TW219370B - - Google Patents

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Publication number
TW219370B
TW219370B TW80110088A TW80110088A TW219370B TW 219370 B TW219370 B TW 219370B TW 80110088 A TW80110088 A TW 80110088A TW 80110088 A TW80110088 A TW 80110088A TW 219370 B TW219370 B TW 219370B
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Taiwan
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layer
propylene
melting point
thickness
foam
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TW80110088A
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Chinese (zh)
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Basf Ag
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219370 A 6 B6 五、發明災明( 郎 t ^Ιΐ-^Α Π 工;/|··;:·人:作ftM-t 工發明係關於以聚 製钧,此琴m製物s 將外黏合於泡沫上之 其上: 如已知的,由丙烯 力。波等之不良表面 被使用作為機動車輛 E P - B 9 7 5 0 4 紋述 險槓之核心材料之使 蓋物1例如由聚丙烯 y複合模製物製造之 本發明之目的ί糸發 装蔺機動車輛及,與 製造之沮件不同的是 泪容.可培解及因此 吸收衝繫•並應具有 卞發明人等已發現 S含泡沬丨I心,而泡 完全或??宵緊密之合 於造本發明捉供吸 设咒物包含: a . W沒自0 .. 5至1 0噌 1 β 5 ° C之丙Μ聚合 b. y/iEiO.05^0.5 丙烯聚合物為基材之吸故1ί擊複合模 含丙铺聚合拘泡,'来,其兩面使甩一種 熱瑢融黏合劏if將丙烯聚合物層台於 聚合物 說明了 外部與 由丙烯 用。據 製成者 具體簧 展複合 迄今使 可回收 可回收 良好之 此等目 ί来核心 物之複 於之一 杓, 皂米之 製造之泡沬具有高吸收衝擊能 由彼等製造之m製物砍然尚未 内部之可見组件 聚合物製造之泡沬作為汽車保 該專利所稱核心材料係與外覆 共同使用;然而,壶未提供有 例, m製物,此種隕製物可使用μ 用之组伴,例如由聚κ甲酸喆 :肢等亦應包含類丨以.相互可 之_ Ρ :彼写應可m久-及同時 機喊性筲與高表面品筲_ 的可由以丙烯聚合物為基付a 兩面Μ由熱:ίΐί融fn合劑阔站合 含隕製物達成> 丙烯聚含物茂合权製沟•此π ti 先«1 a 计 面 之 主 奇 項 再 寫 本 百- ίτ 線- 本纸伎尺度適用中HS家樣準(CMS)甲<)規格(2丨0x297公货) 319370 A 6 B6 五、發明說明(2 ) 9 0至1 4 0 Q C之烯烴共聚物為基材之熱瑢融黏合勁‘, c .厚度自3至2 0 0毫米密度自0 . 0 1 5至0 . 1公克/匣渋3之 一 泡沬層•此泡沬層係K熔點自1 2 5至1 5 5 σ C之丙烯聚合物 為基材| d. 厚度自0.05至0.5牽米之一中間層,此層包含之熔點自 90至140°C之烯烴共物為基材之熱熔融黏合劑* e. 厚度自0.5至10毫米之一層,此層包含瑢點自130至 165°C之丙烯聚合物: 此外,本發明提供一種製造此種類型之聚丙烯複合m製 物之方法,此種方法包含,於非K氣密方式關閉之模型中 ,將具有平均直徑2至8毫米之泡沬C )之空間(此等層(糸配 合模型壁之形狀)和引進蒸汽或熱空氣將此空間中之粒子 加熱使ί皮等陈脹並互相熔接,及此種方法包含瑢解中間層 b )與d )並同時將其熔接於a ) , c )與e )層上, -^郎屮处^-1,-^^:工消'('合作纪卬" (請先聞請计面之注意事項再邋艿本页)219370 A 6 B6 Fifth, the invention of disaster Ming (Lang t ^ ΙΙ- ^ Α Π 工; / | ··; :: People: Zuo ftM-t industrial invention is about the use of poly to make Jun, this piano m system s will be outside Adhesive on the foam: As known, it is made of acrylic. Poor surface is used as a motor vehicle EP-B 9 7 5 0 4 describes the core material of the bumper so that the cover 1 is made of polypropylene, for example y The purpose of the present invention manufactured by composite moldings is to equip motor vehicles and, unlike the manufactured parts, is tears. It can be developed and therefore absorbs impacts. It should have been discovered by the inventors and others. Containing bubbles, I heart, and bubbles completely or ?? is closely combined with the creation of the present invention to catch and set a mantra contains: a. W did not from 0 .. 5 to 1 0 噌 1 β 5 ° C of the propane Polymerization b. Y / iEiO.05 ^ 0.5 The propylene polymer is the base material. Therefore, the 1st impact composite mold contains propylene and polymer foam, and then, on both sides, a thermo-melt is used to bond the propylene polymer layer. The polymer is described as external and is made of propylene. According to the manufacturer, the specific spring-stretch composite has so far made the recoverable and recyclable good for the purpose of recovering the core material The foam made of soap rice has a high absorption of impact energy. The foam made of the m-made products made by them has not yet seen the internal components. The foam made of polymer is used as the core material of the car. This patent is used in conjunction with the outer cover. ; However, there are no examples provided by the pot, m products, such meteorites can be used with a companion of μ, for example, from poly kappa formic acid: limbs, etc. should also contain classes. Mutually acceptable _ Ρ: 彼 写It can be used for a long time-and at the same time, it can be made with propylene polymer as a base and a high surface quality _ can be achieved on both sides by heat: ίΐί melt fn mixture wide station to contain meteorites> propylene polymer inclusions Maohequan system ditch • This π ti first «1 a the main odds of the plan and then write a hundred-ίτ line-This paper trick scale is applicable to the HS home sample standard (CMS) A <) specifications (2 丨 0x297 public goods ) 319370 A 6 B6 V. Description of the invention (2) 90 to 1 4 0 The olefin copolymer of QC is the thermal bonding strength of the base material, c. The thickness is from 3 to 200 mm and the density is from 0.0 1 5 to 0.1 g / one of 3 foam layers • This foam layer is a propylene polymer with a melting point of K from 1 2 5 to 1 5 5 σ C as the substrate | d. Thickness from 0.05 An intermediate layer of up to 0.5 mm, this layer contains an olefin copolymer with a melting point of 90 to 140 ° C as a hot-melt adhesive for the substrate * e. A layer with a thickness of 0.5 to 10 mm, this layer contains Propylene polymer at 130 to 165 ° C: In addition, the present invention provides a method for manufacturing this type of polypropylene composite m product. This method includes, in a model closed in a non-K airtight manner, it will have an average diameter 2 to 8 mm of foam C) space (these layers (together with the shape of the model wall) and the introduction of steam or hot air to heat the particles in this space to make the skin, etc., swell and weld to each other, and this method Including the middle layer b) and d) of the solution and welding it to the layers a), c) and e) at the same time,-^ Langji ^ -1,-^^: Gongxiao '(' Cooperative Ji 卬 " (Please listen to the precautions of the plan first and then sloppy this page)

此新穎枵合隕製物之核心層c )包含以丙烯共眾物r為基付 之泡沬:此層具有自3至2 0 0毫米,較佳自4至1 0 0奄米,持 別是自5至2 0奄米之厚度' 密度自0 . 0丨5至0 . 1公克/公升, 較伎自0 . 0 2至0 . 0 8公克/公幵,持別是自0 . 0 2 5至0 . 0 6公免 /公升7較佳者(系丙烯與1至3 0重S % ,持别是自1至β ΐβ 1 %之乙烯及/或ί: 4至C 〇 « -烯烴之共聚物此共聚物應具有 自]2 5 至 1 5 5 ° .較 ίΙ θ 1 3 0 至 1 5 0 ° C,持别足自 1 4 0 至 1 5 0。C 熔點1此處之熔點除以f丨別W描熱W測定法(DSC π, c t h 〇 ci )測定I樣本第二次再瑢解之砬β培點(访品W熔點)… 此褪_定方法亦(¾用以測定衩合设製物之It他组份之熔點 本纸张又度逡用中國S家样準(CNS)甲4規格(210x297公釐) 219370 A 6 B6 五、發明況明(3 ) 此種泡沬涤一湩粒?泡沬,可由熔接平均直徑自2至8毫 米,較佳自3至6毫米之泡沬粒子而獲得。此核心罾賦予複 合璜製物良好之吸收衝擊性質: 此斬穎複合模製物之外層a )與e 1實質上包含至少一種丙 烯聚合物•或為聚合物或為共聚抅:此丙烯聚合物瞜具有 自U 0至1 6 5 Q C,較佳自1 4 0至1 6 5 Q C |待別是自1 5 0至1 G 5 ° C 熔鲇。外層之熔點應較核心層c丨之丙烯共聚物之熔點高至 少5 C,較佳多於1 0 ° C。外層具有自0 . 5至1 0毫米·較佳自 0 . 8至5毫米厚度: 外層可具有任何需要之表面结構,例如顆粒狀结構。 除了丙烯聚合物以外,外層可以包含有效量之習用添加 ,諸如染料.顏料 m充劑,加強劑.安定劑.抗靜電 劑.潤滑劏.增韌劏.增彈劑及其類m物: 4ΐ;,τ郎屮处^'''qn 工^0合作ft^" (請先閱讀背面之:;i意事項再填寫本頁) 上外層a )(可見層)較佳经彈性It .列如埕由使-兩丙烯 聚合物硬苜相與钦質相之混物;此砰質相包含高度等規. 部份结晶之聚丙烯•可包含高達3重虽%之乙烯單元;此钦 打相包含乙烯一丙烯悻β ,其包含自:丨0罕了 〇 € Μ %之乙烯 ·+此棰類型之雙相丙烯聚合物(可部份夂聯»丨系e知之商 蒗淹品及由已知之逐步丙烯_乙烯一丙晞聚合反應方法· 較作由銳相聚合反®製谢·砰Π相:炊Π相之比手:可η 9 C :1 0靼3 0 : 7 0之間要勅: 丙烯聚合物亦可包含|作為彈性削| Η用之IK ib戍未 ib之苯乙烯—二烯彈性物.乙烯一内烯—二饨橡K ( -5 - 本纸張尺度適用中國®家標準(CNS)T4規格(210x297公釐) 2193^0 A6 B6 五、發明說明(h ) EPDM ).動態硫化丙烯/ E P D Μ摻合物及埭型低密度乙烯共聚 物(線型低密度聚乙烯及超低密度聚乙烯IVLDPE): 外層e )通常除複合模製物之支持層及因此®方丨更地具有 對應於使用需求之剛性,例如涇由使用高度等規聚丙烯。 倘若一部份之橡膠,例如乙烯一丙烯橡膠,與聚合物混合 以改良其低溫衝擊強度,則此部份應僅為約5至3 0重量;S, 填充劑,諸如滑石,白堊.石墨.高嶺土或矽夾石,及/ 或加強劑,諸如短玻璃纖维•較佳與聚合物混合Μ增加其 剛性。此層亦可藉長玻璃纖维或玻璃纖维蓆加強。填充劏 或加強劑一般之使用量Μ此層為基準,自1 0至6 0重量%。 新穎複合模製物之中間層b )與d )用以將外層黏合於泡沬 核心。彼等具有自0,05至0.5毫米,較佳自0.05至0.2毫米 之厚度,及包含作為熱熔融黏合劏之烯烴共聚物|並且較 佳由超過50重量%之乙烯及/或丙烯•外加另一種α-烯 '埋或§1酸乙油3旨,丙酸乙鋪墙,(甲基)丙M 「具有自 1至8個碳原子之醇之(甲基)丙烯酸酯或其他可聚合單腊 所構成。包含8 5至9 5重量%丙烯.2至1 0重量%乙烯及2至 8® Μ % C4至U «—烯烴之三聚物特別適合:·烯烴共聚物之 瑢鲇應自9 0至1 4 0 ° C ‘較佳自1 0 0至1 3 5 σ C,持別是自1丨0至 130°C ^此溶點憋較柊心層c )之丙烯共聚物之熔點低至少 5 C,較佳至少1 0 ° 此新頌报合设製物可迚利地f:丨c )中所迠A荮2至8 €·均, 特別是3至6茔米平均0徑之類型之泡沬粒子開始製造.此 粒F 1控通常應不大於所耑耍泡沐核心丨’/沒之5 0至6 5 %。 本纸伕尺度適用中國國家梂準(C:NS)T4規格(210x297公嫠) (請先閱讀计面之注意事項再琪寫本頁) .:.¾. •Λ" 2193/0 A 6 B6 五、發明說明(5 ) 然凌5丨非以氣密方式關閉之模型中,將此種粒子一方面引 進至a )和b )層間而另一面引進至d )和e )層間之空間中(此 等噚係配合m型壁之形吠),例如使m壓縮空氣將粒子引 進:隨後將蒸汽或熱空氣通入此空間中,較佳自其厠面或 可能地鏜由外層之合適穿孔,將粒子加熱便彼等钦fb .膨 脹及互相熔接,中間層b )及d )熔解並同時將泡沬核心c )熔 接至外廣a )與e )。於冷卻之後•將嗦製物自模型中取出 於較佳程序中,將層a )與b )之預製複合物在降低壓力下 .於1 3 0 ° C至2 0 0 ° C下吸人陰fM中,緊接著將帶有符合m型 堊肜吠之e )層與層合層d )之預製複合物之陽模和陰模併台 ,並使模型兩半間留下較所需泡沬層大數毫米之空間。其 後此空間用泡沬粒子填充,然後用蒸汽或熱空氣加熱,並 於加熱之前或加熱之中將兩半m緊密壓成最後尺寸。於此 操作中,泡沬粒子被壓縮並相互熔接並瑢接至外層以形成 完成m製物。 - 此斩頦複合換製物於其個別層中|亦可含有效;;!之習用 添加劑*諸如染料,顔Η .填充劑.加強剖.防焰劑.脫 股剐.抗p m劑,安定砭其他铺肋劑- ^•^郎屮史^十^::::工消^合作^卬^ (請先閱請背面之注意事項再琪寫本頁) .訂. 此新潁複合模製物較佳使用於機勤車铺之製造,网如(乍 .¾ n m (door panels).链表板.托絮.E陽权.保險择: ,流器(s p ο ; I e「s )及 頮 fW 杓 由诨Π上相似類之材枓1E搞之靳拍报合设製杓:叮進ίί莨 際纯類型冋收,而不必分離成個別m份 诨例1 -7 - 本紙伕尺度適用中國S家梂準(C:NS>甲4規格(210x297公釐)The core layer of this novel anatomic c) contains foams based on propylene common substance r: this layer has from 3 to 200 mm, preferably from 4 to 100 mm, different The thickness is from 5 to 20 mm. The density is from 0.05 to 0.1 g / litre, compared to 0.02 to 0.08 g / g, the difference is from 0. 0 2 5 to 0. 0 6 liters per liter is better (it is propylene and 1 to 30 weight S%, the difference is from 1 to β 1 β 1% ethylene and / or ί: 4 to C 〇 «- Copolymers of olefins. This copolymer should have a range of from 2 5 to 1 5 5 °. Compared to ΙΙ θ 1 3 0 to 1 5 0 ° C, it is not sufficient from 1 4 0 to 1 5 0. C Melting point 1 here The melting point is divided by the measurement method (DSC π, cth 〇ci) to measure the second sample of the second sample of the sample I (the melting point of the visit W) ... The same method is also used (¾ In order to determine the melting point of the other components of the joint-made product, the paper is also used in China S Home Sample Standard (CNS) A 4 specifications (210x297 mm). 219370 A 6 B6 5. The invention is clear (3) Foam polyester-grain? Foam, can be obtained by welding foam particles with an average diameter from 2 to 8 mm, preferably from 3 to 6 mm This core provides the composite with good impact-absorbing properties: the outer layer a) and e 1 of the chopped composite molding substantially contain at least one propylene polymer • either a polymer or a copolymer: this propylene polymer Qu has U 0 to 1 6 5 QC, preferably 1 4 0 to 1 6 5 QC | wait for the melting catfish from 1 5 0 to 1 G 5 ° C. The melting point of the outer layer should be higher than that of the core layer c propylene The melting point of the copolymer is at least 5 C, preferably more than 10 ° C. The outer layer has a thickness from 0.5 to 10 mm · preferably from 0.8 to 5 mm: the outer layer can have any desired surface structure, for example Granular structure. In addition to the propylene polymer, the outer layer can contain effective amounts of customary additives, such as dyes, pigments, m fillers, reinforcing agents, stabilizers, antistatic agents, lubricating agents, toughening agents, elasticizers and the like m thing: 4l ;, τ 郎 屮 处 ^ '' 'qn work ^ 0 cooperation ft ^ " (please read the back of the page:; i matters and fill in this page) upper outer layer a) (visible layer) better experience It is elastic. It is composed of a mixture of a hard alfalfa phase and a prime phase of two propylene polymers; this pop phase contains a highly isotactic. Partially crystallized polypropylene • Contains up to 3% by weight of ethylene units; this kneading phase contains ethylene-propylene beta β, which includes: from 0% to 0% of ethylene. + This type of biphasic propylene polymer (may be partially圂 联 »丨 E-commercially known product and the known step-by-step propylene-ethylene-propylene polymerization polymerization method 9 C: 1 0 靼 3 0: 7 0 between: Propylene polymer can also contain | as an elastic chip | IK ib 戍 未 ib styrene-diene elastomer used for H. Ethylene-lactone-diene饨 Oak K (-5-This paper scale is applicable to China ® Home Standard (CNS) T4 specification (210x297 mm) 2193 ^ 0 A6 B6 V. Description of the invention (h) EPDM). Dynamically vulcanized propylene / EPD Μ blend And Dai-type low-density ethylene copolymers (linear low-density polyethylene and ultra-low-density polyethylene IVLDPE): the outer layer e) usually in addition to the support layer of the composite molded product and therefore ® side has more rigidity corresponding to the use requirements, For example, Jing uses highly isotactic polypropylene. If a part of rubber, such as ethylene-propylene rubber, is mixed with a polymer to improve its low-temperature impact strength, then this part should be only about 5 to 30 weight; S, fillers, such as talc, chalk. Graphite. Kaolin or sillimanite, and / or reinforcing agents, such as short glass fibers • It is better to mix with polymers to increase its rigidity. This layer can also be reinforced with long glass fiber or glass fiber mats. The general amount of filler or reinforcing agent M used is based on this layer, from 10 to 60% by weight. The intermediate layers b) and d) of the novel composite molding are used to bond the outer layer to the foam core. They have a thickness of from 0,05 to 0.5 mm, preferably from 0.05 to 0.2 mm, and contain an olefin copolymer as a hot-melt adhesive | and preferably from more than 50% by weight of ethylene and / or propylene An α-ene ’buried or §1 ethyl acetate 3 purpose, ethyl propionate to lay a wall, (meth) propyl M" (meth) acrylate or other polymerizable monomer with alcohol having 1 to 8 carbon atoms It is composed of wax. It contains 8 5 to 95% by weight of propylene. 2 to 10% by weight of ethylene and 2 to 8% Mn% C4 to U «-olefin terpolymer is particularly suitable: 9 0 to 1 4 0 ° C 'preferably from 1 0 0 to 1 3 5 σ C, the difference is from 1 ~ 0 to 130 ° C ^ this melting point is compared with the melting point of the core layer c) propylene copolymer Low at least 5 C, preferably at least 1 0 ° This new tribute co-production system can be easily f: 丨 c) in the A 2 to 8 € · average, especially 3 to 6 meters average 0 diameter The type of foam particles started to be manufactured. The F 1 control of this particle should usually not be greater than the core of the foam foam 丨 '/ No. 50 to 65%. The paper scale is applicable to the Chinese National Standard (C: NS) T4 specification (210x297 gong) (please read the plan first Matters needing attention and write this page).:. ¾. • 2193/0 A 6 B6 V. Description of the invention (5) Ran Ling 5 丨 In a model that is not closed in an airtight manner, such particles are introduced on the one hand To a) and b) between the layers and the other side is introduced into the space between d) and e) (these fathoms are combined with the shape of the m-shaped wall), for example, to make m compressed air introduce particles: then steam or hot air Access to this space, preferably from its toilet surface or possibly boring a suitable perforation of the outer layer, heating the particles to facilitate the fb. Expansion and fusion, the intermediate layers b) and d) melt and at the same time foam the core c) Welded to the outside wide a) and e). After cooling • Take out the pretentious product from the model in a better procedure, the prefabricated composite of layers a) and b) under reduced pressure. At 1 3 0 ° C to 2 0 0 ° C sucked into the human fM, then the male and female molds of the prefabricated compound with the e-layer and lamination layer d) conforming to the m-type chalky bark are combined, and Make the space between the two halves of the model larger than the required foam layer by a few millimeters. Then the space is filled with foam particles, then heated with steam or hot air, and heated Press the two halves of m tightly to the final size before or during heating. In this operation, the foam particles are compressed and welded to each other and connected to the outer layer to form a finished m.-This chin composite compound is used in its Individual layers | may also contain effective ;; conventional additives * such as dyes, Yan H. Filler. Strengthening profile. Flame retardant. Stretch-cutting. Anti-pm agent, stability Bianbian other ribbing agent-^ • ^ Lang冮 史 ^ Ten ^ :::: 工 消 ^ Cooperation ^ 卬 ^ (Please read the precautions on the back and then write this page). Order. This new Ying compound molding is better used in the locomotive car shop Manufacturing, such as (at first. ¾ nm (door panels). Linked watch plate. Suo Xu. E Yangquan. Insurance options :, flow device (sp ο; I e "s) and 頮 fW 杓 由 訨 Π similar on the similar category Tieling 1E's Jinpai newspaper co-founding system: Dingjin's pure-type harvesting, without having to separate into individual m shares. Example 1 -7-This paper size is applicable to China's S family standards (C: NS > A 4 specifications (210x297 mm)

IX 坪济郎 t 处栉'|1-^5=工消';:-合仃ftM·¾ 319370 A6 B6 五、《r明說明(δ ) 一種保險槓複合搆件之结構 層a ) 包含5 5重量%聚丙烯與4 5重量%乙浠一丙烯搾膠(重量 比1 : 1 )之摻合物,由丙烯與丙烯與乙烯之1 : 1混合物( 商業產品,出自BASF公司(BASF AG>之N〇Y〇len 2900 HX) 之逐步聚合反應製得,隨後用少量之交聯劑後芻理: 硬質相之瑢點1 6 2 ° C,熔體流動指數ί 2 3 0 ° C,2 . 1 6公斤 )=1 . 2公克/ 1 0分鐘,層厚度=1 . 3毫米。 層b ) 包含92重量%丙烯.2重量96乙烯及4重量— 丁烯之無 規三聚物。 瑢點1 3 2 ° C,熔體流動指數(2 3 0 ° C,2 . 1 6公斤)=5 . 5公 克/10分鐘,層厚度= 0.2耷米。 層c ) 由無規乙烯一丙烯共聚物與2 . 2遨1 %之乙烯製淠之泡沫 密度為0 . 0 8公克/厘米3 :· 熔點1 4 7 ° C,熔體流動指數(2 3 0 ° C,2 . 1 6公斤)=7 . 5公 克/ 1 0分Μ,層厚度=7 C毫米) & d ) 如丨M b ) ·但層厚度為0 . 5奄米〃 M e ) 均聚丙烯 熔鲇1 6 3 0 C,熔粑流勅指數(2 3 0 Q C,2 . 1 Γ)公斤)=7 0('> 克/ 1 0分適,用2 !3 T! 61 %玻璃Μ (無定向坡漓灌維)與2 5 (請先M請计面之;±意事項再填為本頁) .¾. 訂* •緣. 本纸伎尺度適用中國國家標準(CNS>甲4規格(210x297公嫠) 219370 A 6 B6 五、發明説明(7 ) 重1 %縱長方向定向之玻璃纖维加強:罾厚度=8毫米 a )簪與b )層ί系用共擠壓方法作成複合物,及於1 7 5 ΰ C用負 熱肜成方法使其苻合陰搰之形吠:囿e ) ί系由半完成板闬壓 縮成型方法製造;於壓製前,將層d )放置於馍型中及以此 方式堅固地黏合於層e ) : e )與d )之複含物使用邡熱釘板穿 孔,以容許熱蒸汽流入揹型中 將塗覆複合層a / b及d / e之模型關閉,使隕®有具7 0毫米 之内直徑。此模槽用具有體密度0 . 0 8公克/厘泶3 .粒子直 徑6毫米之泡沬粒子|自儲槽中1 . 5巴之壓力下填充。然後 將3 . 5巴之熱蒸汽通入模槽中歷8秒鐘及隨後用水將模型冷 卻。將模型打開•及藉彈射器將複合姐件脫膜= 簧例2 儀表板複合構件 層a ) 下列成分之混合构: : 5 0重量% N 〇 v ο 1 e η 2 9 0 0 Η X : B A S F公司1,此物!苕巳紹&:1IX Ping Jilang t at the location '| 1- ^ 5 = Working Consumers';:-Heding ftM · ¾ 319370 A6 B6 V. "R Ming Explanation (δ) A structural layer of a bumper composite member a) Contains 5 A blend of 5 wt% polypropylene and 45 wt% ethylene glycol-propylene squeezed rubber (weight ratio of 1: 1), consisting of a 1: 1 mixture of propylene and propylene and ethylene (commercial product, from BASF AG (BASF AG>) Of N〇Y〇len 2900 HX) was prepared by the stepwise polymerization reaction, and then treated with a small amount of cross-linking agent: rugged point of the hard phase 1 6 2 ° C, melt flow index ί 2 3 0 ° C, 2 . 16 kg) = 1.2 g / 10 minutes, layer thickness = 1.3 mm. Layer b) Random terpolymer containing 92% by weight of propylene. 2% by weight of 96 ethylene and 4% by weight of butene. The point is 1 3 2 ° C, melt flow index (2 3 0 ° C, 2. 16 kg) = 5.5 g / 10 min, layer thickness = 0.2 mm. Layer c) The foam density of random ethylene-propylene copolymer and 2.2% 1% ethylene is 0.08 g / cm3: · Melting point 1 4 7 ° C, melt flow index (2 3 0 ° C, 2. 16 kg) = 7.5 g / 10 minutes Μ, layer thickness = 7 C mm) & d) as 丨 M b) · but the layer thickness is 0.5 m 〃 M e ) Homopolypropylene melted catfish 1 6 3 0 C, flow index of melted cake (2 3 0 QC, 2.1 Γ) kg) = 7 0 ('> g / 10 points, use 2! 3 T! 61% glass Μ (non-directional slope irrigation) and 2 5 (please make plan first; please fill in this page if necessary). ¾. Order * • margin. This paper trick scale is applicable to Chinese national standards ( CNS > A 4 specifications (210x297 gong) 219370 A 6 B6 V. Description of the invention (7) Glass fiber reinforced with 1% weight in the longitudinal direction: thickness = 8 mm a) hairpin and b) layer Extrusion method is used to make a composite, and it is made into a shape of yin and yin by using a negative heat at a temperature of 1 7 5 ΰ C: 囿 e) is made by a semi-finished plate compression molding method; before pressing, The layer d) is placed in the bun shape and in this way is firmly bonded to the layer e): e) and the inclusion of d) so that Perforate the plate with hot nails to allow hot steam to flow into the back. Close the models coated with a / b and d / e, so that Meteor® has an inner diameter of 70 mm. This cavity was filled with foam particles having a bulk density of 0.08 g / cm3. Particle diameter of 6 mm | 1.5 bar pressure from the storage tank. Then hot steam of 3.5 bar was passed into the cavity for 8 seconds and then the model was cooled with water. Open the model • Remove the composite piece with a catapult = Spring Example 2 Instrument panel composite member layer a) A mixed structure of the following components:: 50% by weight N 〇v ο 1 e η 2 9 0 0 Η X: BASF company 1, this thing! Tuo Shao &: 1

入 0 . 4 重量 % U c a r s Π P C 2 A 及 0 . 2 重星 % U c a r s i 1 P C 1 B (永⑽公·司 (IJ n i ο n (: a「b i d 〇 C 〇 r p .))並%热而部份β聯、 ^iIT郎屮史^^'-巧::::工消^八:邝^卬製 ί^先閑ίΓ计面之注意事項再填寫本頁} 培3:3流動指數(2 3 0 0 C,2 . 1 6公斤)=1 . 2公克/ 1 0分碎 2 0 +Φ Μ %之超低密度聚乙烯 Ν 〇 r s ο Π X丨:W 1 9 0 0 I父尼 货公( 1ΐ n i c h e in ) ! 1 0 Φ 1ft %之無規三聚物,此共聚物包含9 2 敁%之内烯 .2道1 %之乙烯反4逭Μ %之丨一丁烯 1 0 Fil a % 之 M il:笨乙烯一—Γ 二 W:忾 B K Ui t ο n G 1 (3 5 0 ( ^ -9 - 本纸伕尺度適用中國國家浮孕(CNS)甲4^fS(210x297公釐) 时:濟郎屮处^·ι,-Α Π工消';'合作汰卬" 219370 A6 B6 五、诠明説明(d ) 0 公司(Shell)) 1 0重量%之滑石粉 硬質相之熔點1 6 2 ° C 層厚度1 . 1毫米 層b ) 如賁Μ 1 ,層厚度0 . 1 5毫米: 層c ) 自包含2. 2重量%乙烯之無規乙烯一丙烯共聚物製造之泡 沬,密度0 . 0 4 5公克/厘米3,Enter 0.4% by weight U cars Π PC 2 A and 0.2 heavy stars% U carsi 1 PC 1 B (Yong ⑽ 公司 (IJ ni ο n (: a "bid 〇C 〇rp.)) And% Hot and partial β-linked, ^ iIT Langji history ^^ '-Qiao :::: Work Consumers ^ Eight: Kwong ^ 卬 制 ί ^ First idle ΓΓ planning considerations and then fill out this page} Pei 3: 3 flow Index (2 3 0 0 C, 2. 1 6 kg) = 1.2 g / 1 0 min. 2 0 + Φ Μ% of ultra-low density polyethylene Ν οrs Π X 丨: W 1 9 0 0 I 1 n niche in! 1 0 Φ 1ft% of random terpolymer, this copolymer contains 9 2% of internal ene. 2 channels of 1% ethylene anti-4 鈭 Μ% of 1-butene 1 0 Fil a% of M il: stupid vinyl one-Γ two W: 忾 BK Ui t ο n G 1 (3 5 0 (^ -9-this paper is suitable for the Chinese National Floating Pregnancy (CNS) A 4 ^ fS (210x297mm) Time: Jilangji ^ · ι, -Α Π 工 消 ';' Cooperative reduction " 219370 A6 B6 V. Explanation (d) 0 Company (Shell)) 10% by weight The melting point of the hard phase of talc is 16 2 ° C. layer thickness 1.1 mm layer b) such as Ben M1, layer thickness 0.1 5 mm: layer c) self-contained 2.2 wt% ethylene Foam made of random ethylene-propylene copolymer with a density of 0.045 g / cm3,

熔點1 4 7 ° C 層厚度於4與2 0毫米之間變動。 層d ) 如層b)。 層e ) 均聚丙烯,熔體流動指數(2 3 0 D C,2 . ] (3公斤)二2 . 5公 克/ 1 0分鐘。 、 熔點1 6 3 ° C,層厚度4毫眾,用4 0重量%之滑石粉填充: W h )係砧熱厲合饱加於Μ壓延方法製造之a )厨:此苻合 物鞀真空熱成形方法使其符合m型壁之形吠·: 包含d )與e )之一層複合物ί系鞀射出成型製造,M d )則除 枚穴於射出悅中並頂向m捫板被吸入;隨後將e )科之熔閗 注人3 將包含拽合阍a / b與d / e之m型關閉ιΐ到m濟之内a s較 所脔要泡沬稱大2奄米為ih >然後此m m η】η有脰密度 -ίο- 本纸张尺度適用中國g家徉準(CNS>f 4規格(2丨0X297公嫠) (請先閱讀计面之注意事項再填寫本页) k. .訂_ 19370 A6 B6 五、诠明說明(〕) 0 . 0 4 0公克/厘米3 .粒子直徑3毫米之泡沬粒子•自ϋ卩屘容 器中於1 . 5巴之壓力下填充,關閉此模型及通入3 . 5巳之蒸 汽至馍槽中歷6秒鐘用水冷卻模型及將模型打開,拉取出 模製物。 簧例3 其程序類(W於簧例2之程序,但e )層除均聚丙烯崮,瑢 體流動指數(2 3 0 ° C · 2 · 1 6公斤)=1 0公克/分鐘,用3 0重 量%之無定向玻璃缴维蓆加強及藉壓縮成型法製造5 (請先閱請计面之注意事邛再填寫本页) -訂. -;,?郎屮九#il,-^xr 工消 i-v人:怍ft卬^ 11 本纸伖又度边用中國®家櫺iMCNS)甲4規格(210X297公嫠)Melting point 1 4 7 ° C. The layer thickness varies between 4 and 20 mm. Layer d) as layer b). Layer e) homopolypropylene, melt flow index (2 3 0 DC, 2.] (3 kg) 2 2.5 g / 10 min., Melting point 1 6 3 ° C, layer thickness 4 milliseconds, use 4 0% by weight of talc powder filling: W h) is an anvil made by hot-melt and added to the M calendering method a) kitchen: this fuming compound vacuum thermoforming method makes it conform to the shape of the m-shaped wall bark: contains d ) And e) a layer of compound ί is manufactured by injection molding, M d) except for the point in the injection Yue and is inhaled toward the m plate; then the e) branch of the melt injection person 3 will contain the drag The m-type closures of a / b and d / e are within the range of ιl to m. As is more preferred, the big 2 mm is called ih > then this mm η] η has the density-ίο- This paper size is applicable Chinese g family standard (CNS > f 4 specifications (2 丨 0X297 public daughter) (please read the precautions before you fill in this page) k.. 訂 定 _ 19370 A6 B6 V. Explanation (〕) 0. 0 4 0 g / cm3. Foam particles with a particle diameter of 3 mm • Filled in a ϋ 屘 屘 container under a pressure of 1.5 bar, close the model and pass the 3.5 steam to the steam tank 6 seconds water cooling model and the model Open and pull out the molded product. Spring Example 3 Its procedure (W is similar to the procedure of Spring Example 2, but e) except for the polypropylene layer, and the body flow index (2 3 0 ° C · 2 · 16 kg) = 1 0 g / min, reinforced with 30% by weight of non-oriented glass payment seats and manufactured by compression molding method 5 (please read the considerations of the plan first and then fill in this page) -Subscribe.-;,?郎 屮 九 #il,-^ xr Workers and Consumers iv: ft 卬 ^ 11 This paper is used again and again with China® 戂 i iMCNS) A 4 specifications (210X297 public daughter)

Claims (1)

2193^0 A7 B7 C7 D7 六,申請專利範’面 範 利層 專間 請中 申解 如熔 成含。 形包e) 接法與 熔方C) 相種、 互此a) 並及層 脹,於 膨(c)接 其層熔 使之其 M j義將 熱定時 加所同 子項並 粒 ld) 中第與 間圍 b ..................................ί ..............St..............................ίτ.........; .................^ (請先閱讀背。之注意事項再填荈本页) 經濟部中央標準局印裝 肀4(210X297 公沒) •,A7 止JB7 C7 D7 六 绥濟部中央揉準局印製 、中請專利範® 219370 L ~種吸收《擊丙烯聚合物複合模製物,包含 a · 厚度自〇. 5至10毫米之一層,此層包含熔點自130至 1 6 5 ° C之丙烯聚合物, b. 厚度自0 . 05至0 . 5奄米之一中間層,此層包含K熔 點自100至135t:且含有以重量計,85至95%丙烯, 2至10%乙烯及2至8%C4-Ce-ct -烯烴之三聚物 '身基材之熱熔融黏合劑, c ·-厚度自3至200毫米k密度自0.015至0..1公克/厘米 « > · ·" 3之一泡沬層,此泡沬層係Μ具有溶點自125至' 155吖之丙烯共聚物為基材, d . 厚度自0.05至0.5奄米之一中間層,此層包含Μ熔 點自100至135Ό且含有Μ重量計,85至95%丙烯, 2至10%乙烯及2至8%C4-Ce-a -烯烴之三聚物 為基材之熱熔融黏合劑· e. 厚度自0.5至10毫米之一層,此層包含熔點自130至 165°C之丙烯聚合物, 其中上述三聚物之層b)和d)之熔點比上述丙烯共聚物之 層c)的熔點至少低5t:。 2. —種製造如申請專利範圍第1項之丙烯聚合物複合模製 物之方劈,此種方法包含,於非K氣密方式關閉之横型 中,用具有2至8奄米平/均'直徑v Μ丙烯共聚物為主之泡 沫粒子,填充於配合模型壁形狀之如申請專射範圃第1 項所定義之曆a)和b)與如申請專$範圍第1項所定義之 層d)和e)之間的空間,並藉由引進蒸汽或熱空氣將此空 f 4 (210X297 公廣) (請先閱讀背面之注意事項再填奪本頁)2193 ^ 0 A7 B7 C7 D7 Sixth, apply for a patent ’s standard Fanli floor Special room Please apply in the case of melting into. The shape of the package e) is connected with the melt side C), and the a) is combined with the layer expansion. When the expansion (c) is connected to the layer fusion to make its M j meaning, the heat is added to the same sub-term and the grain is combined (ld) Zhongdi and Jianwei b ............................ ί ......... ..... St ........................ ίτ .........; ... .............. ^ (Please read the back first. Please pay attention to the matter before filling out this page) Printed by the Central Bureau of Standards of the Ministry of Economic Affairs 4 (210X297 public) •, A7 to JB7 C7 D7 Printed by the Central Squashing Bureau of the Ministry of Economic Affairs of Liusui, Zhongyou Patent Fan® 219370 L ~ a kind of absorbing propylene polymer composite molded product, including a layer with a thickness from 0.5 to 10 mm, which contains a melting point Propylene polymer from 130 to 165 ° C, b. An intermediate layer with a thickness from 0.05 to 0.5 mm, this layer contains K melting point from 100 to 135t: and contains 85 to 95 by weight, % Propylene, 2 to 10% ethylene and 2 to 8% C4-Ce-ct-olefin terpolymer 'hot melt adhesive of the base material, c ·-thickness from 3 to 200 mm k density from 0.015 to 0. .1 g / cm «> · " 3 one foam layer, this foam layer system M has a melting point from 125 '155 acryl propylene copolymer is the substrate, d. An intermediate layer with a thickness from 0.05 to 0.5 mm, this layer contains Μ melting point from 100 to 135Ό and contains Μ weight, 85 to 95% propylene, 2 to 10% Ethylene and 2 to 8% C4-Ce-a-olefin terpolymer as a hot melt adhesive for the substrate · e. A layer with a thickness from 0.5 to 10 mm, this layer contains propylene polymerization with a melting point from 130 to 165 ° C Wherein the melting points of the above terpolymer layers b) and d) are at least 5t lower than the melting point of the above propylene copolymer layer c): 2. A square split for manufacturing a propylene polymer composite molded article such as item 1 of the patent application scope. This method includes, in a horizontal type closed in a non-K airtight manner, with a range of 2 to 8 m² / average 'Diameter v Μ propylene copolymer-based foam particles, filled with the shape of the wall of the model as defined in the application of the first shot of the nursery school as defined in the first calendar a) and b) and as specified in the application of the scope of $ 1 The space between floors d) and e), and by introducing steam or hot air f 4 (210X297 public broadcasting) (please read the precautions on the back before filling this page)
TW80110088A 1991-12-24 1991-12-24 TW219370B (en)

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