TW202223316A - Sintering jig - Google Patents
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- TW202223316A TW202223316A TW110118012A TW110118012A TW202223316A TW 202223316 A TW202223316 A TW 202223316A TW 110118012 A TW110118012 A TW 110118012A TW 110118012 A TW110118012 A TW 110118012A TW 202223316 A TW202223316 A TW 202223316A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/12—Travelling or movable supports or containers for the charge
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Abstract
Description
本發明係關於一種當陶瓷製品等燒結時,載置該等陶瓷製品之燒結治具。The present invention relates to a sintering jig for placing ceramic products and the like when they are sintered.
以往,在製造陶瓷製品等的過程中,包含在燒結爐內將受燒結物進行燒結之燒結步驟。在該燒結步驟中,受燒結物是被載置於燒結爐內的燒結治具而被燒結。Conventionally, in the process of manufacturing ceramic products and the like, a sintering step of sintering a sintered object in a sintering furnace is included. In this sintering step, the object to be sintered is sintered by being placed on a sintering jig in a sintering furnace.
然後,藉由使用如專利文獻1所揭示之具有形成中空部框體之燒結治具,來達成燒結治具的透氣性、輕量化、或是熱容量的降低。Then, by using a sintering jig having a hollow frame body as disclosed in Patent Document 1, the air permeability, weight reduction, or reduction of heat capacity of the sintering jig can be achieved.
先前技術文獻:專利文獻1,日本發明專利第6274454號公報。Prior art documents: Patent Document 1, Japanese Patent Publication No. 6274454.
然而,燒結治具因為於燒結步驟中被搬運到燒結爐內而燒結,又在燒結後被搬出到燒結爐外,以致變成放置在溫差劇烈變化的環境,使其結構的內外容易產生熱膨脹之差,成為容易發生龜裂或變形(潛變)的狀態。However, the sintering jig is sintered because it is transported into the sintering furnace during the sintering step, and then moved out of the sintering furnace after sintering, so that it is placed in an environment where the temperature difference changes drastically, and the difference in thermal expansion between the inside and outside of its structure is likely to occur. , and becomes prone to cracking or deformation (creeping).
本發明鑑於上述課題,提供一種即使在溫差劇烈變化的使用狀況下,仍不易發生龜裂或變形(潛變)之燒結治具。In view of the above-mentioned problems, the present invention provides a sintered jig that is less prone to cracking or deformation (creeping) even under a usage condition where the temperature difference changes drastically.
為了解決上述課題而完成之本發明的燒結治具,其特徵在於具有:一框體,其設置有複數的中空部、與架設於前述中空部之架橋部;前述架橋部朝向前述框體的外周緣延伸,於所交會之前述框體的外周緣的至少一部份形成有切口部。 藉由此構成,即使在溫差劇烈變化的狀況下使用,於燒結治具之結構的內外之中不易產生熱膨脹之差,能夠防止龜裂或變形,且能夠提升耐剝落性。 The sintering jig of the present invention, which has been accomplished in order to solve the above-mentioned problems, is characterized by comprising: a frame body provided with a plurality of hollow parts; The edge extends, and a cutout portion is formed in at least a part of the outer peripheral edge of the frame body that meets. With this configuration, even when the temperature difference changes drastically, the difference in thermal expansion is less likely to occur inside and outside the structure of the sintering jig, cracking and deformation can be prevented, and peeling resistance can be improved.
本發明的燒結治具即使在溫差劇烈變化的狀況下使用,於燒結治具之結構的內外之中不易產生熱膨脹之差,能夠防止龜裂或變形,且能夠提升耐剝落性。Even if the sintering jig of the present invention is used in a situation where the temperature difference changes drastically, the difference in thermal expansion is not easily generated between the inside and outside of the structure of the sintering jig, cracking or deformation can be prevented, and peeling resistance can be improved.
以下,基於附加圖式說明本發明之實施形態的燒結治具。Hereinafter, the sintering jig which concerns on embodiment of this invention is demonstrated based on attached drawing.
首先,基於附加圖式以下說明本發明之實施形態的燒結治具。圖1係本發明之實施形態的燒結治具之平面圖。圖2係本發明之實施形態的燒結治具之正面圖。圖3係本發明之實施形態的燒結治具之右側面圖。First, a sintering jig according to an embodiment of the present invention will be described below based on the attached drawings. Fig. 1 is a plan view of a sintering jig according to an embodiment of the present invention. Fig. 2 is a front view of the sintering jig according to the embodiment of the present invention. Fig. 3 is a right side view of the sintering jig according to the embodiment of the present invention.
如圖1所示,本實施形態的燒結治具10係具有:框體11、複數的架橋部12(在圖1中為2個),以及複數的中空部13(在圖1中為4個)。另外,架橋部12朝向框體11的外周緣延伸,並於所交會之框體11的外周緣的至少一部份形成有切口部14。As shown in FIG. 1 , the
框體11係於俯視時形成為矩形。另,框體11係於正面視及右側面視形成為薄板狀。此處,針對框體11於俯視中的各邊,在框體11的外周緣中,將其上端之邊設為11A,將其下端之邊設為11B,將其右端之邊設為11C,將其左端之邊設為11D。另外,框體11並不限定於圖1所示般橫向較長的矩形,亦可為例如正方形、三角形等之多角形、或是圓形、橢圓形等之其他的形狀。The
如圖2所示,框體11亦可設有:支撐部16,形成於框體11的第1面15並支撐框體11;承受部18,形成於框體11的第2面17且當積層另一個的框體11時可承受於垂直方向載置之框體11的支撐部16。例如,如圖1所示,支撐部16及承受部18分別設置了6個。As shown in FIG. 2 , the
架橋部12係以連續於框體11之方式形成,並且架設在形成於框體11的中空部13的方式配置。在本實施形態的燒結治具10,架橋部12係自框體11的邊11A朝向邊11B,連續於框體11且複數地設置。具體而言,將位於左側的架橋部12設為架橋部12A,將位於右側的架橋部12設為架橋部12B。The bridge portion 12 is formed so as to be continuous with the
此處,如圖1、4所示,架橋部12之被夾在複數中空部13間的架橋部12的最小寬度尺寸W,相對於架橋部12的厚度尺寸T較佳為2~15倍。在本實施形態,被夾在後述之中空部13A與中空部13B間的架橋部12A的最小寬度尺寸W,相對於架橋部12A的厚度尺寸T較佳為2~15倍。此處,當架橋部12A的最小寬度尺寸W相對於架橋部12A的厚度尺寸T為2倍或其以上時,可分散因載置於架橋部12A上的托架以及受燒結物對產生於架橋部12A之每單位面積的載重這點是有利的。另外,架橋部12A的最小寬度尺寸W相對於架橋部12A的厚度尺寸T為15倍或其以下時,就能夠減少因燒結爐內的溫度變化而發生於架橋部12A的溫度分布寬度而較佳。同樣地,被夾在後述之中空部13C與中空部13D間的架橋部12B的最小寬度尺寸W,相對於架橋部12B的厚度尺寸T較佳為2~15倍。Here, as shown in FIGS. 1 and 4 , the minimum width dimension W of the bridge portion 12 sandwiched between the plurality of hollow portions 13 of the bridge portion 12 is preferably 2 to 15 times the thickness T of the bridge portion 12 . In the present embodiment, the minimum width dimension W of the
如圖1所示,中空部13係由以架橋部12A所劃分出的中空部13A、13B、以及以架橋部12B所劃分出的中空部13C、13D所構成。另外,中空部13A、13B、13C以及13D為半圓形,且於由圓弧部與直線部所構成的角部形成有角R為佳。像這樣,由於角部形成為角R,可避免負荷集中於角部,成為不易產生龜裂的形狀。As shown in FIG. 1, the hollow part 13 is comprised by the
切口部14較佳為在架橋部12A、12B延伸所交會之框體11的邊11A或邊11B的交點處,以成為一對的方式設置。在本實施形態,切口部14A與切口部14B是在架橋部12A延伸所交會之框體11的邊11A或邊11B的交點處,以成為一對的方式設置。另外,切口部14C與切口部14D是在架橋部12B延伸所交會之框體11的邊11A或邊11B的交點處,以成為一對的方式設置。The cutout portions 14 are preferably provided as a pair at the intersection of the
像這樣,由於切口部14以成為一對的方式而設置,故能夠使燒結爐內的熱氣不滯留而移動,能夠使燒結治具10以及載置於燒結治具10上的托架、和受燒結物的溫度均勻化,因此能夠縮小於燒結治具10之結構內的熱膨脹之差。另外,切口部14亦可於邊11C或邊11D以成為一對的方式設置。In this way, since the notches 14 are provided as a pair, the hot gas in the sintering furnace can be moved without stagnation, and the
如圖5所示,在切口部14與中空部13之間所形成的架橋部12的最短距離為被夾在複數的中空部13間的架橋部12的最小寬度尺寸的0.5~1.2倍為佳。在本實施形態中,在切口部14A與中空部13A之間所形成的架橋部12A的最短距離D,為被夾在中空部13A與中空部13B間的架橋部12A的最小寬度尺寸W的0.5~1.2倍。此處,如果在切口部14A與中空部13A之間所形成的架橋部12A的最短距離D為被夾在中空部13A與中空部13B間的架橋部12A的最小寬度尺寸W的0.5倍或其以上,則切口部14A與中空部13A之間所形成的架橋部12A的區域相對於被夾在中空部13A與中空部13B間的架橋部12A的區域,可增加1/2程度或其以上的載重耐力而較佳。另外,在切口部14A與中空部13A之間所形成的架橋部12A的最短距離D,如果為被夾在中空部13A與中空部13B間的架橋部12A的最小寬度尺寸W的1.2倍或其以下,則切口部14A與中空部13A之間所形成的架橋部12A的區域相對於被夾在中空部13A與中空部13B間的架橋部12A的區域,可獲得同等程度的溫度分布寬度而較佳。As shown in FIG. 5 , the shortest distance of the bridge parts 12 formed between the notches 14 and the hollow parts 13 is preferably 0.5 to 1.2 times the minimum width dimension of the bridge parts 12 sandwiched between the plurality of hollow parts 13 . In the present embodiment, the shortest distance D of the
又,在切口部14A與中空部13B之間所形成的架橋部12A的最短距離、在切口部14B與中空部13A之間所形成的架橋部12A的最短距離,以及在切口部14B與中空部11B之間所形成的架橋部12A的最短距離亦同樣地為被夾在中空部13A與中空部13B間的架橋部12A的最小寬度尺寸W的0.5~1.2倍。更且,在切口部14C與中空部13C之間所形成的架橋部12B的最短距離、在切口部14C與中空部13D之間所形成的架橋部12B的最短距離、在切口部14D與中空部13C之間所形成的架橋部12B的最短距離,以及在切口部14D與中空部13D之間所形成的架橋部12B的最短距離,為被夾在中空部13C與中空部13D間的架橋部12B的最小寬度尺寸的0.5~1.2倍。Moreover, the shortest distance of the
切口部14A的最大切口尺寸C、亦即自框體11的邊11A的凹量,為複數的被夾在中空部13A與中空部13B間的架橋部12A的最小寬度尺寸W的0.2~2.0倍。此處,如果切口部14A的最大切口尺寸C為被夾在中空部13A與中空部13B間的架橋部12A的最小寬度尺寸W的0.2倍或其以上,則發生在框體11的邊11A之熱應變將趨緩之觀點而言為有利。另外,如果切口部14A的最大切口尺寸C為被夾在中空部13A與中空部13B間的架橋部12A的最小寬度尺寸W的2.0倍或其以下,則針對被夾在中空部13A與中空部13B間的架橋部12A之機械及熱的應力之集中會被分散之點為有利。The maximum notch dimension C of the
同樣地,切口部14B的最大切口尺寸為被夾在中空部13A與中空部13B間的架橋部12A的最小寬度尺寸W的0.2~2.0倍為佳。另外,切口部14C的最大切口尺寸,以及切口部14D的最大切口尺寸為被夾在中空部13C與中空部13D間的架橋部12B的最小寬度尺寸的0.2~2.0倍為佳。Similarly, it is preferable that the maximum notch dimension of
切口部14A的長度尺寸L、亦即框體11的邊11A上的切口部14A的長度尺寸L,為架橋部12A的最小寬度尺寸W的1.0~5.0倍為佳。此處,如果切口部14A的長度尺寸L為架橋部12A的最小寬度尺寸W的1.0倍或其以上,則針對切口14A之機械及熱的應力之集中會被分散這點是有利的。另外,如果切口部14A的長度尺寸L為架橋部12A的最小寬度尺寸W的5.0倍或其以下,則有利於發生在框體11的邊11A之熱應變之趨緩。又,切口部14B的長度尺寸為架橋部12A的最小寬度尺寸W的1.0~5.0倍為佳。此處,與切口部14A相對之中空部13A的外周部係互相以凸狀的曲線相對構成,藉此使應力的分散與溫度分佈寬度的減少這2種相反的特性能夠兼顧之效果得以更進一步地發揮。另外,切口部14C及14D的長度尺寸也各自為架橋部12B的最小寬度尺寸W的1.0~5.0倍為佳。The length dimension L of the
更且,切口部14具有圓弧狀的部位。此處,當切口部14A為圓弧狀時,切口部14A的半徑為架橋部12A的最小寬度尺寸W的0.5~2.50倍為佳。如果切口部14A的半徑為架橋部12A的最小寬度尺寸W的0.5倍或其以上,則切口部14A所產生的熱應變得以分散、使耐剝落性提升這點是有利的。另外,如果切口部14A的半徑為架橋部12A的最小寬度尺寸W的2.5倍或其以下,則框體11的邊11A所產生的機械及熱的應力得以分散這點是有利的。又,切口部14B的半徑為架橋部12A的最小寬度尺寸W的0.5~2.50倍為佳。更且,切口部14C及14D的半徑為架橋部12B的最小寬度尺寸W的0.75~2.50倍為佳,更佳為0.8~2.40倍。Furthermore, the cutout portion 14 has an arc-shaped portion. Here, when the
另外,切口部14的形狀並不限定於圖1所示之圓弧狀,只要是可組合成曲線的形狀即可,例如亦可為組合了複數個橢圓形狀之形狀。In addition, the shape of the notch part 14 is not limited to the arc shape shown in FIG. 1, as long as it is a shape which can be combined into a curve, for example, the shape which combined a plurality of elliptical shapes may be sufficient.
具有上述之構成的燒結治具10是使用將粉狀或黏土狀的耐火物灌注到未圖示的金屬模具而加壓,即所謂的壓製成形;或是灌注到石膏模具使之固化,即所謂的注漿成形等而形成。耐火物例如以氧化鋁、莫來石、二氧化鋯、氧化鎂、堇青石、尖晶石、碳化矽、氮化矽、氮化鋁、碳化硼及這些的混合物等為主者,只要是可耐例如1,200℃為或其以上,較佳為1,300℃或其以上,更佳為1,500℃或其以上之高溫的素材即可。The
關於上述之本實施形態的燒結治具10,係針對實施例1~6之燒結治具、比較例1、2之燒結治具進行爐內放置試驗與耐剝落性評價試驗。實施例1~5的構成如圖6~圖8所示。另外,因為實施例6之燒結治具的構成除了材質與架橋部12A的厚度尺寸T以外,都與實施例1之燒結治具為相同形狀,故省略了圖式。另外,比較例1、2之燒結治具的構成如圖9所示。關於實施例1~6及比較例1、2之燒結治具的構成,因已標上與上述之本實施形態的燒結治具10中構成相同的符號,故省略說明。Regarding the
具體而言,實施例1~5、比較例1、2是將粗粒莫來石(平均粒徑:約70μm)、微粒氧化鋁(平均粒徑D 50:3μm)、微粒二氧化矽(平均粒徑D 50:5μm)之原料粉末與有機黏結劑(聚乙烯醇、甲基纖維素、糊精等)以成為Al 2O 3:78質量%、SiO 2:22質量%的方式,使用高速混合器攪拌混合,生成攪拌混合物。將上述獲得的攪拌混合物進行單軸加壓壓製成形,藉此而分別成形為圖6~圖8、9所示之形狀,而獲得成形體。然後,將這些的成形體在大氣氛圍下進行燒結(到達溫度:1700℃:,維持時間:8小時)獲得燒結體,藉此製作成實施例1~5、比較例1、2之燒結治具。同樣地,實施例6是將粗粒氧化鋁(平均粒徑:約70μm)、微粒氧化鋁(平均粒徑D 50:35μm)、微粒二氧化矽(平均粒徑D 50:5μm)之原料粉末與有機黏結劑(聚乙烯醇、甲基纖維素、糊精等)以成為Al 2O 3:95質量%、SiO 2:5質量%的方式,使用高速混合器來攪拌混合,進行單軸加壓壓製成形(參照圖6(a))以及在大氣氛圍下進行燒結,藉此製作成實施例6之燒結治具。此處,上述之燒結體的外觀氣孔率(依據JISR2205:1902)係實施例1~5及比較例1、2為21%,實施例6為20%。 Specifically, in Examples 1 to 5 and Comparative Examples 1 and 2, coarse-grained mullite (average particle size: about 70 μm), fine-particle alumina (average particle size D 50 : 3 μm), and fine-particle silica (average particle size: 3 μm) were mixed The raw material powder and the organic binder (polyvinyl alcohol, methyl cellulose, dextrin, etc.) having a particle size D 50 : 5 μm) were used at a high speed so that the content of Al 2 O 3 : 78 mass % and SiO 2 : 22 mass % The mixer stirs and mixes to produce a stirred mixture. The kneaded mixture obtained above was subjected to uniaxial press-molding, thereby molding into the shapes shown in FIGS. 6 to 8 and 9 , respectively, to obtain a molded body. Then, these molded bodies were sintered in the atmosphere (attainment temperature: 1700° C., holding time: 8 hours) to obtain sintered bodies, from which sintering jigs of Examples 1 to 5 and Comparative Examples 1 and 2 were produced. . Similarly, in Example 6, raw material powders of coarse-grained alumina (average particle size: about 70 μm), fine-grained alumina (average particle size D 50 : 35 μm), and fine-grained silica (average particle size D 50 : 5 μm) were prepared The organic binder (polyvinyl alcohol, methyl cellulose, dextrin, etc.) is stirred and mixed using a high-speed mixer so as to be Al 2 O 3 : 95 mass % and SiO 2 : 5 mass %, and uniaxially added. Press molding (refer to FIG. 6( a )) and sintering in the atmosphere were carried out, whereby the sintering jig of Example 6 was produced. Here, the apparent porosity (based on JISR2205:1902) of the above-mentioned sintered body was 21% in Examples 1 to 5 and Comparative Examples 1 and 2, and 20% in Example 6.
〈爐內放置試驗〉 爐內放置試驗係如下述進行試驗。在橫長(290mm×120mm)形狀的燒結治具上的整面,以成為600g/燒結治具之均等載重的方式,將2片115mm×115mm尺寸的擬似工件(陶瓷板材)併排載置而成為燒結治具,並以將該燒結治具積層3段的狀態載置於電熱爐內。然後,實施將電熱爐內加熱至最高溫度為1,400℃維持3小時後冷卻至常溫的熱處理,並將調查燒結治具有無龜裂或變形的試驗結果顯示於表1。此處,龜裂之調查是試驗者以目視來進行。另一方面,變形是將位於燒結治具的框體的對角線上之角部彼此連成的假想線間之差作為撓曲量來算出。然後,當撓曲量為0.3mm或其以上時,定義為「有變形」。另外,亦可將位於燒結治具的框體的對角線上之角部與中央部連成的假想線間之差作為撓曲量來算出。 <In-furnace placement test> The furnace placement test was carried out as follows. On the entire surface of a sintering jig with a horizontal length (290mm×120mm), two pieces of 115mm×115mm size pseudo workpieces (ceramic plates) were placed side by side so as to obtain an equal load of 600g/sintering jig. The sintering jig is placed in the electric furnace in a state where the sintering jig is laminated in three stages. Then, the heat treatment of heating the inside of the electric furnace to the maximum temperature of 1,400° C., maintaining it for 3 hours, and cooling to normal temperature is performed. Here, the investigation of cracks was carried out by the tester's eyes. On the other hand, the deformation was calculated by using the difference between the imaginary lines formed by connecting the corners on the diagonal lines of the frame body of the sintering jig as the deflection amount. Then, when the deflection amount was 0.3 mm or more, it was defined as "deformed". Moreover, you may calculate as a deflection amount the difference between the imaginary line which connects the corner part and the center part on the diagonal line of the frame body of a sintering jig.
表1
此處,表1中的「D/W」是表示切口部14與中空部13之間所形成的架橋部12的最短距離D相對於被夾在複數的中空部13間的架橋部12的最小寬度尺寸W之倍率。「C/W」是表示切口部14A的最大切口尺寸C相對於被夾在複數的中空部13A與中空部13B間的架橋部12A的最小寬度尺寸W之倍率。「W/T」是表示,架橋部12之被夾在複數的中空部間的架橋部12的最小寬度尺寸W相對於架橋部12的厚度尺寸T之倍率。「L/W」是表示切口部14A的長度尺寸L相對於架橋部12A的最小寬度尺寸W之倍率。另外,比較例1、2如圖11所示,由於並未形成切口部14,因此「D/W」、「C/W」及「L/W」欄位空白。Here, “D/W” in Table 1 represents the minimum distance D of the bridge portion 12 formed between the cutout portion 14 and the hollow portion 13 with respect to the minimum distance D of the bridge portion 12 sandwiched between the plurality of hollow portions 13 The magnification of the width dimension W. "C/W" represents a ratio of the maximum notch dimension C of the
從表1所示之爐內放置試驗的結果來看,實施例1~6之燒結治具藉由設置有切口部14,而未見到龜裂或變形。另一方面,比較例1、2之燒結治具有確認到龜裂。From the results of the furnace placement test shown in Table 1, the sintering jigs of Examples 1 to 6 were provided with the notches 14, and no cracks or deformation were observed. On the other hand, in the sintered cures of Comparative Examples 1 and 2, cracks were confirmed.
〈耐剝落性評價試驗〉 在橫長(290mm×120mm)形狀的燒結治具上的整面,以成為600g/燒結治具之均等載重的方式,將2片115mm×115mm尺寸的擬似工件(陶瓷板材)併排載置而成為燒結治具(以下稱為燒結組),並以將該燒結治具積層3段的狀態從室溫狀態(T 0=25℃)搬運到保持在預定溫度(T 1)的電熱爐內,保持1小時。藉由將燒結組保持在該電熱爐內1小時後,進而取出到電熱爐外,再度冷卻至室溫(T 0=25℃)之冷卻步驟,來調查有無在冷卻步驟所產生之急遽的溫度變化所導致之燒結治具的龜裂。龜裂的有無是藉由試驗者以目視來進行。此處,電熱爐的預定溫度(T 1)是指將275℃設為開始溫度,只要燒結治具沒有發生龜裂,則使電熱爐內的溫度每次上昇25℃而進行上述之冷卻步驟時的電熱爐內的溫度。然後,在燒結治具發生了龜裂的時點結束耐剝落性評價試驗。 <Peeling resistance evaluation test> On the entire surface of the horizontally long (290mm×120mm) sintered jig, two pieces of 115mm×115mm size of the pseudo workpiece (ceramic Plates) are placed side by side to form a sintering jig (hereinafter referred to as a sintering group), and the sintering jig is transported from a room temperature state (T 0 =25°C) to a predetermined temperature (T 1 ) in a state where the sintering jig is stacked in three stages. ) in the electric furnace for 1 hour. After keeping the sintered group in the electric heating furnace for 1 hour, then taking it out of the electric heating furnace, and cooling it to room temperature (T 0 =25°C) again, the presence or absence of abrupt temperature generated in the cooling step was investigated. Cracks in the sintered jig caused by changes. The presence or absence of cracks was visually checked by the tester. Here, the predetermined temperature (T 1 ) of the electric heating furnace means that 275° C. is set as the starting temperature, and the temperature in the electric heating furnace is increased by 25° C. each time and the above-mentioned cooling step is performed as long as the sintering jig is not cracked. temperature inside the electric furnace. Then, the peeling resistance evaluation test was terminated when the cracking occurred in the sintered jig.
龜裂的評價如以下所述。此處,ΔT係指當實施上述急速加熱+急速冷卻處理的情況時,在燒結治具沒有發生龜裂之電熱爐的預定溫度(T 1)與室溫(T 0)的溫度差(ΔT= T 1- T 0)之上限。 ◎(最佳):ΔT≧475[℃] ○(佳):425<ΔT≦475[℃] △(可):400<ΔT≦425[℃] ×(不佳):ΔT<400[℃] The evaluation of cracks is as follows. Here, ΔT refers to the temperature difference ( ΔT = The upper limit of T 1 - T 0 ). ◎(best): ΔT≧475[℃] ○(best): 425<ΔT≦475[℃] △(good): 400<ΔT≦425[℃] ×(not good): ΔT<400[℃]
表2
從表2所示之耐剝落性評價試驗的結果來看,實施例1~6之燒結治具全部到ΔT=400℃為止都沒有確認到龜裂,故耐剝落性評價為良好。實施例1~6之燒結治具因為如上述般具有優異的耐剝落性,所以變成能夠從電熱爐取出後急速地使之冷卻,而可能在短時間取出製品。藉此,由於能夠達成燒結治具的組裝作業及拆解作業的加速,故燒結步驟能夠高速化。另一方面,比較例1、2之燒結治具即使是在相當低的溫度仍確認到龜裂,故耐剝落性評價為不良。From the results of the peeling resistance evaluation test shown in Table 2, all the sintered jigs of Examples 1 to 6 were found to have no cracks until ΔT=400°C, so the peeling resistance was evaluated as good. Since the sintering jigs of Examples 1 to 6 have excellent peeling resistance as described above, they can be quickly cooled after being taken out from the electric heating furnace, and the products can be taken out in a short time. Thereby, since the assembling operation and the disassembling operation of the sintering jig can be accelerated, the sintering process can be accelerated. On the other hand, in the sintered jigs of Comparative Examples 1 and 2, cracks were observed even at a relatively low temperature, so the peeling resistance was evaluated as unsatisfactory.
上述之本實施形態的燒結治具10係如以下所述載置受燒結物X來實施燒結步驟。In the
如圖10所示,以於本實施形態的燒結治具10的表面載置托架20,在該托架20的上面21載置受燒結物X的狀態,配置在未圖示的燒結爐內,使受燒結物X進行燒結。As shown in FIG. 10 , the
另外,托架20是由透氣性高的耐火物所形成。托架20藉由具有高透氣性,使得燒結爐內的熱風變得容易通過托架20而到達受燒結物X的下面側,能夠效率佳地實施受燒結物X的燒結。作為透氣性高的耐火物,有形成有許多氣孔的多孔質板狀。In addition, the
此處,本實施形態的燒結治具10藉由形成複數的中空部13,使得燒結爐內的熱風變得更容易通過托架20而到達受燒結物X的下面側,因此能夠效率更佳地實施受燒結物X的燒結。Here, in the
再者,如圖11所示,載置有受燒結物X之複數的燒結治具10能夠為積層的狀態。在圖11中,雖然是將燒結治具10積層3段,但並不限定於此,亦可為2段、或4段或其以上。像這樣,藉由燒結治具10為積層有複數段的狀態,而能夠比1段的情況一次燒結更多的受燒結物X。Furthermore, as shown in FIG. 11 , a plurality of sintering jigs 10 on which the sintered object X is placed can be in a state of being stacked. In FIG. 11, although the
本說明書揭示的發明係包含除了各發明或實施形態的構成之外,在能應用的範圍而將這些的部分構成變更為本說明書揭示的其他構成所特定而成者、或者在這些的構成附加了本說明書揭示的其他構成所特定而成者、或者在可獲得部分的作用效果之限度而削除這些的部分構成所特定而成之經上位概念化而成者。The inventions disclosed in this specification include those formed by changing some of the structures disclosed in the present specification to those specified in the other structures disclosed in the present specification within the applicable range, or adding these structures in addition to the structures of the respective inventions or the embodiments. Other structures disclosed in the present specification are specified, or those specified by partial structures are eliminated to the extent that some functions and effects can be obtained, and are conceptualized at a higher level.
本實施形態的燒結治具10的架橋部12係自框體11的邊11A朝向邊11B,連續於框體11而設置,但不限定於此,亦可自框體11的邊11C朝向邊11D,連續於框體11而設置。亦即,亦可將架橋部12以成為十字狀的方式設置,亦可於中空部13設為相互交叉的形狀。藉由架橋部12形成十字狀,當於燒結治具10上載置有托架20時,能夠以更穩定的狀態來支撐托架20。The bridge portion 12 of the
10:燒結治具
11:框體
11A、11B、11C、11D:邊
12、12A、12B:架橋部
13、13A、13B、13C、13D:中空部
14、14A、14B、14C、14D:切口部
15:第1面
16:支撐部
17:第2面
18:承受部
20:托架
X:受燒結物
10: Sintering fixture
11:
圖1係本發明之實施形態的燒結治具之平面圖。 圖2係本發明之實施形態的燒結治具之正面圖。 圖3係本發明之實施形態的燒結治具之右側面圖。 圖4係圖1所示之本發明之實施形態的燒結治具之A-A線剖面圖。 圖5係圖1所示之本發明之實施形態的燒結治具之部分放大圖。 圖6 (a)係為本發明之實施形態的燒結治具的實施例1之平面圖,(b)為本發明之實施形態的燒結治具的實施例2之平面圖。 圖7(a) 係為本發明之實施形態的燒結治具的實施例3之平面圖,(b)為本發明之實施形態的燒結治具的實施例4之平面圖。 圖8係本發明之實施形態的燒結治具的實施例5之平面圖。 圖9(a)係為本發明之實施形態的燒結治具的比較例1之平面圖,(b)為本發明之實施形態的燒結治具的比較例2之平面圖。 圖10係表示於本發明之實施形態的燒結治具載置有受燒結物的狀態之正面圖。 圖11係表示本發明之實施形態的燒結治具被積層的狀態之正面圖。 Fig. 1 is a plan view of a sintering jig according to an embodiment of the present invention. Fig. 2 is a front view of the sintering jig according to the embodiment of the present invention. Fig. 3 is a right side view of the sintering jig according to the embodiment of the present invention. Fig. 4 is a cross-sectional view taken along the line A-A of the sintering jig according to the embodiment of the present invention shown in Fig. 1 . FIG. 5 is a partial enlarged view of the sintering jig according to the embodiment of the present invention shown in FIG. 1 . Fig. 6 (a) is a plan view of Example 1 of the sintering jig according to the embodiment of the present invention, and (b) is a plan view of Example 2 of the sintering jig according to the embodiment of the present invention. Fig. 7(a) is a plan view of Example 3 of the sintering jig according to the embodiment of the present invention, and (b) is a plan view of Example 4 of the sintering jig according to the embodiment of the present invention. Fig. 8 is a plan view of Example 5 of the sintering jig according to the embodiment of the present invention. 9(a) is a plan view of Comparative Example 1 of the sintering jig according to the embodiment of the present invention, and (b) is a plan view of Comparative Example 2 of the sintering jig according to the embodiment of the present invention. 10 is a front view showing a state in which a sintered object is placed on the sintering jig according to the embodiment of the present invention. FIG. 11 is a front view showing a state in which the sintering jig according to the embodiment of the present invention is laminated.
無。none.
10:燒結治具 10: Sintering fixture
11:框體 11: Frame
11A、11B、11C、11D:邊 11A, 11B, 11C, 11D: Side
12A、12B:架橋部 12A, 12B: Bridge section
13A、13B、13C、13D:中空部 13A, 13B, 13C, 13D: hollow part
14、14A、14B、14C:切口部 14, 14A, 14B, 14C: Cutout
17:第2面 17: Side 2
18:承受部 18: Acceptance Department
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