TW202344391A - antistatic film - Google Patents
antistatic film Download PDFInfo
- Publication number
- TW202344391A TW202344391A TW112104501A TW112104501A TW202344391A TW 202344391 A TW202344391 A TW 202344391A TW 112104501 A TW112104501 A TW 112104501A TW 112104501 A TW112104501 A TW 112104501A TW 202344391 A TW202344391 A TW 202344391A
- Authority
- TW
- Taiwan
- Prior art keywords
- film
- antistatic
- antistatic layer
- conductive polymer
- less
- Prior art date
Links
- 229920001940 conductive polymer Polymers 0.000 claims abstract description 71
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 53
- 230000001681 protective effect Effects 0.000 claims abstract description 49
- 229920006267 polyester film Polymers 0.000 claims abstract description 47
- 239000004094 surface-active agent Substances 0.000 claims abstract description 46
- 239000010410 layer Substances 0.000 claims description 98
- 229920000877 Melamine resin Polymers 0.000 claims description 35
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical group NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 29
- -1 poly(3,4-ethylenedioxythiophene) Polymers 0.000 claims description 25
- 239000012790 adhesive layer Substances 0.000 claims description 23
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 13
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 13
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 10
- 150000007974 melamines Chemical class 0.000 claims description 8
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 claims description 7
- 239000004640 Melamine resin Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 238000001035 drying Methods 0.000 abstract description 8
- 239000000758 substrate Substances 0.000 abstract 1
- 239000010408 film Substances 0.000 description 119
- 239000007787 solid Substances 0.000 description 32
- 238000000034 method Methods 0.000 description 25
- 238000000576 coating method Methods 0.000 description 21
- 239000000203 mixture Substances 0.000 description 21
- 239000011248 coating agent Substances 0.000 description 17
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- 150000001875 compounds Chemical class 0.000 description 13
- 238000010438 heat treatment Methods 0.000 description 13
- 230000003287 optical effect Effects 0.000 description 13
- 229920001225 polyester resin Polymers 0.000 description 13
- 239000004645 polyester resin Substances 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 12
- 239000002216 antistatic agent Substances 0.000 description 11
- 238000004132 cross linking Methods 0.000 description 9
- 229930192474 thiophene Natural products 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 7
- 239000002019 doping agent Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 230000009257 reactivity Effects 0.000 description 7
- 238000002834 transmittance Methods 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 5
- 238000010030 laminating Methods 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 description 4
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 4
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 4
- MBHRHUJRKGNOKX-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)amino]methanol Chemical class NC1=NC(N)=NC(NCO)=N1 MBHRHUJRKGNOKX-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 239000004840 adhesive resin Substances 0.000 description 4
- 229920006223 adhesive resin Polymers 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 239000011247 coating layer Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 150000003577 thiophenes Chemical class 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000002482 conductive additive Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 150000002009 diols Chemical class 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 125000001841 imino group Chemical group [H]N=* 0.000 description 3
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- XCSGHNKDXGYELG-UHFFFAOYSA-N 2-phenoxyethoxybenzene Chemical compound C=1C=CC=CC=1OCCOC1=CC=CC=C1 XCSGHNKDXGYELG-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- YGCOKJWKWLYHTG-UHFFFAOYSA-N [[4,6-bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol Chemical compound OCN(CO)C1=NC(N(CO)CO)=NC(N(CO)CO)=N1 YGCOKJWKWLYHTG-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000001767 cationic compounds Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- XBZSBBLNHFMTEB-UHFFFAOYSA-N cyclohexane-1,3-dicarboxylic acid Chemical compound OC(=O)C1CCCC(C(O)=O)C1 XBZSBBLNHFMTEB-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229940005642 polystyrene sulfonic acid Drugs 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- XTUSEBKMEQERQV-UHFFFAOYSA-N propan-2-ol;hydrate Chemical compound O.CC(C)O XTUSEBKMEQERQV-UHFFFAOYSA-N 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- 238000007761 roller coating Methods 0.000 description 2
- 238000007788 roughening Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- GBURUDXSBYGPBL-UHFFFAOYSA-N 2,2,3-trimethylhexanedioic acid Chemical compound OC(=O)C(C)(C)C(C)CCC(O)=O GBURUDXSBYGPBL-UHFFFAOYSA-N 0.000 description 1
- WKRCUUPMCASSBN-UHFFFAOYSA-N 2,2-diethylbutanedioic acid Chemical compound CCC(CC)(C(O)=O)CC(O)=O WKRCUUPMCASSBN-UHFFFAOYSA-N 0.000 description 1
- BTUDGPVTCYNYLK-UHFFFAOYSA-N 2,2-dimethylglutaric acid Chemical compound OC(=O)C(C)(C)CCC(O)=O BTUDGPVTCYNYLK-UHFFFAOYSA-N 0.000 description 1
- JZUMVFMLJGSMRF-UHFFFAOYSA-N 2-Methyladipic acid Chemical compound OC(=O)C(C)CCCC(O)=O JZUMVFMLJGSMRF-UHFFFAOYSA-N 0.000 description 1
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- WMRCTEPOPAZMMN-UHFFFAOYSA-N 2-undecylpropanedioic acid Chemical compound CCCCCCCCCCCC(C(O)=O)C(O)=O WMRCTEPOPAZMMN-UHFFFAOYSA-N 0.000 description 1
- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical class CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 description 1
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- KYXHKHDZJSDWEF-LHLOQNFPSA-N CCCCCCC1=C(CCCCCC)C(\C=C\CCCCCCCC(O)=O)C(CCCCCCCC(O)=O)CC1 Chemical compound CCCCCCC1=C(CCCCCC)C(\C=C\CCCCCCCC(O)=O)C(CCCCCCCC(O)=O)CC1 KYXHKHDZJSDWEF-LHLOQNFPSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- 229920000144 PEDOT:PSS Polymers 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 206010040954 Skin wrinkling Diseases 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- XDODWINGEHBYRT-UHFFFAOYSA-N [2-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCCCC1CO XDODWINGEHBYRT-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 description 1
- SYDYRFPJJJPJFE-UHFFFAOYSA-N [[4,6-bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(N(CO)CO)=NC(N(CO)CO)=N1 SYDYRFPJJJPJFE-UHFFFAOYSA-N 0.000 description 1
- SUPOBRXPULIDDX-UHFFFAOYSA-N [[4-amino-6-(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound NC1=NC(NCO)=NC(NCO)=N1 SUPOBRXPULIDDX-UHFFFAOYSA-N 0.000 description 1
- WEAJVJTWVRAPED-UHFFFAOYSA-N [[4-amino-6-[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol Chemical compound NC1=NC(N(CO)CO)=NC(N(CO)CO)=N1 WEAJVJTWVRAPED-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 125000004849 alkoxymethyl group Chemical group 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 150000001448 anilines Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- FNGGVJIEWDRLFV-UHFFFAOYSA-N anthracene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=CC3=C(C(O)=O)C(C(=O)O)=CC=C3C=C21 FNGGVJIEWDRLFV-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001718 carbodiimides Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 1
- LNGJOYPCXLOTKL-UHFFFAOYSA-N cyclopentane-1,3-dicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)C1 LNGJOYPCXLOTKL-UHFFFAOYSA-N 0.000 description 1
- INSRQEMEVAMETL-UHFFFAOYSA-N decane-1,1-diol Chemical compound CCCCCCCCCC(O)O INSRQEMEVAMETL-UHFFFAOYSA-N 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- OREAFAJWWJHCOT-UHFFFAOYSA-N dimethylmalonic acid Chemical compound OC(=O)C(C)(C)C(O)=O OREAFAJWWJHCOT-UHFFFAOYSA-N 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 125000000879 imine group Chemical group 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000011254 layer-forming composition Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- ABMFBCRYHDZLRD-UHFFFAOYSA-N naphthalene-1,4-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=C(C(O)=O)C2=C1 ABMFBCRYHDZLRD-UHFFFAOYSA-N 0.000 description 1
- DFFZOPXDTCDZDP-UHFFFAOYSA-N naphthalene-1,5-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1C(O)=O DFFZOPXDTCDZDP-UHFFFAOYSA-N 0.000 description 1
- VAWFFNJAPKXVPH-UHFFFAOYSA-N naphthalene-1,6-dicarboxylic acid Chemical compound OC(=O)C1=CC=CC2=CC(C(=O)O)=CC=C21 VAWFFNJAPKXVPH-UHFFFAOYSA-N 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 150000002482 oligosaccharides Chemical class 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229960002796 polystyrene sulfonate Drugs 0.000 description 1
- 239000011970 polystyrene sulfonate Substances 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920002215 polytrimethylene terephthalate Polymers 0.000 description 1
- 150000004032 porphyrins Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- PCCVSPMFGIFTHU-UHFFFAOYSA-N tetracyanoquinodimethane Chemical compound N#CC(C#N)=C1C=CC(=C(C#N)C#N)C=C1 PCCVSPMFGIFTHU-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/26—Layered products comprising a layer of synthetic resin characterised by the use of special additives using curing agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/02—Physical, chemical or physicochemical properties
- B32B7/025—Electric or magnetic properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
Abstract
Description
本發明係關於一種抗靜電膜及於抗靜電膜積層有黏著層之保護膜，尤其係關於光學構件(例如，有機EL或液晶顯示器之組成構件)等保護膜。The present invention relates to an antistatic film and a protective film having an adhesive layer laminated on the antistatic film, and particularly to protective films for optical components (for example, components of organic EL or liquid crystal displays).
於基材膜積層有黏著層之膜作為光學構件等之製造步驟中各構件之保護膜來使用。保護膜經由黏著層貼附於作為被黏著體之各構件，且發揮了如下作用：抑制各構件之加工或於運送時損傷或附著污漬。作為可用於這些保護膜之基材膜，可使用至少於單面積層有抗靜電層之抗靜電膜。積層抗靜電層之目的在於，防止於保護膜附著垃圾或灰塵等異物、或抑制將保護膜自被黏著體剝離時所產生的靜電。(參照專利文獻1)A film with an adhesive layer laminated on a base film is used as a protective film for each component in the manufacturing process of optical components, etc. The protective film is attached to each component as an adherend through an adhesive layer, and plays the following role: preventing damage or stains from being attached to each component during processing or transportation. As a base film that can be used for these protective films, an antistatic film having an antistatic layer laminated on at least a single surface area can be used. The purpose of laminating an antistatic layer is to prevent foreign matter such as garbage or dust from adhering to the protective film, or to suppress static electricity generated when the protective film is peeled off from an adherend. (Refer to patent document 1)
作為抗靜電膜，提案有含有作為抗靜電劑之PEDOT(poly(3,4-ethylenedioxythiophene)；聚(3,4-乙烯二氧噻吩))：PSS(polystyrene sulfonic acid；聚(4-苯乙烯磺酸鹽))之抗靜電膜。(參照專利文獻2) [先前技術文獻] [專利文獻] As an antistatic film, it is proposed to contain PEDOT (poly(3,4-ethylenedioxythiophene); poly(3,4-ethylenedioxythiophene)) as an antistatic agent: PSS (polystyrene sulfonic acid; poly(4-styrene sulfonate)) salt)) antistatic film. (Refer to patent document 2) [Prior technical literature] [Patent Document]
[專利文獻1]國際公開2018／012545。 [專利文獻2]日本特開2018-172473號公報。 [Patent Document 1] International Publication 2018/012545. [Patent Document 2] Japanese Patent Application Publication No. 2018-172473.
[發明所欲解決之課題][Problem to be solved by the invention]
具有抗靜電層之保護膜用作為光學構件等之保護膜，尤其用於顯示器之組成構件之加工步驟。近年來，越來越多地用於有機EL顯示器(尤其是OLED顯示器)之構件之加工步驟。為了將保護膜貼合於光學構件，於保護膜中至少單面設置有黏著層，於積層該黏著層之步驟中包含加熱乾燥步驟。The protective film with an antistatic layer is used as a protective film for optical components, etc., and is especially used in the processing steps of components of displays. In recent years, it has been increasingly used in the processing steps of components of organic EL displays (especially OLED displays). In order to bond the protective film to the optical component, an adhesive layer is provided on at least one side of the protective film, and the step of laminating the adhesive layer includes a heating and drying step.
例如，這樣於保護膜積層黏著層的情形時，有時會因加熱乾燥步驟導致析出寡聚物、霧度上升且膜的外觀變差。伴隨著保護膜之霧度上升而辨識性降低，在將保護膜貼合於被黏著體之狀態下難以檢查外觀而成為課題。For example, when an adhesive layer is laminated on a protective film as described above, oligomers may be precipitated due to the heating and drying step, resulting in an increase in haze and deterioration in the appearance of the film. As the haze of the protective film increases, visibility decreases, making it difficult to inspect the appearance of the protective film while it is attached to the adherend, which poses a problem.
本發明中針對前述保護膜之課題，提供一種抗靜電膜及保護膜，即便抗靜電層之膜厚薄，於加熱乾燥步驟後仍可抑制霧度之上升，且表面電阻率低。 [用以解決課題之手段] In order to solve the above-mentioned problem of the protective film, the present invention provides an antistatic film and a protective film. Even if the antistatic layer is thin, the increase in haze can be suppressed after the heating and drying step, and the surface resistivity is low. [Means used to solve problems]
亦即，本發明由以下構成而成。 [1]一種聚酯膜，係於基材中至少單面積層有抗靜電層，前述抗靜電層至少含有導電性高分子、交聯劑、界面活性劑，前述界面活性劑之HLB值為9以下。 [2]於一態樣中，其中前述交聯劑為三聚氰胺系交聯劑。 [3]於一態樣中，其中前述三聚氰胺系交聯劑為全醚型甲基化三聚氰胺樹脂。 [4]於一態樣中，其中前述抗靜電層之表面電阻率為2[logΩ/□]至7[logΩ/□]。 [5]於一態樣中，其中前述界面活性劑為乙炔系界面活性劑。 [6]於一態樣中，其中前述導電性高分子為PEDOT：PSS(聚(3,4-乙烯二氧噻吩)：聚(4-苯乙烯磺酸鹽))。 [7]於一態樣中，係於聚酯膜中至少單面積層有黏著層之保護膜。 [發明功效] That is, the present invention consists of the following. [1] A polyester film having an antistatic layer layered on at least a single area of a base material. The antistatic layer contains at least a conductive polymer, a cross-linking agent, and a surfactant. The HLB value of the surfactant is 9. the following. [2] In one aspect, the cross-linking agent is a melamine-based cross-linking agent. [3] In one aspect, the aforementioned melamine-based cross-linking agent is a full ether type methylated melamine resin. [4] In one aspect, the surface resistivity of the aforementioned antistatic layer is 2 [logΩ/□] to 7 [logΩ/□]. [5] In one aspect, the aforementioned surfactant is an acetylene-based surfactant. [6] In one aspect, the conductive polymer is PEDOT:PSS (poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate)). [7] In one aspect, a protective film with an adhesive layer is laminated on at least one surface of the polyester film. [Invention effect]
根據本發明，提供一種於聚酯膜中至少單面積層有具有寡聚物嵌段性之抗靜電層的抗靜電膜，藉此可提供一種保護膜，係即便將於本抗靜電膜積層有黏著層之保護膜貼合於被黏著體的情形時亦可檢查外觀，並在剝離時抑制剝離帶電或異物附著。According to the present invention, there is provided an antistatic film in which an antistatic layer having oligomer block properties is laminated on at least a single area of a polyester film, thereby providing a protective film that can be laminated with the antistatic film. The appearance of the protective film of the adhesive layer can be checked even when it is attached to the adherend, and it can suppress peeling electrification or the attachment of foreign matter when peeling off.
本發明之積層聚酯膜(亦有單純稱作抗靜電膜的情形)係於聚酯膜中至少單面積層有抗靜電層的積層聚酯膜。此外，亦可將黏著層積層於抗靜電膜之單面而作為保護膜來使用。 例如，本發明之積層聚酯膜在於黏著層積層步驟中加熱乾燥的情形時，可抑制保護膜之霧度上升，將保護膜貼合於被黏著體的情形時，亦能檢查外觀。 The laminated polyester film of the present invention (sometimes simply called an antistatic film) is a laminated polyester film in which an antistatic layer is laminated on at least a single area of the polyester film. In addition, the adhesive layer can also be laminated on one side of the antistatic film to be used as a protective film. For example, the laminated polyester film of the present invention can suppress the increase in haze of the protective film when it is heated and dried in the step of laminating the adhesive layer, and can also check the appearance of the protective film when it is attached to an adherend.
以下，針對本發明進行詳細說明。Hereinafter, the present invention will be described in detail.
[聚酯膜] 本發明中用作為基材之聚酯膜主要是由聚酯樹脂構成之膜。此處，「主要是由聚酯樹脂構成之膜」意指由含有聚酯樹脂50質量%以上之樹脂組成物所形成之膜；與其他聚合物摻合之情形時，意指含有聚酯樹脂50質量%以上；與其他單體共聚之情形時，意指含有聚酯之重複結構單元50莫耳%以上。較佳為聚酯膜於構成膜之樹脂組成物中，含有聚酯樹脂90質量%以上、更佳為含有95質量%以上、進而更佳為含有100質量%。 [polyester film] The polyester film used as the base material in the present invention is mainly a film composed of polyester resin. Here, "film mainly composed of polyester resin" means a film formed of a resin composition containing more than 50% by mass of polyester resin; when blended with other polymers, it means a film containing polyester resin. More than 50 mass%; when copolymerized with other monomers, it means containing more than 50 mol% of the repeating structural units of polyester. The polyester film preferably contains 90 mass% or more of the polyester resin in the resin composition constituting the film, more preferably 95 mass% or more, and still more preferably 100 mass%.
作為聚酯樹脂，材料並無特別限定，可使用二羧酸成分與二醇成分聚縮合而形成之共聚物、或亦可使用聚酯樹脂之摻合樹脂。作為二羧酸成分，例如可列舉：對苯二甲酸、間苯二甲酸、鄰苯二甲酸、2,5-萘二甲酸、2,6-萘二甲酸、1,4-萘二甲酸、1,5-萘二甲酸、二苯甲酸、二苯氧乙烷二羧酸、二苯基碸羧酸、蒽二羧酸、1,3-環戊烷二羧酸、1,3-環己烷二羧酸、1,4-環己烷二羧酸、六氫鄰苯二甲酸、六氫間苯二甲酸、丙二酸、二甲基丙二酸、丁二酸、3,3-二乙基丁二酸、戊二酸、2,2-二甲基戊二酸、己二酸、2-甲基己二酸、三甲基己二酸、庚二酸、壬二酸、二體酸、癸二酸、辛二酸及十二碳二羧酸等。The material of the polyester resin is not particularly limited, and a copolymer formed by polycondensation of a dicarboxylic acid component and a glycol component can be used, or a blended resin of polyester resin can also be used. Examples of the dicarboxylic acid component include terephthalic acid, isophthalic acid, phthalic acid, 2,5-naphthalenedicarboxylic acid, 2,6-naphthalenedicarboxylic acid, 1,4-naphthalenedicarboxylic acid, 1 ,5-naphthalene dicarboxylic acid, diphenoxyethane dicarboxylic acid, diphenoxyethane dicarboxylic acid, diphenylcarboxylic acid, anthracene dicarboxylic acid, 1,3-cyclopentane dicarboxylic acid, 1,3-cyclohexane Dicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, hexahydrophthalic acid, hexahydroisophthalic acid, malonic acid, dimethylmalonic acid, succinic acid, 3,3-diethyl Succinic acid, glutaric acid, 2,2-dimethylglutaric acid, adipic acid, 2-methyladipic acid, trimethyladipic acid, pimelic acid, azelaic acid, dimeric acid , sebacic acid, suberic acid and dodecanedicarboxylic acid, etc.
作為構成聚酯樹脂之二醇成分，例如可列舉：乙二醇、丙二醇、六亞甲二醇、新戊二醇、1,2-環己烷二甲醇、1,4-環己烷二甲醇、癸二醇、1,3-丙二醇、1,4-丁二醇、1,5-戊二醇、1,6-己二醇、2,2-雙(4-羥基苯基)丙烷、雙(4-羥基苯基)碸等。Examples of glycol components constituting the polyester resin include ethylene glycol, propylene glycol, hexamethylene glycol, neopentyl glycol, 1,2-cyclohexanedimethanol, and 1,4-cyclohexanedimethanol. , Decanediol, 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, 2,2-bis(4-hydroxyphenyl)propane, bis (4-Hydroxyphenyl)碢etc.
構成聚酯樹脂之二羧酸成分與二醇成分可分別使用1種或2種以上。此外，可適當地添加偏苯三甲酸等其他酸成分或三羥甲基丙烷等其他羥基成分。The dicarboxylic acid component and the diol component constituting the polyester resin may be used individually by one type or two or more types. In addition, other acid components such as trimellitic acid or other hydroxyl components such as trimethylolpropane can be added appropriately.
作為聚酯樹脂，具體而言，可列舉：聚對苯二甲酸乙二酯、聚對苯二甲酸丙二酯、聚對苯二甲酸丁二酯、聚萘二甲酸乙二醇酯等，在這些聚酯樹脂中，從物性與成本的平衡來看，較佳為聚對苯二甲酸乙二酯。Specific examples of the polyester resin include polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, and the like. Among these polyester resins, polyethylene terephthalate is preferred in terms of a balance between physical properties and cost.
為了改善聚酯膜之滑動性、捲取性等之操作(handling)性，亦可使膜中含有惰性粒子，但若是用於光學用途等情形時，較佳為聚酯膜實質不含有粒子。於聚酯膜不含粒子的情形時，較佳為以在線塗佈所設置的塗層中含有粒子。藉由於聚酯膜不含粒子且於塗層含有粒子，透明性上升且變得容易檢查外觀等，故而較佳。In order to improve the handling properties such as sliding properties and winding properties of the polyester film, the film may also contain inert particles. However, when used for optical applications, etc., it is preferred that the polyester film contains substantially no particles. When the polyester film does not contain particles, it is preferred that the coating layer provided by in-line coating contains particles. Since the polyester film does not contain particles and contains particles in the coating layer, the transparency increases and the appearance becomes easy to inspect, so it is preferable.
本發明所使用之聚酯膜之霧度較佳為3%以下。更佳為2.5%以下，進而更佳為2.0%以下。若為1.5%以下則極佳。若為3%以下，則可在將保護膜貼合於被黏著體之狀態下檢查外觀等故而較佳，特佳為光學用途之構件為被黏著體的情形。The haze of the polyester film used in the present invention is preferably 3% or less. More preferably, it is 2.5% or less, and still more preferably, it is 2.0% or less. If it is 1.5% or less, it is excellent. If it is 3% or less, it is preferable because the appearance of the protective film can be inspected with the protective film attached to the adherend. It is particularly preferable when the member for optical purposes is the adherend.
本發明所使用之聚酯膜之表面的區域表面平均粗糙度(Sa)較佳為1nm至40nm之範圍，更佳為1nm至30nm。進而更佳為1nm至10nm。本發明所使用之聚酯膜之表面的最大突起高度(P)較佳為2μm以下，更佳為1.5μm以下。進而更佳為0.8μm以下。若Sa為40nm以下、P為2μm以下，則積層黏著層並捲取為輥狀時，沒有使黏著性表面變粗糙的風險，故而較佳。The regional average surface roughness (Sa) of the surface of the polyester film used in the present invention is preferably in the range of 1 nm to 40 nm, more preferably 1 nm to 30 nm. More preferably, it is 1 nm to 10 nm. The maximum protrusion height (P) on the surface of the polyester film used in the present invention is preferably 2 μm or less, more preferably 1.5 μm or less. Furthermore, it is more preferably 0.8 μm or less. When Sa is 40 nm or less and P is 2 μm or less, there is no risk of roughening the adhesive surface when the adhesive layer is laminated and rolled into a roll.
本發明中聚酯膜之厚度並無特別限定，較佳為12μm至188μm之範圍。更佳為18μm至125μm，進而更佳為25μm至100μm。若為12μm以上，則作為保護膜與被黏著體貼合時，產生皺褶的疑慮變低，若為188μm以下，則於成本面而言有利。The thickness of the polyester film in the present invention is not particularly limited, but is preferably in the range of 12 μm to 188 μm. More preferably, it is 18 micrometers - 125 micrometers, and still more preferably, it is 25 micrometers - 100 micrometers. If it is 12 μm or more, the risk of wrinkles occurring when the protective film is bonded to an adherend is reduced. If it is 188 μm or less, it is advantageous in terms of cost.
成為基材之聚酯膜可為單層，亦可為積層兩種以上之層的聚酯膜。此外，只要在能發揮本發明之功效的範圍內，可視需要於膜中含有各種添加劑。作為添加劑，例如可列舉：抗氧化劑、耐光劑、抗膠凝劑、有機潤濕劑、抗靜電劑、紫外線吸收劑、界面活性劑等。膜為積層構成的情形時，較佳為視需要對應各層的功能含有添加劑。The polyester film used as the base material may be a single layer or a polyester film in which two or more layers are laminated. In addition, as long as the effects of the present invention are exerted, various additives may be contained in the film as necessary. Examples of additives include antioxidants, light-resistant agents, anti-gelling agents, organic wetting agents, antistatic agents, ultraviolet absorbers, surfactants, and the like. When the film has a laminated structure, it is preferable to contain additives according to the functions of each layer as necessary.
聚酯膜例如可藉由如下方法獲得：將前述聚酯樹脂以熔融擠出、澆鑄滾筒進行冷卻硬化成為膜狀而形成膜。作為本發明之聚酯膜，可為未延伸膜、延伸膜中任一種，但從機械強度或耐化學品性等耐久性的觀點來看，較佳為延伸膜。於聚酯膜為延伸膜之情形時，聚酯膜的拉伸方法並無特別限定，可採用縱向單軸拉伸法、橫向單軸拉伸法、縱橫逐步雙軸延伸、縱橫同步雙軸延伸法等。The polyester film can be obtained, for example, by melt-extruding the polyester resin and cooling and hardening the polyester resin into a film shape with a casting drum to form a film. The polyester film of the present invention may be an unstretched film or a stretched film, but from the viewpoint of durability such as mechanical strength or chemical resistance, a stretched film is preferred. When the polyester film is a stretched film, the stretching method of the polyester film is not particularly limited. Longitudinal uniaxial stretching, transverse uniaxial stretching, longitudinal and transverse stepwise biaxial stretching, and longitudinal and transverse simultaneous biaxial stretching can be used. Law etc.
為了提高聚酯膜之表層與密接性上升層的密接性，可進行錨塗層、電暈處理、電漿處理、火焰處理等表面處理。設置錨塗層的情形時，從成本等觀點來看，較佳為進行在線塗佈 。In order to improve the adhesion between the surface layer of the polyester film and the adhesion rising layer, surface treatments such as anchor coating, corona treatment, plasma treatment, and flame treatment can be performed. When installing anchor coating, in-line coating is preferred from the viewpoint of cost and other factors.
[抗靜電層] 本發明之抗靜電膜必須於聚酯膜中至少單面積層抗靜電層。抗靜電層可僅積層於單面，亦可積層於雙面。藉由積層抗靜電層，即便於積層黏著層作為保護膜使用的情形時，亦能抑制黏著層與被黏著體之剝離帶電、異物之附著，故而較佳。 [Antistatic layer] The antistatic film of the present invention must have an antistatic layer layered on at least a single area of the polyester film. The antistatic layer may be laminated on only one side or may be laminated on both sides. By laminating an antistatic layer, even when the adhesive layer is laminated and used as a protective film, it is preferable because it can suppress the peeling charge between the adhesive layer and the adherend and the adhesion of foreign matter.
抗靜電層係至少含有導電性高分子、交聯劑、界面活性劑經硬化而成之層。此種組成物亦有被稱作抗靜電層形成用組成物的情形。The antistatic layer is a hardened layer containing at least a conductive polymer, a cross-linking agent, and a surfactant. Such a composition may be called an antistatic layer-forming composition.
抗靜電層之積層手段並無特別限定，可使用塗佈法、真空蒸鍍法、貼合等已知的方法，但從成本的觀點而言，較佳為藉由塗佈含有抗靜電劑之塗液來設置。The method of laminating the antistatic layer is not particularly limited, and known methods such as coating, vacuum evaporation, and lamination can be used. However, from a cost perspective, it is preferable to apply a layer containing an antistatic agent. Apply liquid to set.
[導電性高分子] 本發明之導電性高分子為可賦予抗靜電性之高分子，可使用陽離子性化合物等之利用離子傳導之高分子、π電子共軛系導電性高分子等。於低濕度下的抗靜電性之方面來看，較佳為使用π電子共軛系導電性高分子。此外，π電子共軛系導電性高分子並不依存於空氣中之水分且能以高水準維持抗靜電機能，所以能在保護膜之各種使用環境中均具有良好之抗靜電機能，故而較佳。 此外，於不損及本發明之導電性高分子所發揮之功效的範圍內，可併用抗靜電劑。作為抗靜電劑，可為本發明之導電性高分子以外的陽離子性化合物等之利用離子傳導之高分子、π電子共軛系導電性高分子，可使用界面活性劑、氧化矽化合物、導電性之金屬化合物。 [Conductive polymer] The conductive polymer of the present invention is a polymer that can impart antistatic properties, and polymers utilizing ion conduction such as cationic compounds, π-electron conjugated conductive polymers, etc. can be used. From the viewpoint of antistatic properties under low humidity, it is preferable to use π electron conjugated conductive polymers. In addition, π-electron conjugated conductive polymers do not depend on moisture in the air and can maintain antistatic properties at a high level. Therefore, they can have good antistatic properties in various usage environments of protective films, so they are preferred. . In addition, an antistatic agent may be used together within the range that does not impair the effect of the conductive polymer of the present invention. As the antistatic agent, polymers utilizing ion conduction such as cationic compounds other than the conductive polymer of the present invention, π-electron conjugated conductive polymers, surfactants, silica oxide compounds, conductive polymers, etc. can be used. of metal compounds.
作為π電子共軛系導電性高分子，可列舉：包含苯胺或苯胺之衍生物作為構成單元之苯胺系高分子、包含吡咯或吡咯之衍生物作為構成單元之吡咯系高分子、包含乙炔或乙炔之衍生物作為構成單元之乙炔系高分子、包含噻吩或噻吩之衍生物作為構成單元之噻吩系高分子等。若是想要得到高透明性，則較佳為作為π電子共軛系導電性高分子不含有氮原子，其中從透明性的方面來看，較佳為包含噻吩或噻吩之衍生物作為構成單元之噻吩系高分子，尤佳為聚伸烷基二氧噻吩二醇。作為聚伸烷基二氧噻吩二醇，可列舉：聚乙烯二氧噻吩、聚丙烯二氧噻吩、聚(乙烯／丙烯)二氧噻吩等。Examples of the π-electron conjugated conductive polymer include: aniline-based polymers containing aniline or a derivative of aniline as a structural unit; pyrrole-based polymers containing pyrrole or a derivative of pyrrole as a structural unit; and acetylene or acetylene. Acetylene-based polymers containing derivatives as structural units, thiophene-based polymers containing thiophene or derivatives of thiophene as structural units, etc. If high transparency is desired, it is preferable that the π-electron conjugated conductive polymer does not contain nitrogen atoms. Among them, from the perspective of transparency, it is preferable that the π-electron conjugated conductive polymer contains thiophene or a derivative of thiophene as a structural unit. The thiophene polymer is preferably polyalkylenedioxythiophene diol. Examples of the polyalkylenedioxythiophene diol include polyethylenedioxythiophene, polypropylenedioxythiophene, poly(ethylene/propylene)dioxythiophene, and the like.
再者，包含噻吩或噻吩之衍生物作為構成單元之噻吩系高分子，為了進一步提升抗靜電性可以添加摻雜劑，例如可相對於包含噻吩或噻吩之衍生物作為構成單元之噻吩系高分子100質量份，調配0.1質量份以上至500質量份以下之摻雜劑。調配過多的情形時，電子移動變得困難，故有抗靜電機能降低的問題，反之，調配過少的情形時，有對溶媒的分散性低的問題。作為此種摻雜劑，可列舉：LiCl、R 1-30COOLi(R 1-30：碳數為1以上至30以下之飽和烴基)、R 1-30SO 3Li、R 1-30COONa、R 1-30SO 3Na、R 1-30COOK、R 1-30SO 3K、四乙胺基、I 2、BF 3Na、BF 4Na、HClO 4、CF 3SO 3H、FeCl 3、7,7,8,8-四氰基對苯二醌二甲烷(TCNQ)、Na 2B 10Cl 10、酞青素、紫質、麩胺酸、烷基磺酸鹽、聚苯乙烯磺酸Na(K、Li)鹽、苯乙烯／苯乙烯磺酸Na(K、Li)鹽共聚物、聚苯乙烯磺酸陰離子、苯乙烯磺酸／苯乙烯磺酸陰離子共聚物等。 Furthermore, dopants may be added to thiophene-based polymers containing thiophene or thiophene derivatives as structural units in order to further improve antistatic properties, for example, compared to thiophene-based polymers containing thiophene or thiophene derivatives as structural units. 100 parts by mass, prepare a dopant ranging from 0.1 parts by mass to less than 500 parts by mass. When too much is blended, it becomes difficult for electrons to move, so there is a problem of reduced antistatic performance. On the contrary, when too little is blended, there is a problem of low dispersibility in the solvent. Examples of such dopants include: LiCl, R 1-30 COOLi (R 1-30 : saturated hydrocarbon group with a carbon number of 1 to 30), R 1-30 SO 3 Li, R 1-30 COONa, R 1-30 SO 3 Na, R 1-30 COOK, R 1-30 SO 3 K, tetraethylamino, I 2 , BF 3 Na, BF 4 Na, HClO 4 , CF 3 SO 3 H, FeCl 3 , 7,7,8,8-tetracyanoquinodimethane (TCNQ), Na 2 B 10 Cl 10 , phthalocyanin, porphyrin, glutamic acid, alkyl sulfonate, polystyrene sulfonic acid Na (K, Li) salt, styrene/styrene sulfonate Na (K, Li) salt copolymer, polystyrene sulfonate anion, styrene sulfonate/styrene sulfonate anion copolymer, etc.
本發明中抗靜電層中所含之導電性高分子相對於抗靜電層中之全固體含量100質量%，較佳為含有5質量%以上，更佳為含有10質量%以上。再者，使用π電子共軛系導電性高分子作為抗靜電劑的情況下，使用前述摻雜劑的情形時，本案所規定之π電子共軛系導電性高分子之抗靜電層中之含量為導電性高分子與前述摻雜劑的合計量。 藉由含有此種量的抗靜電劑，可賦予良好之抗靜電性。 In the present invention, the conductive polymer contained in the antistatic layer is preferably 5 mass% or more, and more preferably 10 mass% or more based on 100 mass% of the total solid content in the antistatic layer. Furthermore, when a π-electron conjugated conductive polymer is used as an antistatic agent, when the aforementioned dopant is used, the content of the π-electron conjugated conductive polymer in the antistatic layer stipulated in this case is the total amount of conductive polymer and the aforementioned dopant. By containing this amount of antistatic agent, good antistatic properties can be imparted.
本發明中抗靜電層中所含之導電性高分子相對於抗靜電層中之全固體含量100質量%，較佳為50質量%以下，更佳為40質量%以下。再者，使用π電子共軛系導電性高分子作為抗靜電劑的情況下，使用前述摻雜劑的情形時，本案所規定之π電子共軛系導電性高分子之抗靜電層中之含量為導電性高分子與前述摻雜劑的合計量。 藉由以此種量含有抗靜電劑，可以不引起導電性高分子與交聯劑的相互作用，塗液不易凝集、抗靜電層之缺點少且保持高透明性。 In the present invention, the conductive polymer contained in the antistatic layer is preferably 50 mass% or less, more preferably 40 mass% or less based on 100 mass% of the total solid content in the antistatic layer. Furthermore, when a π-electron conjugated conductive polymer is used as an antistatic agent, when the aforementioned dopant is used, the content of the π-electron conjugated conductive polymer in the antistatic layer stipulated in this case is the total amount of conductive polymer and the aforementioned dopant. By containing the antistatic agent in this amount, the interaction between the conductive polymer and the cross-linking agent is not caused, the coating liquid is less likely to agglomerate, the antistatic layer has fewer defects, and high transparency is maintained.
[交聯劑] 本發明中，為了於抗靜電層形成交聯結構，抗靜電層係由含有交聯劑之組成物所形成。藉由含有交聯劑，提高耐久性且即便於高溫高濕度條件下處理的情形時，抗靜電機能之降低亦能得到抑制，故而較佳。作為具體的交聯劑，可列舉：脲系、環氧系、三聚氰胺系、異氰酸酯系、噁唑啉系、碳二亞胺系、氮丙啶系等。於一態樣中，交聯劑較佳為三聚氰胺系交聯劑，為了提高抗靜電層之交聯密度，較佳為提高三聚氰胺系交聯劑之反應性。關於反應性高之三聚氰胺系交聯劑將於後文說明。此外，為了促進交聯反應，可視需要適當地使用觸媒等。 [Cross-linking agent] In the present invention, in order to form a cross-linked structure in the anti-static layer, the anti-static layer is formed of a composition containing a cross-linking agent. By containing a cross-linking agent, durability can be improved and the decrease in antistatic performance can be suppressed even when treated under high temperature and high humidity conditions, so it is preferable. Specific cross-linking agents include urea-based, epoxy-based, melamine-based, isocyanate-based, oxazoline-based, carbodiimide-based, aziridine-based, and the like. In one aspect, the cross-linking agent is preferably a melamine-based cross-linking agent. In order to increase the cross-linking density of the antistatic layer, it is preferable to increase the reactivity of the melamine-based cross-linking agent. The highly reactive melamine-based cross-linking agent will be described later. In addition, in order to promote the cross-linking reaction, a catalyst, etc. may be used appropriately as necessary.
作為本發明中抗靜電層所使用之三聚氰胺系交聯劑並無特別限定，可使用一般的三聚氰胺系交聯劑，但較佳為將三聚氰胺與甲醛縮合而得，且1分子中分別具有1個以上之三嗪環、以及1個以上之羥甲基及／或烷氧基甲基。具體而言，較佳為對將三聚氰胺與甲醛縮合而得的羥甲基三聚氰胺衍生物與作為低級醇之甲醇、乙醇、異丙醇、丁醇等進行脫水縮合反應而醚化之化合物等。作為羥甲基化三聚氰胺衍生物，例如可列舉：單羥甲基三聚氰胺、二羥甲基三聚氰胺、三羥甲基三聚氰胺、四羥甲基三聚氰胺、五羥甲基三聚氰胺、六羥甲基三聚氰胺。可使用1種，亦可使用2種以上。The melamine-based cross-linking agent used for the antistatic layer in the present invention is not particularly limited. A general melamine-based cross-linking agent can be used, but it is preferably obtained by condensing melamine and formaldehyde, each of which has one in one molecule. The above triazine ring, and one or more hydroxymethyl and/or alkoxymethyl groups. Specifically, preferred are compounds in which a methylol melamine derivative obtained by condensing melamine and formaldehyde and a lower alcohol such as methanol, ethanol, isopropyl alcohol, butanol, etc. are subjected to a dehydration condensation reaction and etherified. Examples of methylol melamine derivatives include monomethylol melamine, dimethylol melamine, trimethylol melamine, tetramethylol melamine, pentamethylol melamine, and hexamethylol melamine. One type may be used, or two or more types may be used.
為了提高三聚氰胺系交聯劑之反應性，且提高抗靜電層之交聯密度，較佳為使用1分子中具備更多交聯點的羥甲基型甲基化三聚氰胺或六烷氧基甲基三聚氰胺，更佳為使用反應性更優異的六烷氧基甲基三聚氰胺，特佳為使用六甲氧基甲基三聚氰胺。此時，所謂六羥甲基三聚氰胺係指下述式(a)中、X為羥甲基(-CH 2-OH)的化合物。所謂六烷氧基甲基三聚氰胺係指於羥甲基三聚氰胺衍生物使用醇進行脫水縮合反應的化合物，X為(-CH 2-OR、R為碳數1至4之烷基)的化合物。所謂六甲氧基甲基三聚氰胺係指X為(-CH 2-OMe)的化合物。 In order to increase the reactivity of the melamine-based cross-linking agent and increase the cross-linking density of the antistatic layer, it is preferable to use hydroxymethyl-type methylated melamine or hexaalkoxymethyl with more cross-linking points per molecule. As for melamine, hexaalkoxymethyl melamine with higher reactivity is more preferably used, and hexamethoxymethyl melamine is particularly preferably used. At this time, hexamethylol melamine means a compound in which X is a hydroxymethyl group (-CH 2 -OH) in the following formula (a). Hexaalkoxymethylmelamine refers to a compound in which a hydroxymethylmelamine derivative is dehydrated and condensated using an alcohol, and X is (-CH 2 -OR, R is an alkyl group having 1 to 4 carbon atoms). The so-called hexamethoxymethylmelamine refers to a compound in which X is (-CH 2 -OMe).
[化學式1] [Chemical formula 1]
前述(a)中之X可各自相同，亦可不同。此外前述R可各自相同，亦可不同。此外，X亦可為(-H)。X in the aforementioned (a) may be the same or different. In addition, the aforementioned R may be the same or different. In addition, X may also be (-H).
本發明所使用之三聚氰胺系交聯劑較佳為並非單一之化合物，而是為多種化合物之混合體。從三聚氰胺系化合物中之主成分的化合物結構來看，可大致分為全醚型(X＝-CH 2-OR、R為碳數1至4之烷基)、羥甲基型(X＝-CH 2-OH)、亞胺基型(X＝-H)、亞胺基／羥甲基型。 於一態樣中，從反應性之觀點來看，較佳為使用全醚型、羥甲基型，更佳為使用全醚型，最佳為使用全醚型中R為甲基的六甲氧基甲基三聚氰胺(CAS編號3089-11-0)。越使用該六甲氧基甲基三聚氰胺之含有率高的三聚氰胺系化合物，越能製成反應性高且交聯密度高的抗靜電層。 The melamine cross-linking agent used in the present invention is preferably not a single compound, but a mixture of multiple compounds. From the perspective of the compound structure of the main component of melamine-based compounds, they can be roughly divided into all-ether type (X=-CH 2 -OR, R is an alkyl group with 1 to 4 carbon atoms), hydroxymethyl type (X=- CH 2 -OH), imino type (X=-H), imino/hydroxymethyl type. In one aspect, from the viewpoint of reactivity, it is preferable to use a full ether type or a hydroxymethyl type, more preferably to use a full ether type, and most preferably to use a full ether type in which R is methyl hexamethoxy Methyl melamine (CAS No. 3089-11-0). The more a melamine-based compound with a high content of hexamethoxymethylmelamine is used, the more reactive and cross-linked an antistatic layer it is possible to produce.
本發明中抗靜電層所使用之三聚氰胺系交聯劑中，較佳為重量平均聚合度為2.5以下，較佳為2.3以下，更佳為2.0以下。若重量平均聚合度為2.5以下，則可與導電性高分子的相溶性良好，此外，可抑制塗液之凝集，形成缺點少的膜。 進而言之，本發明中，若重量平均聚合度為2.5以下，則三聚氰胺系交聯劑所含之單核體之含量變多，可製成反應性優異、交聯密度提高、寡聚物不易析出的抗靜電層，故而較佳。 例如，重量平均聚合度可為1.1以上，亦可超過1.5。 Among the melamine-based cross-linking agents used in the antistatic layer of the present invention, the weight average degree of polymerization is preferably 2.5 or less, preferably 2.3 or less, and more preferably 2.0 or less. If the weight average polymerization degree is 2.5 or less, the compatibility with the conductive polymer will be good, and aggregation of the coating liquid will be suppressed, thereby forming a film with few defects. Furthermore, in the present invention, if the weight average degree of polymerization is 2.5 or less, the content of mononuclear bodies contained in the melamine-based cross-linking agent increases, and it is possible to produce a product with excellent reactivity, increased cross-linking density, and difficult oligomerization. Precipitated antistatic layer, so it is better. For example, the weight average degree of polymerization may be 1.1 or more, or may exceed 1.5.
三聚氰胺系交聯劑在三聚氰胺系交聯劑之合成過程中，有時混入含有亞胺基(-NH 2-)的成分、或混入多核體。即便將這些三聚氰胺衍生物混合，只要三聚氰胺系交聯劑之重量平均聚合度在前述範圍內則反應性優異，可各自適當地使用。 Melamine-based cross-linking agent In the synthesis process of the melamine-based cross-linking agent, a component containing an imine group (-NH 2 -) or a polynuclear body may be mixed into the melamine-based cross-linking agent. Even if these melamine derivatives are mixed, as long as the weight average degree of polymerization of the melamine-based crosslinking agent is within the aforementioned range, the reactivity is excellent, and each of them can be used appropriately.
本發明之抗靜電層中，三聚氰胺系交聯劑相對於抗靜電層中之全固體含量100質量%，較佳為含有50質量%以上至95質量%以下，更佳為含有55質量%以上至95質量%以下，進而更佳為60質量%以上至95質量%以下。藉著含有三聚氰胺系交聯劑50質量%以上，抗靜電層可藉由三聚氰胺系交聯劑之自交聯而得到高交聯密度，由於成為了緻密的抗靜電層而抑制寡聚物析出，故而較佳。此時，由於溶媒或界面活性劑在乾燥過程中大部分被蒸發，因此將抗靜電層之全固體含量視為實質上三聚氰胺系交聯劑與導電性高分子之固體含量的合計值亦沒有問題。In the antistatic layer of the present invention, the melamine cross-linking agent preferably contains 50 mass% or more and 95 mass% or less based on 100 mass% of the total solid content in the antistatic layer, and more preferably 55 mass% or more and no more than 95 mass%. 95 mass% or less, more preferably 60 mass% or more and 95 mass% or less. By containing more than 50% by mass of the melamine-based cross-linking agent, the antistatic layer can obtain a high cross-linking density through self-crosslinking of the melamine-based cross-linking agent, and it becomes a dense antistatic layer that suppresses oligomer precipitation. Therefore it is better. At this time, since most of the solvent or surfactant is evaporated during the drying process, there is no problem in considering the total solid content of the antistatic layer as essentially the total solid content of the melamine-based cross-linking agent and the conductive polymer. .
為了提高外觀，本發明之抗靜電層係由含有界面活性劑之組成物所形成。作為界面活性劑，可列舉：聚矽氧烷系界面活性劑、具有全氟烷基的氟系界面活性劑、或乙炔系界面活性劑等之烴系等。 尤佳為含有乙炔系界面活性劑。藉由含有乙炔系界面活性劑，即便將本抗靜電膜作為保護膜使用的情形時，能夠避免抗靜電膜向所保護之產品的移轉，可減少對最終產品的不良影響。 In order to improve the appearance, the antistatic layer of the present invention is formed of a composition containing a surfactant. Examples of the surfactant include hydrocarbon-based surfactants such as polysiloxane-based surfactants, fluorine-based surfactants having a perfluoroalkyl group, and acetylene-based surfactants. Particularly preferably, it contains an acetylene-based surfactant. By containing an acetylene-based surfactant, even when the antistatic film is used as a protective film, the transfer of the antistatic film to the product being protected can be avoided, thereby reducing adverse effects on the final product.
本發明之抗靜電膜積層有黏著層之保護膜用於光學構件等之製造步驟，因此為了不污染製造步驟，作為用於抗靜電層的界面活性劑，較佳為使用烴系之乙炔系界面活性劑。作為市售的乙炔系界面活性劑之例子，可列舉：Surfynol系列或OLFINE系列(日信化學工業公司)。The antistatic film of the present invention is a protective film laminated with an adhesive layer and is used in the manufacturing process of optical components. Therefore, in order not to contaminate the manufacturing process, it is preferable to use a hydrocarbon-based acetylene-based interface as the surfactant for the antistatic layer. active agent. Examples of commercially available acetylene-based surfactants include Surfynol series or OLFINE series (Nissin Chemical Industry Co., Ltd.).
本發明之抗靜電層所含之界面活性劑的HLB值為9以下。更佳為HLB值為8以下。藉由含有HLB值為9以下之界面活性劑，寡聚物不易向膜表面析出，可得到霧度低之抗靜電膜，故而較佳。雖然此現象無法以理論解釋，但可認為原因如下：一般而言聚酯膜所含之寡聚物之極性高，若HLB值變大則界面活性劑與寡聚物的相溶性變好，故界面活性劑於塗膜表面配向時，寡聚物也一起於塗膜表面析出，因此寡聚物析出量增加。本發明係探明可抑制寡聚物析出量的HLB值之上限而完成的發明。The HLB value of the surfactant contained in the antistatic layer of the present invention is 9 or less. More preferably, the HLB value is 8 or less. By containing a surfactant with an HLB value of 9 or less, oligomers are less likely to precipitate on the film surface and an antistatic film with low haze can be obtained, so it is preferable. Although this phenomenon cannot be explained theoretically, the reason can be considered as follows: Generally speaking, the oligomers contained in the polyester film have high polarity. If the HLB value becomes larger, the compatibility between the surfactant and the oligomers becomes better. Therefore, When the surfactant is aligned on the surface of the coating film, oligomers also precipitate on the surface of the coating film, so the amount of oligomer precipitation increases. The present invention was accomplished by elucidating the upper limit of the HLB value that can suppress the amount of oligomer precipitation.
本發明之抗靜電層所含之界面活性劑的HLB值較佳為3以上，更佳為4以上。若HLB值過低，則作為界面活性劑之能力下降，會導致外觀不良。藉由使用HLB值為3以上之界面活性劑，抗靜電層塗佈液之分散性不會變差，故而較佳。 再者，HLB值(Hydrophile-Lipophile Balance；親水親油平衡值)是表示親水性與疏水性之平衡的值，可藉由格里芬法(Griffin method)或戴維斯法(Davies method)等種種計算方法來求得。 The HLB value of the surfactant contained in the antistatic layer of the present invention is preferably 3 or more, more preferably 4 or more. If the HLB value is too low, the ability to act as a surfactant will be reduced, resulting in poor appearance. It is preferable to use a surfactant with an HLB value of 3 or more because the dispersibility of the antistatic layer coating liquid will not deteriorate. Furthermore, the HLB value (Hydrophile-Lipophile Balance; hydrophile-lipophile balance value) is a value that represents the balance between hydrophilicity and hydrophobicity, and can be measured by the Griffin method or the Davies method, etc. Various calculation methods can be used to obtain it.
以使用HLB值為9以下之界面活性劑來兼顧寡聚物析出與膜外觀的功效而言，更佳為於導電性分子使用PEDOT／PSS之情形。此外，作為交聯劑，較佳為使用三聚氰胺的情形。可認為這是由於各材料與界面活性劑之相容性的平衡良好。 例如，藉由含有具有前述HLB之界面活性劑與三聚氰胺系交聯劑，本發明之抗靜電層可使膜厚更薄，可進一步保持塗膜強度，甚至還能抑制聚酯膜所含之寡聚物的析出。 此外，抗靜電層所要求之抗靜電機能無論於加熱前後、醇處理後均能良好地保持。 In terms of using a surfactant with an HLB value of 9 or less to achieve both oligomer precipitation and film appearance, it is better to use PEDOT/PSS as the conductive molecule. Furthermore, it is preferable to use melamine as the cross-linking agent. This is considered to be because the compatibility of each material and the surfactant is well balanced. For example, by containing the surfactant having the aforementioned HLB and the melamine-based cross-linking agent, the antistatic layer of the present invention can make the film thickness thinner, further maintain the strength of the coating film, and even suppress the oligosaccharide content of the polyester film. Precipitation of polymers. In addition, the antistatic performance required by the antistatic layer can be well maintained before and after heating and after alcohol treatment.
於抗靜電層中，除了前述以外，在不損及本發明之目的之範圍內，亦可視需要混合滑剤、色素、紫外線吸收劑、矽烷偶合劑等。In the antistatic layer, in addition to the above, slip agents, pigments, ultraviolet absorbers, silane coupling agents, etc. may also be mixed as necessary within the scope that does not impair the purpose of the present invention.
抗靜電層中實質上不含聚矽氧烷化合物。 本發明中所謂「實質上不含聚矽氧烷化合物」係定義為以螢光x射線分析定量Si元素時為50ppm以下，較佳為10ppm以下，最佳為偵測極限以下的含量。這是因為即便不主動往抗靜電層中添加聚矽氧烷成分，有時來自外來異物的汙染成分、或者是原料樹脂或膜之製造步驟中附著於產線或裝置的髒污剝離而混入抗靜電層中。 藉由於抗靜電層中實質上不含聚矽氧烷化合物，即便將本抗靜電膜作為保護膜使用的情形時，仍能夠避免抗靜電膜向所保護之產品的聚矽氧烷之移轉，可減少對最終產品的不良影響。 The antistatic layer contains substantially no polysiloxane compounds. The so-called "substantially free of polysiloxane compound" in the present invention is defined as a content of 50 ppm or less, preferably 10 ppm or less, and most preferably less than the detection limit when quantifying Si element by fluorescence x-ray analysis. This is because even if the polysiloxane component is not actively added to the antistatic layer, contamination components from foreign matter or dirt adhering to the production line or equipment during the manufacturing steps of the raw resin or film may be mixed into the antistatic layer. in the electrostatic layer. Since the antistatic layer contains substantially no polysiloxane compounds, even when the antistatic film is used as a protective film, the transfer of the antistatic film to the polysiloxane of the product being protected can still be avoided. Can reduce adverse effects on the final product.
本發明之抗靜電層之膜厚較佳為0.005μm以上至1μm以下。更佳為0.01μm以上至0.5μm以下，進而更佳為0.01μm以上至0.2μm以下。若抗靜電層之膜厚為0.005μm以上，可得到抗靜電劑功效，故而較佳。另一方面，若為1μm以下，著色少且透明性高，故而較佳。The film thickness of the antistatic layer of the present invention is preferably from 0.005 μm to 1 μm. More preferably, it is 0.01 μm or more and 0.5 μm or less, and still more preferably, it is 0.01 μm or more and 0.2 μm or less. If the film thickness of the antistatic layer is 0.005 μm or more, the effect of the antistatic agent can be obtained, so it is preferable. On the other hand, if it is 1 μm or less, the coloring is less and the transparency is high, so it is preferable.
此處，本發明之積層聚酯膜之特徵在於，界面活性劑之HLB值為9以下。藉由使用HLB值為9以下之界面活性劑，即便於抗靜電層加工步驟中進行加熱，寡聚物變得難以向膜表面析出，且即便抗靜電層之膜厚薄，於加熱後霧度上升仍少，並可提供一種保護膜，係將本抗靜電膜積層有黏著層之保護膜貼合於被黏著體的情形時仍能檢查外觀，並於剝離時抑制剝離帶電或異物附著。Here, the laminated polyester film of the present invention is characterized in that the HLB value of the surfactant is 9 or less. By using a surfactant with an HLB value of 9 or less, oligomers become difficult to precipitate on the film surface even if the antistatic layer is heated during the processing step, and even if the antistatic layer has a thin film thickness, the haze increases after heating. It is still less, and can provide a protective film that can still check the appearance when the protective film laminated with the antistatic film and the adhesive layer is attached to the adherend, and can suppress peeling electrification or foreign matter attachment during peeling.
本發明之積層聚酯膜之霧度較佳為3.0%以下。更佳為2.0%以下，進而更佳為1.5%以下。若為1.0%以下則極佳。若為3.0%以下，則可在將保護膜貼合於被黏著體之狀態下可檢查外觀等故而較佳，特佳為光學用途之構件為被黏著體的情形。霧度可為0，亦可為例如0.1%以上。The haze of the laminated polyester film of the present invention is preferably 3.0% or less. More preferably, it is 2.0% or less, and still more preferably, it is 1.5% or less. If it is 1.0% or less, it is excellent. If it is 3.0% or less, it is preferable because the appearance of the protective film can be inspected with the protective film attached to the adherend. It is particularly preferable when the member for optical purposes is the adherend. The haze may be 0 or, for example, 0.1% or more.
本發明之積層聚酯膜在經140℃加熱10分鐘後的霧度較佳為3.0%以下。更佳為2.5%以下，進而更佳為2.0%以下。若為1.5%以下則極佳。若為3.0%以下，則將保護膜貼合於被黏著體之狀態下可檢查外觀等故而較佳，特佳為光學用途之構件為被黏著體的情形。在經140℃加熱10分鐘後的霧度可為0，例如亦可為0.1%以上。 不應僅僅侷限於特定理論的解釋，藉由具有本發明之抗靜電層，可得到反應性優異、交聯密度提高、寡聚物不易析出之抗靜電層。結果推測可抑制在經140℃加熱10分鐘後的霧度之大幅上升。 The haze of the laminated polyester film of the present invention after heating at 140°C for 10 minutes is preferably 3.0% or less. More preferably, it is 2.5% or less, and still more preferably, it is 2.0% or less. If it is 1.5% or less, it is excellent. If it is 3.0% or less, it is preferable because the appearance of the protective film can be inspected with the protective film attached to the adherend. It is particularly preferable when the member for optical purposes is the adherend. The haze after heating at 140°C for 10 minutes may be 0, for example, it may be 0.1% or more. It should not be limited to a specific theoretical explanation. By having the antistatic layer of the present invention, an antistatic layer with excellent reactivity, increased cross-linking density, and less tendency for oligomers to precipitate can be obtained. As a result, it is presumed that a significant increase in haze after heating at 140°C for 10 minutes can be suppressed.
例如，將積層聚酯膜在經140℃加熱10分鐘後的霧度減去加熱前之積層聚酯膜的霧度後之Δ霧度值可為-0.2以上至2.5以下，例如可為-0.2以上至1.6以下。藉由Δ霧度值在此種範圍內，可得到寡聚物不易析出的抗靜電層。 藉由形成寡聚物不易析出的抗靜電層，可發揮如下功效：即便於黏著層積層步驟經過加熱乾燥，保護膜之辨識性不易降低，將保護膜貼合於被黏著體的情形時亦能檢查外觀。 For example, the Δ haze value obtained by subtracting the haze of the laminated polyester film before heating from the haze of the laminated polyester film after heating at 140° C. for 10 minutes can be from -0.2 to 2.5, for example, -0.2 above to below 1.6. When the Δ haze value is within this range, an antistatic layer in which oligomers are less likely to precipitate can be obtained. By forming an antistatic layer in which oligomers are less likely to precipitate, the following effects can be achieved: Even if the adhesive layer lamination step is heated and dried, the visibility of the protective film is not easily reduced, and the protective film can be attached to the adherend. Check the appearance.
本發明之抗靜電層之表面電阻率為7[logΩ／□]以下。更佳為6.5[logΩ／□]以下，進而更佳為6[logΩ／□]以下。藉由將表面電阻率設為7[logΩ／□]以下可抑制對保護膜之靜電，可防止步驟中之異物附著，進而可抑制保護膜之靜電對所保護之產品於電氣面的不良影響。The surface resistivity of the antistatic layer of the present invention is 7 [logΩ/□] or less. More preferably, it is 6.5 [logΩ/□] or less, and still more preferably, it is 6 [logΩ/□] or less. By setting the surface resistivity to 7 [logΩ/□] or less, the static electricity on the protective film can be suppressed, preventing foreign matter from adhering during the process, and thus suppressing the negative impact of the static electricity on the protective film on the electrical surface of the protected product.
此外，抗靜電膜之表面電阻率之下限無需特別設定，較佳為2[logΩ／□]以上。若抗靜電膜之表面電阻率未達2[logΩ／□]，則抗靜電層之加工成本增加故而不佳。In addition, the lower limit of the surface resistivity of the antistatic film does not need to be specifically set, but is preferably 2 [logΩ/□] or more. If the surface resistivity of the antistatic film is less than 2 [logΩ/□], the processing cost of the antistatic layer will increase, which is undesirable.
本發明所使用之抗靜電膜之總透光率較佳為80%以上。更佳為85%以上，進而更佳為88%以上。若為80%以上，則將保護膜貼合於被黏著體之狀態下可檢查外觀等故而較佳，特佳為光學用途之構件為被黏著體的情形。The total light transmittance of the antistatic film used in the present invention is preferably above 80%. More preferably, it is 85% or more, and even more preferably, it is 88% or more. If it is 80% or more, it is preferable because the appearance of the protective film can be inspected while the protective film is attached to the adherend. It is particularly preferable when the member for optical purposes is the adherend.
抗靜電層較佳為即使以醇擦拭後，表面電阻率變化較佳為1.3倍以下。更佳為1.2倍以下，進而更佳為1.1倍以下。若為1.3倍以下，即便於黏著加工等步驟使用醇，在成為保護膜時仍維持初期之表面電阻率故而較佳。The antistatic layer preferably has a surface resistivity change of 1.3 times or less even after wiping with alcohol. More preferably, it is 1.2 times or less, and still more preferably, it is 1.1 times or less. If it is 1.3 times or less, it is preferable because the initial surface resistivity is maintained when forming a protective film even if alcohol is used in steps such as adhesion processing.
抗靜電層之表面之區域表面平均粗糙度(Sa)較佳為1nm至40nm之範圍，更佳為1nm至30nm。進而更佳為1nm至10nm。本發明所使用之抗靜電膜之表面之最大突起高度(P)較佳為2μm以下，更佳為1.5μm以下。進而更佳為0.8μm以下。若Sa為40nm以下、P為2μm以下，則積層黏著層並捲取為輥狀時，沒有使黏著性表面變粗糙的風險，故而較佳。The regional average surface roughness (Sa) of the surface of the antistatic layer is preferably in the range of 1 nm to 40 nm, more preferably 1 nm to 30 nm. More preferably, it is 1 nm to 10 nm. The maximum protrusion height (P) on the surface of the antistatic film used in the present invention is preferably 2 μm or less, more preferably 1.5 μm or less. Furthermore, it is more preferably 0.8 μm or less. When Sa is 40 nm or less and P is 2 μm or less, there is no risk of roughening the adhesive surface when the adhesive layer is laminated and rolled into a roll.
作為於基材膜表面塗佈積層抗靜電層之方法，有將前述抗靜電劑或黏合劑樹脂等分散、溶解於溶媒的塗液，以凹版輥塗法、反向輥塗法、刀塗法、浸塗法、棒塗法、旋塗法進行塗佈方法，適用於導電性組成物的塗佈法並無特別限定。此外，可藉由膜之製造步驟中設置塗佈層之在線塗佈方式、膜製造後設置塗佈層之離線塗佈方式來設置。As a method of coating the laminated antistatic layer on the surface of the base film, there are coating solutions in which the aforementioned antistatic agent or binder resin is dispersed and dissolved in a solvent, gravure roller coating, reverse roller coating, and knife coating. , dip coating method, rod coating method, spin coating method, the coating method suitable for the conductive composition is not particularly limited. In addition, it can be provided by an in-line coating method in which the coating layer is provided during the film production step, or an off-line coating method in which the coating layer is provided after film production.
作為抗靜電層以前述方法形成抗靜電層的乾燥溫度，通常為60℃以上至150℃以下，較佳為90℃以上至140℃以下。若乾燥溫度為60℃以上，則可為短時間之處理，從提高生產性之觀點較佳。此外，含有交聯劑之情形時，交聯反應充分進行故而較佳。另一方面，若乾燥溫度為150℃以下，可保持膜之平面性故而較佳。The drying temperature for forming an antistatic layer by the above method is usually 60°C to 150°C, preferably 90°C to 140°C. If the drying temperature is 60°C or higher, the treatment can be performed in a short time, which is preferable from the viewpoint of improving productivity. In addition, it is preferable to contain a cross-linking agent because the cross-linking reaction proceeds sufficiently. On the other hand, a drying temperature of 150° C. or lower is preferable because the flatness of the film can be maintained.
本發明之積層聚酯膜可塗佈黏著劑且硬化以積層黏著層。黏著劑並無特別限定地使用，所得之積層膜用作為保護膜。積層黏著層之面可為抗靜電膜之任一側。使用僅於單面具有抗靜電層之抗靜電膜的情形時，較佳為於與抗靜電膜中積層有黏著層的面為相反面具有抗靜電層。 此外，亦可於本發明之積層聚酯膜中之抗靜電層積層陶瓷胚片、樹脂膜等。 [實施例] The laminated polyester film of the present invention can be coated with an adhesive and hardened to form an adhesive layer. The adhesive is used without particular limitation, and the obtained laminated film is used as a protective film. The surface of the laminated adhesive layer can be either side of the antistatic film. When using an antistatic film having an antistatic layer on only one side, it is preferable to have an antistatic layer on the opposite side of the antistatic film to the side on which the adhesive layer is laminated. In addition, ceramic green sheets, resin films, etc. may also be laminated on the antistatic layer in the laminated polyester film of the present invention. [Example]
為了詳細說明本發明，以下列舉實施例進行說明，但本發明自不受這些實施例所限定。再者，本發明所使用之評價方法如下所示。In order to illustrate the present invention in detail, examples are given below for description, but the present invention is not limited by these examples. Furthermore, the evaluation method used in the present invention is as follows.
[表面電阻率] 本發明之抗靜電膜表面之表面電阻率係於溫度23℃、濕度55%之條件下調濕24小時後，使用簡易型低電阻率計(日東精工分析科技(股份有限公司)製造之Loresta-AX MCP-T370)來測量表面電阻率，以下述之判定基準進行評價。當表面電阻率超過6[logΩ/□]的情形時，使用表面電阻測試儀(日本Simco(股份有限公司)製造之Work Surface Tester ST-3)來測量。 ◎：表面電阻率為2以上至4以下[logΩ/□] ○：表面電阻率超過4至7以下[logΩ/□] △：表面電阻率超過7[logΩ/□] [Surface resistivity] The surface resistivity of the antistatic film surface of the present invention was determined by using a simple low resistivity meter (Loresta-AX manufactured by Nitto Seiko Analytical Technology Co., Ltd.) after the humidity was adjusted for 24 hours at a temperature of 23°C and a humidity of 55%. MCP-T370) to measure the surface resistivity and evaluate it based on the following criteria. When the surface resistivity exceeds 6 [logΩ/□], use a surface resistance tester (Work Surface Tester ST-3 manufactured by Japan Simco Co., Ltd.) to measure. ◎: Surface resistivity is 2 or more and 4 or less [logΩ/□] ○: Surface resistivity exceeds 4 and is less than 7 [logΩ/□] △: Surface resistivity exceeds 7 [logΩ/□]
[總透光率、霧度] 本發明之膜的總透光率及霧度以JIS K 7136為基準，使用濁度計(日本電色製造之NDH7000II)測量在經140℃加熱10分鐘處理前後之膜。 [Total light transmittance, haze] The total light transmittance and haze of the film of the present invention were measured based on JIS K 7136 using a turbidimeter (NDH7000II manufactured by Nippon Denshoku) before and after the film was heated at 140° C. for 10 minutes.
[耐醇性] 測量使用浸泡在乙醇的拭鏡紙進行往返擦拭膜10次之處理前後的表面電阻值。此外，前述處理後之外觀變化依據下述判定基準進行評價。 ◎：幾乎無變化 〇：有少許變化 △：有變化 ×：抗靜電層產生了染色脫落的程度之變化 [Alcohol resistance] Measure the surface resistance value before and after wiping the film 10 times with lens wiping paper soaked in ethanol. In addition, the change in appearance after the aforementioned treatment was evaluated based on the following criteria. ◎: Almost no change 〇：Slightly changed △: There is a change ×: Changes in the degree of staining and peeling of the antistatic layer
[實施例1] 根據表2所記載之調配量得到抗靜電層塗敷 液。 [抗靜電層塗敷 液] 水 18.31質量份。 異丙醇 42.71質量份。 導電性聚合物 33.3質量份。 交聯劑A-1(日本電石工業公司製造之亞胺基型甲基化三聚氰胺樹脂，固體含量濃度為80質量%) 0.75質量份。 導電助劑 4.5質量份。 界面活性劑B-1(日信化學工業公司製造之乙炔系，表面張力為26mN／m，固體含量濃度為100質量%) 0.4質量份。 [Example 1] The antistatic layer coating liquid was obtained according to the mixing amounts described in Table 2. [Antistatic layer coating fluid] Water: 18.31 parts by mass. Isopropyl alcohol: 42.71 parts by mass. Conductive polymer: 33.3 parts by mass. Cross-linking agent A-1 (imide-based methylated melamine resin manufactured by Nippon Carbide Industry Co., Ltd., solid content concentration: 80 mass%): 0.75 parts by mass. Conductive additive: 4.5 parts by mass. Surfactant B-1 (acetylene series manufactured by Nissin Chemical Industry Co., Ltd., surface tension is 26mN/m, solid content concentration is 100 mass%): 0.4 parts by mass.
[抗靜電層之形成] 將所得之抗靜電層塗佈液以濕(wet)膜厚成為7.5μm的方式，使用凹版塗佈機塗佈於厚度為9.0μm之A4360(CosmoShine(註冊商標)、東洋紡公司製造)之單面，以熱風乾燥爐於140℃乾燥30秒並使抗靜電層塗佈液硬化，從而得到具抗靜電層之聚酯膜。 [Formation of antistatic layer] The obtained antistatic layer coating liquid was coated on one side of A4360 (CosmoShine (registered trademark), manufactured by Toyobo Co., Ltd.) with a thickness of 9.0 μm using a gravure coater so that the wet film thickness became 7.5 μm. , dry in a hot air drying oven at 140°C for 30 seconds and harden the antistatic layer coating liquid, thereby obtaining a polyester film with an antistatic layer.
[實施例2] 以如表2之組成設為界面活性劑B-2(日信化學工業公司製造之乙炔系，表面張力為32mN／m，固體含量濃度為81%)以外，以與實施例1相同的程序形成抗靜電層。 [Example 2] It was formed by the same procedure as Example 1 except that the composition in Table 2 was used as surfactant B-2 (acetylene series manufactured by Nissin Chemical Industry Co., Ltd., surface tension is 32mN/m, solid content concentration is 81%). Antistatic layer.
[實施例3] 以如表2之組成設為交聯劑A-2(日本電石工業公司製造之羥甲基型甲基化三聚氰胺樹脂，固體含量濃度為70質量%)以外，以與實施例1相同的程序形成抗靜電層。 [Example 3] It was formed by the same procedure as Example 1, except that the composition in Table 2 was used as cross-linking agent A-2 (hydroxymethyl-type methylated melamine resin manufactured by Nippon Carbide Industry Co., Ltd., solid content concentration: 70 mass%) Antistatic layer.
[實施例4] 除了依照表2的組成設為交聯劑A-3以外，以與實施例2相同的程序形成抗靜電層。 [Example 4] The antistatic layer was formed in the same procedure as in Example 2, except that the composition in Table 2 was used as cross-linking agent A-3.
[實施例5] 以如表2之組成設為交聯劑A-3(日本電石工業公司製造之全醚型甲基化三聚氰胺樹脂，固體含量濃度為70質量%)以外，以與實施例1相同的程序形成抗靜電層。 [Example 5] The resist was formed by the same procedure as in Example 1, except that the composition in Table 2 was used as cross-linking agent A-3 (fully ether type methylated melamine resin manufactured by Nippon Carbide Industry Co., Ltd., solid content concentration: 70 mass%). Electrostatic layer.
[實施例6] 除了依照表2的組成設為交聯劑A-3以外，以與實施例2相同的程序形成抗靜電層。 [Example 6] The antistatic layer was formed in the same procedure as in Example 2, except that the composition in Table 2 was used as cross-linking agent A-3.
[實施例7] 以如表2之組成設為交聯劑A-4(日本電石工業公司製造之亞胺基／羥甲基型甲基化三聚氰胺樹脂，固體含量濃度為70質量%)以外，以與實施例1相同的程序形成抗靜電層。 [Example 7] The composition in Table 2 was used as cross-linking agent A-4 (imino/methylol type methylated melamine resin manufactured by Nippon Carbide Industry Co., Ltd., solid content concentration is 70 mass%), and the same as in Example 1 The same procedure forms the antistatic layer.
[實施例8] 除了依照表2的組成設為交聯劑A-4以外，以與實施例2相同的程序形成抗靜電層。 [Example 8] The antistatic layer was formed in the same procedure as in Example 2, except that the composition in Table 2 was set to cross-linking agent A-4.
[實施例9、實施例10] 以如表2之組成設為交聯劑A-3、作為黏合劑樹脂之MD1200(東洋紡公司製造，固體含量濃度為35質量%)、界面活性劑B-1以外，以與實施例1相同的程序形成抗靜電層。 [Example 9, Example 10] The composition of Table 2 was the same as in Example 1 except for the cross-linking agent A-3, the binder resin MD1200 (manufactured by Toyobo Co., Ltd., solid content concentration: 35% by mass), and the surfactant B-1. Procedure forms an antistatic layer.
[參考例1] 以如表2之組成設為界面活性劑B-3(日信化學工業公司製造之乙炔系，表面張力為28mN／m，固體含量濃度為75質量%)以外，以與實施例1相同的程序形成抗靜電層。 [Reference example 1] The same procedure as Example 1 was used except that the composition in Table 2 was used as surfactant B-3 (acetylene series manufactured by Nissin Chemical Industry Co., Ltd., surface tension is 28 mN/m, solid content concentration is 75 mass%) Form an antistatic layer.
[參考例2] 除了依照表2的組成設為交聯劑A-2以外，以與比較例1相同的程序形成抗靜電層。 [Reference example 2] The antistatic layer was formed in the same procedure as Comparative Example 1, except that the composition in Table 2 was used as cross-linking agent A-2.
[參考例3] 以如表2之組成設為界面活性劑B-4(Dow‧Toray公司製造之矽氧烷系，表面張力為21mN／m，固體含量濃度為100質量%)以外，以與比較例2相同的程序形成抗靜電層。 [Reference example 3] The same composition as in Comparative Example 2 was used except that surfactant B-4 (siloxane system manufactured by Dow Toray Co., Ltd., surface tension: 21 mN/m, solid content concentration: 100 mass%) was used as the composition in Table 2. Procedure forms an antistatic layer.
[參考例4] 除了依照表2的組成設為交聯劑A-3以外，以與比較例1相同的程序形成抗靜電層。 [Reference Example 4] The antistatic layer was formed in the same procedure as Comparative Example 1, except that the composition in Table 2 was used as cross-linking agent A-3.
[參考例5] 除了依照表2的組成設為交聯劑A-3以外，以與比較例3相同的程序形成抗靜電層。 [Reference Example 5] The antistatic layer was formed in the same procedure as Comparative Example 3, except that the composition in Table 2 was used as cross-linking agent A-3.
[參考例6] 除了依照表2的組成設為交聯劑A-4以外，以與比較例1相同的程序形成抗靜電層。 [Reference Example 6] The antistatic layer was formed in the same procedure as Comparative Example 1, except that the composition in Table 2 was crosslinking agent A-4.
[參考例7] 除了依照表2的組成設為交聯劑A-4以外，以與比較例3相同的程序形成抗靜電層。 [Reference Example 7] The antistatic layer was formed in the same procedure as Comparative Example 3, except that the composition in Table 2 was used as cross-linking agent A-4.
[表1]
[表2A]
[表2B]
[表3A]
[表3B]
應認為本次所揭示之實施型態與實施例中的內容均為例示，而非用以限制本發明。本發明之範圍並非依據前述之實施型態，而是根據申請範圍所示，且意指包含與申請範圍均等的意義、以及範圍內中所有的變更。It should be considered that the implementation modes and contents disclosed in the examples are examples and are not intended to limit the present invention. The scope of the present invention is shown not based on the above-mentioned embodiments but on the scope of the application, and is intended to include meanings equivalent to the scope of the application and all changes within the scope.
實施例所得之本發明之積層聚酯膜，藉由提供一種積層有抗靜電層之抗靜電膜，該抗靜電層即便於聚酯膜中至少單面加熱後霧度仍低，並提供一種保護膜，係在將本抗靜電膜積層於黏著層且作為保護膜使用的情形時，仍能檢查外觀，並抑制剝離時之剝離帶電或異物附著。The laminated polyester film of the present invention obtained from the Examples provides an antistatic film laminated with an antistatic layer that has low haze even after at least one side of the polyester film is heated and provides a protective layer. Film, when this antistatic film is laminated on an adhesive layer and used as a protective film, the appearance can still be checked and peeling off charging or foreign matter adhesion during peeling can be suppressed.
再者，參考例1至參考例7之界面活性劑的HLB值超過9，因此相較於實施例所使用的試料，有加熱後之霧度值變高的傾向。 [產業可利用性] Furthermore, the HLB values of the surfactants in Reference Examples 1 to 7 exceed 9, so compared with the samples used in the examples, the haze value after heating tends to be higher. [Industrial Availability]
本發明係關於一種抗靜電膜及於抗靜電膜積層有黏著層之保護膜，尤其係關於光學構件(例如，有機EL或液晶顯示器之組成構件)等保護膜。The present invention relates to an antistatic film and a protective film having an adhesive layer laminated on the antistatic film, and particularly to protective films for optical components (for example, components of organic EL or liquid crystal displays).
Claims (7)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2022018923 | 2022-02-09 | ||
| JP2022-018923 | 2022-02-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW202344391A true TW202344391A (en) | 2023-11-16 |
Family
ID=87564039
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW112104501A TW202344391A (en) | 2022-02-09 | 2023-02-09 | antistatic film |
Country Status (2)
| Country | Link |
|---|---|
| TW (1) | TW202344391A (en) |
| WO (1) | WO2023153181A1 (en) |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5593366B2 (en) * | 2012-10-22 | 2014-09-24 | 株式会社Ｄｎｐファインケミカル | Maintenance liquid for inkjet recording |
| JP2016186072A (en) * | 2015-03-24 | 2016-10-27 | ユニチカ株式会社 | Antistatic polyester film, and production method thereof |
| JP6557108B2 (en) * | 2015-10-02 | 2019-08-07 | 日本ゼオン株式会社 | Transparent conductive film and touch panel |
| WO2018012545A1 (en) * | 2016-07-15 | 2018-01-18 | 日東電工株式会社 | Surface protection film, and optical member |
| JP2018172473A (en) * | 2017-03-31 | 2018-11-08 | リンテック株式会社 | Adhesive film for display protection |
| JP2021187116A (en) * | 2020-06-03 | 2021-12-13 | 日東電工株式会社 | Film with top coat layer, reinforcing film and image display device |
-
2023
- 2023-01-20 WO PCT/JP2023/001767 patent/WO2023153181A1/en unknown
- 2023-02-09 TW TW112104501A patent/TW202344391A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2023153181A1 (en) | 2023-08-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US7678455B2 (en) | Layered film and process for producing layered film | |
| KR101894758B1 (en) | Polyester film | |
| JP2004058648A (en) | Laminated film and manufacturing process thereof | |
| JP5264009B2 (en) | Polyester film with coating layer | |
| JP5151007B2 (en) | Polyester film for transfer foil | |
| JP5385502B2 (en) | Polyester film having antistatic coating layer | |
| JP2012183811A (en) | Antistatic film | |
| CN107405909B (en) | Mold release film | |
| JP6699816B1 (en) | Release film for manufacturing ceramic green sheets | |
| JP5625556B2 (en) | Antistatic film | |
| TW202344391A (en) | antistatic film | |
| TW202339965A (en) | antistatic film | |
| JP5404733B2 (en) | Coating film | |
| JP2016064625A (en) | Laminate film | |
| TWI842914B (en) | Release film for manufacturing ceramic green body, manufacturing method of ceramic green body, manufacturing method of ceramic capacitor | |
| WO2023282232A1 (en) | Antistatic film and protective film | |
| TW202111028A (en) | Multilayer polyester film and coating composition | |
| JP4259192B2 (en) | Circuit material spacer and manufacturing method thereof | |
| CN117126443A (en) | antistatic polyester film | |
| JP2022065639A (en) | Laminated film | |
| JP2011230516A (en) | Polyester film with antistatic coating layer | |
| JP2018052068A (en) | Laminate film and manufacturing method therefor | |
| JP2016138207A (en) | Coating film |