TW202023021A - Memory structure and manufacturing method thereof - Google Patents

Memory structure and manufacturing method thereof Download PDF

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TW202023021A
TW202023021A TW107144389A TW107144389A TW202023021A TW 202023021 A TW202023021 A TW 202023021A TW 107144389 A TW107144389 A TW 107144389A TW 107144389 A TW107144389 A TW 107144389A TW 202023021 A TW202023021 A TW 202023021A
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opening
electrode
transistor
memory structure
layer
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TW107144389A
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TWI696266B (en
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李志鵬
林家佑
魏易玄
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力晶積成電子製造股份有限公司
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Priority to CN201811588101.XA priority patent/CN111370422B/en
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B43/00EEPROM devices comprising charge-trapping gate insulators
    • H10B43/30EEPROM devices comprising charge-trapping gate insulators characterised by the memory core region

Abstract

A memory structure including a first transistor, a second transistor, a dielectric layer, and a capacitor is provided. The second transistor is located at a side of the first transistor. The dielectric layer covers the first transistor and the second transistor. The dielectric layer has a first opening and a second opening connected with each other therein. The second opening is located at a side of the first opening. The capacitor is coupled between the first transistor and the second transistor. The capacitor includes a first electrode, a second electrode, and an insulating layer. The first electrode is disposed on a surface of the first opening. The second electrode is disposed on the first electrode in the first opening and has an extension portion extending into the second opening. The extension portion covers a side surface of the first electrode exposed by the second opening. The insulating layer is disposed between the first electrode and the second electrode.

Description

記憶體結構及其製造方法Memory structure and manufacturing method thereof

本發明是有關於一種半導體結構及其製造方法,且特別是有關於一種記憶體結構及其製造方法。The present invention relates to a semiconductor structure and its manufacturing method, and more particularly to a memory structure and its manufacturing method.

目前發展出一種記憶體結構,包括彼此耦接電晶體與電容器。在此種記憶體結構中,使用電容器作為儲存組件。因此,如何增加電容器的電容以提升記憶體元件的電性效能為目前業界持續努力的目標。At present, a memory structure has been developed, including a transistor and a capacitor coupled to each other. In this memory structure, capacitors are used as storage components. Therefore, how to increase the capacitance of the capacitor to improve the electrical performance of the memory device is the goal of continuous efforts in the industry.

本發明提供一種記憶體結構及其製造方法,其可有效地增加電容器的電容,進而可提升記憶體元件的電性效能。The present invention provides a memory structure and a manufacturing method thereof, which can effectively increase the capacitance of a capacitor, thereby improving the electrical performance of the memory device.

本發明提出一種記憶體結構,包括第一電晶體、第二電晶體、介電層與電容器。第二電晶體位在第一電晶體的一側。介電層覆蓋第一電晶體與第二電晶體。在介電層中具有相連通的第一開口與第二開口。第二開口位在第一開口的側邊。電容器耦接在第一電晶體與第二電晶體之間。電容器包括第一電極、第二電極與絕緣層。第一電極設置在第一開口的表面上。第二電極設置在第一開口中的第一電極上,且具有延伸至第二開口中的延伸部。延伸部覆蓋第二開口所暴露出的第一電極的側面。絕緣層設置在第一電極與第二電極之間。The present invention provides a memory structure including a first transistor, a second transistor, a dielectric layer and a capacitor. The second transistor is located on one side of the first transistor. The dielectric layer covers the first transistor and the second transistor. The dielectric layer has a first opening and a second opening connected to each other. The second opening is located on the side of the first opening. The capacitor is coupled between the first transistor and the second transistor. The capacitor includes a first electrode, a second electrode and an insulating layer. The first electrode is provided on the surface of the first opening. The second electrode is disposed on the first electrode in the first opening and has an extension part extending into the second opening. The extension part covers the side surface of the first electrode exposed by the second opening. The insulating layer is provided between the first electrode and the second electrode.

依照本發明的一實施例所述,在上述記憶體結構中,第一電晶體與第二電晶體分別可為N型金氧半導體電晶體與P型金氧半導體電晶體中的一者與另一者。According to an embodiment of the present invention, in the above-mentioned memory structure, the first transistor and the second transistor may be one and the other of an N-type MOS transistor and a P-type MOS transistor, respectively. One.

依照本發明的一實施例所述,在上述記憶體結構中,第二開口的底部可高於第一開口的底部。According to an embodiment of the present invention, in the above-mentioned memory structure, the bottom of the second opening may be higher than the bottom of the first opening.

依照本發明的一實施例所述,在上述記憶體結構中,第二開口的底部可低於第一電極的頂部。According to an embodiment of the present invention, in the above-mentioned memory structure, the bottom of the second opening may be lower than the top of the first electrode.

依照本發明的一實施例所述,在上述記憶體結構中,第一電極的頂部可低於第一開口的頂部。According to an embodiment of the present invention, in the above-mentioned memory structure, the top of the first electrode may be lower than the top of the first opening.

依照本發明的一實施例所述,在上述記憶體結構中,延伸部的底部可低於第一電極的頂部。According to an embodiment of the present invention, in the above-mentioned memory structure, the bottom of the extension portion may be lower than the top of the first electrode.

依照本發明的一實施例所述,在上述記憶體結構中,第一電晶體可包括第一閘極結構與位在第一閘極結構兩側的第一摻雜區與第二摻雜區。第二電晶體可包括第二閘極結構與位在第二閘極結構兩側的第三摻雜區與第四摻雜區。第二摻雜區與第三摻雜區可位在第一閘極結構與第二閘極結構之間。According to an embodiment of the present invention, in the aforementioned memory structure, the first transistor may include a first gate structure and a first doped region and a second doped region located on both sides of the first gate structure . The second transistor may include a second gate structure, and third and fourth doped regions located on both sides of the second gate structure. The second doped region and the third doped region may be located between the first gate structure and the second gate structure.

依照本發明的一實施例所述,在上述記憶體結構中,延伸部可位在第一電極與第一閘極結構之間。延伸部的底部可高於第一閘極結構的頂部。According to an embodiment of the present invention, in the above-mentioned memory structure, the extension portion may be located between the first electrode and the first gate structure. The bottom of the extension may be higher than the top of the first gate structure.

依照本發明的一實施例所述,在上述記憶體結構中,延伸部可位在第一電極與第二閘極結構之間。延伸部的底部可高於第二閘極結構的頂部。According to an embodiment of the present invention, in the above-mentioned memory structure, the extension portion may be located between the first electrode and the second gate structure. The bottom of the extension may be higher than the top of the second gate structure.

依照本發明的一實施例所述,在上述記憶體結構中,第一開口可暴露出第二摻雜區與第三摻雜區。According to an embodiment of the present invention, in the above-mentioned memory structure, the first opening can expose the second doped region and the third doped region.

依照本發明的一實施例所述,在上述記憶體結構中,第一電極可耦接至第二摻雜區與第三摻雜區。According to an embodiment of the present invention, in the above-mentioned memory structure, the first electrode can be coupled to the second doped region and the third doped region.

本發明提出一種記憶體結構的製造方法,包括以下步驟。提供第一電晶體與第二電晶體。第二電晶體位在第一電晶體的一側。形成覆蓋第一電晶體與第二電晶體的介電層。在介電層中具有相連通的第一開口與第二開口。第二開口位在第一開口的側邊。形成耦接在第一電晶體與第二電晶體之間的電容器。電容器包括第一電極、第二電極與絕緣層。第一電極設置在第一開口的表面上。第二電極設置在第一開口中的第一電極上,且具有延伸至第二開口中的延伸部。延伸部覆蓋第二開口所暴露出的第一電極的側面。絕緣層設置在第一電極與第二電極之間。The present invention provides a method for manufacturing a memory structure, including the following steps. Provide a first transistor and a second transistor. The second transistor is located on one side of the first transistor. A dielectric layer covering the first transistor and the second transistor is formed. The dielectric layer has a first opening and a second opening connected to each other. The second opening is located on the side of the first opening. A capacitor coupled between the first transistor and the second transistor is formed. The capacitor includes a first electrode, a second electrode and an insulating layer. The first electrode is provided on the surface of the first opening. The second electrode is disposed on the first electrode in the first opening and has an extension part extending into the second opening. The extension part covers the side surface of the first electrode exposed by the second opening. The insulating layer is provided between the first electrode and the second electrode.

依照本發明的一實施例所述,在上述記憶體結構的製造方法中,第一電晶體與第二電晶體分別可為N型金氧半導體電晶體與P型金氧半導體電晶體中的一者與另一者。According to an embodiment of the present invention, in the manufacturing method of the above-mentioned memory structure, the first transistor and the second transistor may be one of an N-type MOS transistor and a P-type MOS transistor, respectively. One and the other.

依照本發明的一實施例所述,在上述記憶體結構的製造方法中,第一電極的形成方法可包括以下步驟。在第一開口的表面上共形地形成第一電極材料層。形成填入第一開口中且覆蓋第一電極材料層的保護層。對保護層與第一電極材料層進行回蝕刻製程。According to an embodiment of the present invention, in the method for manufacturing the memory structure described above, the method for forming the first electrode may include the following steps. A first electrode material layer is conformally formed on the surface of the first opening. A protective layer filled in the first opening and covering the first electrode material layer is formed. Perform an etching back process on the protective layer and the first electrode material layer.

依照本發明的一實施例所述,在上述記憶體結構的製造方法中,第一電極的頂部可低於第一開口的頂部。According to an embodiment of the present invention, in the manufacturing method of the above-mentioned memory structure, the top of the first electrode may be lower than the top of the first opening.

依照本發明的一實施例所述,在上述記憶體結構的製造方法中,述第二開口的形成方法可包括以下步驟。形成填入第一開口且覆蓋第一電極與介電層的保護層。在保護層上形成具有第三開口的圖案化光阻層。第三開口位在部分介電層上方。使用圖案化光阻層作為罩幕,對保護層與介電層進行蝕刻製程。蝕刻製程對介電層的蝕刻速率可高於對保護層的蝕刻速率。According to an embodiment of the present invention, in the method for manufacturing the memory structure described above, the method for forming the second opening may include the following steps. A protective layer filling the first opening and covering the first electrode and the dielectric layer is formed. A patterned photoresist layer with a third opening is formed on the protective layer. The third opening is located above part of the dielectric layer. Using the patterned photoresist layer as a mask, an etching process is performed on the protective layer and the dielectric layer. The etching rate of the dielectric layer in the etching process may be higher than the etching rate of the protective layer.

依照本發明的一實施例所述,在上述記憶體結構的製造方法中,第二開口的底部可高於第一開口的底部。According to an embodiment of the present invention, in the manufacturing method of the above-mentioned memory structure, the bottom of the second opening may be higher than the bottom of the first opening.

依照本發明的一實施例所述,在上述記憶體結構的製造方法中,第二開口的底部可低於第一電極的頂部。According to an embodiment of the present invention, in the manufacturing method of the above-mentioned memory structure, the bottom of the second opening may be lower than the top of the first electrode.

依照本發明的一實施例所述,在上述記憶體結構的製造方法中,絕緣層與第二電極的形成方法可包括以下步驟。在第一電極上與第二開口的表面上共形地形成絕緣材料層。形成填入第一開口與第二開口且覆蓋絕緣材料層的第二電極材料層。移除位於第一開口與第二開口的外部的部分第二電極材料層與所述絕緣材料層。According to an embodiment of the present invention, in the method for manufacturing the above-mentioned memory structure, the method for forming the insulating layer and the second electrode may include the following steps. An insulating material layer is conformally formed on the first electrode and the surface of the second opening. A second electrode material layer filling the first opening and the second opening and covering the insulating material layer is formed. Remove part of the second electrode material layer and the insulating material layer located outside the first opening and the second opening.

依照本發明的一實施例所述,在上述記憶體結構的製造方法中,部分第二電極材料層與部分絕緣材料層的移除方法例如是化學機械研磨法。According to an embodiment of the present invention, in the above-mentioned method for manufacturing the memory structure, the method for removing part of the second electrode material layer and part of the insulating material layer is, for example, a chemical mechanical polishing method.

基於上述,在本發明所提出的記憶體結構及其製造方法中,第二電極的延伸部覆蓋第二開口所暴露出的第一電極的側面,且絕緣層設置在第一電極與第二電極之間,因此可有效地增加電容器的電容,進而可提升記憶體元件的電性效能。此外,本發明所提出的記憶體結構及其製造方法可在不增加記憶體元件的面積的情況下,有效地增加電容器的電容,因此可提升記憶體結構的實用性與可行性。Based on the foregoing, in the memory structure and the manufacturing method thereof proposed in the present invention, the extension portion of the second electrode covers the side surface of the first electrode exposed by the second opening, and the insulating layer is provided on the first electrode and the second electrode Therefore, the capacitance of the capacitor can be effectively increased, and the electrical performance of the memory device can be improved. In addition, the memory structure and the manufacturing method proposed by the present invention can effectively increase the capacitance of the capacitor without increasing the area of the memory element, thus improving the practicability and feasibility of the memory structure.

為讓本發明的上述特徵和優點能更明顯易懂,下文特舉實施例,並配合所附圖式作詳細說明如下。In order to make the above-mentioned features and advantages of the present invention more obvious and understandable, the embodiments are specifically described below and described in detail in conjunction with the accompanying drawings.

圖1A至圖1J為本發明一實施例的記憶體結構的製造流程剖面圖。圖2為圖1F的局部上視圖。1A to 1J are cross-sectional views of a manufacturing process of a memory structure according to an embodiment of the invention. Figure 2 is a partial top view of Figure 1F.

請參照圖1A,提供電晶體102a與電晶體102b。電晶體102b位在電晶體102a的一側。舉例來說,電晶體102a與電晶體102b分別可為N型金氧半導體電晶體與P型金氧半導體電晶體中的一者與另一者。在本實施例中,電晶體102a是以N型金氧半導體電晶體為例,且電晶體102b是以P型金氧半導體電晶體為例,但本發明並不以此為限。所屬技術領域具有通常知識者可依據產品需求來決定電晶體102a與電晶體102b的導電型態。1A, a transistor 102a and a transistor 102b are provided. Transistor 102b is located on one side of transistor 102a. For example, the transistor 102a and the transistor 102b may be one and the other of an N-type MOSFET and a P-type MOSFET, respectively. In this embodiment, the transistor 102a is an N-type MOSFET as an example, and the transistor 102b is an example of a P-type MOSFET, but the invention is not limited to this. Those skilled in the art can determine the conductivity types of the transistor 102a and the transistor 102b according to product requirements.

電晶體102a可包括閘極結構104與位在閘極結構104兩側的摻雜區106與摻雜區108,且更可包括間隙壁110。閘極結構104可包括閘極112與介電層114。閘極112設置在基底100上。基底100例如是矽基底等半導體基底。在本實施例中,基底100是以P型基底為例來進行說明,但本發明並不以此為限。在其他實施例中,基底100亦可為N型基底。介電層114設置在閘極112與基底100之間,且可作為閘介電層。摻雜區106與摻雜區108分別可位在閘極結構104兩側的基底100中,且分別可作為源極或汲極使用。在本實施例中,摻雜區106與摻雜區108是以N型摻雜區為例來進行說明,但本發明並不以此為限。在其他實施例中,摻雜區106與摻雜區108亦可為P型摻雜區。間隙壁110設置在閘極結構104的側壁上。The transistor 102a may include a gate structure 104 and doped regions 106 and 108 located on both sides of the gate structure 104, and may further include spacers 110. The gate structure 104 may include a gate 112 and a dielectric layer 114. The gate 112 is provided on the substrate 100. The substrate 100 is, for example, a semiconductor substrate such as a silicon substrate. In this embodiment, the substrate 100 is described with a P-type substrate as an example, but the invention is not limited to this. In other embodiments, the substrate 100 may also be an N-type substrate. The dielectric layer 114 is disposed between the gate 112 and the substrate 100 and can be used as a gate dielectric layer. The doped region 106 and the doped region 108 can be respectively located in the substrate 100 on both sides of the gate structure 104, and can be used as source or drain respectively. In this embodiment, the doped region 106 and the doped region 108 are described by taking the N-type doped region as an example, but the invention is not limited thereto. In other embodiments, the doped region 106 and the doped region 108 may also be P-type doped regions. The spacer 110 is disposed on the side wall of the gate structure 104.

電晶體102b可包括閘極結構116與位在閘極結構116兩側的摻雜區118與摻雜區120,且更可包括井區122與間隙壁123中的至少一者。閘極結構116可包括閘極124與介電層126。閘極124設置在基底100上。介電層126設置在閘極124與基底100之間,且可作為閘介電層。摻雜區118與摻雜區120分別可位在閘極結構116兩側的基底100中,且分別可作為源極或汲極使用。摻雜區108與摻雜區118可位在閘極結構104與閘極結構116之間。在本實施例中,摻雜區118與摻雜區120是以P型摻雜區為例來進行說明,但本發明並不以此為限。在其他實施例中,摻雜區118與摻雜區120亦可為N型摻雜區。井區122位在基底100中,且摻雜區118與摻雜區120可位在井區122中。在本實施例中,井區122是以N型井區為例來進行說明,但本發明並不以此為限。在其他實施例中,井區122亦可為P型井區。間隙壁123設置在閘極結構116的側壁上。The transistor 102b may include a gate structure 116 and a doped region 118 and a doped region 120 located on both sides of the gate structure 116, and may further include at least one of a well region 122 and a spacer 123. The gate structure 116 may include a gate 124 and a dielectric layer 126. The gate electrode 124 is disposed on the substrate 100. The dielectric layer 126 is disposed between the gate electrode 124 and the substrate 100 and can be used as a gate dielectric layer. The doped region 118 and the doped region 120 can be respectively located in the substrate 100 on both sides of the gate structure 116, and can be used as source or drain respectively. The doped region 108 and the doped region 118 may be located between the gate structure 104 and the gate structure 116. In this embodiment, the doped region 118 and the doped region 120 are described by taking the P-type doped region as an example, but the invention is not limited thereto. In other embodiments, the doped region 118 and the doped region 120 may also be N-type doped regions. The well region 122 is located in the substrate 100, and the doped region 118 and the doped region 120 may be located in the well region 122. In this embodiment, the well area 122 is described with an N-type well area as an example, but the present invention is not limited to this. In other embodiments, the well zone 122 may also be a P-type well zone. The spacer 123 is disposed on the side wall of the gate structure 116.

在本實施例中,電晶體102a與電晶體102b的結構僅為舉例說明,本發明並不以此為限。所屬技術領域具有通常知識者可依照產品需求來調整電晶體102a與電晶體102b的結構。舉例來說,電晶體102a與電晶體102b更可包括輕摻雜汲極(lightly doped drain,LDD)(未示出)或金屬矽化物層(未示出)等,於此不再多作說明。In this embodiment, the structures of the transistor 102a and the transistor 102b are merely examples, and the invention is not limited thereto. Those skilled in the art can adjust the structures of the transistor 102a and the transistor 102b according to product requirements. For example, the transistor 102a and the transistor 102b may further include a lightly doped drain (LDD) (not shown) or a metal silicide layer (not shown), etc., which will not be described here. .

接著,形成覆蓋電晶體102a與電晶體102b的介電層128。介電層128的材料例如是氧化矽。介電層128的形成方法例如是化學氣相沉積法。Next, a dielectric layer 128 covering the transistor 102a and the transistor 102b is formed. The material of the dielectric layer 128 is silicon oxide, for example. The formation method of the dielectric layer 128 is, for example, a chemical vapor deposition method.

然後,在介電層128上形成具有開口130a的圖案化光阻層130。開口130a可位在摻雜區108與摻雜區118上方。圖案化光阻層130可藉由進行微影製程而形成。Then, a patterned photoresist layer 130 having an opening 130a is formed on the dielectric layer 128. The opening 130 a may be located above the doped region 108 and the doped region 118. The patterned photoresist layer 130 can be formed by performing a photolithography process.

請參照圖1B,使用圖案化光阻層130作為罩幕,移除部分介電層128,而在介電層128中形成開口132。開口132可暴露出摻雜區108與摻雜區118。開口132的形態可為溝渠(trench)或介層窗開口(via hole),但本發明並不以此為限。1B, using the patterned photoresist layer 130 as a mask, a portion of the dielectric layer 128 is removed, and an opening 132 is formed in the dielectric layer 128. The opening 132 can expose the doped region 108 and the doped region 118. The shape of the opening 132 may be a trench or a via hole, but the invention is not limited thereto.

接下來,移除圖案化光阻層130。圖案化光阻層130的移除方法例如是乾式去光阻法(dry stripping)或濕式去光阻法(wet stripping)。Next, the patterned photoresist layer 130 is removed. The method for removing the patterned photoresist layer 130 is, for example, a dry stripping method or a wet stripping method.

請參照圖1C,在開口132的表面上共形地形成電極材料層134。電極材料層134的材料例如是Ti、TiN、Ta、TaN、Al、In、Nb、Hf、Sn、Zn、Zr、Cu、Y或其組合。電極材料層134的形成方法例如是化學氣相沉積法、物理氣相沉積法、電鍍法(electroplating)、無電鍍沉積法(electroless deposition)或其組合。1C, an electrode material layer 134 is conformally formed on the surface of the opening 132. The material of the electrode material layer 134 is, for example, Ti, TiN, Ta, TaN, Al, In, Nb, Hf, Sn, Zn, Zr, Cu, Y or a combination thereof. The method for forming the electrode material layer 134 is, for example, a chemical vapor deposition method, a physical vapor deposition method, an electroplating method, an electroless deposition method, or a combination thereof.

隨後,形成填入開口132中且覆蓋電極材料層134的保護層136。保護層136的材料例如是有機材料。舉例來說,保護層136可為有機平坦層(organic planarization layer,OPL)。保護層136的形成方法例如是旋轉塗佈法。Subsequently, a protective layer 136 filling the opening 132 and covering the electrode material layer 134 is formed. The material of the protective layer 136 is, for example, an organic material. For example, the protective layer 136 may be an organic planarization layer (OPL). The method of forming the protective layer 136 is, for example, a spin coating method.

請參照圖1D,對保護層136與電極材料層134進行回蝕刻製程,以移除部分保護層136與部分電極材料層134。藉此,可在開口132的表面上形成電極134a。電極134a可用以作為電容器的下電極。電極134a的頂部可低於開口132的頂部。電極134a可耦接至摻雜區108與摻雜區118。在本實施例中,雖然電極134a的形成方法是以上述方法為例進行說明,但本發明並不以此為限。1D, the protection layer 136 and the electrode material layer 134 are etched back to remove part of the protection layer 136 and part of the electrode material layer 134. Thereby, the electrode 134a can be formed on the surface of the opening 132. The electrode 134a can be used as the lower electrode of the capacitor. The top of the electrode 134a may be lower than the top of the opening 132. The electrode 134 a may be coupled to the doped region 108 and the doped region 118. In this embodiment, although the method for forming the electrode 134a is described using the above method as an example, the present invention is not limited to this.

請參照圖1E,移除保護層136。保護層136可藉由灰化(ash)製程、蝕刻製程或其他適合的製程進行移除。Referring to FIG. 1E, the protective layer 136 is removed. The protective layer 136 can be removed by an ash process, an etching process, or other suitable processes.

接著,形成填入開口132且覆蓋電極134a與介電層128的保護層138。保護層138與保護層136的材料可為相同或不同。保護層138的材料例如是有機材料。舉例來說,保護層138可為有機平坦層(OPL)。保護層138的形成方法例如是旋轉塗佈法。Next, a protective layer 138 filling the opening 132 and covering the electrode 134a and the dielectric layer 128 is formed. The materials of the protective layer 138 and the protective layer 136 may be the same or different. The material of the protective layer 138 is, for example, an organic material. For example, the protective layer 138 may be an organic flat layer (OPL). The method of forming the protective layer 138 is, for example, a spin coating method.

在保護層138上形成具有開口140a的圖案化光阻層140。開口140a位在部分介電層128上方。圖案化光阻層140可藉由進行微影製程而形成。在本實施例中,開口140a的寬度例如是大於開口132的寬度,但本發明並不以此為限。開口140a的寬度與位置可決定後續所要形成的開口142(圖1F)的型態,然而只要開口140a位在部分介電層128上方,即屬於本發明所保護的範圍。在其他實施例中,開口140a的寬度亦可小於或等於開口132的寬度。A patterned photoresist layer 140 having an opening 140a is formed on the protective layer 138. The opening 140 a is located above a portion of the dielectric layer 128. The patterned photoresist layer 140 can be formed by performing a photolithography process. In this embodiment, the width of the opening 140a is, for example, greater than the width of the opening 132, but the invention is not limited to this. The width and position of the opening 140a can determine the type of the opening 142 (FIG. 1F) to be formed later. However, as long as the opening 140a is located above a portion of the dielectric layer 128, it belongs to the scope of the present invention. In other embodiments, the width of the opening 140a may also be less than or equal to the width of the opening 132.

請參照圖1F,使用圖案化光阻層140作為罩幕,對保護層138與介電層128進行蝕刻製程。上述蝕刻製程對介電層128的蝕刻速率可高於對保護層138的蝕刻速率。藉此,可在開口132的側邊形成開口142,且開口132與開口142可相連通。開口142的底部可高於開口132的底部。開口142的底部可低於電極134a的頂部,藉此開口142可暴露出電極134a的部分側面。開口142的形態可為溝渠或介層窗開口。在本實施例中,開口142的形態是以溝渠為例來進行說明。在本實施例中,雖然開口142的形成方法是以上述方法為例進行說明,但本發明並不以此為限。1F, using the patterned photoresist layer 140 as a mask, the protective layer 138 and the dielectric layer 128 are etched. The etching rate of the dielectric layer 128 may be higher than the etching rate of the protective layer 138 in the above etching process. Thereby, an opening 142 can be formed on the side of the opening 132, and the opening 132 and the opening 142 can be communicated. The bottom of the opening 142 may be higher than the bottom of the opening 132. The bottom of the opening 142 can be lower than the top of the electrode 134a, whereby the opening 142 can expose part of the side surface of the electrode 134a. The shape of the opening 142 may be a trench or a via opening. In this embodiment, the shape of the opening 142 is described by taking a trench as an example. In this embodiment, although the method for forming the opening 142 is described by taking the above method as an example, the present invention is not limited thereto.

在圖1F的實施例中,開口142可位在開口132的兩側邊,但本發明並不以此為限。在一實施例中,請參照圖2,開口142可位在開口132的各個側邊,亦即開口142可環繞開口132。在其他實施例中,開口142可僅位在開口132的單一側邊。然而,只要開口142位在開口132的至少一側邊,即屬於本發明所保護的範圍。In the embodiment of FIG. 1F, the opening 142 may be located on both sides of the opening 132, but the present invention is not limited to this. In one embodiment, referring to FIG. 2, the opening 142 may be located on each side of the opening 132, that is, the opening 142 may surround the opening 132. In other embodiments, the opening 142 may only be located on a single side of the opening 132. However, as long as the opening 142 is located on at least one side of the opening 132, it falls within the protection scope of the present invention.

請參照圖1G,移除圖案化光阻層140與保護層138。圖案化光阻層140與保護層138可藉由灰化製程、蝕刻製程或其他適合的製程進行移除。1G, the patterned photoresist layer 140 and the protective layer 138 are removed. The patterned photoresist layer 140 and the protective layer 138 can be removed by an ashing process, an etching process, or other suitable processes.

在本實施例中,在移除保護層136之後,形成保護層138,且在形成開口142之後,移除保護層138,但本發明並不以此為限。在其他實施例中,可在形成電極134a之後,直接在保護層136上形成保護層138,且在形成開口142之後,移除保護層138與保護層136。In this embodiment, after the protective layer 136 is removed, the protective layer 138 is formed, and after the opening 142 is formed, the protective layer 138 is removed, but the present invention is not limited to this. In other embodiments, the protective layer 138 may be formed directly on the protective layer 136 after the electrode 134a is formed, and after the opening 142 is formed, the protective layer 138 and the protective layer 136 are removed.

請參照圖1H,在電極134a上與開口142的表面上共形地形成絕緣材料層144。絕緣材料層144的材料例如是高介電常數材料(high-k material)、氧化矽、氮化矽、氧化矽/氮化矽/氧化矽(oxide-nitride-oxide,ONO)或其組合。高介電常數材料例如是氧化鉭(Ta2 O5 )、氧化鋁(Al2 O3 )、氧化鉿(HfO2 )、氧化鈦(TiO2 )、氧化鋯(ZrO2 )或其組合。絕緣材料層144的形成方法例如是化學氣相沉積法、物理氣相沉積法(PVD)或原子層沉積法(ALD)。1H, an insulating material layer 144 is conformally formed on the electrode 134a and the surface of the opening 142. The material of the insulating material layer 144 is, for example, a high-k material (high-k material), silicon oxide, silicon nitride, silicon oxide/silicon nitride/silicon oxide (oxide-nitride-oxide, ONO) or a combination thereof. The high dielectric constant material is, for example, tantalum oxide (Ta 2 O 5 ), aluminum oxide (Al 2 O 3 ), hafnium oxide (HfO 2 ), titanium oxide (TiO 2 ), zirconium oxide (ZrO 2 ), or a combination thereof. The formation method of the insulating material layer 144 is, for example, chemical vapor deposition, physical vapor deposition (PVD), or atomic layer deposition (ALD).

接著,形成填入開口132與開口142且覆蓋絕緣材料層144的電極材料層146。電極材料層146的材料例如是Ti、TiN、Ta、TaN、Al、In、Nb、Hf、Sn、Zn、Zr、Cu、Y或其組合。電極材料層146的形成方法例如是化學氣相沉積法、物理氣相沉積法、電鍍法、無電鍍沉積法或其組合。Next, an electrode material layer 146 filling the opening 132 and the opening 142 and covering the insulating material layer 144 is formed. The material of the electrode material layer 146 is, for example, Ti, TiN, Ta, TaN, Al, In, Nb, Hf, Sn, Zn, Zr, Cu, Y or a combination thereof. The formation method of the electrode material layer 146 is, for example, a chemical vapor deposition method, a physical vapor deposition method, an electroplating method, an electroless plating method, or a combination thereof.

請參照圖1I,移除位於開口132與開口142的外部的部分電極材料層146與所述絕緣材料層144。藉此,可在開口132中的電極134a上形成電極146a,且可在電極134a與電極146a之間形成絕緣層144a。電極146a可用以作為電容器的上電極。部分電極材料層146與部分絕緣材料層144的移除方法例如是化學機械研磨法。在本實施例中,雖然絕緣層與144a電極146a的形成方法是以上述方法為例進行說明,但本發明並不以此為限。Please refer to FIG. 1I to remove part of the electrode material layer 146 and the insulating material layer 144 located outside the opening 132 and the opening 142. Thereby, the electrode 146a can be formed on the electrode 134a in the opening 132, and the insulating layer 144a can be formed between the electrode 134a and the electrode 146a. The electrode 146a can be used as the upper electrode of the capacitor. The method for removing part of the electrode material layer 146 and part of the insulating material layer 144 is, for example, a chemical mechanical polishing method. In this embodiment, although the method for forming the insulating layer and the electrode 146a of the 144a is described using the above method as an example, the present invention is not limited to this.

電極146a具有延伸至開口142中的延伸部EP。延伸部EP覆蓋開口142所暴露出的電極134a的側面,藉此可有效地增加電容器148的電容。延伸部EP的底部可低於電極134a的頂部。此外,延伸部EP的設置方式可由開口142決定。舉例來說,在開口142位在電極134a的兩側的情況下,延伸部EP可位在電極134a的兩側。在一些實施例中,在開口142環繞電極134a的情況下,延伸部EP可環繞電極134a。在其他實施例中,在開口142僅位在電極134a的一側的情況下,延伸部EP可僅位在電極134a的一側。然而,只要延伸部EP位在電極134a的至少一側,即屬於本發明所保護的範圍。The electrode 146a has an extension EP extending into the opening 142. The extension EP covers the side surface of the electrode 134a exposed by the opening 142, thereby effectively increasing the capacitance of the capacitor 148. The bottom of the extension EP may be lower than the top of the electrode 134a. In addition, the arrangement of the extension part EP can be determined by the opening 142. For example, in the case where the opening 142 is located on both sides of the electrode 134a, the extension part EP may be located on both sides of the electrode 134a. In some embodiments, in the case where the opening 142 surrounds the electrode 134a, the extension EP may surround the electrode 134a. In other embodiments, when the opening 142 is located only on one side of the electrode 134a, the extension EP may be located on only one side of the electrode 134a. However, as long as the extension EP is located on at least one side of the electrode 134a, it belongs to the protection scope of the present invention.

以圖1I為例,延伸部EP可位在電極134a與閘極結構104之間。延伸部EP的底部可高於閘極結構104的頂部,藉此可避免延伸部EP與閘極112發生短路。此外,延伸部EP可位在電極134a與閘極結構116之間。延伸部EP的底部可高於閘極結構116的頂部,藉此可避免延伸部EP與閘極124發生短路。Taking FIG. 1I as an example, the extension EP may be located between the electrode 134 a and the gate structure 104. The bottom of the extension EP can be higher than the top of the gate structure 104, so as to prevent the extension EP and the gate 112 from being short-circuited. In addition, the extension EP may be located between the electrode 134a and the gate structure 116. The bottom of the extension EP can be higher than the top of the gate structure 116, so as to prevent the extension EP and the gate 124 from being short-circuited.

藉由上述方法,可形成耦接在電晶體102a與電晶體102b之間的電容器148。電容器148包括電極134a、電極146a與絕緣層144a。在電容器148中,由於絕緣層144a設置在電極134a與電極146a之間,藉此可形成金屬-絕緣體-金屬(metal-insulator-metal,MIM)電容器。Through the above method, a capacitor 148 coupled between the transistor 102a and the transistor 102b can be formed. The capacitor 148 includes an electrode 134a, an electrode 146a, and an insulating layer 144a. In the capacitor 148, the insulating layer 144a is provided between the electrode 134a and the electrode 146a, thereby forming a metal-insulator-metal (MIM) capacitor.

請參照圖1J,可在介電層128中形成接觸窗150與接觸窗152。接觸窗150與接觸窗152可分別耦接至摻雜區106與摻雜區120。接觸窗150與接觸窗152的材料例如是鎢。接觸窗150與接觸窗152的形成方法例如是金屬鑲嵌法。1J, a contact 150 and a contact 152 may be formed in the dielectric layer 128. The contact window 150 and the contact window 152 may be respectively coupled to the doped region 106 and the doped region 120. The material of the contact window 150 and the contact window 152 is, for example, tungsten. The method of forming the contact window 150 and the contact window 152 is, for example, a damascene method.

接著,可在介電層128上形成介電層154。介電層154的材料例如是氧化矽。介電層154的形成方法例如是化學氣相沉積法。Next, a dielectric layer 154 may be formed on the dielectric layer 128. The material of the dielectric layer 154 is silicon oxide, for example. The formation method of the dielectric layer 154 is, for example, a chemical vapor deposition method.

然後,可在介電層154中形成導體層156、導體層158與導體層160。導體層156、導體層158與導體層160可分別耦接至接觸窗150、接觸窗152與電極146a。導體層156、導體層158與導體層160的材料例如是銅。導體層156、導體層158與導體層160的形成方法例如是金屬鑲嵌法。Then, a conductive layer 156, a conductive layer 158, and a conductive layer 160 may be formed in the dielectric layer 154. The conductor layer 156, the conductor layer 158, and the conductor layer 160 may be respectively coupled to the contact window 150, the contact window 152 and the electrode 146a. The material of the conductor layer 156, the conductor layer 158, and the conductor layer 160 is, for example, copper. The formation method of the conductive layer 156, the conductive layer 158, and the conductive layer 160 is, for example, a damascene method.

以下,藉由圖1J來說明本實施例的記憶體結構10。在本實施例中,此外,雖然記憶體結構10的形成方法是以上述方法為例進行說明,但本發明並不以此為限。Hereinafter, the memory structure 10 of this embodiment will be described with reference to FIG. 1J. In this embodiment, in addition, although the method for forming the memory structure 10 is described by taking the above method as an example, the present invention is not limited thereto.

請參照圖1J,記憶體結構10包括電晶體102a、電晶體102b、介電層128與電容器148。記憶體結構10例如是2電晶體-靜態隨機存取記憶體(2 transistor-static random-access memory,2T-SRAM),但本發明並不以此為限。電晶體102b位在電晶體102a的一側。介電層128覆蓋電晶體102a與電晶體102b。在介電層128中具有相連通的開口132與開口142。開口142位在開口132的側邊。電容器148耦接在電晶體102a與電晶體102b之間。電容器148包括電極134a、電極146a與絕緣層144a。電極134a設置在開口132的表面上。電極146a設置在開口132中的電極134a上,且具有延伸至開口142中的延伸部EP。延伸部EP覆蓋開口142所暴露出的電極134a的側面。絕緣層144a設置在電極134a與電極146a之間。1J, the memory structure 10 includes a transistor 102a, a transistor 102b, a dielectric layer 128 and a capacitor 148. The memory structure 10 is, for example, a 2 transistor-static random-access memory (2T-SRAM), but the invention is not limited to this. Transistor 102b is located on one side of transistor 102a. The dielectric layer 128 covers the transistor 102a and the transistor 102b. The dielectric layer 128 has a communicating opening 132 and an opening 142. The opening 142 is located on the side of the opening 132. The capacitor 148 is coupled between the transistor 102a and the transistor 102b. The capacitor 148 includes an electrode 134a, an electrode 146a, and an insulating layer 144a. The electrode 134a is provided on the surface of the opening 132. The electrode 146a is disposed on the electrode 134a in the opening 132, and has an extension EP extending into the opening 142. The extension EP covers the side surface of the electrode 134a exposed by the opening 142. The insulating layer 144a is provided between the electrode 134a and the electrode 146a.

記憶體結構10更可包括接觸窗150、接觸窗152、介電層154、導體層156、導體層158與導體層160中的至少一者。接觸窗150與接觸窗152位在介電層128中,且可分別耦接至摻雜區106與摻雜區120。介電層154設置在介電層128上。導體層156、導體層158與導體層160設置在介電層154中,且可分別耦接至接觸窗150、接觸窗152與電極146a。The memory structure 10 may further include at least one of a contact window 150, a contact window 152, a dielectric layer 154, a conductive layer 156, a conductive layer 158, and a conductive layer 160. The contact window 150 and the contact window 152 are located in the dielectric layer 128 and can be coupled to the doped region 106 and the doped region 120, respectively. The dielectric layer 154 is disposed on the dielectric layer 128. The conductor layer 156, the conductor layer 158, and the conductor layer 160 are disposed in the dielectric layer 154, and can be coupled to the contact window 150, the contact window 152, and the electrode 146a, respectively.

此外,記憶體結構10中的各構件的材料、設置方式、導電型態、形成方法與功效已於上述實施例進行詳盡地說明,於此不再重複說明。In addition, the materials, disposition methods, conductive types, formation methods, and effects of the components in the memory structure 10 have been described in detail in the foregoing embodiments, and the description will not be repeated here.

基於上述實施例可知,在記憶體結構10及其製造方法中,除了在開口132中的電極146a與電極134a之間可產生電容之外,在電極146a的延伸部EP與電極134a之間亦可產生電容,因此可有效地增加電容器148的電容。藉此,可提升記憶體元件的電性效能,例如可降低記憶體元件的刷新時間週期(refresh time cycle)與耗電量。此外,記憶體結構10及其製造方法可在不增加記憶體元件的面積的情況下,有效地增加電容器148的電容,因此可提升記憶體結構10的實用性與可行性。Based on the above embodiment, in the memory structure 10 and its manufacturing method, in addition to the capacitance generated between the electrode 146a and the electrode 134a in the opening 132, it can also be between the extension EP of the electrode 146a and the electrode 134a. A capacitance is generated, so the capacitance of the capacitor 148 can be effectively increased. In this way, the electrical performance of the memory device can be improved, for example, the refresh time cycle and power consumption of the memory device can be reduced. In addition, the memory structure 10 and the manufacturing method thereof can effectively increase the capacitance of the capacitor 148 without increasing the area of the memory element, so the practicability and feasibility of the memory structure 10 can be improved.

圖3為本發明另一實施例的記憶體結構的剖面圖。圖4A至圖4B為圖3中的開口242的製造流程剖面圖。3 is a cross-sectional view of a memory structure according to another embodiment of the invention. 4A to 4B are cross-sectional views of the manufacturing process of the opening 242 in FIG. 3.

請參照圖1J與圖3,圖3的記憶體結構20與圖1的記憶體結構10在結構上的差異如下。開口242僅位在開口132的單一側邊。在電容器248中,電極246a具有延伸至開口242中的延伸部EP1,且延伸部EP1僅位在電極134a的一側。此外,在記憶體結構20與記憶體結構10中,相同的構件以相同的符號表示並省略其說明。1J and FIG. 3, the difference in structure between the memory structure 20 of FIG. 3 and the memory structure 10 of FIG. 1 is as follows. The opening 242 is located only on a single side of the opening 132. In the capacitor 248, the electrode 246a has an extension EP1 extending into the opening 242, and the extension EP1 is located only on one side of the electrode 134a. In addition, in the memory structure 20 and the memory structure 10, the same components are denoted by the same symbols and their description is omitted.

此外,記憶體結構20與記憶體結構10在製造方法上的差異如下。請參照圖4A,在記憶體結構20的製造方法中,圖案化光阻層240的開口240a僅位在開口132的單一側的介電層128上方。此外,在開口240a的寬度等於開口132的寬度的情況下,開口240a可使用用於形成開口132的同一個光罩進行製作,藉此可降低光罩的數量與生產成本。詳細來說,只要在形成開口240a的微影製程中,將用於形成開口132的光罩往一側偏移,即可製作出開口240a,但本發明並不以此為限。在其他實施例中,開口240a的寬度亦可小於開口132的寬度。接著,請參照圖4B,使用圖案化光阻層240作為罩幕,對保護層138與介電層128進行蝕刻製程,而在開口132的單一側邊形成開口242。在本實施例中,開口242是以位在開口132的鄰近於電晶體102a的一側為例,但本發明並不以此為限。在另一實施例中,開口242亦可位在開口132的鄰近於電晶體102b的一側。此外,用以形成記憶體結構20的後續製程可參考記憶體結構10的製造方法,於此省略其說明。In addition, the manufacturing method differences between the memory structure 20 and the memory structure 10 are as follows. Referring to FIG. 4A, in the manufacturing method of the memory structure 20, the opening 240a of the patterned photoresist layer 240 is only located above the dielectric layer 128 on a single side of the opening 132. In addition, when the width of the opening 240a is equal to the width of the opening 132, the opening 240a can be fabricated using the same mask used to form the opening 132, thereby reducing the number of masks and the production cost. In detail, as long as the photomask for forming the opening 132 is shifted to one side during the lithography process for forming the opening 240a, the opening 240a can be produced, but the present invention is not limited to this. In other embodiments, the width of the opening 240a may be smaller than the width of the opening 132. Next, referring to FIG. 4B, using the patterned photoresist layer 240 as a mask, an etching process is performed on the protective layer 138 and the dielectric layer 128, and an opening 242 is formed on a single side of the opening 132. In this embodiment, the opening 242 is located on the side of the opening 132 adjacent to the transistor 102a as an example, but the invention is not limited to this. In another embodiment, the opening 242 may also be located on the side of the opening 132 adjacent to the transistor 102b. In addition, the subsequent manufacturing process for forming the memory structure 20 can refer to the manufacturing method of the memory structure 10, and its description is omitted here.

基於上述實施例可知,在記憶體結構20及其製造方法中,除了在開口132中的電極246a與電極134a之間可產生電容之外,在電極246a的延伸部EP1與電極134a之間亦可產生電容,因此可有效地增加電容器248的電容。藉此,可提升記憶體元件的電性效能。此外,記憶體結構20及其製造方法可在不增加記憶體元件的面積的情況下,有效地增加電容器248的電容,因此可提升記憶體結構20的實用性與可行性。Based on the above embodiment, in the memory structure 20 and its manufacturing method, in addition to the capacitance generated between the electrode 246a and the electrode 134a in the opening 132, it can also be between the extension EP1 of the electrode 246a and the electrode 134a. A capacitance is generated, so the capacitance of the capacitor 248 can be effectively increased. Thereby, the electrical performance of the memory device can be improved. In addition, the memory structure 20 and the manufacturing method thereof can effectively increase the capacitance of the capacitor 248 without increasing the area of the memory element, so the practicability and feasibility of the memory structure 20 can be improved.

綜上所述,上述實施例的記憶體結構及其製造方法中,可藉由電極的延伸部有效地增加電容器的電容,進而可提升記憶體元件的電性效能。此外,上述實施例的記憶體結構及其製造方法並不會增加記憶體元件的面積,因此可提升記憶體結構的實用性與可行性。To sum up, in the memory structure and manufacturing method of the above-mentioned embodiment, the capacitance of the capacitor can be effectively increased by the extension of the electrode, and the electrical performance of the memory device can be improved. In addition, the memory structure and the manufacturing method thereof of the above-mentioned embodiments do not increase the area of the memory device, so the practicality and feasibility of the memory structure can be improved.

雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明的精神和範圍內,當可作些許的更動與潤飾,故本發明的保護範圍當視後附的申請專利範圍所界定者為準。Although the present invention has been disclosed as above by the embodiments, it is not intended to limit the present invention. Any person with ordinary knowledge in the technical field can make some changes and modifications without departing from the spirit and scope of the present invention. The scope of protection of the present invention shall be subject to the scope defined in the appended patent application.

10、20:記憶體結構100:基底102a、102b:電晶體與電晶體104、116:閘極結構106、108、118、120:摻雜區110、123:間隙壁112、124:閘極114、126、128、154:介電層122:井區130、140、240:圖案化光阻層130a、132、140a、142、240a、242:開口134、146:電極材料層134a、146a、246a:電極136、138:保護層144:絕緣材料層144a:絕緣層148、248:電容器150、152:接觸窗156、158、160:導體層EP、EP1:延伸部10, 20: memory structure 100: substrate 102a, 102b: transistor and transistor 104, 116: gate structure 106, 108, 118, 120: doped area 110, 123: spacer 112, 124: gate 114 , 126, 128, 154: Dielectric layer 122: Well area 130, 140, 240: Patterned photoresist layer 130a, 132, 140a, 142, 240a, 242: Opening 134, 146: Electrode material layer 134a, 146a, 246a : Electrodes 136, 138: Protective layer 144: Insulating material layer 144a: Insulating layer 148, 248: Capacitor 150, 152: Contact window 156, 158, 160: Conductor layer EP, EP1: Extension

圖1A至圖1J為本發明一實施例的記憶體結構的製造流程剖面圖。 圖2為圖1F的局部上視圖。 圖3為本發明另一實施例的記憶體結構的剖面圖。 圖4A至圖4B為圖3中的開口242的製造流程剖面圖。1A to 1J are cross-sectional views of a manufacturing process of a memory structure according to an embodiment of the invention. Figure 2 is a partial top view of Figure 1F. 3 is a cross-sectional view of a memory structure according to another embodiment of the invention. 4A to 4B are cross-sectional views of the manufacturing process of the opening 242 in FIG. 3.

10:記憶體結構 10: Memory structure

100:基底 100: base

102a、102b:電晶體與電晶體 102a, 102b: Transistor and Transistor

104、116:閘極結構 104, 116: Gate structure

106、108、118、120:摻雜區 106, 108, 118, 120: doped area

110、123:間隙壁 110, 123: gap wall

112、124:閘極 112, 124: Gate

114、126、128、154:介電層 114, 126, 128, 154: Dielectric layer

122:井區 122: Well area

132、142:開口 132, 142: Opening

134a、146a:電極 134a, 146a: electrodes

144a:絕緣層 144a: insulating layer

148:電容器 148: Capacitor

150、152:接觸窗 150, 152: contact window

156、158、160:導體層 156, 158, 160: conductor layer

EP:延伸部 EP: Extension

Claims (20)

一種記憶體結構,包括: 第一電晶體; 第二電晶體,位在所述第一電晶體的一側; 介電層,覆蓋所述第一電晶體與所述第二電晶體,其中在所述介電層中具有相連通的第一開口與第二開口,且所述第二開口位在所述第一開口的側邊;以及 電容器,耦接在所述第一電晶體與所述第二電晶體之間,其中所述電容器包括: 第一電極,設置在所述第一開口的表面上; 第二電極,設置在所述第一開口中的所述第一電極上,且具有延伸至所述第二開口中的延伸部,其中所述延伸部覆蓋所述第二開口所暴露出的所述第一電極的側面;以及 絕緣層,設置在所述第一電極與所述第二電極之間。A memory structure includes: a first transistor; a second transistor located on one side of the first transistor; a dielectric layer covering the first transistor and the second transistor, wherein The dielectric layer has a first opening and a second opening that are connected to each other, and the second opening is located on the side of the first opening; and a capacitor is coupled between the first transistor and the Between the second transistors, wherein the capacitor includes: a first electrode arranged on the surface of the first opening; a second electrode arranged on the first electrode in the first opening and having An extension portion extending into the second opening, wherein the extension portion covers the side surface of the first electrode exposed by the second opening; and an insulating layer is provided on the first electrode and the first electrode Between two electrodes. 如申請專利範圍第1項所述的記憶體結構,其中所述第一電晶體與所述第二電晶體分別為N型金氧半導體電晶體與P型金氧半導體電晶體中的一者與另一者。The memory structure according to the first item of the patent application, wherein the first transistor and the second transistor are respectively one of an N-type MOS transistor and a P-type MOS transistor. The other. 如申請專利範圍第1項所述的記憶體結構,其中所述第二開口的底部高於所述第一開口的底部。The memory structure according to claim 1, wherein the bottom of the second opening is higher than the bottom of the first opening. 如申請專利範圍第1項所述的記憶體結構,其中所述第二開口的底部低於所述第一電極的頂部。The memory structure according to the first item of the patent application, wherein the bottom of the second opening is lower than the top of the first electrode. 如申請專利範圍第1項所述的記憶體結構,其中所述第一電極的頂部低於所述第一開口的頂部。The memory structure according to the first item of the patent application, wherein the top of the first electrode is lower than the top of the first opening. 如申請專利範圍第1項所述的記憶體結構,其中所述延伸部的底部低於所述第一電極的頂部。The memory structure according to the first item of the patent application, wherein the bottom of the extension part is lower than the top of the first electrode. 如申請專利範圍第1項所述的記憶體結構,其中 所述第一電晶體包括第一閘極結構與位在所述第一閘極結構兩側的第一摻雜區與第二摻雜區, 所述第二電晶體包括第二閘極結構與位在所述第二閘極結構兩側的第三摻雜區與第四摻雜區,且 所述第二摻雜區與所述第三摻雜區位在所述第一閘極結構與所述第二閘極結構之間。The memory structure according to claim 1, wherein the first transistor includes a first gate structure and a first doped region and a second doped area located on both sides of the first gate structure Region, the second transistor includes a second gate structure, a third doped region and a fourth doped region located on both sides of the second gate structure, and the second doped region and the The third doped region is located between the first gate structure and the second gate structure. 如申請專利範圍第7項所述的記憶體結構,其中所述延伸部位在所述第一電極與所述第一閘極結構之間,且所述延伸部的底部高於所述第一閘極結構的頂部。The memory structure according to claim 7, wherein the extension part is between the first electrode and the first gate structure, and the bottom of the extension part is higher than the first gate The top of the pole structure. 如申請專利範圍第7項所述的記憶體結構,其中所述延伸部位在所述第一電極與所述第二閘極結構之間,且所述延伸部的底部高於所述第二閘極結構的頂部。The memory structure according to claim 7, wherein the extension part is between the first electrode and the second gate structure, and the bottom of the extension part is higher than the second gate The top of the pole structure. 如申請專利範圍第7項所述的記憶體結構,其中所述第一開口暴露出所述第二摻雜區與所述第三摻雜區。According to the memory structure described in claim 7, wherein the first opening exposes the second doped region and the third doped region. 如申請專利範圍第7項所述的記憶體結構,其中所述第一電極耦接至所述第二摻雜區與所述第三摻雜區。The memory structure according to claim 7, wherein the first electrode is coupled to the second doped region and the third doped region. 一種記憶體結構的製造方法,包括: 提供第一電晶體與第二電晶體,其中所述第二電晶體位在所述第一電晶體的一側; 形成覆蓋所述第一電晶體與所述第二電晶體的介電層,其中在所述介電層中具有相連通的第一開口與第二開口,且所述第二開口位在所述第一開口的側邊;以及 形成耦接在所述第一電晶體與所述第二電晶體之間的電容器,其中所述電容器包括: 第一電極,設置在所述第一開口的表面上; 第二電極,設置在所述第一開口中的所述第一電極上,且具有延伸至所述第二開口中的延伸部,其中所述延伸部覆蓋所述第二開口所暴露出的所述第一電極的側面;以及 絕緣層,設置在所述第一電極與所述第二電極之間。A method for manufacturing a memory structure includes: providing a first transistor and a second transistor, wherein the second transistor is located on one side of the first transistor; forming a cover that covers the first transistor and the second transistor. The dielectric layer of the second transistor, wherein a first opening and a second opening are connected in the dielectric layer, and the second opening is located on the side of the first opening; and a coupling is formed A capacitor connected between the first transistor and the second transistor, wherein the capacitor includes: a first electrode disposed on the surface of the first opening; a second electrode disposed on the first opening On the first electrode in an opening, there is an extension portion extending into the second opening, wherein the extension portion covers the side surface of the first electrode exposed by the second opening; and insulation The layer is arranged between the first electrode and the second electrode. 如申請專利範圍第12項所述的記憶體結構的製造方法,其中所述第一電晶體與所述第二電晶體分別為N型金氧半導體電晶體與P型金氧半導體電晶體中的一者與另一者。The manufacturing method of the memory structure as described in item 12 of the scope of the patent application, wherein the first transistor and the second transistor are respectively an N-type MOS transistor and a P-type MOS transistor. One and the other. 如申請專利範圍第12項所述的記憶體結構的製造方法,其中所述第一電極的形成方法包括: 在所述第一開口的表面上共形地形成第一電極材料層; 形成填入所述第一開口中且覆蓋所述第一電極材料層的保護層;以及 對所述保護層所與述第一電極材料層進行回蝕刻製程。The manufacturing method of the memory structure as described in the scope of patent application, wherein the method of forming the first electrode includes: forming a first electrode material layer conformally on the surface of the first opening; forming a filling A protective layer in the first opening and covering the first electrode material layer; and performing an etch-back process on the protective layer and the first electrode material layer. 如申請專利範圍第12項所述的記憶體結構的製造方法,其中所述第一電極的頂部低於所述第一開口的頂部。According to the manufacturing method of the memory structure described in the scope of patent application, the top of the first electrode is lower than the top of the first opening. 如申請專利範圍第12項所述的記憶體結構的製造方法,其中所述第二開口的形成方法包括: 形成填入所述第一開口且覆蓋所述第一電極與所述介電層的保護層; 在所述保護層上形成具有第三開口的圖案化光阻層,其中所述第三開口位在部分所述介電層上方;以及 使用所述圖案化光阻層作為罩幕,對所述保護層與所述介電層進行蝕刻製程,其中所述蝕刻製程對所述介電層的蝕刻速率高於對所述保護層的蝕刻速率。According to the manufacturing method of the memory structure described in claim 12, the method for forming the second opening includes: forming a layer that fills the first opening and covers the first electrode and the dielectric layer A protective layer; forming a patterned photoresist layer with a third opening on the protective layer, wherein the third opening is located above a portion of the dielectric layer; and using the patterned photoresist layer as a mask, An etching process is performed on the protection layer and the dielectric layer, wherein the etching process for the dielectric layer has a higher etching rate than the protection layer. 如申請專利範圍第12項所述的記憶體結構的製造方法,其中所述第二開口的底部高於所述第一開口的底部。According to the manufacturing method of the memory structure described in claim 12, the bottom of the second opening is higher than the bottom of the first opening. 如申請專利範圍第12項所述的記憶體結構的製造方法,其中所述第二開口的底部低於所述第一電極的頂部。According to the manufacturing method of the memory structure described in the scope of patent application item 12, the bottom of the second opening is lower than the top of the first electrode. 如申請專利範圍第12項所述的記憶體結構的製造方法,其中所述絕緣層與所述第二電極的形成方法包括: 在所述第一電極上與所述第二開口的表面上共形地形成絕緣材料層; 形成填入所述第一開口與所述第二開口且覆蓋所述絕緣材料層的第二電極材料層;以及 移除位於所述第一開口與所述第二開口的外部的部分所述第二電極材料層與部分所述絕緣材料層。According to the method of manufacturing the memory structure described in claim 12, the method of forming the insulating layer and the second electrode includes: coordinating on the first electrode and the surface of the second opening Forming an insulating material layer in a manner; forming a second electrode material layer filling the first opening and the second opening and covering the insulating material layer; and removing the first opening and the second opening Part of the second electrode material layer and part of the insulating material layer. 如申請專利範圍第19項所述的記憶體結構的製造方法,其中部分所述第二電極材料層與部分所述絕緣材料層的移除方法包括化學機械研磨法。According to the manufacturing method of the memory structure described in the scope of patent application, the method for removing part of the second electrode material layer and part of the insulating material layer includes a chemical mechanical polishing method.
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US11950409B2 (en) 2022-03-29 2024-04-02 Nanya Technology Corporation Semiconductor device having diode connectedto memory device and circuit including the same

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Publication number Priority date Publication date Assignee Title
TWI809927B (en) * 2022-03-29 2023-07-21 南亞科技股份有限公司 Semiconductor device having diode connectedto memory device and integrated circuit including the same
US11950409B2 (en) 2022-03-29 2024-04-02 Nanya Technology Corporation Semiconductor device having diode connectedto memory device and circuit including the same

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