經濟部中央標準局員工消費合作杜印裝 ^75072 a? _._B7_ 五、發明説明（I ) 本發明乃有關具有吸收熱能並將熱能儲存逹成保溫效 果之高分子聚合物的製作方法，該高分子聚合物與紡絲等 级之聚合物，可經纺絲製成鐵維，做為保溫性紡織品及防 寒衣服的材料，過去習知的保溫防寒性服裝，大部份在表 層及褢層中間夾入厚厚的棉網，以便將熱傳導率較低的空 氣保存在衣服内部，例如習知的棉襖及雪衣、羽毛衣等， 钽此類服裝穿箸起來極其笨重，不利於活動，不合乎戶外 活動如S山、潰習等的要求，為改萑此缺點》最近有技術 報導將鋁粉等反射性強的物質塗佈在内裡的布面上，做為 隔絶熱氣散失的保遵層，此方法雖可防止體熱敌失，但塗 佈鋁粉的結果，使布的手感變硬及變得不透氣，穿著起來 不舒服，旦穿一段時間後塗佈If t剝離耐久性差。 有鑑於此，本發明乃將有吸牧熱能並將熱能儲存逹成 保溫效果之材料，如氣化誥、氣化錁及三氣化二鋁等陶磁 粉末，添加入一般W知的高分子聚会物如聚蘧胺、聚酯等 ，做成A有萏熱保溫的β分子宏合物，此為聚合物經紡絲 做成戤維，可以製成抵輕且裔積極性的保溫注防寒衣料， 很適於活動時穿箸，如雪衣、羽毛衣、登山裝、滑雪裝等 〇 現配&隨式，説明本發明之待徵及功效如下： 圖式簡簞說明The Ministry of Economic Affairs, Central Bureau of Standards, Consumer Cooperation Du Printing ^ 75072 a? _._ B7_ V. Description of the Invention (I) The present invention relates to a method for manufacturing a polymer having the effect of absorbing heat energy and storing the heat energy into a thermal insulation, the Macromolecular polymers and spinning-grade polymers can be made into iron by spinning. They are used as materials for heat-resistant textiles and cold-proof clothes. Most of the heat-resistant and cold-proof clothes used in the past are mostly between the surface layer and the outer layer A thick cotton net is sandwiched in order to keep the air with low thermal conductivity inside the clothes, such as the conventional quilted jackets, snow coats, feather coats, etc. Clothing such as tantalum is extremely cumbersome to wear and is not conducive to activities. The requirements of outdoor activities such as S-mountain, ulceration, etc., to remedy this shortcoming. ”Recently, there have been technical reports of coating highly reflective materials such as aluminum powder on the inner cloth surface as a protective layer to prevent the loss of heat. Although this method can prevent the body from losing heat, the result of applying aluminum powder makes the cloth feel hard and air-impermeable, which makes it uncomfortable to wear. Once worn for a period of time, if t is applied, the peeling durability is poor. In view of this, the present invention is to add materials that have absorbed grazing heat energy and stored the heat energy into a heat preservation effect, such as ceramic powders such as gasification, gasification, and tri-aluminum dioxide, etc., which are added to the generally known polymer gathering Materials such as polyamines, polyesters, etc., are made of β-molecule macro compound with heat insulation, which is made of polymer by spinning to make dimension, which can be made into light and active thermal insulation and cold-proof clothing. It is very suitable for wearing a scoop during activities, such as snow clothes, feather coats, mountaineering clothes, ski clothes, etc. It is now available & casual, indicating that the present invention has the following features and functions as follows:
圔-為不同陶磁粉末之升溫曲線® a二為不同複合比例陶磁粉末之升溫曲線hi 圖三為ί#入陶磁粉末及一般高分子聚合物之升溫 曲線B _四為雙軸壓出機示意0 本呔法尺;1適用中SS家樣辛（CNS ) A4说洛（210.乂二97公i ) -----------^------iT. Λ^. (請^-閲讀背面之注意事項再填交本頁) _______ ^75072 g 五、發明説明（2 ) 圖號部份 (1)攪拌樓 （2)雙螺桿 （3)擠出口 本發明具有1熱保溫能力之高分子聚合物的製作方法 ，其製作過程分為三步驟： (一） 具有蓄熱保溫能力陶磁粉末的發現與應甩 (二） 使蓄熱保溫能力有共乘效果之複合陶磁粉末的研製 (3 )複合陶磁粉末與一般習知高分子聚合物均勻混練製成 具有蓄熱保溫能力之高分子聚合物。 本發叨在兵有萏熱保溫能力陶磁粉末的發現方面，使 用5 ()() 鹵素燈照射淘a材料如三氣化二鋁、氣化鎳及氣化 結等，再以紅外線測溫儀iTherioo Vision 300)測S溫度 變化，所得結果SI參照表1 ,得知在經5Q0W鹵素燈照射10 分鐘後，以氣化錁及氣化鉻具有較強的蓄熱刀·溫效果。 (請t閲讀背面.5-;i意事項再填？本頁) .裝·圔-is the heating curve of different ceramic powders a a2 is the heating curve of ceramic powders with different composite ratio hi Figure 3 is the heating curve of the ceramic powder and general polymer B # _4 is the schematic of the biaxial extruder 0 This is the ruler; 1 applies in the SS family like Xin (CNS) A4 said Luo (210. Qiao two 97 g i) ----------- ^ ------ iT. Λ ^. (Please ^ -read the precautions on the back and fill in this page) _______ ^ 75072 g V. Description of the invention (2) Drawing number part (1) Mixing building (2) Twin screw (3) Extrusion port The invention has 1 heat The manufacturing method of polymer with thermal insulation ability is divided into three steps: (1) Discovery and application of ceramic powder with heat storage and insulation capability (2) Development of composite ceramic powder with heat storage and insulation capability (3) The composite ceramic magnetic powder is evenly kneaded with the conventional polymer to form a polymer with heat storage and thermal insulation capabilities. In the discovery of pottery magnetic powder with the ability of heat preservation and insulation, Benfa used 5 () () halogen lamps to irradiate materials such as aluminum trioxide, nickel vapor and gasification junction, etc., and then use an infrared thermometer iTherioo Vision 300) measured the temperature change of S, and the obtained result SI refers to Table 1. It is known that after being irradiated with a 5Q0W halogen lamp for 10 minutes, vaporized cafium and vaporized chromium have a strong regenerative knife and temperature effect. (Please read the backside. 5-; i fill in the matters needing attention? This page).
表1 :不同陶磁材料之升溫效杲 條件 '、材料 氧化鈷 氣化錁 三m化二鋁 溪化欽 照射前 24.3Γ C z 4 < 8 r C 24. ?r c 24. 75° C 照射10分鐽 25.8 1° C 〇 π f> r 〇 C* L· i , o 0 L C 5 . 4 r. C 25. ar c 升溫效果 1,43° C 2. 5 3。C 0,68。 C l. 17° C 線丨· 經濟部中夬橾準局員工消費合作杜印製 本發明在使菡熱保溫能力有共乘效果之夜合陶磁粉宋 的研製方面，使用5QQW鹵素燈照射氣化鎳、氣化結及三氣 化二鋁依不同比例混合而成的衩合陶磁粉末1 ϋ分鐘，再以 红外線测溫儀（Therfflt) VUUn 900)測逛溫度變化，所得 結果諸銮照表2，經複合過的陶磁粉末比單成份淘磁粉末 炅具升溫效果，尤以表2所示之例3氣化鏍2 3 %氣化給G 〇 %三氣化二铝20%升溫速2. 9。C,為最佳》 上述氣化鎳，氣化鉻，及三氧化二鋁的比例為一較佳 實施例，其允許比例為（(1. 18〜[1. 2 2) : (G· 56〜0 · 641 : (〇 · 1 3〜Q , 2 2)均仍在本專利範11之内。 本纸乐尺度通用中國囤家橾迮（CNS ) A4規格（210X 297公釐） 五 經 濟 部 άτ 央 樣 準 員 S f 合 4土 印 % A7 B7 發明説明（今） 表2 :不同複合比例之升溫效果Table 1: Conditions of heating effect of different ceramic materials' material, cobalt oxide gasification, carbon trioxide, aluminum oxide, aluminum oxide, and Xihuaqin before irradiation 24.3Γ C z 4 < 8 r C 24.? Rc 24. 75 ° C irradiation 10 Min 25.8 1 ° C 〇π f > r 〇C * L · i, o 0 LC 5.4 r. C 25. ar c Heating effect 1,43 ° C 2. 5 3. C 0,68. C l. 17 ° C line 丨 · The Ministry of Economic Affairs of the Ministry of Economic Affairs of the Central Committee of the Ministry of Consumers and Consumer Cooperation Du printed the invention of the present invention to make the heat insulation capacity of the multi-purpose night magnetic ceramic powder Song development, using 5QQW halogen lamp to irradiate gas Nickel oxide, gasification junction and tri-aluminum bismuth are mixed in different proportions to obtain a ceramic powder with a diameter of 1 ϋ minutes, and then use infrared thermometer (Therfflt) VUUn 900) to measure the temperature change. The results are shown in Luang. 2. The compounded ceramic magnetic powder has a warming effect compared to the single-component scouring magnetic powder kneading, especially in the example shown in Table 2 3 Gasification L2 2 3% gasification to G 〇% trigasification bis-aluminum 20% heating rate 2 . 9. C is the best. The ratio of the above vaporized nickel, vaporized chromium, and aluminum oxide is a preferred embodiment, and the allowable ratio is ((1. 18 ~ [1. 2 2): (G · 56 ~ 0 · 641: (〇 · 1 3 ~ Q, 2 2) are still within the scope of this patent model 11. This paper music standard general Chinese hoarding (CNS) A4 specifications (210X 297 mm) Five Ministry of Economic Affairs άτ Central Sample Associate S f 4 in 4% imprint% A7 B7 Description of invention (present) Table 2: Heating effect with different compound ratios
氣化鎳 氧化鉻 三氧化二鋁 照射前 照射10分鐘 升溫效果 例1 20% 20% 60% E5. 15n C 27.47° C 2. 32。C 例2 20% 40% 40% 25. 1 ° C 27.93° C 2.83° C 例3 20% 60% 20% 25. 0 ° C 27.9 α C Ε. 3 ° C 例4 60% 20¾ 20% 25.05° C 27.56° C 2. 51。C 例5 4(1% 20% 40¾ Z5. 14，：，C 27. 12° C 1.33d C 本發明將20¾ 土 2¾上述的凌会淘磁粉末與30% 土 2% — 股晋知的Si分ΐ緊合物如聚逛跤、宏酯等遛泮並添邡 抗氣化劑及分散均勻剷，刹甩雙軸壓出機（諳參照圔四）均 勻混合熔融出，並切成粒狀，此,¾分？聚合物以5(J0W處 素燈照射10分鐘，再用紅外線溯溫儀（Thermo Vision 90(Π 測垦溫度變化，所得結果諳參照表3,獲知摻入陶磁粉末 的高分子聚合物，其升溫效果要比一般習知的高分子聚合 物 ί5 1 〜3 ° C。 表3 :摻入陶磁粉末之高分7聚合物與-胶晋知高分Γ聚 合物；f溫效果之比較 +氣化 載二IS i隨前I照射HI分鐘丨升溫效果丨舆一般習知高分I +- 子聚合物相比 1 例1 ί 4% 1 4:¾ 1 1况 ! 25.47° C U2. ?r Vy 1 η n i ο ί ύ. ύί C ! i,07" c 1 j_____j__________|______j_______ t —_j-------- —— |---- ___!__ —一H 1 例2 1 4% 1 8% 1 8% 1 E5. 4 c， C UfJ. 11。 c |3,7Γ Cl 1.47。 C 1 [----1—~~~— _____1_______________ —— _ _______ ____j____ --------·) 1 例3 1 4% Tl 2% I 4% Us. 37。 C i Z8, 95° c ί 3, 53° c ~1 l‘34n C 1 |___|____ ___j------J———---- ----j----- ——|----- —— --]---- ---j--- — 一4 1 例4 1 12% 14% 14% i 25*46° C 1 23.35° C ! 3.83ΰ C 1 1.65° C 1 |----1-----1------1----- ---1----- —j----- —— j---- ---1--- —一·! 1例5 1 8% 1 4:¾ 18% I 25. 35。 C 1 23,62° c 1 4.27° Cl 2. 03" C 1 I----1-----1------1------ ---j----- —_j----- —— —j---- j · h 1 例G 1 0 10 1 0 i 25.35° π \ on f 〇 。丨o丨< ϋ c 丨 2,24。 Cl 0 1 為使貴審査委員能更進一步瞭解本發明之製作方法， 本發明以50(lff鹵素燈作為照射光源，用紅外線测溫儀 本泜ft尺;1通用〒313家標立（cms ) μ堤洛（：η〇·χ:97公,$ ) 請 先 閲 讀 背 面 之 注_ 意 再 填 ? A7 B7 (Ψ) (TheiiD Vi si B η 9(1 Q)測麗單成份陶磁粉末的升溫曲線諸 螽照窗一，其中氧化錁具有最高的升溫曲線，測量複合陶 磁粉末的升溫曲線，請參照圔二，以例2及例3具有較高 的升溫曲線，而在測a摻入陶磁粉末之高分子聚合物的升 溫曲線方面諳參照圖三，本發明證贳摻入陶磁粉末之高分 眾合锪比' 胶習知高分了聚合物的/卜溫&線高很多，至於 所使用的雙軸is出璣洁參照蘭四，複合陶磁粉末與一般習 知的；分子聚合物在Μ拌{:# U)均勻猛合1¾拌，遝雙螺捍 ί£)熔融品練，由擠出口丨3) ；! ώ ,經水冷郤後洪乾切成 粒狀》成為遂入陶磁粉末具有g熱保温能力之1¾分-/聚合 物。 綜合上文所述，本發明偽提供一種具有蓄熱保溫能力 之高分子聚合物的製作方法，比一般晋知的高分子聚合物 提高1-3" C，该高分子聚合物為紡絲等級，經紡成絲做成 織維，可穑極有效地逹到保溫防寒的功效，如-般常見的 羽毛衣、雪衣、溃雪装、登山装等，既可節省材料逹成琛 保訴求，又可利用S然界能源如太陽光及人SSMil成省 能的目的，可大te IS 1¾産品的附加價值，為—不可多得 的材料。 經濟部中央標準局員工消費合作社印装 -----------裝— (請先閲讀背面之毛意事項再填寫才) 本發明為一首創之方法，其可獲得相當高的產柒價值 ,又顯然增進了無比的蓄熱保溫功效，深具産業之利用儅 值，是以本發明應己符合發明專利之獲准要件.发依法出 具文提出申請。 本纸承尺度通用中S国家檁立（CNS ) A4規洛ί 210X 297公,$ )Vaporized nickel, chromium oxide, aluminum oxide, 10 minutes before irradiation, heating effect Example 1 20% 20% 60% E5. 15n C 27.47 ° C 2. 32. C Example 2 20% 40% 40% 25. 1 ° C 27.93 ° C 2.83 ° C Example 3 20% 60% 20% 25. 0 ° C 27.9 α C Ε. 3 ° C Example 4 60% 20¾ 20% 25.05 ° C 27.56 ° C 2. 51. C Example 5 4 (1% 20% 40¾ Z5. 14,:, C 27. 12 ° C 1.33d C The present invention uses 20¾ soil 2¾ the above-mentioned Linghui Tao magnetic powder and 30% soil 2% — Si Jinzhi It is divided into compacts such as poly wrestling, macro esters, etc., and is added with anti-gasification agent and evenly dispersed shovel. The dual-axis brake extruder (refer to Xiu IV) is evenly mixed and melted, and cut into granules Here, ¾ points? The polymer was irradiated with a 5 (J0W element lamp for 10 minutes, and then used an infrared temperature tracer (Thermo Vision 90 (Π to measure the temperature change of the reclamation. For the obtained results, refer to Table 3 to know the high Molecular polymer, its heating effect is better than the commonly known high-molecular polymer ί 5 1 ~ 3 ° C. Table 3: High score 7 polymer mixed with ceramic powder and -Jin Jin high score Γ polymer; f temperature Comparison of effect + gasification carrier II IS i followed by I irradiation for HI minutes 丨 heating effect 丨 commonly known high score I +-daughter polymer compared with 1 case 1 ί 4% 1 4: ¾ 1 1 condition! 25.47 ° C U2.? R Vy 1 η ni ο ί ύ. Ύί C! I, 07 " c 1 j _____ j __________ | ______ j_______ t —_j -------- —— | ---- ___! __ — 一 H 1 Example 2 1 4% 1 8% 1 8% 1 E5. 4 c, C UfJ. 11. c | 3,7Γ Cl 1.47. C 1 [---- 1— ~~~ — _____1_______________ —— _ _______ ____j____ -------- ·) 1 Example 3 1 4% Tl 2% I 4 % Us. 37. C i Z8, 95 ° c ί 3, 53 ° c ~ 1 l'34n C 1 | ___ | ____ ___ j ------ J ---------- ---- j- ---- —— | ----- ——-] ---- --- j ----1 4 1 Example 4 1 12% 14% 14% i 25 * 46 ° C 1 23.35 ° C! 3.83ΰ C 1 1.65 ° C 1 | ---- 1 ----- 1 ------ 1 ----- --- 1 ----- --j ----- —— j ---- --- 1 --- — 一 ·! 1 case 5 1 8% 1 4: ¾ 18% I 25. 35. C 1 23,62 ° c 1 4.27 ° Cl 2. 03 " C 1 I ---- 1 ----- 1 ------ 1 ------ --- j ----- --_ j ----- ---- --j --- -j · h 1 case G 1 0 10 1 0 i 25.35 ° π \ on f 〇.丨 o 丨 < ϋ c 丨 2,24. Cl 0 1 In order to enable your reviewing committee to further understand the manufacturing method of the present invention, the present invention uses a 50 (lff halogen lamp as the light source of illumination, and uses an infrared thermometer thermometer 泜 ft ruler; 1 universal 〒313 standard (cms)) μTiluo (： η〇 · χ: 97 g, $) Please read the note on the back _ first and then fill in? A7 B7 (Ψ) (TheiiD Vi si B η 9 (1 Q) Measure the temperature rise of single-component ceramic powder Curves of the first photo window, in which the oxide of californium has the highest heating curve. Measure the heating curve of the composite ceramic magnetic powder. Please refer to the second one. Example 2 and Example 3 have a higher heating curve. With reference to FIG. 3, the temperature rise curve of the high molecular weight polymer shows that the present invention has a high score of the ceramic powder blended with the ceramic powder. The conventional rubber score is much higher than the polymer / buwen & line. As for the use The biaxial is out of Ji Jie, refer to Lan IV, composite ceramic magnetic powder and general knowledge; molecular polymer mixed in M {: # U) evenly mixed 1¾ mixed, 雝 双 螺 保 鐑) melted and refined, by extrusion Export 丨 3) ;! ώ, after water cooling, dried and cut into granules "becomes the ceramic powder with g heat insulation 1¾ points of ability- / polymer. In summary, the present invention pseudo provides a method for manufacturing a polymer polymer having heat storage and insulation capabilities, which is 1-3 " C higher than that of a generally known polymer polymer, which is a spinning grade, After weaving into silk to make a weave, it can effectively achieve the effect of thermal insulation and cold protection, such as common feather coats, snow coats, snow-breaking outfits, mountaineering outfits, etc., which can save the material. It can also use the energy of solar energy such as sunlight and SSMil for energy-saving purposes, which can increase the added value of te IS 1¾ products, which are rare materials. Printed and printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs ----------- installed (please read the gross matters on the back before filling in) This invention is a pioneering method, which can obtain quite high The production value has obviously improved the incomparable heat storage and insulation effect, and has the industry's use value. Therefore, the invention should meet the approved requirements of the invention patent. The application is issued in accordance with the law. This paper bears the standard general purpose S national purlin (CNS) A4 regulations Luo 210X 297 gong, $)