TW202216450A - Patterned thermoplastic fabric composite structure and protective gear made therefrom - Google Patents

Patterned thermoplastic fabric composite structure and protective gear made therefrom Download PDF

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TW202216450A
TW202216450A TW109135871A TW109135871A TW202216450A TW 202216450 A TW202216450 A TW 202216450A TW 109135871 A TW109135871 A TW 109135871A TW 109135871 A TW109135871 A TW 109135871A TW 202216450 A TW202216450 A TW 202216450A
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composite structure
fabric composite
thermoplastic
fabric
printing
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TWI786448B (en
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芮祥瑩
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台北智慧材料股份有限公司
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Abstract

A patterned thermoplastic fabric composite structure is provided in which a pattern layer is incorporated into a thermoplastic 3D spacer or 2D planar fabric composite structure. The pattern layer is formed by selectively printing various patterns, characters, colors, or a combination thereof on separate fabric using a printing method, such as a general dyeing technique, a printing technique, or other suitable transfer techniques. A 2D knitted mesh with high breathability can optionally be selected as the fabric main body constituting the pattern layer. The pattern layer is bonded to the thermoplastic fabric composite structure by thermal bonding, thereby forming the patterned thermoplastic fabric composite structure of the present invention. Furthermore, the patterned thermoplastic fabric composite structure of the present invention can be used to manufacture a myriad of support and immobilization products, such as protective gear or paddings for medical, sports, or personal daily use.

Description

具圖樣之熱塑性織物複合材結構及其製成之相關護具Thermoplastic fabric composite structure with pattern and related protective gear made therefrom

本發明是關於一種具圖樣之熱塑性織物複合材結構,尤其是提供一種可製成醫療、運動或個人日常用護具、護墊等支承固定物件的具圖樣之熱塑性織物複合材結構。 The present invention relates to a thermoplastic fabric composite structure with a pattern, in particular to a thermoplastic fabric composite structure with a pattern that can be made into medical, sports or personal daily protective gear, pads and other supporting and fixing objects.

一般醫療護具、運動用品中所使用具有耐衝擊性的矯形支撐物或墊體,通常是利用堅硬材質的鑄型材料為主體。然而,此等堅硬材質的鑄型材料並未能具有所需的柔軟度以及舒適性,故而無法滿足一般使用者之需求。若採用市面上具有柔軟度與舒適性的材料來形成支撐物或墊體,則無法兼顧機械強度以及耐衝擊性。再者,大部分具柔軟性的護墊支撐產品,例如由聚氨酯發泡體(polyurethane foam)等構成的墊體,通常會伴隨有缺乏透氣性的問題。另一方面,具有耐衝擊性的支撐墊體為了具有較佳的透氣性,通常會採取對硬材質墊體進行沖孔的處理作業,以便達到所需的透氣效果。然而,依沖孔密度的不同,將會導致不同的效果。譬如當孔洞密度低時,恐會造成透氣性不足的現象,然而當孔洞密度高時,又恐會產生 機械強度不足的狀況。 The impact-resistant orthopaedic supports or pads used in general medical protective gear and sports equipment are usually made of hard material casting materials as the main body. However, these hard material casting materials do not have the required softness and comfort, so they cannot meet the needs of general users. If a support or a cushion body is formed of a material with softness and comfort on the market, both mechanical strength and impact resistance cannot be taken into consideration. Furthermore, most soft pad support products, such as pads made of polyurethane foam, usually suffer from a lack of air permeability. On the other hand, in order to have better air permeability for the support pad with impact resistance, the hard material pad is usually punched in order to achieve the required air permeability. However, depending on the punching density, different effects will result. For example, when the hole density is low, it may cause insufficient air permeability, but when the hole density is high, it may cause Insufficient mechanical strength.

具形狀記憶能力的高分子聚合物材料係屬於智慧型材料的一種,具有可藉由如熱、光、電場、磁場等的外界刺激,從一變形的暫態(暫時形狀)回到其永久狀態(初始形狀)之能力的材料,故已廣泛地應用於電子電路元件、熱感應元件、生物醫學領域等範疇。有關含有該等具形狀記憶能力之高分子聚合物的熱可塑織物複合材料、結構、墊體、護具,以及熱可塑織物複合材繃帶(thermoshapable fabric composite bandage),已被相繼開發完成,例如揭露於台灣發明專利公告第I646982號-「形狀記憶立體織物複合材料」、發明公告第I648160號-「立體織物複合材料的製造方法、塗佈機以及使用該方法得到之複合材料」、新型專利公告第M577021號-「墊體複合材結構、墊體及護具」、台灣發明專利申請案第109116737號-「熱塑性薄型2D網布複合材結構及其相關產品與製造方法」,以及新型專利申請案第109206227號-「熱塑性薄型2D網布複合材結構及其相關產品」等文獻中,其皆參引合併於本文。 Polymer materials with shape memory capabilities belong to a kind of intelligent materials, which can be returned from a deformed transient state (temporary shape) to its permanent state by external stimuli such as heat, light, electric field, magnetic field, etc. (initial shape) material, it has been widely used in electronic circuit components, thermal sensing components, biomedical fields and other fields. Thermoplastic fabric composite materials, structures, pads, protective gear, and thermoplastic fabric composite bandages containing these polymers with shape memory capabilities have been successively developed. For example, disclosed In Taiwan Invention Patent Publication No. I646982 - "Shape Memory Three-dimensional Fabric Composite Material", Invention Publication No. I648160 - "Manufacturing Method of Three-dimensional Fabric Composite Material, Coating Machine and Composite Material Obtained by Using the Method", New Patent Publication No. No. M577021 - "Cushion Body Composite Structure, Cushion Body and Protective Gear", Taiwan Invention Patent Application No. 109116737 - "Thermoplastic Thin 2D Mesh Composite Material Structure and Related Products and Manufacturing Methods", and New Patent Application No. 109116737 No. 109206227 - "Thermoplastic thin 2D mesh composite structure and related products" and other documents, all of which are incorporated herein by reference.

然而,對於追求美學外觀與時尚感的現代人而言,當穿載這類織物複合材結構所製成的醫療、運動或個人日常用護具、護墊或其他支承物品時,簡單而枯燥的外表毫無美學可言。此外,現代人十分注重個人隱私,由上述織物複合材結構所製成的個人醫療護具,如護腕、護足或護頸等,都因為其簡單而無裝飾性花紋或圖樣的外表,容易曝露出穿載者患有 腕部扭傷或頸部扭傷等問題。因此,如上述病症或不適恰為穿載者原本不欲告人的隱私,由於配戴該等護具或支撐固定物件,無意間此私密症狀即表露無遺,此不啻造成穿戴者心理層面上的莫大壓力與排斥感。 However, for modern people who pursue aesthetic appearance and fashion sense, when wearing medical, sports or personal daily protective gear, pads or other support items made of such fabric composite structures, it is simple and boring. There is nothing aesthetic about the appearance. In addition, modern people attach great importance to personal privacy. Personal medical protective equipment made of the above-mentioned fabric composite structure, such as wrist guards, foot guards or neck guards, are easy to use because of their simple appearance without decorative patterns or patterns. It was revealed that the wearer suffered from Problems such as a sprained wrist or a sprained neck. Therefore, if the above-mentioned symptoms or discomfort are the wearer's privacy that the wearer does not want to tell others, because of wearing these protective gear or supporting fixed objects, the private symptoms will be revealed inadvertently, which will cause the wearer's psychological level. A lot of pressure and rejection.

鑒於上述,本發明提供一種具圖樣之熱塑性織物複合材結構,其是在原有的熱塑性織物複合材結構上,結合具有一圖樣層所形成。該圖樣層係以一般染色技術、印刷技術,或其他適宜的轉印技術等印製方法,選擇性地將各式不同的花樣、文字、色彩或其組合印製於另一織物上所形成。其中構成該圖樣層的織物主體,可以選擇性地為一具高透氣性的2D針織網布。將該圖樣層以熱黏合法結合至熱塑性織物複合材結構上,即形成本案具圖樣之熱塑性織物複合材結構。利用此一具圖樣之熱塑性織物複合材結構,可進一步製成各式提供支承固定用的醫療、運動或個人日常用護具或墊體等。 In view of the above, the present invention provides a thermoplastic fabric composite structure with a pattern, which is formed by combining with a pattern layer on the original thermoplastic fabric composite structure. The pattern layer is formed by selectively printing various patterns, characters, colors or combinations thereof on another fabric by using general dyeing technology, printing technology, or other suitable printing methods such as transfer printing technology. The fabric body constituting the pattern layer can optionally be a 2D knitted mesh fabric with high air permeability. The pattern layer is bonded to the thermoplastic fabric composite structure by thermal bonding, thus forming the thermoplastic fabric composite structure with the pattern in the present case. Using this thermoplastic fabric composite structure with a pattern, it can be further made into various medical, sports or personal daily protective gear or pads for supporting and fixing.

又根據本發明一實施態樣,具圖樣之熱塑性織物複合材結構中的熱塑性複合材結構,可以是由3D(three dimensional)立體態樣之熱塑性織物複合材結構所構成。該熱塑性3D立體複合材結構是在一透氣性3D立體織物上,塗覆有具形狀記憶能力的高分子聚合物所形成。其中該高分子聚合物可利用熱黏塗佈的方式,塗覆至該3D立體織物上。由於該高分子聚合物具有塑形溫度,即熔點(Melting temperature,即Tm 點)介於約攝氏60度至90度(60℃~90℃)之間,可在被加熱至或大於該塑形溫度時具有可重塑性,進而可藉以調整該熱塑性織物複合材結構的幾何外形,而當其冷卻至室溫後即又硬化固定。此3D立體織物主要包括有一第一外層、一第二外層,以及一位在第一外層與第二外層間形成立體空間(spacer)的間隔物,其中該間隔物係可為單絲結構,該單絲結構可由至少一股單絲所構成,其設置於該第一外層與該第二外層之間,可藉此將該第一外層與二外層交纏結合成立體織物。 According to another embodiment of the present invention, the thermoplastic composite structure in the thermoplastic fabric composite structure with the pattern can be composed of a 3D (three dimensional) three-dimensional thermoplastic fabric composite structure. The thermoplastic 3D three-dimensional composite structure is formed by coating a high molecular polymer with shape memory capability on a breathable 3D three-dimensional fabric. The high molecular polymer can be coated on the 3D three-dimensional fabric by means of thermal adhesive coating. Since the high molecular polymer has a molding temperature, namely the melting temperature (Tm) point) between about 60°C to 90°C (60°C~90°C), which can be remodeled when heated to or above the shaping temperature, thereby adjusting the thermoplastic fabric composite structure. geometry, and when it cools to room temperature it hardens back into place. The 3D three-dimensional fabric mainly includes a first outer layer, a second outer layer, and a spacer forming a three-dimensional space (spacer) between the first outer layer and the second outer layer, wherein the spacer can be a monofilament structure, the The monofilament structure can be composed of at least one monofilament, which is disposed between the first outer layer and the second outer layer, whereby the first outer layer and the two outer layers can be intertwined and combined to form a three-dimensional fabric.

於另一實施樣態中,本案具圖樣之熱塑性織物複合材結構中的熱塑性複合材結構,可以是由2D(two dimensional)平面態樣之熱塑性織物複合材結構所構成。該熱塑性2D平面織物複合材結構包括有一透氣性單片2D平面網布,以及具形狀記憶能力的高分子聚合物,且該高分子聚合物係塗覆至該透氣性單片2D平面網布上。該透氣性單片2D平面網布,包含有上、下二層,其在上層與下層間不具有間隔物形成的立體空間(spacer),但可選擇性地該上層與該下層之間增設複數單絲結構,利用單絲結構進一步將上、下層交纏結合在一起,藉以增加該透氣性單片網布的強度和韌性。同樣地利用該高分子聚合物具有的塑形溫度(即熔點Tm),使得該熱塑性2D平面複合材結構具有可重塑性。 In another embodiment, the thermoplastic fabric composite structure in the patterned thermoplastic fabric composite structure may be composed of a 2D (two dimensional) planar thermoplastic fabric composite structure. The thermoplastic 2D flat fabric composite structure includes a breathable monolithic 2D flat mesh fabric and a high molecular polymer with shape memory capability, and the high molecular polymer is coated on the breathable monolithic 2D flat mesh fabric . The breathable single-piece 2D flat mesh fabric includes upper and lower layers, and there is no spacer formed by a spacer between the upper layer and the lower layer, but optionally a plurality of additional layers can be added between the upper layer and the lower layer The monofilament structure is used to further entangle the upper and lower layers together, thereby increasing the strength and toughness of the breathable monolithic mesh. Similarly, the plastic 2D planar composite structure can be remodeled by utilizing the molding temperature (ie the melting point Tm) of the high molecular polymer.

本發明具形狀記憶能力的高分子聚合物,可選自由聚酯(polyester)、聚氨酯(polyurethane,PU)、聚醯胺 (polyamide)、聚醇(polyol)的至少一無規共聚物(random copolymers)或嵌段共聚物(block copolymers)所組成的群組中。在某些實施態樣中,此高分子聚合物(30)可包括聚己內酯(polycaprolactone,PCL)高分子聚合材料。在另一些實施態樣中,高分子聚合物的塑形Tm點可大於約60℃,以確保聚合物具有良好的機械性能。又於某些實施態樣中,高分子聚合物的Tm點可小於約90℃,故而可藉由微波爐或吹風機等裝置,利用低溫加熱的方式將聚合物的溫度提升至或大於塑形Tm點,使其得以讓使用者對熱塑性織物複合材結構進行處理,以利重新塑形並達到重覆使用之目的。在一些實施態樣中,高分子聚合物包括鏈糾纏(chain entangled)的聚合物材料,以增強其機械性能及耐衝擊性。 The high molecular polymer with shape memory capability of the present invention can be selected from polyester, polyurethane (PU), polyamide (polyamide), polyol (polyol) at least one random copolymer (random copolymers) or block copolymers (block copolymers) in the group consisting of. In some embodiments, the high molecular polymer (30) may comprise polycaprolactone (PCL) high molecular polymer material. In other embodiments, the shaping Tm point of the high molecular polymer may be greater than about 60° C. to ensure that the polymer has good mechanical properties. In some embodiments, the Tm point of the high molecular polymer can be less than about 90°C, so the temperature of the polymer can be raised to or greater than the shaping Tm point by means of a microwave oven or a hair dryer and other devices by means of low temperature heating. , which allows the user to process the thermoplastic fabric composite structure for reshaping and reuse. In some embodiments, the high molecular weight polymer includes a chain entangled polymer material to enhance its mechanical properties and impact resistance.

本案選用的圖樣層需具有一定的特性,使其得以在歷經印製處理以及加熱塑形成各式醫療、運動或個人日常用護具或墊體等支承固定物件等過程中,保有一定的鮮明度與牢固性。本案所選用作為圖樣層的織物可為2D針織網布,可利用染色技術、印刷技術或適宜的轉印技術等印製方法,將各式花樣、文字、色彩或其組合印製至該網布上。依本案所形成的圖樣層具有高透性氣、耐熱性,以及一定的色牢度(color fastness)。且該圖樣層耐熱溫度介於攝氏100度至140度之間(100℃~140℃),且加熱加熱10分鐘以上不會變形或熔化,較佳者為加熱15分鐘以上不會變形或熔化。如此當以熱黏合法將圖樣層黏合至熱塑性織物複合材結構上,並經加熱形塑成所需 醫療、運動或個人日常用護具、護墊等支承固定物件時,圖樣層不會因高溫加熱而變形或熔化。形成該圖樣層之織物的材質可為一聚酯(polyester)、一尼龍(nylon)、一棉(cotton)或其混合物。再者,該圖樣層可具有4級以上之色牢度,如此在使用或加工過程中,可承受因外部因素(如加熱、擠壓、摩擦、水洗、雨淋、曝晒、光照、唾液浸漬、水漬、汗漬等等)的作用所導致的褪色程度,使其仍保有一度的鮮明度與固著性。 The pattern layer selected in this case needs to have certain characteristics, so that it can maintain a certain degree of clarity during the process of printing and heat shaping into various medical, sports or personal daily protective gear or pads and other supporting and fixing objects. with firmness. The fabric selected as the pattern layer in this case can be a 2D knitted mesh fabric, and various patterns, characters, colors or combinations thereof can be printed on the mesh fabric by using dyeing technology, printing technology or suitable transfer technology and other printing methods. superior. The pattern layer formed according to the present case has high air permeability, heat resistance, and certain color fastness. And the heat-resistant temperature of the pattern layer is between 100°C and 140°C (100°C-140°C), and it will not deform or melt when heated for more than 10 minutes, preferably, it will not deform or melt when heated for more than 15 minutes. In this way, the pattern layer is bonded to the thermoplastic fabric composite structure by thermal bonding, and is formed into the desired shape by heating. When supporting and fixing objects such as medical, sports or personal daily protective gear, pads, etc., the pattern layer will not be deformed or melted by high temperature heating. The material of the fabric forming the pattern layer can be a polyester, a nylon, a cotton or a mixture thereof. Furthermore, the pattern layer can have a color fastness of more than 4 grades, so that during use or processing, it can withstand external factors (such as heating, extrusion, friction, water washing, rain, exposure, light, saliva immersion, The degree of fading caused by the action of water stains, sweat stains, etc.), so that it still retains a degree of clarity and fixation.

承上所述,本案所選用作為圖樣層的織物可為2D針織網布,可利用染色技術、印刷技術或適宜的轉印技術等印製方法,將各式花樣、文字、色彩或其組合印製至該網布上。舉例來說,適用於本案織物的印製方法,可包含但不限制為網版印刷、膠印、直噴印刷、冷轉印、熱轉印、熱昇華等。 Based on the above, the fabric selected as the pattern layer in this case can be a 2D knitted mesh fabric, which can be printed with various patterns, characters, colors or combinations thereof by using printing methods such as dyeing technology, printing technology or suitable transfer technology. onto the mesh. For example, suitable printing methods for the fabrics of the present case may include, but are not limited to, screen printing, offset printing, direct-jet printing, cold transfer printing, thermal transfer printing, thermal sublimation, and the like.

相較於平版、凸版、凹版印刷等,需利用平、凸、凹版的圓型滾筒印版沾取油墨後壓印在承印物上,限制了只能印刷薄膜或薄片材料(如紙張、紙板、塑膠膜、金屬片),網版印刷則不受材料的限制,更能適用於織物布料類等承印物,如本案2D針織網布織物。網版印刷的特色在於油墨種類多、套色印刷多、功能油墨多,電子印刷功能性油墨最多等。膠印亦屬廣泛使用於織物布料等的印刷方式,原理是藉由橡皮布將帶有墨色的圖像,轉移到承印物品上,其特色在於較不受布料顏色的限制。直噴印刷不同於傳統印刷,屬於一種數位印刷技術,亦適用於紡織品織物類的印製。直噴印刷具環保與節省成 本等優點,由於無需製版且較省油墨,因此能有效降低印刷過程所產生的汙染。其中UV直噴印刷在噴染同時即透過紫外線快速乾燥染料,油墨消耗量少,印好後就能直接進行其他加工,製程簡易且迅速。 Compared with lithographic, letterpress, gravure printing, etc., it is necessary to use flat, convex, and gravure circular cylinder printing plates to pick up ink and then imprint on the substrate, which restricts the printing of only film or sheet materials (such as paper, cardboard, etc.). Plastic film, metal sheet), screen printing is not limited by materials, and is more suitable for fabrics and other substrates, such as the 2D knitted mesh fabric in this case. Screen printing is characterized by a variety of ink types, color printing, functional inks, and electronic printing functional inks. Offset printing is also a printing method that is widely used in fabrics, etc. The principle is to transfer ink-colored images to the substrate through a blanket, which is characterized by being less restricted by the color of the fabric. Direct inkjet printing is different from traditional printing, it belongs to a digital printing technology, and is also suitable for the printing of textile fabrics. Direct inkjet printing tools are environmentally friendly and cost-saving This and other advantages can effectively reduce the pollution caused by the printing process because it does not require plate making and saves ink. Among them, UV direct-injection printing quickly dries the dye through ultraviolet rays at the same time of jet dyeing, and the ink consumption is small. After printing, other processing can be carried out directly. The process is simple and fast.

可使用於本案的轉印技術包含但不限制為冷轉印、熱轉印與熱昇華等。冷轉印需使用冷轉印紙,主要是利用印表機(如噴墨印表機)將圖像、文字以鏡象方式列印至冷轉印紙上,接著再轉移到承印物,如本案的2D針織網布織物。冷轉印製作速度快,無需事先高溫噴塗塗層(即轉印所需溫度較低),印製成品色彩亮麗,且可客製化等為其主要特色。熱轉印與昇華二者皆是利用高溫、加壓原理,將轉印紙上的圖樣轉印至一承印物,如本案的2D針織網布織物。熱轉印技術操作簡易,製作過程速迅,且可依個人喜好而客製化圖樣。熱轉印無需經傳統製版等繁瑣過程,且所使用的熱轉印紙取得容易,材質選擇性也多。其中熱昇華與一般熱轉印技術的差異,僅在於熱昇華多了「墨水從固態到氣態」這個步驟。熱昇華利用了加熱至特定溫度後會產生熱昇現象的熱昇華墨水,墨水染料會由固態昇華為氣態,而當溫度下降時,墨水染料又還原成固態,藉此墨水染料可以滲入該織物的表面,進而達到轉印的目的。 The transfer techniques that can be used in this case include, but are not limited to, cold transfer, thermal transfer, and thermal sublimation. Cold transfer needs to use cold transfer paper, mainly using a printer (such as an inkjet printer) to print images and text on the cold transfer paper in a mirror image, and then transfer to the substrate, as in this case. 2D knitted mesh fabric. The production speed of cold transfer printing is fast, and there is no need for high temperature spray coating in advance (that is, the temperature required for transfer printing is low), and the printed products are bright in color and can be customized as their main features. Both thermal transfer printing and sublimation use the principle of high temperature and pressure to transfer the pattern on the transfer paper to a substrate, such as the 2D knitted mesh fabric in this case. Thermal transfer technology is easy to operate, the production process is fast, and the pattern can be customized according to personal preferences. Thermal transfer does not require tedious processes such as traditional plate making, and the thermal transfer paper used is easy to obtain and has many material options. The difference between thermal sublimation and general thermal transfer printing technology is only that thermal sublimation adds the step of "ink from solid to gaseous state". Dye sublimation utilizes the sublimation ink that will produce heat rise after heating to a specific temperature. The ink dye will be sublimated from a solid state to a gaseous state, and when the temperature drops, the ink dye will be restored to a solid state, whereby the ink dye can penetrate into the fabric. surface, so as to achieve the purpose of transfer printing.

本發明另一實施態樣係有關一種醫療、運動或個人日常用護具、護墊等支承固定物件,係由上述具圖樣之熱塑 性織物複合材結構加熱形塑而成。本案該等支承固定物件,其不僅具備原有的可重塑性外,因著圖樣層所呈現出不同的視覺效果,亦同時增進所形成之護具、墊體等整體的時尚美感,進一步有效提升使用者的穿戴意願。舉例而言,該圖樣層所呈現之視覺圖樣可選擇為卡通,以吸引年齡較小的穿戴者,或者選擇比較適合中/老年紀穿著之花樣或色系。另外藉由該圖樣層所營造出之視覺美感,不僅可增加穿戴之意願,亦可減緩穿戴者心理上所承受旁人異樣眼光之壓力。 Another embodiment of the present invention relates to a supporting and fixing object such as a medical, sports or personal daily protective gear, pad, etc., which is made of the above-mentioned thermoplastic with a pattern. The fabric composite structure is heated and shaped. The supporting and fixing objects in this case not only have the original remodelability, but also enhance the overall fashion and aesthetics of the formed protective gear and cushion body due to the different visual effects presented by the pattern layer, which is further effective. Improve the user's willingness to wear. For example, the visual pattern presented by the pattern layer can be selected as a cartoon to attract younger wearers, or a pattern or color that is more suitable for middle/old age wearers. In addition, the visual aesthetics created by the pattern layer can not only increase the wearer's willingness to wear, but also relieve the wearer's psychological pressure from other people's strange eyes.

10:具圖樣之熱塑性3D立體織物複合材結構 10: Thermoplastic 3D three-dimensional fabric composite structure with pattern

11:具圖樣之熱塑性2D平面織物複合材結構 11: Thermoplastic 2D flat fabric composite structure with pattern

20:熱塑性3D立體織物複合材結構 20: Thermoplastic 3D three-dimensional fabric composite structure

20a:第一外層 20a: First outer layer

20b:第二外層 20b: Second outer layer

22:網孔 22: Mesh

24:單絲結構 24: Monofilament structure

30:圖樣層 30: Pattern Layer

31:2D針織網布 31: 2D knitted mesh

32:網孔 32: mesh

34:圖樣 34: Pattern

40:熱塑性2D平面織物複合材結構 40: Thermoplastic 2D Flat Fabric Composite Structure

40a:上層 40a: upper level

40b:下層 40b: lower level

42:網孔 42: mesh

44:單絲結構 44: Monofilament structure

50:高分子聚合物 50: high polymer

60:孔隙 60: Pore

101:手腕固定物 101: Wrist Immobilizer

102:腳踝固定物 102: Ankle Immobilizer

圖1係依照本發明一實施態樣所形成的具圖樣之熱塑性3D立體織物複合材結構的立體分解視圖。 FIG. 1 is an exploded perspective view of a thermoplastic 3D three-dimensional fabric composite structure with a pattern formed according to an embodiment of the present invention.

圖2係本發明一實施態樣所使用的熱塑性3D立體織物複合材結構的橫斷面視圖,其中位於第一與第二外層的中間部分,是由單絲結構所形成具孔隙的立體空間。 2 is a cross-sectional view of a thermoplastic 3D three-dimensional fabric composite structure used in an embodiment of the present invention, wherein the middle part of the first and second outer layers is a three-dimensional space with pores formed by the monofilament structure.

圖3係於圖2中的熱塑性3D立體織物複合材結構上,黏合一圖樣層的橫斷面視圖。 FIG. 3 is a cross-sectional view of a design layer bonded to the thermoplastic 3D three-dimensional fabric composite structure of FIG. 2 .

圖4係本發明一實施態樣所使用的的熱塑性2D平面織物複合材結構的橫斷面視圖,其中於上、下層間,具有與其呈平行狀設置的單絲結構。 4 is a cross-sectional view of a thermoplastic 2D flat fabric composite structure used in an embodiment of the present invention, wherein a monofilament structure arranged parallel to the upper and lower layers is provided.

圖5係於圖4中的熱塑性2D立體織物複合材結構上,黏合一圖樣層的橫斷面視圖。 FIG. 5 is a cross-sectional view of the thermoplastic 2D three-dimensional fabric composite structure of FIG. 4 bonded with a pattern layer.

圖6係依據本發明一實施態樣,利用本案具圖樣之 熱塑性織物複合材結構所製成的手腕固定物(手腕固定副木),該手腕固定物外層印有具美感之圖樣。 FIG. 6 is a view according to an embodiment of the present invention, using the pattern of the present case A wrist fixer (wrist fixation auxiliary wood) made of thermoplastic fabric composite material structure, the outer layer of the wrist fixation is printed with an aesthetic design.

圖7係根據本發明一實施態樣,利用本案具圖樣之熱塑性織物複合材結構所製成的腳踝固定物(腳踝固定副木),該腳踝固定物外層印有具美感之圖樣。 Fig. 7 is an ankle anchor (ankle anchor auxiliary wood) made of the thermoplastic fabric composite structure with the pattern of the present invention according to an embodiment of the present invention, and the outer layer of the ankle anchor is printed with an aesthetic pattern.

上述本發明技術內容及其特點與功效,在下文參照附圖的實施方式詳細說明中,當可清楚顯露。應瞭解,下文中所提到的方向用語,如「上」、「下」、「左」、「右」、「前」、「後」及類似用語,僅便於描述圖式中某一(些)元件或特徵與另一(些)元件或特徵間的相對關係,該等空間相關用詞非用以將某一(些)元件或特徵,特定侷限於其相對另一(些)元件或特徵之上方或下方的位置,其涵蓋包括元件或特徵的不同方向。所附圖式僅提供作為參考與說明之用,並非用來對本發明加以限制。又,如「A層(或元件)設置於B層(或元件)上」的描述,並不限定A層係直接黏覆並接觸B層的態樣,即在A與B層之間夾入其他黏附性或其他功能性層體,亦屬本發明範圍之內。所屬技術具有通常知識者在閱讀下述實施方式詳細說明後,當知在不偏離本發明範圍下可完成許多修改或添加,它們均包含在本發明範圍內。 The above-mentioned technical content of the present invention and its features and effects can be clearly revealed in the detailed description of the embodiments below with reference to the accompanying drawings. It should be understood that the directional terms mentioned below, such as "up", "down", "left", "right", "front", "rear" and similar terms, are only for the convenience of describing certain (some) in the drawings. ) the relative relationship between an element or feature and another element or feature(s), and these spatially relative terms are not intended to limit a certain element(s) or feature(s) or feature(s) specifically to it relative to the other element(s) or feature(s). position above or below, which encompass different orientations including elements or features. The accompanying drawings are provided for reference and illustration only, and are not intended to limit the present invention. In addition, as described in "A layer (or element) is disposed on B layer (or element)", it is not limited to the state that A layer is directly adhered to and contacts B layer, that is, sandwiched between A and B layers Other adhesive or other functional layers are also within the scope of the present invention. After reading the detailed description of the following embodiments, those skilled in the art will know that many modifications or additions can be made without departing from the scope of the present invention, which are all included in the scope of the present invention.

於本說明書所載的「約」、「大約」、「實質上」之用語,通常表示在一給定數值或範圍的20%內,較佳為10%內,更佳者為5% 內,或3%以內,或2%以內,或1%以內,或0.5%以內。在此給定的數值為大約的數值,亦即在沒有特定說明的情況下,可隱含「約」、「大約」、「實質上」之含義。 The terms "about", "approximately" and "substantially" in this specification usually mean within 20% of a given value or range, preferably within 10%, more preferably within 5% within 3%, or within 2%, or within 1%, or within 0.5%. The numerical values given herein are approximate numerical values, that is, the meanings of "about", "approximately" and "substantially" may be implied unless otherwise specified.

請參照圖1,其係根據本發明一實施態樣所形成的具圖樣之熱塑性3D立體織物複合材結構10的立體分解圖。本案具圖樣之熱塑性3D立體織物複合材結構10如圖所示,主要包含一圖樣層30以及一熱塑性3D-立體織物複合材結構20。其中該圖樣層30可利用熱黏合法結合至該熱塑性3D立體織物複合材結構20上。其中該圖樣層30係利用一般染色技術、印刷技術,或其他適宜的轉印技術等印製方法,選擇性地將各式不同的花樣、文字、色彩或其組合所構成的圖樣34,印製於另一織物(即第二織物)上而形成。其中該圖樣層30的織物主體,可以是具複數網孔32的高透氣性2D針織網布31。 Please refer to FIG. 1 , which is an exploded perspective view of a thermoplastic 3D three-dimensional fabric composite structure 10 with a pattern formed according to an embodiment of the present invention. As shown in the figure, the thermoplastic 3D three-dimensional fabric composite material structure 10 with a pattern mainly includes a pattern layer 30 and a thermoplastic 3D-three-dimensional fabric composite material structure 20 . The pattern layer 30 can be bonded to the thermoplastic 3D three-dimensional fabric composite structure 20 by thermal bonding. The pattern layer 30 is to selectively print patterns 34 composed of various patterns, characters, colors or combinations thereof by using general dyeing technology, printing technology, or other suitable printing methods such as transfer printing technology. formed on another fabric (ie, the second fabric). The fabric body of the pattern layer 30 may be a highly breathable 2D knitted mesh fabric 31 with a plurality of mesh holes 32 .

適用於本案的印刷技術,可選擇性地為一網版印刷、膠印與直噴印刷,其中直噴印刷可為一UV直噴印刷。另外,可使用於本發明的轉印技術則包含但不限制為冷轉印、熱轉印與熱昇華等。利用適宜的印刷技術與轉印技術特,將圖樣34印製於本案的2D針織網布31上。 The printing technology suitable for this case can be selected as a screen printing, offset printing and direct-injection printing, wherein the direct-injection printing can be a UV direct-injection printing. In addition, the transfer techniques that can be used in the present invention include, but are not limited to, cold transfer, thermal transfer, and thermal sublimation. Using suitable printing technology and transfer technology, the pattern 34 is printed on the 2D knitted mesh cloth 31 of this case.

本案選用的圖樣層30需具有一定的特性,使其得以在歷經印製處理以及加熱塑形成各式醫療、運動或個人日常用護具或支承固定物件等過程中,仍維持一定的鮮明度與牢固性。可利用染色技術、印刷技術或適宜的轉印技術等印製方 法,將圖樣34例如各式花樣、文字、色彩或其組合等,印製至該2D針織網布31上。使用於本案圖樣層30中的織物,係由具複數網孔32的2D針織網布31所構成,故具有高度的透性氣。 The pattern layer 30 selected in this case needs to have certain characteristics, so that it can still maintain a certain degree of clarity and clarity during the process of printing and thermal shaping into various medical, sports or personal daily protective gear or supporting and fixing objects. firmness. Printing methods such as dyeing technology, printing technology or suitable transfer technology can be used. In the method, patterns 34 such as various patterns, characters, colors or combinations thereof are printed on the 2D knitted mesh cloth 31 . The fabric used in the pattern layer 30 of this design is composed of a 2D knitted mesh 31 with a plurality of meshes 32, so it has a high degree of air permeability.

圖樣層30亦具有所需的耐熱性,其耐熱溫度約介於攝氏100度至140度之間(100℃~140℃),且加熱10分鐘以上不至變形或熔化,較佳者加熱15分鐘以上不會熔化。如此當以熱黏合法將圖樣層30黏合至熱塑性3D立體織物複合材結構上,並經加熱形塑成所需護具、護墊等支承固定物件時,圖樣層30不會因高溫加熱而變形或熔損。 The pattern layer 30 also has the required heat resistance, and its heat resistance temperature is between about 100°C to 140°C (100°C to 140°C), and is heated for more than 10 minutes without deformation or melting, preferably for 15 minutes. The above will not melt. In this way, when the design layer 30 is adhered to the thermoplastic 3D three-dimensional fabric composite structure by thermal bonding, and heated to form the required supporting and fixing objects such as protective equipment and pads, the design layer 30 will not be deformed due to high temperature heating. or melt loss.

再者,形成該圖樣層30之織物的材質,可以是一聚酯(polyester)、一尼龍(nylon)、一棉(cotton)或其混合物。再者,該圖樣層30可具有4級以上之色牢度,如此在穿戴者使用或加工過程中,可承受因外部因素(如加熱、擠壓、摩擦、水洗、雨淋、曝晒、光照、唾液浸漬、水漬、汗漬等等)的作用,導致印製其上的圖樣34產生褪色或脫落等現象,故仍得以保持原有的鮮明度與完整外觀。 Furthermore, the material of the fabric forming the pattern layer 30 can be a polyester, a nylon, a cotton or a mixture thereof. Furthermore, the pattern layer 30 can have a color fastness of more than 4 grades, so that the wearer can withstand external factors (such as heating, extrusion, friction, washing, rain, exposure, light, The effect of saliva dipping, water stains, sweat stains, etc.) causes the pattern 34 printed on it to fade or fall off, so the original vividness and complete appearance can still be maintained.

配合參閱圖2,依據本發明一實施態樣,所使用的織物複合材結構可為熱塑性3D立體織物複合材結構20。如圖面所示,該熱塑性3D立體織物複合材結構20,其是在一具複數網孔22的透氣性3D立體織物(即第一織物)上,塗覆有一具形狀記憶能力的高分子聚合物50而形成。其中該高分子聚合物50可利用熱黏塗佈的方式,塗覆至該3D立體織物上。該3D立體 織物包括有第一外層20a、第二外層20b,以及一位在該第一、第二層(即X、Y平面)間,且與該X、Y平面垂直之Z軸方向上不等高度的紗線,形成3D立體空間(spacer)及機械支撐的間隔物24。又,該間隔物24可為至少由一股單絲所構成的單絲結構24,設置於該第一外層20a與該第二外層20b之間,其間並形成有複數孔隙60。可藉由該單絲結構24,將該第一外層20a與二外層20b交纏結合成該3D立體織物。 Referring to FIG. 2 , according to an embodiment of the present invention, the used fabric composite structure can be a thermoplastic 3D three-dimensional fabric composite structure 20 . As shown in the figure, the thermoplastic 3D three-dimensional fabric composite structure 20 is coated with a high molecular polymer with shape memory ability on a breathable 3D three-dimensional fabric (ie, the first fabric) with a plurality of meshes 22 50 is formed. The high molecular polymer 50 can be coated on the 3D three-dimensional fabric by means of thermal adhesive coating. The 3D Stereoscopic The fabric includes a first outer layer 20a, a second outer layer 20b, and a position between the first and second layers (that is, the X, Y planes), and the height of the Z axis perpendicular to the X, Y planes is unequal. The yarns form 3D spacers and spacers 24 for mechanical support. In addition, the spacer 24 can be a monofilament structure 24 composed of at least one monofilament, and is disposed between the first outer layer 20a and the second outer layer 20b with a plurality of pores 60 formed therebetween. The 3D three-dimensional fabric can be formed by intertwining the first outer layer 20a and the two outer layers 20b through the monofilament structure 24 .

參閱圖3,其是於圖2中的熱塑性3D立體織物複合材結構20上,結合設置有一圖樣層30之剖面示意圖。可利用熱黏合法,將圖樣層30結合至該熱塑性3D立體織物複合材結構20上,形成本發明具圖樣之熱塑性3D立體織物複合材結構10。 Referring to FIG. 3 , it is a schematic cross-sectional view of the thermoplastic 3D three-dimensional fabric composite material structure 20 in FIG. 2 , combined with a pattern layer 30 . The design layer 30 can be bonded to the thermoplastic 3D three-dimensional fabric composite structure 20 by thermal bonding to form the thermoplastic 3D three-dimensional fabric composite structure 10 with a pattern of the present invention.

又,參閱圖4,依據本發明另一實施態樣,本案所使用的織物複合材結構可為熱塑性2D平面織物複合材結構40。如圖所示,該熱塑性2D平面織物複合材結構40是在一透氣性2D平面織物(即第一織物)上,塗覆有一具形狀記憶能力的高分子聚合物50所形成。其中該高分子聚合物50可利用熱黏塗佈的方式,塗覆至該2D平面織物上。該透氣性2D平面織物,包含有上層40a、下層40b,以及複數個網孔42,該上層40a與該下層40b相互結合而構成2D平面織物(如單片網布),而該等複數網孔42係貫通該上層40a及該下層40b,以達透氣之效用。另外可選擇性地於該上層40a與該下層40b之間,增設複數單絲結構44,該單絲結構44是由至少一股單絲所構成,藉此進一步 將上、下層40a、40b交纏結合在一起,以便增加該透氣性單片網布之強度和韌性,進而有效提升熱塑性2D平面織物複合材結構40之機械性質。另外,於其他實施例中,亦可選擇不增設該單絲結構44。 Also, referring to FIG. 4 , according to another embodiment of the present invention, the fabric composite structure used in this case can be a thermoplastic 2D planar fabric composite structure 40 . As shown in the figure, the thermoplastic 2D flat fabric composite structure 40 is formed by coating a high molecular polymer 50 with shape memory capability on a breathable 2D flat fabric (ie, the first fabric). The high molecular polymer 50 can be coated on the 2D flat fabric by means of thermal adhesive coating. The breathable 2D flat fabric includes an upper layer 40a, a lower layer 40b, and a plurality of mesh holes 42. The upper layer 40a and the lower layer 40b are combined with each other to form a 2D flat fabric (such as a single piece of mesh cloth), and the plurality of mesh holes 42 runs through the upper layer 40a and the lower layer 40b to achieve the effect of ventilation. In addition, a plurality of monofilament structures 44 can be optionally added between the upper layer 40a and the lower layer 40b, and the monofilament structures 44 are composed of at least one monofilament, thereby further The upper and lower layers 40a, 40b are intertwined and bonded together to increase the strength and toughness of the breathable monolithic mesh, thereby effectively improving the mechanical properties of the thermoplastic 2D flat fabric composite structure 40. In addition, in other embodiments, the monofilament structure 44 can also be chosen not to be added.

圖5則為圖4中的熱塑性2D平面織物複合材結構40,結合有一圖樣層30的剖示圖。可利用熱黏合法將圖樣層30結合至熱塑性2D平面織物複合材結構40上,形成本發明具圖樣之熱塑性2D平面織物複合材結構11。 FIG. 5 is a cross-sectional view of the thermoplastic 2D planar fabric composite structure 40 in FIG. 4 , incorporating a pattern layer 30 . The pattern layer 30 can be bonded to the thermoplastic 2D flat fabric composite structure 40 by thermal bonding to form the patterned thermoplastic 2D flat fabric composite structure 11 of the present invention.

本案所採用具形狀記憶能力的高分子聚合物50屬於智慧型材料的一種,具有可藉由如熱、光、電場、磁場等的外界刺激,從一變形的暫態(暫時形狀)回到其永久狀態(初始形狀)之能力的材料,故已廣泛地應用於電子電路元件、熱感應元件、生物醫學領域等範疇。由於高分子聚合物50具有塑形溫度(即熔點Tm),故可使塗覆有該高分子聚合物50的織物複合材結構,其被加熱至或大於該塑形溫度時具有可重塑性,可藉此調整該熱塑性織物複合材結構之幾何外形,而當冷卻至室溫後,隨即又硬化固定。 The polymer 50 with shape memory used in this case belongs to a kind of intelligent material, which can return from a deformed transient state (temporary shape) to its original state by external stimuli such as heat, light, electric field, magnetic field, etc. Materials with the ability of permanent state (initial shape) have been widely used in electronic circuit components, thermal sensing components, biomedical fields and other fields. Since the high-molecular polymer 50 has a shaping temperature (ie, melting point Tm), the fabric composite structure coated with the high-molecular polymer 50 can be remodeled when heated to or above the shaping temperature , the geometric shape of the thermoplastic fabric composite structure can be adjusted, and when cooled to room temperature, it is then hardened and fixed.

該高分子聚合物50係可選自由聚酯(polyester)、聚氨酯(polyurethane,PU)、聚醯胺(polyamide)、聚醇(polyol)的至少一無規共聚物(random copolymers)或嵌段共聚物(block copolymers)所組成的群組中,其塑形溫度(Tm點)可介於約攝氏60度至80度(60℃~80℃)之間。如此,使用者便可利 用居家中可輕易取得之加熱工具(例如:吹風機或蒸氣式熨斗等),依其需求條件對內含有該高分子聚合物的護具、護墊等支承固定物件作局部加熱塑形,令該護具、護墊等支承固定物件更貼合於穿戴者之身形或欲支撐固定之部位,如此不僅可確實發揮其功效以減緩或矯正穿戴者身體各部分的病症,亦可進一步提升該護具、護墊等支承固定物件的穩固支撐力。 The high molecular polymer 50 can be selected from at least one random copolymer or block copolymer of polyester, polyurethane (PU), polyamide and polyol. In the group composed of block copolymers, the molding temperature (Tm point) can be between about 60°C to 80°C (60°C-80°C). In this way, users can benefit from Use heating tools (such as hair dryers or steam irons, etc.) that can be easily obtained at home to locally heat and shape supporting and fixing objects such as protective gear and pads containing the high-molecular polymer according to their requirements, so that the Supporting and fixing objects such as protective gear and pads are more suitable for the body shape of the wearer or the part to be supported and fixed, so that it can not only exert its effect to alleviate or correct the diseases of various parts of the wearer's body, but also further improve the protection of the wearer. The stable supporting force of supporting and fixing objects such as tools and pads.

利用本發明具圖樣之熱塑性織物複合材結構10、11,可製成醫療、運動或日常用的各式護具、護墊等支承固定物件。例如圖6所示者為一個人護理用的手腕固定物101(手腕固定副木),該手腕固定物101外側具有富含美感之圖樣34。又如圖7中顯示者則為另一腳踝固定物102(腳踝固定副木),該腳踝固定物102外側亦具有另一富含時尚美感之圖樣34。應理解的是,利用本發明具圖樣之熱塑性織物複合材結構10、11所製成的護具或護墊等支承固定物件,並不限於手腕固定副木或腳踝固定副木,其可為任何支撐固定用副木或固定繃帶或支撐背架等支承固定物件,本案僅繪示出上述二種護具做為代表性示範例。 Using the thermoplastic fabric composite structures 10 and 11 with patterns of the present invention, it can be made into various supporting and fixing objects such as protective gears, pads, etc. for medical treatment, sports or daily use. For example, what is shown in FIG. 6 is a wrist fixer 101 for personal care (wrist fixation auxiliary wood), and the outer side of the wrist fixer 101 has a pattern 34 rich in aesthetics. As shown in FIG. 7 , it is another ankle anchor 102 (ankle anchor auxiliary wood), and the outer side of the ankle anchor 102 also has another pattern 34 rich in fashion and beauty. It should be understood that the support and fixation objects such as protective gear or pads made by using the thermoplastic fabric composite structures 10 and 11 with patterns of the present invention are not limited to wrist fixation auxiliary wood or ankle fixation auxiliary wood, which can be any Supporting and fixing auxiliary wood or fixing bandage or supporting back frame and other supporting and fixing objects, this case only shows the above two kinds of protective gear as representative examples.

本發明揭露的實施例及其優點承如上述,惟應瞭解的是,任何所屬技術領域中具有通常知識者,在不脫離本揭露之精神與範圍,當可對本發明做進一步之變更、替換與修飾。又,本發明所揭示之具體實施例,包含複數個共同描述且彼此間可協同提供一系列效益之特色。除權利請求項另有聲明 外,本發明並不只侷限在那些包含所有該等特色、或提供全部所述效益的實施例。再者,以單數來指稱所請求元件的任何參照,如「一」、「此」、或「該」,亦不應視為將此元件限制為單數。以上內文所述者,僅為揭示本發明之具體實施例,並非用來限定本發明之實施範圍,即凡依本發明申請專利範圍所作之均等變化與修飾者,皆為本發明專利範圍所涵蓋。 The embodiments disclosed in the present invention and their advantages are as described above, but it should be understood that any person with ordinary knowledge in the technical field can make further changes, substitutions and alterations to the present invention without departing from the spirit and scope of the present disclosure. retouch. Furthermore, the embodiments disclosed in the present invention include a plurality of features that are commonly described and that cooperate with each other to provide a series of benefits. Unless otherwise stated in the claims Furthermore, the present invention is not limited to only those embodiments that incorporate all of these features, or provide all of the described benefits. Furthermore, any reference to a claimed element in the singular, such as "a," "the," or "the," should not be construed as limiting the element to the singular. The above descriptions are only intended to disclose the specific embodiments of the present invention, and are not intended to limit the scope of implementation of the present invention. covered.

10:具圖樣之熱塑性3D立體織物複合材結構 10: Thermoplastic 3D three-dimensional fabric composite structure with pattern

20:熱塑性3D立體織物複合材結構 20: Thermoplastic 3D three-dimensional fabric composite structure

22:網孔 22: Mesh

30:圖樣層 30: Pattern Layer

31:2D針織網布 31: 2D knitted mesh

32:網孔 32: mesh

34:圖樣 34: Pattern

Claims (13)

一種具圖樣之熱塑性織物複合材結構,其包括: A patterned thermoplastic fabric composite structure comprising: 一熱塑性織物複合材結構,其是在第一織物上塗覆一具形狀記憶能力的高分子聚合物所形成;以及 a thermoplastic fabric composite structure, which is formed by coating a high molecular polymer with shape memory capability on the first fabric; and 一圖樣層,係結合至該熱塑性織物複合材料上,其是在第二織物上印製有一圖樣而形成。 A design layer, bonded to the thermoplastic fabric composite material, is formed by printing a design on the second fabric. 如請求項1所述之熱塑性織物複合材結構,其中該熱塑性織物複合材結構中的該第一織物可為2D平面網布或3D立體織物,而塗覆該高分子聚合物的方法可為一熱黏塗佈法。 The thermoplastic fabric composite structure according to claim 1, wherein the first fabric in the thermoplastic fabric composite structure can be a 2D flat mesh fabric or a 3D three-dimensional fabric, and the method of coating the high molecular polymer can be a Hot stick coating. 如請求項1所述之熱塑性織物複合材結構,其中該圖樣層是以一熱黏合法結合至該熱塑性織物複合材料上。 The thermoplastic fabric composite structure of claim 1, wherein the pattern layer is bonded to the thermoplastic fabric composite by a thermal bonding method. 如請求項1所述之熱塑性織物複合材結構,其中該圖樣層係藉由一染色技術、一印刷技術,或一轉印技術等之印製方法,將各式不同的花樣、文字、色彩或其組合等所構成的圖樣,印製於該第二織物上所形成。 The thermoplastic fabric composite material structure as claimed in claim 1, wherein the pattern layer is printed by a dyeing technique, a printing technique, or a transfer technique, etc., to make various patterns, characters, colors or The pattern formed by its combination and the like is formed by printing on the second fabric. 如請求項4所述之熱塑性織物複合材結構,其中該印刷技術可包含網版印刷、膠印與直噴印刷。 The thermoplastic fabric composite structure of claim 4, wherein the printing techniques may include screen printing, offset printing, and direct-jet printing. 如請求項4所述之熱塑性織物複合材結構,其中該轉印技術可包含冷轉印、熱轉印與熱昇華。 The thermoplastic fabric composite structure of claim 4, wherein the transfer technique can include cold transfer, thermal transfer and thermal sublimation. 如請求項5所述之熱塑性織物複合材結構,其中該直噴印刷為UV直噴印刷。 The thermoplastic fabric composite structure of claim 5, wherein the direct jet printing is UV direct jet printing. 如請求項1所述之熱塑性織物複合材結構,其中構成該圖樣層的該第二織物,其材質可選擇一聚酯 (polyester)、一尼龍(nylon)、一棉(cotton)及其混合物之其中一種。 The thermoplastic fabric composite structure as claimed in claim 1, wherein the material of the second fabric constituting the pattern layer can be selected from a polyester (polyester), a nylon (nylon), a cotton (cotton) and one of the mixtures thereof. 如請求項1或4或8所述之熱塑性織物複合材結構,其中該第二織物可為一2D針織網布。 The thermoplastic fabric composite structure of claim 1 or 4 or 8, wherein the second fabric can be a 2D knitted mesh. 如請求項9所述之熱塑性織物複合材結構,其中該圖樣層的耐熱溫度約介於攝氏100℃~140℃之間。 The thermoplastic fabric composite material structure as claimed in claim 9, wherein the heat-resistant temperature of the pattern layer is about 100°C to 140°C. 如請求項9所述之熱塑性織物複合材結構,其中該圖樣層具有一4級以上之色牢度。 The thermoplastic fabric composite structure as claimed in claim 9, wherein the pattern layer has a color fastness of 4 or higher. 一種由請求項1所述之具圖樣之熱塑性織物複合材結構所製成的支承固定物件,該支承固定物件可為適用於醫療、運動或日常生活中的各式護具或護墊。 A supporting and fixing object made of the thermoplastic fabric composite structure with a pattern as claimed in claim 1, the supporting and fixing object can be various protective gears or pads suitable for medical treatment, sports or daily life. 如請求項12所述之支承固定物件,其可為個人護理用的支承固定物件,如四肢固定物、頸部固定物或固定繃帶等。 The support and fixation object according to claim 12, which can be a support and fixation object for personal care, such as a limb fixation, a neck fixation, or a fixation bandage.
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