TW202010849A - Titanium alloy for casting a golf club head - Google Patents

Titanium alloy for casting a golf club head Download PDF

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TW202010849A
TW202010849A TW107132113A TW107132113A TW202010849A TW 202010849 A TW202010849 A TW 202010849A TW 107132113 A TW107132113 A TW 107132113A TW 107132113 A TW107132113 A TW 107132113A TW 202010849 A TW202010849 A TW 202010849A
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golf club
titanium alloy
club head
casting
forming
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TW107132113A
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TWI711704B (en
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利建良
鄭達謙
周根葦
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復盛應用科技股份有限公司
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Priority to TW107132113A priority Critical patent/TWI711704B/en
Priority to US16/561,442 priority patent/US20200080170A1/en
Priority to JP2019164163A priority patent/JP6862517B2/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C14/00Alloys based on titanium
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B53/00Golf clubs
    • A63B53/04Heads
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B2209/00Characteristics of used materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Golf Clubs (AREA)

Abstract

A titanium alloy for casting a golf club head is used to solve the problem of the poor formation rate of the vacuum centrifugal casting method in use of the conventional titanium alloy. The alloy includes 7.0-8.0 wt% of aluminum (Al), 4.0-5.5 wt% of vanadium (V), 0.5-1.5 wt% of chromium (Cr), 0.05-0.15 wt% of silicon (Si) and 0.05-0.3 wt% of iron (Fe). The others are titanium (Ti) and impurities.

Description

用以鑄造成形高爾夫球桿頭之鈦合金 Titanium alloy for casting and forming golf club heads

本發明係關於一種鈦合金,特別係關於一種用以鑄造成形高爾夫球桿頭之鈦合金。 The invention relates to a titanium alloy, in particular to a titanium alloy used for casting and forming a golf club head.

一般而言,為了符合使用者對於高爾夫球桿頭之輕量的需求,工者可以使用鈦合金來製造高爾夫球桿頭,舉例而言,習知鈦合金包含鋁、釩、鉻、矽、鐵、鈦及不可避免之雜質,然而,由於該習知鈦合金的流動性不佳,在搭配真空離心澆鑄法製造高爾夫球桿頭時,高爾夫球桿頭的成形率僅為40~60%,因此仍須提供一種用以鑄造成形高爾夫球桿頭之鈦合金,以解決上述的問題。 Generally speaking, in order to meet the user's lightweight requirements for golf club heads, workers can use titanium alloys to manufacture golf club heads. For example, conventional titanium alloys include aluminum, vanadium, chromium, silicon, and iron , Titanium and inevitable impurities, however, due to the poor fluidity of the conventional titanium alloy, when the golf club head is manufactured with the vacuum centrifugal casting method, the forming rate of the golf club head is only 40-60%, so There is still a need to provide a titanium alloy for casting and forming golf club heads to solve the above-mentioned problems.

為解決前述問題,本發明的目的遂提供一種用以鑄造成形高爾夫球桿頭之鈦合金,係具有良好的高爾夫球桿頭的成形率者。 In order to solve the aforementioned problems, the object of the present invention is to provide a titanium alloy for casting and forming a golf club head, which has a good golf club head forming rate.

本發明的次一目的是提供一種用以鑄造成形高爾夫球桿頭之鈦合金,以該鈦合金製造獲得的高爾夫球桿頭具有良好的抗拉強度及降伏強度者。 The next object of the present invention is to provide a titanium alloy for casting and forming a golf club head, and a golf club head manufactured by using the titanium alloy has good tensile strength and yield strength.

本發明之用以鑄造成形高爾夫球桿頭之鈦合金,係包含:以重量百分比計為7.0~8.0%之鋁、4.0~5.5%之釩、0.5~1.5%之鉻、0.05~0.15% 之矽、0.05~0.3%之鐵,其餘比例為鈦及不可避免之雜質。如此,藉由鋁、釩、鉻、矽、鐵及鈦的組成配比,使本發明之用以鑄造成形高爾夫球桿頭之鈦合金在搭配真空離心澆鑄法製造高爾夫球桿頭時,可以具有良好的成形率,且製造獲得的高爾夫球桿頭亦具有優於習知鈦合金所製得者的機械性質(例如:抗拉強度及降伏強度),為本發明之功效。 The titanium alloy used for casting and forming golf club heads of the present invention comprises: 7.0-8.0% aluminum by weight, 4.0-5.5% vanadium, 0.5-1.5% chromium, 0.05-0.15% silicon , 0.05~0.3% iron, and the remaining proportion is titanium and inevitable impurities. In this way, the composition ratio of aluminum, vanadium, chromium, silicon, iron, and titanium enables the titanium alloy of the present invention to be used to cast and shape golf club heads when used in conjunction with vacuum centrifugal casting to produce golf club heads Good forming rate, and the golf club head obtained by manufacturing also has better mechanical properties (such as tensile strength and yield strength) than those made by the conventional titanium alloy, which is the effect of the present invention.

本發明之用以鑄造成形高爾夫球桿頭之鈦合金,其中,包含以重量百分比計為7.25~7.75%的鋁。如此,藉由鋁含量的調整可以提升該用以鑄造成形高爾夫球桿頭之鈦合金的流動性。 The titanium alloy used in the present invention to cast and shape a golf club head includes aluminum in an amount of 7.25 to 7.75% by weight. In this way, the fluidity of the titanium alloy used to cast and shape the golf club head can be improved by adjusting the aluminum content.

本發明之用以鑄造成形高爾夫球桿頭之鈦合金,其中,包含以重量百分比計為4.25~4.75%的釩。如此,藉由釩含量的調整可以提升該用以鑄造成形高爾夫球桿頭之鈦合金的強度。 The titanium alloy used in the present invention to cast and shape a golf club head includes vanadium in a weight percentage of 4.25 to 4.75%. In this way, the strength of the titanium alloy used to cast and shape the golf club head can be improved by adjusting the vanadium content.

本發明之用以鑄造成形高爾夫球桿頭之鈦合金,其中,包含以重量百分比計為1.0~1.5%的鉻。如此,藉由釩含量的調整可以提升該用以鑄造成形高爾夫球桿頭之鈦合金的強度。 The titanium alloy used in the present invention for casting and forming golf club heads contains 1.0 to 1.5% of chromium by weight. In this way, the strength of the titanium alloy used to cast and shape the golf club head can be improved by adjusting the vanadium content.

本發明之用以鑄造成形高爾夫球桿頭之鈦合金,其中,包含以重量百分比計為0.05~0.10%的矽。 The titanium alloy used in the present invention for casting and forming golf club heads contains 0.05% to 0.10% silicon by weight.

本發明之用以鑄造成形高爾夫球桿頭之鈦合金,其中,包含以重量百分比計為0.05~0.08%的鐵。如此,藉由鐵含量的調整可以提升該用以鑄造成形高爾夫球桿頭之鈦合金的強度。 The titanium alloy used in the present invention for casting and forming golf club heads contains 0.05 to 0.08% iron by weight. In this way, the strength of the titanium alloy used to cast and shape the golf club head can be improved by adjusting the iron content.

本發明之用以鑄造成形高爾夫球桿頭之鈦合金,其中,以該鈦合金製造所得的高爾夫球桿頭之抗拉強度為140~150ksi、降伏強度為128~138ksi,且伸長率為4~8%。如此,使該高爾夫球桿頭具有符合打擊需求的強度,能夠提升該高爾夫球桿頭的使用壽命。 The titanium alloy used for casting and forming a golf club head according to the present invention, wherein the golf club head manufactured from the titanium alloy has a tensile strength of 140 to 150 ksi, a yield strength of 128 to 138 ksi, and an elongation of 4 to 8%. In this way, the golf club head has a strength that meets the demand for hitting, which can increase the service life of the golf club head.

本發明之用以鑄造成形高爾夫球桿頭之鈦合金,用以鑄造成形 一高爾夫球桿頭時,成形率為85~96%。如此,可以減少鑄造成形該高爾夫球桿頭時產生過多的廢料,進而能夠降低該高爾夫球桿頭的製造成本。 When the titanium alloy of the present invention is used to cast and shape a golf club head, when it is used to cast and shape a golf club head, the forming rate is 85 to 96%. In this way, excessive waste generated when casting the golf club head can be reduced, and thus the manufacturing cost of the golf club head can be reduced.

為讓本發明之上述及其他目的、特徵及優點能更明顯易懂,下文特舉本發明之較佳實施例,並配合所附圖式,作詳細說明如下:本發明之用以鑄造成形高爾夫球桿頭之鈦合金係可以包含:特定比例的鋁(aluminum,Al)、釩(vanadium,V)、鉻(chromium,Cr)、矽(silicon,Si)、鐵(iron,Fe),其餘比例為鈦(titanium,Ti)及不可避免之雜質。 In order to make the above-mentioned and other objects, features and advantages of the present invention more obvious and understandable, the preferred embodiments of the present invention are described below in conjunction with the accompanying drawings, which are described in detail as follows: The titanium alloy of the club head may include: a specific ratio of aluminum (Al), vanadium (V), chromium (Cr), silicon (silicon, Si), iron (iron, Fe), the remaining proportion Titanium (Ti) and inevitable impurities.

詳而言之,該用以鑄造成形高爾夫球桿頭之鈦合金可以包含以重量百分比計為7.0~8.0%的鋁,較佳可以包含以重量百分比計為7.25~7.75%的鋁,如此可以提升該用以鑄造成形高爾夫球桿頭之鈦合金的流動性,惟值得注意的是,鋁含量過高時,所製得的高爾夫球桿頭會變脆,因此限定鋁含量不應超過8.0%。 In detail, the titanium alloy used for casting the golf club head may contain 7.0% to 8.0% aluminum by weight, preferably may contain 7.25% to 7.75% aluminum by weight, so that it can be improved The fluidity of the titanium alloy used to cast the golf club head is worth noting that when the aluminum content is too high, the resulting golf club head will become brittle, so the aluminum content should not exceed 8.0%.

該用以鑄造成形高爾夫球桿頭之鈦合金可以包含以重量百分比計為4.0~5.5%的釩,較佳可以包含以重量百分比計為4.25~4.75%的釩,如此可以提升該用以鑄造成形高爾夫球桿頭之鈦合金的機械性質(例如,抗拉強度及降伏強度),惟須注意釩含量過高時會影響高爾夫球桿頭的成形率,因此限定釩含量不應超過5.5%。 The titanium alloy used for casting and shaping the golf club head may contain 4.0 to 5.5% by weight of vanadium, preferably may contain 4.25 to 4.75% by weight of vanadium, so that the casting for casting can be improved The mechanical properties (such as tensile strength and yield strength) of the titanium alloy of the golf club head, but it should be noted that excessively high vanadium content will affect the forming rate of the golf club head, so the limited vanadium content should not exceed 5.5%.

該用以鑄造成形高爾夫球桿頭之鈦合金可以包含以重量百分比計為0.5~1.5%的鉻,較佳可以包含以重量百分比計為1.0~1.5%的鉻,如此可以提升該用以鑄造成形高爾夫球桿頭之鈦合金的機械性質(例如,抗拉強度及降伏強度),惟須注意鉻含量過高時會影響高爾夫球桿頭的成形率, 因此限定鉻含量不應超過1.5%。 The titanium alloy used for casting and forming golf club heads may contain 0.5 to 1.5% by weight of chromium, preferably may contain 1.0 to 1.5% by weight of chromium, so that the casting for casting can be improved The mechanical properties (such as tensile strength and yield strength) of the titanium alloy of the golf club head, but it should be noted that too high chromium content will affect the forming rate of the golf club head, so the chromium content should not exceed 1.5%.

該用以鑄造成形高爾夫球桿頭之鈦合金可以包含以重量百分比計為0.05~0.15%的矽,較佳可以包含以重量百分比計為0.05~0.10%的矽,惟須注意矽含量過高時會降低高爾夫球桿頭的伸長率及成形率,因此限定矽含量不應超過0.10%。 The titanium alloy used to cast and shape the golf club head may contain 0.05% to 0.15% silicon by weight, preferably 0.05% to 0.10% silicon by weight, but it must be noted that when the silicon content is too high Will reduce the elongation and forming rate of the golf club head, so the limited silicon content should not exceed 0.10%.

該用以鑄造成形高爾夫球桿頭之鈦合金可以包含以重量百分比計為0.05~0.3%的鐵,較佳可以包含以重量百分比計為0.05~0.08%的鐵,如此可以提升該用以鑄造成形高爾夫球桿頭之鈦合金的機械性質(例如,抗拉強度及降伏強度),惟須注意鐵含量過高時會影響高爾夫球桿頭的成形率,因此限定鐵含量不應超過0.3%。 The titanium alloy used for casting and shaping the golf club head may contain 0.05% to 0.3% iron by weight, preferably may contain 0.05% to 0.08% iron by weight, so that the casting for casting can be improved The mechanical properties (such as tensile strength and yield strength) of the titanium alloy of the golf club head, but it must be noted that too high iron content will affect the forming rate of the golf club head, so the limited iron content should not exceed 0.3%.

因此,工者在利用前述之用以鑄造成形高爾夫球桿頭之鈦合金,搭配真空澆鑄法製造獲得一高爾夫球桿頭時,可以提升高爾夫球桿頭的成形率,且以該鈦合金鑄造成形所得的高爾夫球桿頭之抗拉強度及降伏強度,亦均優於以習知鈦合金所得的高爾夫球桿頭。 Therefore, when the above-mentioned titanium alloy used for casting and forming a golf club head is used to manufacture a golf club head by using the vacuum casting method, the golf club head forming rate can be improved and the titanium alloy can be cast to form The tensile strength and yield strength of the resulting golf club head are also superior to those obtained with conventional titanium alloys.

為了證實利用前述之用以鑄造成形高爾夫球桿頭之鈦合金,搭配真空澆鑄法製造獲得一高爾夫球桿頭時,確實可以提升高爾夫球桿頭的成形率,且該高爾夫球桿頭也具有較佳的機械性質,遂進行以下試驗: 以本發明之鈦合金(第A1組)製造高爾夫球桿頭時,成形率可以達85~96%,而以習知鈦合金(第A2組)製造高爾夫球桿頭時,成形率僅為40~60%。 In order to verify that the titanium alloy used to cast and shape the golf club head mentioned above, and the vacuum casting method is used to obtain a golf club head, the golf club head forming rate can indeed be improved, and the golf club head also has For the best mechanical properties, the following tests were carried out: When the golf club head is made from the titanium alloy of the present invention (Group A1), the forming rate can reach 85-96%, while the golf ball is made from the conventional titanium alloy (Group A2) At the club head, the forming rate is only 40 to 60%.

又,前述的高爾夫球桿頭的機械性質如第1表所示。 The mechanical properties of the aforementioned golf club head are shown in Table 1.

Figure 107132113-A0101-12-0004-1
Figure 107132113-A0101-12-0004-1
Figure 107132113-A0101-12-0005-2
Figure 107132113-A0101-12-0005-2

如第1表所示,以本發明之鈦合金製得的高爾夫球桿頭的抗拉強度及降伏強度均明顯高於以習知鈦合金製得者,顯示藉由該用以鑄造成形高爾夫球桿頭之鈦合金所含有的鋁、釩、鉻、矽、鐵及鈦的組成配比,不僅能夠提升高爾夫球桿頭的成形率,也可以提升製造獲得的高爾夫球桿頭的機械性質(例如:抗拉強度及降伏強度)。 As shown in Table 1, the tensile strength and yield strength of the golf club head made of the titanium alloy of the present invention are significantly higher than those made of the conventional titanium alloy, showing that the golf ball is formed by casting The composition ratio of aluminum, vanadium, chromium, silicon, iron and titanium contained in the titanium alloy of the club head can not only improve the forming rate of the golf club head, but also improve the mechanical properties of the golf club head obtained by manufacturing (for example : Tensile strength and yield strength).

綜上所述,藉由鋁、釩、鉻、矽、鐵及鈦的組成配比,使本發明之用以鑄造成形高爾夫球桿頭之鈦合金在搭配真空離心澆鑄法製造高爾夫球桿頭時,可以具有良好的成形率,且製造獲得的高爾夫球桿頭亦具有優於以習知鈦合金所製得者的機械性質(例如:抗拉強度及降伏強度),為本發明之功效。 In summary, the titanium alloy used for casting and forming golf club heads of the present invention, when combined with the vacuum centrifugal casting method to manufacture golf club heads, is composed of aluminum, vanadium, chromium, silicon, iron, and titanium. It can have a good forming rate, and the golf club head obtained by manufacturing also has better mechanical properties (such as tensile strength and yield strength) than those made by the conventional titanium alloy, which is the effect of the present invention.

雖然本發明已利用上述較佳實施例揭示,然其並非用以限定本發明,任何熟習此技藝者在不脫離本發明之精神和範圍之內,相對上述實施例進行各種更動與修改仍屬本發明所保護之技術範疇,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。 Although the present invention has been disclosed using the above-mentioned preferred embodiments, it is not intended to limit the present invention. Anyone who is familiar with this art without departing from the spirit and scope of the present invention still makes various changes and modifications to the above-mentioned embodiments. The technical scope of the invention is protected, so the scope of protection of the present invention shall be subject to the scope defined in the appended patent application.

Claims (8)

一種用以鑄造成形高爾夫球桿頭之鈦合金,包含:以重量百分比計為7.0~8.0%的鋁、4.0~5.5%的釩、0.5~1.5%的鉻、0.05~0.15%的矽及0.05~0.3%的鐵,其餘比例為鈦及不可避免之雜質。 A titanium alloy used for casting and forming golf club heads, comprising: 7.0-8.0% aluminum, 4.0-5.5% vanadium, 0.5-1.5% chromium, 0.05-0.15% silicon, and 0.05-% by weight 0.3% iron, the rest is titanium and inevitable impurities. 如申請專利範圍第1項所述之用以鑄造成形高爾夫球桿頭之鈦合金,其中,包含以重量百分比計為7.25~7.75%的鋁。 The titanium alloy used for casting and forming golf club heads as described in item 1 of the patent application scope, which contains aluminum in a weight percentage of 7.25~7.75%. 如申請專利範圍第1項所述之用以鑄造成形高爾夫球桿頭之鈦合金,其中,包含以重量百分比計為4.25~4.75%的釩。 The titanium alloy used for casting and forming golf club heads as described in item 1 of the patent application scope, which contains vanadium in a weight percentage of 4.25 to 4.75%. 如申請專利範圍第1項所述之用以鑄造成形高爾夫球桿頭之鈦合金,其中,包含以重量百分比計為1.0~1.5%的鉻。 The titanium alloy used for casting and forming golf club heads as described in item 1 of the patent application scope, which contains 1.0 to 1.5% of chromium by weight. 如申請專利範圍第1項所述之用以鑄造成形高爾夫球桿頭之鈦合金,其中,包含以重量百分比計為0.05~0.10%的矽。 The titanium alloy used for casting and forming golf club heads as described in item 1 of the scope of the patent application contains 0.05% to 0.10% silicon by weight. 如申請專利範圍第1項所述之用以鑄造成形高爾夫球桿頭之鈦合金,其中,包含以重量百分比計為0.05~0.08%的鐵。 The titanium alloy used for casting and forming golf club heads as described in item 1 of the patent application scope, which contains 0.05 to 0.08% iron by weight. 如申請專利範圍第1項所述之用以鑄造成形高爾夫球桿頭之鈦合金,其中,以該鈦合金製造所得的高爾夫球桿頭之抗拉強度為140~150ksi、降伏強度為128~138ksi,且伸長率為4~8%。 The titanium alloy used for casting and forming a golf club head as described in item 1 of the patent application scope, wherein the tensile strength of the golf club head manufactured from the titanium alloy is 140-150 ksi and the yield strength is 128-138 ksi , And the elongation is 4~8%. 如申請專利範圍第1項所述之用以鑄造成形高爾夫球桿頭之鈦合金,其中,以該鈦合金鑄造成形一高爾夫球桿頭時,成形率為85~96%。 The titanium alloy used for casting and forming a golf club head as described in item 1 of the scope of the patent application, wherein when the titanium alloy is cast to form a golf club head, the forming rate is 85 to 96%.
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