TW202342397A - Soft silicone rubber clay and preparation method of its molded body wherein the soft silicone rubber clay is composed of 89-99.5% by weight of organic silicone, 0.4-1.8% by weight of pigment, 0-0.6% by weight of aromatic essential oil and 0-9.1% by weight of additive - Google Patents

Soft silicone rubber clay and preparation method of its molded body wherein the soft silicone rubber clay is composed of 89-99.5% by weight of organic silicone, 0.4-1.8% by weight of pigment, 0-0.6% by weight of aromatic essential oil and 0-9.1% by weight of additive Download PDF

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TW202342397A
TW202342397A TW111116097A TW111116097A TW202342397A TW 202342397 A TW202342397 A TW 202342397A TW 111116097 A TW111116097 A TW 111116097A TW 111116097 A TW111116097 A TW 111116097A TW 202342397 A TW202342397 A TW 202342397A
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silicone rubber
essential oil
weight
clay
soft silicone
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范坤炎
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科頓聚合物股份有限公司
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Abstract

A soft silicone rubber clay and a preparation method of its molded body are provided. The soft silicone rubber clay is composed of 89-99.5% by weight of organic silicone, 0.4-1.8% by weight of pigment, 0-0.6% by weight of aromatic essential oil and 0-9.1% by weight of additive, wherein the organic silicone is selected from at least one of vinyl silicone rubber raw rubber and methyl silicone rubber raw rubber, and the additive is selected from at least one of hydrated silica, antibacterial agent, anti-slump agent and silicone oil. The formula of this soft silicone rubber clay is simple, safe, and odorless. Its texture is soft, elastic, not easy to dry hard, and can be repeatedly kneaded. It is especially suitable for children for clay kneading and playing. In addition, it can also be used for dexterity and fine training of the hands or hand muscle strengthening.

Description

柔軟矽橡膠黏土及其成型體的製作方法Soft silicone rubber clay and method for producing the same

本發明係有關一種矽橡膠黏土材料,特別是指一種柔軟矽橡膠黏土及其成型體的製作方法。The invention relates to a silicone rubber clay material, and in particular to a method of making soft silicone rubber clay and its molded body.

黏土因為材料的可塑性及價格便宜、容易取得的優點,是極受歡迎的創作媒材之一。市面上的黏土種類眾多,常見有超輕土、樹脂黏土、紙黏土、油土及兒童專用的安全黏土等等,而每一種黏土具有不同的特性,呈現出的效果也不盡相同,選擇上可根據使用需求及價格差異而定。Clay is one of the most popular creative media due to its plasticity, cheap price and easy availability. There are many types of clay on the market, including ultra-light clay, resin clay, paper clay, oil clay, and child-specific safety clay, etc. Each type of clay has different characteristics and exhibits different effects. The choice is important. It can be determined according to usage requirements and price differences.

其中,超輕土的質感輕柔,延展性非常好,色彩也很鮮豔,其乾燥後不像樹脂黏土般堅硬,因為它的密度低且具有彈性,就算掉在地上也不易摔壞;但超輕土在使用上很容易沾手,製作動作要快,否則容易乾燥,而且一旦沾黏在其他物品或衣服上就很難清理,不適合重複捏玩使用。樹脂黏土的顏色相當多樣,韌性強,可塑性高且材質細緻,作品風乾後會呈透明感。樹脂黏土容易保存,可長期收藏也不會損壞,其延展性好,乾了之後質地硬,又不會像輕質土那樣容易黏手,可是樹脂黏土的土質容易乾燥,乾燥後則很難恢復軟度,其成品較重且容易龜裂,而且樹脂黏土主要是由澱粉和樹脂製成,易被蟲啃蝕,放在太潮濕的地方可能會發臭、發霉。紙黏土是由紙漿、石粉、樹脂等素材組成,由於紙黏土的纖維較粗,容易塑型,半乾燥後只需用水搓揉即可恢復軟度;然而,紙黏土的土質硬,易黏手,乾燥後容易有龜裂現象,也較難保存。另外,油土不會乾,但較為油膩,材質硬, 不容易塑型。而強調天然無毒的兒童用安全黏土通常成份包含麵粉、水及食用色素,其缺點為容易乾掉,塑型力差、容易散開,同時也較為沾手或沾黏其他物品,故不易清潔,善後比較麻煩,而且其保存期限短,容易有臭味。Among them, ultra-light clay has a soft texture, very good ductility, and bright colors. After drying, it is not as hard as resin clay because it has low density and elasticity, so it is not easy to break even if it falls on the ground; but it is ultra-light Soil is easy to stick to your hands when using it, so you have to make it quickly, otherwise it will dry easily, and once it sticks to other items or clothes, it will be difficult to clean, so it is not suitable for repeated use. Resin clay comes in a variety of colors, has strong toughness, high plasticity and fine texture. The work will become transparent after drying. Resin clay is easy to preserve and can be stored for a long time without being damaged. It has good ductility and has a hard texture after drying. It is not as sticky as light soil. However, the soil of resin clay dries easily and is difficult to recover after drying. Due to its softness, the finished product is heavy and easy to crack, and resin clay is mainly made of starch and resin, which is easily gnawed by insects and may become smelly and moldy if placed in a place that is too humid. Paper clay is composed of paper pulp, stone powder, resin and other materials. Because the fiber of paper clay is thicker, it is easy to shape. After semi-drying, it can be restored to softness by simply kneading it with water. However, the soil of paper clay is hard and easy to stick to your hands. , prone to cracking after drying, and difficult to preserve. In addition, oily soil will not dry out, but it is greasy, the material is hard, and it is not easy to shape. Safety clay for children, which emphasizes being natural and non-toxic, usually contains flour, water and food coloring. Its disadvantages are that it dries easily, has poor shaping power and spreads easily. It is also more likely to stick to hands or other objects, so it is difficult to clean and troublesome to deal with afterward. , and its shelf life is short and it is easy to smell.

故,如何對於黏土材料及其製作方法進行改良,以解決上述習知技術的不足,即為從事此行業相關業者所亟欲研發的課題。Therefore, how to improve clay materials and their production methods to solve the above-mentioned shortcomings of the conventional technology is an urgent research and development topic for those engaged in this industry.

有鑑於此,本發明的主要目的在於提供一種柔軟矽橡膠黏土及其成型體的製作方法,藉由選用乙烯基矽橡膠生膠或/及甲基矽橡膠生膠的有機矽膠作為主要原料,其配方簡單、安全,可達到操作不沾手、不掉屑、不乾硬,可以重複捏玩,適合幼童用來進行黏土捏塑玩耍,另外,也可用來進行手部的靈巧及精細訓練或手肌強健。In view of this, the main purpose of the present invention is to provide a method for making soft silicone rubber clay and its molded body by selecting organic silicone rubber of vinyl silicone rubber raw rubber or/and methyl silicone rubber raw rubber as the main raw material. The formula is simple and safe, and it can be operated without sticking to your hands, falling off chips, or drying out. It can be kneaded and played with repeatedly. It is suitable for young children to use for clay kneading and modeling. In addition, it can also be used for hand dexterity and fine training or hand training. Strong muscles.

本發明的另一目的在於提供一種柔軟矽橡膠黏土及其成型體的製作方法,此柔軟矽橡膠黏土經充分的揉捏後再製作出的成型體,其亮澤度會大幅提高,顏色鮮艷漂亮。Another object of the present invention is to provide a method for making soft silicone rubber clay and its molded body. The molded body produced after the soft silicone rubber clay is fully kneaded will have a significantly improved gloss and bright and beautiful color. .

為達上述之目的,本發明提供一種柔軟矽橡膠黏土,其由下列成份所組成: (a) 89-99.5重量%的有機矽膠,此有機矽膠選自乙烯基矽橡膠生膠和甲基矽橡膠生膠中的至少一種; (b) 0.4-1.8重量%的顏料; (c) 0-0.6重量%的芳香精油;及 (d) 0-9.1重量%的添加劑,此添加劑選自水製法二氧化矽、抗菌劑、抗坍劑和矽油中的至少一種; 其中,有機矽膠、顏料、芳香精油與添加劑混合後形成矽橡膠黏土組成物並用來於常溫下混煉為柔軟矽橡膠黏土。 In order to achieve the above purpose, the present invention provides a soft silicone rubber clay, which is composed of the following ingredients: (a) 89-99.5% by weight of organic silicone rubber, which is selected from at least one of vinyl silicone rubber raw rubber and methyl silicone rubber raw rubber; (b) 0.4-1.8% by weight of pigment; (c) 0-0.6% by weight of aromatic essential oils; and (d) 0-9.1% by weight of additives, this additive is selected from at least one of aqueous silica, antibacterial agents, anti-slump agents and silicone oil; Among them, organic silicone, pigments, aromatic essential oils and additives are mixed to form a silicone rubber clay composition, which is then mixed into soft silicone rubber clay at room temperature.

本發明也提供一種柔軟矽橡膠黏土成型體的製作方法,其包含下列步驟: (1)            將89-99.5重量%的有機矽膠、0.4-1.8重量%的顏料、0-0.6重量%的芳香精油與0-9.1重量%的添加劑混合後形成矽橡膠黏土組成物 ,其中有機矽膠選自乙烯基矽橡膠生膠和甲基矽橡膠生膠中的至少一種,添加劑選自水製法二氧化矽、抗菌劑、抗坍劑和矽油中的至少一種; (2)            將矽橡膠黏土組成物於常溫下以滾輪混煉後製得柔軟矽橡膠黏土;及 (3)            將柔軟矽橡膠黏土進行揉捏3-5分鐘後,再將柔軟矽橡膠黏土捏塑為預定形狀的柔軟矽橡膠黏土成型體。 The invention also provides a method for making a soft silicone rubber clay molded body, which includes the following steps: (1) Mix 89-99.5% by weight of organic silicone, 0.4-1.8% by weight of pigment, 0-0.6% by weight of aromatic essential oil and 0-9.1% by weight of additives to form a silicone rubber clay composition, in which the organic silicone is selected At least one of vinyl silicone rubber raw rubber and methyl silicone rubber raw rubber, and the additive is selected from at least one of aqueous silicon dioxide, antibacterial agents, anti-slump agents and silicone oil; (2) The silicone rubber clay composition is mixed with a roller at room temperature to obtain soft silicone rubber clay; and (3) After kneading the soft silicone rubber clay for 3-5 minutes, knead the soft silicone rubber clay into a soft silicone rubber clay molded body of a predetermined shape.

根據本發明之實施例,前述乙烯基矽橡膠生膠的分子量為65萬且乙烯基含量為0.16莫爾%的生膠。According to an embodiment of the present invention, the molecular weight of the aforementioned vinyl silicone rubber raw rubber is 650,000 and the vinyl content is 0.16 mol%.

根據本發明之實施例,前述甲基矽橡膠生膠的分子量為74-93萬的甲基生膠。According to an embodiment of the present invention, the molecular weight of the aforementioned methyl silicone rubber raw rubber is 740,000-930,000 methyl raw rubber.

根據本發明之實施例,前述抗菌劑為奈米銀抗菌劑。According to an embodiment of the present invention, the aforementioned antibacterial agent is a nanosilver antibacterial agent.

根據本發明之實施例,前述抗坍劑為蓖麻油衍生物。According to an embodiment of the present invention, the anti-slump agent is a castor oil derivative.

根據本發明之實施例,前述顏料包括無機顏料或有機顏料,該無機顏料為鎘紅、鎘檸檬黃、橘鎘黃、二氧化鈦、碳黑、黑色氧化鐵或黑色錯合無機顏料,該有機顏料為苯胺黑、苝黑、蒽醌黑、聯苯胺類黃色顏料、酞青藍或酞青綠。According to an embodiment of the present invention, the aforementioned pigments include inorganic pigments or organic pigments. The inorganic pigments are cadmium red, cadmium lemon yellow, cadmium orange yellow, titanium dioxide, carbon black, black iron oxide or black complex inorganic pigments. The organic pigment is Aniline black, perylene black, anthraquinone black, benzidine yellow pigment, phthalocyanine blue or phthalocyanine green.

根據本發明之實施例,前述芳香精油為香茅精油、樟腦精油、迷迭香精油、薰衣草精油、檜木精油、玫瑰精油、茉莉花精油、薄荷精油、茶樹精油、柑橘精油、檸檬草精油、鼠尾草精油、尤加利精油、葡萄柚精油、肉桂精油、檸檬草精油或是由上述物質所組成的混合物。According to an embodiment of the present invention, the aforementioned aromatic essential oils are citronella essential oil, camphor essential oil, rosemary essential oil, lavender essential oil, cypress essential oil, rose essential oil, jasmine essential oil, peppermint essential oil, tea tree essential oil, citrus essential oil, lemongrass essential oil, sage essential oil Grass essential oil, eucalyptus essential oil, grapefruit essential oil, cinnamon essential oil, lemongrass essential oil or a mixture of the above substances.

與先前技術相比,本發明具有以下優勢: (1)   本發明提供的柔軟矽橡膠黏土的配方使用簡單、安全的原料,產品無臭、無味、無汙染性,對人體健康或環境都不會造成任何危害。 (2)   本發明提供的柔軟矽橡膠黏土不乾硬、不掉屑、不沾黏,產品壽命長,且可回收再利用。 (3)   本發明提供的柔軟矽橡膠黏土可以方便使用者重複捏塑,就算接觸空氣其硬度也不會產生變化,使用壽命長,有利於成人或孩童訓練手部精細動作或進行手肌訓練。 (4)   本發明提供的柔軟矽橡膠黏土的組成和製作方法相當簡易、安全,能夠有效推廣至大眾成為理想的黏土材料。 Compared with prior art, the present invention has the following advantages: (1) The formula of soft silicone rubber clay provided by the present invention uses simple and safe raw materials. The product is odorless, tasteless and non-polluting, and will not cause any harm to human health or the environment. (2) The soft silicone rubber clay provided by the present invention does not dry out, flake or stick, has a long product life, and can be recycled and reused. (3) The soft silicone rubber clay provided by the present invention can be easily kneaded and molded by the user repeatedly. Its hardness will not change even if it is exposed to air. It has a long service life and is beneficial to adults or children in training fine hand movements or hand muscle training. (4) The composition and production method of the soft silicone rubber clay provided by the present invention are quite simple and safe, and can be effectively promoted to the public as an ideal clay material.

底下藉由具體實施例詳加說明,當更容易瞭解本發明之目的、技術內容、特點及其所達成之功效。It will be easier to understand the purpose, technical content, characteristics and achieved effects of the present invention through detailed description of specific embodiments below.

下面結合具體實施例對本發明進行詳細說明,將有助於本發明所屬技術領域中具有通常知識者進一步理解本發明。The present invention will be described in detail below with reference to specific embodiments, which will help those with ordinary knowledge in the technical field to which the present invention belongs to further understand the present invention.

本發明中的實施例所採用的技術方案均僅作為示例,除非特別說明,不應用以限制本發明。在不衝突的情況下,本發明中的實施例及實施例中的特徵可以相互任意組合。除非特別說明,本發明使用的所有技術和科學術語具有與本發明所屬領域中具有通常知識者通常理解的相同含義。除非特別說明,本發明所列出的數值範圍值在包括範圍的端點,和該範圍之內的所有整數和分數。The technical solutions adopted in the embodiments of the present invention are only examples and should not be used to limit the present invention unless otherwise specified. Without conflict, the embodiments and features in the embodiments of the present invention may be combined with each other arbitrarily. Unless otherwise specified, all technical and scientific terms used herein have the same meanings commonly understood by one of ordinary skill in the art to which this invention belongs. Unless otherwise stated, numerical range values set forth herein include the endpoints of the range, and all integers and fractions within the range.

請參照第1圖,為本發明所提供的柔軟矽橡膠黏土的組成結構示意圖,圖中各成份的重量在柔軟矽橡膠黏土總重量中的比例是以百分比來簡單表示,且各成份所佔的面積比例並非實際比例。本發明所提供的柔軟矽橡膠黏土是由以下成份所組成:89-99.5重量%的有機矽膠,此有機矽膠選自乙烯基矽橡膠生膠和甲基矽橡膠生膠中的至少一種;0.4-1.8重量%的顏料;0-0.6重量%的芳香精油;及0-9.1重量%的添加劑,此添加劑選自水製法二氧化矽、抗菌劑、抗坍劑和矽油中的至少一種。Please refer to Figure 1, which is a schematic diagram of the composition and structure of the soft silicone rubber clay provided by the present invention. The proportion of the weight of each component in the figure to the total weight of the soft silicone rubber clay is simply expressed as a percentage, and the proportion of each component Area ratios are not actual ratios. The soft silicone rubber clay provided by the invention is composed of the following ingredients: 89-99.5% by weight of organic silicone, and the organic silicone is selected from at least one of vinyl silicone rubber and methyl silicone rubber; 0.4- 1.8% by weight of pigments; 0-0.6% by weight of aromatic essential oils; and 0-9.1% by weight of additives. The additives are selected from at least one of aqueous silicon dioxide, antibacterial agents, anti-collapse agents and silicone oil.

其中,適用於本發明的乙烯基矽橡膠生膠的分子量為65萬且乙烯基含量為0.16莫爾%的生膠。適用於本發明的甲基矽橡膠生膠的分子量為74-93萬的甲基生膠。適用於本發明的抗菌劑可以包括但不限於:奈米銀抗菌劑。適用於本發明的抗坍劑可以包括但不限於:蓖麻油衍生物,適用於本發明的顏料可為無機顏料或有機顏料,其中無機顏料可以包括但不限於:鎘紅、鎘檸檬黃、橘鎘黃、二氧化鈦、碳黑、黑色氧化鐵或黑色錯合無機顏料,有機顏料可以包括但不限於:苯胺黑、苝黑、蒽醌黑、聯苯胺類黃色顏料、酞青藍或酞青綠,芳香精油可以包括但不限於:香茅精油、樟腦精油、迷迭香精油、薰衣草精油、檜木精油、玫瑰精油、茉莉花精油、薄荷精油、茶樹精油、柑橘精油、檸檬草精油、鼠尾草精油、尤加利精油、葡萄柚精油、肉桂精油、檸檬草精油或是由上述物質所組成的混合物。上述所列舉之材料皆僅作為示例,實務上不限於此。Among them, the vinyl silicone rubber raw rubber suitable for the present invention has a molecular weight of 650,000 and a vinyl content of 0.16 mol%. The methyl silicone rubber raw rubber suitable for the present invention has a molecular weight of 740,000-930,000. Antibacterial agents suitable for the present invention may include, but are not limited to: nanosilver antibacterial agents. Anti-slump agents suitable for the present invention may include, but are not limited to: castor oil derivatives. Pigments suitable for the present invention may be inorganic pigments or organic pigments. Inorganic pigments may include, but are not limited to: cadmium red, cadmium lemon yellow, orange. Cadmium yellow, titanium dioxide, carbon black, black iron oxide or black complex inorganic pigments, organic pigments may include but are not limited to: aniline black, perylene black, anthraquinone black, benzidine yellow pigments, phthalocyanine blue or phthalocyanine green, aromatic Essential oils may include, but are not limited to: citronella essential oil, camphor essential oil, rosemary essential oil, lavender essential oil, cypress essential oil, rose essential oil, jasmine essential oil, peppermint essential oil, tea tree essential oil, citrus essential oil, lemongrass essential oil, sage essential oil, especially Galli essential oil, grapefruit essential oil, cinnamon essential oil, lemongrass essential oil or a mixture of the above substances. The materials listed above are only examples and are not limited in practice.

另外要說明的是,本發明所使用的芳香精油以及水製法二氧化矽、抗菌劑、抗坍劑和矽油等添加劑的含量可以為0重量%,這表示在本發明的柔軟矽橡膠黏土的配方中也可以不包含芳香精油以及水製法二氧化矽、、抗菌劑、抗坍劑和矽油等添加劑。In addition, it should be noted that the content of the aromatic essential oils and additives such as aqueous silica, antibacterial agents, anti-slump agents and silicone oil used in the present invention can be 0% by weight, which means that in the formula of the soft silicone rubber clay of the present invention It also does not need to contain aromatic essential oils and additives such as aqueous silicon dioxide, antibacterial agents, anti-collapse agents and silicone oil.

上述的有機矽膠、顏料與可選的芳香精油與添加劑混合後形成矽橡膠黏土組成物,此矽橡膠黏土組成物於常溫下混煉後即可形成柔軟矽橡膠黏土,而柔軟矽橡膠黏土具有不容易乾硬之特性,讓使用者可以最大自由度的創意發想重複捏塑,更特別適合用來進行手部的訓練或復建。並且,此柔軟矽橡膠黏土無臭無味,也不會發生掉屑、沾黏等情況,非常容易清理及方便善後。另外,此柔軟矽橡膠黏土經充分揉捏後,再製作成具有預定形狀的成型體,則其亮澤度會大幅提升,顏色鮮艷亮麗。The above-mentioned organic silicone, pigments and optional aromatic essential oils and additives are mixed to form a silicone rubber clay composition. This silicone rubber clay composition can be formed into soft silicone rubber clay after being mixed at room temperature, and the soft silicone rubber clay has unique properties. The characteristics of easy drying and hardening allow users to have maximum freedom of creative ideas and repeated kneading. It is especially suitable for hand training or reconstruction. Moreover, this soft silicone rubber clay is odorless and tasteless, and will not chip or stick, making it very easy to clean and handle aftercare. In addition, after this soft silicone rubber clay is fully kneaded and then made into a molded body with a predetermined shape, its brightness will be greatly improved and its color will be bright and bright.

以下請參照第2圖,詳細說明本發明所提供的柔軟矽橡膠黏土成型體的製作方法之流程步驟。Please refer to Figure 2 below for a detailed description of the process steps of the manufacturing method of the soft silicone rubber clay molded body provided by the present invention.

首先,如步驟S100,如前述第1圖之組成比例,將89-99.5重量%的有機矽膠、0.4-1.8重量%的顏料、0-0.6重量%的芳香精油與0-9.1重量%的添加劑混合後形成矽橡膠黏土組成物 ,有機矽膠選自乙烯基矽橡膠生膠和甲基矽橡膠生膠中的至少一種,添加劑選自水製法二氧化矽、抗菌劑、抗坍劑和矽油中的至少一種。First, as in step S100, mix 89-99.5% by weight of organic silicone, 0.4-1.8% by weight of pigment, 0-0.6% by weight of aromatic essential oil and 0-9.1% by weight of additives as shown in the aforementioned Figure 1. A silicone rubber clay composition is then formed. The organic silicone rubber is selected from at least one of vinyl silicone rubber raw rubber and methyl silicone rubber raw rubber. The additive is selected from at least one of water-based silica, antibacterial agent, anti-slump agent and silicone oil. One kind.

然後,如步驟S110,將矽橡膠黏土組成物於常溫下以滾輪混煉,即製得柔軟矽橡膠黏土。Then, in step S110, the silicone rubber clay composition is kneaded with a roller at normal temperature to obtain soft silicone rubber clay.

此柔軟矽橡膠黏土具有彈性,且不容易乾燥,不易沾手,使用者可以隨心所欲的用它來捏塑成任意形狀,亦可利用模具製成單一形狀的作品。如步驟S120,將柔軟矽橡膠黏土先行揉捏3-5分鐘後,再將柔軟矽橡膠黏土捏塑為預定形狀的柔軟矽橡膠黏土成型體,可使柔軟矽橡膠黏土成型體的表面具有更高的亮澤度,顏色更鮮艷亮麗。This soft silicone rubber clay is elastic, does not dry out easily, and does not stick to your hands. Users can use it to mold it into any shape as they wish, or use molds to create single-shaped works. In step S120, the soft silicone rubber clay is kneaded for 3-5 minutes, and then the soft silicone rubber clay is kneaded into a soft silicone rubber clay molded body of a predetermined shape, which can make the surface of the soft silicone rubber clay molded body have a higher The glossiness and the color are brighter and brighter.

以下結合具體實施例對本發明作進一步詳細說明,但不應將其理解為對本發明保護範圍的限制。本發明實施例1〜3所提供之矽橡膠黏土組成物的具體組成列示於表一,表格中的單位為重量份。The present invention will be further described in detail below with reference to specific examples, which should not be construed as limiting the scope of the present invention. The specific compositions of the silicone rubber clay compositions provided in Embodiments 1 to 3 of the present invention are listed in Table 1, and the units in the table are parts by weight.

表一 矽橡膠黏土組成物的組成成份 實施例1 實施例2 實施例3 乙烯基矽橡膠生膠 100 100 100 甲基矽橡膠生膠 0 0 0 顏料 1 1 1 芳香精油 0 0 1 水製法二氧化矽 0 0 0 抗菌劑 0 0 0 抗坍劑 0 10 10 矽油 0 0 0 總重 101 111 112 Table I The composition of silicone rubber clay composition Example 1 Example 2 Example 3 Vinyl silicone rubber raw rubber 100 100 100 Methyl silicone rubber raw rubber 0 0 0 Pigments 1 1 1 aromatic essential oils 0 0 1 Aqueous silicon dioxide 0 0 0 antibacterial agent 0 0 0 Anti-collapse agent 0 10 10 Silicone oil 0 0 0 total weight 101 111 112

在表一中,實施例1的顏料為二氧化鈦,實施例2的顏料為竹炭,實施例3的顏料為竹炭,並使用綠茶精油,且實施例1-3所使用的乙烯基矽橡膠生膠皆為分子量為65萬且乙烯基含量為0.16莫爾%的生膠,其相對黏度為2.63,可塑度為300,抗坍劑皆為蓖麻油衍生物。由上述可知,實施例1的矽橡膠黏土組成物混煉後可獲得白色的柔軟矽橡膠黏土;實施例2的矽橡膠黏土組成物混煉後可獲得黑色的柔軟矽橡膠黏土;實施例3的矽橡膠黏土組成物混煉後可獲得黑色且具有綠茶香味的柔軟矽橡膠黏土。柔軟矽橡膠黏土的材質非常柔軟且具有彈性,使用者可用來捏製成為具有預定形狀的成型體,而在捏製成型之前,若將柔軟矽橡膠黏土先充分揉捏後再進行製作,則成型體的亮澤度會大幅提升,顏色更鮮艷亮麗。In Table 1, the pigment of Example 1 is titanium dioxide, the pigment of Example 2 is bamboo charcoal, the pigment of Example 3 is bamboo charcoal, and green tea essential oil is used, and the vinyl silicone rubber raw rubber used in Examples 1-3 is It is a raw rubber with a molecular weight of 650,000 and a vinyl content of 0.16 mol%. Its relative viscosity is 2.63 and its plasticity is 300. The anti-slump agents are all castor oil derivatives. It can be seen from the above that after kneading the silicone rubber clay composition of Example 1, white soft silicone rubber clay can be obtained; after kneading the silicone rubber clay composition of Example 2, black soft silicone rubber clay can be obtained; After the silicone rubber clay composition is kneaded, soft silicone rubber clay that is black and has a green tea aroma can be obtained. The material of soft silicone rubber clay is very soft and elastic, and the user can knead it into a molded body with a predetermined shape. Before kneading, if the soft silicone rubber clay is fully kneaded before making, The gloss of the molded body will be greatly improved, and the color will be brighter and brighter.

另一方面,上述實施例1-3的多種矽橡膠黏土組成物可以任意組合方式以及任意比例來混合,也就是說,實施例1的矽橡膠黏土組成物可以分別和實施例2、3的矽橡膠黏土組成物來混合,實施例2的矽橡膠黏土組成物可以分別和實施例1、3的矽橡膠黏土組成物來混合,實施例3的矽橡膠黏土組成物可以分別和實施例1、2的矽橡膠黏土組成物來混合;藉此,使由一種或多種矽橡膠黏土組成物混練得到的柔軟矽橡膠黏土具有各種顏色和香味或是其他特性。On the other hand, the various silicone rubber clay compositions of the above-mentioned embodiments 1-3 can be mixed in any combination and in any proportion. That is to say, the silicone rubber clay composition of embodiment 1 can be mixed with the silicone rubber clay compositions of embodiments 2 and 3 respectively. The silicone rubber clay composition of Example 2 can be mixed with the silicone rubber clay compositions of Examples 1 and 3 respectively. The silicone rubber clay composition of Example 3 can be mixed with the silicone rubber clay compositions of Examples 1 and 2 respectively. The silicone rubber clay composition is mixed; thereby, the soft silicone rubber clay obtained by kneading one or more silicone rubber clay compositions has various colors, fragrances or other characteristics.

根據本發明所提供的柔軟矽橡膠黏土,藉由選用乙烯基矽橡膠生膠或/及甲基矽橡膠生膠的有機矽膠作為主要原料,並添加顏料來增添顏色,另可於實務上搭配芳香精油、水製法二氧化矽、抗菌劑、抗坍劑和矽油,使黏土的成份除了無臭、無味、無汙染性之外,更是非常環保安全,對人體健康或環境都不會造成任何危害,而此黏土最後還可回收再利用,可大幅減少廢棄物的產生,實現資源永續的目標。According to the soft silicone rubber clay provided by the present invention, organic silicone rubber of vinyl silicone rubber raw rubber or/and methyl silicone rubber raw rubber is selected as the main raw material, and pigments are added to add color. In addition, it can be combined with fragrance in practice. Essential oils, water-based silica, antibacterial agents, anti-slump agents and silicone oil make the clay ingredients not only odorless, tasteless and non-polluting, but also very environmentally friendly and safe, and will not cause any harm to human health or the environment. In the end, this clay can be recycled and reused, which can greatly reduce the generation of waste and achieve the goal of resource sustainability.

有別於習知黏土材料的缺點,比如容易乾燥、沾黏,而不利重複塑型,或是容易發臭、發霉,乾燥後容易龜裂,而難以保存,不易清潔及善後等等;本發明所提供的柔軟矽橡膠黏土的優勢在於具有不容易乾硬之特性,可以方便使用者重複捏塑,就算接觸空氣其硬度也不會產生變化,使用壽命長,有利於成人或孩童訓練手部肌肉或進行手部復健。同時,此柔軟矽橡膠黏土不僅不會發出臭味,且使用上不易掉屑、不易沾手,而製作好的成品的使用壽命長達三年以上可重複使用,且其材質不溶於水,不會沾黏衣物或地板,也不會在浴缸或嬉水池中不會留下任何殘留物、不會污染皮膚、頭髮或是浴室,相當容易清潔,也沒有惱人的善後問題。It is different from the shortcomings of conventional clay materials, such as being easy to dry and sticky, which is not conducive to repeated shaping, or being easy to smell and mold, easy to crack after drying, difficult to preserve, difficult to clean and deal with, etc.; the present invention The advantage of the soft silicone rubber clay provided is that it does not dry out easily and can be easily kneaded and molded repeatedly. Its hardness will not change even if it is exposed to air. It has a long service life and is beneficial for adults or children to train their hand muscles. or hand rehabilitation. At the same time, this soft silicone rubber clay not only does not emit odor, but is not easy to chip or stick to your hands during use. The finished product has a service life of more than three years and can be reused, and its material is insoluble in water and will not stick to your hands. It sticks to clothes or floors, doesn't leave any residue in the bathtub or paddling pool, won't stain skin, hair or the bathroom, is easy to clean, and has no annoying aftermath problems.

總的來說,本發明的柔軟矽橡膠黏土及其成型體的製作方法,可以相當程度地提昇矽橡膠黏土的使用特性,方便使用者可以重複捏塑,不會有容易乾燥、掉屑及沾黏等問題,同時也易於清理、善後及保存,其組成及製作方法皆相當簡易、安全,能夠有效地推廣至大眾成為理想的黏土材料。In general, the soft silicone rubber clay and the manufacturing method of the molded body of the present invention can significantly improve the use characteristics of the silicone rubber clay, making it convenient for the user to repeatedly knead and mold without easy drying, chipping and staining. It is also easy to clean, deal with and preserve without problems such as sticking. Its composition and production method are quite simple and safe, and it can be effectively promoted to the public as an ideal clay material.

唯以上所述者,僅為本發明之較佳實施例而已,並非用來限定本發明實施之範圍。故即凡依本發明申請範圍所述之特徵及精神所為之均等變化或修飾,均應包括於本發明之申請專利範圍內。The above descriptions are only preferred embodiments of the present invention and are not intended to limit the scope of the present invention. Therefore, all equivalent changes or modifications made in accordance with the characteristics and spirit described in the scope of the present invention shall be included in the patent scope of the present invention.

without

第1圖為本發明所提供的柔軟矽橡膠黏土的組成結構示意圖。 第2圖為本發明所提供的柔軟矽橡膠黏土成型體的製作方法的流程圖。 Figure 1 is a schematic diagram of the composition and structure of the soft silicone rubber clay provided by the present invention. Figure 2 is a flow chart of the manufacturing method of the soft silicone rubber clay molded body provided by the present invention.

Claims (14)

一種柔軟矽橡膠黏土,係由下列成份所組成: (a)         89-99.5重量%的有機矽膠,該有機矽膠選自乙烯基矽橡膠生膠和甲基矽橡膠生膠中的至少一種; (b)        0.4-1.8重量%的顏料; (c)         0-0.6重量%的芳香精油;及 (d)        0-9.1重量%的添加劑,該添加劑選自水製法二氧化矽、抗菌劑、抗坍劑和矽油中的至少一種; 其中,該有機矽膠、該顏料、該芳香精油與該添加劑係混合後形成一矽橡膠黏土組成物並用來於常溫下混煉為該柔軟矽橡膠黏土。 A soft silicone rubber clay composed of the following ingredients: (a) 89-99.5% by weight of organic silicone, the organic silicone being selected from at least one of vinyl silicone rubber raw rubber and methyl silicone rubber raw rubber; (b) 0.4-1.8% by weight of pigment; (c) 0-0.6% by weight of aromatic essential oils; and (d) 0-9.1% by weight additive, which additive is selected from at least one selected from the group consisting of water-based silica, antibacterial agents, anti-slump agents and silicone oil; Wherein, the organic silicone, the pigment, the aromatic essential oil and the additive are mixed to form a silicone rubber clay composition and used to mix the soft silicone rubber clay at normal temperature. 如請求項1所述之柔軟矽橡膠黏土,其中該乙烯基矽橡膠生膠的分子量為65萬且乙烯基含量為0.16莫爾%的生膠。The soft silicone rubber clay as described in claim 1, wherein the vinyl silicone rubber raw rubber has a molecular weight of 650,000 and a vinyl content of 0.16 mol%. 如請求項1所述之柔軟矽橡膠黏土,其中該甲基矽橡膠生膠的分子量為74-93萬的甲基生膠。The soft silicone rubber clay described in claim 1, wherein the methyl silicone rubber raw rubber has a molecular weight of 740,000-930,000 methyl raw rubber. 如請求項1所述之柔軟矽橡膠黏土,其中該抗菌劑為奈米銀抗菌劑。The soft silicone rubber clay according to claim 1, wherein the antibacterial agent is a nanosilver antibacterial agent. 如請求項1所述之柔軟矽橡膠黏土,其中該抗坍劑為蓖麻油衍生物。The soft silicone rubber clay of claim 1, wherein the anti-slump agent is a castor oil derivative. 如請求項1所述之柔軟矽橡膠黏土,其中該顏料包括無機顏料或有機顏料,該無機顏料為鎘紅、鎘檸檬黃、橘鎘黃、二氧化鈦、碳黑、黑色氧化鐵或黑色錯合無機顏料,該有機顏料為苯胺黑、苝黑、蒽醌黑、聯苯胺類黃色顏料、酞青藍或酞青綠。The soft silicone rubber clay as described in claim 1, wherein the pigment includes an inorganic pigment or an organic pigment, and the inorganic pigment is cadmium red, cadmium lemon yellow, orange cadmium yellow, titanium dioxide, carbon black, black iron oxide or black complex inorganic Pigment, the organic pigment is aniline black, perylene black, anthraquinone black, benzidine yellow pigment, phthalocyanine blue or phthalocyanine green. 如請求項1所述之柔軟矽橡膠黏土,其中該芳香精油為香茅精油、樟腦精油、迷迭香精油、薰衣草精油、檜木精油、玫瑰精油、茉莉花精油、薄荷精油、茶樹精油、柑橘精油、檸檬草精油、鼠尾草精油、尤加利精油、葡萄柚精油、肉桂精油、檸檬草精油或是由上述物質所組成的混合物。The soft silicone rubber clay as described in claim 1, wherein the aromatic essential oils are citronella essential oil, camphor essential oil, rosemary essential oil, lavender essential oil, cypress essential oil, rose essential oil, jasmine essential oil, peppermint essential oil, tea tree essential oil, citrus essential oil, Lemongrass essential oil, sage essential oil, eucalyptus essential oil, grapefruit essential oil, cinnamon essential oil, lemongrass essential oil or a mixture of the above substances. 一種柔軟矽橡膠黏土成型體的製作方法,包含下列步驟: (1)   將89-99.5重量%的有機矽膠、0.4-1.8重量%的顏料、0-0.6重量%的芳香精油與0-9.1重量%的添加劑混合後形成一矽橡膠黏土組成物 ,該有機矽膠選自乙烯基矽橡膠生膠和甲基矽橡膠生膠中的至少一種,該添加劑選自水製法二氧化矽、抗菌劑、抗坍劑和矽油中的至少一種; (2)   將該矽橡膠黏土組成物於常溫下以滾輪混煉後製得一柔軟矽橡膠黏土;及 (3)   將該柔軟矽橡膠黏土充分揉捏後,將該柔軟矽橡膠黏土捏塑為預定形狀之一柔軟矽橡膠黏土成型體。 A method for making a soft silicone rubber clay molded body, including the following steps: (1) Mix 89-99.5% by weight of organic silicone, 0.4-1.8% by weight of pigments, 0-0.6% by weight of aromatic essential oils and 0-9.1% by weight of additives to form a silicone rubber clay composition. The organic silicone At least one selected from vinyl silicone rubber raw rubber and methyl silicone rubber raw rubber, the additive is selected from at least one selected from the group consisting of water-based silicon dioxide, antibacterial agents, anti-slump agents and silicone oil; (2) The silicone rubber clay composition is kneaded with a roller at room temperature to obtain a soft silicone rubber clay; and (3) After fully kneading the soft silicone rubber clay, knead the soft silicone rubber clay into a soft silicone rubber clay molded body of a predetermined shape. 如請求項8所述之柔軟矽橡膠黏土成型體的製作方法,其中該乙烯基矽橡膠生膠的分子量為65萬且乙烯基含量為0.16莫爾%的生膠。The method for making a soft silicone rubber clay molded body as described in claim 8, wherein the vinyl silicone rubber raw rubber has a molecular weight of 650,000 and a vinyl content of 0.16 mol%. 如請求項1所述之柔軟矽橡膠黏土成型體的製作方法,其中該甲基矽橡膠生膠的分子量為74-93萬的甲基生膠。The method for making a soft silicone rubber clay molded body as described in claim 1, wherein the methyl silicone rubber raw rubber has a molecular weight of 740,000-930,000 methyl raw rubber. 如請求項1所述之柔軟矽橡膠黏土成型體的製作方法,其中該抗菌劑為奈米銀抗菌劑。The method for making a soft silicone rubber clay molded body as described in claim 1, wherein the antibacterial agent is a nanosilver antibacterial agent. 如請求項1所述之柔軟矽橡膠黏土成型體的製作方法,其中該抗坍劑為蓖麻油衍生物。The method for making a soft silicone rubber clay molded body as described in claim 1, wherein the anti-slump agent is a castor oil derivative. 如請求項1所述之柔軟矽橡膠黏土成型體的製作方法,其中該顏料包括無機顏料或有機顏料,該無機顏料為鎘紅、鎘檸檬黃、橘鎘黃、二氧化鈦、碳黑、黑色氧化鐵或黑色錯合無機顏料,該有機顏料為苯胺黑、苝黑、蒽醌黑、聯苯胺類黃色顏料、酞青藍或酞青綠。The method for making a soft silicone rubber clay molded body as described in claim 1, wherein the pigment includes an inorganic pigment or an organic pigment, and the inorganic pigment is cadmium red, cadmium lemon yellow, orange cadmium yellow, titanium dioxide, carbon black, black iron oxide Or black complex inorganic pigment, the organic pigment is aniline black, perylene black, anthraquinone black, benzidine yellow pigment, phthalocyanine blue or phthalocyanine green. 如請求項1所述之柔軟矽橡膠黏土成型體的製作方法,其中該芳香精油為香茅精油、樟腦精油、迷迭香精油、薰衣草精油、檜木精油、玫瑰精油、茉莉花精油、薄荷精油、茶樹精油、柑橘精油、檸檬草精油、鼠尾草精油、尤加利精油、葡萄柚精油、肉桂精油、檸檬草精油或是由上述物質所組成的混合物。The method for making a soft silicone rubber clay molded body as described in claim 1, wherein the aromatic essential oils are citronella essential oil, camphor essential oil, rosemary essential oil, lavender essential oil, cypress essential oil, rose essential oil, jasmine essential oil, peppermint essential oil, tea tree Essential oil, citrus essential oil, lemongrass essential oil, sage essential oil, eucalyptus essential oil, grapefruit essential oil, cinnamon essential oil, lemongrass essential oil or a mixture of the above substances.
TW111116097A 2022-04-27 2022-04-27 Soft silicone rubber clay and preparation method of its molded body wherein the soft silicone rubber clay is composed of 89-99.5% by weight of organic silicone, 0.4-1.8% by weight of pigment, 0-0.6% by weight of aromatic essential oil and 0-9.1% by weight of additive TW202342397A (en)

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