04409 Λ 6 Π 6 五、發明説明(i ) 經濟部屮央標準局A工消作合作社印製 詳细說明: 本發明係«於一種罩幂式唯讀記值體(Mask ROM)之暗碼 (code)離子植入製程之改良•以期藉由此一特殊製程,箱 短該罩幂式ROM產品之交期。 罩幕式ROM為目前最廉價的記憶體(依每位元價格計算 )·且因為它的市埸不虡匱乏,遂一直是國內外潰腰《路 的製造廠商競爭的焦點,除了新结構,新製法和新設計的 罩幕式ROM為各廠商的競爭主因外·另有一項相當重要的 因素,那就是產品的交期。顧名思義•產品交期就是指顧 客委製不同的ROM開始,到產品交貨的時間,因此,若產 品交期的時間得Μ縮短,則市場競爭力必亦能大幅提昇。 在目前的罩幂式ROM製程中,此製作方式是於接受客戶 委製之形式及功能後•先規削其中之0與1碼*並製成對 應之光罩,然後Μ暗碼離子植入的方式(code implantation)將雄子打人記憶膜基層中·接下來之步驟 則如一般ROM的製程,共需經過暗碼蝕刻/植入,厚氧化 層沉稹、接觸窗對準/蝕刻、金羼線連接、謅層沉棟、產 品测試等步驟。因此*自接受客戶委託製作所需之ROM之 日起到產品交期日至少箱要3-4個星期。此一時限對於 目前產品需求競爭甚炬的今日賁為一相當不利之因素。 有鑑於此•本發明之目的即為解決交期日之問題而設。 根據傳统的暗碼離子植入罩幂式唯讀記憶體(ROM)之結構 ,其能容許的暗碼離子植入步驟因受限於接觸點佈埭 (contact layout)之限制,故只能在接觸(contact)製程 (請先閲命背而之注意事項^填莴本頁) 裝. 訂_ 本紙尺度边用中《8家樣準(CNS)T4規怙(210Χ297公3t)- 204409 Λ 6 Π 6 五、發明説明(上) 經试部十央櫺準而Α工消费合作社印^ Κ前賁施,因在其傳統方法中,做Ρ*和ίΤ離子後,半導體 结構上即已具有一闼緣麕,因而,做暗碼離子植入時需要 較高的能量使離子穿适該絕緣層1 ,故在量產上有其困擾‘ 之處。針對上述限制發明人乃思及如何將暗碼植入之步驟 挪在產S製程的後段,Μ致於當接受客戶委製產品時,只 要加Μ少許步睡)(包括金羼線連接、護層沉積和產品拥 試等步驟)即可製成,而達到減少產品交期之時日的目的 〇 根據本發明之原理,其中記憶雅結構必須為記憶單元附 近無接觭窗者,(如埋入式位元線之结構),並配合特 殊之製程方可不受接«點佈埭之限制,而將產品交期之時 日降低。 為說明本發明之原理,玆Κ較佳實拖例之說明R合下列 圃式敘述如後: 圓1(A)- 1(E)所示為根據本發明之實拖例之製作流程圈 ;和 圈2(A)- 2(D)所示為根據本發明之另一實施例之製作流 程圖。 囫1(A)- 1(E)所示為本發明之第一實施例之製程圈。依 照本發明之原理,其能使記憶單元暗磚離子植入步驟延後 之先決要件是該記憶單元必須為埋入式Ν*位元皞结構,因 為該结構中,每一記憶體單元四周並無接觸窗,故無需受 限於接觸窗對製程之限制,本第一實施例之製法如下: -⑴依一般的埋入式『位元埭單幂式R0H製程*進行至閛 (請先間請背而之注意事項^项寫本頁) 裝- 線- 本紙張尺度边用中Η國家楳準(CNS)Ή規怙(210x29/公別- Λ Λ ο 9 66 ΛΠ 五、發明説明(3 ) 經濟部屮央標準沁A工消赀合作社印5i 極独刻完後; ⑵在閘極1上成長曆Si〇2 5 •埋入式N*位元線3上亦 同時成長一氧化層2,其中之閛極可為複晶矽或其他材質 ,(如圄1 (A)所示); ⑶在鼷1(A)所示之结構中再沉積一層厚度>l〇〇 A之 SiaN* 6 ,如囫1(B)所示; ⑷M CVD (化學汽相沉積)方式成長一靥氧化層7 (BPSG 或PSG)於圖1(B)之结構上,如麵1(C)所示; ⑸進行接觸窗對準及蝕刻製程(此時記憶單元遇麵並無 接觸窗); ⑹進行暗璀對準,Κ光箪8蓋住不做暗碣離子植入之部 份•然後做選擇性蝕刻處理,此蝕刻步驟採用湄蝕刻或乾 蝕刻皆可; ⑺進行暗碼離子植入步》•如圓(D)所示,植人之離子 位置如符號4所示之位置; ⑻去除光阻、Μ硫酸清洗後*做金属曆沉積;和 ⑼接著Μ檷準的CMOS製程製作。 在上述實例例中,Si3IU雇6的目的係用來保護Si02® 5免於被蝕刻,即其作為步驟(6)中蝕刻過程的终止指示, 即独刻步驟到該庙後即停止,不會再孅續蝕刻其下之 、. Si〇2層,因此•聚矽層1上的介《厚度能予以準確挖制* 使得後續之暗碼離子植入之能饊能精準的確定。 此外,上述《施例尚可視需要以熱磷酸蝕刻去除暗碣植 入區之Si3fU 6 ·此判斷則視Si3H4之厚度是否會影響到 (請先w3ft背而之注意事項邛埙窵本頁) 本紙ft尺度边用中a a家樣準(CNS)甲4規格(210x297公5 ^04409 Λ 6 Β 6 五、發明説明(+) 經濟部屮央榀準局β工消合作杜印5i 暗碼離子植入所需之能量而定,做Si3»U曆蝕刻後之结構 園如圃1 (E>所示。 本發明之方法尚可以第二實梅例之製程賁施之,其步嫌 包含: ⑴同第一實施例之步软⑴; ⑵同第一實施例之步费⑵,但其中5丨〇2層5為熱氧化成 長之Si 〇2,其厚度必須控制於某一定值,如800 A ·此時 該記憧單元之結構如圔2(A)所示; ⑶不進行Si3H4層 6之沉稹,直接KCVD方式沉租一氣 化層7(如PSG)於該5丨〇2曆5上,如圈2(B)所示; ⑷同第一實施例之步《⑸; ⑸同第一 K腌例之步明(Θ,如晒2(C)之圈示所示,但若 選擇濕蝕刻時*係利用CVD氧化層7蝕刻速率大於聚矽物 熱成長《化層Si〇2 5 蝕刻率的方式,K時間控制,使得 聚矽層1上殘餘之氧化層5厚度介於500-800 Α之間; (Θ進行暗碼離子植入步驟,如躕2(D)所示;和 ⑺餘者與第一實施例之步驟⑻和(8)相同。 此寊施例之特點在於利用CVD氣化層7和聚矽層上之热 氧化層5之蝕刻率不同的方式做湄蝕刻,使得聚矽雇1上 之氧化層的厚度得以適當地控剌*以利於後續之暗碼離子 植入之進行。此方法與第一*施例所述之方法比較起來, 較不易控制氧化層的厚度,但其製程較為簡單。 如上所述•無論以第一或第二實施例製作本發明•在進 行暗碼雔子植入Μ前,已先進行了若干製程,故而由客戶 (請先wift背而之注意令項沔填寫本頁) 裝- 線· 本紙浓尺度边用中a困家標準(CNS)f4規格(210x297公史)6 - Λ 6 Π 6 ^〇44〇9_ 五、發明説明($) 委製設計開始(即由暗碼離子植入步驟)到整個製程完成期 間,約可較傳统方式減短一半κ上之時間。 本發明之上述實施例尚可予κ修改及變化,而不脱離本 發明之範睡,本發明之範圍應如後列之申謫專利範圃所列 (請先閲讀j而之注意事項杓填寫本頁) 經濟部屮央榀準局β工消仪合作杜印奴 本紙法尺度边用中Η國家揉準(CNS) T4規怙(210x297公if) 704409 Λ 6 Π 6 V. Description of the invention (i) Printed by the Ministry of Economic Affairs, Bureau of Standards, A Industrial Consumers Cooperative Society Detailed description: The present invention is «in the code of a mask ROM (Mask ROM) ( code) Improvement of ion implantation process • In order to shorten the delivery time of the cover power ROM product by this special process. The mask ROM is currently the cheapest memory (calculated based on the price per bit). And because of its lack of market, it has always been the focus of competition among manufacturers at home and abroad. In addition to the new structure, The new manufacturing method and the newly designed cover-screen ROM are the main reasons for the competition of various manufacturers. Another very important factor is the delivery date of the product. As the name implies, the product delivery time refers to the time from the start of the production of different ROMs to the delivery of the product. Therefore, if the product delivery time is shortened, the market competitiveness will be greatly improved. In the current mask power ROM manufacturing process, this manufacturing method is based on accepting the form and function of the customer's commission. First, cut the 0 and 1 yards * and make the corresponding photomask, and then implant the cipher code ion. (Code implantation) Hit the male son into the memory film base layer. The next steps are like the general ROM process. A total of code etching / implantation is required. Thick oxide layer sinks, contact window alignment / etching, and gold wire connection Steps of Shen Dong, product testing, etc. Therefore, it takes at least 3-4 weeks from the date of acceptance of the customer's commission to produce the required ROM to the product delivery date. This time limit is a very unfavorable factor for today's Ben, which is highly competitive in product demand. In view of this, the purpose of the present invention is to solve the problem of delivery date. According to the structure of the traditional code ion implantation cover power-type read-only memory (ROM), the allowable code ion implantation step is limited by the contact layout, so it can only be used in contact ( contact) manufacturing process (please read the precautions ^ fill in this page) to install. Order _ This paper is used in the "8 home standards (CNS) T4 standard (210Χ297 public 3t)-204409 Λ 6 Π 6 V. Description of the invention (Part 1) The test department is approved by Shi Yang and printed by the A-Consumer Cooperative Society ^ Κ 前 輲 施, because in its traditional method, after making Ρ * and ίΤ ions, the semiconductor structure already has a long edge Therefore, high energy is required to make the ion implantation suitable for the insulating layer 1 when doing code ion implantation, so it has its problems in mass production. In view of the above limitations, the inventor is thinking about how to move the password implantation step in the later stage of the production S process. When the customer commissions the product, only add a little step to sleep (including the Jinyu line connection and the protective layer Steps such as deposition and product testing) can be made to achieve the purpose of reducing the time of product delivery. According to the principles of the present invention, the memory elegant structure must be one without a window near the memory unit (such as buried The structure of the type bit line), and cooperate with the special process can not be restricted by the connection point, and the time of product delivery is reduced. To illustrate the principles of the present invention, the description of the preferred real drag case KK and the following garden-style description are as follows: Circle 1 (A) -1 (E) shows the manufacturing process circle according to the real drag case of the present invention; Hehuan 2 (A) -2 (D) shows a manufacturing flowchart according to another embodiment of the present invention.囫 1 (A)-1 (E) shows the process circle of the first embodiment of the present invention. According to the principles of the present invention, the prerequisite for the postponement of the dark cell ion implantation step of the memory cell is that the memory cell must be an embedded N * bit structure, because in this structure, each memory cell is surrounded by There is no contact window, so there is no need to be limited by the contact window on the process. The manufacturing method of this first embodiment is as follows:-⑴ According to the general embedded type "bit-bit single-power R0H process *, proceed to the end (please first Please pay attention to the note ^ item write this page) Install-Line-This paper is used in the middle of the national standard (CNS) Ή regulations (210x29 / public category-Λ Λ ο 9 66 ΛΠ V. Invention description (3 ) The standard of the Ministry of Economic Affairs, Qin A Industrial Consumer Cooperative Cooperative, printed the 5i pole; ⑵Grow the calendar Si〇2 5 on the gate 1 • The embedded N * bit line 3 also grows an oxide layer 2 at the same time , Where the electrode can be made of polycrystalline silicon or other materials, (as shown in Figure 1 (A)); ⑶ in the structure shown in Na 1 (A) and then deposit a layer of thickness> 10〇A of SiaN * 6, as shown in Fig. 1 (B); ⑷M CVD (Chemical Vapor Deposition) method to grow an oxide layer 7 (BPSG or PSG) on the structure of Fig. 1 (B), as shown in Fig. 1 (C) ⑸ Perform contact window alignment and etching process (at this time, there is no contact window when the memory cell meets the surface); ⑹ Perform dark alignment, Κ 光 箪 8 covers the part that does not do dark ion implantation • Then do the selectivity Etching process, this etching step can be used by Mae etching or dry etching; ⑺ Perform code ion implantation step >> As shown in circle (D), the position of implanted ion is as shown by symbol 4; ⑻Remove photoresist, After sulphuric acid cleaning, metal deposition is performed; and ⑼ followed by quasi CMOS process. In the above example, the purpose of Si3IU 6 is to protect Si02® 5 from being etched, which is the step (6 ) The termination instruction of the etching process in the process, that is, the single step will stop after reaching the temple, and it will not be etched continuously. The Si〇2 layer, so the thickness of the polysilicon layer 1 can be accurately dug The system * enables the subsequent determination of the energy implantation of the code ion implantation to be accurately determined. In addition, the above “Examples can still use hot phosphoric acid etching to remove the Si3fU 6 of the dark mound implantation area as needed. This judgment depends on whether the thickness of Si3H4 will affect Go to (please pay attention to w3ft first Qiongxunyu this page ) The ft scale of the paper is used in the middle of the aa home sample standard (CNS) A 4 specifications (210x297 male 5 ^ 04409 Λ 6 Β 6 V. Description of the invention (+) The quasi-bureau of the Ministry of Economic Affairs of the Ministry of Economic Affairs β Industrial Consumer Cooperation Du Yin 5i code ion Depending on the energy required for implantation, the structure garden after Si3 »U calendar etching is as shown in Garden 1 (E >. The method of the present invention can also be applied to the process of the second real example, and its steps include: (1) The steps are the same as in the first embodiment (1); (2) The steps are the same as in the first embodiment (2), but the 5 layer 2 is thermally grown Si 〇2, and its thickness must be controlled to a certain value, such as 800 A. At this time, the structure of the memory cell is as shown in Figure 2 (A); ⑶Rather than sink the Si3H4 layer 6, the KCVD method directly deposits a vaporized layer 7 (such as PSG) on the 5 calendar. 5 Above, as shown in circle 2 (B); ⑷ Same as the first embodiment step "⑸; ⑸ Same as the first K picking example step (Θ, as shown in the circle of sun 2 (C), but if you choose During wet etching, the etch rate of CVD oxide layer 7 is greater than the thermal growth rate of polysilicon, the etching rate of chemical layer Si〇2 5 is controlled by K time, so that the thickness of residual oxide layer 5 on polysilicon layer 1 is between 500- Between 800 Α ([Theta] password for ion implantation steps, such as undecided 2 (D) as shown; and a step ⑺ remainder of the first embodiment in ⑻ and (8) the same. The feature of this embodiment is that the CVD vaporization layer 7 and the thermal oxidation layer 5 on the polysilicon layer have different etching rates for the Mei etching, so that the thickness of the oxide layer on the polysilicon layer 1 can be properly controlled * In order to facilitate the subsequent code ion implantation. Compared with the method described in the first embodiment, this method is less easy to control the thickness of the oxide layer, but its manufacturing process is simpler. As mentioned above • Whether the first or second embodiment is used to make the present invention • Before implanting the coded carcass M, a number of processes have been carried out first, so it is up to the customer Page) Binding-Line · This paper is used in the thick-edged standard (CNS) f4 specifications (210x297 official history) 6-Λ 6 Π 6 ^ 〇44〇9_ V. Description of the invention ($) The commissioned design begins (ie From the code ion implantation step) to the completion of the entire process, the time on the κ can be reduced by about half compared to the traditional method. The above embodiments of the present invention can be modified and changed without departing from the scope of the present invention. The scope of the present invention should be as listed in the following patent application garden (please read j and note This page) The Ministry of Economic Affairs, the Central Bureau of Economics and Trade, the β-industrial instrument cooperation, the Duyin paper standard, and the Chinese National Standard (CNS) T4 standard (210x297 public if) 7