TW212821B - - Google Patents

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TW212821B
TW212821B TW081103419A TW81103419A TW212821B TW 212821 B TW212821 B TW 212821B TW 081103419 A TW081103419 A TW 081103419A TW 81103419 A TW81103419 A TW 81103419A TW 212821 B TW212821 B TW 212821B
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alkyl
liquid
dispersion
aqueous solution
grams
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TW081103419A
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Henkel Kgaa
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
    • D06L1/14De-sizing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/13Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen using inorganic agents
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/20Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Description

O _Β_6_ 五、發明説明(') 本發明關於使用持洙烷基f當作被單狀織物,纱或短 經濟部中央標準局員工消費合作社印製 織花物及白 一 天理的處在物活有劑整親生 來離 狀印之液潔纱。整目預。嫌面所性他雒被 近陰 單、理漿之或物 、此當維,界,活其 易 等之 被色處、度物污液於適濰中用劑面與度卽 彼型 使染預劑程織及漿用之然白使理界且高, ,典 來如被理夠狀液如要维天漂,整等的有金 性種 式理該整足單漿物主纖於和觸、此熱須安 濕一 方處,、有被、雜滌然用漿接液=耐必態 潤少 心種言物須之劑的洗天施退液漿去和物生 之至 小各色污必成理煩液或滌 、學使除的織對。知及 單η染之質合整麻鹵 / 洗滌化及物定氣應毒己苜 gIBJd 鈦量物,纱去-及液洗之濕缠安去韌無和基 :以-Τ-Ι-Γ-何比力纺涂漿邊鹼液 _ 透龙鹼對性物性垸 朝是# 物任 ,牧之難退潘同鐘性袭能對而活生容有 助Ώ影薄'f-v诗¾.IM 更7或連 ‘活詎均是苕亙中相含 性目會之頃同和除纱除合或洗面物物須互界水物 : 活之去理冧 ,力法和 :對地清界織雜必劑領對生割 面物除整人物色洗物等為濁H1有使維中化這而之潔 界織绒或令雜染清織穋B單理含係缒漿氯 ,η甘清 之理短白含等強被狀果漂常處種的5退如外 基庭 理處或增不維及須單、和般預 一目物和器此丨烷家 處先纱光須潘勻有被撖漿 一諸與之污白學,解於於 預預 ,熒必然均含之 .退 ,述先剤類漂化力降由用 绒 物 、質天和般然劑 ,理上首性種在理和物 應 (請先閲讀背面之注意事项再填窝本頁) 本紙張尺度逍用中《國家搮準(CNS)甲4規格(210x297公釐) 81. 5. 20,000〇〇 經濟部中央標準局员工消費合作社印製 . A 6 幻 U__B6 五、發明説明(> ) 子型界面活性劑的家庭清潔劑已述於歐洲專利案印70014 號中。此外,含有烷基r和某些其他非離子型界面活性 剤及陰雞子型界面活性割之液體清潔劑知自歐洲專利案 印EP105556號。國際專利案W0 86/2943號述及含有烷 基苜及典型陰離子型界面活性劑之液體清潔劑。 然而,識物預豳理用之界面活性劑比家庭清潔劑中使 用者更需符合極g要求,於是,嫌物預處理用之界面活 性爾必須具有對化學品和熱之較高耐抗性,此外,必須 能在較短時間内從被單狀嫌物,纱和短绒中分離出比污 物如漿料、整理劑、果接等更多之其他討厭雜物。 國際專利案W0 90/06353號述及市面洗衣店用之含水 «液清潔劑,其含有式R-0-Gx之垸基苜其中R為C8- 14 垸基Sx為1.2-5者並含有氳氣化納、矽酸納及氮川三 乙酸納等作為肋洗剤成分。芾面上洗衣店使用的稀釋態 之清潔劑濩液對一般家庭污物如在灰塵/羊毛脂、血液 、牛奶、可可、灰饔/皮脂均有良好之清洗結果(水硬 度為05 dH)。然在織物預處理中,其比在家庭清洗中更 多量之其他污物亦必須除去,除此之外,在織物預處理 中也必須除去漿液、整理劑、果膠、半纖維素、(棉)蠟 、金屬邇等。 本發明提出之道可供與一種適合織物預處理之含界面 活性劑之助劑其可耐抗化學品和鹸,有高度潤濕力和分 散力並能使被處理之嫌物有優異之吸收性且在併行漂白 (請先閱讀背面之注意事項再填窝本頁) 装- 訂' 線. 本紙張尺度遑用中面國家»準(CNS) T4規格(210x297公*) 81. 5 . 20,000(3) 2128^1 A 6 B6 經濟部中央標準局员工消費合作社印製 五、發明説明(令) 時可供舆高度潔白者,此外,這含界面活性剤之助劑對 生態是安全的,卽無盡且在短時間内完全被生物降解。 此問葚已由”使用式I之烷基苜 R 1 - 0 - ( G ! „ ( I ) 其中R 1為C 3 - w烷基,G為葡糖單位及η為1 - 3之數 者當作天然及/或合成之被單狀織物、纱或短绒預處理 之含界面活性劑之肋劑”而解決。 在本發明文中,被單狀織物所了解偽指機織和針織 之缠物舆非绻物继物。继物預處理包括清洗、鹼液洗滌 、漂白和退漿,烷基苜此詞通常應用於烷基單苜(n=l) 及其舆浣基寡t(寡聚度η不高於3)之混合物。 依本莽明的使用之垸基苜為本身己知之化合物,彼等 ______ - ... . 裂法已述於許多文獻中,例如美國專利- PSS 3,547,828 ,3,772.269 及 3, 839, 318 等號.歐洲專利案 ΕΡ 301 298 • ΕΡ 357 9 6 9 及 EP 3S 2 6 7 1 等號及 DE-0S 3 9 2 7 9 1 9 號 ,塘輿g之反應物稱之為垸基甘者或由用過量醇及酸作 為镯媒之直接反應或由低醇作為溶劑和反應物之轉縮醛 作用以裂之:依本發明使用之烷基甘為搪類之菊萄糖、 果搪、π露塘、半乳溏、塔羅塘、古羅塘、阿洛糖、阿 卓糖、艾杜溏、阿拉伯瑭、木糖、來冧糖和核糖與C 3 - :4 醇反應;比等塘類彼比可賴糖甘(甘)鍵以連接,彼此連 接之塘Ζ數目可由所讚之募聚度(在式I中以η示之)以 辨知,作為分析上決定值,寡聚度π亦可為分數,一般 (請先閱讀背面之注意事項再蜞寫本頁) 裝· 訂 線· 各紙張尺度邃用中諷家福準(CNS)甲4規格(210x297公*) 81. 5. 20,000(3) A 6 B6 212821 五、發明説明) (請先閱讀背面之注意事項再填寫本頁) 在1和3之間,尤其是在1.1和1.4之間,從述及之糖類 衍生出之塘單位在式I中以G字母表示。在本發明的文 中,G最好衍自葡萄搪,式I中之R1為μ烷基, R1最好衍自直鏈之C3- 14醇,此等醇似脂肪醇可依已 知方式得自再生之原科。亦可用式I化合物其中R1為支 鍵之C3- i4烷基者,其衍自支鏈醇,支鏈醇可由氧化 合成法製成為所諝之氧化醇,R1自亦可表示C8- 14烷 基之混合者。似這些基之混合者尤其可衍自油脂化學一 般遇到之支鏈CS- 14醇的混合物。式I之烷基甘其中 R1為支鏈之12烷基者宜於本發明的目的,式I之 烷基苜其中R1幾金為支鏈之Cid烷基者則待宜。在本發 明文中,此方面”幾乎全部”之詞乃意指8 0 - 1 0 0 %之R 1 表示正癸基,因之.R1可衍自含有80-100%重置之量 的正癸醇R 0-20%重量之量的Cf3- 14醇(最的是C8者) 的醇混合物。 式I之垸基苜其中G為葡萄糖單位和π為1.1-1.4之 數及為幾乎全含10傾C原子之支鐽烷基者更是待佳。 就彼等産製言,依本發明的使用之烷基甘可含有少量 (最好是少於2%重量)未反應之C3- 14醇,惟這不含不 經濟部中央標準局貝工消費合作社印製 當地影署妓等使用α 在預處理液中,烷基苜易以其溶液或分散液用之,水 及/或有機溶劑上尤其是正丁醇,2 -乙基己醇及/或甘 油可甩為溶劑或分散劑。宜用含有”按溶劑和分散劑計 -6 - 各紙張尺度逡用中覊國家樣準(CNS)甲4規格(210x297公*) 81. 5. 20,000(3) ^>12821 A 6 B6 經濟部中央標準局貝工消費合作社印製 五、發明説明(5 ) 之50-100 %重量此量之水作為溶_或分散劑及按溶劑和 分散劑計之0-50%重量此量之有機溶劑”的烷基甘之水 溶液或含水分散液。烷基苷之含水分散液亦所了解其尚 包括專家己知之”湖液”。此等産品。一般言之,使用” 能使1公升相當之預處理液内的烷基W活性物質含量在 0.1-10克/升範圍内”此量之烷基甘溶液或分散液。 情況合成之被單狀織物或纱或短绒時,將能使洗液内 烷基苜活性物質含量在”0.5-2.5克/升溶液”之範画内 此量之式I垸基苜水溶液或含水分散液加入洗液内,或 用按”0.5-2.5克/毎升洗液計”此量之雔酸鹽,涵糖酸 鹽及/或?g丙烯酸鹽且尤其是膝酸鹽(似H e n k e 1 K G a A 産品之SeCU「〇n®540)之典型多價鳌合劑以與烷基甘混 合。根據本發明,此烷基f最好用以清洗合成之被單狀 嫌物或纱或短绒且尤其是聚酯、聚趣胺,坫駿纖維,乙 酸酯迷维及/或聚丙烯睛者,情況偽在一般溫度狀況但 最好是在4 0 - 8 0 υ下行之, 式I之垸基苜最好用為在退漿、鹼液洗滌及/或漂白 中心含界面活性劑之肋劑。 在天然殳/或合成針織缠物之退漿中,烷基甘傜以彼 之水溶液或分散液用於退漿液,其量為烷基苜活性物質 之量在~1-4克/每升退费液"之範画内,若屬需要,這 類烷基莒可舆退漿一般所需之量的一般酵素如澱粉酶併 用,此等酵柔一般以按”2-15克/毎升退漿液"計之置與 -7 - (請先閱讀背面之注意事項再填窝本頁) 装· 訂- 線. 本紙張尺度遑用中酺蘿家樣準(CNS)甲4規格(210x297公*) 81. 5. 20,000(Η) 2128^1 A 6 B6 經濟部中央標準局员工消費合作社印製 五、發明説明) 烷基苜併用,退漿偽依尋常方式行之,所得之針鐡織物 顯示極佳程度之退漿。 漂白時,烷基苷偽以彼之水溶液或分散液用之,其量 為比活性物質含量在”0.25-7.5克/毎升漂白液”之範圍 内,根據本發明,造類烷基甘最好用以漂白天然及/或 合成之被屋狀纗物或纱或短绒,尤其是用以鹼性漂白( 含水)棉、棉/聚酯、棉/聚兩烯腈,棉/粘驪繼維或 绵/聚s按者。這類潔白液含有當作漂白劑之h2〇2或 在水内形成H2〇2之化合物,用_最好是NaOH或Κ0Η收 漂白液之pH調節連至少9。毎升漂白液一般含有5-100牽 升之 35% 重量 H2 02 , 0.5-50 克 NaOH 及 / K0H, 2.5-50 毫升安定酮(尤其是矽酸筘及/或矽酸鉀之溶液),0.1 -1.0克镁鹽(尤其是MgS〇4 ), 0.5-10克雔酸鹽,涵萄 糖酸鹽及/或聚丙烯酸邇此等多價螯合劑(尤其是似 Secu「on:® 540(Henkel KGaA産品膝酸鹽),一升中剩下 者由水溝成。漂白偽在201C (冷或漂白)至120tM熱或漂 白)之溫度且最好是在7〇-120t之溫度下行之。依本發 明使用烷基苷於漂白一方面有極佳之液體吸收,即大量 之漂白液為被單狀織物或纱或短绒吸收,g —方面有極 高度之潔白。此外,該被單狀織物或纱或短绒在協用院 基苜漂白後的顯有極高之吸收性及高而均勻之染料圾收 力3 以齡液洗滌含棉之被單狀織物或纱或短绒(最好是纯 (請先閲讀背面之注意事項再填窝本頁) 裝. 訂· 線. 本紙張尺度遑用中瓤雇家接毕(CNS)甲4規格(210x297公釐) 81. 5 . 20,000(2) B6 BL1_ 五、發明説明(r) (請先閱讀背面之注意事項再填寫本頁) 绵1時,垸基甘偽以彼之水溶液或分散液用之,其量為 該活性物質含量在”0.25-7.5克/毎升洗滌液”之範圍内 ,這洗綠液一般被鐮化至10-14之pH值,毎升洗滌洗最 好甩0.25-7.5克(基於活性物含量)之烷基苜水溶液或分 散液及2-100克鹼i最好是NaOH及/或Κ0Η)與0-5克上述 種類之多價螯合劑。鹼液洗滌偽依尋常方式且最好是在 95-10 Of溫度下進行,在連績洗滌中使用烷基苜可讓在 短暫接《時間内有極高之吸液量3 添加一般性抑制發泡勃如矽酮,礦油及/或磷酸酯對 缠物連缨預處理法是有益的。 在所有織物預處理中,依本發明使用烷基苜含供與極 高吸®量,此鉋而使待處理之織物與預處理浴只需短暫 接《時間。有關工業上缣物預處理之資料(決定於缣物 及所痛之預處理方式 > 亦請査閲丨丨lUanri氏所褊之工業化 學百科f書等2 3冊2 9 - 3 1頁,由V e r 1 a s C h e m丨e , W e丨n h e i π 在1983年出版。 蓄例 A )烷基苜之製取 經濟部中央標準局员工消費合作杜印製 5 0 %重量之烷基ff瑚液(寡聚合度η = 1 . 2 5 )可由依照 DE-0S 3 833 780號之方法由癸醇和無水葡萄糖直接合成 而得: Β )躉用冽 m 1 ··退漿 -9 ~ 81. 5 . 20.000(H) 本紙張尺度遑用中鼷家揉毕(CNS)甲4規格(210x297公*) A 6 B6 21^8^1 五、發明説明(3 ) 在實驗室用之連續式機器内用毎升含有5克酵素( Enzylase®HT,Diamalt産品)和5克例A之烷基苜來浸 漬己被澱粉上漿之棉斜纹布,浸潰溫度為70t及吸液率 為100%,反應可由在連續或蒸汽發生器内用跑和水蒸 汽(102t:>來蒸3分鐘而成,此棉斜紋布隨後在一連續 式清洗機(有6間洗室)内熱洗並在拉輻機上乾燥。 退漿程度可由收織物漾品置入0.005莫耳/升此S度 (C)之碘液内以決定,該W液可依下述配製之使10克KI 溶入100毫升水中,加入0.635克碘,振通後一檷拌該液 以迄礴完金溶解,此液ϋ由加入水逹800毫升及最後用 乙酵使逹1升而製成。 (矣浸在碘液内1分鐘後一用冷水簡單地清洗該識物漾 品,以濾低吸乾,立即與TEGEW Α紫標尺比對,該標尺 分成1-9之刻度,9之刻度表示金無漿液而超過6之任 何刻度刖表示一適度上漿之镟物,在該紫色標尺上之9 刻度偽以依例B 1)退漿之嫌物量得者,易言之,即在該 嫌物上不再有漿液。 例 2 : 洗滌 在實驗室用之連缅機器内用每升含有40克NaOH( 100 96 重量),2 毫升链酸鹽(Securon®540(Henkel KGaA 産 S )反5克例A之烷基苜之液來浸漬己退漿之棉斜紋布, 浸潰溫度為70¾¾吸液率為80%,浸漬及軋水後,在 下收織物連續蒸5分鐘,在一有六間洗室之連續 -10* 本紙張尺度逡Λ中韻鷗家樣準(CNS)f 4規格(210x297公釐) (請先閲讀背面之注意事項再填寫本頁) 裝· 線. 經濟部中央標準局员工消費合作社印製 81. 5. 20.000(H) - 五、發明説明(9) A 6 B6 經濟部中央標準局貝工消費合作社印製 或 清 洗 機 内 進 行 後 缓 之 清 洗 及 中 和 > 用 每 升 含 有 6 . 6克 Η a 0H (1 00% 重 量 ), 0 .8克 之 例 A) 院 基 甘 及 0 . 3毫升瞵酸 鹽 i S e c U Γ 0 Π 5 40 ( He n k e 1 KGa A) 之 液 來 s h a r p e η第一間 洗 室 , 評 估 此 試 m , 以 脹 高 高 度 法 (D IN 53 924) 來決定 绖 鹼 洗 m 過 之 m 物 的 吸 水 率 » 擭 得 下 述 之 值 * 張 高 之 高 度 r 以 毫 米 計 1 5秒 後 13 3 0秒 後 16 60秒 後 20 例 3 : 潔白 業 位 激 粉 上 之 灰 棉 布 接 受 鹼 性 洗 滌 及 情 況 —如洌 B 2 I所述, 但卻不中和, 在用毎升含有0 .1 5克 H g S0 • 10 Η 2 :0 , 12 毫 升 矽 酸 納 液 (38 ° B ' e ) ♦ 6克 NaOH (1 00% 重 量 ), 5 克例A )之烷基甘, 2 克瞵酸鹽( S e c u γ ο η 5 4 0 ( He π k el KGa A ) 及 40 毫 升 Η 2 ;0 2 (3 5%重量之液浸漬 前 - 在 拉 輻 機 上 乾 燥 > 浸 m 溫 度 為 20 及 吸 液 率 為 10 0% SL 水 後 t 在 連 m 式 蒸 汽 發 生 器 内 於 1 0 2 t下收縑物蒸 8 兮 » 然 後 在 連 缅 式 清 洗 機 内 熱 洗 , 之 後 中 和 , 用每 升 有 1 克 Na 0 H 丨1 00% 重 量 ), 0 .8 克 例 A ) 之 院 基 甘及0 . 3 克 菘 酸 鹽 (S e c u Γ ο η ⑧ 5 4 0 ( He π k el KGa A ) 之 液 來 s h a r p e η 連 m 或 式 清 洗 機 内 之 第 一 間 洗 室 » 最 後 » 該 m 物 在拉輻 機上乾燥,這試驗由退漿度,潔白度及吸水率來決定。 -1 1 - 本紙張尺度遠用中钃骥家樣準(CNS)甲4規格(210x297公龙) 81. 5 . 20.000(H) (請先閱讀背面之注意事項再填寫本頁) 装* 訂 線- 2128^1 A 6 B6 五、發明説明(ισ) 定 決 之 度 漿 退 3 輿 中 液 驗 試 之 述 所 \17 1* Β 例 於 品 樣 物 纗 i 置 由 可 度 漿 退 來 較 比 尺 標 色 8 紫得 與量 卽物 立锇 及白 乾漂 吸之 纸後 濾隨 用及 c 和滌液 洗洗漿 清齡無 水經幾 冷此物 經,識 後定該 隨決gnb) 度 刻 之 定 決 之 度 白 潔 計 光 00的 ph物 Θ 我 Γ 38 F 之 ml 5 理 is處 ze預 之經 鏡此 光 -濾計 46% R Π 有10 紀 S 6 S 用 e J e 由 Γ 可以 度 , 白定 潔決 夾 % Π (請先閲讀背面之注意事項再填窝本頁)O _Β_6_ V. Description of the invention (') The present invention relates to the use of soaked alkyl f as a quilted fabric, yarn or short-woven fabric printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs and the day-to-day physical activity agent. The liquid cleansing yarn that was born from the whole birth. All eyes are on. He is susceptible to being affected by the shade, the pulp, or the like, the right dimension, the boundary, the easy-to-use color, the dirty liquid, and the dirty liquid in the suitable Weizhong medicinal surface and the Du Xiebi type. The pre-processed weaving and pulping are of a high degree of rationality, and they can be treated like a liquid. If they are to be floated in the sky, there is a gold type. Touch, this heat must be moistened on one side, and there is a sizing solution for quilts and mixed detergents. It will become a tangled pair of liquid or polyester, and learn to remove. Knowing the single η dyeing quality of the whole hemp halide / washing and chemical fixation should poison the alfalfa gIBJd titanium content, yarn removal-and liquid washing wet entanglement to remove toughness and base: to -Τ-Ι-Γ -Hebi Lifang coated pulp side lye _ Turonine is #property for the physical properties of the emperor. It is difficult to retreat the animal husbandry. Pan Tongzhong ’s sexual attack can be right and the living capacity is helpful. The shadow is thin. Even the living things are the same things in the eyes and eyes, and the yarns are removed or the face wash and objects must be connected to the water. In addition to the uncut face, except for the color wash, etc., it is turbid. H1 has the effect of cleaning the woven cashmere or making the dyeing of the woven fabric. The 5 retreats with constant strength bleaching fruit are often planted, such as the treatment of the external base or the increase of the maintenance of the whisker list, and the pre-ordering of the objects and utensils. The bleaching theory of all things, the solution to the pre-prediction, and the inevitability are all included. Retreat, state that the first class of bleaching power is reduced by the use of wool, quality and natural agents, and the first species is in principle. Yes (please read the precautions on the back before filling in this page) This paper size Xiaoyong used in the "National Standard (CNS) A 4 specifications (210x297 mm) 81. 5. 20,0000000 Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. A 6 Magic U__B6 V. Invention description (>) Subtype Surfactant household cleaners have been described in European Patent Publication No. 70014. In addition, liquid cleaners containing alkyl r and certain other non-ionic surface active agents and yin chicken type interface active cuttings are known from European Patent Publication No. EP105556. International Patent No. W0 86/2943 describes liquid detergents containing alkyl alfalfa and typical anionic surfactants. However, the surface active agent used for pre-identification is more suitable for users than household cleaners. Therefore, the surface active agent used for the pretreatment of the suspect must have higher resistance to chemicals and heat. In addition, it must be able to separate more nasty debris from dirt, yarn and linters in the short time than dirt such as pulp, finishing agent, fruit joints, etc. International Patent Case No. W0 90/06353 refers to an aqueous «liquid cleaner for commercial laundries, which contains an alkaloid of formula R-0-Gx where R is C8- 14 and an Sx of 1.2-5 and contains 氲Vaporized sodium, sodium silicate, and sodium triacetate are used as rib washing ingredients. The diluted detergent liquid used in the Laundry Shop has good cleaning results for general household dirt such as dust / lanolin, blood, milk, cocoa, gray tint / sebum (water hardness 05 dH). However, in the fabric pretreatment, it must also remove a larger amount of other contaminants than in household cleaning. In addition, in the fabric pretreatment, the slurry, finishing agent, pectin, hemicellulose, ( Cotton) wax, metal wax, etc. The method proposed by the present invention can be used with a surfactant-containing additive suitable for fabric pretreatment, which is resistant to chemicals and emu, has high wetting power and dispersing power, and can make the treated suspects have excellent absorption It is bleached in parallel (please read the precautions on the back before filling the nest page). Binding-Ordering. This paper uses the middle country »quasi (CNS) T4 specifications (210x297 g *) 81. 5. 20,000 (3) 2128 ^ 1 A 6 B6 Printed by the Consumers ’Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Invention Instructions (Orders) are available to those with a high degree of innocence. In addition, the additives containing interface active agents are ecologically safe, It is endless and completely biodegradable in a short time. This question has been determined by "using the alkyl alfalfa of formula I R 1-0-(G!„ (I) where R 1 is a C 3-w alkyl group, G is a glucose unit and η is a number of 1-3 It is treated as a natural and / or synthetic ribbed agent containing surfactants pretreated by a single fabric, yarn or linters. "In the context of the present invention, the false fabric refers to the entanglement of woven and knitted fabrics. Succulent secondary. Subsequent pretreatment includes cleaning, lye washing, bleaching and desizing. The term alkyl alfalfa is commonly applied to alkyl monoalfalfa (n = l) and its oligomeric t (oligomeric degree η) The mixture is not higher than 3). The alfalfa used according to this arrogance is a compound known by itself, and their ______-.... The splitting method has been described in many documents, such as US Patent-PSS 3,547,828, 3,772.269 And 3, 839, 318 and so on. European patent case EP 301 298 • EP 357 9 6 9 and EP 3S 2 6 7 1 equal and DE-0S 3 9 2 7 9 1 9 It can be cracked by the direct reaction of excess alcohol and acid as a bracelet medium or by the transacetalization of low alcohol as a solvent and reactant: the alkylglycan used according to the present invention is Kinds of inulin, citrus, pi pond, galacto, tarotang, guluotang, allose, altrose, edible sugar, arabinian yam, xylose, leisuose and ribose and C 3-: 4 Alcohol reaction; equivalence ponds are similar to glycerol glycan (glycan) bonds to connect, and the number of ponds Z connected to each other can be identified by the degree of recruitment (like η in formula I) like , As an analytically determined value, the oligomerization degree π can also be a fraction, generally (please read the precautions on the back before writing this page). Binding · Threading · Various paper scales are used in the Chinese Iron Man (CNS) A 4 Specifications (210x297 g *) 81. 5. 20,000 (3) A 6 B6 212821 5. Description of invention) (Please read the notes on the back before filling in this page) Between 1 and 3, especially between 1.1 and 1.4 In between, the pond units derived from the sugars mentioned are represented by the letter G in formula I. In the context of the present invention, G is preferably derived from grapes, R1 in formula I is an alkyl group, and R1 is preferably derived from From straight-chain C3- 14 alcohols, these alcohol-like fatty alcohols can be obtained from the original family of regeneration in a known manner. Compounds of formula I where R1 is a branched C3-i4 alkyl group, which are derived from branched chains alcohol, Chain alcohols can be made into oxidized alcohols by oxidative synthesis, and R1 can also represent a mixture of C8-14 alkyl groups. Mixers like these groups can be derived from branched CS-14 alcohols commonly encountered in oleochemicals Mixtures. The alkyl glycans of formula I where R1 is a branched 12 alkyl group are suitable for the purposes of the present invention, and the alkyl alfalfa of formula I where R1 is a branched Cid alkyl group is preferred. In the present invention In this context, the term "almost all" in this regard means that 80-10.0% of R 1 represents n-decyl, so R1 can be derived from n-decyl alcohol R 0 containing 80-100% of the reset amount Alcohol mixture of Cf3-14 alcohol (mostly C8) in an amount of -20% by weight. In the formula I, the alfalfa in which G is a glucose unit and π is a number of 1.1-1.4 and is a branched alkyl group containing almost 10 tilt C atoms are more preferred. As far as their production is concerned, the alkylglycols used in accordance with the invention may contain small amounts (preferably less than 2% by weight) of unreacted C3-14 alcohols, but this does not include shellfish consumption by the Central Standards Bureau of the Ministry of Economic Affairs Cooperatives print the use of α by local film agency prostitutes etc. In the pretreatment liquid, alkyl alfalfa is easily used as its solution or dispersion, especially n-butanol, 2-ethylhexanol and / or on water and / or organic solvents Glycerin can be used as a solvent or dispersant. Convenient to contain "according to the solvent and dispersant-6-National Paper Standards (CNS) A4 specifications (210x297 g **) for each paper size 81. 5. 20,000 (3) ^ > 12821 A 6 B6 Economy Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Development 5. Invention Description (5) 50-100% by weight of this amount of water as a solvent or dispersant and 0-50% by weight of this amount of organic matter based on the solvent and dispersant Aqueous solution or aqueous dispersion of "solvent" of alkylglycol. Aqueous dispersions of alkyl glycosides are also known to include "lake liquid" known to experts. These products. Generally speaking, use an amount of a solution or dispersion of alkylglycol that "can make the content of the active substance of alkyl W in the equivalent of 1 liter of pretreatment liquid in the range of 0.1-10 g / liter". In the case of synthetic fabrics, yarns or short piles, the content of alkyl alfalfa active substance in the lotion will be within the range of "0.5-2.5 g / L solution". Add the dispersion to the lotion, or use the amount of carbamate, gluconate and / or according to "0.5-2.5 g / liter of lotion". g a typical polyvalent chelating agent of acrylic acid salt and especially keto acid salt (like SeCU "〇n®540 of H enke 1 KG a A product] to mix with alkyl glycerin. According to the present invention, this alkyl f is preferably used In order to clean synthetic duvets or yarns or velvets, especially polyester, polyacetamide, velvet fiber, acetate labyrinth and / or polypropylene eyes, the situation is assumed to be at normal temperature but it is best In the range of 4 0-8 0 υ, the alkyl alfalfa of formula I is best used as a rib agent containing surfactants in the desizing, lye washing and / or bleaching centers. In natural knitting or synthetic knitting In desizing, alkyl glycerin is used in desizing liquid with its aqueous solution or dispersion, the amount of which is the amount of active substance of alkyl alfalfa in ~ 1-4g / liter of levy fee. As needed, this type of alkyl Ju can be used in combination with the amount of general enzymes such as amylase that are generally required for desizing. These enzymes are generally set according to "2-15 g / liter of desizing solution" and -7 -(Please read the precautions on the back before filling the nest page) Binding · Binding-Line. This paper uses the standard of Zhongyuejia's standard (CNS) Grade 4 (210x297 g *) 81. 5. 20,000 ( ) 2128 ^ 1 A 6 B6 Ministry of Economic Affairs Bureau of Standards consumer cooperative print five employees, description of the invention) and treated with an alkyl clover, desizing of dummy row by an unusual manner, the resulting fabric exhibits excellent needle MTR degree of desizing. When bleaching, the alkyl glycoside is used as an aqueous solution or dispersion of the other, the amount of which is the specific active substance content in the range of "0.25-7.5 grams per liter of bleach". According to the present invention, alkyl glycosides Good for bleaching natural and / or synthetic quilts or yarns or linters, especially for alkaline bleaching (aqueous) cotton, cotton / polyester, cotton / polydiene nitrile, cotton / viscoli Dimension or cotton / poly s button. This type of whitening liquid contains h2〇2 as a bleaching agent or a compound that forms H2〇2 in water. The pH of the bleaching liquid is preferably adjusted to at least 9 with NaOH or KOH. Each liter of bleach generally contains 3-100% of 35% by weight of H2 02, 0.5-50 g of NaOH and / K0H, 2.5-50 ml of diazepam (especially the solution of silicate reed and / or potassium silicate), 0.1 -1.0 g of magnesium salt (especially MgS〇4), 0.5-10 g of carbamate, glucuronate and / or polyacrylic acid and other sequestering agents (especially Secu "on: ® 540 (Henkel KGaA product, ketoate), the rest in one liter is made of gutters. The bleaching temperature is from 201C (cold or bleached) to 120tM (heat or bleached) and preferably at a temperature of 70-120t. The present invention uses alkyl glycosides for bleaching. On the one hand, it has excellent liquid absorption, that is, a large amount of bleach is absorbed by a single fabric or yarn or short pile, and it has a very high degree of whiteness on the g side. In addition, the bleach is a single fabric or yarn Or velvet after bleaching with the alfalfa in the co-appliance, it has a very high absorption and a high and uniform dye waste. 3 Wash the cotton-containing quilt fabric or yarn or velvet with age liquid (preferably pure ( Please read the precautions on the back before filling the nest page.) Binding. Threading. This paper size is not the same as the CNS A4 specification (210x297 5) 20,000 (2) B6 BL1_ V. Description of invention (r) (Please read the precautions on the back before filling out this page) At the time of Mian 1, emulsified glycan was used for its aqueous solution or dispersion, The amount of the active substance is in the range of "0.25-7.5 g / liter washing liquid". This green washing liquid is generally sickled to a pH value of 10-14. It is better to throw 0.25-7.5 grams per washing liquid (Based on the content of active substance) Alkyl alfalfa aqueous solution or dispersion and 2-100 grams of alkali i is preferably NaOH and / or KOH) and 0-5 grams of the above-mentioned sequestering agent. Alkaline washing is pseudo-normal And it is best to carry out at a temperature of 95-10 Of. The use of alkyl alfalfa in continuous washing can allow a very high liquid absorption in a short period of time. 3 Add general suppression of foaming such as silicone, minerals Oils and / or phosphate esters are beneficial to the pretreatment of entanglement. In all fabric pretreatments, alkyl alfalfa is used in accordance with the present invention to provide extremely high absorption. The pretreatment bath only needs to be connected for a short period of time. Information about the pretreatment of the mounds in the industry (determined by the mounds and the pretreatment method of the pain> also please Read 丨 丨 U Enri's Encyclopedia of Industrial Chemistry f book, etc. 2 3 volumes 2 9-3 1 pages, published by V er 1 as C hem 丨 e, We nhei π in 1983. Case A) Alkyl The production of alfalfa can be produced by the consumption cooperation of the Central Standards Bureau of the Ministry of Economic Affairs to produce 50% by weight of alkyl ff liquid (oligomerization degree η = 1. 2 5). Directly synthesized from anhydrous glucose: Β) 冸 用 冽 m 1 ·· Desizing -9 ~ 81. 5. 20.000 (H) This paper size is not used in the Zhongzhijia kneading (CNS) A 4 specifications (210x297 g *) A 6 B6 21 ^ 8 ^ 1 V. Description of the invention (3) In a continuous machine used in the laboratory, it is impregnated with 5 grams of enzyme (Enzylase® HT, Diamalt product) and 5 grams of the alkyl alfalfa of Example A. A cotton twill cloth sized with starch has a dipping temperature of 70t and a liquid absorption rate of 100%. The reaction can be made by running and steaming (102t:> 3 minutes) in a continuous or steam generator. The twill fabric is then hot washed in a continuous washing machine (with 6 washing chambers) and dried on the tensioning machine. The degree of desizing can be determined by placing the collected fabric into 0.005 mol / liter iodine solution of S degree (C). The W solution can be formulated as follows to dissolve 10 grams of KI in 100 ml of water and add 0.635 grams After iodine is shaken, the solution is mixed to dissolve the gold, and the solution is made by adding 800 ml of water and finally making 1 liter with ethyl yeast. (After being immersed in iodine solution for 1 minute, simply rinse the substance with cold water, filter it to dry, and compare it with the TEGEW Α purple scale immediately. The scale is divided into 1-9 scales, and the 9 scale indicates Any scale of gold without slurry and more than 6 indicates a moderately sized sprouting object. The 9 scale on the purple scale is false to follow the example B 1) The measured amount of desizing is easy to say. There is no more slurry on the object. Example 2: Washing in a laboratory-connected Burmese machine containing 5 grams of NaOH (100 96 weight) per litre, 2 ml of chain salt (Securon®540 (S from Henkel KGaA)) and 5 grams of alkyl alfalfa from Example A The liquid is used to impregnate the desizing cotton twill. The impregnation temperature is 70 ¾. The liquid absorption rate is 80%. After impregnation and water rolling, the fabric is continuously collected and steamed for 5 minutes, in a continuous washing room with -10 *. Paper size Λ Zhongyun Gull Family Sample Standard (CNS) f 4 specifications (210x297 mm) (please read the precautions on the back before filling in this page). Installation and line. Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 81. 5. 20.000 (H)-Fifth, the description of the invention (9) A 6 B6 Printed in the washing machine of the Central Standards Bureau of the Ministry of Economic Affairs or the washing machine for post-washing and neutralization > 6.6 grams per liter a 0H (100% by weight), 0.8 g example A) The solution of Yoshigan and 0.3 ml oxalate i S ec U Γ 0 Π 5 40 (He nke 1 KGa A) comes to sharpe η first Wash room, evaluate the test m, and use the swell height method (D IN 53 924) to determine the m Water rate »The following values are obtained * The height r of Zhang Gao in millimeters 15 seconds after 13 30 seconds after 16 seconds after 60 seconds 20 Example 3: The gray cotton cloth on the white powder is subjected to alkaline washing and the condition-eg洌 B 2 I described, but not neutralized, in use contains 0.15 g Hg S0 • 10 Η 2: 0, 12 ml of sodium silicate solution (38 ° B 'e) ♦ 6 g NaOH (100% by weight), 5 g of Example A) alkylglycol, 2 g of oxalate (S ecu γ ο η 5 4 0 (He π k el KGa A) and 40 ml of H 2; 0 2 (3 5 % Weight of liquid before immersion-drying on the tensioning machine> immersion temperature of 20 and liquid absorption rate of 10 0% SL water t after steaming in a m-type steam generator at 1 0 2 t 8 xi »and then hot washed in a Burmese washing machine, and then neutralized, with 1 gram of Na 0 H 丨 100% by weight per liter), 0.8 g of case A) of Yoshigan and 0.3 g of rice Acid salt (S ecu Γ ο η The liquid of 5 4 0 (He π k el KGa A) comes to the first washing room in sharpe η even m or type washing machine »last» The m object is dried on the tensioning machine, this test consists of desizing degree, whiteness And water absorption rate. -1 1-The size of this paper is far away from the Chinese standard (CNS) A 4 specifications (210x297 male dragon) 81.5. 20.000 (H) (please read the precautions on the back before filling this page) Line-2128 ^ 1 A 6 B6 V. Description of the invention (ισ) Determining the degree of pulp retreat 3 As stated in the Yuzhong liquid test \ 17 1 * Β Examples are compared with the degree of pulp retreat in the sample. The scale color 8 is purple and the amount of the material is osmium and white dry bleaching paper. It is used after filtering and c and washing with liquid detergent. It is clean and dry after a few cold. The degree of indecision is the ph of the white clean meter light 00 Θ I Γ 38 F of the ml 5 The reason is the pre-mirror mirror This light-filter meter 46% R Π has 10 times S 6 S with e J e by Γ can be degree, Bai Dingjie decided to clamp% Π (please read the notes on the back before filling the nest page)

C 下 導 獲 定 決 來 定法 決度 之高 率高 水脹 圾4( 的92 ο 物 3 4 .¾ 5 纽 4 7 - N 8 之 I 為過} m: 理 處 預 绖 依 度 可 高 率 之 水果高 吸结賬 列 計 米 毫 以 後後後 秒秒秒 5 0 0 13 6 8 3 1 2 裝· 訂· 線_ 經濟部中央標準局员工消費合作社印製 本紙張尺度逡用中鷂家揉準(CNS)甲4規格(210x297公釐) 31. 5 . 20,000(H)C leads to a decision to determine the high rate of legal decision and high water swelling 4 (of 92 ο things 3 4. ¾ 5 New 4 7-I of N 8 is over) m: Deal with pre-reliability can be high rate The high-suction checkout of the fruit counts the meter after the second, the second, the second, the second, the second, the second, the second, the second, the second, the second, the second, and the second. Standard (CNS) A4 specifications (210x297 mm) 31. 5. 20,000 (H)

Claims (1)

ι3"^-Ί ;j -Vs Α7 Β7 C7 D7 第811 0 3419號「使用特殊烷基苔當作鏃物預處理之肋劑」 專利案 (82年7月修正) A申諳専利範圍 一種用作含界面活性劑之助劑以預處理天然及/或合成 之被單狀餓物或纱或短绒的式(I)烷基苷 (請先閲讀背面之注意事項再埸寫本頁) m. 濟 部 t 央 標 準 局 s 工 消 費 合 作 杜 印 R1 -〇-(G)n 其中R 1像線型C - C 8 1 至1 . 4之數。 2. 如申謫専利範圃第1 液形式用之。 3. 如申誚専利範圈第1 液形式用之,用量為 如申請専利範園第1 薄I之助劑以用於退漿 5.如申誚專利範園第4 液形式用於_性洗滌 至7 . 5克。 艮如申謫專利範園第4 液形式用於退漿液中 Γ7.如申請専利範園第4 液形式用於灌白液中 7.5克。 (I) 烷基,G傜«萄耱單元,n係1 . 1 2 項之烷基苷,其傺以水溶液或分散 項之烷基苷,其像以水溶液或分散 每升預處理液含有0.1至10克。 項之烷基苷,其僳當作含界面活性 、洗滌及/或漯白。 項之烷基苷,其係以水溶液或分散 液中,用量為毎升洗滌液含有0.25 項之烷基苷,其你以水溶液或分散 ,用量為每升退漿液含有1至4克 項之烷基苷,其换以水溶液或分散 ,用量為毎升灌白掖含有0.25至 裝· 、11. 本紙張尺度通用中國國家棵準(CNS)甲4規格mo X 297公釐)ι3 "^-Ί; j -Vs Α7 Β7 C7 D7 No. 811 0 3419 "Using special alkyl moss as a rib agent for the pretreatment of noodles" Patent case (amended in July 82) A application for a range of benefits Used as a surfactant-containing additive to pretreat natural and / or synthetic sheets, yarns or velvet formula (I) alkyl glycosides (please read the precautions on the back before writing this page) m. The Ministry of Economic Affairs and the Central Standards Bureau s industrial and consumer cooperation Du Yin R1 -〇- (G) n where R 1 is like a linear C-C 8 1 to 1.4 number. 2. For example, the first liquid form of Shenfanli Fanpu is used. 3. If it is used in the first liquid form of Shenzhan Fan Circle, the dosage is the additive used in the first thin I of the Zhanli Fanyuan for desizing. 5. If the fourth form of Shenzhan Patent Fanyuan is used for Wash to 7.5 grams. Gen. 4th liquid form of Shenfan patent Fanyuan is used in desizing liquid. Γ7. If applying 4th liquid form of Lifan Garden is used in 7.5 grams of white liquor. (I) Alkyl group, G 傜 «grape unit, n is the alkyl glycoside of item 1.12, which is an aqueous solution or dispersion of alkyl glycoside, which is like an aqueous solution or dispersion containing 0.1 per liter of pretreatment liquid To 10 grams. The alkyl glycoside of the item is considered to contain interfacial activity, washing and / or bleaching. The alkyl glycoside of item is an aqueous solution or dispersion with an amount of 0.25 alkyl alkyl glycosides per wash. The aqueous solution or dispersion with an amount of 1 to 4 grams of alkanes per liter of desizing solution Glycoside, which is replaced by aqueous solution or dispersion, the dosage is 0.25 to 5% for each litre of Baiye. 11. The size of this paper is universally applicable to China National Standard (CNS) A4 (mo X 297 mm)
TW081103419A 1991-06-18 1992-05-01 TW212821B (en)

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EP0716180A1 (en) * 1994-12-08 1996-06-12 Ciba-Geigy Ag Wetting agent for mercerizing
ES2151950T3 (en) * 1994-12-22 2001-01-16 Ciba Sc Holding Ag N-CYANOMETILATED CHITOSANS AND THEIR HYDROLYZED PRODUCTS.
GB9618575D0 (en) * 1996-09-05 1996-10-16 Courtaulds Fibres Holdings Ltd Fibre treatment
SE510989C2 (en) * 1997-10-29 1999-07-19 Akzo Nobel Nv Highly alkaline compositions containing a hexyl glycoside as a hydrotrope
EP0919608A1 (en) * 1997-11-25 1999-06-02 The Procter & Gamble Company Use of a polyhydroxyfatty acid amide compound as a softening compound
DE10030648A1 (en) * 2000-06-29 2002-01-10 Stockhausen Chem Fab Gmbh Use of alkyl polyglucosides as modifiers for the production of cellulose fibers by the viscose process
DE10303328B4 (en) * 2003-01-28 2007-04-26 A. Monforts Textilmaschinen Gmbh & Co.Kg Process for continuous enzymatic desizing
JP5647515B2 (en) * 2007-04-27 2014-12-24 フォルシュングスツェントルム ユーリッヒ ゲゼルシャフト ミット ベシュレンクテル ハフツングForschungszentrum Juelich GmbH Mixture comprising alkyl polyglucoside, co-surfactant and polymer additive

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US3598865A (en) * 1968-02-07 1971-08-10 Atlas Chem Ind Polyglycosides and process of preparing mono and polyglycosides
US3640998A (en) * 1969-06-18 1972-02-08 Richard C Mansfield Alkylene oxide adducts of alkyloligosaccharides and their mixtures with alkylene oxide adducts of bord alkyl glucosides and alkanols
US4781725A (en) * 1986-09-17 1988-11-01 Staley Continental, Inc. Enhanced transfer printability treatment method and composition

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