TW214515B - - Google Patents

Description

" 4 if Λ Τ -2 ο 0 'τ 6 ΙΓ (please read first-back-to-back precautions written by Park Field) The present invention is related to a stable emulsion of fully polyether and fatty substances with terminal perfluoroalkyl groups (Emulsion). It has been found that the perfluoropolyether has high hydrophobicity and lipophilicity, so only by using the same emulsifier component combination, a stable emulsion can be prepared. U.S. Patent 4,803,067 'discloses the use of emulsifiers to prepare stable emulsions of perfluoropolyethers with terminal perfluoroalkyl groups in oil / water or water / oil. These emulsions can be used separately in make-up and care lotions and lotions, because the gold fluoropolyether can form a water-repellent, breathable and permeable protective film on the skin that allows the skin to breathe normally. European Patent Application No. 39G, No. 206 describes the use of emulsifiers to prepare stable emulsions of perfluoropolyethers or other polyhydroxy compounds with terminal perfluoroalkyl groups. In the process of make-up and care products, the aforementioned emulsion is added to the basic formula containing other ingredients. Although there is a strong requirement for an anhydrous or substantially non-aqueous emulsion in terms of make-up and care, the stable emulsion formed by such perfluoropolyethers and fatty substances has not been obtained so far. The aqueous emulsion can maintain the hydrophobicity of the anhydrous product added previously. The Ministry of Economic Affairs, Ministry of Economic Affairs, Central Bureau of β-Consumer " Cooperative Du-printing. Now we have found that we can obtain “perfluoropolyether with terminal perfluoroalkyl group” (hereinafter referred to as “perfluoropolyether”) and the stability of fatty substances The emulsified solution is obtained by adding one or more fatty substances to the emulsion of perfluoropolyether / glycerin or other polyhydroxy compounds in the presence of a surfactant soluble in glycerin or other polyhydroxy compounds. This kind of full polyether and fatty substance is used in glycerin or other polyhydroxy compounds on the paper scale side. Η Home Standard (CNS) Τ4 Specification (210x297) «81. 2. 20,000 5 4 4Χ 2 66 ΛΒ 屮 央The Bureau of Standards and Staff Consumer Cooperatives printed ft ,, 4 5. The stability emulsion of the invention (2) is inconceivable, because it is impossible to emulsify fatty substances in other polyhydroxy compounds, and it is impossible to make perfluoropolyester Emulsification in fatty substances "We were surprised to find that the addition of perfluoropolyether to glycerol or other polyhydroxy compounds can make the fatty substances in the perfluoropolysaccharide-glycerol system or in perfluoropolysaccharide-other polyhydroxy compounds Emulsified in the system. Therefore, the object of the present invention is to provide an anhydrous or substantially anhydrous stable emulsion of perfluoropoly- and fatty substances. Another object of the invention is to provide a method for preparing such an emulsion. The former purpose can be achieved by using the stable emulsion of perylene polyether with end-alkyl group and fatty substance of the present invention. The emulsion contains: 1-5096 weight of one or more terminal perfluoroalkyl groups Perfluorinated polyhydrazone, 10-95% by weight (including water and hydrophilic soluble) One or more polyhydroxy compounds, selected from glycerin and other poly-enzymes and sugars containing at least three tilted hydroxyl groups, if these compounds are solid, then first Soluble in water or hydrophilic solvent, 10-80% by weight of one or more fatty substances with a melting point not higher than 100 ° C, and 0.1-10% by weight of one or more emulsifiers. Fatty substances falsely refer to: 1) liquid products (oil) that are insoluble in water and the aforementioned polyhydroxy compounds, and 2) products that are insoluble in water and polyhydroxy compounds in a solid state at room temperature and have a melting point of not more than 100 ° C ( Fat), perfluoroalkyl group with terminal perfluoroalkyl group, that is, without functional group_Familiar-4-(please read the precautions first, please fill in this package-the size of the paper used in the country of a Sample Standard (CNS) T4 specification (210X297) 81. 2. 20,000 214515_iU 5. Compounds of the invention (many), these compounds and their preparation methods are described in several documents: British Patent No. 1,104,482; US Patent 3,242,218, 3,665,041, 3,715,378, 4,523,039; European Patent Application Nos. 148,482, 151,877 and 191,490; International Patent Application Nos. 87/00538 and 87/022992. There are several kinds of perfluoropoly_commercialized, such as the brand name Fomblin®, Galden® , Krytox® and Deanun® 〇 The appropriate perfluoropolyether emblem is to have one or more of the following repeating perfluoroalkylene units: a) (cf2-cf2〇) b) (~ 〇) C) (C3F60 ), (CF2-j: F-0). CF3d) (CF2 ° -CF2-CF2〇) e) (CF2- CF2-CF2〇) f) (CFO) I CF3 (Please read the precautions in advance and then write the book Γ. 'Binding · Threading-Printed by the Central Standards Bureau of the Ministry of Economic Affairs β Industrial and Consumer Cooperation Co., Ltd. Chinese 9-

Fluorine or sub-fluorinated or non-synthetic fluoroalkyl groups are used on the paper side of the standard Η National Standard (CNS) T4 specifications (210X297 public salivation) 81. 2. 20,000 2 451¾ Λ 6 Β 6 V. Description of the invention (4) It is preferred that the perfluoropolyether used in the present invention has the following individual perfluorofluoroalkylene units or a combination of the following perfluorofluoroalkylene units: I) (CF2-CF2 0) and (CF2 0) The other units are statistically distributed on cyanopolyether; or II) (CF2- CFG) and (CFX0), where X #F or CF3, these »CF 3 units are statistically distributed on the key; or III) (CF2-CF20), (CF2-CF0) and (CFX0), where X is FICF 3 or cf3, these units are statistically distributed on the key; or IV) (CF -CF 2 〇); m \

CF a V) (CF 2 VI) (CF 2 VII) CF wide surface L 1 CF

CIR «· C — 0 (Please read the notes before you fill in this ί The Ministry of Economic Affairs + Central Economic Development Bureau employee consumption cooperation du printing is the same as C is not fluorine or is the same or the same '-child " R original Fluorine in the common formula or alkane m poly 0 all of the alkyl ethane)-gas ο fluorine 2 F all-C column 2 FC contains 0-with 2 CF combination) (suitable for II and the paper size using Chinese national samples Standard (CNS) IM specification (2) 0X297; «:) 81. 2. 20,000 2 6 6 Λπ V. Description of the invention (I)

• CF or

CF I R

In the CF formula, T, A, B and R are the same or different, like perfluoro-gas alkyl, fluorine-containing multi-gas compound or full compound, preferably containing Cl-6 β with repeating perfluoro gas alkylene unit Suitable perfluoropoly_contains: A) Rf- °-(C3F 0) (CF-O) (CF n) -R ·

In the CF3 formula, Rf and 'are the same or different, selected from CF c3 F7; and the unit c3 〇 (gas trifluoromethyl trifluoroethylene), CF-0 ICF 3 and CF2 0 are statistically distributed on the chain; a It is an integer; b and c are like integers or zero; (please read the back-to-back precautions # fill in this Γ install · ft ,, 4 if (b + c) The sum is not zero, then the ratio of ^ is 5 to 40; B) CF.O- (CFO), (CF, 0) -CF_ 3 2 4 α 2 e 3 where C2 F4 0 and CF2 0 are statistically distributed pseudo-by On the chain; d and e are integers; the ratio of d / e is between 0.3 and 5; C) CF_0- (C_Fc0). (C „F .0)-(CFXO) -CF0 3 3 6 f 2 4 gh 3 where C3 F6 0, C2 F4 0 and CFXO are statistically distributed on the chain; the size of this paper uses the Chinese National Standard (CNS) T4 specifications (210X297; «;) 81. 2. 20,000 Λ 6 Β 6 Printed by the Ministry of Economic Affairs Standard A Industrial Consumers Cooperative Society V. Description of invention (Μ x 傺 F or CF 3; f, g and h integers; the ratio is 1 to 50; the ratio of g + h £ is 1 To 10; D) hRj〇- (CF2CF2CF2〇) 々4g where R | and Rg are the same ¥ different, pseudo-CF3 or -C2FS; The perfluoropolyamides usually have a number average molecular weight of 500 to 20,000, and more usually 1, 0 0 0 to 10, 0 0 0. For more detailed information on polyhydroxy compounds suitable for the present invention, please refer to this case Those who applied for the above-mentioned application in No. 390,206 of the Shenzhou Patent Application No. 390. If the polyhydroxy compound is solid pus, it can be dissolved in water or a hydrophilic solvent. It is preferable to use the minimum amount of water or hydrophilic solvent required to dissolve the compound Ο Suitable hydrophilic solvents such as glycols, glycerin, lower enzymes, ether solvents and diglycerol dimethyl ketone, and mixtures of these solvents and water. Usually water is used as a solvent. Concentrated aqueous solution of sugar (syrup). The concentration of the solution is usually reset from 50 to 8096. The final polyols are glycerin, diglycerin, triglycerin and tetraglycerin. The oils and fats used in the present invention can be obtained from plants and animals , Hydrocarbons or synthetic products. Especially fatty enzymes, acids, esters and amides, silicone oils and hydrocarbon oils and -8-(please read the back-to-back notes and fill in the wood factory equipment · line _ paper size Use China National Standards (CNS) 4 specifications (210x2 97 g; ft) 81. 2. 20,000 _ V. Description of the invention (7) Printed by the Ministry of Economic Affairs, Central Bureau of Industry and Commerce, A Industrial Consumer Cooperative Co., Ltd. ¾ Examples of suitable milks for compounding ο More compounds in the compound base than necessary for dissolution Agent:. Milky fat such as thiopercarbane, cinnamic acid, june sulfonate, sulfosuccinate, hemisulfonic acid, t / \ sodium ester acid ester, cocoamine glycine, anchor, polybenzylated alkanoic acid carboxylate, ether potassium acid Ethyl phosphorus gas is arranged in groups, and the following materials are mixed together. For it, the compound of the compound compound base is mixed with hydroxyl or more germplasm. Multi-component or fat-fat amount «B S%% _ milk content thml 3% compound compound-based hydroxy polyhydroxyl species and repolymerized% fluorine 4 all to species 10 containing medium only liquid The emulsification of the neutralized liquid is the best way for the milk to go to the most emulsified milk with a small liquid, and it should be used in a wide range of proportions and appropriate quality. Because of this, Lai Guangduan is very sticky. , On the basis of centigrade or ο ο poise ° ％ 2 ο υ ο is ο o o 00 00 1 ′ ° c 逹 25 high in the case of milky paper that can be emulsified by a liquid such as a degree of viscosity Sample Standard (CNS) specifications (2 丨 0x297 public: ¾) 81. 2. 20,000 (please read the notes to the contrary # 塥 艿 本-The Ministry of Economics of the Installation Line + Central Government Bureau of Industry and Commerce Co., Ltd. Printed 51 V. Description of the invention (") Viscosity rises with the increase of the concentration of the lipids and perfluoropolyethers, and also increases due to the use of more viscous polyhydroxy compounds. At the same concentration, different fatty substances will be produced Different viscosities. If necessary, water or yeast can be added to reduce the viscosity of the emulsion. Suitable yeasts are (^ -4 alkanol and C2- 4 glyphosate. Adding water or alcohol will reduce the stability of the emulsion, so It is preferable to add the suspension not more than about 20% of the total weight of the emulsion. The minimum addition of water or leaven is 196 »Although the ratio between other ingredients is maintained, the addition of water leaven or alcohol equivalent will reduce the ratio of other ingredients. Or yeast emulsion is suitable for low viscosity or lower viscosity that does not require high hydrophobicity In application, the stable emulsion according to the present invention refers to an emulsion that is centrifugally separated at 4,000 rpm for 30 minutes and then heated in a sickle at 50 ° C for 1 period and still does not "phase". The method for preparing the emulsion of the present invention is as follows: one or more perfluoropolyethers in / contains one or more emulsifiers (soluble in the polyhydroxy compound) and one or more polyhydroxy compound emulsions (such emulsion may be referred to as For "pre-emulsion"), add one or more liquid fatty substances with stirring. The temperature of pre-emulsification is not strictly required, and it is often pre-emulsified at room temperature. If the fatty substance is solid at room temperature, it must be melted. The state or dissolution, especially in the liquid fatty substance suitable for the present invention, preferably in a state of forming a solution in hydrocarbon oil, added to the pre-emulsion; if necessary, can be heated to help rib-1 0-(please read the first Zhi's note & 亊 项 #Fill in this book > Binding < Order · The size of the paper is based on China ’s poor standard (CNS) T4 specifications (210X297mm) 81. 2. 20,000 214515 Λ 6 Η 6 V. Description of invention (9) The Central Bureau of Economic Affairs of the Ministry of Economic Affairs The system contains 6 hydroxyaqueous emulsions containing 20 hydroxyl liquids in the entire liquid within the base of 6 liters, and the chemistry uses all this. No pre-zero, more than one minute, milk method, showing pan jlIII. _ ο There are 2 more cases in the case of addition, but this, there is Λ can fat out. First blame or. -1 ,,. Real face machine, Interpretation_ For Shen Yide 30 basis parties have money and slow water is better 。Li ^ xw of 0 ^ β 0 ^ 0 comparability * 0 0 0 rural-Ϊ 度 工 is frustration 0 ^ 0 ^ 00 sticky product, 0 $ ， 之 It ^ 00 相 ® ㈣㈣ 高 0 液 ¾ Cortex is described as a full-speed foreign body & f care (¾ lotion and tt ^ a variety of low fat before the temperature, the quality and light protection are more or less resistant to liquid fat and more makeup items. It is possible to protect fats and fats, or to release them. Milk one! 丨 dilute amount can be converted into lip balm _ warm fat method is to compare the chemical release of the release of liquid containing fat, such as the sliding chamber in the preparation of liquid, are all fluorinated substances. After being mixed into the available sounds, the whole water-fat-phase milk-enriched moisturizing lip can be used with high or liquid milk. The most recognized is oil and fat. Compatible products should be. Add milk. Seeds are added to our phases or glycerin or oil-shaped cosmetics. The solution is as good as the pre-addition. "I will use polyethers in my makeup. The solution will be divided into fluorinated polyglycerides and used for glycation. ........................ installed ..... 1r ···· line (please read 1? / This paper scale is used in China National Standard (CNS) 4 gauge tM21〇x297 mm) 81, 2. 20,000 214515 Printed by KX Gongxiaozuo Cooperative of Ministry of Standards, Bureau of Industry V. Description of invention ((e) emulsification The non-aqueous liquid or the presence of few eggs in any occasion will make the cosmetics and protective products of this emulsion more biologically stable. In fact, these products usually do not need preservatives. In addition, this emulsion The non-aqueous liquid can ensure that the product is permanently attached to the skin. Other advantages in these applications include that the emulsion of the present invention is more perfluoropolymerized in water / oil or oil than the aforementioned US Patent 4,803,067 The emulsion in water requires less surfactant. The following is a non-limiting example of the scope of the invention: Examples 1 to 33 illustrate the various emulsions of the invention and their preparation methods. The composition is calculated in% by weight. The stability test is as described above. The grooves and characteristics of the perfluoropolyether used are as follows: -Fomblin ⑧ HC / 25 ·· CF-(0-CF-CF.) N (〇-CF .) -〇CF0 j I 2 η 2 m 3 CF "n / B is 20 to 40 MW (number average molecular weight) = 3,200. -Galden® D 0 3; The structural formula is as shown above, η / = 20 To 40 M. W. = 870-Fomblin * 8 * HC / R: -1 2-(please read the precautions first and fill in this t-pack-order-this paper size is used in the S-like sample standard ( CNS) A 4 specifications (210x297 male: «:) 81. 2. 20,000 A 6 Π 6 〇 \ 45l5_ V. Description of invention (") The clearing formula is as shown above, n / m = 20 to 40 M. W. = 6, 6 0 0 0 -D e μ num S-6 5: F (CF2-CF2-CF20) nCF2CF3M. W. = 4,500 -F oab 1 i η Z25: CF .- (〇CF_CF) (OCF)- OCF 3 2 Z pcq J p / q = 0.6-0.7 M. W. = 9,400m_1_ 5 9% Foiibl in® HC / 25 29% glycerin 2% Texapon® N / 40 (2. 8 of sodium laurate produced by Henkel) % Solution β 1 〇% petrolatum oil (density 0.83) at room temperature Formblin® HC / 25, glycerin and Texapon® Ν / 40 pre-emulsion, add petrolatum oil, vortex Flow emulsifier (S i 1 vers ο η ® (please read the back-to-back notes # 塡 写 本 * loading · ordering _ line-Central Bureau of Economic Affairs of the Ministry of Economic Affairs CS: industrial and consumer cooperation cooperation Du Du printed in a clear note. Waiting for unpredictable and unrestrained co-dependence. The description of the speed of liquid mixing and the speed of sowing milk is divided into the following examples: down to 00, the in is OS liquid sc, VI milk, d, el, fi, ok, ok, and ro (B, taking into account the degree of stickiness. Jane. Transfer the speed of the 8 liquids to show the milk. The standard of this paper is the Chinese standard (CNS) T4 standard (210x297 male dragon) 81. 2. 20,000 214515 Ministry of Economic Affairs Printed by κχ 工 consumer cooperative V. Description of invention (* Λ), RTV-II type), measured according to the method indicated by the manufacturer: Viscosity i 36,600 centipoise (25 ° C, rotor # 29, 5 revolutions per minute Μ__2 2 9% F〇Bbl in® HC / 25 59% glycerin 2% Texapon® N / 4 0 10% Vaseline oil is a stable emulsion, the viscosity at 25 ° C is 2, 0Q0 centipoise (5 rpm, rotor # 29). M__3 2 0% Fomb 1 in® HC / 2 5 39% glycerin 2% Texapon® N / 4 0 10% Vaseline oil is a stable emulsion with a viscosity of 50,000 centipoise (5 revolutions) at 25 ° C / Minute, rotor # 2 9). Example 4 1 5% Fonblin® HC / 2 5 29% glycerin 2% Texapon® N / 4 0 54% Vaseline oil is a stable emulsion, and the viscosity at 25 ° C is 950,000% Mooring (1 revolution / min Bell, rotor # 29) β -1 4-loaded · This paper scale uses the Chinese National Standard (CNS) f 4 gauge (210X297 male dragon) 81. 2. 20,0⑻ 9,14515 A 6 II 6 5. Description of the invention (d) Example 5 1 0% Fomblin® HC / 2 5 5 9% glycerin 2% Texapon® N / 4 0 2 9% Vaseline oil is a stable emulsion with a viscosity of 3, 100% at 25 ° C Poise (5 revolutions per minute, rotor # 2 9). Example 6 2 0% F〇Hb 1 i η® HC / 2 5 39% glycerin 2% Texapon® N / 40 3 9% silicone oil (3 50% Mooring)

(Please read the notes on the back of Ercheng T-shirt <-" 6 _ The Ministry of Economic Affairs Standards and Beicong Consumer Cooperation Du Yin ¾. Emulsion for stability. Example 7 2 0% Fomblin® HC / 2 5 39% glycerin 2% Texapon®1 N / 40 39% silicone oil and petroleum jelly oil 1: 1 mixture is a stable emulsion. 8 2 0% Foiablin ^ HC / 2 5 3 9% glycerin 2% Texapon ® N / 40 -15- This paper uses the Chinese National Standard (CNS) 4 specifications (210x297 male dragons) 81. 2. 20,000 lines 21451 ^ Λ 6 Π 6 V. Description of the invention (< 4) 39% Abi I11 Κ4 (volatile silicone) is a stable emulsion. Example 9 2 0% Fo mb 1 in < s > HC / 2 5 39% glycerin 2% Te xa ρ ο n⑥ N / 4 0 3 9% wheat germ The oil is a stable emulsion. 1 0 2 0% Fo η b 1 i η ® HC / 2 5 3 9% glycerin 2% Te xapo η ® N / 40 3 9% Zhou Jiaoba Oil Packing. Order_ Ministry of Economic Affairs Standard 'Bureau only works to eliminate crime and cooperate Du Yin ^ is a stable emulsion. M__U 2 Ο% FoUl in® HC / 25 39% glycerin 2% Texapon® N / 4 0 3 9% Eutanol® G (2 produced by henkel company) -Sinki Twelve Fermentation) is a stable emulsion. M__ι_2 2 0% Foiblin® HC / 2 5 -1 6-This paper is used in 8 national standards (〇old) 〒 4 specifications (2) 0x297 public goods) 81. 2. 20 , 0⑻ Jing ^: Ministry of Central Standards' Bureau staff consumption cooperation Du Yin 51 V. Description of invention (, o 39% glycerin 2% Texapon® N / 4 0 39% M iry tol® (decanoic acid and hexyl made by Henke 1 company Acid glycerol ester) is a stable emulsion. M__ι_3 2 0% Fomblin® HC / 2 5 39% glycerin 2% Texapon® N / 40 39% octyl stearate (Cetiol®868 from Henkel) is stable Emulsion of m__l_i 2 0% Fomblin® HC / 25 39% glycerin 2% Texapon® N / 40 39% Olive oil is a stable emulsion. 15 2 0% Fomblin® H C / 2 5 3 9% glycerin 2% Texapon® N / 4 0 3 9% paraffin C10 / C 1 3 is a stable emulsion. -1 7-The size of this paper uses the Chinese National Standard (CNS) specifications (210X297 male dragon) 81. 2. 20,000 (please read the precautions before filling in the copy, install-line-V. Description of the invention (, T〇A 6 η 6 Printed example of CX Gongxin & Co., Ltd. of the Central Standards Bureau of the Ministry of Economic Affairs 1 6 2 0% Fo mb 1 i η ® HC / 2 5 39% glycerin 2% Te X a Ρ ο η ® N / 4 0 3 9% Vaseline pre-emulsion Vaseline preheated to 45 ° C is a stable emulsion. Example 1 7 2 0% Fo nb 1 in® HC / 2 5 3 9% Glycerin 2% T e X a P ο η ^ N / 4 0 13% Sticky Vaseline 2 6% Shiduan C 1 / c 13 Mix Vaseline and Shidolin first, which is a stable emulsion. Example 1 8 2 0% Fo η b 1 in ^ HC / 2 5 39% glycerin 2% Te X a P ο n ^ N / 40 3 9% S sesame oil is a stable emulsion. Example 1 9 -18 The paper standard is based on the Chinese HS standard (CNS) T4 Regulations (210x297 male dragons) 81. 2. 20,000 (please read the back-to-back precautions # fill in this book, install · *? R * line-214511 economy屮 楊 楳 ZXC CX Gongxu Xu Du Cooperative Printing 5. Description of the invention (,?) 2 0% F 〇b 1 i η ® HC / 2 5 3 9% Glycerin 2% Texapon® N / 4 0 3 9% Sticky Vaseline is a stable emulsion. Example 2 0 14% Foiablin ⑧ HC / 2 5 2 7% Glycerin 2% Texapon® N / 40 52% Vaseline oil 5% water and finally add water 〇 to stabilize the emulsion. In 2 5 Viscosity of ° C is 37, 50000 centipoise Example 2 1 13% Foablin1 ^ HC / 2 5 2 7% glycerin 2% Texapon® N / 40 oil Lin Shifan% water is determined by the degree of emulsification P An 25 For sub-rotating shovel \ turn 5 IX / | \ Boli (please read the back-end notes first # filled in this book> installed · sample paper size using Chinese S home sample standard (CNS) specifications (210X297 male dragon ) 81. 2. 20,000 214515 Λ 6 η 6 V. Description of the invention (, s) Printed by the Ministry of Test, Bureau of Standards, A, Gongxiaozuo Cooperative Society 51 1 2% Fo Blin® HC / 25 2 3% Glycerin 2% Texapon ® N / 4 0 4 3% Vaseline oil 20% water is a stable emulsion. Example 2 3 2 0% Galden® D 0 3 3 9% glycerin 2% Texapon® N / 40 39% Shihlin oil is a stable emulsion. Example 2 4 2 0% Fo ^ blin * ® HC / R 3 9% glycerin 2% Texapon® N / 40 39% Vaseline oil is a stable emulsion》 Example 2 5 2 0% D eanu in ® S / 65 39% Glycerin 2% Texapon® N / 40 3 9% Shihlin Oil-20- (please read the precautions first ιτι- 塡 本本 本 纸 5 good-scale side-by-side use of China's National Standards (CNS) lM regulations ΙΜ210Χ297 male dragon ) 81. 2. 20,000 214515 V. Description of the invention (θ) is a stable emulsion. 2 6 20% Fo dirty blin® Z 2 5 39% glycerin 2% Texapon® N / 40 39% Vaseline oil is a stable emulsion. 2 7 2 0% Fo ab 1 i η ^ HC / 25 39% glycerin 2% coconut propylamine beet crocodile 3 9% petroleum jelly (recognize before reading the back and pay attention to the 幀 项 孙 Fill in the wood, install-order_ It is produced as a stable emulsified liquid by the cooperation between the Ministry of Economic Affairs and the Central Bureau of Standards. Example 28 20% Fomblin® HC / 2 5 3 9% glycerin 2% benzyl chloride anchor (50% solution in water) 3 9% Vaseline oil is a stable emulsion "Example 2 9 2 0% Foiblin® HC / 2 5 39% diglycerin 2% Texapon® N / 4 0 -21- line CNS) Yang 4 specifications (210x297 mm) 81. 2. 20,000 V. Description of the invention (> «) 3 9% Vaseline oil is an emulsion of two viscous and stable. At 25 ° C, the degree of rotation is 1, 0 0 0, 0 0 0 丨 Example 3 0 20% Foiblin® HC / 2 5 3 9% Sorbitose (70% in water 2% Texapon® N / 40 3 9% Vaseline oil is a stable emulsion. Example 3 1 8% Fo Gublin ^ ® HC / 2 5 2 7% glycerin 8% diglycerin 5 5% petroleum jelly 2% Texapon® N / 4 0 (please read the opposite first Yu Yu Matter # 塡 艿 木 ， 装. Ordered _ KX Industrial and Consumer Cooperation, Central Standards Bureau of the Ministry of Economic Affairs, du printed as a stable emulsion. The viscosity at 20 ° C is 180,000 centipoise (1 rpm / rotor, rotor # 4) Μ__3_2 5% F 〇ab 1 i η ® HC / 2 5 30% glycerol 2% Anphisol®K (cetyl phosphate produced by Givaudan) 53% Cetiol®868 (octyl stearate by Henkel) 10% Abil®K4 (volatile silicone from Tego Cosmetics Co., Ltd. -22- This paper? Fc scale is used in China National Standard (CNS) A 4 specifications (210X297 male dragon) 81. 2. 20,000 4- 蠤 1 2 66 ΛΠ V. Description of the invention (> 〇Viscosity at 20-C is 34,000 centipoise as a stable emulsion. 3 3 1 0% Fombl in® 20% glycerin 3% Afliphisol, ®> 6 3% C eti 0 1 ® 8 4% Ab i1® K4 (Please read back to note item I before writing. This is printed by the A-Consumer Cooperative of the Bureau of Standards, Ministry of Economic Affairs. Because the viscosity increases at high oil concentrations, it is not easy to operate at low temperatures, so The pre-emulsion must be preheated to about 5 Q ° C. The viscosity at 200 ° C is 50000, 10000 centipoise. It is a stable emulsion. Examples 34 to 37 which do not use the composition of the present invention are for comparison. Μ__34 50% glycerin 49% petroleum jelly 1% Texapon® N / 40 This emulsion is completely unstable and will separate quickly when left. m_3_5 2 0% Fonblin® HC / 25 7 9% Vaseline oil 1% Texapon® N / 40 This emulsion is completely unstable, and it will separate quickly when placed. 2 3-The size of this paper is based on China ’s National Standards (CNS) 4 regulations (210x297 g: «:) 81. 2. 20,000 packs-.Is-line 214515 Ministry of Economic Affairs, Central Bureau of Industry and Commerce A -Ϊ-Cooperative Du Print

V. Description of the invention (》) Example 3 6 5 0% F 〇bb 1 in® HC / 2 5 49% Fanshihe " by 1% T e X ap on® N / 4 0 Stability: Same as Example 3 5 〇 Example 37 30% F 〇 »b 1 in® HC / 2 5 6 7% Petroleum i: oil 1% A r 1 ac el * ® 989 (hydroxyethyl fatty acid manufactured by ICI). Stability: Same as Example 35. Example 38 This example illustrates the light-blocking emulsion and its preparation method. A) 20% glycerol 10% Fomblin® HC / R phosphoric acid 60% of the product is produced by the company (please read the precautions before filling in this package-line \) / K «'

\ 1 / B

〇B Transfer ^ ^ C thin 坫 ο Silicon 5 ° speed 1 is poly 5 mixing h since if ^ u liquid nlp = two t A object Jia Yi slow LI 1 0 t 3J a second release%% two t 氕% child ο 8 OS 2? In # 2 in alkane gas pre-phase 1 for phase addition and gradual stirring, A liquefied milk clock minutes \ turn IX 0 (temperature-pouring room centigrade to 00 drop o 'to 90). This paper scale is used in China National Standard (CNS) T4 specifications ( (210x297 male dragon) 81. 2. 20,000 214515 Ministry of Economic Affairs, Central Bureau of Economics and Trade, only work to eliminate crime, cooperate with Du Yinnu 5. Description of invention (8) This example uses the method of Example 38 to make vitamin hydrate emulsion: A) 3 0% Glycerol 1 0% Fomb lin® HC / 2 5 2% potassium cetyl phosphate B) 50.5% octyl dodecane yeast (Eutanol® G by Henkel) 5% cyclomethicone (Tego Cosmetics) Abil®K4) 2% Tocopherol Acetate 0.5% Retinyl Palmitate Emulsion at 20 ° C has a viscosity of 180,000 centipoise (1 rpm, turn # 6). Example 40 A vitamin hydrated emulsion was prepared following the previous example, but with 1% chamomile oxalase extract. In the presence of a small amount of secondary fermentation, it is enough to reduce the viscosity from 180, ΟϋΟ centipoise to 50, 0.000 centipoise. Example 4 1 Imitate Example 38 to make a sunscreen lotion, but heat phase B first. Α) 30% glycerol 10% Fomb 1 in® HC / R 2% potassium cetyl phosphate B) 4 6% octyl stearate 5% ethylhexyl p-methylcinnamate (Pansol® MCX by Gavandan) 5 The viscosity of the% Huimethicone 2% Karite butter emulsion at 20 ° C is 480,000 centipoise (1 rpm, turn # 6). The standard of the paper is used in the middle-S sleepy home standard (CNS), fM regulations (210x29 / male dragon) 81. 2. 20,000

Claims (1)

214W Amendment and supplement A7 B7 C7 D7 Printed by the Central Standards Bureau of Economics, R Industry and Finance Cooperatives X. Patent Application No. 8110 24 91 "Perfluoropolyether and Fatty Substance Emulsion Composition and Preparation Method J Patent Case (Amended in September 1982) A. Patent application 1. A stable emulsion composition of perfluoropolyether with terminal perfluoroalkyl group and fatty substance, including: ⑴ 5 ~ 59% by weight of one of the following formulas Polyether: a) CP3- (0-CF-CFa) a (0-CP3) m-0CF3 I cf3 with an average molecular weight of 870 to 6600 where η / π = 20 to 40, b) with an average molecular weight of about 4500 FiCFa-CFa-CF ^ OhCFjCFj c) CF3 with an average molecular weight of about 9400 where p / q = 0.6 to 0.7; 029 ~ 59% by weight of polyhydroxy compounds selected from concentrated aqueous solutions of glycerin, diglycerin and glucose alcohol; ⑶10 ~ 68% of one or two fatty substances with melting temperature not higher than 100T, which are selected from petroleum jelly, silicone oil, wheat germ oil, jojoba oil, 2-octyldodecanol, capric acid Triglyceride with hexanoic acid, octyl stearate, olive oil, Shiwan C10 / C13, Vaseline, Castor oil, linseed oil and volatile silicone; ⑼ 0.56 ~ 3% by weight of the emulsifier soluble in the above-mentioned polyhydroxy compounds; the sum of each component is I ». -1-This paper is again suitable for China National Standard (CNS) A4 specifications (210 X 297 mm) (please read the special item on the back and fill in this page)-Pack, order · A7 214515 c '_____D7_ 6. Apply for a patent park 2. According to the scope of the patent application The stable emulsion composition of item 1, the emulsifier here is ionic. 3. The stable emulsion composition according to item χ or 2 of the patent application scope, the special composition of which contains any other 5 ~ 20% by weight ( Percentage is for gold department emulsion composition) in the presence of water, while the relative proportions of other ingredients remain unchanged. 4 A method of manufacturing a stable emulsion composition of patent application scope 1 or 2 A kind of gold fluoropolyether / a polyhydroxy compound (the pre-emulsion contains an emulsifier soluble in the compound) as defined in item 1 of the patent application scope. One or more liquid fatty substances are added to the pre-emulsion during stirring 5. According to Shenzong According to the method in the fourth item of the scope of interest, when the fatty substance is solid at room temperature, the pre-emulsion is added in a molten state. 6. According to the stabilizing emulsion composition in the first or second item of the patent application, the pseudo It is used to make cosmetics and skin care products. (Please read the precautions on the back before writing this page)-Packing. Order · The Ministry of Economic Affairs Central Bureau of Samples and R-Consumer Cooperative Printed Purple-2- The table paper is again suitable for China B Home Standard (CNS) A 4 specifications (210 X 2OT public; t)