A6 B6 202489 五、發明説明(1 ) 本發明乃關於複合織維及其織物之開纖處理方法,適 合於處理的織維,其橫斷面以分割型及海島型爲主,〔如 圖四:(A)〜(F)所示〕,且以聚酯成分及聚醯胺成分形成複 數個分割之分割型複合繅維及海島型複合嫌維爲主。使用 本發明之分織處理方法對此嫌維予以處理之後,能使編織 物變成柔輭之布帛,而且可以染深色調及提高染色堅牢度 Ο 本發明乃提供一種使用分割複合纖維或海島型纖維製 造成布帛,再進行溶除開纖處理,而得到極高的分纖率, 同時藉此分割纖維使布帛成爲極柔輭織物之處理方法。 一般複合超細纖維開纖技術,已知者有以鹸性開纖( NaOH),或以苯甲醇或安息香酸或溶劑開纖(三氯乙烷) 等各種方法,此等方法各有優缺點。現在處理方法趨向節 省能源處理簡便,公害問題少,經濟效益高爲首要目標, 本發明之酸性開纖方法亦以此爲目的。 超細纖維不易濃色化,以往在開纖後染色,再以化學 方法處理之,如以氟素聚合物、矽氧聚合物、丙烯酸共聚 合物等方法,改變纖維表面反射率達到濃色化。一般來講 ,這些方法有濃色化不易、纖維物性降低、染色堅牢度降 低、加工成本較高等爲其缺點。 本發明乃着眼於以酸性開纖較碱性開縑更能節省能源 "...........( t vii ....... ________..... · ----¾. "*^*4··« .·«>· . ,且對織物纖維物性較無破壞,有較佳之強保持篆_,1且以酸 — …屮.丨~1 —'*—__ii I n -I _ I - ** ' — II· ^ ·— ._·.... 性開纖後再進行染色鬼能獲得濃色化,且染色堅牢度佳, 因而能改善碱性開纖或其他染色方法濃色化之缺點的事實 (請先閱讀计面之注意事項再填寫本頁) •裝· •線, 本紙張尺度適用中西困家標準(CNS)甲4規格(210x297公*) A6 B6 202489 五、發明説明(2 ) ,而硏究開發者。 傳統複合超細纖維進行鹹性開纖,例如有以NaOH 10 〜30 % 〇. w· f及浸透劑(陽離子)在高溫〜·130°(:處理 之,使聚酯(PET)纖維減量達到開纖’聚酯部份被NaOH 減量加水分解產生乙二醇造成大量寡聚合物(〇1 igomer), 易造成纖維強度下降,纖維變黃,陽離子界面活性劑殘留 ,造成往後染色工程染斑發生,耐光牢度差,継維織物易 滑溜及大量寡聚合物和碱液廢水等問題產生。 本發明另一突破之製法爲,超細纖維織物先經進行染 色,然後,再以酸性處理劑進行溶除開嫌,如此則可以獲得 更爲優越的染色堅牢度及濃色化。 本發明係將橫斷面具有於複數的分割聚醯胺系聚合物 與該聚醯胺系聚合物之間介在有聚酯系聚合物於其中所成 之開纖分割型複合繅維,先行織造成布帛,然後將此布帛 進行開纖處理〇 m圭m.. .in進.©min 使該聚醯胺系聚合物全部溶除,則可以使單絲纖度更低, FV » ’ · . - ... .......... ----..... 15竺得1〇〇屋m—率。處理液使用有機酸或無機酸於常 溫進行溶除處理即可,主要是使聚醯胺部分產生溶除作用 ,且溶除處理時間非常的短,並可以提高分纖率。使用此 種方法,纖維的光澤性及觸感非常的優良,而且可以染深 色調。 最主要的是經此處理之織物,其洗濯堅牢度皆可達4 級以上,因此,經濟性非常的高。 本發明編織物經由溶除分纖後的單絲纖度爲0.18丹尼 (請先珣讀背面之注意事項再填寫本頁) •裝_ •訂· 本紙張尺度適用中西國家槠準(CNS)甲4規格(210X297公釐)' —〇 — A6 B6 202489 •δ·、發明説明(3 ) (請先聞讀背面之注意事項再瑱寫本页) 以下,因此布帛可以獲得相當柔輭的觸感,特別是在〇.234 〜0.02丹尼最好,因此,本發明中構成複合絲之聚合體的 複合比例與分割數及複合絲之單絲嫌度之設定非常的重要 本發明所使用之聚醯胺爲一般的合成, 例如尼龍6.尼龍10.尼龍11.尼龍12尼龍6d尼龍610.及以此等 爲主成分之聚醯胺共聚合體;而於此等聚醯胺中以尼龍6 與尼龍66特別的好。以PET與尼龍6或尼龍66所組合之分 割型纖維製造成之編織物,於精練等適當之前處理,並於 精練後,再施予有機酸或無機酸之強酸於常溫進行溶除開纖作用’可以 提高分纖率,且可以縮短分纖時間,使完成超細纖維化。 按一般PET與尼龍6或尼龍66所組合之海島橘片型或 分割型複合纖維織造而成之編織物,於精練等之處理後, 必須再U喊霞基行滅霉^工,同時有的染整工廠使用高溫 高壓碱液減量加工處理,且處理時間較長,成本相對提高 ,尤其近來紡織工業如何降低成本,以利產品在市場上的 競爭性非常的重要,因此使用本發明可以降低成本及提高 W濟部中央標节场^工消^合作杜卬" 產品品質。 ^ 本發明利用強酸進行溶除js織法,可以忠ϋ題 染色,或者"4染色後再進行溶除開纖處理,·亦 \ — -- ·|Γ~1 丨丨 ^^ «II I,|i I| >w 1|_ 熔融聚合體中添加色料,再進行紡絲,假撚加工、編織物 織造及溶除開纖處理;經由浸染後可以獲得深染之效果’ 而如先進行色料紡絲後再進行溶除開嫌,對原來之色澤亦 不會有影響。 本纸張尺度通用中西國家標準(CNS)甲4規格(210x297公;¢) 4 Λ 6 Β6 202489 五、發明説明(4) (請先閱讀背而之注意事項Λ·项寫本頁) 本發明若以強酸作爲溶除開纖處理較容易,酸液溶除 濃度爲10 Wt%以上;但若超過65 wt %以上時,開嫌後的殘 留處理劑除去不易,故最佳爲15wt%〜50wt% ;將編織物 放置於酸液開嫌處理液中經常溫短時間處理,繼之將該處 理後之編織物所殘留的藥劑完全去除洗淨,最後乾燥之即 完成。 依本發明可以獲得實質的PET微嫌覆蓋於表面呈現柔 輭且優越的懸垂性,其絲質(Si lk)感及充實之觸感而可以 得到上品光澤之外觀,並提尚商品品位。 本發明之纖維經絲織(Weaving )或針織成布後,$;以 經獻酸置處理溶m面ϋ盟1之目的,η毫兔氬 ^_經由溶除開纖後之成份僅剩單一種成母,對於染色處理 可以達深染之效果,且水洗堅牢度可達4〜5級。而使用 酸液處理之複合嫌維種類以分割型及海島型爲主,經由溶 除開纖後之纖度在〇.〇2〜0.80丹尼間,成份僅含多元酯。 經濟部中央櫺準局员工消伢合作社印挝 本發明亦可使用於短纖複合機紡紗,再經由絲織( Weaving)或針織織造成布後,進行酸液溶除開纖處理而達 到開纖之目的,然後,再進行染色;或者布帛先經由染色 後,再進行開儎,可以獲得深染之效果,且洗濯牢度可以 達4〜5級。 本發明亦可以使用於非織物製造人造麂皮(Suede)之 'M",- III 1 - " 1 mm>複合短纖維經由梳棉機梳理成網後,依所需之重量 要求將棉網疊成棉層,再經鈎針機軋針處理,經過軋針後 之棉片,進行樹脂固著,再經pu樹脂之配合液處理之, 私紙尺度遑用中8鼷家標準(CNS)T4規格(2丨0X297公iit) _ g 2 02489 Λ 6 η 6 經濟部中央梂準局ex工消伢合作社印一4 五、發明説明(5) 最後再以酸液進行溶除開織處理以及染色,或者先行染色 後再進行酸液溶除開織處理,可以獲得濃色化及優越之染 色堅牢度的人造売皮。 本發明之布料就其應用可以區分爲㈠人造皮類··皮箱 用、手提袋用、鞋用、女用涼鞋用、衣料用、家倶與車輛 用,㈡擦拭布類:眼鐃擦拭用,半導體製造廠的無塵室中 用,汽車用,家庭玻璃擦拭用,㈢超高收縮密度織物:寒 冷地區之工作服、滑雪衣、風衣、婦人用外套、旅行袋、手. 提箱手提包,㈣仿桃皮織物:女用衣料、裙料、褲料,㈤ 仿蠶絲織物:女用衣料、裙料、褲料。 〔實施例1〕 分割型複合纖維聚醯胺6/聚對酞酸乙二酯(PA6 / PET )的重量比爲10/90之75丹尼/ 36絲所得的分割型複 合纖維,其斷面如圖一之照片所示。部份延伸複合_以延伸 假撚機進行_加工乍爲緯紗,而以75丹尼/ 72絲作爲經紗, 製造成平織物,此織物於98 °C之蘇打灰水溶液中進行精練 之後,以H2S04 60 %界面活性劑(A) : 1. 0 %水:39 %所配 成之處理液處理30分鐘,然後再將該布胚置於35 °C水液中 水洗,再乾燥之。緯紗開纖率可達到Μ» %如圖二之照片所 示,且織度爲0.16丹尼,最後再使用開纖後之織物進行染 色,染色條件如下所列: 染料:Kayalon Red TL-SF 8 % 〇 . w. f 分散均染劑:lg/β (多環系酯型和萘酚磺酸鹽配合物) 醋 酸:0.3g/^ PH=4.5 〜5 溫度時間·· 130°(:><6〇111111->還原洗淨—水洗 本紙張尺本边用中8國家標準(CNS)甲4規格(210X297公;it) (請先閲讀背而之注意事項#填筠本頁)A6 B6 202489 V. Description of the invention (1) The present invention relates to a method of opening fibers for composite woven fabrics and their fabrics. The woven fabrics are suitable for processing. The cross-sections are mainly divided and island-shaped, as shown in Figure 4. : (A) ~ (F)], and the polyester component and the polyamide component form a plurality of divided split composite reel and sea island composite suspected dimensions. After processing the suspected dimension using the split-weaving treatment method of the present invention, the knitted fabric can be turned into a soft fabric, and can be dyed in dark tones and improve the fastness of dyeing. The present invention provides a split composite fiber or island-in-the-sea fiber The fabric is made into fabrics, and then the fiber-opening treatment is carried out to obtain an extremely high fiber splitting rate. At the same time, the fibers are divided to make the fabric into a very soft fabric treatment method. General composite ultrafine fiber fiber opening technology, known to have various methods such as NaOH opening, or benzyl alcohol or benzoic acid or solvent opening (trichloroethane), these methods have their own advantages and disadvantages . At present, the processing method tends to save energy, the processing is simple, the pollution problem is few, and the economic efficiency is the primary goal. The acid fiber opening method of the present invention also aims at this. Ultra-fine fibers are not easy to be darkened. In the past, they were dyed after opening the fiber, and then treated by chemical methods, such as fluoropolymer, silicone polymer, acrylic copolymer, etc., to change the reflectance of the fiber surface to achieve darkening. . Generally speaking, these methods have disadvantages such as difficulty in coloring, reduced fiber properties, reduced dyeing fastness, and higher processing cost. The present invention is focused on acidic fiber opening to save energy more than alkaline opening " ........... (t vii ....... ________.....- --¾. &Quot; * ^ * 4 ·· «..« > ·., And it has no damage to the fabric fiber physical properties, and has better strength to maintain the seal _, 1 and acid-… 屮. 丨 ~ 1 — '* —__ ii I n -I _ I-**' — II · ^ · — ._ · .... After dyeing the fiber and then dyeing the ghost, it can get a dense color, and the dyeing fastness is good, so it can be improved The facts about the disadvantages of alkaline fiber opening or other dyeing methods to thicken the color (please read the precautions before counting and then fill out this page) • Installation • • Line, this paper scale is applicable to the Chinese and Western Standards (CNS) A 4 specifications ( 210x297 public *) A6 B6 202489 V. Description of the invention (2), and research developer. Traditional composite ultrafine fibers are used for salty fiber opening, such as NaOH 10 ~ 30% 〇. W · f and impregnating agent (cation ) At high temperature ~ · 130 ° (: Treat it to reduce the polyester (PET) fiber weight to reach the fiber opening '. The polyester portion is reduced by NaOH and hydrolyzed to produce ethylene glycol to cause a large amount of oligomer (〇1 igomer), which is easy to cause The fiber strength decreases and the fiber turns yellow , Residual cationic surfactants, causing staining in subsequent dyeing projects, poor light fastness, easy-to-slip fabrics and a large number of oligomers and lye wastewater. Another breakthrough method of the present invention is ultra-fine The fiber fabric is dyed first, and then dissolved with an acid treatment agent, so that more excellent dyeing fastness and thickening can be obtained. The present invention is to divide the cross-section with a plurality of divided polyamides Between the polymer and the polyamide-based polymer, an open-fibre split composite reel formed by a polyester-based polymer is woven into a fabric, and then the fabric is subjected to fiber treatment. .. .in 进. © min When all the polyamide polymers are dissolved, the monofilament fineness can be lowered. FV »'·.-... ..........- --..... 15 Zhu is 100 m. Rate. The treatment solution can be dissolved by using organic acid or inorganic acid at room temperature, mainly to dissolve and remove the polyamide part. The processing time is very short, and can improve the split rate. Using this method, the gloss of the fiber And the touch is very good, and it can be dyed in dark shades. The most important thing is that the treated fabric has a washing fastness of more than 4 grades, so the economy is very high. The knitted fabric of the present invention is divided by dissolution The fineness of the monofilament after the fiber is 0.18 Danny (please read the precautions on the back before filling in this page) • Installed _ • Ordered • This paper size is applicable to the Chinese and Western National Standards (CNS) A 4 specifications (210X297 mm) ' —〇— A6 B6 202489 • δ ·, description of the invention (3) (please read the precautions on the back before writing this page), so the fabric can get a very soft touch, especially at 〇.234 ~ 0.02 Denny is the best. Therefore, the setting of the compounding ratio and the number of divisions of the polymer constituting the composite yarn and the monofilament susceptibility of the composite yarn in the present invention is very important. The polyamide used in the present invention is a general synthesis, for example Nylon 6. Nylon 10. Nylon 11. Nylon 12 Nylon 6d Nylon 610. Polyamide copolymers with these as main components; among these polyamides, nylon 6 and nylon 66 are particularly good. Woven fabric made of divided fibers combined with PET and nylon 6 or nylon 66, treated before appropriate refining, etc., and after refining, strong acids of organic or inorganic acids are applied to dissolve and open the fiber at room temperature ' It can improve the splitting rate and shorten the splitting time, so that the ultrafine fiber can be completed. The woven fabric woven from the island orange slice type or split type composite fiber combined with general PET and nylon 6 or nylon 66, after refining and other treatments, must be called Xiaji to kill mildew ^ work, and some Dyeing and finishing factories use high-temperature and high-pressure alkali reduction processing, and the processing time is relatively long, and the cost is relatively increased. Especially how to reduce the cost recently in the textile industry to facilitate the competitiveness of products in the market is very important, so the use of the present invention can reduce costs And improve the quality of W Jibei Central Standard Festival ^ Work Consumers ^ Cooperate with Du Bai ". ^ The present invention utilizes strong acid to dissolve the js weave, which can be dyed faithfully, or after " 4 dyeing and then dissolve to open the fiber treatment. · Also \ —-· | Γ ~ 1 丨 丨 ^^ «II I, | i I | > w 1 | _ Add colorant to the molten polymer, and then perform spinning, false twisting, weaving, weaving and disentanglement; after dyeing, the effect of deep dyeing can be obtained. After the color material is spun, dissolving and removing it will not affect the original color. The standard of this paper is the Chinese and Western National Standards (CNS) A 4 specifications (210x297 g; ¢) 4 Λ 6 Β6 202489 V. Description of the invention (4) (please read the precautions Λ · item to write this page) This invention If the strong acid is used as the dissolving and opening fiber treatment is easier, the acid solution removal concentration is more than 10 Wt%; but if it exceeds 65 wt%, the residual treatment agent after opening is not easy to remove, so the best is 15wt% ~ 50wt% ; Place the braid in an acid-liquid-treating treatment liquid, which is often treated for a short period of time, followed by completely removing and washing the residual chemicals from the braid after the treatment, and finally drying is completed. According to the present invention, it is possible to obtain a substantial PET micro-covering surface that exhibits soft and superior drape, and its silk feel and full touch can obtain a top-grade luster appearance and improve the quality of the product. After weaving or knitting the fiber of the invention into a cloth, $; for the purpose of dissolving the m-plane by acid-donating treatment, the only component left after the fiber is removed by dissolving the fiber As a mother, it can achieve the effect of deep dyeing for dyeing treatment, and the washing fastness can reach 4 to 5 grades. The type of compound suspected dimension treated with acid solution is mainly divided type and island type, and the fineness after dissolving the fiber is between 0.02 and 0.80 Danny, and the component contains only polyester. The Ministry of Economic Affairs, Ministry of Economic Affairs, Central Bureau of Employee Consumer Cooperatives, Laos The invention can also be used for spinning of staple fiber composite machines, and then weaving or weaving into fabrics, and then performing acid solution to dissolve and open the fiber to achieve fiber opening For the purpose, and then dyeing; or after the fabric is dyed and then opened, the effect of deep dyeing can be obtained, and the washing fastness can reach 4 ~ 5. The present invention can also be used for 'M ",-III 1-" 1 mm > composite short fibers of artificial suede (Suede) manufactured by non-woven fabrics after being carded into a net by a carding machine, and the cotton net can be made according to the required weight. Laminated into a cotton layer, and then processed by needle rolling with a crochet machine, the cotton sheet after the needle rolling is fixed with resin, and then treated with the pu resin compound solution. The private paper scale is used in China 8 Standard (CNS) T4 Specifications (2 丨 0X297 public iit) _ g 2 02489 Λ 6 η 6 Printed by the Central Bureau of Economic Affairs of the Ministry of Economic Affairs of the Ministry of Industry and Commerce Cooperative Co., Ltd. 1 4. V. Description of invention (5) Finally, the acid solution is used to dissolve the weaving process and dye, Or, after dyeing first, and then performing acid solution disentanglement and weaving treatment, it is possible to obtain a thickened artificial leather with superior dyeing fastness. The fabrics of the present invention can be divided into (i) artificial leathers, suitcases, handbags, shoes, women's sandals, clothing, furniture, and vehicles. (Ii) Wiping cloths: eye-rubbing wipes , For use in clean rooms of semiconductor manufacturing plants, for automobiles, for household glass wiping, (3) Ultra-high shrinkage density fabrics: work clothes, ski suits, windbreakers, women's jackets, travel bags, hands in cold areas. Luggage handbags, (iv) Peach-like fabrics: women's clothing, skirts, trousers, (v) Silk-like fabrics: women's clothing, skirts, trousers. [Example 1] A split composite fiber obtained by dividing the composite fiber polyamide 6 / polyethylene terephthalate (PA6 / PET) in a weight ratio of 10/90 to 75 denier / 36 filaments. As shown in the photo of Figure 1. Partially stretched composite_processed with stretched false twisting machine_processed the first weft yarn and 75 denier / 72 yarn as warp yarn to make a flat fabric. After scouring in 98 ° C soda ash aqueous solution, the fabric was H2S04 60 % Surfactant (A): 1.0% water: 39% of the prepared treatment solution was treated for 30 minutes, and then the cloth was placed in a 35 ° C water solution and washed, and then dried. The weft opening rate can reach Μ »% as shown in the photo in Figure 2, and the weave is 0.16 Danny. Finally, the fabric after opening is used for dyeing. The dyeing conditions are as follows: Dye: Kayalon Red TL-SF 8 % 〇. W. F Dispersing and leveling agent: lg / β (polycyclic ester type and naphthol sulfonate complex) Acetic acid: 0.3g / ^ PH = 4.5 ~ 5 Temperature time · 130 ° (: > < 6〇111111- > Reduction Washing-Wash this paper with the ruler side of the 8 National Standard (CNS) A 4 specifications (210X297; it) (please read the back notes before filling #fill the page)
02489 Λ 6 116 五、發明説明(6) 開纖染色後之織物與傳統(碱性)開纖法比較各項特性如 表一及表二所示: 表一: 特性 比較'\ 織物強力保持率 織物變黃 開纖減量率 開纖率 酸性開纖法 85 % ◎ 15.1 % 100% ◎ 喊性開纖法 67 % △ 20.5¾ 95-ΊΟΟ^ △ —t-* —* . 表一* ^特性 加: 開纖減量率 染色性(ΔΕ) 濃色化 洗滌堅牢度 酸性開纖法 15.1% 80.1 〇 4 " (請先閱讀背而之注意事項洱填寫本頁) 經濟部屮央櫺準局β工消伢合作杜印製 本紙張尺度遑用中國Η家樣準(CNS)甲4規格(210X297公龙)—η — 202489 Λ 6 ne 五、發明説明(7 ) 〔實施例2〕 分割型複合纖維DTY之規格如實施例1,同樣以75丹 尼/ 72絲作爲經紗,製造成平織物,此織物於% °C之蘇打 灰水溶液中進行精練之後,再進行染色’條件如實施例1 所示:最後,再將複合纖維染色,織物放置於蟻酸5°%界 面活性劑(A)= 1. 〇%,水=49%所配成之處理液,於35°C 中處理20分鐘,然後再將其放置於25 °C水液中水洗後乾燥 之。緯紗開纖率可以達到1〇〇 %,染色開維後之織物特性如 表三所: 表三: 特性 加工法 開纖減量率 染色性(ΛΕ) 洗滌堅牢度 酸性開纖法 15. 3 % 80. 8 5 (請先閲讀背而之注意亊項洱塡寫本頁) 經濟部屮央櫺準局貝工消费合作社印製 私紙張尺度边用中a Β家樣準(CHS)甲4規格(210x297公龙) 一 8 202489 A 6 Π 6 五、發明説明(8) 〔實施例3〕 以无ΕΓ多元酯及FA6尼龍以283 °C行複合紡絲,斷面 同實施例1 ,捲取速度爲1500 m/min ,紡絲丹尼爲8. 25丹 尼,生產未延伸棉束,經延伸倍率3. 3在83 °C下延伸後, 在135 °C下予熱定型,並經起鏃機起皴後,經115 °C乾燥 ,然後予切棉成2.5 dX51 之複合棉,以該複合棉經由梳 棉機梳理成網後,將棉網疊成棉層,再經鈎針機軋針處理 成2 50 g/w2 ,經過軋針後之棉片進行樹脂固著,再經由PU 樹脂之配合液處理之,處理後,先進行染色之後,再進行 酸液溶除開織處理,可以獲得濃色化及優越之染色堅牢度 之人造麂皮(Suede)。染色條件如下所示,溶除開纖條件 同實施例2。染色開纖後之人造麂皮特性如表四所示。開 鐮狀況則如圖三之照片所示。 染劑:Kayalan Black ExN-SF 300 % 8 % 〇 . w. f 分散均染劑:1 g/』 醋 酸:0.3g/^ PH=4 · 5 〜5 溫度時間:130 °CX 60 mi η —還原洗—水洗 (請先閲讀背而之注意事項洱填窍本頁) 經濟部屮央橾準局CX工消费合作社印製 表四: 特性 加工 開纖減量率 染色性(ΔΕ) 洗滌堅牢度 酸性開纖法 15.4% 77.9 4十〜5 本紙張尺度遑用中國Β家楳準(CNS) Τ4規格(210X297公龙) 2024S9 Λ 6 η 6 五、發明説明(9) 〔比較例〕 複合纖維加工絲織物規格同實施例1,該織物於80 ec 下退漿後,升溫至95 °c處理,60分之後,再予13 0 °c乾燥 3分鐘而予以預定型後,以NaOH 10〜15 %,〇 . w. f及減 量促進劑2〜5 g/Z進行110〜120 °Cx6〇min之鹹減量 開纖處理,減量率控在20 %,染色條件同實施例1 ,開嫌 染色後之特性如表五所示。 表五: ^特性 加工法 開纖減量率 染色性(ΔΕ ) 洗漉堅牢度 碱性開纖法 20.5 71.6 2〜3 (請先間請背而之注意事項存艰筠本頁) 經濟部中央槛準局貝工消评合作杜印製 四、圖面之簡單說明: 圖一係依本發明方法處理之複合纖維一實施例之顯 微放大斷面照片。 圖二係依本發明方法處理之複合纖維另一實施例之 顯微放大斷面照片。 圖三係依本發明方法處理之人造麂皮一實施例之顯 微放大斷面照片。_ 圖四(A)〜(F)表示適用本方法處理之各種分割型及海 島型複合纖維例斷面圖。 本紙ft尺度遴用中SB家猱準(CNS)甲4規格(2丨0X297公;it) — _02489 Λ 6 116 V. Description of the invention (6) The characteristics of the fabric after opening and dyeing are compared with the traditional (alkaline) opening method as shown in Table 1 and Table 2: Table 1: Comparison of characteristics' \ Strength of fabric retention Fabric yellowing opening rate reduction rate opening rate acid opening method 85% ◎ 15.1% 100% ◎ shout opening method 67% △ 20.5¾ 95-ΊΟΟ ^ △ —t- * — *. Table 1 * ^ Characteristics : Fibre Reduction Ratio Dyeability (ΔΕ) Density Washing Fastness Acidic Fibre Opening Method 15.1% 80.1 〇4 " (please read the precautions and fill in this page first) Consumer cooperation and cooperation in printing this paper, using paper-based Chinese standard (CNS) A4 specifications (210X297 male dragon)-η-202489 Λ 6 ne V. Description of the invention (7) [Example 2] Split composite fiber The specification of DTY is the same as that in Example 1. Similarly, 75 denier / 72 silk is used as the warp yarn to make a flat fabric. After the fabric is scouring in a soda ash aqueous solution at% ° C, the dyeing conditions are as shown in Example 1: Finally, the composite fiber is dyed again, and the fabric is placed in formic acid 5 °% surfactant (A) = 1. 〇%, water = 49% of the prepared treatment solution, treated at 35 ° C for 20 minutes, and then placed in 25 ° C water solution after washing and drying. The weft opening rate can reach 100%, and the fabric characteristics after dyeing and opening are shown in Table 3: Table 3: Characteristic processing method Opening fiber reduction rate Dyeability (ΛΕ) Washing fastness Acid opening method 15. 3% 80 . 8 5 (please read the note first and write this page). The Ministry of Economic Affairs, Ministry of Economic Affairs, Pyongyang Bureau, Beigong Consumer Cooperative, prints private paper scales, and uses a beta standard (CHS) A4 specifications ( 210x297 male dragon) I 8 202489 A 6 Π 6 V. Description of the invention (8) [Example 3] Composite spinning with ΕΓ polyester and FA6 nylon at 283 ° C, the cross-section is the same as Example 1, the winding speed 1500 m / min, spinning Danny is 8.25 Danny, producing unstretched cotton bundle, after stretching at a stretch magnification of 3.3 at 83 ° C, heat setting at 135 ° C, and by a screwdriver After picking, dry at 115 ° C, and then cut the cotton into 2.5 dX51 composite cotton. After the composite cotton is carded into a net by a carding machine, the cotton net is stacked into a cotton layer, and then processed by a crochet needle. 2 50 g / w2, the cotton sheet after needle rolling is used to fix the resin, and then treated with the PU resin compound solution. After the treatment, the dyeing is performed first. Acid solution for processing other open weave, color depth can be obtained and excellent fastness of the dyed suede (Suede). The dyeing conditions are as follows, and the conditions for dissolving the fiber are the same as in Example 2. The characteristics of artificial suede after dyeing and fiber opening are shown in Table 4. The situation of the open sickle is shown in the photo of Figure 3. Dyeing agent: Kayalan Black ExN-SF 300% 8% 〇. W. F Dispersing and leveling agent: 1 g / 』Acetic acid: 0.3g / ^ PH = 4 · 5 ~ 5 Temperature time: 130 ° CX 60 mi η —reduction Washing-washing (please read the precautions on this page and fill in this page) CX Industrial and Consumer Cooperatives of the Central Bureau of Economics of the Ministry of Economic Affairs Printed Table 4: Characteristic Processing Fiber Reduction Rate Dyeability (ΔΕ) Wash Fastness Fibre Method 15.4% 77.9 4 Ten ~ 5 This paper size is made of Chinese 戳 楳 准 (CNS) Τ4 specifications (210X297 male dragon) 2024S9 Λ 6 η 6 V. Description of the invention (9) [Comparative Example] Composite fiber processing silk fabric The specifications are the same as in Example 1. After desizing at 80 ec, the fabric is heated to 95 ° C, and after 60 minutes, it is dried at 130 ° C for 3 minutes to give a predetermined shape. w. f and weight-reducing accelerator 2 ~ 5 g / Z were subjected to 110 ~ 120 ° C x 60min salt reduction fiber opening treatment, the reduction rate was controlled at 20%, the dyeing conditions were the same as in Example 1, and the characteristics after opening dyeing were as follows Table 5 shows. Table 5: ^ Characteristic processing method Opening fiber reduction rate Dyeability (ΔΕ) Washing fastness Alkaline opening method 20.5 71.6 2 ~ 3 (Please pay attention to the difficulties beforehand. This page is difficult) The quasi-administrative shellfish consumer evaluation cooperation Du Printing 4. Brief description of the drawing: Figure 1 is a photo of a magnified cross-sectional view of an embodiment of a composite fiber processed according to the method of the present invention. Figure 2 is a photo of a magnified cross-section of another embodiment of a composite fiber treated according to the method of the present invention. Figure 3 is a magnified cross-sectional photograph of an embodiment of artificial suede processed according to the method of the present invention. _ Figure 4 (A) ~ (F) shows the cross-sectional view of various split-type and island-type composite fibers processed by this method. The ft scale of this paper is selected in the SB home standard (CNS) A 4 specification (2 丨 0X297; it) — _