TW219958B - - Google Patents

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Publication number
TW219958B
TW219958B TW081108596A TW81108596A TW219958B TW 219958 B TW219958 B TW 219958B TW 081108596 A TW081108596 A TW 081108596A TW 81108596 A TW81108596 A TW 81108596A TW 219958 B TW219958 B TW 219958B
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TW
Taiwan
Prior art keywords
nonwoven fabric
short
fibers
woven fabric
composite
Prior art date
Application number
TW081108596A
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Chinese (zh)
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Asahi Chemical Ind
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Publication of TW219958B publication Critical patent/TW219958B/zh

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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H5/00Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
    • D04H5/02Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by mechanical methods, e.g. needling
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00Other non-woven fabrics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425Cellulose series
    • D04H1/4258Regenerated cellulose series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326Condensation or reaction polymers
    • D04H1/435Polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • D04H1/74Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being orientated, e.g. in parallel (anisotropic fleeces)
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H5/00Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
    • D04H5/02Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by mechanical methods, e.g. needling
    • D04H5/03Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by mechanical methods, e.g. needling by fluid jet

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nonwoven Fabrics (AREA)

Description

219953 A6 B6 經濟部中央標準局&quot;K工消費合作社印製 五、發明説明(1 ) 技術範曄 本發明有關一種可用為手術衣、尿片、濾器等之具有 優越透氣性及耐水性之非織造布。 背景技藝 為增加非織造布之用途,需賦予非織造布各種特性。 其中之一是優越之透氣性及耐水性。實質上,透氣性為與 耐水性相反之性質。此者需在非織造布中具有許多由非織 造布之前表面延伸至其後表面之通孔以改善其透氣性,但 在改善透氣性的同時亦不可避免地降低了耐水性。 當非織造布用於醫學用途諸如手術衣時,需有較大: 細菌障壁性,即,需較大之耐水性以防止著衣者感染。此 外,在衣服因摺曲或壓縮而變形時,需不致使血液等物滲 過非織造布。而優越之透氣性是使汗漬達最少且不累積濕 氣之需求。 已有人提出兩種不同織物之組合物以谋足此兩相互矛 盾之性質,透氣性及耐水性。 例如,日本未審理專利公告(Kokai) No. 64 — 61555掲示一種複合板之製造技術,其將包括兩種具 不同細度之短纖維的分散液舖於可收縮之針織布上並在水 注流中使短纖維本身充分交織並交織於針織布中。此種複 合板具優越之透氣性,但複合板之耐水性差。日本未審理 專利公告(Koka i ) 1 — 1 1 1 ◦ 5 6掲示一種複合型非 織造布,其包括由漿粕及短纖雒組成之非織造布,及纖維 (請先閲讀背面之注意事項再填V +頁) 裝· 訂. .線. 本纸張又度適用中國國家標準(CNS)甲4規格(210 X 297公贷) -3 — 81.9.25,000 經濟部中央標準局員工消費合作社印製 $广月•氬 - 五、發明説明(2 ) 非織造布。雖然據公告中陳述,此種複合型非織造布可用 爲手術衣,但其耐水性顯然並未明顯改善。 上述非織造布在摺曲或壓縮時同樣會滲漏。 發明揭示 本發明標的是提出一種非織造布,其具充分透氣性及 耐水性,因摺曲或壓縮等而變形時幾乎不滲漏,且强度及 可撓性優越。 符合本發明標的之禊合型非織造布包括具以下要素( 1 )至(3.)之短纖維非織造布(A)及纖絲非織造布( B),彼纖絲部分彼此聯結,其中構成短纖維非織造布( A )之部分短纖維嵌入纖絲非織造布(B )中並與構成纖 絲非織造布(B )之纖絲交織,產生短纖維非織造布(a )及纖絲非織造布(B )之層體,在複合型非織造布中隨 意切面中長5 0 0&quot;m之區中嵌至纖絲非織造布(B)厚 度之1/2或更深之短纖維數n爲2 0或更少; (1 ) F + S25 0%重 1 / 7 S F / S S 4 / 3 式中: F :細度0 . 3旦尼爾或更小之短纖維在所有短纖維 中之比例 3:細度0· 5旦尼爾或更大之短纖維在所有短纖維 中之比例 (2 )每單位面積短纖維之重:1 〇 g/m2至4 〇 本纸張又度適用中國國家標準(CNS)甲4規格(210 X 297公釐〉 ---------^----------------裝------訂 (諳先閱讀背面之注意事項再塡寫本頁) 219958 A6 ___B6_ 五、發明説明(3 ) g / m 2。 (請先閲讀背面之注意事飧再填r 4頁) (3)平均定向度:2. 0至1〇 附圖簡述 匾1為本發明複合型非織造布實例之切面的電子顯微 相片; 圖2為圖1中所示之複合型非織造布之橫切面視圖; 圖3為習用複合型非織造布之横切面視圖; 圖4為同於圖2之複合型非織造布之横切面視圖,除 了添加標準線X。及Y。外; 圖5為定義欲用以測量纖維之平均定向度的直線部分 之視匾; 圖6為說明短纖維之平均定向度與非織造布之耐水性 間之闊偽的圖。 較佳實例描述 經濟部中央標準扃R工消費合作社印i衣 以下將就顯示本發明複合型非織造布實例之附圖描述 本發明。 圖1為本發明複合型非織造布實例之橫切面的電子顯 微相片,而圖2為圖1所示之複合型非織造布之對應横切 面視圖。圖3為習用且一般之複合布的切面視圖。如圖1 及2所示,複合型非織造布包括短纖維非織造布A,其包 括細度◦. 3d或更少之短纖維及細度◦. 5d或更大之 短纖維,與纖絲非織造布B。許多在短纖維非織造布A中 本纸張尺度通用中园國家標準(CNS)甲4规格(210 X 297公釐) -5 - 81.9.25,000 219953 A6 B6 經濟部中央標準局員工消費合作社印製 五、發明説明(4 ) 之短纖維排列在複合型非織造布表面上相當平行之面上, 且短纖維非織造布A中之短纖維與纖絲非織造布B中之纖 絲僅在彼此間之界面交織,此外,短纖維非織造布A中之 短纖維未深嵌於纖絲非織造布B中。圖3所示之習用複合 型非織造布中,構成短纖維非織造布C之短纖維2 1在高 壓下藉柱狀液流深嵌入纖絲非織造布D中,因此短纖維-2 1與構成纖絲非織造布B之纖絲高度交織。因此,雖然 圖3中所示之複合型非織造布由兩種非織造布形成,但所 得之複合型非織造布具有類似由短纖維2 1與纖絲2 2混 合形成之單一非織造布之外觀。 本發明複合型非織造布之第一個特色爲細度0. 3旦 尼爾或更小之短纖維比例F及細度0. 5旦尼爾或更大之 短纖維比例G之和在短纖維非織造布A中爲5 0 %重或更 大,F/G之比例爲1至7或更大及4至3或更少,且短 纖維非織造布A每單位面積重量爲1 0 g/tn2及4 0 g /m2間。短纖維11之細度爲0. 3旦尼爾或更小,較 好爲0. 15旦尼爾或更小,〇_ 001d或更大。並非 所有短纖維皆需具相同細度,短纖維1 1可藉裁切纖維製 得,例如,由海島型纖維分離海組成物,分離具有二或多 種組份之複合型纖維,或以直接紡絲等法所得之超細纖維 。短纖維1 2之細度爲0 . 5 d或更大,較好,0 . 75 旦尼爾或更大及1 0旦尼爾或更小。並非所有短纖維1 2 皆需具相同細度,但短纖維1 1之纖維長度較好大於複合 型非織造布之厚度,但短纖維11與短纖維12並不需具 本紙張尺及通用中國S家桴準(Cfs\S)甲4规格(210 X 297 ) &quot; ~ ' ' ------------------~-------裝------訂 (請先閱讀背面之注意事項再塡寫本頁) 經濟部中央標準局S工消費合作社印製 219953 A6 ________B6_ 五、發明説明(5 ) 相同之缕維長度。 短纖維1 1改善複合型非織造布之耐水性,但當短纖 維1 1在短纖維非織造布A之所有短纖維中之含量增加時 ,透氣性降低。短纖維12具有與短纖維11相反之功用 。因此,當F/G為1至7或更大及4至3或更小時,短 纖雒1 1及12具優越平衡,因而複合型非織造布得到優 越之透氣性但不降低耐水性。但是,F與G之和需為 5 0%重或更大且當F與G之和少於5 0%重時,難以得 到優越效果。因此,F與G之和較好為7 0%重或更大。 毎單位面積之重需為1 0 g/m2或更大及40 g/ γώ2或更小。當每單位面積重超過40g/m2時,複合 型非绻造布之透氣性降低且當每單位面積重低於1 〇 s/ m2時,複合型非織造布之耐水性降低。 短纖維非織造布A之表觀密度較好為0.lg/m2 ,以改善複合型非織造布之耐水性。非織造布之表觀密度 的測量方法述於下文。 複合型非織造布之第二特色為短纖維非織造布A中短 纖維之平均定向度Z為2.◦或更大及1◦或更小。平均 定向度Z為顯示在短纖雒非織造布A之短纖維中與纖絲非 織造布B之表面平行之組份及與纖絲非織造布B之表面垂 直之組份間之比例。平均定向度之測量法述於下文。 本案之發明者發現在複合型非織造布中因摺曲及壓縮 力産生之變形所致之滲漏由平均定向度Z之值而定。圖6 顯示說明短纖維之平均定向度與非織造布間之耐水性的關 (請光閱讀背面之-注意事·項再谪本頁) -装. 訂. —線. 衣紙張尺茂通用中國國家標準(CNS)甲4規格(210 X 297 ) - 7 - 81.9.25,000 219S58 A6 B6 經濟部中央橒準局具工消費合作社印髮 五、發明説明P ) 係之圖。如圇6所示,在短纖維之平均定向度Z與具相同 組成及每單位面積重之非織造布的耐水性間顯然有直線關 係。即使複合型非織造布承受摺曲或壓縮,仍可有效防止 滲液,而得到具優越耐水性之複合型非織造布。當平均定 向度Z超過1〇時,構成短纖維非織造布A之短纖維間之 交織及短纖維非織造布A與纖絲非織造布B間之交織減低 ,使複合型非織造布之强度降低。 因此,需使平均定向度爲2. 0至10,較好2. 3 至10,2. 5至8. 0更佳。 本發明複合型非織造布之第三特色爲在複合型非織造 布之隨意切面長5 0 0 區中嵌至纖絲非織造布B )厚 度之1/2或更深之短纖維數N爲2 0或更少。N之測量 法述於下文,當N超過2 0時,複合型非織造布之耐水性 降低。 如前文所述,本發明標的可藉具特結構之短纖維非織 造布A與纖絲非織造布B之整合達成。 紡粘法所製之非織造布可用爲纖絲非織造布B。構成 纖絲非織造布B之纖絲藉熱熔或使用粘合劑使其彼此部分 粘結以固定其結構。因爲在纖絲非織造布B中粘結部分不 可能與短纖維非織造布A中之短纖維交織,故粘結部分總 面積對纖絲非織造布B總表面積之面積比較好爲2 %至 2 0 %間,且較好使用細度爲0 . 5旦尼爾之纖絲,當在 直角兩向測得之斷裂伸長度平均値爲4 0 %或更少時,在 兩非織造布交織時短纖維可輕易適合以上安排。 ---^-------------- -------裝------訂 (諳先閱为背而之注*&quot;項再塥.骂本頁) 尽紙張適用中KK家抒準(CXS)甲'!規丨!·(210 X ‘297公竑) 219958 A6 B6 蛭濟部中央標準局!®工消費合作社印製 五、發明説明(7 ) 任一種纖維皆可用於本發明之複合型非織造布中。例 如,可使用熱塑性樹脂諸如聚醯胺類纖維、聚酯類繼維、 聚烯烴類纖維、聚丙烯睛類纖維等、乙酸酯類纖維、再生 纖維素類纖維等。此外,若需要,則可使用天然纖維素纖 維、羊毛缕維等,且當再生纖維素纖維用為短纖維非織造 布A時,用於交織之水注産生的軌跡及水注産生之開口可 輕易去除,因而可防止耐水性降低。 聚酯纖雒用於短纖維非織造布A中時,增加了纖絲非 織造布B與短纖維非織造布A中之交織。因此,當使用聚 酯類纖維比例為1至3或更大且再生纖維素類纖維比例為 1或更小時,可得到使用再生纖維素類纖維及聚酯類纖維 之结果所得的持色。 此外,除了細度0. 3旦尼爾或更小之短纖雒及細度 為0. 5旦尼爾或更大之短纖維以外,在短纖維非織造布 中所有短纖雒中較好使用5%重及15%重間之原纖雒化 漿粕狀之纖維,以得到具耐水性及抗張強度稍有改善,但 不降低透氣性之複合型非織造布。原纖化漿粘狀纖維可藉 打擊天然漿粘或可撕裂之丙烯酸糸纖維而得。 本發明複合型非織造布之製法述於下文。 將預定混合比之◦. 3旦尼爾或更小之短纖維及 0. 5旦尼爾或更大之短纖維分散於水中,並將分散液裂 紙得到短纖雒非織造布A。此情況下,較好在分散液中添 加界面活性劑以改善纖維在水中之分散性。其次,將纺粘 法所製之纖絲非織造布B層舖於短纖維非織造布A上。此 (請4閲讀背面之注意事項再填^ |頁) 丨裝. 訂. 衣纸張又度適用中國國家標準(CNS)甲4规格(210 X 297公笼) -Q - 81.9.25,000 烴濟部中央標準局8工消費合作社印製 219958 A6 _B6 五、發明說明(8 ) 層狀物是在纖絲非織造布B上藉將構成短纖雒非織造布A 之短鐵維直接製紙而得。 層狀物藉柱狀流體整合。即是將5 0至2 0 0 me s h之鐵絲網置於在鐵絲網輸送帶上之層狀物再噴嘴 間,且將壓力為3〇kg/cm2或較小之水流由50至 1 ◦0◦ r pm之噴嘴經50至200me s h之鐵絲網 注於層狀物上。通常使用具有多個直徑在0. ◦ 5mm及 0. 3mm間之孔的噴嘴。短纖維非織造布A中短纖維之 平均定向度可藉在噴嘴與輸送帶間置入鐵絲網並控制噴嘴 壓力而控制於前述範圍内,由是可得具優越透氣性及耐水 性之複合型非織造布。 較好再於複合型非織造布上施加防水處理以得到具有 良好耐水性之複合型非織造布。至於已知之防水劑,可使 用,例如,矽酮類防水劑諸如二甲基胺基矽酮等,或氣類 防水劑諸如全氟芳族物等,且防水劑之累積固體部分較好 約0. 1% — 5%複合型非織造布重。 評估本發明複合型非織造布特性所用之测量法述於下 文。 短纖維非織造布A中短纖維之平均定向度的測量法。 1. 由複合型非織造布裁下20crri平方之試片。 2. 試片之縱向及横向皆毎5cm裁一刀,得到 1 6塊5 c m平方之小塊。 3 . 由1 6小塊中隨意選擇3小塊。 4 . 所選擇小塊之横切面以1 ◦ 0倍以電子顯微鏡 (請先Μ讀背.面之注意事項再填一 4頁) 裝. 訂. .線. 衣纸張尺度適用中國國家標準(CNS)甲4規烙(210 X 297公延) ~ 1〇 - 81.9.25,000 2199〇3 A6 B6 經濟部中央標準局貝工消费合作社印製 五、發明說明(9 ) 照相。彼時,在各小塊之兩相郯邊的缕絲非織造布B中不 具部分聯結的部分顯撤照相,因而裂得6張相片。 5. 如圖4所示,各電子顯微相Η中構成纖絲非織 造·布Β之纖絲终端數由纖絲非織造布Β表面之外部向内計 數;由第四终端之切面中心向第五终端切面中心劃一直線 X。,其排列於距離第四终端至少30 Aim之處。此線 X。示此複合型非織造布之標準線。另一標準線Y。繪於 與檫準線Χσ垂直之方向。 6 . 在各電子顯微相片之中間部分平行標準線Υ 〇 繪出距離5cm之垂直線Υ; , Υ2。 7. 在垂直線Υ:及丫2間各選擇縱向長度為纖雒 最大直徑之10倍的0. 3旦尼爾或更細之短纖維及 〇.5旦尼爾或更粗之短纖雒。 8. 如圖5所示,示短纖維中心線L之任一點 ,Ρ 2點選擇於中心線及聯結Ρ ,點與Ρ 2點之直線 卩/卩2上。彼時,當繪出正切於中心線L之直線 時,直線P;P2與切線間之距離_±_ 小於纖維直徑且P ,點與P 2點間之長度比直徑X-之 4倍大。 9. 其他點Pa、P4 ......... P«依同法決定,短 纖維分成許多直線。決定P/、p2 .........P«點之方法 應用於所有在步驟7所選之短纖維。 10. 方向與檫準線X。平行之組份X™及方向與 標準線Y。平行之組份Yn是對各短纖維之各段直線作數 &lt;請先閲讀背«之注意事項再?4頁) 丨裝. 訂 .線. 本紙張尺度適用中S國家標準(CNTS)甲4規格(210 X 297公贷) -H - 81.9.25.000 2139a3 A6 B6 經濟部中央標準局员工消費合作社印製 五、發明說明(10) 量分析,並計算Xn及γη值之和為X及Y。 11. 計算Χ/Υ比例,平均定向度Ζ以來自六張 電子顯微相片之平均值Χ/Υ決定。 嵌入繼絲非織造布Β之短纖維數(Ν )之測量法 1. 如平均定向度之測法般製得相同之三小塊複合 型非織造布及相同之六張電子顯微相片。 2 . 藉由此三小塊各剝除纖絲非織造布Β而製得三 共纖絲非織造布Β。纖絲非織造布之厚度在四點上使用壓 縮試驗機(KES — FB — M3, KES — FB — Ε3) ,其來自ΚΑΤ0 TECH C0. , LTD.,藉K E S — F Β試驗糸統 之壓縮性測量法在1 g /m 2壓力下測量,所得之1 2個 各點間之距離至少2 cm或更大,纖絲非織造布B之厚度 T B由具有厚度值之平均值決定。 3 . 平行於標準線X。且具有步驟2所得之T B之 一半值的距離之直線1 /2 Τ Β各繪於六張電子顯微相 片中。 4. 計數在相距500wm之垂直線丫2與丫2間 與直線1/2 TB相交之短纖雒數,N定為在6張電子 顯微相片中所得之平均數。 短纖維非織造布A之密度測量法 1 . 裂得同於平均定向度測量法中所用之6張電子 顯徹相片。 (請先閱讀背面之注意事項再墀本頁) .装. 訂. —線- 本紙張尺茂適用中S國家揉準(CNS)甲4规烙(210 X 297公贷) -12 - 81.9.25,000 219953 A6 B6 經濟部中央標準局WK工消費合作社印製 五、發明説明(11) 2. 藉同於平均定向度测量法中用於繪製標準線 X。之方法,沿短纖雒非織造布A之上表面及下表面繪出 標準综X:及X2。標準综X/及X2相交所得之小段垂 直線Υ ζ及Υ 2用以測得6張電子顯微相片,並以六張顯 微相片所得之厚度平均值作為短纖維非織造布Α之厚度Τ (u τη ) 0 3. 短纖維非織造布Α之每單位面積重W(g/ m2)是依JIS—L—1096測量複合型非織造布之 每單位面積重並由複合型非織造布之每單位面積重扣除短 纖雒非織造布A數字N之測量法中所得之纖絲非織造布B 之每單位面稹重得到。 4. 短纖維非織造布A之密度是由W/T (g/ m 3 )得到。 摺曲硬度 複合型非織造布之摺曲硬度依K E S - F B試驗糸之 摺曲性質測量法測得。對應於短纖維非織造布A及纖絲非 織造布B交織之方向的縱向及複合型非織造布之横向藉 KATO TECH CO., Ltd.純摺曲試驗器試驗5次,且複合型 非織造布之摺曲硬度定為所得值之平均值。 透氣性 複合型非織造布之透氣性由J I S-L —;L 〇96之 破碎型試驗測量,並由5次測量之平均值表示。 {請先閲讀背面之'注意事喷再埸,'4頁) -裝. 訂. 線. 本纸張尺度通用中國g家樣準(CNS)甲4規格(210 X 297 ) _ 13 - · 81.9.25.000 經濟部中央標準扃βκ工消費合作社印製 219953 A6 ____B6_ 五、發明説明(12) 斷裂強度 複合型非織造布之斷裂強度依JIS-L—1096 測量。首先,裂得寬3cm且夾點距離1〇cm之試樣, 以 TOYO BALDWIN CO., Ltd.,所裂得 Tensilon UTN-1 測量 斷裂強度,並以5次測量之平均值表示(kg/cm)。 斷裂伸長度 複合型非織造布之斷裂伸長度使用同於斷裂強度之方 法測量,並以5次測量值之平均值表示。 耐靜力水壓性 耐水性由在具有1 0 0 0m i nHzO或更小之耐靜 力水壓性之試樣上以低靜水壓法依J I S — L — 1092 測量,並以5次測量值之平均值表示(m m Η 2 ◦)。 Me i son jar 試驗 依 JST80, T — 70, MEISON JAR Method 測量 在複合型非織造布試樣上施加1 14mmH2◦水柱壓之 生理食鹽水至開始滲漏液體之時間,結果以3次測量值之 平均值表示。在Me ison jar test中具有6 0分鐘或更大 值之複合型非織造布可接受。 在壓縮或摺曲寺之抗滲漏性 由複合型非織造布裁得10 cm四方之試片。另製得 (請先閲讀背面之注意事項再項,4頁) .裝. 訂' 線. 本纸張又&gt;1適用中國國家標準(CNS)甲4規格(210 X 297 X延) -14 - 81.9.25,000 經濟部中央標準局mrH消費合作钍印製 219953 A6 __B6 五、發明説明(13) 兩片在中心有直徑6 cm之孔的10 cm四方板片,將試 片置於兩板片間。以滴管將1 0 c c有色之生理食鹽水倒 於上板孔之中心部位。將試片連同兩板片置於丙烯酸条樹 脂圓筒上,其内徑90mm且外徑lOOmm,圓筒置於 TOYO BALDWIN CO., LTD.之 Tensilon 0TM-1 上,且試片之 中心部分藉具有曲度為c m之表面且衝程為2 Omm之桿 往返推動。當有色之生理食鹽水分散在經由丙烯酸糸圓筒 看見之試片下面時,計數桿之頻率。抗滲液性以5次測量 之平均值評估。 本發明將就本發明之複合型非織造布實例詳细說明。 下文之實施例中所有之複合型非織造布皆施以下列防 水處理並測量複合型非織造布之持性。 防水性:A s a h i Guard Series AG-433,來白 MEISEI KAGAKU Co· . Ltd · 處理:複合型非織造布浸入含5%防水劑之水溶液中 ,在1〇〇它乾燥2分鐘,並在160=熱化1分鐘。 實施例中層狀物之複合法由水注施加。水注處理之主 要條件如下: 水注噴口直徑:◦. 2mm 噴嘴與複合型非織造布間之距離:30mm 排列於噴嘴與複合型非織造布間部位之鐵絲網: 7 Ome s h之鐵絲網 噴嘴旋轉條件: (請先閲讀背面之注意事項再填寫本頁) —裝· 訂. -線. 本紙張又度適用中國囷家櫺準(CNS)甲4規格(210 X 297公延) —15 - 81.9.25,000 219903 A6 B6 烴濟部中央標準局βκ工消費合作社印5典 五、發明説明(14) 旋轉半徑:6 m m 旋轉速度:200 r pm 窨旆例1 將預定量之細度為0.1旦尼爾且長度為5mm之聚 對苯二甲酸伸乙酯短纖維,及量同於聚對苯二甲酸伸乙醋 短纖雒之細度為1旦尼爾且長5mm之粘膠人造絲短纖維 分散於水中並攒拌成濃度為0. 63%之漿液。在傾斜鐵 絲網製紙機中將漿液製紙,得到每單位面積重2 5 g / m2之短纖維非織造布A。 纖絲非織造布B則是將聚對苯二甲酸伸乙酯熔融纺絲 ,以吸氣管拉伸由纺絲口擠出之熔融聚合物以製得均勻鐵 絲網,並使用表面有許多凸起部分之上壓花棍與平面之下 锟將該網熱壓。此種纖絲非織造布B之纖絲細度為2旦尼 爾且所得之纖絲非織造布B每單位面積重為2 5 g/m2 且平均斷裂伸長度為2 2. 5%。纖絲非織造布B層叠於 短纖維非織造布A上,然後各由纖絲非織造布B之上面及 短纖維非織造布A之底面施加水注處理.製得本發明之複 合型非織造布。若需要,則水注處理藉改變水注壓力三階 施加。即,在第一步驟中所用之水注壓力為15ks/ cm2 ,第二步驟為15kg/cm2 ,且第三步驟為 30 kg/ cm2。纖絲非織造布B中,歷彳£處理所産生 之聯结部分的面積比為非織造布Β所有面積之10%。 (請先閲讀背面之注意事項再«;'4頁) 裝. 訂. .線. 本纸張又茂適用中因國家標準(CNS)甲4規烙(2丨0 X 297 W«) - 16 - 81.9.25.000 219953 A6 B6 經濟部中央標準局®r工消費合作社印製 五、發明説明(15) 奮旃例ρ _ Λ 實例2至4中,使用裂紙法將短餓維非織造布Α直接 層《於同於例1之纖絲非織造布B上。即,細度0 . 1旦 尼爾且長度5mm之聚對苯二甲酸伸乙酯短纖維,及細度 〇. 1旦尼爾且長度5mm之粘膠人造絲短纖維以三種組 成比分散於水中並攢拌形成濃度為◦. 63%之漿液。每 單位面積重2 5 g/m2之短纖雒非織造布A直接製紙於 纖絲非織造布B上以裂得層狀物。 非織造布A中短纖維之組成 實施例2 實施例3 實施例4 〇.1旦尼爾之短纖維 1 1 3 1旦尼爾之短纖雒 1 3 17 層狀物藉同於例1之方法以來自層狀物上面及底面之 水注處理施加,製得例2至4之複合型非織造布。即,第 —步驟為15kg/cm2 ,第二步驟15g/m2且第 三步驟3 ◦ k g/c m2之壓力各依序施加於層狀物之兩 面。 實施例5 5重量份數細度◦.1旦尼爾且長度5mm之聚對苯 二甲酸伸乙酯短纖雒,7重量份數細度1旦尼爾且長度 5mm之粘膠人造絲短纖維及8重量份數細度0. 4旦尼 (請先閱讀背面之注意事項再说本頁) —裝. 訂· .線. 本紙張又度適用中國國家標準(CNS)甲4规格(210 X 297公楚) -\1 - 81.9.25,000219953 A6 B6 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs &K; K Industry and Consumer Cooperatives 5. Description of the invention (1) Technical Fan Ye Weaving cloth. Background Art In order to increase the use of non-woven fabrics, various characteristics of non-woven fabrics need to be given. One of them is superior air permeability and water resistance. In essence, breathability is the opposite of water resistance. This requires a large number of through holes extending from the front surface to the rear surface of the nonwoven fabric in the nonwoven fabric to improve its air permeability, but inevitably reduces the water resistance while improving the air permeability. When non-woven fabrics are used for medical purposes such as surgical gowns, they need to have a large: bacterial barrier, that is, a large water resistance is required to prevent infection of the wearer. In addition, when the clothes are deformed by bending or compression, it is necessary not to allow blood or the like to permeate through the nonwoven fabric. The superior breathability is the requirement to minimize sweat stains and not to accumulate moisture. A combination of two different fabrics has been proposed to match the mutually contradictory properties, breathability and water resistance. For example, Japanese Unexamined Patent Announcement (Kokai) No. 64 — 61555 shows a manufacturing technology of composite board, which spreads a dispersion liquid including two short fibers with different fineness on a shrinkable knitted fabric and injects water In the flow, the short fiber itself is fully interwoven and interwoven in the knitted fabric. This kind of composite board has excellent air permeability, but the composite board has poor water resistance. Japanese Unexamined Patent Announcement (Koka i) 1 — 1 1 1 ◦ 5 6 shows a composite non-woven fabric, which includes a non-woven fabric composed of pulp and staple fiber loco, and fibers (please read the notes on the back first Refill V + page) Binding · Ordering ... Line. This paper is again applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 public loan) -3 — 81.9.25,000 Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Making $ Guangyue • Argon-V. Description of invention (2) Non-woven fabric. Although according to the announcement, this composite non-woven fabric can be used as a surgical gown, but its water resistance has not improved significantly. The above-mentioned nonwoven fabric also leaks when it is bent or compressed. Disclosure of the Invention The subject of the present invention is to propose a nonwoven fabric which has sufficient air permeability and water resistance, hardly leaks when deformed by bending or compression, and has excellent strength and flexibility. The combined nonwoven fabric conforming to the subject of the present invention includes a short fiber nonwoven fabric (A) and a filament nonwoven fabric (B) having the following elements (1) to (3.), and the filament portions thereof are connected to each other, wherein Part of the short fibers constituting the short fiber non-woven fabric (A) are embedded in the filament non-woven fabric (B) and interwoven with the filaments constituting the filament non-woven fabric (B) to produce the short fiber non-woven fabric (a) and fibers The layered body of silk non-woven fabric (B) is embedded in the non-woven fabric of composite type with a short fiber with a length of 5 0 0 &quot; m in the area of short fiber which is 1/2 or more of the thickness of the filament non-woven fabric (B). The number n is 2 0 or less; (1) F + S25 0% weight 1/7 SF / SS 4/3 where: F: fineness 0.3 denier or smaller short fibers in all short fibers The ratio of 3: The ratio of short fibers with a fineness of 0.5 denier or more in all short fibers (2) The weight of short fibers per unit area: 1 〇g / m2 to 4 〇 Applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) --------- ^ ---------------- installed ------ Order (know the precautions on the back and then write this page) 219958 A6 ___B6_ V. Invention Ming (3) g / m 2. (Please read the notes on the back and fill in page r 4) (3) Average orientation: 2.0 to 10 Brief description of the drawing Plaque 1 is a composite nonwoven of the present invention Electron micrograph of the cut surface of the cloth example; Figure 2 is a cross-sectional view of the composite non-woven fabric shown in Figure 1; Figure 3 is a cross-sectional view of the conventional composite non-woven fabric; Figure 4 is the same as Figure 2 The cross-sectional view of the composite nonwoven fabric, except for the addition of standard lines X. and Y .; Figure 5 is a visual plaque defining the straight line portion to be used to measure the average orientation of the fiber; Figure 6 is an illustration of the average of short fibers A broad picture between the degree of orientation and the water resistance of non-woven fabrics. DESCRIPTION OF PREFERRED EXAMPLES Figure 1 is an electron micrograph of the cross section of the composite nonwoven fabric example of the present invention, and Figure 2 is a corresponding cross section view of the composite nonwoven fabric shown in Figure 1. Figure 3 is a conventional and general composite fabric A cross-sectional view of the composite. As shown in Figures 1 and 2, the composite nonwoven fabric includes staple fibers Nonwoven A, which includes fineness ◦. Short fibers of 3d or less and fineness ◦. Short fibers of 5d or more, and fibrous nonwoven B. Many in short fiber nonwoven A Zhang Standard General Central Park National Standard (CNS) Grade A (210 X 297 mm) -5-81.9.25,000 219953 A6 B6 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention Instructions (4) Short fiber arrangement On the surface of the composite nonwoven fabric that is quite parallel, and the short fibers in the short fiber nonwoven fabric A and the filaments in the filament nonwoven fabric B are interwoven only at the interface between them, in addition, the short fiber nonwoven fabric The short fibers in the cloth A are not deeply embedded in the filament nonwoven cloth B. In the conventional composite nonwoven fabric shown in FIG. 3, the short fibers 21 constituting the short fiber nonwoven fabric C 1 are deeply embedded in the fibrous nonwoven fabric D by a columnar liquid flow under high pressure, so the short fibers -21 are The filaments constituting the filament nonwoven fabric B are highly interwoven. Therefore, although the composite non-woven fabric shown in FIG. 3 is formed of two types of non-woven fabrics, the resulting composite non-woven fabric has a structure similar to a single non-woven fabric formed by mixing staple fibers 21 and filaments 2 2. Exterior. The first feature of the composite nonwoven fabric of the present invention is the sum of the short fiber ratio F of 0.3 denier or less and the short fiber ratio G of 0.5 denier or more in the short 50% by weight or more in fiber nonwoven A, the ratio of F / G is 1 to 7 or more and 4 to 3 or less, and the weight per unit area of short fiber nonwoven A is 10 g / tn2 and 40 g / m2. The fineness of the short fiber 11 is 0.3 denier or less, preferably 0.15 denier or less, _001d or more. Not all staple fibers need to have the same fineness. Staple fibers 11 can be made by cutting fibers, for example, sea-island fibers to separate sea components, composite fibers with two or more components, or direct spinning Superfine fibers obtained by silk and other methods. The fineness of the short fiber 12 is 0.5 d or more, preferably, 0.75 denier or more and 10 denier or less. Not all staple fibers 1 2 need to have the same fineness, but the fiber length of the staple fiber 1 1 is preferably greater than the thickness of the composite nonwoven fabric, but the staple fiber 11 and staple fiber 12 do not need to have this paper ruler and General China S home quasi (Cfs \ S) A 4 specifications (210 X 297) &quot; ~ '' ------------------ ~ ------- installed- ----- Order (please read the precautions on the back before writing this page) 219953 A6 _____B6_ printed by S Industry and Consumer Cooperative of Central Bureau of Standards of the Ministry of Economic Affairs 5. Invention description (5) The same ray length. Staple fiber 1 1 improves the water resistance of the composite nonwoven fabric, but when the content of staple fiber 11 in all staple fibers of the short fiber nonwoven fabric A increases, the air permeability decreases. The short fiber 12 has the opposite function of the short fiber 11. Therefore, when the F / G is 1 to 7 or more and 4 to 3 or less, the staple fibers 11 and 12 have an excellent balance, and thus the composite nonwoven fabric obtains excellent air permeability without reducing water resistance. However, the sum of F and G needs to be 50% by weight or more and when the sum of F and G is less than 50% by weight, it is difficult to obtain a superior effect. Therefore, the sum of F and G is preferably 70% by weight or more. The weight per unit area needs to be 10 g / m2 or more and 40 g / γ2 or less. When the weight per unit area exceeds 40 g / m2, the air permeability of the composite nonwoven fabric decreases and when the weight per unit area is less than 10 s / m2, the water resistance of the composite nonwoven fabric decreases. The apparent density of the short fiber nonwoven fabric A is preferably 0.1 g / m 2 to improve the water resistance of the composite nonwoven fabric. The method of measuring the apparent density of the nonwoven fabric is described below. The second characteristic of the composite nonwoven fabric is that the average orientation degree of the short fibers in the short fiber nonwoven fabric A is 2. ◦ or more and 1 ◦ or less. The average degree of orientation Z is the ratio between the component parallel to the surface of the filament nonwoven fabric B and the component perpendicular to the surface of the filament nonwoven fabric B in the short fibers of the staple fiber nonwoven fabric A. The method of measuring the average orientation is described below. The inventor of the present case discovered that the leakage caused by the deformation caused by bending and compressive force in the composite nonwoven fabric is determined by the value of the average degree of orientation Z. Figure 6 shows the relationship between the average orientation of staple fibers and the water resistance between non-woven fabrics (please read the back of the page-matters needing attention, and then re-enter this page)-binding. Ordering.-Thread. Clothing paper size Mao General China National Standards (CNS) A 4 specifications (210 X 297)-7-81.9.25,000 219S58 A6 B6 The Ministry of Economic Affairs Central Bureau of Industry and Commerce Co-operative Cooperatives printed and issued five, the description of invention P) Department of the drawing. As shown in Fig. 6, there is clearly a linear relationship between the average orientation Z of short fibers and the water resistance of nonwoven fabrics having the same composition and weight per unit area. Even if the composite non-woven fabric is subjected to flexion or compression, it can still effectively prevent liquid leakage and obtain a composite non-woven fabric with excellent water resistance. When the average degree of orientation Z exceeds 10, the interweave between the short fibers constituting the short fiber nonwoven A and the interweave between the short fiber nonwoven A and the filament nonwoven B is reduced, so that the strength of the composite nonwoven reduce. Therefore, it is necessary to make the average orientation degree 2.0 to 10, preferably 2.3 to 10, and 2.5 to 8.0. The third feature of the composite non-woven fabric of the present invention is that the non-woven fabric B is embedded into the filament non-woven fabric in the area of the random cut surface of the composite non-woven fabric with a length of 5000. The number of short fibers N which is 1/2 or more of the thickness is 2 0 or less. The measurement method of N is described below. When N exceeds 20, the water resistance of the composite nonwoven fabric decreases. As described above, the subject of the present invention can be achieved by integrating the short fiber nonwoven fabric A and the filament nonwoven fabric B with a special structure. The nonwoven fabric produced by the spunbond method can be used as the filament nonwoven fabric B. The filaments constituting the filament nonwoven fabric B are partially bonded to each other by hot melt or using an adhesive to fix their structure. Since the bonding portion in the filament nonwoven fabric B cannot interweave with the short fibers in the short fiber nonwoven fabric A, the total area of the bonding portion is preferably 2% to the area of the total surface area of the filament nonwoven fabric B Between 20%, and preferably 0.5 denier filaments, when the average value of the elongation at break measured in two directions at right angles is 40% or less, the two nonwoven fabrics are interwoven Short fiber can easily fit the above arrangement. --- ^ -------------- ------- installed ------ ordered (know first read the note for the back * &quot; item again. Scold This page) Exhaust paper is applied in the KK family express standard (CXS) A '! Regulations 丨! · (210 X' 297 Gonghong) 219958 A6 B6 Central Standards Bureau of the Ministry of Economic Affairs! Printed by ®Industry and Consumer Cooperatives V. Description of Invention (7) Any fiber can be used in the composite nonwoven fabric of the present invention. For example, thermoplastic resins such as polyamide fibers, polyester relay fibers, polyolefin fibers, polyacrylonitrile fibers, etc., acetate fibers, regenerated cellulose fibers, and the like can be used. In addition, if necessary, natural cellulose fibers, wool strands, etc. can be used, and when regenerated cellulose fibers are used as short-fiber nonwoven A, the trajectory and openings of water jets used for interweaving can be Easy to remove, thus preventing the water resistance from decreasing. When the polyester fiber is used in the short fiber nonwoven A, the interweave of the fiber nonwoven B and the short fiber nonwoven A is added. Therefore, when the ratio of polyester fibers is 1 to 3 or more and the ratio of regenerated cellulose fibers is 1 or less, the color retention obtained as a result of using regenerated cellulose fibers and polyester fibers can be obtained. In addition, except for staple fibers with a fineness of 0.3 denier or less and staple fibers with a fineness of 0.5 denier or more, all of the staple fiber nonwoven fabrics are preferred Use fibrillar pulp-like fibers between 5% and 15% by weight to obtain a composite nonwoven fabric with water resistance and tensile strength that is slightly improved, but does not reduce breathability. Fibrillated pulp sticky fibers can be obtained by combating natural pulp sticky or tearable acrylic fiber. The manufacturing method of the composite nonwoven fabric of the present invention is described below. Disperse the predetermined mixing ratio ◦. 3 denier or smaller staple fiber and 0.5 denier or larger staple fiber in water, and split the dispersion into paper to obtain staple fiber nonwoven A. In this case, it is better to add a surfactant to the dispersion to improve the dispersibility of the fiber in water. Next, a layer B of fibrous nonwoven fabric produced by the spunbond method was laid on the staple fiber nonwoven fabric A. This (please read the precautions on the back and then fill in ^ | page) 丨 Packing. Ordering. Clothing paper is also applicable to China National Standard (CNS) A 4 specifications (210 X 297 male cage) -Q-81.9.25,000 hydrocarbon Printed by the Central Bureau of Standards of the Ministry of Industry and Commerce, Co., Ltd. 219958 A6 _B6 V. Description of the invention (8) The layer is obtained by directly making paper on the nonwoven fabric B of the filament by forming the short iron dimension of the short fiber nonwoven fabric A . The layers are integrated by the columnar fluid. That is, the wire mesh of 50 to 200 me sh is placed between the layers on the wire mesh conveyor belt and the nozzle, and the water flow with a pressure of 3kg / cm2 or less is from 50 to 1 ◦0◦ r The nozzle of pm is injected onto the layer through the wire mesh of 50 to 200 mesh. Usually nozzles with multiple holes with diameters between 0. 5mm and 0. 3mm are used. The average orientation of the short fibers in the short fiber nonwoven fabric A can be controlled within the aforementioned range by placing a wire mesh between the nozzle and the conveyor belt and controlling the pressure of the nozzle, so that a composite non-woven fabric with excellent air permeability and water resistance can be obtained Weaving cloth. Preferably, a waterproof treatment is applied to the composite nonwoven fabric to obtain a composite nonwoven fabric having good water resistance. As for the known waterproofing agent, for example, a silicone-based waterproofing agent such as dimethylamino silicone or the like, or a gas-based waterproofing agent such as perfluoroaromatics, etc., and the cumulative solid part of the waterproofing agent is preferably about 0 . 1%-5% composite non-woven fabric weight. The measurement method used to evaluate the characteristics of the composite nonwoven fabric of the present invention is described below. Method for measuring the average orientation of short fibers in short fiber nonwoven fabric A. 1. Cut a 20 crri square test piece from a composite nonwoven fabric. 2. Cut both the longitudinal and lateral directions of the test piece by 5 cm to obtain 16 pieces of 5 cm square. 3. Choose 3 small blocks from 16 small blocks at will. 4. The cross-section of the selected small piece is 1 ◦ 0 times with an electron microscope (please read the back first. Fill in the notes on the surface and fill in a 4 page). Binding. Line. The size of the clothing paper is in accordance with Chinese national standards ( CNS) A4 gauge (210 X 297 extension) ~ 1〇- 81.9.25,000 2199〇3 A6 B6 Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Invention description (9) Photograph. At that time, the non-partially connected part of the nonwoven fabric B of the two sides of the two sides of each strand of the tweed silk was taken out of the photograph, so 6 photos were split. 5. As shown in Fig. 4, the number of filament terminals constituting the fibrous nonwoven fabric B in each electron microphase H is counted inward from the outside of the surface of the filament nonwoven fabric B; from the center of the tangent plane of the fourth terminal The center of the fifth terminal cut line is drawn a straight line X. , Which is arranged at least 30 Aim away from the fourth terminal. This line X. The standard thread of this composite nonwoven fabric is shown. Another standard line Y. Draw in the direction perpendicular to the sassafras line σ. 6. Draw a vertical line Υ;, Υ2 at a distance of 5 cm from the parallel standard line Υ 〇 in the middle of each electron micrograph. 7. In the vertical line Υ: and α2, choose 0.3 denier or finer short fibers and 0.5 denier or thicker short fibers with a longitudinal length of 10 times the maximum diameter of the fibers. . 8. As shown in Fig. 5, any point of the center line L of the short fiber is shown. The point P 2 is selected on the center line and the line connecting the point P and the point P 2 on the line 卩 / 卩 2. At that time, when drawing a straight line tangent to the center line L, the distance between the straight line P; P2 and the tangent _ ± _ is smaller than the fiber diameter and the length between the point P and the point P 2 is greater than 4 times the diameter X-. 9. Other points Pa, P4 ......... P «is determined by the same method, and the short fiber is divided into many straight lines. The method of determining P /, p2 ......... P «points applies to all short fibers selected in step 7. 10. Direction and sassafras X. The parallel component X ™ and direction are parallel to the standard line Y. The parallel component Yn counts the straight lines of each short fiber. <Please read the notes on the back «first? 4 pages) 丨 installation. Order.Line. This paper scale is applicable to the Chinese National Standard (CNTS) A 4 specifications (210 X 297 public loan) -H-81.9.25.000 2139a3 A6 B6 Printed by the Employees Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (10) Quantitative analysis, and calculate the sum of Xn and γη values as X and Y. 11. Calculate the ratio of X / Y, and the average orientation Z is determined by the average X / Y from six electron micrographs. Method of measuring the number of short fibers (Ν) embedded in the secondary silk nonwoven fabric 1. The same three small pieces of composite nonwoven fabric and the same six electron micrographs were prepared as the average orientation measurement method. 2. By stripping the fibrous non-woven fabric B from each of the three small pieces, a tri-common fibrous non-woven fabric B is prepared. The thickness of the filament non-woven fabric is compressed at four points using a compression testing machine (KES — FB — M3, KES — FB — Ε3), which is from KAT0 TECH C0., LTD., And the KES — F Β test is used to test the compressibility of the system. The measurement method is measured under a pressure of 1 g / m 2, and the distance between the 12 points obtained is at least 2 cm or more. The thickness TB of the fibrous nonwoven fabric B is determined by the average value of the thickness values. 3. Parallel to the standard line X. And the straight lines 1/2 TB with the distance of half the value of T B obtained in step 2 are each drawn in six electron micrographs. 4. Count the number of short fiber lobes that intersect the straight line 1/2 TB between the vertical lines Y2 and Y2 at a distance of 500wm, and N is defined as the average number obtained from 6 electron micrographs. Density measurement method of short-fiber nonwoven A. 1. It is split into 6 electronic display photos that are used in the average orientation measurement method. (Please read the precautions on the back before you go to this page). Binding. Binding.-Line-This paper ruler is suitable for China National Scratch (CNS) Grade 4 (210 X 297 public loan) -12-81.9. 25,000 219953 A6 B6 Printed by the WK Industrial and Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (11) 2. Used to draw the standard line X in the average orientation measurement method. The method is to draw the standard harnesses X: and X2 along the upper and lower surfaces of the short-filament nonwoven A. The small vertical lines Υ ζ and Υ 2 obtained by the intersection of the standard composite X / and X2 are used to measure 6 electron micrographs, and the average thickness obtained from the six micrographs is taken as the thickness Τ (u τη) 0 3. The weight per unit area of short fiber non-woven fabric A (g / m2) is the weight per unit area of composite non-woven fabric measured by JIS—L-1096 and the unit weight of composite non-woven fabric The area weight is obtained by deducting the weight per unit area of the fibrous nonwoven fabric B obtained from the measurement method of the number N of the short-filament nonwoven fabric A. 4. The density of short fiber nonwoven A is obtained from W / T (g / m 3). Flexural hardness The flexural hardness of the composite non-woven fabric is measured according to the flexural property measurement method of the K E S-F B test kit. The longitudinal direction corresponding to the direction in which the short fiber nonwoven fabric A and the filament nonwoven fabric B interweave and the transverse direction of the composite nonwoven fabric were tested 5 times by the KATO TECH CO., Ltd. pure bending tester, and the composite nonwoven fabric The flexural hardness of the cloth is determined as the average of the obtained values. Air permeability The air permeability of the composite non-woven fabric is measured by the breaking test of J IS-L-; L 〇96 and is expressed by the average value of 5 measurements. {Please read the back page of "Notes on spraying and then on the back", page 4)-Binding. Order. Line. This paper scale is universal Chinese gjia sample standard (CNS) A 4 specifications (210 X 297) _ 13-· 81.9 .25.000 219953 A6 ____B6_, printed by the Central Standard of the Ministry of Economic Affairs, βκ 工 Consumer Cooperatives V. Description of the invention (12) Breaking strength The breaking strength of the composite nonwoven fabric is measured in accordance with JIS-L-1096. First of all, a sample with a width of 3 cm and a pinch distance of 10 cm was cracked with TOYO BALDWIN CO., Ltd., Tensilon UTN-1 was measured to measure the breaking strength, and expressed as the average of 5 measurements (kg / cm ). Elongation at break The elongation at break of the composite nonwoven fabric was measured using the same method as the breaking strength and expressed as the average of 5 measurements. Hydrostatic pressure resistance Water resistance is measured by a low hydrostatic pressure method according to JIS — L — 1092 on a sample with a hydrostatic pressure resistance of 1 0 0 0 m i nHzO or less, and 5 measurements The average value is expressed (mm Η 2 ◦). The Me i son jar test is based on JST80, T — 70, MEISON JAR Method. It measures the time from the application of 1 14mmH2◦ water pressure physiological saline on the composite nonwoven fabric sample to the start of liquid leakage, and the result is measured in 3 times Mean value. A composite nonwoven fabric having a value of 60 minutes or more in the Meison jar test is acceptable. Leakage resistance at compression or bending temples 10 cm square test pieces were cut from composite nonwoven fabrics. It is prepared separately (please read the precautions on the back first, page 4). Binding. Binding 'line. This paper is also> 1 applicable to China National Standard (CNS) A 4 specifications (210 X 297 X extension) -14 -81.9.25,000 mrH consumer cooperation thorium printed by the Central Bureau of Standards of the Ministry of Economic Affairs 219953 A6 __B6 V. Description of the invention (13) Two 10 cm square plates with a 6 cm diameter hole in the center, place the test plates on the two plates between. Using a dropper, pour 10 c c colored physiological saline into the center of the upper plate hole. Place the test piece and two plates on an acrylic strip resin cylinder with an inner diameter of 90 mm and an outer diameter of 100 mm. The cylinder is placed on Tensilon 0TM-1 of TOYO BALDWIN CO., LTD., And the central part of the test piece is borrowed A rod with a surface with a curvature of cm and a stroke of 2 Omm is pushed back and forth. When the colored physiological saline is dispersed under the test piece seen through the acrylic cylinder, the frequency of the rod is counted. The liquid permeability resistance was evaluated as the average of 5 measurements. The present invention will be described in detail with respect to an example of the composite nonwoven fabric of the present invention. In the following examples, all of the composite nonwoven fabrics were subjected to the following water-repellent treatment and the retention of the composite nonwoven fabric was measured. Water resistance: Asahi Guard Series AG-433, Laibai MEISEI KAGAKU Co .. Ltd. Treatment: The composite nonwoven fabric is immersed in an aqueous solution containing 5% water repellent, it is dried at 100 ℃ for 2 minutes, and at 160 = Heat for 1 minute. The compounding method of the layers in the examples is applied by water injection. The main conditions of water jet treatment are as follows: Water jet nozzle diameter: ◦. 2mm Distance between nozzle and composite nonwoven fabric: 30mm Wire mesh arranged between nozzle and composite nonwoven fabric: 7 Ome sh wire mesh nozzle rotation conditions : (Please read the precautions on the back before filling in this page) — Binding · Ordering.-Line. This paper is again applicable to China's National Standard (CNS) A 4 specifications (210 X 297 extension) — 15-81.9.25,000 219903 A6 B6 The Ministry of Hydrocarbon Economy Central Standards Bureau βκ 工 Consumer Cooperative Printed 5 Code V. Description of Invention (14) Rotation Radius: 6 mm Rotation Speed: 200 r pm Example 1 The predetermined amount of fineness is 0.1 denier and Polyethylene terephthalate staple fiber with a length of 5mm, and the same amount of polyethylene terephthalate staple fiber with a fineness of 1 denier and a 5mm long viscose rayon staple fiber dispersed in 63%。 The water was collected and mixed into a slurry with a concentration of 0.63%. The slurry was made into paper in a tilted wire mesh paper machine to obtain a short-fiber nonwoven fabric A weighing 25 g / m2 per unit area. The filament non-woven fabric B is melt-spinning polyethylene terephthalate, and the molten polymer extruded from the spinning port is drawn by an air suction tube to produce a uniform wire mesh, and the surface has many protrusions The embossing stick on the upper part and the roller under the flat surface heat press the net. The filament fineness of this fibrous nonwoven fabric B was 2 deniers and the resulting fibrous nonwoven fabric B had a weight per unit area of 25 g / m2 and an average elongation at break of 2.5%. The fibril nonwoven fabric B is laminated on the short fiber nonwoven fabric A, and then the water injection treatment is applied from the upper surface of the fibril nonwoven fabric B and the bottom surface of the short fiber nonwoven fabric A. The composite nonwoven fabric of the present invention cloth. If necessary, the water injection process is applied in three steps by changing the water injection pressure. That is, the water injection pressure used in the first step is 15ks / cm2, the second step is 15kg / cm2, and the third step is 30 kg / cm2. In the filament non-woven fabric B, the area ratio of the linking portion generated by the treatment is 10% of the total area of the non-woven fabric B. (Please read the precautions on the back before «; '4 pages) Binding. Ordering ... Line. This paper is also applicable to the China National Standard (CNS) A 4 regulations (2 丨 0 X 297 W«)-16-81.9 .25.000 219953 A6 B6 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs ® Industrial and Consumer Cooperatives Fifth, Invention Description (15) Endeavour Example ρ _ Λ In Examples 2 to 4, the short hungry nonwoven fabric A was directly layered using the split paper method "On the fibrous nonwoven fabric B same as in Example 1." That is, polyethylene terephthalate staple fibers with a fineness of 0.1 denier and a length of 5 mm, and viscose rayon staple fibers with a fineness of 0.1 denier and a length of 5 mm are dispersed in three composition ratios in Mix in water to form a slurry with a concentration of 63%. The staple fiber nonwoven A with a weight of 25 g / m2 per unit area is directly made into paper on the filament nonwoven B to crack a layer. Composition of short fibers in nonwoven fabric A Example 2 Example 3 Example 4 〇.1 denier staple fiber 1 1 3 1 denier staple fiber 1 3 17 The layer is the same as in Example 1 The method was applied by water injection treatment from the top and bottom of the layer to prepare the composite nonwoven fabrics of Examples 2 to 4. That is, the first step is 15kg / cm2, the second step 15g / m2 and the third step 3 ◦ k g / c m2 are applied to both sides of the layer in sequence. Example 5 5 parts by weight fineness ◦. 1 denier polyethylene terephthalate staple fiber length 5 mm, 7 parts by weight fineness 1 denier and 5 mm length viscose rayon short Fiber and 8 parts by weight fineness 0.4 denier (please read the precautions on the back before talking about this page)-Pack. Order · Thread. This paper is also applicable to China National Standard (CNS) A 4 specifications (210 X 297 Gongchu)-\ 1-81.9.25,000

Q Q 蛵濟部中央標準局工消費合作社印« Α6 Β6 五、發明説明(16) 爾且長度5mm之聚對苯二甲酸伸乙酯短纖維分散於水中 並搜拌成濃度為0. 63%之漿液。例5之複合型非織造 布使用例2至4之方法製自漿液。Printed by QQ Gongji Central Standards Bureau Industrial and Consumer Cooperative Society «Α6 Β6 V. Description of invention (16) Polyethylene terephthalate short fibers with a length of 5mm are dispersed in water and mixed to a concentration of 0.63% Slurry. The composite nonwoven fabric of Example 5 was prepared from the slurry using the methods of Examples 2 to 4.

奮旃例A 每單位面積重1 5 g/m2之短纖雒非織造布A藉將 濃度0. 38%之漿液製紙並將1重量份數細度1旦尼爾 且長度5mm之聚酯類超細短纖維及3重量份數細度1旦 尼爾且長度5mm之粘膠人造絲短纖維混合於水中並攪拌 。所得之短纖維非織造布A層璺於同於例1之纖絲非織造 布B上。 層狀物由層狀物之上面及底面接受三階水注處理,製 得例6之複合型非織造布。即,各由層狀物之兩面依序施 加第一步驟10kg/cm2 ,第二步驟l〇kg/ cm2 ,且第三步驟2〇kg/cm2壓力之水注處理。 啻旃例7 將同於例6之漿液製紙得到每單位面積重4 0 g / m2之一短纖維非織造布A,除了漿液濃度變成1 %外, 且短纖維非織造布A層積於同於例1之纖絲非織造布B上 0 層狀物由積層體之上面及底面進行三步驟之水注處理 製得例7之複合型非織造布。即,依序各由層狀物之兩面 施加第一步驟15kg/cm2 ,第二步驟2〇kg/Endeavour Example A Staple fiber nonwoven fabric with a weight of 15 g / m2 per unit area A is made of paper with a concentration of 0.38% slurry and 1 part by weight of polyester with a fineness of 1 denier and a length of 5 mm Superfine short fibers and 3 parts by weight of 1 denier fineness and 5 mm long viscose rayon short fibers are mixed in water and stirred. The resulting short-fiber nonwoven fabric A layer was formed on the fibrous nonwoven fabric B same as in Example 1. The laminate was subjected to a three-stage water jet treatment from the top and bottom of the laminate to obtain the composite nonwoven fabric of Example 6. That is, a water injection treatment of a pressure of 10 kg / cm 2 in the first step, 10 kg / cm 2 in the second step, and 20 kg / cm 2 in the third step is applied in sequence from both sides of the layer. Example 7 Using the same pulp as in Example 6 to obtain a short fiber nonwoven A with a weight of 40 g / m2 per unit area, except that the slurry concentration became 1%, and the short fiber nonwoven A was laminated in the same On the fibril nonwoven fabric B of Example 1, a layered material was subjected to three-step water injection treatment on the top and bottom surfaces of the laminate to obtain the composite nonwoven fabric of Example 7. That is, the first step of 15kg / cm2 and the second step of 20kg /

I---------------装------tr------ 線 (請先M讀背面之注意事項存填r 4頁) - 本纸張尺度適用中國國家標準(CNS)甲4規格(210 X 297公兑) -18 - 81.9.25,000 Α6 Β6 經濟部中央標準局员工消費合作社印製 五、發明説明(17) cm2且第三步驟3〇kg/cm2之壓力。 啻旃例8至1 0 使用同於例3之方法産製例8至1 ◦之複合型非織造 布,除了使用以纺粘法産製之以下纖絲非織造布B外。 實施例8之纖絲非織造布B : 聚丙烯纺粘非織造布,其包括細度為3旦尼爾之缕絲 ,每單位面積重2 5 g/m2且平均斷裂伸長度3 0%, 將聚丙烯聚合物熔融纺絲製得一網並在加熱下使用例1之 方法將該網壓花。 實施例9中之纖絲非織造布B : 耐编6纺粘非織造布,其包括細度2旦尼爾之纖絲, 每單位面積重25g/m2 ,平均斷裂伸長度30%,將 耐编6聚合物熔融纺絲製得一網並在加熱下使用例1之方 法將該網壓花。 實施例10之纖絲非織造布B: 聚對苯二甲酸伸乙酯非織造布,其包括細度2旦尼爾 之纖絲,每單位面積重3 0 g/m2且平均斷裂伸長度 2 5 % ,係使用例1之方法得到。 奮旃例1 1 (請先閲讀背面之注意事項再填V.本頁) —裝. 訂. 線. 衣纸張尺度適用中a國家橒準(CNS)甲4规格(2】0 X 297公兌) -19 - 81.9.25,000 Α6 Β6 經濟部中央標準局ια工消費合作社印Ϊ-Λ 五、發明説明(18 ) 将1重量份數細度◦. 1旦尼爾且長5mni之聚對苯 二甲酸伸乙酯短纖Μ, 1重量份數细度1旦尼爾且長 5mm之粘膠人造絲短纖維及2重量份數细度1旦尼爾且 長5mm之聚對苯二甲酸伸乙酯短纖雒分散於水中並攪拌 成濃度0. 63%之漿液。使用例2至4之方法由漿液産 裂例1 1之複合型非織造布。 曹施例1 2 兩重量份數細度1旦尼爾且長5mm之聚對苯二甲酸 伸乙酯短纖維,7重量份數細度1旦尼爾且長5mm之粘 膠人造絲短纖雒及1重量份數使用下法所得之原纖化丙烯 酸類漿粕分散於水中並攪拌成濃度0. 63%之漿液。使 用例2至4之方法産製例12之複合型非織造布。 例1 2中之原纖化丙烯酸類漿粕使用下法産製。 將包括95. 0%重之丙烯睛,4. 5%重丙烯酸甲 酯及0. 5%重之甲代烯丙基磺酸銶打,及數平均分子量 10, 000且聚氣化乙烯與聚氧化丙烯之重量比例為 7 0比3 0之嵌段型聚氣化乙烯-聚氣化丙烯一聚氣化乙 烯共聚物之聚合物溶於二甲基甲醯胺以得到包括2 3%重 之丙烯酸類聚合物及2. 3%重之嵌段型共聚物之纺絲液 。此纺絲液靜置6小時,並經纺絲板擠至3 5 υ包括濃度 75%之二甲基甲醯胺之凝結浴中,形成未拉伸纖維。未 拉伸纖維經洗滌,以1 2倍拉伸比進行拉伸操作,然後在 8 〇〇之熱風中乾燥形成細度1. 5旦尼爾之纖維。所得 (請先《讀背面之注意事碣再埸一,4頁) —裝· 訂. .線. 本纸張又度適用t國國家橒準(CNS)甲4規格(210 X 297公眾) -20 - 81.9.25,000 19958 A6 B6 五、發明説明(19) 之纖雒裁成5mm小塊,將10重量份數經裁切之纖維分 數於90重量份數之水中。此纖維分散液置入盤距為 ◦ . lmm之圓盤精研器中並擊打至過濾率為零。經擊打 之丙烯酸類漿粕具有因由對應於原先丙烯酸纖維束之部分 表面旁的纖維分離彼者而得之少數细鈎狀原纖維。此外, 缕維束縱向部分分離以製得细纖維。 測量例1 2複合型非織造布之持性的結果,複合型非 織造布之耐水性及抗張強度因使用原纖化之丙烯酸類漿粕 顯然稍有改善,且不降低透氣性。此外,觀察到12之複 合型非織造布之電子顯微相片時,顯然細度0. 3旦尼爾 或更小之短纖維及細度0 . 5旦尼爾或更小之短纖雒保持 高度平均定向度Z且原纖化之丙烯酸類漿粕之纖維與短纖 維非織造布A及纖絲非織造布B充分交織。 請 先· 閲 讀 背 意 事 項- 再 填 頁 裝 訂 經濟部中央樣準局8工消費合作社印製 窨旆例1 3 57%重細度0.1旦尼爾且長5mm之聚對苯二甲 酸伸乙酯短纖維,及43%重細度1旦尼爾且長5mm之 粘膠人造絲短纖維分散於水中並报拌成濃度為〇. 63% 之漿液。在傾斜鐵絲網型裂紙機上將漿液製紙,得到每單 位面積重2 5 g/m2之短纖維非織造布A。將同於例1 之纖絲非織造布B層積於短纖雒非織造布A上以製得層狀 物。層狀物由層狀物之上面及底面進行三步驟水注處理, 製得例13之複合型非織造布。即,依序各在層狀物之兩 面施加第一步驟kg/cm2 ,第二步驟15kg/ 線 本紙張尺度通用中國國家橒準(CNS)甲4规格(210 X 297公窣) -21 - 81.9.25.000 蛵濟部中央橒準局员工消费合作社印製 219953 A6 B6 五、發明説明(20) cm2 ,且第三步驟30kg/cni2壓力之水注處理。 窨旃例1 4· 将1重量份數細度0. 25旦尼爾且長5mm之聚對 苯二甲酸伸乙酯短纖維,及3重量份數細度1旦尼爾且長 5mm之粘膠人造絲短纖維分散於水中並攪拌成濃度為 0 . 6 3 %之漿液。在傾斜鐵絲網型製紙中將漿液製紙得 到每單位面積重2 5 g/m2之短纖維非織造布A。將同 於例1之纖絲非織造布B層積於短纖雒非織造布A上,裂 得層狀物。此層狀物由層狀物之上面及底面進行三階水注 處理,製得例14之複合型非織造布。即,依序各在層狀 物之兩面施加第一步驟15kg/cm2 ,第二步驟 15kg/cm2 ,且第三步驟30kg/cm2之壓力 之水注處理。 啻旃例1 5 將1重量份數細度0.1旦尼爾且長5mm之聚對苯 二甲酸伸乙酯短纖維,及3重量份數細度◦. 5旦尼爾且 長5mm之粘膠人造絲短纖維分散於水中並攪拌成濃度為 0 . 6 3 %之漿液。在傾斜鐵絲網型製紙中將漿液製紙得 到每單位面積重2 5 g/m2之短纖維非織造布_A。將同 於例1之纖絲非織造布B層積於短纖維非織造布A上,製 得層狀物。此層狀物由層狀物之上面及底面進行三階水注 處理,製得例15之複合型非織造布。即,依序各在層狀 本纸張尺度適用中园國家樣準(CNS)甲4規格(210 X 297公贷) -22 ~ 81.9.25,000 (請先閲讀背面之注意事項再填穸本頁) .裝. 訂. 經濟部中央標竿局8工消費合作社印5衣 2199〇3 A6 _B6_ 五、發明説明(21) 物之兩面施加第一步驟15kg/cm2,第二步驟 15kg/cm2 ,且第三步驟30kg/cm2之壓力 之水注處理。 fcb較例1 將1重量份數細度0. 1旦尼爾且長5mm之聚對苯 二甲酸伸乙酯短缕維,及1重量份數细度1旦尼爾且長 5mm之粘膠人造絲短遂維分散於水中並攪拌成濃度為 1 %之漿液。在傾斜鐵絲網型製紙中將漿液製紙得到每單 位面積重40g/ni2之短纖雒非織造布A。使用例1方 法製得包括3旦尼爾纖絲之聚丙烯纺粘非織造布B,其每 單位面積重3〇g/m2且平均斷裂伸長度85%,此纖 絲非織造布B層積於短纖維非織造布A上,製得層狀物。 此層狀物由層狀物之上面及底面進行三階水注處理,製得 比較例1之複合型非織造布。即,依序各在層狀物之兩面 施加第一步驟2〇kg/cm2,第二步&lt;驟 ♦ 4〇kg/cm2 ,且第三步驟40kg/cm2之壓力 之水注處理。 屮較例2 將7重量份數細度〇.1旦尼爾且長5mm之聚對苯 二甲酸伸乙酯短纖雒,及3重量份數細度1旦尼爾且長 5mm之粘膠人造絲短纖維分散於水中並攪拌成濃度為 ◦. 63%之漿液。在傾斜鐵絲網型製紙中將漿液製紙得 本纸張又茂適用中國囷家標準(CNS)甲4規格(210 X 297父贷) -23 - 81.9.25.000 {請先閲讀背面之涅意事項再填厂4頁) -裝- 訂- .線 經濟部中央標準局Η工消費合作社印5衣 21995S A6 ___B6_ 五、發明説明(22) 到每箪位面積重2 5 g/m2之短纖維非織造布A。將同 於例1之纖絲非織造布B層稹於短纖維非織造布A上,裂 得層狀物。此層狀物由層狀物之上面及底面進行三階水注 處理,裂得比較例2之複合型非織造布。即,依序各在層 狀物之兩面施加第一步驟15kg/cm2 ,第二步驟 15kg/cm2 ,且第三步驟3〇kg/cm2之應力 之水注處理。 比較例3 以同於比較例2之方法製得比較例3之複合型非織造 布,除了聚對苯二甲酸伸乙酯短纖維及粘膠人造絲短纖維 之含量由7變成3且由1變成9外。 fch較例4 以漿粘機擊打ALASKA PULP 5分鐘所得之漿粘2重量 份數,及3重量份數細度1旦尼爾且長5mm之聚對苯二 甲酸伸乙酯短纖維分散於水中並攪拌成濃度為0. 63% 之漿液。使用比較例2之方法産製比較例4之複合型非織 造布,除了使用上述漿液外。 屮較例5 將1重量份數細度〇. 1旦尼爾且長5mm之聚對苯 二甲酸伸乙酯短纖維,及3重量份數細度1旦尼爾且長 5mm之粘膠人造絲短纖維分散於水中並攪拌成濃度為 本紙張又度適用中國國家標準(CNS)甲4规格(210 X 297公穿) -24 ~ 81.9.25,000 (請先閲讀背面之注意事喷再域一:本頁 —裝· 訂 .線, 219953 A6 _B6_ 五、發明説明(23) 0. 18%之漿液。在傾斜鐵絲網型製紙中將漿液製紙得 到每單位面積重7 g/m2之短纖維非織造布A。將同於 例1之缕絲非織造布B層積於短纖雒非織造布A上,製得 層狀物。 此層狀物由層狀物之上面及底面進行三階水注處理, 製得比較例5之複合型非織造布。即,依序各在層狀物之 兩面施加第一步驟l〇ks/cm2 ,第二步驟10kg /cm2 ,且第三步驟20kg/cm2之壓力之水注處 理。 (請先閲讀背面之注意事項再π&gt;·.本頁) 丨裝. 經濟部中央標準局β工消費合作社印5衣 裂得同於比較例5之漿液,除了漿液濃度變成 1 . 5 %外。在傾斜鐵絲網型製紙中將漿液製紙得到每單 位面稹重60g/m2之短纖維非織造布A。將同於例1 之纖絲非雜造布B層積於短纖維非織造布A上,製得層狀 物。 此層狀物由層狀物之上面及底面進行三階水注處理, 製得比較例6之複合型非織造布。印,依序各在層狀物之 兩面施加第一步驟15kg/cm2,第二步驟15kg /cm2 ,且第三步驟30kg/cm2之壓力之水注處 理。 吐較例7 使用比較例6之方法製得比較例7之複合型非織造布 本纸張又度適用中國國家標準(CNS)甲4规格(210 X 297公穿) -25 - 81.9.25,000 訂· 線. 經濟部中央標準马8工消费合作社印装 213953 A6 ____B6__ 五、發明説明(24) ,除了水注處理之第一步驟、第二步驟及第三步驟之壓力 各變成 20kg/ cm2、40kg/ cm2 及40kg / c m 2 外。 bh較例8 使用例1之方法製得包括3旦尼爾纖絲之聚丙烯纺粘 非織造布B,其每單位面積重25g/m2且平均斷裂伸 長度5 5 %。 將1重量份數細度0. 1旦尼爾且長5mm之聚對苯 二甲酸伸乙酯短纖維,及3重量份數細度1旦尼爾且長 5mrri之粘膠人造絲短纖維分數於水中並攪成濃度 1 . 5%之漿液。每單位面積重6〇g/m2之短纖維非 織造布A直接由以上漿液裂紙於上述纖絲非織造布B上, 然後在同於比較例8之條件下複合。 bb較例9 將1重量份數細度0. 1旦尼爾且長5mm之聚對苯 二甲酸伸乙醋短纖維,及3重量份數細度1旦尼爾且長5 mm之粘膠人造絲短纖雒分散於水中並攪拌成濃度為 0. 63%之漿液。直接在上述纖絲非織造布B上由上述 漿液裂得每單位面積重2 5 g/m2之短纖維非織造布A 〇 此層狀物由層狀物之上面及底面進行三階水注處理. 裂得比較例9之複合型非織造布。即,依序各在層狀物之 兩面施加第一步驟15kg/cm2,第二步驟15kg 衣纸張又度通用中國國家橒準(CNS)甲4規格(210 X 297公穿) -26 ~ 81.9.25.000 (請先閲讀背面之.注意事項再€.:本頁) .裝· 訂 .線. 219953 A6 B6 五、發明説明(25) /cm2 ,且第三步驟30kg/cm2之壓力之水注處 理。 (請先閲讀背面之.注意事項再填广.本頁) 裝_ .11. 線. 經濟部中央標準局3工消費合作社印製 本纸張又度適用中國國家揉準(CNS)甲4規格(2] Ο X 297么'笼) —27 - 81.9.25,000 219953 A6 B6 五、發明説明(26) 表1 短鐵^嫌选布 雖油笄嫩进布 结構 柱狀萊es之條件 ^fasm 其他 每轚位 F+&lt;3 F/G 缠度 平均斷S 每轚位 導人儀M 平雄 使用鐵 流碰力 0.34 0.54 面播s 伸ft* 面積£ 素(N) 间度 mm 1st 2nd 3rd 或史小(F) 班大⑹ 步《Ε步· 步藿 鲡度 mmm. m i «abt 细度 msm 比例 比例 比例 id) :«tv id) (,⑴ (d) (s/_,! (d) (Z) (Z) 實腌例1 0-1 50 1 50 - - 25 100 1 1 22.5 23 4 3.3 s 15 15 30 實旋例2 0-1 SO 1 50 - - 2S iOO 1 1 22.5 25 5 3.7 定 15 15 30 資施例3 0.1 25 1 75 - 25 100 1/3 1 22.S 25 7 3.2 5 15 15 30 實施例4 0-1 15 1 85 - - 25 100 0.18 1 22.5 25 10 3.0 足 15 15 30 實施例5 0-1 25 I .15 0.*! 40 25 60 0.71 1 22.5 25 9 3-3 m 15 15 30 霣旅例6 0.1 25 I 75 - - 15 100 1/3 1 22-5 25 5 3-5 足 10 10 30 實施例7 0-1 25 1 75 - - 40 100 1/3 t 22.5 25 15 4.3 足 15 20 30 蓄施例S 0-1 25 1 75 - - 25 iOO 1/3 2 30 25 12 2.8 是 15 15 30 *細9 0-1 25 1 75 - - 25 100 1/3 t 30 2Q 15 2-7 IS 15 30 «酬⑴ 0-1 25 1 75 - - 25 100 1/3 1 Z5 20 10 3.3 足 15 15 30 實施例11 0.1 25 1 25 I 50 25 100 1 I 22.5 25 12 3.1 足 15 15 30 «娜2 0-1 20 1 70原»化β柏10 25 90 0.29 l 22.S 25 8 3-4 足 15 15 30 «施例13 0Λ 57 1 43 - - 25 100 1-33 1 22.5 25 5 4.0 垤 15 15 30 實施例U 0.25 25 Ϊ 75 - - 25 100 1/3 1 22.5 25 6 3.J 足 15 15 30 贿例15 0.1 25 0-5 7:S - - 25 100 1/3 1 22.5 IS 7 3-4 足 15 15 30 經濟部中央標準局tec工消費合作社印剎衣 (請先閲讀背面之注意事項再填I. 4頁) 本紙張又度適用中國國家標準(CNS)甲4規格(210 X 297公廷) 81.9.25,000 219958 A6B6 五、發明説明(27 ) 表1 &lt;續&gt; 短饑绝非纗选布 纖线非縑造布结檐柱狀流處理之鑲件 mast 每5位 F*C F/G 繡度 平均断製 每S位 導人嚴禮 平均定 使用鐵 庚碰力 0.3- 0.5·* 面穰籯 伸S度 面積篁 mis) 向度 mm 1st 2nd 3rd 额ΦίΠ 3*a:(g) 步ff步S 步β mm wmt. mm 细度 比例 比例 比例 tdi iwtl) (d) imt%) (d) is^m1) (d) (2) (s/-M ίΖ) 比較洌1 0.1 50 1 50 - - 40 100 1 3 85 30 50 1-1 否 20 40 40 比較例2 ο.ι 70 1 30 - - 25 100 7/3 1 22.5 25 10 3-5 1 15 15 30 比較例3 0.1 10 1 90 - - 25 100 1/9 1 22.5 25 8 3-2 足 15 15 30 比較例4 - - 1 40 pulp 60 25 40 0 1 22-5 25 13 2-1 是 15 15 30 比較例5 0.1 25 1 75 - - 7 100 1/3 1 22.5 25 25 1.3 S 10 10 20 比較例6 0-1 25 I 75 - - 60 100 1/3 1 22-5 23 3 12 足 15 15 30 比較例7 0.1 2S 1 75 - - 60 100 1/3 1 22.5 25 40 2-0 否 20 40 40 比較例8 0-1 25 1 75 - - 25 100 1/3 3 55 25 30 2.1 足 15 15 30 比較例9 0Λ 25 1 75 • _ 25 100 1/3 l 22-S 25 22 1-8 § 15 15 30 (請先閲讀背面之注意事項再塡,4頁) .裝. 訂 .線. 蛵濟部中央橒準局KK工消t合作社印製 本纸張又度迺用中a囷家揉準(CNS)甲4規格(210 X 297公贷) 一 29 - 81.9.25,000 213958 A6 _B6 五、發明説明(28) «2 毎單位覃度1C曲庚度 透氣性隹度 伸畏度 抗水K力Mason Jar變形時之 面積 S6重 (ecVc) (ks/3cm) (t) Test 抗缪掖性 ί*/*Μ (·) _ 禳向(oc/ca7.sec) ft向 向勘^ fff向(μΗ,Ο) (_in) (畤R3&gt; (請先閱讀背面之·注意事項再填V,本頁) 寶蝴1 50 0.31 0.09 0-06 38 6-0 2.7 25 42 380 喊更長 5 vmm 2 50 0.31 0.09 0*06 60 6-0 2.7 26 40 370 60或更長 5 賃施例3 50 0.32 ο.οβ 0-06 90 6-2 2-9 28 40 300 60或更長 5 wmm 4 50 0.33 0-08 0-06 130 6.4 3.0 30 40 270 60或更長 5 實接例5 50 0.33 0.09 0-06 95 6-4 3-2 30 d〇 290 60¾¾¾ 5 W绝例6 40 0.28 0.06 0.05 200 5.7 2,5 22 34 250 60¾¾ 丧 5 實施例7 65 0-37 0-14 0.07 50 7.8 4.5 35 50 450 60或更畏 5 實蝴8 50 0.34 0.CT7 0-05 so 6.2 2.5 30 50 230 6〇^5E 長 5 «施例9 45 0-34 0-07 0.03 75 6.9 3-3 35 55 270 喊更庋 5 雜例10 55 0-35 0.14 0.07 80 8-0 5-4 30 45 330 6〇或更畏 5 實酬U 50 0-34 0.10 0.07 80 7.0 3.5 30 40 290 60¾史長 5 實細12 50 0-34 0-12 0.09 85 6.5 3-0 27 38 290 60或更長 5 實施例η 50 0.31 0-09 0.06 45 6.0 2-6 25 41 415 6〇或更畏 5 霣施例14 50 0.33 0-10 0-07 98 6.4 3-2 30 42 270 60或更長 4 實細15 50 0.31 0-07 0-05 50 6.0 2.8 27 40 330 60或更g 5 經濟部中央標準局8工消費合作社印製 本紙張又度通用中國國家櫺準(CNS)甲4規格(210 X 297公笼) 30 81.9.25,000 219958 A6B6 五、發明説明(29) 表2⑽) 每羣位9度擂曲设度 透《性 ft度 伸畏度 抗水fi力U»oit Jar變形畤之 mmmm (ec-vc) (k«/3c·) (*) T«t 抗繆«性 (g/-?) (·.) 向 (cc/ca7.se 〇 «fSj 镘向 ΰ向 蠘向 (mmHiQ) (in) (畤聞) 比較例1 70 0-33 0.20 0-11 40 7.5 3-8 80 120 m 1 1 HMm 2 50 0.31 0-Π ο.οβ 20 S-8 3-0 30 42 450 s 比較例3 50 0-37 0.08 0-06 90 6.6 3-2 30 45 200 10 1 比較例4 SO 0.28 0.15 0.10 20 6.S 3-3 30 45 230 so 2 比較例5 32 0-22 0.06 0-04 220 5-3 2-1 20 30 190 5 1 比較例6 as 0.57 0.13 0-08 10 6-5 3-0 28 45 250 60¾更畏 4 比較例7 85 0-36 0-27 o.is 30 9.0 5-4 35 50 200 10 1 比較例8 50 0.J7 0-05 0.03 100 5-8 2-8 24 40 220 so 2 比較例9 50 0-35 0.07 0-03 95 6.0 3-4 32 45 220 50 2 (請先閲讀背面之注意事項再填寫本頁) —裝. 訂. 線. 經濟部中央標準局0K工消費合作社印製 木纸張又度適用中國國家標準(CNS)甲4規格(210 X 297公釐) -31 - 81.9.25,000 經濟部中央標準局MS工消費合作社印製 A6 ___B6_ 五、發明説明(30) 表1顯示例1至15及比較例1至9之複合型非織造 布構造,而表2為複合型非織造布之特性。如表2所示, 例1至15之複合型非織造布具有優越之透氣性,掻高之 耐水性及可接受,即60分鐘或更大之Mason jar值。且 液體障壁性及細菌障壁性亦佳。此外,因為在因摺曲或壓 缩力而變形時之抗滲液性差,故複合型非織造布對於,例 如在手術枱上手術者壓縮時之血液摻透有優越之預防能力 ,且因優越之透氣性,故不累積濕度,且複合型非織造布 之強度之撓性優越。 本發明之複合型非織造布之以上特色可藉彼者與比較 例1至9之複合型非織造布之持性而說明。例如,比較例 1、4、5、7、8及9中N值大,但平均定向度小,短 纖維非織造布A中細度0 . 3旦尼爾或更大之短纖維比例 在比較例2中大,在比較例3中小,因此,前者之透氣性 差而後者之耐水性差。此外,因為短纖維非織造布A之每 單位面積重在比較例6之複合型非織造布中過大,故透氣 性差且此複合型非織造布之短纖維非織造布A及纖絲非織 造布B間之交織不足。 例1至15中短纖维非織造布A之表觀密度為0. 1 kg/cm3或更小。而比較例1、5及9中平均定向度 Z值小之短纖雒非織造布A之表觀密度小於0 . 1 g / c m 3 〇 本發明之複合型非織造布可用於醫學應用,諸如手術 衣、布單、布幔、面罩等,另可用為生理護墊及尿片之頂 衣纸張尺度通用中國S家橒準(CNS)甲4规格(210 X 297公笼) -32 - 81.9.25.000 (挤先閱讀背面-之注意事項再彡寫本頁) 裝. 訂. 丨煖·- 2199^)8 A6 B6 五、發明説明(31)層、濾器、壁紙、人工皮革等之基質。 (請*先閲讀背面之注意事項再A-本頁) —裝. .11. 丨線丨 經濟部中央標準局8工消費合作社印*'1衣 衣紙張尺度適用中國國家橒準(CNTS)甲4規格(210 X 297父坌) _ 33 - 81.9.25,000I --------------- installed ------ tr ------ line (please read the notes on the back of M and fill in page 4)-this paper The standard is applicable to China National Standard (CNS) A4 specifications (210 X 297 public conversion) -18-81.9.25,000 Α6 Β6 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Invention description (17) cm2 and the third step 3 kg / cm2 pressure. Examples 8 to 10 Use the same method as in Example 3 to produce the composite nonwoven fabrics of Examples 8 to 1 ◦ except that the following filament nonwoven fabric B produced by the spun bond method is used. The filament nonwoven fabric B of Example 8: polypropylene spunbond nonwoven fabric, which includes strands of fineness of 3 denier, weight per unit area of 25 g / m2 and average elongation at break of 30%, A polypropylene polymer was melt-spun to produce a net and the net was embossed using the method of Example 1 under heating. The filament nonwoven fabric B in Example 9: knitting-resistant 6 spunbond nonwoven fabric, which includes filaments with a fineness of 2 denier, a weight per unit area of 25 g / m2, and an average elongation at break of 30%. The polymer 6 was melt-spun to produce a net and the net was embossed using the method of Example 1 under heating. The fibril nonwoven fabric of Example 10 B: polyethylene terephthalate nonwoven fabric, which includes filaments with a fineness of 2 denier, a weight per unit area of 30 g / m2, and an average elongation at break of 2 5% was obtained using the method of Example 1. Endeavour Example 1 1 (Please read the notes on the back before filling in V. This page) — Binding. Ordering. Thread. Clothing paper size is applicable to a National Standard (CNS) A 4 specifications (2) 0 X 297 )--19-81.9.25,000 Α6 Β6 Central Standards Bureau of the Ministry of Economic Affairs ια Industrial and Consumer Cooperatives printed Ϊ-Λ V. Description of the invention (18) will be 1 part by weight fineness ◦. 1 denier and 5mni long polyparaben Ethylene dicarboxylate staple fiber, 1 part by weight viscose rayon staple fiber with a fineness of 1 denier and a length of 5 mm, and 2 parts by weight polyolefin terephthalate with a fineness of 1 denier and a length of 5 mm Ethyl ethyl staple fiber was dispersed in water and stirred into a slurry with a concentration of 0.63%. The method of Examples 2 to 4 was used to produce the composite nonwoven fabric of Example 11 from the slurry. Cao Shi Example 1 2 Two parts by weight of polyethylene terephthalate staple fiber with a fineness of 1 denier and a length of 5 mm, and 7 parts by weight of viscose rayon staple fiber with a fineness of 1 denier and a length of 5 mm 63% 的 粉状。 Luo and 1 part by weight using the fibrillated acrylic pulp obtained by the following method dispersed in water and stirred into a concentration of 0.63% slurry. The method of Examples 2 to 4 was used to produce the composite nonwoven fabric of Example 12. The fibrillated acrylic pulp in Example 12 was produced using the following method. Will include 95.0% by weight of acrylonitrile, 4.5% by weight of methyl acrylate and 0.5% by weight of methallyl sulfonate, and a number average molecular weight of 10,000 and polygasified ethylene and poly The polymer of block type polygasified ethylene-polygasified propylene-polygasified ethylene copolymer with a weight ratio of propylene oxide of 70 to 30 is dissolved in dimethylformamide to obtain Spinning solution of acrylic polymer and 2.3% by weight block copolymer. The spinning solution was allowed to stand for 6 hours, and was squeezed through a spinning board into a coagulation bath containing 75% dimethylformamide to form undrawn fibers. The undrawn fibers were washed, stretched at a draw ratio of 12 times, and then dried in hot air at 8,000 to form fibers with a fineness of 1.5 denier. Earnings (please read "Notes on the back of the book first, then 4 pages")-Binding · Ordering ... Line. This paper is again applicable to the National Standards (CNS) A 4 specifications of the country t (210 X 297 public)- 20-81.9.25,000 19958 A6 B6 V. Description of invention (19) The fiber lobe is cut into 5 mm pieces, and 10 parts by weight of the cut fiber fraction is in 90 parts by weight of water. This fiber dispersion is placed in a disc lapping machine with a disc pitch of .1 mm and hit to a filtration rate of zero. The beaten acrylic pulp has a small number of fine hook-like fibrils obtained by separating the fibers beside the surface of the portion corresponding to the original acrylic fiber bundle. In addition, the longitudinal portions of the strands are separated to produce fine fibers. Measurement Example 12 As a result of the retention of the composite nonwoven fabric, the water resistance and tensile strength of the composite nonwoven fabric were obviously improved slightly by using the fibrillated acrylic pulp, and the air permeability was not reduced. In addition, when an electron micrograph of the composite nonwoven fabric of 12 was observed, it was apparent that the short fibers with a fineness of 0.3 denier or less and the short fibers with a fineness of 0.5 denier or less remained The fibers of the highly average orientation Z and fibrillated acrylic pulp are fully interwoven with the short fiber nonwoven fabric A and the filament nonwoven fabric B. Please read it first-then fill in the pages to bind the Central Sample Bureau of the Ministry of Economic Affairs, the 8th Industrial Consumer Cooperatives to print a sample of 1 3 57% polyethylene terephthalate with a fineness of 0.1 denier and a length of 5 mm The short fiber and 43% viscose rayon short fiber with a fineness of 1 denier and a length of 5 mm were dispersed in water and mixed into a slurry with a concentration of 0.63%. The slurry was made into paper on an inclined wire mesh type paper splitter to obtain a short-fiber nonwoven fabric A weighing 25 g / m2 per unit area. The fibril nonwoven fabric B same as that in Example 1 was laminated on the short fiber lobe nonwoven fabric A to obtain a layered product. The laminate was subjected to three-step water injection treatment from the top and bottom surfaces of the laminate to obtain the composite nonwoven fabric of Example 13. That is, apply the first step kg / cm2 on both sides of the layer in sequence, and the second step 15kg / line paper size. General Chinese National Standard (CNS) A 4 specifications (210 X 297 male) -21-81.9 .25.000 Printed 219953 A6 B6 by Employee Consumer Cooperative of the Central Bureau of Prospects of the Ministry of Economics and V. Description of the invention (20) cm2, and the third step is water injection treatment at a pressure of 30kg / cni2. Example 1 4 · 1 part by weight of 0.25 denier polyethylene terephthalate staple fiber with a length of 5 mm, and 3 parts by weight of 1 denier fine fiber with a length of 5 mm The rayon staple fibers are dispersed in water and stirred into a slurry with a concentration of 0.63%. Short-fiber non-woven fabric A with a weight of 25 g / m2 per unit area was obtained by sizing the paper in a slanted wire mesh papermaking. The fibril nonwoven fabric B of the same example 1 was laminated on the staple fiber nonwoven fabric A, and a layer was obtained. This layered material was subjected to a three-stage water injection treatment on the top and bottom surfaces of the layered material to obtain the composite nonwoven fabric of Example 14. That is, water injection treatments with a pressure of 15 kg / cm2 in the first step, 15 kg / cm2 in the second step, and 30 kg / cm2 in the third step are applied in sequence on both sides of the layered object. Example 1 5 1 part by weight of 0.1 denier fine polyethylene terephthalate staple fiber with a length of 5 mm, and 3 parts by weight fineness ◦. 5 denier with a length of 5 mm of viscose The rayon staple fibers are dispersed in water and stirred into a slurry with a concentration of 0.63%. Short-fiber non-woven fabric_A with a weight of 25 g / m2 per unit area was obtained by making the pulp paper in the inclined wire mesh papermaking. The fibril nonwoven fabric B of Example 1 was laminated on the short fiber nonwoven fabric A to obtain a layered product. This layered material was subjected to a three-stage water injection treatment from the top and bottom surfaces of the layered material to obtain the composite nonwoven fabric of Example 15. That is, in accordance with the specifications of the Central Park National Sample Standard (CNS) Grade 4 (210 X 297 public loan) -22 ~ 81.9.25,000 (please read the precautions on the back before filling out this page) ). Packing. Ordering. The Central Standards Bureau of the Ministry of Economic Affairs, the 8 Industrial and Consumer Cooperatives, printed 5 clothes 2199〇3 A6 _B6_ 5. Description of the invention (21) The first step of 15kg / cm2 and the second step of 15kg / cm2 are applied on both sides of the object, and The third step is water injection treatment with a pressure of 30kg / cm2. fcb Comparative Example 1 1 part by weight fineness of 0.1 denier and 5 mm long polyethylene terephthalate short strand, and 1 part by weight fineness of 1 denier and 5 mm long viscose The rayon fiber is dispersed in water and stirred into a slurry with a concentration of 1%. The pulp was made into paper in a slanted wire mesh type paper to obtain a staple fiber nonwoven fabric A having a weight of 40 g / ni2 per unit area. Using the method of Example 1, a polypropylene spunbond nonwoven fabric B including 3 denier filaments was produced, which had a weight of 30 g / m2 per unit area and an average elongation at break of 85%. On the short fiber non-woven fabric A, a layer was prepared. This layered material was subjected to a three-stage water injection treatment on the top and bottom surfaces of the layered material to prepare the composite nonwoven fabric of Comparative Example 1. That is, a water injection treatment of a pressure of 40 kg / cm2 in the first step, a second step &lt; 40 kg / cm2 in the second step, and a step of 40 kg / cm2 in the third step are applied in sequence on both sides of the layer in sequence. Comparative Example 2 7 parts by weight of 0.1 denier and 5 mm long polyethylene terephthalate short fiber molybdenum, and 3 parts by weight of 1 denier and 5 mm long viscose The rayon staple fibers are dispersed in water and stirred into a slurry with a concentration of 63%. The paper is made from the slurry in the inclined wire mesh paper making. The paper is also suitable for the Chinese standard (CNS) A 4 specifications (210 X 297 father loan) -23-81.9.25.000 {Please read the back of the nirvana before filling the factory 4 Page)-Installation-Ordering-. The Ministry of Economic Affairs Central Standards Bureau H Engineering Consumer Cooperative Printed 5 Clothing 21995S A6 ___B6_ Fifth, the invention description (22) to the short fiber nonwoven fabric A weighing 25 g / m2 per basket area. The fibril nonwoven fabric B of the same example 1 was layered on the short fiber nonwoven fabric A, and a layer was obtained. This layered material was subjected to a three-stage water injection treatment from the top and bottom surfaces of the layered material, and the composite nonwoven fabric of Comparative Example 2 was cracked. That is, a water injection treatment of stress of 15kg / cm2 in the first step, 15kg / cm2 in the second step, and 30kg / cm2 in the third step is applied to both sides of the layer in sequence. Comparative Example 3 The composite nonwoven fabric of Comparative Example 3 was prepared by the same method as Comparative Example 2, except that the content of polyethylene terephthalate staple fiber and viscose rayon staple fiber changed from 7 to 3 and from 1 Becomes 9 outside. fch Comparative Example 4 2 parts by weight of paste and 3 parts by weight of polyethylene terephthalate short fibers with a fineness of 1 denier and a length of 5 mm were dispersed in ALASKA PULP with a paste bonder for 5 minutes. Stir in water to a concentration of 0.63% slurry. The method of Comparative Example 2 was used to produce the composite nonwoven fabric of Comparative Example 4 except that the above-mentioned slurry was used. Comparative Example 5 1 part by weight fineness 0.1 denier and 5 mm long polyethylene terephthalate short fiber, and 3 parts by weight fineness 1 denier and 5 mm long viscose man-made The silk staple fibers are dispersed in water and stirred into a concentration based paper. The Chinese National Standard (CNS) A 4 specifications are also applicable (210 X 297 male wear) -24 ~ 81.9.25,000 (please read the precautions on the back before spraying and then domain one : This page—Finishing and binding. Thread, 219953 A6 _B6_ V. Description of the invention (23) 0.18% slurry. In the inclined wire mesh papermaking, the slurry is made into paper to obtain a short fiber nonwoven of 7 g / m2 per unit area. Cloth A. Lay the non-woven cloth B of the same example as Example 1 on the staple fiber non-woven cloth A to obtain a layered material. This layered material is subjected to three-stage water injection from the top and bottom of the layer Treatment to produce the composite nonwoven fabric of Comparative Example 5. That is, apply the first step 10ks / cm2, the second step 10kg / cm2, and the third step 20kg / cm2 on both sides of the layer in order. Pressure water injection treatment. (Please read the precautions on the back and then π> .. This page) 丨 Installed. Printed by the Ministry of Economic Affairs Central Standards Bureau β 工 consumer cooperative cooperative The slurry was cracked to the same as that of Comparative Example 5, except that the slurry concentration became 1.5%. In the inclined wire-type papermaking, the slurry was made into paper to obtain a short-fiber nonwoven fabric A with a weight of 60 g / m2 per unit surface. The same as in the example The fibril non-hybrid cloth 1 is laminated on the short fiber non-woven fabric A to obtain a layered product. This layered product is subjected to a three-stage water injection treatment from the top and bottom surfaces of the layered product to produce Comparative Example 6 The composite non-woven fabric. For printing, apply water injection treatment with pressure of 15kg / cm2 in the first step, 15kg / cm2 in the second step, and 30kg / cm2 in the third step in sequence. 7 The method of Comparative Example 6 was used to prepare the composite non-woven fabric paper of Comparative Example 7 again applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 male wear) -25-81.9.25,000 order · thread. 213953 A6 ____B6__ printed by the Central Standard Ma 8 Consumer Cooperative of the Ministry of Economic Affairs 5. Description of the invention (24), except that the pressures in the first, second and third steps of the water injection treatment become 20kg / cm2, 40kg / cm2 and 40kg / cm 2 outside. Bh Comparative Example 8 Using the method of Example 1, a polypropylene including 3 denier filaments was prepared Spunbond nonwoven fabric B, which has a weight per unit area of 25 g / m2 and an average elongation at break of 55%. The weight of 1 part by weight of polyethylene terephthalate with a fineness of 0.1 denier and a length of 5 mm is short Fiber, and 3 parts by weight of 1 denier and 5 mrri viscose rayon short fiber fraction in water and stirred into a 1.5% concentration slurry. Short fiber weight per unit area of 60 g / m2 is not The woven fabric A was directly split from the above pulp-broken paper on the fibrous nonwoven fabric B, and then compounded under the same conditions as in Comparative Example 8. bb Comparative Example 9 1 part by weight of 0.1 denier and 5 mm long polyethylene terephthalate short fiber, and 3 parts by weight of 1 denier and 5 mm long viscose The rayon staple fiber was dispersed in water and stirred into a slurry with a concentration of 0.63%. The short fiber nonwoven fabric A with a weight of 25 g / m2 per unit area was directly cracked from the slurry on the fibrous nonwoven fabric B. This layer was subjected to three-stage water injection treatment from the top and bottom of the layer . The composite nonwoven fabric of Comparative Example 9 was cracked. That is, apply the first step of 15kg / cm2 on both sides of the layer in sequence, and the second step of 15kg of clothing and paper are again universal China National Standard (CNS) A 4 specifications (210 X 297 male wear) -26 ~ 81.9 .25.000 (please read the back of the page. Note before proceeding to € .: this page). Binding, ordering, thread. 219953 A6 B6 5. Description of the invention (25) / cm2, and the third step of 30kg / cm2 pressure water injection deal with. (Please read the back of the page. Note before filling in. This page) Install _ .11. Line. This paper printed by the Central Standards Bureau of the Ministry of Economic Affairs 3 Industrial and Consumer Cooperatives is again suitable for China National Standard (CNS) A 4 specifications (2) Ο X 297? 'Cage) —27-81.9.25,000 219953 A6 B6 V. Description of the invention (26) Table 1 Short iron ^ Suitable for selection of cloth although oil is tender and the condition of the cloth columnar ^ fasm other F + &lt; 3 F / G entanglement average breakage per position S per position guide M Pingxiong uses iron current force 0.34 0.54 surface broadcast s extension ft * area £ prime (N) interval mm 1st 2nd 3rd or Shi Xiao (F) Ban Da⑹ Step "Estep · Step Huo Degree mmm. Mi« abt Fineness msm Proportion Proportion Proportion id): «tv id) (, ⑴ (d) (s / _, (d) (Z) (Z) Real salting example 1 0-1 50 1 50--25 100 1 1 22.5 23 4 3.3 s 15 15 30 Real salting example 2 0-1 SO 1 50--2S iOO 1 1 22.5 25 5 3.7 Fixed 15 15 30 Example 3 0.1 25 1 75-25 100 1/3 1 22. S 25 7 3.2 5 15 15 30 Example 4 0-1 15 1 85--25 100 0.18 1 22.5 25 10 3.0 foot 15 15 30 Example 5 0-1 25 I .15 0. *! 4 0 25 60 0.71 1 22.5 25 9 3-3 m 15 15 30 霣 旅 Example 6 0.1 25 I 75--15 100 1/3 1 22-5 25 5 3-5 Foot 10 10 30 Example 7 0-1 25 1 75--40 100 1/3 t 22.5 25 15 4.3 foot 15 20 30 Storage Example S 0-1 25 1 75--25 iOO 1/3 2 30 25 12 2.8 Yes 15 15 30 * fine 9 0-1 25 1 75--25 100 1/3 t 30 2Q 15 2-7 IS 15 30 «Pay ⑴ 0-1 25 1 75--25 100 1/3 1 Z5 20 10 3.3 foot 15 15 30 Example 11 0.1 25 1 25 I 50 25 100 1 I 22.5 25 12 3.1 foot 15 15 30 «na 2 0-1 20 1 70 original» beta cypress 10 25 90 0.29 l 22.S 25 8 3-4 foot 15 15 30 «Example 13 0Λ 57 1 43--25 100 1-33 1 22.5 25 5 4.0 0 15 15 30 Example U 0.25 25 Ϊ 75--25 100 1/3 1 22.5 25 6 3. J foot 15 15 30 Bribery example 15 0.1 25 0-5 7: S--25 100 1/3 1 22.5 IS 7 3-4 foot 15 15 30 Central China Bureau of Economic Affairs tec industrial and consumer cooperatives printed brake clothing (please read the precautions on the back before filling in I. 4 Page) This paper is again applicable to the Chinese National Standard (CNS) Grade 4 specifications (210 X 297 courts) 81.9.25,000 219958 A6B6 V. Description of invention (27) Table 1 &lt; continued &gt; Short hunger is not to choose fabric fiber line Inlaid fabric with eaves and columnar flow treatment. Mast Every 5 digits F * CF / G Embroidery degree is cut off averagely Every S guide person Yan Li averages to use Tiegeng touch force 0.3- 0.5 · * 面 穰 Extend S Degree area 篁 mis) Dimension mm 1st 2nd 3rd Amount ΦίΠ 3 * a: (g) Step ff Step S Step β mm wmt. Mm Fineness proportion ratio tdi iwtl) (d) imt%) (d) is ^ m1 ) (d) (2) (s / -M ίZO) Comparison Xuan 1 0.1 50 1 50--40 100 1 3 85 30 50 1-1 No 20 40 40 Comparative Example 2 ο.ι 70 1 30--25 100 7/3 1 22.5 25 10 3-5 1 15 15 30 Comparative Example 3 0.1 10 1 90--25 100 1/9 1 22.5 25 8 3-2 Foot 15 15 30 Comparative Example 4--1 40 pulp 60 25 40 0 1 22-5 25 13 2-1 Yes 15 15 30 Comparative Example 5 0.1 25 1 75--7 100 1/3 1 22.5 25 25 1.3 S 10 10 20 Comparative Example 6 0-1 25 I 75--60 100 1/3 1 22-5 23 3 12 feet 15 15 30 Comparative Example 7 0.1 2S 1 75--60 100 1/3 1 22.5 25 40 2-0 No 20 40 40 Comparative Example 8 0-1 25 1 75-- 25 100 1/3 3 55 25 30 2.1 Foot 15 15 30 Comparative Example 9 0Λ 25 1 75 • _ 25 100 1/3 l 22-S 25 22 1-8 § 15 15 30 (Please read the precautions on the back first, then 4 pages). Packing. Ordering. Line. Printed by the KK Gongxiaot Cooperative of the Central Office of the Ministry of Economics and Trade Cooperatives. ) A 4 specifications (210 X 297 public loan) One 29-81.9.25,000 213958 A6 _B6 V. Description of the invention (28) «2 Each unit Qin degree 1C Qu Geng degree Breathability Cyan degree Extensibility degree Water resistance Kson Mason Jar Deformed area S6 weight (ecVc) (ks / 3cm) (t) Test Anti-Miaoye resistance ί * / * Μ (·) _ 禳 向 (oc / ca7.sec) ft direction survey ^ fff direction (μΗ, Ο) (_in) (畤 R3> (please read the notes on the back first and then fill in V, this page) Baohu 1 50 0.31 0.09 0-06 38 6-0 2.7 25 42 380 call longer 5 vmm 2 50 0.31 0.09 0 * 06 60 6-0 2.7 26 40 370 60 or longer 5 Lease Example 3 50 0.32 ο.ο β 0-06 90 6-2 2-9 28 40 300 60 or longer 5 wmm 4 50 0.33 0- 08 0-06 130 6.4 3.0 30 40 270 60 or longer 5 Real connection example 5 50 0.33 0.09 0-06 95 6-4 3-2 30 d〇290 60¾¾¾ 5 W Extinction 6 40 0.28 0.06 0.05 200 5.7 2, 5 22 34 250 60 ¾ mourning 5 Example 7 65 0-37 0-14 0.07 50 7.8 4.5 35 50 450 60 or more fearful 5 real butterfly 8 50 0.34 0.CT7 0-05 so 6.2 2.5 30 50 230 6〇 ^ 5E Length 5 «Example 9 45 0-34 0-07 0.03 75 6.9 3-3 35 55 270 Call out 5 Miscellaneous examples 10 55 0-35 0.14 0.07 80 8-0 5-4 30 45 330 60 or more 5 Real pay U 50 0-34 0.10 0.07 80 7.0 3.5 30 40 290 60¾ Shi Chang 5 Real fine 12 50 0-34 0-12 0.09 85 6.5 3-0 27 38 290 60 or more Length 5 Example η 50 0.31 0-09 0.06 45 6.0 2-6 25 41 415 6〇 or more fearful 5 Example 14 50 0.33 0-10 0-07 98 6.4 3-2 30 42 270 60 or longer 4 Actual size 15 50 0.31 0-07 0-05 50 6.0 2.8 27 40 330 60 or more 5 The Central Standards Bureau of the Ministry of Economic Affairs 8 Industrial and Consumer Cooperatives printed this paper and it is once again universal China National Standards (CNS) A 4 specifications (210 X 297 male cage) 30 81.9.25,000 219958 A6B6 V. Description of the invention (29) Table 2⑽) 9 degrees of flexion set per group position, "sexual ft degree, degree of extension, water resistance, water resistance, U» oit Jar deformation mmmm (ec-vc) (k «/ 3c ·) (*) T« t anti-miao «(g /-?) (·.) direction (cc / ca7.se 〇« fSj trowel direction ΰ direction 蠘 direction (mmHiQ ) (in) (畤 闻) Comparative Example 1 70 0-33 0.20 0-11 40 7.5 3-8 80 120 m 1 1 HMm 2 50 0.31 0-Π ο.οβ 20 S-8 3-0 30 42 450 s Comparative Example 3 50 0-37 0.08 0-06 90 6.6 3-2 30 45 200 10 1 Comparative Example 4 SO 0.28 0.15 0.10 20 6.S 3-3 30 45 230 so 2 Comparative Example 5 32 0-22 0.06 0-04 220 5- 3 2-1 20 30 190 5 1 Comparative example 6 as 0.57 0.13 0-08 10 6-5 3-0 28 45 250 60¾ more fear 4 Comparative example 7 85 0-36 0-27 o.is 30 9.0 5-4 35 50 200 10 1 Comparative Example 8 50 0.J7 0-05 0.03 100 5-8 2-8 24 40 220 so 2 Comparative Example 9 50 0-35 0.07 0-03 95 6.0 3-4 32 45 220 50 2 ( Please read the precautions on the back and then fill out this page)-Packing. Ordering. Thread. The Central Standards Bureau of the Ministry of Economic Affairs 0K Industrial and Consumer Cooperative printed wooden paper again applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 %) -31-81.9.25,000 Printed by the Ministry of Economic Affairs, Bureau of Central Standards, MS Industrial and Consumer Cooperative A6 ___B6_ V. Description of invention (30) Table 1 shows the composite nonwoven fabric structure of Examples 1 to 15 and Comparative Examples 1 to 9, and Table 2 shows the characteristics of composite nonwoven fabrics. As shown in Table 2, the composite nonwoven fabrics of Examples 1 to 15 have excellent air permeability, high water resistance and acceptable, that is, a Mason jar value of 60 minutes or more. And liquid barrier and bacterial barrier are also good. In addition, because of poor resistance to liquid leakage when deformed due to bending or compressive forces, the composite nonwoven fabric has excellent preventive ability for blood penetration during compression by the operator on the operating table, for example It is breathable, so it does not accumulate humidity, and the strength of the composite nonwoven fabric is excellent in flexibility. The above characteristics of the composite nonwoven fabric of the present invention can be explained by the holding properties of the composite nonwoven fabric of the other and Comparative Examples 1 to 9. For example, in Comparative Examples 1, 4, 5, 7, 8, and 9, the N value is large, but the average orientation is small, and the ratio of short fibers of 0.3 denier or more in the short fiber nonwoven A is in comparison. Example 2 is large and is small in Comparative Example 3. Therefore, the former has poor air permeability and the latter has poor water resistance. In addition, since the weight per unit area of the short fiber nonwoven fabric A is too large in the composite nonwoven fabric of Comparative Example 6, the air permeability is poor and the short fiber nonwoven fabric A and the filament nonwoven fabric of this composite nonwoven fabric are poor Insufficient interweave between B. The apparent density of the short fiber nonwoven fabric A in Examples 1 to 15 was 0.1 kg / cm3 or less. However, in Comparative Examples 1, 5 and 9, the short fiber A nonwoven fabric A having a small average orientation Z value has an apparent density of less than 0.1 g / cm 3. The composite nonwoven fabric of the present invention can be used for medical applications, such as Surgical gowns, drapes, drapes, face masks, etc., can also be used as physiological pads and toppers for diapers. Paper size General Chinese S Jiaju standard (CNS) A 4 specifications (210 X 297 male cage) -32-81.9 .25.000 (squeeze the back-read the notes before writing this page). Binding. 丨 Warm.-2199 ^) 8 A6 B6 5. Description of the invention (31) Layer, filter, wallpaper, artificial leather and other substrates. (Please * first read the precautions on the back and then A- this page) — Packing ... 11. 4 specifications (210 X 297 parent-child) _ 33-81.9.25,000

Claims (1)

*濟部中央樣準居Λ工消费合作社印5# 219958 a? B7 __. . , W 一 六、申請專利範圍 附件三: 第81108596號專利申請案 中文申請專利範困修正本 民國82年9月修正 1 . 一種複合型非織造布,其包括具以下要素(1 ) 至(3 )之短纖維非織造布(A)及纖絲非織造布(B ) ,彼纖絲部分彼此聯結,其中構成短纖維非織造布(A ) 之部分短纖維嵌入纖絲非織造布(B )中並與構成纖絲非 織造布(B)之織絲交織,產生短纖維非織造布(A)及 纖絲非織造布(B )之層體,在複合型非織造布中隨意切 面中長5 0 0 pm之區中嵌至纖絲非織造布(B)厚度之 1/2或更深之短纖維數N爲2 0或更少: (1 ) F + S 会 5 0 % 重 1/7 客 F/SS4/3 式中: F :細度0 . 3旦尼爾或更小之短織維在所有短纖維 中之比例 曰:細度0. 5旦尼爾或更大之短纖維在所有短纖維 中之比例 (2 )每單位面積短纖維之重:1 〇 g/m2至4 0 g / m 2 ° (3)平均定向度:2. 0至10。 2 .如申請專利範圍第1項之複合型非織造布’其中 短纖維非織造布(A)之表觀密度爲〇 . 1 g/cm3或 (請先閲讀背面之注意事項再瑣寫本頁) 裝· 訂. 本紙張又度適用中國國家標準(CNS)甲4规格(210 X 297公藿) 219958 A7 B7 C7 D7 六、申請專利範園 更大。 3 .如申請專利範圜第1項之複合型非織造布,其中 纖絲非織造布(B)之平均伸長度爲4 0%或更小: 其中: 平均伸長度爲雨個相互垂直方向所測之斷裂伸長度的 平均値。 4.如申請專利範圍第1項之複合型非織造布,其中 短纖維非織造布(A )由至少一種再生纖維素類之纖維組 成,且再生纖維素類纖維之比例爲5 0 %重或較多及8 0 %重或較少。 5 .如申請專利範圍第1項之複合型非織造布\,其中 短纖維非織造布(A )由再生纖維素類纖維及聚酯類纖維 組成,且聚酯類纖維相對於再生纖維素類纖維之比例爲1 至3或較大及1或較小。 6.如申請專利範圍第1項之複合型非織造布,其中 短纖維非織造布(A )由至少一種原纖化之丙烯酸類漿粕 組成,且原纖化之丙烯酸類漿粕比例爲5 %重或較大及 1 5 %重或較小。 (請先閲讀背面之注意事項再碘寫本頁) 經濟部中央樣準局員工消费合作社印5# 本紙張尺度通用中國困家標準(CNS)甲4規烙(210 X 297公釐)* The Central Ministry of Economics and Economics of the Ministry of Economic Affairs printed 5 # 219958 a? B7 __.., W 16th, the scope of the patent application Annex III: Patent Application No. 81108596, the Chinese application for patent norms, amended September, 82 Amendment 1. A composite non-woven fabric, which includes short-fiber non-woven fabric (A) and fibrous non-woven fabric (B) with the following elements (1) to (3). Part of the short fibers of the staple fiber nonwoven fabric (A) are embedded in the filament nonwoven fabric (B) and interwoven with the woven filaments constituting the filament nonwoven fabric (B) to produce the staple fiber nonwoven fabric (A) and filament The layered body of non-woven fabric (B) is embedded in the area of a random non-woven fabric with a length of 500 pm in the composite non-woven fabric to the number of short fibers N of 1/2 or deeper than the thickness of the fibrous non-woven fabric (B) For 2 0 or less: (1) F + S will be 5 0% weight 1/7 guest F / SS4 / 3 where: F: fineness 0.3 denier or less short weave dimension in all short The ratio of fibers: the ratio of short fibers with a fineness of 0.5 denier or more among all short fibers (2) The weight of short fibers per unit area: 1 〇g / m2 to 4 0 g / m 2 ° (3) Average degree of orientation: 2.0 to 10. 2. If the composite non-woven fabric of item 1 of the patent scope is applied, the apparent density of the short-fiber non-woven fabric (A) is 0.1 g / cm3 or (please read the precautions on the back before writing this page ) Binding and ordering. This paper is again applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 commonweed) 219958 A7 B7 C7 D7 Sixth, apply for a larger patent garden. 3. The composite non-woven fabric as claimed in item 1 of the patent application, in which the average elongation of the filament non-woven fabric (B) is 40% or less: where: the average elongation is measured in the mutually perpendicular directions The average value of the measured elongation at break. 4. The composite nonwoven fabric as claimed in item 1 of the patent scope, in which the short fiber nonwoven fabric (A) is composed of at least one kind of regenerated cellulose fibers, and the proportion of regenerated cellulose fibers is 50% by weight or More and 80% heavier or less. 5. The composite non-woven fabric as claimed in item 1 of the patent scope, in which the short-fiber non-woven fabric (A) is composed of regenerated cellulose fibers and polyester fibers, and polyester fibers are relative to regenerated cellulose The ratio of fibers is 1 to 3 or larger and 1 or smaller. 6. The composite nonwoven fabric as claimed in item 1 of the patent scope, wherein the short fiber nonwoven fabric (A) is composed of at least one fibrillated acrylic pulp, and the proportion of fibrillated acrylic pulp is 5 % Heavy or larger and 15% heavy or smaller. (Please read the precautions on the back first and then write this page). The Central Sample Bureau of the Ministry of Economic Affairs, Employee Consumer Cooperative Printed 5 # This paper standard is universal Chinese Standards (CNS) Grade 4 (210 X 297 mm)
TW081108596A 1992-05-01 1992-10-28 TW219958B (en)

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NL129557C (en) * 1962-03-09
FR1587774A (en) * 1968-09-30 1970-03-27
GB1453447A (en) * 1972-09-06 1976-10-20 Kimberly Clark Co Nonwoven thermoplastic fabric
US4190695A (en) * 1978-11-30 1980-02-26 E. I. Du Pont De Nemours And Company Hydraulically needling fabric of continuous filament textile and staple fibers
JPS6461555A (en) * 1987-08-28 1989-03-08 Mitsubishi Rayon Co Production of composite sheet
US4808467A (en) * 1987-09-15 1989-02-28 James River Corporation Of Virginia High strength hydroentangled nonwoven fabric
DE3942813A1 (en) * 1989-12-23 1991-06-27 Akzo Gmbh LAMINATE

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Publication number Publication date
IT1256092B (en) 1995-11-27
FR2690697A1 (en) 1993-11-05
DE4236667A1 (en) 1993-11-04
FR2690697B1 (en) 1995-09-29
ITMI922511A1 (en) 1994-05-02
KR940010902B1 (en) 1994-11-19
DE4236667C2 (en) 1995-03-23
ITMI922511A0 (en) 1992-11-02
KR930023516A (en) 1993-12-18

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