TW202023392A - Oil-in-water emulsion composition for foaming cake dough - Google Patents

Oil-in-water emulsion composition for foaming cake dough Download PDF

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TW202023392A
TW202023392A TW108136564A TW108136564A TW202023392A TW 202023392 A TW202023392 A TW 202023392A TW 108136564 A TW108136564 A TW 108136564A TW 108136564 A TW108136564 A TW 108136564A TW 202023392 A TW202023392 A TW 202023392A
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mass
content
component
fatty acid
emulsified composition
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会田渉
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日商花王股份有限公司
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    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/80Pastry not otherwise provided for elsewhere, e.g. cakes, biscuits or cookies
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/16Fatty acid esters
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/18Carbohydrates
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/005Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by ingredients other than fatty acid triglycerides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/01Other fatty acid esters, e.g. phosphatides

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Edible Oils And Fats (AREA)

Abstract

Provided is an oil-in-water emulsion composition for foaming cake dough, the composition containing: a monoacylglycerol (A) containing a saturated fatty acid as a constituent fatty acid; a sugar alcohol (B) having 6 or more carbon atoms; a sucrose fatty acid ester (C); and water (D), wherein the content of component (B) is 20-65 mass%, the content of component (D) is 10-30 mass%, the value of the ratio of the content of component (C) to the content of component (A) is 0.45-1.5 in mass ratio, and the content of oil and fat is 2.0 mass% or less.

Description

蛋糕麵團起泡用水中油型乳化組合物Oil type emulsified composition in water for frothing cake dough

本發明係關於一種蛋糕麵團起泡用水中油型乳化組合物。The invention relates to an oil-type emulsified composition in water for frothing cake dough.

蛋糕類係以麵粉、蛋、糖類、油脂等為原料製備蛋糕麵團,並對該蛋糕麵團進行烘烤而製造。蛋糕類通常為比容積較大、鬆軟之食感者受到喜愛。為達成該食感,較重要為使蛋糕麵團充分地起泡,通常可包裹大量空氣之蛋發揮該作用。 另一方面,亦已知有為進一步提高比容積及食感,於蛋糕麵團中進而調配起泡性之乳化組合物。作為該乳化組合物,含有脂肪酸甘油單酯作為主要成分者被廣泛使用。Cakes are manufactured by preparing cake dough using flour, eggs, sugar, fat, etc. as raw materials, and baking the cake dough. Cakes are usually loved by those with a larger specific volume and a soft texture. In order to achieve this texture, it is more important to fully foam the cake dough. Usually, a large amount of air-wrapped eggs can play this role. On the other hand, it is also known that in order to further increase the specific volume and the food texture, a foaming emulsified composition is further formulated in the cake dough. As this emulsified composition, those containing fatty acid monoglyceride as a main component are widely used.

脂肪酸甘油單酯(單醯甘油)於α結晶(α凝膠)之狀態下起泡力及維持其之能力較高,但轉移至β結晶(β凝膠)後,起泡力等大幅度降低。因此,為維持單醯甘油之α凝膠之狀態,提出包含除單醯甘油以外,含有山梨糖醇之乳化組合物之起泡劑(例如參照專利文獻1~3)。 [先前技術文獻] [專利文獻]Fatty acid monoglyceride (monoglycerin) has high foaming power and ability to maintain it in the state of α crystal (α gel), but after transferring to β crystal (β gel), the foaming power is greatly reduced. . Therefore, in order to maintain the state of the alpha gel of monoglycerin, a foaming agent containing an emulsified composition containing sorbitol in addition to monoglycerol has been proposed (for example, refer to Patent Documents 1 to 3). [Prior Technical Literature] [Patent Literature]

[專利文獻1]日本專利特開昭57-22640號公報 [專利文獻2]日本專利特開2002-247952號公報 [專利文獻3]日本專利特開2004-329156號公報[Patent Document 1] Japanese Patent Laid-Open No. 57-22640 [Patent Document 2] Japanese Patent Laid-Open No. 2002-247952 [Patent Document 3] Japanese Patent Laid-Open No. 2004-329156

本發明提供一種蛋糕麵團起泡用水中油型乳化組合物,其含有:A:以飽和脂肪酸為結構脂肪酸之單醯甘油(以下亦稱為「飽和單醯甘油」、「成分A」)、B:碳數6以上之糖醇(以下亦稱為「成分B」)、C:蔗糖脂肪酸酯(以下亦稱為「成分C」)、D:水(以下亦稱為「成分D」),且上述成分B之含量為20~65質量%,上述成分D之含量為10~30質量%,上述成分C之含量相對於上述成分A之含量之比之值以質量比計為0.45~1.5,油脂之含量為2.0質量%以下。The present invention provides an oil-in-water emulsified composition for cake dough foaming, which contains: A: monoglycerin with saturated fatty acid as structural fatty acid (hereinafter also referred to as "saturated monoglycerin" and "component A"), B: Sugar alcohols with 6 or more carbon atoms (hereinafter also referred to as "component B"), C: sucrose fatty acid ester (hereinafter also referred to as "component C"), D: water (hereinafter also referred to as "component D"), and The content of the component B is 20-65% by mass, the content of the component D is 10-30% by mass, and the ratio of the content of the component C to the content of the component A is 0.45 to 1.5 in terms of mass ratio. The content is 2.0% by mass or less.

專利文獻1~3中揭示之起泡劑之含水量較多,為使蛋糕麵團充分地起泡,必須添加更多量之起泡劑。又,該等起泡劑係為了使所添加之起泡劑擴散至整個麵團,麵團充分地起泡,需要相應之時間。The foaming agent disclosed in Patent Documents 1 to 3 has a high water content, and it is necessary to add a larger amount of foaming agent in order to fully foam the cake dough. In addition, the foaming agent needs a corresponding time in order to spread the added foaming agent to the entire dough, and the dough is fully foamed.

乳化組合物係溫度條件等對乳化穩定性產生影響,有於保存中容易產生構成成分之分離、相狀態之變化、及變色之傾向。若乳化狀態或相狀態崩壞,則起泡作用大幅度降低。因此,對包含乳化組合物之起泡劑要求可長期穩定地顯現起泡作用之特性。The temperature conditions of the emulsified composition affect the stability of the emulsification, and it tends to cause separation of constituent components, change in phase state, and discoloration during storage. If the emulsified state or phase state collapses, the foaming effect is greatly reduced. Therefore, the foaming agent containing the emulsified composition is required to exhibit the characteristics of foaming stably for a long time.

本發明者等人鑒於上述情況,進行努力研究。其結果為發現:含有特定量之以飽和脂肪酸為結構脂肪酸之單醯甘油,且具有抑制油脂之含量之油相作為分散相,具有組合含有特定量之特定碳數之糖醇與蔗糖脂肪酸酯與水之水相作為連續相的水中油型乳化組合物之長期保存穩定性優異,可長期穩定地顯現對蛋糕麵團之起泡作用,於蛋糕麵團之製造時快速起泡,且烤完之蛋糕之鬆散性良好,具有口溶感良好之食感。 本發明係基於該等見解而完成者。In view of the above situation, the inventors of the present invention conducted diligent research. As a result, it was found that: a specific amount of monoglycerin containing saturated fatty acids as structural fatty acids, and an oil phase that inhibits the content of fats and oils as a dispersed phase, has a combination of specific amounts of specific carbon number sugar alcohols and sucrose fatty acid esters The oil-in-water emulsified composition with the water phase as the continuous phase has excellent long-term storage stability, can stably exhibit the foaming effect on the cake dough for a long time, and foam quickly during the manufacture of the cake dough, and the baked cake Its looseness is good, and it has a good texture in the mouth. The present invention was completed based on these findings.

本發明係關於一種蛋糕麵團起泡用水中油型乳化組合物之提供,該蛋糕麵團起泡用水中油型乳化組合物可長期穩定地顯現對蛋糕麵團之優異之起泡作用,即便長期保存外觀亦不會變色,乳化狀態亦穩定,可於蛋糕麵團之製造時快速起泡,使烤完之蛋糕之鬆散性良好,具有口溶感良好之食感。The present invention relates to the provision of an oil-based emulsified composition in water for frothing cake dough. The oil-based emulsified composition in water for frothing cake dough can stably exhibit excellent frothing effect on cake dough for a long time, even if stored for a long time. It will change color and the emulsified state is also stable. It can foam quickly during the manufacture of cake dough, so that the baked cake has good looseness and good taste.

本發明之蛋糕麵團起泡用水中油型乳化組合物可長期穩定地維持對蛋糕麵團之優異之起泡作用,即便長期保存外觀亦不會變色,乳化狀態亦穩定,可於蛋糕麵團之製造時快速起泡,使所獲得之蛋糕之鬆散性良好,具有口溶感良好之食感。又,本發明之蛋糕之鬆散性良好,具有口溶感良好之食感。 本發明之上述及其他特徵及優點根據下述之記載明確。The cake dough foaming water-in-oil type emulsified composition of the present invention can maintain the excellent foaming effect on the cake dough stably for a long time, even if it is stored for a long time, the appearance will not change color, the emulsified state is also stable, and it can be used quickly in the manufacture of cake dough Foaming makes the obtained cake have good looseness and good texture. In addition, the cake of the present invention has good looseness and a good texture. The above and other features and advantages of the present invention are clarified from the following description.

關於本發明之蛋糕麵團起泡用水中油型乳化組合物(以下有時簡稱為本發明之乳化組合物),於以下說明較佳之實施形態。With regard to the oily emulsified composition in water for frothing cake dough of the present invention (hereinafter sometimes referred to as the emulsified composition of the present invention), preferred embodiments are described below.

本發明之乳化組合物中所含之成分A(飽和單醯甘油)係具有甘油具有之3個羥基中之任一個與飽和脂肪酸具有之羧基酯鍵結之結構之單酯化合物。飽和脂肪酸鍵結之甘油之羥基可為α-位亦可為β-位,較佳為α位。 上述飽和脂肪酸之種類並無特別限制,就使組合物之初期及長期保存後之起泡性變得良好之觀點而言,較佳為包含選自由肉豆蔻酸(C14:0)、棕櫚酸(C16:0)、硬脂酸(C18:0)、及二十酸(C20:0)所組成之群中之1種或2種以上,更佳為包含棕櫚酸及硬脂酸。硬脂酸占成分A之結構脂肪酸之比率較佳為40質量%以上,更佳為50質量%以上。作為成分A,可使用飽和單醯甘油之1種或2種以上。The component A (saturated monoglycerin) contained in the emulsified composition of the present invention is a monoester compound having a structure in which any one of the three hydroxyl groups of glycerol is bonded to the carboxyl ester of a saturated fatty acid. The hydroxyl group of glycerol bonded by saturated fatty acid may be α-position or β-position, preferably α-position. The type of saturated fatty acid is not particularly limited. From the viewpoint of improving the foamability of the composition at the initial stage and after long-term storage, it preferably contains selected from the group consisting of myristic acid (C14:0) and palmitic acid ( One or two or more of the group consisting of C16:0), stearic acid (C18:0), and arachidic acid (C20:0), and more preferably include palmitic acid and stearic acid. The ratio of stearic acid to the structural fatty acid of component A is preferably 40% by mass or more, more preferably 50% by mass or more. As the component A, one type or two or more types of saturated monoglycerin can be used.

本發明之乳化組合物中之成分A之含量就使組合物之初期及長期保存後之起泡性變得良好之觀點而言,較佳為2.0~10質量%,更佳為3.0~9.5質量%,進而較佳為5.0~9.0質量%。 成分A構成本發明之乳化組合物之油相。The content of Component A in the emulsified composition of the present invention is preferably 2.0-10% by mass, more preferably 3.0-9.5 mass% from the viewpoint of improving the foamability of the composition at the initial stage and after long-term storage %, more preferably 5.0 to 9.0% by mass. Component A constitutes the oil phase of the emulsified composition of the present invention.

本發明之乳化組合物中所含之成分B(碳數6以上之糖醇)係意指使醛糖或酮醣之羰基還原而獲得之糖。作為成分B之具體例,可列舉:山梨糖醇、木糖醇、赤藻糖醇、麥芽糖醇、甘露醇、還原飴糖、異麥芽酮糖醇、及乳糖醇,其中,較佳為山梨糖醇或麥芽糖醇,更佳為山梨糖醇。作為成分B,可使用碳數6以上之糖醇之1種或2種以上。Component B (sugar alcohol with 6 or more carbon atoms) contained in the emulsified composition of the present invention means a sugar obtained by reducing the carbonyl group of aldose or ketose. Specific examples of component B include: sorbitol, xylitol, erythritol, maltitol, mannitol, reduced maltose, isomalt, and lactitol. Among them, sorbitol is preferred. Alcohol or maltitol, more preferably sorbitol. As Component B, one or two or more of sugar alcohols having 6 or more carbon atoms can be used.

本發明之乳化組合物中之成分B之含量為20~65質量%,就使組合物之初期及長期保存後之起泡性變得良好之觀點而言,較佳為20~55質量%,更佳為22~50質量%,進而較佳為25~45質量%。 成分B構成本發明之乳化組合物之水相。The content of Component B in the emulsified composition of the present invention is 20 to 65% by mass, and from the viewpoint of improving the foamability of the composition at the initial stage and after long-term storage, it is preferably 20 to 55% by mass. It is more preferably 22 to 50% by mass, and still more preferably 25 to 45% by mass. Component B constitutes the water phase of the emulsified composition of the present invention.

本發明之乳化組合物中所含之成分C(蔗糖脂肪酸酯)係構成水相之成分。成分C之一分子具有之結構脂肪酸之數量只要成分C可作為水相成分存在則並無特別限制。脂肪酸單酯之形態之成分C占本發明之乳化組合物中所含之全部成分C之比率較佳為30~90質量%,更佳為40~85質量%,進而較佳為50~80質量%。作為構成蔗糖脂肪酸酯之脂肪酸,可列舉月桂酸、肉豆蔻酸、棕櫚酸、硬脂酸、油酸、山萮酸、芥子酸等,該等之中,更佳為飽和脂肪酸。用於本發明之成分C較佳為包含蔗糖硬脂酸酯(較佳為蔗糖硬脂酸酯占成分C之比率為50質量%以上)。作為成分C,可使用蔗糖脂肪酸酯之1種或2種以上。The component C (sucrose fatty acid ester) contained in the emulsified composition of the present invention is a component constituting the water phase. The number of structural fatty acids in a molecule of component C is not particularly limited as long as component C can exist as an aqueous phase component. The ratio of the component C in the form of fatty acid monoester to the total component C contained in the emulsified composition of the present invention is preferably 30 to 90% by mass, more preferably 40 to 85% by mass, and even more preferably 50 to 80% by mass %. As the fatty acid constituting the sucrose fatty acid ester, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, erucic acid, etc. can be cited. Among these, saturated fatty acids are more preferred. Component C used in the present invention preferably contains sucrose stearate (preferably, the ratio of sucrose stearate to component C is 50% by mass or more). As Component C, one kind or two or more kinds of sucrose fatty acid esters can be used.

本發明之乳化組合物中之成分C之含量就使組合物之初期及長期保存後之起泡性變得良好之觀點而言,較佳為1.0~10質量%,更佳為2.0~8.0質量%,進而較佳為4.0~6.0質量%。The content of component C in the emulsified composition of the present invention is preferably 1.0-10% by mass, more preferably 2.0-8.0% by mass, from the viewpoint of improving the foamability of the composition at the initial stage and after long-term storage %, more preferably 4.0 to 6.0% by mass.

本發明之乳化組合物中所含之成分D(水)只要為飲用水,則並無特別限制,例如可使用自來水、純化水、離子交換水、礦泉水等。又,於在包含水溶液等之水之狀態下調配成分D以外之成分之情形時,該水溶液等中所含之水構成成分D。The component D (water) contained in the emulsified composition of the present invention is not particularly limited as long as it is drinking water. For example, tap water, purified water, ion exchange water, mineral water, etc. can be used. Furthermore, when a component other than component D is prepared in a state containing water such as an aqueous solution, the water contained in the aqueous solution or the like constitutes component D.

本發明之乳化組合物中之成分D之含量為10~30質量%。就使組合物之初期及長期保存後之起泡性變得良好之觀點而言,本發明之乳化組合物中之成分D之含量較佳為15~29質量%,更佳為20~28質量%。 成分D成為本發明之乳化組合物中之水相成分之基劑。 本發明之乳化組合物即便將成分D之含量抑制於上述特定範圍內亦可提高保存穩定性,可長期穩定地顯現優異之起泡作用。又,由於將成分D之含量抑制於上述特定範圍內,其他成分之相對之量提高,故而可抑制乳化組合物相對於蛋糕麵團之使用量。又,藉由將成分D之含量抑制於上述特定範圍內,乳化組合物可快速均勻地擴散至整個蛋糕麵團,可使蛋糕麵團更快速、充分地起泡。The content of component D in the emulsified composition of the present invention is 10-30% by mass. From the viewpoint of improving the foamability of the composition at the initial stage and after long-term storage, the content of component D in the emulsified composition of the present invention is preferably 15-29% by mass, more preferably 20-28% by mass %. Component D becomes the base of the water phase component in the emulsified composition of the present invention. The emulsified composition of the present invention can improve storage stability even if the content of component D is suppressed within the above-mentioned specific range, and can stably exhibit excellent foaming effect over a long period of time. In addition, since the content of the component D is suppressed within the above-mentioned specific range, the relative amounts of other components are increased, so that the use amount of the emulsified composition relative to the cake dough can be suppressed. In addition, by suppressing the content of component D within the above-mentioned specific range, the emulsified composition can quickly and uniformly spread to the entire cake dough, and the cake dough can be foamed more quickly and fully.

本發明之乳化組合物亦可含有E:甘油(以下亦稱為「成分E」)。於本發明之乳化組合物含有成分E之情形時,就使組合物之初期及長期保存後之起泡性變得良好之觀點而言,乳化組合物中之成分E之含量較佳為0~40質量%,更佳為3.0~35質量%,進而較佳為7.0~30質量%。 成分E構成本發明之乳化組合物之水相。The emulsified composition of the present invention may also contain E: glycerin (hereinafter also referred to as "component E"). When the emulsified composition of the present invention contains component E, the content of component E in the emulsified composition is preferably 0 to from the viewpoint of improving the foamability of the composition at the initial stage and after long-term storage. 40% by mass, more preferably 3.0 to 35% by mass, and still more preferably 7.0 to 30% by mass. Component E constitutes the water phase of the emulsified composition of the present invention.

本發明之乳化組合物亦可含有F:油脂(以下亦稱為「成分F」)。即便於本發明之乳化組合物含有成分F之情形時,乳化組合物中之成分F之含量亦為2.0質量%以下。成分F例如包含於食用之動物性油脂、及食用之植物性油脂中,又,有包含於其他原料之製劑等中之情況。 於本發明中,成分F係意指三醯甘油及二醯甘油,單醯甘油設為不包含於上述「油脂」中者。The emulsified composition of the present invention may also contain F: fats and oils (hereinafter also referred to as "component F"). Even when the emulsified composition of the present invention contains component F, the content of component F in the emulsified composition is 2.0% by mass or less. Component F is contained in edible animal oils and fats, and edible vegetable oils and fats, and may be contained in preparations of other raw materials. In the present invention, component F means triglycerin and diglycerin, and monoglycerin is not contained in the above-mentioned "fat".

於本發明之乳化組合物含有成分F之情形時,就使組合物之初期及長期保存後之起泡性變得良好之觀點而言,乳化組合物中之成分F之含量較佳為1.0質量%以下,更佳為0.60質量%以下,進而較佳為0.30質量%以下。 成分F構成本發明之乳化組合物之油相。When the emulsified composition of the present invention contains component F, the content of component F in the emulsified composition is preferably 1.0 mass from the viewpoint of improving the foamability of the composition during the initial period and after long-term storage % Or less, more preferably 0.60 mass% or less, and still more preferably 0.30 mass% or less. Component F constitutes the oil phase of the emulsified composition of the present invention.

本發明之乳化組合物中,上述成分C之含量相對於上述成分A之含量之比之值(成分C之含量/成分A之含量,質量比)為0.45~1.5。就使組合物之初期及長期保存後之起泡性變得良好之觀點,及於烘烤後食用蛋糕時鬆散性良好、使口溶感變得良好之觀點而言,上述成分C之含量相對於上述成分A之含量之比之值較佳為0.45~1.3,更佳為0.50~1.0,進而較佳為0.55~0.80。In the emulsified composition of the present invention, the ratio of the content of the component C to the content of the component A (content of component C/content of component A, mass ratio) is 0.45 to 1.5. From the viewpoint of making the foamability of the composition good at the initial stage and after long-term storage, and from the viewpoint of good looseness when eating cake after baking, the content of the above-mentioned component C is relatively The value of the ratio of the content of the aforementioned component A is preferably 0.45 to 1.3, more preferably 0.50 to 1.0, and still more preferably 0.55 to 0.80.

本發明之乳化組合物中,上述成分B之含量與上述成分E之含量之合計較佳為40~70質量%,就使組合物之初期及長期保存後之起泡性變得良好之觀點而言,上述成分B之含量與上述成分E之含量之合計更佳為42~65質量%,進而較佳為44~60質量%,尤佳為46~55質量%。In the emulsified composition of the present invention, the sum of the content of the above-mentioned component B and the content of the above-mentioned component E is preferably 40 to 70% by mass, from the viewpoint of improving the foamability of the composition at the initial stage and after long-term storage In other words, the total of the content of the component B and the content of the component E is more preferably 42 to 65% by mass, still more preferably 44 to 60% by mass, and particularly preferably 46 to 55% by mass.

又,於本發明之乳化組合物含有上述成分E之情形時,就使組合物之初期及長期保存後之起泡性變得良好之觀點而言,乳化組合物中,上述成分E之含量相對於上述成分B之含量之比之值(成分E之含量/成分B之含量,質量比)較佳為0.10~1.0,更佳為0.15~0.95,進而較佳為0.20~0.90。In addition, when the emulsified composition of the present invention contains the above-mentioned component E, from the viewpoint of improving the foamability of the composition at the initial stage and after long-term storage, the content of the above-mentioned component E in the emulsified composition is relatively The value of the ratio of the content of component B (content of component E/content of component B, mass ratio) is preferably 0.10 to 1.0, more preferably 0.15 to 0.95, and even more preferably 0.20 to 0.90.

本發明之乳化組合物亦較佳為除上述成分以外,進而含有G:丙二醇脂肪酸酯(以下亦稱為「成分G」)。構成成分G之脂肪酸並無特別限制,可列舉月桂酸、肉豆蔻酸、棕櫚酸、硬脂酸、油酸、山萮酸、芥子酸,該等之中,更佳為飽和脂肪酸。成分G較佳為包含丙二醇脂肪酸單酯,其中,較佳為包含丙二醇山萮酸酯。作為成分G,可使用丙二醇脂肪酸酯之1種或2種以上。The emulsified composition of the present invention also preferably further contains G: propylene glycol fatty acid ester (hereinafter also referred to as "component G") in addition to the above-mentioned components. The fatty acid constituting Component G is not particularly limited, and examples include lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, and erucic acid. Among these, saturated fatty acids are more preferred. Component G preferably contains propylene glycol fatty acid monoester, and among them, preferably contains propylene glycol behenate. As component G, one type or two or more types of propylene glycol fatty acid ester can be used.

本發明之乳化組合物中之成分G之含量就使組合物之初期及長期保存後之起泡性變得良好之觀點而言,較佳為1.5~5.5質量%,更佳為2.0~5.5質量%,進而較佳為3.0~5.4質量%。 成分G構成本發明之乳化組合物之油相。The content of Component G in the emulsified composition of the present invention is preferably 1.5-5.5 mass%, more preferably 2.0-5.5 mass from the viewpoint of improving the foamability of the composition at the initial stage and after long-term storage %, more preferably 3.0 to 5.4% by mass. Component G constitutes the oil phase of the emulsified composition of the present invention.

本發明之乳化組合物亦較佳為含有H:脂肪酸(以下亦稱為「成分H」)。成分H較佳為油相之構成成分。作為較佳地用於本發明之脂肪酸,飽和、不飽和中之任一者均可,較佳為碳原子數16~24之脂肪酸,更佳為碳原子數18~22之脂肪酸,進而較佳為碳原子數20~22之脂肪酸。成分H較佳為包含山萮酸。作為成分H,可使用脂肪酸之1種或2種以上。The emulsified composition of the present invention also preferably contains H: fatty acid (hereinafter also referred to as "component H"). Component H is preferably a constituent of the oil phase. The fatty acid preferably used in the present invention may be either saturated or unsaturated, preferably a fatty acid with 16 to 24 carbon atoms, more preferably a fatty acid with 18 to 22 carbon atoms, and even more preferred It is a fatty acid with 20 to 22 carbon atoms. Component H preferably contains behenic acid. As the component H, one kind or two or more kinds of fatty acids can be used.

本發明之乳化組合物中之成分H之含量就使組合物之初期及長期保存後之起泡性變得良好之觀點而言,較佳為0.10~1.0質量%,更佳為0.15~0.80質量%,進而較佳為0.20~0.60質量%。The content of component H in the emulsified composition of the present invention is preferably 0.10 to 1.0 mass%, more preferably 0.15 to 0.80 mass from the viewpoint of improving the foamability of the composition at the initial stage and after long-term storage %, more preferably 0.20 to 0.60 mass%.

本發明之乳化組合物亦較佳為含有I:山梨醇酐脂肪酸酯(以下亦稱為「成分I」)。構成成分I之脂肪酸並無特別限制,可列舉月桂酸、肉豆蔻酸、棕櫚酸、硬脂酸、油酸、山萮酸、芥子酸。其中,較佳為包含飽和脂肪酸。構成成分I之脂肪酸更佳為包含硬脂酸。成分I較佳為山梨醇酐脂肪酸單酯、山梨醇酐脂肪酸二酯、或山梨醇酐脂肪酸三酯之形態。作為成分I,可使用山梨醇酐脂肪酸酯之1種或2種以上。The emulsified composition of the present invention also preferably contains I: sorbitan fatty acid ester (hereinafter also referred to as "component I"). The fatty acid constituting Component I is not particularly limited, and examples include lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, and erucic acid. Among them, saturated fatty acids are preferably contained. The fatty acid constituting component I more preferably contains stearic acid. Component I is preferably in the form of sorbitan fatty acid monoester, sorbitan fatty acid diester, or sorbitan fatty acid triester. As Component I, one or two or more types of sorbitan fatty acid esters can be used.

本發明之乳化組合物中之成分I之含量就使組合物之初期及長期保存後之起泡性變得良好之觀點而言,較佳為0.5~5.0質量%,更佳為1.0~4.0質量%,進而較佳為1.5~3.5質量%。 成分I構成本發明之乳化組合物之油相。The content of Component I in the emulsified composition of the present invention is preferably 0.5-5.0% by mass, more preferably 1.0-4.0% by mass from the viewpoint of improving the foamability of the composition at the initial stage and after long-term storage %, more preferably 1.5 to 3.5% by mass. Component I constitutes the oil phase of the emulsified composition of the present invention.

本發明之乳化組合物亦較佳為含有J:磷脂(以下亦稱為「成分J」)。作為成分J,例如可列舉磷脂膽鹼、磷脂醯乙醇胺、磷脂醯肌醇、磷脂酸等或該等之酵素處理物。作為成分J,亦可使用大豆卵磷脂或蛋黃卵磷脂等天然卵磷脂或其酵素分解物。又,作為成分J,亦可使用磷脂複合體(例如磷脂與蛋白質之複合體等)。作為成分J,可使用磷脂之1種或2種以上。The emulsified composition of the present invention also preferably contains J: phospholipid (hereinafter also referred to as "component J"). As component J, for example, phospholipid choline, phospholipid ethanolamine, phospholipid inositol, phosphatidic acid, etc. or these enzyme-treated products can be cited. As Component J, natural lecithin such as soybean lecithin or egg yolk lecithin or its enzymatic degradation product can also be used. In addition, as component J, a phospholipid complex (for example, a complex of phospholipids and protein, etc.) may also be used. As component J, one kind or two or more kinds of phospholipids can be used.

本發明之乳化組合物中之成分J之含量就使組合物之初期及長期保存後之起泡性變得良好之觀點而言,較佳為0~1.0質量%,更佳為0.05~0.80質量%,進而較佳為0.10~0.50質量%。 成分J構成本發明之乳化組合物之油相。The content of component J in the emulsified composition of the present invention is preferably 0 to 1.0 mass%, more preferably 0.05 to 0.80 mass from the viewpoint of improving the foamability of the composition at the initial stage and after long-term storage %, more preferably 0.10 to 0.50% by mass. Component J constitutes the oil phase of the emulsified composition of the present invention.

本發明之乳化組合物亦較佳為含有K:低級醇(以下亦稱為「成分K」)。作為成分K,較佳為乙醇。 就使乳化物之製造變得容易之觀點而言,本發明之乳化組合物中之成分K之含量較佳為0~10質量%,更佳為1.0~8.0質量%,進而較佳為2.0~7.0質量%。 成分K構成本發明之乳化組合物之水相。The emulsified composition of the present invention also preferably contains K: lower alcohol (hereinafter also referred to as "component K"). As the component K, ethanol is preferred. From the viewpoint of facilitating the production of emulsions, the content of component K in the emulsified composition of the present invention is preferably 0-10% by mass, more preferably 1.0-8.0% by mass, and still more preferably 2.0- 7.0% by mass. Component K constitutes the water phase of the emulsified composition of the present invention.

本發明之乳化組合物除上述成分以外,亦可於無損本發明之效果之範圍內,含有各種添加劑。作為添加劑之例,可列舉:液體載體、油性載體、穩定劑、濕潤劑、乳化劑、結合劑、等張劑、崩解劑、潤滑劑、增量劑、界面活性劑、分散劑、懸浮劑、稀釋劑、滲透壓調整劑、pH值調整劑、防腐劑、抗氧化劑、著色劑、紫外線吸收劑、保濕劑、增黏劑、光澤劑、緩衝劑、保存劑、矯味劑、香料、覆膜劑、矯臭劑、抗菌劑等。In addition to the above-mentioned components, the emulsified composition of the present invention may contain various additives within a range that does not impair the effects of the present invention. Examples of additives include: liquid carriers, oily carriers, stabilizers, wetting agents, emulsifiers, binders, isotonic agents, disintegrants, lubricants, extenders, surfactants, dispersants, suspending agents , Thinner, osmotic pressure adjuster, pH adjuster, preservative, antioxidant, colorant, ultraviolet absorber, moisturizer, tackifier, gloss agent, buffer, preservative, flavoring agent, fragrance, film Agents, odorants, antibacterial agents, etc.

本發明之乳化組合物例如可藉由利用通常之方法將含有油相成分之油脂組合物、與含有水相成分之水溶液乳化混合而獲得。例如,對含有油相之各構成成分之油脂組合物,加熱至80℃左右並進行攪拌,另外,將含有水相之各構成成分之水溶液加熱至80℃左右並進行攪拌。然後,於上述水溶液中添加上述油脂組合物並進行攪拌,使油脂組合物乳化分散於水溶液中,藉此可獲得目標水中油型乳化組合物。就提高本發明之乳化組合物之乳化穩定性之觀點而言,上述水溶液相對於上述油脂組合物,以質量比(水溶液/油脂組合物)計較佳為2.0以上,更佳為4.0~15。The emulsified composition of the present invention can be obtained, for example, by emulsifying and mixing a fat composition containing an oil phase component and an aqueous solution containing an aqueous phase component by a usual method. For example, the oil and fat composition containing the constituent components of the oil phase is heated to about 80°C and stirred, and the aqueous solution containing the constituent components of the water phase is heated to about 80°C and stirred. Then, the oil and fat composition is added to the aqueous solution and stirred to emulsify and disperse the oil and fat composition in the aqueous solution, thereby obtaining the target oil-in-water emulsion composition. From the viewpoint of improving the emulsion stability of the emulsified composition of the present invention, the mass ratio (aqueous solution/fat composition) of the aqueous solution to the oil and fat composition is preferably 2.0 or more, and more preferably 4.0-15.

本發明之水中油型乳化組合物用於蛋糕製品之製造。作為蛋糕製品,可列舉海綿蛋糕、乳酪餅、戚風蛋糕、蛋糕卷、瑞士卷、小餡餅、年輪蛋糕、磅蛋糕、乾酪糕、點心蛋糕、蒸蛋糕等。The oil-in-water emulsified composition of the present invention is used for the manufacture of cake products. Examples of cake products include sponge cakes, cheesecakes, chiffon cakes, cake rolls, Swiss rolls, small pies, baumkuchen, pound cakes, cheese cakes, snack cakes, steamed cakes, and the like.

本發明之蛋糕藉由烘烤含有本發明之乳化組合物之蛋糕麵團而製造。該蛋糕麵團除添加本發明之乳化組合物以外,可利用通常之方法製備。例如,可至少將穀粉、蛋、糖類、與本發明之乳化組合物混合而獲得。就獲得良好之食感與風味之觀點而言,本發明之蛋糕較佳為至少將穀粉、與相對於該穀粉100質量份為50~300質量份之蛋、20~250質量份之糖類、3~100質量份之本發明之乳化劑混合而製備持氣之蛋糕麵團,對該蛋糕麵團進行烘烤而製造。更佳為相對於穀粉100質量份,以蛋80~250質量份、糖類50~180質量份、本發明之乳化組合物5~50質量份之比率進行混合,烘烤持氣之蛋糕麵團而製造。 上述穀粉並無特別限制,例如可列舉麵粉、米粉、大麥粉、黑麥粉、玉米粉、稗子粉等,其中可較佳地使用麵粉。 作為上述蛋,可列舉雞蛋、鴕鳥蛋、鴨蛋等,其中可較佳地使用雞蛋。又,上述蛋係意指蛋白及/或蛋黃。 所使用之蛋之加工形態並無特別限制,可使用生蛋、冷凍蛋、粉末蛋、加糖蛋、殺菌蛋等,其中可較佳地使用殺菌蛋。 上述蛋糕麵團可進而包含乳粉、醱酵粉、砂糖、食用油、香料等調配於蛋糕麵團之慣用添加物等。The cake of the present invention is manufactured by baking cake dough containing the emulsified composition of the present invention. In addition to adding the emulsified composition of the present invention, the cake dough can be prepared by usual methods. For example, it can be obtained by mixing at least cereal flour, eggs, sugars, and the emulsified composition of the present invention. From the viewpoint of obtaining a good texture and flavor, the cake of the present invention preferably comprises at least cereal flour, 50-300 parts by mass of eggs, 20-250 parts by mass of sugar, and 3 ~100 parts by mass of the emulsifier of the present invention is mixed to prepare a cake dough that retains air, and the cake dough is baked to manufacture. More preferably, it is produced by mixing 80-250 parts by mass of eggs, 50-180 parts by mass of sugars, and 5-50 parts by mass of the emulsified composition of the present invention, relative to 100 parts by mass of cereal flour, and baking the cake dough that retains air . The above-mentioned cereal flour is not particularly limited, and examples thereof include flour, rice flour, barley flour, rye flour, corn flour, and tares flour. Among them, flour can be preferably used. Examples of the above-mentioned eggs include eggs, ostrich eggs, duck eggs, etc. Among them, eggs can be preferably used. In addition, the above-mentioned egg system means egg white and/or egg yolk. The processing form of the eggs used is not particularly limited. Raw eggs, frozen eggs, powdered eggs, sweetened eggs, sterilized eggs, etc. can be used, among which sterilized eggs can be preferably used. The above-mentioned cake dough may further include customary additives such as milk powder, fermented powder, sugar, edible oil, spices, etc., which are formulated in the cake dough.

上述烘烤方法並無特別限制,通常藉由將蛋糕麵團放入所需之模具(圓筒、三角筒或四角筒等角形筒等),利用烤箱等烘烤(加熱)而進行。The above-mentioned baking method is not particularly limited, and it is usually carried out by putting the cake dough into the required mold (cylinder, triangular tube, quadrangular tube, etc.), and baking (heating) in an oven or the like.

關於上述之實施形態,本發明進而揭示以下之水中油型乳化組合物、蛋糕、及蛋糕之製造方法。Regarding the above-mentioned embodiments, the present invention further discloses the following oil-in-water emulsified compositions, cakes, and cake manufacturing methods.

<1> 一種蛋糕麵團起泡用水中油型乳化組合物,其 含有: A:以飽和脂肪酸為結構脂肪酸之單醯甘油、 B:碳數6以上之糖醇、 C:蔗糖脂肪酸酯、及 D:水;且 上述碳數6以上之糖醇之含量為20~65質量%,較佳為20~55質量%,更佳為22~50質量%,進而較佳為25~45質量%; 上述水之含量為10~30質量%,較佳為15~29質量%,更佳為20~28質量%; 上述蔗糖脂肪酸酯之含量相對於上述以飽和脂肪酸為結構脂肪酸之單醯甘油之含量之比之值以質量比計為0.45~1.5,較佳為0.45~1.3,更佳為0.50~1.0,進而較佳為0.55~0.80; 油脂之含量為2.0質量%以下,較佳為1.0質量%以下,更佳為0.60質量%以下,進而較佳為0.30質量%以下。<1> An oil type emulsified composition in water for frothing cake dough, which contain: A: Monoglycerin with saturated fatty acid as structural fatty acid, B: Sugar alcohol with carbon number 6 or more, C: Sucrose fatty acid ester, and D: water; and The content of the sugar alcohol with 6 or more carbons is 20-65% by mass, preferably 20-55% by mass, more preferably 22-50% by mass, and still more preferably 25-45% by mass; The content of the aforementioned water is 10-30% by mass, preferably 15-29% by mass, more preferably 20-28% by mass; The ratio of the content of the above-mentioned sucrose fatty acid ester to the content of the above-mentioned monoglycerin with saturated fatty acid as the structural fatty acid is 0.45-1.5 in terms of mass ratio, preferably 0.45-1.3, more preferably 0.50-1.0, and further Preferably it is 0.55~0.80; The content of fats and oils is 2.0% by mass or less, preferably 1.0% by mass or less, more preferably 0.60% by mass or less, and still more preferably 0.30% by mass or less.

<2> 如上述<1>項記載之蛋糕麵團起泡用水中油型乳化組合物,其含有 E:甘油,且 上述碳數6以上之糖醇之含量與上述甘油之含量之合計為40質量%以上,較佳為42質量%以上,更佳為44質量%以上,進而較佳為46質量%以上,上述甘油之含量相對於上述碳數6以上之糖醇之含量之比之值以質量比計為0.1以上,較佳為0.15以上,更佳為0.20以上。 <3> 如上述<1>或<2>項記載之蛋糕麵團起泡用水中油型乳化組合物,其含有 E:甘油,且 上述碳數6以上之糖醇之含量與上述甘油之含量之合計為70質量%以下,較佳為65質量%以下,更佳為60質量%以下,進而較佳為55質量%以下,上述甘油之含量相對於上述碳數6以上之糖醇之含量之比之值以質量比計為1以下,較佳為0.95以下,更佳為0.90以下。 <4> 如上述<1>至<3>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其含有 E:甘油,且 上述碳數6以上之糖醇之含量與上述甘油之含量之合計為40~70質量%,較佳為42~65質量%,更佳為44~60質量%,進而較佳為46~55質量%,上述甘油之含量相對於上述碳數6以上之糖醇之含量之比之值以質量比計為0.1~1,較佳為0.15~0.95,更佳為0.20~0.90。 <5> 如上述<1>至<4>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中作為上述單醯甘油之結構脂肪酸之飽和脂肪酸為選自由肉豆蔻酸、棕櫚酸、硬脂酸、及二十酸所組成之群中之1種或2種以上,較佳為棕櫚酸及硬脂酸,更佳為棕櫚酸或硬脂酸。 <6> 如上述<1>至<5>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物中之以飽和脂肪酸為結構脂肪酸之單醯甘油之含量較佳為2.0質量%以上,更佳為3.0質量%以上,進而較佳為5.0質量%以上。 <7> 如上述<1>至<6>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物中之以飽和脂肪酸為結構脂肪酸之單醯甘油之含量較佳為10質量%以下,更佳為9.5質量%以下,進而較佳為9.0質量%以下。 <8> 如上述<1>至<7>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物中之以飽和脂肪酸為結構脂肪酸之單醯甘油之含量較佳為2.0~10質量%,更佳為3.0~9.5質量%,進而較佳為5.0~9.0質量%。 <9> 如上述<1>至<8>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述糖醇較佳為選自山梨糖醇、木糖醇、赤藻糖醇、麥芽糖醇、及丙二醇中之1種或2種以上,更佳為山梨糖醇或麥芽糖醇,進而較佳為山梨糖醇。 <10> 如上述<1>至<9>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述蔗糖脂肪酸酯較佳為單酯含量為30~90質量%,更佳為40~85質量%,進而較佳為50~80質量%之蔗糖脂肪酸酯。 <11> 如上述<1>至<10>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中構成上述蔗糖脂肪酸酯之脂肪酸較佳為月桂酸、肉豆蔻酸、棕櫚酸、硬脂酸、油酸、山萮酸、或芥子酸,更佳為該等中之飽和脂肪酸,進而較佳為硬脂酸。 <12> 如上述<1>至<11>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物中之蔗糖脂肪酸酯之含量較佳為1.0質量%以上,更佳為2.0質量%以上,進而較佳為4.0質量%以上。 <13> 如上述<1>至<12>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物中之蔗糖脂肪酸酯之含量較佳為10質量%以下,更佳為8.0質量%以下,進而較佳為6.0質量%以下。 <14> 如上述<1>至<13>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物中之蔗糖脂肪酸酯之含量較佳為1.0~10質量%,更佳為2.0~8.0質量%,進而較佳為4.0~6.0質量%。 <15> 如上述<1>至<14>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物中之甘油之含量較佳為0質量%以上,更佳為3.0質量%以上,進而較佳為7.0質量%以上。 <16> 如上述<1>至<15>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物中之甘油之含量較佳為40質量%以下,更佳為35質量%以下,進而較佳為30質量%以下。 <17> 如上述<1>至<16>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物中之甘油之含量較佳為0~40質量%,更佳為3.0~35質量%,進而較佳為7.0~30質量%。 <18> 如上述<1>至<17>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述油脂為食用之動物性油脂、食用之植物性油脂中所含之油脂。 <19> 如上述<18>項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述植物性油脂為選自大豆油、橄欖油、紅花油、玉米油、菜籽油、棉籽油、該等之分類油、酯交換油、氫化油中之1種或2種以上之油脂。<2> The oil-in-oil emulsified composition in water for frothing cake dough as described in item <1> above, which contains E: Glycerin, and The total content of the sugar alcohol having 6 or more carbon atoms and the content of the glycerin is 40% by mass or more, preferably 42% by mass or more, more preferably 44% by mass or more, and still more preferably 46% by mass or more. The value of the ratio of the content to the content of the sugar alcohol with carbon number 6 or more is 0.1 or more in mass ratio, preferably 0.15 or more, more preferably 0.20 or more. <3> The oil-based emulsified composition in water for frothing cake dough as described in the above item <1> or <2>, which contains E: Glycerin, and The total of the content of the sugar alcohol with 6 or more carbon atoms and the content of the glycerin is 70% by mass or less, preferably 65% by mass or less, more preferably 60% by mass or less, and still more preferably 55% by mass or less. The value of the ratio of the content to the content of the above-mentioned sugar alcohol with carbon number 6 or more is 1 or less in mass ratio, preferably 0.95 or less, more preferably 0.90 or less. <4> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <3>, which contains E: Glycerin, and The total of the content of the sugar alcohol having 6 or more carbon atoms and the content of the glycerin is 40 to 70% by mass, preferably 42 to 65% by mass, more preferably 44 to 60% by mass, and still more preferably 46 to 55% by mass %, the ratio of the content of the above-mentioned glycerin to the content of the above-mentioned carbon number 6 sugar alcohol is 0.1 to 1, preferably 0.15 to 0.95, more preferably 0.20 to 0.90 in terms of mass ratio. <5> The oil-in-oil type emulsified composition in water for frothing cake dough as described in any one of the above <1> to <4>, wherein the saturated fatty acid as the structural fatty acid of the monoglycerin is selected from the group consisting of myristic acid, palmitic acid, and stearin One or two or more of the group consisting of acid and arachidic acid, preferably palmitic acid and stearic acid, more preferably palmitic acid or stearic acid. <6> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <5>, wherein the content of monoglycerin containing saturated fatty acids as structural fatty acids in the emulsified composition is preferably 2.0 mass % Or more, more preferably 3.0% by mass or more, and still more preferably 5.0% by mass or more. <7> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <6>, wherein the content of monoglycerin containing saturated fatty acids as structural fatty acids in the emulsified composition is preferably 10 mass % Or less, more preferably 9.5% by mass or less, and still more preferably 9.0% by mass or less. <8> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <7>, wherein the content of monoglycerin containing saturated fatty acids as structural fatty acids in the emulsified composition is preferably 2.0 to 10% by mass, more preferably 3.0 to 9.5% by mass, and still more preferably 5.0 to 9.0% by mass. <9> The oil-in-oil type emulsified composition in water for foaming cake dough as described in any one of the above <1> to <8>, wherein the sugar alcohol is preferably selected from sorbitol, xylitol, erythritol, and maltitol 1 or 2 or more of propylene glycol, more preferably sorbitol or maltitol, and still more preferably sorbitol. <10> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <9>, wherein the sucrose fatty acid ester preferably has a monoester content of 30 to 90% by mass, more preferably 40 to 85% by mass, more preferably 50 to 80% by mass of sucrose fatty acid ester. <11> The oil-in-oil type emulsified composition in water for frothing cake dough as described in any one of the above <1> to <10>, wherein the fatty acid constituting the sucrose fatty acid ester is preferably lauric acid, myristic acid, palmitic acid, and stearin Acid, oleic acid, behenic acid, or erucic acid, more preferably saturated fatty acid among them, and more preferably stearic acid. <12> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <11>, wherein the content of the sucrose fatty acid ester in the emulsified composition is preferably 1.0% by mass or more, more preferably 2.0% by mass or more, more preferably 4.0% by mass or more. <13> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <12>, wherein the content of the sucrose fatty acid ester in the emulsified composition is preferably 10% by mass or less, more preferably 8.0% by mass or less, more preferably 6.0% by mass or less. <14> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <13>, wherein the content of the sucrose fatty acid ester in the emulsified composition is preferably 1.0-10% by mass, more preferably It is 2.0-8.0 mass %, More preferably, it is 4.0-6.0 mass %. <15> The oil type emulsified composition in water for frothing cake dough as described in any one of the above <1> to <14>, wherein the content of glycerin in the emulsified composition is preferably 0% by mass or more, more preferably 3.0% by mass Above, more preferably 7.0% by mass or more. <16> The oil type emulsified composition in water for frothing cake dough as described in any one of the above <1> to <15>, wherein the content of glycerin in the emulsified composition is preferably 40% by mass or less, more preferably 35% by mass Hereinafter, it is more preferably 30% by mass or less. <17> The oil type emulsified composition in water for frothing cake dough as described in any one of the above <1> to <16>, wherein the content of glycerin in the emulsified composition is preferably 0-40% by mass, more preferably 3.0- 35 mass %, more preferably 7.0 to 30 mass %. <18> The oil-in-oil type emulsified composition in water for frothing cake dough as described in any one of the above <1> to <17>, wherein the above-mentioned oils and fats are oils contained in edible animal oils and edible vegetable oils. <19> The oil-in-oil emulsified composition in water for frothing cake dough as described in item <18>, wherein the vegetable oil is selected from soybean oil, olive oil, safflower oil, corn oil, rapeseed oil, cottonseed oil, and the like One or more of oils, transesterified oils, and hydrogenated oils.

<20> 如上述<1>至<19>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物含有 G:丙二醇脂肪酸酯,且 該丙二醇脂肪酸酯之含量為1.5質量%以上,較佳為2.0質量%以上,更佳為3.0質量%以上。 <21> 如上述<1>至<20>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物含有 G:丙二醇脂肪酸酯,且 該丙二醇脂肪酸酯之含量為5.5質量%以下,較佳為5.4質量%以下。 <22> 如上述<1>至<21>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物含有 G:丙二醇脂肪酸酯,且 該丙二醇脂肪酸酯之含量為1.5~5.5質量%,較佳為2.0~5.5質量%,更佳為3.0~5.4質量%。 <23> 如上述<20>至<22>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中構成上述丙二醇脂肪酸酯之脂肪酸較佳為月桂酸、肉豆蔻酸、棕櫚酸、硬脂酸、油酸、山萮酸、或芥子酸,更佳為飽和脂肪酸,進而較佳為山萮酸。<20> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <19>, wherein the emulsified composition contains G: propylene glycol fatty acid ester, and The content of the propylene glycol fatty acid ester is 1.5% by mass or more, preferably 2.0% by mass or more, and more preferably 3.0% by mass or more. <21> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <20>, wherein the emulsified composition contains G: propylene glycol fatty acid ester, and The content of the propylene glycol fatty acid ester is 5.5% by mass or less, preferably 5.4% by mass or less. <22> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <21>, wherein the emulsified composition contains G: propylene glycol fatty acid ester, and The content of the propylene glycol fatty acid ester is 1.5 to 5.5% by mass, preferably 2.0 to 5.5% by mass, and more preferably 3.0 to 5.4% by mass. <23> As described in any one of the above <20> to <22>, the oil-in-oil emulsified composition in water for foaming cake dough, wherein the fatty acid constituting the propylene glycol fatty acid ester is preferably lauric acid, myristic acid, palmitic acid, and stearin Acid, oleic acid, behenic acid, or erucic acid, more preferably saturated fatty acid, more preferably behenic acid.

<24> 如上述<1>至<23>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物含有 H:脂肪酸,且 該脂肪酸之含量為0.10質量%以上,較佳為0.15質量%以上,更佳為0.20質量%以上。 <25> 如上述<1>至<24>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物含有 H:脂肪酸,且 該脂肪酸之含量為1.0質量%以下,較佳為0.80質量%以下,更佳為0.60質量%以下。 <26> 如上述<1>至<25>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物含有 H:脂肪酸,且 該脂肪酸之含量為0.10~1.0質量%,較佳為0.15~0.80質量%,更佳為0.20~0.60質量%。 <27> 如上述<24>至<26>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述脂肪酸較佳為碳原子數16~24之脂肪酸,更佳為碳原子數18~22之脂肪酸,進而較佳為碳原子數20~22之脂肪酸。<24> The oil-based emulsified composition in water for foaming cake dough as described in any one of the above <1> to <23>, wherein the emulsified composition contains H: fatty acid, and The content of the fatty acid is 0.10% by mass or more, preferably 0.15% by mass or more, and more preferably 0.20% by mass or more. <25> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <24>, wherein the emulsified composition contains H: fatty acid, and The content of the fatty acid is 1.0% by mass or less, preferably 0.80% by mass or less, and more preferably 0.60% by mass or less. <26> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <25>, wherein the emulsified composition contains H: fatty acid, and The content of the fatty acid is 0.10 to 1.0% by mass, preferably 0.15 to 0.80% by mass, more preferably 0.20 to 0.60% by mass. <27> The oil-in-oil type emulsified composition in water for frothing cake dough as described in any one of the above <24> to <26>, wherein the fatty acid is preferably a fatty acid having 16 to 24 carbon atoms, more preferably 18 to 22 carbon atoms The fatty acid is more preferably a fatty acid having 20-22 carbon atoms.

<28> 如上述<1>至<27>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物含有 I:山梨醇酐脂肪酸酯,且 該山梨醇酐脂肪酸酯之含量為0.5質量%以上,較佳為1.0質量%以上,更佳為1.5質量%以上。 <29> 如上述<1>至<28>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物含有 I:山梨醇酐脂肪酸酯,且 該山梨醇酐脂肪酸酯之含量為5.0質量%以下,較佳為4.0質量%以下,更佳為3.5質量%以下。 <30> 如上述<1>至<29>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物含有 I:山梨醇酐脂肪酸酯,且 該山梨醇酐脂肪酸酯之含量為0.5~5.0質量%,較佳為1.0~4.0質量%,更佳為1.5~3.5質量%。 <31> 如上述<28>至<30>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中構成上述山梨醇酐脂肪酸酯之脂肪酸較佳為月桂酸、肉豆蔻酸、棕櫚酸、硬脂酸、油酸、山萮酸、或芥子酸,更佳為飽和脂肪酸,進而較佳為硬脂酸。 <32> 如上述<1>至<31>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物含有 J:磷脂,且 該磷脂之含量為0質量%以上,較佳為0.05質量%以上,更佳為0.10質量%以上。 <33> 如上述<1>至<32>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物含有 J:磷脂,且 該磷脂之含量為1.0質量%以下,較佳為0.80質量%以下,更佳為0.50質量%以下。 <34> 如上述<1>至<33>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物含有 J:磷脂,且 該磷脂之含量為0~1.0質量%,較佳為0.05~0.80質量%,更佳為0.10~0.50質量%。 <35> 如上述<1>至<34>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物含有 K:低級醇,且 該低級醇之含量為0質量%以上,較佳為1.0質量%以上,更佳為2.0質量%以上。 <36> 如上述<1>至<35>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物含有 K:低級醇,且 該低級醇之含量為10質量%以下,較佳為8.0質量%以下,更佳為7.0質量%以下。 <37> 如上述<1>至<36>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述乳化組合物含有 K:低級醇,且 該低級醇之含量為0~10質量%,較佳為1.0~8.0質量%,更佳為2.0~7.0質量%。 <38> 如上述<35>至<37>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物,其中上述低級醇較佳為乙醇。<28> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <27>, wherein the emulsified composition contains I: sorbitan fatty acid ester, and The content of the sorbitan fatty acid ester is 0.5% by mass or more, preferably 1.0% by mass or more, and more preferably 1.5% by mass or more. <29> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <28>, wherein the emulsified composition contains I: sorbitan fatty acid ester, and The content of the sorbitan fatty acid ester is 5.0% by mass or less, preferably 4.0% by mass or less, and more preferably 3.5% by mass or less. <30> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <29>, wherein the emulsified composition contains I: sorbitan fatty acid ester, and The content of the sorbitan fatty acid ester is 0.5 to 5.0% by mass, preferably 1.0 to 4.0% by mass, and more preferably 1.5 to 3.5% by mass. <31> As described in any one of the above <28> to <30>, the cake dough foaming water-in-oil type emulsified composition, wherein the fatty acid constituting the sorbitan fatty acid ester is preferably lauric acid, myristic acid, palmitic acid, Stearic acid, oleic acid, behenic acid, or erucic acid is more preferably saturated fatty acid, and more preferably stearic acid. <32> The oil-in-oil emulsified composition in water for frothing cake dough as described in any one of the above <1> to <31>, wherein the emulsified composition contains J: Phospholipids, and The content of the phospholipid is 0% by mass or more, preferably 0.05% by mass or more, more preferably 0.10% by mass or more. <33> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <32>, wherein the emulsified composition contains J: Phospholipids, and The content of the phospholipid is 1.0% by mass or less, preferably 0.80% by mass or less, and more preferably 0.50% by mass or less. <34> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <33>, wherein the emulsified composition contains J: Phospholipids, and The content of the phospholipid is 0 to 1.0% by mass, preferably 0.05 to 0.80% by mass, and more preferably 0.10 to 0.50% by mass. <35> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <34>, wherein the emulsified composition contains K: lower alcohol, and The content of the lower alcohol is 0% by mass or more, preferably 1.0% by mass or more, more preferably 2.0% by mass or more. <36> The oil-based emulsified composition in water for foaming cake dough as described in any one of the above <1> to <35>, wherein the emulsified composition contains K: lower alcohol, and The content of the lower alcohol is 10% by mass or less, preferably 8.0% by mass or less, and more preferably 7.0% by mass or less. <37> The oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <36>, wherein the emulsified composition contains K: lower alcohol, and The content of the lower alcohol is 0-10% by mass, preferably 1.0-8.0% by mass, more preferably 2.0-7.0% by mass. <38> The oil-in-oil type emulsified composition in water for frothing cake dough as described in any one of the above <35> to <37>, wherein the above-mentioned lower alcohol is preferably ethanol.

<39> 一種蛋糕,其係對包含如上述<1>至<38>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物之蛋糕麵團進行烘烤而獲得。 <40> 一種蛋糕之製造方法,其包含將如上述<1>至<38>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物調配於麵團中而製備蛋糕麵團,並對該蛋糕麵團進行烘烤。 <41> 如上述<40>項記載之蛋糕之製造方法,其中上述蛋糕麵團為至少調配穀粉、及相對於該穀粉100質量份為50~300質量份之蛋、20~250質量份之糖類、3~100質量份之如上述<1>至<38>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物者,較佳為調配相對於穀粉100質量份為80~250質量份之蛋、50~180質量份之糖類、及5~50質量份之如上述<1>至<38>中任一項記載之蛋糕麵團起泡用水中油型乳化組合物者。 [實施例]<39> A cake obtained by baking a cake dough containing the oil-based emulsified composition in water for frothing cake dough as described in any one of the above <1> to <38>. <40> A method for manufacturing a cake, which comprises mixing the cake dough foaming water-in-oil type emulsified composition as described in any one of the above <1> to <38> in the dough to prepare a cake dough, and baking the cake dough grilled. <41> The method for manufacturing a cake as described in the above item <40>, wherein the cake dough comprises at least blending of cereal flour, 50 to 300 parts by mass of eggs, 20 to 250 parts by mass of sugar, and 3 to 100 parts by mass of the cereal flour. The mass parts of the cake dough foaming water-in-oil type emulsified composition as described in any one of the above <1> to <38> is preferably blended with 80 to 250 parts by mass of eggs and 50 parts by mass relative to 100 parts by mass of cereal flour -180 parts by mass of sugars, and 5-50 parts by mass of the cake dough foaming water-in-oil type emulsified composition as described in any one of the above <1> to <38>. [Example]

以下基於實施例詳細地說明本發明,但本發明並不限定於該等。The present invention will be described in detail below based on examples, but the present invention is not limited to these.

[製備例1 水中油型乳化組合物之製備] 將飽和單醯甘油(商品名:EXCEL VS-95,甘油單硬脂酸酯,花王股份有限公司製造)、山梨醇酐脂肪酸酯(商品名:Emasol S-10VHL,山梨醇酐單硬脂酸酯,花王股份有限公司製造,或商品名:Emasol S-30V,山梨醇酐三硬脂酸酯,花王股份有限公司製造)、丙二醇脂肪酸酯(商品名:Grinstead PGMB,丙二醇單山萮酸酯,Danisco製造)、脂肪酸(商品名:Lunac BA,山萮酸,花王股份有限公司製造)、卵磷脂(商品名:Yelkin TS,大豆卵磷脂,ADM公司製造)、聚氧乙烯山梨醇酐脂肪酸酯(商品名:Emasol S-120V,花王股份有限公司製造)、及菜籽油(商品名:菜籽精製油,Nisshin OilliO Group股份有限公司製造),以下述表1所示之比率進行混合,加熱至80℃並進行攪拌溶解,藉此製備用以形成油相之油脂組合物。 再者,表1之上欄中記載之各成分之數值表示將油相成分與水相成分之合計設為100質量%時之質量%。[Preparation Example 1 Preparation of oil-in-water emulsified composition] Saturated monoglycerin (trade name: EXCEL VS-95, glycerol monostearate, manufactured by Kao Co., Ltd.), sorbitan fatty acid ester (trade name: Emsol S-10VHL, sorbitan monostearate) Ester, manufactured by Kao Co., Ltd., or trade name: Emsol S-30V, sorbitan tristearate, manufactured by Kao Co., Ltd., propylene glycol fatty acid ester (trade name: Grinstead PGMB, propylene glycol monobehenate , Manufactured by Danisco), fatty acids (trade name: Lunac BA, behenic acid, manufactured by Kao Co., Ltd.), lecithin (trade name: Yelkin TS, soybean lecithin, manufactured by ADM), polyoxyethylene sorbitan fatty acid Ester (trade name: Emsol S-120V, manufactured by Kao Co., Ltd.) and rapeseed oil (trade name: rapeseed refined oil, manufactured by Nisshin OilliO Group Co., Ltd.) were mixed at the ratio shown in Table 1 below, Heat to 80°C and stir to dissolve, thereby preparing a grease composition for forming an oil phase. In addition, the numerical value of each component described in the upper column of Table 1 shows the mass% when the sum of the oil phase component and the water phase component is 100 mass %.

將蔗糖脂肪酸酯(商品名:Ryoto Sugar Ester S-1170S,蔗糖硬脂酸酯(單酯55%,二、三、聚酯45%),Mitsubishi Chemical Foods股份有限公司製造)、水(離子交換水)、山梨糖醇(商品名:山梨糖醇(固形物成分70%),花王股份有限公司製造)、糖醇(商品名:SWEET OL(固形物成分70%,原料DE45),還原飴糖,B Food Science公司製造)、精製甘油(商品名:甘油,花王股份有限公司製造)、乙醇(商品名:Traceable95,Japan Alcohol Industry Business公司製造)、微晶纖維素(商品名:Ceolus RC-N30,旭化成股份有限公司製造)、三仙膠(商品名:BISTOP D-3000,San-Ei Gen F.F.I公司製造),以下述表1所示之比率進行混合,調溫至80℃後,於槳120 rpm、均質攪拌機1500 rpm之條件下進行5分鐘攪拌溶解,藉此獲得用以形成水相之水溶液。 再者,表1之上欄中記載之各成分之數值表示將油相成分與水相成分之合計設為100質量%時之質量%。Sucrose fatty acid ester (trade name: Ryoto Sugar Ester S-1170S, sucrose stearate (monoester 55%, di-, tri-, polyester 45%), manufactured by Mitsubishi Chemical Foods Co., Ltd.), water (ion exchange Water), sorbitol (trade name: sorbitol (solid content 70%), manufactured by Kao Co., Ltd.), sugar alcohol (trade name: SWEET OL (solid content 70%, raw material DE45), reduced caramel, B Food Science Corporation), refined glycerin (trade name: glycerin, manufactured by Kao Co., Ltd.), ethanol (trade name: Traceable 95, manufactured by Japan Alcohol Industry Business), microcrystalline cellulose (trade name: Ceolus RC-N30, Asahi Kasei Co., Ltd.), Sanxian gum (trade name: BISTOP D-3000, manufactured by San-Ei Gen FFI Co., Ltd.), mixed at the ratio shown in Table 1 below, adjusted to 80°C, and set at 120 rpm. , Stir and dissolve for 5 minutes under the condition of 1500 rpm in a homomixer to obtain an aqueous solution for forming the water phase. In addition, the numerical value of each component described in the upper column of Table 1 shows the mass% when the sum of the oil phase component and the water phase component is 100 mass %.

一面將上述油脂組合物緩慢地添加至上述水溶液中,一面使用真空乳化機(PRIMIX公司製造,2M-03型公司製造),於80℃、槳120 rpm、均質攪拌機1500 rpm之條件進行10分鐘攪拌乳化,獲得水中油型乳化組合物(本發明品1~9、比較品1~13)。將所獲得之各乳化組合物冷卻至20℃後,用於下述之試驗例。 於表1中,對照表示各乳化組合物中之以飽和脂肪酸為結構脂肪酸之單醯甘油(成分A)、碳數6以上之糖醇(成分B)、蔗糖脂肪酸酯(成分C)、水(成分D)、甘油(成分E)、油脂(成分F)、丙二醇脂肪酸酯(成分G)、脂肪酸(成分H)之各含量(單位:質量%),進而亦對照表示成分B之含量與成分E之含量之合計值、成分C之含量相對於成分A之含量之比率(C/A、質量比)、及成分E之含量相對於成分B之含量之比率(E/B、質量比)。While slowly adding the above-mentioned oil and fat composition to the above-mentioned aqueous solution, a vacuum emulsifier (manufactured by PRIMIX Corporation, manufactured by 2M-03 type company) was used for 10 minutes under the conditions of 80°C, 120 rpm paddle and 1500 rpm of the homomixer Emulsify to obtain an oil-in-water emulsion composition (products 1 to 9 of the present invention, and comparative products 1 to 13). After cooling each obtained emulsion composition to 20 degreeC, it used for the following test example. In Table 1, the control indicates the monoglycerin (component A) with saturated fatty acid as the structural fatty acid, the sugar alcohol with 6 or more carbons (component B), the sucrose fatty acid ester (component C), water The contents (unit: mass %) of (component D), glycerin (component E), oil (component F), propylene glycol fatty acid ester (component G), and fatty acid (component H) (unit: mass %). The total value of the content of component E, the ratio of the content of component C to the content of component A (C/A, mass ratio), and the ratio of the content of component E to the content of component B (E/B, mass ratio) .

[試驗例1 起泡性試驗] 於蛋(生雞蛋)200 g中添加綿白糖180 g,一面使用桌上攪拌機(HOBART公司製造之N-50,攪打器:N-5D)以低速進行攪拌,一面加溫至20℃。添加上述製備例1中製作之乳化組合物(本發明品1~9、或比較品1~13)30 g、及水50 g,以中速攪拌1分鐘。添加低筋麵粉(日清製粉公司製造)200 g,以低速攪拌1分鐘後,以中速攪拌9分鐘,獲得蛋糕麵團。將所獲得之蛋糕麵團移至108 ml之杯中快速地計量,算出蛋糕麵團之比重(容積比重,單位:g/cm3 ),對起泡性進行評價。該比重越小,意指攪拌後之蛋糕麵團之膨脹越大,意指起泡性越高。 再者,上述乳化組合物使用剛製造後(1~3天後)者,其次使用製造後於20℃下保存30天(30 d)者,最後使用製造後於40℃下保存40天(40 d)者,於蛋糕麵團之比重超過0.43 g/cm3 之情形時,設為不進行下述試驗者。 將結果示於下述表1。[Test Example 1 Foaming test] Add 180 g of soft sugar to 200 g of eggs (raw eggs), and stir at low speed with a table mixer (N-50 manufactured by HOBART, beater: N-5D) , And heat up to 20°C. 30 g of the emulsified composition (products 1 to 9 of the present invention or comparative products 1 to 13) prepared in the above preparation example 1 and 50 g of water were added, and stirred at a medium speed for 1 minute. 200 g of low-gluten flour (manufactured by Nisshin Flour Co., Ltd.) was added and stirred at a low speed for 1 minute, and then stirred at a medium speed for 9 minutes to obtain a cake dough. Move the obtained cake dough to a 108 ml cup and quickly measure it, calculate the specific gravity of the cake dough (volume specific gravity, unit: g/cm 3 ), and evaluate the foamability. The smaller the specific gravity, the greater the expansion of the cake dough after mixing, and the higher the foaming property. In addition, the above-mentioned emulsified composition was used immediately after manufacture (1 to 3 days later), the second used was stored at 20°C for 30 days (30 d) after manufacturing, and the last used was stored at 40°C for 40 days (40 For d), when the specific gravity of the cake dough exceeds 0.43 g/cm 3, it is assumed that the following test is not performed. The results are shown in Table 1 below.

[表1-1] 表1-1    本發明品 比較品 1 2 3 4 5 6 7 8 9 1 2 調配原料 [質量%] 油相 飽和單醯甘油 7.0% 8.7% 7.0% 8.4% 7.0% 7.0% 7.0% 5.2% 7.7% 7.0% 7.0% 山梨醇酐脂肪酸酯(*1) 2.0% 2.0% 2.0% 2.4% 2.0% 2.0% 2.0% 3.4% 2.2% 2.0% 2.0% 山梨醇酐脂肪酸酯(*2)    1.7%                            丙二醇脂肪酸酯 3.4%    3.4% 4.1% 3.4% 3.4% 3.4% 2.0% 5.4% 3.4% 3.4% 脂肪酸 0.30% 0.30% 0.30% 0.36% 0.30% 0.30% 0.30%    0.33% 0.3% 0.3% 卵磷脂(含油分38%) 0.20% 0.20% 0.20% 0.24% 1.20% 0.20% 0.20%    0.22% 2.2% 0.2% 聚氧乙烯山梨醇酐脂肪酸酯                                  菜籽油                                  水相 蔗糖脂肪酸酯 4.2% 4.2% 4.2% 5.0% 3.2% 4.2% 4.2% 6.5% 4.6% 2.2% 4.2% 23.1% 23.1% 24.6% 23.4% 23.1% 23.1% 26.9% 24.6% 23.4% 23.1% 30.8% 山梨糖醇(固形物成分量) 53.8% 53.8% 43.1% 41.0% 53.8%    26.9% 43.1% 41.0% 53.8%    糖醇(固形物成分量)                53.8%                精製甘油       9.2% 8.8%       23.1% 9.2% 8.8%    46.1% 乙醇 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 微晶纖維素          0.2%             0.2%       三仙膠          0.075%             0.075%       合計※ 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100%    成分組成(組合物中之質量%) A:以飽和脂肪酸為結構脂肪酸之單醯甘油 7.0% 8.7% 7.0% 8.4% 7.0% 7.0% 7.0% 5.2% 7.7% 7.0% 7.0% B:碳數6以上之糖醇 53.8% 53.8% 43.1% 41.0% 53.8% 53.8% 26.9% 43.1% 41.0% 53.8% 0.0% C:蔗糖脂肪酸酯 4.2% 4.2% 4.2% 5.0% 3.2% 4.2% 4.2% 6.5% 4.6% 2.2% 4.2% D:水 23.1% 23.1% 24.6% 23.4% 23.1% 23.1% 26.9% 24.6% 23.4% 23.1% 30.8% E:甘油 0.0% 0.0% 9.2% 8.8% 0.0% 0.0% 23.1% 9.2% 8.8% 0.0% 46.1% F:油脂之含量 0.08% 0.08% 0.08% 0.09% 0.46% 0.08% 0.08% 0.00% 0.08% 0.84% 0.08% G:丙二醇脂肪酸酯 3.4% 0.0% 3.4% 4.1% 3.4% 3.4% 3.4% 2.0% 5.4% 3.4% 3.4% H:脂肪酸 0.3% 0.3% 0.3% 0.4% 0.3% 0.3% 0.3% 0.0% 0.3% 0.3% 0.3% B之含量+E之含量 53.8% 53.8% 52.3% 49.8% 53.8% 53.8% 50.0% 52.2% 49.8% 53.8% 46.1% 比率 (質量比) C之含量/A之含量 0.60 0.48 0.60 0.60 0.46 0.60 0.60 1.25 0.60 0.31 0.60 E之含量/B之含量 0.00 0.00 0.21 0.22 0.00 0.00 0.86 0.21 0.22 0.00 -    起泡性 評價 (比重) 剛製備後 0.35 0.35 0.31 0.31 0.35 0.34 0.35 0.38 0.32 0.36 0.33 20℃30 d 0.35 0.36 0.33 0.30 0.36 0.38 0.33 0.38 0.32 0.37 0.47 40℃40 d 0.36 0.39 0.31 0.32 0.42 0.31 0.31 0.33 0.32 0.46 - *1:Emasol S-10VHL *2:Emasol S-30V (※有因小數點以下之第2位之四捨五入之關係,合計無法嚴格成為100%之情況。以下之表亦相同) [Table 1-1] Table 1-1 Product of the invention Comparison 1 2 3 4 5 6 7 8 9 1 2 Blending raw materials [mass%] Oil phase Saturated monoglycerin 7.0% 8.7% 7.0% 8.4% 7.0% 7.0% 7.0% 5.2% 7.7% 7.0% 7.0% Sorbitan fatty acid ester (*1) 2.0% 2.0% 2.0% 2.4% 2.0% 2.0% 2.0% 3.4% 2.2% 2.0% 2.0% Sorbitan fatty acid ester (*2) 1.7% Propylene Glycol Fatty Acid Ester 3.4% 3.4% 4.1% 3.4% 3.4% 3.4% 2.0% 5.4% 3.4% 3.4% fatty acid 0.30% 0.30% 0.30% 0.36% 0.30% 0.30% 0.30% 0.33% 0.3% 0.3% Lecithin (38% oil content) 0.20% 0.20% 0.20% 0.24% 1.20% 0.20% 0.20% 0.22% 2.2% 0.2% Polyoxyethylene sorbitan fatty acid ester Canola oil water box Sucrose Fatty Acid Ester 4.2% 4.2% 4.2% 5.0% 3.2% 4.2% 4.2% 6.5% 4.6% 2.2% 4.2% water 23.1% 23.1% 24.6% 23.4% 23.1% 23.1% 26.9% 24.6% 23.4% 23.1% 30.8% Sorbitol (solid content) 53.8% 53.8% 43.1% 41.0% 53.8% 26.9% 43.1% 41.0% 53.8% Sugar alcohol (solid content) 53.8% Refined glycerin 9.2% 8.8% 23.1% 9.2% 8.8% 46.1% Ethanol 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% Microcrystalline cellulose 0.2% 0.2% Sanxian Gum 0.075% 0.075% total※ 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% Composition (mass% in the composition) A: Monoglycerin with saturated fatty acid as structural fatty acid 7.0% 8.7% 7.0% 8.4% 7.0% 7.0% 7.0% 5.2% 7.7% 7.0% 7.0% B: Sugar alcohol with carbon number 6 or more 53.8% 53.8% 43.1% 41.0% 53.8% 53.8% 26.9% 43.1% 41.0% 53.8% 0.0% C: Sucrose fatty acid ester 4.2% 4.2% 4.2% 5.0% 3.2% 4.2% 4.2% 6.5% 4.6% 2.2% 4.2% D: water 23.1% 23.1% 24.6% 23.4% 23.1% 23.1% 26.9% 24.6% 23.4% 23.1% 30.8% E: Glycerin 0.0% 0.0% 9.2% 8.8% 0.0% 0.0% 23.1% 9.2% 8.8% 0.0% 46.1% F: The content of fat 0.08% 0.08% 0.08% 0.09% 0.46% 0.08% 0.08% 0.00% 0.08% 0.84% 0.08% G: Propylene glycol fatty acid ester 3.4% 0.0% 3.4% 4.1% 3.4% 3.4% 3.4% 2.0% 5.4% 3.4% 3.4% H: Fatty acid 0.3% 0.3% 0.3% 0.4% 0.3% 0.3% 0.3% 0.0% 0.3% 0.3% 0.3% B content + E content 53.8% 53.8% 52.3% 49.8% 53.8% 53.8% 50.0% 52.2% 49.8% 53.8% 46.1% Ratio (mass ratio) Content of C/Content of A 0.60 0.48 0.60 0.60 0.46 0.60 0.60 1.25 0.60 0.31 0.60 E content/B content 0.00 0.00 0.21 0.22 0.00 0.00 0.86 0.21 0.22 0.00 - Foaming evaluation (specific gravity) Just after preparation 0.35 0.35 0.31 0.31 0.35 0.34 0.35 0.38 0.32 0.36 0.33 20℃30 d 0.35 0.36 0.33 0.30 0.36 0.38 0.33 0.38 0.32 0.37 0.47 40℃40 d 0.36 0.39 0.31 0.32 0.42 0.31 0.31 0.33 0.32 0.46 - *1: Emsol S-10VHL *2: Emsol S-30V (※There may be cases where the total cannot be strictly 100% due to rounding to the second digit below the decimal point. The following table is also the same)

[表1-2] 表1-2    比較品 3 4 5 6 7 8 9 10 11 12 13 調配原料 [質量%] 油相 飽和單醯甘油 8.7% 7.0% 7.0% 8.7% 7.0% 7.0% 7.0% 7.0% 7.0% 7.0% 6.2% 山梨醇酐脂肪酸酯(*1) 2.0% 2.0% 2.0% 2.0% 2.0% 2.0% 2.0% 2.0% 2.0% 2.0% 1.8% 山梨醇酐脂肪酸酯(*2) 1.7%       1.7%                      丙二醇脂肪酸酯    3.4% 3.4%    3.4% 3.4% 3.4% 3.4% 3.4% 3.4% 3.0% 脂肪酸 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 卵磷脂(含油分38%) 0.2% 2.2% 0.2% 2.2% 0.2% 0.2% 0.2% 2.2% 0.2% 0.2% 0.2% 聚氧乙烯山梨醇酐脂肪酸酯       2.0%    4.2%    4.2% 2.0% 2.0%       菜籽油                            20.0% 11.0% 水相 蔗糖脂肪酸酯 4.2% 2.2% 2.2% 2.2%             2.2% 4.2% 3.7% 30.8% 30.8% 23.1% 23.1% 30.8% 24.3% 23.1% 30.9% 30.8% 17.0% 21.8% 山梨糖醇(固形物成分量)       53.8% 53.8%    56.8% 53.8%       39.6% 38.2% 糖醇(固形物成分量)                                  精製甘油 46.1% 46.1%       46.1%       46.2% 46.1%    8.2% 乙醇 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 5.3% 微晶纖維素                            0.2% 0.2% 三仙膠                            0.1% 0.1% 合計 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100%    成分組成(組合物中之質量%) A:以飽和脂肪酸為結構脂肪酸之單醯甘油 8.7% 7.0% 7.0% 8.7% 7.0% 7.0% 7.0% 7.0% 7.0% 7.0% 6.2% B:碳數6以上之糖醇 0.0% 0.0% 53.8% 53.8% 0.0% 56.8% 53.8% 0.0% 0.0% 39.6% 38.2% C:蔗糖脂肪酸酯 4.2% 2.2% 2.2% 2.2% 0.0% 0.0% 0.0% 0.0% 2.2% 4.2% 3.7% D:水 30.8% 30.8% 23.1% 23.1% 30.8% 24.3% 23.1% 30.9% 30.8% 17.0% 21.8% E:甘油 46.1% 46.1% 0.0% 0.0% 46.1% 0.0% 0.0% 46.2% 46.1% 0.0% 8.2% F:油脂之含量 0.08% 0.84% 0.08% 0.84% 0.08% 0.08% 0.08% 0.84% 0.08% 20.1% 11.1% G:丙二醇脂肪酸酯 0.0% 3.4% 3.4% 0.0% 3.4% 3.4% 3.4% 3.4% 3.4% 3.4% 3.0% H:脂肪酸 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% B之含量+E之含量 46.1% 46.1% 53.8% 53.8% 46.1% 56.8% 53.8% 46.2% 46.1% 39.6% 46.4% 比率 (質量比) C之含量/A之含量 0.48 0.31 0.31 0.25 0.00 0.00 0.00 0.00 0.31 0.60 0.60 E之含量/B之含量 - - 0.00 0.00 - 0.00 0.00 - - 0.00 0.21    起泡性 評價 (比重) 剛製備後 0.36 0.36 0.39 0.40 0.38 0.67 0.59 0.50 0.47 0.48 0.44 20℃30 d 0.55 0.53 0.56 0.48 0.53 - - - - - - 40℃40 d - - - - - - - - - - - *1:Emasol S-10VHL *2:Emasol S-30V [Table 1-2] Table 1-2 Comparison 3 4 5 6 7 8 9 10 11 12 13 Blending raw materials [mass%] Oil phase Saturated monoglycerin 8.7% 7.0% 7.0% 8.7% 7.0% 7.0% 7.0% 7.0% 7.0% 7.0% 6.2% Sorbitan fatty acid ester (*1) 2.0% 2.0% 2.0% 2.0% 2.0% 2.0% 2.0% 2.0% 2.0% 2.0% 1.8% Sorbitan fatty acid ester (*2) 1.7% 1.7% Propylene Glycol Fatty Acid Ester 3.4% 3.4% 3.4% 3.4% 3.4% 3.4% 3.4% 3.4% 3.0% fatty acid 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% Lecithin (38% oil content) 0.2% 2.2% 0.2% 2.2% 0.2% 0.2% 0.2% 2.2% 0.2% 0.2% 0.2% Polyoxyethylene sorbitan fatty acid ester 2.0% 4.2% 4.2% 2.0% 2.0% Canola oil 20.0% 11.0% water box Sucrose Fatty Acid Ester 4.2% 2.2% 2.2% 2.2% 2.2% 4.2% 3.7% water 30.8% 30.8% 23.1% 23.1% 30.8% 24.3% 23.1% 30.9% 30.8% 17.0% 21.8% Sorbitol (solid content) 53.8% 53.8% 56.8% 53.8% 39.6% 38.2% Sugar alcohol (solid content) Refined glycerin 46.1% 46.1% 46.1% 46.2% 46.1% 8.2% Ethanol 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 5.3% Microcrystalline cellulose 0.2% 0.2% Sanxian Gum 0.1% 0.1% total 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% 100% Composition (mass% in the composition) A: Monoglycerin with saturated fatty acid as structural fatty acid 8.7% 7.0% 7.0% 8.7% 7.0% 7.0% 7.0% 7.0% 7.0% 7.0% 6.2% B: Sugar alcohol with carbon number 6 or more 0.0% 0.0% 53.8% 53.8% 0.0% 56.8% 53.8% 0.0% 0.0% 39.6% 38.2% C: Sucrose fatty acid ester 4.2% 2.2% 2.2% 2.2% 0.0% 0.0% 0.0% 0.0% 2.2% 4.2% 3.7% D: water 30.8% 30.8% 23.1% 23.1% 30.8% 24.3% 23.1% 30.9% 30.8% 17.0% 21.8% E: Glycerin 46.1% 46.1% 0.0% 0.0% 46.1% 0.0% 0.0% 46.2% 46.1% 0.0% 8.2% F: The content of fat 0.08% 0.84% 0.08% 0.84% 0.08% 0.08% 0.08% 0.84% 0.08% 20.1% 11.1% G: Propylene glycol fatty acid ester 0.0% 3.4% 3.4% 0.0% 3.4% 3.4% 3.4% 3.4% 3.4% 3.4% 3.0% H: Fatty acid 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% 0.3% B content + E content 46.1% 46.1% 53.8% 53.8% 46.1% 56.8% 53.8% 46.2% 46.1% 39.6% 46.4% Ratio (mass ratio) Content of C/Content of A 0.48 0.31 0.31 0.25 0.00 0.00 0.00 0.00 0.31 0.60 0.60 E content/B content - - 0.00 0.00 - 0.00 0.00 - - 0.00 0.21 Foaming evaluation (specific gravity) Just after preparation 0.36 0.36 0.39 0.40 0.38 0.67 0.59 0.50 0.47 0.48 0.44 20℃30 d 0.55 0.53 0.56 0.48 0.53 - - - - - - 40℃40 d - - - - - - - - - - - *1: Emsol S-10VHL *2: Emsol S-30V

根據上述表1明確可知,於使用比較品攪拌蛋糕麵團之情形時,於比較品8~13,自剛製造後起泡性較差(容積比重超過0.43 g/cm3 ),比較品2~7因於20℃下保存30天而起泡性受損(容積比重超過0.43 g/cm3 ),進而,比較品1因於40℃下保存40天,起泡性受損(容積比重超過0.43 g/cm3 )。另一方面,明確可知於使用本發明品製備蛋糕麵團之情形時,可獲得起泡性優異之蛋糕麵團,進而,即便於20℃下保存30天、或於40℃下保存40天後使用本發明品,起泡性亦優異(本發明品1~9)。It is clear from Table 1 above that when the comparative products are used for mixing cake dough, the comparative products 8-13 have poor foaming properties immediately after manufacture (the volumetric specific gravity exceeds 0.43 g/cm 3 ), and the comparative products 2-7 When stored at 20°C for 30 days, the foamability was impaired (the volume specific gravity exceeded 0.43 g/cm 3 ). Furthermore, the comparative product 1 was stored at 40°C for 40 days, and the foamability was impaired (the volume specific gravity exceeded 0.43 g/cm 3 ). cm 3 ). On the other hand, it is clearly known that when cake dough is prepared using the product of the present invention, cake dough with excellent foamability can be obtained, and furthermore, it can be used even after storage at 20°C for 30 days or 40°C at 40°C. The invention product is also excellent in foamability (the invention products 1 to 9).

[製備例2 水中油型乳化組合物之製備] 將飽和單醯甘油(商品名:EXCEL VS-95,花王股份有限公司製造)、山梨醇酐脂肪酸酯(商品名:Emasol S-10VHL,花王股份有限公司製造)、丙二醇脂肪酸酯(商品名:Grinstead PGMB,Danisco製造)、脂肪酸(商品名:Lunac BA,花王股份有限公司製造)、卵磷脂(商品名:Yelkin TS,ADM公司製造)、脂蛋白、及菜籽油(商品名:菜籽精製油,Nisshin OilliO Group股份有限公司製造),以下述表2所示之比率進行混合,加熱至80℃並進行攪拌溶解,藉此製備油相成分。 再者,表2之上欄中記載之各成分之數值表示將油相成分與水相成分之合計設為100質量%時之質量%。[Preparation Example 2 Preparation of oil-in-water emulsion composition] Saturated monoglycerin (trade name: EXCEL VS-95, manufactured by Kao Co., Ltd.), sorbitan fatty acid ester (trade name: Emsol S-10VHL, manufactured by Kao Co., Ltd.), and propylene glycol fatty acid ester (trade name) : Grinstead PGMB, manufactured by Danisco), fatty acids (trade name: Lunac BA, manufactured by Kao Co., Ltd.), lecithin (trade name: Yelkin TS, manufactured by ADM), lipoprotein, and rapeseed oil (trade name: rapeseed The refined oil (manufactured by Nisshin OilliO Group Co., Ltd.) was mixed at the ratio shown in Table 2 below, heated to 80°C and stirred and dissolved to prepare an oil phase component. In addition, the numerical value of each component described in the upper column of Table 2 shows the mass% when the sum of the oil phase component and the water phase component is 100 mass %.

將蔗糖脂肪酸酯(商品名:Ryoto Sugar Ester S-1170S,Mitsubishi Chemical Foods股份有限公司製造)、水(離子交換水)、山梨糖醇(商品名:山梨糖醇(固形物成分70%),花王股份有限公司製造)、液糖(商品名:高麥芽糖MC-45,糖分70質量%,以葡萄糖與麥芽糖為主成分之糖漿,日本食品化工股份有限公司製造)、異構化糖(商品名:Highsweet LI(固形物成分76%),大日本明治製糖股份有限公司製造)、精製甘油(商品名:甘油,花王股份有限公司製造)、乙醇(商品名:Traceable95,Japan Alcohol Industry Business公司製造)、微晶纖維素(商品名:Ceolus RC-N30,旭化成股份有限公司製造)、三仙膠(商品名:BISTOP D-3000,San-Ei Gen F.F.I公司製造),以下述表2所示之比率進行混合,調溫至80℃後,於槳120 rpm、均質攪拌機1500 rpm之條件下進行5分鐘攪拌溶解,藉此獲得水相成分。 再者,表2之上欄中記載之各成分之數值表示將油相成分與水相成分之合計設為100質量%時之質量%。Sucrose fatty acid ester (trade name: Ryoto Sugar Ester S-1170S, manufactured by Mitsubishi Chemical Foods Co., Ltd.), water (ion-exchanged water), and sorbitol (trade name: sorbitol (solid content 70%)), Kao Co., Ltd. manufacture), liquid sugar (trade name: high maltose MC-45, sugar content 70% by mass, glucose and maltose as main components of syrup, Nippon Food & Chemical Co., Ltd. manufacture), isomerized sugar (trade name : Highsweet LI (76% solid content), manufactured by Dai Nippon Meiji Sugar Co., Ltd., refined glycerin (trade name: glycerin, manufactured by Kao Co., Ltd.), ethanol (trade name: Traceable 95, manufactured by Japan Alcohol Industry Business) , Microcrystalline cellulose (trade name: Ceolus RC-N30, manufactured by Asahi Kasei Co., Ltd.), Sanxian gum (trade name: BISTOP D-3000, manufactured by San-Ei Gen FFI), at the ratio shown in Table 2 below After mixing, adjusting the temperature to 80°C, stirring and dissolving under the conditions of a paddle 120 rpm and a homomixer 1500 rpm for 5 minutes, thereby obtaining water phase components. In addition, the numerical value of each component described in the upper column of Table 2 shows the mass% when the sum of the oil phase component and the water phase component is 100 mass %.

一面將上述水相成分緩慢地添加至上述油相成分中,一面使用真空乳化機(PRIMIX公司製造,2M-03型公司製造),於80℃、槳120 rpm、均質攪拌機1,500 rpm之條件下進行10分鐘攪拌乳化,獲得水中油型乳化組合物(本發明品10、及比較品14)。將所獲得之各乳化組合物(本發明品10、及比較品14)、與上述製備例1中獲得之乳化組合物(比較品12及13)冷卻至20℃後,用於下述之試驗例。 於表2中,對照表示各乳化組合物中之以飽和脂肪酸為結構脂肪酸之單醯甘油(成分A)、碳數6以上之糖醇(成分B)、蔗糖脂肪酸酯(成分C)、水(成分D)、甘油(成分E)、油脂(成分F)、丙二醇脂肪酸酯(成分G)、脂肪酸(成分H)之各含量(單位:質量%),進而亦對照表示成分B之含量與成分E之含量之合計值、成分C之含量相對於成分A之含量之比率(C/A、質量比)、及成分E之含量相對於成分B之含量之比率(E/B、質量比)。While slowly adding the above water phase ingredients to the above oil phase ingredients, use a vacuum emulsifier (manufactured by PRIMIX Corporation, 2M-03 model company) at 80°C, paddle 120 rpm, and homogeneous mixer 1,500 rpm. It was stirred and emulsified for 10 minutes to obtain an oil-in-water type emulsified composition (product 10 of the present invention and comparative product 14). After cooling the obtained emulsified compositions (product 10 of the present invention and comparative product 14) and the emulsified compositions (comparative products 12 and 13) obtained in Preparation Example 1 above to 20°C, they were used in the following tests example. In Table 2, the control indicates the monoglycerol (component A) with saturated fatty acid as the structural fatty acid, the sugar alcohol with 6 or more carbons (component B), the sucrose fatty acid ester (component C), water in each emulsified composition The contents (unit: mass %) of (component D), glycerin (component E), oil (component F), propylene glycol fatty acid ester (component G), and fatty acid (component H) (unit: mass %). The total value of the content of component E, the ratio of the content of component C to the content of component A (C/A, mass ratio), and the ratio of the content of component E to the content of component B (E/B, mass ratio) .

[試驗例2 起泡性試驗] 於蛋(生雞蛋)260 g中,添加綿白糖210 g,一面利用桌上攪拌機(HOBART公司製造之N-50,攪打器:N-5D)進行攪拌一面加溫至20℃。添加上述製備例1及2中製作之乳化組合物(本發明品10、或比較品12~14)10 g、及水100 g,以中速攪拌1分鐘。添加低筋麵粉(日清製粉公司製造)200 g、及菜籽油20 g,以中速攪拌9分鐘,其後將蛋糕麵團移至108 ml之杯中快速計量而計算比重,對起泡性進行評價。 再者,上述乳化組合物使用剛製造後(1~3天後)者、製造後於40℃下保存40天(40 d)者、製造後於40℃下保存2個月(2 M)者、及製造後於40℃下保存3個月(3 M)者。 將結果示於下述表2。[Test Example 2 Foaming Test] To 260 g of eggs (raw eggs), 210 g of soft white sugar was added, and while stirring with a table mixer (N-50 manufactured by HOBART, beater: N-5D), the temperature was heated to 20°C. 10 g of the emulsified composition (product 10 of the present invention or comparative products 12-14) prepared in the above preparation examples 1 and 2 and 100 g of water were added, and stirred at a medium speed for 1 minute. Add 200 g of low-gluten flour (manufactured by Nisshin Flour Co., Ltd.) and 20 g of rapeseed oil, stir at medium speed for 9 minutes, then move the cake dough to a 108 ml cup and quickly measure the specific gravity. Make an evaluation. In addition, the above-mentioned emulsified composition used immediately after manufacture (1 to 3 days later), stored at 40°C for 40 days (40 d) after manufacture, and stored at 40°C for 2 months (2 M) after manufacture , And stored at 40°C for 3 months (3 M) after manufacture. The results are shown in Table 2 below.

[試驗例3 乳化組合物之變色試驗] 對上述製備例1及2中製備之乳化組合物(本發明品10、及比較品12~14),使用色差計(NIPPON DENSHOKU Color Meter ZE2000),以CIE表色系統(L 、a 、b )測量剛製造後與製造後於40℃下保存3個月時之色調。再者,於試驗中使用視感亮度(L )之值,L 之值越接近0,意指亮度越低(黑色越強),L 之值越接近100,意指亮度越高(白色越強)。又,對保存前後之乳化組合物之外觀藉由目視進行觀察。 將結果示於下述表2。[Test Example 3 Discoloration test of emulsified composition] The emulsified compositions prepared in the above preparation examples 1 and 2 (the present invention product 10 and the comparative products 12-14) were used with a color difference meter (NIPPON DENSHOKU Color Meter ZE2000) to The CIE color system (L , a , b ) measures the hue immediately after manufacture and after being stored at 40°C for 3 months. Furthermore, the value of visual brightness (L ) is used in the experiment. The closer the value of L is to 0, the lower the brightness (the stronger the black). The closer the value of L to 100, the higher the brightness ( The stronger the white). In addition, the appearance of the emulsified composition before and after storage was observed visually. The results are shown in Table 2 below.

[表2] 表2    本發明品 比較品 10 12 13 14 調配原料 [質量%] 油 相 飽和單醯甘油 7.0% 7.0% 6.2% 7.0% 山梨醇酐脂肪酸酯(*1) 2.0% 2.0% 1.8% 2.0% 丙二醇脂肪酸酯 3.4% 3.4% 3.0% 3.4% 脂肪酸 0.30% 0.30% 0.27% 0.30% 卵磷脂(含油分38%) 0.20% 0.20% 0.18% 0.20% 脂蛋白(含油分11%)          2.0% 菜籽油    20.0% 11.0% 23.2% 水 相 蔗糖脂肪酸酯 4.2% 4.2% 3.7% 4.2% 24.5% 17.0% 21.8% 27.4% 山梨糖醇(固形物成分量) 42.9% 39.6% 38.2%    液糖(固形物成分量)          23.6% 異構化糖(固形物成分量)          3.8% 精製甘油 9.2%    8.2%    乙醇 6.0% 6.0% 5.3% 2.6% 微晶纖維素 0.2% 0.2% 0.2% 0.2% 三仙膠 0.075% 0.1% 0.1% 0.075% 合計 100% 100% 100% 100%    成分組成 (組合物中之質量%) A:以飽和脂肪酸為結構脂肪酸之單醯甘油 7.0% 7.0% 6.2% 7.0% B:碳數6以上之糖醇 42.9% 39.6% 38.2% 0.0% C:蔗糖脂肪酸酯 4.2% 4.2% 3.7% 4.2% D:水 24.5% 17.0% 21.8% 27.4% E:甘油 9.2% 0.0% 8.2% 0.0% F:油脂之含量 0.08% 20.1% 11.1% 23.5% G:丙二醇脂肪酸酯 3.4% 3.4% 3.0% 3.4% H:脂肪酸 0.3% 0.3% 0.3% 0.3% B之含量+E之含量 52.1% 39.6% 46.4% 0.0% 比率 (質量比) C之含量/A之含量 0.60 0.60 0.60 0.60 E之含量/B之含量 0.21 0.0 0.21 -    起泡性 評價 (比重) 剛製備後 0.42 0.74 0.73 0.44 40℃40 d 0.42 0.76 0.72 0.46 40℃2 M 0.43 0.70 0.68 0.48 40℃3 M 0.42 0.74 0.70 0.50 色調(L*) 40℃保存前 59.1 54.9 61.2 63.6 40℃3 M保存品 59.7 54.3 60.0 59.0 -0.6 0.6 1.2 4.6 外觀 40℃3 M保存前後 無變化 無變化 無變化 褐變 *1:Emasol S-10VHL [Table 2] Table 2 Product of the invention Comparison 10 12 13 14 Blending raw materials [mass%] Oil phase Saturated monoglycerin 7.0% 7.0% 6.2% 7.0% Sorbitan fatty acid ester (*1) 2.0% 2.0% 1.8% 2.0% Propylene Glycol Fatty Acid Ester 3.4% 3.4% 3.0% 3.4% fatty acid 0.30% 0.30% 0.27% 0.30% Lecithin (38% oil content) 0.20% 0.20% 0.18% 0.20% Lipoprotein (11% oil content) 2.0% Canola oil 20.0% 11.0% 23.2% water box Sucrose Fatty Acid Ester 4.2% 4.2% 3.7% 4.2% water 24.5% 17.0% 21.8% 27.4% Sorbitol (solid content) 42.9% 39.6% 38.2% Liquid sugar (solid content) 23.6% Isomerized sugar (solid content) 3.8% Refined glycerin 9.2% 8.2% Ethanol 6.0% 6.0% 5.3% 2.6% Microcrystalline cellulose 0.2% 0.2% 0.2% 0.2% Sanxian Gum 0.075% 0.1% 0.1% 0.075% total 100% 100% 100% 100% Composition (mass% in the composition) A: Monoglycerin with saturated fatty acid as structural fatty acid 7.0% 7.0% 6.2% 7.0% B: Sugar alcohol with carbon number 6 or more 42.9% 39.6% 38.2% 0.0% C: Sucrose fatty acid ester 4.2% 4.2% 3.7% 4.2% D: water 24.5% 17.0% 21.8% 27.4% E: Glycerin 9.2% 0.0% 8.2% 0.0% F: The content of fat 0.08% 20.1% 11.1% 23.5% G: Propylene glycol fatty acid ester 3.4% 3.4% 3.0% 3.4% H: Fatty acid 0.3% 0.3% 0.3% 0.3% B content + E content 52.1% 39.6% 46.4% 0.0% Ratio (mass ratio) Content of C/Content of A 0.60 0.60 0.60 0.60 E content/B content 0.21 0.0 0.21 - Foaming evaluation (specific gravity) Just after preparation 0.42 0.74 0.73 0.44 40℃40 d 0.42 0.76 0.72 0.46 40℃2 M 0.43 0.70 0.68 0.48 40℃3 M 0.42 0.74 0.70 0.50 Hue (L*) Before storage at 40°C 59.1 54.9 61.2 63.6 40℃3 M preserved product 59.7 54.3 60.0 59.0 difference -0.6 0.6 1.2 4.6 Exterior Before and after storage at 40℃3 M No change No change No change Browning *1: Emsol S-10VHL

根據表2明確可知,於使用剛製造後、於40℃下保存40天後、於40℃下保存2個月後、或於40℃下保存3個月後之比較品14攪拌蛋糕麵團之情形時,起泡性較差,又,隨著40℃下之保存時間變長,攪拌後之蛋糕麵團之比重變大,起泡性受損。又,可知於比較品12及13時,即便於使用剛製造後者之情形時起泡性亦明顯差。進而,測量40℃保存前後之比較品14之色調,結果40℃保存前為63.6,相對於此,保存後為59.0,其差為4.6。該情況表示,因40℃3個月之保存,比較品之色調褐變。進而,藉由目視比較40℃保存前後之比較品14之色調,結果明確可知,比較品因於40℃下保存3個月,進行梅納(Maillard)反應等而產生褐變。 另一方面,於使用本發明品(本發明品10)攪拌蛋糕麵團之情形時,即便使用剛製造後、於40℃下保存40天後、於40℃下保存2個月後、或於40℃下保存3個月後者,攪拌後之蛋糕麵團之比重亦未見到差異,全部起泡性優異。進而,測量40℃保存前後之本發明品(本發明品10)之色調,結果40℃保存前為59.1,相對於此,保存後為59.7,保存前後色調幾乎未產生變化。進而,藉由目視比較40℃保存前後之本發明品(本發明品10)之色調,結果本發明品即便於40℃下保存3個月,外觀亦未產生變化。According to Table 2, it is clear that the comparative product 14 mixed with cake dough just after manufacturing, after 40 days of storage at 40°C, after 2 months of storage at 40°C, or after 3 months of storage at 40°C When the foaming is poor, and as the storage time at 40℃ becomes longer, the specific gravity of the cake dough after mixing becomes larger, and the foaming is impaired. In addition, it can be seen that in the case of the comparative products 12 and 13, the foaming property was significantly inferior even when the latter was used. Furthermore, the color tone of the comparative product 14 before and after storage at 40°C was measured. As a result, it was 63.6 before storage at 40°C, while it was 59.0 after storage, and the difference was 4.6. This situation indicates that the color of the comparison product has browned due to storage at 40°C for 3 months. Furthermore, by visually comparing the color tone of the comparative product 14 before and after storage at 40°C, it was clear that the comparative product had browning due to the Maillard reaction and the like after being stored at 40°C for 3 months. On the other hand, when using the product of the present invention (product 10 of the present invention) to mix cake dough, even if it is used immediately after manufacture, after storing at 40°C for 40 days, after storing at 40°C for 2 months, or at 40°C After storing the latter for 3 months at ℃, there was no difference in the specific gravity of the cake dough after mixing, and all the cake dough was excellent in foamability. Furthermore, the hue of the present invention (inventive product 10) before and after storage at 40°C was measured. As a result, it was 59.1 before storage at 40°C, compared to 59.7 after storage, and there was almost no change in the hue before and after storage. Furthermore, by visually comparing the color tone of the product of the present invention (the product of the present invention 10) before and after storage at 40°C, the appearance of the product of the present invention did not change even if it was stored at 40°C for 3 months.

[製備例3 水中油型乳化組合物之製備] 藉由與上述製備例2相同之方法,以下述表3所示之比率製備本發明品11、12、及比較品15。再者,表3之上欄中記載之各成分之數值表示將油相成分與水相成分之合計設為100質量%時之質量%。 又,於表3中,對照表示各乳化組合物中之以飽和脂肪酸為結構脂肪酸之單醯甘油(成分A)、碳數6以上之糖醇(成分B)、蔗糖脂肪酸酯(成分C)、水(成分D)、甘油(成分E)、油脂(成分F)、丙二醇脂肪酸酯(成分G)、脂肪酸(成分H)之各含量(單位:質量%),進而,亦對照表示成分B之含量與成分E之含量之合計值、成分C之含量相對於成分A之含量之比率(C/A、質量比)、及成分E之含量相對於成分B之含量之比率(E/B、質量比)。[Preparation Example 3 Preparation of oil-in-water emulsion composition] By the same method as the above-mentioned preparation example 2, the present invention products 11 and 12, and the comparative product 15 were prepared at the ratios shown in Table 3 below. In addition, the numerical value of each component described in the upper column of Table 3 shows the mass% when the sum of the oil phase component and the water phase component is 100 mass %. In addition, in Table 3, the comparison shows monoglycerin (component A) with saturated fatty acid as structural fatty acid, sugar alcohol with 6 or more carbon atoms (component B), and sucrose fatty acid ester (component C) in each emulsified composition , Water (component D), glycerin (component E), oil (component F), propylene glycol fatty acid ester (component G), and fatty acid (component H) contents (unit: mass %), and also indicated component B in comparison The total value of the content and the content of component E, the ratio of the content of component C to the content of component A (C/A, mass ratio), and the ratio of the content of component E to the content of component B (E/B, Quality ratio).

[試驗例3 起泡性試驗] 於蛋(生雞蛋)260 g中添加綿白糖210 g,一面使用桌上攪拌機(HOBART公司製造之N-50,攪打器:N-5D)進行攪拌一面加溫至20℃。添加上述製備例1中製作之乳化組合物(本發明品1、3、4、7)、上述製備例2中製作之乳化組合物(本發明品10)、或上述製備例3中製作之乳化組合物(本發明品11、12、比較品15)10 g、及水100 g,以中速攪拌1分鐘。添加低筋麵粉(日清製粉公司製造)200 g、及菜籽油20 g,以中速攪拌5、7、或9分鐘,獲得蛋糕麵團。將所獲得之蛋糕麵團移至108 ml之杯中快速計量,算出蛋糕麵團之比重(容積比重,單位:g/cm3 ),而對起泡性進行評價。 再者,上述乳化組合物使用剛製造後(1~3天後)者。[Test Example 3 Foaming Test] Add 210 g of soft white sugar to 260 g of eggs (raw eggs), and use a table mixer (N-50 manufactured by HOBART, beater: N-5D) while mixing. Warm to 20°C. Add the emulsified composition prepared in Preparation Example 1 above (products 1, 3, 4, 7 of the present invention), the emulsified composition prepared in Preparation Example 2 above (product 10 of the present invention), or the emulsified composition prepared in Preparation Example 3 above 10 g of the composition (products 11 and 12 of the present invention, and comparative product 15) and 100 g of water were stirred at a medium speed for 1 minute. Add 200 g of low-gluten flour (manufactured by Nissin Flour Co., Ltd.) and 20 g of rapeseed oil, and stir at medium speed for 5, 7, or 9 minutes to obtain cake dough. Move the obtained cake dough to a 108 ml cup and quickly measure it, calculate the specific gravity of the cake dough (volume specific gravity, unit: g/cm 3 ), and evaluate the foamability. In addition, the above-mentioned emulsified composition was used immediately after production (1 to 3 days later).

[試驗例4 乳化組合物之製劑物性試驗] 將上述製備例1中製作之乳化組合物(本發明品1、3、4、7)、上述製備例2中製作之乳化組合物(本發明品10)、或上述製備例3中製作之乳化組合物(本發明品11、12、比較品15),以不產生間隙之方式放入至容器(底面

Figure 02_image001
45 mm/上表面61 mm/高度47 mm之逆圓錐台狀杯)中,並利用刮刀使表面變得平坦。使用PENETROMETER RPM-101(離合公司製造),將金屬圓錐(類別1/1A,重量102.5 g)以與乳化組合物表面接觸之方式合併,使圓錐插入乳化組合物中5秒鐘,測定自乳化組合物表面至插入之圓錐之前端之深度。將插入之深度[mm]之10倍值設為稠度。 將結果與上述試驗例3之結果一併示於下述表3。[Test Example 4 Preparation property test of emulsified composition] The emulsified composition prepared in Preparation Example 1 above (products 1, 3, 4, and 7 of the present invention) and the emulsified composition prepared in Preparation Example 2 (product of the present invention) 10), or the emulsified composition (products 11 and 12 of the present invention, and comparative product 15) prepared in the above preparation example 3, put it in the container (bottom
Figure 02_image001
45 mm/upper surface 61 mm/height 47 mm in an inverted truncated cone-shaped cup), and use a scraper to make the surface flat. Using PENETROMETER RPM-101 (manufactured by Lihe Co., Ltd.), combine the metal cone (category 1/1A, weight 102.5 g) in contact with the surface of the emulsified composition, insert the cone into the emulsified composition for 5 seconds, and measure the self-emulsified composition The depth from the surface of the object to the front end of the inserted cone. Set the 10 times value of the inserted depth [mm] as the consistency. The results are shown in Table 3 below together with the results of Test Example 3 described above.

[表3] 表3    本發明品 比較品 1 3 4 7 10 11 12 15 調配原料 [質量%] 油 相 飽和單醯甘油 7.0% 7.0% 8.4% 7.0% 7.0% 8.0% 3.5% 4.3% 山梨醇酐脂肪酸酯(*1) 2.0% 2.0% 2.4% 2.0% 2.0% 2.3% 1.0% 2.0% 丙二醇脂肪酸酯 3.4% 3.4% 4.1% 3.4% 3.4% 5.2% 1.7% 3.4% 脂肪酸 0.30% 0.30% 0.36% 0.30% 0.30% 0.34% 0.15% 0.30% 卵磷脂(含油分38%) 0.20% 0.20% 0.24% 0.20% 0.20% 0.23% 0.10% 0.20% 脂蛋白(含油分11%)                         菜籽油                         水 相 蔗糖脂肪酸酯 4.2% 4.2% 5.0% 4.2% 4.2% 4.8% 2.1% 6.9% 23.1% 24.6% 23.4% 26.9% 24.5% 23.3% 27.2% 24.6% 山梨糖醇(固形物成分量) 53.8% 43.1% 41.0% 26.9% 42.9% 41.0% 47.9% 43.1% 液糖(固形物成分量)                         異構化糖(固形物成分量)                         精製甘油    9.2% 8.8% 23.1% 9.2% 8.8% 10.3% 9.2% 乙醇 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 微晶纖維素       0.2%    0.2%          三仙膠       0.075%    0.075%          合計 100% 100% 100% 100% 100% 100% 100% 100%    成分組成(組合物中之質量%) A:以飽和脂肪酸為結構脂肪酸之單醯甘油 7.0% 7.0% 8.4% 7.0% 7.0% 8.0% 3.5% 4.3% B:碳數6以上之糖醇 53.8% 43.1% 41.0% 26.9% 42.9% 41.0% 47.9% 43.1% C:蔗糖脂肪酸酯 4.2% 4.2% 5.0% 4.2% 4.2% 4.8% 2.1% 6.9% D:水 23.1% 24.6% 23.4% 26.9% 24.5% 23.3% 27.2% 24.6% E:甘油 0.0% 9.2% 8.8% 23.1% 9.2% 8.8% 10.3% 9.2% F:油脂之含量 0.08% 0.08% 0.09% 0.08% 0.08% 0.09% 0.04% 0.08% G:丙二醇脂肪酸酯 3.4% 3.4% 4.1% 3.4% 3.4% 5.2% 1.7% 3.4% H:脂肪酸 0.3% 0.3% 0.4% 0.3% 0.3% 0.3% 0.2% 0.3% B之含量+E之含量 53.8% 52.3% 49.8% 50.0% 52.1% 49.8% 58.1% 52.3% 比率 (質量比) C之含量/A之含量 0.60 0.60 0.60 0.60 0.60 0.60 0.60 1.60 E之含量/B之含量 0.00 0.21 0.22 0.86 0.21 0.21 0.21 0.21    製劑物性 評價 稠度 215 242 258 243 245 239 310 209 起泡性 評價 (比重) 攪拌5分鐘 0.65 0.52 0.47 0.58 0.49 0.51 0.60 0.74 攪拌7分鐘 0.57 0.46 0.43 0.53 0.44 0.46 0.55 0.67 攪拌9分鐘 0.53 0.43 0.41 0.49 0.42 0.43 0.52 0.61 *1:Emasol S-10VHL [table 3] table 3 Product of the invention Comparison 1 3 4 7 10 11 12 15 Blending raw materials [mass%] Oil phase Saturated monoglycerin 7.0% 7.0% 8.4% 7.0% 7.0% 8.0% 3.5% 4.3% Sorbitan fatty acid ester (*1) 2.0% 2.0% 2.4% 2.0% 2.0% 2.3% 1.0% 2.0% Propylene Glycol Fatty Acid Ester 3.4% 3.4% 4.1% 3.4% 3.4% 5.2% 1.7% 3.4% fatty acid 0.30% 0.30% 0.36% 0.30% 0.30% 0.34% 0.15% 0.30% Lecithin (38% oil content) 0.20% 0.20% 0.24% 0.20% 0.20% 0.23% 0.10% 0.20% Lipoprotein (11% oil content) Canola oil water box Sucrose Fatty Acid Ester 4.2% 4.2% 5.0% 4.2% 4.2% 4.8% 2.1% 6.9% water 23.1% 24.6% 23.4% 26.9% 24.5% 23.3% 27.2% 24.6% Sorbitol (solid content) 53.8% 43.1% 41.0% 26.9% 42.9% 41.0% 47.9% 43.1% Liquid sugar (solid content) Isomerized sugar (solid content) Refined glycerin 9.2% 8.8% 23.1% 9.2% 8.8% 10.3% 9.2% Ethanol 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% 6.0% Microcrystalline cellulose 0.2% 0.2% Sanxian Gum 0.075% 0.075% total 100% 100% 100% 100% 100% 100% 100% 100% Composition (mass% in the composition) A: Monoglycerin with saturated fatty acid as structural fatty acid 7.0% 7.0% 8.4% 7.0% 7.0% 8.0% 3.5% 4.3% B: Sugar alcohol with carbon number 6 or more 53.8% 43.1% 41.0% 26.9% 42.9% 41.0% 47.9% 43.1% C: Sucrose fatty acid ester 4.2% 4.2% 5.0% 4.2% 4.2% 4.8% 2.1% 6.9% D: water 23.1% 24.6% 23.4% 26.9% 24.5% 23.3% 27.2% 24.6% E: Glycerin 0.0% 9.2% 8.8% 23.1% 9.2% 8.8% 10.3% 9.2% F: The content of fat 0.08% 0.08% 0.09% 0.08% 0.08% 0.09% 0.04% 0.08% G: Propylene glycol fatty acid ester 3.4% 3.4% 4.1% 3.4% 3.4% 5.2% 1.7% 3.4% H: Fatty acid 0.3% 0.3% 0.4% 0.3% 0.3% 0.3% 0.2% 0.3% B content + E content 53.8% 52.3% 49.8% 50.0% 52.1% 49.8% 58.1% 52.3% Ratio (mass ratio) Content of C/Content of A 0.60 0.60 0.60 0.60 0.60 0.60 0.60 1.60 E content/B content 0.00 0.21 0.22 0.86 0.21 0.21 0.21 0.21 Evaluation of preparation properties Consistency 215 242 258 243 245 239 310 209 Foaming evaluation (specific gravity) Stir for 5 minutes 0.65 0.52 0.47 0.58 0.49 0.51 0.60 0.74 Stir for 7 minutes 0.57 0.46 0.43 0.53 0.44 0.46 0.55 0.67 Stir for 9 minutes 0.53 0.43 0.41 0.49 0.42 0.43 0.52 0.61 *1: Emsol S-10VHL

如上述表3所示,滿足本發明之規定之乳化組合物藉由設為含有甘油之形態(本發明品3、4、7、及10~12),可提高稠度。而且,於使用含有甘油之本發明之乳化組合物攪拌蛋糕麵團之情形時,所製備之蛋糕麵團之起泡性優異。 另一方面,不滿足本發明之規定之乳化組合物(比較品15)即便含有甘油,亦無法提高稠度,成為較硬之物性。進而,即便使用含有甘油之該乳化組合物(比較品15)製備蛋糕麵團,所獲得之麵團之比重亦較大,起泡性亦較差。As shown in the above Table 3, the emulsified composition satisfying the requirements of the present invention can increase its consistency by setting it to a form containing glycerin (products 3, 4, 7, and 10-12 of the present invention). Moreover, when the emulsified composition of the present invention containing glycerin is used to mix cake dough, the prepared cake dough has excellent foamability. On the other hand, even if the emulsified composition (Comparative Product 15) which does not satisfy the requirements of the present invention contains glycerin, the consistency cannot be increased, and the physical properties are relatively hard. Furthermore, even if cake dough is prepared using this emulsified composition containing glycerin (Comparative Product 15), the specific gravity of the obtained dough is relatively large, and the foamability is also poor.

[試驗例4 蛋糕之烘烤試驗] 於蛋(生雞蛋)200 g中添加綿白糖180 g,一面利用桌上攪拌機(HOBART公司製造之N-50,攪打器:N-5D)進行攪拌一面加溫至20℃。添加上述製備例1中製作之乳化組合物(本發明品3)、或上述製備例3中製作之乳化組合物(比較品15)30 g、及水50 g,以中速攪拌1分鐘。添加低筋麵粉(日清製粉公司製造)200 g,以低速攪拌1分鐘後,以中速攪拌直至比重成為0.36~0.37。其後,使所獲得之蛋糕麵團300 g流入至圓形鋼模具(模具6號)中,利用上火175℃、下火180℃之烤箱烘烤30分鐘而製造蛋糕,於20℃下放置冷卻一夜。 對所獲得之蛋糕,由5名專業官能檢查員根據下述評價基準評價食感。於專業官能檢查員間之評價有差異時,協議決定評價數值。[Test Example 4 Baking Test of Cake] Add 180 g of soft white sugar to 200 g of eggs (raw eggs). While stirring with a table mixer (N-50 manufactured by HOBART, whisk: N-5D), heat it to 20°C. Add 30 g of the emulsified composition prepared in Preparation Example 1 above (product 3 of the present invention) or the emulsified composition prepared in Preparation Example 3 above (comparative product 15) and 50 g of water, and stir at a medium speed for 1 minute. Add 200 g of low-gluten flour (manufactured by Nisshin Flour Co., Ltd.), stir at low speed for 1 minute, and stir at medium speed until the specific gravity becomes 0.36 to 0.37. Thereafter, 300 g of the obtained cake dough was poured into a round steel mold (mold No. 6), and baked in an oven with an upper fire of 175°C and a lower fire of 180°C for 30 minutes to make a cake. The cake was left to cool at 20°C. Overnight. For the obtained cake, 5 professional panelists evaluated the texture according to the following evaluation criteria. When there is a discrepancy in the evaluation between professional inspectors, the agreement determines the evaluation value.

-食感之評價基準- 3:鬆散性良好,無黏性且口溶感良好 2:鬆散性良好,但有黏性,稍難咽下 1:鬆散性較差,有較強之黏性,難以咽下 將結果示於表4。-Evaluation criteria for food texture- 3: Good looseness, no stickiness and good mouth melting 2: Good looseness, but sticky, slightly difficult to swallow 1: Poor looseness, strong viscosity, difficult to swallow The results are shown in Table 4.

[表4] 表4    本發明品 比較品 3 15 調配原料 [質量%] 油 相 飽和單醯甘油 7.0% 4.3% 山梨醇酐脂肪酸酯1(*1) 2.0% 2.0% 丙二醇脂肪酸酯 3.4% 3.4% 脂肪酸 0.30% 0.30% 卵磷脂(含油分38%) 0.20% 0.20% 水 相 蔗糖脂肪酸酯 4.2% 6.9% 24.6% 24.6% 山梨糖醇(固形物成分量) 43.1% 43.1% 精製甘油 9.2% 9.2% 乙醇 6.0% 6.0% 合計 100% 100%    成分組成(組合物中之質量%) A:以飽和脂肪酸為結構脂肪酸之單醯甘油 7.0% 4.3% B:碳數6以上之糖醇 43.1% 43.1% C:蔗糖脂肪酸酯 4.2% 6.9% D:水 24.6% 24.6% E:甘油 9.2% 9.2% F:油脂之含量 0.08% 0.08% G:丙二醇脂肪酸酯 3.4% 3.4% H:脂肪酸 0.3% 0.3% B之含量+E之含量 52.3% 52.3% 比率 (質量比) C之含量/A之含量 0.60 1.60 E之含量/B之含量 0.21 0.21    烘烤試驗 起泡時間 5min. 9min. 起泡後麵團比重 0.365 0.366 烘烤品 食感(口溶感) 3 2 *1:Emasol S-10VHL [Table 4] Table 4 Product of the invention Comparison 3 15 Blending raw materials [mass%] Oil phase Saturated monoglycerin 7.0% 4.3% Sorbitan fatty acid ester 1(*1) 2.0% 2.0% Propylene Glycol Fatty Acid Ester 3.4% 3.4% fatty acid 0.30% 0.30% Lecithin (38% oil content) 0.20% 0.20% water box Sucrose Fatty Acid Ester 4.2% 6.9% water 24.6% 24.6% Sorbitol (solid content) 43.1% 43.1% Refined glycerin 9.2% 9.2% Ethanol 6.0% 6.0% total 100% 100% Composition (mass% in the composition) A: Monoglycerin with saturated fatty acid as structural fatty acid 7.0% 4.3% B: Sugar alcohol with carbon number 6 or more 43.1% 43.1% C: Sucrose fatty acid ester 4.2% 6.9% D: water 24.6% 24.6% E: Glycerin 9.2% 9.2% F: The content of fat 0.08% 0.08% G: Propylene glycol fatty acid ester 3.4% 3.4% H: Fatty acid 0.3% 0.3% B content + E content 52.3% 52.3% Ratio (mass ratio) Content of C/Content of A 0.60 1.60 E content/B content 0.21 0.21 Baking test Bubble time 5min. 9min. Specific gravity of dough after foaming 0.365 0.366 Baked food texture (melting texture) 3 2 *1: Emsol S-10VHL

根據表4明確可知,於使用比較品15之乳化組合物製備蛋糕麵團之情形時,進行攪拌直至麵團比重成為0.36~0.37需要約9分鐘之時間。進而,結果為烘烤該蛋糕麵團而獲得之蛋糕之鬆散性良好,但有黏性,稍難咽下。另一方面,明確可知於使用本發明之乳化組合物(本發明品3)製備蛋糕麵團之情形時,進行攪拌直至麵團比重成為0.36~0.37需要之時間為約5分鐘,快速地發揮起泡性。進而,使用本發明之乳化組合物製備蛋糕麵團,對其進行烘烤而獲得之蛋糕之鬆散性良好,無黏性,口溶感亦良好。It is clear from Table 4 that when the emulsified composition of Comparative Product 15 is used to prepare cake dough, it takes about 9 minutes to stir until the specific gravity of the dough becomes 0.36 to 0.37. Furthermore, the result was that the cake obtained by baking the cake dough had good looseness, but it was sticky and was slightly difficult to swallow. On the other hand, it is clear that when the emulsified composition of the present invention (product 3 of the present invention) is used to prepare cake dough, it takes about 5 minutes to stir until the specific gravity of the dough becomes 0.36 to 0.37, and the foaming property is quickly exhibited. . Furthermore, the cake dough is prepared by using the emulsified composition of the present invention, and the cake obtained by baking it has good looseness, no stickiness, and good mouth melting.

如上所述,藉由使用本發明之乳化組合物,可獲得快速地起泡,進而起泡性亦優異之蛋糕麵團。又,本發明之乳化組合物即便長期保存亦無損起泡性,無變色,可長期維持穩定之起泡作用或者品質。進而,藉由使用本發明之乳化組合物製造蛋糕,可使蛋糕之鬆散性良好,成為口溶感良好之食感。As described above, by using the emulsified composition of the present invention, it is possible to obtain a cake dough that foams quickly and has excellent foamability. In addition, the emulsified composition of the present invention does not damage the foaming property even if it is stored for a long time, has no discoloration, and can maintain stable foaming effect or quality for a long time. Furthermore, by using the emulsified composition of the present invention to produce a cake, the looseness of the cake can be made good, and it can become a good texture in the mouth.

與該實施態樣一併說明本發明,但只要未特別指定,則不於說明之任一細節限定本發明,認為應該不違反隨附之申請專利範圍所示之發明之精神與範圍而廣泛地解釋。The present invention will be described together with this embodiment mode, but as long as it is not specified, the present invention will not be limited to any details of the description, and it should be considered that it should not violate the spirit and scope of the invention shown in the appended patent application. Explanation.

本案係主張基於在2018年10月10日於日本提出專利申請之日本專利特願2018-191702之優先權者,此處進行參照而將其內容作為本說明書之記載之一部分併入本文中。This case claims priority based on Japanese Patent Application No. 2018-191702 filed in Japan on October 10, 2018, and the content is incorporated herein by reference as part of the description of this specification.

Claims (6)

一種蛋糕麵團起泡用水中油型乳化組合物,其含有 A:以飽和脂肪酸為結構脂肪酸之單醯甘油、 B:碳數6以上之糖醇、 C:蔗糖脂肪酸酯、及 D:水,且 上述成分B之含量為20~65質量%,上述成分D之含量為10~30質量%,上述成分C之含量相對於上述成分A之含量之比之值以質量比計為0.45~1.5,油脂之含量為2.0質量%以下。An oil type emulsified composition in water for frothing cake dough, which contains A: Monoglycerin with saturated fatty acid as structural fatty acid, B: Sugar alcohol with carbon number 6 or more, C: Sucrose fatty acid ester, and D: water, and The content of the component B is 20-65% by mass, the content of the component D is 10-30% by mass, and the ratio of the content of the component C to the content of the component A is 0.45 to 1.5 in terms of mass ratio. The content is 2.0% by mass or less. 如請求項1之蛋糕麵團起泡用水中油型乳化組合物,其含有 E:甘油,且 上述成分B之含量與上述成分E之含量之合計為40~70質量%,上述成分E之含量相對於上述B之含量之比之值以質量比計為0.1~1。Such as the oil-type emulsified composition in water for frothing cake dough of claim 1, which contains E: Glycerin, and The total of the content of the component B and the content of the component E is 40 to 70% by mass, and the ratio of the content of the component E to the content of the B is 0.1 to 1 in terms of mass ratio. 如請求項1之蛋糕麵團起泡用水中油型乳化組合物,其含有 G:丙二醇脂肪酸酯,且 上述成分G之含量為1.5~5.5質量%。Such as the oil-type emulsified composition in water for frothing cake dough of claim 1, which contains G: propylene glycol fatty acid ester, and The content of the aforementioned component G is 1.5 to 5.5% by mass. 如請求項1之蛋糕麵團起泡用水中油型乳化組合物,其含有 H:脂肪酸,且 上述成分H之含量為0.1~1.0質量%。Such as the oil-type emulsified composition in water for frothing cake dough of claim 1, which contains H: fatty acid, and The content of the above component H is 0.1 to 1.0% by mass. 一種蛋糕,其係烘烤使用如請求項1至4中任一項之乳化組合物之蛋糕麵團而獲得。A cake obtained by baking cake dough using the emulsified composition of any one of claims 1 to 4. 一種蛋糕之製造方法,其包含將如請求項1至4中任一項之乳化組合物調配於麵團中而製備蛋糕麵團,並對該蛋糕麵團進行烘烤。A method for manufacturing a cake, which comprises mixing the emulsified composition according to any one of claims 1 to 4 in a dough to prepare a cake dough, and baking the cake dough.
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