 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2: 0Q 1 1 1 t 1 1 1 1 1 1 1 ! 1 1 1 1 1 1 1 t 1 ο η •—» 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I Μ η <=> «一J <_»1 1 •ί 令 爻 交 爻 爻 令 爻 爻 Η 1 1 1 ° 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 F3 ϊί 5: 爻 $ 爻 5: F=> α> k 55 p1衡量 > <=> <=> c=> c_n β 〇〇 ! 1 1 = : {ν3 Ρ 犧杵忖材料合金的绍成(軍m % 1 1 t 1 1 1 ί: 1 1 1 1 1 ==* 1 s F=» 1 5= 1 1 5: = 1 F= 1 1 ! 1 1 1 - 1 - 2. 3 | ―平衡贵 Ρ 1 夂 1 1 1 I: 1 <^1 1 1 1 i 1 1 1 1 1 1 1 々 1 爻 1 1 1 1 CO Ρ 0Q 1 ·: 1 匚 1 1 1 1 i 1 1 1 = 1 1 '<^ Ρ ί > -39- (請先閲讀背面之注意事項再塡寫本頁) —裝 :玎_ 本紙張尺度適用中國國家標準(CNS)甲4規格UlO X 297公釐) 82. 9. 6,000 A6 B6 經濟部中夹標準局R工消费合作社印製 五、發明説明(轺) 二 c^» 5 S CO oo s <>n 5 〇·> r>a 5 5 5 Ξ S Ξ Ε Ξ »— m 鞣 硬焊片 £=> »—· c~n *—» o »—· <s 4=> % % ω 硬焊材料合金的組成,重量% ° ° c ί: <=3 ° $ % % Λ C-Λ CJt Γ"* r>3 «rt c*» % c; 爻 % ο C - 1 C^t k 爻 CO c-n 二 ί Ρ f 1 1 1 1 1 1 <=3 1 1 1 1 1 1 1 1 1 1 1 1 1 1 *—1 s 1 1 1 1 i 1 1 t 1 1 1 1 1 1 1 α> $ 令 爻 爻 ί 爻 柳量 > 二 ·: π % ί : ·= C=3 : : ω - 二 二 % «=3 οα C3 C3 〇〇 CO 〇> »—· C^9 »—· c->d Ι-— ΟΊ ο C 爻 二 ° : π 夂 % cs ^a~ w> &·> ,_, ο οο ♦—· *—· r- Μη 核心材料合金的組成,重量% 1 1 1 1 1 1 I 1 1 1 1 1 1 1 j 0. 20 1 1 % ο ΙΌ ο 1 0. 15 ος 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 ο ! 1 I 1 1 ! 1 1 1 1 1 t 1 l c=> CJ1 1 1 1 I 0. 10 <=3 • I ί 1 ! CZ3 Cj〇 二 <ζ> Of 1 爻 ==» 1 1 1 .= 5= ΰ. 01 F3 1 Η 1 1 1 1 c=t 1 1 1 1 1 1 1 1 1 1 1 ί F=» 1 1 5: : <=» 5 <=- cr i ί= .° -η α> '、 < 平衡量 > yJ Ci- ' 、 < < 4»«- CL-- ν° - '、 < 〇 〇> CO :J 犧牲件材料合金的組成(重虽%) 1 1 1 I 1 1 1 1 1 1 1 1 j 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I cn .j : I i 1 < r^> 1 < •ο <^ OQ I 1 I 1 1 1 1 1 5: 1 1 1 I 1 1 1 1 1 1 ~平衡擧 1 - . X Ρ 5; 欠 ί; 5; > -40- 煳00 ----------------- -------裝------.訂(請先閲讀背面之注意事項再塡寫本頁) 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公;ϊ ) «2. 9. 6,000 五、發明説明(蚵) 戔讁紫涵 s 55. Description of the invention (29) Substances printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs: 0.03% by weight or more and not more than 0.5% by weight magnesium, 0.03% or more by weight and not more than 0.6 Weight percent manganese, 0.G5 weight percent or more and not more than 2.0 weight percent nickel, 0.03 weight percent or more and not more than 0.3 weight percent chromium, 0.03 weight percent or more and not more than 0.3 weight percent and 0.03 weight percent The above and not more than 0.3% by weight of titanium, the remaining components are aluminum and some inevitable impurities β Regarding the role of the above-mentioned different components and the reasons for the use restrictions, silicon and iron as basic elements , Manganese, zinc, phosphorous, and tin, and magnesium, nickel, chromium, cobalt, and titanium as selective elements have the same reasons as in the case of the first core material of the present invention for hard brazing H . However, in this core material, 0.03 wt% or more and not more than 0.6 wt% manganese can be selectively added as an element. "Similar to other selective components: the addition of manganese is to further improve The strength of this kind of core material, however, if the amount does not exceed 0.03% by weight, the effect of improving strength cannot be obtained, and at the same time, if the amount exceeds 0.6% by weight, the conductivity will start to decrease. In addition, similar to the case of the first hard solder H used for heat dissipation 1 = 1: if the content of the leaching element does not exceed 0.03% by weight, unavoidable impurities can also be safely contained in the core material. The core material alloy in the first wave of the present invention and the second brazing material for heat dissipation H is as described above. On the other hand, the brazing material plated on both sides is an aluminum alloy, which Contains 7 · (]% by weight or more, R does not exceed 12.0% by weight of silicon, 0.5% by weight or more does not exceed 8.0% by weight -3 1-This paper size uses the Chinese National Standard (CNS) f 4 specifications (210x297 mm ) ................................................. .................................... # ............. .......... Subscribe ............... ^ {Please read the notes on the back before filling this page) Central Ministry of Economic Affairs Printed by the Staff Consumer Cooperative of the Bureau of Standards ^ ό1 Β β Β6 V. Description of invention (30) Copper, and further containing at least one substance selected from the following elements: 0.5% by weight or more and not more than 5.5% by weight of zinc, 0.002% by weight % And no more than 0.3% by weight of 絪 and 0.02% by weight and not more than fl. 3% by weight of tin, the remaining components are aluminum and some inevitable impurities. The plating rate of this brazing material on the core material is generally about 3 to 20%. The composition of this brazing material is the same as that of the brazing material alloy of the other brazing sheet of the present invention, so the role of the added element and the reason for the limitation of the amount are also the same. The manufacturing method of aluminum alloy heat exchanger will be explained. In the present invention, this kind of brazing material and brazing material H are pseudo-used, and brazing is performed in a temperature range of 5 70 to 585 ° C. This is because if the brazing temperature is lower than 570 ° C, a part of the composition will not melt into the brazing material of the present invention, and brazing cannot be performed. Similarly, if the temperature is higher than 585 ° C, the thermal conductivity of the heat dissipation H will be reduced (as described above U and the bending properties at high temperatures will also be reduced, resulting in further melting β. In addition, in this way To reduce the brazing temperature, it can extend the life of the brazing furnace and improve the corrosion resistance of the refrigerant path forming components. Although the brazing conditions of the present invention limit the temperature range, other conditions can be compared with the traditional brazing conditions Maintain the same. In other words, the fusion brazing method, the H 〇c 〇〇〇 brazing method using a non-corrosive rib flux (fluoride type, absolute type), etc., can be used directly without special restrictions. Before brazing, if necessary, you can carry out Tai-install and Qing-3 in the traditional way. 2-This paper standard uses the Chinese National Standard (CNS) A4 specification (210x297 mm) ...... .................................................. ............................. Installed ...—… ordered! _!., Line (please read the precautions on the back first (Fill this page) A6 B6 printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Description of the invention (31) Washing and flow coating. In this case, even if a rib flux (for example, an rib flux with an absolute shape) is used, brazing can still be performed within the temperature range of the present invention. In addition, in the present invention, The treatment procedure after heating is not particularly limited. That is, the procedures such as treatment, removal of rib flux and paint can be performed up to this point. To produce ingots, however, it can be manufactured through the procedures of hot rolling (multilayer rolling) and cold rolling-annealing, or it can also be produced through the procedures of continuous casting rolling and cold rolling-annealing. , These examples will be used to explain the present invention more specifically. Example 1 The present invention has a three-layer structure (including brazing materials, core materials and sacrificial materials) aluminum alloy brazing pads, used for heat dissipation The flat tubes and headers of the device are tested in the following manner: Using the alloy composition shown in Table 3 to Table 9, the core material, brazing material and sacrificial material are joined together, and Borrow the general method Method to produce a three-layer structure with a huge thickness of 0.25 mm brazed pads. The rate of electroplating of the brazing material is 0%, and the rate of electroplating of sacrificial material is 15%. In addition, in sacrificial materials, iron and silicon are impurity elements, and their content (others have the most range between 0.01 to 0.2% and the most weight. This ® hard soldering Η in Table 10 to Table 1 2 under the temperature conditions, placed in nitrogen heating „Braking the brazing material part of the brazing Η outward, 3-3-This paper standard uses the Chinese standard (CNS) A 4 Specifications (210x297mm) Pack .................... Order ..................... .. Line f, please read the precautions on the back before filling the nest page) A6 B6 V. Description of the invention (32) The material part is facing inwards, and after the brazing Η is heated, the tensile test, external corrosion resistance test and internal corrosion resistance are performed Sexual testing. In the external corrosion resistance tide test, only the middle part of the surface of the brazing material is exposed, and the other faces are sealed, and then a 360-hour CASS (JIS H 8 6 8 1) test is performed to check the location where pitting occurs. In the internal corrosion resistance test, the brazing pad partially masked with the brazing material is immersed in tap water with 10 pp β of Cu2 + Ran ion for 5 months, and who will do 8 0 ° CX 8 hours and Periodic corrosion test at room temperature X 16 hours. Then, under the optical display mirror, the depth of focus is used to determine the depth of pitting generated on the surface of the sled material. These results will be listed in Table 10 to Table 12. (Please read the precautions on the back before filling the nest page). Binding. Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economics-3 4-This paper size is applicable to the Chinese National Standard (CNS) f 4 specifications (210X297 mm) A6B6 V. Description of the invention (printed by the Central Prototype Bureau of the Ministry of Economics and the Consumer Industry Cooperative Society m to CO csa * Ό-2 Ξ CD 00 --3 σ> cn Οί ro 1 braided braid% ii. 0 ii . δ% · — · c ^ > ο ►— * · «n%« = »11. 5! ί 55% 爻% ο in the composition of the brazing material alloy, weight%% °% II: II%%: ·:% =% = Scoop a > c ^ s Ca > CT »C *» csa ϊ: € = > JO < = »〇 仁 二 r ^ > cross ro Ol-II« νβ c = > tSJ pt 1 1 1 1 1 a 〇CO < = > tn 1 1 1 I 1 1 m D%% ί ί 5: w-mm >% 55% ϊ% ί%% 55 l · -— CaJ (j ) The composition of the core material alloy, which weighs the most %% %%% ί gold% !: two two ·: < zr > oc 爻 爻 令令% 令% 令% %%%% Two zs 1 1 1 1 1 1 1 1 1 ί 1 e = > 1 s: OQ I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 〇 &n; n 1 1 1 1 1 1 1 I i ι I 1 1 t 5 = * Μ n Yao 5: 55 Yao 55 5i Ling Ling Yao 0.18 5s * H 1 1 1 1 1 1 () I tt 1 1 1 1 1 1 〇〇 爻% Yao $ ί ί ί ί -n fD ί ί $ Balancing > ί::: ί MP Uncovering the balance of the material balance (examination%) 1 1 1 1 1-1 1 I 1 0. 01 1 1 1 1 ο. Οι 1 1 f 1 1 1 1 1 1 1 i 1 1 1 I ί 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 cn Γ3 tO »--k 1 1 1 α 〇Q 1 1 1 1 1 t 1 1 1 Γ. 1 1 1 1 1 1 1 1 1 1 1 Γ3 $% ί: 5: 5i i Balance 詈 > (please read the precautions on the back before filling in this page). Pack. Order. Paper size Applicable to the Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 82. 9. 6,000 V. Description of the invention (bucket) sw β A6B6-r > a Gk c * ».« ≫ CAft 〇〇c « a Ca * en «• η Ca * & > * CO o * cva Ck» * — »C *» G9 〇 · »** 〇CsA oo < sa — > rsa 〇 «csa cn Cs» Ca »m eagle%%%% 55 · — · ω:%% ί ί ί ί%% 5: two (H Γ'3 r ^ s« -Γ »Rvs C ^ l CO ο c delivery%% Lingjiao Ji **-Λ ^-cxa & / I 1-Μ p 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 CSt« s < = »A« -Γ »« = > «= d 〇 > P 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I 1 1 i ω 口 ί 5ί ί ί% ί ί; Balance · > Yao • 5 of 2 爻 爻; ϊί 匚 CO ls:% 爻 ί J5% η c 爻-% of 爻% Let% make the woman praise 55 々r: Μη 1 1 Ο.ΊΟ 1 1 1 1 1 1 1 1 1 1 1 1 1 oq 1 ο 1 tl 1 1 1 1 1 1 i 1 ί 1 1 1 1 1 i 1 o »n t--s» < C3 1-1 1 1 1 1 1 1 1 1 1 1 I 1 1 1 1 1 1 1 1 1 IM • nt 0. 53 [-J = > 1 1 令 爻 1 爻 ϋ 爻 5ί ί% < = > oo H 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 ° 5: 丨 0.3: Balance ls i 0 Φ > 1 1 1 ί ί: ί t $, —, oo oo 1 1 1: ESI p 1 1 t I 1! 1 1 1 < = > 1 1 1 < = »t = > 〇-» 1 I ο. Oi j one | — 1 1 1 1 1 1 1 1 1 1 1! 1 1 P ί 1 5: 1 1 = 1 1 1 1 1 1 £ = _ > to: 1 CO P ·: =: 1 oq 1-1 1 1 t 1 1 1 ί 1 Z. 1 1 1 i-1 balance scene P ί \ $ ί > s ^ Xie 4 | Binding · Ordering · 36 This paper scale is applicable to China National Standard (CNS) A 4 specifications (210 X 297 mm) H2. 6,000 5604 V. Description of invention (^) A6 B6 The Ministry of Economic Affairs-Λ sample quasi-bureau Ri consumer inclusion agency Qiu Ke. Pet Μ Nirvana θ '»er > cn« XI cr > C7 > c * > en csa-cr *-* JF \ 00 & n e > n cr > & ^ 1 «Π CO« • η «Α» «η CO-& Π tz II s: Brazed tab 1 number *-· CS ·-· C3 GS%%% I 11.0 < Λ Composition of the brazing material alloy,% by weight ° Z c = > ί% 5:% ° 〇 > Γ ° e ^ rt = two lines 4.Ό CZt 〇C l, c; 5:: ¾ two 55 % 爻 玻 口 z 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Ρ : 1 1 1 1 1 1 1 1 1 f 1 1 1 1 1 1 1 1 1 1 1 1 1 cn P Yao 5i ii ΪΪ 5; 5; 5: female% balance stiffness _1 >% Order: 爻 二 二% 令 二 ω The formation of core material alloy, weight% 爻%%% 5S%%% 1 ·: ο c: %% Ling Yao Ling 5: Yao C ^ t 〇 > C * · »〇 > = * CS Ca > C9, Bu < ^ Λ,. 1 Μ η 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 C3 C ^ b < = > I 1 1 1 ο C ^ 9 C3 C3 < jr \ (Ki 1 1 1 1 1 1 1 1 1 I 1 1 1 1 S 1 1 1 1 1 .β 1 1 0 • η 1 i 1 1 1 1 1 1 \ 1 1 1 * — «-Π 1 1 1 1 1 1 0. 10? = ^ Η-5:% 55 爻 = (1 1 1 CX1 c = > α ►- · rm cn 1 Η 1 1 1 1 1 1 1 1 1 1 1 1 I 1 1 1 1 1 1 1 < = > 1 1 5ί G > C3 〇〇G3 0 · »α« 〇C = 3 0 C ^ ~ 3 1 ο. Γ Balance ii) Ο) 5: > C = 3 «= >-Ρ is the clamping of the surplus of animal materials (vehicle bill ° /. ) 1 1 1 1 1 1 1 1 1 0. 01 1 1 F3 1 1 1 1 1 1 1 I 1 1 1 1 Ρ 1 1 I 1 1 1 1 1 1 1 1 1 I 1 1 1 1 1 夂 1 1 1 LO Ρ oq 1 1's 2.5 j -balanced most '1 \ 1: 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Μ η ΐ; > -37-(read the precautions on the back before reading the book Page) — Binding. Ordered. This paper scale is applicable to China National Standards (CNS) A 4 specifications (210 X 297: PCT) 82. 9. 6,000 A6B6 V. Description of Invention (払) R Industry and Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs Print a Si 〇〇〇〇〇〇〇> 〇〇〇% 〇〇 «_η oe oo 〇» oo rs »〇〇oo« 〇oo — * «—1 H —4 —4 en« 〇〇 > e 〇σ > m thin brazing pad i 11.0 CO ο »— ►— · ca cs ►— ♦ — · C3« rt ►— »►—» ►— * cn (Λ composition of brazing material alloy, weight% 5: CZJ ro o < u »cs CO C3 · — · C3 U1 c» c ^ sz spoon Λ ΪΌ «-Π CO GS > cxi < ^ Λ o c_n o —1 C > 3 5i% 5: € NS ο c -1 1_ r «A r-« s. ^. CV9 ►— · cn 5: 5ί% 爻 之 ii • b- Μ ρ 1 1 IIII i II 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Ρ 〇r〇 «S on I i IIII. I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 (Λ Ρ 爻 令% 爻 爻 Balance amount> $ 55 55: 2 ·:% 55 2 2 ⑺ 爻 >: 5: z L ez> 2 5S% = ο C% order l female $% 2 Z 二二二 ° Μ η Core-material alloy composition, weight% 1 1 IIIIIII 1 1 1 C = 3 1 1 < = > 1! Γ 1 0Q 1 1 IIIIIII 1 f 1 0. 10 f 1 1 1 1 1 1 1 1 ο -1 1 1 IIIIIII 1 1 = 1 1 1 1 1 1 1 1 1 1 1 Ν-~ t $ i: II 爻 夂 5: 2 1 1 1 1 1 ί = · 1: 1 Η 1 1 IIIII 1 1 1 1 1 1 i 1 I 1 1 1 ί; < i: I 1% $ 1 1 II. _Books Λ Οι < < > '' <, ten cu to < < < <Ν; J Composition of sacrificial material balance (% by weight) 1 IIII {1 1 1 1 1 1 1 1 1 1 1 1 τ— · ρ ν < ', < *-rf 1- < < < < ►w < »2: oq 1 I i IIII i 1 1 1 1 1 1 1 1 1 1 1 t 1 Ρ 平 iSif > -3 θ- Xie 6 (please read the precautions on the back before writing this page). Binding. k paper size is applicable to China National Standard (CNS) A 4 specifications (21〇X 297 Dream) 82. 9. 6,000 A6 B6 V. Description of the invention (^) Printed mms by the R-Consumer Cooperative of the Bureau of Loss of Standards of the Ministry of Economy ^ 5 is 5 ·-«< =» CO »-» es csa 5 CO «ο U9 oo CO «ο cr >« ο crt CO «〇Ca» «〇CSS« ο «ο Ο0 < 〇 brazing pad: job ΪΪ! I%%% tn composition of brazing material alloy, weight%%% ° Boast% Ϊ5 it 5¾ 爻 ° α% fsd οι%% fa Cfl 〇Λ (= > < = »(= > C3 Ρ 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 -ί Balance ¥ 0. 8 in Ρ ί% $% 爻% > %: ° II 5:%%% CO The composition of the core material alloy, weight% 1:%% Yao% Yao: ¾ of ο C Yao command order Yu order command% 5:% 55 5: 55 匚 Μη 1 1 < = > 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2: 0Q 1 1 1 t 1 1 1 1 1 1 1! 1 1 1 1 1 1 1 t 1 ο η • — »1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I Μ η < = >« 一 J < _ »1 1 • ί 令 爻Fahrenheit 1 1 1 ° 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 F3 ϊί 5: 爻 $ 爻 5: F = > α > k 55 p1 measure > < = > < = > c = > c_n β 〇〇! 1 1 =: {ν3 Ρ Shaocheng of the material alloy (jun m% 1 1 t 1 1 1 ί: 1 1 1 1 1 == * 1 s F = »1 5 = 1 1 5: = 1 F = 1 1! 1 1 1-1-2. 3 | ―Balance Expansion 1 1 1 1 I: 1 < ^ 1 1 1 1 i 1 1 1 1 1 1 1 々1 爻 1 1 1 1 CO Ρ 0Q 1 ·: 1 匚 1 1 1 1 1 i 1 1 1 = 1 1 '< ^ Ρ ί > -39- (please first Read the precautions on the back and then write this page) —Package: 玎 _ This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications UlO X 297 mm) 82. 9. 6,000 A6 B6 Ministry of Economic Affairs China Standards Bureau R Engineering Printed by consumer cooperatives轺) 2 c ^ »5 S CO oo s < > n 5 〇 · > r > a 5 5 5 Ξ S Ξ Ε Ξ» — m tanned brazing pad £ = > »— · c ~ n * — »O» — · < s 4 = >%% ω Composition of brazing material alloy, weight% ° ° c ί: < = 3 ° $%% Λ C-Λ CJt Γ " * r > 3 « rt c * »% c; 爻% ο C-1 C ^ tk 爻 CO cn two ί Ρ f 1 1 1 1 1 1 1 < = 3 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 * —1 s 1 1 1 1 i 1 1 t 1 1 1 1 1 1 1 1 α > $ 令 爻 爻 ί 爻 柳 量> Two ·: π% ί: · = C = 3:: ω-two two% «= 3 οα C3 C3 〇〇CO 〇 > »— · C ^ 9» — · c- > d Ι-— ΟΊ ο C 爻 二 °: π 夂% cs ^ a ~ w > & · >, _, ο οο ♦ — * — · r- Μη core material alloy composition, weight% 1 1 1 1 1 1 1 I 1 1 1 1 1 1 1 1 j 0. 20 1 1% ο ΙΌ ο 1 0. 15 ος 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 ο! 1 I 1 1! 1 1 1 1 1 1 t 1 lc = > CJ1 1 1 1 I 0. 10 < = 3 • I ί 1! CZ3 Cj〇 二 < ζ > Of 1 爻 == »1 1 1. = 5 = ΰ. 01 F3 1 Η 1 1 1 1 c = t 1 1 1 1 1 1 1 1 1 1 1 1 ί F =» 1 1 5:: < = »5 < =-cr i ί =. ° -η α > ', < balance amount> yJ Ci-', < < 4» «-CL-- ν °- ', ≪ 〇〇 > CO: J composition of sacrificial material alloy (though weight%) 1 1 1 I 1 1 1 1 1 1 1 1 1 j 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I cn .j: I i 1 < r ^ > 1 < • O < ^ OQ I 1 I 1 1 1 1 1 1 5: 1 1 1 I 1 1 1 1 1 1 ~ balance 1-. X Ρ 5; owed; 5; > -40- 煳 00 ----------------- ------- installed ------ . Order (please read the precautions on the back before writing this page) This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 g; ϊ)残 讁 紫 涵 s 5

二 CO u s u u 1-0 i-0 0. 3 ·0 U52 CO u s u u 1-0 i-0 0. 3 · 0 U5

2J 4. 0 -0 9.0 ·0 022J 4. 0 -0 9.0 · 0 02

U ·0 A6 B6 5 5U · 0 A6 B6 5 5

mm :JT mmm: JT m

UU

0.T 0.05 6· 0 1L00.T 0.05 6 · 0 1L0

Si uSi u

U 0. 02 0」 ·0 0.3 F e ·0U 0. 02 0 "· 0 0.3 F e · 0

U ϊ_! C uU ϊ_! C u

Zn S n A 1 (請先閲讀背面之注意事項再墣寫本頁) -裝. •3 -3 3. 0 0-Zn S n A 1 (Please read the precautions on the back before writing this page) -installation. • 3 -3 3. 0 0-

3. G3. G

Si 0.5 0.1Si 0.5 0.1

U 3.0 1.3 u ·0 ΜηU 3.0 1.3 u · 0 Μη

Mw 訂. c zMw order. C z

Mi •13 0· 10 u 0.10Mi • 13 0 · 10 u 0.10

T •3 經濟部中與樣準局貝工消费合作杜印製 ·0T • 3 Printed by the Ministry of Economic Affairs in cooperation with the sample bureau of shellfish consumption.

MM

4-I 6. 2. I i· .1 . -g ί M r A i 菊琪 芸卟咏s-sf_rt。/0) 本紙張尺度適用中國S家標準(CNS)甲4规格(210 X 297公釐) H2. 9. 6,000 A64-I 6. 2. I i. .1. -G ί M r A i Ju Qi Yun porch s-sf_rt. / 0) This paper scale is applicable to China S Standard (CNS) Grade 4 (210 X 297 mm) H2. 9. 6,000 A6

6 B 五、發明説明(40 經濟部中央標準局R工消費合作杜印製 表10 硬焊片 職 硬焊的 加熱條 件V (X吩鐘) 抗張 強度 MPa 外部的酎 a性孔蝕 的最大深 度(微米> 内部的耐 拽性孔拽 的最大深 度(橄米> 硬焊片 编號 硬焊的 加熱條 tAr *p (X玢鐘) 抗張 強度 MPa 外部的耐 ft性孔蝕 的最大深 度(撖米) 内部的駙 蝕性孔蝕 的最大深 度(撤米> 1 580 240 80 60 29 580 2^0 70 80 2 〃 250 // 10 30 " 〃 // 60 3 〃 〃 // tt 31 〃 〃 〃 〃 \ tf 〃 〃 〃 32 〃 〃 // 70 5 // 〃 // // 33 〃 2,50 80 60 6 η // 70 〃 34 〃 220 〃 80 I t/ 230 〃 〃 35 〃 〃 〃 50 8 〃 240 〃 〃 36 〃 〃 〃 70 9 // 250 60 〃 37 〃 230 〃 〃 10 // 〃 100 〃 38 〃 • // 〃 It 11 " 230 80 '/ 39 " 240 tt It 發 12 " 2<0 〃 ft 發 40 〃 250 // 〃 明 13 tr 250 Ϊ0 η 明 “ η 〃 f/ 〃 Η ft tt 100 〃 42 〃 〃 " 〃 實 15 〃 // 80 tt 實 43 〃 〃 tt 〃 例 16 // 230 〃 〃 例 44 ft 〃 tf 〃 17 〃 〃 〃 U 〃 〃 〃 " 18 n 250 〃 '〃 U 〃 " 〃 // 19 〃 〃 〃 〃 〃 〃 " 〃 20 〃 // 〃 〃 〃 230 // // 21 〃 〃 100 〃 49 160 〃 〃 22 〃 〃 // 〃 50 〃 no 〃 " 23 〃 " 90 it 51 〃 190 〃 〃 " " " " 52 // 200 〃 // 25 " " " 〃 53 // 〃 " " 26 〃 230 〃 〃 〃 〃 〃 // Ϊ1 // 240 // 〃 bh 〃 〃 70 〃 η " " 70 80 56 〃 180 " " ---------------------------裝------.玎 (請先閲讀背面之注意事項再塡寫本頁) 本紙張尺度適用中國國家標準(CNS)甲4规格(210 X 297公) 82. 9. 6,000 經濟部中央標準局W工消費合作杜印製 295604 A6 B6 五、發明説明(屮) 表11 硬焊片 硬焊的 加熱條 件ec (X吩鐘) 抗張 強度 MPa 外部的射 胜性孔蝕 的最大深 度(撤米) 内部的W 蝕性孔蝕 的最大深 度(撤米> 硬焊片 编號 硬焊的 加熱條 件。C (X5分鐘) 抗張 強度 MPa 外部的射 蝕性孔蝕 的最大深 度(撤米) 内部的酌 蝕性孔蝕 的最大深 度(榭米> 57 580 190 70 70 85 580 220 80 70 58 " 200 80 86 // It // tt 59 〃 180 // 〃 87 t/ 200 90 rt 60 〃 190 〃 88 〃 t, 70 // 61 〃 200 70 rt 89 〃 〃 90 〃 62 〃 180 〃 tt 90 〃 220 80 〃 63 // 190 // 〃 91 tf // 〃 80 // 20fl 80 // 92 〃 200 〃 70 65 // 180 〃 〃 93 〃 220 ¢/ 〃 66 〃 190 // 〃 U 575 210 〃 80 67 tf 200 〃 〃 95 〃 〃 // 90 發 68 575 220 〃 〃 發 96 // // 70 明 69 η 250 〃 〃 97 〃 ;t 〃 SO 70 〃 // // 〃 明 98 η 〃 〃 〃 富 71 // 260 // tt s 99 S80 220 ?0 例 72 // // // // 例 100 〃 200 〃 90 T3 580 210 // // !01 〃 〃 //· 80 U // 220 〃 70 102 〃 〃 " 〃 75 " 23G 〃 80 103 " // // 〃 76 /t 220 〃 〃 104 tt 210 // 70 11 // 〃 70 〃 105 〃 〃 " 〃 η 〃 200 80 90 106 tt 220 // " 79 " 220 // 70 107 〃 /V 〃 〃 80 " // 90 〃 108 〃 tf " 80 81 ft 80 // 109 rr " 〃 Ϊ0 82 " // 90 〃 110 〃 〃 〃 " 83 〃 ff 10 〃 111 〃 〃 // 80 U " 〃 // 〃 112 ff // If 〃 -4」一 (請先閲讀背面之注意事項再埃寫本頁) —裝. 訂. 本紙張尺度適用中國國家標準(CNS)甲4规格(210 X 297公釐) 82. 9. 6,0006 B V. Description of the invention (40 Ministry of Economic Affairs, Central Standards Bureau, R, Industry and Consumer Cooperation, Du Yin, Tab. 10, Heating conditions for brazing and brazing V (X phen) Tensile strength MPa Maximum external pitting corrosion Depth (microns> Maximum depth of internal drag-resistant holes to be pulled (olive rice)> Brazed pad number Brazed heating bar tAr * p (X 玢 钟) Tensile strength MPa External resistance to pitting corrosion Maximum Depth (撖 米) The maximum depth of internal corrosive pitting corrosion (withdrawal> 1 580 240 80 60 29 580 2 ^ 0 70 80 2 〃 250 // 10 30 " 〃 // 60 3 〃 〃 / / tt 31 〃 〃 〃 〃 \ tf 〃 〃 〃 32 〃 〃 // 70 5 // 〃 // // 33 〃 2,50 80 60 6 η // 70 〃 34 〃 220 〃 80 I t / 230 〃 〃 35 〃 〃 〃 50 8 〃 240 〃 〃 36 〃 〃 〃 70 9 // 250 60 〃 37 〃 230 〃 〃 10 // 〃 100 〃 38 〃 • // 〃 It 11 " 230 80 '/ 39 & tt It sends 12 " 2 < 0 〃 ft sends 40 〃 250 // 〃 Ming 13 tr 250 Ϊ0 η Ming "η 〃 f / 〃 Η ft tt 100 〃 42 〃 〃 " 〃 real 15 〃 // 80 tt real 43 〃 〃 tt 〃 Example 16 // 230 〃 〃 Example 44 ft 〃 tf 〃 17 〃 〃 〃 U 〃 〃 〃 " 18 n 250 〃 '〃; 〃 〃 〃 〃 〃 " 〃 20 〃 // 〃 〃 〃 230 // // 21 〃 〃 100 〃 49 160 〃 〃 22 〃 〃 // 〃 50 〃 no 〃 &quotation; 〃 〃 " " " " 52 // 200 〃 // 25 " " " 〃 53 // 〃 " " 26 〃 230 〃 〃 〃 〃 〃 // Ϊ1 // 240 // 〃 bh 〃 〃 70 〃 η " " 70 80 56 〃 180 " " --------------------------- install --- ---. 玎 (Please read the precautions on the back before writing this page) This paper scale is applicable to China National Standard (CNS) A 4 specifications (210 X 297) 82. 9. 6,000 W Ministry of Economic Affairs Central Standards Bureau Consumer Cooperation Du Printed 295604 A6 B6 V. Description of the invention (屮) Table 11 Heating conditions for brazing brazing ec (X phen) Tensile strength MPa Maximum depth of external pitting corrosion (withdrawal) Internal W The maximum depth of pitting corrosion (withdrawal m > heating conditions brazing sheet number brazing. C (X5 minutes) Tensile strength MPa Maximum depth of external erosive pitting corrosion (removal of meters) Maximum depth of internal erosive pitting corrosion (Xie Mi> 57 580 190 70 70 85 580 220 80 70 58 " 200 80 86 // It // tt 59 〃 180 // 〃 87 t / 200 90 rt 60 〃 190 〃 88 〃 t, 70 // 61 〃 200 70 rt 89 〃 〃 90 〃 62 〃 180 〃 tt 90 〃 220 80 〃 63 // 190 // 〃 91 tf // 〃 80 // 20fl 80 // 92 〃 200 〃 70 65 // 180 〃 〃 93 〃 220 ¢ / 〃 66 〃 190 // 〃 U 575 210 〃 80 67 tf 200 〃 〃 95 〃 〃 // 90 hair 68 575 220 〃 〃 hair 96 // // 70 Ming 69 η 250 〃 〃 97 〃; t 〃 SO 70 〃 // // 〃 Ming 98 η 〃 〃 〃 rich 71 // 260 // tt s 99 S80 220? 0 Example 72 // // // // Example 100 〃 200 〃 90 T3 580 210 // //! 01 〃 〃 // · 80 U // 220 〃 70 102 〃 〃 " 〃 75 " 23G 〃 80 103 " // // 〃 76 / t 220 〃 〃 104 tt 210 // 70 11 // 〃 70 〃 105 〃 〃 " 〃 η 〃 200 80 90 106 tt 220 // " 79 " 220 // 70 107 〃 / V 〃 〃 80 " // 90 〃 108 〃 tf " 80 81 ft 80 // 109 rr " 〃 Ϊ0 82 " // 90 〃 110 〃 〃 〃 " 83 〃 ff 10 〃 111 〃 〃 // 80 U " 〃 // 〃 112 ff // If 〃 -4 "one (please read the precautions on the back before writing this page)-Pack. Order. This paper size Applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) 82. 9. 6,000

A B6 明 明 、 4 賧 S 鸸 0 潑镝 Η 翳紫 113 1U 115 116 117 118 119 1S m 122 123 12私 5 126 m S Is 130 131 132 缃12 湔镝3 ^ 〇0 X 5Φ 廳) 580 580soso E 580soso 580 580 5000 580 580 580 ~^~~ 5 75 5S°so 580 __E_A B6 Mingming, 4 賧 S Emu 0 長 钝 Η 緳 紫 113 1U 115 116 117 118 119 1S m 122 123 12 private 5 126 m S Is 130 131 132 缃 12 湔 镝 3 ^ 〇0 X 5Φ Hall) 580 580soso E 580soso 580 580 5000 580 580 580 ~ ^ ~~ 5 75 5S ° so 580 __E_

24QI 180so s 170 180 190 180 190 s 190 s 190 200 190 UPa (請先閲讀背面之注意事項再填窝本頁) co 00 〇 0024QI 180so s 170 180 190 180 190 s 190 s 190 200 190 UPa (please read the precautions on the back before filling this page) co 00 〇 00

CDCD

CO σ> cn» —-3 CJ\CO σ > cn »—-3 CJ \

CO Q»S?g CMmm »3^2· a»se?>f^3 裝 漥 聃潘锻 m m^m鞣输 訂 600 600 580 575 600 580 575 Φο m 經濟部中央標準局員工消費合作社印製 } 1 160 1 ] 130 _1_ 産生泡蝕 120 140 ffl-涿莰葡到铕浒蓮_ »涿窃葡到铕铬蓮_ 250 70 »筇窈葡到箱臶蓮_ ffls窃爺到铕浒蓮_ 250 70 丑涿莰爾到铕浒蓮_ »涿玆爺到铕笫蓮邮CO Q »S? G CMmm» 3 ^ 2 · a »se? ≫ f ^ 3 漥 聃 潘 華 mm ^ m tanning and ordering 600 600 580 575 600 580 575 Φο m Printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Control system 1 160 1] 130 _1_ produces bubble 120 140 ffl-Zhejiang to Europium lotus _ »Zhejiang to Europium chromium lotus _ 250 70» Scarlet Portuguese to box galanthus _ ffls thief to Europium lotus _ 250 70 Ugly Zhuoer to Euhulian _ »Zhuozhe to Eucalyptus Post

落a· 米 狀3 mwm 4 Ϊ 本紙張尺度適用中國國家標準(CNS)甲4規格(210X297公釐) 經濟部中央標準局員工消費合作社印製 A6 _ B6_ 乓明説明(43 ) 由表10到表12中可清楚的看出,本發明實例的硬焊Η 在硬焊時不會熔解,且具有高強度,並且在耐鈾性方面 也很優越。 然而,在比較實例1 3 3 , 1 3 4 , 1 3 9和1 4 0中,其核心材料 或犧牲性材料皆超出本發明的範圍,卽使是在575 °C下 進行硬焊時,它們仍會開始熔解。在比較實例1 3 5和1 4 1 中,其硬焊材料並不含鋅、铟和錫,使得其外部的耐蝕 性下降〇在比較實例〗36, 137,142和143中,其硬焊材料 超出了本發明的範圍,因為硬焊材料不會在5 8 5 °C (或更 低)的溫度下熔解,因此在600 °C下進行加熱,但是此時 核心材料卻開始熔解了。在比較實例1 3 8和1 4 4中,其硬 焊材料中的鋦和鋅之使用量大於本發明所列之範圍,在 滾軋時會發生破裂的現象,而使得其無法製成硬焊Η。 在傳統實例i45中,其中一般為0.4毫米之厚度的平板 變薄了,且其強度和耐蝕性皆比本發明實例之硬焊片為 差β在傳統奮例】4 6中,其在核心材料中含有很多的銅 ,因此耐鈾件不佳 例 1 將以表1 3中所列之合金組成物所製成的鋁合金散熱ϋ 材料,和以表1 4中所列之具有硬焊材料,核心材料和犧 牲件材料之三層結構的管材和管集箱材料,如表1 5中所 述之方式予以接合,以紺成圖1所示的散熱器。除此之 外、在散熱Η材料方面,使用厚度為ϋ . 0 6毫米,巨具有 -4 5 - 本紙張尺度適用中國國家標準(CNS)甲4規格(210X297公釐) ............................................................................裝…— -訂.....................線 {請先閲讀背面之注意事項再填窝本頁) 經濟部中央標準局員工消費合作社印製 A6 _ B6_ 五、發明説明(44) 如表13中所示之合金組成的裸材;在管材方面,以一般 方法來製造厚度為0.3毫米之螺管線圈狀的硬焊片,其係 在核心材料的一制鍍上厚度為10%的硬焊材料,另一側 則鍍上厚度為15%的犧牲性材料。這些螺管線圈狀的硬 焊片將予以切割,調整成鉛缝熔接管的大小,以製成3 5 . 0 毫米寬的條狀材料。以製造鉛縫熔接管的裝置將這些條 狀物質予以加工成16.0毫米寬,2.2毫米厚的鉛缝熔接 管,以用於流體流經的管子。此外,厚度為1.0毫米之 相同紐成的螺管線圈狀之硬焊片,將被切成寬度為60毫 米。以製成管集箱材料用的條狀材料。 在組裝散熱器時,將含有3%絶型肋熔劑和氟化鉀型 肋熔劑之混合物的肋熔劑液體(濃度為10% )塗佈上去, 並在表15所示的硬焊條件下,於氮氣中加熱。材料的組 合方式及加熱條件皆列於表1 5中。 - 這樣所獲得的散熱器,將藉由外表的觀察來研究散熱片 和管子的崩潰狀態及填角焊缝的形成。此外,對於已硬 焊好的散熱器,將做導熱度的研究。導熱度偽依JIS D 1 6 1 8 (用於汽車之冷暖氣機的測試方法)之規定來測量, 並且分別以相對於傳統散熱器的熱效率之改善百分比來 表示。 此外,管材在經過硬焊加熱之後所得之張力測試的結 果也列於表]5中。 -46- 本紙張尺度逋用中Η國家標準(CNS)甲4規格(210x297公釐) .....................................................................................裝.......................玎..................-線 {猜先閲讀背面之注意事項再填窝本頁) A6 B6 五、發明説明(45 ) 表13 散熱 Η材 料 合金的組成重量% Si Cu Μη Ζη Zr Ti Fe A1 A 0.2 0.05 1.1 1.0 - 0.01 0.5 平衡量 B 1.10 - - Μ 0.15 II 0.65 It (請先閲讀背面之注意事項再填寫本頁) .裝 管材 集管 材料 硬焊材料合金的組成,重量% 核心材料合金的組成,重量% 犧牲性材料合金 的組成(重量%) Si V c C u Z η Λ 1 Si Cu Μη M R Z r T i F e Λ ! Ζ η Μκ Λ 1 a II. 0 0」 1. 5 1. 5 f-m :0. 9 1. 2 1. 1 0. 15 — 0. II 0. 3 _ 0 2. 0 - m b // 0. 2 2. 5 l 0 " 1. 0 0. 8 /〆 — — 0. 18 // // " // " c // // 3. 5 3. 5 // 0. 8 1. 5 0. 3 0. 15 — 0. 11 // // // — " i\ 9. 8 0_ 6 一 — // 0. 3 0. 15 1. 1 — — 0. 01 0. 5 // 1. 0 — " c " " — — // 0. 8 0. 5 ft 0. 15 0. 15 0. 10 // " L 0 2. 0 " 經濟部中央標準局員工消費合作社印製Drop a · rice-shaped 3 mwm 4 Ϊ The paper size is in accordance with Chinese National Standard (CNS) A 4 specifications (210X297 mm) Printed by A6 _ B6_ Ping Ming Instructions (43) from Employee Consumer Cooperative of Central Bureau of Standards of the Ministry of Economy It can be clearly seen in Table 12 that the brazing Η of the example of the present invention does not melt during brazing, has high strength, and is also superior in uranium resistance. However, in Comparative Examples 1 3 3, 1 3 4, 1 3 9 and 1 4 0, the core materials or sacrificial materials are beyond the scope of the present invention, even when brazing at 575 ° C, they Will still begin to melt. In Comparative Examples 1 3 5 and 1 4 1, the brazing material does not contain zinc, indium and tin, so that the external corrosion resistance is reduced. In Comparative Examples 36, 137, 142 and 143, the brazing material exceeds In the scope of the present invention, because the brazing material does not melt at a temperature of 585 ° C (or lower), it is heated at 600 ° C, but the core material begins to melt. In Comparative Examples 1 3 8 and 1 4 4, the amount of molybdenum and zinc in the brazing material is greater than the range listed in the present invention, and the phenomenon of cracking will occur during rolling, making it impossible to make brazing Η. In the traditional example i45, the flat plate with a thickness of generally 0.4 mm is thinned, and its strength and corrosion resistance are both inferior to the brazed pads of the example of the present invention. Contains a lot of copper, so the uranium-resistant parts are poor. Example 1 The aluminum alloy heat dissipation material made of the alloy composition listed in Table 13 and the brazing material listed in Table 14 The three-layer tube and header materials of the core material and sacrificial material are joined in the manner described in Table 15 to form the heat sink shown in Figure 1. In addition, in terms of heat dissipation Η materials, the thickness is ϋ. 0 6 mm, the giant has -4 5-This paper size is applicable to China National Standard (CNS) A 4 specifications (210X297 mm) ...... .................................................. .................... installed ...--ordered .................. line {please first Read the precautions on the back and fill this page.) A6 _ B6_ printed by the Employees ’Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (44) The bare material composed of the alloy shown in Table 13; The method is to manufacture a solenoid coil-shaped brazing sheet with a thickness of 0.3 mm, which is coated with a brazing material with a thickness of 10% on one of the core materials, and a sacrificial material with a thickness of 15% on the other side . These coil-shaped hard solder pieces will be cut and adjusted to the size of the lead-seam welded tube to make a strip material with a width of 35.0 mm. These strip-shaped materials are processed into a lead-seam welded pipe 16.0 mm wide and 2.2 mm-thick by a device for manufacturing a lead-seam welded pipe for a pipe through which fluid flows. In addition, the same coil with a thickness of 1.0 mm is formed into a coil-shaped brazing sheet, which is cut to a width of 60 mm. In order to make the strip material for the header material. When assembling the radiator, apply a rib flux liquid (concentration of 10%) containing a mixture of 3% absolute rib flux and potassium fluoride rib flux, and under the brazing conditions shown in Table 15, Heat in nitrogen. The combination of materials and heating conditions are listed in Table 15. -The radiator obtained in this way will be used to study the collapse state of the fins and the tube and the formation of fillet welds by external observation. In addition, for the heat sink that has been brazed, the thermal conductivity will be studied. The thermal conductivity is pseudo-measured in accordance with the provisions of JIS D 1 6 1 8 (Test Method for Automobile Air Conditioners), and is expressed as a percentage improvement over the thermal efficiency of conventional radiators, respectively. In addition, the results of the tensile test of the pipe after brazing and heating are also listed in Table 5]. -46- This paper uses the National Standards (CNS) A4 specifications (210x297 mm) of this paper ................................. .................................................. ........ 装 ............................................................ .-Line (Guess to read the precautions on the back before filling the nest page) A6 B6 V. Description of the invention (45) Table 13 The composition of the heat dissipation H material alloy weight% Si Cu Μη ζη Zr Ti Fe A1 A 0.2 0.05 1.1 1.0- 0.01 0.5 Balance B 1.10--Μ 0.15 II 0.65 It (please read the precautions on the back before filling in this page). The composition of the brazing material alloy of the pipe header material, weight% The composition of the core material alloy, weight% sacrifice Composition of the material alloy (% by weight) Si V c C u Z η Λ 1 Si Cu Μη MRZ r T i F e Λ! Ζ η Μκ Λ 1 a II. 0 0 ″ 1. 5 1. 5 fm : 0. 9 1. 2 1. 1 0. 15 — 0. II 0. 3 _ 0 2. 0-mb // 0. 2 2. 5 l 0 " 1. 0 0. 8 / 〆— — 0. 18 / / // " // " c // // 3. 5 3. 5 // 0. 8 1. 5 0. 3 0. 15 — 0. 11 // // // — " i \ 9 . 8 0_ 6 one — // 0. 3 0. 15 1. 1 — 0. 01 0. 5 // 1. 0 — " c " " — — // 0. 8 0. 5 ft 0. 15 0. 15 0. 10 // " L 0 2. 0 " Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

6 6 A B 五、發明説明(4b ) 表15 编 號 組合方式 硬焊的加 熱溫度 oc X纖) 産生 崩潰 的位 置 硬 焊 性 熱效率 硬焊加熱 後管子的 抗張強度 MPa 散熱Η 材料 管材管集 箱材料 發 明 方 法 ① A a 580 無 良好 比⑦增加〇观上 220 ② B " " |< ” 比⑦增加2.5m上 " ③ A b tl <( 比⑦增加〇·55ί以上 200 ④ B II " " ft 比⑦增加2观上 " ⑤ A c Μ Η 比⑦增加〇.5似上 220 ⑥ B If It ft 比⑦增加2.5似上 " 傳統方法 ⑦ A d 600 Η 標準 130 比較方法 ⑧ B ” " 散熱片 Μ 比⑦減少2. Q%以上 ” ⑨ A e If 管子 " 無法測量 - .....................................................................................裝 ..............可:…:—線 {請先閲讀背面之注意事項再填窝本頁} 經濟部中央標準局員工消費合作社印製 對於管子⑨,無法進行熱效率的測量和張力測試,因其 在硬焊加熱時熔解掉了。 -4 8 -本紙張尺度適用t Η躅家棵準(CNS)甲4規格(210X297公釐) A6 B6 205604 五、發明説明(47 ) 裝 (請先閲讀背面之注意事項再填窝本頁) 此外,將表13中所顯示的鋁合金散熱片,和表16中所 顯示的具三層結構之管集箱材料,接合在一起,以組成 圖1中所示的散熱器。除此之外,這些散熱Η材料、管 材和管集箱材料的組成與前面所述的相同。 並且,在組裝散熱器時,以類似上述的方法來塗佈肋 熔劑,同時在表17所示的條件下,於氛氣中加熱。然後, 進行外表的觀察和導熱度的_量,結果係列於表17中。 同樣的,管材經過硬焊加熱之後所得之張力測試的結果 也列於表1 7中。 表16 經濟部中央標準局員工消費合作社印製 管材 集管 材料 硬焊材料合金的組成,重量% 核心材料合金的組成,重量% 犧牲性材料合金 的組成(重量%) Si F e Cu Z n Λ 1 Si C υ Μη Mg Z r T i F e Λ 1 Ζ η Mg Λ 1 f II. 0 0. < 1. 5 1.5 - tm 1」 0. 8 1. 1 0. 15 — 0. 11 0.5 難 i 0 2. 0 - f-m g 9. 8 — — — // 0. 3 0. IS // 一 — 0.01 // // 1. 0 — // h ft — — // 1. 6 0. 5 ff 0. 15 0. 15 0. 10 // // ί 0 2. 0 // 本紙張尺度適用中國國家標準(CNS)甲4規格(210X297公釐) 五、發明説明U8 ) A6 B6 表17 编 OJa m 組合方式 硬焊的加 熱溫度 °C (X盼鐘) 産生 崩潰 的位 置 硬 焊 性 熱效率 硬焊加熱 後管子的 抗張強度 MPa 散熱片 材料 管材管集 箱材料 發明方法 ⑩ A f 580 無 良好 [:b⑪增加〇观上 210 ⑪ B ” n II 1:130增加2.5似上 Μ 傳统方法 ⑫ A 600 " Μ 標準 130 比較方法 ⑬ B " II 散熱片 tl 比!^少2.03;以上 fl ⑭ A h «爭 管子 Μ 無法測量 - 對於管子1 4,無法進行熱效率的測量和張力測試,因為 其在硬焊加熱時熔解掉了 〇 裝.......................玎.....................線 {請先閲讀背面之注意事項再填窝本頁) 經濟部中央標準局員工消费合作社印製 -50- 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公釐) 經濟部中央標準局員工消费合作社印製 A6 B6_ 五、發明説明(49) 由表1 5和1 7可很明顯的看出,以本發明之方法所製得 的散熱器,不會引起散熱片崩潰的問題,在加熱之後具 有高強度,並且在導熱度方面也很優異。 例 3 將具有表18到表21中所示之合金組成的硬焊材料和核 心材料予以結合,以一般的方法來製造厚度為0.4毫米 的硬焊片。在硬焊Η兩側的雷鍍比率為1 0 % ^ 這些硬焊片將在表22和表23所示的條件下,於氮氣中 加熱。這些硬焊Η在加熱之後,進行張力测試及耐蝕性 測試。 在耐蝕性測試中,只有硬焊材料表面的中間部分暴露 ,並且其它面皆予以密封,然後進行3 6 0小時的C A S S ( J I S Η 8 6 8 1 )潮試,以檢査孔蝕産生的位置。 這些結果皆列於表22和2 3中。 .....................................................................................裝.......................Τ : i:線 <請先闖讀背面之注意事項再填窝本頁) -51- 本紙張尺度適用中國國家標準(CNS)甲4規格(210X297公釐) 五、發明説明(50) A6 B66 6 AB V. Description of the invention (4b) Table 15 Numbered combination heating temperature for brazing oc X fiber) Location where the crash occurred Brazing resistance Thermal efficiency Brazing heating Tensile strength of the tube MPa Heat dissipation Η Material Pipe header The method of material invention ① A a 580 has no good ratio ⑦ increased by 280. ② B " " | <》 increased by 2.5m from ⑦ " ③ A b tl < B II " " ft is increased by 2 more than ⑦ " ⑤ A c Μ Η is increased by ⑦ 0.5. It is similar to 220 ⑥ B If It ft is increased by 2.5 than ⑦ 2.5 is similar to " traditional method ⑦ A d 600 Η standard 130 Comparison method ⑧ B ”" The heat sink M is reduced by 2. Q% or more than ⑦” ⑨ A e If tube " Unable to measure-......................... .................................................. ............... Installed .............. Available: ...-line {please read the precautions on the back before filling the nest page} Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. For tube ⑨, thermal efficiency measurement and tensile test cannot be performed because of its It melted when brazing was heated. -4 8 -This paper size is suitable for Η 躅 家計 准 (CNS) A 4 specifications (210X297 mm) A6 B6 205604 5. Invention description (47) Install (please read the back side first (Notes and refill this page) In addition, the aluminum alloy heat sink shown in Table 13 and the three-layer structure of the header material shown in Table 16 are joined together to form the composition shown in Figure 1. In addition, the composition of these heat dissipation materials, tubes and header materials is the same as described above. In addition, when assembling the radiator, the rib flux is applied in a similar manner to the above, while Heated in an atmosphere under the conditions shown in Table 17. Then, the appearance was observed and the amount of thermal conductivity was measured, and the result series is shown in Table 17. Similarly, the results of the tensile test obtained after the tube was brazed and heated Listed in Table 17. Table 16 Composition of the brazing material alloy of the tube header material printed by the Ministry of Economy, Central Bureau of Standards, Employee and Consumer Cooperative, weight% Composition of core material alloy, weight% Composition of sacrificial material alloy (weight%) Si F e Cu Z n Λ 1 Si C υ Μη Mg Z r T i F e Λ 1 AZ η Mg Λ 1 f II. 0 0. < 1. 5 1.5-tm 1 '' 0. 8 1. 1 0. 15 — 0. 11 0.5 difficult i 0 2. 0-fm g 9. 8 — — — // 0. 3 0. IS // one — 0.01 // // 1. 0 — // h ft — — // 1. 6 0. 5 ff 0. 15 0. 15 0. 10 // // ί 0 2. 0 // This paper scale is applicable to China National Standard (CNS) A 4 specifications (210X297 mm) V. Invention description U8) A6 B6 Table 17 The heating temperature of the brazed OJa m combination method ° C (X Panzhong) The position where the collapse occurs The brazeability Thermal efficiency The tensile strength of the tube after brazing heating MPa Heat sink material Pipe tube header material Invention method ⑩ A f 580 None Good [: b ⑪ increase in view 210 210 ⑪ B ”n II 1: 130 increase by 2.5 similar to M traditional method ⑫ A 600 " M standard 130 comparison method ⑬ B " II heat sink tl 2.03 less than! ^; Above fl ⑭ A h «Disputable tube Μ Cannot be measured-For tube 14 it is not possible to measure the thermal efficiency and the tensile test, because it is melted when brazing is heated. .................. ................................. ... line {Please read the precautions on the back before filling the nest page) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs-50-This paper scale is applicable to the Chinese National Standard (CNS) Grade 4 (210x297 mm) Economy A6 B6_ printed by the Employees ’Consumer Cooperative of the Central Standards Bureau of the Ministry of Education (49) It can be clearly seen from Tables 15 and 17 that the heat sink made by the method of the present invention will not cause the heat sink to collapse The problem is that it has high strength after heating and is also excellent in thermal conductivity. Example 3 A brazing material having the alloy composition shown in Table 18 to Table 21 and a core material were combined to produce a brazing sheet with a thickness of 0.4 mm in a general method. The ratio of the lightning plating on both sides of the hard solder Η is 10% ^ These hard solder pieces will be heated under nitrogen under the conditions shown in Table 22 and Table 23. After heating these brazing alloys H, a tensile test and a corrosion resistance test are performed. In the corrosion resistance test, only the middle part of the surface of the brazing material is exposed, and the other surfaces are sealed, and then a 360-hour CA S S (J I S Η 8 6 8 1) moisture test is carried out to check the location of the pitting. These results are listed in Tables 22 and 23. .................................................. .................................. Pretend .............. ......... T: i: line < Please read the precautions on the back and fill this page) -51- ) 5. Description of the invention (50) A6 B6

經濟部中央標準局員工消費合作杜印M S t-o *——» Ξ; CO ►— CD 00 -3 cn 〇} CO K) m m 阄 4p 交 ►—· c=> C£3 »—· c=> I . t—ί ·—-» G=* ·—» *-— cjn % *—* G> cn ►-·· 澈 荖 φ w 3 *«—N hfnlt Pp . _. 0\〇 s— 令 CO C=» tO c_n C^9 c=& CO C_T* C^O €=3 σ> o c-o. ed r<o c_n ►—» trt —4 1-^ c*o c--o o P 爻 ro c-n 1 1~1 1 <z=> ΓΌ CXI c_n ΓΟ c_n t—· c-n tsi 口 1 1 1 CT3 c=> ►—* cr> c=> c-n 1 1 1 1 1 1 ►—H 口 1 1 1 <=> CZ3 CO cz> C=3 c_n 1 1 cn P ° o ΓΌ era c^o <=> <Ln o <=> C_»1 cz> CO c=> •η a> Ϊ5 $ 书 薄 _ •二 > cn ♦—· 菸 c- □> 3 舜 llmll ρΠφ w o\〇 = <=9 to 匚 二 % I 1: «=> o c = - »—* = S 口 1 •CT3 *—^ 1 1 era CO era 1 <=» era 1 1 1 1 1 1 1 oq 1 1 1 cr» > - · crj 1 1 1 1 1 1 1 1 1 1 o ~t C3> c-n 1 1 1 c=> c=> 1 1 1 1 1 1 1 1 1 era ►—· CJ 1 N) M 1 i <=» CJ1 <r=> CZ3 cz.z> wZP ί: 、' CT3 or·» crj cr.:> C I 1 H 1 j d .- 1 丨 1 'y C > ' .'·· ‘ ^ ·' <iS> ϊ: l 二 ο 二 :V i -; 卡i 赛 _ i · > 她18 .................................................装..............................#r(請先閱讀背面之注意事項再瑱寫本页) 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公蹵) 295604MS to * —— »Ξ; CO ►— CD 00 -3 cn 〇} CO K) mm 阄 4p delivery ►— · c = > C £ 3» — · c = > I. t—ί · —- »G = * · —» * -— cjn% * — * G > cn ►- ·· Che 荖 φ w 3 * «— N hfnlt Pp. _. 0 \ 〇s — Let CO C = »tO c_n C ^ 9 c = & CO C_T * C ^ O € = 3 σ > o co. Ed r < o c_n ►—» trt —4 1- ^ c * o c--oo P 爻 ro cn 1 1 ~ 1 1 < z = > ΓΌ CXI c_n ΓΟ c_n t-- cn tsi port 1 1 1 CT3 c = > ►-* cr > c = > cn 1 1 1 1 1 1 ►—H port 1 1 1 < = > CZ3 CO cz > C = 3 c_n 1 1 cn P ° o ΓΌ era c ^ o < = > < Ln o < = > C_ »1 cz > CO c = > • η a > Ϊ5 $ Book _ • Two > cn ♦ — · 烟 c- □ > 3 Shunllmll ρΠφ wo \ 〇 = < = 9 to 匚 二% I 1: «= > oc =-»— * = S port 1 • CT3 * — ^ 1 1 era CO era 1 < =» era 1 1 1 1 1 1 1 oq 1 1 1 cr »>-· crj 1 1 1 1 1 1 1 1 1 1 1 o ~ t C3 > cn 1 1 1 c = > c = > 1 1 1 1 1 1 1 1 1 era ►— · CJ 1 N) M 1 i < = »CJ1 < r = > CZ3 cz.z > wZP ί:, 'CT3 or ·» crj cr.:> CI 1 H 1 jd .- 1 丨 1 'y C >'. '·' ^ · '≪ iS > ϊ: l two ο two: V i-; card i 赛 _ i · > her 18 .... ....................................... Pretend ... .......................... # r (please read the precautions on the back before writing this page) CNS) A 4 specifications (210x297 male) 295604

6 B 五、發明説明(51) 經濟部中央標準局員工消費合作杜印製6 B V. Description of Invention (51) Printed by the Consumer Cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs

11.5 11.0 1. 5 2. 5 4.5 » ii. ii l-i h 问 iL ii M li 22 1L 011.5 11.0 1. 5 2. 5 4.5 »ii. Ii l-i h ask iL ii M li 22 1L 0

S 0 19 2.0 2_ 5 0 4. 0 2. 5 0. 01 0.2S 0 19 2.0 2_ 5 0 4. 0 2. 5 0. 01 0.2

A. 2 Ί*. U 0100 10 0·〇〇 0」 L 0 u 1. 9 1. 8 i.- 1· 5 L 3 0. 10 0. 15 0. 13A. 2 Ί *. U 0100 10 0 · 〇〇 0 "L 0 u 1. 9 1. 8 i.- 1 · 5 L 3 0. 10 0. 15 0. 13

Z S η F e A 1 菊¾¾筚π>ιφ3 薛铒(_ t %) (請先閱讀背面之注意事項再填寫本頁) •裝· 1. 5 0. Ϊ ill 1. 2 l. 2 U 1. 1 1. 50」 1. 3 1. 1 0. 15 0. 15 0·〇〇 U 0 .一 — 、.s·* U) *-♦· 〇 C ! Mn Mg C r Zr Ti Ni F e 核心材料合金的組成(重量%) > -線. 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公犛) 五、發明説明(52: A6B6 經濟部中央標準局員工消費合 細紫猶 ct- 〇〇 5 —a —a ~4 cn CO σ> oo CT* C7> «=n cn cr> m §E •Hv % CO 〇〇 »—»· Γ° C43 〇〇 CT* ►—» »—· esa t—» Ps» c=d <L〇 OO CT> »— ⑺ »—·· 1 1 CO <rr> CT3 <Ln C--3 £=3 c=» e-o era CO c=> era o cn ro cr> c=> t-o o c 1 1 〇〇 C=> 4=9 CO oo 1 era c^> CO 1 CS) 口 1 1 1 1 1 1 1 1 1 *—< 1 1 1 I 1 1 1 1 1 1 cn 口 夂 !: ° «=· era c_n ° G» o^» cr> ·= c=> 0*0 •n 〇) $ *— •Si· in > t—< : 匚 »*-» <L^> OO eu» C=3 »—· 1~» c=» -a o oo ⑺ —· Ζ I i =5 CO OO OO CD •-~» oo ►«-* c-n €=» Oo 〇 c $ 二 = c=> ° 口 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 〇q 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 〇 卜t 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 INI <ζ=> •-* oo era 1 ,— CJO £ZL> 〇 '1 c=> CTJ CTJ V 二 C J 1 1 H 1 1 1 1 f 1 1 1 1 1 1 1 1 1 I - 1 ..-ϊ^ 、、 5 : 5 :: 、.r j Cl 1 s v_n-> Ί ..」平衡僵I 勹-】 (D > 阄碥冰阄^茸龙卟睁^皞玛<sl:"効^其龙0>除迅晬妈(^_%> 谢21 (請先閱讀背面之注意事項再瑱寫本页) •装. •訂...... _線· -54- t適用中國國家標準(CNS)甲4規格(210x297公势) A6 B6 經濟部中央標準局員工消費合作杜印製 3 s m cr> CO cr* cn cr> €£» CXI oo cn —>a CJ1 era CJ1 Cjri C^I 43k. c-n Ca9 tn CO CXI K-ri £ s; c-n ·«·» s m 紫 硬焊片 G> 1-* CZ3 55 令 c=> (/) ·—>. 硬焊材料合金的組成(重量%) ro c-n 二 =¾ CO G> CO c-n CO c=s o r-·» Qj-% 〇 c ΓΌ 二 = CO tut 1 »——* CS3 0. 01 1 1 1 1 1 1 1 1 1 1 1 0. 01 <=» <=> CJ% 0. 03 1 »—» 1 1 1 1 1 o o cn c=» ° $ era CO TJ 〇> i > = <=» 〇〇 ·= = c~> = = i; ⑺ 核心材料合金的組成(重量%) C3 —~a G» OO 1-^ CO 〇» CO CO ►—» CJ·» »-— 〇 c <=> Ca» «=> «Τ» c=> CT* CZ> <=> OO » » ►—» oo 二 二 Mn i 1 1 1 1 1 c=> CO CZ> 1 1 1 ez> c^o C=3 1—1 c-n 1 1 cr> *-—· C=3 1 1 ! s OQ 1 1 1 1 1 ^z> c=> oo 1 1 1 1 o » - c=> 1 1 1 <=» C_/l 1 1 1 〇 I 1 1 1 «=> dJl 1 1 1 1 1 CT3 cr> cz> CJ1 CZa *—» CZ3 1 1 1 i 1 1 1 N *~\ i c=> -JZ3 1 1 1 1 cz^> CJ 1 0. 03 0. 01 CZ3 C_/ 1 1 cr> 卜一 <=3 | 0. 02 cz^> cz^> C > 1 1 «l .j l i: CZ.J H 1 ! 1 - _-w 1 s-.Z > CJ 1 1 : 1 czr> c^> 1 erzzi <..> » 1 wTT> 1 CLa '< C=J cru <^> l-·。 1 crr.> ~ -Cl 1 ν ' J 1 1 t :'* 1 1 :— :s平衡量 .......1 X r n <l> > .................................................¾...............................ίτ..... ......................sf (請先聞讀计面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公犛) A6 B6 經濟部中央標準局員工消費合作杜印製 硬焊片 編號 硬焊的加 熱條件 (X扮鐘) 臟強度 MPa 孔蝕的最 大深度 (細 硬焊片 編號 硬焊的加 熱條件 X (X扮鐘) 抗張強度 MFa 孔蝕的最 大深度 (齡) 1 575 210 80 29 580 190 80 2 580 220 // 30 " 200 " 3 // // // 31 // 190 90 4 // // 70 32 575 // 70 5 // // 60 33 580 170 80 6 // " 100 3< // 190 " 1 // // ff 35 // // 90 8 // // 80 36 " rf 80 9 // ft " 37 tf ft 90 10 // // // 38 // rt 70 11 // " 100 39 ft // 12 // " // 發 <0 " // 80 13 // rf 90 41 " // " Η ff // " 明 <2 " // 90 15 // // 80 實 <3 " // 70 16 " " // 例 // " 90 17 " // " 45 // // 80 18 // 200 // 46 " ft // 19 // 170 // 47 // // 70 20 // " // 48 " " ” 21 ff // // 49 // tf // 22 ff // " 50 " // // 23 575 190 // 51 // r/ tf // 220 ff 52 " // // 25 // // // 53 " // ff 26 " 230 " 54 " 160 " 21 // // ff 55 ft 190 // 28 580 180 ff 56 " 160 // -5ϋ~ (請先《讀背面之注意事項再填寫本页) 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公發) 205604 A6 B6 M.' (55) 硬焊片 編號 硬焊的加 熱條件 (xSm) 抗張強度 MPa 孔蝕的最 人深度 (齡) 硬焊片 編號 硬焊的加 熱條件 V (X吩鐘} 扼長強度 孔蝕的最 大深度 (齡) 57 580 170 70 72 由於在滾軋時破對而無 58 " 160 // 法製得 發 59 " // // 73 575 由於熔解而無法 60 tf // 90 測量 明 61 // // // 比 74 // 由於熔解而無注1 宵 62 // " 70 測量 例 63 // " // 較 75 580 220 穿孔 575 // 80 實 16 600 由於熔解而無法 65 // 170 90 測量 66 // 200 // 例 77 由於熔解而無法 67 // 由於熔解而無法 測量 測量: 78 由於在滾軋時破裂而無 比 68 // 由於熔解而無法 法製得 較 測量 79 600 130 120 69 580 220 穿孔 1守 統 實 70 600 由於熔解而無法 實 例 80 // 160 産生泡訑 例 測量 71 600 由於熔解而無法 測量_ (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作杜印製 -o7- 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公釐) A6 B6 經濟部中央標準局員工消費合作社印製 乓1>發明説明(56 ) 由表22和23中可明顯的看出,本發明宵例的硬焊片在 硬焊時不會熔解,具有高強度,且在耐蝕性方面也很優 異。 然而,在比較實例67、68、73和74中,其核心材料超 出本發明的範圍,即使是在575 °C下進行硬焊時,它仍 會開始熔解。在比較實例6 9和7 5中,其硬焊材料並不含 鋅、絪和錫,使得其耐蝕性下降。在比較實例70、71、 7 6和7 7中,其硬焊材料超出了本發明的範圍,因為硬焊 材料不會在585 °C (或更低)的溫度下熔解,因此在6G0°C 下進行加熱,但是此時核心材料卻開始熔解了。在比較 實例7 2和7 8中,其硬焊材料中的銅和鋅之使用量大於本 發明所列之範圍,在滾軋時會發生破裂的現象,而使得 其無法製成硬焊Η。 在傳統實例79中,其強度比本發明實例之硬焊片為差 β在傳統實例80中,其在核心材料中含有很多的銅,因 此耐蝕性不佳。 例4 將含有鋁合金的散熱Η裸材Α和Β,以及包含硬焊Η 之平板材料a到c (其具有如表24所示之合金組成)接合在 一起,以組装成如圖2所示之多層型蒸發器。散熱Η材 料為0 . 0 8毫米厚的裸材,並且平板材料為0 . 3 5毫米厚的 硬焊Η (其傜在核心材料兩侧_ h 1 Π %的硬焊材料)^ 在組裝熱交換器時,將含有3%絶型肋熔劑和氟化鉀 -5 8 - 裝......................訂...................線 {請先閲讀背面之注意事項再填窝本頁) 本紙張尺度逋用中國國家標準(CNS)甲4規格(210X297公釐) 散熱Η材料平板材料 經濟部中央標準局員工消费合作社印製 A6 B6 五’ 、發明説明( 57 ) 型 肋 熔 劑 之 混 合 物 之 助 溶 劑 液 體 (濃度為1 0 % 塗 佈 上 去 1 並 在 表 2 5所 示 的 硬 焊 條 件 下 > 於 氡 氣 中 加 熱 〇 材 料 的 組 合 方 式 及 加 熱 條 件 皆 列 於 表 2 5 中 〇 這 樣 所 獲 得 的 熱 交 換 器 » 將 Μ 由 外 表 的 觀 察 來 研 究 散 熱 Η 和 管 子 的 mil 朋 潰 狀 態 及 m 角 焊 缝 的 形 成 〇 此 外 9 對 於 已 硬 焊 好 的 熱 交 換 器 » 將 做 導 熱 度 的 研 究 〇 導 熱 度 像 依 J I S D I 6 1 8 (用 於 汽 車 之 冷 暖 氣 體 的 Cfli/ 試 方 法 )之規定來 測 量 > 並 且 分 別 以 相 對 於 傳 統 方 法 所 製 之 熱 交 換 器 的 熱 效 率 的 改 善 百 分 hb 來 表 示 〇 此 外 » 管 材 在 經 過 硬 焊 加 熱 之 後 所 得 之 張 力 測 試 的 結 果 也 列 於 表 2 5 中 〇 表 2 4 .裝 (請先閲讀背面之注意事項再填窝本頁) 编硬ί旱材料合金的組成 < 重量核心材料合金的組成 <重量*> 份,J I'}- u η i 一 ο 劑:劑I彳 焊焊pr 硬硬 2. 無無-? nu. 材 裸 量. 衡 平 ο_ο nw· J4· Λυ· ΛΙΟ ο·ZS η F e A 1 菊 ¾¾ 譚 π> ιφ3 Xue Er (_ t%) (please read the precautions on the back before filling this page) • Install · 1. 5 0. Ϊ ill 1. 2 l. 2 U 1 . 1 1. 50 ″ 1. 3 1. 1 0. 15 0. 15 0 · 〇〇U 0. 一 —, .s · * U) *-♦ · 〇C! Mn Mg C r Zr Ti Ni F e The composition of the core material alloy (% by weight) > -line. This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210x297 g) 5. Invention description (52: A6B6 Employee consumption of the Central Standards Bureau of the Ministry of Economic Affairs Ct- 〇〇5 —a —a ~ 4 cn CO σ > oo CT * C7 > «= n cn cr > m §E • Hv% CO 〇〇» — »· Γ ° C43 〇〇CT * ►—» »— · Esa t—» Ps »c = d < LOOOO CT >» — ⑺ »— ·· 1 1 CO < rr > CT3 < Ln C--3 £ = 3 c =» eo era CO c = > era o cn ro cr > c = > to oc 1 1 〇〇C = > 4 = 9 CO oo 1 era c ^ > CO 1 CS) port 1 1 1 1 1 1 1 1 1 1 * — ≪ 1 1 1 I 1 1 1 1 1 1 cn mouth !: ° «= · era c_n ° G» o ^ »cr > · = c = > 0 * 0 • n 〇) $ * — • Si · in > t— <: 匚 »**» < L ^ > OO eu »C = 3» — · 1 ~ »c =» -ao oo ⑺ — · ZO I i = 5 CO OO OO CD •-~ »oo ►«-* cn € = »Oo 〇c $ 2 = c => ° Port 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 〇q 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 〇 Bu t 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 INI < ζ = > •-* oo era 1, — CJO £ ZL > 〇'1 c = > CTJ CTJ V 2 CJ 1 1 H 1 1 1 1 f 1 1 1 1 1 1 1 1 1 1 I-1 ..- ϊ ^,, 5: 5 ::,. rj Cl 1 s v_n- > Ί .. "Balance stiffness I 勹-] (D > 阄 碥 冰 阄 ^ Rong Long Por open ^ 皞 玛 < sl: " Effect ^ Qi Long 0 > Except Xunmo Mom (^ _% > Xie 21 (please read the precautions on the back before writing this page) • Install. • Order ... _ 线 · -54- t applies to China National Standard (CNS) A4 specifications (210x297 public power) A6 B6 Central China Bureau of Economic Affairs Employee consumption cooperation du printing 3 sm cr > CO cr * cn cr > € £ »CXI oo cn —> a CJ1 era CJ1 Cjri C ^ I 43k. Cn Ca9 tn CO CXI K-ri £ s; cn · · »Sm purple brazing sheet G > 1- * CZ3 55 let c = > (/) · — >. composition of the brazing material alloy (wt%) ro cn two = ¾ CO G > CO cn CO c = so r- · »Qj-% 〇c ΓΌ 2 = CO tut 1» —— * CS3 0. 01 1 1 1 1 1 1 1 1 1 1 1 1 0. 01 < = »< = > CJ% 0 . 03 1 »—» 1 1 1 1 1 oo cn c = »° $ era CO TJ 〇 > i > = < =» 〇〇 · = = c ~ > = = i; ⑺ core material alloy Composition (% by weight) C3 — ~ a G »OO 1- ^ CO 〇» CO CO ►— »CJ ·» »-— 〇c < = > Ca» «= >« Τ »c = > CT * CZ > < = > OO »» ►— »oo two two Mn i 1 1 1 1 1 1 c = > CO CZ > 1 1 1 ez > c ^ o C = 3 1—1 cn 1 1 cr > * -— · C = 3 1 1! S OQ 1 1 1 1 1 ^ z > c = > oo 1 1 1 1 o »-c = > 1 1 1 < =» C_ / l 1 1 1 〇 I 1 1 1 «= > dJl 1 1 1 1 1 CT3 cr > cz > CJ1 CZa * —» CZ3 1 1 1 i 1 1 1 N * ~ \ ic = > -JZ3 1 1 1 1 cz ^ > CJ 1 0. 03 0. 01 CZ3 C_ / 1 1 cr > Bu Yi < = 3 | 0. 02 cz ^ > cz ^ > C > 1 1 «l .jli: CZ. JH 1! 1-_-w 1 s-.Z > CJ 1 1: 1 czr > c ^ > 1 erzzi < .. > »1 wTT > 1 CLa '< C = J cru < ^ > l- ·. 1 crr. ≫ ~ -Cl 1 ν 'J 1 1 t:' * 1 1:-: s balance ....... 1 X rn < l > > ........ ................................. ¾ ........ ...................... ίτ ..... ..................... .sf (please read the precautions before you fill in this page) This paper size is applicable to China National Standard (CNS) A 4 specifications (210x297 g) A6 B6 Employee consumption cooperation du printing by the Central Bureau of Standards of the Ministry of Economic Affairs The heating condition of the plate number brazing (X played bell) Dirty strength MPa The maximum depth of pitting corrosion (The heating condition of the fine brazing plate number brazing X (X played bell) The maximum strength of the tensile strength MFa pitting corrosion (age) 1 575 210 80 29 580 190 80 2 580 220 // 30 " 200 " 3 // // // 31 // 190 90 4 // // 70 32 575 // 70 5 // // 60 33 580 170 80 6 // " 100 3 < // 190 " 1 // // ff 35 // // 90 8 // // 80 36 " rf 80 9 // ft " 37 tf ft 90 10 // // // 38 // rt 70 11 // " 100 39 ft // 12 // " // Hair < 0 " // 80 13 // rf 90 41 " // " Η ff / / " Ming < 2 " // 90 15 // // 80 Actual < 3 " // 70 16 " " // Example // " 90 17 " // " 45 // // 80 18 // 200 // 46 " ft // 19 // 170 // 47 // // 70 20 // " // 48 " " ”21 ff // // 49 // tf // 22 ff // " 50 " // // 23 575 190 // 51 // r / tf // 220 ff 52 " // // 25 // // // 53 " // ff 26 " 230 " 54 " 160 " 21 // // ff 55 ft 190 // 28 580 180 ff 56 " 160 // -5ϋ ~ (please read "Precautions on the back side and fill in this page first] This paper size is applicable China National Standards (CNS) Grade 4 specifications (210x297 public) 205604 A6 B6 M. '(55) Brazing pad number Heating conditions for brazing (xSm) Tensile strength MPa The most human depth of pitting (age) Brazing The heating condition of the chip number brazing V (X phen clock) The maximum depth of pitting strength pitting corrosion (age) 57 580 170 70 72 Because it is broken during rolling, there is no 58 " 160 // Law made by 59 " // // 73 575 60 tf is not possible due to melting // 90 is measured 61 // // // than 74 // No note due to melting 1 Siu 62 // " 70 Measurement example 63 // " // Compared to 75 580 220 Perforation 575 // 80 Actual 16 600 Unable to 65 due to melting 65 // 170 90 Measuring 66 // 200 // Example 77 Cannot be measured due to melting 67 // Cannot be measured due to melting: 78 Incomparable due to cracking during rolling 68 // Cannot be measured due to melting 79 600 130 120 69 580 220 Perforation 1 Actual 70 600 Cannot be instanced due to melting 80 // 160 Examples of blemishes produced 71 600 Cannot be measured due to melting_ (Please read the notes on the back before filling this page) Employee consumption cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs Du Printed- o7- This paper scale is applicable to China National Standard (CNS) A4 specifications (210x297 mm) A6 B6 Printed table tennis 1> Invention Description (56) by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. It can be clearly seen from Tables 22 and 23 It is found that the brazing sheet of the present invention does not melt during brazing, has high strength, and is also excellent in corrosion resistance. However, in Comparative Examples 67, 68, 73, and 74, the core material is beyond the scope of the present invention, and even when brazing is performed at 575 ° C, it will start to melt. In Comparative Examples 6.9 and 7.5, the brazing material does not contain zinc, condensate, and tin, making its corrosion resistance lower. In Comparative Examples 70, 71, 76, and 77, the brazing material is beyond the scope of the present invention, because the brazing material does not melt at a temperature of 585 ° C (or lower), and therefore at 6G0 ° C Under the heating, but at this time the core material began to melt. In Comparative Examples 72 and 78, the amount of copper and zinc in the brazing material is greater than the range listed in the present invention, and the phenomenon of cracking occurs during rolling, making it impossible to make brazing H. In the conventional example 79, its strength is inferior to that of the brazed pad of the example of the present invention. In the conventional example 80, it contains a lot of copper in the core material, so the corrosion resistance is not good. Example 4 Heat dissipating H bare materials A and B containing aluminum alloy, and flat materials a to c containing brazing H (which have the alloy composition shown in Table 24) are joined together to assemble as shown in FIG. 2 The multi-layer evaporator shown. The heat dissipation H material is 0.08 mm thick bare material, and the flat plate material is 0.3 5 mm thick brazed H (whose on both sides of the core material _ h 1 Π% of the brazed material) ^ in the assembly heat When the exchanger, it will contain 3% extruded rib flux and potassium fluoride-5 8-Pack ...................... Order ... ............. Line {Please read the precautions on the back before filling the nest page) This paper uses the Chinese National Standard (CNS) A 4 specifications (210X297 mm) heat dissipation material A6 B6 5 'printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs of the Ministry of Economic Affairs, the invention description (57), the cosolvent liquid of the mixture of rib fluxes (concentration is 10%, coated with 1 and the hardness shown in Table 25 Under welding conditions> Heating in radon gas. The combination of the materials and the heating conditions are listed in Table 25. The heat exchanger obtained in this way »The heat dissipation Η and the mils of the tube are studied from the external observation State and formation of m fillet welds. In addition 9 for brazed Heat exchanger »The thermal conductivity will be studied. The thermal conductivity will be measured in accordance with JISDI 6 1 8 (Cfli / Test Method for Automobile Air-Conditioning and Heating Body) > The improvement of the heat efficiency of the exchanger is expressed as a percentage of hb. In addition »the results of the tensile test of the pipe after being brazed and heated are also listed in Table 25. Table 24. Installation (please read the precautions on the back before filling (This page) The composition of the hard alloy of the dry material < the composition of the alloy of the weight core material < weight * > parts, J I '}-u η i ο Agent: Agent I welding pr hard and hard 2. Nothing-? Nu. Bare amount of material. Equilibrium ο_ο nw · J4 · Λυ · ΛΙΟ ο ·

o 1米 爲材 侧焊 兩硬 在灼 il·'/ I /! I -6- 用 適 度 尺 張 紙 本 準 標 家 胁o 1 meter as the material, side welding, two hard, il · '/ I /!

釐 公 7 9 2 XCentimeters 7 9 2 X

6 6 A B 五、發明説明(58 ) 表25 编 號 組合方式 硬焊的加 熱溫度 V f_X5分鐘) 産生 崩潰 的位 置 硬 焊 性 熱效率 硬焊加熱 後管子的 抗張強度 MPa 散熱片 材料 管材管集 箱材料 發明實例 ① A a 580 無 良好 比⑤增加0.5%以上 190 ② B Μ " (1 " 比«加2.5:!:以上 II ③ A b ” " tf 比⑤增加0.53:以上 160 ④ B " ” ” " 比⑤增加2.52以上 " t成實例 ⑤ A c 600 U ” 標準 130 涛統實例 ⑥ B Μ If 散熱Η 11 比⑤減少2.0¾以上 - .................................................. ^.......................玎;..iiii {請先閲讀背面之注意事項再填窝本頁) 經濟部中央標準局員工消費合作社印製 -60- 本紙張尺度適用t國國家標準(CNS)fM規格(210X297公釐) A6 B6 五、發明説明(59 ) 由表2 5可很明顯的看出,以本發明之方法所製得的熱 交換器,不會引起散熱片崩潰的問題,在加熱之後具有 高強度,並且在導熱度方面也很優異。 例5 製造具有表26到29中所示之合金組成的硬焊片散熱片 材料(其傜在核心材料的兩側鍍上硬焊材料)。換句話說 ,這些硬焊Η散熱Η為0.1〗毫米厚的H14精煉物(傜在核 心材料的兩側各鍍上1 0 %的硬焊材料)。同時,這些编 號1到6 7的硬焊Η散熱Η材料,將在表3 0和3 1所示的條 件下,於氮氣中加熱,以進行下垂測試和張力測試。並 且將這些結果列於表3 0和3 1中。 下垂測試傜在50毫米的突出長度下進行的。 此外,在張力潮試中,硬焊材料存在於硬焊Η散熱Η 之表面上,並且在硬焊加熱之後,很難精確的決定散熱 Η的截而積,因此,即使可測量出強度,但是可信度不 夠。因此,對於強度的數值,在表26到29的最右邊一橱 中,列有0 . 0 6毫米厚之散熱Η裸材(其合金組成與構成 這些硬焊片散熱Η材料的核心材料之合金組成相同)的 強度潮最值。此外,已知硬焊片散熱Η的強度與含有相 同核心材料之組成的散熱片裸材之強度的趨勢相同。 I.......................ΤΓ....................._ (請先閲讀背面之注意事項再填窝本頁) 經濟部中央標準局員工消費合作社印製 -61- 本紙張尺度適用中國國家標準(CNS)甲4規格(210X297公釐) 五 A6B6 經濟部中央標準局員工消費合作杜印製 S η IN3 ·—* <£> 00 ① CJ1 CO to I—1 ;a 1—^ >·—» C=» ·—* c^n «Χ9 «Τ» C£> c_n ►— C9 «-η » C3 C^l 1-^ cr» C/3 淘 Π> 睁 S 铒 limit (ππρ _ 〇\〇 c=> <rr> 5ί CNA CXI Ca9 <_Γ» CO σ% <=> Cn9 QJ~X Ca» <=» ►—» 〇 二 »—» ro CXI 二 c-o c-n O c 1 e^> *~* 1 二 二 •te· 爻 CO «Π CO Cjr\ Jt^~ (S3 0 ο ο •—a d> G» CO 1 1 1 1 1 1 1 1 1 1 <=* C=3 t-o 1 i 1 1 1 1—H 口 1 1 ο C=3 CO <=3 〇 >\n 1 1 1 1 1 1 1 1 ! 1 ω 口 Ϊ: 5: ο ♦—- CO 4=9 CO o »—* c=> Jim. % : <=> ° G> CO TJ α> 卡i n M > ►—* 匚 $ *~~» 二 σ> »-·· c? 萆 Φ W 3 薛 limit ftnrn _ o\〇 »w<» % = = = Ο) ϊ: ° c=s <=> = ° era Ο C 令 - ►—· % % z S 口 二 C^3 : 1~~* 1 1 1 Ν 1 1 1 1 1 1 ca «=> 〇〇 ~*r> c=» C-/ 1 *—4 0 1 1 1 1 1 1 CT3 CT3 ΓΌ c=r> c=> CO cn 1 1 crui 4^ 1 1 1 0Q 1 1 1 l X 1 Ν 1 1 1 1 1 Ο •-1 ; CZ> uri «£» cr> cr> 1 1 1 l ί'、] - Η 4 卡1 I. > 0 26 (請先閱讀背面之注意事項再填寫本百) 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公烙) iiNl iiii ΙΟ 4· 0 2.0 02 0· 1 Ι. 4 0. 7 0」 0. 01 經濟部中央標f-局員工消費合作杜印製 VJ 五6 6 AB V. Description of invention (58) Table 25 Numbered combination heating temperature for brazing V f_X5 minutes) The position where the crash occurred Brazing resistance Thermal efficiency The tensile strength of the tube after brazing heating MPa Heat sink material Pipe header Examples of material invention ① A a 580 No good ratio ⑤ increase by more than 0.5% 190 ② B Μ " (1 " than «Plus 2.5:!: Above II ③ A b” " tf increase by 0.53 than ⑤: above 160 ④ B " ”” " Increased by more than 2.52 than ⑤ " t into an example ⑤ A c 600 U ”Standard 130 Taotong example ⑥ B Μ If heat dissipation Η 11 decreased by more than 2.0¾ than ⑤-......... ....................................... ^ ........ ............... 玎; .. iiii (Please read the precautions on the back before filling the nest page) Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs-60- This paper size Applicable to the national standard of country t (CNS) fM specification (210X297mm) A6 B6 V. Description of invention (59) It can be clearly seen from Table 2 5 that the heat exchanger made by the method of the present invention will not The problem of causing the heat sink to collapse is caused by heating It has high strength and excellent thermal conductivity. Example 5 Fabrication of a brazed fin material having the alloy composition shown in Tables 26 to 29 (whose brazing material is plated on both sides of the core material). In other words, the heat dissipation of these brazing materials is 0.1 mm thick H14 refining material (won each side is coated with 10% brazing material on both sides of the core material). At the same time, these hard soldered heat dissipating H materials numbered 1 to 67 will be heated under nitrogen under the conditions shown in Tables 30 and 31 to perform sag test and tensile test. And these results are listed in Tables 30 and 31. The sagging test was carried out under a protruding length of 50 mm. In addition, in the tension tide test, the brazing material is present on the surface of the brazing H heat dissipation H, and it is difficult to accurately determine the cross-sectional product of the heat dissipation H after brazing heating. Credibility is not enough. Therefore, for the strength values, in the rightmost cabinet of Tables 26 to 29, 0.06 mm thick heat-dissipating Η bare material (the alloy composition and the alloy that constitutes the core material of these hard solder heat-dissipating Η materials are listed The composition is the same) the intensity tide is the most value. In addition, it is known that the strength of the heat dissipation H of the brazed fins is the same as the strength of the bare fins composed of the same core material. I ................. TΓ ........................_ (please first Read the precautions on the back and fill in the nest page) Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs-61- This paper scale is applicable to China National Standard (CNS) A4 specifications (210X297 mm). Consumer Cooperation Du Print S η IN3 · — * < £ > 00 ① CJ1 CO to I-1; a 1— ^ > · — »C =» · — * c ^ n «Χ9« Τ »C £ > c_n ►— C9 «-η» C3 C ^ l 1- ^ cr »C / 3 淘 Π > Open S erbium limit (ππρ _ 〇 \ 〇c = > < rr > 5ί CNA CXI Ca9 < _Γ »CO σ% < = > Cn9 QJ ~ X Ca» < = »►—» 〇 二 »—» ro CXI two co cn O c 1 e ^ > * ~ * 1 two two • te · 爻 CO «Π CO Cjr \ Jt ^ ~ (S3 0 ο ο • —a d > G» CO 1 1 1 1 1 1 1 1 1 1 1 < = * C = 3 to 1 i 1 1 1 1—H port 1 1 ο C = 3 CO < = 3 〇 > \ n 1 1 1 1 1 1 1 1 1! 1 ω port Ϊ: 5: ο —- CO 4 = 9 CO o »— * c => Jim.% : < = > ° G > CO TJ α > Card in M > ►— * 匚 $ * ~~ »Two σ >»-·· c? 萆 Φ W 3 Xue limit ftnrn _ o \ 〇 »w <»% = = = Ο) ϊ: ° c = s < = > = ° era Ο C order- ►— ·%% z S port 2 C ^ 3: 1 ~~ * 1 1 1 Ν 1 1 1 1 1 1 1 ca «= > 〇〇 ~ * r > c = »C- / 1 * —4 0 1 1 1 1 1 1 1 CT3 CT3 ΓΌ c = r > c = > CO cn 1 1 crui 4 ^ 1 1 1 0Q 1 1 1 l X 1 Ν 1 1 1 1 1 Ο • -1; CZ > uri «£» cr > cr > 1 1 1 l ί ',]-Η 4 card 1 I. > 0 26 (please read the precautions on the back before filling in this hundred) This paper The scale is applicable to the Chinese National Standard (CNS) Grade 4 (210x297 public brand) iiNl iiii ΙΟ 4 · 0 2.0 02 0 · 1 Ι. 4 0. 7 0 "0. 01 Central Standard f- Bureau of the Ministry of Economic Affairs-Industrial Consumer Consumption Cooperation Duin VJ Five

1¾ 2· 0 11!1¾ 2 · 0 11!

6 B ii Μii 1-7Γ 10.0 11· 0 1.0 3. 0 4. 06 B ii Μii 1-7Γ 10.0 11 · 0 1.0 3. 0 4. 0

3.0 二.C 1. 53.0 II.C 1. 5

U L 5 0. 2 0· 3U L 5 0. 2 0 · 3

M /、 0. 3 M 01· 1. 1 1.0 2· 0 L 5 0. 1M /, 0. 3 M 01 · 1. 1 1.0 2 · 0 L 5 0. 1

I 0.rI I C. u: 10. 2.5 1_ 0I 0.rI I C. u: 10. 2.5 1_ 0

•2 U 0. 2• 2 U 0.2

.0. 3 U 1. 5.0. 3 U 1. 5

Is 01 续 cn ►-*· 潑 口> 3 舜 limit Pp _ 〇\〇 〇 P tS 口 ►—Η Ρ cn P a> > cn ►—· 荖 π> 1Φ S 薛 铒 limh W Mu 〇\° >·_··« n> O C S P 03 0 ►—H 口 cr> OQ 〇 ΓΊ > m 27 (請先閲讀背面之注意事項再填寫本页) 本紙張尺度適用中國國家標準CCNS)甲4規格(2] Ο V297公修)- 五、發明説明(02 ) A6 B6 經濟部中央標準局員工消費合作社印^ S濰S斛 CXI c_n οο CJ、 CXI O'» CJ1 CJ1 CXI CXI CO CJ1 «-〇 CXI ex» •te· s; s; s: 散熱片1 材料1 编號 <=» t —— <=> c-n *—» C=3 10.5 ►—* c=> 55 ►—* c_n »—» cz> ►—· tn ►—» ►—» «=> *~—* c_n *—* c=> 10.5 ω 1—·· 硬焊材料合金的組成(重量%) Γ-Ο CJS SLT» r° c_n i: r° c,n $ c; e*o 二 r-o c>n t-— e-o CJl ο C r° c_n 令, r° c_n *K*~ CO c_r» 5: ΓΌ C-n CO CO C-n ISJ 口 1 1 1 1 1 1 1 1 1 1 c=> cs c^o 1 ►—t 0 1 1 1 1 1 1 1 1 1 ⑺ ° ° z = ezu cr> TJ n> ΪΪ $ 书— —_. : > ΟΟ CO 1» t—* CO ►—* oo *—» CO CO <rz> oo CO »—* Λ^— C*3 »—* »—· c_n cn 核心材料合金的組成(重量%) r- era cr> era. C-n c-o cs c--o era C=3 Ca> cz> -C»- » · <=» 1—» e-o era oo era CO . ° 〇> C=> C=P = <= = C=> z 二 二 : o c = •—‘ = »—* : s: P C-»3 CaS CJ1 cr> t~~* CJ1 C^-D <LJ » = CS5 0 era era OO era c=> fO era c=> 1 1 1 0. 02 CZT3 d> OO 0. Oi ►—H 0. 01 C=> o t—· 1 1 1 1 1 1 ! <Zj _- t_r\ C=J c=> 1 cn 口 1 1 1 1 1 ..-. 1 »—- I r-7) C-.J 1 I 1 i 1 i 1 1 1 1 ! 1 i: 1 1 、 -! - - 0. 15 0. 02 平衡ί 〇q X o • \ t 0 r 1 H > ! - ο 1 1 1 1 i i v'.T_^ 1 1 1 1 1 . 1 l — > ;. d C_ZJ c~; 1 1 1 1 1 1 < )1 (二· C~..i I 1 ! 1 1 i 1 1 1 〇n *. ~ j ! 1 1 1 i CT-- c> ! 1 ϊ; ...................-.................................................. I… …:…:町…{請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)甲4规格(210x297公釐) —C ^ — 五、發明説明(63 戔砷郭_ GT> cn C7> tn CO oo c=> A6 B6 σ> cr> co *~—· itIs 01 Continued cn ►- * · Pokou > 3 Shun limit Pp _ 〇 \ 〇〇P tS port ►—Η Ρ cn P a > > cn ►-- · 荖 π > 1Φ S 薛 铒 limh W Mu 〇 \ ° > · _ ·· «n > OCSP 03 0 ►—H port cr > OQ 〇ΓΊ > m 27 (please read the precautions on the back before filling in this page) This paper size is applicable to the Chinese national standard CCNS) A 4 Specification (2) Ο V297 public repair)-V. Description of invention (02) A6 B6 Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy ^ S Wei S 斛 CXI c_n οο CJ, CXI O '»CJ1 CJ1 CXI CXI CO CJ1«- 〇CXI ex »• te · s; s; s: heat sink 1 material 1 number < =» t —— < = > cn * — »C = 3 10.5 ►— * c = > 55 ►— * c_n »—» cz > ►— · tn ►— »►—» «= > * ~ — * c_n * — * c = > 10.5 ω 1— ·· Composition of the brazing material alloy (% by weight) Γ -Ο CJS SLT »r ° c_n i: r ° c, n $ c; e * o two ro c > n t-— eo CJl ο C r ° c_n order, r ° c_n * K * ~ CO c_r» 5: ΓΌ Cn CO CO Cn ISJ port 1 1 1 1 1 1 1 1 1 1 1 c = > cs c ^ o 1 ►—t 0 1 1 1 1 1 1 1 1 1 1 ⑺ ° ° z = ezu cr > TJ n > ΪΪ $ 书 — —_.: > ΟΟ CO 1 »t— * CO ► — * Oo * — »CO CO < rz > oo CO» — * Λ ^ — C * 3 »— *» — · c_n cn composition of core material alloy (% by weight) r- era cr > era. Cn co cs c--o era C = 3 Ca > cz > -C »-» · < = »1—» eo era oo era CO. ° 〇 > C = > C = P = < = = C = > z two two: oc = • — '= »— *: s: P C-» 3 CaS CJ1 cr > t ~~ * CJ1 C ^ -D < LJ »= CS5 0 era era OO era c = > fO era c = > 1 1 1 0. 02 CZT3 d > OO 0. Oi ►—H 0. 01 C = > ot— · 1 1 1 1 1 1! < Zj _- t_r \ C = J c => 1 cn port 1 1 1 1 1 ..-. 1 »—- I r-7) C-.J 1 I 1 i 1 i 1 1 1 1! 1 i: 1 1,-!--0 . 15 0. 02 Balance ί 〇q X o • \ t 0 r 1 H >!-Ο 1 1 1 1 ii v'.T_ ^ 1 1 1 1 1. 1 l — >;. D C_ZJ c ~ ; 1 1 1 1 1 1 <) 1 (2 · C ~ ..i I 1! 1 1 i 1 1 1 〇n *. ~ J! 1 1 1 i CT-- c >! 1 ϊ; ...................-.......... ....................................... I ... ...: ...: Machi ... {please Please read the precautions on the back and then fill out this page) This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210x297 mm) —C ^ — V. Description of the invention (63 戋 隋 郭 _ GT> cn C7> tn CO oo c = > A6 B6 σ > cr > co * ~ — · it

Is11 52 tests? m 紫獅 m29 5· 0 <=3Is11 52 tests? M Purple Lion m29 5 · 0 < = 3

CO OO 2.0 1.0 0. 3 0. 21.- 11. 0 I 2· 5 4· 0CO OO 2.0 1.0 0. 3 0. 21.- 11. 0 I 2 · 5 4 · 0

C u Z S η F e A 1 潑^^莖°>咏3薛诗(»_ %)C u Z S η F e A 1 Splash ^^ stem ° > Yong 3 Xue Shi (»_%)

Si 0. 2 0. 3 0. 2 0· 3 1.1 01 ο 1. 0 0. 1 Μι 1. 5 !. ΊSi 0. 2 0. 3 0. 2 0 · 3 1.1 01 ο 1. 0 0. 1 Μι 1. 5!. Ί

Z η I S n 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS)甲4規格(210X297公釐) —b5 — 琪亡过筚卟睁3薛舜(S4o\o) ...................................................................................^.......................ΤΓ.....................線 (請先閱讀背面之注意事項再填寫本頁)Z η IS n The standard paper printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs is applicable to the Chinese National Standard (CNS) Grade 4 (210X297 mm) —b5 — Qi Xun Guo Xun Peng 3 Xue Shun (S4o \ o). .................................................. ............................... ^ ................. ...... ΤΓ ..................... line (please read the precautions on the back before filling this page)

I I ϋ. Ξ 书ϊ A 1 A6B6 五、發明説明(分) 表 30 經濟部中央標"-局員工消費合作社印製 散熱片 材料 编號 硬焊的加 熱條件 (X玢鐘) 下垂量 散熱片 裸材 (毫米) 硬焊片 舦熱片 材料 妝熱片裸 材的抗張 強度 散熱片 材料 编號 硬焊的加 熱條件 (X扮鏵) 下垂量( 散熱片 裸材 畜米) 硬焊片 散熱片 材η 牧熟片裸 村的抗張 強苽 1 580 "C 6 if) Mi] 21 575 Τ: 5 Ί 160 2 // // 〃 〃 22 580 °c % // 3 〃 〃 〃 150 23 // 〃 " " i // ft " // 24 · ". 7 10 150 5 515 °c 5 8 // 25 〃 5 8 160 6 // " " // 26 〃 〃 // " 7 〃 〃 〃 // 27 〃 〃 " " 8 // 〃 t/ // 28 575 V " 1 〃 9 // // 1 160 發 29 〃 // // U0 10 580 V 〃 8 " 明 30 !/ // 〃 〃 11 /f // " " η 31 // 〃 tt 150 12 〃 〃 " " 例 32 580 π 〃 l 〃 13 57。 V 〃 1 // 33 〃 6 10 " U 580 V 〃 8 " 3^ 〃 1 12 170 15 // 〃 〃 〃 35 575 τ: 〃 10 〃 16 5T5 °c 〃 1 // 36 // 8 12 " Π 580 °c 〃 8 . " 37 580 τ: tf " 180 18 t/ t/ // 〃 38 〃 10 15 〃 19 〃 rt // tf 39 〃 〃 tt " 20 tt 〃 // // 美0 // 〃 // // (請先閱讀背面之注意事項再填寫本頁) .本紙張尺度適用中國國家標準(CNS)甲4規格(210X 297公釐) A6B6 五、發明説明(G) (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作杜印製 1 3 表 散熱Η 材料 编號 硬焊的 加熱條1 ft (X5分鐘) 下垂量1 敢熱片 裸材 毫米) 硬焊片 散熱片 材料 散熱片裸 村的抗張 強度 Μη 11 m x: 8 12 no 5 7 5 nC 6 10 // 580 V 8 12 // 〃 10 15 , 210 <5 〃 8 10 〃 Η // 10 15 " 斗7 // - 8 10 // 48 〃 10 15 〃 發 // 8 10 〃 明 50 " 10 15 180 實 Μ 8 10 " 例 52 // 10 15 160 53 " 8 10 ITO // 10 15 " 55 // 8 10 〃 56 // to 15 190 W n 9 12 〃 58 〃 10 no 59 575 °C 8 10 " 比較實例 傳統實例 散熱片 材料 编號 硬焊的 加熱條_ 件 (X玢鐘) '下垂量(奄米) π2熱^丨齡^ 深材i材料 故熱片裸 忖的抗張 強哎 «Μ 60 !)75 "C 由於熔解而無法測量 6t // 8 15 80 62 610 °C 由於熔解而無法測量 63 無法製成故熱片 64 600 V 由於熔解而無法測量 65 〃 由於熔声 库而無法測量 66 610 T: 25 35 110 67 〃 30 40 80 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公贽) 295604 a6 _ B6_ 马p發明説明() 雖然在傳統實例和比較實例中,没有一種散熱片材料 在抗張強度和下垂性質方面是優異的,但是所有本發明 的散熱片材料皆顯現出優異的數值。 例6 製造具有表32和33中所示之合金組成的硬焊片散熱片 材料(其傜在核心材料的兩側鍍上硬焊材料)。造些硬焊 Μ散熱Η的平板厚度為0.11毫米且為H14精煉物(傑在核 心材料的兩側各鍍上1 0 %的硬焊材料)。這些硬焊片散 熱片材料,將在表3 4所示的條件下,於氮氣中加熱,以 進行下垂測試Sift力潮試。同時,將這些結果列於表3 4中〇 下垂測試係在5 0毫米的突出長度下進行的。此外,在 張力測試中,與例5所述的方式類似,以具有相同核心 材料組成的裸材來取代硬焊Η散熱片,而施以相同的加 熱,來測量抗張強度。 裝......................."…線 {請先閲讀背面之注意事項再螇窝本頁) 經濟部中央標準局員工消費合作社印製 -68- 本紙張尺度適用中國Η家標準(CNS)甲4規格(210X297公釐) A6 B6 經濟部中央標準局員工消費合作社印製 五、發明説明(b7 ) 漥« S歟 CvP »- · ¥—* »—* CO 03 -<ϊ cn C71 CO ro H-* CXI 1—* ctp %.〇 G> C3> t—-· C=9 cr> <j〇 g—^ G> % *—* d> txs era es *—* G» *_〇 G> CI3 * c=> CO era <=> CO C=9 c_rt G9 c-o C3 ►—-· tr» o C*J> €=> cr> ►—» c_n c=> CO c=> η—· c_n o CO C=7 〇 •~~* C-r* G> CO ^^ c=> era c=> ο CaS <=> C=3 CO CZ3 o <=» <=> C^9 CT3 <=> O Cv9 〇 CZ3 *—» o CO <=> d> 夂 »~*· C=3 G> oo 〇 <=> 1 1 1 1 1 1 1 1 1 1 t 1 1 1 1 1 I 1 t—* CZ3 1 1 1 1 1 1 1 1 1 1 1 1 ! 1 1 1 1 1 1 czn »—-· c=> 1 1 夂 令 爻 5: ii 0. 20 WS| ο 〇〇 cr=> CT3 ro c=> c=> CO C-n ►—* c=> ro C-n c=o » « CT3 C~O cn <r> oo •~» <rr> oo cn> r-3 era ►—* cr> ro c-n v^3 ►—» ϊϊ cz> CO c-n o c%o C=9 ►—» CJ1 〇 〇 ►—* c_n cn> o —a c=> o t-o €=> era CO ert c=> a era CO cz> err» ΓΌ c-n <=> 0-3 era <=> c=> cr* <ΞΞ> »—*· <=» czs c_n c=> cr> CO c=> c=> t~~* c-n e=s. O- c-n czz> CO cz> CHS »—· tn G> CO era <=p t—· C-n CO c=> cr> »«♦ «>Γ* $ $ c=> » ¢.-/¾ ο C-O <=» *—* cj·» C=3 1 1 1* c=> c=> <zz> —J era <r=> da c_n era ►—» c=> c=> c=» *—· ez> o —4 era V ^=> <=> —-1 <=» o 1 1 1 i l era c=> C-ri 1 t i 1 1 1 1 i 1 1 1 1 1 1 c=> CZ3 \ I 1 1 1 1 1 1 1 i 1 1 1 1 1 1 1 1 1 1 1 1 1 i 1 <ζ=» 1 1 I <=> era 1 1 1 1 I 1 1 c=> 令《 1 1 c=> <=> 1 1 1 1 1 CT3 <=> 1 1 1 1 1 1 ►—* 1 1 I 1 1 — i t t CJ 1 1 1 . 1 1 1 1 1 i ·, > 1 e -) I 1 1 1 1 1 vLJ · 1—» CJ I tn> 1 1 CZ3 «1 » 1 CZJ 1 1 1 1 trn> f 1 i 1 1 t 1 cl .> 1 1 1 1 1 I 1 1II ϋ. Ξ book ϊ A 1 A6B6 V. Description of invention (minutes) Table 30 Central Standard of the Ministry of Economic Affairs " -Bureau Employee Consumer Cooperative printed heat sink material number Heating conditions for brazing (X 玢 钟) Sagging heat sink Bare material (mm) Brazed sheet slab heat sheet material Make-up sheet tensile strength of bare material Heat sink material number Heating condition of brazing (X plays a role) Sagging amount (heat sink bare material livestock meter) Brazed sheet heat dissipation Sheet η Zhang Qiang's anti-zhangqiang 1 in the nude village of Mushu 1 580 " C 6 if) Mi] 21 575 Τ: 5 Ί 160 2 // // 〃 〃 22 580 ° c% // 3 〃 〃 〃 150 23 / / 〃 " " i // ft " // 24 · ". 7 10 150 5 515 ° c 5 8 // 25 〃 5 8 160 6 // " " // 26 〃 〃 // " 7 〃 〃 〃 // 27 〃 〃 " " 8 // 〃 t / // 28 575 V " 1 〃 9 // // 1 160 hair 29 〃 // // U0 10 580 V 〃 8 " Ming 30! / // 〃 〃 11 / f // " " η 31 // 〃 tt 150 12 〃 〃 " " Example 32 580 π 〃 l 〃 13 57. V 〃 1 // 33 〃 6 10 " U 580 V 〃 8 " 3 ^ 〃 1 12 170 15 // 〃 〃 〃 35 575 τ: 〃 10 〃 16 5T5 ° c 〃 1 // 36 // 8 12 " Π 580 ° c 〃 8. " 37 580 τ: tf " 180 18 t / t / // 〃 38 〃 10 15 〃 19 〃 rt // tf 39 〃 〃 tt " 20 tt 〃 // / / 美 0 // 〃 // // (Please read the precautions on the back before filling in this page). The paper size is applicable to the Chinese National Standard (CNS) A 4 specifications (210X 297 mm) A6B6 V. Invention description (G ) (Please read the precautions on the back before filling in this page) Du Printed by the Consumer Cooperation of the Central Standards Bureau of the Ministry of Economic Affairs 1 3 Table Heat Dissipation Η Material Number Brazed Heating Bar 1 ft (X5 minutes) Sagging amount 1 Dare to heat sheet Bare material mm) Hard solder fins Heat sink material Tensile strength of heat sinks η 11 mx: 8 12 no 5 7 5 nC 6 10 // 580 V 8 12 // 〃 10 15, 210 < 5 〃 8 10 〃 Η // 10 15 " Bucket 7 //-8 10 // 48 〃 10 15 〃 hair // 8 10 〃 Ming 50 " 10 15 180 actual M 8 10 " Example 52 // 10 15 160 53 " 8 10 ITO // 10 15 " 55 // 8 10 〃 56 // to 15 190 W n 9 12 〃 58 〃 10 no 59 575 ° C 8 10 " Comparative example Traditional example Heat sink material number Brazing heating Article _ Pieces (X 玢 钟) 'Dripping amount (庄 米) π2 thermal ^ 丨 age ^ Deep material i material, so the thermal sheet is barely tensile resistant «Μ 60!) 75 " C cannot measure 6t due to melting / 8 15 80 62 610 ° C Cannot measure due to melting 63 Cannot be made so the hot plate 64 600 V Cannot measure due to melting 65 〃 Cannot measure due to the melting sound library 66 610 T: 25 35 110 67 〃 30 40 80 books The paper scale is applicable to the Chinese National Standard (CNS) A4 specifications (210x297 g) 295604 a6 _ B6_ Ma p Description of invention () Although in the traditional examples and comparative examples, none of the heat sink materials are in terms of tensile strength and sagging properties. Excellent, but all the fin materials of the present invention show excellent values. Example 6 A brazed fin material having the alloy composition shown in Tables 32 and 33 was manufactured (whose brazing material was plated on both sides of the core material). The thickness of the plates for making some brazed M heat dissipation H is 0.11 mm and is H14 refined (Jie plated 10% brazed material on both sides of the core material). These brazed pad heat sink materials will be heated under nitrogen under the conditions shown in Table 34 to perform the sag test Sift force tide test. At the same time, these results are listed in Table 34. The sagging test was performed at a protrusion length of 50 mm. In addition, in the tensile test, in a manner similar to that described in Example 5, a bare material having the same core material composition was used to replace the brazed H heat sink, and the same heating was applied to measure the tensile strength. Installed .................... "… line (please read the precautions on the back before stinging this page) Employee Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs Printed-68- This paper scale is applicable to China's H Family Standards (CNS) A4 specifications (210X297 mm) A6 B6 Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention Instructions (b7) 漥 «S 欤 CvP»- · ¥ — * »— * CO 03-< ϊ cn C71 CO ro H- * CXI 1— * ctp% .〇G > C3 > t—- · C = 9 cr > < j〇g— ^ G > % * — * D > txs era es * — * G »* _〇G > CI3 * c = > CO era < = > CO C = 9 c_rt G9 co C3 ►—- · tr» o C * J > € = > cr > ►— »c_n c = > CO c = > η— · c_n o CO C = 7 〇 • ~~ * Cr * G > CO ^^ c = > era c = > ο CaS < = > C = 3 CO CZ3 o < = »< = > C ^ 9 CT3 < = > O Cv9 〇CZ3 * —» o CO < = > d > 夂 »~ * · C = 3 G > oo 〇 < = > 1 1 1 1 1 1 1 1 1 1 1 t 1 1 1 1 1 I 1 t- * CZ3 1 1 1 1 1 1 1 1 1 1 1 1 1! 1 1 1 1 1 1 czn »—- · c = > 1 1 Xuan Ling Yao 5 : Ii 0. 20 WS | ο 〇〇cr = > CT3 ro c = > c = > CO Cn ►— * c = > ro Cn c = o »« CT3 C ~ O cn < r > oo • ~ »< rr > oo cn > r-3 era ►— * cr > ro cn v ^ 3 ►—» ϊϊ cz > CO cn oc% o C = 9 ►— »CJ1 〇〇►— * c_n cn > o —ac = > o to € = > era CO ert c = > a era CO cz > err »ΓΌ cn < = > 0-3 era < = > c = > cr * < ΞΞ > »— * · < =» czs c_n c = > cr > CO c = > c = > t ~~ * cn e = s. O- cn czz > CO cz > CHS »— · tn G > CO era < = pt— · Cn CO c = > cr > »« ♦ «> Γ * $ $ c = >» ¢ .- / ¾ ο CO < = »* — * cj ·» C = 3 1 1 1 * c = > c = > < zz > —J era < r = > da c_n era ►— »c = > c = > c =» * — · ez > o —4 era V ^ = > < = > —-1 < = »o 1 1 1 il era c = > C-ri 1 ti 1 1 1 1 i 1 1 1 1 1 1 c = > CZ3 \ I 1 1 1 1 1 1 1 i 1 1 1 1 1 1 1 1 1 1 1 1 1 1 i 1 < ζ = »1 1 I < = > era 1 1 1 1 I 1 1 c = > Let "1 1 c = > < = > 1 1 1 1 1 CT3 < = > 1 1 1 1 1 1 ►— * 1 1 I 1 1 — itt CJ 1 1 1. 1 1 1 1 1 i ·, > 1 e-) I 1 1 1 1 1 vLJ · 1— »CJ I tn > 1 1 CZ3« 1 »1 CZJ 1 1 1 1 trn > f 1 i 1 1 t 1 cl. ≫ 1 1 1 1 1 I 1 1

S i CS i C

ZnZn

In S η A 1In S η A 1

F 0F 0

MiMi

ZZ

In S nIn S n

MoqN A 1 m u> 闯猫其^0>^»降舜<»3; % >.MoqN A 1 m u > Chuang Maoqi ^ 0 > ^ »降顺 <»3;% >.

Mn'2t^:n&gt;^®^^〈w»*; ..................................................................................裝.......................玎.....................線 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)甲4規格(210X297公釐) b8 A6B6 經濟部中央標準局R工消費合作杜印$i s » s兢 〇〇 CO CO en Ca» cn CO CO CjA CO CO Ok&gt; CO CsUt &lt;£3 C^3 〇〇 ro c&gt;s &amp;&gt; tO cn tO !&gt;0 OJ CO t«sS 翳过球 G&gt; I—» o era c-ri ⑺ w« 阄 4S π&gt; 迅 m ? ίϋ _ rtP 〇&gt; m 玛 陆Jl f» 1 令 ro c-n G3 &lt;j〇 c=&gt; C9 CZZi C^O CJ-l o ο c I 1 c-o C=9 c=&gt; —~4 d=&gt; era CO C=3 &lt;=3 ϊϊ i: U^~ c=&gt; C=3 C^3 cr&gt; tN) a 1 cr&gt; »—» cz» 1 1 t—t P 1 1 1 1 1 cn cz&gt; €=3 era CO &lt;=3 〇 —J era c=&gt; CO i 勺 a&gt; &gt; c=&gt; ΓΌ c=&gt; »~»· CXI c=» i: c=s CO CT3 &lt;=s era 〇〇 〇 t—» c=&gt; era oo d&gt; in -9 CO C=3 $ e=a —1 «=&gt; r-a ς_^ a&gt; era ς&gt;η c=&gt; G9 CJ1 CT3 —~a e=a c=&gt; t~~» C_n V &lt;-n C=3 1~» G&gt; &lt;==&gt; O -C CT3 CO CnS ►—* S cz&gt; 4 cr» ezs&gt; &lt;j-r era *—· C-T1 era c=&gt; — g~^ €=3 c-n cz=&gt; C=3 Ca_9 C=3 ϊ: 〇〇 CJ·» cr&gt; CJ1 cr&gt; M 1 1 a 1 1 i 1 1 1 1 1 1 1 1 ctp &lt;=» cn 口 1 1 1 1 1 1 1 1 1 1 ! 1 1 cn o 1 1 1 1 cr&gt; cn 1 1 1 1 y^&gt; xjrv «η» i oq X o M N • \ &gt; 1 1 ' I 1 1 1 1 1 1 夂 1 1 1 i 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 ►--· CJ 1 C 二·&gt; 1 ! 1 1 &lt;jr\ 1 1 1 d 1 1 1 1 —7(j— m u U) ..................................................................................裝......................訂:----........線 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)甲4規格(210X297公釐) A6 B6 五、發明説明(L9 ) 表34 . 散熱片 材料 编號 硬焊的加 熱條件 (X纖) 下垂量 (毫米) 扼長強度 MPa 散熱片 材料 编號 硬焊的加 熱條件 (X盼鐘) 下垂量 (奄米) 抗張強度 WPi 1 ί)Ι5 Τ: 12 ISO r 1 2〇β 2 &quot; !) // U &quot; &quot; 2 in 3 580 °C &quot; 160 23 &quot; // // 4 // 10 // 發 2^ 〃 〃 220 5 &quot; 11 tt 明 25 &quot; &quot; // 6 // 9 170 實 例 26 &quot; tf &quot; 7 // 11 180 27 &quot; &quot; 2^0 8 // 9 170 28 tf // // 9 // // // 29 // tf &quot; 10 // 11 // 30 tf // // 11 9 180 31 無法製成散熱片 12 &quot; // &quot; 比 32 無法製成散熱片 13 &quot; II no 較 33 610 °C 散熱片熔解 14 V 9 180 實 34 600 °C 25 150 15 // 8 190 例 35 610 °C 散熱片泡蝕 16 // // &quot; 36 無法塑模成波浪狀 17 ft // 210 倩 37 610 V 35 130 18 1汗 統 實 例 19 // ft 230 38 // 45 150 20 fr 7 &quot; 裝......................訂.....................線 {請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 -71- 本紙張尺度適用中國國家標準(CNS)〒4規格(210X297公釐4 經濟部中央標準局員工消费合作社印製 A6 B6_ 兩{&gt;發明説明(70 ) 雖然在傳統實例和比較實例中,沒有一種散熱Η材料 在抗張強度和下垂性質方面是優異的,但是所有本發明 的散熱Η材料皆顯現出優異的數值^ 接下來,將表32和33中所示的硬焊片散熱Η和一般所 使用的JIS 1050擠壓管(4. 00毫米)連接在一起,並且在 575 °C的溫度下,置於氮氣中加熱5分鐘,而與本發明 實例编號第1號到第30號的散熱Η組合,並且也在600°C 的溫度下,置於氮氣中加熱5分鐘,並與比較實例和傳 統實例中的散熱1=1材料組合,以製成如圖2所示之彎曲 型的冷卻器的核心。這些核心將依照J I S Η 8 6 8 1之規定 來進行C A S S測試7 5 0小時,並目.測量在測試之後,管子 的孔蝕深度,以證實散熱片的犧牲效果。這些測量的結 果將列於表3 5中〇此外,在5 %氯化納溶液中所測得散 熱片的天然電位值,tt列於表3 5中。 裝 .................玎i…— i線 {請先閲讀背面之注意事項再填窵本頁) -72- 本紙張尺度適用中國國家標準(CNS)甲4規格(210X297公釐) 五、發明説明(…) A6 B6 經濟部中央標準局興工消費合作杜印製 表 35 i 1 丨散熱片 材料 溢號 散熱片的 天然電位 ImV V: SCh) ίίι ^n;uCIJ 經過CASSPJ試後 的最大孔触測度 (奄米) (管子乃糾裤) 敎熱片 材料 鏞號 散熱片的 丨天然電位 (mV vs K[ti 經過CASS®試後 的最大孔蝕測度 1 (奄米) (管子75〇j、時) 1 W 1. 0 21 -920 ί Γ丨 2 -8.10 1 2 22 // - 3 -850 2. 0 23 -900 1. 2 〃 〃 發 2^ 〃 // 5 -830 2. 2 明 25 // &quot; 6 -850 2. 0 實 26 〃 &quot; 1 -73.0 ;3. 2 例 27 -590 &quot; 8 -川 2. 0 28 // 〃 發 9 〃 // 29 〃 &quot; 明 10 -m 21 30 〃 &quot; 實 II -850 2. 0 31 無法製成散熱片 例 12 -8&quot; 〃 比 32 無法製成散熱片 13 -830 1. 2 較 33 散熱片熔解 ,無法測量 Μ 〃 〃 實 34 -830 穿孔 15 -860 U 例 35 散熱片泡蝕,無法測量 16 〃 // 36 無法塑模成液浪狀 17 // 1. 2 傳 37 -800 穿孔 18 -880 統 實 19 &quot; 例 38 -180 穿孔 2Ρ &quot; 〃 注意事項)第1-30猇:在575°c進行硬焊 第31-38號:在600°(:進行硬焊 -7 3- (請先閲讀背面之注意事項再螭寫本頁) -裝‘ 訂‘ 本紙張尺度適用中國國家標準(CNS)甲4规格(210 X 297公釐) _ «2.9.6,000 經濟部中央標準局員工消費合作杜印製 A6 B6_ 4 P發明説明(72 ) 本發明之實例的散熱Η與比較實例和傳統實例相比。 其具有較低的天然電位,並且冷卻管的孔蝕也較淺。 例7 製造具有表36到38中所示之合金組成的硬焊Η散熱Η 材料(其係在核心材料的兩側鍍上硬焊材料)。這些硬焊 Η散熱Η的平板厚度為G. 11毫米且為Η14精煉物(傺在核 心材料的兩側各鍍上1 〇 %的硬焊材料)。這些硬焊片散 熱Η材料,將在表3 9和4 0所示的條件下,於氮氣中加熱 ,以進行下垂測試和張力測試,並測量導電度。同時, 將這些結果列於表39和40中。 下垂測試傜在50毫米的突出長度下進行的。 此外,在張力測試中,與例5所述的方法類似,以具 有相同核心材料組成的裸材來取代該種硬焊片散熱片, 而施以相同的加熱,來澜量抗張強度。 此外,硬焊片散熱Η的導電度,是以測量在相同相熱 條件下,具有如該種核心材料之相同組成的裸材散熱片 來取代硬焊片散熱片的測量,這些由於硬焊材料存在於 這些散熱Μ的表而上,並目在硬焊之後,很難精確的決 定散熱片的截面積。已知硬焊片散熱片的導電度與含有 相同核心材料之組成的硬焊Η裸材之導電度的趨勢相同。 此外,導電度是導熱度的指標,當散熱Η的導電度改善 了 5 % I A C S,則熱交換器的熱效率也大約會改善】%。 裝—訂…:……!線 (請先閲讀背面之注意事項再填寫本頁) -74- 本紙張尺度適用中國國家橾準(CNS)甲4規格(210X297公釐) 鄉SΜ A6B6 經濟部中夬標準局員工消費合作社印製 c-o CO s: 1-» 5: CJ1 : »—» 1~‘ CD 00 -&lt;J cn Ol CO CO Η-4 «ζζ&gt; c_n 令 1*-» 〇 10. 5 11.0 &lt;LT* $ »—· »—· era t—* C=&gt; CJ1 t—· ►—* era c=&gt; CJl *—· *—» c=&gt; C-O C7 〇Γ&gt; C=9 C^-3 C-Γ» oo era 1—*· C=3 CO c_n ►—* CO c_n 二 CO c_r» ►—*· C=3 CO c_n »—» c_ri ΓΌ c_n ►-—· CJ-1 CXI •C·» G3 CO G&gt; »—» C-n c-~o ·«&gt;» CO C-n c=&gt; C-O 〇 c=» tO c_n pK»- C=3 1 1 ! 1 1 1 cr&gt; C=3 ΓΌ 1 1 I era G3 e-o 1 1 1 1 ! 1 1 1 1 1 1 i &lt;=&gt; 5s* ro C=&gt; 1—* C=3 -e^~ •° c=&gt; ° = &lt;=D r-o CZ3 *—» CT5 ro &lt;=&gt; CO era CO ί 5: - 二 I: 二 *—· &lt;=&gt; CO o c=&gt; oo % ·— t—· CO &lt;=» u=&gt; c~&gt; oo cr&gt; ►—» CO c=&gt; »—· CTD CT3 CO o c_n «=&gt; &lt;=&gt; CO tzr&gt; t-o 1 &gt; _ r° CJT = = ·— O-S I-* = «=&gt; c=&gt; ΓΌ cz=&gt; d» c_n c=&gt; c=» 1 era &lt;=&gt; 〇 G9 C-n o cs c-o CZ3 CX3 crr&gt; era ro g—&gt; CZ^i CO &lt;~.τ&gt; •«a- o cz&gt; c-n 1 1 1 1 1 c=» c=» C-J&gt; 1 t 1 1 1 I 1 1 1 l 1 I 1 t *1 1 1 1 1 1 1 1 1 1 1 1 1 1 . i 1 1 1 ! ϊ: CZ3 «cr&gt; era —-J c=&gt; rrs 1 1 — » » era era .(一 cjr&gt; c.^&gt; 1 1 I * J I 1 1 f 1 丨 &lt;^z&gt; 1 1 、二· I 1 1 1 1 1 1 1 1 1 f 1 1 i 1 1 &lt;=&gt; f CJI.J -_r_&gt; c^» i o i: OL-. CTi· 1 i 1 f 1 | 夂 iMn'2t ^: n &gt; ^ ® ^^ <w »*; ........................................ .......................................... Pretend. .......................................................... (Please read the back first Please pay attention to this page and then fill out this page) This paper scale is applicable to the Chinese National Standard (CNS) A4 specifications (210X297 mm) b8 A6B6 Central Bureau of Standards, Ministry of Economic Affairs, Industry, Industry and Consumer Cooperation Duin $ is »Cn CO CO CjA CO CO Ok &gt; CO CsUt &lt; £ 3 C ^ 3 〇〇ro c &gt; s & &gt; tO cn tO! &Gt; 0 OJ CO t« sS 翳 过 球 G &gt; I— »o era c-ri ⑺ w «阄 4S π &gt; Xun m? ίϋ _ rtP 〇 &gt; m Malu Jl f» 1 order ro cn G3 &lt; j〇c = &gt; C9 CZZi C ^ O CJ-l o ο c I 1 co C = 9 c = &gt; — ~ 4 d = &gt; era CO C = 3 &lt; = 3 ϊϊ i: U ^ ~ c = &gt; C = 3 C ^ 3 cr &gt; tN) a 1 cr &gt; » — »Cz» 1 1 t—t P 1 1 1 1 1 cn cz &gt; € = 3 era CO &lt; = 3 〇—J era c = &gt; CO i scoop a &gt; &gt; c = &gt; ΓΌ c = &gt; »~» · CXI c = »i: c = s CO CT3 &lt; = s era 〇〇〇t— »c => era oo d &gt; in -9 CO C = 3 $ e = a —1« = &gt; ra ς_ ^ a &gt; era ς &gt; η c = &gt; G9 CJ1 CT3 — ~ ae = ac = &gt; t ~~ »C_n V &lt; -n C = 3 1 ~» G &gt; &lt; == &gt; O -C CT3 CO CnS ►— * S cz &gt; 4 cr »ezs &gt; &lt; jr era * — · C-T1 era c = &gt; — g ~ ^ € = 3 cn cz = &gt; C = 3 Ca_9 C = 3 ϊ: 〇〇CJ · »cr &gt; CJ1 cr &gt; M 1 1 a 1 1 i 1 1 1 1 1 1 1 1 ctp &lt; = »cn port 1 1 1 1 1 1 1 1 1 1 1! 1 1 cn o 1 1 1 1 cr &gt; cn 1 1 1 1 y ^ &gt; xjrv« η »i oq X o MN • \ &1; I 1 1 1 1 1 1 1 夂 1 1 1 i 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 ►--CJ 1 C II &gt; 1! 1 1 &lt; jr \ 1 1 1 d 1 1 1 1 —7 (j— mu U) ...................................... .................................................. ...... install ........................ Order: ----........ line (please read the back of the first (Notes and fill in this page again) This paper scale is applicable to China National Standard (CNS) A4 specifications (210X297 mm) A6 B6 V. Description of invention (L9) Table 34 . Heatsink material number brazing heating condition (X fiber) Sag amount (mm) Choke length strength MPa Heatsink material number brazing heating condition (X hope clock) Sag amount (庄 米) Tensile strength WPi 1 ί) Ι5 Τ : 12 ISO r 1 2〇β 2 &quot;!) // U &quot; &quot; 2 in 3 580 ° C &quot; 160 23 &quot; // // 4 // 10 // Send 2 ^ 〃 〃 220 5 &quot; 11 tt Ming 25 &quot; &quot; // 6 // 9 170 Example 26 &quot; tf &quot; 7 // 11 180 27 &quot; &quot; 2 ^ 0 8 // 9 170 28 tf // / / 9 // // // 29 // tf &quot; 10 // 11 // 30 tf // // 11 9 180 31 Can't make heat sink 12 &quot; // &quot; than 32 Can't make heat sink 13 &quot; II no compared to 33 610 ° C heat sink melting 14 V 9 180 actual 34 600 ° C 25 150 15 // 8 190 Case 35 610 ° C heat sink bubble erosion 16 // // &quot; 36 cannot be molded into waves Shape 17 ft // 210 Qian 37 610 V 35 130 18 1 Khan system example 19 // ft 230 38 // 45 150 20 fr 7 &quot; loaded ... ..... order ..................... line {Please read the notes on the back before filling in Page) Printed by the Ministry of Economic Affairs, Central Bureau of Standards, Employee Consumer Cooperative-71- This paper scale is applicable to the Chinese National Standard (CNS) 〒4 specifications (210X297mm 4 Printed by the Ministry of Economic Affairs, Central Bureau of Standards Employee Consumer Cooperative, A6 B6_ two Description (70) Although none of the heat dissipation H materials is excellent in tensile strength and sagging properties in the conventional examples and comparative examples, all the heat dissipation H materials of the present invention show excellent values ^ Next, the table The heat dissipation of the brazed pads shown in 32 and 33 is connected to the commonly used JIS 1050 extruded tube (4.0 mm), and heated at 575 ° C in nitrogen for 5 minutes, and Combined with the heat dissipation Η of the present invention No. 1 to No. 30, and also heated at 600 ° C in nitrogen for 5 minutes, and the heat dissipation 1 = 1 material in the comparative example and the traditional example Combine to make the core of the curved cooler as shown in Figure 2. These cores will be subjected to the CASS test for 750 hours in accordance with the provisions of JIS H 8 6 81, and the purpose is to measure the pitting depth of the tube after the test to confirm the sacrificial effect of the heat sink. The results of these measurements are listed in Table 35. In addition, the natural potential values of the heat sinks measured in 5% sodium chloride solution are listed in Table 35. Installed ..................... i line (please read the precautions on the back before filling this page) -72- This paper size is applicable to China National Standards (CNS ) A4 specifications (210X297 mm) V. Description of the invention (…) A6 B6 The Central Standards Bureau of the Ministry of Economic Affairs Xinggong Consumer Cooperation Co., Ltd. du printing 35 i 1 丨 Heat sink material overflow number Natural potential of the heat sink ImV V: SCh) ^ n; uCIJ The maximum hole touch measurement after the CASSPJ test (庄 米) (The tube is the trousers) The natural potential of the heat sink material Yung No. heat sink (mV vs K [ti The maximum hole corrosion after the CASS® test Measure 1 (庄 米) (tube 75〇j, hour) 1 W 1. 0 21 -920 ί Γ 丨 2 -8.10 1 2 22 //-3 -850 2. 0 23 -900 1. 2 〃 〃 Hair 2 ^ 〃 // 5 -830 2. 2 Ming 25 // &quot; 6 -850 2. 0 Actual 26 〃 &quot; 1 -73.0; 3. 2 Example 27 -590 &quot; 8 -Chuan 2. 0 28 // 〃 Issue 9 〃 // 29 〃 &quot; Ming 10 -m 21 30 〃 &quot; Real II -850 2. 0 31 Cannot make heat sink example 12 -8 &quot; 〃 Ratio 32 Cannot make heat sink 13 -830 1.2 Unable to measure than 33 heat sink melts Quantity M 〃 〃 Actual 34 -830 Perforation 15 -860 U Example 35 Heat sink blister, unable to measure 16 〃 // 36 Unable to mold into liquid waves 17 // 1. 2 pass 37 -800 Perforation 18 -880 19 &quot; Example 38 -180 Perforation 2Ρ &quot; 〃 Note) No. 1-30 猇: brazing at 575 ° c No. 31-38: at 600 ° (: brazing -7 3- (please read first Note on the back and then write this page)-Install 'book' This paper scale is applicable to China National Standard (CNS) A 4 specifications (210 X 297 mm) _ «2.9.6,000 Ministry of Economic Affairs Central Standards Bureau employee consumption cooperation Du Yin Preparation A6 B6_ 4 P Description of the invention (72) The heat dissipation H of the example of the present invention is compared with the comparative example and the traditional example. It has a lower natural potential, and the pitting of the cooling pipe is also shallow. Example 7 is manufactured with Table 36 To the alloy shown in 38 brazed H heat dissipation H material (which is coated on both sides of the core material with brazed material). The thickness of these brazed H heat dissipation H plates is G. 11 mm and is H14 refined (Ye is plated with 10% brazing material on both sides of the core material). These brazing pads dissipate heat Η materials, which will be heated under nitrogen under the conditions shown in Tables 39 and 40 to perform sag tests and tensile tests, and to measure electrical conductivity. At the same time, these results are listed in Tables 39 and 40. The sagging test was carried out under a protruding length of 50 mm. In addition, in the tensile test, similar to the method described in Example 5, a bare material with the same core material composition was used to replace the brazed fin heat sink, and the same heating was applied to measure the tensile strength. In addition, the conductivity of the brazed fin heat dissipation H is a measurement of replacing the brazed fin heat sink with the same composition of the bare material fin as the core material under the same phase thermal conditions. These are due to the brazed material Existing on the surface of these heat sinks M, and after brazing, it is difficult to accurately determine the cross-sectional area of the heat sink. It is known that the conductivity of the brazed fins is the same as that of the brazed H bare material containing the same core material. In addition, electrical conductivity is an indicator of thermal conductivity. When the electrical conductivity of heat dissipation H is improved by 5% I A C S, the thermal efficiency of the heat exchanger will also be improved by approximately 1%. Binding-binding ...: ...! Line (please read the precautions on the back before filling in this page) -74- This paper size is applicable to China National Standard (CNS) Grade 4 (210X297mm) Township SMU A6B6 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs co CO s: 1- »5: CJ1:» — »1 ~ 'CD 00-&lt; J cn Ol CO CO Η-4« ζζ &gt; c_n order 1 *-»〇10. 5 11.0 &lt; LT * $» — · »— · Era t— * CJ1 t— • ►— * era c = &gt; CJl * — · * —» c = &gt; CO C7 〇Γ &gt; C = 9 C ^ -3 C- Γ »oo era 1— * · C = 3 CO c_n ►— * CO c_n II CO c_r» ►— * · C = 3 CO c_n »—» c_ri ΓΌ c_n ►-— · CJ-1 CXI • C · »G3 CO G &gt; »—» Cn c- ~ o · «&gt;» CO Cn c = &gt; CO 〇c = »tO c_n pK»-C = 3 1 1! 1 1 1 cr &gt; C = 3 ΓΌ 1 1 I era G3 eo 1 1 1 1! 1 1 1 1 1 1 i &lt; = &gt; 5s * ro C = &gt; 1— * C = 3 -e ^ ~ • ° c = &gt; ° = &lt; = D ro CZ3 * — »CT5 ro &lt; = &gt; CO era CO ί 5:-II I: II * — · &lt; = &gt; CO oc = &gt; oo% · — t— · CO &lt; = »u = &gt; c ~ &gt; oo cr &gt; ►—» CO c = &gt; »— · CTD CT3 CO o c_n« = &gt; &lt; = &gt; CO tzr &gt; to 1 &gt; _ r ° CJT = = · — OS I- * = «= &gt; c = &gt; ΓΌ cz = &gt; d» c_n c = &gt; c = »1 era &lt; = &gt; 〇G9 Cn o cs co CZ3 CX3 crr &gt; era ro g— &gt; CZ ^ i CO &lt; ~ .τ &gt; • «a- o cz &gt; cn 1 1 1 1 1 c =» c = »C-J &gt; 1 t 1 1 1 I 1 1 1 l 1 I 1 t * 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1. i 1 1 1! ϊ: CZ3 «cr &gt; era —-J c = &gt; rrs 1 1 —» »era era. ( 1 cjr &gt; c. ^ &Gt; 1 1 I * JI 1 1 f 1 丨 &lt; ^ z &gt; 1 1, 2 · I 1 1 1 1 1 1 1 1 1 1 f 1 1 i 1 1 &lt; = &gt; f CJI.J -_r_ &gt; c ^ »ioi: OL-. CTi · 1 i 1 f 1 | 夂 i

C/5 t-*· 硬焊材料合金的組成 &lt; 重量%&gt; η c N 0 1~~4 cn 0 勺 α&gt; &gt; V—· cn ►-*· 核心材料合金的組成(重量% &gt; TJ 〇&gt; O C tSJ ㈡ I n i S η M g Μ π N i ' C ...........-.....................-......................................................^.......................可.....................Φ {請先閲讀背面之注意事項再填寫本頁) _ ^Jd I 格 规 4 甲 Ns C 準 標 家 國 國 中 用 適 度 尺 張 紙 本 五、發明説明(74 A6 B6 經濟部中央標準局員工消費合作社印製 S 5¾ CO CO Ca» 〇〇 Ca3 C*A Ca3 &lt;jy CaS CO CO Ca» tO CO CO c-o CO CSD OO CO ro σ* tO tn Cn〇 CO 〇» CO ro V·~» c-ri *—· C=3 CJ1 5: % »—» o »~~ H—^ ►—* *—* c,»» 1~~* o U3 C&gt;T» c&gt;o «_n &gt;—* ro C-n 二 CO CJ1 CO €=D CO c-n CV&gt; = r-o «_n c_n t^a :5 •— l&gt;-D «=&gt; era c-o I c=&gt; CO 1 C=&gt; c=&gt; K—· C=3 C=P CO &lt;=&gt; c=&gt; —3 &lt;T3 d=&gt; CO 1 1 1 1 1 1 1 1 era c^ c*〇 cr&gt; cz&gt; C-Tl 1 C=3 ·= = C=&gt; :¾ era t-o c=s i I: A i: i: 5: : : 二 &gt;~~* 二 »— o C43 = ►—· CO 1~' -: h—· c=&gt; cr&gt; CJ1 C3 ·= 1 c^o o-n =¾ t-» C^ri CaA ►-—· CO crp ers ς_τν 1 c=» &lt;z=&gt; CJ, C=3 &lt;=&gt; 〇〇 c=&gt; o CO CZ&gt; (=13 1 1 &lt;=&gt; €^=&gt; tO 1 I 1 1 1 1 1 1 1 i 1 CT3 cr&gt; 1 1 1 1 1 1 i 1 1 1 era &lt;z=&gt; &lt;30 1 1 1 c=&gt; o oo c=&gt; c=&gt; 1 1 ! 1 O V./J 1 V二 J ! 1 1 1 cn&gt; :.. cz&gt; c=&gt; oo CZ3 = 1 I 1 1 1 1 1 ΐ; 1 1 i 1 i 1 1 i 1 i i 1 cr&gt; CXj c=&gt; 1 1 C'二 &lt; -Ο 1 1 era CJ&gt; l D to 1 ! i 1 1 1 1 、、 i: c^&gt; 1 〇 l| 二:1 〇:; ! 1 cr&gt; 1、·+-) 1 1 l 1 W—.J CJ 1 ,M 1 \ : i :: Γ:: &lt; &lt; i ' 〇 «=&gt; &lt;=» 1 1 .一&gt; t.O i: t_. i. SB2tS? m ⑺ ►—*· 觸 -Hm π&gt; 除 $ m » _ βΡ 〇 c tsi ►—&lt; p cn •η (X) &gt; cn ♦—·· Φ 除 皞 _ dfi cb O C tsi P P CO Π V; 〇Q :5 *z o 格规 4 甲 CNS標家 國 國 中 用適 度尺張紙本C / 5 t- * · Composition of brazing material alloy &lt; wt% &gt; η c N 0 1 ~~ 4 cn 0 scoop α &gt; &gt; V— · cn ►- * · Composition of core material alloy (wt% &gt; TJ 〇 &gt; OC tSJ ㈡ I ni S η M g Μ π N i 'C ...........-................. ....-............................................. ......... ^ ....................... can ..................... ..... Φ {Please read the precautions on the back before filling out this page) _ ^ Jd I Standard 4 A Ns C Prospective bidder home country middle school with a moderate size sheet of paper V. Invention description (74 A6 B6 Ministry of Economic Affairs Printed S 5¾ CO CO Ca »〇〇Ca3 C * A Ca3 &lt; jy CaS CO CO Ca» tO CO CO co CO CSD OO CO ro σ * tO tn Cn〇CO 〇 »CO ro V · ~ »C-ri * — · C = 3 CJ1 5:%» — »o» ~~ H— ^ ►— * * — * c, »» 1 ~~ * U3 C &gt; T »c &gt; o« _n &gt; — * ro Cn II CO CJ1 CO € = D CO cn CV &gt; = ro «_n c_n t ^ a: 5 • — l &gt;-D« = &gt; era co I c = &gt; CO 1 C = &gt; c = &gt; K— · C = 3 C = PC O &lt; = &gt; c = &gt; —3 &lt; T3 d = &gt; CO 1 1 1 1 1 1 1 1 1 era c ^ c * 〇cr &gt; cz &gt; C-Tl 1 C = 3 · = = C = &gt;: ¾ era to c = si I: A i: i: 5::: two &gt; ~~ * second »— o C43 = ►— · CO 1 ~ '-: h— · c = &gt; cr &gt; CJ1 C3 · = 1 c ^ o on = ¾ t- »C ^ ri CaA ►-— · CO crp ers ς_τν 1 c =» &lt; z = &gt; CJ, C = 3 &lt; = &gt; 〇〇c = &gt; o CO CZ &gt; (= 13 1 1 &lt; = &gt; € ^ = &gt; tO 1 I 1 1 1 1 1 1 1 i 1 CT3 cr &gt; 1 1 1 1 1 1 i 1 1 1 era &lt; z = &gt; &lt; 30 1 1 1 c = &gt; o oo c = &gt; c = &gt; 1 1! 1 O V./J 1 V II J! 1 1 1 cn &gt;: .. cz &gt; c = &gt; oo CZ3 = 1 I 1 1 1 1 1 1; 1 1 i 1 i 1 1 i 1 ii 1 cr &gt; CXj c = &gt; 1 1 C '二 &lt; -Ο 1 1 era CJ &gt; l D to 1! i 1 1 1 1, i: c ^ &gt; 1 〇l | 2: 1 〇 :;! 1 cr &gt; 1, · +-) 1 1 l 1 W—.J CJ 1, M 1 \: i: : Γ :: &lt; &lt; i '〇 «= &gt; &lt; =» 1 1. 一 &gt; tO i: t_. I. SB2 tS? m ⑺ ►— * · touch-Hm π &gt; except $ m »_ βΡ 〇c tsi ►— &lt; p cn • η (X) &gt; cn ♦ — ·· Φ 皞 _ dfi cb OC tsi PP CO Π V; 〇Q: 5 * zo format 4 A CNS standard home country middle school with a moderate size paper

公 7 295604 A6 B6 五、發明説曰j (75) 經濟部中央標準局員工消費合作社印奴 窆珅郭葙1 m η n ^ s赙s卸 &lt;_n cr&gt; CJ1 CXI CXI CXI CO CXI CO c*n CXI — s; pO. CO on 〇〇 » . CT&gt; &lt;=&gt; *— &lt;—^ era cjn »—· *-—» czza &lt;=&gt; c_n 1 1 &lt;=3 G3 «_〇 cz» CvD cz&gt; OO c_n era CO c_n ►—» CJ-t *—» &lt;=&gt; CO C_X1 ►—· c_n 1 C=&gt; CO oo &lt;=&gt; t*· c=&gt; u&gt;» C3&gt; ro cs c=&gt; CO c_n CO tr~% o ΓΌ on 1 1 1 l era era ΓΌ 1 1 erra cr~a f-O t 1 1 1 cr&gt; = era c-o c=&gt; c=&gt; c-o €=3 C-O €=D c=&gt; CO c=* C*J ϊ; $ | 1 二 c=» c_n 二 CO c_n ΓΌ 二 = ° ►—» &lt;=&gt; 1—* cr&gt; r^o ►— c·»» 1~* &lt;=» C=d ~4 ►—* H—* 1 G&gt; &lt;zz? C=3 1 I~» 匚 = = 二 二 = »-* 0-9 c_n t—» i 03 t-* i 爻 i; c=&gt; &lt;=&gt; t^-=&gt; 1 &lt;z=&gt; &lt;=&gt; CO c=&gt; c=&gt; r-o era c=» —-1 d&gt; «=» 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I 1 ! 1 t 1 1 1 1 1 1 1 1 二 1 i 1 1 1 1 . i cru CJ&gt; 1 C=J&gt; C-»l 1 I c r&gt; -t ! 1 1 &lt;z^ C^_i 1 1 &lt;r&gt; &lt;j〇 1 1 1 1 CHJ «_»&gt; 1 1 、.&gt; t3-&gt; 1 1 1 5=3&gt; Zrx 1 1 1 cn&gt; c—j 1 1 vZ^ CJ i 1 &lt;z&gt; ϊ'-» ⑺ »—· 5ϋ 〇&gt; 玛 Ilrnh W Ms o c N ►—&lt; 0 CO 勺 Π) &gt; cn *--· 2t 睁 m m 妈 w _ dfi Tl CD 〇 c N 口 to 口 〇ς ο —ι Ν * η Η &gt; 0 300 ..................................................................................^......................^.....................線 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公釐) - -/7- A6 B6 五、發明説明(7‘) 經濟部中央標準局R工消费合作杜印製 表 39 1 戠熱片 材料 编m 1硬谢fV 下垂量(毫米&gt; 抗張 強度 散熱Η 材料 编號 硬焊的 下垂ft &lt;奄米&gt; 抗張 強庇 1加熱條 件 妝熱片 丨裸材 硬焊片 妝熱片 禅m度 加熱條 件 敗热片 棵材 硬焊片 妝熱片 丨(X5^鐘 材料 m •JiiACS (Χ5分鐘 材料 •Λ (ACS I 1 1 ^8〇°c R I4fl 2! .5 g \%0 51 1 .ws V fi 10 ', U ·· ? 1 &quot; - &quot; ,, Π sin r ϊ It ,, \ m v 7 12 &quot; SI η ,' &quot; &quot; ·. ί. SU T: 5 8 ISO 52 U ,. &quot; &quot; 6 &quot; ·, - 26 〃 -I &quot; h &quot; Ϊ &quot; - Μ 21 - 〃 tt &quot; 發 S &quot; 〃 53 η .· &quot; .· - &quot; 9 - - &quot; 52 發 η 5T5 V b s - 明 10 5ί0 V % 10 51 明 30 r/ &quot; ,. 50 K II S75 V 5 J HO n 實 例 31 &quot; 〃 &quot; 例 12 ,' 〃 - &quot; η 580 ^ τ 10 NO S? Π - - η &quot; 10 13 M Μ &quot; - 150 5Z U &quot; ί 12 150 &quot; 15 &quot; &quot; &quot; ,r 35 W5 T: 5 8 MO - &quot; - &quot; 51 Η 11 - &quot; *10 π 1 π - 31 &quot; &quot; - ISO &quot; IS &quot; &quot; 3S 580 r 7 11 - 19 &quot; &quot; ·' 39 &quot; ί 12 &quot; 51 η - 〃 &quot; U . &quot; &quot; 〃 &quot; &quot; — 78 — (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)甲4规格(210 X 297公* ) 82. 9. 6,000 五、發明説明(77 ) 表40 A6 B6 散熱片 材料 编號 硬焊的加 熱條件 (X5分鐘) 下垂量 散熱片 裸材 (毫米&gt; 硬焊片 散熱片 材料 抗張強度 MPa 褐Hi度 U 5 7 5 T 6_ 10 150 50 η 580 &quot;C 9 12 // 51 發 &quot; &quot; ff 160 50 明 “ // 6 10 &quot; 49 實 45 // // 9 ff ff 例 46 // &quot; // // κι 47 // &quot; // // // a // // // // &quot; 49 575 °C 由於熔解而無法測量. 比 50 // 1 10 150 34 較 51 610 °C 由於熔解而無法測量 實 52 無法製成硬焊片散熱片- 例 53 600 °C 由於熔解而無法測量 54 // 由於熔解而無法測量 傳 統 55 610 °C 25 35 110 36 實 例 56 // 30 40 80 52 ............................................. ...............................裝.....................可.....................線 (請先閲讀背面之注意事項再填寫本頁) 烴濟部中央標準局員工消費合作社印^ -79- 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公釐) 經濟部中央標準局員工消费合作社印製 A6 B6 马f發明説明(78 ) 由表39和40中可明顯的看出,雖然在傳統實例和比較 實例中,没有一種散熱片材料在抗張強度和下垂性質方 面是優異的,但是所有本發明的散熱Η材料皆顯現出優 異的數值。 例8 製造具有表41到43中所示之合金組成的硬焊Η散熱片 材料(其偽在核心材料的兩側鍍上硬焊材料)。這些硬焊 Η散熱Η的平板厚度為0.11毫米且為Η14精煉物(係在核 心材料的兩側各鍍上1 0 %硬焊材料)。將散熱片予以切 割後而製成這些樣Η ,並且在表4 4和4 5所示的條件下, 於氮氣中進行硬焊加熱,以進行下垂测試。至於下垂測 試則係在50毫米的突出長度下進行的。此外,樣品經過 加熱之後的導電度,將在表44和45中所列的條件下測量 β除此之外,薄電度的測量係依與例7中所示的類似方 式來進行。 這些結果將列於表44和45中。 ........................................... 裝::1 訂線 {請先閲讀背面之注意事項再填寫本頁) -80- 本紙張尺度適用中Η國家標準(CNS)甲4規格(210X297公釐) q 5 〇 善—. — --.—— q 5 〇 善—. — --.—— 經濟部中央標肀局員工消費合作杜印製 A6 B6 五、發明説明(79) CO ΓΌ CO Ξ; s; f—» ro to 00 Oi ΟΊ CO to H* t—* C=3 ^2» c_n 11. 0 »—» tn 1~» G&gt; ΓΌ C-Π 二 二 5; 5: ΐ: CO &lt;Ln t—* ϊϊ C-n r-o ΙΌ CO c»n CO 1 «=» C=3 CO 1 1 1 1 1 1 1 1 &lt;=9 C=&gt; Γ 〇 1 1 1 1 1 1 1 1 1 ° = &lt;=&gt; : cr&gt; cn t-o 〇 o. 2 mm o. 5 _;_i dD G3 c_n crz&gt; era C=3 C=3 C-n &lt;=3 CTi c-n &lt;=» r—· ►—» c=&gt; CO c=&gt; •~» CO H—» &lt;=&gt; r- *—» era G&gt; —-i ca oo »—· *— OO c=» *— CO o ►—· = ·= f--- 二 c=&gt; = era ° cz=&gt; ° C=3 = 夂 t~* CjO = 二 »~* t-o «L/ί 1~* = 1 c=&gt; «=&gt; era €ZZ&gt; C-n V era c=a tO cr&gt; c=&gt; CO c=&gt; CZ3 c_n 0. 01 &lt;zr&gt; c=&gt; &lt;LO 0. 01 c=s *zz&gt; 1 0. 05 1 1 1 1 &lt;rz&gt; C=3 1 c_..a era OO 1 1 . g~» G=&gt; oo 1 C=3 CZ&gt; OO 1 1 1 1 1 1 l ! t 1 1 C :-J 1 rr» «ru &lt;^&gt; ί ! CT-) j 1 :~~5 ' t &lt;Z&gt; 1 1 1 1 1 cr&gt; az&gt; &lt;m CXD cr&gt; 1 1 1 1 1 di 1 c-:&gt; CTJ 1 1 1 :,; 1 1 1 1 1 t _. c.ZU 1 1 I c 1J 1 -二 1 1 1 1 1 \.^Lj &lt;:i 1 1 CZ3 • o«.-j . C^~J 1 rr J l.».J &lt;.—&gt; c 〇 1 f cr.-; 1 二 I 1 二-t 二 1 CT3 CJ &gt; -- i ! 1 •rj •- ctj 1 CT J cr^ 1 cza .-i 1 i cn »—*· O c tSJ t—^ p 00 硬焊材料合金的組成 &lt; 重量*&gt; a&gt; &gt; m 〇&gt; 〇 c (S3 核心材料合金的組成(重量* &gt; I n S n Mg Μ η : N : • 5 (請先閱讀背面之注意事項再填寫本頁) -οι- 本紙張尺汶谪用中闽國芡燸mfCNS'l Ψ4钼枚_ni_D v?f)7y,v格Ί 五、發明説明(80 ) A6B6 經濟部中央標準局員工消費合作社印知 C9 Ca» CO c*a oo CO CO C7» oo cn CO CO c^&gt; CO OO C*a CO eo t-o oo oo CO CT&gt; CO ex» ro rs·» eo Ϊ5 &lt;〇 oo 1~~* o c_n ►—»· *—* CT&gt; &lt;JO c_n CO «=&gt; ►—» o CJH ♦—· »—* c=&gt; »—» e=&gt; CJ1 H—· »~^ G9 10. 5 ! 1 1 1 1 1 CO c=&gt; ►—* «=► CO c_n c^&gt; c_ri Ca» ctj cr&gt; era &lt;=» CO C_X1 *—» C-ΓΊ 1 1 1 ! .1 1 .^. cz=&gt; CO C=&gt; t · CT3 e=&gt; CJl c_n c-n CO cz&gt; cr&gt; CO C-n CO 1 1 1 1 c=&gt; C=) t—* CZ3 cz&gt; t&gt;s&gt; «=* era tO cm c=&gt; to 1 1 1 era c=&gt; CxJ 1 1 = ί c=&gt; h— CO CO o CO era t—— C=3 c-o CO c=&gt; i = c=&gt; ° - $ ° 1-- •画- &lt;=&gt; c=&gt; -&gt;i cr&gt; 〇〇 r- C£9 cs oo *—» d3 ►—* ro CZZ3 ί - 二 二 CZ3 CJ1 5: C-3 ° era CO ° 1--* ►—» CO 1 1 二 CO CJ1 t~* = ΓΌ Ca» CJI t~- 1 «=» ΓΌ C=3 c=&gt; c*n 1 a% ►—· 1 o cn&gt; CO era t~» CZ3 C=&gt; CO ezr» c=&gt; CJ、 5: &lt;=» &lt;=Z3 CO t cz=&gt; C=3 CO C7T&gt; &lt;=» —·! 1 1 0. 03 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 f. 1 Ί 1 1 1 I 1 1 1 1 1 1 1 1 1 1 1 1 cz^ :, I 1 cz- ί i c· 1 1 i 1 1 1 1 1 1 cz&gt; 1 1 CT3 Cd&gt; 1 1 »:二 J 〇·- 1 1 ! 1 1 I 1 1 1 1 i 1 1 1 1 1 N 1 CJ^J … 1 1 cz--i 1 1 i 1 &lt; I j 1 -:- :j 1 1 1 1 I s ·. o yzj &lt; o «•二. &lt;〇 '、 二- 1 1' -j ««TD C.J l o 1-* 1 1 1 '' &lt; c~ · c二- cz^ ΙΌ ί -二 c.二 &lt; 卞 ί 1 屮 1¾雅 阄;#笼0&gt;.^&gt;-$薛妈 &lt;»_%&gt; | 劾 &lt;6驾箪0&gt;睜$阵玛(»»*) S i C u Ζ η I η 一 S n F e A 1 S i F e f C u Ζ η I n S η M g ί Μ π N:.:c r j .Ϊ「一-Τ ί A 1Gong 7 295604 A6 B6 V. Invention description j (75) Employee Consumer Cooperative of the Ministry of Economic Affairs Central Standards Bureau Yin Nuo Shou Guo Guo 1 m η n ^ s 赙 s discharge &lt; _n cr &gt; CJ1 CXI CXI CXI CO CXI CO c * n CXI — s; pO. CO on 〇〇 ». CT &gt; &lt; = &gt; * — &lt; — ^ era cjn» — · * -— »czza &lt; = &gt; c_n 1 1 &lt; = 3 G3 «_〇cz» CvD cz &gt; OO c_n era CO c_n ►— »CJ-t * —» &lt; = &gt; CO C_X1 ►— · c_n 1 C = &gt; CO oo &lt; = &gt; t * · c = &gt; u &gt; »C3 &gt; ro cs c = &gt; CO c_n CO tr ~% o ΓΌ on 1 1 1 l era era ΓΌ 1 1 erra cr ~ a fO t 1 1 1 cr &gt; = era co c = &gt; c = &gt; co € = 3 CO € = D c = &gt; CO c = * C * J ϊ; $ | 1 two c = »c_n two CO c_n ΓΌ two = ° ►—» &lt; = &gt; 1— * cr &gt; r ^ o ►— c · »» 1 ~ * &lt; = »C = d ~ 4 ►— * H— * 1 G &gt; &lt; zz? C = 3 1 I ~» 匚 = = 二 二 = » -* 0-9 c_n t— »i 03 t- * i 爻 i; c = &gt; &lt; = &gt; t ^-= &gt; 1 &lt; z = &gt; &lt; = &gt; CO c = &gt; c = &gt; ro era c = »—-1 d &gt;« = »1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I 1! 1 t 1 1 1 1 1 1 1 1 2 1 i 1 1 1 1 1. I cru CJ &gt; 1 C = J &gt; C- »l 1 I c r &gt; -t! 1 1 &lt; z ^ C ^ _i 1 1 &lt; r &gt; &lt; j〇1 1 1 1 CHJ «_» &gt; 1 1,. &gt; t3- &gt; 1 1 1 5 = 3 &gt; Zrx 1 1 1 cn &gt; c—j 1 1 vZ ^ CJ i 1 &lt; z &gt; ϊ'- »⑺» — · 5ϋ 〇 &gt; Ma Ilrnh W Ms oc N ►— &lt; 0 CO spoon Π) &gt; cn *-· 2t open mm dam w _ dfi Tl CD 〇c N port to port 〇ς ο —ι Ν * η Η &gt; 0 300 ........................ .................................................. .............. ^ ..................................... ......... Line (please read the precautions on the back before filling in this page) This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210x297 mm)--/ 7- A6 B6 5. Description of the invention (7 ') Ministry of Economic Affairs, Central Bureau of Standards, R, Industry and Consumer Cooperation, Du Printing, 39. 1 戠 Hot film material, m 1 hard thanks fV sag (mm)> tensile strength heat dissipation Η material number sag ft for brazing &lt; 奄 米 &gt; Anti-Zhang Qiangpi 1 heating condition makeup hot film 丨 bare material hard Pieces of makeup hot piece Zen m degree heating conditions defeat heat sheet wood brazing piece makeup hot piece 丨 (X5 ^ clock material m • JiiACS (Χ5 minutes material • Λ (ACS I 1 1 ^ 8〇 ° C R I4fl 2! 5 g \% 0 51 1 .ws V fi 10 ', U ··? 1 &quot;-&quot; ,, Π sin r ϊ It,, \ mv 7 12 &quot; SI η,' &quot; &quot; ·. Ί . SU T: 5 8 ISO 52 U,. &Quot; &quot; 6 &quot; ·,-26 〃 -I &quot; h &quot; Ϊ &quot;-Μ 21-〃 tt &quot; Hair S &quot; 〃 53 η. &quot;. ·-&quot; 9--&quot; 52 Hair η 5T5 V bs-Ming 10 5ί0 V% 10 51 Ming 30 r / &quot;,. 50 K II S75 V 5 J HO n Example 31 &quot; 〃 &quot; Example 12, '〃-&quot; η 580 ^ τ 10 NO S? Π--η &quot; 10 13 M Μ &quot;-150 5Z U &quot; ί 12 150 &quot; 15 &quot; &quot; &quot;, r 35 W5 T: 5 8 MO-&quot;-&quot; 51 Η 11-&quot; * 10 π 1 π-31 &quot; &quot;-ISO &quot; IS &quot; &quot; 3S 580 r 7 11-19 &quot; &quot; · ' 39 &quot; ί 12 &quot; 51 η-〃 &quot; U. &quot; &quot; 〃 &quot; &quot; — 78 — (Please read the precautions on the back before filling in this page) This paper scale is applicable to China National Standards (CNS) A4 specifications (210 X 297 Gong *) 82. 9. 6,000 V. Description of invention (77) Table 40 A6 B6 Heat sink material number Heating conditions for brazing (X5 minutes) Sagging amount Heat sink bare material (mm> Brazed heat sink Material tensile strength MPa Brown Hi degree U 5 7 5 T 6_ 10 150 50 η 580 &quot; C 9 12 // 51 hair &quot; &quot; ff 160 50 Ming "// 6 10 &quot; 49 Actual 45 // // 9 ff ff Example 46 // &quot; // // κι 47 // &quot; // // // a // // // // &quot; 49 575 ° C cannot be measured due to melting. Than 50 // 1 10 150 34 Compared to 51 610 ° C Cannot be measured due to melting 52 Cannot be manufactured as a heat sink with brazed pads-Example 53 600 ° C Cannot measure due to melting 54 // Cannot measure due to melting traditional 55 610 ° C 25 35 110 36 Example 56 // 30 40 80 52 ............................................. ....................................... Pretend ............. .. ...... Can ..................... line (please read the precautions on the back before filling this page) Employee consumption of the Central Standards Bureau of the Ministry of Hydrocarbon Economy Cooperative cooperative print ^ -79- This paper scale is applicable to China National Standard (CNS) A4 specifications (210x297 mm) A6 B6 Ma f invention description printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (78) Available in Tables 39 and 40 It is obvious that although none of the heat sink materials is excellent in tensile strength and sagging properties in the conventional examples and comparative examples, all the heat sink H materials of the present invention show excellent values. Example 8 Fabrication of a brazed H heat sink material having the alloy composition shown in Tables 41 to 43 (which is pseudo-coated with braze material on both sides of the core material). The thickness of these brazed H heat dissipation H plates is 0.11 mm and is a refined H14 (deposited on each side of the core material with 10% brazed material). These samples were made by cutting the heat sink, and under the conditions shown in Tables 44 and 45, brazing heating was carried out in nitrogen to perform the sag test. As for the sag test, it was carried out under a protruding length of 50 mm. In addition, the conductivity of the sample after being heated will be measured under the conditions listed in Tables 44 and 45. Except for the measurement of thinness, the measurement of the thinness is performed in a similar manner as shown in Example 7. These results will be listed in Tables 44 and 45. ..................................... Packing :: 1 Threading { Please read the precautions on the back before filling in this page) -80- The paper size is applicable to the Chinese National Standard (CNS) A 4 specifications (210X297mm) q 5 〇 good —. — --.—— q 5 〇 good —. — --.—— The Ministry of Economic Affairs Central Standardization Bureau employee consumption cooperation du printed A6 B6 V. Description of invention (79) CO ΓΌ CO Ξ; s; f— »ro to 00 Oi ΟΊ CO to H * t— * C = 3 ^ 2 »c_n 11. 0» — »tn 1 ~» G &gt; ΓΌ C-Π 22: 5; 5: ΐ: CO &lt; Ln t— * ϊϊ Cn ro ΙΌ CO c »n CO 1« = »C = 3 CO 1 1 1 1 1 1 1 1 &lt; = 9 C = &gt; Γ 〇1 1 1 1 1 1 1 1 1 1 ° = &lt; = &gt;: cr &gt; cn to 〇o. 2 mm o. 5 _; _i dD G3 c_n crz &gt; era C = 3 C = 3 Cn &lt; = 3 CTi cn &lt; = »r— · ►—» c = &gt; CO c = &gt; • ~ »CO H— »&Lt; = &gt; r- * —» era G &gt; —-i ca oo »— · * — OO c =» * — CO o ►— · = · = f --- 二 c = &gt; = era ° cz = &gt; ° C = 3 = 夂 t ~ * CjO = 2 »~ * to« L / ί 1 ~ * = 1 c = &gt; «= &gt; era € ZZ &gt; Cn V era c = a tO cr &gt; c = &gt; CO c = &gt; CZ3 c_n 0. 01 &lt; zr &gt; c = &gt; &lt; LO 0. 01 c = s * zz &gt; 1 0. 05 1 1 1 1 &lt; rz &gt; C = 3 1 c _ .. a era OO 1 1. G ~ »G = &gt; oo 1 C = 3 CZ &gt; OO 1 1 1 1 1 1 l! T 1 1 C: -J 1 rr» «ru &lt; ^ &gt; ί! CT-) j 1: ~~ 5 't &lt; Z &gt; 1 1 1 1 1 cr &gt; az &gt; &lt; m CXD cr &gt; 1 1 1 1 1 di 1 c-: &gt; CTJ 1 1 1 :,; 1 1 1 1 1 t _. C.ZU 1 1 I c 1J 1 -two 1 1 1 1 1 \. ^ Lj &lt;: i 1 1 CZ3 • o «.- j. C ^ ~ J 1 rr J l. ». J &lt; .— &gt; c 〇1 f cr.-; 1 two I 1 two-t two 1 CT3 CJ &gt;-i! 1 • rj •-ctj 1 CT J cr ^ 1 cza .-i 1 i cn »— * · O c tSJ t— ^ p 00 Composition of brazing material alloy &lt; weight * &gt; a &gt; &gt; m 〇 &gt; 〇c (S3 composition of core material alloy (weight * &gt; I n S n Mg Μ η: N: • 5 (please read the precautions on the back before filling out this page) -οι-芡 燸 mfCNS'l Ψ4 molybdenum_ni_D v? F) 7y, v grid Ί V. Description of invention (80) A6B6 Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs printed C9 Ca »CO c * a oo CO CO C7» oo cn CO CO c ^ &gt; CO OO C * a CO eo to oo oo CO CT &gt; CO ex »ro rs ·» eo Ϊ5 &lt; 〇oo 1 ~~ * o c_n ►— »· * — * CT &gt; &lt; JO c_n CO «= &gt; ►—» o CJH ♦ — »» — * c = &gt; »—» e = &gt; CJ1 H— · »~ ^ G9 10. 5! 1 1 1 1 1 CO c = &gt; ►— * «= ► CO c_n c ^ &gt; c_ri Ca» ctj cr &gt; era &lt; = »CO C_X1 * —» C-ΓΊ 1 1 1! .1 1. ^. Cz = &gt; CO C = &gt;; t CT3 e = &gt; CJl c_n cn CO cz &gt; cr &gt; CO Cn CO 1 1 1 1 c = &gt; C =) t— * CZ3 cz &gt; t &gt; s &gt; «= * era tO cm c = &gt; to 1 1 1 era c = &gt; CxJ 1 1 = ί c = &gt; h— CO CO o CO era t—— C = 3 co CO c = &gt; i = c = &gt; °-$ ° 1-- • Painting-&lt; = &gt; c = &gt;-&gt; i cr &gt; 〇〇r- C £ 9 cs oo * — »d3 ►— * ro CZZ3 ί-two two CZ3 CJ1 5: C-3 ° era CO ° 1-* ►— »CO 1 1 2 CO CJ1 t ~ * = ΓΌ Ca» CJI t ~-1 «=» ΓΌ C = 3 c = &gt; c * n 1 a% ►— · 1 o cn &gt; CO era t ~ »CZ3 C = &gt; CO ezr» c = &gt; CJ, 5: &lt; = »&lt; = Z3 CO t cz = &gt; C = 3 CO C7T &gt; &lt; =» — ·! 1 1 0. 03 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 f. 1 Ί 1 1 1 I 1 1 1 1 1 1 1 1 1 1 1 1 cz ^ :, I 1 cz- ί ic · 1 1 i 1 1 1 1 1 1 1 cz &gt; 1 1 CT3 Cd &gt; 1 1 »: Two J 〇 ·-1 1! 1 1 I 1 1 1 1 i 1 1 1 1 1 N 1 CJ ^ J… 1 1 cz--i 1 1 i 1 &lt; I j 1-:-: j 1 1 1 1 I s ·. O yzj &lt; o «• 二. &Lt; 〇 '、 二- 1 1 '-j «« TD CJ lo 1- * 1 1 1' '&lt; c ~ · c 二-cz ^ ΙΌ ί-二 c. 二 &lt; 卞 ί 1 屮 1¾ 雅 阄; # cage0 &gt;. ^ &gt;-$ 薛 妈 &lt; »_% &gt; | 劾 &lt; 6 驾 箪 0 &gt; Open $ Array Ma (» »*) S i C u ζ η I η 一 S n F e A 1 S i F ef C u AZ η I n S η M g ί Μ π N:.: crj .Ϊ 「一 -Τ ί A 1

....................................................................................裝..................訂.....................線 •L諳先注意事項再填寫本頁) 洳 42 ! I -82- 本紙張尺度適用中國國家標準(CNS)甲4规格(210X297公梦).................................................. ................................. install ............... ... Order ..................... Line • L first notice before filling this page) 洳 42! I -82- This paper size is for Chinese Standard (CNS) A 4 specifications (210X297 Gongmeng)

6 B 經濟部中央標準局員工消費合作社印製6 B Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

mn n V*r CT CT&gt; GT&gt; Ca» cr&gt; CO CT&gt; cr&gt; tn &lt;£&gt; cn OO CXI C^l cn CXI on CXI CJl Ca&gt; c-n CO c-n C^l s s s; CO 〇〇 *—» »—» G&gt; CT&gt; »—* c=&gt; 令 夂 A 交 CO OO 1 1 G» CJ1 1—-* &lt;-〇 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 cm c=&gt; 03 oo 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 i 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 c=&gt; % ° ί c=&gt; ΐ: i C=3 c_n ·= = t* c=&gt; c-r* era 〇-&gt; c=&gt; Λλ. &lt;=3 cza cr» &lt;T3 c-n c=» cn era CZ3 crs = 1—» »—* »—* C=3 I~* $ »—* 1 o era = era iza OO era CG» ►—* c^&gt; ►—» CO c=&gt; &lt;=&gt; cr» t—* 1* eo c-n 1-- 1 OO : 1 二 - OO cr&gt; CZ3 c=&gt; era C=&gt; c=&gt; era 1 &lt;=&gt; ro I CZ3 CO o —-) c=&gt; C=3 C-Γϊ $ c=» CO 1 CT3 ΓΌ 1 ! Ί 1 1 1 1 1 1 1 1 1 1 1 1 t 1 1 CZ3 C=3 1 1 I 1 1 1 1 1 1- 1 1 1 era ds&gt; OO 1 c=&gt; e=z&gt; OO 1 1 r- ! I 1 1 1 1 1 1 1 1 era &lt;zz&gt; d3&gt; &lt;)〇 c~&gt; 1 1 1 1 1 i: CZj CD - CZJ -¾ &lt; 、、 = : 1 : &lt;=&gt; CU 1 1 1 1 I 1 1 l i 1 1 1 &lt;Zj cy cc 1 1 i o cn 1 1 &lt;z&gt; era Cl. &lt;Z- CJ^· OP dp o cr&gt; c-n i era 1 ^ d_i CTj* &lt;TTi OO 1 1 1 1 cr&gt; CP co C=&gt; &lt;z&gt; 1 Cn &lt;3&gt; i: 二.-J ΙΌ &lt;3/ 1 c=&gt; 1 o r^4&gt; 1 i: s •Kmn n V * r CT CT &gt; GT &gt; Ca »cr &gt; CO CT &gt; cr &gt; tn &lt; £ &gt; cn OO CXI C ^ l cn CXI on CXI CJl Ca &gt; cn CO cn C ^ lsss; CO 〇〇 * — »» — »G &gt; CT &gt;» — * c = &gt; Lingsuo A pays CO OO 1 1 G »CJ1 1 —- * &lt; -〇1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 cm c => 03 oo 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 i 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 c = &gt;% ° ί c = &gt; ls: i C = 3 c_n · = = t * c = &gt; cr * era 〇- &gt; c = &gt; Λλ. &Lt; = 3 cza cr »&lt; T3 cn c = »cn era CZ3 crs = 1—» »— *» — * C = 3 I ~ * $ »— * 1 o era = era iza OO era CG» ►— * c ^ &gt; ►— » CO c = &gt; &lt; = &gt; cr »t— * 1 * eo cn 1-- 1 OO: 1 two- OO cr &gt; CZ3 c = &gt; era C = &gt; c = &gt; era 1 &lt; = &gt; ro I CZ3 CO o —-) c = &gt; C = 3 C-Γϊ $ c = »CO 1 CT3 ΓΌ 1! Ί 1 1 1 1 1 1 1 1 1 1 1 1 1 t 1 1 CZ3 C = 3 1 1 I 1 1 1 1 1 1- 1- 1 1 1 era ds &gt; OO 1 c = &gt; e = z &gt; OO 1 1 r-! I 1 1 1 1 1 1 1 1 1 era &lt; zz &gt; d3 &gt; &lt;) 〇c ~ &gt; 1 1 1 1 1 i: CZj CD- CZJ -¾ &lt;,, =: 1: &lt; = &gt; CU 1 1 1 1 I 1 1 li 1 1 1 &lt; Zj cy cc 1 1 io cn 1 1 &lt; z &gt; era Cl. &Lt; Z- CJ ^ · OP dp o cr &gt; cn i era 1 ^ d_i CTj * &lt; TTi OO 1 1 1 1 cr &gt; CP co C = &gt; &lt; z &gt; 1 Cn &lt; 3 &gt; i: II.-J ΙΌ &lt; 3/1 c = &gt; 1 or ^ 4 &gt; 1 i: s • K

鞣荖:IT co Ο c tsi 3 cnπ &gt;Tanning: IT co Ο c tsi 3 cnπ &gt;

1 a&gt; Ο 匚 tM1 a &gt; Ο 匚 tM

ω 口 〇QS &gt; ¾}¾¾¾卟睁® 薛妈 &lt;__%&gt; 筠亡¾萃D&gt;^s餌a&lt;w_%&gt; (請先閲讀背面之注意事项再填寫本頁) 本紙張尺度適用中國國家標準(CNS)甲4規格(210x297公釐) A6 B6 五、發明説明() 表44 經濟部中央標準局员工消費合作社印製 散熱片 硬焊的加 下垂量 硬焊的加 下垂量 材料 熱條件 捣诳度 敗熱Μ 材料 熱條件 編號 (x^m) (毫米)_ WACS 编號 (Χ5鴻) (毫米) Vi ACS 1 fiSII &quot;C 8 Γ.3 % S75 \: 1 5 7¾ nC ID &quot; Η // &quot; Η 3 &quot; // 發 21 58 0 °C II &quot; \ 58 0 °C 12 &quot; 明 28 〃 // 53 5 5 7 5 °C 8 // 萁 29 ff If 6 // ·· 〃 30 // &quot; &quot; 例 Ί 〃 〃 // 31 〃 〃 53 8 〃 〃 53 32 // // U 9 // 〃 &quot; 33 575 V 9 〃 10 580 V 10 55 600 T: 30 5! 11 575 °C 8 &quot; 35 u &quot; 50 12 〃 ft 36 &quot; 51 13 // // 53 31 // 30 // Μ // 〃 38 &quot; 35 // 15 〃 It 55 比 39 〃 “ &quot; 16 // 〃 53 較 ff 30 52 17 580 °C 11 U 〃 f/ 51 18 u 〃 55 貧 〃 〃 19 // // 例 43 /t 30 fr 20 5 7 5 eC 8 〃 “ 〃 35 〃 21 // 〃 53 &quot; // &quot; 22 58(J °C 11 5為 fr Ο &quot; 23 &quot; 〃 // &lt;7 // 30 〃 〃 // 53 〃 35 〃 (諳先閲讀背面之注意事項再堉寫本頁) —裝. .11. 本紙張又度適用中國國家標準(CNS)甲4规格(210 X 297公* ) 82. 9. 6,000 五、發明説明(83 ) A6 B6 經濟部中央標準局貝工消费合作社印製ω 口 〇QS &gt; ¾} ¾¾¾Porrel® Xue Ma &lt; __% &gt; 歠 死 ¾Extract D &gt; ^ sbait &lt; w _% &gt; (Please read the precautions on the back before filling this page) The scale is applicable to the Chinese National Standard (CNS) A4 specifications (210x297 mm) A6 B6 V. Description of invention () Table 44 The amount of sag added to the heat sink printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Thermal conditions of the material are unsatisfactory. Μ Thermal condition number of the material (x ^ m) (mm) _ WACS number (Χ5 鸿) (mm) Vi ACS 1 fiSII &quot; C 8 Γ.3% S75 \: 1 5 7¾ nC ID &quot; Η // &quot; Η 3 &quot; // Fat 21 58 0 ° C II &quot; \ 58 0 ° C 12 &quot; Ming 28 〃 // 53 5 5 7 5 ° C 8 // 萁 29 ff If 6 // ·· 〃 30 // &quot; &quot; Example Ί 〃 〃 // 31 〃 〃 53 8 〃 〃 53 32 // // U 9 // 〃 &quot; 33 575 V 9 〃 10 580 V 10 55 600 T: 30 5! 11 575 ° C 8 &quot; 35 u &quot; 50 12 〃 ft 36 &quot; 51 13 // // 53 31 // 30 // Μ // 〃 38 &quot; 35 // 15 〃 It 55 to 39 〃 "&quot; 16 // 〃 53 compared to ff 30 52 17 580 ° C 11 U 〃 f / 51 18 u 〃 55 poor 〃 〃 19 // // Example 43 / t 30 fr 20 5 7 5 eC 8 〃 “〃 35 〃 21 / / 〃 53 &quot; // &quot; 22 58 (J ° C 11 5 is fr Ο &quot; 23 &quot; 〃 // &lt; 7 // 30 〃 〃 // 53 〃 35 〃 (Remember to read the precautions on the back Rewrite this page) — installed. .11. This paper is again applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 g *) 82. 9. 6,000 V. Description of the invention (83) A6 B6 Central Ministry of Economic Affairs Printed by Peking Consumer Cooperative

&lt;^η CT5 c_n cjn Cjn cr&gt; 0^9 cjn CN3 4 cj-&gt; i-n 1 —— -^=3 1 --=3 散熱片 材料 编號 1 1 硬焊的加 熱條件 (X盼鐘) Γ,ΟΟ τ. // •A·- c_n 〇〇 ς-η C-J 下垂量 (毫米) c_n CJ1 CVD cj-» 導m度 窆W n' σ&gt; 〇» CO 〇&gt; CO CT&gt; cn c-n CO ς,η ΟΟ 散熱片 材料 编號 610 °C 600 °C 610 °C 無法製成硬焊片散熱片 '、 1 I MO Τ: ' IS ____________________ i 硬焊的加1下垂量 熱條件 (Χ5分鐘)(毫米) cj-&gt; c&gt;o c*n c-n c_n c=&gt; C-Γ» &lt;!&lt;0 0&quot;S tr» oo CJ-1 &lt;Ln CJ~* — 導带度 MACS ..................................................................................裝......................訂.....................線 &lt;請先閱讀背面之注意事項再填窝本頁) 本紙張尺度適用中國國家標準(CNS)甲4规格(210x297公釐) 經濟部中央標準局員工消費合作社印製 A6 B6 _ 為ρ發明説明(84 ) 由表4 4和4 5中可明顯的看出,在本發明實例中的物品 (第】-33號),同時具有優良的下垂性質優良的導電度。 這是因為硬焊Η散熱片的硬焊材料之熔點低的緣故,因 此測試的溫度也設定在較低的溫度。然而在比較實例中 的物品(34-59號、61號、62號),其下垂性質和導電度 皆差β這是因為硬焊片散熱片之硬焊材料的熔點高的緣 故,潮試溫度也因而設定在硬焊溫度之熔點- 6Q(TC或 610 °C的較高溫度。在比較實例中的物品(第60號),在 硬焊材料中所添加的銅和鋅,其用鼍比本發明所列的範 圍要高,因而會發生滾軋破裂的現象,而使其無法加工 成硬焊Η。優異的數俏。 例9 將具有表4 6中所列之組成的散熱Η材料A - C和管材a - c 予以接合,以組成圖2中所示的冷卻器。散熱Η材料為 0.12毫米厚的硬焊片散熱Η材料(其偽在組成為表46中 所示之核心材料的兩側,鍍上厚度為1 0 %的硬焊材料) ;並目管材為以擠壓裸材(其含有如表4 6中所示之合金 紐成)的方式所製成1 6 . 0毫米寬的多孔管在冷卻器h ,將含有3 %絶型肋熔劑和氟化鉀型肋熔劑之混合物的 肋熔劑液體(濃度為1 〇 % )塗佈h去,並於氛氣中進行硬 焊加熱。這樣所_得的冷卻器,將⑽由外表的觀察來研 究散熱片的崩潰狀態及其硬焊性。此外,也將測最管子 的抗張強度。此外,硬焊好的冷卻器,將依,1 I S D 1 8 -8 6 - (請先閲讀背面之注意事項再填寫本頁) 裝 訂 本紙張尺度適用中國國家標準(CNS)罗4規格(210X297公釐) A6 B6 效 熱 其 量 測 來 定 規 之 式 方 試 測 的 機 氣 暖 5)冷 8 ί之 月 Jml 説气 明 發於 、用 五'— 做和 率料 效材 熱之 之用 器使 換所 交有 熱列 的時 统同 傳且 與並 將 , 率中 效47 熱表 的於 出列 。 量果件 測結條 所 e 的 C 較熱 4 率比加表 {請先閲讀背面之注意事項再填 合金 的編 號 硬焊材料合金的組成(蜇負% &gt; 梭心材料合金的組成 &lt;踅量%&gt; Si C υ Z η F c Λ 1 Si F e C u Z n Μ n N i Z r T i Λ 1 散熱片 村料 Λ II. 0 2. 5 u 0. 2 ws 0. 5 1. 0 0. 5 0. 5 1. 2 — 0. 6 0. 10 0, 01 η 9. 8 一 — 0. 6 // 0. 2 0. 04 i. 1 1. i 0. 6 0. 10 // &quot; // 〃 &quot; c &quot; - — &quot; ft 0. 5 1. 0 0. 5 1. 2 — 管材 a - — — — — i. 8 0. 5 - — 1. I 0. 20 — 0. 18 b - — — - — U ff 0. 8 — ft 0. 15 - 0. 11 // c — — — — — 0. 3 // 0. 15 — ft — — 0. 01 &quot; -裝 表 訂 經濟部中央標準局貝工消費合作社印製 编 OJa 彌 散熱Η 的合金 编號 管子的 合金 编號 硬焊溫 度。c (X 5分鐘) 崩潰 位置 硬焊 性 熱效率 餘勺 杭張 強度 發明奮例 ① A a 580 無 良好 卜b⑤增加2.5%Wt: 170MPa ② A b Η If Η Η 22f)MPa 卜b較啻例 ③ C c fiOO Μ Μ &quot; 130MPa ④ Γ h II 管子 Μ 無法測量 - 傳統宵例 ⑤ Β c ” 無 Μ 標準 130MPa 對於管子④,無法進行熱效率的測最和張力測試,因其 存硬焊加熱時熔解掉了。 -8 7 - 本紙張尺度適用中國國家標準(CNS)甲4規格(210X297公釐) A6 B6 五、發明説明(8b ) 由表47可很明顯的看出,本發明實例中的①號和②號 物品,不會引起散熱Η崩潰的問題,且具有良好的硬焊 性及優良的熱效率。卽使是以含有1.2重量% (或更多)的 矽之鋁合金做為管子,也能維持高的強度而不會熔解。 然而,在比較實例中的③號和④號物品,傺使用傳統 的硬焊材料,並且硬焊溫度為6 0 0 °C。比較實例③所具 有的強度低,並目在比較實例④的物品中,由於管子所 使用的鋁合金中含有1 · 2重量% (或更多)的矽,且硬焊 溫度高達6Gfl°C,管子會開始熔解。 如前所述,依照本發明,由於構成用來製造鋁合金熱 交換器之硬焊Η的硬焊材料之熔點低,所以可在較低的 溫度下進行硬焊,因此硬焊片散熱片材料之彎曲現象和 導熱度之降低等琨象,發生的機會較低,而使得其能夠 將散熱片的壁變薄。除上之外,當使用此種硬焊片做為 管材或平板材料時,這些成份將具有高強度,a耐蝕性 優異,而可使得管材和平板材料的荦等薄,且強度高, 因而對於熱交換器的撤型化和重最減輕,具有非常可觀 的效果。 裝......................訂.....................線 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 -88- 本紙張尺度逋用中國國家標準(CNS)甲4規格(210X297公釐)&lt; ^ η CT5 c_n cjn Cjn cr &gt; 0 ^ 9 cjn CN3 4 cj- &gt; in 1 ——-^ = 3 1-= 3 Heat sink material number 1 1 Heating conditions for brazing (X Panzhong) Γ, ΟΟ τ. // • A ·-c_n 〇〇ς-η CJ sag (mm) c_n CJ1 CVD cj- »Conductivity degree W n 'σ &gt; 〇» CO 〇 &gt; CO CT &gt; cn cn CO ς, η ΟΟ Heat sink material number 610 ° C 600 ° C 610 ° C Can not be made into a brazed fin heat sink ', 1 I MO Τ:' IS ____________________ i Brazed plus 1 sag calorimeter condition (Χ5minutes) (Mm) cj- &gt; c &gt; oc * n cn c_n c = &gt; C-Γ »&lt;! &Lt; 0 0 &quot; S tr» oo CJ-1 &lt; Ln CJ ~ * — conduction band MACS .. .................................................. ........................ Pretend ........................ ... Order ..................... Line &lt; Please read the precautions on the back before filling this page) This paper size is applicable to the Chinese National Standard (CNS ) A4 specifications (210x297 mm) A6 B6 printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs _ Description of the invention (84) It can be clearly seen from Tables 4 4 and 4 5 Examples of items in the present invention (No. -33] s), and having excellent sag properties superior conductivity. This is because the melting point of the brazing material of the brazing H heat sink is low, so the test temperature is also set at a lower temperature. However, in the comparative example (34-59, 61, 62), the sagging properties and conductivity are poor β. This is because the melting point of the brazing material of the brazing fin heat sink is high, the temperature of the moisture test Therefore, it is set at the melting point of the brazing temperature-6Q (TC or 610 ° C higher temperature. The article in the comparative example (No. 60), the copper and zinc added in the brazing material, the use of mole ratio The range listed in the present invention is higher, so that the phenomenon of rolling cracking occurs, which makes it impossible to process into brazing H. Excellent number. Example 9 A heat dissipation H material A having the composition listed in Table 4 6 -C and pipes a-c are joined to form the cooler shown in Fig. 2. The heat dissipation material is 0.12 mm thick brazed heat dissipation material (the composition of which is the core material shown in Table 46 Both sides are plated with a brazing material with a thickness of 10%); and the mesh tube is made by extruding bare material (which contains alloy buttons as shown in Table 46) by 16.0 mm The wide porous tube in the cooler h will contain a rib flux liquid containing a mixture of 3% absolute rib flux and potassium fluoride rib flux ( Degree is 10%) apply h, and braze heating in the atmosphere. The cooler obtained in this way will be ⑽ from the external observation to study the collapse state of the heat sink and its brazing property. In addition, The tensile strength of the most tube will also be measured. In addition, the hard-welded cooler will be based on, 1 ISD 1 8 -8 6-(please read the precautions on the back before filling this page) The size of the bound paper is suitable for China Standard (CNS) Luo 4 specifications (210X297 mm) A6 B6 Efficacy and heat measurement to determine the test of the machine gas warmth 5) Cold 8 LM of the month Jml said that the gas is bright, use five '-do and The device that heats the material and heats the material is used for simultaneous exchange and exchange with the heat column, and the heat table with the efficiency of 47 is listed. Calculate the C hotter rate of the test piece by measuring the pieces. 4 Please add the table {please read the precautions on the back first and then fill in the alloy number of the brazing material alloy composition (sting negative% &gt; composition of the bobbin material alloy &lt;踅 量%> Si C υ Z η F c Λ 1 Si F e C u Z n Μ n N i Z r T i Λ 1 Heat sink material Λ II. 0 2. 5 u 0. 2 ws 0.5 1. 0 0. 5 0. 5 1. 2 — 0. 6 0. 10 0, 01 η 9. 8 a — 0. 6 // 0. 2 0. 04 i. 1 1. i 0. 6 0. 10 // &quot; // 〃 &quot; c &quot;-— &quot; ft 0. 5 1. 0 0. 5 1. 2 — Tube a-— — — — i. 8 0. 5-— 1. I 0 . 20 — 0. 18 b-— —-— U ff 0. 8 — ft 0. 15-0. 11 // c — — — — — 0. 3 // 0. 15 — ft — — 0. 01 &quot;-The table number is bound and printed by the Ministry of Economic Affairs, Central Standards Bureau, Beigong Consumer Cooperatives, and the alloy number of the OJa heat dissipation alloy is brazed. C (X 5 minutes) Crash position brazing performance thermal efficiency Examples of strength invention ① A a 580 no good bu b ⑤ increase 2.5% Wt: 170MPa ② A b Η If Η Η 22f) MPa b b comparison example ③ C c fiOO Μ Μ &quot; 130MPa ④ Γ h II tube Μ cannot be measured-traditional example ⑤ Β c ”without Μ standard 130MPa For the tube ④, the thermal efficiency measurement and tensile test cannot be performed, because it is melted when brazed and heated -8 7-This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210X297 mm) A6 B6 V. Description of the invention (8b) From Table 47, it can be clearly seen that the ① and Article ② does not cause the problem of heat dissipation Η collapse, and has good solderability and excellent thermal efficiency. Even if an aluminum alloy containing 1.2% by weight (or more) of silicon is used as a tube, it can also be maintained High strength without melting. However, in items ③ and ④ in the comparative example, Ye uses traditional brazing materials and the brazing temperature is 600 ° C. Comparative example ③ has low strength, And in the article of Comparative Example ④, since the aluminum alloy used in the tube contains 1.2% by weight (or more) of silicon, and the brazing temperature is as high as 6Gfl ° C, the tube will start to melt. As described above, according to the present invention, since the brazing material constituting the brazing material for manufacturing an aluminum alloy heat exchanger has a low melting point, it can be brazed at a relatively low temperature, so the brazed fin material The bending phenomenon and the reduction in thermal conductivity are less likely to occur, which makes it possible to thin the wall of the heat sink. In addition to the above, when using such a brazed sheet as a pipe or a flat material, these components will have high strength, excellent corrosion resistance, and can make the pipe and flat material thin and high strength, so for The dismantlement and weight reduction of the heat exchanger is the most reduced, and it has a very considerable effect. Install ................... Order ............... Thread (please read first Note on the back and then fill out this page) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs -88- This paper uses the Chinese National Standard (CNS) A4 specifications (210X297 mm)

Claims (1)

圍範 tuw 專請 中 過 超 不 及 上 以 % 量 ibnll 3 ABCD 和 鈦 的 % 量 ibnll 3 合 鋁 用 使 層 ~ 括 0 包 族其 鎳 , 的 Η %焊 量硬 5 合 1.鋁 過用 超器 不換 及交 上熱 以種 %1 6 5 的 2% 過量 超重 不 5 且 2 上過 以超 %不 S:且 重上 6 以 0 % 有量 含重 其 5 , 8 料 、 材矽 心的 核% 的量 s 過 超 不 且 上 以 % 量 If 1 -B 其 錳 的 % 量 —hmi S 側 兩 其7· 在有 且含 並料 ; 材 質焊 雜硬 的種 免該 避 -可料 無材 些焊 一 硬 和金 鋁合 為鋁 Θ 則層 0份一 、成上 銅餘鍍 S 過 超 不 且 上 以 % 量 矽 的 % 量 S 上 以 % 量 重 過自 超選 不種 且 一 上少 以至 % 有 量含 05步 0 一 、 進 銅更 的及 % 以 量 , 重鐵 0 I • 的 超量 不S 且0. 質 物 之 素 0 元 、 下鋅 以的 量 s 2 0 -----------衣-- (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消费合作社印製 % 量 、 ^ 0 5 的 過% 超量 不重 且.3 上 以 % 量 Ρ 過 且 W- 過 超 不 且 上 以 不 且 上 以 % 置 S 的 餘 其 錫 的 % 量 ΒΒ 5 心重 核 5 該 0 中過 其超 , 不 Η 及 。焊上 質硬以 雜金% 的合量 免鋁重 避之03 可項0. 無 6 自 些 &gt; 第選 一 〃圍種 和範一 鋁利含 為專包 則請尚 份申料 成如材 絡重及 的03上 % 0 以 量 、% 重結量 Sthnll S 0.%03 過量0. 超重和 不 3 欽 及 0 的 上過% 以超量 %不重 量及3 重上 3 乂 0 ΐ 0 % 、量 鎂重 J 3 的 0 % 0 量 、量 過 超 不 及 上 以 族 鎳 的 % 量 3 訂 合 5 用過 使超 層不 1 且 括上 包以 其 % -量 Η 重 焊03 / · 硬 0 金有 合 含 鋁其 用 , 器料 換材 1.交心 過熱核 超種的 不 一 金 8 本紙張尺度適用中國國家標準(CNS ) A4規格(2丨0X297公釐)Wei Fan tuw specially requested that it should be less than or equal to the amount of ibnll 3 ABCD and titanium. The amount of ibnll 3 is used for aluminum alloy ~ including 0 package of its nickel, the H% welding volume is hard 5 in 1. aluminum is used over Don't change the device and put it on the heat to 2% of the% 1 6 5. Excessive overweight is not 5 and 2 is overweight but not over S: and the weight is 6 to 0%. It contains 5, 8 materials and materials. The amount of the core% of the s is too much and not more than the amount of If 1 -B The% of its manganese-hmi S side two of the seven 7. In the presence and inclusion of the material; the welding of hard and hard materials is not to be avoided-expected If the material is not welded, the hard and the gold and aluminum are combined into aluminum Θ, then the layer is 0 parts. One, the copper is over-plated, the S is over, and the amount of silicon is%, and the amount of S is over%. One is as low as%, and the amount contains 05 steps 0. One, more copper and more than%, heavy iron 0 I • The excess is not S and 0. The quality of the element is 0 yuan, and the amount of zinc is s 2 0- ---------- Clothing-- (Please read the precautions on the back before filling out this page) Printed by the Ministry of Economic Affairs Central Standards Bureau Employee Consumer Cooperative,% volume, ^ 0 5 over% The excess is not heavy and .3 is over the amount of P and the W- is over the excess and the upper is not over and the% is the% of the rest of the tin that sets S. Β 5 Core heavy core 5 The 0 is over its excess, not Η and. Welding quality is hard and the amount of miscellaneous gold% is free of aluminum. 03 can be 0. No. 6 Since some &gt; The first selected 〃 surrounding species and Fan Yili are included as special packages, please apply for a material. 0% of the weight of 0% of the weight that is equal to 0%, and the amount of the weight of the weight of Sthnll S 0.% 03 excess 0. Overweight and not 3. Overweight percentage of 0 and 3%. , The amount of magnesium is 0% of the weight of J3, the amount is too much less than the% of the upper group nickel. 3 The combination of 5 is used, the super layer is not 1 and it is covered with its%-amount H. Rewelding 03 / · Hard 0 Gold has a combination of aluminum and its materials are used for material replacement. 1. Super-core super-heated super-different gold 8 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (2 丨 0X297mm) 第83 1 00779號「鋁合金硬焊材料及熱交換器用硬焊Μ及 鋁合金熱交換器之製造法」專利案 (85年9月14日修正) 杰申請專利範圍: 1. 一種鋁合金硬焊材料,其含有7.0重量%以上且不超 過12.0重量S;的矽、0.5重量!1;以上且不超過8.0重量% 的銅、0.05重量%以上且不超過0.5重量%的鐵,以 及更進一步的含有至少一種選自以下元素之物質: 0.5重量%以上且不超過5.5重量%的鋅、0.002重量 %以上且不超過0 . 3重量%的铟、和0 . 002重量%以 上且不超過0.3重量%的錫,其餘的成份則為鋁和一 些無可避免的雜質。 經濟部中央標準局員工消费合作社印繁 (請先閱讀背面之注意事項再填寫本頁) 2. —種鋁合金硬焊材料,其中含有7.0重量%以上且不 超過12.0重量%的矽、0.8重量%以上且不超過3.0 重量S;的銅、0.05重量%以上且不超過0.4重量%的 鐵,1.0重量%以上且不超過5.0重量%的鋅,或者 是更含有一或兩種0.002重量%以上且不超過0.05重 量%的絪和0.002重量%以上且不超過0.05重量%的 錫,其餘的成份則為鋁和一些無可避免的雜質。 3. —種熱交換器用鋁合金硬焊Η,在此種硬焊Η中具有 三層結構,其係在鋁合金所構成的核心材料之一側鍍 上一層含有鋁合金的硬焊材料,並且在另一側鍍上一 靥含有鋁合金的犧牲性材料,其中鋁合金的硬焊材料 -1 - 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) 六、申請專利範圍 過 有¾.超 含量不 A8 B8 C8 D8 矽 的 重且 1 5上少 0以至 、%有 量含 LL 5 -量 0 步 lil . 一 3 θ I fe£ 、 通 12銅更 過的及 超 % 以 不量 , 且重鐵 上.0的 I 8 p 1¾¾ %超量 量1重 3 過 超 不 且 上 以 質 物 之00 素 0 元 、 下鋅 以的 自% 選量 種重 置 tgl 一 ΡΠ 5 的 過% 超量 不重 1 3 且 . SJ- 上 以 % 量 S 過 超 不 且 上 以 和 、 絪 其 易 的 % 量 —Ifnlt 8 3 Θ 過 超 不 且 上 以 % 量 limit S 和 鋁 為 0 則有 份含 成料 的材 餘心 質51銅 栽 2 序 的過% 免超量 避不重 可且5 無上1§2 ⑭一⑶超 量不 重且 6上 以 % 量 ΡΠ 核 的 金 合 鋁 矽 的 ¾ 量 B ΡΠ % 量 —?二 S (請先閲讀背面之注意事項再填寫本頁) i 質 2 雜 過的 超免 不避 且可 上無 以些 和 鋁 為 則 份 成 餘 其 錳 的 % 量 thnlt S 至 有 含 則 料 材 性 牲 犧 的 金 合 鋁 少過 超 不 且 上 以 % 量 ilwit 3 5 0 質 物 之 素 元 下 以 自 選 種 過 超 不 且 上 以 % 量 B ΡΠ 2 Θ 0 0 、 鋅 的 % 量 ί 0 為第 0.則圍 和份範 、成利 絪餘專 的其請 % ,申 量錫如 以 % 量α 重si 2 錦 過 超 不 且 上 的 牲 % 犧 量 該 重 。中 3質其 雜 , 的 Η 免焊 避硬 可金 無合 些鋁 一 之 項 3 訂 經濟部中央標準局負工消费合作社印製 少和 至鎂 含的 包%。 尚量族 料重錳 材 LO 的 性 2¾ 種 1 0 過量 超重 不 6 及1. 上過 以超 %不 置及 重上 5 ΙΛ 0 以 0% 自量 選重 其及 , 上 Η 以 焊% 硬量 ΡΠ 1·3 合 0 銘 0 之自 項選 _Γ CRE 4 種 第一 或少 項 3 第包 圍尚 範料 利材 專、ίϋ 請核 申該 如中 至 含 過絡 超的 不% ίι 的 % 量 3 過 超 不 及 % 量 S 過 超 不 及 上 以 % 量 3 置 5 量 、 W 吐α 3 J * 的 % 本紙張尺度逋用中國國家標準(CNS } A4規格(210X297公釐) 295604六、申請專利範圍 量 、 重鐵 矽 的 % 量 E 3 且 上 以 % 量 thnil S 的 6 ^0 量, &amp;&amp; {VS* S 發 Θ 的 2 % 過量 超重 不0 2 且 上 過 步且 一 上 進以 更% 及量 以重 5 , QD Μ Θ 的 ·· % 質 量物 重的 0 下 2 以 過自 超選 不種 且 一 上少 以至 % 有 量含 重的 量 S 和 洇 5 的 過% 超量 ΡΓ S 鋅 的 0 t 的 1Θ% is* iR 6 1 hr 3 且 0 上過 以超 %不 量且 重上 2 乂 0&quot; 0 .% 量 S 在有 且含 並料 材 質焊 雜硬 的種 免該 避 , 可料 無材 些焊 1 硬 和金 鋁合 為鋁 則層 份一 成上 餘鍍 偵 , 兩 錫其 矽 的 % 量 Umtl S 0 2 1X 過 超 不 且 上 以 % 量 tgc 3 0 7 ¾ 量 B S 不種 且一 上少 以至 %有 量含 05步 0.一 、進 銅更 的及 %以 量 , 重鐵 0的 1§8% 量 βυ 超重 不S 且 0 上過 以超 物 8 之 0 素 0 元 、 下鋅 以的 自% 選量 質 WS 不 且 0 上過 以超 %不 量且 重上 5·以 0 % 量 過 超 置 Ε 3 «因 箱 5 J • 的 13 % n i— I -- - In I 尤水 I (請先閱讀背面之注意事項再填寫本頁) 訂 過 超 不 且 上 以 % 量 I 3 和 鋁 為 nu 貝 份 成 的 餘 其 錫 的 ¾ 量 0 重質 3 i . 雜 的 免 避 可 無 些 8 片 焊 硬 金 合 銘 0 之自 項選 8 種 第 一 、 圍少鎂 範至的 利含% 專包量 請尚重 申料 5 如材 0 9 量 S 3 0 心 核 該 中 其 經濟部中央標準局員工消费合作社印製 上 以 % 量 重 3 8 0 量 過重 超 3 不 0 及過 上超 以不 %及 及 2 上過 03以超 0%不 、 量 及 鉻重上 的03以 %0% 過 超 不 及 上 以 % 量 tbml S 結 的 % 量 ΡΠ 和 鈦 的 % 0 量族 Ws^ 芻 3 J , 的 0 過% 量 超 ift S i hr 0 量 S 鋁 用 使 層 1 括 包 其 Η 焊 硬 金 合 鋁其 用 -器料 換材 交心 熱核 種的 1 金 . 合 過 超 不 且 上 以 % 置 In 3 3 0 0 有 含 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) A8 295604 cl D8 六、申請專利範圍 2.5重置%的矽、0.05重S%以上且不超過2.0重量% 的鐵、0.05重量%以上且不超過2.0重量%的銅,以 及更進一步的含有至少一種選自以下的物質:0.05重 量%以上且不超過5.0重量%的鋅、0,002重量%以上 且不超過0.3重量%的洇和0 . 00 2重量%以上且不超過 0.3重量%的錫,其餘成份則為鋁和一些無可避免的 雜質;並且在其兩側鍍上一層鋁合金硬焊材料,該種 硬焊材料含有7.0重量%以上且不超過12.0重量%的 矽、0.5重量%以上且不超過8.0重量%的銅、0.05重 量%以上且不超過0.5重量%的鐵,以及更進一步的 含有至少一種選自以下元素之物質:0.5重量%以上 且不超過5.5重置%的鈴、0.002重量%以上且不超過 0.3重量%的絪和0.002重量%以上且不超過0.3重量% 的錫,其餘的成份則為鋁和一些無可避免的雜質。 ί 11 .如申請專利範圍第1 0項之鋁合金硬焊Η ,其中該核 心材料尚包含至少一種選自0.03重量%以上及不超過 0.5重量%的鎂、0.03重量X以上及不超過0.6重量% ----------士取-------1T (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標隼局員工消費合作社印裝 量 —hnlt、 3 結05 的 0 %和 量鈦 3 % 0 量 過重 超 3 不 0 及過 上超 以不 ¾及 量上 重以 03% 0 量 S、 3 猛03 的0. 族 鎳 的% 置 E S Θ 2 過 超 不 及 上 以% 本紙張尺度適用中國國家標準(CNS &gt; A4規格(210X297公釐)Patent Case No. 83 1 00779 "Aluminum alloy brazing material and manufacturing method of brazing M for heat exchanger and aluminum alloy heat exchanger" (Amended on September 14, 1985) Jie applies for patent scope: 1. A kind of aluminum alloy hard Welding material, which contains more than 7.0% by weight and no more than 12.0% by weight of silicon; 0.5% by weight! 1; more than and not more than 8.0% by weight of copper, 0.05% or more and not more than 0.5% by weight of iron, and further containing at least one substance selected from the following elements: more than 0.5% by weight and not more than 5.5% by weight Zinc, 0.002 wt% or more and not more than 0.3 wt% indium, and 0.002 wt% or more and not more than 0.3 wt% tin, the remaining components are aluminum and some inevitable impurities. Printing and Propagation by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling in this page) 2. A kind of aluminum alloy brazing material, which contains more than 7.0% by weight and no more than 12.0% by weight of silicon, 0.8% % Or more and not more than 3.0% by weight S; copper, 0.05% or more and not more than 0.4% by weight iron, 1.0% or more and not more than 5.0% by weight zinc, or one or two kinds of 0.002% by weight or more And not more than 0.05% by weight of 絪 and 0.002% by weight and not more than 0.05% by weight of tin, the remaining components are aluminum and some inevitable impurities. 3. A type of aluminum alloy brazed Η for heat exchanger, which has a three-layer structure, which is coated with a layer of brazed material containing aluminum alloy on one side of the core material composed of aluminum alloy, and A sacrificial material containing aluminum alloy is plated on the other side, of which the brazing material of aluminum alloy-1-This paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (210Χ297mm) ¾. Excess A8 B8 C8 D8 silicon is heavier and less than 1 or less than 15%, 5% contains LL 5-amount 0 step lil. A 3 θ I fe £, pass 12 copper and over% not The amount, and the heavy iron. 0 I 8 p 1¾¾% excess amount 1 weight 3 excess excess and above the quality of the 00 element 0 yuan, the following zinc to select the amount to reset tgl-ΡΠ 5 over % Overweight does not weigh 1 3 and. SJ- on the amount of S is over the amount of S is not over and over, and the amount of easy-ifnlt 8 3 Θ over the amount of over limit and the amount of limit S and aluminum is 0 There is a portion of the remaining heart material of the material 51 copper plant 2 2% of the order is not overweight and avoidable, and 5 is superior 1 § 2 ⑭ 1 ⑶ Overweight and 6% of the aluminosilicate core with ΡΠ core of ¾ volume B ΡΠ% volume-? 2S (please read the precautions on the back before filling this page) i Quality 2 Miscellaneous Excessive unavoidable and can be used with some aluminum and the amount of the remaining manganese is thnlt S to less than the amount of aluminum alloy containing the material sacrifice. 5 0 Under the prime of the substance, the selected species is over the top and the top is the amount of B ΡΠ 2 Θ 0 0, and the amount of zinc is 0. No. Therefore, if the amount of tin is in%, the weight of si 2 is over 2%, and the weight is sacrificed. Among the three kinds of quality, the H is solder-free, hard to avoid, gold-free, and some aluminum-free. 3 Set a package that is printed by the Ministry of Economic Affairs, Central Standards Bureau, and the consumer cooperative to produce a package containing less than magnesium. The quality of the material of the heavy metal group LO is 2¾ kinds. 1 0 Excess excess weight is not 6 and 1. Over-exceeded by over-% and re-emphasized 5 ΙΛ 0 Selected by 0% and re-weighted, on Η by welding% Hardness ΡΠ 1 · 3 in 0 Ming 0's self-selection _Γ CRE 4 kinds of first or fewer items 3 first enveloping Shangfan materials and materials, ίϋ Please verify that the amount of the above is not less than 5% 3 Exceeding the amount of% S Exceeding the amount of% 3 Set 5 amount, W spit α 3% of J * This paper scale adopts the Chinese National Standard (CNS) A4 specification (210X297 mm) 295604 VI. Patent application Range amount, heavy iron silicon% amount E 3 and up to 6% of the amount of thnil S ^ 0, & &amp; {VS * S 2% of Θ excess excess weight is not 0 2 and go forward and step forward More than 5% of the weight, QD Μ Θ ··% of the mass weight of 0 under 2 is not selected from the super-selection, and is less than 1% of the amount of weight S and the excess of 5 The amount ΘΓ of zinc at 0 t is 1% of ΓΓ is * iR 6 1 hr 3 and 0 is over% but not overweight and is over 2% 0 quot; 0.% S It is necessary to avoid the welding of hard materials that are mixed with the material and the material is mixed. It is expected that some materials are not welded. 1 Hard and gold aluminum are combined into aluminum, and the layer is more than 10%. The amount of two tin and its silicon is Umtl S 0 2 1X Exceeding the maximum amount of tgc 3 0 7 ¾ The amount of BS is not planted and the amount is less than one percent. The amount contains 05 steps. 8% amount βυ is overweight but not S, and 0 is overweight, 0 is 0 element, 0 is zinc, and self-% is selected. WS is not over 0, overweight is over%, and overweight is 5 · 0%. Excessive reset Ε 3 «Because of the box 5 J • 13% ni— I--In I Youshui I (please read the precautions on the back and then fill out this page). Aluminium is nu shell parts and more than ¾ of its tin. 0 Heavy weight 3 i. Miscellaneous avoidance can be no more than 8 pieces of welded hard gold Heming 0. Choose 8 kinds of first, around less magnesium range. The amount of special contract, please reiterate the material 5 as the material 0 9 the amount S 3 0 The core of which is printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs % Weight 3 8 0 Overweight over 3 No 0 and over over 10% over and over 2 over 03 over 0% over 0% over weight and chromium overweight under 0% 0% over under overweight over tbml % Of S-junction ΡΠ and% of titanium 0 0 family Ws ^ 3J, 0% over 0% of ift S i hr 0 Amount of aluminum for layer 1 including its H-welded hard aluminum alloy 1 gold for materials exchanged to the core thermonuclear species. Excessive and over-performing and set in% In 3 3 0 0 Including the paper size Applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) A8 295604 cl D8 VI. Application Patent scope 2.5% by weight of silicon, 0.05% by weight or more and not more than 2.0% by weight of iron, 0.05% or more and not more than 2.0% by weight of copper, and further containing at least one substance selected from the following: 0.05 Zinc above 5% by weight and not more than 5.0% by weight, 0,002% by weight and not more than 0.3% by weight of plume and 0.002% by weight and not more than 0.3% by weight of tin, the remaining ingredients are aluminum and some Impurities to avoid; and a layer of aluminum alloy brazing on both sides It is expected that this brazing material contains 7.0% by weight or more and not more than 12.0% by weight of silicon, 0.5% or more and not more than 8.0% by weight of copper, 0.05% by weight or more and not more than 0.5% by weight of iron, and further Substances containing at least one element selected from the group consisting of bells with 0.5% by weight or more and not more than 5.5 reset%, 0.002% by weight or more and not more than 0.3% by weight, and 0.002% or more and not more than 0.3% by weight of tin The remaining ingredients are aluminum and some inevitable impurities. ί 11. The aluminum alloy brazing Η as claimed in item 10 of the patent scope, wherein the core material still contains at least one magnesium selected from 0.03% by weight or more and not more than 0.5% by weight, 0.03% by weight or more and not more than 0.6% by weight % ---------- Shitou ------- 1T (please read the notes on the back before filling this page) Printed quantity of employees' consumer cooperatives of the Central Standard Falcon Bureau of the Ministry of Economic Affairs—hnlt, 3 0% of the junction 05 and the amount of titanium 3% 0 The amount of excess weight is more than 3 not 0 and the amount of excess is less than ¾ and the amount of weight is 03% 0 The amount of S, 3% of the 3% of the 0. Nickel of the family set ES Θ 2 over Less than or equal to% This paper scale applies the Chinese national standard (CNS & A4 specifications (210X297mm)
TW83100779A 1993-08-03 1994-01-31 TW295604B (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP21237793A JPH0790445A (en) 1993-08-03 1993-08-03 Aluminum alloy brazing sheet for heat exchanger and manufacture of aluminum alloy-made heat exchanger
JP5214879A JP2686037B2 (en) 1993-08-06 1993-08-06 Method of manufacturing aluminum alloy brazing material and aluminum alloy heat exchanger
JP21801993A JPH0797651A (en) 1993-08-10 1993-08-10 Production of aluminum alloy brazing sheet for heat exchanger and heat exchanger made of aluminum alloy
JP24056393A JPH0790449A (en) 1993-08-31 1993-08-31 Aluminum alloy brazing sheet fin material and manufacture of aluminum alloy-made heat exchanger
JP23897193A JPH0790448A (en) 1993-08-31 1993-08-31 Aluminum alloy fin material for brazing and manufacture of aluminum alloy-made heat exchanger using the same

Publications (1)

Publication Number Publication Date
TW295604B true TW295604B (en) 1997-01-11

Family

ID=51565271

Family Applications (1)

Application Number Title Priority Date Filing Date
TW83100779A TW295604B (en) 1993-08-03 1994-01-31

Country Status (1)

Country Link
TW (1) TW295604B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI468535B (en) * 2012-11-20 2015-01-11 Truan Sheng Lui Method for inhibiting the diffusion of silicon by means of coarse aluminum crystals

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI468535B (en) * 2012-11-20 2015-01-11 Truan Sheng Lui Method for inhibiting the diffusion of silicon by means of coarse aluminum crystals

Similar Documents

Publication Publication Date Title
JP6186239B2 (en) Aluminum alloy heat exchanger
JP6463262B2 (en) Aluminum alloy brazing sheet and method for producing aluminum alloy heat exchanger
JP5057439B2 (en) Aluminum alloy clad material for high strength, high melting point heat exchanger excellent in durability, its manufacturing method, and aluminum alloy heat exchanger
JP2015096655A (en) Brazing sheet made of aluminum alloy for heat exchanger and brazed body made of aluminum alloy for heat exchanger
JP2014512452A5 (en)
JP2008188616A (en) Aluminum alloy-brazing sheet for heat exchanger having excellent brazability and corrosion resistance, and heat exchanger tube having excellent corrosion resistance
JP6372950B2 (en) Aluminum alloy clad material and manufacturing method thereof
JPH08246117A (en) High strength aluminum brazing sheet and its production
EP1436438A1 (en) Aluminium alloy for making fin stock material
TW201313376A (en) Lead-free solder compositions
JP6132330B2 (en) Aluminum alloy clad material and heat exchanger assembled with a tube formed from the clad material
BR112018009675B1 (en) BRAZING SHEET, PROCESS TO PRODUCE A BRAZING SHEET, USE OF A BRAZING SHEET AND HEAT EXCHANGER
JP2012001748A (en) Aluminum clad material for heat exchanger
JP2007301570A (en) Solder alloy
TW201116357A (en) Ti-Based Brazing Filler Metal and Method for Producing the Same
TW295604B (en)
TW200927358A (en) Pb-free solder alloy
JP2011038163A (en) Aluminum-clad material for heat-exchanger
JP2008013844A (en) Clad aluminum alloy material for heat exchanger and process for producing the same
JP2007169745A (en) Header member in heat exchanger, and aluminum clad material for tank member
JP2015166101A (en) Joining method of aluminum material, joining body of aluminum material
JP2014177708A (en) Aluminum clad material for heat exchanger
JP2011038164A (en) Aluminum-clad material for heat-exchangers
JP2019011922A (en) Method for manufacturing aluminum alloy heat exchanger with excellent anticorrosion, and aluminum alloy heat exchanger
JP6415144B2 (en) Aluminum alloy clad material and heat exchanger