TW202034436A - Electrostatic chuck and processing device capable of reducing arc discharge - Google Patents

Electrostatic chuck and processing device capable of reducing arc discharge Download PDF

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TW202034436A
TW202034436A TW109106638A TW109106638A TW202034436A TW 202034436 A TW202034436 A TW 202034436A TW 109106638 A TW109106638 A TW 109106638A TW 109106638 A TW109106638 A TW 109106638A TW 202034436 A TW202034436 A TW 202034436A
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porous
dense
hole
electrostatic chuck
sparse
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TWI751505B (en
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白石純
西願修一郎
森達哉
渡邉仁弘
佐佐木雄基
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日商Toto股份有限公司
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/683Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
    • H01L21/6831Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using electrostatic chucks
    • H01L21/6833Details of electrostatic chucks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23QDETAILS, COMPONENTS, OR ACCESSORIES FOR MACHINE TOOLS, e.g. ARRANGEMENTS FOR COPYING OR CONTROLLING; MACHINE TOOLS IN GENERAL CHARACTERISED BY THE CONSTRUCTION OF PARTICULAR DETAILS OR COMPONENTS; COMBINATIONS OR ASSOCIATIONS OF METAL-WORKING MACHINES, NOT DIRECTED TO A PARTICULAR RESULT
    • B23Q3/00Devices holding, supporting, or positioning work or tools, of a kind normally removable from the machine
    • B23Q3/15Devices for holding work using magnetic or electric force acting directly on the work
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32431Constructional details of the reactor
    • H01J37/32715Workpiece holder
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02NELECTRIC MACHINES NOT OTHERWISE PROVIDED FOR
    • H02N13/00Clutches or holding devices using electrostatic attraction, e.g. using Johnson-Rahbek effect

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  • Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
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  • Container, Conveyance, Adherence, Positioning, Of Wafer (AREA)
  • Drying Of Semiconductors (AREA)

Abstract

The object of the present invention is to provide an electrostatic chuck and a processing device capable of reducing arc discharge. The solution of the present invention is to provide the first invention as an electrostatic chuck, which is characterized by comprising: a ceramic dielectric substrate having: a first principal surface on which a suction object is placed, and a second principal surface opposite to the first principal surface; a base plate, supporting the ceramic dielectric substrate and having a gas introducing channel; a first porous part, arranged on the ceramic dielectric substrate and opposite to the gas introducing channel; and a second porous part, arranged on the base plate and opposite to the gas introducing channel. The ceramic dielectric substrate has a first hole part located between the first principal surface and the first porous part. The first porous part has a first porous region having a plurality of pores, and a first dense region denser than the first porous region. The first porous region further has at least one first dense part. The second porous part has a second porous region having a plurality of pores, and a second dense region denser than the second porous region. The second porous region further has at least one second dense part. When projected on a plane perpendicular to a first direction from the base plate toward the ceramic dielectric substrate, the first dense part overlaps the first hole part, at least a part of the second dense part overlaps at least a part of the first dense part, or at least a part of the second dense part is in contact with at least a part of the first dense part.

Description

靜電吸盤及處理裝置Electrostatic chuck and processing device

本發明的態樣是關於靜電吸盤(electrostatic chuck)及處理裝置。The aspect of the present invention relates to an electrostatic chuck and a processing device.

在氧化鋁(alumina)等的陶瓷介電質基板(ceramic dielectric substrate)之間夾住電極,藉由燒成製作的陶瓷製的靜電吸盤是施加靜電吸附用電力在內建的電極,藉由靜電力吸附矽晶圓(silicon wafer)等的基板。在這種靜電吸盤中,在陶瓷介電質基板的表面與吸附對象物之基板的背面之間流過氦(He)等的惰性氣體,控制吸附對象物之基板的溫度。The electrode is sandwiched between ceramic dielectric substrates such as alumina, and the ceramic electrostatic chuck produced by firing is a built-in electrode that applies electricity for electrostatic adsorption. Adhere to substrates such as silicon wafers. In this type of electrostatic chuck, an inert gas such as helium (He) flows between the surface of the ceramic dielectric substrate and the back surface of the substrate of the object to be adsorbed to control the temperature of the substrate of the object to be adsorbed.

例如在CVD(Chemical Vapor Deposition:化學氣相沉積)裝置、濺鍍(sputtering)裝置、離子注入(ion implantation)裝置、蝕刻(etching)裝置等進行對基板的處理的裝置中,有在處理中伴隨基板的溫度上升的裝置。在這種裝置所使用的靜電吸盤中,在陶瓷介電質基板與吸附對象物之基板之間流過He等的惰性氣體,藉由使惰性氣體接觸基板抑制基板的溫度上升。For example, in CVD (Chemical Vapor Deposition: Chemical Vapor Deposition) equipment, sputtering equipment, ion implantation equipment, etching equipment and other equipment for processing substrates, there are A device that increases the temperature of the substrate. In the electrostatic chuck used in such a device, an inert gas such as He flows between the ceramic dielectric substrate and the substrate to be adsorbed, and the inert gas is brought into contact with the substrate to suppress the temperature rise of the substrate.

在藉由He等的惰性氣體進行基板溫度的控制的靜電吸盤中,在陶瓷介電質基板及支撐陶瓷介電質基板的底板(base plate)設有用以導入He等的惰性氣體的孔(氣體導入道)。而且,在陶瓷介電質基板設有與底板的氣體導入道連通的貫通孔。據此,自底板的氣體導入道導入的惰性氣體通過陶瓷介電質基板的貫通孔而被導引至基板的背面。In the electrostatic chuck that controls the substrate temperature by inert gas such as He, the ceramic dielectric substrate and the base plate supporting the ceramic dielectric substrate are provided with holes for introducing inert gas such as He (gas Lead-in road). Furthermore, the ceramic dielectric substrate is provided with a through hole communicating with the gas introduction passage of the bottom plate. Accordingly, the inert gas introduced from the gas introduction channel of the bottom plate is guided to the back surface of the substrate through the through hole of the ceramic dielectric substrate.

此處,在裝置內對基板進行處理時,有時會發生來自裝置內的電漿(plasma)朝向金屬製的底板的放電(電弧放電(arc discharge))。底板的氣體導入道及陶瓷介電質基板的貫通孔往往容易成為放電的路徑。因此,有藉由在底板的氣體導入道及陶瓷介電質基板的貫通孔設置多孔質部,提高對電弧放電的抗性(耐受電壓(withstand voltage)等)的技術。例如在專利文獻1揭示如下的靜電吸盤:藉由在氣體導入道內配設陶瓷燒結多孔體,以陶瓷燒結多孔體的構造及膜孔作為氣體流道,提高在氣體導入道內的絕緣性。而且,在專利文獻2揭示如下的靜電吸盤:在氣體擴散用空隙內配設由陶瓷多孔體構成防止放電用的處理氣體流道用的放電防止構件。而且,在專利文獻3揭示如下的靜電吸盤:配設介電質嵌件(dielectric insert)當作如氧化鋁的多孔質介電質,降低電弧放電。而且,在專利文獻4揭示如下的技術:藉由雷射加工法在由氮化鋁等構成的靜電吸盤設置與氣體供給孔連通的複數個細孔。 在這種靜電吸盤中,電弧放電的更進一步降低被期望。Here, when the substrate is processed in the device, discharge (arc discharge) from the plasma in the device toward the metal bottom plate may occur. The gas introduction channel of the bottom plate and the through hole of the ceramic dielectric substrate tend to become the discharge path. Therefore, there is a technology to improve the resistance to arc discharge (withstand voltage, etc.) by providing a porous part in the gas introduction channel of the bottom plate and the through hole of the ceramic dielectric substrate. For example, Patent Document 1 discloses an electrostatic chuck in which a ceramic sintered porous body is arranged in a gas introduction channel, and the structure and membrane pores of the ceramic sintered porous body are used as gas channels to improve the insulation in the gas introduction channel. In addition, Patent Document 2 discloses an electrostatic chuck in which a discharge prevention member for a process gas flow path for preventing discharge is formed of a ceramic porous body in a gas diffusion gap. Furthermore, Patent Document 3 discloses an electrostatic chuck in which a dielectric insert is provided as a porous dielectric such as alumina to reduce arc discharge. Furthermore, Patent Document 4 discloses a technique in which a plurality of pores communicating with a gas supply hole are provided on an electrostatic chuck made of aluminum nitride or the like by a laser processing method. In this type of electrostatic chuck, a further reduction in arc discharge is expected.

[專利文獻1] 日本國特開2010-123712號公報 [專利文獻2] 日本國特開2003-338492號公報 [專利文獻3] 日本國特開平10-50813號公報 [專利文獻4] 日本國特開2009-218592號公報[Patent Document 1] Japanese Patent Application Publication No. 2010-123712 [Patent Document 2] Japanese Patent Application Publication No. 2003-338492 [Patent Document 3] Japanese Patent Application Publication No. 10-50813 [Patent Document 4] Japanese Patent Application Publication No. 2009-218592

本發明是基於如此的課題的認識所進行的創作,其目的是提供一種靜電吸盤及處理裝置,可謀求電弧放電的降低。The present invention is based on the recognition of such a subject, and its purpose is to provide an electrostatic chuck and a processing device that can reduce arc discharge.

第一發明為一種靜電吸盤,其特徵在於包含:陶瓷介電質基板,具有:載置吸附的對象物之第一主表面(principal surface),和與前述第一主表面相反側之第二主表面;底板,支撐前述陶瓷介電質基板,具有氣體導入道;第一多孔質部,配設於前述陶瓷介電質基板,與前述氣體導入道對向;以及第二多孔質部,配設於前述底板,與前述氣體導入道對向,前述陶瓷介電質基板具有位於前述第一主表面與前述第一多孔質部之間的第一孔部,前述第一多孔質部具有:具有複數個孔之第一多孔區域,和比前述第一多孔區域還緻密之第一緻密區域,前述第一多孔區域更具有至少一個第一緻密部,前述第二多孔質部具有:具有複數個孔之第二多孔區域,和比前述第二多孔區域還緻密之第二緻密區域,前述第二多孔區域更具有至少一個第二緻密部,在投影於對從前述底板朝向前述陶瓷介電質基板的第一方向垂直的平面時,前述第一緻密部與前述第一孔部重疊,前述第二緻密部的至少一部分與前述第一緻密部的至少一部分重疊,或者前述第二緻密部的至少一部分與前述第一緻密部的至少一部分接觸而構成。The first invention is an electrostatic chuck, which is characterized by comprising: a ceramic dielectric substrate having: a first principal surface (principal surface) on which an object to be adsorbed is placed, and a second principal surface opposite to the aforementioned first principal surface Surface; a bottom plate, which supports the ceramic dielectric substrate and has a gas introduction channel; a first porous portion, which is arranged on the ceramic dielectric substrate and is opposed to the gas introduction channel; and a second porous portion, Disposed on the bottom plate and opposed to the gas inlet, the ceramic dielectric substrate has a first hole located between the first main surface and the first porous portion, and the first porous portion It has: a first porous region with a plurality of pores, and a first dense region denser than the first porous region, the first porous region further has at least one first dense part, and the second porous region The part has: a second porous region with a plurality of pores, and a second dense region denser than the aforementioned second porous region. The second porous region further has at least one second dense part, which is projected on the opposite When the bottom plate faces a plane perpendicular to the first direction of the ceramic dielectric substrate, the first dense part overlaps the first hole part, and at least a part of the second dense part overlaps with at least a part of the first dense part. Or, at least a part of the second dense part is in contact with at least a part of the first dense part.

依照該靜電吸盤,流動於第一多孔質部的電流在流動於設置有第二緻密部的第二多孔質部時迂回流動於第二緻密部。因此,因可加長電流流動的距離(導電路徑(conductive path)),故電子難以被加速,進而可抑制電弧放電的發生。According to this electrostatic chuck, the current flowing in the first porous part flows to the second dense part in a detour when flowing in the second porous part provided with the second dense part. Therefore, since the distance through which the current flows (conductive path) can be lengthened, electrons are difficult to be accelerated, and the occurrence of arc discharge can be suppressed.

第二發明為一種靜電吸盤,其特徵在於:在第一發明中,在投影於對前述第一方向垂直的平面時,前述第一緻密部的尺寸與前述第一孔部的尺寸相同,或者前述第一緻密部的尺寸大於前述第一孔部的尺寸。The second invention is an electrostatic chuck, characterized in that: in the first invention, when projected on a plane perpendicular to the first direction, the size of the first dense portion is the same as the size of the first hole, or The size of the first dense portion is larger than the size of the aforementioned first hole portion.

依照該靜電吸盤,可將流動於第一孔部的內部的電流導引到第一緻密部。因此,可有效地加長電流流動的距離(導電路徑)。According to the electrostatic chuck, the current flowing inside the first hole portion can be guided to the first dense portion. Therefore, the distance (conducting path) through which the current flows can be effectively lengthened.

第三發明為一種靜電吸盤,其特徵在於:在第一發明或第二發明中,在投影於對前述第一方向垂直的平面時,前述第二緻密部與前述第一緻密區域重疊,或者前述第二緻密部與前述第一緻密區域相接。The third invention is an electrostatic chuck, characterized in that, in the first or second invention, when projected on a plane perpendicular to the first direction, the second dense portion overlaps the first dense region, or the The second dense part is connected to the aforementioned first dense region.

依照該靜電吸盤,可抑制流動於第一多孔質部的電流不經由第二緻密部而流動於第二多孔質部。因此,可有效地加長電流流動的距離(導電路徑)。According to this electrostatic chuck, it is possible to suppress the current flowing in the first porous part from flowing in the second porous part without passing through the second dense part. Therefore, the distance (conducting path) through which the current flows can be effectively lengthened.

第四發明為一種靜電吸盤,其特徵在於:在第一發明至第三發明中的任一項發明中,前述第一多孔區域具有複數個第一疏鬆部分與第一緊密部分,前述第一稀疏部分具有前述複數個孔,前述第一緊密部分具有比前述第一稀疏部分的密度還高的密度,前述第二方向上的尺寸小於前述第二方向上的前述第一緻密區域的尺寸,前述複數個第一稀疏部分的各個延伸於前述第一方向,前述第一緊密部分位於前述複數個第一稀疏部分彼此之間,前述第一稀疏部分具有設置於前述複數個孔彼此之間的第一壁部,在略正交於前述第一方向的第二方向上,前述第一壁部的尺寸的最小值小於前述第一緊密部分的尺寸的最小值。The fourth invention is an electrostatic chuck, characterized in that, in any one of the first to third inventions, the first porous region has a plurality of first loose parts and first tight parts, and the first The sparse portion has the plurality of holes, the first dense portion has a higher density than the first sparse portion, the size in the second direction is smaller than the size of the first dense area in the second direction, Each of the plurality of first sparse portions extends in the first direction, the first dense portion is located between the plurality of first sparse portions, and the first sparse portion has a first sparse portion disposed between the plurality of holes. In the wall portion, in a second direction that is slightly orthogonal to the first direction, the minimum value of the size of the first wall portion is smaller than the minimum value of the size of the first compact portion.

依照該靜電吸盤,因在第一多孔質部設置有延伸於第一方向的第一稀疏部分與第一緊密部分,故可確保對電弧放電的抗性與氣體流量,同時可提高第一多孔質部的機械強度(mechanical strength) (剛性)。According to this electrostatic chuck, since the first porous portion is provided with the first sparse portion and the first dense portion extending in the first direction, the resistance to arc discharge and the gas flow rate can be ensured, and the first porous portion can be increased. The mechanical strength (rigidity) of the pore mass.

第五發明為一種靜電吸盤,其特徵在於:在第一發明至第四發明中的任一項發明中,在前述第二方向上,設置於前述複數個第一稀疏部分的各個的前述複數個孔的尺寸比前述第一緊密部分的尺寸還小,及/或在前述第二方向上,設置於前述複數個第二稀疏部分的各個的前述複數個孔的尺寸比前述第二緊密部分的尺寸還小。The fifth invention is an electrostatic chuck characterized in that, in any one of the first to fourth inventions, the plurality of first sparse portions are provided in the second direction in the first direction. The size of the hole is smaller than the size of the first tight portion, and/or the size of the plurality of holes provided in each of the plurality of second sparse portions in the second direction is greater than the size of the second tight portion Still small.

依照該靜電吸盤,因可充分減小複數個孔的尺寸,故可更提高對電弧放電的抗性。According to the electrostatic chuck, since the size of the plurality of holes can be sufficiently reduced, the resistance to arc discharge can be further improved.

第六發明為一種靜電吸盤,其特徵在於:在第一發明至第五發明中的任一項發明中,設置於前述複數個第一稀疏部分的各個的前述複數個孔的縱橫比(aspect ratio),及/或設置於前述複數個第二稀疏部分的各個的前述複數個孔的縱橫比為30以上。The sixth invention is an electrostatic chuck characterized in that, in any one of the first to fifth inventions, the aspect ratio of the plurality of holes provided in each of the plurality of first sparse portions is ), and/or the aspect ratio of the plurality of holes provided in each of the plurality of second sparse portions is 30 or more.

依照該靜電吸盤,可更提高對電弧放電的抗性。According to the electrostatic chuck, the resistance to arc discharge can be further improved.

第七發明為一種靜電吸盤,其特徵在於:在第一發明至第六發明中的任一項發明中,在前述第二方向上,設置於前述複數個第一稀疏部分的各個的前述複數個孔的尺寸,及/或設置於前述複數個第二稀疏部分的各個的前述複數個孔的尺寸為1微米(micrometer)以上、20微米以下。The seventh invention is an electrostatic chuck, characterized in that, in any one of the first to sixth inventions, the plurality of first sparse portions are arranged in the second direction in the first direction. The size of the hole and/or the size of the plurality of holes provided in each of the plurality of second sparse portions is 1 micrometer or more and 20 micrometers or less.

依照該靜電吸盤,因可排列孔的尺寸為1~20微米之延伸於一方向的孔,故可實現對電弧放電的高的抗性。According to the electrostatic chuck, since holes with a size of 1-20 micrometers extending in one direction can be arranged, high resistance to arc discharge can be realized.

第八發明為一種靜電吸盤,其特徵在於:在第一發明至第七發明中的任一項發明中,在沿著前述第一方向看時,設置於前述第一稀疏部分的複數個孔包含位於前述第一稀疏部分的中心部的第一孔,前述複數個孔之中與前述第一孔鄰接且包圍前述第一孔的孔的數目為6,及/或在沿著前述第一方向看時,設置於前述第二稀疏部分的複數個孔包含位於前述第二稀疏部分的中心部的第二孔,前述複數個孔之中與前述第二孔鄰接且包圍前述第二孔的孔的數目為6。The eighth invention is an electrostatic chuck characterized in that, in any one of the first to seventh inventions, when viewed along the first direction, the plurality of holes provided in the first sparse portion include The first hole located at the center of the first sparse portion, the number of holes adjacent to and surrounding the first hole among the plurality of holes is 6, and/or when viewed along the first direction When, the plurality of holes provided in the second sparse part includes a second hole located at the center of the second sparse part, and the number of holes adjacent to the second hole and surrounding the second hole among the plurality of holes For 6.

依照該靜電吸盤,以平面視看,能以高的等向性(isotropy)且高的密度配置複數個孔。據此,可確保對電弧放電的抗性與流動的氣體的流量,同時可提高第一多孔質部的剛性。According to this electrostatic chuck, it is possible to arrange a plurality of holes with high isotropy and high density in a plan view. Accordingly, the resistance to arc discharge and the flow rate of the flowing gas can be ensured, and the rigidity of the first porous portion can be improved.

第九發明為一種靜電吸盤,其特徵在於:在第一發明至第八發明中的任一項發明中,前述第一緻密部之沿著前述第一方向的長度小於前述第一多孔質部之沿著前述第一方向的長度。The ninth invention is an electrostatic chuck characterized in that, in any one of the first to eighth inventions, the length of the first dense portion along the first direction is smaller than that of the first porous portion Its length along the aforementioned first direction.

依照該靜電吸盤,可更提高對電弧放電的抗性。According to the electrostatic chuck, the resistance to arc discharge can be further improved.

第十發明為一種靜電吸盤,其特徵在於:在第一發明至第九發明中的任一項發明中,在前述第一方向上,在前述第一緻密部與前述底板之間設置有前述第一多孔區域。The tenth invention is an electrostatic chuck characterized in that, in any one of the first to ninth inventions, in the first direction, the first dense part is provided between the first dense portion and the bottom plate. A porous area.

依照該靜電吸盤,可更提高對電弧放電的抗性。According to the electrostatic chuck, the resistance to arc discharge can be further improved.

第十一發明為一種靜電吸盤,其特徵在於:在第一發明至第十發明中的任一項發明中,前述第一緻密部之沿著前述第一方向的長度與前述第一多孔質部之沿著前述第一方向的長度大致相同。The eleventh invention is an electrostatic chuck characterized in that, in any one of the first to tenth inventions, the length of the first dense portion along the first direction and the first porous The lengths of the parts along the aforementioned first direction are approximately the same.

依照該靜電吸盤,可更提高對電弧放電的抗性。According to the electrostatic chuck, the resistance to arc discharge can be further improved.

第十二發明為一種靜電吸盤,其特徵在於:在第一發明至第十一發明中的任一項發明中,在投影於對前述第一方向垂直的平面時,在前述第一緻密部的周圍設置有前述複數個第一稀疏部分。The twelfth invention is an electrostatic chuck characterized in that in any one of the first to eleventh inventions, when projected on a plane perpendicular to the first direction, the first dense part A plurality of the aforementioned first sparse parts are arranged around.

依照該靜電吸盤,可確保氣流,同時可有效地抑制電弧放電的發生。According to the electrostatic chuck, the air flow can be ensured and the occurrence of arc discharge can be effectively suppressed.

第十三發明為一種靜電吸盤,其特徵在於:在第一發明至第十二發明中的任一項發明中,設置於前述第二多孔質部的前述複數個孔的直徑的平均值比設置於前述第一多孔質部的複數個孔的直徑的平均值還大。The thirteenth invention is an electrostatic chuck, characterized in that, in any one of the first to twelfth inventions, the ratio of the average diameter of the plurality of holes provided in the second porous portion The average value of the diameters of the plurality of pores provided in the first porous portion is still large.

依照該靜電吸盤,因設置有孔的直徑大的第二多孔質部,故可謀求氣體流動的順暢化。而且,因孔的直徑小的第一多孔質部設置於吸附的對象物側,故可更有效地抑制電弧放電的發生。According to this electrostatic chuck, since the second porous part with a large hole diameter is provided, the flow of gas can be smoothed. Furthermore, since the first porous portion with a small hole diameter is provided on the side of the object to be adsorbed, the occurrence of arc discharge can be suppressed more effectively.

第十四發明為一種靜電吸盤,其特徵在於:在第一發明至第十三發明中的任一項發明中,前述氣體導入道的前述陶瓷介電質基板側的開口的邊緣的至少一部分以曲線構成。The fourteenth invention is an electrostatic chuck characterized in that, in any one of the first to thirteenth inventions, at least a part of the edge of the opening on the ceramic dielectric substrate side of the gas introduction path is Curve composition.

依照該靜電吸盤,因氣體導入道的開口的邊緣的至少一部分以曲線構成,故可抑制電場集中,進而可謀求電弧放電的降低。According to this electrostatic chuck, since at least a part of the edge of the opening of the gas introduction channel is formed in a curved line, the concentration of the electric field can be suppressed, and the arc discharge can be reduced.

第十五發明為一種靜電吸盤,其特徵在於:在第一發明至第十四發明中的任一項發明中,前述陶瓷介電質基板具有位於前述第一主表面與前述第一多孔質部之間的第一孔部,前述陶瓷介電質基板及前述第一多孔質部的至少任一個具有位於前述第一孔部與前述第一多孔質部之間的第二孔部,在與前述第一方向略正交的第二方向上,前述第二孔部的尺寸小於前述第一多孔質部的尺寸,大於前述第一孔部的尺寸。The fifteenth invention is an electrostatic chuck, characterized in that, in any one of the first to fourteenth inventions, the ceramic dielectric substrate has a structure located on the first main surface and the first porous The first hole between the portions, at least any one of the ceramic dielectric substrate and the first porous portion has a second hole located between the first hole and the first porous portion, In a second direction that is slightly orthogonal to the first direction, the size of the second hole is smaller than the size of the first porous portion and larger than the size of the first hole.

依照該靜電吸盤,藉由設置於與氣體導入道對向的位置的第一多孔質部,可確保流動於第一孔部的氣體的流量,同時可提高對電弧放電的抗性。而且,因設置有具有規定的尺寸的第二孔部,故可將導入到尺寸大的第一多孔質部的氣體的大部分經由第二孔部導入到尺寸小的第一孔部。也就是說,可謀求電弧放電的降低與氣體流動的順暢化。According to the electrostatic chuck, the first porous part provided at the position opposite to the gas introduction channel can ensure the flow rate of the gas flowing through the first hole part and at the same time improve the resistance to arc discharge. Furthermore, since the second hole portion having a predetermined size is provided, most of the gas introduced into the first porous portion with a large size can be introduced to the first hole portion with a small size via the second hole. In other words, it is possible to reduce arc discharge and smooth gas flow.

第一六發明為一種處理裝置,其特徵在於包含:上述任一個靜電吸盤;以及供給部,可將氣體供給到設置於前述靜電吸盤的氣體導入道。 依照該處理裝置,可謀求電弧放電的降低。The sixteenth invention is a processing device characterized by comprising: any one of the above-mentioned electrostatic chuck; and a supply part capable of supplying gas to a gas introduction path provided in the aforementioned electrostatic chuck. According to this processing device, arc discharge can be reduced.

依照本發明的態樣,可提供一種可謀求電弧放電的降低之靜電吸盤及處理裝置。According to aspects of the present invention, an electrostatic chuck and processing device that can reduce arc discharge can be provided.

以下,就本發明的實施的形態一邊參照圖式,一邊進行說明。此外各圖式中,對同樣的構成元件附加同一符號而適宜省略詳細的說明。 此外,在各圖中,以從底板50朝向陶瓷介電質基板11的方向當作Z方向(相當於第一方向的一例),以與Z方向略正交的方向之一當作Y方向(相當於第二方向的一例),以略正交於Z方向及Y方向的方向當作X方向(相當於第二方向的一例)。Hereinafter, the embodiments of the present invention will be described with reference to the drawings. In addition, in each drawing, the same reference numeral is attached to the same constituent element, and detailed description is appropriately omitted. In addition, in each figure, the direction from the base plate 50 to the ceramic dielectric substrate 11 is regarded as the Z direction (corresponding to an example of the first direction), and one of the directions slightly orthogonal to the Z direction is regarded as the Y direction ( It corresponds to an example of the second direction), and a direction slightly orthogonal to the Z direction and the Y direction is regarded as the X direction (corresponding to an example of the second direction).

(靜電吸盤) 圖1是舉例說明與本實施形態有關的靜電吸盤之示意剖面圖。 如圖1所示,與本實施形態有關的靜電吸盤110具備陶瓷介電質基板11、底板50及多孔質部90。在該例子中,靜電吸盤110更具備多孔質部70。(Electrostatic chuck) Fig. 1 is a schematic cross-sectional view illustrating an electrostatic chuck related to this embodiment. As shown in FIG. 1, the electrostatic chuck 110 related to this embodiment includes a ceramic dielectric substrate 11, a bottom plate 50, and a porous portion 90. In this example, the electrostatic chuck 110 further includes a porous portion 70.

陶瓷介電質基板11例如為由燒結陶瓷構成的平板狀的基材。例如陶瓷介電質基板11包含氧化鋁(Al2 O3 )。例如陶瓷介電質基板11由高純度的氧化鋁形成。陶瓷介電質基板11中的氧化鋁的濃度為例如99原子%(atomic%)以上、100 atomic %以下。藉由使用高純度的氧化鋁,可提高陶瓷介電質基板11的耐電漿性(plasma resistance)。陶瓷介電質基板11具有:載置對象物W(吸附的對象物)的第一主表面11a,和與第一主表面11a相反側之第二主表面11b。對象物W例如為矽晶圓等的半導體基板。The ceramic dielectric substrate 11 is, for example, a flat substrate made of sintered ceramic. For example, the ceramic dielectric substrate 11 includes aluminum oxide (Al 2 O 3 ). For example, the ceramic dielectric substrate 11 is formed of high-purity alumina. The concentration of alumina in the ceramic dielectric substrate 11 is, for example, 99 atomic% (atomic %) or more and 100 atomic% or less. By using high-purity alumina, the plasma resistance of the ceramic dielectric substrate 11 can be improved. The ceramic dielectric substrate 11 has a first main surface 11a on which an object W (an object to be adsorbed) is placed, and a second main surface 11b on the opposite side of the first main surface 11a. The object W is, for example, a semiconductor substrate such as a silicon wafer.

在陶瓷介電質基板11配設有電極12。電極12配設於陶瓷介電質基板11的第一主表面11a與第二主表面11b之間。電極12以插入於陶瓷介電質基板11之中的方式形成。在電極12經由連接部20及配線211電連接有電源210。可利用電源210藉由對電極12施加吸附保持用電壓,在電極12的第一主表面11a側產生電荷,利用靜電力吸附保持對象物W。Electrodes 12 are arranged on the ceramic dielectric substrate 11. The electrode 12 is arranged between the first main surface 11 a and the second main surface 11 b of the ceramic dielectric substrate 11. The electrode 12 is formed so as to be inserted into the ceramic dielectric substrate 11. A power source 210 is electrically connected to the electrode 12 via the connection portion 20 and the wiring 211. The power supply 210 can be used to apply a voltage for adsorption and holding to the electrode 12 to generate an electric charge on the first main surface 11a side of the electrode 12, and the object W can be adsorbed and held by electrostatic force.

電極12的形狀是沿著陶瓷介電質基板11的第一主表面11a及第二主表面11b的薄膜狀。電極12是用以吸附保持對象物W的吸附電極。電極12既可以是單極型也可以是雙極型。圖1所示的電極12是雙極型,在同一面上配設有2極的電極12。The shape of the electrode 12 is a thin film along the first main surface 11 a and the second main surface 11 b of the ceramic dielectric substrate 11. The electrode 12 is an adsorption electrode for adsorbing and holding the object W. The electrode 12 may be either a unipolar type or a bipolar type. The electrode 12 shown in FIG. 1 is a bipolar type, and two electrodes 12 are arranged on the same surface.

在電極12配設有延伸於陶瓷介電質基板11的第二主表面11b側的連接部20。連接部20例如是與電極12導通的介層(via)(實心型)或介層孔(via hole)(空心型)。連接部20也可以是藉由硬銲(brazing)等的適切的方法連接的金屬端子。The electrode 12 is provided with a connection portion 20 extending on the second main surface 11 b side of the ceramic dielectric substrate 11. The connection portion 20 is, for example, a via (solid type) or a via hole (hollow type) that is electrically connected to the electrode 12. The connecting portion 20 may be a metal terminal connected by an appropriate method such as brazing.

底板50是支撐陶瓷介電質基板11的構件。陶瓷介電質基板11透過圖2(a)所示的接合部60固定在底板50之上。接合部60例如能以矽接著劑(silicone adhesive)硬化者The bottom plate 50 is a member that supports the ceramic dielectric substrate 11. The ceramic dielectric substrate 11 is fixed on the bottom plate 50 through the joint 60 shown in FIG. 2(a). The bonding portion 60 can be cured with a silicone adhesive, for example

底板50例如是金屬製。底板50例如分成鋁製的上部50a與下部50b,在上部50a與下部50b之間設置有連通道55。連通道55的一端側連接於輸入道51,連通道55的他端側連接於輸出道52。底板50在第二主表面11b側的端部具有熔射部(未圖示)也可以。熔射部例如藉由熔射(thermal spraying)形成。熔射部構成底板50的第二主表面11b側的端面(頂面50U)也可以。熔射部依照需要而配設,也能省略。The bottom plate 50 is made of metal, for example. The bottom plate 50 is divided into, for example, an upper portion 50a and a lower portion 50b made of aluminum, and a connecting channel 55 is provided between the upper portion 50a and the lower portion 50b. One end of the connecting channel 55 is connected to the input channel 51, and the other end of the connecting channel 55 is connected to the output channel 52. The bottom plate 50 may have a spray part (not shown) at the end on the second main surface 11b side. The spray part is formed by, for example, thermal spraying. The spray part may constitute the end surface (top surface 50U) of the bottom plate 50 on the second main surface 11b side. The spraying part is arranged according to needs, and can also be omitted.

底板50也發揮進行靜電吸盤110的溫度調整的作用。例如在將靜電吸盤110冷卻的情形下,從輸入道51流入冷卻介質(cooling medium),使其通過連通道55從輸出道52流出。據此,藉由冷卻介質吸收底板50的熱,可冷卻安裝在其上的陶瓷介電質基板11。另一方面,在將靜電吸盤110保溫的情形下,也可將保溫介質放入連通道55內。也可將發熱體內建於陶瓷介電質基板11或底板50。藉由調整底板50或陶瓷介電質基板11的溫度,可調整藉由靜電吸盤110吸附保持的對象物W的溫度。The bottom plate 50 also functions to adjust the temperature of the electrostatic chuck 110. For example, in the case of cooling the electrostatic chuck 110, a cooling medium (cooling medium) flows from the input channel 51 and flows out from the output channel 52 through the connecting channel 55. Accordingly, by absorbing the heat of the bottom plate 50 by the cooling medium, the ceramic dielectric substrate 11 mounted thereon can be cooled. On the other hand, when the electrostatic chuck 110 is kept warm, the heat preservation medium can also be put into the connecting channel 55. The heating body can also be built on the ceramic dielectric substrate 11 or the bottom plate 50. By adjusting the temperature of the bottom plate 50 or the ceramic dielectric substrate 11, the temperature of the object W held by the electrostatic chuck 110 can be adjusted.

而且,在陶瓷介電質基板11的第一主表面11a側,依照需要設置有點13,在點13之間設置有溝14。也就是說,第一主表面11a是凹凸面,具有凹部與凸部。第一主表面11a的凸部相當於點13,第一主表面11a的凹部相當於溝14。溝14例如可在XY平面內連續延伸而構成。據此,可將He等的氣體分配於第一主表面11a整體。在載置於靜電吸盤110的對象物W的背面與包含溝14的第一主表面11a之間形成有空間。Furthermore, on the first main surface 11a side of the ceramic dielectric substrate 11, dots 13 are provided as necessary, and grooves 14 are provided between the dots 13. That is, the first main surface 11a is a concave-convex surface and has concave and convex portions. The convex portion of the first main surface 11 a corresponds to the point 13, and the concave portion of the first main surface 11 a corresponds to the groove 14. The groove 14 may be formed by continuously extending in the XY plane, for example. According to this, a gas such as He can be distributed to the entire first main surface 11a. A space is formed between the back surface of the object W placed on the electrostatic chuck 110 and the first main surface 11 a including the groove 14.

陶瓷介電質基板11具有與溝14連接的貫通孔15。貫通孔15由第二主表面11b到第一主表面11a被設置。也就是說,貫通孔15從第二主表面11b到第一主表面11a為止延伸於Z方向,貫通陶瓷介電質基板11。貫通孔15例如包含孔部15a、孔部15b、孔部15c、孔部15d(詳細於後述)。The ceramic dielectric substrate 11 has a through hole 15 connected to the groove 14. The through hole 15 is provided from the second main surface 11b to the first main surface 11a. That is, the through hole 15 extends in the Z direction from the second main surface 11 b to the first main surface 11 a, and penetrates the ceramic dielectric substrate 11. The through hole 15 includes, for example, a hole portion 15a, a hole portion 15b, a hole portion 15c, and a hole portion 15d (details will be described later).

藉由適宜選擇點13的高度、溝14的深度、點13及溝14的面積比率、形狀等,可將對象物W的溫度或附著於對象物W的微粒控制在適合的狀態。By appropriately selecting the height of the dot 13, the depth of the groove 14, the area ratio of the dot 13 and the groove 14, the shape, etc., the temperature of the object W or the particles attached to the object W can be controlled in an appropriate state.

在底板50設置有氣體導入道53。氣體導入道53以例如貫通底板50的方式被設置。氣體導入道53也可以不貫通底板50而從其他的氣體導入道53的途中分岔而設置到陶瓷介電質基板11側。而且,氣體導入道53也可以設置於底板50的複數處。A gas introduction path 53 is provided on the bottom plate 50. The gas introduction path 53 is provided so as to penetrate the bottom plate 50, for example. The gas introduction path 53 may not penetrate the bottom plate 50 but branch from the middle of another gas introduction path 53 and may be provided to the ceramic dielectric substrate 11 side. In addition, the gas introduction passage 53 may be provided in a plurality of places on the bottom plate 50.

氣體導入道53與貫通孔15連通。也就是說,流入氣體導入道53的氣體(氦(He)等)在通過氣體導入道53之後流入貫通孔15。The gas introduction passage 53 communicates with the through hole 15. That is, the gas (helium (He), etc.) flowing into the gas introduction passage 53 flows into the through hole 15 after passing through the gas introduction passage 53.

流入貫通孔15的氣體在通過貫通孔15之後流入設置於對象物W與包含溝14的第一主表面11a之間的空間。據此,可藉由氣體直接冷卻對象物W。The gas flowing into the through hole 15 flows into the space provided between the object W and the first main surface 11 a including the groove 14 after passing through the through hole 15. According to this, the object W can be directly cooled by the gas.

多孔質部90可設置於例如在Z方向上底板50與陶瓷介電質基板11的第一主表面11a之間。多孔質部90例如可設置於與氣體導入道53對向的位置。例如多孔質部90被設置於陶瓷介電質基板11的貫通孔15。例如多孔質部90被插入於貫通孔15。The porous portion 90 may be provided, for example, between the bottom plate 50 and the first main surface 11 a of the ceramic dielectric substrate 11 in the Z direction. The porous part 90 may be provided, for example, at a position facing the gas introduction path 53. For example, the porous portion 90 is provided in the through hole 15 of the ceramic dielectric substrate 11. For example, the porous part 90 is inserted into the through hole 15.

圖2(a)、(b)是舉例說明與實施形態有關的靜電吸盤之示意圖。圖2(a)舉例說明多孔質部90及多孔質部70的周邊。圖2(a)相當於圖1所示的區域A的放大視圖。圖2(b)是舉例說明多孔質部90之俯視圖。Figure 2 (a) and (b) are schematic diagrams illustrating the electrostatic chuck related to the embodiment. FIG. 2(a) illustrates the porous part 90 and the periphery of the porous part 70 by way of example. Fig. 2(a) corresponds to an enlarged view of the area A shown in Fig. 1. Fig. 2(b) is a plan view illustrating the porous part 90.

而且,圖2(c)、(d)是用以舉例說明與其他的實施形態有關的孔部15c及孔部15d之示意剖面圖。2(c) and (d) are schematic cross-sectional views for illustrating the hole 15c and the hole 15d related to other embodiments.

此外,為了避免變得煩雜,在圖2(a)、(c)、(d)中省略點13(例如參照圖1)而進行了描繪。In addition, in order to avoid becoming complicated, point 13 is omitted in FIGS. 2(a), (c), and (d) (for example, refer to FIG. 1) and drawn.

在該例子中,貫通孔15具有孔部15a與孔部15b(第一孔部)。孔部15a的一端位於陶瓷介電質基板11的第二主表面11b。In this example, the through hole 15 has a hole portion 15a and a hole portion 15b (first hole portion). One end of the hole 15 a is located on the second main surface 11 b of the ceramic dielectric substrate 11.

而且,陶瓷介電質基板11可具有在Z方向上位於第一主表面11a與多孔質部90之間的孔部15b。孔部15b與孔部15a連通,延伸至陶瓷介電質基板11的第一主表面11a。也就是說,孔部15b的一端位於第一主表面11a(溝14的底面14a)。孔部15b位於陶瓷介電質基板11的第一主表面11a與多孔質部90之間。孔部15b是連結多孔質部90與溝14的連結孔。孔部15b的直徑(沿著X方向的長度)比孔部15a的直徑(沿著X方向的長度)小。藉由設置直徑小的孔部15b,可提高形成於陶瓷介電質基板11與對象物W之間的空間(例如包含溝14的第一主表面11a)的設計的自由度。例如如圖2(a)所示,可使溝14的寬度(沿著X方向的長度)比多孔質部90的寬度(沿著X方向的長度)短。據此,例如可抑制形成於陶瓷介電質基板11與對象物W之間的空間中的放電。Furthermore, the ceramic dielectric substrate 11 may have a hole portion 15b located between the first main surface 11a and the porous portion 90 in the Z direction. The hole 15 b communicates with the hole 15 a and extends to the first main surface 11 a of the ceramic dielectric substrate 11. That is, one end of the hole 15b is located on the first main surface 11a (the bottom surface 14a of the groove 14). The hole 15 b is located between the first main surface 11 a of the ceramic dielectric substrate 11 and the porous portion 90. The hole portion 15b is a connecting hole connecting the porous portion 90 and the groove 14. The diameter (length along the X direction) of the hole 15b is smaller than the diameter (length along the X direction) of the hole 15a. By providing the hole 15b with a small diameter, the freedom of design of the space formed between the ceramic dielectric substrate 11 and the object W (for example, the first main surface 11a including the groove 14) can be increased. For example, as shown in FIG. 2(a), the width (length along the X direction) of the groove 14 can be made shorter than the width (length along the X direction) of the porous portion 90. Accordingly, for example, the discharge formed in the space between the ceramic dielectric substrate 11 and the object W can be suppressed.

孔部15b的直徑為例如0.05毫米(mm)以上、0.5mm以下。孔部15a的直徑為例如1mm以上、5mm以下。此外,孔部15b也可以與孔部15a間接地連通。也就是說,也可以設置有連接孔部15a與孔部15b的孔部15c(第二孔部)。如圖2(a)所舉例說明,孔部15c可設置於陶瓷介電質基板11。如圖2(c)所舉例說明,孔部15c也可設置於多孔質部90。如圖2(d)所舉例說明,孔部15c也可設置於陶瓷介電質基板11及多孔質部90。也就是說,陶瓷介電質基板11及多孔質部90的至少任一個可具有位於孔部15b與多孔質部90之間的孔部15c。此情形,若孔部15c被設置於陶瓷介電質基板11,則可提高孔部15c的周圍中的強度,可抑制孔部15c的周邊中的傾斜等的發生。因此,可更有效地抑制電弧放電的發生。若孔部15c被設置於多孔質部90,則孔部15c與多孔質部90的對準變的容易。因此,使電弧放電的降低與氣體流動的順暢化並存變的更容易。孔部15a、孔部15b及孔部15c的各個例如為延伸於Z方向的圓筒狀。The diameter of the hole 15b is, for example, 0.05 millimeter (mm) or more and 0.5 mm or less. The diameter of the hole 15a is, for example, 1 mm or more and 5 mm or less. In addition, the hole 15b may indirectly communicate with the hole 15a. That is, a hole portion 15c (second hole portion) connecting the hole portion 15a and the hole portion 15b may be provided. As illustrated in FIG. 2( a ), the hole 15 c may be provided in the ceramic dielectric substrate 11. As illustrated in FIG. 2(c), the hole portion 15c may also be provided in the porous portion 90. As illustrated in FIG. 2(d), the hole 15c may also be provided in the ceramic dielectric substrate 11 and the porous portion 90. In other words, at least any one of the ceramic dielectric substrate 11 and the porous portion 90 may have the hole portion 15 c located between the hole portion 15 b and the porous portion 90. In this case, if the hole 15c is provided in the ceramic dielectric substrate 11, the strength in the periphery of the hole 15c can be increased, and the occurrence of inclination or the like in the periphery of the hole 15c can be suppressed. Therefore, the occurrence of arc discharge can be suppressed more effectively. If the hole part 15c is provided in the porous part 90, the alignment of the hole part 15c and the porous part 90 becomes easy. Therefore, it becomes easier to coexist the reduction of arc discharge and the smoothing of gas flow. Each of the hole 15a, the hole 15b, and the hole 15c has a cylindrical shape extending in the Z direction, for example.

此情形,在X方向或Y方向上,可使孔部15c的尺寸比多孔質部90的尺寸小,比孔部15b的尺寸大。依照與本實施形態有關的靜電吸盤110,藉由設置於與氣體導入道53對向的位置的多孔質部90,可確保流動於孔部15b的氣體的流量,同時可提高對電弧放電的抗性。而且,因使孔部15c的X方向或Y方向上的尺寸大於孔部15b的該尺寸,故可將導入到尺寸大的多孔質部90的氣體的大部分經由孔部15c導入到尺寸小的孔部15b。也就是說,可謀求電弧放電的降低與氣體流動的順暢化。In this case, in the X direction or the Y direction, the size of the hole 15c can be made smaller than the size of the porous portion 90 and larger than the size of the hole 15b. According to the electrostatic chuck 110 related to the present embodiment, the porous portion 90 provided at the position opposite to the gas introduction path 53 can ensure the flow rate of the gas flowing through the hole portion 15b and improve the resistance to arc discharge. Sex. Furthermore, since the size of the hole portion 15c in the X direction or the Y direction is made larger than the size of the hole portion 15b, most of the gas introduced into the porous portion 90 with a large size can be introduced to the small size via the hole portion 15c.孔部15b. In other words, it is possible to reduce arc discharge and smooth gas flow.

如前述,陶瓷介電質基板11具有開口於第一主表面11a,與貫通孔15連通的至少一個溝14。而且,可使孔部15c之Z方向上的尺寸比溝14之Z方向上的尺寸小。據此,可縮短氣體通過孔部15c的時間。也就是說,可謀求氣體流動的順暢化,同時可更有效地抑制電弧放電的發生。而且,在X方向或Y方向上,可使孔部15c的尺寸大於溝14的尺寸。如此,使氣體流入溝14變得容易。因此,藉由氣體有效地冷卻對象物W成為可能。As mentioned above, the ceramic dielectric substrate 11 has at least one groove 14 that opens on the first main surface 11 a and communicates with the through hole 15. Furthermore, the size of the hole 15c in the Z direction can be made smaller than the size of the groove 14 in the Z direction. Accordingly, the time for the gas to pass through the hole 15c can be shortened. In other words, the flow of gas can be smoothed, and the occurrence of arc discharge can be more effectively suppressed. Moreover, the size of the hole 15c can be made larger than the size of the groove 14 in the X direction or the Y direction. In this way, it becomes easy for the gas to flow into the groove 14. Therefore, it is possible to effectively cool the object W by the gas.

而且,使孔部15c的第一主表面11a側的面15c1(頂面)的算術平均表面粗糙度Ra小於溝14的底面14a(第二主表面11b側的面)的算術平均表面粗糙度Ra較佳。據此,因在孔部15c的面15c1無大的凹凸,故可有效地抑制電弧放電的發生。Furthermore, the arithmetic mean surface roughness Ra of the surface 15c1 (top surface) of the hole 15c on the first main surface 11a side is smaller than the arithmetic mean surface roughness Ra of the bottom surface 14a (the surface on the second main surface 11b side) of the groove 14 Better. Accordingly, since there are no large irregularities on the surface 15c1 of the hole portion 15c, the occurrence of arc discharge can be effectively suppressed.

而且,使溝14的第二主表面11b側的面14a的算術平均表面粗糙度Ra小於第二主表面11b的算術平均表面粗糙度Ra較佳。據此,因在溝14的面14a無大的凹凸,故可有效地抑制電弧放電的發生。Furthermore, it is preferable to make the arithmetic mean surface roughness Ra of the surface 14a on the second main surface 11b side of the groove 14 smaller than the arithmetic mean surface roughness Ra of the second main surface 11b. According to this, since there are no large irregularities on the surface 14a of the groove 14, the occurrence of arc discharge can be effectively suppressed.

而且,可更具備設置於孔部15b與孔部15c之間的孔部15d(第三孔部)。在X方向或Y方向上,可使孔部15d的尺寸大於孔部15b,小於孔部15c。若設置孔部15d,則可謀求氣體流動的順暢化。Furthermore, the hole 15d (third hole) provided between the hole 15b and the hole 15c may be further provided. In the X direction or the Y direction, the size of the hole 15d can be larger than the hole 15b and smaller than the hole 15c. If the hole 15d is provided, the gas flow can be smoothed.

如前述,可在陶瓷介電質基板11與底板50之間設置接合部60。在Z方向上,可使孔部15c的尺寸比接合部60的尺寸小。據此,可提高陶瓷介電質基板11與底板50的接合強度。而且,因可使Z方向上的孔部15c的尺寸比接合部60的尺寸小,故可謀求氣體流動的順暢化,同時可更有效地抑制電弧放電的發生。As mentioned above, the joint 60 may be provided between the ceramic dielectric substrate 11 and the bottom plate 50. In the Z direction, the size of the hole 15c can be made smaller than the size of the joint 60. Accordingly, the bonding strength between the ceramic dielectric substrate 11 and the bottom plate 50 can be improved. Furthermore, since the size of the hole portion 15c in the Z direction can be made smaller than the size of the joint portion 60, the gas flow can be smoothed, and the occurrence of arc discharge can be more effectively suppressed.

在該例子中,多孔質部90被設置於孔部15a。因此,多孔質部90的頂面90U不露出於第一主表面11a。也就是說,多孔質部90的頂面90U位於第一主表面11a與第二主表面11b之間。另一方面,多孔質部90的底面90L露出於第二主表面11b。In this example, the porous part 90 is provided in the hole part 15a. Therefore, the top surface 90U of the porous portion 90 is not exposed on the first main surface 11a. That is, the top surface 90U of the porous portion 90 is located between the first main surface 11a and the second main surface 11b. On the other hand, the bottom surface 90L of the porous portion 90 is exposed on the second main surface 11b.

接著,就多孔質部90進行說明。多孔質部90具有後述的複數個稀疏部分94與複數個緊密部分95。此外,雖然在圖2中舉例說明將多孔質部90設置於陶瓷基板11的情形,但是如後述,也可以將多孔質部90設置於底板50(例如圖12(b)等)。 多孔質部90具有:具有複數個孔96之多孔區域91(第一多孔區域、第二多孔區域的一例),與比多孔區域91還緻密之緻密區域93(第一緻密區域、第二緻密區域的一例)。多孔區域91構成為氣體可流通。複數個孔96的各個係氣體流通於內部。緻密區域93為孔96比多孔區域91少的區域,或者實質上不具有孔96的區域。緻密區域93的孔隙率(porosity)(百分比:%)低於多孔區域91的孔隙率(%)。緻密區域93的密度(克/立方公分:g/cm3 )高於多孔區域91的密度(g/cm3 )。因緻密區域93比多孔區域91還緻密,故例如緻密區域93的剛性(機械強度)高於多孔區域91的剛性。Next, the porous part 90 will be described. The porous portion 90 has a plurality of sparse portions 94 and a plurality of dense portions 95 described later. In addition, although the case where the porous part 90 is provided on the ceramic substrate 11 is illustrated in FIG. 2, as will be described later, the porous part 90 may be provided on the bottom plate 50 (for example, FIG. 12(b) etc.). The porous portion 90 has a porous region 91 (an example of a first porous region and a second porous region) having a plurality of pores 96, and a dense region 93 that is denser than the porous region 91 (first dense region, second An example of dense area). The porous region 91 is configured to allow gas to flow. Each system gas of the plurality of holes 96 flows inside. The dense area 93 is an area in which the pores 96 are less than the porous area 91 or an area that does not substantially have the pores 96. The porosity (percentage: %) of the dense region 93 is lower than the porosity (%) of the porous region 91. The density of the dense area 93 (g/cm3: g/cm 3 ) is higher than the density of the porous area 91 (g/cm 3 ). Since the dense region 93 is denser than the porous region 91, the rigidity (mechanical strength) of the dense region 93 is higher than the rigidity of the porous region 91, for example.

緻密區域93的孔隙率為例如緻密區域93所包含的空間(孔96)的體積在緻密區域93的全體積所佔的比例。多孔區域91的孔隙率為例如多孔區域91所包含的空間(孔96)的體積在多孔區域91的全體積所佔的比例。例如多孔區域91的孔隙率為5%以上、40%以下,較佳為10%以上、30%以下,緻密區域93的孔隙率為0%以上、5%以下。The porosity of the dense region 93 is, for example, the ratio of the volume of the space (pore 96) included in the dense region 93 to the entire volume of the dense region 93. The porosity of the porous region 91 is, for example, the ratio of the volume of the space (pore 96) included in the porous region 91 to the total volume of the porous region 91. For example, the porosity of the porous region 91 is 5% or more and 40% or less, preferably 10% or more and 30% or less, and the porosity of the dense region 93 is 0% or more and 5% or less.

多孔質部90為柱狀(例如圓柱狀)。而且,多孔區域91為柱狀(例如圓柱狀)。緻密區域93與多孔區域91相接或者與多孔區域91接續。如圖2(b)所示,在投影到對Z方向垂直的平面(XY平面)時,緻密區域93包圍多孔區域91的外周。緻密區域93為包圍多孔區域91的側面91s的筒狀(例如圖筒狀)。換言之,多孔區域91以將緻密區域93貫通於Z方向的方式設置。自氣體導入道53流入貫通孔15的氣體通過設置於多孔區域91的複數個孔96而被供給到溝14。The porous part 90 has a columnar shape (for example, a columnar shape). Furthermore, the porous region 91 is columnar (for example, cylindrical). The dense area 93 is in contact with the porous area 91 or continues with the porous area 91. As shown in FIG. 2( b ), when projected on a plane (XY plane) perpendicular to the Z direction, the dense region 93 surrounds the outer periphery of the porous region 91. The dense region 93 has a cylindrical shape (for example, a cylindrical shape in the figure) surrounding the side 91s of the porous region 91. In other words, the porous region 91 is provided so as to penetrate the dense region 93 in the Z direction. The gas flowing into the through hole 15 from the gas introduction path 53 is supplied to the groove 14 through the plurality of holes 96 provided in the porous region 91.

藉由設置具有這種多孔區域91的多孔質部90,可確保流動於貫通孔15的氣體流量,同時可提高對電弧放電的抗性。而且,因多孔質部90具有緻密區域93,故可提高多孔質部90的剛性(機械強度)。By providing the porous portion 90 having such a porous region 91, the gas flow rate flowing through the through hole 15 can be ensured, and the resistance to arc discharge can be improved. Furthermore, since the porous portion 90 has the dense region 93, the rigidity (mechanical strength) of the porous portion 90 can be improved.

在多孔質部90設置於陶瓷介電質基板11的情形下,多孔質部90例如與陶瓷介電質基板11一體化也可以。兩個構件一體化的狀態是指兩個構件化學地結合的狀態。在兩個構件之間不設置用以對他方的構件固定一方的構件的材料(例如接著劑)。也就是說,在該例子中,在多孔質部90與陶瓷介電質基板11之間未設置有接著劑等的其他的構件,多孔質部90與陶瓷介電質基板11一體化。When the porous portion 90 is provided on the ceramic dielectric substrate 11, the porous portion 90 may be integrated with the ceramic dielectric substrate 11, for example. The state where the two members are integrated refers to the state where the two members are chemically bonded. A material (for example, adhesive) for fixing one member to the other member is not provided between the two members. That is, in this example, no other member such as an adhesive is provided between the porous portion 90 and the ceramic dielectric substrate 11, and the porous portion 90 is integrated with the ceramic dielectric substrate 11.

如此,在多孔質部90藉由與陶瓷介電質基板11一體化而對陶瓷介電質基板11固定的情形下,與藉由接著劑等將多孔質部90固定於陶瓷介電質基板11的情形比較,可提高靜電吸盤110的強度。例如不發生因接著劑的腐蝕或沖蝕(erosion)等造成靜電吸盤的劣化。In this way, when the porous portion 90 is fixed to the ceramic dielectric substrate 11 by being integrated with the ceramic dielectric substrate 11, the porous portion 90 is fixed to the ceramic dielectric substrate 11 by an adhesive or the like. Compared with the situation, the strength of the electrostatic chuck 110 can be improved. For example, no deterioration of the electrostatic chuck due to corrosion or erosion of the adhesive occurs.

使多孔質部90與陶瓷介電質基板11一體化的情形,力自陶瓷介電質基板11施加於多孔質部90的外周的側面。另一方面,為了確保氣體的流量,在多孔質部90設置複數個孔的情形,多孔質部90的機械強度降低。因此,在使多孔質部90與陶瓷介電質基板11一體化時,有藉由自陶瓷介電質基板11施加於多孔質部90的力而使多孔質部90破損之虞。When the porous portion 90 and the ceramic dielectric substrate 11 are integrated, force is applied from the ceramic dielectric substrate 11 to the outer peripheral side surface of the porous portion 90. On the other hand, in order to ensure the flow rate of gas, when a plurality of holes are provided in the porous portion 90, the mechanical strength of the porous portion 90 is reduced. Therefore, when the porous portion 90 and the ceramic dielectric substrate 11 are integrated, the porous portion 90 may be damaged by the force applied to the porous portion 90 from the ceramic dielectric substrate 11.

相對於此,藉由多孔質部90具有緻密區域93,可提高多孔質部90的剛性(機械強度),且可使多孔質部90與陶瓷介電質基板11一體化。In contrast, since the porous portion 90 has the dense region 93, the rigidity (mechanical strength) of the porous portion 90 can be increased, and the porous portion 90 and the ceramic dielectric substrate 11 can be integrated.

此外,在實施形態中多孔質部90未必與陶瓷介電質基板11一體化也可以。例如如圖11所示,使用接著劑將多孔質部90安裝於陶瓷介電質基板也可以。In addition, in the embodiment, the porous portion 90 may not necessarily be integrated with the ceramic dielectric substrate 11. For example, as shown in FIG. 11, the porous portion 90 may be mounted on the ceramic dielectric substrate using an adhesive.

而且,緻密區域93位於形成貫通孔15的陶瓷介電質基板11的內壁15w與多孔區域91之間。也就是說,在多孔質部90的內側設置有多孔區域91,在外側設置有緻密區域93。藉由在多孔質部90的外側設置有緻密區域93,可提高對自陶瓷介電質基板11施加於多孔質部90的力的剛性。據此,可容易使多孔質部90與陶瓷介電質基板11一體化。而且,例如在多孔質部90與陶瓷介電質基板11之間設置有接著構件61(參照圖11)的情形,可藉由緻密區域93抑制通過多孔質部90內的氣體接觸接著構件61。據此,可抑制接著構件61的劣化。而且,藉由在多孔質部90的內側設置有多孔區域91,可抑制陶瓷介電質基板11的貫通孔15被緻密區域93堵塞,可確保氣體的流量。Furthermore, the dense region 93 is located between the inner wall 15w of the ceramic dielectric substrate 11 where the through hole 15 is formed and the porous region 91. That is, the porous region 91 is provided on the inner side of the porous portion 90, and the dense region 93 is provided on the outer side. By providing the dense region 93 on the outer side of the porous portion 90, the rigidity of the force applied to the porous portion 90 from the ceramic dielectric substrate 11 can be improved. According to this, the porous portion 90 and the ceramic dielectric substrate 11 can be easily integrated. Furthermore, for example, when the adhesive member 61 (see FIG. 11) is provided between the porous portion 90 and the ceramic dielectric substrate 11, the dense region 93 can prevent the gas passing through the porous portion 90 from contacting the adhesive member 61. Accordingly, the deterioration of the adhesive member 61 can be suppressed. Furthermore, by providing the porous region 91 inside the porous portion 90, the through hole 15 of the ceramic dielectric substrate 11 can be prevented from being blocked by the dense region 93, and the flow rate of gas can be ensured.

緻密區域93的厚度(多孔區域91的側面91s與緻密區域93的側面93s之間的長度L0)為例如100μm以上、1000μm以下。The thickness of the dense region 93 (the length L0 between the side surface 91s of the porous region 91 and the side surface 93s of the dense region 93) is, for example, 100 μm or more and 1000 μm or less.

多孔質部90的材料使用具有絕緣性的陶瓷。多孔質部90(多孔區域91及緻密區域93的各個)包含氧化鋁(Al2 O3 )、氧化鈦(TiO2 )及氧化釔(Y2 O3 )的至少任一個。據此,可得到多孔質部90的高的耐受電壓與高的剛性。As the material of the porous portion 90, an insulating ceramic is used. The porous portion 90 (each of the porous region 91 and the dense region 93) contains at least any one of aluminum oxide (Al 2 O 3 ), titanium oxide (TiO 2 ), and yttrium oxide (Y 2 O 3 ). Accordingly, a high withstand voltage and high rigidity of the porous part 90 can be obtained.

例如多孔質部90以氧化鋁、氧化鈦及氧化釔的任一個作為主成分。 此情形,可使陶瓷介電質基板11的氧化鋁的純度比多孔質部90的氧化鋁的純度高。據此,可確保靜電吸盤110的耐電漿性等的性能,且可確保多孔質部90的機械強度。作為一例,藉由使多孔質部90含有微量的添加物而促進多孔質部90的燒結,使氣孔的控制及機械強度的確保成為可能。For example, the porous part 90 contains any one of aluminum oxide, titanium oxide, and yttrium oxide as a main component. In this case, the purity of the alumina of the ceramic dielectric substrate 11 can be made higher than the purity of the alumina of the porous portion 90. Accordingly, performance such as plasma resistance of the electrostatic chuck 110 can be ensured, and the mechanical strength of the porous portion 90 can be ensured. As an example, the sintering of the porous portion 90 is promoted by including a trace amount of additives in the porous portion 90, thereby making it possible to control pores and ensure mechanical strength.

在本說明書中,陶瓷介電質基板11的氧化鋁等的陶瓷純度可藉由X射線螢光分析(X‐ray fluorescence analysis)、ICP-AES法(Inductively Coupled Plasma-Atomic Emission Spectrometry:感應耦合電漿原子發射光譜分析儀法)等進行測定。In this specification, the purity of the ceramics such as alumina of the ceramic dielectric substrate 11 can be determined by X-ray fluorescence analysis and ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometry). Pulp Atomic Emission Spectrometer Method) and so on.

例如多孔區域91的材料與緻密區域93的材料相同。但是,多孔區域91的材料與緻密區域93的材料不同也可以。多孔區域91的材料的組成與緻密區域93的材料的組成不同也可以。For example, the material of the porous area 91 is the same as the material of the dense area 93. However, the material of the porous region 91 and the material of the dense region 93 may be different. The composition of the material of the porous region 91 and the composition of the material of the dense region 93 may be different.

圖3(a)、(b)是舉例說明與實施形態有關的靜電吸盤的多孔質部90之示意圖。 圖3(a)是沿著Z方向看的多孔質部90之俯視圖,圖3(b)是多孔質部90的ZY平面上的剖面圖。3(a) and (b) are schematic diagrams illustrating the porous part 90 of the electrostatic chuck according to the embodiment. FIG. 3(a) is a plan view of the porous part 90 viewed along the Z direction, and FIG. 3(b) is a cross-sectional view of the porous part 90 on the ZY plane.

如圖3(a)及圖3(b)所示,在多孔質部90中,多孔區域91具有複數個稀疏部分94 (第一稀疏部分、第二稀疏部分的一例)與緊密部分95(第一緊密部分、第二緊密部分的一例)。也可以具有複數個緊密部分95。複數個稀疏部分94的各個具有複數個孔96。緊密部分95比稀疏部分94還緻密。也就是說,緊密部分95是孔比稀疏部分94少的部分,或者實質上不具有孔的部分。X方向或Y方向上的緊密部分95的尺寸小於X方向或Y方向上的緻密區域93的尺寸。緊密部分95的孔隙率比稀疏部分94的孔隙率低。因此,緊密部分95的密度比稀疏部分94的密度高。緊密部分95的孔隙率也可以與緻密區域93的孔隙率相同。藉由緊密部分95比稀疏部分94還緻密,使得緊密部分95的剛性比稀疏部分94的剛性高。3(a) and 3(b), in the porous portion 90, the porous area 91 has a plurality of sparse portions 94 (an example of the first sparse portion and the second sparse portion) and a dense portion 95 (the first sparse portion). An example of a compact part and a second compact part). There may also be a plurality of compact portions 95. Each of the plurality of sparse portions 94 has a plurality of holes 96. The dense part 95 is denser than the sparse part 94. That is, the dense portion 95 is a portion having fewer holes than the sparse portion 94, or a portion having substantially no holes. The size of the dense portion 95 in the X direction or the Y direction is smaller than the size of the dense region 93 in the X direction or the Y direction. The porosity of the dense portion 95 is lower than the porosity of the sparse portion 94. Therefore, the density of the dense part 95 is higher than the density of the sparse part 94. The porosity of the dense portion 95 may also be the same as the porosity of the dense region 93. Since the dense part 95 is denser than the sparse part 94, the rigidity of the dense part 95 is higher than that of the sparse part 94.

1個稀疏部分94的孔隙率例如為該稀疏部分94所包含的空間(孔96)的體積在該稀疏部分94的全體積所佔的比例。緊密部分95的孔隙率例如為緊密部分95所包含的空間(孔96)的體積在緊密部分95的全體積所佔的比例。例如稀疏部分94的孔隙率為20%以上、60%以下,較佳為30%以上、50%以下,緊密部分95的孔隙率為0%以上、5%以下。The porosity of one sparse portion 94 is, for example, the ratio of the volume of the space (pore 96) included in the sparse portion 94 to the total volume of the sparse portion 94. The porosity of the compact portion 95 is, for example, the ratio of the volume of the space (pore 96) contained in the compact portion 95 to the entire volume of the compact portion 95. For example, the porosity of the sparse part 94 is 20% or more and 60% or less, preferably 30% or more and 50% or less, and the porosity of the dense part 95 is 0% or more and 5% or less.

複數個稀疏部分94的各個延伸於Z方向。例如複數個稀疏部分94的各個為柱狀(圓柱狀或多角柱狀),設置成將多孔區域91貫通於Z方向。緊密部分95位於複數個稀疏部分94彼此之間。緊密部分95為將互相鄰接的稀疏部分94隔開的壁狀。如圖3(a)所示,在投影於對Z方向垂直的平面(XY平面)時,緊密部分95設置成包圍複數個稀疏部分94的各個的外周。緊密部分95在多孔區域91的外周中與緻密區域93接續。Each of the plurality of sparse portions 94 extends in the Z direction. For example, each of the plurality of sparse portions 94 is columnar (cylindrical or polygonal columnar), and is provided so as to penetrate the porous region 91 in the Z direction. The tight portion 95 is located between the plurality of sparse portions 94. The dense portion 95 is in the shape of a wall separating the sparse portions 94 adjacent to each other. As shown in FIG. 3(a), when projecting on a plane (XY plane) perpendicular to the Z direction, the dense portion 95 is provided so as to surround the outer periphery of each of the plurality of sparse portions 94. The dense portion 95 continues with the dense area 93 in the outer periphery of the porous area 91.

設置於多孔區域91內的稀疏部分94的數目為例如50個以上、1000個以下。如圖3(a)所示,在投影於對Z方向垂直的平面(XY平面)時,複數個稀疏部分94彼此為互相大致相同的大小。例如在投影於對Z方向垂直的平面(XY平面)時,複數個稀疏部分94在多孔區域91內等向性地均勻地分散。例如鄰接的稀疏部分94彼此的距離(亦即緊密部分95的厚度)大致一定。The number of sparse portions 94 provided in the porous region 91 is, for example, 50 or more and 1,000 or less. As shown in FIG. 3(a), when projecting on a plane (XY plane) perpendicular to the Z direction, the plurality of sparse portions 94 have substantially the same size as each other. For example, when projecting on a plane (XY plane) perpendicular to the Z direction, a plurality of sparse portions 94 are uniformly dispersed in the porous region 91 isotropically. For example, the distance between adjacent sparse portions 94 (that is, the thickness of the dense portion 95) is approximately constant.

例如在投影於對Z方向垂直的平面(XY平面)時,緻密區域93的側面93s與複數個稀疏部分94之中最靠近側面93s的稀疏部分94之間的距離L11為100μm以上、1000μm以下。For example, when projecting on a plane (XY plane) perpendicular to the Z direction, the distance L11 between the side surface 93s of the dense region 93 and the sparse portion 94 closest to the side surface 93s among the plurality of sparse portions 94 is 100 μm or more and 1000 μm or less.

如此,藉由在多孔區域91設置複數個稀疏部分94與比稀疏部分94還緻密的緊密部分95,與在多孔區域內三維地隨機分散有複數個孔的情形比較,可確保對電弧放電的抗性與流動於貫通孔15的氣體的流量,同時可提高多孔質部90的剛性。 例如若多孔區域91的孔隙率變大,則氣體的流量變大,另一方面對電弧放電的抗性及剛性降低。相對於此,藉由在多孔區域91設置X方向或Y方向的尺寸小於緻密區域93的X方向或Y方向的尺寸的緊密部分95,即使是加大孔隙率的情形,也可抑制對電弧放電的抗性及剛性的降低。In this way, by providing a plurality of sparse portions 94 and a dense portion 95 denser than the sparse portions 94 in the porous area 91, compared with the case where a plurality of holes are randomly dispersed in the porous area in three dimensions, the resistance to arc discharge can be ensured. It is possible to increase the rigidity of the porous portion 90 while maintaining the flexibility and the flow rate of the gas flowing through the through holes 15. For example, if the porosity of the porous region 91 increases, the flow rate of the gas increases, and on the other hand, the resistance to arc discharge and rigidity decrease. In contrast, by providing the porous region 91 with a dense portion 95 whose size in the X or Y direction is smaller than the size of the dense region 93 in the X or Y direction, even when the porosity is increased, the arc discharge can be suppressed. The resistance and rigidity are reduced.

例如在投影於對Z方向垂直的平面(XY平面)時,假定包含複數個稀疏部分94的全部的最小的圓、橢圓或多角形。可將該圓、橢圓或多角形的內側當作多孔區域91而將該圓、橢圓或多角形的外側考慮為緻密區域93。For example, when projecting on a plane (XY plane) perpendicular to the Z direction, the smallest circle, ellipse, or polygon including all the sparse portions 94 is assumed. The inner side of the circle, ellipse, or polygon can be regarded as the porous area 91 and the outer side of the circle, ellipse, or polygon can be regarded as the dense area 93.

如以上說明的,多孔質部90可具有:具有包含第一孔96及第二孔96的複數個孔96之複數個稀疏部分94;具有比稀疏部分94的密度高的密度之緊密部分95。複數個稀疏部分94的各個延伸於Z方向。緊密部分95位於複數個稀疏部分94彼此之間。稀疏部分94具有設置於複數個孔96彼此之間(第一孔96與第二孔96之間)的壁部97(第一壁部、第二壁部的例子)。在X方向或Y方向上,可使壁部97的尺寸的最小值比緊密部分95的尺寸的最小值小。據此,因在多孔質部90設置有延伸於Z方向的稀疏部分94與緊密部分95,故可確保對電弧放電的抗性與氣體流量,同時可提高多孔質部90的機械強度(剛性)。As described above, the porous portion 90 may have a plurality of sparse portions 94 having a plurality of pores 96 including the first hole 96 and the second hole 96; and a dense portion 95 having a density higher than that of the sparse portion 94. Each of the plurality of sparse portions 94 extends in the Z direction. The tight portion 95 is located between the plurality of sparse portions 94. The sparse portion 94 has a wall portion 97 (examples of the first wall portion and the second wall portion) provided between the plurality of holes 96 (between the first hole 96 and the second hole 96). In the X direction or the Y direction, the minimum size of the wall portion 97 can be made smaller than the minimum size of the compact portion 95. Accordingly, since the porous portion 90 is provided with the sparse portion 94 and the dense portion 95 extending in the Z direction, the resistance to arc discharge and the gas flow rate can be ensured, and the mechanical strength (rigidity) of the porous portion 90 can be improved. .

而且,如後述的圖5所舉例說明的,在X方向或Y方向上,可使設置於複數個稀疏部分94的各個的複數個孔96的尺寸比緊密部分95的尺寸小。據此,因可充分減小複數個孔96的尺寸,故可更提高對電弧放電的抗性。Moreover, as illustrated in FIG. 5 described later, the size of the plurality of holes 96 provided in each of the plurality of sparse portions 94 can be made smaller than the size of the dense portion 95 in the X direction or the Y direction. According to this, since the size of the plurality of holes 96 can be sufficiently reduced, the resistance to arc discharge can be further improved.

而且,設置於複數個稀疏部分94的各個的複數個孔96的縱橫比能以30以上、10000以下。據此,可更提高對電弧放電的抗性。更佳為複數個孔96的縱橫比的下限為100以上,上限為1600以下。Furthermore, the aspect ratio of the plurality of holes 96 provided in each of the plurality of sparse portions 94 can be 30 or more and 10,000 or less. Accordingly, the resistance to arc discharge can be further improved. More preferably, the lower limit of the aspect ratio of the plurality of holes 96 is 100 or more, and the upper limit is 1600 or less.

而且,在X方向或Y方向上,設置於複數個稀疏部分94的各個的複數個孔96的尺寸能以1微米以上、20微米以下。據此,因可排列孔96的尺寸為1~20微米之延伸於一方向的孔96,故可實現對電弧放電的高的抗性。In addition, in the X direction or the Y direction, the size of the plurality of holes 96 provided in each of the plurality of sparse portions 94 can be 1 micrometer or more and 20 micrometers or less. According to this, since the holes 96 extending in one direction with a size of 1 to 20 microns can be arranged, high resistance to arc discharge can be realized.

而且,如後述的圖6(a)、(b)所舉例說明的,在投影於對Z方向垂直的平面(XY平面)時,孔96a位於稀疏部分94的中心部,複數個孔96之中與孔96a鄰接且包圍孔96a的孔96b~96g的數目能以6。據此,在平面視中,能以高的等向性且高的密度配置複數個孔96。據此,可確保對電弧放電的抗性與流動的氣體的流量,同時可提高多孔質部90的剛性。6(a) and (b) described later, when projected on a plane perpendicular to the Z direction (XY plane), the hole 96a is located in the center of the sparse portion 94, and among the plurality of holes 96 The number of holes 96b to 96g adjacent to and surrounding the hole 96a can be six. Accordingly, in a plan view, a plurality of holes 96 can be arranged with high isotropy and high density. Accordingly, the resistance to arc discharge and the flow rate of the flowing gas can be ensured, and the rigidity of the porous portion 90 can be improved.

圖4是舉例說明與實施形態有關的靜電吸盤的多孔質部90之示意俯視圖。 圖4顯示沿著Z方向看的多孔質部90的一部分,相當於圖3(a)的放大視圖。 在投影於對Z方向垂直的平面(XY平面)時,複數個稀疏部分94的各個為略六角形(略正六角形)。在投影於對Z方向垂直的平面(XY平面)時,複數個稀疏部分94具有:位於多孔區域91的中心部之稀疏部分94a;包圍稀疏部分94a之6個稀疏部分94(稀疏部分94b~94g)。Fig. 4 is a schematic plan view illustrating the porous part 90 of the electrostatic chuck according to the embodiment. Fig. 4 shows a part of the porous portion 90 viewed along the Z direction, which corresponds to an enlarged view of Fig. 3(a). When projecting on a plane (XY plane) perpendicular to the Z direction, each of the plurality of sparse portions 94 has a slightly hexagonal shape (slightly regular hexagonal shape). When projected on a plane perpendicular to the Z direction (XY plane), the plural sparse portions 94 have: a sparse portion 94a located at the center of the porous area 91; six sparse portions 94 (sparse portions 94b to 94g) surrounding the sparse portion 94a ).

稀疏部分94b~94g與稀疏部分94a鄰接。稀疏部分94b~94g是複數個稀疏部分94之中最接近稀疏部分94a而設置。The sparse portions 94b to 94g are adjacent to the sparse portion 94a. The sparse portions 94b to 94g are provided closest to the sparse portion 94a among the plurality of sparse portions 94.

稀疏部分94b及稀疏部分94c與稀疏部分94a在X方向上並排。也就是說,稀疏部分94a位於稀疏部分94b與稀疏部分94c之間。The sparse portion 94b and the sparse portion 94c and the sparse portion 94a are arranged side by side in the X direction. That is, the sparse part 94a is located between the sparse part 94b and the sparse part 94c.

稀疏部分94a之沿著X方向的長度L1(稀疏部分94a的直徑)比稀疏部分94a與稀疏部分94b之間之沿著X方向的長度L2長,比稀疏部分94a與稀疏部分94c之間之沿著X方向的長度L3長。The length L1 of the sparse part 94a along the X direction (the diameter of the sparse part 94a) is longer than the length L2 between the sparse part 94a and the sparse part 94b along the X direction, and is longer than the length between the sparse part 94a and the sparse part 94c The length L3 in the X direction is long.

此外,長度L2及長度L3的各個相當於緊密部分95的厚度。也就是說,長度L2是稀疏部分94a與稀疏部分94b之間的緊密部分95之沿著X方向的長度。長度L3是稀疏部分94a與稀疏部分94c之間的緊密部分95之沿著X方向的長度。可使長度L2與長度L3大致相同。例如可使長度L2為長度L3的0.5倍以上、2.0倍以下。In addition, each of the length L2 and the length L3 corresponds to the thickness of the compact portion 95. That is, the length L2 is the length along the X direction of the tight portion 95 between the sparse portion 94a and the sparse portion 94b. The length L3 is the length along the X direction of the tight portion 95 between the sparse portion 94a and the sparse portion 94c. The length L2 can be approximately the same as the length L3. For example, the length L2 may be 0.5 times or more and 2.0 times or less the length L3.

而且,可使長度L1與稀疏部分94b之沿著X方向的長度L4(稀疏部分94b的直徑)大致相同。可使長度L1與稀疏部分94c之沿著X方向的長度L5(稀疏部分95c的直徑)大致相同。例如可使長度L4及長度L5的各個為長度L1的0.5倍以上、2.0倍以下。Furthermore, the length L1 and the length L4 of the sparse portion 94b along the X direction (the diameter of the sparse portion 94b) can be made substantially the same. The length L1 and the length L5 of the sparse portion 94c along the X direction (the diameter of the sparse portion 95c) can be made substantially the same. For example, each of the length L4 and the length L5 may be 0.5 times or more and 2.0 times or less the length L1.

如此,稀疏部分94a鄰接於複數個稀疏部分94之中的6個稀疏部分94並被6個稀疏部分94包圍。也就是說,在投影於對Z方向垂直的平面(XY平面)時,在多孔區域91的中心部中與1個稀疏部分94鄰接的稀疏部分94的數目為6。據此,在平面視中,能以高的等向性且高的密度配置複數個稀疏部分94。據此,可確保對電弧放電的抗性與流動於貫通孔15的氣體的流量,同時可提高多孔質部90的剛性。而且,可抑制對電弧放電的抗性的不均、流動於貫通孔15的氣體的流量的不均及多孔質部90的剛性的不均。In this way, the sparse portion 94 a is adjacent to and surrounded by six sparse portions 94 among the plurality of sparse portions 94. That is, when projecting on a plane (XY plane) perpendicular to the Z direction, the number of sparse portions 94 adjacent to one sparse portion 94 in the center of the porous region 91 is six. Accordingly, in plan view, a plurality of sparse portions 94 can be arranged with high isotropy and high density. Accordingly, the resistance to arc discharge and the flow rate of the gas flowing through the through holes 15 can be ensured, and the rigidity of the porous portion 90 can be improved. Furthermore, it is possible to suppress unevenness in resistance to arc discharge, unevenness in the flow rate of the gas flowing through the through holes 15 and unevenness in the rigidity of the porous portion 90.

稀疏部分94的直徑(長度L1、L4或L5等)為例如50μm以上、500μm以下。緊密部分95的厚度(長度L2或L3等)為例如10μm以上、100μm以下。稀疏部分94的直徑比緊密部分95的厚度大。而且如前述,緊密部分95的厚度比緻密區域93的厚度小。The diameter (length L1, L4, or L5, etc.) of the sparse portion 94 is, for example, 50 μm or more and 500 μm or less. The thickness (length L2 or L3, etc.) of the tight portion 95 is, for example, 10 μm or more and 100 μm or less. The diameter of the sparse portion 94 is larger than the thickness of the dense portion 95. Also, as described above, the thickness of the dense portion 95 is smaller than the thickness of the dense region 93.

圖5是舉例說明與實施形態有關的靜電吸盤的多孔質部90之示意俯視圖。 圖5顯示沿著Z方向看的多孔質部90的一部分。圖5是1個稀疏部分94的周邊的放大視圖。 如圖5所示,在該例子中,稀疏部分94具有:複數個孔96;設置於複數個孔96彼此之間的壁部97。Fig. 5 is a schematic plan view illustrating the porous part 90 of the electrostatic chuck according to the embodiment. FIG. 5 shows a part of the porous part 90 viewed in the Z direction. FIG. 5 is an enlarged view of the periphery of one sparse part 94. As shown in FIG. 5, in this example, the sparse portion 94 has a plurality of holes 96 and a wall portion 97 provided between the plurality of holes 96.

複數個孔96的各個延伸於Z方向。複數個孔96的各個為延伸於一方向的毛細管狀(一維毛細管構造),將稀疏部分94貫通於Z方向。壁部97為將互相鄰接的孔96隔開的壁狀。如圖5所示,在投影於對Z方向垂直的平面(XY平面)時,壁部97設置成包圍複數個孔96的各個的外周。壁部97在稀疏部分94的外周中與緊密部分95接續。Each of the plurality of holes 96 extends in the Z direction. Each of the plurality of holes 96 has a capillary shape (one-dimensional capillary structure) extending in one direction, and penetrates the sparse portion 94 in the Z direction. The wall portion 97 has a wall shape that partitions the holes 96 adjacent to each other. As shown in FIG. 5, when projecting on a plane (XY plane) perpendicular to the Z direction, the wall portion 97 is provided so as to surround the outer circumference of each of the plurality of holes 96. The wall portion 97 continues with the dense portion 95 in the outer circumference of the sparse portion 94.

設置於1個稀疏部分94內的孔96的數目為例如50個以上、1000個以下。如圖5所示,在投影於對Z方向垂直的平面(XY平面)時,複數個孔96彼此為互相大致相同的大小。例如在投影於對Z方向垂直的平面(XY平面)時,複數個孔96在稀疏部分94內等向性地均勻地分散。例如鄰接的孔96彼此的距離(亦即壁部97的厚度)大致一定。The number of holes 96 provided in one sparse part 94 is, for example, 50 or more and 1000 or less. As shown in FIG. 5, when projected on a plane (XY plane) perpendicular to the Z direction, the plurality of holes 96 have substantially the same size as each other. For example, when projecting on a plane (XY plane) perpendicular to the Z direction, a plurality of holes 96 are uniformly dispersed in the sparse portion 94 isotropically. For example, the distance between adjacent holes 96 (that is, the thickness of the wall 97) is approximately constant.

如此,藉由延伸於一方向的孔96排列在稀疏部分94內,與在稀疏部分內三維地隨機分散有複數個孔的情形比較,能以少的不均實現對電弧放電的高的抗性。In this way, by arranging the holes 96 extending in one direction in the sparse portion 94, compared with the case where a plurality of holes are randomly dispersed three-dimensionally in the sparse portion, high resistance to arc discharge can be realized with less unevenness .

此處,就複數個孔96的[毛細管狀構造]更進一步進行說明。 近幾年,更進行了以半導體的高集積化為目的的電路線寬的細線化、電路間距的微細化。被要求對靜電吸盤施加更進一步的高功率,在更高水準下的對象物W的溫度控制。在這種背景下,被要求即使在高功率環境下也確實地抑制電弧放電,同時充分確保氣體流量,並且高精度地控制其流量。在與本實施形態有關的靜電吸盤110中,在為了防止氦供給孔(氣體導入道53)中的電弧放電而以往就已經設置的陶瓷插塞(ceramic plug)(多孔質部90)中,減小該孔徑(孔96的直徑)到例如數μm~十幾μm的水準為止(關於孔96的直徑的詳細於後述)。若直徑減小到該水準,則有氣體的流量控制變的困難之虞。因此在本發明中,例如更對孔96其形狀下功夫以使孔96沿著Z方向。具體而言,以往是藉由比較大的孔確保流量,且藉由使其形狀成三維地複雜來達成防止電弧放電。另一方面在本發明中,藉由使孔96微細到例如其直徑為數μm~十幾μm的水準而達成防止電弧放電,相反地藉由使其形狀單純化確保流量。也就是說,基於與以往完全不同的思想而想到了本發明。Here, the [capillary structure] of the plurality of holes 96 will be further described. In recent years, circuit line widths and circuit pitches have been reduced for the purpose of increasing semiconductor integration. It is required to apply further high power to the electrostatic chuck to control the temperature of the object W at a higher level. In this context, it is required to reliably suppress arc discharge even in a high-power environment, while ensuring a sufficient gas flow rate and controlling the flow rate with high accuracy. In the electrostatic chuck 110 related to this embodiment, a ceramic plug (porous portion 90) that has been installed conventionally in order to prevent arc discharge in the helium supply hole (gas introduction path 53) is reduced The pore diameter (the diameter of the hole 96) is reduced to a level of, for example, a few μm to several dozen μm (the diameter of the hole 96 will be described in detail later). If the diameter is reduced to this level, it may become difficult to control the flow rate of the gas. Therefore, in the present invention, for example, more effort is made to the shape of the hole 96 so that the hole 96 is along the Z direction. Specifically, in the past, a relatively large hole was used to ensure the flow rate, and the shape was three-dimensionally complicated to prevent arc discharge. On the other hand, in the present invention, the hole 96 is made fine to the level of, for example, a few μm to more than ten μm in diameter to prevent arc discharge, and conversely, the shape is simplified to ensure the flow rate. That is, the present invention was conceived based on a completely different idea from the past.

此外,稀疏部分94的形狀不限於六角形,也可以是圓(或橢圓)及其他的多角形。例如在投影於對Z方向垂直的平面(XY平面)時,假定包含以10μm以下的間隔排列的複數個孔96的全部之最小的圓、橢圓或多角形。可將該圓、橢圓或多角形的內側當作稀疏部分94,將該圓、橢圓或多角形的外側考慮為緊密部分95。In addition, the shape of the sparse portion 94 is not limited to a hexagonal shape, and may be a circle (or ellipse) or other polygonal shapes. For example, when projecting on a plane (XY plane) perpendicular to the Z direction, it is assumed that the smallest circle, ellipse, or polygon includes all the holes 96 arranged at intervals of 10 μm or less. The inner side of the circle, ellipse, or polygon can be regarded as the sparse portion 94, and the outer side of the circle, ellipse, or polygon can be regarded as the dense portion 95.

圖6(a)、(b)是舉例說明與實施形態有關的靜電吸盤的多孔質部90之示意俯視圖。 圖6(a)及圖6(b)顯示沿著Z方向看的多孔質部90的一部分,是顯示1個稀疏部分94內的孔96的放大視圖。6(a) and (b) are schematic plan views illustrating examples of the porous portion 90 of the electrostatic chuck according to the embodiment. 6(a) and 6(b) show a part of the porous part 90 viewed along the Z direction, and are enlarged views showing the pores 96 in one sparse part 94. As shown in FIG.

如圖6(a)所示,在投影於對Z方向垂直的平面(XY平面)時,複數個孔96具有:位於稀疏部分94的中心部之孔96a;包圍孔96a之6個孔96(孔96b~96g)。孔96b~96g與孔96a鄰接。孔96b~96g是複數個孔96之中最接近孔96a的孔96。As shown in Fig. 6(a), when projected on a plane perpendicular to the Z direction (XY plane), a plurality of holes 96 have: a hole 96a located in the center of the sparse part 94; 6 holes 96 ( Well 96b~96g). The wells 96b to 96g are adjacent to the well 96a. The holes 96b to 96g are the holes 96 closest to the hole 96a among the plurality of holes 96.

孔96b及孔96c與孔96a在X方向上並排。也就是說,孔96a位於孔96b與孔96c之間。The hole 96b and the hole 96c are aligned with the hole 96a in the X direction. That is, the hole 96a is located between the hole 96b and the hole 96c.

例如孔96a之沿著X方向的長度L6(孔96a的直徑)比孔96a與孔96b之間之沿著X方向的長度L7長,比孔96a與孔96c之間之沿著X方向的長度L8長。For example, the length L6 of the hole 96a along the X direction (the diameter of the hole 96a) is longer than the length L7 between the holes 96a and 96b along the X direction, and is longer than the length between the holes 96a and 96c along the X direction. L8 is long.

此外,長度L7及長度L8的各個相當於壁部97的厚度。也就是說,長度L7是孔96a與孔96b之間的壁部97之沿著X方向的長度。長度L8是孔96a與孔96c之間的壁部97之沿著X方向的長度。可使長度L7與長度L8大致相同。例如可使長度L7為長度L8的0.5倍以上、2.0倍以下。In addition, each of the length L7 and the length L8 corresponds to the thickness of the wall portion 97. In other words, the length L7 is the length of the wall 97 between the hole 96a and the hole 96b along the X direction. The length L8 is the length of the wall 97 between the hole 96a and the hole 96c along the X direction. The length L7 can be approximately the same as the length L8. For example, the length L7 can be 0.5 times or more and 2.0 times or less the length L8.

而且,可使長度L6與孔96b之沿著X方向的長度L9(孔96b的直徑)大致相同。可使長度L6與孔96c之沿著X方向的長度L10(孔96c的直徑)大致相同。例如可使長度L9及長度L10的各個為長度L6的0.5倍以上、2.0倍以下。Furthermore, the length L6 and the length L9 of the hole 96b along the X direction (the diameter of the hole 96b) can be made substantially the same. The length L6 and the length L10 of the hole 96c along the X direction (the diameter of the hole 96c) can be made substantially the same. For example, each of the length L9 and the length L10 may be 0.5 times or more and 2.0 times or less the length L6.

例如若孔的直徑小,則對電弧放電的抗性及剛性提高。另一方面,若孔的直徑大,則可加大氣體的流量。孔96的直徑(長度L6、L9或L10等)為例如1微米(μm)以上、20μm以下。藉由排列直徑1~20μm之延伸於一方向的孔,可藉由少的不均實現對電弧放電的高的抗性。更佳為孔96的直徑為3μm以上、10μm以下。For example, if the diameter of the hole is small, the resistance to arc discharge and rigidity are improved. On the other hand, if the diameter of the hole is large, the gas flow rate can be increased. The diameter (length L6, L9, or L10, etc.) of the hole 96 is, for example, 1 micrometer (μm) or more and 20 μm or less. By arranging holes extending in one direction with a diameter of 1-20 μm, high resistance to arc discharge can be achieved with less unevenness. More preferably, the diameter of the hole 96 is 3 μm or more and 10 μm or less.

此處,就孔96的直徑的測定方法進行說明。使用掃描式電子顯微鏡(scanning electron microscope)(例如日立高新技術公司(Hitachi High:Technologies)、S-3000)藉由1000倍以上的倍率取得影像。使用市售品的影像分析軟體,就孔96算出100個份的相當於圓的直徑,以其平均值當作孔96的直徑。Here, the method of measuring the diameter of the hole 96 will be described. Use a scanning electron microscope (for example, Hitachi High: Technologies, S-3000) to obtain images with a magnification of more than 1000 times. Using a commercially available image analysis software, the diameter of the circle equivalent to 100 parts of the hole 96 is calculated, and the average value is used as the diameter of the hole 96.

抑制複數個孔96的直徑的不均更佳。藉由減小直徑的不均,可更精密地控制流動的氣體的流量及耐受電壓。作為複數個孔96的直徑的不均,可利用在上述孔96的直徑的算出中取得的100個份的相當於圓的直徑的累積分布(cumulative distribution)。具體而言,適用在粒度分布測定(particle size distribution measurement)一般被使用的累積分布50vol%時的粒徑D50(中值粒徑(median size))及累積分布90vol%時的粒徑D90的概念,使用以橫軸為孔徑(μm),以縱軸為相對孔量(%)的孔96的累積分布圖,求出該孔徑的累積分布50vol%時的孔徑(相當於D50直徑)及累積分布90vol%時的孔徑(相當於D90直徑)。將複數個孔96的直徑的不均抑制為滿足D50:D90≤1:2的關係的程度較佳。It is more preferable to suppress the unevenness of the diameter of the plurality of holes 96. By reducing the uneven diameter, the flow rate and withstand voltage of the flowing gas can be more precisely controlled. As the unevenness in the diameter of the plurality of holes 96, the cumulative distribution of the diameter corresponding to the circle of 100 obtained in the calculation of the diameter of the hole 96 can be used. Specifically, the concepts of particle size D50 (median size) at a cumulative distribution of 50 vol% and D90 at a cumulative distribution of 90 vol%, which are generally used in particle size distribution measurement, are applied. , Using the cumulative distribution of pores 96 with the horizontal axis as the pore diameter (μm) and the vertical axis as the relative pore volume (%), find the pore diameter (equivalent to D50 diameter) and cumulative distribution when the cumulative distribution of the pore diameter is 50vol% Hole diameter at 90vol% (equivalent to D90 diameter). It is preferable to suppress the unevenness of the diameter of the plurality of holes 96 to a degree that satisfies the relationship of D50:D90≦1:2.

壁部97的厚度(長度L7、L8等)為例如1μm以上、10μm以下。壁部97的厚度比緊密部分95的厚度薄。The thickness (length L7, L8, etc.) of the wall portion 97 is, for example, 1 μm or more and 10 μm or less. The thickness of the wall portion 97 is thinner than the thickness of the dense portion 95.

如此,孔96a鄰接於複數個孔96之中的6個孔96並被6個孔96包圍。也就是說,在投影於對Z方向垂直的平面(XY平面)時,在稀疏部分94的中心部中與1個孔96鄰接的孔96的數目為6。據此,在平面視中,能以高的等向性且高的密度配置複數個孔96。據此,可確保對電弧放電的抗性與流動於貫通孔15的氣體的流量,同時可提高多孔質部90的剛性。而且,可抑制對電弧放電的抗性的不均、流動於貫通孔15的氣體的流量的不均及多孔質部90的剛性的不均。In this way, the hole 96 a is adjacent to and surrounded by 6 holes 96 among the plurality of holes 96. That is, when projecting on a plane (XY plane) perpendicular to the Z direction, the number of holes 96 adjacent to one hole 96 in the center portion of the sparse portion 94 is six. Accordingly, in a plan view, a plurality of holes 96 can be arranged with high isotropy and high density. Accordingly, the resistance to arc discharge and the flow rate of the gas flowing through the through holes 15 can be ensured, and the rigidity of the porous portion 90 can be improved. Furthermore, it is possible to suppress unevenness in resistance to arc discharge, unevenness in the flow rate of the gas flowing through the through holes 15 and unevenness in the rigidity of the porous portion 90.

圖6(b)顯示稀疏部分94內的複數個孔96的配置的另一例。如圖6(b)所示,在該例子中,複數個孔96以孔96a為中心配置成同心圓狀。據此,在投影於對Z方向垂直的平面(XY平面)時,能以高的等向性且高的密度配置複數個孔。FIG. 6(b) shows another example of the arrangement of a plurality of holes 96 in the sparse portion 94. As shown in FIG. 6(b), in this example, a plurality of holes 96 are arranged concentrically with the hole 96a as the center. According to this, when projecting on a plane (XY plane) perpendicular to the Z direction, a plurality of holes can be arranged with high isotropy and high density.

而且,長度L0~L10的各個可藉由使用掃描式電子顯微鏡等的顯微鏡的觀察進行測定。Moreover, each of the lengths L0 to L10 can be measured by observation using a microscope such as a scanning electron microscope.

就本說明書中的孔隙率的評價進行說明。此處,以多孔質部90中的孔隙率的評價為例進行說明。 取得如圖3(a)之俯視圖的影像,藉由影像分析(image analysis)算出複數個稀疏部分94在多孔區域91所佔的比例R1。影像的取得係使用掃描式電子顯微鏡(例如日立高新技術公司、S-3000)。加速電壓以15kV、倍率以30倍取得BSE影像(Backscattered Electron image)。例如影像尺寸為1280×960像素(pixel),影像色調為256色調。The evaluation of porosity in this specification will be described. Here, the evaluation of the porosity in the porous portion 90 will be described as an example. An image of the top view of FIG. 3(a) is obtained, and the ratio R1 of the plurality of sparse parts 94 in the porous area 91 is calculated by image analysis. The image is obtained using a scanning electron microscope (for example, Hitachi High-Technologies Corporation, S-3000). Acquire BSE images (Backscattered Electron image) with an acceleration voltage of 15kV and a magnification of 30 times. For example, the image size is 1280×960 pixels (pixel), and the image tone is 256 tones.

複數個稀疏部分94在多孔區域91所佔的比例R1的算出係使用影像分析軟體(例如Win-ROOFVer6.5(三谷商事))。 使用Win-ROOFVer6.5之算出比例R1可如下進行。 評價範圍ROI1(參照圖3(a))以包含全部的稀疏部分94的最小圓(或橢圓)。 進行依照單一臨限值(threshold value)(例如0)的二值化(binarization)處理,算出評價範圍ROI1的面積S1。 進行依照兩個臨限值(例如0及136)的二值化處理,算出評價範圍ROI1內的複數個稀疏部分94的合計面積S2。此時,進行稀疏部分94內的填孔處理及被考慮為雜訊(noise)的小的面積的區域的刪除(臨限值:0.002以下)。而且,兩個臨限值係藉由影像的亮度或對比(contrast)適宜調整。 作為面積S2對面積S1的比例,算出比例R1。也就是說,比例R1(%)=(面積S2)/(面積S1)×100。The ratio R1 of the plurality of sparse parts 94 in the porous area 91 is calculated using image analysis software (for example, Win-ROOFVer6.5 (Mitani Corporation)). The calculation ratio R1 using Win-ROOFVer6.5 can be performed as follows. The evaluation range ROI1 (refer to FIG. 3(a)) is the smallest circle (or ellipse) that includes all the sparse portions 94. A binarization process according to a single threshold value (for example, 0) is performed to calculate the area S1 of the evaluation range ROI1. Binarization processing in accordance with two threshold values (for example, 0 and 136) is performed, and the total area S2 of a plurality of sparse parts 94 in the evaluation range ROI1 is calculated. At this time, the hole filling process in the sparse part 94 and the deletion of a small area considered as noise (threshold value: 0.002 or less) are performed. Moreover, the two thresholds are appropriately adjusted by the brightness or contrast of the image. As the ratio of the area S2 to the area S1, the ratio R1 is calculated. That is, the ratio R1(%)=(area S2)/(area S1)×100.

在實施形態中,複數個稀疏部分94在多孔區域91所佔的比例R1為例如40%以上、70%以下,較佳為50%以上、70%以下。比例R1為例如60%左右。In the embodiment, the ratio R1 of the plurality of sparse portions 94 in the porous region 91 is, for example, 40% or more and 70% or less, preferably 50% or more and 70% or less. The ratio R1 is, for example, about 60%.

取得如圖5之俯視圖的影像,藉由影像分析算出複數個孔96在稀疏部分94所佔的比例R2。比例R2例如相當於稀疏部分94的孔隙率。影像的取得係使用掃描式電子顯微鏡(例如日立高新技術公司、S-3000)。加速電壓以15kV、倍率以600倍取得BSE影像。例如影像尺寸為1280×960像素,影像色調為256色調。An image of the top view as shown in FIG. 5 is obtained, and the ratio R2 of a plurality of holes 96 in the sparse part 94 is calculated by image analysis. The ratio R2 corresponds to the porosity of the sparse portion 94, for example. The image is obtained using a scanning electron microscope (for example, Hitachi High-Technologies Corporation, S-3000). The acceleration voltage is 15kV and the magnification is 600 times to obtain BSE images. For example, the image size is 1280×960 pixels, and the image tone is 256 tones.

複數個孔96在稀疏部分94所佔比例R2的算出係使用影像分析軟體(例如Win-ROOFVer6.5(三谷商事))。 使用Win-ROOFVer6.5之算出比例R1可如下進行。 評價範圍ROI2(參照圖5)係以稀疏部分94的形狀以近似的六角形。在評價範圍ROI2內包含有設置於1個稀疏部分94的全部的孔96。 進行依照單一臨限值(例如0)的二值化處理,算出評價範圍ROI2的面積S3。 進行依照兩個臨限值(例如0及96)的二值化處理,算出評價範圍ROI2內的複數個孔96的合計面積S4。此時,進行孔96內的填孔處理及被考慮為雜訊的小的面積區域的刪除(臨限值:1以下)。而且,兩個臨限值係藉由影像的亮度或對比適宜調整。 作為面積S4對面積S3的比例,算出比例R2。也就是說,比例R2(%)=(面積S4)/(面積S3)×100。The ratio R2 of the sparse part 94 of the plurality of wells 96 is calculated by using image analysis software (for example, Win-ROOFVer6.5 (Mitani Corporation)). The calculation ratio R1 using Win-ROOFVer6.5 can be performed as follows. The evaluation range ROI2 (refer to FIG. 5) is approximately hexagonal in the shape of the sparse portion 94. All the wells 96 provided in one sparse part 94 are included in the evaluation range ROI2. The binarization process in accordance with a single threshold value (for example, 0) is performed to calculate the area S3 of the evaluation range ROI2. Binarization processing in accordance with two threshold values (for example, 0 and 96) is performed, and the total area S4 of a plurality of holes 96 in the evaluation range ROI2 is calculated. At this time, the filling process in the hole 96 and the deletion of a small area considered as noise (threshold value: 1 or less) are performed. Moreover, the two thresholds are appropriately adjusted by the brightness or contrast of the image. As the ratio of the area S4 to the area S3, the ratio R2 is calculated. That is, the ratio R2(%)=(area S4)/(area S3)×100.

在實施形態中,複數個孔96在稀疏部分94所佔比例R2(稀疏部分94的孔隙率)為例如20%以上、60%以下,較佳為30%以上、50%以下。比例R2為例如40%左右。In the embodiment, the ratio R2 (porosity of the sparse portion 94) of the sparse portion 94 of the plurality of pores 96 is, for example, 20% or more and 60% or less, preferably 30% or more and 50% or less. The ratio R2 is, for example, about 40%.

多孔區域91的孔隙率例如相當於複數個稀疏部分94在多孔區域91所佔的比例R1與複數個孔96在稀疏部分94所佔的比例R2的積。例如當比例R1為60%、比例R2為40%時,多孔區域91的孔隙率可算出為24%左右。The porosity of the porous region 91 corresponds to, for example, the product of the ratio R1 occupied by the plurality of sparse portions 94 in the porous region 91 and the ratio R2 occupied by the plurality of pores 96 in the sparse portion 94. For example, when the ratio R1 is 60% and the ratio R2 is 40%, the porosity of the porous region 91 can be calculated to be about 24%.

藉由使用具有這種孔隙率的多孔區域91的多孔質部90,可確保流動於貫通孔15的氣體的流量,同時可提高耐受電壓。By using the porous portion 90 having the porous region 91 having such a porosity, the flow rate of the gas flowing through the through holes 15 can be ensured, and the withstand voltage can be improved.

同樣地,可算出陶瓷介電質基板11、多孔質部70的孔隙率。此外,掃描式電子顯微鏡的倍率對應觀察對象在例如數十倍~數千倍的範圍中適宜選擇較佳。Similarly, the porosity of the ceramic dielectric substrate 11 and the porous portion 70 can be calculated. In addition, the magnification of the scanning electron microscope is preferably selected appropriately in the range of, for example, several tens of times to several thousands of times in accordance with the observation object.

圖7(a)、(b)是舉例說明與其他的實施形態有關的多孔質部90之示意圖。 圖7(a)是沿著Z方向看的多孔質部90之俯視圖,圖7(b)相當於圖7(a)的一部分的放大視圖。 如圖7(a)及圖7(b)所示,在該例子中,稀疏部分94的平面形狀為圓形。如此,稀疏部分94的平面形狀也可以不是六角形。Figs. 7(a) and (b) are schematic diagrams illustrating examples of porous portions 90 related to other embodiments. Fig. 7(a) is a plan view of the porous portion 90 viewed along the Z direction, and Fig. 7(b) corresponds to an enlarged view of a part of Fig. 7(a). As shown in FIGS. 7(a) and 7(b), in this example, the planar shape of the sparse portion 94 is a circle. In this way, the planar shape of the sparse portion 94 may not be hexagonal.

圖8是舉例說明與實施形態有關的靜電吸盤之示意剖面圖。 圖8相當於圖2所示的區域B的放大視圖。也就是說,圖8顯示多孔質部90(緻密區域93)與陶瓷介電質基板11的界面F1的近旁。此外,在該例子中,多孔質部90及陶瓷介電質基板11的材料使用氧化鋁。Fig. 8 is a schematic sectional view illustrating an electrostatic chuck related to the embodiment. FIG. 8 corresponds to an enlarged view of the area B shown in FIG. 2. That is, FIG. 8 shows the vicinity of the interface F1 between the porous portion 90 (the dense region 93) and the ceramic dielectric substrate 11. In addition, in this example, alumina is used as the material of the porous portion 90 and the ceramic dielectric substrate 11.

如圖8所示,多孔質部90具有:在X方向或Y方向上位於陶瓷介電質基板11側之第一區域90p;與第一區域90p在X方向或Y方向上接續之第二區域90q。第一區域90p及第二區域90q是多孔質部90的緻密區域93的一部分。As shown in FIG. 8, the porous portion 90 has: a first region 90p located on the side of the ceramic dielectric substrate 11 in the X direction or Y direction; and a second region continuous with the first region 90p in the X direction or Y direction 90q. The first region 90p and the second region 90q are a part of the dense region 93 of the porous part 90.

第一區域90p在X方向或Y方向上位於第二區域90q與陶瓷介電質基板11之間。第一區域90p是在X方向或Y方向距界面F1為40~60μm左右的區域。也就是說,第一區域90p之沿著X方向或Y方向的寬度W1(對界面F1垂直的方向上的第一區域90p的長度)為例如40μm以上、60μm以下。The first region 90p is located between the second region 90q and the ceramic dielectric substrate 11 in the X direction or the Y direction. The first region 90p is a region about 40 to 60 μm from the interface F1 in the X direction or the Y direction. That is, the width W1 of the first region 90p along the X direction or the Y direction (the length of the first region 90p in the direction perpendicular to the interface F1) is, for example, 40 μm or more and 60 μm or less.

而且,陶瓷介電質基板11具有:在X方向或Y方向上位於多孔質部90(第一區域90p)側之第一基板區域11p;與第一基板區域11p在X方向或Y方向上接續之第二基板區域11q。第一區域90p與第一基板區域11p相接而被設置。第一基板區域11p在X方向或Y方向上位於第二基板區域11q與多孔質部90之間。第一基板區域11p是在X方向或Y方向距界面F1為40~60μm左右的區域。也就是說,第一基板區域11p之沿著X方向或Y方向的寬度W2(對界面F1垂直的方向上的第一基板區域11p的長度)為例如40μm以上、60μm以下。Furthermore, the ceramic dielectric substrate 11 has: a first substrate region 11p located on the side of the porous portion 90 (first region 90p) in the X direction or the Y direction; and continues with the first substrate region 11p in the X direction or Y direction The second substrate area 11q. The first region 90p is provided in contact with the first substrate region 11p. The first substrate region 11p is located between the second substrate region 11q and the porous portion 90 in the X direction or the Y direction. The first substrate region 11p is a region that is about 40 to 60 μm from the interface F1 in the X direction or the Y direction. That is, the width W2 of the first substrate region 11p along the X direction or the Y direction (the length of the first substrate region 11p in the direction perpendicular to the interface F1) is, for example, 40 μm or more and 60 μm or less.

圖9(a)、(b)是舉例說明與實施形態有關的靜電吸盤之示意剖面圖。 圖9(a)是圖8所示的第一區域90p的一部分的放大視圖。圖9(b)是圖8所示的第一基板區域11p的一部分的放大視圖。 如圖9(a)所示,第一區域90p包含複數個粒子g1(晶粒(crystal grain))。而且,如圖9(b)所示,第一基板區域11p包含複數個粒子g2(晶粒)。Figures 9(a) and (b) are schematic cross-sectional views illustrating an electrostatic chuck related to the embodiment. Fig. 9(a) is an enlarged view of a part of the first region 90p shown in Fig. 8. Fig. 9(b) is an enlarged view of a part of the first substrate region 11p shown in Fig. 8. As shown in FIG. 9(a), the first region 90p includes a plurality of particles g1 (crystal grains). Furthermore, as shown in FIG. 9(b), the first substrate region 11p includes a plurality of particles g2 (crystal grains).

第一區域90p中的平均粒徑(mean particle size)(複數個粒子g1的直徑的平均值)與第一基板區域11p中的平均粒徑(複數個粒子g2的直徑的平均值)不同。The mean particle size (average of the diameters of the plurality of particles g1) in the first region 90p is different from the average particle size (the average of the diameters of the plurality of particles g2) in the first substrate region 11p.

藉由第一區域90p中的平均粒徑與第一基板區域11p中的平均粒徑不同,在界面F1上可提高多孔質部90的晶粒與陶瓷介電質基板11的晶粒的結合強度(界面強度)。例如可抑制多孔質部90自陶瓷介電質基板11剝離及/或晶粒的脫粒。Since the average particle size in the first region 90p is different from the average particle size in the first substrate region 11p, the bonding strength between the crystal grains of the porous portion 90 and the crystal grains of the ceramic dielectric substrate 11 can be improved at the interface F1 (Interface strength). For example, peeling of the porous portion 90 from the ceramic dielectric substrate 11 and/or degranulation of crystal grains can be suppressed.

此外,平均粒徑可使用如圖9(a)及圖9(b)的剖面的影像中的晶粒的相當於圓的直徑的平均值。相當於圓的直徑是指具有與作為對象的平面形狀的面積相同面積的圓的直徑。In addition, the average particle diameter can use the average value of the diameter equivalent to the circle of the crystal grains in the image of the cross section of FIG. 9(a) and FIG. 9(b). The diameter equivalent to a circle refers to the diameter of a circle having the same area as the area of the target planar shape.

陶瓷介電質基板11與多孔質部90一體化也較佳。多孔質部90藉由與陶瓷介電質基板11一體化而被固定於陶瓷介電質基板11。據此,與藉由接著劑等將多孔質部90固定於陶瓷介電質基板11的情形比較,可提高靜電吸盤的強度。例如可抑制因接著劑的腐蝕或沖蝕(erosion)等造成靜電吸盤的劣化。The ceramic dielectric substrate 11 and the porous portion 90 are also preferably integrated. The porous portion 90 is fixed to the ceramic dielectric substrate 11 by being integrated with the ceramic dielectric substrate 11. According to this, compared with the case where the porous portion 90 is fixed to the ceramic dielectric substrate 11 by an adhesive or the like, the strength of the electrostatic chuck can be improved. For example, it is possible to suppress the deterioration of the electrostatic chuck due to corrosion or erosion of the adhesive.

在該例子中,第一基板區域11p中的平均粒徑比第一區域90p中的平均粒徑小。藉由第一基板區域11p中的粒徑小,在多孔質部90與陶瓷介電質基板的界面上可提高多孔質部90與陶瓷介電質基板的結合強度。而且,藉由第一基板區域中的粒徑小可提高陶瓷介電質基板11的強度,可抑制因在製作時或製程時發生的應力造成的裂痕(crack)等的風險。例如第一區域90p中的平均粒徑為3μm以上、5μm以下。例如第一基板區域11p中的平均粒徑為0.5μm以上、2μm以下。第一基板區域11p中的平均粒徑為第一區域90p中的平均粒徑的1.1倍以上、5倍以下。In this example, the average particle diameter in the first substrate region 11p is smaller than the average particle diameter in the first region 90p. Due to the small particle size in the first substrate region 11p, the bonding strength between the porous portion 90 and the ceramic dielectric substrate can be improved at the interface between the porous portion 90 and the ceramic dielectric substrate. Moreover, the small particle size in the first substrate region can increase the strength of the ceramic dielectric substrate 11, and can suppress the risk of cracks due to stress generated during production or during the process. For example, the average particle size in the first region 90p is 3 μm or more and 5 μm or less. For example, the average particle size in the first substrate region 11p is 0.5 μm or more and 2 μm or less. The average particle diameter in the first substrate region 11p is 1.1 times or more and 5 times or less the average particle diameter in the first region 90p.

而且,例如第一基板區域11p中的平均粒徑比第二基板區域11q中的平均粒徑小。在與第一區域90p相接而設置的第一基板區域11p中,藉由與第一區域90p之間的擴散等的相互作用而提高與第一區域90p之間的界面強度較佳。另一方面,在第二基板區域11q中,顯現陶瓷介電質基板11的材料本來的特性較佳。藉由使第一基板區域11p中的平均粒徑比第二基板區域11q中的平均粒徑小,可使第一基板區域11p中的界面強度的擔保與第二基板區域11q中的陶瓷介電質基板11的特性並存。Furthermore, for example, the average particle diameter in the first substrate region 11p is smaller than the average particle diameter in the second substrate region 11q. In the first substrate region 11p provided in contact with the first region 90p, it is better to increase the strength of the interface with the first region 90p by interaction with the first region 90p such as diffusion. On the other hand, in the second substrate region 11q, the original characteristics of the material of the ceramic dielectric substrate 11 are better. By making the average particle diameter in the first substrate region 11p smaller than the average particle diameter in the second substrate region 11q, the interface strength in the first substrate region 11p can be ensured with the ceramic dielectric in the second substrate region 11q. The characteristics of the substrate 11 coexist.

第一區域90p中的平均粒徑也可以比第一基板區域11p中的平均粒徑小。據此,在多孔質部90與陶瓷介電質基板11的界面上,可提高多孔質部90與陶瓷介電質基板的結合強度。而且,因藉由第一區域90p中的平均粒徑小,使得多孔質部90的強度變高,故可抑制製程時的粒子的脫落,可減少微粒。The average particle diameter in the first region 90p may be smaller than the average particle diameter in the first substrate region 11p. Accordingly, at the interface between the porous portion 90 and the ceramic dielectric substrate 11, the bonding strength of the porous portion 90 and the ceramic dielectric substrate can be improved. In addition, since the average particle diameter in the first region 90p is small, the strength of the porous portion 90 is increased, so that the falling of particles during the manufacturing process can be suppressed, and the particles can be reduced.

而且,與前述的一樣,也可以使第一區域90p中的平均粒徑比第二基板區域11q中的平均粒徑小。據此,可提高第一區域90p中的機械強度。In addition, as described above, the average particle diameter in the first region 90p may be smaller than the average particle diameter in the second substrate region 11q. According to this, the mechanical strength in the first region 90p can be improved.

再度參照圖2(a)就靜電吸盤110的構造繼續進行說明。靜電吸盤110如前述更具有多孔質部70(第一多孔質部、第二多孔質部)也可以。多孔質部70不具有在圖3~7中說明的複數個稀疏部分94與複數個緊密部分95。在該例子中,多孔質部70設置於底板,與氣體導入道53對向配置。多孔質部70例如在Z方向上可設置於多孔質部90與氣體導入道53之間。例如多孔質部70被嵌入底板50之陶瓷介電質基板11側。如圖2(a)所示,例如在底板50之陶瓷介電質基板11側配設有鏜孔(counterbore)部53a。鏜孔部53a配設成筒狀。藉由適切地設計鏜孔部53a的內徑,使得多孔質部70被嵌合於鏜孔部53a。此外,如後述,將多孔質部70設置於陶瓷基板11也可以。The description of the structure of the electrostatic chuck 110 will continue with reference to FIG. 2(a) again. The electrostatic chuck 110 may further have the porous part 70 (the first porous part and the second porous part) as described above. The porous part 70 does not have the plurality of sparse portions 94 and the plurality of dense portions 95 described in FIGS. 3 to 7. In this example, the porous part 70 is provided on the bottom plate, and is arranged opposite to the gas introduction passage 53. The porous part 70 may be provided between the porous part 90 and the gas introduction passage 53 in the Z direction, for example. For example, the porous part 70 is embedded in the ceramic dielectric substrate 11 side of the bottom plate 50. As shown in FIG. 2(a), for example, a counterbore portion 53a is provided on the ceramic dielectric substrate 11 side of the bottom plate 50. The bore 53a is arranged in a cylindrical shape. By appropriately designing the inner diameter of the bore 53a, the porous part 70 is fitted into the bore 53a. In addition, as described later, the porous portion 70 may be provided on the ceramic substrate 11.

在該例子中,多孔質部70的頂面70U露出於底板50的頂面50U。多孔質部70的頂面70U與多孔質部90的底面90L對向。在該例子中,多孔質部70的頂面70U與多孔質部90的底面90L之間成為空間SP。可使第一多孔質部為多孔質部90、多孔質部70的任一個。可使第二多孔質部為多孔質部90、多孔質部70的任一個。In this example, the top surface 70U of the porous portion 70 is exposed on the top surface 50U of the bottom plate 50. The top surface 70U of the porous portion 70 faces the bottom surface 90L of the porous portion 90. In this example, a space SP is formed between the top surface 70U of the porous portion 70 and the bottom surface 90L of the porous portion 90. The first porous part may be either the porous part 90 or the porous part 70. The second porous part may be either the porous part 90 or the porous part 70.

多孔質部70具有:具有複數個孔之多孔區域71(第一多孔區域、第二多孔區域的例子),和比多孔區域71還緻密之緻密區域72(第一緻密區域、第二緻密區域的例子)。多孔區域71配設成筒狀(例如圓筒形),被嵌合於鏜孔部53a。雖然多孔質部70的形狀為圓筒形較理想,但不是被限定於圓筒形。多孔質部70使用具有絕緣性的材料。多孔質部70的材料例如為Al2 O3 或Y2 O3 、ZrO2 、MgO、SiC、AlN、Si3 N4 。多孔質部70的材料也可以是SiO2 等的玻璃。多孔質部70的材料也可以是Al2 O3 -TiO2 或Al2 O3 -MgO、Al2 O3 -SiO2 、Al6 O13 Si2 、YAG、ZrSiO4 等。The porous portion 70 has a porous region 71 (examples of the first porous region and the second porous region) having a plurality of pores, and a dense region 72 (first dense region, second dense region) that is denser than the porous region 71 Area example). The porous region 71 is arranged in a cylindrical shape (for example, a cylindrical shape), and is fitted in the bore portion 53a. Although the shape of the porous portion 70 is preferably a cylindrical shape, it is not limited to a cylindrical shape. The porous part 70 uses an insulating material. The material of the porous part 70 is, for example, Al 2 O 3 or Y 2 O 3 , ZrO 2 , MgO, SiC, AlN, or Si 3 N 4 . The material of the porous part 70 may be glass such as SiO 2 . The material of the porous part 70 may be Al 2 O 3 -TiO 2 or Al 2 O 3 -MgO, Al 2 O 3 -SiO 2 , Al 6 O 13 Si 2 , YAG, ZrSiO 4, or the like.

多孔區域71的孔隙率為例如20%以上、60%以下。多孔區域71的密度為例如1.5g/cm3 以上、3.0g/cm3 以下。流過氣體導入道53而來的He等的氣體通過多孔區域71的複數個孔71p,自設置於陶瓷介電質基板11的貫通孔15被送到溝14。The porosity of the porous region 71 is, for example, 20% or more and 60% or less. The density of the porous region 71 is, for example, 1.5 g/cm 3 or more and 3.0 g/cm 3 or less. The gas such as He flowing through the gas introduction passage 53 passes through the plurality of holes 71 p of the porous region 71 and is sent to the groove 14 from the through holes 15 provided in the ceramic dielectric substrate 11.

緻密區域72例如具有由陶瓷絕緣膜構成的部分。陶瓷絕緣膜配設於多孔區域71與氣體導入道53之間。陶瓷絕緣膜比多孔區域71還緻密。陶瓷絕緣膜的孔隙率為例如10%以下。陶瓷絕緣膜的密度為例如3.0g/cm3 以上、4.0g/cm3 以下。陶瓷絕緣膜設置於多孔質部70的側面。The dense region 72 has, for example, a portion made of a ceramic insulating film. The ceramic insulating film is arranged between the porous area 71 and the gas introduction passage 53. The ceramic insulating film is denser than the porous region 71. The porosity of the ceramic insulating film is, for example, 10% or less. The density of the ceramic insulating film is, for example, 3.0 g/cm 3 or more and 4.0 g/cm 3 or less. The ceramic insulating film is provided on the side surface of the porous part 70.

陶瓷絕緣膜的材料例如使用Al2 O3 、Y2 O3 、ZrO2 、MgO等。陶瓷絕緣膜的材料也可以使用Al2 O3 -TiO2 、Al2 O3 -MgO、Al2 O3 -SiO2 、Al6 O13 Si2 、YAG、ZrSiO4 等。As the material of the ceramic insulating film, for example, Al 2 O 3 , Y 2 O 3 , ZrO 2 , MgO, etc. are used. As the material of the ceramic insulating film, Al 2 O 3 -TiO 2 , Al 2 O 3 -MgO, Al 2 O 3 -SiO 2 , Al 6 O 13 Si 2 , YAG, ZrSiO 4 and the like can also be used.

陶瓷絕緣膜例如可藉由熔射、PVD(Physical Vapor Deposition:物理氣相沉積)或CVD(Chemical Vapor Deposition:化學氣相沉積)、溶膠凝膠法(sol-gel method)、氣溶膠沉積法(aerosol deposition method)等形成於多孔質部70的側面。陶瓷絕緣膜的膜厚為例如0.05mm以上、0.5mm以下。The ceramic insulating film can be sprayed, PVD (Physical Vapor Deposition) or CVD (Chemical Vapor Deposition), sol-gel method (sol-gel method), aerosol deposition method ( Aerosol deposition method) and the like are formed on the side surface of the porous part 70. The film thickness of the ceramic insulating film is, for example, 0.05 mm or more and 0.5 mm or less.

陶瓷介電質基板11的孔隙率為例如1%以下。陶瓷介電質基板11的密度為例如4.2g/cm3The porosity of the ceramic dielectric substrate 11 is, for example, 1% or less. The density of the ceramic dielectric substrate 11 is, for example, 4.2 g/cm 3 .

陶瓷介電質基板11及多孔質部70中的孔隙率如前述,藉由掃描式電子顯微鏡測定。密度係根據JIS(Japanese Industrial Standard:日本工業標準) C 2141 5.4.3進行測定。The porosity in the ceramic dielectric substrate 11 and the porous portion 70 is measured by a scanning electron microscope as described above. The density is measured in accordance with JIS (Japanese Industrial Standard) C 2141 5.4.3.

多孔質部70一被嵌合於氣體導入道53的鏜孔部53a,就成為陶瓷絕緣膜與底板50接觸的狀態。也就是說,成為在將He等的氣體導引至溝14的貫通孔15與金屬製的底板50之間中介具有絕緣性高的多孔區域71及緻密區域73的多孔質部70。藉由使用這種多孔質部70,與僅將多孔區域71設置於氣體導入道53的情形比較,可發揮高的絕緣性。Once the porous portion 70 is fitted into the bore portion 53 a of the gas introduction passage 53, the ceramic insulating film is in contact with the bottom plate 50. That is, it becomes the porous part 70 which has the porous region 71 and the dense region 73 with high insulation between the through-hole 15 which guides gas, such as He, to the groove 14 and the bottom plate 50 made of metal. By using such a porous part 70, compared with the case where only the porous region 71 is provided in the gas introduction path 53, it is possible to exhibit high insulation.

而且,設置於多孔質部70的複數個孔71p比設置於多孔質部90的複數個孔96還三維地分散,可使多孔質部90之貫通於Z方向的孔的比例比多孔質部70之貫通於Z方向的孔的比例還多。由於可藉由設置具有三維地分散的複數個孔71p的多孔質部70得到更高的耐受電壓,因此可謀求氣體流動的順暢化,同時可有效地抑制電弧放電的發生。而且,如圖2(a)所示,藉由將貫通於Z方向的孔的比例多的多孔質部90設置於陶瓷介電質基板11,例如即使是在電漿密度高的情形下,也可更有效地抑制電弧放電的發生。Furthermore, the plurality of pores 71p provided in the porous part 70 are more three-dimensionally dispersed than the plural pores 96 provided in the porous part 90, so that the ratio of the pores penetrating the Z direction in the porous part 90 can be higher than that of the porous part 70. The proportion of holes penetrating in the Z direction is still more. Since a higher withstand voltage can be obtained by providing the porous portion 70 having a plurality of pores 71p dispersed three-dimensionally, the gas flow can be smoothed, and the occurrence of arc discharge can be effectively suppressed. Furthermore, as shown in FIG. 2(a), by providing a porous portion 90 with a large proportion of holes penetrating the Z direction on the ceramic dielectric substrate 11, for example, even when the plasma density is high, It can more effectively suppress the occurrence of arc discharge.

可使設於設置於底板50的多孔質部(第二多孔質部,在圖2(a)中為多孔質部70)的複數個孔的平均值,比設於設置於陶瓷介電質基板11的多孔質部(第一多孔質部,在圖2(a)中為多孔質部90)的複數個孔的平均值還大。據此,因孔的直徑大的多孔質部設於氣體導入道53側,故可謀求氣體流動的順暢化。而且,因孔的直徑小的多孔質部設於吸附的對象物側,故可更有效地抑制電弧放電的發生。 而且,在多孔質部70設置於底板50,多孔質部90設置於陶瓷介電質基板11的例子中,可使設置於多孔質部70的複數個孔71p的直徑的平均值比設置於多孔質部90的複數個孔96的直徑的平均值還大。據此,由於設置有孔的直徑大的多孔質部70,因此可謀求氣體流動的順暢化。而且,由於孔的直徑小的多孔質部90配設於吸附的對象物側,因此可更有效地抑制電弧放電的發生。 而且,由於可減小複數個孔的直徑的不均,因此可謀求電弧放電之更有效的抑制。The average value of a plurality of pores provided in the porous part (the second porous part, porous part 70 in FIG. 2(a)) provided on the bottom plate 50 can be compared to the average value provided in the ceramic dielectric The average value of the plurality of pores in the porous part of the substrate 11 (the first porous part, which is the porous part 90 in FIG. 2(a)) is still large. According to this, since the porous part with a large hole diameter is provided on the side of the gas introduction passage 53, it is possible to smooth the flow of gas. Furthermore, since the porous part with a small hole diameter is provided on the side of the object to be adsorbed, the occurrence of arc discharge can be suppressed more effectively. Furthermore, in an example in which the porous portion 70 is provided on the bottom plate 50 and the porous portion 90 is provided on the ceramic dielectric substrate 11, the average diameter of the plurality of holes 71p provided in the porous portion 70 can be made to be higher than The average value of the diameters of the plurality of holes 96 of the mass portion 90 is still large. According to this, since the porous portion 70 with a large hole diameter is provided, it is possible to smooth the flow of gas. Furthermore, since the porous portion 90 with a small hole diameter is arranged on the side of the object to be adsorbed, the occurrence of arc discharge can be suppressed more effectively. Furthermore, since the unevenness in the diameter of the plurality of holes can be reduced, more effective suppression of arc discharge can be achieved.

圖10是舉例說明與實施形態有關的靜電吸盤的多孔質部70之示意剖面圖。 圖10是多孔區域71的剖面的一部分的放大視圖。 設置於多孔區域71的複數個孔71p在多孔區域71的內部中,三維地分散在X方向、Y方向及Z方向。換言之,多孔區域71為孔71p擴展於X方向、Y方向及Z方向之三維的網狀構造。在多孔質部70中,複數個孔71p在多孔區域71例如隨機或均勻地分散。Fig. 10 is a schematic cross-sectional view illustrating the porous part 70 of the electrostatic chuck according to the embodiment. FIG. 10 is an enlarged view of a part of the cross section of the porous region 71. The plurality of holes 71p provided in the porous region 71 are three-dimensionally dispersed in the X direction, the Y direction, and the Z direction in the inside of the porous region 71. In other words, the porous region 71 is a three-dimensional network structure in which the holes 71p expand in the X direction, the Y direction, and the Z direction. In the porous portion 70, a plurality of pores 71p are randomly or uniformly dispersed in the porous region 71, for example.

因複數個孔71p三維地分散,故複數個孔71p的一部分也露出於多孔區域71的表面。因此,在多孔區域71的表面形成有細小的凹凸。也就是說,可使多孔區域71的表面粗糙。藉由多孔區域71的表面粗糙度(surface roughness),可在多孔區域71的表面容易形成例如陶瓷絕緣膜(緻密區域72)。例如陶瓷絕緣膜(緻密區域72)與多孔區域71的接觸提高。而且,可抑制陶瓷絕緣膜(緻密區域72)的剝離。Since the plurality of holes 71p are three-dimensionally dispersed, part of the plurality of holes 71p is also exposed on the surface of the porous region 71. Therefore, fine irregularities are formed on the surface of the porous region 71. That is, the surface of the porous region 71 can be roughened. Due to the surface roughness of the porous area 71, a ceramic insulating film (dense area 72) can be easily formed on the surface of the porous area 71, for example. For example, the contact between the ceramic insulating film (the dense region 72) and the porous region 71 is improved. Furthermore, peeling of the ceramic insulating film (dense region 72) can be suppressed.

設置於多孔區域71的複數個孔71p的直徑的平均值比例如設置於多孔區域91的複數個孔96的直徑的平均值大。孔71p的直徑為例如10μm以上、50μm以下。藉由孔96的直徑小的多孔區域91,可控制(限制)流動於貫通孔15的氣體的流量。據此,可抑制起因於多孔區域71的氣體流量的不均。孔71p的直徑及孔96的直徑的測定如前述,可藉由掃描式電子顯微鏡進行。The average value of the diameters of the plurality of holes 71p provided in the porous region 71 is larger than the average value of the diameters of the plurality of holes 96 provided in the porous region 91, for example. The diameter of the hole 71p is, for example, 10 μm or more and 50 μm or less. With the porous region 91 having the small diameter of the hole 96, the flow rate of the gas flowing through the through hole 15 can be controlled (restricted). According to this, it is possible to suppress the unevenness of the gas flow rate caused by the porous region 71. The measurement of the diameter of the hole 71p and the diameter of the hole 96 can be performed by a scanning electron microscope as described above.

圖11是舉例說明與其他的實施形態有關的多孔質部90之示意剖面圖。 圖11係與圖2(a)一樣舉例說明多孔質部90的周邊。 在該例子中,多孔質部90設置於陶瓷介電質基板11。多孔質部70設置於底板50。也就是說,第一多孔質部使用多孔質部90。第二多孔質部使用多孔質部70。此外,多孔質部90也可以設置於陶瓷介電質基板11及底板50的雙方。Fig. 11 is a schematic cross-sectional view illustrating a porous portion 90 related to another embodiment. Fig. 11 illustrates the periphery of the porous portion 90 as in Fig. 2(a). In this example, the porous part 90 is provided on the ceramic dielectric substrate 11. The porous part 70 is provided on the bottom plate 50. That is, the porous part 90 is used as the first porous part. The porous part 70 is used as the second porous part. In addition, the porous portion 90 may be provided on both the ceramic dielectric substrate 11 and the bottom plate 50.

在該例子中,在多孔質部90與陶瓷介電質基板11之間設置有接著構件61(接著劑)。多孔質部90藉由接著構件61接著於陶瓷介電質基板11。例如接著構件61設置於多孔質部90的側面(緻密區域93的側面93s)與貫通孔15的內壁15w之間。多孔質部90與陶瓷介電質基板11不接觸也可以。In this example, an adhesive member 61 (adhesive agent) is provided between the porous portion 90 and the ceramic dielectric substrate 11. The porous part 90 is adhered to the ceramic dielectric substrate 11 by the adhesive member 61. For example, the adhesive member 61 is provided between the side surface of the porous portion 90 (the side surface 93 s of the dense region 93) and the inner wall 15 w of the through hole 15. The porous portion 90 and the ceramic dielectric substrate 11 may not be in contact with each other.

接著構件61例如使用矽接著劑。接著構件61例如為具有彈性的彈性構件。接著構件61的彈性模數(elastic modulus)例如比多孔質部90的緻密區域93的彈性模數低,比陶瓷介電質基板11的彈性模數低。The bonding member 61 uses, for example, a silicon adhesive. The next member 61 is, for example, an elastic member having elasticity. The elastic modulus (elastic modulus) of the member 61 is lower than the elastic modulus of the dense region 93 of the porous portion 90, and lower than the elastic modulus of the ceramic dielectric substrate 11, for example.

在藉由接著構件61接著多孔質部90與陶瓷介電質基板11的構造中,可將接著構件61作為對多孔質部90的熱收縮與陶瓷介電質基板11的熱收縮之差的緩衝材。In the structure in which the porous portion 90 and the ceramic dielectric substrate 11 are bonded by the bonding member 61, the bonding member 61 can be used as a buffer for the difference between the thermal contraction of the porous portion 90 and the thermal contraction of the ceramic dielectric substrate 11. material.

圖12(a)、(b)是舉例說明與其他的實施形態有關的多孔質部90之示意剖面圖。 在前述的實施形態(參照圖2)中,多孔質部90設置於陶瓷介電質基板11,多孔質部70設置於底板50。 但是,在使用多孔質部90的情形下,也可以省略設置於底板50的多孔質部、設置於陶瓷介電質基板11的多孔質部的任一個。 例如在圖12(a)所示的例子中,將多孔質部90設置於陶瓷介電質基板11,在底板50設置氣體導入道53。據此,可降低供給到多孔質部90的He等的氣體的流道阻力。Figs. 12(a) and (b) are schematic cross-sectional views illustrating examples of porous portions 90 related to other embodiments. In the aforementioned embodiment (see FIG. 2 ), the porous portion 90 is provided on the ceramic dielectric substrate 11, and the porous portion 70 is provided on the bottom plate 50. However, when the porous portion 90 is used, either the porous portion provided on the bottom plate 50 or the porous portion provided on the ceramic dielectric substrate 11 may be omitted. For example, in the example shown in FIG. 12(a), the porous portion 90 is provided on the ceramic dielectric substrate 11, and the gas introduction path 53 is provided on the bottom plate 50. Accordingly, the flow path resistance of the gas such as He supplied to the porous portion 90 can be reduced.

而且,在圖12(b)所示的例子中,在陶瓷介電質基板11設置孔部15b,將多孔質部90設置於底板50。據此,可降低供給到多孔質部90的He等的氣體的流道阻力。Furthermore, in the example shown in FIG. 12( b ), the ceramic dielectric substrate 11 is provided with a hole 15 b, and the porous section 90 is provided on the bottom plate 50. Accordingly, the flow path resistance of the gas such as He supplied to the porous portion 90 can be reduced.

而且,如圖12(a)所示,氣體導入道53的陶瓷介電質基板11側的開口的邊緣53b的至少一部分能以曲線構成。例如可對氣體導入道53的開口的邊緣53b施以所謂的[R面倒角]。此情形,可使氣體導入道53的開口的邊緣53b以半徑0.2毫米(mm)左右的曲線構成。 如前述,底板50由鋁等的金屬形成。因此,若氣體導入道53的開口的邊緣尖銳,則電場集中容易發生,有電弧放電容易發生之虞。Furthermore, as shown in FIG. 12(a), at least a part of the edge 53b of the opening on the ceramic dielectric substrate 11 side of the gas introduction path 53 can be formed in a curved line. For example, so-called [R face chamfering] may be applied to the edge 53b of the opening of the gas introduction passage 53. In this case, the edge 53b of the opening of the gas introduction passage 53 may be formed with a curve with a radius of about 0.2 millimeters (mm). As described above, the bottom plate 50 is formed of metal such as aluminum. Therefore, if the edge of the opening of the gas introduction channel 53 is sharp, electric field concentration is likely to occur, and arc discharge may easily occur.

在本實施的形態中,因氣體導入道53的開口的邊緣53b的至少一部分以曲線構成,故可抑制電場集中,進而可謀求電弧放電的降低。In the embodiment of the present embodiment, since at least a part of the edge 53b of the opening of the gas introduction passage 53 is formed in a curved line, the concentration of the electric field can be suppressed, and the arc discharge can be reduced.

圖13(a)~(d)是舉例說明與其他的實施形態有關的多孔質部90a、70a之示意剖面圖。 圖14(a)~(c)是舉例說明與其他的實施形態有關的多孔質部90a、90b之示意剖面圖。 圖13(a)為在陶瓷介電質基板11設置多孔質部90的緻密區域93變更的多孔質部90a,在底板50設置多孔質部70的緻密區域72變更的多孔質部70a的情形的例子。圖14(a)為在陶瓷介電質基板11及底板50分別設置多孔質部90的緻密區域93變更的多孔質部90a及多孔質部70的緻密區域72變更的多孔質部70b的情形的例子。 如圖13(a)、圖13(b)及圖14(a)所示,在設置於陶瓷介電質基板11的多孔質部90a中,多孔區域91更具有緻密部92a。也就是說,多孔質部90a是在前述的多孔質部90更加入緻密部92a的部分。Figs. 13(a) to (d) are schematic cross-sectional views illustrating examples of porous portions 90a and 70a related to other embodiments. 14(a) to (c) are schematic cross-sectional views illustrating examples of porous portions 90a and 90b related to other embodiments. Fig. 13(a) is a case where a porous portion 90a with a modified dense region 93 of the porous portion 90 is provided on the ceramic dielectric substrate 11, and a porous portion 70a with a modified dense region 72 of the porous portion 70 is provided on the bottom plate 50 example. Fig. 14(a) is a case where a porous portion 90a with a modified dense region 93 of the porous portion 90 and a porous portion 70b with a modified dense region 72 of the porous portion 70 are provided on the ceramic dielectric substrate 11 and the bottom plate 50, respectively example. As shown in FIG. 13(a), FIG. 13(b), and FIG. 14(a), in the porous portion 90a provided on the ceramic dielectric substrate 11, the porous region 91 further has a dense portion 92a. That is, the porous part 90a is a part where the dense part 92a is added to the aforementioned porous part 90.

如圖13(a)及圖13(b)所示,緻密部92a能呈板狀(例如圓板狀)而構成。如圖14(a)所示,緻密部92a也能呈柱狀(例如圓柱狀)而構成。可使緻密部92a的材料例如與前述的緻密區域93的材料一樣。緻密部92a比多孔區域91還緻密。緻密部92a與緻密區域93的緻密度為同程度也可以。在投影於對Z方向垂直的平面(XY平面)時,緻密部92a與孔部15b重疊。多孔區域91與孔部15b不重疊而構成更佳。依照這種構成,產生的電流迂回流動於緻密部92a。因此,因可加長電流流動的距離(導電路徑),故電子難以被加速,進而可抑制電弧放電的發生。As shown in FIGS. 13(a) and 13(b), the dense portion 92a can be formed in a plate shape (for example, a disc shape). As shown in FIG. 14(a), the dense portion 92a can also be formed in a columnar shape (for example, a columnar shape). The material of the dense portion 92a may be the same as the material of the aforementioned dense region 93, for example. The dense portion 92 a is denser than the porous region 91. The density of the dense portion 92a and the dense region 93 may be the same degree. When projected on a plane (XY plane) perpendicular to the Z direction, the dense portion 92a overlaps the hole portion 15b. The porous region 91 and the hole 15b do not overlap and are more preferably configured. According to this configuration, the generated current flows in the dense portion 92a in a detour. Therefore, since the distance (conduction path) through which the current flows can be lengthened, electrons are difficult to be accelerated, and the occurrence of arc discharge can be suppressed.

而且,在投影於對Z方向垂直的平面(XY平面)時,緻密部92a的尺寸與孔部15b的尺寸相同,或者緻密部92a的尺寸大於孔部15b的尺寸較佳。據此,可將流動於孔部15b的內部的電流導引到緻密部92a。因此,可有效地加長電流流動的距離(導電路程)。Moreover, when projecting on a plane (XY plane) perpendicular to the Z direction, the size of the dense portion 92a is the same as the size of the hole 15b, or the size of the dense portion 92a is preferably larger than the size of the hole 15b. According to this, the current flowing inside the hole 15b can be guided to the dense portion 92a. Therefore, it is possible to effectively lengthen the distance through which the current flows (the conductive path).

在該例子中,在投影於對Z方向垂直的平面(XY平面)時,在緻密部92a的周圍設置有多孔區域91。因在與孔部15b對向的位置配置緻密部92a提高對電弧放電的抗性,同時以其周圍當作多孔區域91,故可確保充分的氣流。也就是說,可使電弧放電的降低與氣體流動的順暢化並存。In this example, when projecting on a plane (XY plane) perpendicular to the Z direction, a porous region 91 is provided around the dense portion 92a. Since the dense portion 92a is arranged at a position opposed to the hole portion 15b to improve resistance to arc discharge, and at the same time, the surrounding area is regarded as the porous area 91, so that sufficient air flow can be ensured. In other words, the reduction of arc discharge and the smoothing of the gas flow can coexist.

如圖13(a)所示,既可以使緻密部92a之沿著Z方向的長度小於多孔質部90a之沿著Z方向的長度,如圖14(a)所示,也可以與多孔質部90a之沿著Z方向的長度大致相同。若加長緻密部92a之沿著Z方向的長度,則可更有效地抑制電弧放電的發生。若使緻密部92a之沿著Z方向的長度小於多孔質部90a之沿著Z方向的長度,則可謀求氣體流動的順暢化。As shown in Fig. 13(a), the length of the dense part 92a along the Z direction may be smaller than the length of the porous part 90a along the Z direction. As shown in Fig. 14(a), it may be combined with the porous part The length of 90a along the Z direction is approximately the same. If the length of the dense portion 92a along the Z direction is increased, the occurrence of arc discharge can be suppressed more effectively. If the length of the dense portion 92a along the Z direction is smaller than the length of the porous portion 90a along the Z direction, the flow of gas can be smoothed.

緻密部92a由實質上不具有孔的緻密體構成也可以,且若比多孔區域91還緻密,則也可以具有複數個孔而構成。在緻密部92a具有複數個孔的情形下,使該孔的直徑比多孔區域91所具有的孔的直徑還小較佳。可使緻密部92a的孔隙率(百分比:%)比多孔區域91的孔隙率(%)低。因此,可使緻密部92a的密度(克/立方公分:g/cm3 )比多孔區域91的密度(g/cm3 )高。可使緻密部92a的孔隙率例如與前述的緻密區域93的孔隙率一樣。The dense portion 92a may be composed of a dense body having substantially no pores, and if it is denser than the porous region 91, it may be composed of a plurality of pores. In the case where the dense portion 92a has a plurality of pores, it is better to make the diameter of the pores smaller than the diameter of the pores of the porous region 91. The porosity (percentage: %) of the dense portion 92a can be made lower than the porosity (%) of the porous region 91. Therefore, the density (g/cm³: g/cm 3 ) of the dense portion 92a can be made higher than the density (g/cm 3 ) of the porous region 91. The porosity of the dense portion 92a can be made the same as the porosity of the aforementioned dense region 93, for example.

此處,電弧放電時常因電流自陶瓷介電質基板11側朝向底板50側流動於孔部15b的內部而發生。因此,若具有低的孔隙率的緻密部92a配設於孔部15b的近旁,則如圖13(a)及圖14(a)所示,電流200迂回流動於緻密部92a。因此,因可加長電流200流動的距離(導電路徑),故電子難以被加速,進而可抑制電弧放電的發生。Here, arc discharge often occurs when current flows inside the hole 15b from the ceramic dielectric substrate 11 side toward the bottom plate 50 side. Therefore, if the dense portion 92a having a low porosity is arranged near the hole 15b, as shown in Figs. 13(a) and 14(a), the current 200 bypasses the dense portion 92a. Therefore, since the distance (conduction path) through which the current 200 flows can be lengthened, electrons are difficult to be accelerated, and the occurrence of arc discharge can be suppressed.

而且,如圖13(a)所示,也能使用例如在設置於底板50的多孔質部70中多孔區域71更具備緻密部92b的多孔質部70a。 而且,如圖14(a)所示,也能將多孔質部90a設置於陶瓷介電質基板11,將多孔質部70b設置於底板50。多孔質部70b係多孔區域71更具有緻密部92b。也就是說,多孔質部70b是在前述的多孔質部70更加入緻密部92b的部分。 也就是說,也能在設置於底板50的多孔質部70或多孔質部90更加入緻密部92b。In addition, as shown in FIG. 13(a), for example, a porous portion 70a having a dense portion 92b in the porous region 71 of the porous portion 70 provided on the bottom plate 50 can be used. Furthermore, as shown in FIG. 14( a ), the porous portion 90 a may be provided on the ceramic dielectric substrate 11 and the porous portion 70 b may be provided on the bottom plate 50. The porous portion 70b is the porous region 71 and further has a dense portion 92b. That is, the porous part 70b is a part where the dense part 92b is further added to the aforementioned porous part 70. That is, the dense part 92b can also be added to the porous part 70 or the porous part 90 provided in the bottom plate 50.

緻密部92b可設置至少一個。如圖13(c)及圖14(b)所示,也能設置複數個呈板狀(例如圓板狀)或柱狀(例如圓柱狀)的緻密部92b。如圖13(d)及圖14(c)所示,也能設置呈環狀(例如圓環狀)或筒狀(例如圖筒狀)的緻密部92b。可使緻密部92b的材料、密度、孔隙率等與緻密部92a一樣。At least one dense portion 92b may be provided. As shown in FIG. 13(c) and FIG. 14(b), a plurality of dense portions 92b having a plate shape (for example, a disc shape) or a column shape (for example, a column shape) can be provided. As shown in FIG. 13(d) and FIG. 14(c), a dense portion 92b having a ring shape (for example, an annular shape) or a cylindrical shape (for example, a cylindrical shape) can be provided. The material, density, porosity, etc. of the dense part 92b can be made the same as the dense part 92a.

在投影於對Z方向垂直的平面(XY平面)時,使設置於底板50的多孔質部所具有的緻密部(例如緻密部92b)的至少一部分與設置於陶瓷介電質基板11的多孔質部所具有的緻密部(例如緻密部92a)重疊較佳。依照這種構成,當例如在多孔質部90a(陶瓷介電質基板11側多孔質部)中迂回流動於緻密部92a的電流流動於設置有緻密部92b的多孔質部70、90b(底板50側多孔質部)時,不會流動於設置於底板50側的多孔質部的多孔區域(例如多孔區域71、91),而是更進一步迂回流動於緻密部92b。因此,因可更加長電流流動的距離(導電路徑),故電子更難以被加速,進而可有效地抑制電弧放電的發生。When projecting on a plane (XY plane) perpendicular to the Z direction, at least a part of the dense part (for example, dense part 92b) of the porous part provided on the bottom plate 50 and the porous part provided on the ceramic dielectric substrate 11 It is preferable that the dense part (for example, the dense part 92a) which the part has overlapped. According to this configuration, for example, in the porous portion 90a (porous portion on the ceramic dielectric substrate 11 side), the current flowing through the dense portion 92a flows through the porous portions 70, 90b (bottom plate 50) provided with the dense portion 92b. In the case of the side porous part), it does not flow in the porous region (for example, the porous regions 71 and 91) of the porous part provided on the bottom plate 50 side, but flows in a detour to the dense part 92b. Therefore, since the distance (conduction path) through which the current flows can be longer, electrons are more difficult to be accelerated, and the occurrence of arc discharge can be effectively suppressed.

圖15(a)、(b)是舉例說明與其他的實施形態有關的多孔質部之示意剖面圖。 如圖15(a)、(b)所示,在投影於對Z方向垂直的平面(XY平面)時,可使緻密部92a與緻密部92b重疊。而且,在投影於對Z方向垂直的平面(XY平面)時,也可以使緻密部92a與緻密部92b接觸。此外,在投影於對Z方向垂直的平面(XY平面)時,若緻密部92a與緻密部92b之間的間隙為些微,則可抑制電流流動於緻密部92a與緻密部92b之間。因此,若是可抑制電流流動於緻密部92a與緻密部92b之間的程度,則也能在緻密部92a與緻密部92b之間設置間隙。 據此,可抑制流動於多孔質部90a的電流不經由緻密部92b而流動於多孔質部70a。因此,可有效地加長電流流動的距離(導電路徑)。15(a) and (b) are schematic cross-sectional views illustrating examples of porous parts related to other embodiments. As shown in FIGS. 15(a) and (b), when projecting on a plane (XY plane) perpendicular to the Z direction, the dense portion 92a and the dense portion 92b can be overlapped. Moreover, when projecting on a plane (XY plane) perpendicular to the Z direction, the dense portion 92a and the dense portion 92b may be brought into contact. In addition, when projecting on a plane (XY plane) perpendicular to the Z direction, if the gap between the dense portion 92a and the dense portion 92b is small, current can be suppressed from flowing between the dense portion 92a and the dense portion 92b. Therefore, if the current can be suppressed from flowing between the dense portion 92a and the dense portion 92b, a gap can also be provided between the dense portion 92a and the dense portion 92b. Accordingly, it is possible to suppress the current flowing in the porous portion 90a from flowing in the porous portion 70a without passing through the dense portion 92b. Therefore, the distance (conducting path) through which the current flows can be effectively lengthened.

而且,如圖15(a)、(b)所示,在投影於對Z方向垂直的平面(XY平面)時,使緻密部92b與緻密區域93重疊較佳。而且,在投影於對Z方向垂直的平面(XY平面)時,也可以使緻密部92b與緻密區域93接觸。據此,因可更加長電流流動的距離(導電路徑),故電子更難以被加速,進而可有效地抑制電弧放電的發生。Furthermore, as shown in FIGS. 15(a) and (b), when projecting on a plane (XY plane) perpendicular to the Z direction, it is preferable that the dense portion 92b overlaps the dense region 93. In addition, when projecting on a plane (XY plane) perpendicular to the Z direction, the dense portion 92b may be brought into contact with the dense region 93. According to this, since the distance (conduction path) through which the current flows can be longer, electrons are more difficult to be accelerated, and the occurrence of arc discharge can be effectively suppressed.

圖16是舉例說明與其他的實施形態有關的靜電吸盤之示意剖面圖。 圖17(a)、(b)相當於圖16所示的區域C之放大視圖。 如圖16及圖17(a)、(b)所示,靜電吸盤110a具備陶瓷介電質基板11c與底板50。也就是說,在陶瓷介電質基板11c中未設置有多孔質部(多孔質部70或多孔質部90)。 在陶瓷介電質基板11c直接設置有複數個孔16。複數個孔16可藉由例如照射雷射或超音波加工等形成於陶瓷介電質基板11c。在該例子中,複數個孔16的一端位於溝14的面14a。複數個孔16的另一端位於陶瓷介電質基板11c的第二主表面11b。也就是說,複數個孔16貫通陶瓷介電質基板11c於Z方向。Fig. 16 is a schematic cross-sectional view illustrating an electrostatic chuck related to another embodiment. Figs. 17(a) and (b) correspond to enlarged views of the area C shown in Fig. 16. As shown in FIGS. 16 and 17(a) and (b), the electrostatic chuck 110a includes a ceramic dielectric substrate 11c and a bottom plate 50. That is, no porous part (porous part 70 or porous part 90) is provided in the ceramic dielectric substrate 11c. A plurality of holes 16 are directly provided in the ceramic dielectric substrate 11c. The plurality of holes 16 may be formed in the ceramic dielectric substrate 11c by, for example, laser irradiation or ultrasonic processing. In this example, one end of the plurality of holes 16 is located on the surface 14 a of the groove 14. The other ends of the plurality of holes 16 are located on the second main surface 11b of the ceramic dielectric substrate 11c. That is, the plurality of holes 16 penetrate the ceramic dielectric substrate 11c in the Z direction.

如圖17(a)、(b)所示,在底板50可設置多孔質部(例如多孔質部70a)。此外,也可以在底板50設置有多孔質部90b。而且,如圖12(a)所舉例說明,也可以在底板50不設置多孔質部70或多孔質部90,而設置氣體導入道53。As shown in FIGS. 17(a) and (b), a porous part (for example, a porous part 70a) may be provided on the bottom plate 50. In addition, the bottom plate 50 may be provided with a porous portion 90b. Furthermore, as illustrated in FIG. 12( a ), the bottom plate 50 may not be provided with the porous portion 70 or the porous portion 90 and the gas introduction path 53 may be provided.

而且,如圖17(a)、(b)所示,設置於底板50的多孔質部70的頂面70U(或多孔質部90的頂面90U)與陶瓷介電質基板11c的第二主表面11b不接觸也可以。而且,與前述的內容一樣,也能以曲線構成氣體導入道53的陶瓷介電質基板11c側的開口的邊緣53b的至少一部分。17(a) and (b), the top surface 70U of the porous portion 70 (or the top surface 90U of the porous portion 90) of the bottom plate 50 and the second main body of the ceramic dielectric substrate 11c are provided The surface 11b does not need to be in contact. Furthermore, as with the foregoing, at least a part of the edge 53b of the opening on the ceramic dielectric substrate 11c side of the gas introduction channel 53 can be formed in a curved line.

若將複數個孔16設置於陶瓷介電質基板11c,則可確保供給到載置於靜電吸盤110a的對象物W的背面與包含溝14的第一主表面11a之間的氣體的流量,同時可提高對電弧放電的抗性。If a plurality of holes 16 are provided in the ceramic dielectric substrate 11c, the flow rate of the gas supplied between the back surface of the object W placed on the electrostatic chuck 110a and the first main surface 11a including the groove 14 can be ensured, and at the same time Can improve the resistance to arc discharge.

可使緻密部92b之沿著Z方向的長度小於多孔質部70a、90b之沿著Z方向的長度。而且,也可以使緻密部92b之沿著Z方向的長度與多孔質部70a、90b之沿著Z方向的長度大致相同。若縮短緻密部92b之沿著Z方向的長度,則可謀求氣流的順暢化。若加長緻密部92b之沿著Z方向的長度,則可更有效地抑制電弧放電的發生。The length along the Z direction of the dense portion 92b can be made smaller than the length along the Z direction of the porous portions 70a and 90b. In addition, the length of the dense portion 92b along the Z direction may be approximately the same as the length of the porous portions 70a and 90b along the Z direction. If the length of the dense portion 92b along the Z direction is shortened, the air flow can be smoothed. If the length of the dense portion 92b along the Z direction is increased, the occurrence of arc discharge can be more effectively suppressed.

在投影於對Z方向垂直的平面(XY平面)時,可使複數個孔16的至少1個與緻密部92b重疊。複數個緻密部92b的材料、密度、孔隙率等例如如前述。 如圖17(a)所示,具有複數個緻密部92b的多孔質部70a設置於底板50也可以。如圖17(b)所示,具有複數個緻密部92b的多孔質部90b設置於底板50也可以。When projecting on a plane (XY plane) perpendicular to the Z direction, at least one of the plurality of holes 16 can be overlapped with the dense portion 92b. The material, density, porosity, etc. of the plurality of dense portions 92b are as described above, for example. As shown in FIG. 17(a), the porous portion 70a having a plurality of dense portions 92b may be provided on the bottom plate 50. As shown in FIG. 17(b), the porous portion 90b having a plurality of dense portions 92b may be provided on the bottom plate 50.

圖18是舉例說明與其他的實施形態有關的複數個孔16h之示意剖面圖。 複數個孔16h可藉由照射雷射或超音波加工等形成於陶瓷介電質基板11。 如圖18所示,設置於陶瓷介電質基板11的複數個孔16h的至少一個可具有:開口於槽部14的第一部分16h1,與開口於第二主表面11b的第二部分16h2。在X方向或Y方向上,可使第一部分16h1的尺寸小於第二部分16h2的尺寸。在X方向或Y方向上,可使複數個孔16h的至少一個其溝14的面14a側的開口尺寸D4小於底板50側的開口尺寸D3。此外,雖然在圖18中舉例說明了具有階梯構造的孔16h,但是也能以具有推拔(taper)構造的孔16h。例如開口尺寸D4也能以直徑為0.01毫米(mm)~0.1毫米(mm)。例如開口尺寸D3也能以直徑為0.15毫米(mm)~0.2毫米(mm)左右。若開口尺寸D4小於開口尺寸D3,則可有效地抑制電弧放電的發生。 而且,孔16h的縱橫比(aspect ratio)也能以例如3~60。在縱橫比的算出中,[縱]例如以圖18中的孔16h的Z方向的長度,[橫]以孔16h的頂面(面14a)上的孔16h的X方向長度與孔16h的底面(第二主表面11b)上的孔16h的X方向的長度的平均長度。此外,孔16h的X方向的長度的測定可使用雷射顯微鏡、工廠顯微鏡等的光學顯微鏡、數位顯微鏡(digital microscope)等。 而且,可使開口尺寸D4小於圖4所舉例說明的稀疏部分94a的長度L1(稀疏部分94b的長度L4、稀疏部分94c的長度L5)。Fig. 18 is a schematic cross-sectional view illustrating a plurality of holes 16h related to another embodiment. The plurality of holes 16h can be formed in the ceramic dielectric substrate 11 by laser irradiation, ultrasonic processing, or the like. As shown in FIG. 18, at least one of the plurality of holes 16h provided in the ceramic dielectric substrate 11 may have a first portion 16h1 opening in the groove 14 and a second portion 16h2 opening in the second main surface 11b. In the X direction or the Y direction, the size of the first portion 16h1 can be made smaller than the size of the second portion 16h2. In the X direction or the Y direction, the opening size D4 of at least one of the plurality of holes 16h on the surface 14a side of the groove 14 can be made smaller than the opening size D3 on the bottom plate 50 side. In addition, although the hole 16h having a stepped structure is illustrated in FIG. 18, the hole 16h having a taper structure may also be used. For example, the opening size D4 can also be 0.01 millimeters (mm) to 0.1 millimeters (mm) in diameter. For example, the opening size D3 can also be about 0.15 millimeters (mm) to 0.2 millimeters (mm) in diameter. If the opening size D4 is smaller than the opening size D3, the occurrence of arc discharge can be effectively suppressed. Moreover, the aspect ratio of the hole 16h can also be 3-60, for example. In the calculation of the aspect ratio, [vertical] is, for example, the length of the hole 16h in the Z direction in FIG. 18, and [horizontal] is the X-direction length of the hole 16h on the top surface (face 14a) of the hole 16h and the bottom surface of the hole 16h (2nd main surface 11b) The average length of the length of the X direction of the hole 16h. In addition, the length of the hole 16h in the X direction can be measured using an optical microscope such as a laser microscope, a factory microscope, or a digital microscope. Furthermore, the opening size D4 can be made smaller than the length L1 of the sparse part 94a illustrated in FIG. 4 (the length L4 of the sparse part 94b, the length L5 of the sparse part 94c).

圖19(a)、(b)是舉例說明孔16的開口部分的形狀之示意剖面圖。 圖19(b)相當於圖19(a)所示的區域D的放大視圖。在圖19(a)中,在孔16中無圖18的開口尺寸D3的部分。也就是說,孔16的開口尺寸對應於圖18中的開口尺寸D4。 如圖19(a)、(b)所示,可使孔16的第一主表面11a側(溝14的面14a側)的開口的邊緣16i比孔16的第二主表面11b側的開口的邊緣16j還平緩地傾斜。在該例子中,複數個孔16的至少一個在以由孔16的溝14側的開口的邊緣16i與溝14的第二主表面11b側的面14a所成的角度為α,以由孔16的第二主表面11b側的開口的邊緣16j與第二主表面11b所成的角度為β的情形下,成為[α<β]。據此,可抑制電場集中,進而可謀求電弧放電的降低。此外,在該例子中,邊緣16i以直線構成。但是,邊緣16i既能以曲線構成,也能以直線與曲線構成。在邊緣16i與邊緣16j以曲線構成的情形下,可使邊緣16i的曲率半徑大於邊緣16j的曲率半徑。在邊緣16i與邊緣16j以直線與曲線構成的情形下,只要直線部分彼此的關係及曲線部分彼此的關係的至少任一個滿足前述的關係即可。19(a) and (b) are schematic cross-sectional views illustrating the shape of the opening portion of the hole 16. FIG. 19(b) corresponds to an enlarged view of the area D shown in FIG. 19(a). In FIG. 19(a), there is no part of the opening size D3 of FIG. 18 in the hole 16. That is, the opening size of the hole 16 corresponds to the opening size D4 in FIG. 18. As shown in Figure 19 (a) and (b), the edge 16i of the opening on the first main surface 11a side of the hole 16 (the surface 14a side of the groove 14) can be made larger than the opening on the second main surface 11b side of the hole 16 The edge 16j also slopes gently. In this example, at least one of the plurality of holes 16 has an angle formed by the edge 16i of the opening on the side of the groove 14 of the hole 16 and the surface 14a on the side of the second main surface 11b of the groove 14 as α. When the angle between the edge 16j of the opening on the second main surface 11b side and the second main surface 11b is β, it becomes [α<β]. According to this, the concentration of the electric field can be suppressed, and the arc discharge can be reduced. In addition, in this example, the edge 16i is formed with a straight line. However, the edge 16i can be composed of a curve, or a straight line and a curve. In the case where the edge 16i and the edge 16j are formed by curves, the radius of curvature of the edge 16i can be made larger than the radius of curvature of the edge 16j. In the case where the edge 16i and the edge 16j are composed of straight lines and curved lines, at least any one of the relationship between the linear portions and the relationship between the curved portions may satisfy the aforementioned relationship.

若邊緣16i比邊緣16j還平緩地傾斜,則可抑制傾斜等的發生及電場集中。因此,可更有效地抑制電弧放電的發生。 此外,作為一例,雖然舉例說明了孔16的開口部分的形狀,但是具有階梯構造或推拔構造的孔16h的情形也一樣。If the edge 16i is more gently inclined than the edge 16j, the occurrence of inclination and the like and electric field concentration can be suppressed. Therefore, the occurrence of arc discharge can be suppressed more effectively. In addition, as an example, although the shape of the opening portion of the hole 16 has been exemplified, the same is true for the hole 16h having a stepped structure or a push-out structure.

圖20是舉例說明與其他的實施形態有關的靜電吸盤之示意剖面圖。 圖20相當於圖16所示的區域C的放大視圖。 在圖17(a)所舉例說明的複數個孔16的各個延伸於大致Z方向。相對於此,在圖20所舉例說明的複數個孔16的至少一個也能對Z方向傾斜而構成。若複數個孔16的至少一個延伸於對Z方向傾斜的方向,則可考慮為在電流流動於孔16的內部時,電子難以被加速。因此,可有效地抑制電弧放電的發生。依照本發明人們所得到的知識,若使對Z方向傾斜的角度θ成為5°以上、30°以下,較佳為成為5°以上、15°以下,則可不減小孔16的直徑而抑制電弧放電的發生。Fig. 20 is a schematic cross-sectional view illustrating an electrostatic chuck related to another embodiment. FIG. 20 is equivalent to an enlarged view of the area C shown in FIG. 16. Each of the plurality of holes 16 illustrated in FIG. 17(a) extends substantially in the Z direction. In contrast, at least one of the plurality of holes 16 illustrated in FIG. 20 can also be configured to be inclined to the Z direction. If at least one of the plurality of holes 16 extends in a direction inclined to the Z direction, it can be considered that electrons are difficult to be accelerated when current flows inside the hole 16. Therefore, the occurrence of arc discharge can be effectively suppressed. According to the knowledge obtained by the inventors, if the angle θ inclined to the Z direction is 5° or more and 30° or less, preferably 5° or more and 15° or less, the arc can be suppressed without reducing the diameter of the hole 16 The occurrence of discharge.

此外,作為一例,雖然舉例說明了孔16的情形,但是具有階梯構造或推拔構造的孔16h的情形也一樣。In addition, as an example, although the case of the hole 16 was illustrated, the case of the hole 16h having a stepped structure or a push-out structure is the same.

對Z方向傾斜的孔16可藉由照射雷射或超音波加工等直接形成於陶瓷介電質基板11c。因此,設置有對Z方向傾斜的至少一個孔16的區域包含與陶瓷介電質基板11相同的材料。The hole 16 inclined to the Z direction can be directly formed in the ceramic dielectric substrate 11c by laser irradiation, ultrasonic processing, or the like. Therefore, the area provided with at least one hole 16 inclined to the Z direction contains the same material as the ceramic dielectric substrate 11.

圖21是舉例說明與其他的實施形態有關的靜電吸盤之示意剖面圖。 圖21相當於圖16所示的區域C的放大視圖。 如圖21所示,多孔質部90b係多孔區域91更具有緻密部92b。也就是說,多孔質部90b是在前述的多孔質部90更加入緻密部92b的部分。也就是說,也可以在設置於底板50的多孔質部70或多孔質部90更加入緻密部92b。 在投影於對Z方向垂直的平面(XY平面)時,可使複數個孔16的緻密部92b側的開口的至少一個與緻密部92b重疊。複數個緻密部92b的材料、密度、孔隙率等例如如前述。Fig. 21 is a schematic cross-sectional view illustrating an electrostatic chuck related to another embodiment. FIG. 21 is equivalent to an enlarged view of the area C shown in FIG. 16. As shown in FIG. 21, the porous portion 90b is the porous region 91 further having a dense portion 92b. That is, the porous part 90b is a part where the dense part 92b is added to the aforementioned porous part 90. That is, the dense portion 92b may be further added to the porous portion 70 or the porous portion 90 provided on the bottom plate 50. When projecting on a plane (XY plane) perpendicular to the Z direction, at least one of the openings on the dense portion 92b side of the plurality of holes 16 may overlap the dense portion 92b. The material, density, porosity, etc. of the plurality of dense portions 92b are as described above, for example.

圖22是舉例說明與其他的實施形態有關的靜電吸盤之示意剖面圖。 圖23相當於圖22所示的區域E的放大視圖。 圖24是顯示圖22所示的區域E的其他實施形態之放大視圖。 如圖22、圖23及圖24所示,靜電吸盤110b具備陶瓷介電質基板11d與底板50。在陶瓷介電質基板11d設置有多孔質部90b或多孔質部90a。 在陶瓷介電質基板11d設置有複數個孔16。複數個孔16例如可藉由照射雷射或超音波加工等形成於陶瓷介電質基板11d。在該例子中,複數個孔16的一端位於溝14的面14a。複數個孔16的另一端位於孔部15c的底面。也就是說,複數個孔16貫通陶瓷介電質基板11d於Z方向。Fig. 22 is a schematic cross-sectional view illustrating an electrostatic chuck related to another embodiment. FIG. 23 is equivalent to an enlarged view of the area E shown in FIG. 22. Fig. 24 is an enlarged view showing another embodiment of the area E shown in Fig. 22. As shown in FIGS. 22, 23, and 24, the electrostatic chuck 110b includes a ceramic dielectric substrate 11d and a bottom plate 50. The ceramic dielectric substrate 11d is provided with a porous portion 90b or a porous portion 90a. A plurality of holes 16 are provided in the ceramic dielectric substrate 11d. The plurality of holes 16 can be formed in the ceramic dielectric substrate 11d by, for example, laser irradiation or ultrasonic processing. In this example, one end of the plurality of holes 16 is located on the surface 14 a of the groove 14. The other ends of the plurality of holes 16 are located on the bottom surface of the hole portion 15c. That is, the plurality of holes 16 penetrate through the ceramic dielectric substrate 11d in the Z direction.

如圖23所示,在投影於對Z方向垂直的平面(XY平面)時,可使複數個孔16的至少一個與緻密部92b重疊。緻密部92b的材料、密度、孔隙率等例如如前述。 如圖24所示,在投影於對Z方向垂直的平面(XY平面)時,可使複數個孔16的至少一個與緻密部92a重疊。緻密部92a的材料、密度、孔隙率等例如如前述。As shown in FIG. 23, when projecting on a plane (XY plane) perpendicular to the Z direction, at least one of the plurality of holes 16 can be overlapped with the dense portion 92b. The material, density, porosity, etc. of the dense portion 92b are as described above, for example. As shown in FIG. 24, when projecting on a plane (XY plane) perpendicular to the Z direction, at least one of the plurality of holes 16 can be overlapped with the dense portion 92a. The material, density, porosity, etc. of the dense portion 92a are as described above, for example.

(處理裝置) 圖25是舉例說明與本實施的形態有關的處理裝置200之示意圖。 如圖25所示,在處理裝置200可配設靜電吸盤110、電源210、介質供給部220、供給部230。 電源210與設置於靜電吸盤110的電極12電連接。電源210例如能以直流電源。電源210對電極12施加規定的電壓。而且,也能在電源210配設切換電壓的施加與停止電壓的施加的開關。(Processing device) FIG. 25 is a schematic diagram illustrating a processing device 200 related to the embodiment of the present invention. As shown in FIG. 25, an electrostatic chuck 110, a power supply 210, a medium supply unit 220, and a supply unit 230 can be arranged in the processing device 200. The power supply 210 is electrically connected to the electrode 12 provided on the electrostatic chuck 110. The power supply 210 can be a DC power supply, for example. The power supply 210 applies a predetermined voltage to the electrode 12. Furthermore, the power supply 210 may be provided with a switch for switching the application of the voltage and stopping the application of the voltage.

介質供給部220連接於輸入道51及輸出道52。介質供給部220例如可進行成為冷卻介質或保溫介質的液體的供給而構成。 介質供給部220例如具有收容部221、控制閥222及排出部223。The medium supply unit 220 is connected to the input channel 51 and the output channel 52. The medium supply unit 220 may be configured to supply a liquid as a cooling medium or a heat-retaining medium, for example. The medium supply unit 220 has, for example, a storage unit 221, a control valve 222, and a discharge unit 223.

收容部221例如能以收容液體的槽(tank)或工廠配管等。而且,在收容部221可設置控制液體的溫度的冷卻裝置或加熱裝置。在收容部221也能具備用以送出液體的泵等。The accommodating part 221 can be, for example, a tank for accommodating a liquid or factory piping. In addition, a cooling device or a heating device that controls the temperature of the liquid may be installed in the storage portion 221. The accommodating part 221 can also be equipped with a pump etc. for sending a liquid.

控制閥222連接於輸入道51與收容部221之間。控制閥222可控制液體的流量及壓力的至少任一個。而且,控制閥222也能切換液體的供給與停止供給而構成。The control valve 222 is connected between the input passage 51 and the receiving portion 221. The control valve 222 can control at least any one of the flow rate and pressure of the liquid. Furthermore, the control valve 222 can also be configured to switch the supply and stop of the liquid supply.

排出部223連接於輸出道52。排出部223能以回收從輸出道52排出的液體的槽或排洩管(drain pipe)等。此外,未必需要排出部223,使從輸出道52排出的液體供給到收容部221也可以。據此,因可使冷卻介質或保溫介質循環,故可謀求省資源化。The discharge part 223 is connected to the output channel 52. The discharge part 223 can be a tank or a drain pipe for recovering the liquid discharged from the output channel 52. In addition, the discharge part 223 is not necessarily required, and the liquid discharged from the output channel 52 may be supplied to the storage part 221. According to this, since the cooling medium or the heat insulating medium can be circulated, resource saving can be achieved.

供給部230具有氣體供給部231及氣體控制部232。 氣體供給部231能以收容氦等的氣體的高壓鋼瓶或工廠配管等。此外,雖然舉例說明了設置有1個氣體供給部231的情形,但是也可以設置有複數個氣體供給部231。The supply unit 230 has a gas supply unit 231 and a gas control unit 232. The gas supply unit 231 can be a high-pressure steel cylinder or factory piping that stores gas such as helium. In addition, although the case where one gas supply unit 231 is provided is described as an example, a plurality of gas supply units 231 may be provided.

氣體控制部232連接於複數個氣體導入道53與氣體供給部231之間。氣體控制部232可控制氣體的流量及壓力的至少任一個。而且,氣體控制部232也能更具有切換氣體的供給與停止供給的功能而構成。氣體控制部232例如能以質流控制器(mass flow controller)或質量流量計(mass flow meter)等。The gas control unit 232 is connected between the plurality of gas introduction passages 53 and the gas supply unit 231. The gas control unit 232 can control at least one of the flow rate and pressure of the gas. In addition, the gas control unit 232 can be further configured to switch the supply of gas and stop the supply of gas. The gas control unit 232 can be, for example, a mass flow controller or a mass flow meter.

如圖25所示,氣體控制部232可設置複數個。例如氣體控制部232可第一主表面11a的每一複數個區域設置。據此,可每一複數個區域進行供給的氣體的控制。此情形,也能每一複數個氣體導入道53設置氣體控制部232。據此,可更精密地進行複數個區域中的氣體的控制。此外,雖然舉例說明了設置複數個氣體控制部232的情形,但是若氣體控制部232可獨立控制複數個供給系統中的氣體的供給,則一台也可以。As shown in FIG. 25, a plurality of gas control units 232 can be provided. For example, the gas control part 232 may be provided for every plural areas of the first main surface 11a. According to this, it is possible to control the gas supplied for each of a plurality of areas. In this case, the gas control unit 232 can also be provided for every plural gas introduction passages 53. According to this, the gas in a plurality of regions can be controlled more precisely. In addition, although the case where a plurality of gas control units 232 are provided is described as an example, if the gas control unit 232 can independently control the supply of gas in a plurality of supply systems, one unit may be sufficient.

此處,保持對象物W的手段有真空吸盤或機械式吸盤等。但是,真空吸盤在比大氣壓還被減壓的環境中無法使用。而且,若使用機械式吸盤,則有對象物W損傷或者產生微粒之虞。因此,例如在半導體製程等中使用的處理裝置使用靜電吸盤。Here, the means for holding the object W includes a vacuum chuck or a mechanical chuck. However, the vacuum chuck cannot be used in an environment where the pressure is lower than atmospheric pressure. Furthermore, if a mechanical chuck is used, the object W may be damaged or particles may be generated. Therefore, for example, processing devices used in semiconductor manufacturing processes use electrostatic chucks.

在這種處理裝置中,需從外部的環境隔離處理空間。因此,處理裝置200可更具備反應室(chamber)240。反應室240例如也能具有可維持比大氣壓還被減壓的環境的氣密構造而構成。 而且,處理裝置200可具備複數個頂出銷(lift pin),與使複數個頂出銷升降的驅動裝置。在從搬送裝置接受對象物W或者將對象物W遞送到搬送裝置時,頂出銷藉由驅動裝置而上升並自第一主表面11a突出。在將從搬運裝置接受的對象物W載置於第一主表面11a時,頂出銷藉由驅動裝置而下降並收容於陶瓷介電質基板11的內部。In this processing device, the processing space needs to be isolated from the external environment. Therefore, the processing device 200 may further include a chamber 240. The reaction chamber 240 can also be configured to have an airtight structure capable of maintaining an environment decompressed more than atmospheric pressure, for example. In addition, the processing device 200 may include a plurality of lift pins and a driving device for raising and lowering the plurality of lift pins. When receiving the object W from the conveying device or delivering the object W to the conveying device, the ejector pin is raised by the driving device and protrudes from the first main surface 11a. When the object W received from the conveying device is placed on the first main surface 11 a, the ejector pin is lowered by the driving device and is housed in the ceramic dielectric substrate 11.

而且,在處理裝置200可對應處理的內容而設置各種裝置。例如可設置對反應室240的內部進行排氣的真空泵等。在反應室240的內部可設置產生電漿的電漿產生裝置。在反應室240的內部可設置供給製程氣體的製程氣體供給部。在反應室240的內部中也可設置將對象物W或製程氣體加熱的加熱器。此外,設置於處理裝置200的裝置並非被限定於所舉例說明者。因在設置於處理裝置200的裝置可適用已知的技術,故省略詳細的說明。Furthermore, the processing device 200 can be provided with various devices corresponding to the content to be processed. For example, a vacuum pump etc. which exhaust the inside of the reaction chamber 240 may be provided. A plasma generator for generating plasma may be provided in the reaction chamber 240. A process gas supply part for supplying process gas may be provided inside the reaction chamber 240. A heater for heating the object W or the process gas may be provided in the reaction chamber 240. In addition, the devices provided in the processing device 200 are not limited to those illustrated. Since a known technology can be applied to the device installed in the processing device 200, a detailed description is omitted.

以上針對本發明的實施的形態進行了說明。但是,本發明不是被限定於該等記述。例如雖然作為靜電吸盤110舉例說明了利用庫侖力(Coulomb force)的構成,但是即使是利用Johnsen - Rahbek 力(Johnsen - Rahbek force)的構成也能適用。而且,關於前述的實施的形態,熟習該項技術者適宜加入了設計變更只要也具備本發明的特徵就包含於本發明的範圍。而且,前述的各實施的形態所具備的各元件在技術上盡可能可組合,組合該等元件只要也包含本發明的特徵就包含於本發明的範圍。The foregoing has described the mode of implementation of the present invention. However, the present invention is not limited to these descriptions. For example, although a configuration using Coulomb force (Coulomb force) is exemplified as the electrostatic chuck 110, even a configuration using Johnsen-Rahbek force (Johnsen-Rahbek force) is applicable. In addition, regarding the aforementioned embodiment, those skilled in the art may appropriately add design changes as long as they also have the characteristics of the present invention, and they are included in the scope of the present invention. In addition, the various elements provided in the aforementioned embodiments can be combined as technically as possible, and the combination of these elements is included in the scope of the present invention as long as they also include the features of the present invention.

11c、11d:陶瓷介電質基板 11a:第一主表面 11b:第二主表面 11p:第一基板區域 12:電極 13:點 14:溝 14a:底面 15:貫通孔 15a、15b、15c、15d:孔部 15c1:面 15w:內壁 16、16h、96:孔 16i、16j:邊緣 20:連接部 50:底板 50a:上部 50b:下部 50U、70U、90U:頂面 51:輸入道 52:輸出道 53:氣體導入道 53a:鏜孔部 53b:邊緣 55:連通道 60:接合部 61:接著構件 70、90、90a、90b:多孔質部 70a:多孔質部 71:多孔區域 72、93:緻密區域 90p:第一區域 90q:第二區域 90L:底面 91:多孔區域 91s、93s:側面 92a、92b:緻密部 94、94a~94g、95c:稀疏部分 95:緊密部分 96、96a~96g:孔 97:壁部 110、110a:靜電吸盤 200:處理裝置 210:電源 211:配線 220:介質供給部 221:收容部 222:控制閥 223:排出部 230:供給部 231:氣體供給部 232:氣體控制部 A、B、C、D、E:區域 F1:界面 L0~L11:長度 ROI1:評價範圍 ROI2:評價範圍 SP:空間 W:對象物 W1、W2:寬度11c, 11d: ceramic dielectric substrate 11a: First major surface 11b: Second major surface 11p: first substrate area 12: Electrode 13: Point 14: groove 14a: bottom surface 15: Through hole 15a, 15b, 15c, 15d: hole 15c1: surface 15w: inner wall 16, 16h, 96: well 16i, 16j: edge 20: Connection part 50: bottom plate 50a: upper part 50b: lower part 50U, 70U, 90U: top surface 51: input channel 52: output channel 53: Gas inlet 53a: Boring part 53b: Edge 55: Connect Channel 60: Joint 61: Next component 70, 90, 90a, 90b: porous part 70a: Porous part 71: porous area 72, 93: dense area 90p: first area 90q: second area 90L: bottom surface 91: porous area 91s, 93s: side 92a, 92b: dense part 94, 94a~94g, 95c: sparse part 95: tight part 96, 96a~96g: well 97: Wall 110, 110a: Electrostatic chuck 200: processing device 210: Power 211: Wiring 220: Media Supply Department 221: Containment Department 222: control valve 223: discharge part 230: Supply Department 231: Gas Supply Department 232: Gas Control Department A, B, C, D, E: area F1: Interface L0~L11: length ROI1: Evaluation scope ROI2: Evaluation scope SP: Space W: Object W1, W2: width

圖1是舉例說明與本實施形態有關的靜電吸盤之示意剖面圖。 圖2(a)~(d)是舉例說明與實施形態有關的靜電吸盤之示意圖。 圖3(a)、(b)是舉例說明與實施形態有關的靜電吸盤的多孔質部之示意圖。 圖4是舉例說明與實施形態有關的靜電吸盤的多孔質部之示意俯視圖。 圖5是舉例說明與實施形態有關的靜電吸盤的多孔質部之示意俯視圖。 圖6(a)、(b)是舉例說明與實施形態有關的靜電吸盤的多孔質部之示意俯視圖。 圖7(a)、(b)是舉例說明與其他的實施形態有關的第一多孔質部之示意圖。 圖8是舉例說明與實施形態有關的靜電吸盤之示意剖面圖。 圖9(a)、(b)是舉例說明與實施形態有關的靜電吸盤之示意剖面圖。 圖10是舉例說明與實施形態有關的靜電吸盤的多孔質部之示意剖面圖。 圖11是舉例說明與其他的實施形態有關的多孔質部之示意剖面圖。 圖12(a)、(b)是舉例說明與其他的實施形態有關的多孔質部之示意剖面圖。 圖13(a)~(d)是舉例說明與其他的實施形態有關的多孔質部之示意剖面圖。 圖14(a)~(c)是舉例說明與其他的實施形態有關的多孔質部之示意剖面圖。 圖15(a)、(b)是舉例說明與其他的實施形態有關的多孔質部之示意剖面圖。 圖16是舉例說明與其他的實施形態有關的靜電吸盤之示意剖面圖。 圖17(a)、(b)是圖16所示的區域C之放大視圖。 圖18是舉例說明與其他的實施形態有關的複數個孔之示意剖面圖。 圖19(a)、(b)是舉例說明孔的開口部分的形狀之示意剖面圖。 圖20是舉例說明與其他的實施形態有關的靜電吸盤之示意剖面圖。 圖21是舉例說明與其他的實施形態有關的靜電吸盤之示意剖面圖。 圖22是舉例說明與其他的實施形態有關的靜電吸盤之示意剖面圖。 圖23是圖22所示的區域E之放大視圖。 圖24是顯示圖22所示的區域E之其他的實施形態之放大視圖。 圖25是舉例說明與本實施的形態有關的處理裝置之示意圖。Fig. 1 is a schematic cross-sectional view illustrating an electrostatic chuck related to this embodiment. 2(a)~(d) are schematic diagrams illustrating the electrostatic chuck related to the embodiment. 3(a) and (b) are schematic diagrams illustrating the porous part of the electrostatic chuck related to the embodiment. Fig. 4 is a schematic plan view illustrating the porous part of the electrostatic chuck according to the embodiment. Fig. 5 is a schematic plan view illustrating the porous part of the electrostatic chuck according to the embodiment. Fig. 6 (a) and (b) are schematic plan views illustrating examples of the porous part of the electrostatic chuck related to the embodiment. Fig. 7 (a) and (b) are schematic diagrams illustrating the first porous part related to other embodiments. Fig. 8 is a schematic sectional view illustrating an electrostatic chuck related to the embodiment. Figures 9(a) and (b) are schematic cross-sectional views illustrating an electrostatic chuck related to the embodiment. Fig. 10 is a schematic cross-sectional view illustrating the porous part of the electrostatic chuck according to the embodiment. Fig. 11 is a schematic cross-sectional view illustrating a porous part related to another embodiment. Figs. 12(a) and (b) are schematic cross-sectional views illustrating examples of porous parts related to other embodiments. Fig. 13 (a) to (d) are schematic cross-sectional views illustrating examples of porous parts related to other embodiments. 14(a) to (c) are schematic cross-sectional views illustrating examples of porous parts related to other embodiments. 15(a) and (b) are schematic cross-sectional views illustrating examples of porous parts related to other embodiments. Fig. 16 is a schematic cross-sectional view illustrating an electrostatic chuck related to another embodiment. 17(a) and (b) are enlarged views of the area C shown in FIG. 16. Fig. 18 is a schematic cross-sectional view illustrating a plurality of holes related to another embodiment. 19(a) and (b) are schematic cross-sectional views illustrating the shape of the opening portion of the hole. Fig. 20 is a schematic cross-sectional view illustrating an electrostatic chuck related to another embodiment. Fig. 21 is a schematic cross-sectional view illustrating an electrostatic chuck related to another embodiment. Fig. 22 is a schematic cross-sectional view illustrating an electrostatic chuck related to another embodiment. Fig. 23 is an enlarged view of the area E shown in Fig. 22. Fig. 24 is an enlarged view showing another embodiment of the area E shown in Fig. 22. Fig. 25 is a schematic diagram illustrating a processing device related to the embodiment of the present invention.

11:陶瓷介電質基板 11: Ceramic dielectric substrate

11a:第一主表面 11a: First major surface

11b:第二主表面 11b: Second major surface

12:電極 12: Electrode

13:點 13: Point

14:溝 14: groove

14a:底面 14a: bottom surface

15:貫通孔 15: Through hole

15a、15b、15c:孔部 15a, 15b, 15c: hole

15w:內壁 15w: inner wall

50U、70U、90U:頂面 50U, 70U, 90U: top surface

53:氣體導入道 53: Gas inlet

53a:鏜孔部 53a: Boring part

53b:邊緣 53b: Edge

60:接合部 60: Joint

90a:多孔質部 90a: Porous part

70a:多孔質部 70a: Porous part

71:多孔區域 71: porous area

72、93:緻密區域 72, 93: dense area

90L:底面 90L: bottom surface

91:多孔區域 91: porous area

91s、93s:側面 91s, 93s: side

92a、92b:緻密部 92a, 92b: dense part

200:處理裝置 200: processing device

SP:空間 SP: Space

W:對象物 W: Object

Claims (16)

一種靜電吸盤,其特徵在於包含: 陶瓷介電質基板,具有:載置吸附的對象物之第一主表面,和與該第一主表面相反側之第二主表面; 底板,支撐該陶瓷介電質基板,具有氣體導入道; 第一多孔質部,配設於該陶瓷介電質基板,與該氣體導入道對向;以及 第二多孔質部,配設於該底板,與該氣體導入道對向, 該陶瓷介電質基板具有位於該第一主表面與該第一多孔質部之間的第一孔部, 該第一多孔質部具有:具有複數個孔之第一多孔區域,和比該第一多孔區域還緻密之第一緻密區域,該第一多孔區域更具有至少一個第一緻密部, 該第二多孔質部具有:具有複數個孔之第二多孔區域,和比該第二多孔區域還緻密之第二緻密區域,該第二多孔區域更具有至少一個第二緻密部, 在投影於對從該底板朝向該陶瓷介電質基板的第一方向垂直的平面時,該第一緻密部與該第一孔部重疊,該第二緻密部的至少一部分與該第一緻密部的至少一部分重疊,或者該第二緻密部的至少一部分與該第一緻密部的至少一部分接觸而構成。An electrostatic chuck, characterized in that it contains: The ceramic dielectric substrate has: a first main surface on which the object to be adsorbed is placed, and a second main surface opposite to the first main surface; The bottom plate supports the ceramic dielectric substrate and has a gas introduction channel; The first porous part is arranged on the ceramic dielectric substrate and is opposite to the gas introduction channel; and The second porous part is arranged on the bottom plate and is opposite to the gas introduction channel, The ceramic dielectric substrate has a first hole portion located between the first main surface and the first porous portion, The first porous part has: a first porous region having a plurality of pores, and a first dense region denser than the first porous region, and the first porous region further has at least one first dense part , The second porous part has: a second porous region having a plurality of pores, and a second dense region denser than the second porous region, and the second porous region further has at least one second dense part , When projected on a plane perpendicular to the first direction from the bottom plate to the ceramic dielectric substrate, the first dense part overlaps the first hole part, and at least a part of the second dense part is overlapped with the first dense part At least a part of overlaps, or at least a part of the second dense part is in contact with at least part of the first dense part. 如請求項1之靜電吸盤,其中在投影於對該第一方向垂直的平面時,該第一緻密部的尺寸與該第一孔部的尺寸相同,或者該第一緻密部的尺寸大於該第一孔部的尺寸。Such as the electrostatic chuck of claim 1, wherein when projected on a plane perpendicular to the first direction, the size of the first dense portion is the same as the size of the first hole, or the size of the first dense portion is larger than the size of the first hole The size of a hole. 如請求項1或請求項2之靜電吸盤,其中在投影於對該第一方向垂直的平面時,該第二緻密部與該第一緻密區域重疊,或者該第二緻密部與該第一緻密區域相接。Such as the electrostatic chuck of claim 1 or claim 2, wherein when projected on a plane perpendicular to the first direction, the second dense part overlaps the first dense region, or the second dense part overlaps the first dense region Areas meet. 如請求項1或請求項2之靜電吸盤,其中該第一多孔區域具有複數個第一疏鬆部分與第一緊密部分, 該第一稀疏部分具有該複數個孔, 該第一緊密部分具有比該第一稀疏部分的密度還高的密度,該第二方向上的尺寸小於該第二方向上的該第一緻密區域的尺寸, 該複數個第一稀疏部分的各個延伸於該第一方向, 該第一緊密部分位於該複數個第一稀疏部分彼此之間, 該第一稀疏部分具有設置於該複數個孔彼此之間的第一壁部, 在略正交於該第一方向的第二方向上,該第一壁部的尺寸的最小值小於該第一緊密部分的尺寸的最小值。For example, the electrostatic chuck of claim 1 or claim 2, wherein the first porous area has a plurality of first loose parts and first tight parts, The first sparse part has the plurality of holes, The first dense portion has a density higher than the density of the first sparse portion, and the size in the second direction is smaller than the size of the first dense area in the second direction, Each of the plurality of first sparse parts extends in the first direction, The first tight part is located between the plurality of first sparse parts, The first sparse portion has a first wall portion arranged between the plurality of holes, In a second direction that is slightly orthogonal to the first direction, the minimum value of the size of the first wall portion is smaller than the minimum value of the size of the first compact portion. 如請求項1或請求項2之靜電吸盤,其中在該第二方向上,設置於該複數個第一稀疏部分的各個的該複數個孔的尺寸比該第一緊密部分的尺寸還小,及/或在該第二方向上,設置於該複數個第二稀疏部分的各個的該複數個孔的尺寸比該第二緊密部分的尺寸還小。For example, the electrostatic chuck of claim 1 or claim 2, wherein in the second direction, the size of the plurality of holes provided in each of the plurality of first sparse portions is smaller than the size of the first compact portion, and /Or in the second direction, the size of the plurality of holes provided in each of the plurality of second sparse portions is smaller than the size of the second dense portion. 如請求項1或請求項2之靜電吸盤,其中設置於該複數個第一稀疏部分的各個的該複數個孔的縱橫比,及/或設置於該複數個第二稀疏部分的各個的該複數個孔的縱橫比為30以上。For example, the electrostatic chuck of claim 1 or claim 2, wherein the aspect ratio of the plurality of holes provided in each of the plurality of first sparse parts, and/or the plurality of holes provided in each of the plurality of second sparse parts The aspect ratio of each hole is 30 or more. 如請求項1或請求項2之靜電吸盤,其中在該第二方向上,設置於該複數個第一稀疏部分的各個的該複數個孔的尺寸,及/或設置於該複數個第二稀疏部分的各個的該複數個孔的尺寸為1微米以上、20微米以下。For example, the electrostatic chuck of claim 1 or claim 2, wherein in the second direction, the size of the plurality of holes arranged in each of the plurality of first sparse parts, and/or the size of the plurality of holes arranged in the plurality of second sparse parts The size of each of the plurality of holes is 1 micrometer or more and 20 micrometers or less. 如請求項1或請求項2之靜電吸盤,其中在沿著該第一方向看時,設置於該第一稀疏部分的複數個孔包含位於該第一稀疏部分的中心部的第一孔, 該複數個孔之中與該第一孔鄰接且包圍該第一孔的孔的數目為6,及/或 在沿著該第一方向看時,設置於該第二稀疏部分的複數個孔包含位於該第二稀疏部分的中心部的第二孔, 該複數個孔之中與該第二孔鄰接且包圍該第二孔的孔的數目為6。For example, the electrostatic chuck of claim 1 or claim 2, wherein when viewed along the first direction, the plurality of holes provided in the first sparse part includes a first hole located at the center of the first sparse part, Among the plurality of holes, the number of holes adjacent to and surrounding the first hole is 6, and/or When viewed along the first direction, the plurality of holes provided in the second sparse part includes a second hole located at the center of the second sparse part, The number of holes adjacent to and surrounding the second hole among the plurality of holes is 6. 如請求項1或請求項2之靜電吸盤,其中該第一緻密部之沿著該第一方向的長度小於該第一多孔質部之沿著該第一方向的長度。Such as the electrostatic chuck of claim 1 or claim 2, wherein the length of the first dense part along the first direction is smaller than the length of the first porous part along the first direction. 如請求項1或請求項2之靜電吸盤,其中在該第一方向上,在該第一緻密部與該底板之間設置有該第一多孔區域。For example, the electrostatic chuck of claim 1 or claim 2, wherein in the first direction, the first porous area is provided between the first dense portion and the bottom plate. 如請求項1或請求項2之靜電吸盤,其中該第一緻密部之沿著該第一方向的長度與該第一多孔質部之沿著該第一方向的長度大致相同。Such as the electrostatic chuck of claim 1 or claim 2, wherein the length of the first dense part along the first direction is substantially the same as the length of the first porous part along the first direction. 如請求項1或請求項2之靜電吸盤,其中在投影於對該第一方向垂直的平面時,在該第一緻密部的周圍設置有該複數個第一稀疏部分。For example, the electrostatic chuck of claim 1 or claim 2, wherein when projected on a plane perpendicular to the first direction, the plurality of first sparse parts are arranged around the first dense part. 如請求項1或請求項2之靜電吸盤,其中設置於該第二多孔質部的該複數個孔的直徑的平均值比設置於該第一多孔質部的複數個孔的直徑的平均值還大。For example, the electrostatic chuck of claim 1 or claim 2, wherein the average diameter of the plurality of holes provided in the second porous part is greater than the average diameter of the plurality of holes provided in the first porous part The value is still great. 如請求項1或請求項2之靜電吸盤,其中該氣體導入道的該陶瓷介電質基板側的開口的邊緣的至少一部分以曲線構成。For example, the electrostatic chuck of claim 1 or claim 2, wherein at least a part of the edge of the opening on the ceramic dielectric substrate side of the gas introduction channel is formed by a curve. 如請求項1或請求項2之靜電吸盤,其中該陶瓷介電質基板具有位於該第一主表面與該第一多孔質部之間的第一孔部, 該陶瓷介電質基板及該第一多孔質部的至少任一個具有位於該第一孔部與該第一多孔質部之間的第二孔部, 在與該第一方向略正交的第二方向上,該第二孔部的尺寸小於該第一多孔質部的尺寸,大於該第一孔部的尺寸。The electrostatic chuck of claim 1 or claim 2, wherein the ceramic dielectric substrate has a first hole located between the first main surface and the first porous portion, At least any one of the ceramic dielectric substrate and the first porous portion has a second hole portion located between the first hole portion and the first porous portion, In a second direction that is slightly orthogonal to the first direction, the size of the second hole is smaller than the size of the first porous portion and larger than the size of the first hole. 一種處理裝置,其特徵在於包含: 請求項1至請求項15中任一項之靜電吸盤;以及 供給部,可將氣體供給到設置於該靜電吸盤的氣體導入道。A processing device, characterized by comprising: The electrostatic chuck of any one of Claim 1 to Claim 15; and The supply unit can supply gas to the gas introduction path provided in the electrostatic chuck.
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JP7259765B2 (en) * 2017-12-28 2023-04-18 住友大阪セメント株式会社 Electrostatic chuck device
JP6504532B1 (en) * 2018-03-14 2019-04-24 Toto株式会社 Electrostatic chuck
KR20210072114A (en) * 2018-11-01 2021-06-16 램 리써치 코포레이션 High power electrostatic chuck with features to prevent He hole light-up/arcing

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KR102340524B1 (en) 2021-12-20

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