TW202042661A - Heated aroma generator composition, heated aroma generator using the composition, and incense core using the heated aroma generator - Google Patents

Abstract

A problem that it is difficult to feel various aromas in the mouth like liquid electronic cigarettes because raw materials and fragrances containing aroma ingredients that form aromas felt when aerosol formed by volatilization with an aerosol-forming agent is inhaled cannot be prepared in a large scale exists in electronic cigarettes in which heated aroma generators containing rod-shaped aerosol-forming agents must be shaped and processed. The invention can provide a heated aroma generator and an incense core using the heated aroma generator, which are characterized in that a heated aroma generator composition is prepared from raw materials, which allow, when the heated aroma generator is heated and inhaled together with aerosol, aromas of beverages, such as coffee and cola, desserts, such as chocolate and vanilla, fruits such as oranges and melons, refreshing agents such as menthol and medicinal herbs and the like to be strongly felt, an adsorption material and a holding material; the composition is completely free of tobacco ingredients, and a user can enjoy various aromas in the mouth just like liquid electronic cigarettes and feel tobacco.

Description

Rod type heated aroma generating substrate composition, rod type heated aroma generating substrate using the composition, and aroma box using the rod type heated aroma generating substrate

The present invention relates to a composition comprising a rod-type heated aroma generating substrate containing an aerosol generating agent that generates an aerosol by heat transferred by an electric heat source other than a flame, and a rod-type quilt using the composition A heated aroma generating substrate and an aroma box using the rod-shaped heated aroma generating substrate.

In particular, there is provided a structure that does not contain tobacco and plants of the same genus of Nicotiana solanaceae, and its components, and when heated and heated to produce a substrate while inhaling aerosols, it can be strongly felt in the oral cavity The composition of the rod-shaped heated aroma-generating substrate using the "flavor" of the aroma that the whole feels, the rod-shaped heated aroma-generating substrate using the composition, and the aroma box using the rod-shaped heated aroma-generating substrate.

More specifically, the present invention relates to a stick type that contains a large amount of specific parts of angiosperm plants that have aroma components that are effective in enhancing health and beauty by smoking, etc. A heated aroma generating substrate composition, a rod-shaped heated aroma generating substrate using the composition, and an aroma box using the rod-shaped heated aroma generating substrate.

In recent years, because of the tendency of smoking zoning and smoking bans to spread to workplaces or restaurants, etc. people gather in spaces, compared with the number of smokers who smoke cigarettes that burn tobacco with flames such as paper cigarettes. , The number of smoking enthusiasts using electronic cigarettes using heated smoking devices that inhale the smoke or vapor generated by heat transferred by heat sources such as heaters has rapidly increased. The reason is that if the previous flame smoking is used, smokers and non-smokers around them will inhale harmful substances produced by the thermal decomposition and combustion of tobacco leaves and paper. Without the need for thermal decomposition and combustion of tobacco leaves, smokers can inhale harmless smoke and vapors that use the composition as non-tobacco raw materials, and can enjoy smoking and reduce the impact on non-smokers around them.

There are two types of such electronic cigarettes by generation (Non-Patent Documents 1 and 2). One is to inhale capsule-type electronic cigarettes and stick-type electronic cigarettes such as cigarettes in order to heat capsules or sticks containing tobacco leaves and the like. The other is a liquid type electronic cigarette that sucks vapor produced by heating a liquid with a fragrance or taste.

In particular, stick-type e-cigarettes have high similarity in shape, smoking method, and taste compared with conventional paper cigarettes, and the inhalation of harmful substances such as paper cigarettes is less, so there are many fans. , And carried out various developments (for example, Patent Documents 1 to 3). Specifically, e-cigarettes are used to process tobacco components, together with aerosol generators, flavors, binders, etc. that generate smoke aerosols into a stick-shaped aerosol such as paper cigarettes. The aerosol forming body is provided with a rod with a cigarette holder, and is installed on a heated smoking device to smoke. The smoking mechanism is installed and heated so that the aerosol-forming substrate is in contact with the heat source of the heating smoking device. When the volatile matter containing the aerosol-forming agent is released from the aerosol-forming substrate, the volatile matter is The smoker’s suction and air are inhaled from the cigarette holder side at the other end. In this volatile transportation step, the volatiles of the aerosol generating agent cool and condense and form smoke-like aerosols. The volatiles of the volatiles give the smoker's mouth and nose fragrance, and as a result, people who can enjoy smoking (Patent Document 2). With this mechanism, in the case of heated smoking such as a stick-type electronic cigarette, it is possible to use a temperature of about 200 to 350°C that can volatilize aerosol generating agents such as glycerin or propylene glycol contained in the aerosol forming substrate. That is, smoking is carried out at a temperature of the extent that the thermal decomposition of tobacco leaves starts. Therefore, heating smoking, compared to at least 600°C for burning, flame smoking is used for burning at a temperature exceeding 900°C, which suppresses the so-called increase in temperature while producing excessive amounts The production of harmful substances has less adverse effects on health.

In addition, liquid e-cigarettes are different from stick-type e-cigarettes. They do not contain tobacco ingredients, and can enjoy coffee, cola, Red Bull and other beverages, chocolate, vanilla, cream and other desserts, citrus, lemon, cantaloupe and other fruits, mint Novel smoking articles with various flavors such as cooling agents such as alcohol, mint, and herbs (Non-Patent Document 2). Specifically, it is an electronic cigarette in which volatiles evaporated by heating a liquid mixed with fragrances in propylene glycol and vegetable glycerin are inhaled (Non-Patent Document 2). Its biggest feature is that no harmful substances are added at all, and no tar or nicotine is produced. You can enjoy all kinds of flavors. In fact, all kinds of liquids for electronic cigarettes are currently on sale.

Based on these two types of electronic cigarettes, an electronic cigarette that combines the characteristics of the two has been developed (Patent Document 4). As described above, because the conventional rod-type electronic cigarette is heated and processed into a rod-shaped aerosol-forming substrate that contains tobacco components, although a small amount, harmful substances and tar or nicotine are also generated. Therefore, Patent Document 4 discloses a stick-type electronic cigarette that uses a stick-type electronic cigarette that does not contain tobacco components as the subject. That is, this stick-type electronic cigarette uses non-tobacco plants that only produce aromas that can stabilize the body and mind by smoking and have an effect on the promotion of health and beauty instead of tobacco components, and blend aerosol generating agents, flavors, Stick-type electronic cigarettes such as binding agents.

However, the stick-type e-cigarette using this non-tobacco plant is different from the liquid-type e-cigarette However, it is necessary to process the aerosol-forming substrate into a rod shape and fix the formulation without falling off. However, because it contains a large amount of the aroma component of the aroma "flavor" that can be strongly felt in the whole oral cavity when the aerosol formed by volatilizing together with the aerosol generating agent is sucked, it is generally fiber Less, making it difficult to fix these materials. Therefore, the stick-type electronic cigarette is difficult to make the whole oral cavity feel the strong taste or refreshing sensation such as the liquid-type electronic cigarette. Along with this, stick-type electronic cigarettes cannot limit the type of taste.

This rod-shaped aerosol forms a problem inherent to the substrate, and is still considered to be a rod-shaped electronic cigarette containing conventional tobacco ingredients. For example, Patent Document 1 describes the use of a tobacco sheet for aerosol-forming substrate containing at least an aerosol generating agent, flavor, binder, and tobacco material, but the tobacco sheet uses tobacco produced during tobacco processing The leaf, tobacco stem, tobacco dust, and/or the main leaf blade of the tobacco leaf are used as tobacco materials and contain at least 50% by weight. In addition, Patent Document 2 describes an aerosol-forming substrate composed of thin filaments containing at least an aerosol generating agent, a flavor, a binder, and a tobacco material, but the filaments contain at least 75% by weight or more of the tobacco material.

As such, the stick-type e-cigarette must be processed into a stick-shaped aerosol-forming substrate. Therefore, the inherent problem is that it cannot be prepared in large quantities and contains a large amount of aerosols that are generated when they are volatilized together with the aerosol-generating agent. To the materials or fragrances of the aroma components of the aroma "flavor" felt by the whole mouth, the inhaled "flavor" is complicatedly mixed with the aroma components produced by heated tobacco leaves or non-tobacco plants, and Contains a large amount of aroma components that make people feel "flavor" or aroma components of spices.

【Prior Technical Literature】

【Patent Literature】

[Patent Document 1] JP 2010-520764 Publication

[Patent Document 2] JP 2013-519384 Publication

[Patent Document 3] JP 2016-538848 Publication

[Patent Document 4] Japanese Patent No. 6371928

【Non-Patent Literature】

[Non-Patent Document 1] "Eight popular e-cigarettes! Explanation of types of e-cigarettes for beginners", Digmo homepage, https:digmo.infoseek.co.jp/articles-410

[Non-Patent Document 2] "E-cigarette case recommendation ranking|15 delicious and smokable popular products", Customlife homepage, https://customlife-media.jp/electronic-cigarette-liquid

[Non-Patent Document 3] "Knowledge of coffee beans-the taste of coffee changes due to roasting", coffee market BanCa homepage, http://www.coffee-banca.jp/user_data/bits_of_knowledge3.php

[Non-Patent Document 4] "Healthy tea made from coffee leaves", Nikkei, March 26, 2019

Stick-type e-cigarettes are different from liquid-type e-cigarettes. They must be processed into a rod-shaped aerosol to form a base material, and the formulation will not fall off and be fixed, but because it contains a large amount of gas formed by volatilizing with the aerosol generator It can be felt strongly when sol is felt in the whole mouth The material of the aroma component of the aroma "flavor" is generally low in fiber and difficult to fix, so it must be fixed by adding tobacco leaves or non-tobacco plants. As a result, stick-type e-cigarettes have the "flavor" that can be smoked. They are complicatedly mixed with aroma components produced by heating tobacco leaves, or non-tobacco plants, and materials or materials that contain a large amount of aroma components that make people feel the "flavor". The problem of the aroma components of spices makes it difficult to make the whole oral cavity feel the strong taste or cooling sensation such as liquid electronic cigarettes. Along with this, stick-type electronic cigarettes cannot limit the type of taste.

The purpose of the present invention is to provide a method that solves such a problem and is completely free of tobacco of the Nicotiana genus Solanaceae and its genus and its components, and can make people feel the "flavor" strongly for forming a stick-shaped heated aroma A composition that generates a substrate, a rod-shaped heated aroma generating substrate using the composition, and an aroma box using the rod-shaped heated aroma generating substrate.

In more detail, the rod-shaped heated aroma generating substrate composition of the present invention is used to form a rod-shaped heated aroma generating substrate containing an aerosol generating agent that generates aerosol by heat transferred from a heat source The composition is characterized in that it contains an aerosol generating agent, a heating rod-shaped heated aroma generating substrate, and at the same time when the aerosol is inhaled, it releases the aroma component that is the flavor of the fragrance in the mouth, and the host contains The material of the aroma component is an adsorbent for the liquid component of the aroma component. Furthermore, the present invention provides a rod type heated aroma generating substrate using the composition, and an aroma box using the rod type heated aroma generating substrate.

Furthermore, the base material on which the aerosol generating agent that generates the aerosol is volatilized by inserting a heating element to heat it is generally called "aerosol forming base material". "However, because the smoke of the aerosol and the aroma of the fragrance material or fragrance are enjoyed by smoking, it is called "heated fragrance generating substrate" in the present invention. Based on this, the aggregate of aerosol-forming substrates is called "heated aroma source", which will have aerosol The "e-cigarette", "e-cigarette case", and "box" from which the glue is produced are called "aroma box", and the "smoking appliance" equipped with the heating element for smoking with the "aroma box" is called "aroma box" With".

In particular, the aroma box of the present invention refers to a heated aroma generating base material that does not contain tobacco components and is composed of at least aerosol generating agents such as glycols or glycerols and materials containing aroma components, At least those with a cigarette holder and a stick rolled up by a packaging component. Therefore, this fragrance box is used to install a heated fragrance appliance with a heat source to suck the aerosol generating agent volatiles generated by heating from the cigarette holder The aerosol that looks like smoke formed by the cooling and condensation and the aroma component released by heating, and the aerosol smoke and aroma can be enjoyed in the mouth and nasal cavity. Although the operation is similar to that of paper cigarettes, the smoke and aroma are completely Different hobbies. Accordingly, the aroma box of the present invention can enjoy aromas not based on tobacco ingredients, but coffee, cola, red bull and other beverages, chocolate, vanilla, cream and other desserts, citrus, lemon, cantaloupe and other fruits, menthol, mint, Herbal plants and other cooling agents and other fragrances.

As a result of investigating the aroma components contained in various materials of various parts of angiosperms, the present inventors found that a large number of materials contain aroma components that are effective in improving health and beauty by smoking to stabilize the body and mind. It was discovered that the composition containing the aroma components constituting the material was hosted as an adsorbent, and the present invention was completed. Furthermore, it has been found that it is preferable to formulate a heated aroma generating substrate composition in which a material containing a large amount of the aroma component is used as the main component to be used for fixing the heated aroma generating substrate that can be processed into a rod shape. The holding material can improve the completion of the present invention.

That is, the present invention is used at least to form the heat produced by the heat transfer The composition of the rod-shaped heated aroma generating substrate of the aerosol generating agent of aerosol, and containing the aerosol generating agent, containing the heated rod-shaped heated aroma generating substrate, and emitting the aroma in the mouth when the aerosol is simultaneously sucked The material of the aroma component of the flavor, and the stick-shaped absorbing material containing the liquid component of the aroma component of the material containing the aroma component is heated to produce the base composition. More preferably, the rod-shaped heated aroma generating substrate of the present invention further includes a holding material for the heated aroma generating substrate that can be processed into a rod shape.

Such an adsorbent is preferably cross-linked polyvinylpyrrolidone (PVP) or silicon dioxide powder. In addition, preferably, chitosan, chitosan derivatives, activated carbon, alumina, activated clay, and zeolite can also be used. For cross-linked PVP, you can directly use the commercially available products represented by Divergan (registered trademark) made by BASF Europe, or Polyclar (registered trademark) VT made by ISP joint stock company. On the other hand, silicon dioxide powder can be widely used from the gas phase silicon dioxide which is mainly used to improve the rheological properties of inks or coatings. The primary particle diameter is tens of nanometers. From silica particles to true spherical silica particles with primary particle diameters of several μm, such as anti-sticking agents or matting agents for inks or paints, or reinforcing agents for paints or rubbers. However, the adsorbent of the present invention is preferably true spherical silica particles with a primary particle diameter of submicron level, that is, an average primary particle diameter of 0.1 to 1.0 μm. Examples of such silica powder include P10 (average primary particle diameter: 0.1μm) and P30 (average primary particle diameter: 0.1μm) of SEAHOSTAR (registered trademark) KE-S high-purity silica spherical fine particle powder manufactured by Nippon Shokubai Co., Ltd. Particle diameter: 0.3μm), P50 (average primary particle diameter: 0.5μm), and P100 (average primary particle diameter: 1.0μm), and Toagosei's functional spherical silica HPS-0500 (average primary Particle diameter: 0.5μm) and HPS-1000 (average primary particle diameter: 1.0μm), and submicron spherical silica micropowder HM051-11 manufactured by Powder Systems Co., Ltd. (Average primary particle diameter: 0.5μm) and so on. The surface of such silicon dioxide powder is a hydrophilic surface with high concentration of silanol groups. However, hydrophobized silicon dioxide powders such as alkylchlorosilanes or alkoxysilanes can also be used. In particular, when the aroma-containing material contains a large amount of lipophilic ingredients, it is preferably hydrophobized silica powder. Furthermore, silica powder used in general industrial products such as inks or paints is non-porous fine powder, but when used as a catalyst support or adsorption material, use pores of several nm to tens of nm. Porous silica powder with extremely large specific surface area. Therefore, the silica powder of the present invention is preferably also porous silica powder. Chitosan, chitosan derivatives, activated carbon, alumina, activated clay, and zeolite are preferably used in powder form. As the zeolite, any one of natural zeolite and artificial zeolite can be used, and preferably, zeolite processed into spherical, granular, and hollow filament shapes can also be used.

Such an adsorbent, in the heated aroma generating substrate made of the composition of the present invention, contains the liquid component of the aroma component of the aroma component-containing material, that is, it fulfills the following function: making the aroma component-containing lipophilicity Ingredients, hydrophilic ingredients containing aroma components are hosted, and aroma components with hydrophilic groups such as hydroxyl groups, ether bonds, ester bonds, etc. are temporarily adsorbed and fixed, and the lipophilic and hydrophilic components with aroma components dissolved therein are maintained; When heated during smoking, the aroma components quickly volatilize together with the aerosol generating agent.

The mechanism for achieving such a function is still uncertain, but in the case of cross-linking PVP, it is assumed that there are lipophilic parts of the network formed by the hydrocarbons constituting the backbone, and hydrophilic parts of pyrrolidone bonded to the side chains. Achieve the function of emulsifying lipophilic components and hydrophilic components of the protective colloid. On the other hand, in the case of silicon dioxide powder, it is believed that a high concentration of silanol groups on the surface adsorb the hydrophilic components, so that the lipophilic components form a continuous layer, and the hydrophilic components form a discontinuous layer. The result of the emulsified state of the protective colloid. this In addition, the porous silica powder is considered to be deeply related to the adsorption energy of the huge specific surface area with a large number of fine pores. From this point of view, chitin and its derivatives are polymer electrolytes with amine groups and have the same mechanism as cross-linked PVP. Next, it is believed that the hydroxyl groups present in large quantities on the surface of alumina have the same effect as silica, and activated clay and zeolite, with the adsorption energy of the large specific surface area with fine pores, and porous silica powder Has the same effect.

Cross-linked PVP, silica powder, chitin, chitin derivatives, activated carbon, alumina, activated clay, and zeolite, etc., have important functions as such an adsorbent, and have no aroma even if heated The ingredients have the advantage of not having any adverse effects on the aroma components produced from the aroma components and the flavor felt in the mouth.

Next, the aroma-containing material must be contained in 5-50% by mass of the total mass of the rod-shaped heated aroma generating substrate composition. If it is less than 5% by mass, the flavor that is felt in the oral cavity when the rod-shaped heated aroma-generating substrate composition is made from the rod-shaped heated aroma-generating substrate composition is heated and sucked. If it exceeds 50% by mass, Since the aroma-containing material has less fibers and the aroma-containing liquid component is large, the aroma-containing material is generated in the step of forming the rod-shaped heated aroma generating substrate composition into a rod-shaped heated aroma generating substrate. The material of the component has problems such as falling off or cracking. In addition, when the rod-shaped heated aroma generating substrate is heated and sucked, there is also the problem of preventing the passage of volatiles.

In order to host the liquid component containing the aroma components contained in the material containing the aroma components prepared in this way, the blending ratio of the aroma component-containing material and the adsorbent is preferably about 1:1 to 43:1 (mass ratio). When the adsorption material is less than 43:1, there is a problem that the liquid component containing the aroma component cannot be fully accommodated, and the liquid component containing the aroma component is separated; when the rod type is heated In the step of forming the aroma-generating substrate composition into a rod-shaped heated aroma-generating substrate, the material containing the aroma component may fall off or break; and when the rod-shaped heated aroma-generating substrate is heated and sucked , The problem of preventing the passage of volatiles. Conversely, when there are more adsorbents than 1:1, the adsorbent has a strong ability to retain water by bonding with hydrogen, so there is a problem of increased drying time.

In addition, with regard to the total amount of the aerosol generating agent, the aroma-containing material and the adsorbing material, the aerosol generating agent, the aroma-containing material and the adsorbing material, the preferred blending ratio is about 1.9 :1~1:1 (mass ratio). In this blending ratio, when heated and smoked as a rod-shaped heated aroma generating base material, moderate smoke similar to a paper cigarette can be produced.

Furthermore, it is preferable to contain 5-25 mass% of water of the total mass of the main composition of the rod-shaped heated aroma generating base material. As water, tap water, boiling water, distilled water, ion-exchange water, etc. can be used, but the production method is not limited, and general pure water is preferably used. If it is less than 5% by mass, in the step of forming the rod-shaped heated aroma generating substrate composition into a rod-shaped heated aroma generating substrate, there is a problem that the aroma component-containing material may fall off or crack. If it exceeds 25% by mass, the viscosity of the rod-shaped heated aroma-generating substrate composition is too low, the molding process of the rod-shaped heated aroma-generating substrate is difficult, and the drying time increases.

In this way, the composition used to form the rod-shaped heated aroma generating substrate of the present invention contains at least an aerosol generating agent, a fragrance component-containing material that releases the fragrance (flavor) from the mouth when inhaled at the same time as the aerosol , And an adsorbent that hosts a liquid component containing an aroma component of a material containing this aroma component, but the fourth component is more preferably a holding material that fixes the aerosol generating agent, aroma component-containing material, and adsorbent . With this retaining material, not only can it be further stabilized The rod-shaped heated aroma generating substrate is fixed and manufactured, and the aerosol generating agent that heats the rod-shaped heated aroma generating substrate and volatilizes together with the aroma components can pass through the rod-shaped heated aroma generating substrate without hindrance. And enjoy the flavor of smoking that calms the body and mind.

That is, the present invention is a composition for forming a rod-shaped heated aroma generating base material containing aerosol generating agent that generates aerosol by heat transmitted by a heat source, and further preferably contains an aerosol generating agent; Type is heated by the aroma-generating substrate, and when the aerosol is inhaled, the aroma (flavor) is released from the mouth to the aroma-containing material; the liquid component containing the aroma of the aroma-containing material is used to host the absorbent material ; And a holding material for fixing aerosol generating agents, aroma-containing materials, and adsorbing materials.

The holding material is preferably a non-tobacco material containing 30% by mass or more of fiber (cellulose) by dry mass. In this way, non-tobacco materials containing a large amount of fibers have high ability to fix aerosol generating agents, aroma-containing materials, and adsorbents, which can solve the problem of forming a rod-shaped heated aroma generating substrate composition into a rod-shaped quilt. In the step of heating the aroma-generating substrate, the aroma-containing material may fall off or crack. In addition, since there are few components other than fibers, it has the advantage of less volatilization of unnecessary aroma components when the aroma generating substrate is heated in the shape of a heating rod, and the flavor that can be enjoyed in the mouth is only the aroma of the aroma components containing materials . The fiber itself, the so-called cellulose, has a decomposition temperature of about 350°C and is mixed with aerosol generators that volatilize at 200 to 250°C, so there are almost no volatile components.

Furthermore, it is more preferable to use a non-tobacco plant with a fiber diameter of 10-50 μm. The reason is that the finer the fiber diameter, the higher the ability to fix the aerosol generating agent, the aroma-containing material, and the adsorbent. However, the lower limit of this fiber is based on the diameter of the thinnest plant fiber, not set intentionally.

The fiber is a non-tobacco plant containing more than 30% by mass based on the dry mass. Examples include the stems and leaves of the Acerola Linaceae, the stems and leaves of the Urticaria Urticaceae, the stems and leaves of the Malvaceae Malvaceae, and the rose The stems and leaves of the Cannabis family, the stems and leaves of the Zingiberaceae Musaceae, the stems and leaves of the Asparagus Asparagus plants, the stems and leaves of the Gramineae Gramineae, the stems and leaves of the Gramineae Cyperaceae, the grass rush The stems and leaves of the Gramineae plants, the stems and leaves of the Grainaceae plants, the stems and leaves of the Gramineae Typhaeaceae plants, the stems and leaves of the Gramineae bromeliad plants, the mushrooms (umbrella, gills, stipe, fungus ring, Bacteria), cotton, bark of Myrtaceae plants, and bark of Rosales Moraceae plants, can be used individually or in plural.

Specific examples of plants of the Acerolata Linaceae, Urtica Urticaceae, Malvaceae Malvaceae, Rosales Cannabisaceae, Ginger Musaceae, and Asparagus Asparagus plants, including flax, ramie, jute, hemp Hibiscus, hemp, manila hemp, and sisal hemp, etc. Specific examples of gramineous plants in the Gramineae order include rice, barley, wheat, rye, coix, rye, sorghum, corn, millet, sugarcane, millet, goosegrass, miku, paspalum, Japanese barnyard, and Forney Omi (Digitaria exilis), rice white, spartina, Chinese awn, Spanish grass (esparto), lingfeng grass, red bamboo, and bamboo. Specific examples of plants of the Cyperaceae of the order Gramineae, Juncusaceae of the order Gramineae, Esseriaceae of the order Gramineae, Typhaceae of the order Gramineae, and bromeliaceae of the order Gramineae, include sedge, lepidoptera dimorpha, wan, and divergence. , Rushes, glutinous grass, cattails, and pineapples.

Specific examples of mushrooms include edible matsutake, white mushroom, honey fungus, hongxi mushroom, lotus leaf fold umbrella, jade mushroom fold umbrella, night oyster mushroom, Xiuzhen mushroom, shiitake mushroom, golden brown umbrella, red Brown amanita, stropharia, brick red scorpion mushroom, scorpion mushroom, golden linoleum, sticky scale, tetrasporus mushroom, wild mushroom, oyster mushroom, crispy stalk mushroom, lamina frondosa, purpura , Cortinarius lotus , Cortinarius bright, Boletus edulis, Boletus hiratukae ( Boletus hiratukae ), Boletus purple, Boletus edulis, White mushroom, Lactarius succulent, Lactarius red, Truffle ( Rhizopogon) roseolus ), Boletus edulis, Pleurotus ostreatus, Boletus edulis, Ganoderma lucidum, Toothricin volvulus, Mycoleptodonoides aitchisoni i, Hericium ramosum ( Hericium ramosum ), Shiitake mushroom, Fungus, Hairy fungus , Western truffle, large pellicle fungus, white ghost pen, reticulated puffball, and reticulated puffball. Cotton is a fiber taken from the seeds of cotton, a perennial herb of the genus Cotton of the Malvaceae Malvaceae. Specific examples of plants in the Myrtaceae and Rosales of the Moraceae family include jasmine, goose skin, and chu, etc.

In the above-mentioned specific example, the stems, leaves and bark of non-tobacco plants other than mushrooms containing 50% by mass or more of fiber by dry mass, and more preferably cotton. However, fungus contains more than 50% fiber and can be used preferably. Furthermore, the fiber diameter is 10-50 μm, the stems, leaves and bark of non-tobacco plants other than ramie, and it is still more preferably cotton. In particular, flax, jute, hibiscus, hemp, manila hemp, and sisal, rice, barley, wheat, rye, coix, rye, sorghum, corn, millet, sugarcane, millet, goosegrass , Migu, Paspalum, Japanese barnyard, Digitaria exilis , Zizania, Spartina, Chinese awn, Spanish grass (esparto), Great ling wind grass, red bamboo, bamboo, sedge, two-shaped scales The stems and leaves of grass, wan, divergent stalk grass, rush grass, glutinous grass, cattail, and pineapple.

In the case of using such a holding material, for the same reason as in the case of not using the holding material, the aroma-containing material must be contained in 5-50 mass of the total mass of the main composition of the rod-shaped heated aroma generating substrate %. Next, the blending ratio of the aroma-containing material to the adsorbent material and the retaining material is preferably about 1:1:2 to 43:1:5 (mass ratio). As a result of various studies, it was found that if the mixing ratio is within this range, the adsorbent can not fully host the liquid component containing the fragrance component (the liquid component containing the fragrance component is separated); In the step of forming the substrate composition into a rod-shaped heated aroma producing substrate, the aroma-containing material is degraded The problem of falling or cracking; and the problem of obstructing the passage of volatiles when the rod-shaped heated aroma generating substrate is heated and sucked are all solved. In addition, it was confirmed that the aroma components produced by heating the aroma component-containing materials have no adverse effect on the flavor felt in the oral cavity.

When the holding material is used, it can be used as a rod-shaped heated aroma generating substrate to heat and smoke, and produce moderate smoke similar to paper cigarettes. The amount of aerosol generating agent, and the combination of the aerosol generating agent and aroma components The blending ratio of the total amount of the material, the adsorbing material, and the holding material is preferably 2:1~0.3:1 (mass ratio).

Next, the amount of water necessary to process the rod-shaped heated aroma generating substrate composition into a rod-shaped heated aroma body is the same as the case without using the holding material, if it is the main composition of the heated aroma generating substrate 5-25% by mass of the total mass of the object, there will be no problems such as peeling or cracking of the aroma-containing material; the stick-shaped heated aroma-generating substrate composition has too low viscosity, and it is difficult to form a rod-shaped quilt. The problem of heating the aroma to produce the substrate; and the problem of increasing the drying time.

In this way, in order to use a material containing a large amount of aroma components to produce a rod-shaped heated aroma generating substrate, it is necessary to add an adsorbent to the composition used to produce it, and further, it is more preferable to add a holding material. The reason is clear from the following specific materials containing a large amount of aroma components. A material containing a large amount of aroma components contains a large amount of liquid components containing aroma components and contains almost no fiber.

As described later, in order to produce a rod-shaped heated aroma generating substrate, there are steps of pulverizing a material containing a large amount of aroma components, a step of dispersing the pulverized material in water, and a step of forming a sheet from the dispersion. In each of these steps, since the liquid component containing the aroma component is precipitated from the material containing a large amount of aroma component, if there is no adsorbent for the liquid component, the Fragrance components and/or liquid components are separated, and the material containing the fragrance components falls off or cracks, and there is a problem in forming a sheet, etc. In addition, even if the rod-shaped heated aroma generating substrate is heated and sucked, it is difficult for the aroma components and the volatile components of the aerosol generating agent to pass through. Among these, the liquid component containing the aroma component is the same in the case of the lipophilic component and the case of the hydrophilic component, but it is more prominent in the case of the lipophilic component.

If the holding material is added, the holding material fixes the aerosol generating agent, the aroma-containing material, and the adsorbing material, so it can solve the problem that the aroma-containing material falls off or breaks and cannot be formed into a sheet. In addition, the fiber makes moderate voids, and volatile components can easily pass through by suction. In addition, even if the fiber is heated, the aroma components produced from the aroma component materials have little adverse effect on the flavor felt in the oral cavity.

In this way, materials containing a large amount of aroma components that are difficult to manufacture and process with a rod-shaped heated aroma producing substrate include angiosperm fruit seeds, angiosperm fruit pulp, angiosperm fruit peel, angiosperm fruit, and herbaceous plants The stems and leaves can be used individually or in plural, and adjust the flavor that can be felt in the mouth.

Specifically, the seeds of angiosperm fruits include, for example, Australian walnuts, hazelnuts, chestnuts, walnuts, almonds, pecans, cashews, pistachios, Brazil nuts, coffee beans, cocoa beans, vanilla beans, nutmeg, cola Seeds of fruit, peanuts, dill, cumin, juniper, caraway, celery, cardamom, fennel, fenugreek, parsley, Indian fennel, and anise, etc.

Even if it is the seeds of angiosperm fruit, Australian walnuts, hazelnuts, chestnuts, walnuts, almonds, pecans, cashews, pistachios, Brazil nuts, coffee beans, cocoa beans, nutmeg, The seeds of kola nuts and peanuts are better used for baking. It is to increase the aroma components by thermally decomposing the constituent components of the seeds by baking. E.g, In the case of coffee beans, caffeic acid or quinic acid, which is decomposed by chlorogenic acid, and acetic acid or lactic acid, which is decomposed by oligosaccharides, are analyzed to increase aroma components (Non-Patent Document 3).

On the other hand, in the seeds of angiosperm fruits, there are also those that increase aroma components through fermentation. In particular, vanilla beans are preferably fermented.

A large amount of oils containing such lipophilic components and seeds with few fibers, even when used as materials containing a large amount of aroma components, due to the emulsification effect of the cross-linked PVP of the adsorbent, or the water absorption function of the silica powder, And the fixing function of the holding material works extremely effectively, so it can fully host the liquid ingredients containing the aroma components. Thereby, it is also possible to solve the separation of the liquid component containing the aroma component, and the falling off of the aroma component-containing material when the rod-shaped heated aroma generating substrate composition is formed into a rod-shaped heated aroma generating substrate. Or the problem of cracking of the substrate when the rod is heated, or the problem of obstructing the passage of volatiles when the rod is heated and sucked.

The pulp of angiosperm fruit also contains a lot of aroma components. Specifically, western pears, Japanese pears, Chinese pears, peaches, fruits of citrus plants of the Rutaceae family of Sapindus, apple, banana, pineapple, mango, and passion fruit , Kiwi, guava, durian, mangosteen, papaya, carambola, lychee, watermelon, muskmelon, apricot, cherry, papaya, cantaloupe, cantaloupe, strawberry, raspberry, blueberry, blackcurrant, grapevine grape Pulp of grapes of the genus of wine grapes ( vinifera ) and grapes of the American grapes ( labrusca ) of the grape family Vitis. In particular, the fruits of the citrus plant of the Rutaceae family Sapindus are preferably the late summer orange, Wenzhou mandarin, grapefruit, lemon, lime, and Iyo mandarin.

In addition, the peel of the fruit contains a lot of aroma components above the pulp. In particular, it is preferable that the late-lun summer orange, Wenzhou orange, grapefruit, lemon, lime, and Iyo orange are Representative of the fruit peel of the fruit of the citrus genus of the Rutaceae family of Sapindus.

The fruit of angiosperm is preferably the fruit of coriander, allspice, star anise, and pepper.

In addition, the stems and leaves of herbaceous plants, particularly preferably stems and leaves of tarragon, basil, rosemary, and lavender, as well as allspice, oregano, thyme, dill, parsley, and Lamiaceae Spicy mint plants of the genus Labiatae, spearmint plants of the genus Labiatae Lamiaceae, lemon balm, hyssopus, European mint, marjoram, lemongrass, bay leaf, medicinal sage , And the leaves of lemon verbena.

Furthermore, for materials containing aroma components, seeds that produce Australian walnuts, hazelnuts, chestnuts, walnuts, almonds, pecans, cashews, pistachios, Brazil nuts, coffee beans, cocoa beans, nutmeg, and kola nuts can be used The leaves of the plant. In particular, coffee leaves contain trigonelline, which activates brain nerves, and mangiferin, which has antioxidant effects, and can be preferably used as materials containing healthy aroma components (Non-Patent Document 4).

When the pulp, peel, and whole fruit of such angiosperms are used as a material containing a large amount of aroma components, the aroma components contained in these are also lipophilic and less fiber, so the adsorbent and holding materials are it works. In particular, since the pulp of the fruit also contains a large amount of water, the need for the adsorption material of cross-linked PVP or silica with the function of holding water, and the fixing function of the holding material has increased.

On the other hand, an aerosol generating agent is used to form the indispensable smoke of the rod-shaped heated aroma generating substrate of the present invention. Because of the addition of an adsorbent and a holding material, even if it is a material that contains a large amount of aroma components and has few fibers , Can be used singly or in plurals to use commonly used propylene glycol, 1,3-butanediol, sorbitol, ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, propylene glycol Alcohol, lactic acid, glycerol monoacetate (monoglyceride acetate), glycerol diacetate (diglyceride acetate), glycerol triacetate (triglyceride acetate), triethylene glycol diacetate, triethyl citrate , Isopropyl myristate, methyl stearate, dimethyl dodecanedioate, dimethyl myristate. In particular, it is preferable to use glycerol diacetate (glycerol diacetate) selected from propylene glycol, ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, glycerol, glycerol monoacetate (glycerol monoacetate), ester).

In the rod-shaped heated aroma generating substrate composition of the present invention, it is preferable to further add a thickening agent. This tackifier has the function of adjusting the viscosity of the composition for forming the rod-shaped heated aroma generating substrate composition into a rod-shaped heated aroma generating substrate and assisting in holding the material.

In particular, the thickener is preferably selected from konjac mannan (glucomannan), Guanhua bean gum, pectin, carrageenan, tamarind gum, acacia gum, and soybean Polysaccharides, locust bean gum, Indian tragacanth gum, Sanxian gum, and Hantian, as well as methyl cellulose, ethyl cellulose, carboxymethyl cellulose, carboxyethyl cellulose, which are cellulose polymers, One or more of hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, and sodium, potassium, and calcium salts of carboxymethyl cellulose and carboxyethyl cellulose, but more preferably From one or more of sodium, potassium, and calcium salts of carboxymethyl cellulose, carboxyethyl cellulose and carboxymethyl cellulose, and carboxymethyl cellulose and carboxyethyl cellulose. Such a thickening agent, like fiber, is a kind of polysaccharide, and has no adverse effect on the flavor of the aroma components generated from the aroma component-containing materials by heating.

The amount of thickener used needs to be adjusted appropriately according to the material containing a large amount of aroma components, but only 1.0~5.0% by mass of the thickener based on the total mass of the main composition of the rod-shaped heated aroma generating substrate can be added.

From the standpoint of the auxiliary adsorbent, in particular, to simultaneously host aroma components having hydroxyl groups, it is preferable to add β-cyclodextrin, which is a cyclic compound of dextrin having hydroxyl groups, as an adsorption auxiliary. Conventional β-cyclodextrin not only uses the bond between hydroxyl and hydrogen, but also due to the particularity of the cyclic structure, menthol is used as the guest molecule and β-cyclodextrin as the host molecule, and it is combined with menthol. Connect the compound. It does not need to be added in large amounts, and it can be 0.2 to 1.0 mass% of the total mass of the main composition of the rod-shaped heated aroma generating substrate. This β-cyclodextrin is also a kind of polysaccharide, and it has no adverse effect on the flavor of the aroma components produced from the aroma component-containing materials by heating.

In addition, for the purpose of an auxiliary holding material, it is preferable to add microcrystalline cellulose to the rod-shaped heated aroma generating base composition. Thereby, the subsequent forming process can be performed more stably. As described later, after the step of forming the rod-shaped heated aroma generating substrate composition into a rod-shaped heated aroma generating substrate sheet, in order to better suck the aroma components or aerosol, the sheet is cut It is the steps of prismatic, cylindrical, and granular shapes, and then, the steps of rolling the packaging parts into rods. These forming methods can use roll forming or press forming, but either of them will cause a load on the composition due to the strong compression force generated by metals such as stainless steel. At this time, due to this compressive force, agglomeration failure of the composition, adhesion to the metal, etc. occur, and the forming process is difficult. As a method for solving such problems, it is preferable to add microcrystalline cellulose.

For a long time, the pulp is hydrolyzed and refined with high purity microcrystalline cellulose. It is a fluid powder that cannot be dissolved in organic solvents such as water and ethanol. It can be used as an excipient for the formation of medical tablets. . The reason is that due to the fluidity of microcrystalline cellulose and the high compressibility due to large changes in volume, the prevention of agglomeration failure in the formation of tablets by the direct-punching method, and the metal mold It is effective to prevent the attachment of tools. In the present invention, microcrystalline cellulose can also be added, for example, in sheet forming by three-roller roll forming, or in sheet cutting of press forming, etc., to effectively prevent the agglomeration and destruction of the sheet and metal的Attachment.

The average particle diameter of the microcrystalline cellulose is preferably 30~200μm, and it can be added to the extent that it can assist in holding the material, and it is preferably added to 1.0~ of the total mass of the main composition of the rod-shaped heated aroma generating substrate. 5.0% by mass. Microcrystalline cellulose also has no adverse effect on the taste of aroma components produced from aroma components containing materials by heating.

In addition, the rod-shaped heated aroma-generating base composition using various parts of non-tobacco plants is preferably added with an antibacterial preservative, and the rod-shaped heated aroma-generating base composition is added to 0.005 to the total mass of the main composition. 0.04% by mass is sufficient. The antibacterial preservative is preferably potassium sorbate and/or sodium benzoate.

Finally, the rod-shaped heated aroma generating substrate composition of the present invention can also be formulated with inorganic particles. The heated aroma generating substrate made by adding inorganic particles has less dirt attached to the heat source of the heated smoking article than the heated aroma generating substrate without adding inorganic particles. The compounding amount is preferably 0.05 to 10 parts by mass, more preferably 0.1 to 5 parts by mass relative to the total mass of the main composition of the rod-shaped heated aroma generating substrate.

This effect does not limit the material or particle diameter of the inorganic particles. Metal oxides such as magnesium oxide, calcium oxide, titanium oxide, iron oxide, and aluminum oxide can be used; metal carbonates such as magnesium carbonate and calcium carbonate; and calcium phosphate, etc. Metal phosphate; titanate such as calcium titanate and magnesium titanate; further, silica such as zeolite, colloidal silica, fumed silica, etc. can also be used. Among them, magnesium carbonate, calcium carbonate, silica, and alumina are preferred. The reason for this has not been confirmed, but it is believed that the inorganic particles grind the surface of the heat source when they are separated from the heat source, and reduce the difference between the heat source and the heated aromatic body during heating. Contact area, etc.

Above, the rod-shaped heated aroma generating substrate composition is described in detail. The material constituting the composition is used to form the rod-shaped heated aroma generating substrate in the next step and then assembled into an aroma box.

The materials containing the used aroma components are sterilized at high temperature and crushed. In this step, when a holding material is used, it is similarly sterilized at high temperature and crushed. Next, the material and the adsorbent containing a predetermined amount of aroma components are dry mixed with a dry mixer such as a drum mixer. Next, a predetermined amount of aerosol generating agent and pure water are added to the dry-mixed raw materials, and wet-mixed with a wet mixer such as a kneader. In this step, a predetermined amount of retaining material, thickener, β-cyclodextrin, microcrystalline cellulose, antibacterial preservative, and inorganic particles are wet-mixed according to needs. This dispersion liquid is formed into a sheet by three-roller roll forming. This sheet is cut into a column shape, and after being rolled up with a packaging member, it is cut into a predetermined length and formed into a rod. The rod thus manufactured is dried, installed on the multiple ends of the supporting parts with cigarette holders, and assembled into a fragrance box with packaging parts. This step is in accordance with the manufacturing steps of the conventional stick-type electronic cigarette case. As a result, a rod-shaped heated aroma body characterized by using the rod-shaped heated aroma generating substrate composition of the present invention is obtained, and an aroma box characterized by using a rod-shaped heated aroma body is obtained.

According to the present invention, there is no need to contain tobacco ingredients. Like the liquid type, you can enjoy various flavors such as coffee, cola, red bull and other beverages, chocolate, vanilla, cream and other desserts, citrus, lemon, cantaloupe and other fruits, menthol, mint, and herbs Cooling agents for plants, etc. A stick-type electronic cigarette can be provided, which is completely free of tobacco of the Nicotiana genus Solanaceae and its plants of the same genus, and its components In this case, it is possible to strongly feel the "flavor" of the aroma felt throughout the oral cavity when the heated aroma-generating substrate is heated and the aerosol is inhaled simultaneously, and it has a high similarity to conventional paper cigarettes Type and smoking method.

Therefore, the present invention is not only for those experienced in flame smoking, but for first-time smokers, they can also enjoy coffee, cola and other beverages, chocolate, vanilla, cream and other desserts, citrus, lemon, Various "flavors" such as fruits such as cantaloupe, menthol, mint, herbs and other cooling agents, and stabilize the body and mind.

Furthermore, since the present invention is derived from the harmless aroma of tobacco and the same genus of Nicotiana solanaceae, and plants of its constituents, it has the advantages of not only smokers themselves, but also non-smokers around them. Health does not cause adverse effects.

Therefore, the present invention can provide a novel aroma box, which is not intended to replace the conventional stick-type electronic cigarette, but to enjoy coffee, cola and other beverages, chocolate, vanilla, cream and other desserts, citrus, lemon under the feeling of smoking Various "flavors" such as fruits such as cantaloupe, menthol, mint, herbal plants and other cooling agents, bring the healing effect of alpha waves in the brain, which is beneficial to the improvement of health and beauty.

100, 101: Aroma Box

110: heated aroma source

111: Shredded into angular columnar shape and filled with heated aroma producing substrate

1111: Separate body of heated aroma generating substrate

1112: Heated aroma produces substrate aggregate

1113A: The gas channel in the heated aroma producing substrate aggregate

1113B: The gas channel between the heated aroma producing substrate aggregates

1113C: Separate body of heated aroma generating substrate-gas channel between heated aroma generating substrate aggregates

1113D: Gas passage between heated aroma producing substrate and packaging material

120: Supporting parts

121: Supporting part center

122: Peripheral part of support member

122A: Peripheral part of the first support member

122B: Peripheral part of the second support member

130: Cooling parts

140: cigarette holder

150: packaging parts

200: heated smoking device

210: Installation part of heated smoking device

211: Heat Source

L: length of supporting part

D: The diameter of the supporting part

d: The distance between the periphery of the first support member and the periphery of the second support member

[Fig. 1] A schematic diagram of the manufacturing steps of an aroma box using a rod-shaped heated aroma generating substrate in one embodiment of the present invention.

[Fig. 2] A representative oblique view showing the appearance of an aroma box using a rod-shaped heated aroma generating substrate in an embodiment of the present invention.

[Figure 3] (A), an embodiment of the present invention cut along the line A-A in Figure 2, using the The rod-shaped heated aroma generating substrate, the supporting member, and the cigarette holder are connected in sequence, and the rod-shaped heated aroma generating substrate is rolled up by the packaging member. A cross-sectional representative view of the aroma box of the heated aroma generating substrate; (B), along Figure 2 One embodiment of the present invention cut off the AA line uses a rod-shaped heated aroma generating substrate, a support member, a cooling member, and a cigarette holder to be connected in sequence, and the rod-shaped heated aroma is generated by a packaging member. A representative drawing of the cross section of the fragrance box of the base material.

[Fig. 4] An embodiment of the present invention is a representative cross-sectional view of a rod-shaped heated aroma generating base material in which a heated aroma generating base material cut into corners is rolled up by a packaging member.

[Figure 5] One embodiment of the present invention is a cross-sectional representation of a typical heated smoking appliance using an aroma box using a rod-shaped heated aroma generating substrate.

[Fig. 6] One embodiment of the present invention, from the perspective of the X direction, is a plan view of the supporting member of Fig. 3(A) installed in the aroma box using a rod-shaped heated aroma generating substrate.

[Fig. 7] One embodiment of the present invention, a side view of the supporting member shown in Fig. 3(A) when viewed from the Y-direction perspective, mounted on the aroma box using a rod-shaped heated aroma generating substrate.

Hereinafter, the present invention will be explained in more detail using implementation forms, but the present invention is not limited to these, and various changes and implementations can be made without departing from the spirit of the present invention, and are limited only to those with technical concepts described in the scope of the patent application. .

"raw material"

The raw material of the main composition of the rod-shaped heated aroma producing substrate. Roasted coffee beans are used as the material for the oil containing a large amount of lipophilic components containing aroma components, cross-linked PVP is used as the adsorbent, and the dried rice straw is used as the holding material. As aerosol generators, propylene glycol and diethylene glycol. additive The raw materials are Sanxian gum as a thickener, β-cyclodextrin as an adsorption aid, potassium sorbate as an antibacterial preservative, and pure water for water.

"Manufacturing of rod-shaped heated aroma generating substrate composition"

Follow the manufacturing steps of M1~M4 in Figure 1. In step M1, the roasted coffee beans and straws are dried and crushed. In the M2 step, a predetermined amount of crushed roasted coffee beans and straws, cross-linked PVP, aerosol generator, Sanxian gum, β-cyclodextrin, potassium sorbate, and pure water are weighed. Then, in the M3 step, the pulverized roasted coffee beans, straws, and cross-linked PVP are dry-mixed using a drum mixer, and then in the M4 step, the aerosol generator, Sanxian gum, and β-cyclodextrin are added , Potassium sorbate, and pure water are wet-mixed using a kneader to produce a rod-shaped heated aroma generating base composition.

"Manufacturing of rod-shaped heated aroma generating substrate"

The rod-shaped heated aroma generating substrate composition thus manufactured is formed into a sheet with a thickness of 0.28 ± 0.02 mm by using three rollers in the M5 step. In the M6 step, the thus formed sheet is cut into a width of 1.5±0.1 mm. In the M7 step, the paper is rolled up at a predetermined amount of filling rate to form a rod. Next, in the M8 step, the heated aroma-generating base composition in a rod-shaped roll of paper is cut to a length of 11.5 to 12.0 mm. In the M9 step, it is dried to a moisture content of 8 to 10% by mass. Manufacture the rod type heated aroma generating substrate.

"The Making of Aroma Box"

As shown in FIGS. 2 and 3(A), the manufactured rod-shaped heated aroma source 110, the supporting member 120, and the cigarette holder 140 are sequentially connected in the X direction, and the packaging member 150 is used to manufacture the aroma box 100. In addition, other types, as shown in Figures 2 and 3(B), will be manufactured to produce a rod-shaped heated aroma source 110, a supporting member 120, a cooling member 130, and a cigarette holder 140, in the X direction The packaging component 150 is used to manufacture the fragrance box 101 by the sequential connection.

"The Structure of Aroma Box"

The supporting member 120 used here is a supporting rod type connected by the heated aroma generating source 110, and its central portion 121 is arranged along the central axis of the aroma box 100 in the X direction, and has a plurality of supporting member peripheral portions 122. The plurality of supporting member peripheral portions 122 extend from the central portion 121 to the outside, are in contact with the packaging member 150 located on the periphery of the fragrance box 100, and are fixed to the inner surface of the packaging member 150 by an adhesive to hold the fragrance box 100 The strength.

"The structure of the rod-shaped heated aroma generating substrate"

The heated aroma generating source 110, which is an assembly of the heated aroma generating substrate 111, forms a structure that the smoker can draw with a stable air flow. Its internal structure will be described by taking the heated aroma generating substrate 111 and the heated aroma generating source 110 after the packaging member 150 is wound as an example. Fig. 4 shows a schematic representation of its cross-section. Since the heated aroma generating substrates 111 are assembled, by forming a large number of heated aroma generating substrate aggregates 1112, in the heated aroma generating substrate aggregates 11112, individual heated aroma generating substrates 1111 are formed The gas channel 1113A in the heated aroma generating substrate aggregate, the gas channel 1113B between the heated aroma generating substrate aggregate 1112, the heated aroma generating substrate separate body 1111-the heated aroma generating substrate The gas channel 1113C between the agglomerates 1112 and the gas channel 1113D between the heated aroma generating substrate 111 and the packaging member 150. Therefore, the heated and generated volatiles can pass through these gas channels. Smokers Able to smoke fragrance and smoke with a stable airflow.

"How to use the aroma box"

When used by a smoker, as shown in Figure 5, the aroma box 100 (or 101) is mounted on the mounting part 210 of the heating smoking device body 200, and then the heat source 211 at the center of the bottom of the mounting part 210 is installed. The rod type heated aroma generating source 110 can be pierced, and the heated aroma generating substrate 111 can be heated to enjoy smoking.

"Evaluation of Rod Type Heated Aroma Production Base Material"

As shown in Table 1, the rod-shaped heated aroma-generating substrates made of various rod-shaped heated aroma-generating substrate compositions were used as shown in Figure 5, and the rods were evaluated by 10 subjects As a result of the aroma emitted by the heated aroma producing substrate, 7 or more subjects considered that the "flavor" of the pleasant coffee aroma in the oral cavity was considered as pass (○), and the other cases It is unqualified (×). On the other hand, as shown in Table 1, during the process of manufacturing a rod-shaped heated aroma-generating substrate composition from various rod-shaped heated aroma-generating substrate compositions, there is no such thing as pulverized coffee beans falling off or sheet defects or cracks. The situation is qualified (○), if there is, it is unqualified (×).

"result"

The conditions of Examples 1 to 8 of the various rod-shaped heated aroma generating substrate compositions of the present invention were all passed in the sensory test and the forming and processing test, but in Comparative Examples 1 and 2 which exceeded the range of the blending ratio of the present invention Among them, the sensory test and the forming process test were not qualified at the same time. In addition, although it is not described in the examples, the use of materials containing a large amount of the aroma components disclosed in the present invention and the results of investigations show that the roasted coffee beans are the same with good results. Furthermore, although not described in this comparative example, other materials that can be used as adsorbents or holding materials have been studied extensively, and it is believed that there is no better one than the materials disclosed in the present invention.

【Table 1】

Claims (38)

A rod-shaped heated aroma generating substrate composition, which is used to form a rod-shaped heated aroma generating substrate composition containing an aerosol generating agent that generates aerosol by heat transferred from a heat source, and is characterized by It contains: The aforementioned aerosol, Materials containing aroma components that release aromas, and Lodging an adsorbent containing a liquid component with the aforementioned aroma component of the aforementioned material. The rod-shaped heated aroma generating substrate composition described in the first item of the scope of the patent application, wherein the aforementioned adsorbent is selected from cross-linked polyvinylpyrrolidone, silica powder, activated carbon, alumina, activated clay, One or more of chitosan and chitosan derivatives. The rod-shaped heated aroma generating substrate composition described in item 1 or 2 of the scope of the patent application, wherein 5-50 mass% of the total mass of the rod-shaped heated aroma generating substrate composition is the aforementioned material, The mixing ratio of the material and the aforementioned adsorbent is about 1:1~43:1 in terms of mass ratio. The rod-shaped heated aroma generating substrate composition described in item 3 of the scope of patent application, wherein the blending ratio of the aforementioned aerosol generating agent, the aforementioned material and the aforementioned adsorbent is about 1.9 in terms of mass ratio :1~1:1. The rod-shaped heated aroma-generating substrate composition described in item 4 of the scope of patent application, wherein 5-25% by mass of the total mass of the rod-shaped heated aroma-generating substrate composition is water. The rod-shaped heated aroma generating substrate composition as described in any one of items 1 to 5 of the scope of the patent application further includes a holding material for fixing the rod-shaped heated aroma generating substrate composition. The rod-shaped heated aroma generating substrate composition as described in item 6 of the scope of patent application, wherein the holding material is a non-tobacco material containing 30% by mass or more of fibers by dry mass. The rod-shaped heated aroma generating substrate composition described in item 7 of the scope of patent application, wherein the diameter of the aforementioned fibers is 10-50 μm. The rod-shaped heated aroma producing substrate composition as described in item 7 or 8 of the scope of patent application, wherein the aforementioned non-tobacco material is selected from the stems and leaves of plants of the order Acerola, Linaceae, and plants of Malvaceae. The stems and leaves of the Rosales, the stems and leaves of the Cannabisaceae plants, the stems and leaves of the Ginger Musaceae plants, the stems and leaves of the Asparagus Asparagus plants, the stems and leaves of the Gramineae plants, and the stems of the Gramineae Cyperaceae plants Leaves, stems and leaves of Juncusaceae plants of the order Gramineae, stems and leaves of Grainaceae plants of the order Gramineae, stems and leaves of Typhaceae plants of the order Gramineae, mushrooms, cotton, bark of plants of the Myrtle family Ruixiang family, and Morus Rosales At least one of the bark of the family plant. The rod-shaped heated aroma generating substrate composition described in any one of items 6 to 9 in the scope of the patent application, wherein the mixing ratio of the aforementioned material, the aforementioned adsorbing material, and the aforementioned retaining material is about approximately 1:1:2~43:1:5. The rod-shaped heated aroma-generating substrate composition described in item 10 of the scope of patent application, wherein the aerosol-generating agent is combined with the total amount of the material, the adsorbing material, and the holding material in a mass ratio Counted as about 1:1. The rod-shaped heated aroma generating substrate composition described in item 11 of the scope of patent application, wherein 5 to 25% by mass of the total mass of the rod-shaped heated aroma generating substrate composition is water. The rod-shaped heated aroma producing substrate composition as described in any one of items 1 to 12 in the scope of the patent application, wherein the aforementioned material is selected from the group consisting of seeds of angiosperm fruits, pulp of angiosperm fruits, and angiosperm fruits In the peel, fruit of angiosperms, and stems and leaves of herbs More than one kind. The rod-shaped heated aroma producing substrate composition described in item 13 of the scope of patent application, wherein the seeds of the aforementioned angiosperm fruit are selected from the group consisting of Australian walnut, hazelnut, chestnut, walnut, almond, pecan, cashew, Pistachios, Brazil nuts, coffee beans, cocoa beans, vanilla beans, nutmeg, kola nuts, peanuts, dill, cumin, juniper, caraway, parsley, cardamom, fennel, fenugreek, parsley One or more of the seeds of Indian Tibetan Fennel and Anise. The rod-shaped heated aroma producing substrate composition as described in item 14 of the scope of patent application, wherein the seeds of the aforementioned angiosperm fruit are selected from roasted Australian walnut, hazelnut, chestnut, walnut, almond, and Changshan One or more of the seeds of walnuts, cashews, pistachios, Brazil nuts, coffee beans, cocoa beans, nutmeg, kola nuts, and peanuts. The rod-shaped heated aroma producing substrate composition described in item 14 of the scope of patent application, wherein the seeds of the aforementioned angiosperm fruit are fermented vanilla beans. The stick-shaped heated aroma producing substrate composition as described in item 13 of the scope of the patent application, wherein the pulp of the aforementioned angiosperm fruit is selected from the group consisting of Western pear, Japanese pear, Chinese pear, peach, Sapindus Rutaceae Citrus Plant fruit, apple, banana, pineapple, mango, passion fruit, kiwi, guava, durian, mangosteen, papaya, carambola, lychee, watermelon, cantaloupe, apricot, cherry, papaya, cantaloupe, cantaloupe, strawberry, Raspberry, blueberry, blackcurrant, grapes of grapes of grapes of the grape family Vitis genus ( vinifera ), and grapes of grapes of the American grape ( labrusca ) of the grape family Vitis genus. The rod-shaped heated aroma producing substrate composition described in item 13 of the scope of the patent application, wherein the peel of the angiosperm fruit is one or more selected from the peel of the fruit of the citrus genus of the Rutaceae of the Sapindus family. The rod-shaped heated aroma producing substrate composition described in item 13 of the scope of the patent application, wherein the fruit of the angiosperm is one or more selected from the fruit of coriander, allspice, star anise, and black pepper. The rod-shaped heated aroma producing substrate composition as described in item 13 of the scope of patent application, wherein the stems and leaves of the aforementioned herbaceous plants are selected from the stems and leaves of tarragon, basil, rosemary, and lavender, and many others. Fragrant fruit, oregano, thyme, dill, parsley, spicy mint plants of the Lamiaceae Lamiaceae, spearmint plants of the Lamiaceae Lamiaceae, lemon balm, god One or more of vanilla, European mint, marjoram, lemongrass, bay leaf, medicinal sage, and lemon verbena leaves. As described in any one of items 1 to 12 of the scope of the patent application, the rod-shaped heated aroma generating substrate composition, wherein the aforementioned material is selected from the group consisting of Australian walnut, hazelnut, chestnut, walnut, almond, pecan, One or more of cashew nuts, pistachios, Brazil nuts, coffee beans, cocoa beans, nutmeg, and leaves of plants that produce the seeds of cola nuts. The rod-shaped heated aroma generating substrate composition as described in any one of the claims 1 to 21, wherein the aerosol generating agent is selected from propylene glycol, 1,3-butanediol, and sorbose Alcohol, ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, glycerol, lactic acid, glycerol monoacetate (glycerol monoacetate), glycerol diacetate (diglyceride acetate), glycerol triacetate (Triglyceride acetate), trimethylene glycol diacetate, triethyl citrate, isopropyl myristate, methyl stearate, dimethyl dodecanedioate, dimethyl tetradecenedioate More than one kind of ester. The rod-shaped heated aroma generating substrate composition as described in any one of items 1 to 21 in the scope of the patent application, wherein a thickener is further added. Such as the rod-shaped heated aroma generating substrate composition described in item 23 of the scope of patent application, which Among them, the aforementioned viscosity-increasing agent is selected from konjac mannan (glucomannan), Guanhua bean gum, pectin, carrageenan, tamarind gum, gum arabic, and soybean polysaccharide which are polysaccharide polymers. Species, locust bean gum, Indian tragacanth gum, Sanxian gum, and Hantian, as well as cellulosic polymers such as methyl cellulose, ethyl cellulose, carboxymethyl cellulose, carboxyethyl cellulose, hydroxymethyl One or more of cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, and sodium, potassium, and calcium salts of carboxymethyl cellulose and carboxyethyl cellulose. The rod-shaped heated aroma generating substrate composition described in item 23 or 24 of the scope of the patent application, wherein 1.0 to 10% by mass of the above-mentioned thickening of the total mass of the rod-shaped heated aroma generating substrate composition is added Agent. The rod-shaped heated aroma generating base composition as described in any one of items 1 to 25 in the scope of patent application, wherein β-cyclodextrin is further added. The rod-shaped heated aroma-generating substrate composition described in item 26 of the scope of patent application, wherein 0.2 to 1.0 mass% of the aforementioned β-cyclopaste is added to the total mass of the aforementioned rod-shaped heated aroma-generating substrate composition fine. The rod-shaped heated aroma generating base composition as described in any one of items 1 to 27 in the scope of the patent application, wherein microcrystalline cellulose is further added. The rod-shaped heated aroma generating substrate composition described in item 28 of the scope of patent application, wherein the average particle diameter of the aforementioned microcrystalline cellulose is 30 to 200 μm. The rod-shaped heated aroma generating substrate composition described in item 28 or 29 of the scope of the patent application, wherein 1.0 to 10% by mass of the aforementioned microcrystals of the total mass of the rod-shaped heated aroma generating substrate composition is added Cellulose. The rod-shaped heated aroma generating substrate as described in any one of items 1 to 30 in the scope of patent application A composition in which an antibacterial preservative is further added. The rod-shaped heated aroma-generating substrate composition as described in item 31 of the scope of the patent application, wherein 0.005 to 0.04 mass% of the aforementioned antibacterial preservative is added to the total mass of the rod-shaped heated aroma-generating substrate composition . The rod-shaped heated aroma generating substrate composition as described in item 31 or 32 of the scope of patent application, wherein the antibacterial preservative is potassium sorbate and/or sodium benzoate. The rod-shaped heated aroma generating substrate composition as described in any one of items 1 to 27 in the scope of patent application, wherein inorganic particles are further added. The rod-shaped heated aroma-generating substrate composition described in item 34 of the scope of patent application, wherein 0.05-10% by mass of the aforementioned inorganic particles are added to the total mass of the rod-shaped heated aroma-generating substrate composition. The rod-shaped heated aroma generating substrate composition described in item 34 or 35 of the scope of the patent application, wherein the aforementioned inorganic particles are selected from magnesium oxide, calcium oxide, titanium oxide, iron oxide, aluminum oxide, magnesium carbonate, One or more of calcium carbonate, calcium phosphate, potassium titanate, magnesium titanate, zeolite, colloidal silica, and fumed silica. A rod-shaped heated aroma generating substrate, characterized in that it has the rod-shaped heated aroma generating substrate composition as described in any one of items 1 to 36 in the scope of the patent application. An aroma box characterized in that it has a rod-shaped heated aroma generating substrate as described in item 37 of the scope of the patent application.

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