TW202202458A - Nozzle for deformed cross-section glass fiber, and manufacturing method of deformed cross-section glass fiber - Google Patents

Nozzle for deformed cross-section glass fiber, and manufacturing method of deformed cross-section glass fiber Download PDF

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TW202202458A
TW202202458A TW110121348A TW110121348A TW202202458A TW 202202458 A TW202202458 A TW 202202458A TW 110121348 A TW110121348 A TW 110121348A TW 110121348 A TW110121348 A TW 110121348A TW 202202458 A TW202202458 A TW 202202458A
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nozzle
section
glass fiber
long
wall surface
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TW110121348A
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TWI859452B (en
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Yuzuru Matsuura
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日商日本電氣硝子股份有限公司
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/08Bushings, e.g. construction, bushing reinforcement means; Spinnerettes; Nozzles; Nozzle plates
    • C03B37/083Nozzles; Bushing nozzle plates
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/253Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor

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  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacture, Treatment Of Glass Fibers (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

This nozzle 8 for deformed cross-section glass fiber, for manufacturing deformed cross-section glass fiber 2f from molten glass 2 flowing out of a nozzle hole 6, comprises the flat nozzle hole 6, which has an inlet 6a and an outlet 6b for the molten glass 2, and wall sections surrounding the nozzle hole 6, which comprise a pair of short wall sections 12 opposite in the long-diameter direction of the nozzle hole 6 and a pair of long wall sections 12 opposite in the short-diameter direction, wherein, viewing the nozzle hole 6 from the outlet 6b side, the average width of the bottom wall surface 12b of the short wall sections 12 is greater than the average width of the bottom wall surface 11b of the long wall sections 11.

Description

異形剖面玻璃纖維用噴嘴、及異形剖面玻璃纖維之製造方法Nozzle for special-shaped section glass fiber, and manufacturing method of special-shaped section glass fiber

本發明係關於用於從熔融玻璃製造剖面形狀呈扁平的異形剖面玻璃纖維之噴嘴、以及使用該噴嘴的異形剖面玻璃纖維之製造方法。The present invention relates to a nozzle for producing a flat cross-section glass fiber from molten glass, and a method for producing the special-shaped glass fiber using the nozzle.

剖面形狀呈扁平的異形剖面玻璃纖維是作為玻璃纖維的一種而被製造(參照專利文獻1)。當異形剖面玻璃纖維與樹脂混煉而複合化的情況,可實現良好的補強效果,因此是採用其作為纖維強化塑膠(FRP)用的纖維等而被利用在各種領域。A cross-sectional glass fiber with a flat cross-section is produced as a type of glass fiber (refer to Patent Document 1). When the profiled cross-section glass fiber is kneaded and compounded with resin, a good reinforcing effect can be achieved, so it is used as fiber for fiber reinforced plastics (FRP), etc., and is used in various fields.

在製造異形剖面玻璃纖維時,例如從用於讓熔融玻璃流通之給料器朝漏板(bushing)供給熔融玻璃,從漏板所具備之多數個噴嘴分別將熔融玻璃拉出並冷卻。設置在該噴嘴之噴嘴孔的形狀,一般是成為扁平的孔狀(橢圓形、扁圓形等)。 [先前技術文獻] [專利文獻]When producing a profiled glass fiber, for example, molten glass is supplied to a bushing from a feeder for flowing molten glass, and the molten glass is drawn out from a plurality of nozzles provided in the bushing and cooled. The shape of the nozzle hole provided in the nozzle is generally a flat hole shape (oval, oblate, etc.). [Prior Art Literature] [Patent Literature]

[專利文獻1] 國際公開第2017/221471號[Patent Document 1] International Publication No. 2017/221471

[發明所欲解決之問題][Problems to be Solved by Invention]

在製造異形剖面玻璃纖維時,存在下述般有待解決的問題。亦即,從噴嘴孔流出的熔融玻璃,在表面張力的作用下會以表面積變小的方式變形,因此要成形高扁平率的異形剖面玻璃纖維是困難的。In the manufacture of profiled-section glass fibers, there are the following problems to be solved. That is, the molten glass flowing out of the nozzle hole is deformed so that the surface area becomes smaller due to the surface tension, so it is difficult to form a glass fiber with a high oblateness and an irregular cross-section.

有鑑於上述事情之本發明所欲解決之技術上的問題在於,在製造異形剖面玻璃纖維時,使高扁平率的異形剖面玻璃纖維之製造成為可能。 [解決問題之技術手段]The technical problem to be solved by the present invention in view of the above is to make it possible to manufacture a special-shaped glass fiber with a high aspect ratio when producing a special-shaped glass fiber. [Technical means to solve problems]

用以解決上述問題之本發明的異形剖面玻璃纖維用噴嘴,係設置具有熔融玻璃的流入口及流出口且具有扁平的剖面之噴嘴孔,噴嘴孔係包含:在噴嘴孔之扁平的剖面之長徑方向相對向之一對的短壁部、及在噴嘴孔之扁平的剖面之短徑方向相對向之一對的長壁部,該異形剖面玻璃纖維用噴嘴是用於從自噴嘴孔流出的熔融玻璃製造異形剖面玻璃纖維,短壁部之底壁面的平均寬度比長壁部之底壁面的平均寬度更寬。In order to solve the above-mentioned problems, the nozzle for glass fiber with irregular cross section of the present invention is provided with a nozzle hole having an inflow port and an outflow port of molten glass and having a flat cross section, and the nozzle hole includes: the length of the flat cross section of the nozzle hole A pair of short wall portions facing each other in the radial direction, and a pair of long wall portions facing each other in the short diameter direction of the flat cross section of the nozzle hole. Glass is made of profiled-section glass fiber, and the average width of the bottom wall of the short wall portion is wider than the average width of the bottom wall of the long wall portion.

在製造異形剖面玻璃纖維時,除了噴嘴孔的內周面(包含短壁部及長壁部的內壁面)以外,短壁部及長壁部之底壁面也成為被熔融玻璃潤濕的狀態。這時,短壁部及長壁部之底壁面分別可將熔融玻璃朝沿著底壁面的方向拉伸,底壁面的寬度(沿著短壁部的厚度方向之寬度、或沿著長壁部的厚度方向之寬度)越寬則越容易將熔融玻璃拉伸。 而且,為了將所製造的異形剖面玻璃纖維之扁平率提高,比起噴嘴孔的短徑方向,沿著噴嘴孔的長徑方向將熔融玻璃拉伸更有利。因此,像本構成這樣,使短壁部之底壁面的平均寬度比長壁部之底壁面的平均寬度更寬,可將熔融玻璃沿著噴嘴孔之扁平的剖面之長徑方向有效地拉伸。結果,能將異形剖面玻璃纖維以高扁平率成形。When producing glass fibers with irregular cross-sections, in addition to the inner peripheral surface of the nozzle hole (including the inner wall surfaces of the short and long walls), the bottom walls of the short and long walls are also wetted with molten glass. At this time, the bottom wall surfaces of the short wall portion and the long wall portion can stretch the molten glass in the direction along the bottom wall surface, respectively, and the width of the bottom wall surface (the width along the thickness direction of the short wall portion, or the width along the thickness direction of the long wall portion) The wider the width), the easier it is to stretch the molten glass. Furthermore, in order to improve the oblateness of the produced irregular-section glass fiber, it is more advantageous to stretch the molten glass along the long diameter direction of the nozzle hole rather than the short diameter direction of the nozzle hole. Therefore, in this configuration, the average width of the bottom wall surface of the short wall portion is made wider than the average width of the bottom wall surface of the long wall portion, and the molten glass can be effectively stretched along the longitudinal direction of the flat cross section of the nozzle hole. As a result, the profiled glass fiber can be formed with a high aspect ratio.

本發明的異形剖面玻璃纖維用噴嘴較佳為,短壁部之底壁面的平均寬度是長壁部之底壁面的平均寬度之1.5倍以上。It is preferable that the average width of the bottom wall surface of the short wall part of the nozzle for glass fibers with a special-shaped cross section of the present invention is 1.5 times or more the average width of the bottom wall surface of the long wall part.

依據此構成,能有效顯現出將熔融玻璃沿著噴嘴孔之扁平的剖面之長徑方向拉伸的作用,在將異形剖面玻璃纖維以高扁平率成形方面變得更有利。According to this configuration, the effect of stretching the molten glass in the longitudinal direction of the flat cross-section of the nozzle hole can be effectively exhibited, and it is more advantageous in forming the glass fiber with a special-shaped cross-section at a high aspect ratio.

本發明的異形剖面玻璃纖維用噴嘴較佳為,短壁部之底壁面的面積比長壁部之底壁面的面積更大。It is preferable that the area of the bottom wall surface of a short wall part is larger than the area of the bottom wall surface of a long wall part in the nozzle for glass fibers with a special-shaped cross-section of this invention.

依據此構成,能有效顯現出將熔融玻璃沿著噴嘴孔之扁平的剖面之長徑方向拉伸的作用,在將異形剖面玻璃纖維以高扁平率成形方面變得更有利。According to this configuration, the effect of stretching the molten glass in the longitudinal direction of the flat cross-section of the nozzle hole can be effectively exhibited, and it is more advantageous in forming the glass fiber with a special-shaped cross-section at a high aspect ratio.

再者,用以解決上述問題之本發明的異形剖面玻璃纖維之製造方法,係使用設置有噴嘴孔之異形剖面玻璃纖維用噴嘴而從自噴嘴孔流出的熔融玻璃製造異形剖面玻璃纖維之方法,噴嘴孔,係具有熔融玻璃的流入口及流出口且具有扁平的剖面,並包含:在噴嘴孔之扁平的剖面之長徑方向相對向之一對的短壁部、及在噴嘴孔之扁平的剖面之短徑方向相對向之一對的長壁部,短壁部之底壁面的平均寬度比長壁部之底壁面的平均寬度更寬。Furthermore, the method for producing a special-shaped glass fiber of the present invention for solving the above-mentioned problems is a method for producing a special-shaped glass fiber from molten glass flowing out from the nozzle hole using a nozzle for the special-shaped glass fiber provided with a nozzle hole, The nozzle hole has an inflow port and an outflow port of the molten glass and has a flat cross section, and includes: a pair of short walls facing each other in the long-diameter direction of the flat cross section of the nozzle hole, and a flat part of the nozzle hole. The short diameter direction of the cross section faces a pair of long wall parts, and the average width of the bottom wall surface of the short wall part is wider than the average width of the bottom wall surface of the long wall part.

依據本方法,可獲得與針對上述本發明之異形剖面玻璃纖維用噴嘴所敘述的作用及效果相同之作用及效果。 [發明之效果]According to this method, it is possible to obtain the same functions and effects as those described above with respect to the nozzle for glass fibers with a special-shaped cross section of the present invention. [Effect of invention]

依據本發明,在製造異形剖面玻璃纖維時,使高扁平率纖維的製造成為可能。According to the present invention, it is possible to manufacture fibers with high oblateness when manufacturing profiled glass fibers.

以下,針對本發明的實施形態之異形剖面玻璃纖維用噴嘴、及異形剖面玻璃纖維之製造方法,參照所附的圖式做說明。 本說明書中,用「~」表示的數值範圍,係以「~」的前後所記載的數值分別作為最小值及最大值所包含的範圍。Hereinafter, the nozzle for irregular-section glass fibers and the manufacturing method of the irregular-section glass fibers according to the embodiment of the present invention will be described with reference to the attached drawings. In this specification, the numerical range indicated by "~" means that the numerical value described before and after the "~" is the range included in the minimum value and the maximum value, respectively.

如圖1所示般,異形剖面玻璃纖維係藉由製造裝置1所製造。製造裝置1係具備:讓由圖示省略的熔爐所生成之熔融玻璃2流通之給料器3、配置在比給料器3更下方之漏板4、以及用於連接給料器3和漏板4之管子5。熔融玻璃2是從給料器3透過管子5而往漏板4供給。然後,熔融玻璃2從漏板4的噴嘴孔6流出。熔融玻璃2被冷卻而成為異形剖面玻璃纖維2f(以下稱為「玻璃纖維2f」)。As shown in FIG. 1 , the glass fiber with irregular cross section is manufactured by the manufacturing apparatus 1 . The manufacturing apparatus 1 is provided with: the feeder 3 which circulates the molten glass 2 produced|generated by the melting furnace which is not shown in the figure, the bushing plate 4 arrange|positioned below the feeder 3, and the connection for connecting the feeder 3 and the bushing plate 4. Tube 5. The molten glass 2 is supplied from the feeder 3 to the bushing 4 through the pipe 5 . Then, the molten glass 2 flows out from the nozzle holes 6 of the bushing plate 4 . The molten glass 2 is cooled and becomes 2 f of glass fiber (henceforth "glass fiber 2f") with a special-shaped cross section.

在本實施形態,熔融玻璃2是由E玻璃所構成。然而,並不限定於此,熔融玻璃2亦可由D玻璃、S玻璃、AR玻璃、C玻璃等的其他玻璃所構成。In the present embodiment, the molten glass 2 is made of E glass. However, it is not limited to this, The molten glass 2 may be comprised with other glass, such as D glass, S glass, AR glass, and C glass.

給料器3是與圖示省略之玻璃熔爐連接。給料器3可讓在玻璃熔爐連續地生成之熔融玻璃2流通。在給料器3的內部形成有熔融玻璃2的液面2a。The feeder 3 is connected to a glass melting furnace (not shown). The feeder 3 circulates the molten glass 2 continuously produced in the glass melting furnace. The liquid level 2a of the molten glass 2 is formed in the feeder 3 inside.

漏板4是在底部具備底板7。底板7係具備:複數個異形剖面玻璃纖維用噴嘴8(以下稱為「噴嘴8」)、及配置在該等噴嘴8的附近之冷卻管9。複數個噴嘴8具有彼此相同的構成。雖詳如後述,設置在各噴嘴8之噴嘴孔6形成為扁平。The bushing 4 is provided with a bottom plate 7 at the bottom. The bottom plate 7 is provided with a plurality of nozzles 8 for glass fibers with irregular cross-sections (hereinafter referred to as "nozzles 8"), and cooling pipes 9 arranged in the vicinity of the nozzles 8. The plurality of nozzles 8 have the same configuration as each other. Although the details will be described later, the nozzle holes 6 provided in the respective nozzles 8 are formed to be flat.

管子5形成為管軸朝上下方向延伸之圓筒狀。管子5的上端部與給料器3的底部連結,管子5的下端部與漏板4的上端部連結。管子5只要是能將給料器3和漏板4連接者即可,其形狀、管軸的延伸方向與本實施形態不同亦可。The pipe 5 is formed in a cylindrical shape whose pipe axis extends in the vertical direction. The upper end of the tube 5 is connected to the bottom of the feeder 3 , and the lower end of the tube 5 is connected to the upper end of the bushing 4 . As long as the pipe 5 can connect the feeder 3 and the bushing 4, the shape and the extending direction of the pipe axis may be different from those of the present embodiment.

關於漏板4、管子5、噴嘴8及冷卻管9等之各構件,其一部分或全體是由鉑或鉑合金(例如,鉑銠合金等)所構成。又在本實施形態,該等構件中的管子5整體是由鉑或鉑合金所構成。The bushing 4 , the tube 5 , the nozzle 8 , the cooling pipe 9 , etc., are partially or entirely made of platinum or a platinum alloy (for example, platinum-rhodium alloy). Also in the present embodiment, the entirety of the tube 5 in these components is made of platinum or platinum alloy.

從給料器3和管子5的連接部到漏板4之噴嘴孔6之流路全體,是充滿熔融玻璃2。藉此,用於從噴嘴孔6讓熔融玻璃2流出之壓力(壓差(head pressure)),是由噴嘴孔6和給料器3內之熔融玻璃2之液面2a的高低差H所決定。在此,高低差H可藉由例如變更管子5的長度來調節。The entire flow path from the connection portion of the feeder 3 and the tube 5 to the nozzle hole 6 of the bushing 4 is filled with the molten glass 2 . Thereby, the pressure (head pressure) for letting the molten glass 2 flow out from the nozzle hole 6 is determined by the height difference H between the nozzle hole 6 and the liquid level 2a of the molten glass 2 in the feeder 3 . Here, the height difference H can be adjusted by, for example, changing the length of the tube 5 .

將玻璃纖維2f成形時之熔融玻璃2的溫度、黏度分別設定成1100℃~1250℃(較佳為1150℃~1200℃)、102.6 dPa・s~103.8 dPa・s(較佳為102.9 dPa・s~103.3 dPa・s)。又在此所稱之「熔融玻璃2的溫度、黏度」,係在流入噴嘴8的位置之熔融玻璃2的溫度、黏度。熔融玻璃2的溫度、黏度之調整,例如,可將漏板4和管子5分別藉由任意的加熱手段(例如通電加熱裝置)個別進行加熱等。此外,將玻璃熔爐內的熔融玻璃2、給料器3藉由通電加熱等進行加熱來調整熔融玻璃2的溫度、黏度亦可。The temperature and viscosity of the molten glass 2 when the glass fiber 2f is formed are set to 1100°C to 1250°C (preferably 1150°C to 1200°C) and 10 2.6 dPa・s to 10 3.8 dPa・s (preferably 10 2.9 dPa・s~10 3.3 dPa・s). The "temperature and viscosity of the molten glass 2" also referred to here refer to the temperature and viscosity of the molten glass 2 at the position where the molten glass 2 flows into the nozzle 8 . For the adjustment of the temperature and viscosity of the molten glass 2, for example, the bushing 4 and the tube 5 can be individually heated by any heating means (for example, an electric heating device). In addition, the temperature and viscosity of the molten glass 2 may be adjusted by heating the molten glass 2 and the feeder 3 in the glass melting furnace by electric heating or the like.

在玻璃纖維2f的表面,藉由圖示省略的塗布器(applicator)來塗布集束劑。藉此將數百根~數千根左右的玻璃纖維2f紡絲成一根的股2s。紡絲而成的股2s,是在捲繞裝置之筒管10的周圍捲繞成纖維束2r。股2s,例如被切斷成1mm~20mm左右的長度而成為切股(chopped strand)來利用。On the surface of the glass fiber 2f, a sizing agent is applied by an applicator (not shown). Thereby, hundreds to thousands of glass fibers 2f are spun into one strand 2s. The spun strand 2s is wound around the bobbin 10 of the winding device into a fiber bundle 2r. The strand 2s is cut into a length of about 1 mm to 20 mm, for example, to be used as a chopped strand.

如圖2及圖3所示般,噴嘴8係具有一對的長壁部11,11及一對的短壁部12,12。被該等長壁部及短壁部包圍而作成具有扁平的剖面之噴嘴孔6。噴嘴孔6係具有:讓熔融玻璃2流入之流入口6a、及讓熔融玻璃2流出之流出口6b。在一對的長壁部11,11分別設置朝向流出口6b側開口之缺口部13。藉此,使噴嘴孔6通過缺口部13來與噴嘴8的外部空間連通。As shown in FIGS. 2 and 3 , the nozzle 8 has a pair of long wall portions 11 and 11 and a pair of short wall portions 12 and 12 . A nozzle hole 6 having a flat cross section is formed by being surrounded by these long wall portions and short wall portions. The nozzle hole 6 has the inflow port 6a which lets the molten glass 2 flow in, and the outflow port 6b which lets the molten glass 2 flow out. The pair of long wall portions 11 and 11 are respectively provided with notch portions 13 which are opened toward the outflow port 6b side. Thereby, the nozzle hole 6 is made to communicate with the external space of the nozzle 8 through the notch part 13 .

冷卻管9,係在其內部讓冷卻水14循環,藉此將熔融玻璃2冷卻。冷卻管9的外形形成為板狀,其板面與長壁部11平行。在此,冷卻管9雖是與底板7一體地設置,但亦可設置在與底板7分開的位置。又冷卻管9亦可形成為圓管狀。The cooling pipe 9 cools the molten glass 2 by circulating cooling water 14 in the cooling pipe 9 . The outer shape of the cooling pipe 9 is formed in a plate shape, and the plate surface thereof is parallel to the long wall portion 11 . Here, although the cooling pipe 9 is provided integrally with the bottom plate 7 , it may be provided at a position separated from the bottom plate 7 . In addition, the cooling pipe 9 may be formed in a circular tube shape.

冷卻管9之高度位置可按照熔融玻璃2的冷卻條件來做調整。作為一例,冷卻管9可配置在比噴嘴8的下端部更上方,而避免其板面與從噴嘴8拉出之熔融玻璃2面對面。另一方面,也能以噴嘴8之下端部為基準而橫跨其上方及下方配置冷卻管9,藉此使冷卻管9的板面與噴嘴8及從噴嘴8拉出之熔融玻璃2雙方面對面。又關於熔融玻璃2的冷卻,除了冷卻管9以外,亦可採用利用空氣流進行冷卻之散熱片等。又冷卻管9不是必須的構成,將其省略亦可。The height position of the cooling pipe 9 can be adjusted according to the cooling conditions of the molten glass 2 . As an example, the cooling pipe 9 may be arranged above the lower end of the nozzle 8 so that its plate surface does not face the molten glass 2 drawn from the nozzle 8 . On the other hand, the cooling pipe 9 can also be arranged across the upper and lower sides of the nozzle 8 with reference to the lower end thereof, whereby the plate surface of the cooling pipe 9 faces both the nozzle 8 and the molten glass 2 drawn from the nozzle 8 . Moreover, regarding the cooling of the molten glass 2, in addition to the cooling pipe 9, the cooling fin etc. which are cooled by air flow can also be used. In addition, the cooling pipe 9 is not an essential structure, and may be omitted.

在底板7,將複數列的噴嘴列P隔著間隔平行地配置。在各噴嘴列P包含複數個噴嘴8。屬於同一噴嘴列P之複數個噴嘴8配置成,使形成於其等之噴嘴孔6位於同一直線上。On the base plate 7, the nozzle rows P of a plurality of rows are arranged in parallel with intervals therebetween. Each nozzle row P includes a plurality of nozzles 8 . The plurality of nozzles 8 belonging to the same nozzle row P are arranged so that the nozzle holes 6 formed thereon are located on the same straight line.

上述冷卻管9,係在相鄰的兩噴嘴列P,P相互間以與噴嘴列P平行延伸的方式配置。藉此,通過面向冷卻管9之缺口部13而將噴嘴孔6內的熔融玻璃2冷卻。具體而言,熔融玻璃2是藉由冷卻管9而從1000℃以上的溫度急劇冷卻。在此,冷卻管9還具有以下功能,亦即,藉由將漏板4(底板7)、噴嘴8冷卻,抑制該等構件之受熱所造成的劣化而將耐久性提高。The above-mentioned cooling pipes 9 are arranged so as to extend parallel to the nozzle row P between two adjacent nozzle rows P and P. Thereby, the molten glass 2 in the nozzle hole 6 is cooled by facing the notch part 13 of the cooling pipe 9. Specifically, the molten glass 2 is rapidly cooled from a temperature of 1000° C. or higher by the cooling pipe 9 . Here, the cooling pipe 9 also has a function of improving the durability by cooling the bushing 4 (the bottom plate 7 ) and the nozzle 8 to suppress deterioration due to heat of these members.

如圖4(a)~(c)所示般,設置於各噴嘴8的長壁部11之缺口部13,是成為上底比下底短之等腰梯形。藉此,缺口部13隨著從噴嘴孔6之流入口6a側朝向流出口6b側其開口寬度逐漸擴大。缺口部13的深度(沿著噴嘴孔6之軸線6x的方向之長度)設定成0.1mm~2mm。這是因為,當缺口部13的深度超過2mm的情況,在所製造之玻璃纖維2f的剖面上,長邊方向的兩端部變得過細,玻璃纖維2f變得容易破損。As shown in FIGS. 4( a ) to ( c ), the notch portion 13 provided in the long wall portion 11 of each nozzle 8 is an isosceles trapezoid whose upper base is shorter than the lower base. Thereby, the opening width of the notch part 13 gradually expands from the inflow port 6a side of the nozzle hole 6 toward the outflow port 6b side. The depth of the cutout portion 13 (the length in the direction along the axis 6x of the nozzle hole 6) is set to 0.1 mm to 2 mm. This is because, when the depth of the notch portion 13 exceeds 2 mm, the glass fibers 2f are easily damaged because both ends in the longitudinal direction become too thin in the cross section of the glass fibers 2f to be produced.

缺口部13的形狀並不限定於梯形,亦可為其他形狀。亦可為例如三角形、半圓形、矩形。但就算是採用其他形狀的情況,缺口部13仍較佳為隨著從噴嘴孔6之流入口6a側朝向流出口6b側其開口寬度逐漸擴大。The shape of the notch portion 13 is not limited to a trapezoid, and may be other shapes. It can also be, for example, a triangle, a semicircle, or a rectangle. However, even in the case of adopting other shapes, it is preferable that the opening width of the notch portion 13 gradually expands from the side of the inflow port 6a of the nozzle hole 6 to the side of the outflow port 6b.

如圖4所示般,在本實施形態,是在一個噴嘴8設置單一的噴嘴孔6。噴嘴孔6形成為長孔形狀。一對的長壁部11,11是在噴嘴孔6之扁平的剖面之短徑方向相對向,一對的短壁部12,12是在噴嘴孔6之扁平的剖面之長徑方向相對向。在此,噴嘴孔6之扁平比(長徑和短徑的比)設定成2~5。包含長壁部11的內壁面11a及短壁部12的內壁面12a之噴嘴孔6的內周面是由鉑或鉑合金所構成。又長壁部11的內壁面11a如圖4(c)所示般呈直線狀,相對向的內壁面11a互相平行。As shown in FIG. 4 , in this embodiment, a single nozzle hole 6 is provided in one nozzle 8 . The nozzle hole 6 is formed in a long hole shape. The pair of long wall parts 11 and 11 face each other in the short diameter direction of the flat cross section of the nozzle hole 6 , and the pair of short wall parts 12 and 12 face each other in the long diameter direction of the flat cross section of the nozzle hole 6 . Here, the flatness ratio (ratio of the long diameter and the short diameter) of the nozzle holes 6 is set to 2 to 5. The inner peripheral surface of the nozzle hole 6 including the inner wall surface 11a of the long wall portion 11 and the inner wall surface 12a of the short wall portion 12 is made of platinum or a platinum alloy. Moreover, the inner wall surface 11a of the long wall part 11 is linear as shown in FIG.4(c), and the opposing inner wall surfaces 11a are mutually parallel.

又長壁部11和短壁部12的邊界15,係內壁面相對於圖4(c)的左右方向(Z方向)之斜率從0變化的點,相對於圖4(c)的左右方向之斜率為0的部分是長壁部11,斜率0以外的部分是短壁部12。The boundary 15 between the long wall portion 11 and the short wall portion 12 is the point at which the slope of the inner wall surface with respect to the left-right direction (Z direction) in FIG. 4(c) changes from 0, and the slope with respect to the left-right direction in FIG. The part with 0 is the long wall part 11 , and the part other than the slope 0 is the short wall part 12 .

長壁部11具有與內壁面11a相連之底壁面11b。又長壁部11中之設有缺口部13的部位之底壁面11b,是相當於等腰梯形的上底、或連結上底和下底的邊之部位。在本實施形態,底壁面11b是平坦面(在相當於等腰梯形之上底的部位,與軸線6x正交的平坦面)。同樣的,短壁部12具有與內壁面12a相連的底壁面12b。在本實施形態,底壁面12b是與軸線6x正交的平坦面。又底壁面11b及底壁面12b不一定要是平坦面,亦可為具有凹凸或彎曲之面。The long wall portion 11 has a bottom wall surface 11b connected to the inner wall surface 11a. In addition, the bottom wall surface 11b of the portion of the long wall portion 11 where the cutout portion 13 is provided corresponds to the upper bottom of the isosceles trapezoid, or the portion that connects the upper bottom and the lower bottom. In the present embodiment, the bottom wall surface 11b is a flat surface (a flat surface orthogonal to the axis 6x at a portion corresponding to the upper bottom of the isosceles trapezoid). Similarly, the short wall portion 12 has a bottom wall surface 12b connected to the inner wall surface 12a. In the present embodiment, the bottom wall surface 12b is a flat surface orthogonal to the axis 6x. In addition, the bottom wall surface 11b and the bottom wall surface 12b are not necessarily flat surfaces, and may be surfaces having unevenness or curvature.

在此,如圖4(c)所示般,在將噴嘴孔6從流出口6b側正面觀察時,將長壁部11之底壁面11b的寬度(沿著噴嘴孔6之扁平的剖面之短徑方向的寬度)之平均值設為平均寬度W1,將短壁部12之底壁面12b的寬度(沿著噴嘴孔6之扁平的剖面之長徑方向的寬度)之平均值設為平均寬度W2。這時,平均寬度W2比平均寬度W1大。具體而言,平均寬度W2較佳為平均寬度W1的1.5倍以上,更佳為2倍以上。又在本實施形態,長壁部11的厚度W11是恆定的,因此W1=W11,但短壁部12的厚度並不是恆定(例如,W21≠W22≠W23)。因此,平均寬度W2乃是短壁部12的各部位的厚度之平均值。又在本實施形態,短壁部12之底壁面12b的面積比長壁部11之底壁面11b的面積大。Here, as shown in FIG. 4( c ), when the nozzle hole 6 is viewed from the outflow port 6 b side, the width of the bottom wall surface 11 b of the long wall portion 11 (the short diameter along the flat cross section of the nozzle hole 6 ) The average value of the width in the direction) is the average width W1, and the average value of the width of the bottom wall surface 12b of the short wall portion 12 (the width in the longitudinal direction of the flat cross section of the nozzle hole 6) is the average width W2. At this time, the average width W2 is larger than the average width W1. Specifically, the average width W2 is preferably 1.5 times or more, more preferably 2 times or more, of the average width W1. Also in this embodiment, the thickness W11 of the long wall portion 11 is constant, so W1=W11, but the thickness of the short wall portion 12 is not constant (for example, W21≠W22≠W23). Therefore, the average width W2 is the average value of the thicknesses of the respective portions of the short wall portion 12 . Also in this embodiment, the area of the bottom wall surface 12b of the short wall portion 12 is larger than the area of the bottom wall surface 11b of the long wall portion 11 .

以下說明,使用上述噴嘴8的異形剖面玻璃纖維之製造方法的主要作用及效果。Hereinafter, the main function and effect of the manufacturing method of the glass fiber with a special-shaped cross section using the above-mentioned nozzle 8 will be described.

上述噴嘴8,當長壁部11之底壁面11b及短壁部12之底壁面12b分別被熔融玻璃2潤濕時,該等底壁面11b,12b可將熔融玻璃2朝沿著底壁面11b、12b的方向拉伸。而且,因為底壁面11b,12b的寬度越寬越容易將熔融玻璃2拉伸,依據上述平均寬度W2比上述平均寬度W1大的噴嘴8,能將熔融玻璃2沿著噴嘴孔6之扁平的剖面之長徑方向有效地拉伸。結果,如圖5所示般之高扁平率的玻璃纖維2f之製造成為可能。在此,玻璃纖維2f的剖面形狀形成為接近扁圓形的形狀。In the nozzle 8, when the bottom wall surface 11b of the long wall portion 11 and the bottom wall surface 12b of the short wall portion 12 are respectively wetted by the molten glass 2, the bottom wall surfaces 11b, 12b can direct the molten glass 2 toward the bottom wall surfaces 11b, 12b along the bottom wall surfaces 11b, 12b. stretch in the direction. Further, since the molten glass 2 is easily stretched as the widths of the bottom wall surfaces 11b and 12b are wider, the molten glass 2 can be drawn along the flat cross section of the nozzle hole 6 by the nozzle 8 having the average width W2 larger than the average width W1. Effectively stretch in the longitudinal direction. As a result, as shown in FIG. 5, it becomes possible to manufacture glass fiber 2f with a high aspect ratio. Here, the cross-sectional shape of the glass fiber 2f is formed in a shape close to an oblate shape.

在此,本發明的異形剖面玻璃纖維用噴嘴、及異形剖面玻璃纖維之製造方法,並不限定於在上述實施形態所說明的構成、態樣。例如在上述實施形態,雖是在一對的長壁部11,11各個設置缺口部13,但設置缺口部13不是必須的,將其去除也無妨。又噴嘴孔6除了長孔形以外,亦可為橢圓形、啞鈴形、菱形、3個相連的正圓形、矩形等。Here, the nozzle for irregular cross-section glass fiber and the manufacturing method of irregular cross-section glass fiber of this invention are not limited to the structure and aspect demonstrated in the said embodiment. For example, in the above-described embodiment, the notch portion 13 is provided in each of the pair of long wall portions 11 , 11 , but the notch portion 13 is not necessarily provided and may be removed. In addition to the long hole shape, the nozzle hole 6 can also be an oval shape, a dumbbell shape, a rhombus shape, three consecutive circles, a rectangle, or the like.

接下來說明與上述實施形態不同的第二實施形態。又噴嘴8以外的構成是與上述實施形態相同。因此,僅針對與上述實施形態之差異點做說明。Next, a second embodiment different from the above-described embodiment will be described. The configuration other than the nozzle 8 is the same as that of the above-described embodiment. Therefore, only the differences from the above-described embodiment will be described.

第二實施形態的噴嘴18,如圖6所示般,係具有一對的長壁部21,21及一對的短壁部22,22。短壁部22具有與內壁面22a相連的底壁面22b。在一對的長壁部21,21分別設有朝向流出口6b側開口之缺口部23。缺口部23的形狀是與上述實施形態相同。As shown in FIG. 6, the nozzle 18 of 2nd Embodiment has a pair of long wall part 21,21 and a pair of short wall part 22,22. The short wall portion 22 has a bottom wall surface 22b which is continuous with the inner wall surface 22a. The pair of long wall portions 21 and 21 are respectively provided with notch portions 23 which are opened toward the outflow port 6b side. The shape of the notch part 23 is the same as that of the above-mentioned embodiment.

長壁部21具有內壁面21a、及與內壁面21a相連的底壁面21b。而且,在第二實施形態中,不同於上述實施形態,內壁面21a不是與外壁面21c平行,內壁面21a是形成為,隨著靠近內壁面21a的中央部而接近長壁部21之外壁面21c。因此,長壁部21之底壁面21b之中央部分的寬度W13變得比短壁部22側的長壁部21之底壁面21b的寬度W12窄。如此,第二實施形態的平均寬度W1乃是長壁部22之各部位的厚度之平均值。又在第二實施形態中,短壁部22之底壁面22b的厚度W24是恆定的,因此W2=W24。又平均寬度W2比平均寬度W1大。The long wall portion 21 has an inner wall surface 21a and a bottom wall surface 21b which is continuous with the inner wall surface 21a. Furthermore, in the second embodiment, unlike the above-described embodiments, the inner wall surface 21a is not parallel to the outer wall surface 21c, but the inner wall surface 21a is formed so as to approach the outer wall surface 21c of the long wall portion 21 as it approaches the center portion of the inner wall surface 21a . Therefore, the width W13 of the center portion of the bottom wall surface 21b of the long wall portion 21 is narrower than the width W12 of the bottom wall surface 21b of the long wall portion 21 on the short wall portion 22 side. In this way, the average width W1 of the second embodiment is the average value of the thicknesses of the respective portions of the long wall portion 22 . Also, in the second embodiment, the thickness W24 of the bottom wall surface 22b of the short wall portion 22 is constant, so that W2=W24. Furthermore, the average width W2 is larger than the average width W1.

又不同於上述實施形態,像第二實施形態那樣當內壁面21a不是與外壁面21c平行的情況,長壁部21和短壁部22之邊界15可用以下的方法來決定。首先,如圖6般,像以下所記載的那樣畫出與噴嘴18的內壁部接觸之矩形C,矩形C的各頂點成為邊界15。該矩形C,當將由矩形C的第一邊C1和內壁部所包圍之圖形的面積設為D1,將由與該第一邊C1相對向之第二邊C2和內壁部所包圍之圖形的面積設為D2,將由與第一邊C1鄰接的第三邊C3和內壁部所包圍之圖形的面積設為D3,將由與第三邊C3相對向之第四邊C4和內壁部所包圍之圖形的面積設為D4的情況,乃是D1+D2=D3+D4的形狀。Unlike the above-described embodiment, when the inner wall surface 21a is not parallel to the outer wall surface 21c as in the second embodiment, the boundary 15 between the long wall portion 21 and the short wall portion 22 can be determined by the following method. First, as shown in FIG. 6 , a rectangle C in contact with the inner wall portion of the nozzle 18 is drawn as described below, and each vertex of the rectangle C becomes the boundary 15 . In the rectangle C, when the area of the figure enclosed by the first side C1 and the inner wall of the rectangle C is D1, the area of the figure enclosed by the second side C2 opposite the first side C1 and the inner wall is defined as D1. Let the area be D2, and let the area of the figure surrounded by the third side C3 adjacent to the first side C1 and the inner wall be D3, and the area of the figure surrounded by the fourth side C4 facing the third side C3 and the inner wall shall be When the area of the figure is set to D4, it is the shape of D1+D2=D3+D4.

在第二實施形態也是,因為平均寬度W2比平均寬度W1大,藉由噴嘴18,能將熔融玻璃2沿著噴嘴孔16之扁平的剖面之長徑方向有效地拉伸。結果,如圖5所示般之高扁平率的玻璃纖維2f之製造成為可能。Also in the second embodiment, since the average width W2 is larger than the average width W1 , the molten glass 2 can be effectively stretched along the longitudinal direction of the flat cross section of the nozzle hole 16 by the nozzle 18 . As a result, as shown in FIG. 5, it becomes possible to manufacture glass fiber 2f with a high aspect ratio.

接下來說明與上述2個實施形態不同之第三實施形態。又噴嘴8以外的構成是與上述實施形態相同。因此,僅針對與上述實施形態之差異點做說明。Next, a third embodiment different from the above-mentioned two embodiments will be described. The configuration other than the nozzle 8 is the same as that of the above-described embodiment. Therefore, only the differences from the above-described embodiment will be described.

第三實施形態的噴嘴28,如圖7所示般,係具有一對的長壁部31,31及一對的短壁部32,32。在一對的長壁部31,31分別設有朝向流出口6b側開口之缺口部33。缺口部33的形狀是與上述實施形態相同。而且,長壁部31及短壁部32俯視時的寬度W3都是恆定的。長壁部31具有與內壁面31a相連的底壁面31b。As shown in FIG. 7 , the nozzle 28 of the third embodiment has a pair of long wall portions 31 and 31 and a pair of short wall portions 32 and 32 . The pair of long wall portions 31 and 31 is provided with a notch portion 33 that opens toward the outflow port 6b side, respectively. The shape of the cutout portion 33 is the same as that of the above-described embodiment. Moreover, the width W3 of the long wall portion 31 and the short wall portion 32 in plan view is constant. The long wall portion 31 has a bottom wall surface 31b continuous with the inner wall surface 31a.

如圖8所示般,短壁部32係具有內壁面32a、及與內壁面32a相連的底壁面T。底壁面T具有垂直底壁面32b及傾斜底壁面32c,垂直底壁面32b是與內壁面32a垂直;傾斜底壁面32c係連接於垂直底壁面32b和內壁面32a,且相對於內壁面32a成為傾斜。而且,在第三實施形態中,短壁部32的厚度與第二實施形態同樣是恆定的。如圖8所示般,垂直底壁面32b的寬度為L2,傾斜底壁面32c的寬度為L1。在此,底壁面T之平均寬度W2為(L1+L2)。As shown in FIG. 8 , the short wall portion 32 has an inner wall surface 32a and a bottom wall surface T that is continuous with the inner wall surface 32a. The bottom wall surface T has a vertical bottom wall surface 32b and an inclined bottom wall surface 32c. The vertical bottom wall surface 32b is perpendicular to the inner wall surface 32a; Furthermore, in the third embodiment, the thickness of the short wall portion 32 is constant as in the second embodiment. As shown in FIG. 8, the width|variety of the vertical bottom wall surface 32b is L2, and the width|variety of the inclined bottom wall surface 32c is L1. Here, the average width W2 of the bottom wall surface T is (L1+L2).

藉由如此般設置傾斜底壁面32c,比起未設置傾斜底壁面32c的情況(在此情況,底壁面的寬度為L2+L3=W3),底壁面T的平均寬度W2是比W3增加(L1-L3)。L1和L3的關係,因為L1=L3/cosθ,例如θ=55°時,L1=1.74×L3。By providing the inclined bottom wall surface 32c in this way, the average width W2 of the bottom wall surface T is larger than that of W3 (L1 -L3). The relationship between L1 and L3, because L1=L3/cosθ, for example, when θ=55°, L1=1.74×L3.

在第三實施形態也是,因為平均寬度W2 (W3+1.74L3)比平均寬度W1(W3)增加1.74L3,藉由噴嘴28,能將熔融玻璃2沿著噴嘴孔26之扁平的剖面的長徑方向有效地拉伸。結果,如圖5所示般之高扁平率的玻璃纖維2f之製造成為可能。Also in the third embodiment, since the average width W2 (W3+1.74L3) is increased by 1.74L3 from the average width W1 (W3), the molten glass 2 can be directed along the long axis of the flat cross-section of the nozzle hole 26 by the nozzle 28 direction is effectively stretched. As a result, as shown in FIG. 5, it becomes possible to manufacture glass fiber 2f with a high aspect ratio.

2:熔融玻璃 2f:異形剖面玻璃纖維 6:噴嘴孔 6a:流入口 6b:流出口 8:異形剖面玻璃纖維用噴嘴 11:長壁部 11b:底壁面 12:短壁部 12b:底壁面 W1:寬度 W2:寬度2: molten glass 2f: Profiled glass fiber 6: Nozzle hole 6a: Inflow port 6b: Outlet 8: Nozzle for special-shaped section glass fiber 11: Long Wall 11b: Bottom wall 12: Short Wall 12b: Bottom wall W1: width W2: width

[圖1]係概略顯示具備本實施形態的異形剖面玻璃纖維用噴嘴的異形剖面玻璃纖維之製造裝置的剖面圖。 [圖2]係概略顯示本實施形態的異形剖面玻璃纖維用噴嘴的周邊之剖面圖。 [圖3]係概略顯示本實施形態的異形剖面玻璃纖維用噴嘴的周邊之仰視圖。 [圖4]係顯示本實施形態的異形剖面玻璃纖維用噴嘴,圖4(a)係將異形剖面玻璃纖維用噴嘴從長壁部側觀察之側視圖,圖4(b)係異形剖面玻璃纖維用噴嘴之剖面圖,圖4(c)係異形剖面玻璃纖維用噴嘴之仰視圖。 [圖5]係顯示異形剖面玻璃纖維之剖面圖。 [圖6]係第二實施形態的異形剖面玻璃纖維用噴嘴之仰視圖。 [圖7]係顯示第三實施形態的異形剖面玻璃纖維用噴嘴,圖7(a)係將異形剖面玻璃纖維用噴嘴從長壁部側觀察之側視圖,圖7(b)係異形剖面玻璃纖維用噴嘴的仰視圖,圖7(c)係圖7(b)之4b-4b剖面圖。 [圖8]係圖7(c)的A部分之放大圖。FIG. 1 is a cross-sectional view schematically showing an apparatus for producing a glass fiber with a special-shaped cross-section provided with a nozzle for a glass fiber with a special-shaped cross-section according to the present embodiment. [ Fig. 2] Fig. 2 is a cross-sectional view schematically showing the periphery of the nozzle for glass fiber with a special-shaped cross-section of the present embodiment. [ Fig. 3] Fig. 3 is a bottom view schematically showing the periphery of the nozzle for glass fiber with a special-shaped cross-section of the present embodiment. Fig. 4 is a side view showing the nozzle for glass fibers with an irregular cross section according to the present embodiment, Fig. 4(a) is a side view of the nozzle for glass fibers with an irregular cross section viewed from the long wall side, and Fig. 4(b) is a nozzle for glass fibers with an irregular cross section. The cross-sectional view of the nozzle, Fig. 4(c) is a bottom view of the nozzle for glass fiber with a special-shaped cross-section. [Fig. 5] is a cross-sectional view showing a glass fiber with an irregular cross-section. 6] It is a bottom view of the nozzle for glass fibers with an irregular cross section of the second embodiment. [ Fig. 7 ] is a side view of the nozzle for glass fibers with a special-shaped cross-section, which shows the third embodiment, Fig. 7(a) is a side view of the nozzle for glass fibers with a special-shaped cross-section viewed from the long wall side, and Fig. 7(b) is a glass fiber with a special-shaped cross-section. Using the bottom view of the nozzle, Fig. 7(c) is a sectional view taken along the line 4b-4b of Fig. 7(b). [Fig. 8] It is an enlarged view of part A of Fig. 7(c).

6:噴嘴孔 6: Nozzle hole

6a:流入口 6a: Inflow port

6b:流出口 6b: Outlet

6x:軸線 6x: axis

8:異形剖面玻璃纖維用噴嘴 8: Nozzle for special-shaped section glass fiber

11:長壁部 11: Long Wall

11a:內壁面 11a: inner wall surface

11b:底壁面 11b: Bottom wall

12:短壁部 12: Short Wall

12a:內壁面 12a: inner wall surface

12b:底壁面 12b: Bottom wall

13:缺口部 13: Notch part

15:邊界 15: Boundaries

W1,W11,W21,W22,W23:寬度 W1,W11,W21,W22,W23: Width

Z:左右方向 Z: left and right direction

Claims (4)

一種異形剖面玻璃纖維用噴嘴,係設置具有熔融玻璃的流入口及流出口且具有扁平的剖面之噴嘴孔,前述噴嘴孔係包含:在前述扁平的剖面之長徑方向相對向之一對的短壁部、及在前述扁平的剖面之短徑方向相對向之一對的長壁部,該異形剖面玻璃纖維用噴嘴是用於從自前述噴嘴孔流出的熔融玻璃製造異形剖面玻璃纖維, 前述短壁部之底壁面的平均寬度比前述長壁部之底壁面的平均寬度更寬。A nozzle for glass fiber with a special-shaped cross-section is provided with a nozzle hole having an inflow port and an outflow port for molten glass and having a flat cross-section, the nozzle hole is composed of: a pair of short and long-diameter opposite to each other in the long-diameter direction of the flat cross-section. A pair of long wall portions facing each other in the short diameter direction of the flat cross-section, the nozzle for glass fiber with special-shaped cross-section is used for producing glass fiber with special-shaped cross-section from molten glass flowing out from the nozzle hole, The average width of the bottom wall surface of the short wall portion is wider than the average width of the bottom wall surface of the long wall portion. 如請求項1所述之異形剖面玻璃纖維用噴嘴,其中, 前述短壁部之底壁面的平均寬度是前述長壁部之底壁面的平均寬度之1.5倍以上。The nozzle for glass fiber with special-shaped cross-section according to claim 1, wherein, The average width of the bottom wall surface of the short wall portion is 1.5 times or more the average width of the bottom wall surface of the long wall portion. 如請求項1或2所述之異形剖面玻璃纖維用噴嘴,其中, 前述短壁部之底壁面的面積比前述長壁部之底壁面的面積更大。The nozzle for glass fiber with a profiled profile according to claim 1 or 2, wherein, The area of the bottom wall of the short wall portion is larger than the area of the bottom wall of the long wall portion. 一種異形剖面玻璃纖維之製造方法,係使用設置有噴嘴孔之異形剖面玻璃纖維用噴嘴而從自該噴嘴孔流出的熔融玻璃製造異形剖面玻璃纖維之方法, 前述噴嘴孔,係具有熔融玻璃的流入口及流出口且具有扁平的剖面,並包含:在前述扁平的剖面之長徑方向相對向之一對的短壁部、及在前述扁平的剖面之短徑方向相對向之一對的長壁部, 前述短壁部之底壁面的平均寬度比前述長壁部之底壁面的平均寬度更寬。A method for producing a special-shaped glass fiber, which is a method for producing a special-shaped glass fiber from a molten glass flowing out of the nozzle hole using a nozzle for the special-shaped glass fiber provided with a nozzle hole, The nozzle hole has an inflow port and an outflow port of the molten glass and has a flat cross section, and includes a pair of short wall portions facing each other in the longitudinal direction of the flat cross section, and a short wall section in the flat cross section. A pair of long walls facing each other in the radial direction, The average width of the bottom wall surface of the short wall portion is wider than the average width of the bottom wall surface of the long wall portion.
TW110121348A 2020-06-16 2021-06-11 Nozzle for irregular cross-section glass fiber, and method for producing irregular cross-section glass fiber TWI859452B (en)

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JP2020-103647 2020-06-16
JP2020103647A JP7522387B2 (en) 2020-06-16 2020-06-16 Nozzle for irregular cross-section glass fiber and manufacturing method for irregular cross-section glass fiber

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TW202202458A true TW202202458A (en) 2022-01-16
TWI859452B TWI859452B (en) 2024-10-21

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