TW202026278A - Cleaning composition - Google Patents

Abstract

The cleaning composition of the present invention contains a trialkylamine oxide. Trialkylamine oxides include, for example, decyltetradecyldimethylamine oxide.

Description

Detergent composition [Related Application Case]

The present invention is based on the priority claim of Japanese Patent Application: Japanese Patent Application No. 2018-220594 (filed on November 26, 2018), and all the contents of the same application are cited and described in this specification.

This disclosure relates to detergent compositions. This disclosure relates, for example, to a detergent composition for dyes used to wash away dyes from the skin. In addition, the present disclosure, for example, relates to a detergent composition applicable to the cleaning of cosmetics, and particularly relates to a detergent composition applicable to the cleaning of cosmetics containing oily cosmetics and/or dyes.

There are water-based components and oily components in cosmetic ingredients. In the case of washing the cosmetics applied on the face, if the detergents for water-based cosmetics and the detergents for oil-based cosmetics are used for washing, both the water-based and oily ingredients can be washed. However, the trouble is that at least two washing actions are required. Therefore, for example, Patent Document 1 discloses a cleansing cosmetic for washing off water and oily dirt.

The cleansing cosmetic described in Patent Document 1 contains N-coconut oil fatty acid glycine calcium salt, and oxylauryldimethylamine or oxystearyldimethylamine.

[Prior Technical Literature]

[Patent Literature]

Patent Document 1: Japanese Patent Laid-Open No. 11-199437

The following analysis is proposed from the viewpoint of this disclosure.

Cosmetics that are blended with dyes are known. In the present disclosure, this cosmetic is hereinafter referred to as "coloring cosmetic". As the coloring cosmetics, there are, for example, lip stains or lipsticks that suppress bleaching. In dyeing cosmetics, dyes are allowed to penetrate into the stratum corneum of the skin such as lips to be colored, thereby suppressing decolorization. However, since the dye penetrates into the stratum corneum and may form a chemical bond between the dye and the protein, it is difficult to sufficiently remove the dyed cosmetics only with the usual detergents for washing cosmetics applied on the skin. Therefore, in order to lighten the color of the dyed cosmetics on the skin appearance, it is better to completely wash off the color of the dyed cosmetics from the skin, and a special detergent for the dyed cosmetics is necessary.

The cleansing cosmetics described in Patent Document 1 do not have high cleansing properties compared to dyed cosmetics.

Therefore, a cleansing material with high cleansing properties relative to dyed cosmetics is expected.

According to the first aspect of the present disclosure, a detergent composition containing trialkylamine oxide represented by Chemical Formula 1 is provided.

Chemical formula 1

In the chemical formula shown in Chemical Formula ¹ , any two of R ¹ , R ² and R ³ are an alkyl group having 1 to 4 carbons, and the remaining one is an alkyl group having 22 to 26 carbons.

The detergent composition of the present disclosure has high detergency compared to dyed cosmetics.

The following is a description of preferable aspects of the above-mentioned viewpoints.

According to a preferred aspect of the above-mentioned first viewpoint, in Chemical Formula 1, R ¹ and R ² are methyl groups. R ³ is decyltetradecyl.

According to a preferable aspect of the above-mentioned first viewpoint, the content of trialkylamine oxide is 0.01% by mass to 2% by mass relative to the mass of the composition.

According to a preferred aspect of the first viewpoint described above, the detergent composition has an oil phase and a water phase. The oil phase and the water phase are mainly not emulsified in the static state.

According to a preferred aspect of the first viewpoint described above, the content of the oil phase is 20% by mass to 80% by mass relative to the mass of the composition. The content of the water phase is 20% by mass to 80% by mass relative to the mass of the composition.

According to a preferred aspect of the above-mentioned first viewpoint, the pH of the water phase is 4-8.

According to a preferred aspect of the above-mentioned first viewpoint, the content of the surfactant is 0.2% by mass or less with respect to the mass of the composition.

According to a preferred aspect of the above-mentioned first viewpoint, the detergent composition further contains an Alkyl betaine type surfactant.

According to a preferred aspect of the first viewpoint described above, the detergent composition further contains 1% to 20% by mass of water-soluble alcohol relative to the mass of the composition.

According to a preferred aspect of the first viewpoint described above, the detergent composition further contains 15 to 50% by mass of volatile oily components relative to the mass of the composition.

According to a preferred aspect of the first viewpoint, the volatile oil component is at least one selected from the group consisting of hydrocarbon oil, ester oil, and silicone oil.

According to a preferred aspect of the first viewpoint described above, the detergent composition further contains 0.1% to 5% by mass of salt relative to the mass of the composition.

According to a preferred aspect of the first aspect described above, the detergent composition contains a polyol derivative in an amount of 0.05% to 5% by mass relative to the mass of the composition. The polyhydric alcohol derivative is at least one of the glycerin derivative represented by Chemical Formula 2 and the ethylene glycol derivative represented by Chemical Formula 3.

Chemical formula 2

In the chemical formula shown in Chemical Formula 2, any one of R ⁴ , R ⁵ and R ⁶ is an alkyl group, alkenyl group, or acyl group having 4 to 15 carbon atoms, and the other two are hydrogen atoms.

Chemical formula 3

In the chemical formula shown in Chemical Formula 3, one of R ⁷ and R ⁸ is an alkyl group, alkenyl group, or acyl group having 10 to 20 carbon atoms, and the other is a hydrogen atom. R ⁹ is an alkyl group having 1 to 4 carbons, an alkenyl group, an acyl group, or a hydrogen atom.

According to a preferred aspect of the above-mentioned first viewpoint, the glycerin derivative contains at least one of ethylhexylglycerol and hexylglycerol.

According to a preferred aspect of the first viewpoint, the ethylene glycol derivative contains at least one of propylene glycol laurate, propylene glycol stearate, and propylene glycol isostearate.

According to a preferred aspect of the first viewpoint described above, the detergent composition is a cosmetic detergent composition.

According to a preferred aspect of the above-mentioned first viewpoint, the detergent composition is a detergent composition for washing cosmetics containing dyes from the skin.

According to a preferred aspect of the above-mentioned first viewpoint, the detergent composition is a disposable type.

In the following description, POE is polyoxyethylene, POP is the abbreviation of polyoxypropylene, and the number in square brackets after POE or POP indicates the average number of added moles of the POE group or POP group in the compound.

In the present disclosure, the "substantial amount" means the amount that can produce the effect brought about by the addition of the compound.

[(A) Trialkylamine oxide]

The detergent composition system of the first embodiment contains (A) trialkylamine oxide. Trialkylamine oxide can be water-soluble or non-water-soluble (oil-soluble). Trialkylamine oxide can also be a mixture of water-soluble trialkylamine oxide and oil-soluble trialkylamine oxide. In the case of improving the detergency with respect to oily cosmetics and/or dyed cosmetics, trialkylamine oxide is preferably water-insoluble. The solubility to water or oily components can be adjusted by the length of the alkyl group of trialkylamine oxide.

The trialkylamine oxide may have a structure shown in Chemical Formula 4. R ¹ , R ² and R ³ may each be a straight chain alkyl group or a branched chain alkyl group.

Any two of R ¹ , R ² and R ³ (for example, R ¹ and R ² ) may be an alkyl group having 1 to 4 carbon atoms. Among R ¹ , R ² and R ³ , the remaining one (for example, R ³ ) may be an alkyl group having 22 to 26 carbons (for example, an alkyl group having 24 carbons). The trialkylamine oxide can be configured such that R ¹ and R ² are methyl groups and R ³ is decyl tetradecyl tetradecyl dimethylamine represented by Chemical Formula 5, for example. One of the three alkyl groups (e.g., R ³ ) has a trialkylamine oxide with a carbon number of 22 or more. Compared with a trialkylamine oxide with an alkyl group with a carbon number of 21 or less, it can improve the resistance to dye makeup The detergency of the material.

Chemical formula 4

Chemical formula 5

In the first embodiment, the content rate of the component (A) relative to the mass of the composition is preferably 0.01% by mass or more, more preferably 0.02% by mass or more, particularly preferably 0.05% by mass or more, and particularly preferably 0.08% by mass Above, 0.1% by mass or more is more preferable, 0.12% by mass or more is more preferable, 0.15% by mass or more is more preferable, and 0.18% by mass or more is more preferable. When the component (A) is less than 0.01% by mass, the detergency with respect to the dye component decreases. The content rate of the component (A) relative to the mass of the composition can be, for example, 2% by mass or less, 1% by mass or less, 0.8% by mass or less, 0.6% by mass or less, or 0.4% by mass or less.

According to the cleansing composition of the first embodiment, dyes (for example, color cosmetics) colored on the skin can be washed away from the skin.

The detergent composition of the first embodiment can also be used as a no-clean detergent without washing.

In the detergent composition of the first embodiment, the component (A) can be dissolved in either the oil phase or the water phase. For example, when the component (A) is oil-soluble, it can be added to the water phase by dissolving the component (A) in a water-soluble alcohol.

The detergent composition of the first embodiment may further contain at least one of (B) oily components, (C) surfactants, (D) water, (E) water-soluble alcohols, and (F) polyol derivatives.

[(B) Oily ingredients]

When the component (A) is oil-soluble, the oily component is preferably a component that can dissolve the component (A). In addition, the component (B) preferably has high cleansing properties with respect to oily cosmetics such as mascara. The component (B) is preferably mainly liquid at room temperature.

As the oily component, for example, liquid fats, solid fats, waxes, hydrocarbons, higher fatty acids, higher alcohols, synthetic ester oils, silicone oils, etc. can be used.

Examples of liquid fats and oils include avocado oil, camellia oil, turtle oil, Hawaiian soybean oil, corn oil, mink oil, olive oil, rapeseed oil, egg butter, sesame oil, peach kernel oil, wheat germ oil, camellia oil, castor oil, Linseed oil, sunflower oil, cottonseed oil, perilla oil, soybean oil, peanut oil, tea seed oil, Kaya oil, rice bran oil, Chinese tung oil, Japanese tung oil, jojoba oil, germ oil, Triglycerin and so on.

Examples of solid fats and oils include cocoa butter, coconut oil, horse oil, hardened coconut oil, palm oil, tallow, lanolin, hardened tallow, palm kernel oil, lard, tallow, wood wax kernel oil, hardened oil , Beef foot oil, wood wax, hardened castor oil, etc.

Examples of waxes include beeswax, candelilla wax, cotton wax, carnauba wax, laurel wax, white wax, spermaceti, montan wax, rice bran wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, Sugarcane wax, lanolin fatty acid isopropyl ester, hexyl laurate, reduced lanolin, jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, Lanolin fatty acid polyethylene glycol ester, POE hydrogenated lanolin alcohol ether, etc.

Hydrocarbon oils include, for example, fluid paraffin, natural ozocerite (Ozokerite), squalane (Squalane), squalane (Pristane), paraffin, refined ceresin (Ceresin), squalene (Squalene), petrolatum, microcrystalline wax, N-hexane, isohexane, cyclohexane, n-octane, isooctane, n-nonane, n-decane, isododecane, isohexadecane, etc.

Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, pine oil fatty acid, isostearin Acid, Linoleic Acid, Linolenic Acid, Eicosapentaenoic Acid (EPA), Docosahexaenoic Acid (DHA), etc.

For higher alcohols, for example, straight-chain alcohols (such as lauryl alcohol, cetyl alcohol, stearyl alcohol, diethyl alcohol, myristyl alcohol, oleyl alcohol, cetearyl alcohol, etc.) can be used; branched-chain alcohols (such as monostearyl alcohol ( Squalol, 2-decyltetradecyl alcohol, lanolin alcohol, cholesterol, Phytosterol, hexyldodecanol, isostearyl alcohol, octyldodecanol, etc.).

Synthetic ester oils include isopropyl myristate, cetyl caprylate, octyl lauryl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, Lauryl oleate, hexyl lauryl dimethyl octanoate, cetyl lactate, myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, 12-hydroxy hard Cholesterol fatty acid ester, ethylene glycol di-2-ethylhexanoate, dineopentyl erythritol fatty acid ester, N-alkanediol monoisostearate, neopentyl glycol dicaprate, malic acid Diisostearyl ester, glyceryl di-2-heptylundecanoate, trimethylolpropane tri-2-ethylhexanoate, trimethylolpropane triisostearate, tetra-2-ethylhexyl Neopentyl erythritol ester, glyceryl tri-2-ethylhexanoate, glyceryl tricaprylate, glyceryl triisopalmitate, trimethylolpropane triisostearate, cetyl ethylhexanoate, octyl palmitate , Trimyristic acid glyceride, tri-2-heptylundecanoic acid glyceride, castor oil fatty acid methyl ester, oleyl oleate, acetyl glyceride, 2-heptyl undecyl palmitate, two adipate Isobutyl ester, N-laurel-L-glutamic acid-2-octyladecyl ester, di-2-heptyl undecyl adipate, ethyl laurate, di-2-ethyl sebacate Hexyl ester, nutmeg 2-hexyldecyl acid, 2-hexyldecyl palmitate, 2-hexyldecyl adipate, diisopropyl sebacate, 2-ethylhexyl succinate, triethyl citrate, etc.

Polysiloxane oils include dimethyl polysiloxane, methyl hydrogen polysiloxane, methyl phenyl polysiloxane, stearyloxy methyl polysiloxane, and organic polysiloxane modified by polyether. Silicone, fluoroalkyl and polyoxyalkylene co-modified organopolysiloxane, alkyl-modified organopolysiloxane, terminal modified organopolysiloxane, fluorine-modified organopolysiloxane Alkyl, amine modified organic polysiloxane, polysiloxane gel, acrylic polysiloxane, trimethylsiloxy silicic acid, polysiloxane RTV rubber and other polysiloxane compounds.

Among the above-mentioned oily components, hydrocarbon oils, ester oils, silicone oils, etc., have good affinity with oily cosmetics and are therefore preferred. Examples of volatile oily components include isododecane and dimethylpolysiloxane.

The content rate of the component (B) relative to the mass of the composition is preferably 20% by mass or more, particularly preferably 25% by mass or more, and more preferably 28% by mass or more. When the component (B) is less than 20% by mass, the component (A) precipitates, and the transparency of the liquid composition may decrease. The content rate of the component (B) relative to the mass of the composition can be, for example, 80% by mass or less, 70% by mass or less, or 60% by mass or less.

In the component (B), the volatile oily component relative to the mass of the composition is preferably 15% by mass or more, particularly preferably 20% by mass or more, and more preferably 25% by mass or more. When the volatile oil content is less than 15% by mass, the cleansing properties of the oily cosmetics are reduced. The content rate of the volatile oily component relative to the mass of the composition can be, for example, 50% by mass or less, 45% by mass or less, or 40% by mass or less.

[(C) Surfactant]

The component (C) can be added, for example, in an oil-water double-layer detergent composition, to temporarily emulsify the detergent composition during use. Examples of the component (C) include the following surfactants.

[(C1) Anionic Surfactant]

Anionic surfactants, for example, fatty acid soaps (such as sodium laurate, sodium palmitate, etc.); higher alkyl sulfate ester salts (such as sodium lauryl sulfate, potassium lauryl sulfate, etc.); alkyl ether sulfate ester salts (such as POE-Triethanolamine Lauryl Sulfate, POE-Sodium Lauryl Sulfate, etc.); N-Carnosine (such as Sodium Lauryl sarcosine, etc.); Higher Fatty Acid Sulfonates (such as N-Stearyl Sarcosine) Sodium-N-methyl taurate, sodium N-myristyl-N-methyl taurate, coconut oil fatty acid methyl taurate sodium, sodium lauryl methyl taurate, etc.); phosphate ester Salt (POE-sodium oleyl ether phosphate, POE-stearyl ether phosphoric acid, etc.); sulfonic acid succinate (such as sodium di-2-ethylhexyl sulfosuccinate, monolaurin monoethanolamide polyoxy Sodium ethylene sulfonate succinate, sodium lauryl polypropylene glycol sulfonate succinate, etc.); alkylbenzene sulfonate (such as linear sodium dodecylbenzene sulfonate, linear triethanolamine dodecylbenzenesulfonate, linear ten Dibasic benzene sulfonic acid, etc.); higher fatty acid ester sulfate salt (for example, hardened coconut oil fatty acid sodium glycerol sulfate, etc.); N-glycol glutamate (for example, N-laurinyl glutamate monosodium, N- Disodium stearyl glutamate, monosodium N-myristyl-L-glutamate, etc.); sulfated oils (such as Turkish red oil, etc.); POE-alkyl ether carboxylic acid; POE-alkylene Propyl ether carboxylate; α-olefin sulfonate; higher fatty acid ester sulfonate; secondary alcohol sulfate ester salt; higher fatty acid alkanol amide sulfate ester salt; sodium lauryl monoethanolamide succinate; N -Palmitoyl aspartate di-triethanolamine; sodium caseinate, etc.

[(C2) Cationic Surfactant]

啉鹽；POE-烷胺；烷胺鹽；多胺脂肪酸衍生物；戊醇脂肪酸衍生物；氯化苯二甲烴銨(Benzalkonium Chloride)；氯化本索寧(Benzethonium Chloride)；胺基酸系陽離子界面活性劑(例如N-椰子油脂肪酸醯基-L-精胺酸乙基-DL-吡咯啶酮羧酸鹽)等。 Examples of the cationic surfactant include alkyl trimethyl ammonium salts (for example, stearyl trimethyl ammonium chloride, lauryl trimethyl ammonium chloride, etc.); alkyl pyridinium salts (for example, cetyl chloride Pyridine salt, etc.); Dialkyl dimethyl ammonium salt (such as distearyl dimethyl ammonium chloride, etc.); Chlorinated poly(N,N'-dimethyl-3,5-methylene piperidine Salt); alkyl quaternary ammonium salt; alkyl dimethyl benzyl ammonium salt; alkyl isoquinoline salt; dialkyl

Alkylamine salts; POE-alkylamines; alkylamine salts; polyamine fatty acid derivatives; pentanol fatty acid derivatives; Benzalkonium Chloride; Benzethonium Chloride; Amino acid series Cationic surfactants (for example, N-coconut oil fatty acid acyl-L-arginine ethyl-DL-pyrrolidone carboxylate) and the like.

[(C3) Amphoteric Surfactant]

Amphoteric surfactants include, for example, imidazoline (Imidazoline)-based ampholytic surfactants (e.g. 2-undecyl-N,N,N-(hydroxyethylcarboxymethyl)-2-imidazoline sodium, 2 -Coconut fat acyl-2-hydroxyl imidazoline-1-carboxyethoxy 2 sodium salt, etc.); Betaine is a surfactant (for example, 2-heptadecyl-N-carboxymethyl-N -Hydroxyethyl imidazoline betaine, lauryl dimethyl amino betaine, alkyl betaine, amido betaine, sulfobetaine, etc.).

[(C4) Hydrophilic nonionic surfactant]

Hydrophilic nonionic surfactants include, for example, POE-sorbose fatty acid esters (e.g., POE-sorbose monooleate, POE-sorbose monostearate, POE-sorbose monooleate, POE -Sorbitan tetraoleate, etc.); POE-sorbitol fatty acid esters (such as POE-sorbitol monolaurate, POE-sorbitol monooleate, POE-sorbitol pentaoleate, POE-sorbitol Monostearate, etc.); POE-glycerol fatty acid esters (such as POE-glycerol monostearate, POE-glycerol monoisostearate, POE-glycerol triisostearate, etc.); POE-monostearate Acid esters, etc.); POE-fatty acid esters (such as POE-distearate, POE-mono-dioleate, ethylene glycol distearate, etc.); POE- Alkyl ethers (such as POE-lauryl ether, POE-oleyl ether, POE-stearyl ether, POE-pyrol ether, POE-2-octyl lauryl ether, POE-cholesteryl ether, etc.); Pluronic Type (e.g. Pranick, etc.); POE/POP-alkyl ether (e.g. POE/POP-cetyl ether, POE/POP-2-decyl tetradecyl ether, POE/POP-monobutyl ether, POE/POP-hydrogenated wool Fat, POE/POP-glyceryl ether, etc.); four POE/tetra POP-ethylenediamine condensates (such as Tetronic, etc.); POE-castor oil hardened castor oil derivatives (such as POE-castor oil, POE-hardened castor oil, POE-hardened castor oil monoisostearate, POE-hardened castor oil triisostearate, POE-hardened castor oil mono-pyroglutamate monoisostearate diester, POE-hardened castor oil maleate Diacids, etc.); POE-beeswax/lanolin derivatives (such as POE-sorbitol beeswax, etc.); Alkanol amides (such as coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanol Amide, etc.); POE-propylene glycol fatty acid ester; POE-alkylamine; POE-fatty acid amide; sucrose fatty acid ester; oxyalkyl ethoxy dimethyl amine; trioleyl phosphoric acid, etc.

[(C5) Lipophilic nonionic surfactant]

Lipophilic nonionic surfactants include, for example, sorbose fatty acid esters (e.g. sorbose monooleate, sorbose monoisostearate, sorbose monolaurate, sorbose monopalmitate, sorbose Sugar monostearate, sorbose sesquioleate, sorbose trioleate, penta-2-ethylhexanoic acid diglycerol sorbose, tetra-2-ethylhexanoic acid diglycerol sorbose, etc.); Glycerol polyglycerol fatty acids (e.g. mono-cottonseed oil fatty acid glyceride, mono-erucic acid glyceride, glyceryl sesquioleate, glyceryl monostearate, α,α'-oleic acid pyroglutamate, monostearate Acid glycerol malate, etc.); propylene glycol fatty acid esters (such as propylene glycol monostearate, etc.); hardened castor oil derivatives; glycerol alkyl ethers, etc.

In the case where the detergent composition can be used in a leave-on type, from the viewpoint of low skin irritation, the surfactant is particularly preferably lauryl alkyl betaine and N-coconut oil Fatty acid-L-arginine ethyl-DL-pyrrolidone carboxylate (coconut fat arginine ethyl PCA), xylylenediammonium chloride, etc.

In the case of forming a detergent composition that can be used in the leave-in type, the content of the component (C) relative to the mass of the composition can be set to 0.02% by mass or more, 0.05% by mass or more, or 0.07% by mass or more. When the component (C) is less than 0.02% by mass, the detergency relative to the dyeing component is reduced. The content rate of the component (C) relative to the mass of the composition can be set to, for example, 0.3% by mass or less, 0.2% by mass or less, 0.15% by mass or less, or 0.1% by mass or less.

In the case of forming a detergent composition that is not used in the leave-in type, the content of the component (C) relative to the mass of the composition can be set to 1% by mass or more, 1.5% by mass or more, or 2% by mass or more. The content rate of the component (C) relative to the mass of the composition can be set to, for example, 5 mass% or less, 3 mass% or less, or 2 mass% or less.

[(D)Water]

Water used for cosmetics, quasi-drugs, etc. can be used. For example, purified water, ion exchange water, tap water, etc. can be used.

The content of the component (D) relative to the mass of the composition is preferably 20% by mass or more, particularly preferably 30% by mass or more, and more preferably 40% by mass or more. When the component (D) is less than 20% by mass, the emulsification time after shaking may become insufficient when the composition is an oil-water double-separation type. The content rate of the component (D) relative to the mass of the composition can be, for example, 80% by mass or less, 70% by mass or less, or 60% by mass or less.

[(E) Water-soluble alcohol]

Examples of water-soluble alcohols include lower alcohols, polyhydric alcohols, polyhydric alcohol polymers, dihydric alcohol alkyl ethers, dihydric alcohol alkyl ethers, dihydric alcohol ether esters, glycerol monoalkyl ethers, sugar alcohols, mono At least one of sugars, oligosaccharides, polysaccharides and their derivatives.

Examples of lower alcohols include ethanol, propanol, isopropanol, isobutanol, and tertiary butanol.

Examples of polyols include divalent alcohols (e.g., ethylene glycol, propylene glycol, propylene glycol, 1,2-butanediol, 1,3-butanediol, butylene glycol, 2,3-butanediol, Pentylene glycol, 2-butene-1,4-diol, hexylene glycol, octylene glycol, etc.); 3-valent alcohols (such as glycerol, trimethylolpropane, etc.); 4-valent alcohols (such as 1,2,6-hexanetriol, etc. (neopentylerythritol, etc.); 5-valent alcohols (such as Xylitol, etc.); 6-valent alcohols (such as sorbitol, Mannitol, etc.); multiple Alcohol polymers (for example, diethylene glycol, dipropylene glycol, triethylene glycol, polypropylene glycol, triethylene glycol, diglycerol, polyethylene glycol, triglycerol, tetraglycerol, polyglycerol, etc.); Divalent alcohol alkyl ethers (such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monophenyl ether, ethylene glycol monohexyl ether, ethylene glycol 2-methyl ether Hexyl ether, ethylene glycol isoamyl ether, ethylene glycol benzyl ether, ethylene glycol isopropyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, etc.); dihydric alcohol alkyl ether Class (such as diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol monoethyl ether Butyl alcohol, diethylene glycol methyl ethyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol isopropyl ether, dipropylene glycol Alcohol methyl ether, dipropylene glycol ethyl ether, dipropylene glycol butyl ether, etc.); 2-basic alcohol ether esters (such as ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl Ether acetate, ethylene glycol monophenyl ether acetate, ethylene glycol diadipate, ethylene glycol disuccinate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl Ether acetate, propylene glycol monomethyl ether acetic acid Ester, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, propylene glycol monophenyl ether acetate, etc.); glycerol monoalkyl ethers (such as Chimyl Alcohol, Selachyl Alcohol, Shark Batyl Alcohol, etc.); Sugar alcohols (e.g. sorbitol, maltitol, maltotriose, mannitol, sucrose, erythritol, glucose, fructose, starch decomposition sugar , Maltose, xylitol, starch decomposition sugar reducing alcohol, etc.); glycolide (Glycolide); tetrahydrofurfuryl alcohol; POE-tetrahydrofurfuryl alcohol; POP-butyl ether, POP/POE-butyl ether; tripolyoxypropylene glycerol ether ; POP-glyceryl ether; POP-glyceryl ether phosphoric acid; POP/POE-neopentyl erythritol ether, polyglycerol, etc.

Monosaccharides, for example, can be selected from three-carbon sugars (e.g. D-glyceric acid, D-dihydroxyacetone, etc.), four-carbon sugars (e.g. D-erythrose (D-Erythrose), D-erythrose (D -Erythrulose, D-Threose, D-erythritol, etc.), five-carbon sugars (such as L-Arabinose, D-Xylose), L-Lyxose (L-Lyxose), D-arabinose, D-Ribose (D-Ribose), D-Ribulose (D-Ribulose), D-Xylulose (D-Xylulose), L-wood Ketose, etc.), six carbon sugars (such as D-glucose, D-Talose, D-Psicose, D-Galactose, D-fructose, L -Galactose, L-mannose, D-Tagatose, etc.), seven-carbon sugars (e.g. Aldoheptose, Heptulose, etc.), eight-carbon sugars (e.g. octanone) Sugar (Octulose, etc.), deoxy sugars (e.g. 2-deoxy-D-ribose, 6-deoxy-L-galactose, 6-deoxy-L-mannose, etc.), amino sugars (e.g. D- Glucosamine, D-galactosamine, sialic acid, amino uronic acid, muramic acid, etc.), uronic acid (such as D-glucuronic acid (D- Glucuronic Acid), D-Mannuronic Acid (D-Mannuronic Acid), L-Guluronic Acid (L-Guluronic Acid), D-Galacturonic Acid (D-Galacturonic Acid), L-Idose At least one of L-Iduronic Acid and the like.

For example, oligosaccharides can be selected from the group consisting of sucrose, gentianose (Guntianose), umbrella sugar (Umbelliferose), lactose, plant sugar (Planteose), iso-campose (Isolychnose), α,α-cocoon At least one of sugar (α,α-Trehalose), raffinose (Raffinose), campionose, Umbilicin, Stachyose, Verbascose, etc.

Examples of polysaccharides are selected from cellulose, quince seeds (Quince Seed), chondroitin sulfate (Chondroitin Sulfate), starch, galactan (Galactan), dermatan sulfate (Dermatan Sulfate), glycogen (Glycogen), Gum Arabic, Heparan Sulfate, Hyaluronic Acid, Gum, Keratan Sulfate, Chondroitin, Xanthan Gum, Mucoitin Sulfuric Acid, Guar Gum, Grape At least one of Dextran, Keratosulfate, Locust Bean Gum, Succinoglucan, Charonic Acid, etc.

Examples of other polyols include at least one selected from polyoxyethylene methyl glyceride (Glucam E-10), polyoxypropylene methyl glyceride (Glucam P-10), and the like.

Among the above, the water-soluble alcohol is particularly preferably ethanol, butylene glycol, dipropylene glycol, etc., from the viewpoint of emulsification adjustment and corrosion resistance.

The content of the component (E) relative to the mass of the composition is preferably 2% by mass or more, particularly preferably 5% by mass or more, and more preferably 10% by mass or more. When the component (E) is less than 2% by mass, the anticorrosive power becomes insufficient. The content rate of the component (E) relative to the mass of the composition is, for example, preferably 30% by mass or less, particularly preferably 20% by mass or less, and more preferably 15% by mass or less. When the component (E) exceeds 30% by mass, the emulsification after shaking may become insufficient when the composition is an oil-water two-layer separation type.

[(F) Polyol derivatives]

The detergent composition of the first embodiment may further contain a polyol derivative. The polyol derivative can be set to at least one of a glycerin derivative and an ethylene glycol derivative.

As the glycerol derivative, for example, alkyl glycerol ether and/or glycerol ether, especially monoalkyl glycerol ether can be used. As the glycerin derivative, any of the compounds represented by the following chemical formula 6 can be used. In the chemical formula shown in Chemical Formula ⁶ , any one of R ⁴ , R ⁵ and R ⁶ can be an alkyl group, an alkenyl group or an acyl group, and the other two can be a hydrogen atom. The number of carbon atoms in the alkyl group, alkenyl group or acyl group is preferably 4 or more. When the carbon number is less than 4, a sufficient cleaning effect cannot be obtained. The number of carbon atoms in the alkyl group, alkenyl group, or acyl group is preferably 15 or less, and particularly preferably 12 or less. When the carbon number exceeds 15, a sufficient cleaning effect cannot be obtained. The alkyl group, alkenyl group, or acyl group may be linear or branched.

Examples of glycerin derivatives include ethylhexylglycerol (octyloxyglycerol), hexylglycerol, glyceryl isooctanoate, polyglycerol-2-laurate, and glycerol monocaprylate. Among them, from the viewpoint of eliminating droplets adhering to the inner surface of the container, ethylhexylglycerol having a 2-ethylhexyl group and/or hexylglycerol having a hexyl group are preferred. Examples of commercially available products of ethylhexylglycerol include Sensiva SC50 (manufactured by Schulke & Mayr).

Chemical formula 6

As the glycol derivative, for example, glycol ester and/or glycol ether can be used. As the ethylene glycol derivative, for example, propylene glycol fatty acid ester and/or propylene glycol ether, especially propylene glycol mono fatty acid ester can be used. The ethylene glycol derivative can be a compound represented by Chemical Formula 7. In the chemical formula shown in chemical formula 7, one of R ⁷ and R ⁸ can be an alkyl group, alkenyl group or acyl group with 10 to 20 carbons, the others can be hydrogen atoms, and R ⁹ can be carbon Alkyl group, alkenyl group, acyl group or hydrogen atom of number 1 to 4. The alkyl group, alkenyl group, or acyl group may be linear or branched.

Examples of ethylene glycol derivatives include propylene glycol laurate, propylene glycol stearate, and propylene glycol isostearate.

Chemical formula 7

The glycerin derivative and the glycol derivative may exist in either the oil phase or the water phase.

The component (F) can suppress the remaining of the droplets attached to the inner surface of the container by the detergent composition. For example, especially when the detergent composition is an oil-water two-layer liquid, the droplets adhering to the inner surface of the transparent container above the liquid can be prevented from being seen through, and the appearance of the product can be improved.

When the detergent composition is an oil-water two-layer type, the component (F) also has a clear separation of the oil phase and the water phase when the oil phase and the water phase are re-separated by standing after temporary emulsification. The role of phase interface. This can further improve the appearance of the oil-water separation composition seen through the container.

When the detergent composition has an oil-water double layer structure and the oil-soluble component (A) is blended in the water phase, the component (F) can improve the stability of the detergent composition after temporary emulsification. In addition, glycerin derivatives can improve the detergency of the detergent composition.

The content of the component (F) relative to the mass of the composition is preferably 0.06% by mass or more, particularly preferably 0.07% by mass or more, and more preferably 0.08% by mass or more. The content of polyol derivatives can be set to 0.1% by mass or more, 0.2% by mass or more, or 0.5% by mass relative to the mass of the composition Above mass%. When the polyol derivative is less than 0.06% by mass, the above-mentioned effects cannot be sufficiently obtained. The content of the component (F) relative to the mass of the composition is preferably 1.8% by mass or less, particularly preferably 1.5% by mass or less, and more preferably 1.2% by mass or less. The content of the polyol derivative relative to the mass of the composition can be 1% by mass or less, 0.8% by mass or less, or 0.5% by mass or less. When the polyol derivative exceeds 1.8% by mass, the interface between the oil phase and the water phase becomes unclear.

[(G) Salt]

When the detergent composition of the first embodiment contains water or an aqueous phase, it may further contain a salt. In particular, when the detergent composition is formed into an oil-water double layer type, the detergent composition preferably contains a salt. The re-separation speed after temporary emulsification can be adjusted by adding salt.

The component (G) may be an inorganic salt or an organic salt as long as it has low irritation to the skin. Examples of the component (G) include sodium chloride, potassium chloride, sodium citrate, and sodium edetate.

The content of the component (G) relative to the mass of the composition is preferably 0.1% by mass or more, more preferably 0.2% by mass or more, and more preferably 0.3% by mass or more. When the component (G) is less than 0.1% by mass, the above-mentioned effects cannot be sufficiently obtained. The content rate of the component (G) relative to the mass of the composition is preferably 2% by mass or less, particularly preferably 1.5% by mass or less, and more preferably 1% by mass or less. When the component (G) exceeds 2% by mass, when the composition is an oil-water two-layer separation type, emulsification after shaking becomes insufficient.

[(H)Other]

The detergent composition of the present disclosure may optionally contain other ingredients such as powders, moisturizers, water-soluble polymers, thickeners, film coating agents, UV absorbers, sequestering agents, amino acids, organic amines, polymer emulsions, pH adjusters, skin nutrients, vitamins, antioxidants, antioxidant adjuvants, fragrances, etc.

The term "powder" used in this manual has the same meaning as "powder". The powder is not particularly limited as long as it can be used by general users such as cosmetics. As the powder, for example, inorganic powders (such as talc, kaolin, mica, sericite), muscovite, phlogopite, synthetic mica, red mica, biotite, lepidolite, fired mica, fired Talc, Vermiculite, magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, zeolite, glass, sulfuric acid Barium, calcined calcium sulfate (calcined gypsum), calcium phosphate, fluoroapatite, hydroxyapatite, ceramic powder, metal soap (e.g. zinc myristate, calcium palmitate, aluminum stearate), boron nitride, etc. ); organic powder (such as polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, benzoguanamine (Benzoguanamine) Resin powder, polytetrafluoroethylene powder, cellulose powder, silicone powder, silk powder, wool powder, urethane powder, etc.); inorganic white pigments (such as titanium dioxide, zinc oxide, etc.); inorganic red pigments (such as Iron oxide (red lead), iron titanate, etc.); inorganic brown pigments (γ-iron oxide, etc.), inorganic yellow pigments (yellow iron oxide, loess, etc.), inorganic black pigments (black iron oxide, carbon black, etc.) Titanium oxide, etc.), inorganic purple pigments (such as manganese violet, cobalt violet, etc.); inorganic green pigments (such as chromium oxide, chromium hydroxide, cobalt titanate, etc.); inorganic blue pigments (such as ultramarine, indigo, etc.) Etc.); pearl pigments (such as titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil, etc.) ; Metal powder pigments (such as aluminum powder, copper powder, etc.), zirconium, barium or aluminum lake pigments and other organic pigments (such as red 201, red 202, red 204, red 205, red 220, red 226 number, Red No. 228, Red No. 405, Orange No. 203, Orange No. 204, Yellow No. 205, Yellow No. 401, Blue No. 404 and other organic pigments, Red No. 3, Red No. 104, Red No. 106, Red No. 227, Red 230, red 401, red 505, orange 205, yellow 4, yellow 5, yellow 202, yellow 203, green 3, blue 1, etc.); natural pigments (such as chlorophyll, carotene) and many more.

The humectant can include, for example, polyethylene glycol, propylene glycol, glycerin, 1,3-butanediol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucopolysaccharide sulfate, polysaccharides, and end Peptide collagen (Atelocollagen), cholesterol hydroxystearate-12-ester, sodium lactate, bile acid salt, dl-pyrrolidone carboxylate, alkylene oxide derivatives, short-chain soluble collagen, diglycerol (EO) PO Adducts, reeling flower extracts, yarrow extracts, clover extracts, etc.

Examples of natural water-soluble polymers include plant-based polymers (such as gum arabic, gum, galactan, guar gum, locust bean gum, karaya gum, carrageenan). (Carrageenan), pectin (Pectin), Chinese cabbage, quince seeds (quinces), alginate (brown algae extract), starch (rice, corn, potato, wheat), glycyrrhizin); microbial macromolecule ( For example, xanthan gum, dextran, succinate glucan, pullulan, etc.); animal-based polymers (such as collagen, casein, albumin, gelatin, etc.).

Examples of semi-synthetic water-soluble polymers include starch-based polymers (such as carboxymethyl starch, methyl hydroxypropyl starch, etc.); cellulose-based polymers (such as methyl cellulose, ethyl cellulose, methyl Hydroxypropyl cellulose, hydroxyethyl cellulose, sodium cellulose sulfate, hydroxypropyl cellulose, carboxymethyl cellulose, sodium carboxymethyl cellulose, crystalline cellulose, cellulose powder, etc.); high alginic acid Molecules (for example (sodium alginate, propylene glycol alginate, etc.), etc.

Synthetic water-soluble polymers include, for example, vinyl polymers (such as polyvinyl alcohol, polyvinyl methyl ether, polyvinylpyrrolidone, carboxyvinyl polymers, etc.); polyoxyethylene polymers (such as polyethylene Polyoxyethylene polyoxypropylene copolymers of 20,000, 40,000, 60,000 diols, etc.); acrylic polymers (such as sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.); polyethylene imine; cationic polymers, etc. .

Examples of the thickener include gum arabic, carrageenan, gum, locust bean gum, quince seeds (quince), casein, dextrin (Dextrin), gelatin, pectic acid, sodium alginate, and methyl fiber Cellulose, ethyl cellulose, carboxymethyl cellulose (CMC: Carboxymethyl Cellulose), hydroxyethyl cellulose, hydroxypropyl cellulose, polyvinyl alcohol (PVA: Polyvinyl Alcohol), polyvinyl methyl ether (PVM: Polyvinyl Methylether) ), PVP (Polyvinyl Pyrrolidone), sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, tamarind gum (Tamarind Gum), dialkyl dimethyl ammonium sulfate fiber Vegetarian, Xanthan Gum, Magnesium Aluminum Silicate, Bentonite, Hectorite, Magnesium Aluminum Silicate (Veegum), Laponite, Anhydrous Silicic Acid, Taurine Series Synthetic polymers, acrylic synthetic polymers, etc.

Examples of the coating agent include anionic coating agents (e.g. (meth)acrylic acid/(meth)acrylate copolymer, methyl vinyl ether/maleic anhydride copolymer, etc.), cationic coating agents ( For example, cationized cellulose, dimethyl diallyl ammonium chloride polymer, dimethyl diallyl ammonium chloride/acrylamide copolymer, etc.), non-ionic coating agents (such as polyvinyl alcohol, Polyvinylpyrrolidone, polyvinyl acetate, polyacrylate copolymer, (meth)acrylamide, polymer polysiloxane, polysiloxane resin, trimethylsiloxysilicic acid, etc.).

啉噠嗪(Dimorpholinopyridazinone)；丙烯 酸2-乙基己基-2-氰基-3,3-二苯酯；2,4-雙-{[4-(2-乙基己氧基)-2-羥基]-苯基}-6-(4-甲氧基苯基)-(1,3,5)-三嗪等。 Examples of ultraviolet absorbers include benzoic acid-based ultraviolet absorbers (for example, p-aminobenzoic acid (hereinafter referred to as PABA), PABA monoglyceride, N,N-dipropoxy PABA ethyl ester, N,N-di Ethoxy PABA ethyl ester, N,N-dimethyl PABA ethyl ester, N,N-dimethyl PABA butyl ester, N,N-dimethyl PABA ethyl ester, etc.); Anthranilic Acid (Anthranilic Acid) UV absorbers (for example, allo-menthol-N-anthranilate acetyl ester, etc.); salicylic acid UV absorbers (for example, amyl salicylate, menthol salicylate, menthol salicylate , Octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate, etc.); cinnamic acid UV absorbers (such as octyl methoxy cinnamic acid, ethyl 4-iso cinnamic acid Propyl ester, methyl-2,5-diisopropyl cinnamic acid, ethyl-2,4-diisopropyl cinnamic acid, methyl-2,4-diisopropyl cinnamic acid, propyl cinnamic acid Methoxy ester, isopropyl p-methoxy cinnamic acid, isoamyl p-methoxy cinnamic acid, octyl p-methoxy cinnamic acid (2-ethylhexyl p-methoxy cinnamic acid), 2-ethyl cinnamic acid P-methoxy ethyl p-methoxy ester, p-methoxy cyclohexyl cinnamic acid ester, ethyl-α-cyano-β-phenyl cinnamic acid ester, 2-ethylhexyl-α-cyano-β-phenyl cinnamic acid ester , Cinnamic acid glycerol mono-2-ethylhexyl di-p-methoxy ester, etc.); Benzophenone UV absorbers (such as 2,4-dihydroxydiphenyl ketone, 2,2'- Dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2,2',4,4'-tetrahydroxydiphenyl Ketone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone- 5-sulfonate, 4-phenyldiphenylketone, 2-ethylhexyl-4'-phenyl-diphenylketone-2-carboxylate, 2-hydroxy-4-n-octyloxydiphenyl Ketone, 4-hydroxy-3-carboxydiphenyl ketone, etc.); 3-(4'-methylbenzylidene)-d,l-camphor, 3-benzylidene-d,l-camphor; 2- Phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5-methylphenylbenzotriazole;2-(2'-hydroxy-5'-tertiary octylphenyl)benzo Triazole; 2-(2'-hydroxy-5'-methylphenyl) benzotriazole; Dibenzalazine; Dianisoylmethane; 4-Methoxy -4'-tertiary butyl dibenzyl methane; 5-(3,3-dimethyl-2-norbornylidene)-3-benzene-2-one, two

Dimorpholinopyridazinone; 2-ethylhexyl-2-cyano-3,3-diphenyl acrylate; 2,4-bis-{[4-(2-ethylhexyloxy)-2-hydroxyl ]-Phenyl}-6-(4-methoxyphenyl)-(1,3,5)-triazine and the like.

The chelating agent includes, for example, 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate, and Tetrasodium oleate, sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, edetic acid, trisodium ethylenediamine hydroxyethyl triacetate, etc.

Examples of the amino acid include neutral amino acids (for example, threonine, cysteine, etc.); basic amino acids (for example, hydroxylysine, etc.). In addition, the amino acid derivatives include, for example, sodium sarcosine (sodium lauryl sarcosine), glutamate, sodium β-alanine, glutathione (Glutathione), Pyrrolidone carboxylic acid, etc.

啉(Morpholine)、三異丙醇胺、2-胺基-2-甲基-1,3-丙二醇、2-胺基-2-甲基-1-丙醇等。 Examples of organic amines include monoethanolamine, diethanolamine, triethanolamine,

Morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-methyl-1-propanol, etc.

Examples of the polymer emulsion include acrylic resin emulsion, polyethyl acrylate emulsion, acrylic resin liquid, polyalkyl acrylate emulsion, polyvinyl acetate resin emulsion, natural rubber latex, and the like.

Examples of pH adjusters include buffers such as lactic acid-sodium lactate, citric acid-sodium citrate, and succinic acid-sodium succinate.

Examples of vitamins include vitamins A, B1, B2, B6, C, E and their derivatives, pantothenic acid and its derivatives, and biotin.

Examples of antioxidants include Toeopherols, dibutylhydroxytoluene, butylhydroxymethoxybenzene, and gallic acid esters.

Examples of antioxidant adjuvants include phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, cephalin (Kephalin), hexametaphosphate, phytic acid (Phytin) , Ethylenediaminetetraacetic acid, etc.

Other adjustable ingredients include, for example, preservatives (such as ethyl p-hydroxybenzoate, butyl p-hydroxybenzoate, Chlorphenesin, phenoxyethanol, etc.); anti-inflammatory agents (such as glycyrrhizin derivatives) , Glycyrrhizic acid derivatives, salicylic acid derivatives, juniper alcohol, zinc oxide, allantoin (Allantoin, etc.); whitening agents (such as placental extract, saxifrage extract, arbutin, etc.); various extracts (E.g. yellow leaves, Japanese coptis, comfrey, peony, Chinese medicine, birch, sage, loquat, radish, aloe vera, mallow, iris, grape, coix, loofah, lily, saffron, chuanxiong, ginger, small Forsythia, formononet, garlic, pepper, tangerine peel, angelica, seaweed, etc.), activators (such as royal jelly, photosensitizer, cholesterol derivatives, etc.); blood promoting agents (such as nonanoic acid vanillyl amide, nicotine benzyl Ester, β-butoxyethyl nicotinic acid, Capsaicin, Zingerone, Cantharis tincture, Ichthammol, tannic acid, α-Borneol , Tocopherol nicotinate, inositol hexanicotinate, Cyclandelate, anticoagulant antagonist (Cinnarizine), benzimidazoline (Tolazoline), acetylcholine, verapamil (Verapamil) ), Cepharanthine (Cepharanthine), γ-Oryzanol (γ-Oryzanol, etc.); Anti-liporrhea agents (such as sulfur, Thianthol, etc.); Anti-inflammatory agents (such as Tranexamic acid ( Tranexamic acid), Thiotaurine (Thiotaurine), Hypotaurine (Hypotaurine), etc.).

Furthermore, the composition of the present disclosure may also contain caffeine, tannins, verapamil, tranexamic acid and its derivatives, licorice, papaya begonia, Japanese buckwheat and other crude drug extracts, acetic acid Phenol, glycyrrhizic acid, glycyrrhizin and its derivatives or salts and other pharmaceuticals, life support Vitamin C, magnesium ascorbyl phosphate, ascorbyl glucoside, arbutin, kojic acid and other whitening agents, arginine, lysine and other amino acids and their derivatives.

[Phase Composition]

The detergent composition of the first embodiment can adopt a desired phase composition according to the purpose and/or application. The detergent composition may take the form of an aqueous composition, an oily composition, an oil-in-water composition, an oil-in-water composition, a bi-continuous composition, an oil-water separation composition, a fatty acid soap composition, and the like.

The oil-water separation type composition has a two-layer structure in which the oil phase and the water phase are separated vertically in a static state. Since the oil-water separation type composition can increase the blending amount of oily components, it can improve the detergency. Due to the presence of the water phase, the feeling of use can be improved. In addition, since the blending amount of surfactant can be reduced, it can be used without washing (wiping off). In the case of the oil-water two-layer separation type, the mass ratio of the water phase to the oil phase is preferably 0.25 or more for the water phase relative to the oil phase 1, more preferably 0.5 or more, and more preferably 1 or more. When the mass ratio of the water phase is less than 0.25, the refreshing feeling during use will be impaired. The mass ratio of the water phase to the oil phase is preferably 4 or less for the water phase relative to the oil phase 1, particularly preferably 2.5 or less, and more preferably 2 or less. When the mass ratio of the water phase exceeds 4, the component (A) will precipitate and the transparency will decrease.

[pH]

In the case where the detergent composition of the first embodiment has an aqueous phase, the pH of the aqueous phase is preferably 5 or more, and particularly preferably 5.5 or more. When the pH is less than 5, the component (A) is likely to precipitate and the transparency is reduced. The pH of the water phase is preferably 8 or less, and particularly preferably 7.5 or less. When the pH exceeds 8, the skin irritation will increase.

[Exterior]

The detergent composition of the first embodiment can have high transparency. Thereby, the detergent composition can be put into a transparent container and used. When a transparent container can be used, for example, when the detergent composition is an oil-water separation type, the emulsified state formed by the shaking operation can be confirmed visually.

When the detergent composition is an oil-water two-layer separation type, it can form a composition in which neither the water phase nor the oil phase is turbid and the interface between the water phase and the oil phase is clear.

[Cleaning property]

Next, the detergency of the detergent composition of the present disclosure will be explained. The detergent composition of the first embodiment can be preferably applied to, for example, cosmetic remover detergent, hand soap, body wash, shampoo, kitchen detergent, and the like.

The detergent composition of the present disclosure can be used as a detergent for washing off dyes (for example, acid dyes) colored on the skin. For example, the detergent composition of the present disclosure can be formed into a detergent suitable for dyeing cosmetics. Acid dyes (anionic dyes) are generally used as dyes in dyeing cosmetics. Acid dyes are believed to form bonds with skin proteins through chemical interactions (such as ionic interactions). The detergent composition of the present disclosure has a high detergency relative to this type of acid dye by blending component (A).

The detergent composition of the present disclosure can be formed as a detergent used for rinsing with water, or can be formed as a type of detergent used without rinsing with water (no-wash type). In the case of a no-clean type, for example, the detergent composition can be applied or dripped on the object to be cleaned (such as skin), etc., and then wiped off with toilet paper or cotton cotton and other fibers to complete the cleaning. . In addition, the cleansing object (for example, skin) can be wiped with the fibrous body impregnated with the detergent composition to remove the removed components. Even in the case of washing away the dye from the skin as described above (for example, washing away dyed cosmetics Under circumstances), it can also be used in a disposable type. For example, coconut oil amphoteric sodium acetate has cleansing properties relative to dyed cosmetics, but because it is highly irritating to the skin, it must be rinsed with water when washing the dyed cosmetics. If it is the detergent composition of the present disclosure, it can be applied to a leave-in detergent that can be applied to dyed cosmetics.

The detergent composition of the present disclosure can be used as a detergent for washing off waterproof oily cosmetics (such as mascara) by formulating component (B). The detergent composition of the present disclosure can be applied to a detergent for washing away dyed cosmetics and waterproof cosmetics with one wash. In addition, the detergent composition of the present disclosure can be applied to a disposable detergent that washes away dyed cosmetics and waterproof cosmetics with one wash.

[Instructions]

In the case where the detergent composition of the first embodiment is a two-layer separation of oil and water, the container can be shaken to form a temporary emulsified state (including an emulsified virtual state) before being pressed out of the container, and then pressed out of the container to wash剂组合物。 Agent composition.

The number of oscillations of the container for forming an emulsified state is preferably, for example, 20 times or less, more preferably 15 times or less, and more preferably 10 times or less. The temporary emulsification state formed by the shaking operation preferably lasts for a certain period of time. For example, the temporary emulsification state preferably lasts for 10 seconds or more, preferably for 15 seconds or more, and more preferably for 20 seconds or more. In addition, in the case of returning to the oil-water double-separated state from the temporary emulsified state by standing, the detergent composition preferably has transparency without causing white turbidity. In addition, the interface between the oil phase and the water phase is preferably clear.

[Manufacturing method]

Next, the manufacturing method of the detergent composition of this disclosure will be described. The detergent composition of the present disclosure is not limited to a specific method, and can be produced by generally known methods. For example, The above components are mixed to prepare a detergent composition. When the component (A) is oil-soluble, the component (A) can be dissolved in the component (B) to produce a detergent composition. When component (A) is water-soluble, component (A) can be dissolved in component (D) and/or component (E) to produce a detergent composition.

In the detergent composition of the present disclosure, the phase structure and the like are sometimes difficult to be directly specified by the composition or generally impractical. In this case, the detergent composition of the present disclosure should allow the detergent composition to be specified by the manufacturing method.

[Example]

The following series of examples illustrate the detergent composition of the present disclosure. However, the detergent composition of the present disclosure is not limited to the following examples. In addition, in the following examples, examples of applying the detergent composition of each test example to the washing of cosmetics are described, but the composition of the present disclosure is not limited to cosmetics. The unit of the content rate of each component shown in each table is mass%.

[Test Examples 1 to 4]

First, an oil-water two-layer separation type detergent composition was made, and the detergency, appearance, and stability were tested. As the component (A), decyltetradecyl dimethylamine oxide is used, and this is formulated in the water phase. The composition and results in each test example are shown in Table 1.

In each test example, the oil phase and the water phase were prepared separately and then the two were mixed to prepare an oil-water double-layer detergent composition. The oil phase and the water phase shown in the following table show the phases in which each component is blended during the preparation of the detergent composition. Therefore, it is mentioned here that during shaking treatment and/or standing still, there is a possibility that the components formulated in the oil phase move to the water phase and/or the components formulated in the water phase move to the oil phase.

[Compared to the detergency of dyed cosmetics]

A color difference meter (Nippon Denshoku Corporation Spectrophotometer SE7700) was used to measure the L*a*b* color space of the inner arm part coated with the dyed cosmetic. The value of a* at this time is described as a(Base). Then, on the part where the color space is measured, the dyed cosmetics are applied to the inner wrist and left for 20 minutes to dye the skin. Wipe off excess dyed cosmetics. Dyed cosmetics are dyed cosmetics containing tetrafluorotetrabromofluorescent yellow as acidic cosmetics. Measure the L*a*b* color space of the part dyed with dyed cosmetics. The value of a* at this time is described as a(Blank). After the oil-water two-layer separation type detergent composition of each test example was formed into an emulsified state, the cotton sheet impregnated with 1g of the detergent composition was used to form a dyed cosmetic and waterproof mascara with a uniform force. Wipe 20 times on the colored part. After wiping off the detergent composition, the L*a*b* color space of the colored part after washing is measured. The a* value at this time is described as a(Sample). The detergency of the detergent composition of each test example was evaluated by the detergency (%) calculated from the following formula. The calculation formula and evaluation criteria of the cleaning rate are as follows.

[Number 1]

A: The cleaning rate is over 90%;

B: The cleaning rate is over 75% and less than 90%;

C: The cleaning rate is over 60% and less than 75%;

D: The cleaning rate is over 45% and less than 60%;

E: The cleaning rate is less than 45%.

[Compared to the detergency of waterproof mascara]

The coating and washing system of waterproof mascara is the same as that of dyed cosmetics. The cleansing property of waterproof mascara is confirmed by visually observing whether there is any cosmetic color remaining on the wrist. The cleansing property of waterproof mascara is judged by the following criteria.

A: Fully remove waterproof mascara;

B: Most of the waterproof mascara is removed;

C: A small amount of waterproof mascara remains;

D: Most of the waterproof mascara remains.

[Appearance and emulsification]

[Standing state before oscillation]

Put the produced oil-water two-layer separation type detergent composition into a transparent polyester container. Before shaking, in the state of allowing the container to stand still, confirm the state of the interface between the oil phase and the water phase and the transparency of each phase with the following criteria.

A: The interface between the oil phase and the water phase is clear and each phase does not produce turbidity;

B: The interface between the oil phase and the water phase is not clear or any phase is slightly turbid;

C: Turbidity in any phase;

D: A precipitate is produced.

[Oscillation emulsification state]

In the state where the oil phase and the water phase are separated into two layers, shake the container in the vertical direction 8 times by hand to emulsify the oil and water phases, and confirm the continuity of the emulsified state by the following criteria.

A: The duration of the emulsified state is more than 10 seconds;

B: The duration of the emulsified state is less than 10 seconds.

[Standing state after shaking]

After shaking treatment, the detergent is allowed to stand for 3 hours and/or 24 hours, and the presence or absence of turbidity in the oil phase and the water phase is confirmed by the following criteria.

A: Neither the oil phase nor the water phase is turbid;

B: Turbidity occurred in either of the oil phase and the water phase.

[stability]

The detergent was allowed to stand at each temperature of 0°C, room temperature, and 50°C to a temperature equilibrium state, and the stability of the detergent was confirmed by the following criteria.

A: There is no turbidity in the oil phase and the water phase, and the double layer state can be maintained;

B: The water or oil phase is turbid;

C: A precipitate is generated or the third layer appears.

The detergent composition of Test Example 1 which does not contain the component (A) has low detergency with respect to dyed cosmetics. However, in Test Examples 2 to 4 in which the component (A) was added, the cleansing property with respect to color cosmetics was improved. Therefore, it is considered that the effect of the component (A) in washing off the dye attached to the skin is high. In addition, it was confirmed that the cleansing composition of Test Examples 2 to 4 also had high cleansing properties compared to the waterproof mascara, which is an oil-based cosmetic.

In Test Examples 2 to 4, it was confirmed that the temporary emulsification state formed by the shaking treatment lasted for more than 10 seconds. In addition, in Test Examples 3 and 4, it was confirmed that by leaving the detergent composition in a temporarily emulsified state at rest, the oil phase and the water phase were completely separated, and neither layer had white turbidity and transparency. However, in Test Example 2, the generation of precipitates was confirmed during re-separation. Therefore, it is considered that when the oil-soluble component (A) is blended in the water phase, it is preferable to increase the blending amount of the component (E) and/or the blending component (F).

The detergent compositions of Test Examples 2 to 4 can be used as a leave-in type.

[Table 1]

[Test Examples 5 to 6]

In Test Examples 1 to 4, the component (A) was blended in the water phase, but in the oil-water double separation type detergent compositions of Test Examples 5 to 6, the component (A) was blended in the oil phase. In Test Example 5, the component (C) was blended in the oil phase, and in Test Example 6, the component (C) was blended in the water phase. The test method and evaluation criteria are the same as those of Test Examples 1 to 4. The composition and results in each test example are shown in Table 2.

In either of Test Examples 5 and 6, it showed good cleansing properties with respect to both dyed cosmetics and oily cosmetics. In addition, in any of Test Examples 5 and 6, there were no problems in appearance, emulsification, and stability. From this, it is known that the component (A) can be formulated in the oil phase. In addition, it is thought that the component (C) may be formulated in either the oil phase or the water phase. However, in Test Example 6, the water phase tends to become slightly blurred at low temperatures, so it is considered that the component (C) is particularly preferably formulated in the water phase.

The detergent compositions of Test Examples 5 and 6 can be used as a leave-in type.

[Table 2]

[Test Examples 7 to 9]

In the oil-water two-layer separation type detergent composition of Test Examples 7 to 9, the content rate of the component (A) was changed. The test method and evaluation criteria are the same as those of Test Examples 1 to 4. The composition and results in each test example are shown in Table 3.

Any of the compositions of Test Examples 7 to 9 had sufficient cleansing properties with respect to dyed cosmetics. Compared with Test Example 7, Test Examples 8 and 9 can confirm the improvement of the detergency with respect to dyed cosmetics. Therefore, it is considered that the content of the component (A) relative to the mass of the composition is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, and more preferably 0.15% by mass or more.

The detergent compositions of Test Examples 7 to 9 can be used as a leave-in type.

[Table 3]

[Test Examples 10 to 11]

In the oil-water two-layer separation type detergent composition of Test Examples 10 to 11, the content of component (E), especially the content of ethanol, was changed to confirm the effect on stability. The test method and evaluation criteria are the same as those of Test Examples 1 to 4. The composition and results in each test example are shown in Table 4.

In any of the test examples 10 to 11, stability did not cause problems. Therefore, it is considered that the content rate of the component (E) relative to the mass of the composition can be 2% by mass or more, 4% by mass or more, 6% by mass or more, or 8% by mass or more.

The detergent compositions of Test Examples 10 and 11 can be used as a leave-in type.

[Table 4]

[Test Examples 12 to 13]

In the oil-water two-layer separation type detergent composition of Test Examples 12 to 13, the content of component (C), especially the content of component (C3) was changed to confirm the effect on stability. The test method and evaluation criteria are the same as those of Test Examples 1 to 4. The composition and results in each test example are shown in Table 5.

In any of Test Examples 12 to 13, there was no problem with stability. Therefore, it is considered that the content of the component (C) relative to the mass of the composition can be set to 0.02% by mass or more, 0.03% by mass or more, 0.05% by mass or more, 0.07% by mass or more, or 0.1% by mass or more.

The detergent compositions of Test Examples 12 and 13 can be used as a leave-in type.

[Table 5]

[Test Examples 14 to 15]

In the oil-water two-layer separation type detergent composition of Test Examples 14 to 15, the content of component (G) was changed to confirm the effect on stability. The test method and evaluation criteria are the same as those of Test Examples 1 to 4. The composition and results in each test example are shown in Table 6.

In any of Test Examples 14 to 15, stability problems did not arise. Therefore, it is considered that the content of the component (G) can be set to 0.1% by mass or more, 0.2% by mass relative to the mass of the composition. Mass% or more, 0.4 mass% or more, 0.6 mass% or more, 0.8 mass% or more, or 1 mass% or more.

The detergent compositions of Test Examples 14 and 15 can be used as a leave-in type.

[Table 6]

[Test Examples 16 to 23]

In the oil-water two-layer separation type detergent composition of Test Examples 16 to 23, the content of the pH buffer was changed in component (H), that is, the pH of the water phase was changed to confirm the effect on stability. test The test methods and evaluation criteria are the same as those of Test Examples 1 to 4. The composition and results in each test example are shown in Table 7 and Table 8.

When the pH of the water phase is lowered, precipitates are easily generated. In addition, the stability at low temperatures is also reduced. Therefore, it is considered that the pH of the water phase is preferably 5 or more, and particularly preferably 5.5 or more.

The detergent compositions of Test Examples 16 to 23 can be used as a leave-in type.

[Table 7]

[Table 8]

[Test Examples 24 to 28]

In the oil-water two-layer separation type detergent composition of Test Examples 24 to 28, the compounding amount of the component (A) was changed and the detergency with respect to dyed cosmetics was tested. The ingredient (A) is added to the from phase. The evaluation method and evaluation criteria of detergency are the same as those of Test Examples 1 to 4. The composition and results in each test example are shown in Table 9.

Compared with Test Example 1 in which the component (A) was not added, in Test Example 24 in which 0.02% by mass of the component (A) was blended, a significant improvement in detergency was observed. In addition, in Test Examples 25 to 28, when the blending amount of the component (A) was increased, further improvement in detergency was observed. Therefore, it is considered that the blending amount of the component (A) is preferably 0.01% by mass or more relative to the mass of the detergent composition. It is particularly preferably 0.02 mass% or more, particularly preferably 0.03 mass% or more, particularly preferably 0.05 mass% or more, particularly preferably 0.08 mass% or more, particularly preferably 0.1 mass% or more, particularly preferably 0.12 mass% or more, particularly preferably It is 0.15% by mass or more, more preferably 0.18% by mass or more.

Referring to Test Examples 2 to 4 in which the component (A) is blended in the water phase, high detergency can be obtained regardless of whether the component (A) is blended in either the water phase or the oil phase.

The detergent compositions of Test Examples 24 to 28 can be used as a leave-in type.

[Table 9]

[Test Examples 29 to 31]

In Test Examples 1 to 28, the oil-water two-layer separation type detergent composition was made, but in Test Examples 29 to 31, the water-based detergent composition (clean water) was made to cleanse the dyeing cosmetics. Sexually test. The evaluation method of detergency is in addition to directly impregnating the detergent composition in the cotton sheet. Otherwise, the same as Test Examples 1 to 4. The evaluation criteria are the same as in Test Examples 1 to 4. The composition and results in each test example are shown in Table 10.

Compared with the test example 29 in which the component (A) was not added, test examples 30 and 31 in which the component (A) was added had higher cleansing properties with respect to the color cosmetics. From this, it turns out that even if the component (A) is in an aqueous detergent composition, it can improve the detergency with respect to a color cosmetics. In addition, when the addition amount of the component (A) was increased, the improvement in detergency was confirmed.

The detergent compositions of Test Examples 30 and 31 can be used as a leave-in type.

[Table 10]

[Test Examples 32 to 39]

In Test Examples 32 to 39, an oil-in-water type detergent composition was produced and the detergency against dyed cosmetics was tested. The compositions of Test Examples 32 and 33 are cleansing gels. The compositions of Test Examples 34 to 36 are emulsion types. The compositions of Test Examples 37 to 39 are cream type. The method of evaluating the detergency is to apply the detergent composition directly to the colored part and wipe it by hand for 20 times. Except for the water-rinsing detergent composition, the others were the same as those of Test Examples 1 to 4. The evaluation criteria are the same as in Test Examples 1 to 4. The composition and results in each test example are shown in Table 11 to Table 13.

In Test Examples 32, 34, and 37 where the component (A) was not added, the cleansing properties of the dyed cosmetics were very low. However, when ingredient (A) is added, an improvement in detergency relative to dyed cosmetics can be observed. From this, it was found that even in the oil-in-water detergent composition, the component (A) can improve the detergency with respect to dyed cosmetics. In addition, when the addition amount of the component (A) was increased, the improvement in detergency was confirmed.

The detergent compositions of Test Examples 33, 35, and 36 can be used as a leave-in type.

[Table 11]

[Table 12]

[Table 13]

[Test Examples 40 to 43]

In Test Examples 40 to 43, a composition that can be regarded as a fatty acid soap formed was produced, and the detergency with respect to dyed cosmetics was tested. The method of evaluating the detergency is to foam the detergent composition, apply it to the colored part, wipe the detergent composition with water 20 times, and rinse the detergent composition with water. Other than that, the others are the same as those in Test Examples 1 to 1 4 is the same. The evaluation criteria are the same as in Test Examples 1 to 4. The composition and results in each test example are shown in Table 14 to Table 15.

In Test Examples 40 and 42, where the component (A) was not added, the cleansing properties of the dyed cosmetics were low. However, when ingredient (A) is added, the detergency compared to dyed cosmetics can be observed Improvement. From this, it was found that the component (A) can add the cleansing properties of the color cosmetics to the cleansing properties of the fatty acid soap.

[Table 14]

[Table 15]

[Test Examples 44 to 45]

In Test Examples 44 to 45, a dual-continuous (oil phase and water phase continuous phase) type detergent composition (cleansing liquid) was produced, and the detergency against dyed cosmetics was tested. The method of evaluating the detergency is the same as in Test Examples 32 to 39. The evaluation criteria are the same as in Test Examples 1 to 4. The composition and results in each test example are shown in Table 16.

The test examples 44 and 45 in which the component (A) was added had high cleansing properties relative to color cosmetics. From this, it was found that even in a bi-continuous composition, the component (A) can improve the detergency with respect to the color cosmetics.

[Table 16]

[Test Examples 46 to 47]

In Test Examples 46 to 47, oil-based detergent compositions (cleansing oils) were prepared, and the detergency against dyed cosmetics was tested. The method of evaluating the detergency is the same as in Test Examples 32 to 39. The evaluation criteria are the same as in Test Examples 1 to 4. The composition and results in each test example are shown in Table 17.

The test examples 46 and 47 in which the component (A) was added had high cleansing properties relative to color cosmetics. From this, it was found that even in the oil-based detergent composition, the component (A) can improve the detergency with respect to dyed cosmetics.

[Table 17]

[Test Examples 48 to 58]

The carbon number of the alkyl group in the component (A) was changed and the detergency test against the color cosmetics was performed. In Test Examples 48 to 50, decyltetradecyl dimethylamine oxide in which one of the alkyl groups in the above chemical formula 4 is decyl tetradecyl dimethyl amine was used as the component (A). In Test Examples 51 to 53, lauryl dimethylamine oxide in which one of the alkyl groups in the chemical formula 4 is dodecyl (lauryl) is used as the component (A'). In Test Examples 54 to 56, stearyl dimethylamine oxide in which one of the alkyl groups in the above chemical formula 4 is octadecyl (stearyl) is used as the component (A'). In Test Example 57, an ethylenediamine compound was used instead of component (A) and the same test was performed. In Test Example 58, neither of the component (A) nor the ethylenediamine compound was added. The compositions of Test Examples 48 to 58 are oil-water double-separation type detergent compositions. The evaluation method and evaluation criteria of detergency are the same as those of Test Examples 1 to 4. The composition and results in each test example are shown in Table 18 to Table 19.

In Test Examples 51 to 56 in which the component (A') with a short alkyl group was used, compared with Test Example 58 in which the component (A') was not added, an improvement in detergency was observed. However, when the amount of addition is small, the detergency will decrease. In order to improve the detergency, the addition amount of the component (A') must be increased. On the other hand, according to Test Examples 48 to 50 using the component (A) with a longer alkyl group, even if the amount of the component (A) added is small, high detergency can be obtained. In addition, compared with Test Examples 51 to 53 in which the alkyl group of the component (A') is dodecyl, Test Examples 50 to 56 in which the alkyl group of the component (A') is octadecyl has higher detergency. Therefore, it is considered that a larger number of carbon atoms in one of the alkyl groups in the above chemical formula 4 can improve the detergency with respect to dyed cosmetics.

In Test Example 57 in which an ethylenediamine compound was used instead of component (A), the cleansing property was improved compared to Test Example 58, but it was compared with the addition of a smaller amount of component (A) or component (A') than Test Example 57 Compared with Test Examples 50, 53, and 56, its detergency is lower. Therefore, it is considered that the compound represented by the above-mentioned chemical formula 4 has high cleansing properties with respect to color cosmetics.

[Table 18]

[Table 19]

The detergent composition of the present invention is described based on the above-mentioned embodiments and examples, but is not limited to the above-mentioned embodiments and examples. It may include within the scope of the present invention and based on the basic technical idea of the present invention. Various modifications, changes, and improvements have been made to the disclosed elements (including the elements described in the scope of patent application, specification and drawings). In addition, within the scope of the patent application of the present invention, various combinations, substitutions and selections of the disclosed elements can be made.

The further subject, object, and aspect (including modified aspects) of the present invention can also be clarified from all the disclosure matters of the present invention including the scope of the patent application.

For the numerical range described in this specification, even if it is not described in other paragraphs, any numerical value and range included in the range should be interpreted as what is specifically described in this specification.

Part or all of the above-mentioned embodiment may be as described in the following supplementary notes, but is not limited to the following description. Each supplementary note can also be combined with each application item described in the scope of the patent application.

[Supplement 1]

A cleaning method that uses a detergent composition containing trialkylamine oxide to wash away dyes from the skin.

[Supplement 2]

A cleaning method using a cleaning agent composition containing trialkylamine oxide represented by chemical formula 1.

[Supplement 3]

A cleaning method which uses the aforementioned detergent composition in a no-wash type.

[Supplement 4]

A detergent composition, which is a detergent composition for dyes used to wash away dyes from the skin,

Contains trialkylamine oxide.

[Supplement 5]

The detergent composition as described in the appendix, wherein the trialkylamine oxide is water-insoluble.

[Supplement 6]

The detergent composition described in the appendix, wherein the trialkylamine oxide has a structure shown in the following chemical formula 8.

Chemical formula 8

(In the chemical formula shown in chemical formula 8, any two of R ¹ , R ² and R ³ are alkyl groups having 1 to 4 carbons, and the other one is alkyl having 12 to 26 carbons)

[Supplement 7]

The detergent composition as described in the appendix, wherein in Chemical Formula 8, R ¹ and R ² are methyl groups, and R ³ is decyltetradecyl.

[Supplement 8]

The detergent composition as described in the appendix, wherein the aforementioned dye is an acid dye.

[Industrial Applicability]

The cleansing composition of the present disclosure can be preferably used to cleanse the skin. In particular, the composition of the present disclosure can be preferably used for washing cosmetics used to wash off the skin.

Claims (18)

A detergent composition containing trialkylamine oxide represented by chemical formula 1,

In the chemical formula shown in Chemical Formula ¹ , any two of R ¹ , R ² and R ³ are an alkyl group having 1 to 4 carbons, and the other one is an alkyl group having 22 to 26 carbons. The detergent composition described in item 1 of the scope of patent application, wherein, in the chemical formula 1, R ¹ and R ² are methyl groups, and R ³ is decyltetradecyl. The detergent composition according to item 1 or 2 of the scope of patent application, wherein the content of the trialkylamine oxide is 0.01% to 2% by mass relative to the mass of the composition. The detergent composition described in any one of items 1 to 3 in the scope of patent application has an oil phase and a water phase, The oil phase and the water phase are mainly not emulsified in the standing state. The detergent composition described in item 4 of the scope of patent application, wherein the content of the oil phase is 20% to 80% by mass relative to the mass of the composition, The content of the water phase is 20% to 80% by mass relative to the mass of the composition. The detergent composition according to item 4 or 5 of the scope of patent application, wherein the pH of the aforementioned water phase is 4-8. The detergent composition according to any one of the claims 1 to 6, wherein the content of the surfactant is 0.2% by mass or less relative to the mass of the composition. The detergent composition described in any one of items 1 to 7 of the scope of patent application further contains an alkyl betaine type surfactant. The detergent composition described in any one of items 1 to 8 in the scope of the patent application further contains 1% to 20% by mass of water-soluble alcohol relative to the mass of the aforementioned composition. The detergent composition described in any one of items 1 to 9 in the scope of the patent application further contains 15-50% by mass of volatile oily components relative to the mass of the aforementioned composition. The detergent composition according to item 10 of the scope of patent application, wherein the aforementioned volatile oily component is at least one selected from the group consisting of hydrocarbon oil, ester oil and silicone oil. The detergent composition described in any one of items 1 to 11 in the scope of the patent application further contains 0.1% to 5% by mass of salt relative to the mass of the aforementioned composition. The detergent composition described in any one of items 1 to 12 in the scope of the patent application, which contains a polyol derivative of 0.05% to 5% by mass relative to the mass of the aforementioned composition, The aforementioned polyol derivative is at least one of the glycerol derivative represented by Chemical Formula 2 and the ethylene glycol derivative represented by Chemical Formula 3.

In the chemical formula shown in chemical formula 2, any one of R ⁴ , R ⁵ and R ⁶ is an alkyl group, alkenyl group or acyl group having 4 to 15 carbon atoms, and the other 2 are hydrogen atoms

In the chemical formula shown in chemical formula 3, one of R ⁷ and R ⁸ is an alkyl group, alkenyl group or acyl group having 10 to 20 carbons, the other is a hydrogen atom, and R ⁹ is a carbon number of 1 to 4 The alkyl group, alkenyl group, acyl group or hydrogen atom. The detergent composition according to claim 13, wherein the glycerin derivative contains at least one of ethylhexylglycerol and hexylglycerol. The detergent composition according to any one of items 1 to 14 in the scope of patent application, wherein the aforementioned ethylene glycol derivative contains one of propylene glycol laurate, propylene glycol stearate, and propylene glycol isostearate At least one. The detergent composition described in any one of items 1 to 15 in the scope of the patent application is a detergent composition for cosmetics. The detergent composition described in any one of items 1 to 16 in the scope of the patent application is a detergent composition used to wash away cosmetics containing dyes from the skin. The detergent composition described in any one of items 1 to 17 in the scope of the patent application is a disposable type.