JP7121239B2 - Oil-in-water emulsified fat composition for confectionery and cake dough - Google Patents

Oil-in-water emulsified fat composition for confectionery and cake dough Download PDF

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JP7121239B2
JP7121239B2 JP2018063473A JP2018063473A JP7121239B2 JP 7121239 B2 JP7121239 B2 JP 7121239B2 JP 2018063473 A JP2018063473 A JP 2018063473A JP 2018063473 A JP2018063473 A JP 2018063473A JP 7121239 B2 JP7121239 B2 JP 7121239B2
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仁 日下
幸子 田島
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Description

本発明は、種々のケーキの製造に用いられる水中油型の乳化形態を有する油脂組成物、およびこれを用いたケーキ生地に関する。より詳しくは、焼成や蒸し等の加熱処理を施してケーキを製造する際に、卵、砂糖、小麦粉等の原材料に添加して用いる油脂組成物、およびその際に得られるケーキ生地に関する。 TECHNICAL FIELD The present invention relates to a fat composition having an oil-in-water emulsified form, which is used in the production of various cakes, and a cake dough using the same. More specifically, the present invention relates to a fat and oil composition that is added to raw materials such as eggs, sugar, and wheat flour when producing cakes by heat treatment such as baking and steaming, and cake dough obtained at that time.

一般にケーキとは、卵、砂糖、小麦粉等の原材料を混合して得られた生地に、焼成や蒸し等の加熱処理を施して製造される菓子類のことである。原材料の配合や製造方法によって、様々な種類のケーキが存在する。中でも、生地比重の軽いケーキ生地は、卵白と砂糖とを起泡してメレンゲとし、これを砂糖や小麦粉などを含む卵黄生地に加える別立て法、または、卵を卵黄と卵白に分けずに、全卵に砂糖を加えて泡立てた後に、小麦粉や油脂などを加える共立て法によって製造される。これらの製造方法によってつくられるケーキは、シフォンケーキやスポンジケーキと呼ばれ、嵩比重の大きな外観とふんわりとした食感、良好な口溶けを持つことを特徴としており、広く一般に供されている。一方、これらの製造方法は、卵の起泡性能に強く依存しているため、卵の鮮度や作業時の気温などによって起泡作業の見極めが必要になること、また、時間の経過によっても気泡が崩壊するため起泡した生地を型に充填した後、オーブンや蒸し機などで加熱し、生地の骨格が形成されるまで短時間で作業する必要があるなど、非常に熟練性を要し、かつ大量にケーキ生地を作ることができないなど、作業性も非常に低いという問題点も抱えている。大量生産メーカーでは、熟練者の不足から、ケーキ生地が不安定な共立てケーキを大量生産することが困難であった。 In general, cakes are confectioneries made by mixing raw materials such as eggs, sugar, and wheat flour, and then subjecting the dough to heat treatment such as baking or steaming. There are various types of cakes depending on the composition of raw materials and manufacturing method. Among them, cake dough with a light dough specific gravity is made by whipping egg whites and sugar to make meringue, and adding this to egg yolk dough containing sugar and flour, or by separating eggs into egg yolks and egg whites. After adding sugar to whole eggs and whisking, it is produced by the kyoritsu method, which adds flour, oil, etc. The cakes produced by these production methods are called chiffon cakes or sponge cakes, and are widely available because of their high bulk density, fluffy texture, and good meltability in the mouth. On the other hand, these manufacturing methods strongly depend on the foaming performance of the egg, so it is necessary to determine the foaming process depending on the freshness of the egg and the temperature at the time of work. After filling the foamed dough into the mold, it is necessary to heat it in an oven or a steamer until the skeleton of the dough is formed. In addition, there is also a problem that the workability is very low, such as the inability to make a large amount of cake dough. Due to the lack of skilled workers, it was difficult for mass-production manufacturers to mass-produce kyoritsu cakes with unstable cake dough.

このような問題点に対して、起泡剤や、起泡性乳化油脂といわれる15~20質量%の大量の乳化剤が含まれる素材や、製菓用流動状ショートニングといわれる10~15質量%の大量の乳化剤が含まれる素材を用いる技術が開発された。このような技術の利用によって、オールインミックス法で生地を製造し、作業性、熟練性およびケーキ生地安定性を補い、大きなバッチサイズでケーキ生地を製造することや、連続ミキサーなどの連続ケーキ生地製造機を用いて、大量に生地を製造することにより対応している。 To address these problems, foaming agents, materials containing a large amount of 15 to 20% by mass of emulsifiers called foaming emulsified oils and fats, and large amounts of 10 to 15% by mass called fluid shortening for confectionery A technology has been developed that uses a material containing an emulsifier. By using such technology, it is possible to manufacture the dough by the all-in-mix method, supplement workability, skill and cake dough stability, manufacture cake dough in a large batch size, and use a continuous cake dough such as a continuous mixer. We deal with this by mass-producing fabrics using manufacturing machines.

しかしながら、このような乳化剤を多量に含む素材を用いてケーキ生地を起泡させ、製造したケーキは、乳化剤に由来する収斂味や苦味によって、ケーキ本来の良好な卵風味や食感を失うという結果を招く。このような洋菓子大量生産メーカーの環境とその状況に対して、消費者は天然物指向を高め、より良好な風味と、より良好な口溶けを厳しく要求するようになり、従来の乳化剤を多量に含む素材を用いたケーキでは、消費者を満足させることはできなくなってきた。このために、風味と食感に優れたケーキを、安価に安定的に消費者に提供するために、ケーキ本来の風味と食感を阻害する乳化剤を使用することなく、大量生産を可能とする製菓用素材とケーキの製造方法が要望されている。 However, the cake produced by foaming the cake dough using a material containing a large amount of such emulsifier loses the original good egg flavor and texture of the cake due to the astringent taste and bitterness derived from the emulsifier. invite. In response to the environment and circumstances of such mass-produced Western confectionery manufacturers, consumers have become more oriented toward natural products, and have come to strictly demand better flavor and better meltability in the mouth. It has become impossible to satisfy consumers with cakes using ingredients. For this reason, in order to stably provide consumers with cakes with excellent flavor and texture at a low cost, mass production is possible without using emulsifiers that inhibit the original flavor and texture of cakes. There is a need for a confectionery material and method for making cakes.

乳たんぱく質の主要構成成分に由来するカゼイネートは食品分野で幅広く使用されている。乳たんぱく質は約80%のカゼインと約20%の乳清タンパク質から構成されており、ここからアルカリ金属で中和し、カゼイネートとして利用されることが多い。カゼイネートはその分子中に極性領域と非極性領域を持つ両親媒性分子であること、また、疎水性相互作用により油/水界面へ吸着しやすいことから乳化作用を示し、乳飲料やホイップクリーム、コーヒーホワイトナー、アイスクリームなどに応用されている。また、カゼイネートは、乳清タンパク質に比べて、規則的な二次構造部分が少なく、加熱しても変性凝集することはない。しかし、食塩などの塩類を多く含む場合には加熱によって凝集が発生し、乳化作用が低下することが知られている(非特許文献1)。 Caseinates, which are the main components of milk protein, are widely used in the food industry. Milk protein consists of about 80% casein and about 20% whey protein, from which it is often neutralized with an alkali metal and used as caseinate. Caseinate is an amphiphilic molecule with polar and non-polar regions in its molecule, and it easily adsorbs to the oil/water interface due to hydrophobic interaction, so it exhibits emulsifying action and is used in milk drinks, whipped cream, It is applied to coffee whitener, ice cream, etc. In addition, caseinate has less regular secondary structure than whey protein, and does not denature and aggregate even when heated. However, it is known that when a large amount of salt such as common salt is contained, aggregation occurs due to heating, and the emulsifying action is reduced (Non-Patent Document 1).

特許文献1には、カゼイネートを含有する製菓用水中油型乳化組成物とそれを用いたケーキの製造方法が開示されている。この開示技術によって、カゼイネートを配合した組成物の作用によって乳化剤を含まずにオールインミックスでケーキを大量生産することが可能である。しかし、この方法では、乳化剤を含まずにケーキを製造するためには、小麦粉を澱粉に置き換えた生地に対してのみ効果が得られる。一般に、ケーキには小麦粉が使用されるが、小麦粉はケーキ生地中で吸水することによって、起泡性能が低下することが知られている。特許文献1は、小麦粉を澱粉に置き換えることで、起泡性能の低下が抑えているが、一方で、焼成後のケーキにざらつきや弾力が出ることや、澱粉の老化によって、経時的にソフトさが失われることなど、食感が悪化するという課題がある。これらの課題を解決させるためには、澱粉による置換率を下げる必要があり、具体的には小麦粉を澱粉に置換する量を小麦粉の50質量%以下とすることが必要である。したがって、ケーキの大量生産が可能なオールインミックス法において、乳化剤を使用しないで、風味と食感が良好なケーキを作ることのできる製菓用素材は未だ必ずしも十分満足できるまでに至っていないのが現状である。 Patent Document 1 discloses an oil-in-water emulsified composition for confectionery containing caseinate and a method for producing a cake using the same. According to this disclosed technology, it is possible to mass-produce cakes with an all-in-mix without containing an emulsifier by the action of a composition containing caseinate. However, this method is effective only for doughs in which starch is substituted for wheat flour in order to produce cakes without containing emulsifiers. Wheat flour is generally used for cakes, and it is known that wheat flour absorbs water in the cake dough, thereby reducing foaming performance. In Patent Document 1, by replacing wheat flour with starch, the deterioration of foaming performance is suppressed. There is a problem that the texture deteriorates, such as the loss of In order to solve these problems, it is necessary to lower the rate of replacement with starch. Specifically, the amount of wheat flour replaced with starch must be 50% by mass or less of the wheat flour. Therefore, in the all-in-mix method that enables mass production of cakes, the current situation is that confectionery materials that can make cakes with good flavor and texture without using emulsifiers are not necessarily fully satisfactory. is.

特開2000-03070号公報JP-A-2000-03070

藤田哲著,「食品の乳化(基礎と応用)」初版,幸書房,2006年2月発行,第376頁Tetsu Fujita, "Food Emulsification (Fundamentals and Applications)" First Edition, Saiwai Shobo, February 2006, pp. 376

上記の通り、本発明の課題は、乳化剤を使用せずに、良好な風味と食感を有する比重が軽い生地のケーキを安定かつ大量に生産することを可能にする水中油型乳化油脂組成物を提供すること、また、前記の製菓用水中油型乳化油脂組成物を用いるケーキの製造方法を提供することである。 As described above, an object of the present invention is to provide an oil-in-water emulsified fat composition that makes it possible to stably and mass-produce a dough cake having a good flavor and texture and a light specific gravity without using an emulsifier. and to provide a method for producing a cake using the oil-in-water emulsified fat composition for confectionery.

本発明者らは、上記の課題を解決するにあたって鋭意検討した結果、食塩凝集カゼイネート(すなわち、カゼイネート溶解液に食塩を加えて凝集させたもの)、食用油脂、および、糖質を特定量含有する水中油型乳化油脂組成物を用いることで、上記の課題を解決し得ることの知見を見出し、本発明を完成するに至った。
すなわち、本発明は下記の〔1〕および〔2〕である。
As a result of intensive studies conducted by the present inventors to solve the above problems, the present inventors found that salt-aggregated caseinate (i.e., aggregated caseinate by adding salt to a caseinate solution), edible oils and fats, and carbohydrates in specific amounts. By using an oil-in-water emulsified fat composition, the inventors have discovered that the above problems can be solved, and have completed the present invention.
That is, the present invention is the following [1] and [2].

〔1〕食塩凝集カゼイネート(a)、食用油脂(b)、糖質(c)および水(d)を含有し、食塩凝集カゼイネート(a)の含有量が1.0~10.0質量%、食用油脂(b)の含有量が30~65質量%、糖質(c)の含有量が10~45質量%、および水(d)の含有量が5~45質量%である製菓用水中油型乳化油脂組成物。
〔2〕前記の〔1〕に記載の製菓用水中油型乳化油脂組成物、小麦粉、澱粉および水を含有し、小麦粉と澱粉の合計100質量部に対して製菓用水中油型乳化油脂組成物の含有量が5~50質量部であるケーキ生地。
[1] Contains salt-aggregated caseinate (a), edible oil and fat (b), sugar (c) and water (d), and the content of salt-aggregated caseinate (a) is 1.0 to 10.0% by mass, Confectionery oil-in-water type containing 30 to 65% by mass of edible oil and fat, 10 to 45% by mass of carbohydrate (c), and 5 to 45% by mass of water (d) Emulsified fat composition.
[2] Containing the oil-in-water emulsified oil composition for confectionery described in [1] above, wheat flour, starch and water, and containing the oil-in-water emulsified oil composition for confectionery with respect to a total of 100 parts by mass of wheat flour and starch A cake dough having an amount of 5 to 50 parts by mass.

本発明によって、乳化剤を含有しなくとも、オールインミックス法で生地比重が0.6以下に起泡させることができる製菓用水中油型乳化油脂組成物が提供できるとともに、風味や食感が良好なケーキに用いるケーキ生地を提供できる。 INDUSTRIAL APPLICABILITY According to the present invention, it is possible to provide an oil-in-water emulsified fat composition for confectionery that can be foamed to a dough specific gravity of 0.6 or less by an all-in-mix method without containing an emulsifier, and has good flavor and texture. Cake dough for use in cakes can be provided.

本発明の水中油型乳化油脂組成物は、食塩凝集カゼイネート(a)、食用油脂(b)、糖質(c)および水(d)を含有する。以下に各成分について詳述する。
<食塩凝集カゼイネート(a)>
本発明に用いる食塩凝集カゼイネート(a)は、カゼイネート溶解液に食塩を加えて凝集させたものを分離して得られる。例えば、予め食塩を溶解した水溶液にカゼイネートを分散させ加熱溶解させたものを、噴霧乾燥するなどして粉末として、または、蒸気等を用いて直接、または間接的に加熱し滅菌した溶液として得ることができる。または、食塩存在下でカゼイネートを加熱溶解させたものを水相部として用いて本発明の乳化油脂組成物を調製する際に用事調製することも出来る。
特に、カゼイネートは上述したように疎水性領域と親水性領域をもつ両親媒性をもち、油/水界面では油層に吸着し、乳化作用を示す。同じく、気/水界面においても気層界面に吸着することはできるが、カゼイネートの吸着膜は弱いため安定性を示さないことが知られている。しかし、食塩を加えて加熱することで、カゼイネートは適度に電荷を失い、微凝集を起こす。これにより親水性領域の反発が抑えられ、気層界面に吸着した凝集カゼインの膜は厚く壊れにくくなり、ケーキ生地において起泡性能の向上に寄与すると考えられる。カゼイネートの凝集の程度は本発明の水中油型乳化油脂組成物を形成するにあたり非常に重要な要素である。
The oil-in-water emulsified fat composition of the present invention contains salt-aggregated caseinate (a), edible fat (b), sugar (c) and water (d). Each component is described in detail below.
<Salt-aggregated caseinate (a)>
The salt-aggregated caseinate (a) used in the present invention is obtained by adding salt to a caseinate solution and separating the aggregates. For example, caseinate is dispersed in an aqueous solution in which salt has been dissolved in advance, and the mixture is heated and dissolved to obtain a powder by spray drying, or a sterilized solution by directly or indirectly heating with steam or the like. can be done. Alternatively, caseinate may be heated and dissolved in the presence of common salt, and used as the aqueous phase to prepare the emulsified oil/fat composition of the present invention.
In particular, caseinate has amphipathic properties with a hydrophobic region and a hydrophilic region as described above, and adsorbs to the oil layer at the oil/water interface to exhibit an emulsifying action. Similarly, it is known that caseinate can adsorb to the air layer interface at the air/water interface, but does not exhibit stability due to the weak adsorption film of caseinate. However, by adding sodium chloride and heating, the caseinate moderately loses its electric charge and undergoes fine agglomeration. As a result, the repulsion of the hydrophilic region is suppressed, and the film of aggregated casein adsorbed on the air layer interface becomes thicker and less likely to break, which is thought to contribute to the improvement of the foaming performance of the cake dough. The degree of aggregation of caseinate is a very important factor in forming the oil-in-water emulsified fat composition of the present invention.

本発明の乳化油脂組成物に使用されるカゼイネートは特に制限はなく、例としては、ナトリウム塩、カリウム塩、カルシウム塩、マグネシウム塩などが挙げられる。これらのカゼイネートは、1種を単独で用いることができ、あるいは、2種以上を組み合わせて用いることもできる。カルシウム塩やマグネシウム塩などの2価イオン性の塩を用いる場合には、その溶解性のために、クエン酸塩やリン酸塩を、組成物中に0.05~0.5質量%添加することが好ましい。カゼイネートのうち、好ましくはナトリウム塩、カリウム塩であり、より好ましくはナトリウム塩である。 The caseinate used in the emulsified oil and fat composition of the present invention is not particularly limited, and examples thereof include sodium salts, potassium salts, calcium salts, magnesium salts and the like. These caseinates can be used singly or in combination of two or more. When divalent ionic salts such as calcium salts and magnesium salts are used, 0.05 to 0.5% by mass of citrates and phosphates are added to the composition for their solubility. is preferred. Of the caseinates, sodium salts and potassium salts are preferred, and sodium salts are more preferred.

本発明の乳化油脂組成物中の食塩凝集カゼイネートの含有量は1.0~10.0質量%であり、下限値としては、好ましくは2.0質量%以上であり、より好ましくは2.5質量%以上である。上限値としては、好ましくは8.0質量%以下であり、より好ましくは6.0質量%以下である。食塩凝集カゼイネートの配合量が1.0質量%未満では、卵の気泡を安定に保つことが困難になり、ケーキ生地の安定性に劣る。また、10.0質量%より多い場合には、糖質溶液に分散・溶解させる際に時間がかかり、タンパク質を由来とする粘度上昇が発生し、目的とする乳化油脂組成物を形成することができなくなる。 The content of salt-aggregated caseinate in the emulsified oil and fat composition of the present invention is 1.0 to 10.0% by mass, and the lower limit is preferably 2.0% by mass or more, more preferably 2.5%. It is mass % or more. The upper limit is preferably 8.0% by mass or less, more preferably 6.0% by mass or less. If the amount of salt-aggregated caseinate is less than 1.0% by mass, it becomes difficult to keep the air bubbles of the egg stable, and the stability of the cake dough is poor. On the other hand, when it is more than 10.0% by mass, it takes time to disperse and dissolve in the saccharide solution, the viscosity is increased due to the protein, and the desired emulsified oil and fat composition cannot be formed. become unable.

本発明において、食塩によるカゼイネートの凝集の程度は、色差計を用いて測定した透過率によって評価することができる。凝集の程度として、例えば、カゼイネートの6質量%水溶液において、透過率が4~40%となるように凝集させればよく、下限値としては、好ましくは5%以上であり、より好ましくは6%以上である。上限値としては、好ましくは35%以下であり、より好ましくは30%以下である。カゼイネートの凝集率を上記の透過率の範囲内で制御することで、気泡界面で安定な吸着膜を形成することができ、起泡によって生地比重が0.6以下まで軽い生地を提供することができる。
さらに、カゼイネートに対する食塩の比率(食塩配合量/カゼイネート配合量)は、0.2~1.0が望ましい。下限値としては、好ましくは0.25以上であり、より好ましくは0.3以上である。上限値としては、好ましくは0.8以下であり、より好ましくは0.6以下である。カゼイネートに対する食塩の比率を上記の範囲内とすることで、気泡界面で安定な吸着膜を形成することができ、起泡によって生地比重が0.6以下まで軽い生地を提供することができる。
In the present invention, the degree of aggregation of caseinate by salt can be evaluated by the transmittance measured using a color difference meter. As the degree of aggregation, for example, in a 6% by mass aqueous solution of caseinate, aggregation may be carried out so that the transmittance is 4 to 40%, and the lower limit is preferably 5% or more, more preferably 6%. That's it. The upper limit is preferably 35% or less, more preferably 30% or less. By controlling the aggregation rate of the caseinate within the range of the above permeability, it is possible to form a stable adsorption film at the bubble interface, and to provide a light dough with a specific gravity of 0.6 or less by foaming. can.
Further, the ratio of salt to caseinate (amount of salt mixed/amount of caseinate mixed) is desirably 0.2 to 1.0. The lower limit is preferably 0.25 or more, more preferably 0.3 or more. The upper limit is preferably 0.8 or less, more preferably 0.6 or less. By setting the ratio of salt to caseinate within the above range, a stable adsorption film can be formed at the bubble interface, and by foaming, a light dough with a specific gravity of 0.6 or less can be provided.

<食用油脂(b)>
本発明の油脂組成物に使用される食用油脂は、例えば、コーン油、菜種油、大豆油、綿実油、サフラワー油、米油、ゴマ油、オリーブ油、ヤシ油、カカオ脂、パーム油等の植物性油脂、乳脂、豚脂、牛脂、魚油などの動物性油脂、およびこれらの油脂を水素添加した硬化油、組成を分別した分別油、エステル交換したエステル油などが挙げられる。さらに、精製した脂肪酸などを用いた合成油、たとえば中鎖脂肪酸トリグリセリド等が挙げられる。これらの食用油脂のうち、油脂結晶の成長によって乳化破壊が起こり、乳化安定性が低下することを防止する点から、上昇融点が5℃以下であることが望ましい。上昇融点が5℃以下である食用油脂の例としては、コーン油、菜種油、大豆油、綿実油、サフラワー油、米油、ゴマ油、オリーブ油等が挙げられる。
本発明の乳化油脂組成物中の食用油脂の配合量は、30~65質量%であり、下限値としては、好ましくは35質量%以上であり、より好ましくは40質量%以上である。上限値としては、60質量%以下であり、より好ましくは55質量%以下である。食用油脂の含有量が30質量%未満では、ケーキ中の油脂分の量が不足し、油脂による旨みやしっとり感などの食感が低下する。含有量が65質量%を超えると、製菓用水中油型乳化油脂組成物の乳化状態が悪化するために、ケーキ生地の安定性や全卵の起泡性についても悪影響が生じる恐れがある。
<Edible oil (b)>
The edible oils and fats used in the oil and fat composition of the present invention are, for example, vegetable oils such as corn oil, rapeseed oil, soybean oil, cottonseed oil, safflower oil, rice oil, sesame oil, olive oil, coconut oil, cocoa butter, and palm oil. , milk fat, lard, beef tallow, fish oil, and other animal oils, hydrogenated oils obtained by hydrogenating these oils, fractionated oils obtained by fractionating the composition, ester oils obtained by transesterification, and the like. Furthermore, synthetic oils using refined fatty acids, such as medium-chain fatty acid triglycerides, and the like are included. Among these edible fats and oils, it is preferable that the rising melting point is 5° C. or less from the viewpoint of preventing emulsification failure due to growth of fat crystals and deterioration of emulsification stability. Examples of edible oils and fats having an elevated melting point of 5°C or less include corn oil, rapeseed oil, soybean oil, cottonseed oil, safflower oil, rice oil, sesame oil, and olive oil.
The amount of the edible oil/fat compounded in the emulsified oil/fat composition of the present invention is 30 to 65% by mass, and the lower limit is preferably 35% by mass or more, more preferably 40% by mass or more. The upper limit is 60% by mass or less, more preferably 55% by mass or less. If the edible oil content is less than 30% by mass, the amount of oil in the cake is insufficient, and texture such as umami and moistness due to oil is reduced. If the content exceeds 65% by mass, the emulsified state of the oil-in-water emulsified fat composition for confectionery deteriorates, which may adversely affect the stability of the cake dough and the foamability of the whole egg.

<糖質(c)>
本発明に使用される糖質に特に制限はなく、例としては、単糖類であるグルコース、ガラクトース、キシルロース、フルクトースや、二糖類であるスクロース、ラクトース、マルトース、トレハロースが挙げられる。また、三糖類以上の多糖類としては、オリゴ糖、水あめ、デキストリンなどの糖類、グリセリン、ジグリセリン、ポリグリセリン、エリスリトール、キシリトール、ソルビトール、マンニトール、イノシトールなどの糖アルコール、が挙げられる。
<Sugar (c)>
Carbohydrates used in the present invention are not particularly limited, and examples include monosaccharides such as glucose, galactose, xylulose and fructose, and disaccharides such as sucrose, lactose, maltose and trehalose. Examples of polysaccharides of trisaccharides or higher include sugars such as oligosaccharide, starch syrup and dextrin, and sugar alcohols such as glycerin, diglycerin, polyglycerin, erythritol, xylitol, sorbitol, mannitol and inositol.

上記のこれらの糖質は単独、または2つ以上を組み合わせて使用することができる。これらの糖質のうち、タンパク質の界面活性能を補助する能力が高い点からは、糖アルコールを使用することが望ましい。使用される糖アルコールの価数は、特に制限されないが、好ましくは3~8価であり、より好ましくは3~6価である。また、炭素数は、特に制限されないが、好ましくは3~8であり、より好ましくは3~6である。
糖アルコールとして、好ましくはグリセリン、ショ糖、キシリトール、ソルビトール、マンニトールであり、より好ましくはソルビトールである。
These saccharides described above can be used alone or in combination of two or more. Among these carbohydrates, it is preferable to use sugar alcohols because of their high ability to assist the surface activity of proteins. The valence of the sugar alcohol used is not particularly limited, but is preferably 3-8 valence, more preferably 3-6 valence. The number of carbon atoms is not particularly limited, but preferably 3-8, more preferably 3-6.
Preferred sugar alcohols are glycerin, sucrose, xylitol, sorbitol and mannitol, and more preferred is sorbitol.

本発明の乳化油脂組成物中の糖質の配合量は、10~45質量%であり、下限値としては、好ましくは15質量%以上であり、より好ましくは20質量%以上である。上限値としては、40質量%以下であり、より好ましくは35質量%以下である。糖質の含有量が10質量%未満であると、組成物中の水分含量が多くなり組成物の衛生度を保てない場合や、ケーキ生地中の水分率が高くなり起泡性能や粘度に悪影響を及ぼす。糖質の含有量が45質量%を超えると、本発明の乳化油脂組成物の乳化状態が悪化し、ケーキの気泡を消泡し生地安定性が低下する。 The amount of carbohydrates in the emulsified oil and fat composition of the present invention is 10 to 45% by mass, and the lower limit is preferably 15% by mass or more, more preferably 20% by mass or more. The upper limit is 40% by mass or less, more preferably 35% by mass or less. If the sugar content is less than 10% by mass, the moisture content in the composition increases and the hygiene of the composition cannot be maintained, or the moisture content in the cake dough increases and the foaming performance and viscosity are affected. Adversely affect. When the sugar content exceeds 45% by mass, the emulsified state of the emulsified oil and fat composition of the present invention deteriorates, defoaming air bubbles in the cake, and lowering the stability of the dough.

<水(d)>
本発明の乳化油脂組成物中の水の配合量は、5~45質量%であり、下限値としては、好ましくは10質量%以上であり、より好ましくは15質量%以上である。上限値としては、40質量%以下であり、より好ましくは35質量%以下である。
<Water (d)>
The amount of water in the emulsified oil and fat composition of the present invention is 5 to 45% by mass, and the lower limit is preferably 10% by mass or more, more preferably 15% by mass or more. The upper limit is 40% by mass or less, more preferably 35% by mass or less.

本発明の乳化油脂組成物には、必要に応じて、食塩凝集カゼイネート以外のタンパク質やタンパク質を含む素材を配合することができる。例えば、カゼイン、乳清タンパク質、卵タンパク質、ゼラチン、大豆タンパク質、分離大豆タンパク質、小麦タンパク質等のタンパク質、およびこれらを酵素または酸・アルカリで分解処理したペプチド、脱脂粉乳、全脂粉乳、卵加工品を配合することができる。
その添加量は、0~10質量%、好ましくは0~5質量%配合される。また、各種タンパク質に含まれるカルシウム等の塩類を溶解するために、リン酸塩やクエン酸塩等のキレート剤を添加することも出来る。これらキレート剤の添加量は0.05~0.3質量%が好ましい。
The emulsified oil and fat composition of the present invention may optionally contain proteins other than salt-aggregated caseinate or materials containing proteins. For example, proteins such as casein, whey protein, egg protein, gelatin, soybean protein, isolated soybean protein, and wheat protein, peptides obtained by enzymatic or acid/alkali decomposition, skim milk powder, whole milk powder, processed egg products can be blended.
The amount added is 0 to 10% by mass, preferably 0 to 5% by mass. Chelating agents such as phosphates and citrates can also be added in order to dissolve salts such as calcium contained in various proteins. The amount of these chelating agents to be added is preferably 0.05 to 0.3% by mass.

また、本発明の乳化油脂組成物の乳化状態を改善するため、ペクチン、寒天、キサンタンガム、タマリンド種子ガム、ローカストビーンガム、カラギーナン等の増粘多糖類を必要に応じて配合することもできる。増粘多糖類の配合量については、配合時の増粘や焼成したケーキの火通り、口溶けの観点から増粘多糖類の合計で0.01~1質量%、好ましくは0.05~0.2質量%であることが望ましい。
加えて、本発明の乳化油脂組成物には、必要に応じて、調味料、香辛料、着色料、香料などを配合することも可能である。
Further, in order to improve the emulsified state of the emulsified oil and fat composition of the present invention, thickening polysaccharides such as pectin, agar, xanthan gum, tamarind seed gum, locust bean gum, and carrageenan can be blended as needed. The amount of polysaccharide thickener to be blended is 0.01 to 1% by mass in total, preferably 0.05 to 0.05%, from the viewpoints of thickening at the time of blending, smoothness of the baked cake, and meltability in the mouth. It is desirable to be 2% by mass.
In addition, the emulsified oil and fat composition of the present invention can be blended with seasonings, spices, coloring agents, fragrances, and the like, if necessary.

本発明の乳化油脂組成物の製造方法としては、特に制限されないが、例えば、糖質(c)と水(d)を混合させた水溶液に食塩凝集カゼイネート(a)を溶解分散し、必要に応じキレート剤を加えて20~80℃に加熱溶解し水相部とし、これを攪拌混合しながら加熱した食用油脂(b)を徐々に加えて水中油型乳化油脂を得ることが出来る。攪拌混合には、一般的な攪拌混合機が利用され、撹拌混合機としては、例えば、プロペラ羽根(4枚)を備えたスリーワンモーターやホモミキサー、ホモゲナイザー、アジホモミキサー等の一般的に使用される乳化機が用いられる。 The method for producing the emulsified oil and fat composition of the present invention is not particularly limited. A chelating agent is added and dissolved by heating to 20 to 80° C. to obtain an aqueous phase, and the heated edible fat (b) is gradually added while stirring and mixing to obtain an oil-in-water emulsified fat. A general stirring mixer is used for stirring and mixing, and examples of the stirring mixer include a three-one motor equipped with propeller blades (four pieces), a homomixer, a homogenizer, an ajihomomixer, and the like. An emulsifying machine is used.

本発明のケーキ生地は、本発明の製菓用水中油型乳化油脂組成物、穀粉および水を含有する。本発明のケーキ生地において、小麦粉と澱粉の合計100質量部に対して製菓用水中油型乳化油脂組成物の含有量が5~50質量部である。本発明の乳化油脂組成物の配合量が少なすぎると、ケーキ生地の安定性向上効果が十分でなくなる。本発明の乳化油脂組成物の配合量が多すぎると、配合量に応じたケーキ生地の安定性向上効果が得られず、卵の配合割合が減少することによる風味の悪化が問題となる。本発明のケーキ生地を用いることによって、ケーキ配合中の小麦粉の30質量%以上を澱粉に置き換えることができる。 The cake dough of the present invention contains the oil-in-water emulsified fat composition for confectionery of the present invention, flour and water. In the cake dough of the present invention, the content of the oil-in-water emulsified fat composition for confectionery is 5 to 50 parts by mass with respect to the total of 100 parts by mass of wheat flour and starch. If the blending amount of the emulsified oil and fat composition of the present invention is too small, the effect of improving the stability of the cake dough will be insufficient. If the amount of the emulsified oil and fat composition of the present invention is too large, the effect of improving the stability of the cake dough corresponding to the amount of the mixture cannot be obtained, and the deterioration of the flavor due to the decrease in the proportion of eggs becomes a problem. By using the cake dough of the present invention, 30% by weight or more of the wheat flour in the cake formula can be replaced with starch.

本発明の乳化油脂組成物を用いるケーキの製造方法としては、特に制限はないが、例えば、共立て法や後粉法、別立て法、オールインミックス法が挙げられる。中でも、最も起泡性能を必要とし、本発明の効果が最も現れるオールインミックス法について説明する。オールインミックス法は、本発明の乳化油脂組成物を、全卵や砂糖、油脂類とともに配合し、ミキサーで混合し、これに小麦粉と澱粉を加えた後に起泡し、ケーキ生地とする。起泡には、縦型ミキサーやカッターミキサー、大量生産の場合は連続ミキサー等が用いられる。 The method for producing a cake using the emulsified oil and fat composition of the present invention is not particularly limited, and examples thereof include a co-baking method, a post-baking method, a separate baking method, and an all-in-mix method. Among them, the all-in-mix method, which requires the most foaming performance and exhibits the effects of the present invention, will be described. In the all-in-mix method, the emulsified oil-and-fat composition of the present invention is blended with whole eggs, sugar, and oils and fats, mixed in a mixer, wheat flour and starch are added, and then foamed to form a cake dough. For foaming, a vertical mixer, a cutter mixer, and a continuous mixer or the like are used for mass production.

ケーキの食感を改善することを目的に、本発明のケーキ配合に澱粉を用いることができる。使用できる澱粉に特に制限はなく、例えば、トウモロコシ、ジャガイモ、サツマイモ、キャッサバ、小麦、米などから分離された澱粉を挙げることが出来る。これらの中で、小麦澱粉とコーンスターチは、ケーキの食感を維持する上で有効であるので好適に使用することができる。さらに、澱粉の老化を防止する目的でリン酸架橋澱粉などの化工澱粉を一部配合することもできるが、α化処理された化工澱粉の添加は、生地粘度の著しい上昇を招き、ケーキの火どおりを悪化させるので、澱粉中10質量%以下に抑えることが好ましい。本発明において、澱粉によるケーキ配合中の小麦粉の置換量は30質量%以上であり、より好ましくは40質量%以上である。ケーキ配合中に小麦粉を澱粉によって置き換える割合を上記の範囲内とすることで、小麦粉の吸水による起泡性が損なわれることを防ぎ、優れたケーキの食感を維持することができる。 Starch can be used in the cake formulations of the present invention to improve the texture of the cake. The starch that can be used is not particularly limited, and examples thereof include starches separated from corn, potato, sweet potato, cassava, wheat, rice, and the like. Among these, wheat starch and cornstarch are preferably used because they are effective in maintaining the texture of the cake. Furthermore, in order to prevent aging of starch, it is possible to add a part of modified starch such as phosphate-crosslinked starch, but the addition of pregelatinized modified starch causes a significant increase in the viscosity of the dough, resulting in cake fire. Since it deteriorates the texture, it is preferable to suppress it to 10% by mass or less in the starch. In the present invention, the replacement amount of wheat flour in the cake formulation by starch is 30% by mass or more, more preferably 40% by mass or more. By setting the ratio of replacing wheat flour with starch in the cake formulation within the above range, it is possible to prevent deterioration of foamability due to water absorption of wheat flour and maintain excellent texture of the cake.

本発明の乳化油脂組成物は、例えば、スポンジケーキやスナックケーキ、蒸しケーキ、シフォンケーキ、ブッセ、パフケーキ、半生菓子等のケーキに使用でき、生地の起泡性や生地安定性に優れ、出来たケーキのボリュームは大きく、口溶けのよい食感に優れたケーキを製造するのに適する。本発明のケーキ製造方法に用いるケーキ材料は、小麦粉、澱粉、砂糖、卵などの必須成分のほかに、特に制限はないが、例えば、必要に応じて膨張剤や着色料、香料、リキュール、調味料を配合して作ることが出来る。 The emulsified oil and fat composition of the present invention can be used, for example, in cakes such as sponge cakes, snack cakes, steamed cakes, chiffon cakes, busse, puff cakes, semi-baked confectionery, etc., and has excellent dough foamability and dough stability. The volume of the cake is large, and it is suitable for producing a cake that melts in the mouth and has an excellent texture. The cake materials used in the cake manufacturing method of the present invention are not particularly limited in addition to essential ingredients such as wheat flour, starch, sugar, eggs, etc., but for example, swelling agents, coloring agents, flavors, liqueurs, seasonings, etc. It can be made by mixing ingredients.

以下に実施例を示し、本発明をより具体的に説明する。
(色差計を用いた食塩凝集カゼイネートの凝集評価)
糖質溶液中のカゼインナトリウムの配合量を一定にし、食塩の配合量を変更した場合の透過率の推移を表1に示す。透過率の測定は、表1の原材料を混合溶解し、85℃になるまで加熱した後、室温まで冷却した水溶液を石英製の1cmセルにいれ、東京電色社製全自動色差計カラーエースTC-8600Aにて行った。
EXAMPLES The present invention will be explained more specifically by showing examples below.
(Aggregation evaluation of salt-aggregated caseinate using a color difference meter)
Table 1 shows the change in transmittance when the compounding amount of sodium caseinate in the sugar solution was kept constant and the compounding amount of salt was changed. The transmittance was measured by mixing and dissolving the raw materials in Table 1, heating to 85° C., cooling to room temperature, placing the aqueous solution in a 1 cm cell made of quartz, and using a fully automatic color difference meter Color Ace TC manufactured by Tokyo Denshoku Co., Ltd. -8600A was used.

Figure 0007121239000001
Figure 0007121239000001

表1の結果より、食塩を配合していない非凝集物Aの透過率に比べて、食塩を配合し凝集させた凝集物B~Eの透過率が有意に低下していたことから、食塩によってカゼインナトリウムの一部が凝集していることが示された。また、配合量を多くするにしたがって、透過率が低下しており、凝集の程度が増加していることが示された。 From the results in Table 1, compared to the transmittance of non-aggregate A not containing salt, the transmittance of aggregates B to E aggregated with salt was significantly lower. It was shown that some of the sodium caseinate was aggregated. Moreover, as the compounding amount increased, the transmittance decreased, indicating that the degree of aggregation increased.

次に、食塩凝集カゼイナートを用いた製菓用水中油型乳化油脂組成物の調製方法と評価方法と内容を示す。 Next, the preparation method, evaluation method, and contents of the oil-in-water emulsified fat composition for confectionery using the salt-aggregated caseinate will be described.

(菓子用水中油型乳化油脂組成物の調製とケーキ生地への配合:実施例1~5、比較例1~6)
(実施例1)
表3に示す組成で乳化油脂組成物を次の方法により調製した。すなわち、ソルビトール(c)30質量%と水(d)27.5質量%にクエン酸三ナトリウム0.5質量%と食塩(a)1.0質量%を溶解した後、カゼインナトリウム(a)2.0質量%を分散させ、70℃に調温した。その後30分間攪拌し溶解したものを、さらに85℃になるまで加熱し食塩凝集カゼイネート溶解したものを水相部とした。菜種油(b)39質量%を60℃に加熱し、水相部に徐々に加えて65℃で30分間予備乳化した後、ホモゲナイザー((株)日阪製作所製)を用いて、20MPaで乳化処理し、乳化油脂組成物を得た。
得られた乳化油脂組成物は、下記のケーキ生地の配合と調製方法のようにケーキに配合した。
(Preparation of confectionery oil-in-water emulsified fat composition and formulation into cake dough: Examples 1 to 5, Comparative Examples 1 to 6)
(Example 1)
An emulsified fat composition having the composition shown in Table 3 was prepared by the following method. That is, after dissolving 0.5% by mass of trisodium citrate and 1.0% by mass of salt (a) in 30% by mass of sorbitol (c) and 27.5% by mass of water (d), sodium caseinate (a) 2 0% by mass was dispersed and the temperature was adjusted to 70°C. After that, the mixture was stirred for 30 minutes and dissolved, and then heated to 85° C. to dissolve salt aggregated caseinate, which was used as the aqueous phase. 39% by mass of rapeseed oil (b) is heated to 60° C., gradually added to the aqueous phase, pre-emulsified at 65° C. for 30 minutes, and then emulsified at 20 MPa using a homogenizer (manufactured by Hisaka Seisakusho Co., Ltd.). to obtain an emulsified fat composition.
The obtained emulsified oil and fat composition was blended into a cake in the same manner as in the formulation and preparation method of cake dough below.

(実施例2~4)
表3に示す組成を実施例1と同様の条件で処理して乳化油脂組成物を得た。すなわち、ソルビトールまたは還元水あめ(c)と水(d)を混合した溶液に食塩(a)を溶解させた。その後、カゼインナトリウム、カゼインカリウム、カゼインカルシウムを単独もしくは2種を混合したもの(a)を加熱溶解させた後、さらに加熱して得た食塩凝集カゼイネート溶液を水相部とした。加熱した菜種油またはコーン油(b)を水相部に加えた後、乳化処理した。
得られた乳化油脂組成物は、下記のケーキ生地の配合と調製方法のようにケーキに配合した。
(実施例5)
表3に示す組成を実施例1と同様の条件で処理して乳化油脂組成物を得た。カゼインナトリウム(a)と他のタンパク質としてカゼイン加水分解物(a’)を用いて同様の処理を行って作成した食塩凝集カゼイネート溶液を水相部とし、加熱した菜種油を加えた後、乳化処理した。
得られた乳化油脂組成物は、下記のケーキ生地の配合と調製方法のようにケーキに配合した。
(Examples 2-4)
The composition shown in Table 3 was treated under the same conditions as in Example 1 to obtain an emulsified oil composition. That is, salt (a) was dissolved in a mixed solution of sorbitol or reduced starch syrup (c) and water (d). After that, sodium caseinate, potassium caseinate, and calcium caseinate (a) alone or a mixture of the two was dissolved by heating, and then further heated to obtain a salt-aggregated caseinate solution, which was used as the aqueous phase. The heated rapeseed oil or corn oil (b) was added to the aqueous phase and then emulsified.
The obtained emulsified oil and fat composition was blended into a cake in the same manner as in the formulation and preparation method of cake dough below.
(Example 5)
The composition shown in Table 3 was treated under the same conditions as in Example 1 to obtain an emulsified oil composition. A sodium caseinate (a) and a casein hydrolyzate (a') as another protein were treated in the same manner to prepare a salt-aggregated caseinate solution as the aqueous phase, and heated rapeseed oil was added and then emulsified. .
The obtained emulsified oil and fat composition was blended into a cake in the same manner as in the formulation and preparation method of cake dough below.

(比較例1)
実施例1で得られた乳化油脂組成物を、表2のケーキ配合において対粉あたり60質量%(600g)配合してケーキ生地を調製した。
(比較例2)
表3に示す組成を実施例1と同様の条件で処理して乳化油脂組成物を得た。本組成は特許文献1に記載の実施例に基づくものである。
得られた乳化油脂組成物は、下記のケーキ生地の配合と調製方法のようにケーキに配合した。
(比較例3~4)
食塩凝集カゼイネート(a)中のカゼイネートの配合量を本発明の範囲外の配合で乳化油脂組成物を調製し、対粉あたり30質量%(300g)添加してケーキ生地を調製した。
得られた乳化油脂組成物は、下記のケーキ生地の配合と調製方法のようにケーキに配合した。
(比較例5)
食塩凝集カゼイネート(a)の代わりに乳清タンパク質分離物(a’)を用いて乳化油脂組成物を調製した。
得られた乳化油脂組成物は、下記のケーキ生地の配合と調製方法のようにケーキに配合した。
(比較例6)
油脂(b)の配合量を、本発明の範囲外の配合で乳化油脂組成物を調製した。
得られた乳化油脂組成物は、下記のケーキ生地の配合と調製方法のようにケーキに配合した。
(Comparative example 1)
The emulsified oil-and-fat composition obtained in Example 1 was blended in an amount of 60% by mass (600 g) based on the flour in the cake composition shown in Table 2 to prepare a cake dough.
(Comparative example 2)
The composition shown in Table 3 was treated under the same conditions as in Example 1 to obtain an emulsified oil composition. This composition is based on the example described in Patent Document 1.
The obtained emulsified oil and fat composition was blended into a cake in the same manner as in the formulation and preparation method of cake dough below.
(Comparative Examples 3-4)
An emulsified oil/fat composition was prepared with the amount of caseinate in the salt-aggregated caseinate (a) outside the range of the present invention, and 30% by mass (300 g) of the composition was added to the flour to prepare a cake dough.
The obtained emulsified oil and fat composition was blended into a cake in the same manner as in the formulation and preparation method of cake dough below.
(Comparative Example 5)
An emulsified fat composition was prepared using whey protein isolate (a') instead of salt-aggregated caseinate (a).
The obtained emulsified oil and fat composition was blended into a cake in the same manner as in the formulation and preparation method of cake dough below.
(Comparative Example 6)
An emulsified fat composition was prepared with the blending amount of the fat (b) outside the range of the present invention.
The obtained emulsified oil and fat composition was blended into a cake in the same manner as in the formulation and preparation method of cake dough below.

1.<乳化油脂組成物の状態の評価>
下記、表3に示す組成で得られた乳化油脂組成物の状態を以下の4段階で評価した。
評価◎;油脂の分離がなく、かつ非常に滑らかで分散性に優れる。
評価○;分離がなく、かつ分散性が良好である。
評価△;やや分離がある、または、やや硬く分散性が低い。
評価×;分離がはっきりと認められる、または、硬く分散性に劣る。
1. <Evaluation of the state of the emulsified oil composition>
The state of the emulsified fat composition obtained with the composition shown in Table 3 below was evaluated in the following four stages.
Evaluation ⊚: No segregation of fats and oils, very smooth and excellent in dispersibility.
Evaluation ◯: No separation and good dispersibility.
Evaluation Δ: Slightly separated, or slightly hard with low dispersibility.
Evaluation x; clear separation is observed, or hard and poor dispersibility.

2.<評価に用いたケーキ生地の配合と調製方法>
生地の調製は、表2に示すケーキ配合を用いてオールインミックス法で行った。すなわち、20コート縦型ミキサーに鶏卵1200gと上白糖1000g、ナタネサラダ油100g、水200gに加えて、乳化油脂組成物を表3に示した実施例と比較例の範囲(50~600g)を添加して、低速で1分間ミキシングした後、薄力粉700gと澱粉300gとベーキングパウダー30gを混合し予め篩ったものを添加し、低速で30秒間、高速で4分間ミキシングしてケーキ生地を得た。得られたケーキ生地は6号丸型に350gはかりとり、10KW電気オーブンにて170℃で30分間焼成しケーキを得た。
2. <Formulation and preparation method of cake dough used for evaluation>
Dough preparation was done by the all-in-mix method using the cake formulation shown in Table 2. That is, in addition to 1200 g of chicken eggs, 1000 g of white sugar, 100 g of rapeseed salad oil, and 200 g of water in a 20-coat vertical mixer, an emulsified oil and fat composition in the range of Examples and Comparative Examples shown in Table 3 (50 to 600 g) was added. After mixing at a low speed for 1 minute, 700 g of soft flour, 300 g of starch and 30 g of baking powder were mixed and the pre-sieved mixture was added, followed by mixing at a low speed for 30 seconds and at a high speed for 4 minutes to obtain a cake dough. 350 g of the resulting cake dough was weighed into a No. 6 round mold and baked in a 10 kW electric oven at 170° C. for 30 minutes to obtain a cake.

Figure 0007121239000002
Figure 0007121239000002

3.<ケーキ生地の起泡性能の評価>
上記の方法で調製したケーキ生地の起泡性能の評価は、ホイップした生地の比重を測定して調べた。つまり、ケーキ生地を一定時間ホイップさせた直後の生地比重を、100mLの容器に均一になるようにはかりとり、その生地の重量から生地比重を算出した(測定温度23℃)。生地比重が0.6以下であると、生地比重の軽いケーキにおいて実用上問題ないレベルとして用いることができる。
3. <Evaluation of foaming performance of cake dough>
The foaming performance of the cake dough prepared by the above method was evaluated by measuring the specific gravity of the whipped dough. That is, the specific gravity of the dough immediately after whipping the cake dough for a certain period of time was uniformly weighed in a 100 mL container, and the specific gravity of the dough was calculated from the weight of the dough (measurement temperature: 23°C). When the specific gravity of the dough is 0.6 or less, it can be used as a practically acceptable level for a cake having a light dough specific gravity.

4.<焼成したケーキの官能評価>
上記の方法で焼成したケーキの風味と食感を評価した。つまり、得られたケーキを10名のパネラーが試食して官能検査を行い、風味と食感を次の4段階評価で官能評価を行って平均化した。評価基準は下記のとおりである。
[風味]
評価◎;極めて良好
評価○;良好
評価△;やや不良
評価×;不良
[食感]
評価◎;極めて良好
評価○;良好
評価△;やや不良
評価×;不良
4. <Sensory evaluation of baked cake>
The flavor and texture of the cake baked by the above method were evaluated. That is, 10 panelists tasted the obtained cakes and conducted sensory tests, and sensory evaluations were carried out on the flavor and texture according to the following four-grade evaluation, and the results were averaged. Evaluation criteria are as follows.
[Flavor]
Evaluation ◎: Very good Evaluation ○: Good Evaluation △: Slightly poor Evaluation ×: Poor [texture]
Evaluation ◎: Very good Evaluation ○: Good Evaluation △: Slightly poor Evaluation ×: Poor

Figure 0007121239000003
Figure 0007121239000003

実施例1~5で得られた乳化油脂組成物の状態は、いずれも油脂の分離がなく、かつ非常に滑らかで分散性に優れていた。ケーキ生地調製方法で乳化油脂組成物をそれぞれ対粉あたり15~40質量%加えて、上記した方法で調製したケーキ生地の比重は、いずれも目標とした0.60以下であった。焼成して得たケーキの風味と食感は、いずれも極めて良好であり、本発明の目的であるケーキを調製できたことが示された。 The state of the emulsified fat and oil compositions obtained in Examples 1 to 5 was very smooth with no separation of fat and oil, and excellent in dispersibility. The specific gravity of the cake dough prepared by adding 15 to 40% by mass of the emulsified oil and fat composition based on the flour in the cake dough preparation method was 0.60 or less, which was the target. Both the flavor and texture of the cake obtained by baking were extremely good, indicating that the cake, which is the object of the present invention, could be prepared.

対粉あたり60質量%(600g)配合してケーキ生地を調製した比較例1は、既定のミキシング時間では生地比重は0.62までしか低下しなかった。また、その生地を焼成して得られたケーキの風味は卵由来の風味が薄く感じられ不良であった。また、ケーキの食感も生地比重が重いために口溶けが悪く、やや不良であった。 In Comparative Example 1, in which the cake dough was prepared by blending 60% by mass (600 g) based on the flour, the specific gravity of the dough only decreased to 0.62 during the predetermined mixing time. In addition, the flavor of the cake obtained by baking the dough was poor because the flavor derived from the egg was felt weak. In addition, the texture of the cake was somewhat poor because it did not melt in the mouth due to the heavy specific gravity of the dough.

食塩で凝集していないカゼイネートを用いた比較例2は、既定のミキシング時間では生地比重が0.68までしか低下しなかった。また、その生地を焼成して得られたケーキの食感は生地比重が重いために口溶けが悪く、やや不良であった。 Comparative Example 2, which used caseinate that was not agglomerated with salt, only reduced the specific gravity of the dough to 0.68 with the prescribed mixing time. In addition, the texture of the cake obtained by baking the dough was not good because it did not melt in the mouth due to the heavy specific gravity of the dough.

食塩凝集カゼイネート(a)の含有量が1.0質量%未満である比較例3は、既定のミキシング時間で得られた生地比重が0.82までしか低下せず、ケーキの食感は、硬く、口溶けも悪く、不良であった。
食塩凝集カゼイネート(a)の含有量が10.0質量%より多い比較例4は、既定のミキシング時間で得られた生地比重が0.75までしか低下せず、ケーキの食感は、硬く、口溶けも悪く、不良であった。
In Comparative Example 3, in which the content of salt-aggregated caseinate (a) is less than 1.0% by mass, the specific gravity of the dough obtained in the predetermined mixing time is only reduced to 0.82, and the cake has a hard texture. , Melt in the mouth was also bad, and it was poor.
In Comparative Example 4, in which the content of salt-aggregated caseinate (a) was more than 10.0% by mass, the specific gravity of the dough obtained in the predetermined mixing time was reduced only to 0.75, and the texture of the cake was hard. Melt-in-the-mouth was also bad and it was unsatisfactory.

食塩凝集カゼイネート(a)の代わりに乳清タンパク質分離物(a’)を用いて乳化油脂組成物を調製した比較例5は、乳化油脂の状態は非常に硬く、分散性が悪かった。また、既定のミキシング時間で得られた生地比重は0.89までしか低下せず、ケーキの食感は、浮きが悪いために非常に硬く、口溶けも悪く、不良であった。 In Comparative Example 5, in which the whey protein isolate (a') was used instead of the salt-aggregated caseinate (a) to prepare the emulsified fat composition, the emulsified fat was very hard and had poor dispersibility. In addition, the specific gravity of the dough obtained with the predetermined mixing time was reduced only to 0.89, and the texture of the cake was very hard due to poor floating and poor meltability in the mouth.

食用油脂(b)の含有量を65質量%より多く配合した比較例6は、得られた乳化油脂組成物から明らかな油分離が認められた。また、既定のミキシング時間で得られた生地比重は0.80までしか低下しなかった。さらに、その生地を焼成して得られたケーキの食感は、浮きが悪いために非常に硬く、口溶けも悪く、不良であった。 In Comparative Example 6, in which the content of the edible fat (b) was more than 65% by mass, clear oil separation was observed from the resulting emulsified fat and oil composition. Also, the specific gravity of the dough obtained with the given mixing time only decreased to 0.80. Furthermore, the texture of the cake obtained by baking the dough was very hard due to poor floating, and the melt-in-your-mouth texture was poor.

以上の結果から、本発明の範囲にある製菓用水中油型乳化油脂組成物を用いることで、乳化剤を含有しなくとも、オールインミックス法で生地比重が0.60以下に起泡させることができ、さらにその生地を焼成して得られるケーキは、風味と食感が良好である製菓用水中油型乳化油脂組成物を形成することができたことが分かる。 From the above results, by using the oil-in-water emulsified oil and fat composition for confectionery within the scope of the present invention, the specific gravity of the dough can be foamed to 0.60 or less by the all-in-mix method without containing an emulsifier. Furthermore, it can be seen that the cake obtained by baking the dough was able to form an oil-in-water emulsified fat composition for confectionery with good flavor and texture.

Claims (2)

食塩凝集カゼイネート(a)、食用油脂(b)、糖アルコール(c)および水(d)を含有し、食塩凝集カゼイネート(a)の含有量が2.08.0質量%、食用油脂(b)の含有量が30~55質量%、糖アルコール(c)の含有量が20~45質量%、および水(d)の含有量が1035質量%であるケーキ用水中油型乳化油脂組成物。 Salt-aggregated caseinate (a), edible fat (b), sugar alcohol (c) and water (d) are contained, and the content of salt-aggregated caseinate (a) is 2.0 to 8.0 % by mass, edible fat ( An oil-in-water emulsified fat composition for cakes , wherein the content of b) is 30 to 55 % by mass, the content of sugar alcohol (c) is 20 to 45% by mass, and the content of water (d) is 10 to 35 % by mass. thing. 請求項1に記載のケーキ用水中油型乳化油脂組成物、小麦粉、澱粉および水を含有し、小麦粉と澱粉の合計100質量部に対してケーキ用水中油型乳化油脂組成物の含有量が1540質量部であるケーキ生地。
The oil-in-water emulsified fat composition for cakes according to claim 1, wheat flour, starch and water are contained, and the content of the oil-in-water emulsified fat composition for cakes is 15 to 40 with respect to a total of 100 parts by mass of wheat flour and starch. Cake dough, which is the mass part.
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JP2000093070A (en) 1998-09-21 2000-04-04 Nof Corp Oil-in-water type emulsion composition for confectionery and production of cake using the same
WO2013008904A1 (en) 2011-07-14 2013-01-17 株式会社明治 Foamable oil-in-water emulsion and method for producing same

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