TW265304B - Process of producing light-shielding flame-retardant drapery - Google Patents

Process of producing light-shielding flame-retardant drapery Download PDF

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TW265304B
TW265304B TW83105291A TW83105291A TW265304B TW 265304 B TW265304 B TW 265304B TW 83105291 A TW83105291 A TW 83105291A TW 83105291 A TW83105291 A TW 83105291A TW 265304 B TW265304 B TW 265304B
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Taiwan
Prior art keywords
flame
flame retardant
retardant
shielding
light
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TW83105291A
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Chinese (zh)
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Jong-Fu Wu
Kuen-Long Juang
Chiou-Shyong Tsay
Farn-Pyng Koong
Meng-Liang Lin
Jin-Liou Liou
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China Textile Inst
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Abstract

A process of producing light-shielding flame-retardant drapery, which comprises adding main flame-retardant, inorganic auxiliary flame retardants and special flame retardant additives into the PU resin composition, blending the mixture thoroughly by a three-roller grinder, using delamination cloth to undergo wet formation to produce flame retardant membrane; during the PU resin composition production process, sequentially adding a mixed high performance flame retardant composition comprising main flame retardant, inorganic auxiliary flame retardants and special flame retardant additives, anion surfactant, light-shielding pigment, cross-linking agent and cross-linking aid comprising adducts of TMP and TDI and adducts of TMP and HDI, blending the mixture by a three-roller grinder to form a flame retardant light-shielding resin with flame-retardant, light-shielding and adhesive properties, using the flame retardant light-shielding resin to form a flame retardant and light-shielding adhesive layer on the flame retardant membrane, laminating the flame retardant membrane on a fabric or woven fabric to produce a drapery product with soft and high flame retardance light-shielding properties.

Description

265304 A7 B7 經濟部中央標準局爲工消费合作社印製 五、發明説明() 、 本發明係有闞於一種遮光阻燃窗簾布之制造方法,尤 指一種應用於窗簾産品制程,及兼具以阳燃_膜産品配合 陥燃性之遮光樹脂,貼合於窗簾之嫩物或編物上,依適當 製程所製成之具遮光及阻燃特性窗廉産品之製造方法者。 按,PU樹HB( Polyurethanes聚氛基甲酸醋,俗稱Ί0? 泡塑滕之熱固性塑滕)原料廣泛地應用於一般日常生活中 之垫子、枕頭、沙發、大衣内襯、手提袋、窗簾布、糗衡 材料、隔音材料及隔熱材料等産品h,而以一般P丨丨樹脂材 料特性而言,係可视其用途,適當地配製其合成比例,而 使該PU樹脂可製成可軟、可硬之形態應用.但一般之PI丨樹 脂材料本身,並未具有阳燃之效果,間接地侷限其晦闲之 範圔與彩響其使用h之安全性。 然,以一般包含P丨丨樹_成份之裔簾布産品斛造爲洌, 其産品性能要求,除了要有基本之遮光性能外,不外乎就 是高阻燃性,然而,業界一般於製造窗簾布産品遇程中, 爲使PU樹脂材料具有阻燃效果,則多於構造物中添加有機 或無機阻燃化合物,但一般無機阻燃削大都爲水溶型,且 與PU樹脂之相容性較差,故於加工遇程中或爾後長期使用 時,常會潘出於PI丨樹脂之表面中,而使加工徕之所得之産 品阻燃效果辦差或没有效果。 此外,由於一般阻燃劑本身跚酸性物質,經作用時會 釋放出_素或确系等酸性物質,而促使PU樹脂痒生顚著加 水分解,同時亦會促進産品光劣化及熱劣化等現靠,導致 PIJ樹脂原料有晩化及劣化等缺陷,並使得産品之耐久性顯 *3— 本紙張尺度速用中國國家標準(CNS ) Α4規格(210Χ297公釐) 83. 3.10,000 請 先 閲 Λ 之 注 項 再 本 頁 裝 訂 經濟部中央標準局貝工消費合作社印製 265304_b7_ 五、發明説明() 、265304 A7 B7 Printed by the Central Bureau of Standards of the Ministry of Economy for the Industrial and Consumer Cooperatives 5. Description of the invention (). The present invention relates to a method for manufacturing light-shielding and flame-retardant curtain fabrics, especially a process applied to curtain products, and both Sunburn_membrane products are combined with long-flammable shading resins, and they are attached to the tender or knitted fabric of curtains, and are manufactured according to the appropriate manufacturing process. Press, PU tree HB (Polyurethanes Polyurethane vinegar, commonly known as Ί0? Foam plastic thermosetting plastic) raw materials are widely used in general daily life cushions, pillows, sofas, coat lining, handbags, curtain cloth, Products such as gill materials, sound insulation materials, and heat insulation materials, and in terms of the general resin characteristics, the synthetic ratio can be appropriately formulated according to its use, so that the PU resin can be made soft, It can be applied in a hard form. However, the general PI 丨 resin material itself does not have the effect of flaming, indirectly limiting its unsophisticated range and the safety of its use. Of course, it is made of a fabric product that generally contains P 丨 丨 tree_ ingredients. In addition to the basic light-shielding performance, the product performance requirements are nothing but high flame retardancy. However, the industry generally manufactures curtains. In the course of fabric products, in order to make the PU resin material have a flame retardant effect, more organic or inorganic flame retardant compounds are added to the structure, but the general inorganic flame retardant is mostly water-soluble and has poor compatibility with PU resin. Therefore, in the process of processing or long-term use afterwards, it is often caused by the surface of the PI 丨 resin, which makes the flame retardant effect of the product obtained by processing poor or no effect. In addition, because the general flame retardant itself destabilizes acidic substances, it will release acidic substances such as ketones or certain systems, which promotes the PU resin to itch and decompose and decompose with water. At the same time, it will also promote the photo- and thermal degradation of products Reliable, which leads to defects such as deterioration and deterioration of PIJ resin raw materials, and makes the durability of the product obvious * 3—This paper scale uses the Chinese National Standard (CNS) Α4 specification (210Χ297 mm) 83. 3.10,000 Please read first The note item of Λ is re-bound on this page. 265304_b7_ Printed by Beigong Consumer Cooperative of Central Bureau of Standards of the Ministry of Economy

著降低。 IDown. I

爯者,或有於構造物中添加含歯素或含_、确系之PUIf it is, it may be added to the structure containing PU or containing PU, indeed PU

I 樹脂者,賭如日本國専利公報中「平4-11917號 I専利案所掲之技術手段,除了製造成本因此提髙外,尚 爾添加較多量如上所述之阻燃_方能達到阻燃之效果,並 導致産品於製造上之經濟效益偏低,且使該PH榭脂産品物 性變差,亦即無法製造出阻燃性能較佳之産品。 除此之外,一般以乾式法制造阴燃遮光裔簾布者,諸 如日本画専利公報中「平4-1 51 241號π牛b 7丨専利案所 掲之技術手段,除了有如h所述之阻燃性、耐久性及物性 差等三項缺點外,其稂層雅手慼(PAPER -L IKE )較差,且 缺乏産品體稂慼。 男外,或有濕式法製造阻燃遮光窗簾布者,賭如日本 國専利公報中「平4-108183號夕牛b」専利案所掲之技 術手段,除了有如上所述之阻燃性、耐久性及物性差之賭 多缺點外,其稂層體剝離強度及耐水壓性亦不佳,故使産 品在使用時,織物容易剝離,而導致耐久性圼現較差之現 象〇 本發明人有也於此,乃致力研究改良,經再三試作修 飾後,今終開發出一稽遮光阻燃窗簾布之製造方法,藉以 使窗簾布産品具有商阻燃性、髙耐久性及柔軟之産品手慼 ,降低生産成本等産業上利用價値之優點者。 緣此,本發明之主要目的即是在提供一種遮光阻燃窗 簾布之製造方法,尤以其中係於pu榭脂組成中添加水不溶 | -4- 本紙張尺度速用中國國家標準(CNS ) A4就格(210X297公釐)~~" 83.3.10,000 -----------^-------IT------^ (請先閲讀背面之注$項再填k本頁) 265304 A7 B7 經濟部中央標準局貝工消費合作社印製 五、發明説明() 、 型之_棄系列阻燃劑及無機系列阻燃削,再將鹵素系列阻 燃劑與銻系列阻燃_依逋當比例添加,並藉該歯棄系列阻 燃刺及鋪系列阻燃刺具有有協效作用,而使其添加量降至 最低,並再藉由三輥筒研磨機將一般呈粉體狀之銻系列阻 燃劑或鹵素系列阻燃劑充分研磨,使賅粉雅狀之阻燃_興 PU樹脂原料充分混合,並再依適當之製程添加以適當陰離 子界面活性削,而使上述研磨後之粉艚細度化、提昇表面 稹及阻燃劑興PU樹脂原料之相容性、安定性,同時,亦不 會影響濕式加工製程或爾後阻燃刺於應用時滲出於薄腆之 表面,而再於上述歯棄系列及銻系列之PU樹賭阻燃浪合液 中,迪度地添加_助系列阻燃刺及添加劑,俾以産生高阻 燃效果之阻燃薄瞋産品;並再於無黄變PU樹脂組成過程中 ,依序添加高性能阻燃刺、架橘削、架橘促進刺、陰離子 羿面活性削及遮光性色料等,經三餛简研磨機充分摻合後 製成具阻燃、遮光性能及接著性質之阻燃性遮光型樹脂, 並將上述之阻燃薄膜産品,藉由該阻燃性之遮光型樹瞻, 貼合於窗簾布之織物或編物上,而據以製得具高阻燃及商 遮光特性之窗簾布産品.,雜以降低於窗簾布産品整體製程 中阻燃刺之用量,及大幡提昇本發明中之阻燃産品之阻燃 效果及産品生産之經濟效益。 爲使 贵審査委員得進--步具艚瞭解本锻明之具艚 技術内容及發明内函,以下兹舉一較佳之操作例與若干寶 施例、比較例詳細蛻明之,俾便於 贵審査委員之審理。 其中: 一 5— 本紙張尺度逋用中國國家揉準(CNS ) Α4规格(210Χ297公釐) 83.3.10,000 請 先 閲 之 注I Resin, bet on the technical means in the Japanese National Gazette's "Hei 4-11917 No. I case", in addition to the high manufacturing cost, Shanger added a large amount of flame retardant as mentioned above to achieve resistance The effect of burning, and lead to low economic benefits of the product in manufacturing, and make the PH resin product physical properties worse, that is, unable to produce products with better flame retardant properties. In addition, generally dry method is used to produce negative Those who burn black curtains, such as the technical measures described in the "Pai 4-1 51 241 No. b Niu b 7i" case in the Japanese Gazette, in addition to the flame retardancy, durability, and poor physical properties described in h In addition to its shortcomings, its PAPER-L IKE is poor, and it lacks product body. Men, or those who have a flame-retardant blackout curtain fabric manufactured by the wet method, bet like the "Ping In addition to the above-mentioned shortcomings such as flame retardancy, durability and poor physical properties, the technical means of the "Xiu Niu b" No. 4-108183 case, as well as its shortcomings such as flame retardancy, durability and poor physical properties, also have poor peel strength and water pressure resistance , So that when the product is used, the fabric is easily peeled off, resulting in resistance The phenomenon of poor performance is present. The inventors are here to dedicate themselves to research and improvement. After repeated trial and error modification, a manufacturing method of shading flame retardant curtain fabrics has been developed to make curtain fabric products commercially flame retardant. The advantages of the industry, such as sex, high durability and soft product, and the reduction of production costs. Therefore, the main purpose of the present invention is to provide a method for manufacturing light-shielding flame-retardant curtain fabrics, especially in which water-insoluble is added to the composition of puchelin | -4- The speed of this paper standard China National Standard (CNS) A4 on the grid (210X297mm) ~~ " 83.3.10,000 ----------- ^ ------- IT ------ ^ (Please read the note on the back first $ Item and then fill in this page) 265304 A7 B7 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy V. Invention description (), type_ Discarded flame retardant and inorganic flame retardant, and then halogen halogen flame retardant It is added with antimony series flame retardant _ in accordance with the current proportion, and by the use of the discarded series flame retardant thorn and the spreading series flame retardant thorn has a synergistic effect, so that the amount of addition is reduced to a minimum, and then grinding by three rollers The machine fully grinds the antimony series flame retardant or halogen series flame retardant which is generally in powder form to fully mix the powdery flame retardant _Xing PU resin raw materials, and then add the appropriate anionic interface activity according to the appropriate process. To reduce the fineness of the powdered stern after grinding, to improve the compatibility and stability of PU resin raw materials for surface grain and flame retardant. It will not affect the wet processing process or the flame retardant thorns will penetrate into the thin surface during application, and then be added to the PU flame retardant wave mixture of the above-mentioned discarded series and antimony series. A series of flame retardant thorns and additives, in order to produce flame retardant thin flame retardant products with high flame retardant effect; and then in the process of non-yellowing PU resin composition, add high-performance flame retardant thorns, orange peeling, orange promotion thorns in sequence , Anionic surface active shaving and shading pigments, etc., fully blended by the three Wengjian grinding machine to make flame retardant shading resin with flame retardant, shading properties and adhesion properties, and the above flame retardant film products , With the flame-retardant shading tree, it is attached to the fabric or knitted fabric of the curtain fabric, and the curtain fabric product with high flame retardant and commercial shading characteristics is made according to it, which is reduced to the curtain fabric product. The amount of flame-retardant thorns in the overall process, and Dabanwa enhance the flame-retardant effect of the flame-retardant product of the present invention and the economic benefits of product production. In order to enable your reviewing committee to advance-to understand the technical content and invention letter of this forge, here is a better operation example and a number of Bao Shi examples and comparative examples in detail, so that it is convenient for your reviewing committee Trial. Among them: 1. 5—This paper scale uses the Chinese National Standard (CNS) Α4 specification (210Χ297 mm) 83.3.10,000 Please read the note first

I 裝 訂 線 265304 A7 B7 經濟部中央梂準局貞工消費合作社印製 五、發明説明() 、 A.本發明遮光瞄燃窗簾布之製造方法構成技術及其制程步 驟一 (1) 在PU樹脂組成過程中,迪當地添加商性能阳燃刺( 係由歯、練系列主要阻燃刺、無機系列阻燃刺及特 殊耐熱阻燃系列添加_等部份所組成),並經三锟 筒研磨機充分撺和後,再用離型布行溻式成型,先 行製造出柔軟及兼具阻燃性能之阻燃薄膜産品備用 Ο (2) 另在於無黄變型PU榭脂、亞克力樹脂或兩者混合所 構成之樹脂組成過程中,逋當地添加混合型高性能 阻燃劑、架橘劑、架橋促進_、陰離子羿面活性劑 及遮光性色料等,並經三親简研磨機充分撺和後, 製成具阻燃、遮光性能及接著性質之阻燃性之遮光 型樹脂。 (3) 將步驟一中所製得之阻燃薄膜成品,透過上述步驟 二所得具阻燃及遮光效果之樹脂接著層,將阻燃薄 膜貼合於窗簾布織物或繡物,而使該繊物或編物具 有優良之阻燃及迪光機能,而製成本發明遮光咀燃 窗簾布産品。 (4) 另在上述本發明操作步驟一、二中所使用之主要阻 燃削則以幽素系列阻燃劑,併用銻系列阻燃削等所 構成,且該鹵素系列阻燃劑與綈系列阻燃削之混用 比例範園則在1 : 1 0〜1 0 : 1,較佳之狀態爲1 : 1〜4: 1 之比例。 -6- 本紙铢尺度適用中國國家標準(CNS ) A4规格(210><297公釐) 83. 3.10,000 請 先 閲 面 之 注 項 再 本 頁 裝 訂 線 經濟部中央標準局貝工消費合作社印製 265304 a? B7五、發明説明() 、 (5) 此外,在上述本發明中所使用之無機系列_助阻燃 | I ,貝包 tSMg (0H)2 ♦ Al (0H)3 、 MoOj 、 P、 CaC〇5 '、ca〇Aiao5 ♦ 6Hzo 、 Mgco5 、 Cuo. cUjto 化合物所楙成,且該添加劑則爲Zn、Mg、ZrOj;、T i 〇z、Si〇z、SnO、ZnO、BaBjfCU等無機化合物所構 成,且上述之無機系列軸助阻燃劑及添加劑於PU樹 脂原料内之添加量分別爲核PU樹脂之3〜100w.t%& l~30w. t% i匕 (6) 另爲使上述之主要阻燃劑、無機系列輔助阻燃劑及 添加削等配料能均匀混合,及使該配料之料徑分佈 在5微米以下,故爾再經三輥简研磨機充分研磨, 而使該配方液之粒徑分佈於5微米以下,而其較佳 之粒很分佈範圔爲2微米以下,且於研磨時爾使用 陰離子系界面活性雜以提昇其乳化安定,, (7) 在本發明搡作步嫌二所使用之接著層,乃於無黄變 型PU樹脂(亦可爲亞克力樹脂或無黄變型PU樹脂及 亞克力樹脂兩者混合而成之樹脂)組成中,添加以 逾量之髙性能阻燃劑、架橘劑、架橘促進劑、陰離 子界面活性劑及遮光性色料,經三概简研磨機充分 摻和後,所配製而成具阻燃及遮光效果之接著層α (8) 在本發明操作步驟中所使用之遮光性色料,係爲有 機色料或金粉、銀粉、銷粉、銅粉、 carbon black 等無機色料所構成。 > (9) 在本發明之操作步驟二所使用之_物,則可爲不具 | -7- — III—— I 裝— — I 訂 1 I I 矣 (請先閲讀背面之注意事項再^,>本頁) 本紙張尺度逋用中國國家標準(CNS ) A4规格(210X297公釐) 83. 3.10,000 265304 A7 B7 經濟部中央梂準局系工消費合作社印製 五、發明説明() 、 阻燃彳·生之薄基材(例如:棉、聚醋或聚醋及棉之混 妨織物)、具阻燃性之基材(例如聚酿、聚酿胺織 物)及經適當之阻燃處理後之基材(例如:棉、聚 醋及聚酿胺織物)等材料所檐成。 (10) 另在上述本锻明中之操作步驟二中所使用之架橘劑 則爲TMP與TD [之加合物、TMP與HDI之加合物及 TMP與IPDI之加合物或HDI之三合體化合物所構成 〇 (11) 爲使本發明所製成之阻燃産品播得髙性能之柔軟兼 具阻燃遮光繊物或編物,本發明在操作步驟一中則 以離型布製作式阻燃薄膜,再配合操作步驟二所 述具阻燃、遮光效果之接著層,而使該貼合漏式阻 燃薄膜之織物,成爲具有商阻燃、髙遮光性能之窗 簾布産品。 (12) 由上述本發明之遮光阻燃窗簾布産品之各製造及操 作步驟後,即可播得兼具上述步驟各項特潋之髙阻 燃及兼具遮光特性之窗簾布産品, 經以上之本频明之遮光陥.燃窗簾布産品之製造方法之 製程及搡作步驟之詳細説明後,已初步地掲露本潑明之技 術内容與技術手段之構成,但爲 使贵審査委員更進-步 陳解本锻明之技術重點及産業上利闲價値所在,以下兹舉 數個較佳之寶施例及比較例加以閭述説明之,其中: B.總合寶施例: 1.在本發明中所使用之PU樹脂原料,係由polyol、dii- -8 一 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 83. 3.10,000 請 先 閲 之 注 項 再 本 頁 裝 訂 線 ^65304 A7 B7 經濟部中央揉準局月工消费合作社印製 五、發明説明() 、 socyanate chain extender三部份所組成,且其中p-olyol 種類以 polyester polyol.、polycarbonate p -olyol 及 po 1 yea-pro 1 actone polyol 系列爲主;二異 氰酸化合物則有黃變型與非黃變型兩類,且於本發明 中刖可使用黄變型PU樹脂原料或非黃變型PU樹脂原料 ;其中,黄變型PU樹脂中必須添加紫外線吸收劑及抗 氣化劑,使其難以變黃;chain ex tender部份主要有 d i ο 1系及d i am i ne系歹?I兩類;diol方面有EG、1,3PG、 1,4B.D.、1,5P.D.、16,H.D 及芳番瓌之短鍵 diol (如 :H〇-<n>~<S>-〇H...等等),而 diamine 類刖有 HH、 EDA . Η 2 N-<a>-CH -<5>-NH …等等,並再經一段 聚合或二段聚合方式合成該PLJ榭脂,合成後以DMF稀 釋至30% PU樹脂溶液。 2 .爲使上述PU樹脂溶液賦予優良之阻燃效果,乃於配方 中添加主要阻燃刺、輔助系列阻燃劑及各種添加刺, 並將該所添加之各種阻燃劑及添如劑之相關種類及組 成詳述如后: a.主要阻燃劑方面一 則包含有_棄系列阻燃刺及鋪系列阻燃劑兩種,且 於歯素系列阻燃劑方面則有Paraffine chlorinated^ Decabromodiphenyl oxide、 Hexach1oro ben-zene^ Hexabromo benzene 、 Pentabromo ethyl benzene、Pentabromo diphenyl oxide .、Ootabr-omo diphenyl ether 等之ιϋ ft:物;i弟系歹1 P且燃劑 -9- 本紙张尺度適用中國國家揉準(CNS〉A4洗格(210X297公釐) 83. 3.10,000 請 先 閲 之 注 項 再 本 頁 裝 訂 線 經濟部中央標準局®C工消費合作社印製 265304 A7 B7 五、發明説明() 、 貝U有Sba〇s、Sb, 〇5 等兩種綈系化合物。 b.輔助系列阻燃劑及添加_方面一 闞於輔助系列阻燃_及添加劑則有CaCOi、CaOA1 ;^04 • 6H*CU A1 (0H)3 . MgCOHL 、MgC〇3 、Mo〇3、Si 0 2 ^ CuO -, Cua 0 ^ Zn % ZnO Λ 2ZnO * 3Ba,〇3 * 3.5ΗΛ 0、BaB;i (¾、T i 0Z、SnO等無機化合物類所構成。 C .寶施例一: 1 .以經退漿、精楝、染色、傾定型之耐龍平繊布,組繊 爲70D/24F , 210倐,且以2%之氟碳樹脂壓吸處理, 壓吸率爲40% ,並再進行烘紇定型製成離型布。 2. 將配置完成之表面層塗佈液以刮73方式塗佈於以h述 步驟1所製成之離型布上,該塗佈量約爲100〜300 g/ma , 並再經攝氏201 X 10分之濕式凝固浴成型後 ,經水洗、熱水洗等步驟處理後,再於攝氏120〜1 40 °<0溫度之烘箱中烘乾約三分鐘後,即得柔軟且兼具阻 燃之薄膜成品。 3. 上述步驟2中阻燃薄膜之塗佈液組成成份如下: a.聚醋型PU樹脂(DU-1030 W )...............1 00g b .鹵素系列眭燃劑............ 20« c .銻系列阻燃劑..............................5κ d · Mg (0Η)*.................................. 1 Og e. A] (0H)3..................................lOg f - M〇03.....................................10k g .陰離子界面活性劑..........................6g -10- 本紙張尺度逋用中國國家標準(CNS ) A4規格(210X297公釐) 83. 3.10,000 I. 裝 訂 線 ' / (請先閲讀背面之注意事項再本頁) 一 彳郊中央標準局貝工消费合作社印製 A7 B7 五、發明説明() 、 h.色料.....................................20g 4. 將配置完成之接著層塗佈液以刮刀方式塗佈於上述步 驟2所製成之阻燃性之薄膜表面,其塗佈量約爲1 00 〜300g/m1並再以1 OKg /citT之麵力,與不具阻燃彳生之薄 棉平織物進行貼合處理,最後再於攝氏1 70 °C 濕度之 拱箱中作熱處理二分鐘後,即可得陁燃及兼具遮光特 性之窗簾布産品。 5. 上述步驟4之接著層塗佈液組成成份如下: a. 無黃變型PU樹脂..........................100g b. HDI三合艚架橘劑..........................5g c .架橘促進剌(肢系化合物)..................2g d.鹵棄系列阻燃劑...........................20g e .銻系列阻燃酬..............................5g f . Mg (0H)a..................................lOg g. A1 (0H)j................. ............ . . . . 1 Ok h . MoO 5.....................................1 Og i . ZnO......................................1 5g j .陰離子界面活性劑..........................6κ k . carbon black.............................20g D .寶施例二: 1.加工方法同於寶施例一中之步驟1、步驟2及步驟4 ,但繊物採用經阻燃處理之棉平繊布。 2 .阻燃薄膜之塗佈液組成成份如下: a. polyester .系歹 *JPU 樹 Η旨....................100g -11- 裝 訂 線 · 、 一. (請先閲讀背面之注意事項再^w本頁) 本紙張尺度適用中國國家揉準(CNS ) A4规格(210X297公釐) 83. 3.10,000 ^65804 ΑΊ Β7 五、發明説明() 、 b. 鹵素系列阻燃劑...........................i5g: c. 鋪系列阻燃劑..............................8g d. Mg(OH)*..................................ι〇κ e. A1 COH)3..................................20g f ·ΖηΟ......................................15g s .陰離子界面活性劑..........................6g h.色料......... 15g 3 .接著湣塗佈液組成成份如下: a. 無黃變型PU樹脂..........................1〇〇8 b. TMP與IPDI化合物..........................5g c·架橘促進劑................................2g d .鹵素系列阻燃劑...........................1 e .鋪系列阻燃劑............................... f . Mg (0Η)α..................................1 〇(5 g . A 1 (0Η >3........ 2〇{? h . ZnO............................ 1 5g i .陰離子界面活性劑..........................6 k j . 1 〇g E .寶施例三: (請先閲讀背面之注意Ϋ項再填穿氺頁) •裝· 訂 線· 經濟部中央標準局只工消費合作社印裝 1. 加工方法同於寶施例一之步驟1、步驟2及步驟4 , 但在步驟4執行前多增加一層遮光層塗佈步驟,且其 織物採用具阻燃性之聚酯織物。 2. 阻燃薄膜之塗佈液組成成份如下: a .—液型脂肪族PI丨糊脂......................ι〇〇κ | -12- 本紙張尺度逋用中國國家標率(CNS > A4规格(210X297公釐) 83. 3.10,000 ^65S〇4 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明() 、 b .鹵素系列阻燃劑...........................15g c .鋪系列阻燃劑.............................10g d. Hg (OH)i..................................lOg e . Zr02.....................................lOg f .陰離子界面活性劑..........................2g g.色料.....................................lOg 3.步驟1所述遮光層塗佈液組成成份如下: a.—液型脂肪族PIJ樹脂......................100g b .鹵素系列阻燃劑...........................10κ c .鋪系列阻燃劑.............................10t? d . Mg (0Η):................................. . . 5κ e - ZrO2 . . . ...................................5g f .陰離子界面活性劑..........................2g g.carbon black.............................20g 3 .接著層塗佈液組成成份如下: a. 無黄變型亞克力樹脂......................100g b. HDI三合雅架橋削......................... 5g c. 架橘促進劑..... 2g d. 鹵素系列阻燃劑...........................15g e .鋪系列阻燃劑.............................l〇g f . Mg (OH)a ..................................1 Or g . ZrOz............ 10k h .陰離子界面活性劑............. 2g i .色料.....................................Τ〇κ _13— 請 先 閲 Λ 之 注 意 項 再 f 本 % 裝 訂 線 本紙張尺度速用中B國家揉準(CNS ) A4規格(210X297公釐) 83. 3.10,000 —»ι.·Μηιπ>||· ιίιϋΙΜΜΜΙΜ·Ι"·»"11·1·1 - · 經濟部中央梂準局負工消费合作社印製 265304 ΑΊ _Β7_ 五、發明説明() 、 F .比較例一: 1.首先在離型紙上,先行以表面層塗佈液塗佈於表面, 塗佈量爲200g/n^ 並再以90C X 2分鐘之條件進行預 乾處理,並再以接著層塗佈液進行接著屠塗佈步驟, 其塗佈量mi50g/ma,並於塗佈完成後,再以70它X 2 分鐘之條件,進行熱風乾燥處理步驟,並以阻燃性之 聚醯胺織物爲基布,而再進行以貼合步驟,再以160 °C X 2分鐘之條件,進行熱風供培處理步驟,並以60 °C X 48小時之條件,執行熟成處理步驟,並經剝離嗛 理後,而得到遮光阻燃之窗簾布産品, 2.表面層塗佈液組成成份如下: a.—液型聚醋PII榭脂........................100g b .含溴含磷PU化合物.........................25g c. 改質 polyisocyanate.......................1 0g d. urethane oligomer.........................5g e. 色料.....................................20g 3 .接著層塗佈液組成成份如下: a.二液型聚醋PU榭脂........................100g b .三聚氰胺系架橘劑..........................5g c.架橋促進劑................................2κ d .鹵素系列阻燃劑...........................25g e. SicWpolyisocyanat.e. . ............. 23g f. urethane oligomer.........................5g g· Die thane amine.........................25 矜 | 一 14— 本紙張又度逋用中國國家標準(CNS ) A4规格(210X297公嫠) 83. 3.10,000 I· 裝 j 系 (請先閲讀背面之注意事項再本頁) ( 經濟部中央揉準局βς工消費合作社印製 B7 五、發明説明() 、 h .色料.....................................25g G .比較例二: 1 .加工方法亦冏於比較例一之步驟各操作及處理步驟, ,但基布爲不具阻燃性之薄棉織物。 2.表面層塗佈液組成成份如下: a. —液型聚醋PU樹脂........................1 OOg b. 鹵素系列阻燃劑...........................25g c .鋪系列阻燃劑.............................10g d. 改質 polyisocyanate.......................12g e. 色料.....................................20g 3 .接著層塗佈液組成成份如下: a.二液型聚酿PIJ樹脂........................100κ b .鹵素列阻燃劑.............................25g c .架橘促進酬...............................1 8« d.色料............................... 25κ 由以上本锻明所述之各個寶施例及比較例之特殊製造 方法,並將該各個寶施例及比較例依不同條件所製成阻燃 兼具遮光特性之窗簾布産品,並分別依ASTM D2863-74法 分別測試其限氧指數(L . 0 . I ), 及以CPA卜84型垂直燃 燒試驗機測試其碳化長度等數據,俾使該測試結果與習知 方法相爲比較,並將其所測得之相閭數捕及比較結果(本 發明寶施例與比較例之效果比較)表列如下: -15- 本紙張尺度逋用中國國家揉準(CNS ) Λ4規格(210X297公董) 一 83. 3.10,000 (锖先閲讀背面之注意事項再I笑本頁) -裝· 訂 線· A7^65304 B7 五、發明説明() 加工方式 限氣指数 (L . 0 . I ) «庚化長度 柔軟性 餘燃 寶施例1 35 3.3 ϊ nch ◎ 0 寶施例2 41 3 * 0 i nch ◎ 0 寶施例3 40 2.0!nch ◎ 0 比較例1 28 6.2 i nch △ 12 比較例2 26 完全燃燒 〇 — 附註: ◎表示佳 〇表示可 A 表示差 經濟部中央標準局負工消費合作社印製 由以上之表列結果則可明顯由寶施例一〜三之限氧指 數(L. 0.1 ) 大於35之效果,寶較如比較例之一般習闲防 水産品之限氧指數(L . 0 . T ) 28高出許多,再者由h列其 他之喊化長度、餘燃及柔軟性等相闞數捕中亦可明_比較 出該本锻明之寶施例一〜三結果.寶速優於如比較例------- 二所示之典型習用製造方法所製出之遮光阳燃裔_布産品 之寶驗数捕,故由此可知本锻明之遮光阻燃窗簾布之製造 方法則可播得極優良且兼具高阻燃及髙柔軟性能之遮光窗 簾布産品。 -16- 本紙張尺度適用中B國家標準(CNS ) A4规格(210X297公嫠) 83. 3.10,000 26SS04 A7 B7 五、發明説明() 綜上所述,本發明整艚之技術内容與技術思想賣爲前| I 所未見者,且本發明中遮光阻燃窗簾布之製造方法,無腧 在製作流程及降低産品生産成本方面,均可達伐期之目的 與功效,誠爲一利用自然法則之技術思想之髙度削作,且 亦合於産業上之利用價値,兹已符専利法潑明専利之法定 要件,愛依法具文申請之。爲此,懇請 贵審査委員詳予 審査,並析早日賜准専利,至慼德便。 (請先Η讀背面之注意事項再填寫本頁) 裝· 訂 經濟部中央橾準局貝工消費合作社印製 -17- 本紙張尺及_逍用中困國家標準(CNS ) 格(210X297公釐) 83. 3.10,000I. Binding line 265304 A7 B7 Printed by the Ministry of Economic Affairs, Central Bureau of Economic Affairs, Jeonggong Consumer Cooperative V. Description of the invention (), A. Composition technology of the manufacturing method of the shading aiming curtain curtain fabric of the present invention and its manufacturing process step 1 (1) in PU resin In the process of composition, Di local added commercial properties of flaming spurs (composed of the main flame retardant spurs of the 歯 and Lian series, inorganic flame retardant spurs, and special heat-resistant flame retardant series _ and other parts), and was ground by three rollers. After the machine is fully reconciled, it will be molded with a release cloth line, first to produce soft and flame-retardant flame retardant film products for use. Ο (2) Another is non-yellowing PU resin, acrylic resin or both In the process of resin composition, the mixed high-performance flame retardant, orange agent, bridging accelerator, anionic surfactant and shading color, etc., are added locally and fully neutralized by the three-parent Jane grinder After that, a flame-retardant light-shielding resin with flame retardant, light-shielding properties and adhesive properties is made. (3) Apply the flame retardant film finished in step 1 to the flame retardant and shading effect resin adhesive layer obtained in step 2 above, and then apply the flame retardant film to the curtain fabric or embroidery to make the flame The fabric or knitted fabric has excellent flame retardant and Diguang functions, and is made into the shading burnt curtain fabric product of the present invention. (4) In addition, the main flame retardants used in the above operation steps 1 and 2 of the present invention are composed of Yusu series flame retardants and antimony series flame retardants, etc., and the halogen series flame retardants and the satin series The mixed ratio of flame-retardant chip is in the range of 1: 1 0 ~ 1 0: 1, and the preferred state is the ratio of 1: 1 ~ 4: 1. -6- This paper baht scale is applicable to the Chinese National Standard (CNS) A4 specification (210 > < 297mm) 83. 3.10,000 Please read the notes on this page first and then this page binding line Ministry of Economic Affairs Central Standards Bureau Beigong Consumer Cooperative Printed 265304 a? B7 V. Description of the invention (), (5) In addition, the inorganic series used in the above-mentioned invention _to help flame retardant | I, babe tSMg (0H) 2 ♦ Al (0H) 3, MoOj , P, CaC〇5 ', ca〇Aiao5 ♦ 6Hzo, Mgco5, Cuo. CUjto compound is made up, and the additive is Zn, Mg, ZrOj ;, T i 〇z, Si〇z, SnO, ZnO, BaBjfCU It is composed of inorganic compounds such as inorganic compounds, and the above-mentioned inorganic series of shaft flame retardants and additives in the PU resin raw materials are added to the core PU resin 3 ~ 100w.t% & l ~ 30w. T% i dagger (6 ) In order to make the above-mentioned main flame retardants, inorganic series auxiliary flame retardants and additional ingredients such as additives can be mixed uniformly, and the material diameter of the ingredients is distributed below 5 microns, then it is fully ground by a three-roller simple grinding machine And the particle size of the formula is distributed below 5 microns, and the preferred particle size distribution range is 2 microns. , And use anionic interfacial active compound to improve its emulsification stability during grinding, (7) The adhesive layer used in the second step of this invention is non-yellowing PU resin (also can be acrylic resin or Non-yellowing type PU resin and acrylic resin are mixed resin) composition, added with excessive amount of high performance flame retardant, orange frame agent, orange frame accelerator, anionic surfactant and shading colorant, after After being fully blended, the three-layer simple grinder is formulated with a flame retardant and light-shielding adhesive layer α (8) The light-shielding colorant used in the operation steps of the present invention is an organic colorant or gold powder or silver powder , Sales powder, copper powder, carbon black and other inorganic colors. > (9) The objects used in the second operation step of the present invention may not be used | -7--III-I equipment--I order 1 II carry on (please read the precautions on the back first ^, > This page) This paper uses the Chinese National Standard (CNS) A4 (210X297mm) 83. 3.10,000 265304 A7 B7 Printed by the Central Bureau of Economic Affairs of the Ministry of Economy, Industry and Consumer Cooperatives 5. Description of invention (), Flame-retardant and raw thin substrate (for example: cotton, polyester or mixed fabric of polyester and cotton), flame-retardant substrate (for example, poly brew, poly amine fabric) and after appropriate flame retardant treatment The base material (for example: cotton, poly vinegar and poly amine fabric) is made of eaves. (10) In addition, the orange agent used in the second step of the present operation is the adduct of TMP and TD [the adduct of TMP and HDI and the adduct of TMP and IPDI or HDI. Triad compound 〇 (11) In order to make the flame-retardant products made by the present invention have high flexibility and have both flame-retardant shading or knitted fabrics, in the first step of the present invention, it is made of release cloth The flame-retardant film is combined with the flame retardant and shading effect of the second layer described in the second step, so that the fabric with the leak-proof flame-retardant film becomes a curtain cloth product with commercial flame retardant and high shading performance. (12) After the above manufacturing and operating steps of the light-shielding and flame-retardant curtain fabric products of the present invention, it is possible to broadcast high-quality flame-retardant and light-shielding curtain fabric products that have all the above steps. After the detailed description of the manufacturing process and manufacturing steps of the method of manufacturing curtain-burning fabric products, the technical content and technical means of Benpomin have been initially revealed, but in order to make your review committee more advanced- Steps to explain the technical focus of this book and the value of the industry's profitable value. Here are a few examples and comparative examples of the best treasures to explain them. Among them: B. The total treasures: 1. In the present invention The raw material of PU resin used is made of polyol and dii-8. A paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) 83. 3.10,000 Please read the note first and then the binding line on this page ^ 65304 A7 B7 Printed by the Ministry of Economic Affairs of the Ministry of Economic Affairs of the Ministry of Economic Cooperation of the Monthly Industry Consumer Cooperative V. The description of invention (), socyanate chain extender, and the p-olyol types are polyester polyol., Polycarbonate p-olyol and po 1 y ea-pro 1 actone polyol series mainly; diisocyanate compounds have two types of yellowing and non-yellowing, and in the present invention, yellowing PU resin raw materials or non-yellowing PU resin raw materials can be used; Modified PU resin must add ultraviolet absorber and anti-gasification agent to make it difficult to turn yellow; the chain ex tender part mainly includes di ο 1 series and di am i ne series? There are two types of I; diol has EG, 1,3PG, 1,4B.D., 1,5P.D., 16, HD and short bond diol (eg: H〇- < n > ~ <; S > -〇H ... etc.), And the diamines are HH, EDA. Η 2 N- < a > -CH- < 5 > -NH… and so on, and then undergo a period of polymerization or two The PLJ resin is synthesized in a stage polymerization mode, and after synthesis, it is diluted with DMF to a 30% PU resin solution. 2. In order to impart the excellent flame retardant effect to the above PU resin solution, the main flame retardant thorn, auxiliary series flame retardant and various added thorns are added to the formulation, and the added various flame retardants and additives such as Relevant types and composition are detailed as follows: a. The main flame retardant includes two types of flame retardant _ abandoned flame retardant and shop series flame retardant, and Paraffinine chlorinated ^ Decabromodiphenyl oxide in the flame retardant series , Hexach1oro ben-zene ^ Hexabromo benzene, Pentabromo ethyl benzene, Pentabromo diphenyl oxide., Ootabr-omo diphenyl ether, etc. ft: thing; i younger brother 1 P and flammable agent-9 (CNS> A4 wash grid (210X297mm) 83. 3.10,000 Please read the notes first and then this page binding line Printed by the Ministry of Economic Affairs Central Standards Bureau® C Industrial and Consumer Cooperatives 265304 A7 B7 V. Description of invention (), Bei U has two kinds of taco compounds such as Sba〇s, Sb, 〇5, etc. b. Auxiliary series flame retardants and additives _aside from the auxiliary series flame retardants _ and additives are CaCOi, CaOA1; ^ 04 • 6H * CU A1 (0H) 3. MgCOH L, MgC〇3, Mo〇3, Si 0 2 ^ CuO-, Cua 0 ^ Zn% ZnO Λ 2ZnO * 3Ba, 〇3 * 3.5ΗΛ 0, BaB; i (¾, T i 0Z, SnO and other inorganic compounds Composed of: C. Bao Shiyi Example 1: 1. Desizing, neem, dyeing, definite-resistant Long Ping cloth, the composition is 70D / 24F, 210, and 2% fluorocarbon resin pressure treatment , The pressure absorption rate is 40%, and then baking and shaping to make a release cloth. 2. Apply the surface layer coating liquid that has been configured to the release cloth made in step 1 described in step h by applying the 73 method The coating amount is about 100 ~ 300 g / ma, and it is formed by a wet coagulation bath of 201 X 10 centigrade Celsius, processed by water washing and hot water washing, and then at 120 ~ 1 40 Celsius degrees. ; After drying in an oven at 0 temperature for about three minutes, you will get a soft and flame-retardant film. 3. The composition of the coating solution of the flame-retardant film in step 2 above is as follows: a. Polyester-type PU resin ( DU-1030 W) ............ 1 00g b. Halogen series flame retardant ............ 20 «c. Antimony series flame retardant ........................ 5κ d · Mg (0Η) * ............ ...................... 1 Og e. A] (0H ) 3 .............................. 10g f-M〇03 ........ ............................. 10k g. Anionic surfactant .............. ............ 6g -10- This paper scale uses the Chinese National Standard (CNS) A4 specification (210X297mm) 83. 3.10,000 I. Gutter '/' Please read the back first (Notes on this page again) A7 B7 printed by the Beigong Consumer Cooperative of the Central Standards Bureau of Yiku. V. Description of the invention (), h. Pigment ........................ ............. 20g 4. Apply the finished coating solution of the next layer to the surface of the flame-retardant film made in the above step 2 with a doctor blade , The coating amount is about 100 ~ 300g / m1, and then with 1 OKg / citT surface strength, and the non-flame retardant thin cotton flat fabric lamination treatment, and finally in the arch box at 1 70 ° C humidity After two minutes of heat treatment in the middle, you can get the curtain fabric products that have both flaming and shading characteristics. 5. The composition of the coating solution of the next layer in the above step 4 is as follows: a. Non-yellowing PU resin .......................... 100g b . HDI Triad Tie Frame Orange ................................ 5g c. Frame Orange Promotes Tick (Limb Compound) .... .............. 2g d. Halogen Abandoned Flame Retardant ........................... 20g e. Antimony flame retardant ........................... 5g f. Mg (0H) a ... ........................ lOg g. A1 (0H) j ............ ..................... 1 Ok h. MoO 5 ....................... .............. 1 Og i. ZnO ............................... ....... 1 5g j .Anionic surfactant .......................... 6κ k .carbon black .... ................... 20g D. Bao Shi Example 2: 1. The processing method is the same as Step 1, Step 2 in Bao Shi Example 1 And step 4, but the flame retardant cotton plain cloth is used. 2. The composition of the coating liquid of the flame retardant film is as follows: a. Polyester. Department * JPU tree Η purpose .................. 100g -11- binding line ·, 1. (Please read the precautions on the back before ^ w this page) This paper size is suitable for China National Standard (CNS) A4 specifications (210X297mm) 83. 3.10,000 ^ 65804 ΑΊ Β7 V. Description of invention ( ), B. Halogen series flame retardant ........................... i5g: c. Shop series flame retardant ... ................... 8g d. Mg (OH) * ........................ ................ ι〇κ e. A1 COH) 3 .............................. .......... 20g f · ZηΟ .................................... .. 15g s. Anionic surfactant .................... 6g h. Colorant ... 15g 3. The composition of the coating liquid is as follows: a. Non-yellowing PU resin .................... 10〇8 b. TMP and IPDI compounds .......................... 5g c · Tangerine accelerator ............. ............. 2g d. Halogen series flame retardant .......................... .... 1 e. Shop series flame retardant ......................... f. Mg (0Η) α ............ ...................... 1 〇 (5 g. A 1 (0Η> 3 ........ 2〇 {? H. ZnO ........................... 1 5g i. Anionic surfactant .............. ............ 6 kj. 1 〇g E. Bao Shi Example 3: (please read the note Ϋ on the back before filling in the page) • Binding · Threading · Ministry of Economic Affairs Central Standards Printing only by the consumer cooperative 1. The processing method is the same as step 1, step 2 and step 4 of Baoshi Example 1, but before step 4 is executed, an additional layer of shading layer coating step is added, and the fabric is flame retardant. Polyester fabric 2. The composition of the coating liquid of the flame retardant film is as follows: a.—Liquid aliphatic PI 丨 paste ..................... .ι〇〇κ | -12- This paper scale is printed in China ’s national standard (CNS> A4 size (210X297 mm) 83. 3.10,000 ^ 65S〇4 A7 B7 Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (), b. Halogen series flame retardant ........................ 15g c. Paving series flame retardant. ...................... 10g d. Hg (OH) i .............. .............. lOg e. Zr02 .......................... ......... .. lOg f. Anionic surfactant .................... 2g g. colorant .............. ..................... lOg 3. The composition of the coating liquid for the shading layer described in step 1 is as follows: a.—Liquid aliphatic PIJ resin ........................ 100g b. Halogen series flame retardant .................. ......... 10κ c. Paving series flame retardant ........................... 10t? D. Mg (0Η): .................................... 5κ e-ZrO2... ... ................................ 5g f. Anionic surfactant .............. ............... 2g g.carbon black .......................... 20g 3. The composition of the subsequent layer coating liquid is as follows: a. Non-yellowing type acrylic resin .................... 100g b. HDI Sanhe elegant bridge cutting. ........................ 5g c. Orange tackifier ..... 2g d. Halogen flame retardant ... ............... 15g e. Shop series flame retardant ..................... ........ l〇gf. Mg (OH) a ................................. .1 Or g. ZrOz ............ 10k h. Anionic surfactant ........ 2g i. Colorant ....... ............................ ..Τ〇κ _13—Please read the notes of Λ first and then f this% of the binding line paper. The speed of the paper is used in the B country (CNS) A4 specification (210X297 mm) 83. 3.10,000 — »ι. · Μηιπ > || ιίιϋΙΜΜΜΙΜ · Ι " · »" 11 · 1 · 1-· Printed 265304 ΑΊ _Β7_ V. Description of invention (), F. Comparative example 1: 1. First, on the release paper, first apply the surface layer coating liquid to the surface, the coating amount is 200g / n ^, and then pre-dry the condition at 90C X 2 minutes, and then follow the layer coating liquid In the coating step, the coating amount is mi50g / ma, and after the coating is completed, the hot air drying treatment step is carried out under the condition of 70 x 2 minutes, and the flame-retardant polyamide fabric is used as the base cloth. Then, the lamination step is carried out, and then the hot air supply treatment step is carried out at 160 ° CX for 2 minutes, and the ripening treatment step is carried out at 60 ° CX for 48 hours, and after shaving, the shading is obtained. Flame retardant curtain fabric products, 2. The composition of the coating liquid on the surface layer is as follows: a.—liquid Polyvinyl acetate PII resin .................. 100g b. Bromine and phosphorus containing PU compounds ............ ............. 25g c. Modified polyisocyanate ......................... 10g d. Urethane oligomer .. ....................... 5g e. Pigment ........................... ............... 20g 3. The composition of the subsequent layer coating liquid is as follows: a. Two-component polyurethane PU resin ............. ........... 100g b. Melamine orange agent .......................... 5g c. Bridge promotion Agent ........................... 2κ d. Halogen series flame retardant ... ............ 25g e. SicWpolyisocyanat.e ... 23g f. Urethane oligomer ...... ................... 5g g · Die thane amine ......................... 25 矜 | A 14- This paper also uses the Chinese National Standard (CNS) A4 specification (210X297 public daughter) 83. 3.10,000 I · installed j series (please read the precautions on the back and then this page) (Ministry of Economic Affairs Printed B7 by the β-Consumer Cooperative Cooperative of the Central Bureau of Vulnerability. V. Description of the invention (), h. Pigment .................................... ......... 25g G. Comparative Example 2: 1. Processing methods are also inferior to comparison The operations and treatment steps in the steps of Example 1, but the base fabric is a thin cotton fabric that is not flame retardant. 2. The composition of the coating liquid on the surface layer is as follows: a. —Liquid Polyurethane PU Resin .................. 1 OOg b. Halogen Series Flame retardant ..................... 25g c. Paving series flame retardant ... ................. 10g d. Modified polyisocyanate ....................... 12g e. Color Material ............................... 20g 3. The composition of the subsequent layer coating liquid is as follows: a. Two-component polybrew PIJ resin ........................ 100κ b. Halogen flame retardant ... .................... 25g c. Frame orange promotes remuneration ....................... ........ 1 8 «d.Colorant ..................................... 25κ by the above Forge the special manufacturing method of each Bao Shi example and comparative example, and make the curtain cloth products with flame retardant and shading characteristics according to different conditions, and according to ASTM D2863- Method 74 tests their oxygen-limiting index (L. 0. I), and the carbonation length and other data of CPA Bu 84 vertical combustion test machine, so that the test results are compared with the conventional methods, and the Measured phase comparison and comparison results (this issue The comparison of the effect of Mingbao ’s examples and comparative examples) is listed as follows: -15- The paper size is based on the Chinese National Standard (CNS) Λ4 specification (210X297 company director) 1.83. 3.10,000 (Read the notes on the back first Matters and then I laugh on this page)-Installation · Threading · A7 ^ 65304 B7 V. Description of the invention () Processing method gas limit index (L. 0. I) «Henghua length softness afterburning treasure Example 1 35 3.3 ϊ nch ◎ 0 Bao Shi Example 2 41 3 * 0 i nch ◎ 0 Bao Shi Example 3 40 2.0! nch ◎ 0 Comparative Example 1 28 6.2 i nch △ 12 Comparative Example 2 26 Complete combustion 〇— Note: ◎ means good 〇 means OK A indicates that the Ministry of Economic Affairs, Central Bureau of Standards, Negative Labor Consumer Cooperative printed by the above listed results can clearly show the effect of Bao Shi 1 to 3 oxygen limit index (L. 0.1) greater than 35, Bao is more like the comparative example The oxygen limit index (L. 0. T) 28 of general waterproof products is much higher. Furthermore, the number of other columns such as the length, afterburning and softness of column h can also be found in the comparison. The results of the first to third examples of this forging treasure. Baosu is better than the typical conventional manufacturing method shown in the comparative example ----- The shading of the sun-burning fabric_The treasures of the fabric products are tested, so it can be seen that the manufacturing method of the forging shading flame retardant curtain fabric can broadcast the excellent shading curtain fabric products with high flame retardancy and high softness. . -16- This paper scale is applicable to China National Standard (CNS) A4 specification (210X297 public daughter) 83. 3.10,000 26SS04 A7 B7 V. Description of invention () In summary, the technical content and technical ideas of the present invention Selling before | I have not seen, and the manufacturing method of the shading flame retardant curtain fabric of the present invention, no matter in the production process and reduce the production cost of the product, both can achieve the purpose and effect of cutting period, sincerely use natural The technical ideas of the law are refined and are also in line with the industry's utilization price. I have applied the legal requirements in accordance with the law. To this end, I urge your review committee to review in detail, and analyze as soon as possible to grant permission to Qi Debian. (Please read the precautions on the back first and then fill out this page) Binding · Order Printed by the Ministry of Economic Affairs Central Bureau of Customs Beigong Consumer Cooperatives -17- This paper ruler and the _ National Standard for Use in Distress (CNS) grid (210X297 Cent) 83. 3.10,000

Claims (1)

經濟部中央梯準局属工消费合作社印裝 ^65304 A8 B8 C8 D8 六、申請專利範圍 1. 一種遮光阻燃窗簾布之製造方法,係於PU樹脂組成中添 加以主要阻燃劑、無機系列輔助阻燃劑及特殊耐熱阻燃 系列添加削所構成之非水溶性之髙性能阻燃劑,經三概 筒研磨機充分摻和後,用離型布行溻式成型,而先行製 成阻燃薄膜成品;並再於無黄變PU樹脂組成遇程中,依 序添加以由主要阻燃_、無機系列輔助阻燃劑及特殊耐 熱阻燃_所組成之混合型髙性能阻燃刺、陰離子界面活 性劑、遮光性色料、以TMP與TDI之加合物和TMP與HD I之加合物及TMP與IPDI之加合物構成之架橘剡及梁橘 促進劑等,經三概简研磨機充分摻合後製成具阻燃、遮 光特性及接著性能之阻燃性遮光型之樹脂,並再將該阻 燃薄膜成品,藉由該咀燃性之遮光型樹脂,形成一具阻 燃及遮光性能之接著層,而貼合於繊物或編物上,而製 得具柔軟及髙阻燃遮光特性之窗簾布産品者。 2 .如申請専利範園第1項所述之遮光阻燃窗簾布之製造方 法,其中,該主要阻燃刺係以鹵素系列阻燃劑併用銻系 列胆燃劑,且該_棄系列胆燃劑與綈系列阻燃削之混用 比例範圍在1:10〜10:1之内,且以比例範圔在1:1〜4:1 間較佳者。 3.如申請専利範圍第1項所述之遮光阻燃窗簾布之製造方 法,其中,於該阻燃薄膜成品之製程中,賅PU樹脂、鹵 素系列及綈系列阻燃削、無機系列阻燃刺及特殊耐熱阻 燃系列添加劑等配料爾再經三輥简研磨機充分研磨,並 使其研磨後之配方液粒很分佈於5微米以下,而使該研 _Ί8— 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X297公釐) ---i--------f -裝------訂-----線 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 A8265S04 1六、申請專利範圍 磨後之配料得以均勻混合,及研磨粒彳1在2微米以下爲 最佳者。 4. 如申請寒利範圔第1 項所述之遮光阻燃窗簾布之製造方 法,其中,該無機系列輔助阻燃_係包括由Mg (0H )2、 Mo〇d、 A1 (0H)3 、 P、 CaCO? 、 (:8〇Α1χ03 * 6Ha0 、 MgCO^ 、CuO、Cu/〕等無機化合物類所構成者。 5. 如申請専利範園第1 項所述之遮光阻燃窗簾布之製造方 法,其中,該特殊耐熱阳燃添加割係爲Zn、Mg、Zr 、 Τί〇2、SiO*、 SnO、ZnO、Baf^C^ 等無機化合物類所 構成者。 6. 如申請専利範圔第1 項所述之遮光阻燃窗簾布之製造方 法,其中,該無機系列輔助阻燃劑及特殊耐熱阻燃添加 命I於PU樹脂原料添加量分別爲該PU樹脂之3〜100 w . t% 及1·* 30 w. t%之比例者。 7. 如申請専利範圍第1項所述之遮光阻燃窗簾布之製造方 法,其中,該架橘刺及架椭促進刺亦可爲HDT之三合雅 化合物所楙成者。 8. 如申請専利範園第1項所述之遮光阻燃窗簾布之製造方 法,其中,該遮光性色料係尤指以有機色料、金粉、銀 粉、銷粉、鋼粉及carbon black等無機色料所構成者。 9. 如申請専利範圃第1項所述之遮光阻燃窗簾布之製造方 法,其中,該峨物可爲不具阻燃性之薄基材、具陥燃性 之基材及經阻燃處理後之基材所構成者。 10. 如申捕専利範園第9項所述之遮光阻燃窗簾布之製造 -19- . 裝 訂 J 線 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 265304 韶 C8 D8 六、申請專利範圍 方法,其中,該縐I物中不具阻燃性之基材,係尤指如棉 、聚酯、棉及聚酯之、聚酿胺嫩物混紡物所構成者。 11. 如申請専利範園第9項所述之遮光阻燃窗簾布之製造 方法,其中,該織物中具随燃性之基材,係尤指如聚S旨 及聚酿胺繊物所構成者。 12 . 如申請専利範園第9項所述之遮光阻燃窗簾布之製造 方法,其中,該細I物中經胆燃嗛理後之基材,係尤指如 棉、聚醋及聚醯賊繊物所構成者。 13. 如申請専利範圍第1項所述之遮光阻燃窗簾布之製造 方法,其中,該阻燃薄膜之製程中,係以離型布製作濕 式之阻燃薄膜成品,俾以配合具阻燃作用之遮光型接著 層,而播得髙性能具阻燃及遮光之窗簾布。 ----------ί 裝------訂------冰 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 -20- 本紙張尺度適用中國國家梯準(CNS ) Α4規格(2丨0Χ297公釐)Printed by the Industrial and Consumer Cooperatives of the Central Bureau of Economics and Trade of the Ministry of Economic Affairs ^ 65304 A8 B8 C8 D8 VI. Patent application 1. A method of manufacturing light-shielding flame-retardant curtain fabrics, in which the main flame retardants and inorganic series are added to the composition of PU resin Auxiliary flame retardant and special heat-resistant flame retardant series are added with non-water-soluble high-performance flame retardant formed by cutting, after fully blended by a three-barrel grinding machine, it is molded with a release cloth and made into resistance first. Film-finished products; and then in the course of non-yellowing PU resin composition, sequentially add a mixed high-performance flame retardant consisting of main flame retardant_, inorganic series auxiliary flame retardant and special heat-resistant flame retardant_, Anionic surfactants, shading pigments, tangerine and Liangtang accelerators composed of TMP and TDI adducts, TMP and HD I adducts and TMP and IPDI adducts, etc. The Jane grinder is fully blended to make a flame-retardant light-shielding resin with flame retardant, light-shielding properties and adhesion properties, and then the finished flame-retardant film is formed into a flame-retardant light-shielding resin. Adhesive layer of flame retardant and shading properties, and fit Those who made curtain fabric products with soft and high flame retardant shading characteristics on the fabrics or knitted fabrics. 2. The method for manufacturing the light-shielding flame retardant curtain fabric as described in item 1 of the Fanli Garden, wherein the main flame retardant spur is a halogen flame retardant in combination with an antimony flame retardant, and the _discard series flame retardant The mixing ratio of the agent and the flame retardant series of flame retardant is in the range of 1: 10 ~ 10: 1, and the ratio is preferably in the range of 1: 1 ~ 4: 1. 3. The method for manufacturing light-shielding flame-retardant curtain fabric as described in item 1 of the scope of application, wherein in the process of the finished flame-retardant film, the PU resin, halogen series and satin series flame retardant chips, inorganic series flame retardant The ingredients such as thorns and special heat-resistant flame retardant series are fully ground by a three-roller simple grinder, and the grinded formula liquid particles are very distributed below 5 microns, so that the research _Ί8-This paper size is suitable for China Standard (CNS) Α4 specification (210X297mm) --- i -------- f -installed ------ ordered ----- line (please read the notes on the back before filling in this Page) A8265S04 1 printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. 6. The range of patent-applied ingredients can be evenly mixed, and the best size is less than 2 microns. 4. The method for manufacturing light-shielding flame-retardant curtain fabric as described in item 1 of Hanli Fanyi, wherein the inorganic series of auxiliary flame retardants include Mg (0H) 2, Mo〇d, A1 (0H) 3, P, CaCO ?, (: 8〇Α1χ03 * 6Ha0, MgCO ^, CuO, Cu /] and other inorganic compounds. 5. As for the application of the 1st Fanfan Garden, the production method of shading flame retardant curtain fabric Among them, the special heat-resistant flammable addition system is composed of Zn, Mg, Zr, Τί〇2, SiO *, SnO, ZnO, Baf ^ C ^ and other inorganic compounds. 6. If you apply for the first The method for manufacturing light-shielding flame-retardant curtain fabric described in the item, wherein the inorganic series auxiliary flame retardant and the special heat-resistant flame-retardant additive I added to the PU resin raw material are 3 ~ 100 w. T% of the PU resin and 1 · * 30 w. T%. 7. The method of manufacturing light-shielding flame-retardant curtain fabric as described in item 1 of the scope of application, in which the frame of orange thorns and frame ellipse-promoting thorns can also be HDT three Completed by He Ya Compound. 8. The method for manufacturing the light-shielding flame-retardant curtain fabric as described in item 1 of the Fanli Garden, in which the light-shielding Sexual pigments refer to those composed of organic pigments, gold powders, silver powders, sales powders, steel powders, carbon black and other inorganic pigments. 9. As for the application of light-shielding flame-retardant curtain fabrics mentioned in Item 1 A manufacturing method, in which the E-object can be composed of a thin base material that is not flame retardant, a base material that is flame retardant, and a base material that has undergone flame retardant treatment. 10. As described in Item 9 of Shenhufan Park Manufacture of light-shielding flame-retardant curtain fabric -19-. Binding J line (please read the precautions on the back before filling in this page) This paper size is applicable to China National Standard (CNS) A4 specification (210X297mm) 265304 Shao C8 D8 VI 1. The method of applying for a patent, in which the non-flame retardant base material in the crepe I refers to, for example, cotton, polyester, cotton and polyester, which is composed of a blend of polyamine amine tenders. Application for the manufacturing method of light-shielding flame-retardant curtain fabric as described in Item 9 of the Fan Garden, wherein the substrate with flammability in the fabric is especially composed of poly-S and polyamines. 12 . The method for manufacturing light-shielding flame-retardant curtain fabric as described in item 9 of the Fanli Garden, in which , The base material in this fine I after gall blazing treatment, especially those composed of cotton, poly vinegar and poly thieves. 13. Light-shielding flame-retardant curtains as described in item 1 of the scope of application Fabric manufacturing method, wherein, in the process of the flame retardant film, a wet type flame retardant film is made of release cloth to match the light-shielding adhesive layer with flame retardant, and the high performance is flame retardant And blackout curtain fabric. ---------- ί outfit ------ order ------ ice (please read the notes on the back before filling this page) Central Bureau of Standards, Ministry of Economic Affairs Printed by Employee Consumer Cooperatives -20- This paper standard applies to China National Standards (CNS) Α4 specification (2 丨 0Χ297mm)
TW83105291A 1994-06-10 1994-06-10 Process of producing light-shielding flame-retardant drapery TW265304B (en)

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Application Number Priority Date Filing Date Title
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TW265304B true TW265304B (en) 1995-12-11

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