TW202140253A - Optical film - Google Patents

Optical film Download PDF

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TW202140253A
TW202140253A TW109113962A TW109113962A TW202140253A TW 202140253 A TW202140253 A TW 202140253A TW 109113962 A TW109113962 A TW 109113962A TW 109113962 A TW109113962 A TW 109113962A TW 202140253 A TW202140253 A TW 202140253A
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optical film
acrylate
resin
film
present
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TW109113962A
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TWI758716B (en
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汪宗興
周俊宏
葉昆明
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長興材料工業股份有限公司
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Abstract

An optical film is provided. The optical film includes a reflective polarizing element having a first surface and a second surface opposing the first surface and a concave-convex layer disposed on the first surface. The concave-convex layer include a plurality of acrylic resin particles. The optical film has excellent brightness enhancement effect and is cost-effective.

Description

光學膜Optical film

本發明係關於一種光學膜,尤指一種可用於背光模組以增加出光輝度的光學膜。The present invention relates to an optical film, in particular to an optical film that can be used in a backlight module to increase the brightness.

液晶顯示器因其具有高畫質、低輻射、低消耗功率、較佳空間利用性等優越性,為目前顯示技術的主流。液晶顯示器的主要結構包含液晶面板與背光模組兩大部分。由於液晶面板本身並不會發光,故須藉助背光模組提供液晶面板所需之面光源,以使液晶面板顯示影像。Liquid crystal displays have become the mainstream of current display technology due to their advantages such as high image quality, low radiation, low power consumption, and better space utilization. The main structure of a liquid crystal display includes two parts: a liquid crystal panel and a backlight module. Since the liquid crystal panel itself does not emit light, a backlight module must be used to provide the surface light source required by the liquid crystal panel so that the liquid crystal panel can display images.

背光模組中利用各式各樣的光學膜,以云化光源並提高亮度。此種做法不需更動任何元件設計或消耗額外能源,是較經濟且簡便的方案。背光模組常用的光學膜片包含:反射膜、擴散板、擴散膜、聚光膜及反射式增亮膜(Dual Brightness Enhancement Film)等。聚光膜又稱增亮膜(Brightness Enhancement Film; BEF),主要是藉由稜鏡微結構將散亂的光線集中至約±35度的正視角(On-axis)方向出光,以提高液晶面板的輝度。不同於聚光膜,反射式增亮膜是利用具有不同折射率的材料製成多層作為核心層,可使穿透方向上的偏振光通過,而將非穿透方向之偏振光反射回背光模組,再藉由背光模組中其它膜片(例如反射膜)的作用,使其回到反射式增亮膜並部分轉化為穿透方向之偏振光,如此往復多次,最終可將大多數原本應被液晶面板中的偏光板所吸收的光線,轉變成可利用的有效光,達到增亮效果。因此,反射式增亮膜不但可取代聚光膜亦可與聚光膜搭配,應用至高階的顯示產品。Various optical films are used in the backlight module to cloud the light source and increase the brightness. This approach does not need to change any component design or consume additional energy, and is a more economical and simple solution. Optical films commonly used in backlight modules include: reflective film, diffuser, diffuser, light-concentrating film, and dual brightness enhancement film (Dual Brightness Enhancement Film), etc. Brightness Enhancement Film (BEF), also known as Brightness Enhancement Film (BEF), is mainly used to concentrate scattered light to a positive viewing angle (On-axis) of about ±35 degrees through the microstructure to enhance the liquid crystal panel. The brightness. Different from the light-concentrating film, the reflective brightness enhancement film is made of multiple layers of materials with different refractive indexes as the core layer, which can pass the polarized light in the penetrating direction and reflect the polarized light in the non-penetrating direction back to the backlight mode. Group, through the action of other films (such as reflective film) in the backlight module, make it return to the reflective brightness enhancement film and partially convert it into polarized light in the penetrating direction. The light that should be absorbed by the polarizer in the liquid crystal panel is converted into usable effective light to achieve a brightening effect. Therefore, the reflective brightness enhancement film can not only replace the light-concentrating film, but also be matched with the light-concentrating film, which can be applied to high-end display products.

圖1是一般反射式增亮膜的結構示意圖。如圖1所示,一般的反射式增亮膜100具有反射偏振效果的核心層11,並利用黏著劑14a及14b在核心層上下表面貼附聚碳酸酯膜12及13。聚碳酸酯膜表面雖經壓花處理以提供散射及漫射效果,然而效果有限。此外,這種反射式增亮膜價格較高。因此,技術領域中期待一種光線利用度高且具價格優勢的光學膜。Fig. 1 is a schematic diagram of the structure of a general reflective brightness enhancement film. As shown in FIG. 1, a general reflective brightness enhancement film 100 has a core layer 11 with a reflective polarization effect, and polycarbonate films 12 and 13 are attached to the upper and lower surfaces of the core layer using adhesives 14a and 14b. Although the surface of the polycarbonate film is embossed to provide scattering and diffusion effects, the effect is limited. In addition, this reflective brightness enhancement film is relatively expensive. Therefore, in the technical field, an optical film with high light utilization and price advantage is expected.

此外,背光模組中的光源可例如為點光源或線光源。然而,不論是點光源或是線光源,若背光模組的出光無法被勻化,可於面板察見明顯的光源輪廓,影響顯像品質。因此,此技術領域亦期待一種可勻化光線以遮蔽光源輪廓之光學膜。In addition, the light source in the backlight module can be, for example, a point light source or a line light source. However, whether it is a point light source or a line light source, if the light emitted by the backlight module cannot be homogenized, an obvious light source profile can be observed on the panel, which affects the image quality. Therefore, this technical field also expects an optical film that can homogenize light to shield the contour of the light source.

本發明提供一種可提升輝度、具遮蔽效果且具成本優勢的光學膜。本發明之光學膜包含:一反射偏振元件,該反射偏振元件具有第一表面及相對於該第一表面的第二表面;及位於該偏振元件第一表面上的凹凸結構層,其中該凹凸結構層包含複數個丙烯酸樹脂顆粒。The present invention provides an optical film that can improve brightness, has a shielding effect, and has a cost advantage. The optical film of the present invention includes: a reflective polarizing element having a first surface and a second surface opposite to the first surface; and a concavo-convex structure layer on the first surface of the polarizing element, wherein the concavo-convex structure The layer contains a plurality of acrylic resin particles.

本發明提供一種包含上述光學膜的背光模組。The present invention provides a backlight module containing the above-mentioned optical film.

以下茲以實施例配合所附圖式,詳述本發明的光學膜。應注意,下文描述的附圖僅只是本發明的部分實施例,其各種結構可能未按比例繪製,且各種結構的尺寸可出於論述的清楚起見而增大或減小。任何所屬技術領域中具有通常知識者可輕易達成之修飾及改變均包括於本說明書揭示內容。Hereinafter, the optical film of the present invention will be described in detail with examples in conjunction with the accompanying drawings. It should be noted that the drawings described below are only part of the embodiments of the present invention, and various structures thereof may not be drawn to scale, and the sizes of various structures may be increased or decreased for clarity of discussion. Any modifications and changes that can be easily achieved by a person with ordinary knowledge in the relevant technical field are included in the disclosure of this specification.

在本說明書及申請專利範圍中,除非上下文另外明確規定,否則單數形式「一」及「該」包括可為單數或複數。除非另外主張,否則使用本文所提供之任何及所有實例或例示性語言(例如「諸如」)僅為更好地闡述本發明內容,而不應對本發明之範疇形成限制。本說明書中之語言不應解釋為指示任何未主張之要素為實施本發明所必需。In this specification and the scope of the patent application, unless the context clearly dictates otherwise, the singular form "a" and "the" include the singular or plural. Unless otherwise claimed, the use of any and all examples or illustrative language (such as "such as") provided herein is only to better illustrate the content of the present invention, and should not limit the scope of the present invention. The language in this specification should not be interpreted as indicating that any unclaimed element is necessary for implementing the present invention.

如本文中所使用,術語“大致”、“大體上”、“實質上”及“約”用以描述及說明小的變化。當與事件或情形結合使用時,所述術語可指代其中事件或情形精確發生的例子以及其中事件或情形極近似地發生的例子。舉例來說,當結合數值使用時,該術語可指小於或等於所述數值的±10%的變化範圍,例如小於或等於±5%、小於或等於±4%、小於或等於±3%、小於或等於±2%、小於或等於±1%、小於或等於±0.5%、小於或等於±0.1%、或小於或等於±0.05%。舉例來說,如果兩個數值之間的差值小於或等於所述值的平均值的±10% (例如小於或等於±5%、小於或等於±4%、小於或等於±3%、小於或等於±2%、小於或等於±1%、小於或等於±0.5%、小於或等於±0.1%、或小於或等於±0.05%),那麼可認為所述兩個數值“大體上”相同。As used herein, the terms "approximately", "substantially", "substantially" and "about" are used to describe and illustrate small changes. When used in conjunction with an event or situation, the term may refer to an example in which the event or situation occurs precisely and an example in which the event or situation occurs very closely. For example, when used in conjunction with a value, the term can refer to a range of variation less than or equal to ±10% of the stated value, such as less than or equal to ±5%, less than or equal to ±4%, less than or equal to ±3%, Less than or equal to ±2%, less than or equal to ±1%, less than or equal to ±0.5%, less than or equal to ±0.1%, or less than or equal to ±0.05%. For example, if the difference between two values is less than or equal to ±10% of the average value of the value (for example, less than or equal to ±5%, less than or equal to ±4%, less than or equal to ±3%, less than Or equal to ±2%, less than or equal to ±1%, less than or equal to ±0.5%, less than or equal to ±0.1%, or less than or equal to ±0.05%), then the two values can be considered "substantially" the same.

另外,有時在本文中以範圍格式呈現量、比率和其它數值。應理解,此類範圍格式是用於便利及簡潔起見,且應靈活地理解,不僅包含明確地指定為範圍限制的數值,而且包含涵蓋於該範圍內的所有個別數值或子範圍,如同明確地指定每一數值及子範圍一般。In addition, sometimes amounts, ratios, and other numerical values are presented in range format herein. It should be understood that this type of range format is for convenience and brevity, and should be understood flexibly. It not only includes values explicitly designated as range limits, but also encompasses all individual values or sub-ranges within the range, as if clearly Specify each value and sub-range in general.

圖2是根據本發明的一些實施例所提供的光學膜的結構示意圖。如圖2所示,本發明實施例所提供的光學膜200包含反射偏振元件21、位於反射偏振元件21之第一表面上的凹凸結構層22,該凹凸結構層含有複數個丙烯酸樹脂顆粒23。Fig. 2 is a schematic structural diagram of an optical film provided according to some embodiments of the present invention. As shown in FIG. 2, the optical film 200 provided by the embodiment of the present invention includes a reflective polarizing element 21 and a concavo-convex structure layer 22 on the first surface of the reflective polarizing element 21. The concavo-convex structure layer contains a plurality of acrylic resin particles 23.

本發明所使用的反射偏振元件21可為所屬技術領域具有通常知識者已知之適當反射偏振元件,例如多層反射偏振元件。多層反射偏振元件至少包含第一雙折射層及第二雙折射層,該第一雙折射層及第二雙折射層係分別由不同的雙折射性聚合物所構成,使得兩層的界面形成光反射平面。第一雙折射層及第二雙折射層交替地堆疊成多層,層的數目及各層的厚度可視所欲的反射偏振效果所調整。層的數目一般係介於2至5000,例如2、25、50、75、100、200、500、1000、2000、3000、4000、5000或介於中間的任意數目。各層的厚度可相同或不同,一般小於1微米(μ m)。The reflective polarizing element 21 used in the present invention may be a suitable reflective polarizing element known to those with ordinary knowledge in the art, such as a multilayer reflective polarizing element. The multilayer reflective polarizing element includes at least a first birefringent layer and a second birefringent layer. The first birefringent layer and the second birefringent layer are respectively composed of different birefringent polymers, so that the interface between the two layers forms a light Reflection plane. The first birefringent layer and the second birefringent layer are alternately stacked into multiple layers, and the number of layers and the thickness of each layer can be adjusted according to the desired reflection polarization effect. The number of layers generally ranges from 2 to 5000, such as 2, 25, 50, 75, 100, 200, 500, 1000, 2000, 3000, 4000, 5000 or any number in between. The thickness of each layer can be the same or different, and is generally less than 1 micrometer ( μm ).

反射偏振元件21之厚度係視所含之層及各層的厚度而定。在本發明的一些實施例中,所使用的反射偏振元件21具有介於2微米(μ m)至10微米(μ m)之厚度,例如,2μ m、3μ m、4μ m、5μ m、6μ m、8μ m或10μ m;較佳為3μ m至6μ m。The thickness of the reflective polarizing element 21 depends on the layers included and the thickness of each layer. In some embodiments of the present invention, the reflective polarizing element 21 used has a thickness ranging from 2 micrometers ( μm ) to 10 micrometers ( μm ), for example, 2 μm , 3 μm , 4 μm , 5 μm. μ m, 6 μ m, 8 μ m or 10 μ m; preferably 3 μ m to 6 μ m.

在本發明的一些實施例中,該一雙折射層及第二雙折射層的材料可為:聚酯(polyester)、如聚對苯二甲酸乙二酯(polyethylene terephthalate, PET)、聚對苯二甲酸丁二醇酯(polybutylene terephthalate, PBT)、聚萘二甲酸乙二酯(polyethylene naphthalate, PEN)或聚對萘二甲酸丁二醇酯(polybutylene naphthalate, PBN);聚甲基丙烯酸酯(polymethacrylate);聚醯亞胺樹脂(polyimide resin);聚苯乙烯 (polystyrene);聚烯烴樹脂(polyolefin);環烯共聚物(cyclic olefin copolymer, COC);聚碳酸酯(polycarbonate);聚胺基甲酸酯樹脂(polyurethane);三醋酸纖維素(triacetate cellulose, TAC);聚乳酸(Polylactide, PLA);或者以上述材料混合或聚合所得的材質,較佳為聚酯或聚碳酸酯(polycarbonate)。該一雙折射層及第二雙折射層係經單軸或雙軸拉伸成形,使其具有偏光效果。In some embodiments of the present invention, the materials of the one birefringent layer and the second birefringent layer may be: polyester, such as polyethylene terephthalate (PET), polyethylene terephthalate Polybutylene terephthalate (PBT), polyethylene naphthalate (PEN) or polybutylene naphthalate (PBN); polymethacrylate (polymethacrylate) ); Polyimide resin (polyimide resin); Polystyrene (polystyrene); Polyolefin resin (polyolefin); Cyclic olefin copolymer (COC); Polycarbonate (polycarbonate); Polyurethane Ester resin (polyurethane); triacetate cellulose (TAC); polylactic acid (Polylactide, PLA); or a material obtained by mixing or polymerizing the above materials, preferably polyester or polycarbonate. The one birefringent layer and the second birefringent layer are uniaxially or biaxially stretched to form a polarization effect.

在本發明的一些實施例中,該凹凸結構層22係藉由在反射偏振元件21的第一表面上塗佈含有複數個丙烯酸樹脂顆粒及接合劑的樹脂塗層所形成,因此相較於習知反射式增亮膜,不需使用價格昂貴的聚碳酸酯膜,同時,本發明的光學膜可展現優異的輝度增益值且具有成本優勢。此外,在本發明之一些較佳實施態樣中,本發明的光學膜可進一步提供良好的遮蔽效果。In some embodiments of the present invention, the concavo-convex structure layer 22 is formed by coating a resin coating containing a plurality of acrylic resin particles and a bonding agent on the first surface of the reflective polarizing element 21. Knowing that the reflective brightness enhancement film does not need to use an expensive polycarbonate film, at the same time, the optical film of the present invention can exhibit excellent brightness gain value and has a cost advantage. In addition, in some preferred embodiments of the present invention, the optical film of the present invention can further provide a good shielding effect.

在本發明的一些實施例中,本發明之接合劑可選自由紫外線硬化樹脂、熱固性樹脂(thermal setting resin)、熱塑性樹脂(thermal plastic resin)及其混合物所構成群組,並視需要以加熱固化、紫外線固化、或加熱和紫外線雙固化(dual curing)方式處理形成本發明之樹脂塗層。In some embodiments of the present invention, the bonding agent of the present invention can be selected from the group consisting of ultraviolet curable resin, thermal setting resin, thermal plastic resin and mixtures thereof, and can be cured by heating as necessary. , Ultraviolet curing, or heating and ultraviolet dual curing (dual curing) to form the resin coating of the present invention.

可用於本發明之紫外線硬化樹脂係由包含至少一種具有一或多個官能基之丙烯酸類單體或丙烯酸酯類單體所構成,較佳為丙烯酸酯類單體。可用於本發明的丙烯酸酯類單體例如但不限於:(甲基)丙烯酸酯((meth)acrylate),如2-羥基-3-苯氧丙基丙烯酸酯;胺基甲酸酯丙烯酸酯(urethane acrylate),如脂肪族胺基甲酸酯丙烯酸酯(aliphatic urethane acrylate)、脂肪族胺基甲酸酯六丙烯酸酯(aliphatic urethane hexaacrylate)或芳香族胺基甲酸酯六丙烯酸酯(aromatic urethane hexaacrylate);聚酯丙烯酸酯(polyester acrylate),如聚酯二丙烯酸酯(polyester diacrylate);環氧丙烯酸酯(epoxy acrylate),如雙酚A環氧二丙烯酸酯(bisphenol-A epoxy diacrylate),酚醛環氧丙烯酸酯(novolac epoxy acrylate);或其混合物。The ultraviolet curable resin that can be used in the present invention is composed of at least one acrylic monomer or acrylate monomer having one or more functional groups, preferably an acrylate monomer. Acrylic monomers that can be used in the present invention include, but are not limited to: (meth)acrylate, such as 2-hydroxy-3-phenoxypropyl acrylate; urethane acrylate ((meth)acrylate) urethane acrylate, such as aliphatic urethane acrylate, aliphatic urethane hexaacrylate, or aromatic urethane hexaacrylate ); polyester acrylate, such as polyester diacrylate; epoxy acrylate, such as bisphenol-A epoxy diacrylate, phenolic ring Novolac epoxy acrylate; or a mixture thereof.

可用於本發明之熱固性樹脂,其平均分子量一般介於約104 至約2×106 之間,較佳介於約2×104 至約3×105 之間,更佳介於約4×104 至約105 之間。本發明之熱固性樹脂可選自含有羧基(-COOH)及/或羥基(-OH)之聚酯樹脂、環氧樹脂、聚甲基丙烯酸酯樹脂、聚醯胺樹脂、氟素樹脂、聚醯亞胺樹脂、聚胺基甲酸酯樹脂、醇酸樹脂(alkyd resin)及其混合物所組成之群組,較佳為含有羧基(-COOH)及/或羥基(-OH)之聚甲基丙烯酸酯樹脂或聚丙烯酸酯樹脂,如聚甲基丙烯酸多元醇樹脂。The average molecular weight of the thermosetting resin that can be used in the present invention is generally between about 10 4 and about 2×10 6 , preferably between about 2×10 4 and about 3×10 5 , and more preferably between about 4×10 between about 4 to 105. The thermosetting resin of the present invention can be selected from polyester resins, epoxy resins, polymethacrylate resins, polyamide resins, fluorine resins, and polyamides containing carboxyl groups (-COOH) and/or hydroxyl groups (-OH). A group consisting of amine resin, polyurethane resin, alkyd resin and mixtures thereof, preferably polymethacrylate containing carboxyl group (-COOH) and/or hydroxyl group (-OH) Resin or polyacrylate resin, such as polymethacrylic polyol resin.

可用於本發明之熱塑性樹脂可選自聚酯樹脂;聚甲基丙烯酸酯樹脂,如聚甲基丙烯酸甲酯(PMMA);及彼等之混合物所組成之群組。The thermoplastic resins that can be used in the present invention can be selected from the group consisting of polyester resins; polymethacrylate resins, such as polymethyl methacrylate (PMMA); and their mixtures.

在本發明的一些實施例中,該凹凸結構層22有複數個丙烯酸樹脂顆粒23,本案發明人發現,相較於其它種類的顆粒(例如二氧化矽顆粒、聚苯乙烯顆粒、尼龍顆粒),使用丙烯酸樹脂顆粒可使輝度增進,且具有良好遮蔽效果。在本發明的一些實施例中,該等丙烯酸樹脂顆粒可為選自由下列丙烯酸酯單體所製成的均聚物或共聚物:甲基丙烯酸甲酯、甲基丙烯酸丁酯、2-苯氧基乙基丙烯酸酯(2-phenoxy ethyl acrylate)、乙氧化2-苯氧基乙基丙烯酸酯(ethoxylated 2-phenoxy ethyl acrylate)、2-(2-乙氧基乙氧基)乙基丙烯酸酯(2-(2-ethoxyethoxy)ethyl acrylate)、環三羥甲基丙烷甲縮醛丙烯酸酯(cyclic trimethylolpropane formal acrylate)、β-羧乙基丙烯酸酯(β-carboxyethyl acrylate)、月桂酸甲基丙烯酸酯(lauryl methacrylate)、異辛基丙烯酸酯(isooctyl acrylate)、硬脂酸甲基丙烯酸酯(stearyl methacrylate)、異癸基丙烯酸酯(isodecyl acrylate)、異冰片基甲基丙烯酸酯(isoborny methacrylate)、芐基丙烯酸酯(benzyl acrylate)、2-羥基乙基甲基丙烯酸酯磷酸酯(2-hydroxyethyl metharcrylate phosphate)、丙烯酸羥乙酯(hydroxyethyl acrylate, HEA)、甲基丙烯酸-2-羥基乙酯(2-hydroxyethyl methacrylate, HEMA)及彼等之混合物所組成之群組,較佳為甲基丙烯酸甲酯、甲基丙烯酸丁酯或其組合。In some embodiments of the present invention, the concavo-convex structure layer 22 has a plurality of acrylic resin particles 23. The inventor of the present invention found that compared with other types of particles (such as silica particles, polystyrene particles, nylon particles), The use of acrylic resin particles can increase the brightness and have a good masking effect. In some embodiments of the present invention, the acrylic resin particles may be homopolymers or copolymers made from the following acrylate monomers: methyl methacrylate, butyl methacrylate, 2-phenoxy 2-phenoxy ethyl acrylate, ethoxylated 2-phenoxy ethyl acrylate, 2-(2-ethoxyethoxy) ethyl acrylate ( 2-(2-ethoxyethoxy)ethyl acrylate), cyclic trimethylolpropane formal acrylate, β-carboxyethyl acrylate, lauric acid methacrylate ( lauryl methacrylate, isooctyl acrylate, stearyl methacrylate, isodecyl acrylate, isoborny methacrylate, benzyl Acrylate (benzyl acrylate), 2-hydroxyethyl metharcrylate phosphate (2-hydroxyethyl metharcrylate phosphate), hydroxyethyl acrylate (HEA), 2-hydroxyethyl methacrylate (2-hydroxyethyl acrylate) methacrylate (HEMA) and their mixtures are preferably methyl methacrylate, butyl methacrylate or a combination thereof.

在本發明的一些實施例中,該等丙烯酸樹脂顆粒的形狀並無特殊限制,例如可為圓球形、橢圓球形或不規則形等,較佳為圓球形。該等丙烯酸樹脂顆粒的平均粒徑範圍介於3微米(μ m)至10微米(μ m),例如可為3μ m、4μ m、5μ m、6μ m、7μ m、8μ m、9μ m或10μ m,較佳為5μ m至8μ m,藉此可使光學膜具備優異的輝度增益值及良好的遮蔽效果。在本發明之一些實施態樣中,若丙烯酸樹脂顆粒的平均粒徑低於3μ m或超過10μ m時,無法發揮遮蔽效果。In some embodiments of the present invention, the shape of the acrylic resin particles is not particularly limited. For example, they may be spherical, elliptical, or irregular, and preferably spherical. The average particle size of the acrylic resin particles ranges from 3 microns ( μ m) to 10 microns ( μ m), for example, 3 μ m, 4 μ m, 5 μ m, 6 μ m, 7 μ m, 8 μm , 9 μm, or 10 μm , preferably 5 μm to 8 μm , so that the optical film can have an excellent brightness gain value and a good shielding effect. In some embodiments of the present invention, if the average particle size of the acrylic resin particles is less than 3 μm or exceeds 10 μm , the shielding effect cannot be exerted.

在本發明的一些實施例中,該等丙烯酸樹脂顆粒之重量與接合劑之重量比介於0.8至1.8,例如可為0.8、0.9、1、1.2、1.5、1.6或1.8。In some embodiments of the present invention, the weight ratio of the acrylic resin particles to the bonding agent is between 0.8 and 1.8, for example, 0.8, 0.9, 1, 1.2, 1.5, 1.6, or 1.8.

在本發明的一些實施例中,該等丙烯酸樹脂顆粒可全部或部分突出於樹脂塗層外,以提供凹凸表面。在本發明的一些實施例中,如圖1所示,該等丙烯酸樹脂顆粒可全部包埋在樹脂塗層中,仍能提供凹凸表面。In some embodiments of the present invention, the acrylic resin particles may protrude completely or partly from the resin coating to provide a concave-convex surface. In some embodiments of the present invention, as shown in FIG. 1, the acrylic resin particles can be all embedded in the resin coating and still provide a concave-convex surface.

在本發明的一些實施例中,該凹凸結構層具有700奈米(nm)至1800奈米(nm)之算數平均粗糙度(Ra),例如700nm、800nm、900nm、1000nm、1100nm、1200nm、1300nm、1400nm、1500nm、1600nm、1700nm或1800nm;較佳為900nm至1800nm。前述算數平均粗糙度(Ra)可使用JIS B-0601標準方法測量。凹凸結構層的算數平均粗糙度若太小(例如小於700nm),則遮蔽性不足,凹凸結構層的算數平均粗糙度若過高(例如大於1800nm),則光線過於發散,影響輝度。In some embodiments of the present invention, the uneven structure layer has an arithmetic average roughness (Ra) of 700 nanometers (nm) to 1800 nanometers (nm), such as 700nm, 800nm, 900nm, 1000nm, 1100nm, 1200nm, 1300nm , 1400nm, 1500nm, 1600nm, 1700nm or 1800nm; preferably 900nm to 1800nm. The aforementioned arithmetic average roughness (Ra) can be measured using the JIS B-0601 standard method. If the arithmetic average roughness of the concavo-convex structure layer is too small (for example, less than 700 nm), the shielding property will be insufficient. If the arithmetic average roughness of the concavo-convex structure layer is too high (for example, greater than 1800 nm), the light will diverge too much and affect the brightness.

在本發明的一些實施例中,該凹凸結構層之厚度係介於約5微米(μ m)至約10微米(μ m),例如可為5μ m、6μ m、7μ m、8μ m、9μ m或10μ m。In some embodiments of the present invention, the thickness of the concave-convex structure layer is between about 5 micrometers ( μm ) to about 10 micrometers ( μm ), for example, 5 μm , 6 μm , 7 μm , 8 μm. μ m, 9 μ m or 10 μ m.

在本發明的一些實施例中,該光學膜相較於不具有丙烯酸樹脂顆粒的相同光學膜而言,可對發光裝置提供1%以上的輝度增益(亦即,輝度增益值為101%或更高),例如1%以上、2%以上、5%以上、10%以上、20%以上、30%以上或40%以上。該發光裝置例如但不限於:背光模組。In some embodiments of the present invention, compared with the same optical film without acrylic resin particles, the optical film can provide a luminance gain of more than 1% to the light-emitting device (that is, the luminance gain value is 101% or more). High), such as 1% or more, 2% or more, 5% or more, 10% or more, 20% or more, 30% or more, or 40% or more. The light-emitting device is, for example, but not limited to: a backlight module.

在本發明的一些實施例中,該反射偏振元件的第二表面可包含一或多個功能性塗層或膜片,以使光學膜具有增進或額外之功效。前述功能性塗層或膜片例如但不限於聚碳酸酯膜、聚酯膜、密著防止層、抗靜電層、抗刮層或稜鏡片或其組合。該聚酯膜較佳為聚對苯二甲酸乙二酯膜或聚萘二甲酸乙二酯膜。在本發明的一些實施例中,該反射偏振元件的第二表面上包含聚碳酸酯膜、聚酯膜或稜鏡片或其組合。In some embodiments of the present invention, the second surface of the reflective polarizing element may include one or more functional coatings or films, so that the optical film has enhanced or additional functions. The aforementioned functional coatings or films are, for example, but not limited to, polycarbonate film, polyester film, adhesion prevention layer, antistatic layer, anti-scratch layer, or sheet, or a combination thereof. The polyester film is preferably a polyethylene terephthalate film or a polyethylene naphthalate film. In some embodiments of the present invention, the second surface of the reflective polarizing element includes a polycarbonate film, a polyester film, or a sheet, or a combination thereof.

圖3至5例示本發明光學膜中反射偏振元件第二表面包含一或多個功能性塗層或膜片的實施態樣。雖然在圖3至5例示的實施態樣中,稜鏡片或係聚酯膜直接貼附於第二表面,然而其僅為舉例說明用,在本發明之範疇下,一功能性塗層或膜片與第二表面間可視需要存在一或多個其它塗層或膜片,上述其它塗層或膜片可為另一功能性塗層或膜片。Figures 3 to 5 illustrate embodiments in which the second surface of the reflective polarizing element in the optical film of the present invention includes one or more functional coatings or films. Although in the embodiments illustrated in FIGS. 3 to 5, the scallop sheet or polyester film is directly attached to the second surface, it is only for illustrative purposes. Under the scope of the present invention, a functional coating or film There may be one or more other coatings or membranes between the sheet and the second surface as needed, and the above-mentioned other coatings or membranes may be another functional coating or membrane.

如圖3所示,在本發明的一些實施例中,該反射偏振元件21的第二表面包含稜鏡片24。稜鏡片24可為任何已知之市售的稜鏡片或者可由所屬技術領域具有通常知識者已知之適當材料所構成。在本發明的一些實施例中,稜鏡片可由任何折射率大於空氣折射率之樹脂所構成,一般而言折射率越高,效果越好。用以形成該稜鏡片之樹脂為所屬技術領域中具有通常知識者所熟知者,例如,熱硬化樹脂或紫外線硬化樹脂,較佳為紫外線硬化樹脂。熱硬化樹脂或紫外線硬化樹脂之種類係如上文所述。稜鏡片之高度可介於例如5微米(μ m)至100微米(μ m)之範圍;稜鏡結構之頂角角度可介於例如40°至120°之範圍,較佳介於85°至95°之範圍。As shown in FIG. 3, in some embodiments of the present invention, the second surface of the reflective polarizing element 21 includes a sheet 24. The flakes 24 can be any known commercially available flakes or can be composed of suitable materials known by those having ordinary knowledge in the art. In some embodiments of the present invention, the flakes can be made of any resin with a refractive index greater than that of air. Generally speaking, the higher the refractive index, the better the effect. The resin used to form the sheet is well-known to those having ordinary knowledge in the art, for example, a thermosetting resin or an ultraviolet curing resin, preferably an ultraviolet curing resin. The types of thermosetting resin or ultraviolet curing resin are as described above. The height of the flakes can be in the range of, for example, 5 micrometers ( μm ) to 100 microns ( μm ); the apex angle of the flakes structure can be in the range of, for example, 40° to 120°, preferably 85° to 95 °The range.

如圖4所示,在本發明的一些實施例中,該反射偏振元件21的第二表面上包含聚酯膜25,該聚酯膜25係透過黏著劑24a貼附於第二表面上。加入聚酯膜可增加偏振元件的支撐性。在本發明的一些實施例中,該聚酯膜為聚對苯二甲酸乙二酯膜或聚萘二甲酸乙二酯膜,聚酯膜之厚度可介於例如100微米(μ m)至300微米(μ m)之範圍,例如,100μ m、120μ m、150μ m、180μ m、200μ m、250μ m、280μ m或300μ m。黏著劑可為所屬技術領域中具有通常知識者所知之適當黏著劑。As shown in FIG. 4, in some embodiments of the present invention, the second surface of the reflective polarizing element 21 includes a polyester film 25, and the polyester film 25 is attached to the second surface through an adhesive 24a. Adding a polyester film can increase the support of the polarizing element. In some embodiments of the present invention, the polyester film is a polyethylene terephthalate film or a polyethylene naphthalate film, and the thickness of the polyester film can be, for example, 100 micrometers ( μm ) to 300. The range of micrometers ( μm ), for example, 100 μm , 120 μm , 150 μm , 180 μm , 200 μm , 250 μm , 280 μm, or 300 μm . The adhesive may be an appropriate adhesive known to those with ordinary knowledge in the art.

如圖5所示,在本發明的一些實施例中,該反射偏振元件21的第二表面上包含含顆粒27之塗層26。塗層26所含接合劑及顆粒27之材料可與凹凸結構層23之接合劑及丙烯酸樹脂顆粒相同或不同,顆粒27可採用本發明之丙烯酸樹脂顆粒或者是其它常見於光學膜之顆粒。在本發明的一些實施例中,該塗層26為與凹凸結構層23相同或相似之塗層,其能與凹凸結構層23搭配進一步調整光學膜之輝度增益及遮蔽性效果至最佳。在本發明的另一些實施例中,可使塗層26具有較小的厚度並降低顆粒含量。含顆粒27之塗層26具有防止密著之效果。在圖5的實施態樣中,該反射偏振元件21的第二表面上依序包含:聚酯膜25及含顆粒27之塗層26(其中該聚酯膜25係透過黏著劑24a貼附於第二表面上);然而,在一些實施態樣中,亦可於反射偏振元件21的第二表面上直接製備該含顆粒27之塗層26。As shown in FIG. 5, in some embodiments of the present invention, the second surface of the reflective polarizing element 21 includes a coating 26 containing particles 27. The material of the bonding agent and particles 27 contained in the coating layer 26 may be the same as or different from the bonding agent and acrylic resin particles of the concave-convex structure layer 23. The particles 27 may be acrylic resin particles of the present invention or other particles commonly used in optical films. In some embodiments of the present invention, the coating 26 is the same or similar to the concave-convex structure layer 23, which can be used with the concave-convex structure layer 23 to further adjust the brightness gain and shielding effect of the optical film to the best. In other embodiments of the present invention, the coating layer 26 can be made to have a smaller thickness and the particle content can be reduced. The coating 26 containing the particles 27 has the effect of preventing adhesion. In the embodiment of FIG. 5, the second surface of the reflective polarizing element 21 sequentially includes a polyester film 25 and a coating layer 26 containing particles 27 (wherein the polyester film 25 is affixed to it through an adhesive 24a) On the second surface); however, in some embodiments, the particle 27-containing coating 26 can also be directly prepared on the second surface of the reflective polarizing element 21.

本發明之光學膜具有良好的輝度增益及遮蔽性效果,因此可應用至背光模組與其它光學膜片一起搭配使用,或者可取代一或多種其它光學膜片。因此,在本發明進一步提供一種包含本發明之光學膜的背光模組,相較於習知背光模組,採用本發明之光學膜具有較佳的輝度增益及遮蔽性效果。The optical film of the present invention has good brightness gain and shielding effects, so it can be applied to a backlight module to be used in conjunction with other optical films, or can replace one or more other optical films. Therefore, the present invention further provides a backlight module including the optical film of the present invention. Compared with conventional backlight modules, the optical film of the present invention has better brightness gain and shielding effect.

以下茲以具體實施例配合所附圖式,詳述本發明的光學膜,唯非用以限制本發明之範圍。任何所屬技術領域中具有通常知識者可輕易達成之修飾及改變均包括於本案說明書揭示內容。[ 測試方法 ] Hereinafter, the optical film of the present invention is described in detail with specific embodiments in conjunction with the accompanying drawings, but it is not intended to limit the scope of the present invention. Any modifications and changes that can be easily achieved by a person with ordinary knowledge in the relevant technical field are included in the disclosure of the specification of this case. [ Test method ]

表面粗糙度測試 :使用手持粗糙度計(型號:SJ-201P),以標準方法JIS B 0601量測待測光學膜片之表面粗糙度(Ra)。 Surface roughness test : Use a hand-held roughness meter (model: SJ-201P) to measure the surface roughness (Ra) of the optical film under test according to the standard method JIS B 0601.

遮蔽效果評估: 將待測光學膜片,設置於燈管前方30公分距離之處,使未塗佈塗層之面朝向光源而塗佈塗層之面背離光源。以肉眼觀察,若透過膜片仍可清楚觀察到燈管輪廓,遮蔽效果差;若透過膜片無法觀察到燈管輪廓,且出光均勻,則遮蔽效果佳。圖6(a)至圖6(d)是膜片之遮蔽程度評估示意圖:(a)測試用燈管;(b)無塗層膜片(比較例1)之遮蔽效果;(c)、(d)及(e)分別顯示遮蔽效果差、遮蔽效果尚可、及遮蔽效果佳。 Evaluation of shielding effect: Set the optical film to be tested at a distance of 30 cm in front of the lamp tube, so that the uncoated surface faces the light source and the coated surface faces away from the light source. Observed by naked eyes, if the outline of the lamp tube can be clearly observed through the diaphragm, the shielding effect is poor; if the outline of the lamp tube cannot be observed through the diaphragm, and the light is uniform, the shielding effect is good. Figures 6(a) to 6(d) are schematic diagrams of the evaluation of the degree of shielding of the diaphragm: (a) the test tube; (b) the shielding effect of the uncoated diaphragm (comparative example 1); (c), ( d) and (e) respectively show that the shielding effect is poor, the shielding effect is fair, and the shielding effect is good.

輝度增益測試: 將待測光學膜片組裝至BenQ公司所提供的22側邊式背光模組,用輝度計(Topcon公司,型號:SC-777)於背光模組正上方(0°角)50公分距離處,以2°測定角量測中心輝度(Brightness;單位:cd/m2 )。以組裝無塗層膜片(即,樣品1-1)之模組所得中心輝度值作為基值,將組裝另一待測膜片之模組所得中心輝度值除以基值再乘以100%,即可得知該待測樣品之輝度增益值。大於100%,表示該塗層提供輝度增益效果;小於100%,表示該塗層導致輝度減損。[ 簡稱說明 ] PMMA (2μ m):聚甲基丙烯酸甲酯粒子(SSX-102型號,台灣積水化成品部份有限公司) PMMA (3μ m):聚甲基丙烯酸甲酯粒子(SSX-103型號,台灣積水化成品股份有限公司) PMMA (5μ m):聚甲基丙烯酸甲酯粒子(MBX-05型號,台灣積水化成品股份有限公司) PMMA (8μ m):聚甲基丙烯酸甲酯粒子(MBX-08型號,台灣積水化成品股份有限公司) PBMA (5μ m):聚甲基丙烯酸丁酯粒子(BM30X-5型號,台灣積水化成品股份有限公司) PBMA (12μ m):聚甲基丙烯酸丁酯粒子(BM30X-12型號,台灣積水化成品股份有限公司) PS (5μ m):聚苯乙烯粒子(SBX-4型號,台灣積水化成品股份有限公司) Nylon (5μ m):尼龍粒子(自行合成) Silica (5μ m):二氧化矽粒子(sunsil 50型號,先進化學(sunjin chemical)公司)[ 實施例 1] Luminance gain test: Assemble the optical film to be tested to the 22-side backlight module provided by BenQ, and use a luminance meter (Topcon, model: SC-777) directly above the backlight module (0° angle) 50 At a distance of cm, the central brightness (Brightness; unit: cd/m 2 ) is measured at a measuring angle of 2°. Take the center luminance value of the module assembled with the uncoated membrane (ie, sample 1-1) as the base value, divide the center luminance value of the module assembled with another membrane to be tested by the base value and multiply by 100% , You can know the brightness gain value of the sample to be tested. More than 100%, it means that the coating provides brightness gain effect; less than 100%, it means that the coating causes brightness loss. [ Description of abbreviation ] PMMA (2 μ m): Polymethyl methacrylate particles (SSX-102 model, Taiwan Sekisui Chemical Products Co., Ltd.) PMMA (3 μ m): Polymethyl methacrylate particles (SSX- Model 103, Taiwan Sekisui Chemical Products Co., Ltd.) PMMA (5 μm ): Polymethylmethacrylate particles (Model MBX-05, Taiwan Sekisui Chemicals Co., Ltd.) PMMA (8 μm ): Polymethacrylic acid Methyl ester particles (MBX-08 model, Taiwan Sekisui Chemical Products Co., Ltd.) PBMA (5 μm ): Polybutyl methacrylate particles (BM30X-5 model, Taiwan Sekisui Chemical Products Co., Ltd.) PBMA (12 μ m ): Polybutyl methacrylate particles (Model BM30X-12, Taiwan Sekisui Chemical Co., Ltd.) PS (5 μm ): Polystyrene particles (Model SBX-4, Taiwan Sekisui Chemical Co., Ltd.) Nylon ( 5 μ m): Nylon particles (in- house synthesis) Silica (5 μ m): Silicon dioxide particles (sunsil 50 model, Sunjin Chemical Company) [ Example 1]

將粒子與丙烯酸酯樹脂(ETERMER 2386及ETERCURE 6145-100,長興材料股份有限公司;固形份約NV40%)以表1所載粒子/樹脂固形份之比例(下稱「BB值」)均勻混合,製備成塗料。Mix the particles with acrylic resin (ETERMER 2386 and ETERCURE 6145-100, Evergreen Materials Co., Ltd.; solid content is about NV40%) at the particle/resin solid content ratio (hereinafter referred to as "BB value") listed in Table 1. Prepared into paint.

以RDS塗抹棒#12將塗料塗佈在厚度為38μ m之多層聚合光學薄膜基材(AF型號,宏騰光電公司)表面上,經乾燥後製得具有厚度約6μ m之塗層的光學膜片,進行各項測試。 表1 樣品 粒子材質 粒徑 BB值 粗糙度(nm) 輝度增益值(%) 遮蔽效果 1-1 無塗佈 - - - 100 1-2 PS 5μm 1.0 800 8.4 1-3 Nylon 5μm 1.0 1300 12.8 1-4 Silica 5μm 1.0 1800 21.7 1-5 PMMA 5μm 1.0 960 118.3 1-6 PBMA 5μm 1.0 1570 111.3 Use RDS smear stick #12 to coat the coating on the surface of a multilayer polymeric optical film substrate (AF model, Hongteng Optoelectronics Co., Ltd.) with a thickness of 38 μm . After drying, a coating with a thickness of about 6 μm is obtained. Various tests are carried out on the optical film. Table 1 sample Particle material Particle size BB value Roughness (nm) Brightness gain value (%) Masking effect 1-1 Uncoated - - - 100 1-2 PS 5μm 1.0 800 8.4 1-3 Nylon 5μm 1.0 1300 12.8 1-4 Silica 5μm 1.0 1800 21.7 1-5 PMMA 5μm 1.0 960 118.3 1-6 PBMA 5μm 1.0 1570 111.3

由表1可知,相較於其它種類的顆粒(例如二氧化矽顆粒、聚苯乙烯顆粒、尼龍顆粒),使用包含丙烯酸樹脂顆粒(例如PMMA顆粒、PBMA顆粒)之塗層的膜片可提供優異的輝度增益效果且具良好遮蔽效果。[ 實施例 2] As can be seen from Table 1, compared to other types of particles (such as silica particles, polystyrene particles, nylon particles), the use of acrylic resin particles (such as PMMA particles, PBMA particles) coating film can provide excellent Brightness gain effect and good shading effect. [ Example 2]

同實施例1之方法,改採表2所載粒子及BB值,製備塗料及光學膜片,進行各項測試。 表2 樣品 粒子材質 粒徑 BB值 粗糙度(nm) 輝度增益值(%) 遮蔽效果 2-1 PMMA 2μm 1.0 650 108.6 2-2 PMMA 3μm 1.0 740 115.5 2-3 PMMA 5μm 1.0 960 118.3 2-4 PMMA 8μm 1.0 1800 116.9 2-5 PMMA 15μm 1.0 4100 111.7 2-6 PBMA 5μm 1.0 1570 111.3 2-7 PBMA 8μm 1.0 1700 111.2 2-8 PBMA 12μm 1.0 2600 110.7 With the same method as in Example 1, the particles and BB values in Table 2 were changed to prepare coatings and optical films, and various tests were performed. Table 2 sample Particle material Particle size BB value Roughness (nm) Brightness gain value (%) Masking effect 2-1 PMMA 2μm 1.0 650 108.6 2-2 PMMA 3μm 1.0 740 115.5 2-3 PMMA 5μm 1.0 960 118.3 2-4 PMMA 8μm 1.0 1800 116.9 2-5 PMMA 15μm 1.0 4100 111.7 2-6 PBMA 5μm 1.0 1570 111.3 2-7 PBMA 8μm 1.0 1700 111.2 2-8 PBMA 12μm 1.0 2600 110.7

由表2可知,丙烯酸樹脂顆粒具有輝度增益效果;然而,粒徑過小或過大,輝度增益值降低且遮蔽效果不佳。[ 實施例 3] It can be seen from Table 2 that the acrylic resin particles have a brightness gain effect; however, if the particle size is too small or too large, the brightness gain value will be reduced and the shielding effect will not be good. [ Example 3]

同實施例1之方法,改採表3所載粒子及BB值,製備塗料及光學膜片,進行各項測試。 表3 樣品 粒子材質 粒徑 BB值 粗糙度(nm) 輝度增益值(%) 遮蔽效果 3-1 PMMA 5μm 0.5 840 96.2 3-2 PMMA 5μm 0.7 950 101.4 3-3 PMMA 5μm 1.0 960 118.3 3-4 PMMA 5μm 1.5 1110 105.2 3-5 PMMA 5μm 2.0 850 95.8 3-6 PBMA 5μm 0.5 1130 101.8 3-7 PBMA 5μm 0.7 1450 102.1 3-8 PBMA 5μm 1.0 1570 111.3 3-9 PBMA 5μm 1.5 1620 107.5 3-10 PBMA 5μm 2.0 1580 97.5 With the same method as in Example 1, the particles and BB values in Table 3 were changed to prepare coatings and optical films, and various tests were performed. table 3 sample Particle material Particle size BB value Roughness (nm) Brightness gain value (%) Masking effect 3-1 PMMA 5μm 0.5 840 96.2 3-2 PMMA 5μm 0.7 950 101.4 3-3 PMMA 5μm 1.0 960 118.3 3-4 PMMA 5μm 1.5 1110 105.2 3-5 PMMA 5μm 2.0 850 95.8 3-6 PBMA 5μm 0.5 1130 101.8 3-7 PBMA 5μm 0.7 1450 102.1 3-8 PBMA 5μm 1.0 1570 111.3 3-9 PBMA 5μm 1.5 1620 107.5 3-10 PBMA 5μm 2.0 1580 97.5

由表3可知,丙烯酸樹脂顆粒含量增加可提升遮蔽效果;然而,顆粒含量過多,將導致輝度增益值降低。It can be seen from Table 3 that an increase in the content of acrylic resin particles can improve the shielding effect; however, too much particle content will result in a decrease in the brightness gain value.

上述實施例僅為例示性說明本發明之實施態樣,並闡述本發明之技術特徵,而非用於限制本發明之保護範疇。任何熟悉本技術者在不違背本發明之技術原理及精神下,可輕易完成之改變或安排,均屬本發明所主張之範圍。因此,本發明之權利保護範圍係如後附申請專利範圍所列。The above-mentioned embodiments are only illustrative of the implementation of the present invention, and illustrate the technical features of the present invention, and are not used to limit the protection scope of the present invention. Any changes or arrangements that can be easily made by a person familiar with the present invention without departing from the technical principles and spirit of the present invention fall within the scope of the present invention. Therefore, the scope of protection of the rights of the present invention is as listed in the appended patent scope.

11:核心層 12,13:聚碳酸酯膜 14a,14b:黏著劑 21:反射偏振元件 22:凹凸結構層 23:丙烯酸樹脂顆粒 24:稜鏡片 24a:黏著劑 25:聚酯膜 26:塗層 27:顆粒 100:反射式增亮膜 200:光學膜11: core layer 12, 13: Polycarbonate film 14a, 14b: Adhesive 21: Reflective polarizing element 22: Concave-convex structure layer 23: Acrylic resin particles 24: 稜鏡片 24a: Adhesive 25: Polyester film 26: Coating 27: particles 100: reflective brightness enhancement film 200: Optical film

圖1是一般反射式增亮膜的結構示意圖。Figure 1 is a schematic diagram of the structure of a general reflective brightness enhancement film.

圖2至5是根據本發明的一些實施例所提供的光學膜的結構示意圖。2 to 5 are schematic diagrams of the structure of optical films provided according to some embodiments of the present invention.

圖6(a)至圖6(e)是膜片之遮蔽效果評估示意圖:(a)測試用燈管;(b)無塗層膜片之遮蔽效果;(c)遮蔽效果差;(d)遮蔽效果尚可;(e)遮蔽效果佳。Figures 6(a) to 6(e) are schematic diagrams of the evaluation of the shielding effect of the diaphragm: (a) the test tube; (b) the shielding effect of the uncoated diaphragm; (c) the poor shielding effect; (d) The covering effect is acceptable; (e) The covering effect is good.

21:反射偏振元件21: Reflective polarizing element

22:凹凸結構層22: Concave-convex structure layer

23:丙烯酸樹脂顆粒23: Acrylic resin particles

200:光學膜200: Optical film

Claims (9)

一種光學膜,其包含: 一反射偏振元件,該反射偏振元件具有第一表面及相對於該第一表面的第二表面;及位於該偏振元件第一表面上的凹凸結構層,其中該凹凸結構層包含複數個丙烯酸樹脂顆粒。 其中該等丙烯酸樹脂顆粒的平均粒徑範圍介於3微米至10微米。An optical film comprising: A reflective polarizing element, the reflective polarizing element has a first surface and a second surface opposite to the first surface; and a concavo-convex structure layer on the first surface of the polarizing element, wherein the concavo-convex structure layer includes a plurality of acrylic resin particles . The average particle size of the acrylic resin particles ranges from 3 microns to 10 microns. 如請求項1之光學膜,其中該凹凸結構層具有介於700奈米至1800奈米之算數平均粗糙度(Ra)。The optical film of claim 1, wherein the concave-convex structure layer has an arithmetic average roughness (Ra) ranging from 700 nm to 1800 nm. 請求項1之光學膜,其中該凹凸結構層包含複數個丙烯酸樹脂顆粒及接合劑,其中接合劑係選自紫外線硬化樹脂或熱固性樹脂,該紫外線硬化樹脂係由包含至少一種具有一或多個官能基之丙烯酸類單體或丙烯酸酯類單體所構成,該熱固性樹脂可選自含有羧基(-COOH)及/或羥基(-OH)之聚酯樹脂、環氧樹脂、聚甲基丙烯酸酯樹脂、聚醯胺樹脂、氟素樹脂、聚醯亞胺樹脂、聚胺基甲酸酯樹脂、醇酸樹脂及其混合物。The optical film of claim 1, wherein the concavo-convex structure layer comprises a plurality of acrylic resin particles and a bonding agent, wherein the bonding agent is selected from ultraviolet curable resin or thermosetting resin, and the ultraviolet curable resin is composed of at least one having one or more functionalities. The thermosetting resin can be selected from polyester resin, epoxy resin, polymethacrylate resin containing carboxyl group (-COOH) and/or hydroxyl group (-OH) , Polyamide resin, fluorine resin, polyimide resin, polyurethane resin, alkyd resin and mixtures thereof. 如請求項3之光學膜,其中該等丙烯酸樹脂顆粒之重量與接合劑之重量比介於0.8至1.8。The optical film of claim 3, wherein the weight ratio of the acrylic resin particles to the bonding agent is 0.8 to 1.8. 如請求項1之光學膜,其中該反射偏振元件的第二表面上包含一或多種功能性塗層或膜片。The optical film of claim 1, wherein the second surface of the reflective polarizing element includes one or more functional coatings or films. 如請求項5之光學膜,其中該一或多種功能性塗層或膜片為聚碳酸酯膜、聚酯膜、密著防止層、抗靜電層、抗刮層或稜鏡片或其組合。Such as the optical film of claim 5, wherein the one or more functional coatings or films are polycarbonate film, polyester film, adhesion prevention layer, antistatic layer, anti-scratch layer or sheet or combination thereof. 如請求項1之光學膜,其中該光學膜相較於不具有丙烯酸樹脂顆粒的相同光學膜而言,可對發光裝置產生1%以上的輝度增益。The optical film of claim 1, wherein the optical film can produce a luminance gain of more than 1% for the light-emitting device compared with the same optical film without acrylic resin particles. 如請求項1之光學膜,其中該丙烯酸樹脂顆粒可為選自由下列丙烯酸酯單體所製成的均聚物或共聚物:甲基丙烯酸甲酯、甲基丙烯酸丁酯、2-苯氧基乙基丙烯酸酯、乙氧化2-苯氧基乙基丙烯酸酯、2-(2-乙氧基乙氧基)乙基丙烯酸酯、環三羥甲基丙烷甲縮醛丙烯酸酯、β-羧乙基丙烯酸酯、月桂酸甲基丙烯酸酯、異辛基丙烯酸酯、硬脂酸甲基丙烯酸酯、異癸基丙烯酸酯、異冰片基甲基丙烯酸酯、芐基丙烯酸酯、2-羥基乙基甲基丙烯酸酯磷酸酯、丙烯酸羥乙酯、甲基丙烯酸-2-羥基乙酯及彼等之混合物所組成之群組。The optical film of claim 1, wherein the acrylic resin particles may be a homopolymer or copolymer selected from the following acrylic acid ester monomers: methyl methacrylate, butyl methacrylate, 2-phenoxy Ethyl acrylate, ethoxylated 2-phenoxyethyl acrylate, 2-(2-ethoxyethoxy) ethyl acrylate, cyclotrimethylolpropane methylal acrylate, β-carboxyethyl Base acrylate, lauric acid methacrylate, isooctyl acrylate, stearic acid methacrylate, isodecyl acrylate, isobornyl methacrylate, benzyl acrylate, 2-hydroxyethylmethacrylate It is a group consisting of acrylate phosphate, hydroxyethyl acrylate, 2-hydroxyethyl methacrylate and their mixtures. 一種背光模組,其包含如請求項1至8中任一項之光學膜。A backlight module comprising the optical film as claimed in any one of claims 1 to 8.
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