TW214567B - - Google Patents

Description

214561 Λ 6 Η 6 V. Description of the invention (丄) The present invention is sanitary and self-evident. in. Such as the adjustment of hydrogel type, for example, repeatedly musk. The foaming property of the soap bar of the stick and the foaming The foaming value of the soap in the soap is the soap bar containing the polyhydroxy fatty acid amide or the soap bar for beauty. Especially for the best people (that is, fragrant and unappealing in the past, users use it to clean soap when using it. However, the manufacturer and state of the art, especially household toilets are generally beautiful except for the method of storage. No The quality is not high enough · Out of view • This will reduce the broken bar of soap. In addition, the adjustment of the negative street attack and the use of the soap bar " when stored with low iodine is known to be stored in the use Causes it to be used for a standard soap. Reduce the value of T " fat will break) adjustment * soap bar soap bar can be used with soap in the water soap dish. However, the cleansing bar contains soap bar and the content of fatty acid Soaps, many of them are still made with improper contact, etc. The wave of the bar, the water volume of the soap bar is reduced to another cost. However, there will be many problems in the year that the soap will be formed / under the environment * Then this bar Fees. Reducing low water content and having high reduction waste. 1. Method and system • Low deficiency is not what you want πϋ In back flT; Attention item Pu. Η Ministry of Economics Youyang · > ίοκχ 工 消 伢 Cooperative Seal ¾., The phase of soap is low according to the Timki method. ΜStoragesaponamine does not affect the degree of storage. It is acid-resistant, hard and fatty, and fatty acids are more wave-like. It is sticky fat and stick-negative grease soap. It has suitable foaming and dissolving hydroxyl groups to reduce the printing surface, and the water is low. It ’s a combination of decay and pollution. It ’s more economical to find a good match. You ca n’t find a low-ammonium compound. You can use it to describe what you ’re doing. However, the effect of raising enough fat to pour is still good enough to get enough hydration, soapy cleansing. If you gather it, you can use it to clean the eyes and use the stick to make the square stick. Because the fee is a wave of soap to make the square stick. The soap sensation will reduce the bubble to the stated statement, and it will be free from the low-sensitivity hair loss. The continuous crack can be sanded and smashed. This paper is added to the 5fc scale. The medium is a sleepy home sample iMCNS) 1M specifications (2 丨 0x297 public; ¢) 214567 5. Description of the invention (2) First 1 «in the back notes and then 14-page. Furthermore, polyhydroxy fatty acid acetamide can increase foaming and reduce _ rupture. These and other objects can be obtained by thinning the present invention, as can be understood from the following disclosure. Fang Zhubeilu 4-4-1967 issued to D. T. Hooker US Patent No. 3312627 mentioned that when the soap bar is wet, the soap bar is wasted, and the problem of dissolution or chopping is encountered. Hooker describes the sticks containing lithium soaps of certain fatty acids. He believes that these lithium soaps are unique to the invention of Line S (Ju 8) • Line 20. In a nutshell: Hooker also describes various types of non-ionic surfactants and non-ionic foaming agents. This may include polyhydroxyglyceramines of the formula RC (0) N1T (R2) * where RC (0) Contains about 10 to about 14½ carbon atoms, and 1URR2 is ^ 1 or (: 1-Ce alkyl, the alkyl group contains about 2 to about 7 缌 carbon atoms and 2 to about 6 substituted hydrocarbyl male Number (Tangerine 4 * 11 a 28 lines). In this bubble-sister serving, Hooke "proposed stearic N-glucosamine and laurel N — methylglucosamine. See also 4-4- U.S. Patent No. 3312626 issued to D, T. Hooker in 1967. The following references may be helpful to the formulator in synthesizing the polyhydroxy fatty acid glycosamine surfactant used here: U.S. Patent Nos. 2016962; 1985424; 2703798; 2993887; EP-A 285768; can also participate in the cooperation between the Ministry of Economic Affairs and Yang Yongjun / {ΟΗ 工 消 坨 Cooperation Du Yin ¾. Photo H. Kelkenberg at Tenside Surfactants Detergents 25 (1988) 8-13; and Biochem J. 1982, Vol . 207 pp 363-366. This technology has described various polyhydroxy fatty acid amines. For example, N — acetyl group> N — methyl glucosamine has been developed by J. y. Goodby, [.1. A. Marcus, SB domestic standard (CNS) T4 regulation (210X297 public goods) for the use of table paper scales 214567 Λ 6 116 Ministry of Economic Affairs 揮 央 梂 准 x; ts 工 消 作 ^ 作 社 印 | 4. 5, Description of the invention () 3 E-Chin and P ... L. Finn revealed in ♦ The Thermotropic Liquid -Crystal 1 in Properties of S obe S traihgt Chain Carbohydnate Amph i ph i 1 es ^ · Liquid Crystals · 1988, Volume 3, Ho. 11, pp 1569-1581, and by _ Muller-Fahrnow, V, Zabel, M. Steifa, and R. Hilgenfeld are shown in * Molecular and Crystal Structure of a Nonionic Detergent · · N ο na η o y1- N-methylglucanide, * (non-ionic cleaning agent: the molecular and crystal structure of nona-N-methylglucosamine), J. Chbm. Soc. Chem Coi ^ un 1986, pp 1573-1574. The use of N-synthetic polyphenylene amine surfactants has recently been of considerable interest in biochemistry, such as the dissociation of biofilms. For example, see D—Glucose-N-methyl-alkanamide compound • One of a new class of nonionic cleaners used in biochemical membranes " Biochea. J. (1982), Vo 1Γ-207 · ρρ 363-366 · J. Ε. Κ. Hildreth 0 The use of N-alkyl glucosamine in detergent detergents has also been discussed. 12.20.1960 U.S. Patent No. 2965576 issued to ER Wilson and 2-18-1959 Announcement · GB Patent 809060 transferred to James Hedley & Co. Ltd. A detergent composition that can contain N-methylglucamide surfactants. These surfactants are added as low-temperature foam to increase the viscosity. ◊ These ib compounds include N of higher linear fatty acids with 10-14 carbon atoms — Acryl. These compositions may also contain auxiliary rib materials such as alkali metal phosphates, alkali gold tartrate silicic acid II · sulfates and carbonates. In general, it is also pointed out that the properties of its constituents can be assigned (please read the back side first ^ .item #fill 5: -Watt) Binding · Binding-Line · This paper 5 good-scale side use in a Η 家 标兵 (CNS ) T4 specifications (210 297 public goods) 5 Λ 6 Π 6 214567 5. Description of the invention (4) (please read the back first. And note * 亊 项 # JaifI ** page) Other ingredients may also be included in the composition Among them, such as fluorescent dyes, whitening agents, perfumes, etc. US Patent No. 2703798 issued to AM Schwartz in 3-8-1955 is the condensation reaction of aliphatic esters containing N-alkyl glucosamine and fatty acids The product is a water-based cleaner. The product of this reaction is said to be used in water-based cleaner compositions without further purification. It is also known as the US Patent No. 9 -13- 1 955 issued to AM Schwartz 2717894 discloses the preparation of sulfated glucosamine sulfate. 12-22-1983 Announcement of J. Hildreth PCT International Application WO 83/04412 is an amphiphilic compound containing a polyhydroxy fatty acid group and is said to be used for various purposes including Surfactants for cosmetics, medicines, shampoos, lotions and eye sounds / and emulsifiers and ingredients for medicines Powders, and used in biochemistry to dissolve membranes, whole cells, or other groups of samples, and to prepare americium liposomes. The compounds shown here include the formula R'C0N (R) CH2R "and R" C0N (R) IT compounds, where R is hydrogen or an organic group, R 'is an aliphatic hydrocarbon group of at least 3 carbon atoms, R " is aldose residue 0 10-1 2-1988 Published H. Kelkenbers European Patent No. 0285768 It is about the use of N-polyhydroxyalkyl fatty acid amine as a thickening agent in an aqueous detergent system. Inclusions include the amides of formula Ι ^ (:( 0) Ν () () Ι? 2, where R 1 ^ C 1-CT r (preferably Cv- C1V) alkyl, hydrogen, (^ -Cie (preferably (^-(: 〇) alkyl or alkylene oxide, X is 4 to 7 carbon atoms Polyhydrocarbon alkyls, such as N-methyl coconut fatty acid filled amines. The concentrated properties of amides are shown in the liquid surfactants containing alkane sulfonates. This paper is used on the scale of this paper (CNS 8 in China) ) TM specification (210X297) 214567 Λ 6 Η 6 5. Description of the invention (5) Particularly useful · Surfactant · Half ester salt • And fatty alcohol polyglycol ether Although the aqueous interface such as alkylaryl Fatty alcohol ether sulfonate, alkylphenol polydipropylene-polyethylene oxide mixed polyhydrocarbon sulfonate / N activator shampoo succinic acid purinate purportedly with 5-2-1961 issued Kan contains urea, a Methyl coconut fat formula. In addition to having excellent skin, give Boettner et al. Sodium lauryl sulfate active agent system ester · olefin sulfonate, and non-ionic alcohol ether, fatty compounds and so on. List Fatty acid glucose glucoside thick property · tolerance characteristics. United States Anion Interface

May contain other anionic acid esters * sulfosuccinic acid surfactants such as fatty acid polyglycol esters * polyoxygen is exemplified by alkylamine / nonionic interface N-polyhydroxyalkyl fatty acids No. 2982737 series Active agent • N-alkyl gluconamide non-ionic surfactant selected from N-methyl, N-sorbosyl lauramide and N-methyl, N-sorbosyltetradecylamide Qing Ministry of Economy t Central Standard} h A x 消 1ί He Du Yin cleanser stick. Others include the HW announced in the 12-20-1973 interface of glucosamine. Except for the inclusion of one or more phosphates, multivalent mixtures, and IUC (0) N (R2) CH2 (CH0H) improvements, of which 1 is (: 1 1 (: 3 alkane 3 or 4. Add N-acryl-based poly 4-4-1 9 7 2 awarded to H. W. E c series on the inclusion of at least one boundary chick and non-ionic surfactant • It has been disclosed in, for example, Eckert et al., DT 2226872, the patented surfactant and builder salt (selected from polymeric bases) for washing, and by adding „CH2〇H N- 醢 基 聚 hydroxy Alkyl plus M group, 1 to 2 is (^. A C22 alkyl group, η is a hydroxyalkylamine used as a dirt floating agent 3 Kert et al., US Erli No. 3 6 5 4 1 6 6 surfactant One is selected from the group consisting of Yin yin, two agents, and a fabric softener

RiN (Z) C (0) R2—where 1 is (: 1〇—Cw alkane ;, R2 ^ C-, — C: It is used on the paper side of the standard Η Η 家 《准 (CNS) > P4 regulations ( 210x207 male dragon) 214567 Λ 6 It 6 V. Description of the invention (6) Alkyl · 1 ^ and R2 have a total carbon number of 23 to 39, and Z is a polyhydroxyalkyl may be -CH2 (CHOH) · ί: Η2〇Η · The cleaning agent of its hydroxyalkyl compound was awarded to H. Moller 5-3-1977 for the treatment of skin care and maintenance. The base of the formula iUH (R) CH (CHOH) • Hydroxy lower alkane Group or aminoalkane, but the two can not be the same as Η, R2 is 4-26-1963 issued to Commerci French Patent No. 1360018 system is stable and does not polymerize; where R is | Ra is hydrogen or lower alkyl, G is the middle m is the thing 0, etc. * Contains the compound group and the CH2〇H a 1 Sol to add at least 5 3 or 4 N-alkyl poly U.S. Patent No. 4021539 N-polyhydroxyalkylamine , Its package, where 1U is Η, lower alkane cyclic amino alkyl, R is the same as 1 or C00H. Vents Corporation formula RC (0) N (Ri) G makes formaldehyde 7 carboxylic acid carbon atoms function carbon Atomic glycitol group, first read 1¾ back to the main Item fb 2-29-1968 was issued to A. Heins-German Patent No. 1261861 is a glucosamine derivative of the formula fUnUdUd which can be used as a wetting and dispersing agent where R is a sugar residue of glucosamine · 1 ^ is (: 10—C2. Alkyl-C5 alkyl. It is the economic quasi-central bureau Π 工 Consumer fri, 'made by the agency. 2-1 5-1 9 5 6 Announcement, transfer A11 As P 〇wder C 〇mpany G. B. Patent No. 745036 is aimed at heterocyclic amide and its carboxylic acid ester. It is said to be used as a chemical intermediate * emulsifier • wetting and dispersing agent, cleaning agent , Fabric softener, etc. This compound is represented by the formula N (R) (R t) C (0) R 2, where R is the residue of anhydrous hexane pentazyme or its carboxylic acid ester, which is a monovalent hydrocarbon group,- C (0) R2 .¾ The carboxylic acid group containing 2 to 25 carbon atoms. The yin yin make-up paper size is based on the Chinese standard (CNS) IM standard (210x297 public Λ) 8 Λ 6 Π 6 214561 V. Description of the invention (7) (Please read the note first and then fill in f fliw. The present invention covers the bar soap bar sister composition • contains: a. About 75 to 85% by weight of substantial water solubility • Non-lithium fatty acid soap; b. About 1% by weight Polyhydroxy fatty acid acetamide surfactant; and c. The rest is generally water and a small amount of optional ingredients such as fragrances, preservatives, etc. A typical soap bar here contains about 75 to about 85% by weight of sodium, potassium, or C12-cie soap in the form of or alkanoate salt; about 1 to about 10% by weight of polyamine fatty acid acetamide surfactant; and About 8 to about 12% by weight of water. The preferred polyhydroxy fatty acid acetamide surfactant is C12-Clealkyl-based glucosamine, and the preferred fatty acid soap contains mixed sodium salt of C12-cle 1¾ g. The preferred bar according to the invention is characterized by a hardness of less than 3, and more preferably less than 2 (M, 'dry " (or, as measured by penetrant test). R «The best soap bars here include: a · About 75 to 85%, with an IV value iT of about 25 to about 35; b. About 3% of C12-C18N-methyl glucosamine surfactant

I C. About 0.3 to 0.5% of NaCl; and d. About 10% of water, and the rest includes a small amount of ingredients of general soap bars. 3 The stick's intensity is about 2 to about 2.5. By the tenth standard of the ministry ^ -XJn work dissipation {-,-made Du Yin ¾ The present invention also covers improved water solubility including Qu Xiao. Non-g purpose κ g ^ 棹 (where the soap bar contains about 8 to about 1 2 Φ 銀 ％ 的 水) @@ 胃 but it has a harmful effect on the blistering feces and the stick breaks during storage or use _ & _ j, its legal system is modulated; it should include: a. About 8 to about 12% of the water; the paper is used in the standard a S Song Pun Zhun (CNS) 悀 4 regulations (210x297 g) and Λ 6 116 214567 5. Description of the invention (8) b. about 75 to About 85% by weight of substantially water-soluble, non-lithium fatty acid-derived soap • The soap preferably has an iodine value in the range of 25 to 35. c. about 1 to about 10% by weight of polyhydroxy fatty acid amide surfactant; d. about 0.2 to about 0.6 wt% electrolyte; e. K-general processing technology to form the raw material into a rod shape. The soap bar here may also contain synthetic ("Syndet") non-soap, non-polyhydroxy fatty acid acetamide, and detergent, depending on the meaning of the formulator, generally containing about 0 to about 30% of the stick. The percentages, proportions and parts used herein are all by weight unless otherwise stated. The patents and articles mentioned here are hereby incorporated by reference. The details of the thief are as follows:. The soap bar of the present invention is prepared by using well-known and standard methods and equipment in the industry, and the forming operation of the castellated shape is not part of the present invention. However, for the sake of cooperation, the following description is provided by way of illustration, not by way of limiting the operation of the present invention with soap bars. Mix 1δ9 lbs (85-6 kg) of bovine fatty acid, 27 lbs (12.2 kg) of stearic acid, and 54 lbs (24.4 kg) of coconut fatty acid at a temperature of 120T (49 ℃) in, and search engines. with. This machine is equipped with the standard Ye Bin Ministry of Economic Affairs t 戀 揀 A industrial consumption " cooperation Du Yin% Μ mixer and recirculation loop to further improve the mixing: the blended fatty acid is then neutralized with MaOH solution . It takes about 84 pounds (38kg) of 5% solution to be completely neutralized: before the alkali is added. Turn over the pound (〇 Q5kg) (

NaCl) was added to the solution. During the neutralization process, the temperature rises to 18〇-i9〇τ (8 2-88 ¾). After the neutralization is completed, 9.7 lb (4.4 U) portions of the final tallow alkyl μ-this paper For standard scale use, a B home sample standard (CNS), 4-gauge tft (210x29 · 丨 commercial product) Λ 6 It 6 21456 * 7 V. Description of the invention (9) Adding methyl glucosamine to the neutralizer · maintenance Stir vigorously to obtain good mixing. The temperature is maintained at about 180TF (82 =). After the bovine alkyl N-methylglucamine is added, mixing for about 15 minutes is sufficient to obtain a good mix. The resulting mixture contains approximately 30% moisture. Then, the mixture was dried to 10.5% moisture in the vacuum rapid drying tart under the following operating conditions. The temperature before the heat exchanger = 180T (82 ^ 0) The temperature after the heat exchange = 220 times (104t :) The temperature of the dried product strip = 120T (49¾) The vacuum chamber strength = 40maiHg. The dried castellated product strip is then used the following barley The quasi-program equipment is processed into rods: pre-grinding, mixer, grinding, lateral pressing, and die punching. The rods manufactured in this way can be shown by the penetrometer test 1 described later-hardness level (w dry is about 2 〇 The following steps can be used to measure the physical parameters of the rod of the present invention. The obituary cooperative printed a hardness test step box: the hardness of the sticks prepared here can be measured by the following steps. Generally, in the first test listed (test 1), the hardness value of the stick is less than 3, preferably low Yu 2 has a good consumer value, 'acceptable infiltration, etc. The first test listed includes, dry, stick, and needle penetration, that is, the stick has about 10% moisture in addition to itself , Do not connect with other moisture ^ in another 1 test (test 2, also listed below). Wet the salary first: in the second test step. Use, ball penetration, and here In the class test, the wear score should be lower than 1 · 2 5 and preferably lower than 1 · 0 ^ Luan 1 帄 1st floor wear temptation I 』Yiben paper-scale side-by-side use of the Chinese SS Jiatbi (CNS) A 4 Regulations (210x297 g) Λ 6 η 6 214561 V. Description of the invention (10) Equipment: ——Precision penetrometer 1/10 mm scale instrument ^ 〇〇 ^ 11-Meter 538 Fisher Scie ntific) ——Cone Penetration Meter (12.79kg) --230,6g Weight ——Kodak Timer Method: ——Place the stick on the wooden block and penetrate the cone cone. Cover the stick with tissue paper. -Lower the Jin Yi penetrating needle until the tip of the dimension touches the surface of the paper (Place the paper between the rod and the dimension, and lower the dimension until the point where the paper can move without tearing). — ——Remove the paper ——The weight at the top of the dimension axis is 230.66g ——Press down the cone release lever; hold for 10 seconds, release; raise the arm; move to a new point on the surface of the rod; repeat this procedure. -Repeat three times to form a triangle with three penetration points on the rod. ——Press the top shaft button to get the pointer reading of penetrometer depth scale = 1 / 10mm. One handicap will be the addition of three penetrations-divide by 3 to get the average penetration number. Then divide Μ 10 to get the reading of m | and get the hardness value (m). Test 2 ball test score credit / 1 00 Ml · Smudged and privately-used standard-aside home standard (CNS) specifications (210x297 g) and first mi in back-to-back / X meaning fb 塡 Μ 1 2 V. Description of the invention (13_) Equipment: Method: Λ 6 Η 6 precision penetrometer 1/10 mm scale (Model 1 — Meter 538 Fisher Scientific) Ball penetrometer (11.40g) 300. 6g weight A petri dish, with an inner diameter of 90 mm and a depth of 22 mm. Standard plastic lift (soap dish form; stick just touched water). Measuring cylinder or dispensing bottle. ih-first Ml in the back of the note Item ΪΤMinistry of Economics, Central Standards: 工 工 消 作 合作社 印 rt'14 1. Place the rod in the plastic center of the petri dish. —Put the stick into 80? 80 (80 T / 80% relative humidity) room, and add 100 m 1 distilled water. Store the rod in (overnight) δ 0/80 room. Take the stick back to the laboratory in the morning the next morning. Remove the stick gently from the petri dish and place the wet side up under the penetrometer ball. One lowers the metal penetration ball so that it just touches the surface of the rod. —When the ball has a curved rod of 300.6g at the top of the shaft * Fix it firmly and measure at the same time. Release the lever for 10 seconds, release it, raise the ball arm, wipe off the excess gel, move the ball to a new point on the surface of the stick, and repeat the procedure of pressing down the ball. Repeat 3 times. When bending the bar, when the bar is iii three-pointed on the arc, make an angle. Press the top uranium button to get the penetration depth scale = 1/1 0 mm. ) TM regulation (2 丨 0 father 297 gong) 1 21.4561 Λ 6 It 6 V. Description of the invention (12) It is used to draw the composition of the composition. Pointer reading. This handicap is a plus for penetration. -Divide Μ 3 Μ to get the average penetrometer reading. Then divide by 10 to get the millimeter, which is the hardness (mm). The ingredients for practicing the present invention are all known substances, and neither the ingredients themselves nor the method of making them form part of the present invention. On the contrary, it is the combination of these to provide the compositions disclosed herein to achieve the desired results with M cost. However, in order to assist the dispenser, the ingredients are described

Tk Λ See ifi back WJ it * Item η Wood Soap 1 The soap component here is a well-known commodity C12 — Cie fatty acid food-soluble water-soluble salt, alcohol amine salt, etc. Sodium salt, potash | Three cases are not limiting. (Non-water-soluble soaps, calcium and magnesium soaps, are prepared without the use of the synthetic method of S of the present invention, or, more generally, obtained by alkaline hydrolysis of fat butter> coconut oil, etc. Fatty acids are representative In addition, the limit of typical soaps, including fatty acids, is generally. These toilets contain alkali, ammonium, ethanolamine, amines and other salts are all mentioned especially lithium soap • and insoluble soap (quote): fatty acids can be combined with oils such as Lard, palm rest oil, coconut, tallow, and palm rest fat-based fatty acid source. From all kinds of Jiakejiang / caso, the soap is oily, but the V is sour, this value is I fatty soap, iodine and low fat mixed in the middle and low, and those who think about it are buried, good and know Chang Hu is expected to have a reason to change the chain. Soap with skill, source of production, if it is available, it can be used as an example. Cheers. The If 'small material may be prepared with R and 35 at a time, the prepared mixture is reduced and the acid is acidic to M value fat, the fat is 25% lower, V fat Sizhi is about the original I. The meaning of the child is in glycosides揶 之 生 有 valuable fat / 訂 載>: Fatty acid acid source soap I The original fat is adjusted to its K1 low-hardness clean paper size. The medium NH National Brown Standard (CNS) T4mtM2 丨 0x297 male and ) V. Description of the invention The amount of water is preferably 15¾ for the bar here. * The chain length of fatty acid soaps can be used according to the general regulations. This quality is generally used for soaps. It is cheaper and more common. It is better. quasi). A variety of options are available: balsamic agent added to the soap and the water-soluble inorganic salt, only * 2% chlorinated water content to about 10% by weight will be adjusted according to the formulation, used in the stick. The stick can be selected in the stick to make the saponification selectivity, and the toxicity can be as exemplified by alkali gold, potassium, sodium sulfate and preferably account for about A 6 η 6 at least about 8%, and generally about 8 to about (M is the weight of the rod) The blending and user-acceptable softness of the stick, the amount of fatty acid polyhydroxy fatty acid amide, etc. depend on. Yes, but preferably contains electrolyte. Electrolysis becomes a form generally called " net phase. It is commendable with the formulation, but generally accepted electrolytes include various organic or halide • sulfate, phosphate, etc. These non-limiting mentions are: sodium chloride (, sodium phosphate, etc.) Generally, the electrolyte does not need 0.2 to about 0.6% (the weight of the stick is used as an ingredient-the stick here can contain soap bars as needed, generally used Other ingredients. Various ingredients that can be mentioned by way of example and not by way of limitation, including bait; opacifiers, pearl fluorescent agents; antibacterial agents; dyes; '' super like glycerin; abrasives such as pumice; etc. This ingredient Generally, it can be taken as a great reading ifi back, and the note item is then 3 wooden pages, the Ministry of Economic Affairs, Shiyang Daping, and persuaded the work to be eliminated. : ^ W ^ -including surplus · thing · 1 Ding Bao Xiu. 1 and iisstw. ^ The formation and the basic amine h mesh use ¾ B, i choose the hydroxyl group C11 can be out of favor Of., Code test adjustment first class 5_ >,# 依 外 笨 | 子 可. Another base is 2 separate and ¾ kinds of alkane C1 properties, the amount is one, as the heavy alcohol of S-, know 15 Nao 3 agent ester heat about C1 oleic acid is a phosphorous agent everywhere. These two sex-based agents are used in C1 alkanes. For example, the agent is 80% off. It is not a C! Hebifu Zhang standard general purpose SB iUiiMCHS) T4 regulation (210x297 public and ) Λ 6 Η 6 Fifth, the description of the invention i first 'read iti back-and the / X * market item-Fy Muta standard listed article. If used, this kind of synthetic cleaning agent generally accounts for about 2 to about 15% of the weight of the stick »Poly These substances are active in the lipid amides and active cocoons, and their various synthetic methods are also known in the literature (see, for example, the references cited in the background art above). However, in order to further help the formulation The following provides an example of a simple but non-limiting synthesis of the polyhydroxy fatty acid amide surfactant used herein. The preparation reaction of the polyhydroxy amine used to prepare the polyhydroxy fatty acid amide surfactant used herein can be referred to as " R-1 " reaction, and the formation of MN-methylglucamine is explained, where R1 is methyl. CH3NH2 (XS) 1ΤΚΗ2 + glucose- ^ adduct + Η2〇 catalyst

Adduct + Η2- =? RXN (H) CHa (CHOH) 4CH2〇HR — 1 anti-imaginary substance used in the reaction, the solvent and the catalyst are all known substances that can usually be obtained from various sources, the following It is a non-limiting example of substances available in wood. Amine is a useful amine in the R-1 reaction herein is one of the amines of the formula R 1 Η 丨 丨 2, wherein R 1 is for example alkyl, especially C 1 -C * alkyl, or C i-C4 Hydroxyalkanes: Pycnogenol contains methyl, ethyl acetone, propylene M, hydroxyethyl, etc. ◊ Non-limiting examples of amines available in this article include amaranth, ethyl estromine 'propylene® paper? Good size side use 1 214¾ ^ V. Description of the invention (15) Amine, butylamine, 2-hydroxypropylamine, 2-hydroxyethylamine; methylamine is preferred. All such amines are sometimes referred to as " Ν-alkylamines ". The polysaccharide 詈 一 R-1 reaction raw sugar or also contains glucose, including reducing sugar encapsulated sugar, galactose, lactose medium hydrogen and other catalysts among them * hydrogenation reaction alloy, etc., a joint Louis in silicon oxide county Taxi solvent

When R is used as a solvent, depending on the situation, the amine and hydroxyethylamine in the hydrogenamine-sugar adduct; raw sugar derivatives (preferred), sugar and its mixed reaction catalyst nickel (preferred). This article is better on the micro-catalyst carrier on the carrier. One of the methods. This excess amine reaction can use alcohol as the available solvent and methylamine as the preferred source of polyhydroxy materials. To be more specific, this article is suitable for maltose, fructose, maltose, and wood. Can be used in the R-1 reaction included here, platinum, palladium, osmium, cobalt, tungsten, various catalysts including, and the joint catalyst G49B " Grain Hi catalyst, which can be seen from KFC, the formation system of adducts The use of excess amine is also used in the subsequent reaction with hydrogen. Such as methanol instead of amine. The typical examples of Xuan Cheng in this article include methylamine, ethyl is preferred; methylamine / water solvent can also be used

Tk Λ m Read back to the market item i Page as usual with pit tendon reaction plus plus I formed into plus al ο As in a piece of the article should be reversed from time to time ® should be reversed 1 Use-All R formed V 0 亦 ί In the 1 often reversible in the R can be fixed at a time when the temperature range of temperature and temperature should be longer than the opposite of the need to choose the V need to choose 60 degrees I apparent temperature should be less than 30 more than the reverse, Low, good, right, and left, when Ρ, often small, CC, in the reverse shape, one thing, plus i. £ Good, good examples are often better than through ear Ϊ. Rate 1 production: 30% to good 1 good: To 4 Dayo within the time sugar paper 5 moxibustion and another side of the use of Η sleep «Sample standard (210X297 public release) 214¾ ^ Λ 6 It 6 V. Description of invention) (please read the back first, and pay attention to the apple Outer Θ. Winter spike) The concentration of the substance in the amine solvent is in the range of 10%-60% (weight). The adduct formation can be carried out at atmospheric pressure or superatmospheric S (preferred). (b) Reaction with hydrogen The reaction with hydrogen can generally be carried out at a temperature of 50_1000psi and 40t-120¾, or at a temperature of 100-500psi and 50 ° C-90¾ for 0.1-35 hours, usually 0.5-8 Hours · Generally 1 to 3 hours. The adduct / solvent solution used in the hydrogenation reaction is generally in the range of 10% to 60% (by weight) soluble mass> (It should be understood that the choice of hydrogenation reaction conditions depends on the type of pressure device available to the formulator, Therefore, the above reaction conditions can be changed without departing from the invention). The amount of the hydrogenation catalyst is generally 1% to 40%, preferably about 2% to about 30% solids weight, which is calculated based on the weight of the catalyst in the batch process: the weight of the reducing sugar substitute. Of course, the continuous process can be carried out under a higher catalyst volume. The product of step (b > can be stripped by solvent / water • or by crystallization, crushed, or dried by an effective drying agent.%

Example T Weigh anhydrous glucose (36.00g; Aldrich Chemical Company) into a glass liner. Place this glass liner in a dry ice bath • Condensate methylamine gas (68.00 g, Matheson) into the glass liner. Then place the pad in a pan autoclave (500ml stain). The autoclave was heated to 50 t * and rocked at 600 pS nitrogen and 5 ° C for 5 hours to form an adduct (N-methyl uronic acid amine). The reaction was then cooled in a dry ice bath: the pressure Heater exhaust gas cooling. Join Ruan Niwan (50% of 7.2 s suspended in water, type W / 2, Aldrich Chemical Company): heat the invert under 500-600 psig bin gas To 5 0 C · and save it for 6 hours in a dry ice bath and use this paper as a standard for Chinese fraud (CNSl'fM regulations (2 Chuan X297 Gong and A) A 6 Η6 214561 V. Invention description 7) The reaction was cooled and vented and filled with nitrogen. The reaction solution was pressure-filtered with a Zeofluor extinguisher (ρτρε, 4 7 am · 0.5 μm filter) with a 4-inch Serry plastic 545 (Fisher Scientific Corporation) bed. Under nitrogen The filtrate was shrunk under the flow to obtain 8.4 white solid. The plastic filling of the plug was washed with about 300ml of water • and the water was removed on the rotary evaporator to obtain 18.77g of white solid. The two solids were analyzed as similar (90 ♦ Purity 'is analyzed by GC), so the two solids are combined, and the product is N-methylglucamine. With the vitreous outlet filter, the three-wheeled sowing mixer *, the outlet and inlet pipe and the mixing and heating autoclave of the Yuanhong plate, the method of Example 1 was repeated. The reagents and reaction conditions for preparing N-methylglucamine are as follows : 20% G 4 9 B catalyst (N ί / silica, combined catalyst) and 7 5 s glucose powder (Aldrich, Catalog No. 07605LW) in 15s are slurried in 160ml of methanol and pretreated with H2 1 hour (50t)-? Then, the mixture was cooled, and the methanol was removed under pressure. Μ 济 郎 十 央 榀 萍 · -Χ 消 汾 八 ： · 作 ：： 一 印 ¾ Cool the reactor to 5 1C Κ , And add 76®1 of liquid methylamine-heat the reaction mixture slowly in 250Psi hydrogen to 60 l within 46 minutes: and take a sample. Continue heating at 60 ° C for 20 minutes and take the sample at 2 ° C. Continue heating at 60 5C for 46 minutes (Sample 3), followed by heating at 60 for 17 minutes (Sample 4). The reaction mixture is cooked to 7 0; c 'for another 3 3 minutes (Sample 5). The conjecture time is 2.7 hours: The dry product is 93.2% N-methylglucamine (GC analysis). The polyhydroxyamine product of the aforementioned R-1 reaction is better than Gui Most of them have been removed as required, and can be used further in this paper. R- — 2 〃Reverse V. Description of the invention (18) Λ 6 Π 6 should be used in the formation of acylamine. Typical R in this article — 2 Acetylamine formation reaction can be described by adding K to the formation of the following lauryl N-methylglucosamine. Methanol R2COOMe + MeN (H) CH2 (CHOH) 4CH2〇H-, methoxy

R2C (0) N (Me) CHz (CH0H) 4CH20H + MeOH Please read the note on back \ fTj fi-event item wood 1 where R2 is C11H23. Therefore, the reaction for preparing polyhydroxy fatty acid acetamine surfactants includes dissolving the reverse amine} in the amine 'base, as the derivative is better than the original sugar {selection. Or should be anti-glycosamine · grape and glucose, for } It's better to make it more suitable than amine-based sugar to add sugar to make it more ^ ('agent should be β residual gold in the matter of adding (a) in the step of dissolving amine should be Hydrogen dissolves and dissolves the two amines in tb). The amount of I is over R and according to the water. The amount after removal is large and the medium is activated. Mixed into what should be obtained instead * (c) Agent · 'France Economic Langfang Fire Preservation Bureau Π.Ι- Consumer:. ≪ > ·· As a Du Yin ¾ 中 中 丨 S · ?, II The product is produced or amine age 4.UJ ί ί OH. Hydroxyl is more water than the public. No agent is dissolved. Μ Large hydroxy. The machine has the advantage of (c), and the next step is to make the agent of (d). Sexual activity 'time, the whole amine is completely finished, 0 b fat, fat and large hydroxy}, and the degree of polymerization becomes the opposite of the temperature and shape. When the anti 10 ester is about to be acidic, it should be acidic. "CCQ / t ** ---- Fat in sight and depression⑻ Use this standard to move to the right side and use the standard (CNS) IM standard Dai (210x297 public release) 2145 ^ Λ 6 It 6 5. Description of the invention (the solvent used in step (d). More specifically, this article The whole process of R-1 and R-2 reaction · The whole method (R-1 plus R-2) can be used to prepare polyhydroxy fatty acid amide surfactants of the following formula: 0 R1 provides

I

II IC-N-Z read B / J first, but it item is not. In the page format: R1 is Η, Ca-C4 hydrocarbon group, 2-hydroxyethyl. 2-hydroxyl or a mixture thereof, preferably Ci- "Alkyl, more preferably" or (: 2 alkane is preferably "alkyl (ie methyl); and" is "a C31 hydrocarbyl portion is a straight chain C7-Cie alkyl k alkenyl, more preferably a straight chain Ce-Ci7 dilute group, preferably a straight bond Cll — Cl ·? Comprehensive or dilute group; or a mixture thereof and Z is a linear hydrocarbon hydroxyhydrocarbon group portion having at least 3 hydroxyl groups directly connected to the bond, or Alkoxy derivatives (preferably ethoxylated or propoxylated) 3Z is preferably derived from the original amidation reaction • derived sugar; more preferably Z is a glycidyl moiety, suitable degenerated sugar Packages include fructose, maltose, lactulose, galactose, ganzose, and xylogenogen. High dextrose corn syrup, high fructose corn syrup, and sugar cane can be used: These corn syrups can be used as a mixture of sugar and sugar. The box knows that there is no need to exclude other suitable sources. Z is preferably selected from the group consisting of-(: 丨 丨:,-(c 丨 丨 0 11) n-C 丨丨 0 丨 I .-CH (CHzOH)-(CHOH) n-i_CH ^ OII '' -c Η 2-(C Η 0 H) 2 (C [i 0 (? 1) (CH 0 fl)-C Η 2 ϋ Η, where η is an integer of 3 S), and R 1 is H or in 'Like + m-or polycondensation, and order: propyl * base * the best • burnt base or compound · the polyoxygenated arsenic also contains grapes. As, and high production z material excluded to 5 ( Alkoxy fb This scale is used in the middle of a sleepy family (CNS) Gu Dai (210 χ 2 lJ 7 mm) 2145 ^ Λ 6 Η 6 5. Description of the invention (20) Economic Lang t ^^^^ ur -" ^ '-it: fLe ,,, t' ', u derivatives. The best one is the sugar group where η is 4, especially -CH 2 (C _) 4-C Η 2 0 Η In the formula (I), R1 may be, for example, N-methyl, N-ethyl, N-propyl, N-isopropyl, N-butyl, N-isobutyl, N-2—cyclyl Ethyl, or N 2 —hydroxypropyl. R 2 —CO— Ν < may be, for example, cocaamide, stearylamine, oleamide, lauramide, nutmegamide, decamide, palmetto. Acetylamine, tallow legs, etc. Z may be 1 -deoxyglucosyl I 2 -deoxyfructose, 1 -deoxymaltoglycan · 1 -deoxyglucose · 1 -deoxyhalf Glycosyl group, 1-deoxymannosyl group, 1-deoxy S-triose group, etc. The following reactants, catalysts and solvents can be conveniently used in the R-2 reaction in this article, and are only examples. Not restrictive. These substances are known and are usually available from various commercial sources. Each of the reactants, fatty acid esters, can be used in the R-2 reaction and contains single, di-, and tri-esters (ie, triglycerides). Methyl esters, yilong, etc. are quite suitable. The polyhydroxylamine reactant includes the reactant obtained from the above R-1 reaction, such as N-alkyl group and N-substituent with N-substituents such as CHa-, C2H5-, C3H7-, H0CH2CH2-, etc. —Hydroxyalkane S polyhydroxylamine, (the polyhydroxylamine obtained from the reaction of R-1 is preferably free from the most contaminated metal i (chemical residues, although there may be several PP m (eg 1-20 ppm), A mixture of Zhe mixture and polyhydroxylamine reactant can also be used. 3 Catalyst-R-2 The catalyst used in the reaction is biomass, such as alkanes (preferably), hydroxides (due to possible hydrolysis reactions) Therefore, it is less appropriate to use the Chinese standard as (4) ^ (210 father 297 public) winter page) 214¾67 Λ 6 Η 6 5. Description of the invention (2 1)), carbonic acid "alkane gas The compound should be produced by the mixture. * It should not be present. * R-concentration of the brewing reactant, ethyl fermentation • Propylene * 1 »3-Propyl fermentation is more—» R — eel, etc. More * such as a gas preparation * or It can be used in the form of enzyme fermentation up to the catalyst of about 5 qier-1 reaction enzyme, isopropyl malonylase and other good enzymes. 2 is a good reaction of sodium alkoxide, the use of Μι gold solvent The production is completely%. Alcohol can also be used in * Butyrase. The formazan is a chemical catalyst containing potassium oxide, etc. It is better to use the organic hydrogen solvent as a catalyst. ; Glycerol fermentation, 1 is better. Fermentation solvent dissolving_. Salty gold 18 medium which can also use solvent can be spawned. It is a compound of other medium.

Cl-Do not use M in response to in-situ reactants as for example, enzyme 2-malonate 2-4? Read the first 1ΚΙ and note that the formation of amines and colored bodies is minimized * to 1351C *-generally The reaction rate from about 401C to about Fanpu can be achieved in this order ~ Generally about 0.5-2 hours or even. It can tolerate a slightly higher residence in the continuous ore process-one is preferably to prepare the desired loot while smelting it: preferably at 1¾ • especially its up to 6 hours temperature * and can be reduced * and 1 mixture by-product product , 5 01C to medium-reaction batch type short stop, ester male use low 8〇r time-in-process time. The standard of the Ministry of Economic Affairs along the CX Gongxiao 1ί cooperative print ft'14 The following example will use Μ to illustrate the use of the N-1 polyhydroxyamine (most of Η2〇 has been removed) prepared by the above R-1 to conduct R-2 Reaction * but not intended to be limited by it. It is pointed out that the concentration range of the anti-substance and solvent in Example I can be referred to as * 70% concentrated (relative to the reactant) reaction mixture. This 70% concentrated mixture can provide good results-because the boxed polyhydroxy fatty acid acetamide product can be quickly obtained in high yield. Indeed • There are traces showing that the reaction is almost complete within 1 hour or less. The reaction mixture is in the 70% of this paper scale, and it is used in a small scale. A Β 家 訂 准 (CNS) Τ4 潙 悙 (210x297 gonglong) 23 Ministry of Economic Affairs 揮 央 i'A standard and A work price Φ for Du Yin 31 V. Invention Description (22) The concentration of the concentration tank makes it easy to handle. However, even better results can be obtained at 80% and 90% concentration, because the analytical data shows that at these higher concentrations, the formation of undesirable by-products is even less. At higher concentrations • The reaction system is a bit more difficult to handle and requires more efficient agitation (due to the consistency of the starting material) etc. • At least in the early stages of the reaction, the agitation should be more efficient. Once the reaction has proceeded to any significant degree • the viscosity of the reaction system will decrease and the ease of mixing will increase. In a round bottom bottle equipped with a condenser, a dry tube, and an argon coating • Combine the product of Example I (9.00 g, 0.0461 guar · N-methyl meglumine) with 0.2 2 g of anhydrous formaldehyde. The reaction enzyme and N-methylglucamine were heated to reflux for 15 minutes. Add sodium methoxide-(0.12 45g · 0.0023 mol, Aldrich Chemical Company) and methyl ester (10.18g · 0.0461 mol, Procter & Gamble CE 1270,-including Ci2-Cie fatty acid ester), and react Following reflux for 3 hours. Next, the formazan was removed under reduced calendar to obtain a substantially colorless white product. Because the sampling system reacts with a 30-minute gun before drying, sampling within 1 hour, 2 hours, and 3 hours, the yield cannot be reported. The dried samples were washed with cold formazan | filtered and dried under vacuum to obtain 10.99g of polyhydroxy fatty acid amide surfactant. The process for the synthesis of Acetamide at the concentration of 80% reactants is as follows. Using 84.87g fatty acid methyl ester (source: Procter & Gamble methyl ester CE 1270), 75g of N-methylglucamine of the above-mentioned buttercup example I, 1.04s sodium methoxide and 39.96g of formazan (about 20 of the reaction mixture first 15) ifi back 1¾ note items M paper? Fc scale side using the Chinese national 擒 哗 (CNS) A 4 specifications (2 丨 0x297 public A) 2 4 Λ 6 Π 6 V. Description of the invention ( 23) Reactor flow device. (Reflow). The reaction is mixed. Remove only suspected by-products. Fuli V synthesis step In the by-product mode, in the reaction_excess%) mixture. Apparatus and mechanical agitation, the quasi-methyl glucosamine / formazan heating. • The ester and sodium methoxide catalyst were added and the reaction was completed within 105 hours. 105.57g eJB analysis showed that the substance was present and no ring was detected. The method of Example IV was repeated for polyhydroxy fatty acid amines. It is completed by 30 minutes. At the beginning of the concentration of the other substance • The methanol may consist of a dry tube, condensed under stirring and will be N in S gas. After the solution reached the desired temperature, the compound was maintained at reflux for 6 hours. After formazan fermentation, the product is recovered as a by-product of heavy undesirable ester-ammonium amine, which is very low at a concentration of 90% of the reactant, and the reaction is roughly for example the reaction can be removed in the 70% reaction process and the reaction is completed first Read the notes on the back / 1/1% to make π ν a good product. In another mode-2 steps, a solvent such as 1.2-propanediol is used, and formazan is completely removed. The resulting surfactant / second fermentation mixture can be used directly as a detergent compound. The Ministry of Economic Affairs of the People's Republic of China advised XII to cooperate with Du Yin ¾ Reaction conditions involving amine solvents in step 1 The amine / water solvent mixture used can still be mentioned. In particular, the use of amine / water solvents to form a color will result in a relatively high content in the product, and the remaining R-supply R-1: almost no product yield separately from ethyl yeast, (99%) And 1, 2-the method of repeating Example I in malonylase (approximately dry dai) • and middle • used in R methods Yu Qing in this way reveals this method R —

Afterwards, it has been further determined that the extra advantage in the R reaction will be in the reaction product; and generally will not be used in this paper scale. It is used in 9 sleepy home standard (CNS) A 4 regulations (210x297 male dragon) 25 21456 * 7 Λ (5 Η 6 V. Description of the invention (24 2 reaction will lead to the formation of buried raw sugar. The reaction of R-1 in mixed amine / water solvent is as follows. Fenli W using the stirrer heater and the steps of Example I [ , 15g 649 B catalyst, grape seed powder (75g; Aldrich> and 160b1 formic enzymes are awarded, and MH2 treatment K removes the oxide on the surface of the catalyst. Formic enzyme is removed. Below 5 t: 80 ml of methylamine was added to the glucose / catalyst mixture, and 22b1 water was added at room temperature. The reaction mixture was heated to 70 1C in 34 minutes, and during the hydrogenation reaction, maintained at 70 T for 40 minutes. The reaction product was H2. / Methylamine solution is blown out of the reactor from the glass frit (removing the catalyst), and dry to produce N-methylglucamine product. When using mixed amine plant water solvent, amine (especially methyl Amine) and water weight ratio of about 10:11 to about 1: 1 Fanyuan. Almost no water (compared It is preferably less than about 1%, more preferably less than about 0.3% by weight of water). The R-1 reaction product can then be used in the R-2 reaction to prepare the above-mentioned polyhydroxy fatty acid acetamide. Although the foregoing disclosure is generally Kan in the preparation of N-methyl polyhydroxy amines such as N-methyl glucamine, and the use of fatty acid methyl esters to prepare fatty acid amide derivatives of the solvent auxiliary method, but it should be understood that various changes can be made. Therefore • Cannose sugar such as sugar, galactose, mannose, maltose and lactose, and sugar sources such as high dextrose corn syrup • high fructose corn syrup and high maltose corn syrup can be prepared by reaction of polyhydroxyamine substances (Glycosamine) 3 Similarly, a wide variety of fats and oils can be used in this article (triglycerine first iKl ifi, back-to-back market entry, table method, standard use, 8 national standard (CNS) Ή specification (210x297 male dragon) 26 214567 Λ 6 It 6 V. Description of the invention (251 esters) Take Meixuan oil * Peanuts can be used as a mild product, when the pre-preparation of the base amine agent is transferred, the initiator of malonylase is transferred to entrain the dissolved polyhydroxylamine in the initiator. High degree factor The following ingredients can be used to formulate the above-mentioned ingredients. Caihua oil and fish are used as the reaction temperature. Therefore, at this time, this part can be used or glycerin ° R — after removal, the agent and reaction can complete the non-fatty acid, exemplified Oil, beef tallow, vegetable method moderate and strip checks are more unique than the invention • In M help or its pre 2 methods in the case of for example) The reaction of glutamine is a large fatty acid ester. Fat · Lard · Seed oil Etc., or the triglyceride pieces used can be provided with long grains (such as h is not particularly useful. Polymerization When using triglycerol R-2 2 amine to form a single-+ + interface activity under 50¾ will be solid storage for several hours to start the original surfactant surfactant. Large-scale industrial processes such as fat safflower oil and its hardened esters come with a minimum amount of a) and hydroxy fatty oil esters or the formation of anti-use agents to produce chemical products can increase the last part of the production process to produce fat and oil, corn (hydrogenation source. By The by-product unsaturated fatty acid silver has a longer bond and it can help to suspend the ribs as long as it contains. According to the share of achievements such as soybean oil, oil, gourd oil, are all in the form of the required fatty acid polymer The reactive methyl ester of urinary amine is used as the reverse. Furthermore, the R-2 reaction has a small amount of self-reaction capacity that can be stored and formed in this way can be significantly increased, that is, an important consideration will explain the whole R-1 The above surfactants with R-2 method are used * to prepare the soap bar compound in the method of the present invention. Because of the various surfactants known to soap users. Fragrances and other optional ingredients can be used for these sisters as needed The products are all used in conventional amounts, so the examples are not limiting. The general composition of soap sticks is as follows: Civil paper scale side-use medium Η Β home-like standard (CNS) Τ4 regulations (210x297 male dragon) Read the back Λ first Law & Item Ι Mounted so Μ η 27 A6 B6 percent Η: f g 83.75 3.00 0.44 2.5 10.25 2l456 ,? remaining gas May said sash Day t V ^ Q - \ 81. 8 · · alkyl glucose fatty acid soap stuffed amine

NaCl Less Λ ingredients (spices, etc.) Water «Small amount of 70/10/20 mixture of tallow / stearic acid / sodium fatty acid sodium salt. «$ Mixed tallow alkyl N-methylglucamine prepared according to the method of Example B; tallow bond alkyl is in the C12-Cle function. This soap bar has a hardness value of less than 3.

Fenyong IX lowered the soap ft to 76% and increased the alkyl glucosamine (made according to Example IV) to 10% to modify the soap bar of Example VI. Thus, a softer soap bar is obtained. • m m y Increase the amount of soap to 85% and decrease the alkyl glucosamine surfactant to 2% to modify the soap bar of Example VI. Thus, a hard soap bar is obtained. This soap bar has a hardness value of less than 3. Window Li) Π Soap / Synthetic Cleaner »Mixed soap bars are as follows Ingredients Cellulose soap · syndet **-A 4 (210X297W hair) 斉 分 卜卜. (A a) 78.0 6.0

V. Description of the invention (A6 B6 Glucoamylamines HaCl / KC1 water 1 weight ft ratio) 8.0 0.38 Other (weight) mixed Na / K coconut oil soap

Mixed ballast acid Ci4 # Right read mixed C 12 —. C

Cie alkyl ester • sodium salt alkyl N-methyl glucosamine The preparation is shown in Example V above. This soap bar has a hardness value less than 3

9Q (Please read the precautions on the back before filling out this page).

C A 4 (210X 297 public)

Claims (1)

Μ 4 &, 4 5ΛΛ repair 7 7 7 ABC 1 A bar soap composition, comprising ⑻75 to 85% by weight of substantially water-soluble non-lithium fatty acid soap; 1g less than 1% by weight of polyhydroxy fatty acid acetamide interface activity 2. The rest includes the application of water root thump ⑻75 Up to 85% by weight and a small amount of optional ingredients. China's 1st bar soap compound * contains -C soap in the form of Na, K, Ammonium or Alkyl ammonium; (please read the note on the back and fill this page) 3. 4. 5. 6. 7. Printed by the Central Bureau of Economic Development of the Ministry of Economic Affairs (b > 1 to and (c > 8 to root beat Shenhua Fatty Methyl Glucose according to Shen acid soap package according to Shen hardness value according to Shen hardness value according to Shen⑻75 to Soap; (b > 3 weight 10% by weight of polyhydroxy fatty acid acetamide interface activity 12% by weight Please patent range of acid amine glucosamine. Please patent range of mixed C i Please patent range below 3. Patent range Less than 2. Please patent 85% by weight of water. The rod-shaped soap compound of the garden item 2 * wherein the polyhydroxyl surfactant is N — C12 — C18 alkyl N — the camphor-shaped soap compound of the garden item 3. Compound • Among them the fat 2 -Cie fatty acid nano M. Draw item 1 of the bar soap sister compound * its special emblem is the garden of item 5 beech-like soap sister compound, and its microscopic is the round item 1 The bar soap compound contains:% of the nano amount with a pancreatic value in the range of about 25 to about 35 (: 12 —Cie Ν —methylglucose_amine interface activity .. St. • Line. F 4 (210X297 Public Broadcasting) VI. Patent application area A7 B7 C7 D7 Contains Jiebaoshangshang amine and its acid 'fatty acid fatty fatty base. Soap hydroxyl and 5-like poly., 2 sticks not C to it The value of the Na2 soap is 1% of the amount of the non-% degree, and the hard water of the heavy nursery is the sharpness of 5 of the range ¾ 0.% of the special amount to the amount, please weigh 3 heavy sticks 3, 0.10 soap according to. s (d) The root agent (please read the precautions on the back before filling in this page) Printed by the Central Ministry of Economic Affairs f 4 (210X297 Kwangju) 9