TW202243868A - Heat-dissipation substrate structure and method for manufacturing the same - Google Patents
Heat-dissipation substrate structure and method for manufacturing the same Download PDFInfo
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Abstract
Description
本發明涉及一種基材結構及其形成方法,具體來說是涉及一種散熱基材結構及其形成方法。The present invention relates to a base material structure and a forming method thereof, in particular to a heat dissipation base material structure and a forming method thereof.
將固相金屬粉末與低壓壓縮氣體一起噴塗到散熱基材表面上所形成的冷噴塗層,其因著金屬粉末為固相狀,所以接合強度不高。然而,將固相金屬粉末與高壓壓縮氣體一起噴塗到散熱基材表面上所形成的冷噴塗層,其因著高壓噴塗會使嵌入的深度太深,且容易產生複雜多樣且不可預測的微結構或是裂紋。The cold spray coating formed by spraying solid phase metal powder and low-pressure compressed gas onto the surface of the heat dissipation substrate has low joint strength because the metal powder is in solid phase. However, the cold spray coating formed by spraying the solid phase metal powder and high-pressure compressed gas onto the surface of the heat-dissipating substrate will make the embedding depth too deep due to high-pressure spraying, and it is easy to produce complex, diverse and unpredictable microstructures Or crack.
有鑑於此,本發明人本於多年從事相關產品之開發與設計,有感上述缺失之可改善,乃特潛心研究並配合學理之運用,終於提出一種設計合理且有效改善上述缺失之本發明。In view of this, the inventor has been engaged in the development and design of related products for many years, and felt that the above-mentioned defects can be improved, so he devoted himself to research and combined with the application of theories, and finally proposed an invention with a reasonable design and effective improvement of the above-mentioned defects.
本發明所要解決的技術問題在於,針對現有技術的不足提供一種散熱基材結構及其形成方法。The technical problem to be solved by the present invention is to provide a heat-dissipating base material structure and a forming method thereof in view of the deficiencies of the prior art.
為了解決上述的技術問題,本發明提供一種散熱基材結構,包括:一基底層,以及一冷噴塗層,其形成於所述基底層的表面上;其中,所述冷噴塗層是通過將固相金屬粉末與高壓壓縮氣體一起噴塗到所述基底層,而在所述基底層的表面上形成的一薄膜;其中,所述固相金屬粉末為至少含有視密度介於3~4g/cm 3且中值粒徑(D50)為30µm以下的成膜用粉末;其中,所述冷噴塗層底部嵌入所述基底層中的最大深度≦100µm。 In order to solve the above technical problems, the present invention provides a heat dissipation base material structure, comprising: a base layer, and a cold sprayed layer formed on the surface of the base layer; wherein, the cold sprayed layer is formed by Phase metal powder is sprayed onto the base layer together with high-pressure compressed gas to form a thin film on the surface of the base layer; wherein, the solid phase metal powder contains at least an apparent density of 3 to 4 g/cm 3 Film-forming powder with a median particle size (D50) of 30 µm or less; wherein, the maximum depth of the bottom of the cold sprayed layer embedded in the base layer is ≦100 µm.
在一優選實施例中,所述冷噴塗層為一冷噴塗銅層。In a preferred embodiment, the cold sprayed layer is a cold sprayed copper layer.
在一優選實施例中,所述基底層為一鋁製基板。In a preferred embodiment, the base layer is an aluminum substrate.
在一優選實施例中,所述高壓壓縮氣體為壓力介於4~6Mpa的壓縮氣體。In a preferred embodiment, the high-pressure compressed gas is a compressed gas with a pressure between 4-6Mpa.
為了解決上述的技術問題,本發明另提供一種散熱基材結構的形成方法,包括:(a)提供一基底層,以及(b)形成一冷噴塗層於所述基底層的表面上;其中,所述冷噴塗層是通過將固相金屬粉末與高壓壓縮氣體一起噴塗到所述基底層,而在所述基底層的表面上形成的一薄膜;其中,所述固相金屬粉末為至少含有視密度介於3~4g/cm 3且中值粒徑(D50)為30µm以下的成膜用粉末;其中,所述冷噴塗層底部嵌入所述基底層中的最大深度≦100µm。 In order to solve the above technical problems, the present invention further provides a method for forming a heat dissipation substrate structure, comprising: (a) providing a base layer, and (b) forming a cold sprayed layer on the surface of the base layer; wherein, The cold spray coating is a thin film formed on the surface of the base layer by spraying the solid phase metal powder together with high-pressure compressed gas onto the base layer; wherein, the solid phase metal powder contains at least visual A film-forming powder with a density of 3-4g/cm 3 and a median particle size (D50) of 30µm or less; wherein, the maximum depth of the bottom of the cold sprayed layer embedded in the base layer is ≦100µm.
本發明的有益效果至少在於,本發明提供的散熱基材結構及其形成方法,其可以通過「所述冷噴塗層是通過將固相金屬粉末與高壓壓縮氣體一起噴塗到所述基底層,而在所述基底層的表面上形成的一薄膜」、「所述固相金屬粉末為至少含有視密度介於3~4g/cm 3且中值粒徑(D50)為30µm以下的成膜用粉末」、以及「所述冷噴塗層底部嵌入基底層中的最大深度≦100µm」的技術方案,可以使得冷噴塗層與基底層的接合強度達到40MPa以上,並且可以使得冷噴塗層底部嵌入基底層中的最大深度≦100µm,從而達到使高壓噴塗影響深度不深,但接合強度仍可以達到40MPa以上的效果。 The beneficial effect of the present invention lies at least in that the heat dissipation base material structure provided by the present invention and its forming method can pass through "the cold sprayed layer is sprayed onto the base layer by solid-phase metal powder and high-pressure compressed gas together, and A thin film formed on the surface of the base layer", "the solid-phase metal powder is a film-forming powder containing at least an apparent density of 3 to 4 g/cm 3 and a median particle size (D50) of 30 µm or less ", and "the maximum depth of the bottom of the cold spray coating embedded in the base layer≦100µm" can make the bonding strength between the cold spray coating and the base layer reach more than 40MPa, and can make the bottom of the cold spray coating embedded in the base layer The maximum depth of ≦100µm, so as to achieve the effect that the depth of high-pressure spraying is not deep, but the joint strength can still reach more than 40MPa.
為使能更進一步瞭解本發明的特徵及技術內容,請參閱以下有關本發明的詳細說明與圖式,然而所提供的圖式僅用於提供參考與說明,並非用來對本發明加以限制。In order to further understand the features and technical content of the present invention, please refer to the following detailed description and drawings related to the present invention. However, the provided drawings are only for reference and description, and are not intended to limit the present invention.
以下是通過特定的具體實施例來說明本發明所公開有關的實施方式,本領域技術人員可由本說明書所公開的內容瞭解本發明的優點與效果。本發明可通過其他不同的具體實施例加以施行或應用,本說明書中的各項細節也可基於不同觀點與應用,在不背離本發明的構思下進行各種修改與變更。另外,本發明的附圖僅為簡單示意說明,並非依實際尺寸的描繪,事先聲明。以下的實施方式將進一步詳細說明本發明的相關技術內容,但所公開的內容並非用以限制本發明的保護範圍。另外,本文中所使用的術語“或”,應視實際情況可能包括相關聯的列出項目中的任一個或者多個的組合。The following are specific examples to illustrate the implementation methods disclosed in the present invention. Those skilled in the art can understand the advantages and effects of the present invention from the content disclosed in this specification. The present invention can be implemented or applied through other different specific embodiments, and various modifications and changes can be made to the details in this specification based on different viewpoints and applications without departing from the concept of the present invention. In addition, the drawings of the present invention are only for simple illustration, and are not drawn according to the actual size, which is stated in advance. The following embodiments will further describe the relevant technical content of the present invention in detail, but the disclosed content is not intended to limit the protection scope of the present invention. In addition, the term "or" used herein may include any one or a combination of more of the associated listed items depending on the actual situation.
請參考圖1,為本發明提供的一種散熱基材結構。如圖所示,根據本發明所提供的散熱基材結構,其具有一基底層10及一冷噴塗層20。Please refer to FIG. 1 , which shows a heat dissipation substrate structure provided by the present invention. As shown in the figure, the heat dissipation substrate structure provided by the present invention has a
承上,冷噴塗層20形成於基底層10上。在本實施例中,基底層10為一鋁製散熱基板,但也可以為一鋁製散熱器(heat sink),然並不侷限於此。On top of that, the cold sprayed
在本實施例中,冷噴塗層20是通過將固相金屬粉末與高壓壓縮氣體一起噴塗到基底層10,而在基底層10的表面上形成的一薄膜。並且,本實施例的高壓壓縮氣體較佳為壓力介於4~6Mpa的壓縮氣體。In this embodiment, the cold sprayed
再者,在本實施例中,用來形成冷噴塗層20的固相金屬粉末為至少含有視密度介於3~4g/cm
3,且中值粒徑(D50)為30μm以下的成膜用粉末。
Furthermore, in this embodiment, the solid-phase metal powder used to form the cold sprayed
並且,根據實際實驗結果,當用來形成冷噴塗層20的固相金屬粉末為至少含有視密度介於3~4g/cm
3,且中值粒徑(D50)為30μm以下的成膜用粉末,並且通過將固相金屬粉末與高壓(4~6Mpa)壓縮氣體一起噴塗到基底層10時,可以使得冷噴塗層20與基底層10的接合強度達到40MPa以上。並且,參考圖2所示,冷噴塗層20底部嵌入基底層10中的最大深度D小於等於(≦)100µm,甚至可以小於60µm,從而達到使高壓噴塗影響深度不深,但接合強度仍可以達到40MPa以上,且可以避免出現複雜多樣且不可預測的微結構或是裂紋。
Moreover, according to actual experimental results, when the solid phase metal powder used to form the cold sprayed
在一實施例中,冷噴塗層20可為一冷噴塗銅層。進一步說,冷噴塗銅層可以是通過將固相銅粉末與高壓壓縮氣體一起噴塗到基底層10,而在基底層10的表面上形成的一薄膜。In one embodiment, the cold sprayed
在一實施例中,冷噴塗層20可為一冷噴塗鋁層。進一步說,冷噴塗鋁層可以是通過將固相鋁粉末與高壓壓縮氣體一起噴塗到基底層10,而在基底層10的表面上形成的一薄膜。In one embodiment, the cold sprayed
在一實施例中,冷噴塗層20可為一冷噴塗鎳層。進一步說,冷噴塗鎳層可以是通過將固相鎳粉末與高壓壓縮氣體一起噴塗到基底層10,而在基底層10的表面上形成的一薄膜。In one embodiment, the cold sprayed
在一實施例中,冷噴塗層20可為一冷噴塗鐵層。進一步說,冷噴塗鐵層可以是通過將固相鐵粉末與高壓壓縮氣體一起噴塗到基底層10,而在基底層10的表面上形成的一薄膜。In one embodiment, the cold sprayed
在一實施例中,冷噴塗層20可為一冷噴塗合金層。進一步說,冷噴塗合金層可以是通過將固相銅粉末、固相鋁粉末、固相鎳粉末、固相鐵粉末的其中至少二種粉末與高壓壓縮氣體一起噴塗到基底層10,而在基底層10的表面上形成的一薄膜。In one embodiment, the cold sprayed
根據上面所敘述的,本發明亦提供一種散熱基材結構的形成方法,主要包括以下步驟:(a)提供一基底層,以及(b)形成一冷噴塗層於基底層的表面上。詳細來說,本實施例的冷噴塗層是通過將固相金屬粉末與高壓(4~6Mpa)壓縮氣體一起噴塗到基底層,而在基底層的表面上形成的一薄膜。並且,用來形成冷噴塗層的固相金屬粉末為至少含有視密度介於3~4g/cm 3且中值粒徑(D50)為30μm以下的成膜用粉末。再者,冷噴塗層底部嵌入基底層中的最大深度≦100µm。 According to the above, the present invention also provides a method for forming a heat dissipation substrate structure, which mainly includes the following steps: (a) providing a base layer, and (b) forming a cold sprayed layer on the surface of the base layer. In detail, the cold spray coating in this embodiment is a thin film formed on the surface of the base layer by spraying solid phase metal powder and high-pressure (4~6Mpa) compressed gas onto the base layer together. Moreover, the solid-phase metal powder used to form the cold spray coating is a film-forming powder containing at least an apparent density of 3-4 g/cm 3 and a median particle size (D50) of 30 μm or less. Furthermore, the maximum depth of the bottom of the cold sprayed coating embedded in the base layer is ≦100µm.
綜合以上所述,本發明提供的散熱基材結構及其形成方法,其可以通過「所述冷噴塗層是通過將固相金屬粉末與高壓壓縮氣體一起噴塗到所述基底層,而在所述基底層的表面上形成的一薄膜」、「所述固相金屬粉末為至少含有視密度介於3~4g/cm
3且中值粒徑(D50)為30µm以下的成膜用粉末」、以及「所述冷噴塗層底部嵌入基底層中的最大深度≦100µm」的技術方案,可以使得冷噴塗層20與基底層10的接合強度達到40MPa以上,並且可以使得冷噴塗層20底部嵌入基底層10中的最大深度≦100µm,從而達到使高壓噴塗影響深度不深,但接合強度仍可以達到40MPa以上的效果。
Based on the above, the heat dissipation base material structure and its forming method provided by the present invention can be achieved by "the cold spray coating is sprayed onto the base layer by solid-phase metal powder and high-pressure compressed gas, and on the A thin film formed on the surface of the base layer", "the solid-phase metal powder is a film-forming powder containing at least an apparent density of 3 to 4 g/cm 3 and a median particle size (D50) of 30 µm or less", and The technical scheme of "the maximum depth of the bottom of the cold sprayed layer embedded in the base layer≦100µm" can make the bonding strength between the cold sprayed
以上所公開的內容僅為本發明的優選可行實施例,並非因此侷限本發明的申請專利範圍,所以凡是運用本發明說明書及圖式內容所做的等效技術變化,均包含於本發明的申請專利範圍內。The content disclosed above is only a preferred feasible embodiment of the present invention, and does not therefore limit the scope of the patent application of the present invention. Therefore, all equivalent technical changes made by using the description and drawings of the present invention are included in the application of the present invention. within the scope of the patent.
10:基底層 20:冷噴塗層 D:最大深度 10: Base layer 20: cold spray coating D: maximum depth
圖1為本發明散熱基材結構的側視示意圖。FIG. 1 is a schematic side view of the heat dissipation substrate structure of the present invention.
圖2為圖1的II部分的放大示意圖。FIG. 2 is an enlarged schematic view of part II of FIG. 1 .
10:基底層 10: Base layer
20:冷噴塗層 20: cold spray coating
D:最大深度 D: maximum depth
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