TW202002782A - Emulsifiable pesticide composition - Google Patents

Emulsifiable pesticide composition Download PDF

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TW202002782A
TW202002782A TW108118221A TW108118221A TW202002782A TW 202002782 A TW202002782 A TW 202002782A TW 108118221 A TW108118221 A TW 108118221A TW 108118221 A TW108118221 A TW 108118221A TW 202002782 A TW202002782 A TW 202002782A
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mass
acid
methyl
pesticide
parts
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TW108118221A
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TWI800652B (en
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堀雅仁
釜谷拓和
高橋寛明
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日商日產化學股份有限公司
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system

Abstract

Provided is an emulsifiable pesticide composition that, when diluted with water, has significantly improved emulsification stability. This emulsifiable pesticide composition contains: (a) at least one active pesticide substance selected from fluxametamide, pyridaben, amisulbrom, and quizalofop-P-ethyl; (b) (b-1) a polar solvent containing 3-methoxy-N,N-dimethylpropaneamide and (b-2) a mixed solvent containing a nonpolar solvent; and (c) a surfactant.

Description

農藥乳化性組成物Pesticide emulsifiable composition

本發明係關於農藥乳化性組成物。The present invention relates to a pesticide emulsifiable composition.

農藥乳化性組成物為混合農藥活性成分、界面活性劑(乳化劑)及溶劑之均勻的液狀組成物。農藥乳化性組成物使用時以水稀釋，自發性形成乳液(emulsion)(微細之油滴分散在水中的狀態)。此時，有乳液中之溶劑漸漸溶解在水的情況，因此，有乳液中之農藥有效成分的溶解力減少，於水中析出農藥有效成分的結晶的情況。析出結晶時，由於生物活性的減少或對散布機過濾器之堵塞等對使用者產生不利，故期望能盡可能不析出結晶。本發明者們報告有即使以水稀釋後，乳化安定性亦良好之農藥乳化性組成物(專利文獻1)。 [先前技術文獻] [專利文獻]Pesticide emulsifiable composition is a uniform liquid composition in which pesticide active ingredient, surfactant (emulsifier) and solvent are mixed. The pesticide emulsifiable composition is diluted with water when used, and an emulsion (a state in which fine oil droplets are dispersed in water) spontaneously forms (emulsion). At this time, the solvent in the emulsion may gradually dissolve in water. Therefore, the solubility of the active ingredient of the pesticide in the emulsion may be reduced, and crystals of the active ingredient of the pesticide may be precipitated in water. In the case of precipitation of crystals, the reduction of biological activity or clogging of the filter of the dispenser is harmful to the user, so it is expected that the crystals will not be precipitated as much as possible. The inventors of the present invention have reported an emulsifiable composition of pesticides with good emulsion stability even after dilution with water (Patent Document 1). [Prior Technical Literature] [Patent Literature]

[專利文獻1]國際公開第2014/119519號[Patent Literature 1] International Publication No. 2014/119519

[發明欲解決之課題][Problem to be solved by invention]

本發明係鑑於前述問題而完成者，以提供一種大幅改善以水稀釋時之乳化安定性的農藥乳化性組成物作為目的。 [用以解決課題之手段]The present invention has been completed in view of the foregoing problems, and aims to provide a pesticide emulsifiable composition that greatly improves the emulsion stability when diluted with water. [Means to solve the problem]

本發明者們為了解決前述課題重複努力研究的結果，發現藉由使用3-甲氧基-N,N-二甲基丙醯胺作為極性溶劑，得到大幅改善以水稀釋時之乳化安定性的農藥乳化性組成物，而完成本發明。As a result of repeated efforts to solve the aforementioned problems, the present inventors found that by using 3-methoxy-N,N-dimethylpropylamide as a polar solvent, the emulsion stability when diluted with water is greatly improved. The present invention is completed by an emulsified composition of pesticides.

亦即，本發明係提供下述農藥乳化性組成物。 1.一種農藥乳化性組成物，其係包含： (a)選自氟米塔麥(fluxametamide)、畢達本、安美速及快伏草中之至少1種的農藥活性物質、 (b)包含(b-1)包含3-甲氧基-N,N-二甲基丙醯胺之極性溶劑及(b-2)非極性溶劑之混合溶劑、以及 (c)界面活性劑。 2.如1之農藥乳化性組成物，其中，(b-2)非極性溶劑為芳香族烴。 3.如1或2之農藥乳化性組成物，其中，(b-1)極性溶劑及(b-2)非極性溶劑的混合比以質量比為極性溶劑：非極性溶劑=15：85～65：35。 4.如1～3中任一項之農藥乳化性組成物，其中，(c)界面活性劑為包含非離子性界面活性劑。 5.如4之農藥乳化性組成物，其中，前述非離子性界面活性劑係包含選自由聚氧化烯基芳基苯基醚、聚氧化烯基芳基苯基醚之福馬林縮合物、聚氧化烯基植物油及聚氧乙烯聚氧丙烯嵌段聚合物所構成之群組中之至少1種。 6.如4或5之農藥乳化性組成物，其中，(c)界面活性劑係進一步包含陰離子性界面活性劑。 [發明效果]That is, the present invention provides the following pesticide emulsifiable composition. 1. A pesticide emulsifiable composition, which comprises: (a) At least one pesticide active substance selected from the group consisting of fluxametamide, Pidaben, Amethicone, and fast Fu grass, (b) a mixed solvent containing (b-1) a polar solvent containing 3-methoxy-N,N-dimethylpropylamide and (b-2) a non-polar solvent, and (c) Surfactant. 2. The pesticide emulsifiable composition of 1, wherein (b-2) the non-polar solvent is an aromatic hydrocarbon. 3. Pesticide emulsified composition as in 1 or 2, wherein the mixing ratio of (b-1) polar solvent and (b-2) non-polar solvent is the mass ratio of polar solvent: non-polar solvent = 15: 85～65 : 35. 4. The pesticide emulsifiable composition according to any one of 1 to 3, wherein (c) the surfactant contains a nonionic surfactant. 5. The pesticide emulsifiable composition of 4, wherein the nonionic surfactant includes a formalin condensate selected from polyoxyalkylene aryl phenyl ether, polyoxyalkylene aryl phenyl ether, poly At least one of the group consisting of oxyalkylene-based vegetable oil and polyoxyethylene polyoxypropylene block polymer. 6. The pesticide emulsifiable composition according to 4 or 5, wherein (c) the surfactant system further contains an anionic surfactant. [Effect of the invention]

本發明之農藥乳化性組成物由於大幅改善以水稀釋時之乳化安定性，故操作性優異，生物活性亦高。Since the pesticide emulsifiable composition of the present invention greatly improves the emulsification stability when diluted with water, it has excellent operability and high biological activity.

[(a)農藥活性成分] (a)成分之農藥活性成分係包含選自氟米塔麥(fluxametamide)、畢達本、安美速及快伏草中之至少1種者。[(a) Pesticide active ingredient] (a) The pesticide active ingredient of the component includes at least one selected from the group consisting of fluametamide, pyridaben, amethicone, and fast grass.

本發明之農藥乳化性組成物可進一步包含前述農藥活性成分以外之農藥活性成分(以下，亦稱為其他農藥活性成分)，尤其是包含殺菌劑、殺細菌劑、殺線蟲劑、殺蟎劑、殺蟲劑或除草劑。將其他農藥活性成分之具體例作為一般名例示於以下。The pesticide emulsifiable composition of the present invention may further contain pesticide active ingredients (hereinafter, also referred to as other pesticide active ingredients) other than the aforementioned pesticide active ingredients, and particularly include bactericides, bactericides, nematicides, acaricides, Insecticide or herbicide. Specific examples of other pesticide active ingredients are shown below as general names.

作為殺菌劑，可列舉阿拉酸式苯Ｓ甲基(acibenzolar-S-methyl)、艾莎派(acypetacs)、殺螟丹(aldimorph)、烯丙醇(allyl alcohol)、唑嘧菌胺(ametoctradin)、胺基吡芬(aminopyrifen)、代森銨(amobam)、胺基丙基磷酸(ampropylfos)、防霉靈(anilazine)、戊環唑(azaconazole)、塞侖(azithiram)、亞托敏(azoxystrobin)、鋇聚硫化物(barium polysulfide)、苯霜靈(benalaxyl)、苯霜靈-M (benalaxyl-M)、麥鏽靈(benodanil)、苯菌靈(benomyl)、敵菌腙(benquinox)、丙唑草隆(bentaluron)、苯噻菌胺(benthiavalicarb-isopropyl)、苯噻硫氰(benthiazole)、節烯酸(benzamacril)、苯雜嗎(benzamorf)、苯并烯氟菌唑(benzovindiflupyr)、樂殺蟎(binapacryl)、聯苯(biphenyl)、聯苯三唑醇(bitertanol)、聯苯吡菌胺(bixafen)、殺稻瘟菌素-S(blasticidin-S)、波爾多液(bordeaux mixture)、白克列(boscalid)、溴克座(bromoconazole)、布瑞莫(bupirimate)、得滅多(buthiobate)、丁胺(butylamine)、石灰硫合劑(calcium polysulfide)、四氯丹(captafol)、克菌丹(captan)、嗎菌威(carbamorph)、貝芬替(carbendazim)、萎銹靈(carboxin)、環丙醯菌胺(carpropamid)、香芹酮(carvone)、切欣特混合液(cheshunt mixture)、蟎離丹(chinomethionat)、克氯綜(chlobenthiazone)、氯黴素(chloraniformethane)、克氯尼(chloranil)、氯苯咪唑(chlorfenazole)、地茂散(chloroneb)、氯化苦(chloropicrin)、百菌清(chlorothalonil)、四氯噁(chlorquinox)、乙菌利(chlozolinate)、甘寶素(climbazole)、乙酸銅(copper acetate)、鹼性碳酸銅(copper carbonate, basic)、氫氧化銅(copper hydroxide)、環烷酸銅(copper naphthenate)、油酸銅(copper oleate)、鹼性氯氧化銅(copper oxychloride)、硫酸銅(copper sulfate)、鹼性硫酸銅(copper sulfate, basic)、銅鋅鉻酸鹽(copper zinc chromate)、丁香菌酯(coumoxystrobin)、甲酚(cresol)、鋅錳(cufraneb)、銅普丹(cuprobam)、賽座滅(cyazofamid)、環氟醯胺(cyclafuramid)、環己醯亞胺(cycloheximide)、賽芬胺(cyflufenamid)、克絕(cymoxanil)、氰菌靈(cypendazole)、環克座(cyproconazole)、賽普洛(cyprodinil)、酯菌胺(cyprofuram)、邁隆(dazomet)、咪菌威(debacarb)、癸磷錫(decafentin)、脫氫乙酸(dehydroacetic acid)、二氯苯賽鐸(dichlobentiazox)、益發靈(dichlofluanid)、大克隆(dichlone)、雙氯酚(dichlorophen)、菌核利(dichlozoline)、苄氯三唑醇(diclobutrazol)、雙氯氰菌胺(diclocymet)、達滅淨(diclomezine)、大克爛(dicloran)、乙黴威(diethofencarb)、待克利(difenoconazole)、二氟林(diflumetorim)、二甲嘧酚(dimethirimol)、達滅芬(dimethomorph)、醚菌胺(dimoxystrobin)、達克利(diniconazole)、達克利-M (diniconazole-M)、敵蟎通(dinobuton)、敵蟎普(dinocap)、敵蟎普-4(dinocap-4)、敵蟎普-6(dinocap-6)、敵菌死(dinocton)、硝辛酯(dinosulfon)、硝丁酯(dinoterbon)、二苯基胺(diphenylamine)、大芬滅替松(dipymetitrone)、雙吡啶硫酮(dipyrithione)、雙硫崙(disulfiram)、普得松(ditalimfos)、腈硫醌(dithianon)、DNOC、嗎菌靈(dodemorph)、多果定(dodine)、菌酮(drazoxolon)、護粒松(edifenphos)、因司唑賓(enestrobin)、烯肟菌酯(enoxastrobin)、依普座(epoxiconazole)、噻唑菌胺(ethaboxam)、乙環唑(etaconazole)、伊特姆(etem)、依瑞莫(ethirimol)、乙氧基喹啉(ethoxyquin)、依得利(etridiazole)、噁唑菌酮(famoxadone)、咪唑菌酮(fenamidone)、敵克松(fenaminosulf)、烯肟菌胺(fenaminstrobin)、菌拿靈(fenapanil)、芬瑞莫(fenarimol)、芬克座(fenbuconazole)、甲呋醯胺(fenfuram)、環醯菌胺(fenhexamid)、種衣酯(fenitropan)、氰菌胺(fenoxanil)、拌種咯(fenpiclonil)、芬庇科米得(fenpicoxamid)、苯鏽啶(fenpropidin)、芬普福(fenpropimorph)、胺苯吡菌酮(fenpyrazamine)、三苯基錫(fentin)、福美鐵(ferbam)、嘧菌腙(ferimzone)、吡啶醯菌胺(florylpicoxamid)、扶吉胺(fluazinam)、護汰寧(fludioxonil)、氟菌蟎酯(flufenoxystrobin)、氟因菌唑(fluindapyr)、氟醯菌胺(flumetover)、氟嗎啉(flumorph)、氟比來(fluopicolide)、氟醚菌醯胺(fluopimomide)、氟吡菌醯胺(fluopyram)、氟醯亞胺(fluoroimide)、三氟苯唑(fluotrimazole)、氟嘧菌酯(fluoxastrobin)、氟喹唑(fluquinconazole)、護矽得(flusilazole)、氟硫滅(flusulfamide)、福多寧(flutolanil)、氟噻菌淨(flutianil)、護汰芬(flutriafol)、氟苯吡菌胺(fluxapyroxad)、福爾培(folpet)、福賽得鋁(fosetyl-aluminium)、熱必斯(fthalide)、麥穗寧(fuberidazole)、呋霜靈(furalaxyl)、福拉比(furametpyr)、二甲呋醯胺(furcarbanil)、氟康唑(furconazole)、呋醚唑(furconazole-cis)、拌種胺(furmecyclox)、呋甲硫菌靈(furophanate)、固毆寧(glyodin)、吉膚黴素(griseofulvin)、克熱淨(guazatine)、丙烯酸喹啉酯(halacrinate)、六氯苯(hexachlorobenzene)、菲克利(hexaconazole)、己硫松(hexylthiofos)、硫酸氧喹啉(8-hydroxyquinoline sulfate)、殺紋寧(hymexazol)、依滅列(imazalil)、易胺座(imibenconazole)、克熱淨烷苯磺酸鹽(iminoctadine-albesilate)、克熱淨三乙酸鹽(iminoctadine-triacetate)、應吡福安(inpyrfluxam)、碘代丙炔基丁基甲胺酸酯(iodocarb)、種菌唑(ipconazole)、抑吩伏唑(ipfentrifluconazole)、艾氟芬喹啉(ipflufenoquin)、丙基喜樂松(iprobenfos)、依普同(iprodione)、抑發利(iprovalicarb)、異丙噻菌胺(isofetamid)、異氟西波(isoflucypram)、亞汰尼(isotianil)、亞賜圃(isoprothiolane)、吡唑萘菌胺(isopyrazam)、異醯菌酮(isovaledione)、嘉賜黴素(kasugamycin)、克收欣(kresoxim-methyl)、昆布糖(laminarin)、代森錳銅(mancopper)、鋅錳乃浦(mancozeb)、杏仁菌酯(mandestrobin)、雙炔醯菌胺(mandipropamid)、錳乃浦(maneb)、巴斯丹(mebenil)、苯并威(mecarbinzid)、甲分三康唑(mefentrifluconazole)、滅派林(mepanipyrim)、滅普寧(mepronil)、消蟎多(meptyldinocap)、滅達樂(metalaxyl)、右滅達樂(metalaxyl-M)、威百畝(metam)、間氯敵菌酮(metazoxolon)、滅特座(metconazole)、磺菌威(methasulfocarb)、呋菌胺(methfuroxam)、甲基四菌唑(metyltetraprole)、免得爛(metiram)、苯氧菌胺(metominostrobin)、滅芬農(metrafenone)、塞菌胺(metsulfovax)、代森環(milneb)、邁克尼(myclobutanil)、滅克寧(myclozolin)、代森鈉(nabam)、萘替芬(naftifine)、鏈黴菌素(natamycin)、有機鎳(nickel bis (dimethyldithiocarbamate))、硝基苯乙烯(nitrostyrene)、酞菌酯(nitrothal-isopropyl)、尼瑞莫(nuarimol)、辛噻酮(octhilinone)、呋醯胺(ofurace)、肟醚菌胺(orysastrobin)、歐殺斯(oxadixyl)、奧賽普林(oxathiapiprolin)、氧喹啉銅(oxine copper)、噁咪唑富馬酸鹽(oxpoconazole fumarate)、嘉保信(oxycarboxin)、披扶座(pefurazoate)、平克座(penconazole)、戊菌隆(pencycuron)、戊苯吡菌胺(penflufen)、五氯酚(pentachlorophenol)、噻菌胺(penthiopyrad)、鄰苯基酚(2-phenylphenol)、氯瘟磷(phosdiphen)、熱必斯(phthalide)、皮卡布西(picarbutrazox)、啶氧菌酯(picoxystrobin)、粉病靈(piperalin)、代森福美鋅(polycarbamate)、保粒黴素(polyoxins)、保粒黴素-D (polyoxorim)、疊氮化鉀(potassium azide)、碳酸氫鉀(potassium hydrogen carbonate)、撲殺熱(probenazole)、撲克拉(prochloraz)、撲滅寧(procymidone)、普拔克鹽酸鹽(propamocarb hydrochloride)、普克利(propiconazole)、甲基鋅乃浦(propineb)、丙氧喹啉(proquinazid)、硫菌威(prothiocarb)、白粉松(pyrazophos)、吡菌苯威(pyribencarb)、啶斑肟(pyrifenox)、嘧黴胺(pyrimethanil)、嘧蟎胺(pyriminostrobin)、百快隆(pyroquilon)、硫菌威(prothiocarb)、普硫座(prothioconazole)、氟唑菌醯羥胺(pydiflumetofen)、吡喃靈(pyracarbolid)、百克敏(pyraclostrobin)、唑胺菌酯(pyrametostrobin)、唑菌酯(pyraoxystrobin)、派瑞頗波因(pyrapropoyne)、必記福敏(pyraziflumid)、派瑞達奇拉米堤(pyridachlometyl)、定菌腈(pyridinitril)、甲氧苯啶菌(pyriofenone)、啶菌唑(pyrisoxazole)、氯甲氧吡啶(pyroxychlor)、氯吡呋醚(pyroxyfur)、喹烯酮-硫酸鹽(quinacetol-sulfate)、醌菌腙(quinazamid)、氯苯喹唑(quinconazole)、快諾芬(quinoxyfen)、昆諾浮美林(quinofumelin)、五氯硝基苯(quintozene)、吡咪唑(rabenzazole)、柳醯胺苯(salicylanilide)、環丙吡菌胺(sedaxane)、矽噻菌胺(silthiofam)、矽氟唑(simeconazole)、碳酸氫鈉(sodium hydrogen carbonate)、次氯酸鈉(sodium hypochlorite)、螺噁茂胺(spiroxamine)、硫(sulfur)、戊唑醇(tebuconazole)、異丁乙氧喹啉(tebufloquin)、克枯爛(tecloftalam)、四氯硝基苯(tecnazene)、福美雙聯(tecoram)、四克利(tetraconazole)、腐絕(thiabendazole)、氟噻亞菌胺(thiadifluor)、噻菌晴(thicyofen)、賽氟滅(thifluzamide)、硫氯苯亞胺(thiochlorfenphim)、多保淨(thiophanate)、甲基多保淨(thiophanate-methyl)、福美雙(thiram)、噻醯菌胺(tiadinil)、替歐西密(tioxymid)、脫克松(tolclofos-methyl)、托普洛卡(tolprocarb)、托福寧(tolylfluanid)、三泰芬(triadimefon)、三泰隆(triadimenol)、三唑磷胺(triamiphos)、嘧菌醇(triarimol)、丁基三唑(triazbutil)、三挫磷(triazoxide)、三丁基氧化錫(tributyltin oxide)、水楊菌胺(trichlamide)、三環吡菌威(triclopyricarb)、三賽唑(tricyclazole)、三得芬(tridemorph)、三氟敏(trifloxystrobin)、賽福座(triflumizole)、賽福寧(triforine)、滅菌唑(triticonazole)、維利黴素(validamycin)、維利芬那(valifenalate)、免克寧(vinclozolin)、氰菌胺(zarilamid)、環烷酸鋅(zinc naphthenate)、硫酸鋅(zinc sulfate)、代森鋅(zineb)、福美鋅(ziram)、座賽胺(zoxamide)、菇類菌絲體萃取物(shiitake mycelium extract)、菇類子實體萃取物(shiitake fruiting body extract)等。Examples of the bactericide include acibenzolar-S-methyl, acypetacs, aldimorph, allyl alcohol, and amethocradin. , Aminopyrifen, amobam, ampropylfos, anilazine, azaconazole, azithiram, azoxystrobin ), barium polysulfide, benalaxyl, benalaxyl-M, benodanil, benomyl, benquinox, Bentaluron, benthiavalicarb-isopropyl, benthiazole, benzenoic acid (benzamacril), benzamorf (benzamorf), benzovindiflupyr (benzovindiflupyr), Binapacryl, biphenyl, bitertanol, bixafen, blasticidin-S, bordeaux mixture , Boscalid, bromoconazole, bupirimate, buthiobate, butylamine, calcium polysulfide, captafol, gram Captan, carbamorph, carbendazim, carboxin, carpropamid, carvone, cheshunt mixture, chinomethionat, chlobenthiazone, chloraniformethane, chloranil, chlorfenazole, chloroneb, chloropicrin ), chlorothalonil, chlorquinox, chlozolinate, climbazole, Copper acetate, copper carbonate, basic, copper hydroxide, copper naphthenate, copper oleate, copper oxychloride (copper) oxychloride, copper sulfate, copper sulfate, basic, copper zinc chromate, coumoxystrobin, cresol, cufraneb , Cuprobam, cyazofamid, cyclafuramid, cycloheximide, cyflufenamid, cymoxanil, cypendazole ), cyproconazole, cyprodinil, cyprofuram, dazomet, debacarb, decafentin, dehydroacetic acid , Dichlobentiazox, dichlofluanid, dichlone, dichlorophen, dichlozoline, diclobutrazol, diclofenac (diclocymet), diclomezine, dicloran, diethofencarb, diffenoconazole, diflumetorim, dimethirimol, darfenfen (dimethirimol) dimethomorph), dimoxystrobin, diniconazole, diniconazole-M, diniconazole-M, dinobuton, dinocap, dinocap-4 , Dinocap-6, dinocapton, dinosulfon, dinoterbon, diphenylamine, dipymetitrone, Dipyrithione (dipyrithione), disulfiram (disulfi ram), dipotimfos, dithianon, DNOC, dodemorph, dodine, drazoxolon, edifenphos, indozobine (enestrobin), enoxastrobin, epoxiconazole, ethaboxam, etaconazole, etem, ethirimol, ethoxy Quinoline (ethoxyquin), etridiazole, famoxadone, fenamidone, fenaminosulf, fenaminstrobin, fenapanil, Fenarimol, fenbuconazole, fenfuram, fenhexamid, fenitropan, fenoxanil, fenpiclonil , Fenpicoxamid, fenpropidin, fenpropimorph, fenpyrazamine, fentin, fentin, ferbam, pyrimethanil (ferimzone), florylpicoxamid, fluazinam, fludioxonil, flufenoxystrobin, fluindapyr, flumetover, Flumorph, fluopicolide, fluopimomide, fluopyram, fluoroimide, fluotrimazole, fluoropyrimidine Fluoxastrobin, Fluquinconazole, Flusilazole, Flusulfamide, Flutolanil, Flutianil, Flutriafol, Fluoride Fluxapyroxad, folpet, fosetyl-aluminium, fthalide, fuberidazole, furaxyl (furalaxyl), furametpyr, furcarbanil, furconazole, furconazole, furconazole-cis, furmecyclox, furophanate ), glyodin, griseofulvin, guazatine, halacrinate, hexachlorobenzene, hexaconazole, hexylthiofos ), 8-hydroxyquinoline sulfate, hymexazol, imazalil, imibenconazole, iminoctadine-albesilate, gram heat Net triacetate (iminoctadine-triacetate), inpyrfluxam, iodocarb, iodocarb, ipconazole, ipfentrifluconazole, eflufenquinoline ( ipflufenoquin), iprobenfos, iprodione, iprodione, iprovalicarb, isofetamid, isoflurcypram, isotianil, isotianil Isoprothiolane, isopyrazam, isovaledione, kasugamycin, kresoxim-methyl, laminarin, and mancocob (mancopper), mancozeb, mandestrobin, mandipropamid, maneb, mebenil, mecarbinzid, alpha It is divided into mefentrifluconazole, mepanipyrim, mepronil, meptyldinocap, metalaxyl, metalaxyl-M, and metam ), metazoxolon, metconazole, methasulfocar b), methfuroxam, metyltetraprole, metiram, metominostrobin, metrafenone, metsulfovax, dexamethasone (milneb), myclobutanil, myclozolin, nabam, naftifine, natamycin, nickel bis (dimethyldithiocarbamate), nitro Nitrostyrene, nitrothal-isopropyl, nuarimol, octhilinone, ofurace, orysastrobin, oxadixyl , Oxathiapiprolin, oxine copper, oxpoconazole fumarate, oxycarboxin, pefurazoate, penconazole, pentotricium Pencycuron, penflufen, pentachlorophenol, penthiopyrad, 2-phenylphenol, phosdiphen, phthalide ), picarbutrazox, picoxystrobin, piperalin, polycarbamate, polyoxins, polyoxorim, Potassium azide, potassium hydrogen carbonate, probenazole, prochloraz, procymidone, propamocarb hydrochloride, pockly ( propiconazole), propineb, proquinazid, prothiocarb, pyrazophos, pyrribencarb, pyrifenox, pyrimidine Amine (pyrimethani l), pyriminostrobin, pyroquilon, prothiocarb, prothioconazole, pydiflumetofen, pyracarbolid, and grammin ( pyraclostrobin), pyrametostrobin, pyraoxystrobin, pyrapropoyne, pyraziflumid, pyridachlometyl, pyridachlometyl (pyridachlometyl) pyridinitril), pyriofenone, pyrisoxazole, pyroxychlor, pyroxyfur, quinacetol-sulfate, quinazamid ), quinconazole, quinoxyfen, quinofumelin, quintozene, rabenzazole, salicylanilide, cyclopropyl Sedaxane, silthiofam, simeconazole, sodium hydrogen carbonate, sodium hypochlorite, spiroxamine, sulfur, Tebuconazole, tebufloquin, tecloftalam, tecnafte, tecnazene, tecoram, tetraconazole, thiabendazole ), thiadifluor, thicyofen, thifluzamide, thiochlorfenphim, thiophanate, thiophanate-methyl ), thiram, tiadinil, tioxymid, tolclofos-methyl, tolprocarb, tolprocarb, tolylfluanid, and tritaifen ( triadimefon) and triadimenol ), triamiphos, triarimol, triazbutil, triazoxide, tributyltin oxide, trihltinamide, Triclopyricarb, tricyclazole, tridemorph, trifloxystrobin, triflumizole, triforine, triticonazole, Validamycin, valifenalate, vinclozolin, zarilamid, zinc naphthenate, zinc sulfate, and zinc zineb), ziram, zoxamide, shiitake mycelium extract, shiitake fruiting body extract, etc.

作為殺細菌劑，可列舉阿莫西林(amoxicillin)、胺苄青黴素(ampicillin)、比托沙(bethoxazin)、硫雙二氯酚(bithionol)、溴硝醇(bronopol)、頭孢匹林(cefapirin)、西華樂林(cefazolin)、頭孢喹肟(cefquinome)、頭孢噻呋(ceftiofur)、金黴素(chlortetracycline)、棒酸(clavulanic acid)、達氟沙星(danofloxacin)、二氟沙星(difloxacin)、二硝托胺(dinitolmide)、恩諾沙星(enrofloxacin)、氟甲碸黴素(florfenicol)、林可黴素(lincomycin)、洛美沙星(lomefloxacin)、麻佛微素(marbofloxacin)、米洛沙星(miloxacin)、米羅米星(mirosamycin)、氯啶(nitrapyrin)、諾氟沙星(norfloxacin)、辛噻酮(octhilinone)、氧氟沙星(ofloxacin)、奧比沙星(orbifloxacin)、歐索林酸(oxolinic acid)、土黴素(oxytetracycline)、青黴素(penicillin)、鏈黴素(streptomycin)、甲碸黴素(thiamphenicol)、富馬酸泰妙菌素(tiamulin fumarate)、磷酸替米考星(tilmicosin phosphate)、乙醯異戊醯泰樂黴素(acetylisovaleryltylosin)、泰黴素(tylosin phosphate)、托拉菌素(tulathromycin)、沃尼妙林(valnemulin)、貝殼燒成鈣(氧化鈣)、籃狀菌屬菌、木黴菌屬菌、盾殼黴菌屬菌等。Examples of the bactericide include amoxicillin, ampicillin, bethoxazin, bethoxazin, bithionol, bronopol, and cefapirin. , Cefazolin, cefquinome, ceftiofur, chlortetracycline, clavulanic acid, danofloxacin, difloxacin ( difloxacin), dinitolmide, enrofloxacin, florfenicol, lincomycin, lomefloxacin, marbofloxacin , Miloxacin, mirosamycin, nitrapyrin, norfloxacin, octhilinone, ofloxacin, orfloxacin (ofloxacin) orbifloxacin), oxolinic acid, oxytetracycline, penicillin, streptomycin, thiamphenicol, tiamulin fumarate , Tilmicosin phosphate, acetylisovaleryltylosin, tylosin phosphate, tulathromycin, valnemulin, shellfish Calcium (calcium oxide), basket fungi, trichoderma, sclerotium, etc.

作為殺線蟲劑，可列舉碸滅威(aldoxycarb)、異噻蟲唑(benclothiaz)、硫線磷(cadusafos)、DBCP、除線磷(dichlofenthion)、DSP、滅線磷(ethoprophos)、芬滅松(fenamiphos)、繁福松(fensulfothion)、氟紮吲哚巾(fluazaindolizine)、氟噻蟲碸(fluensulfone)、福賽絕(fosthiazate)、吉福松(fosthietan)、依米賽松(imicyafos)、依殺米朵孚斯(isamidofos)、依殺松(isazofos)、歐殺滅(oxamyl)、thiaxazafen、治線磷(thionazin)、替阿札芬(tioxazafen)等。Examples of nematicides include aldoxycarb, benclothiaz, cadusafos, DBCP, dichlofenthion, DSP, ethoprophos, and fenpropion (fenamiphos), fensulfothion, fluazaindolizine, fluensulfone, flussulfone, fosthiazate, fosthietan, imicyafos, and killing Midasfoss (isamidofos), Isazofos (isazofos), oxamyl (oxamyl), thiaxazafen, thionazin (thionazin), tiazazafen (tioxazafen), etc.

作為殺蟎劑，可列舉滅蟎醌(acequinocyl)、氟丙菊酯(acrinathrin)、呋蟲胺(amidoflumet)、三亞蟎(amitraz)、亞環鍚(azocyclotin)、西脫蟎(benzoximate)、必芬蟎(bifenazate)、新殺蟎(bromopropylate)、克芬蟎(clofentezine)、唑蟎氰(cyenopyrafen)、賽芬蟎(cyflumetofen)、大克蟎(dicofol)、除蟎靈(dienochlor)、依殺蟎(etoxazole)、芬殺蟎(fenazaquin)、芬佈賜(fenbutatin oxide)、苯硫威(fenothiocarb)、芬普寧(fenpropathrin)、芬普蟎(fenpyroximate)、嘧蟎酯(fluacrypyrim)、覆滅蟎(formetanate)、合芬寧(halfenprox)、合賽多(hexythiazox)、密滅汀(milbemectin)、毆蟎多(propargite)、氟蟲雙醯胺(pyflubumide)、畢汰芬(pyrimidifen)、賜派芬(spirodiclofen)、螺甲蟎酯(spiromesifen)、得芬瑞(tebufenpyrad)、NA-89(試驗名)等。Examples of acaricides include acequinocyl, acrinathrin, amidoflumet, amitraz, azocyclotin, benzoximate, and Bifenazate, bromopropylate, clofentezine, cyenopyrafen, cyflumetofen, dicofol, dienochlor, dimethoate Mites (etoxazole), fenazaquin, fenbutatin oxide, fenothiocarb, fenpropathrin, fenpyroximate, fenpyroximate, fluacrypyrim, mite formetanate), halfenprox, hexythiazox, milbemectin, propargite, pyflubumide, pyrimidifen, cipine (spirodiclofen), spiromesifen, tebufenpyrad, NA-89 (test name), etc.

作為殺蟲劑，可列舉阿巴汀(abamectin)、毆殺松(acephate)、滅蟎醌(acequinocyl)、亞滅培(acetamipirid)、氟丙菊酯(acrinathrin)、阿非比平(afidopyropen)、阿佛拉那(afoxolaner)、棉鈴威(alanycarb)、得滅克(aldicarb)、亞列寧(allethrin)、α-亞滅寧(alpha-cypermethrin)、α-安殺番(alpha-endosulfan)、呋蟲胺(amidoflumet)、三亞蟎(amitraz)、亞滅松(azamethiphos)、谷速松-乙基(azinphos-ethyl)、谷速松-甲基(azinphos-methyl)、亞環鍚(azocyclotin)、蘇力菌(bacillus thuringiensis)、免敵克(bendiocarb)、拜富寧(benfluthrin)、免扶克(benfuracarb)、免速達(bensultap)、西脫蟎(benzoximate)、β-賽扶寧(beta-cyfluthrin)、β-賽滅寧(beta-cypermethrin)、必芬蟎(bifenazate)、畢芬寧(bifenthrin)、百亞列寧(bioallethrin)、百列滅寧(bioresmethrin)、雙三氟蟲脲(bistrifluron)、布洛苯胺(broflanilide)、新殺蟎(bromopropylate)、布芬淨(buprofezin)、佈嘉信(butocarboxim)、加保利(carbaryl)、加保扶(carbofuran)、丁基加保扶(carbosulfan)、培丹(cartap)、蟎離丹(chinomethionat)、氯蟲醯胺(chlorantraniliprole)、氯氧磷(chlorethxyfos)、克凡派(chlorfenapyr)、克芬松(chlorfenvinphos)、克福隆(chlorfluazuron)、氯甲硫磷(chlormephos)、克氯苯(chlorobezilate)、氯普亞列寧(chloroprallethrin)、陶斯松(chlorpyrifos)、陶斯松-甲基(chlorpyrifos-methyl)、可芬諾(chromafenozide)、克芬蟎(clofentezine)、可尼丁(clothianidin)、氰乃松(cyanophos)、氰蟲醯胺(cyantraniliprole)、環溴蟲醯胺(cyclaniliprole)、乙氰菊酯(cycloprothrin)、唑蟎氰(cyenopyrafen)、賽芬蟎(cyflumetofen)、賽芬蟎(cyflumetofen)、賽扶寧(cyfluthrin)、氯氟氰蟲醯胺(cyhalodiamide)、賽洛寧(cyhalothrin)、鍚蟎丹(cyhexatine)、亞滅寧(cypermethrin)、賽芬寧(cyphenothrin)、賽滅淨(cyromazine)、第滅寧(deltamethrin)、大可定(diacloden)、汰芬隆(diafenthiuron)、二嗪農(diazinon)、二氯松(dichlorvos)、二氯滅嗪(dicloromezotiaz)、大克蟎(dicofol)、除蟎靈(dienochlor)、氟蟎嗪(diflovidazin)、二福隆(diflubenzuron)、四氟甲醚菊酯(dimefluthrin)、大滅松(dimethoate)、甲基毒蟲畏(dimethylvinphos)、達特南(dinotefuran)、二苯丙醚(diofenolan)、二硫松(disulfoton)、DNOC、d-T-80-異治滅寧(d-tetramethrin)、因滅汀(emamectin-benzoate)、益避寧(empenthrin)、安殺番(endosulfan)、EPN、ε-甲氧苄氟菊酯(epsilon-metofluthrin)、ε-甲氧苄氟菊酯單體(epsilon-momfluorothrin)、益化利(esfenvalerate)、愛芬克(ethiofencarb)、益斯普(ethiprole)、依芬寧(etofenprox)、依殺蟎(etoxazole)、益多松(etrimfos)、飛盼特(Febantel)、芬殺蟎(fenazaquin)、氧化芬佈賜(fenbutatin oxide)、撲滅松(fenitrothion)、仲丁威(fenobucarb)、苯硫威(fenothiocarb)、芬諾克(fenoxycarb)、芬普寧(fenpropathrin)、芬普寧(fenpropathrin)、芬普蟎(fenpyroximate)、芬殺松(fenthion)、芬化利(fenvalerate)、芬普尼(fipronil)、福美昆(flometoquin)、氟尼胺(flonicamid)、嘧蟎酯(fluacrypyrim)、氟佐隆(fluazuron)、氟大滅(flubendiamide)、氟環隆(flucycloxuron)、護賽寧(flucythrinate)、福芬靈(flufenerim)、氟芬隆(flufenoxuron)、三氟醚菊酯(flufenprox)、丁蟲腈(flufiprole)、氟殺逢(fluhexafon)、福滅寧(flumethrin)、氟吡呋喃酮(flupyradifurone)、氟拉蘭(fluralaner)、福化利(fluvalinate)、大福松(fonophos)、覆滅蟎(formetanate)、福木松(formothion)、扶線威(furathiocarb)、γ-賽洛寧(gamma-cyhalothrin)、合芬寧(halfenprox)、氯蟲醯肼(halofenozide)、右旋七氟甲醚菊酯(heptafluthrin)、六伏隆(hexaflumuron)、合賽多(hexythiazox)、海滅隆(hydramethylnon)、益達胺(imidacloprid)、依普寧(imiprothrin)、因得克(indoxacarb)、因得克-MP (indoxacarb-MP)、亞芬松(isofenphos)、滅必蝨(isoprocarb)、加福松(isoxathion)、κ-畢芬寧(kappa-bifenthrin)、κ-七氟菊酯(kappa-tefluthrin)、λ-賽洛寧(lambda-cyhalothrin)、雷皮菌素(lepimectin)、祿芬隆(lufenuron)、馬拉松(malathion)、氯氟醚菊酯(meperfluthrin)、美氟綜(metaflumizone)、滅賜克(metalcarb)、聚乙醛(metaldehyde)、滅克松(methacrifos)、達馬松(methamidophos)、滅大松(methidathion)、納乃得(methomyl)、美賜平(methoprene)、氧氯甲氧氯(methoxychlor)、滅芬諾(methoxyfenozide)、甲基溴(methyl bromide)、美特寧(metofluthrin)、密滅汀(milbemectin)、甲氧苄氟菊酯單體(momfluorothrin)、亞素靈(monocrotophos)、誘蟲烯(muscalure)、烯啶蟲胺(nitenpyram)、諾伐隆(novaluron)、諾福隆(noviflumuron)、毆滅松(omethoate)、噁唑硫非(oxazosulfyl)、滅多松(oxydemeton-methyl)、異亞碸磷(oxydeprofos)、巴拉松(parathion)、甲基巴拉松(parathion-methyl)、五氯酚(pentachlorophenol)、百滅寧(permethrin)、酚丁滅寧(phenothrin)、賽達松(phenthoate)、福瑞松(phorate)、裕必松(phosalone)、益滅松(phosmet)、福賜米松(phosphamidon)、巴賽松(phoxim)、比加普(pirimicarb)、亞特松(pirimiphos-methyl)、吡喹酮(Praziquantel)、佈飛松(profenofos)、丙氟菊酯(profluthrin)、加護松(propaphos)、毆蟎多(propargite)、普硫松(prothiofos)、氟蟲清(protrifenbute)、氟蟲雙醯胺(pyflubumide)、派滅淨(pymetrozine)、白克松(pyraclofos)、吡嗪氟蟲腈(pyrafluprole)、除蟲菊精(pyrethrins)、啶蟲丙醚(pyridalyl)、百利福腙(pyrifluquinazon)、畢汰芬(pyrimidifen)、皮瑞普(pyriprole)、百利普芬(pyriproxyfen)、列滅寧(resmethrin)、魚藤精(rotenone)、矽護芬(silafluofen)、賜諾特(spinetoram)、賜諾殺(spinosad)、賜派芬(spirodiclofen)、螺甲蟎酯(spiromesifen)、賜派滅(spirotetramat)、螺甲蟎酯(spyromesifen)、治螟磷(sulfotep)、速殺氟(sulfoxaflor)、海羅松(sulprofos)、福化利(tau-fluvalinate)、得芬諾(tebfenozide)、得芬瑞(tebufenpyrad)、得福隆(teflubenzuron)、七氟菊酯(tefluthorin)、托福松(terbufos)、四氯蟲醯胺(tetrachlorantraniliprole)、樂本松(tetrachlorvinphos)、治滅寧(tetramethrin)、四氟醚菊酯(tetramethylfluthrin)、氟氰蟲醯胺(tetraniliprole)、賽果培(thiacloprid)、賽速安(thiamethoxam)、硫賜安(thiocyclam)、硫敵克(thiodicarb)、硫伐隆(thiofanox)、硫滅松(thiometon)、脫芬瑞(tolfenpyrad)、泰滅寧(tralomethrin)、拜富寧(transfluthrin)、唑蚜威(triazamate)、三唑磷(triazuron)、三氯松(trichlorfon)、三氟苯嘧啶(triflumezopyrim)、三福隆(triflumuron)、替克樂比薩佛(tyclopyrazoflor)、繁米松(vamidothion)、ζ-亞滅寧(zeta-cypermethrin)等。Examples of insecticides include abamectin, acephate, acequinocyl, acetamipirid, acetamipirid, acrinathrin and afidopyropen. , Afoxolaner, alanycarb, aldicarb, allethrin, alpha-cypermethrin, alpha-endosulfan, Amidoflumet, amitraz, azamethiphos, azinphos-ethyl, azinphos-methyl, azocyclotin , Bacillus thuringiensis, bendiocarb, benfluthrin, benfuracarb, bensultap, benzoximate, beta-sifulin (beta) -cyfluthrin), beta-cypermethrin, bifenazate, bifenthrin, bioallethrin, bioresmethrin, bistrifluron , Broflanilide, bromopropylate, buprofezin, butocarboxim, carbaryl, carbofuran, butyl plus carbosulfan, Cartap, Chinomethionat, Chlorantraniliprole, Chlorethxyfos, Chlorfenapyr, Chlorfenvinphos, Chlorfluazuron, Chlorine Chlormephos, chlorobezilate, chloroprallethrin, chlorpyrifos, chlorpyrifos-methyl, chromafenozide, clofentezine , Conidine (clothianid in), cyanophos, cyantraniliprole, cyclaniliprole, cycloprothrin, cyenopyrafen, cyflumetofen, saifen Cyflumetofen, cyfluthrin, cyhalodiamide, cyhalothrin, cyhexatine, cypertine, cypermethrin, cyphenothrin , Cyromazine, deltamethrin, diacloden, diafenthiuron, diazinon, dichlorvos, dicloromezotiaz , Dicofol, dienochlor, diflovidazin, diflubenzuron, dimefluthrin, dimethoate, methyl toxin Dimethylvinphos, dinotefuran, diofenolan, disulfoton, DNOC, dT-80-d-tetramethrin, emamectin-benzoate ), empenthrin, endosulfan, EPN, epsilon-metofluthrin, epsilon-momfluorothrin, Yihua Esfenvalerate, ethiofencarb, ethiprole, etofenprox, etoxazole, etrimfos, febantel, fenmite (fenazaquin), fenbutatin oxide, fenitrothion, fenobucarb, fenothiocarb, fenoxycarb, fenpropathrin, fenpropathrin ), fenpyroximate, fenthion, fenval erate), fipronil, flometoquin, flonicamid, fluacrypyrim, fluazuron, flubendiamide, flucycloxuron , Flucythrinate, flufenerim, flufenoxuron, flufenprox, flufiprole, fluhexafon, flumethrin ), flupyradifurone, fluralaner, fluvalinate, fonophos, formetanate, formothion, furathiocarb, Gamma-cyhalothrin, halfenprox, halofenozide, heptafluthrin, hexaflumuron, hexythiazox ), hydramethylnon, imidacloprid, imiprothrin, indoxacarb, indoxacarb-MP, indoxacarb-MP, isofenphos, chlorpyrifos (isoprocarb), isofathion, kappa-bifenthrin, kappa-tefluthrin, lambda-cyhalothrin, lepimectin, Lufenuron, malathion, meperfluthrin, metaflumizone, metalcarb, metaldehyde, methacrifos, and Methamidophos, methidathion, methomyl, methoprene, methoxychlor, methoxyfenozide, methyl bromide, Metofluthrin, milbemectin, Momfluorothrin, monocrotophos, muscalure, nitenpyram, novaluron, noviflumuron, assault Omethoate, oxazosulfyl, oxydemeton-methyl, oxydeprofos, parathion, parathion-methyl, pentachlorophenol (pentachlorophenol), permethrin, phenothrin, phenthoate, phorate, phosalone, phosmet, fucimethasone ( phosphamidon, phoxim, pirimicarb, pirimiphos-methyl, praziquantel, praziquantel, profenofos, profluthrin, plus pine ( propaphos), propargite, prothiofos, protrifenbute, pyflubumide, pymetrozine, pyraclofos, pyrazin and fipronil (pyrafluprole), pyrethrins, pyridalyl, pyrifluquinazon, pyrimidifen, pyriprofen, pyriproxyfen, Resmethrin, rotenone, silafluofen, spinetoram, spinosad, spirodiclofen, spiromesifen, Spirotetramat, spyromesifen, sulfotep, sulfoxaflor, sulprofos, tau-fluvalinate, tebfenozide ), tebufenpyrad, teflubenzuron, tefluthorin, and tofusone (ter bufos), tetrachlorantraniliprole, tetrachlorvinphophos, tetramethrin, tetramethylfluthrin, tetraniliprole, thiacloprid , Thiamethoxam, thiocyclam, thiodicarb, thiofanox, thiometon, tolfenpyrad, tralomethrin, Transfluthrin, triazamate, triazuron, trichlorfon, triflumezopyrim, triflumurzoon, triflumuron, tyclopyrazoflor ), vamidothion, zeta-cypermethrin, etc.

作為除草劑，可列舉4-CPA(4-CPA)、4-CPA之鹽(4-CPA-salts)、4-CPB(4-CPB)、4-CPP(4-CPP)、2,4-D (2,4-D、2,4-PA)、2,4-D之鹽(2,4-D-salts)、2,4-D之酯(2,4-D-esters)、3,4-DA(3,4-DA)、2,4-DB(2,4-DB)、2,4-DB之鹽(2,4-DB-salts)、2,4-DB之酯(2,4-DB-esters)、3,4-DB (3,4-DB)、2,4-DEB(2,4-DEB)、2,4-DEP(2,4-DEP)、3,4-DP (3,4-DP)、2,4,5-T(2,4,5-T)、2,4,5-T之鹽(2,4,5-T-salts)、2,4,5-T之酯(2,4,5-T-esters)、2,4,5-TB(2,4,5-T)、2,3,6-TBA(2,3,6-TBA, TCBA)、2,3,6-TBA之鹽(2,3,6-TBA-salts)、乙草胺(acetochlor)、亞喜芬(acifluorfen)、亞喜芬甲基(acifluorfen-methyl)、亞喜芬鈉(acifluorfen-sodium)、苯草醚(aclonifen)、丙烯醛(acrolein)、拉草(alachlor)、草毒死(allidochlor, CDAA)、亞汰草(alloxydim)、亞汰草鈉(alloxydim-sodium)、烯丙醇(allyl alchol)、亞羅列克(alorac)、胺酮(ametridione)、草殺淨(ametryn)、胺草酮(amibuzin)、胺唑草酮(amicarbazone)、先甲草胺(amidochlor)、醯嘧磺隆(amidosulfuron)、氯丙嘧啶酸(aminocyclopyrachlor)、氯丙嘧啶酸甲基(aminocyclopyrachlor-methyl)、氯丙嘧啶酸鉀(aminocyclopyrachlor-potassium)、氯胺吡啶酸(aminopyralid)、氯胺吡啶酸之鹽(aminopyralid-salts)、胺草磷(amiprophos)、甲基胺草磷(amiprophos-methyl)、殺草強(amitrole, aminotriazole, ATA)、氨基磺酸銨(ammonium sulfamate, AMS)、莎稗磷(anilofos)、安尼速隆(anisuron)、磺草靈(asulam)、磺草靈之鹽(asulam-salts)、阿特拉通(atraton)、草脫淨(atrazine)、草芬定(azafenidin)、四唑嘧磺隆(azimsulfuron)、滅蘇民(aziprotryne, azyprotryn)、燕麥靈(barban, CBN)、BCPC(BCPC)、氟丁醯草胺(beflubutamid)、草除靈(benazolin)、乙基草除靈(benazolin-ethyl)、草除靈之鹽(benazolin-salts)、醯苯草酮(bencarbazone)、氟草胺(benfluralin, benefin)、呋草黃(benfuresate)、免速隆(bensulfuron)、甲基免速隆(bensulfuron-methyl)、地散磷(bensulide, SAP)、本達隆(bentazon, bentazone)、本達隆鈉(bentazone-sodium)、草噁嗪(bentranil)、苯甲醯胺氧乙酸(benzadox)、苯甲醯胺氧乙酸銨(benzadox-ammonium)、雙苯嘧草酮(benzfendizone)、苄草胺(benzipram)、苯并雙環酮(benzobicyclon)、吡草酮(benzofenap)、氟草黃(benzofluor)、新燕靈(benzoylprop)、乙基新燕靈(benzoylprop-ethyl)、苯噻隆(benzthiazuron)、雙環哌喃酮(bicyclopyrone)、治草醚(bifenox)、畢拉草(bilanafos, bialaphos)、畢拉草鈉(bilanafos-sodium)、樂殺蟎(binapacryl)、雙草醚(bispyribac)、雙草醚鈉(bispyribac-sodium)、硼砂(borax)、克草(bromacil)、克草之鹽(bromacil-salts)、除草溴(bromobonil)、溴丁醯草胺(bromobutide)、溴酚肟(bromofenoxim)、bromopyrazon、溴苯腈(bromoxynil)、溴苯腈鉀(bromoxynil-potassium)、溴苯腈之酯(bromoxynil-esters)、丁基拉草(butachlor)、布芬草(butafenacil)、抑草磷(butamifos)、丁烯草胺(butenachlor)、仲丁靈(butralin, butraline)、丁硫咪唑酮(buthidazole)、丁噻隆(buthiuron)、丁苯草酮(butroxydim)、炔草隆(buturon)、丁酯(butylate)、苯酮唑(cafenstrole)、氰氮化鈣(calcium cyanamide)、卡本二氯(cambendichlor)、氯酸鈣(calcium chlorate)、除草隆(carbasulam)、雙醯草胺(carbetamide)、羧酸唑(carboxazole)、克繁草(carfentrazone)、乙基克繁草(carfentrazone-ethyl)、CDEA(CDEA)、CEPC(CEPC)、甲氧基護谷(chlomethoxyfen, chlomethoxynil)、克攔本(chloramben)、克攔本之鹽(chloramben-salts)、甲基克攔本(chloramben-methyl)、克攔本甲基銨(chloramben-methylammonium)、丁醯草胺(chloranocryl, dicryl)、炔禾靈(chlorazifop)、炔丙基炔禾靈(chlorazifop-propargyl)、氯阿淨(chlorazine)、滅落寧(chlorbromuron)、氯草靈(chlorbufam, BIPC)、氯氧隆(chloreturon)、伐草克(chlorfenac, fenac)、伐草克之鹽(chlorfenac-salts)、燕麥酯(chlorfenprop)、甲基燕麥酯(chlorfenprop-methyl)、氟咪殺(chlorflurazole)、整形醇(chlorflurenol)、甲基整形醇(chlorflurenol-methyl)、氯草敏(chloridazon, PAC, pyrazon)、氯嘧磺隆(chlorimuron)、乙基氯嘧磺隆(chlorimuron-ethyl)、氯乙靈(chlornidine)、全滅草(chlornitrofen, CNP)、氯乙酸(chloroacetic acid, monochloroacetic acid)、氯乙酸鈉(sodium chloroacetate, SMA)、氯麥隆(chlorotoluron)、枯草龍(chloroxuron)、氯二甲酚(chloroxynil)、氯普卡(chlorprocarb)、氯黴素(chlorphtalim)、克普芬(chlorpropham, IPC)、氯磺隆(chlorsulfuron)、大克草(chlorthal, TCTP)、大克草之酯(chlorthal-esters)、草克樂(chlorthiamid, DCBN)、乙基環醯草酯(cinidon-ethyl)、環庚草醚(cinmethylin)、西速隆(cinosulfuron)、落草胺(cisanilide)、氯醯草膦(clacyfos)、剋草同(clethodim)、一氯吡啶酯(cliodinate)、炔草酯(clodinafop)、炔丙基炔草酯(clodinafop-propargyl)、氯下草(clofop)、異丁基氯下草(clofop-isobutyl)、可滅蹤(clomazone)、克普草(clomeprop)、果美生長素(cloprop)、氯丙殺草(cloproxydim)、畢克草(clopyralid)、甲基畢克草(clopyralid-methyl)、畢克草之鹽(clopyralid-salts)、氯酯磺草胺(cloransulam)、甲基氯酯磺草胺(cloransulam-methyl)、硫酸銅(2價)(copper sulfate)、CPMF(CPMF)、CPPC(CPPC)、必滅草(credazine)、甲酚(cresol)、草隆(cumyluron)、氰草淨(cyanatryn)、氰胺(cyanamide)、氰乃淨(cyanazine)、環草敵(cycloate)、環吡瑞諾(cyclopyranil)、環吡瑞莫(cyclopyrimorate)、環丙嘧磺隆(cyclosulfamuron)、環殺草(cycloxydim)、環莠隆(cycluron, COMU)、賽伏草(cyhalofop)、丁基賽伏草(cyhalofop-butyl)、牧草快(cyperquat)、牧草快氯化物(cyperquat-chloride)、環丙津(cyprazine)、三環噻草胺(cyprazole)、環草胺(cypromid)、香草隆(daimuron, dymron)、茅草枯(dalapon)、茅草枯之鹽(dalapon-salts)、邁隆(dazomet)、邁隆鈉(dazomet-sodium)、異丁草胺(delachlor)、甜菜安(desmedipham)、敵草淨(desmetryn)、燕麥敵(di-allate)、麥草畏(dicamba, MDBA)、麥草畏之鹽(dicamba-salts)、麥草畏之酯(dicamba-esters)、敵草腈(dichlobenil、DBN)、二氯脲(dichloraurea, DCU)、苄胺靈(dichlormate)、鄰二氯苯(o-dichlorobenzene, DCB)、2,4-滴丙酸(dichlorprop)、2,4-滴丙酸之鹽(dichlorprop-salts)、2,4-滴丙酸之酯(dichlorprop-esters)、2,4-滴丙酸P (dichlorprop-P)、2,4-滴丙酸P之鹽(dichlorprop-P-salts)、2,4-滴丙酸P之酯(dichlorprop-P-esters)、禾草靈(diclofop)、甲基禾草靈(diclofop-methyl)、禾草靈P(diclofop-P)、禾草靈P甲基(diclofop-P-methyl)、雙氯磺草胺(diclosulam)、迭森快(diethamquat)、迭森快二氯化物(diethamquat dichloride)、乙醯甲草胺(diethatyl)、乙基乙醯甲草胺(diethatyl-ethyl)、戊味禾草靈(difenopenten)、乙基戊味禾草靈(difenopenten-ethyl)、枯莠隆(difenoxuron)、野燕枯(difenzoquat)、大芬克(difenzoquat metilsulfate)、大伏肯(diflufenican)、大芬比(diflufenzopyr)、大芬比鈉(diflufenzopyr-sodium)、大滅能(dimefuron)、大滅普(dimepiperate)、大滅克(dimethachlor)、戊草津(dimethametryn)、汰草滅(dimethenamid)、汰草滅P(dimethenamid-p)、草滅散(dimexano)、地米達腙(dimidazon)、二甲基二硫化物(dimethyl disulfide)、敵樂胺(dinitramine)、迪樂芬諾(dinofenate)、硝丙酚(dinoprop)、戊硝酚(dinosam)、特樂酚(dinoseb, DNBP)、特樂酚之鹽(dinoseb-salts)、特樂酚之酯(dinoseb-esters)、特樂酯(dinoterb)、特樂酯之鹽(dinoterb-salts)、特樂酯之酯(dinoterb-esters)、雙苯醯草胺(diphenamid)、地樂靈(dipropalin)、異丙淨(dipropetryn)、敵草快(diquqt)、敵草快二溴化物(diquqt dibromide)、2,4-滴硫鈉(disul, 2,4-PS)、2,4-滴硫鈉鈉(disul-sodium)、氟硫草定(dithiopyr)、敵草隆(diuron, DCMU)、DMPA (DMPA)、DNOC(DNOC)、DNOC之鹽(DNOC-salts)、EBEP (EBEP)、甘草津(eglinazine)、乙基甘草津(eglinazine-ethyl)、草藻滅(endothal)、草藻滅之鹽(endothal-salts)、三唑磺(epronaz)、EPTC(EPTC)、抑草蓬(erbon)、戊草丹(esprocarb)、克草胺(ethachlor)、抑伏靈(ethalfluralin)、胺苯磺隆(ethametsulfuron)、甲基胺苯磺隆(ethametsulfuron-methyl)、殺草胺(ethaprochlor)、磺噻隆(ethidimuron)、抑草威(ethiolate)、乙嗪草酮(ethiozin)、乙氧草黃(ethofumesate)、氯氟草醚(ethoxyfen)、乙基氯氟草醚(ethoxyfen-ethyl)、乙氧嘧磺隆(ethoxysulfuron)、硝草酚(etinofen)、艾尼丙密(etnipromid)、乙氧苯草胺(etobenzanid)、EXD(EXD)、苯威(fenasulam)、涕丙酸(fenoprop, 2,4,5-TP, silvex)、涕丙酸之鹽(fenoprop-salts)、涕丙酸之酯(fenoprop-esters)、噁唑菌胺(fenoxaprop)、乙基噁唑菌胺(fenoxaprop-ethyl)、噁唑菌胺P(fenoxaprop-p)、乙基噁唑菌胺P(fenoxaprop-p-ethyl)、異噁苯碸(fenoxasulfone)、芬昆諾三酮(fenquinotrione)、非諾特羅(fenteracol)、唑禾草酸(fenthiaprop)、乙基唑禾草酸(fenthiaprop-ethyl)、四唑醯草胺(fentrazamide)、硫酸鐵(2價)(ferrous sulfate)、非草隆(fenuron)、非草隆TCA(fenuron-TCA)、麥草伏(flamprop)、麥草伏之酯(flamprop-esters)、麥草伏M (flamprop-M)、麥草伏M之酯(flamprop-M-esters)、啶嘧磺隆(flazasulfuron)、雙氟磺草胺(florasulam)、氯氟吡啶酯(florpyrauxifen)、苄基氯氟吡啶酯(florpyrauxifen-benzyl)、吡氟禾草靈(fluazifop)、吡氟禾草靈之酯(fluazifop-esters)、吡氟禾草靈P(fluazifop-P)、吡氟禾草靈P之酯(fluazifop-p-esters)、異丙吡草酯(fluazolate)、氟酮磺隆(flucarbazone)、氟酮磺隆鈉(flucarbazone-sodium)、氟吡磺隆(flucetosulfuron)、氟消草(fluchloralin)、氟噻草胺(flufenacet)、氟芬尼康(flufenican)、氟噠嗪草酯(flufenpyr)、乙基氟噠嗪草酯(flufenpyr-ethyl)、唑嘧磺草胺(flumetsulam)、氟默嗪(flumezin)、氟烯草酸(flumiclorac)、氟胺草酯(flumiclorac-pentyl)、丙炔氟草胺(flumioxazin)、炔草胺(flumipropyn)、伏草隆(fluometuron)、消草醚(fluorodifen)、乙羧氟草醚(fluoroglycofen)、乙基乙羧氟草醚(fluoroglycofen-ethyl)、唑啶草(fluoromidine)、氟除草醚(fluoronitrofen, CFNP)、氟硫隆(fluothiuron)、氟胺草唑(flupoxam)、氟丙鉑秀(flupropacil)、四氟丙酸(flupropanate, tetrapion)、四氟丙酸鈉(flupropanate-sodium)、氟啶嘧磺隆(flupyrsulfuron)、甲基氟啶嘧磺隆(flupyrsulfuron-methyl)、氟啶嘧磺隆鈉(flupyrsulfuron-sodium)、甲基氟啶嘧磺隆鈉(flupyrsulfuron-methyl-sodium)、氟啶草酮(fluridone)、氟咯草酮(flurochloridone)、氯氟吡氧乙酸(fluroxypyr)、氯氟吡氧乙酸之酯(fluroxypyr-esters)、呋草酮(flurtamone)、氟噻草酯(fluthiacet)、嗪草酸甲酯(fluthiacet-methyl)、氟磺胺草醚(fomesafen)、氟磺胺草醚鈉(fomesafen-sodium)、甲醯嘧磺隆(foramsulfuron)、殺木膦(fosamine)、殺木膦銨(fosamine-ammonium)、呋氧草醚(furyloxyfen)、草銨膦(glufosinate)、草銨膦之鹽(glufosinate-salts)、草銨膦P(glufosinate-P)、草銨膦P之鹽(glufosinate-P-salts)、草甘膦(glyphosate)、草甘膦之鹽(glyphosate-salts)、哈洛昔芬(halauxifen)、氟氯吡啶酯(halauxifen-methyl)、鹵殺芬(halosafen)、合速隆(halosulfuron)、甲基合速隆(halosulfuron-methyl)、氟啶草(haloxydine)、合氯氟(haloxyfop)、合氯氟鈉(haloxyfop-sodium)、合氯氟之酯(haloxyfop-esters)、合氯氟P (haloxyfop-P)、合氯氟P之酯(haloxyfop-p-esters)、除莠黴素(herbimycin)、六氯丙酮(hexachloroacetone, HCA)、菲殺淨(hexazinone)、咪草酸(imazamethabenz)、甲基咪草酸(imazamethabenz-methyl)、咪草啶酸(imazamox)、咪草啶酸銨(imazamox-ammonium)、甲咪唑烟酸(imazapic)、甲咪唑烟酸銨(imazapic-ammonium)、依滅草(imazapyr)、依滅草異丙銨(imazapyr-isopropylammonium)、滅草喹(imazaquin)、甲基滅草喹(imazaquin-methyl)、滅草喹之鹽(imazaquin-salts)、咪唑乙煙酸(imazethapyr)、咪唑乙煙酸銨(imazethapyr-ammonium)、依速隆(imazosulfuron)、茚草酮(indanofan)、吲嗪氟胺(indaziflam)、除草碘(iodobonil)、碘甲磺隆(iodosulfuron)、碘甲磺隆鈉(iodosulfuron-sodium)、甲基碘甲磺隆(iodosulfuron-methyl)、甲基碘甲磺隆鈉(iodosulfuron-methyl-sodium)、依歐芬速隆(iofensulfuron)、依歐芬速隆鈉(iofensulfuron-sodium)、碘苯腈(ioxynil)、碘苯腈之鹽(ioxynil-salts)、碘苯腈之酯(ioxynil-esters)、抑草津(ipazine)、鹵苯胺唑(ipfencarbazone)、抑吡嘧丹iprymidam)、草特靈(isocarbamid)、異草定(isocil, isoprocil)、丁嗪草酮(isomethiozin)、異草完隆(isonoruron)、異丙林特(isopolinate)、異丙樂靈(isopropalin)、異丙隆(isoproturon)、愛速隆(isouron)、異惡草胺(isoxaben)、依索氯托(isoxachlortole)、抑殺特(isoxaflutole)、異惡草醚((isoxapyrifop)、特胺靈(karbutilate)、酮螺達(ketospiradox)、酮螺達鉀(ketospiradox-potassium)、乳氟禾草靈(lactofen)、朗剋三酮(lancotrione)、朗剋三酮鈉(lancotrione-sodium)、環草定(lenacil)、理有龍(linuron)、MCPA(MCPA)、MCPA之鹽(MCPA-salts)、MCPA之酯(MCPA-esters)、MCPB(MCPB)、MCPB之鹽(MCPB-salts)、MCPB之鹽酯(MCPB-esters)、2-甲-4-氯丙酸(mecoprop, MCPP)、2-甲-4-氯丙酸之鹽(mecoprop-salts)、2-甲-4-氯丙酸之酯(mecoprop-esters)、2-甲-4-氯丙酸P (mecoprop-P)、2-甲-4-氯丙酸P之鹽(mecoprop-P-salts)、2-甲-4-氯丙酸P之酯(mecoprop-P-esters)、甲基特樂酯(medinoterb)、甲基特樂酯乙酸鹽(medinoterb actate)、滅芬草(mefenacet)、美福泰(mefluidide)、美福泰之鹽(mefluidide-salts)、滅莠津(mesoprazine)、磺胺磺隆(mesosulfuron)、甲基磺胺磺隆(mesosulfuron-methyl)、硝草酮(mesotrione)、威百畝(metam, carbam)、威百畝之鹽(metam-salts)、甲氯丙酸(metamifop)、苯嗪草酮(metamitron)、滅草胺(metazachlor)、雙醚氯吡嘧磺隆(metazosulfuron)、二甲噠草伏(metflurazon)、甲基苯噻隆(methabenzthiazuron, methibenzuron)、甲基丙樂靈(methalpropalin)、滅草唑(methazole)、甲殺丹(methiobencarb)、滅草恆(methiuron)、醚草通(methometon)、格草淨(methoprotryne, methoprotryn)、甲氧基苯酮(methoxyphenone)、甲硫嘧磺隆(methiopyrisulfuron)、美西除靈(methiozolin)、甲基疊氮化物(methyl azide)、甲基溴(methyl bromide)、甲基殺草隆(methyl dymron)、甲基碘(methyl iodide)、異硫氰酸甲酯(methyl isothiocyanate)、吡喃隆(metobenzuron)、撲多草(metobromuron)、莫多草(metolachlor)、S莫多草(S-metolachlor)、磺草唑胺(metosulam)、甲氧隆(metoxuron)、滅必淨(metribuzin)、磺隆(metsulfuron)、甲基磺隆(metsulfuron-methyl)、稻得壯(molinate)、庚醯草胺(monalide)、莫尼速隆(monisouron)、綠谷龍(monolinuron)、單嘧磺隆(monosulfuron)、甲基單嘧磺隆(monosulfuron-methyl)、滅草隆(monuron, CMU)、滅草隆TCA(monuron-TCA)、伐草快(morfamquat)、伐草快二氯化物(morfamquat dichloride)、萘普草(naproanilide)、敵草胺(napropamide)、敵草胺M(napropamide-M)、納得爛(naptalam, NPA)、納得爛鈉(naptalam-sodium)、草不龍(neburon)、煙嘧磺隆(nicosulfuron)、吡氯草胺(nipyraclofen)、滅殺草(nitralin)、護谷(nitrofen, NIP, niclofen)、三氟甲草醚(nitrofluorfen)、氟草敏(norflurazon)、草完隆(noruron, norea)、OCH(OCH)、油酸(oleic acid)、坪草丹(orbencarb)、嘧苯胺磺隆(orthosulfamuron)、歐拉靈(oryzalin)、快噁草酮(oxadiargyl)、樂滅草(oxadiazon)、草噠松(oxapyrazon)、草噠松之鹽(oxapyrazon-salts)、環氧嘧磺隆(oxasulfuron)、歐克芬(oxaziclomefone)、復祿芬(oxyfluorfen)、對氟隆(parafluron)、巴拉刈(paraquat)、巴拉刈二氯化物(paraquat dichloride)、巴拉刈二甲基硫酸鹽(paraquat dimetilsulfate)、克草猛(pebulate)、壬酸(pelargonic acid, nonanoic acid)、施得圃(pendimethalin)、平速爛(penoxsulam)、五氯酚(pentachlorophenol)、五氯酚鈉(sodium pentachlorophenoxide)、月桂酸五氯苯(pentachlorophenyl laurate)、甲氯醯草胺(pentanochlor, solan, CMMP)、本特松(pentoxazone)、佈福松(perfluidone)、烯草胺(pethoxamid)、棉胺寧(phenisopham)、甜菜寧(phenmedipham)、乙基甜菜寧(phenmedipham-ethyl)、醯草隆(phenobenzuron)、畢克爛(picloram)、畢克爛之鹽(picloram-salts)、畢克爛之酯(picloram-esters)、氟吡醯草胺(picolinafen)、唑啉草酯(pinoxaden)、哌草磷(piperophos)、疊氮化鉀(potassium azide)、氰酸鉀(potassium cyanate)、普拉草(pretilachlor)、氟嘧磺隆(primisulfuron)、甲基氟嘧磺隆(primisulfuron-methyl)、環丙腈津(procyazine)、氨氟樂靈(prodiamine)、氟唑草胺(profluazol)、環丙氟靈(profluralin)、氯苯噻草酮(profoxydim)、甘撲津(proglinazine)、乙基甘撲津(proglinazine-ethyl)、撲滅通(prometon)、佈滅淨(prometryn, prometryne)、雷蒙得(propachlor)、除草靈(propanil, DCPA)、普拔草(propaquizafop)、普拔根(propazine)、苯胺靈(propham)、普樂寶(propisochlor)、丙苯磺隆(propoxycarbazone)、丙苯磺隆鈉(propoxycarbazone-sodium)、咪唑嘧磺隆(propyrisulfuron)、戊炔草胺(propyzamide, pronamide)、甲硫磺樂靈(prosulfalin)、苄草丹(prosulfocarb)、三氟丙磺隆(prosulfuron)、撲滅生(proxan, IPX)、撲滅生鈉(proxan-sodium)、拔地草(prynachlor)、吡達農(pydanon)、雙唑草腈(pyraclonil)、派芬草(pyraflufen)、乙基派芬草(pyraflufen-ethyl)、磺醯草吡唑(pyrasulfotole)、苄草唑(pyrazolynate, pyrazolate)、百速隆(pyrazosulfuron)、乙基百速隆(pyrazosulfuron-ethyl)、匹唑芬(pyrazoxyfen)、比立本-異丙基(pyribambenz-isopropyl)、比立本-丙基(pyribambenz-propyl)、嘧啶肟草醚(pyribenzoxim)、稗草丹(pyributicarb)、三氯吡啶醇(pyriclor)、噠草福(pyridafol)、必汰草(pyridate)、環酯草醚(pyriftalid)、嘧草醚(pyriminobac)、甲基嘧草醚(pyriminobac-methyl)、嘧啶硫蕃(pyrimisulfan)、嘧硫草醚(pyrithiobac)、嘧硫草醚鈉(pyrithiobac-sodium)、吡唑碸(pyroxasulfone)、吡唑磺草胺(pyroxsulam)、快克草(quinclorac)、快克草二甲基銨(quinclorac-dimethylammonium)、甲基快克草(quinclorac-methyl)、氯甲喹啉酸(quinmerac)、莫克草(quinoclamine, ACN)、克藻胺(quinonamid)、快伏草(quizalofop)、快伏草之酯(quizalofop-esters)、快伏草P(quizalofop-P)、快伏草以外之快伏草P之酯(quizalofop-P-esters)、硫氰苯胺(rhodethanil)、碸嘧磺隆(rimsulfuron)、嘧啶肟草醚(saflufenacil)、另丁津(sebuthylazine)、仲丁通(secbumeton)、西殺草(sethoxydim)、環草隆(siduron)、草滅淨(simazine, CAT)、西瑪通(simeton)、西草淨(simetryn, simetryne)、疊氮化鈉(sodium azide)、氯酸鈉(sodium chlorate)、磺草酮(sulcotrione)、草克死(sulfallate, CDEC)、氟磺唑草胺(sulfentrazone)、嘧磺隆(sulfometuron)、甲基嘧磺隆(sulfometuron-methyl)、磺醯磺隆(sulfosulfuron)、硫酸(sulfuric acid)、磺格坎平(sulglycapin)、滅草靈(swep, MCC)、稗草烯(tavron)、TCA(TCA, trichloroacetic acid)、TCA之鹽(TCA-salts)、TCA-乙二基(TCA-ethadyl)、牧草胺(tebutam, butam)、得匍隆(tebuthiuron)、特呋喃三酮(tefuryltrione)、田寶三酮(tembotrione)、得殺草(tepraloxydim)、特草定(terbacil)、特草靈(terbucarb, terbutol, MPMC)、特丁草胺(terbuchlor)、特丁通(terbumeton)、草淨津(terbuthylazine)、特丁淨(terbutryn)、四氟隆(tetrafluron)、欣克草(thenylchlor)、噻氟隆(thiazafluron)、噻草啶(thiazopyr)、噻二唑草胺(thidiazimin)、噻苯隆(thidiazuron)、唑酮磺吩酸(thiencarbazone)、噻酮磺隆(thiencarbazone-methyl)、噻吩磺隆(thifensulfuron)、噻黃隆(thifensulfuron-methyl)、殺丹(thiobencarb, benthiocarb)、氟丙嘧草酯(tiafenacil)、仲草丹(tiocarbazil)、仲草丹(tioclorim)、硝黃草酮(tolpyralate)、吡草磺(topramezone)、三甲苯草酮(tralkoxydim)、賽法猛(triafamone)、野麥畏(triallate, tri-allate)、醚苯磺隆(triasulfuron)、賽其爛(triaziflam)、苯磺隆(tribenuron)、甲基苯磺隆(tribenuron-methyl)、殺草畏(tricamba)、三氯比(triclopyr)、三氯比之鹽(triclopyr-salts)、三氯比之酯(triclopyr-esters)、三地芬(tridiphane)、草達津(trietazine)、三氟啶磺隆(trifloxysulfuron)、三氟啶磺隆鈉(trifloxysulfuron-sodium)、三福戴嗎沙(trifludimoxadin)、三福林(trifluralin)、氟胺磺隆(triflusulfuron)、甲基氟胺磺隆(triflusulfuron-methyl)、三氟普(trifop)、甲基三氟普(trifop-methyl)、三氟森(trifopsime)、三羥基三嗪(trihydroxytriazine, cyanuric acid)、三甲隆(trimeturon)、草普平丹(tripropindan)、草達克(tritac)、三氟甲磺隆(tritosulfuron)、萬隆(vernolate)、二甲苯草胺(xylachlor)、6-{(二氟甲基)硫基}-N2,N4-二異丙基-1,3,5-三嗪-2,4-二胺(CAS 103427-73-2)、(R)-2-[{7-(2-氯-4-(三氟甲基)苯氧基)萘-2-基}氧基]丙酸甲酯(CAS 103055-25-0)、丙烷-2-酮 O-(12H-二苯并[d,g][1,3]二噁英(dioxin)-6-羰基)肟(CAS 503819-68-9)、[{(2-(N-甲基甲基磺醯胺)-2-氧代乙基)胺基}甲基]膦酸(CAS 98565-18-5)、2-[{2-(4-((6-氯喹喔啉-2-基)氧基)苯氧基)丙醯基}氧基]-3-甲基-3-丁烯酸乙酯(CAS 1191932-79-2)、O-(2,4-二甲基-6-硝基苯基)O-甲基異丙基磷醯胺硫代酯(CAS 189517-75-7)、5-[N-{(4,6-二甲基嘧啶-2-基)胺甲醯基}胺磺醯基]-1-(吡啶-2-基)-1H-吡唑-4-羧酸甲酯(CAS 104770-29-8)、4-[2-氯-3-{(3,5-二甲基-1H-吡唑-1-基)甲基}-4-(甲基磺醯基)苯甲醯基]-1,3-二甲基-1H-吡唑-5-基 1,3-二甲基-1H-吡唑-4-羧酸酯(CAS 1911613-97-2)、4-[2-氯-4-(甲基磺醯基)-3-{(2,2,2-三氟乙氧基)甲基}苯甲醯基]-1-乙基-1H-吡唑-5-基 1,3-二甲基-1H-吡唑-4-羧酸酯(CAS 1992017-55-6)、1-{2-氯-3-(3-環丙基-5-羥基-1-甲基-1H-吡唑-4-羰基)-6-(三氟甲基)苯基}哌啶-2-酮(CAS 1855929-45-1)、1,3-二甲基-4-{2-(甲基磺醯基)-4-(三氟甲基)苯甲醯基}-1H-吡唑-5-基 1,3-二甲基-1H-吡唑-4-羧酸酯(CAS 1622908-18-2)、2-[{3-(2-氯-4-氟-5-(3-甲基-2,6-二氧代-4-(三氟甲基)-3,6-二氫嘧啶-1(2H)-基)苯氧基)吡啶-2-基}氧基]乙酸乙酯(CAS 353292-31-6)、2-甲基-N-(5-甲基-1,3,4-噁二唑-2-基)-3-(甲基磺醯基)-4-(三氟甲基)苯甲醯胺(CAS 1400904-50-8)、2-氯-N-(1-甲基-1H-四氮唑-5-基)-3-(甲基硫基)-4-(三氟甲基)苯甲醯胺(CAS 1361139-71-0)、2-氯-N-(1-甲基-1H-四氮唑-5-基)-3-(甲基磺醯基)-4-(三氟甲基)苯甲醯胺(CAS 1361139-73-2)、F4050(試驗名)、F9600(試驗名)、F9960(試驗名)、OK-701(試驗名)、SL-1201(試驗名)等。Examples of herbicides include 4-CPA (4-CPA), 4-CPA salts (4-CPA-salts), 4-CPB (4-CPB), 4-CPP (4-CPP), and 2,4- D (2,4-D, 2,4-PA), 2,4-D salt (2,4-D-salts), 2,4-D ester (2,4-D-esters), 3 , 4-DA (3,4-DA), 2,4-DB (2,4-DB), 2,4-DB salt (2,4-DB-salts), 2,4-DB ester ( 2,4-DB-esters), 3,4-DB (3,4-DB), 2,4-DEB (2,4-DEB), 2,4-DEP (2,4-DEP), 3, 4-DP (3,4-DP), 2,4,5-T (2,4,5-T), 2,4,5-T salt (2,4,5-T-salts), 2 ,4,5-T ester (2,4,5-T-esters), 2,4,5-TB (2,4,5-T), 2,3,6-TBA (2,3,6 -TBA, TCBA), 2,3,6-TBA salts (2,3,6-TBA-salts), acetochlor, acetochlor, acifluorfen, acifluorfen-methyl ), acifluorfen-sodium, aclonifen, acrolein, alachlor, alachlor, allidochlor (CDAA), alloxydim, and acetoxanthin Sodium (alloxydim-sodium), allyl alcohol (allyl alchol), alorac (alorac), acetamid (ametridione), azoxyn (ametryn), amichlorin (amibuzin), amicarbazone (amicarbazone), Amidochlor, amidosulfuron, aminocyclopyrachlor, aminocyclopyrachlor-methyl, aminocyclopyrachlor-potassium, chlorpyridine Acid (aminopyralid), aminopyralid-salts, amiprophos, amiprophos-methyl, amitrole, aminotriazole (ATA), ammonium sulfamate (ammonium sulfamate, AMS), analof os), anisuron, asulam, asulam-salts, atraton, atrazine, azafenidin , Azimsulfuron, aziprotryne, azyprotryn, baran, CBN, BCPC (BCPC), beflubutamid, benazolin, ethyl Benazolin-ethyl, benazolin-salts, bencarbazone, benfluralin, benefin, benfuresate, bensulfuron , Bensulfuron-methyl, bensulide (SAP), bentazon (bentazon, bentazone), bentazone-sodium, bentranil, benzophenone Benzadox, Benzadox-ammonium, benzfendizone, benzipram, benzobicyclon, benzofenap , Benzofluor, benzoylprop, benzoylprop-ethyl, benzthiazuron, bicyclopyrone, bifenox, bira Grass (bilanafos, bialaphos), bilanafos-sodium, binapacryl, bispyribac, bispyribac-sodium, borax, bromacil ), bromacil-salts, bromobonil, bromobutide, bromofenoxim, bromopyrazon, bromoxynil, bromooxynil- potassium), bromoxynil-esters, butachlor, butafenacil, butamifos ), butenachlor, butralin, butraline, buthidazole, buthiuron, butroxydim, buturon, butyl ester ( butylate), cafenstrole, calcium cyanamide, cambendichlor, calcium chlorate, carbasulam, carbetamide, carboxyl Carboxazole, carfentrazone, carfentrazone-ethyl, CDEA (CDEA), CEPC (CEPC), chlomethoxyfen, chlomethoxynil, chloramben ), chloramben-salts, chloramben-methyl, chloramben-methylammonium, chloranocryl, dicryl, yinheling ( chlorazifop, chlorazifop-propargyl, chlorazine, chlorbromuron, chlorbufam (BIPC), chloreturon, chlorfenac , fenac), chlorfenac-salts, chlorfenprop, chlorfenprop-methyl, chlorflurazole, chlorflurenol, chlorflurenol- methyl), chloridazon, PAC, pyrazon, chlorimuron, chlorimuron-ethyl, chlornidine, chlornitrofen (CNP), chlorine Acetic acid (chloroacetic acid, monochloroacetic acid), sodium chloroacetate (SMA), chlorotoluron, chloroxuron, chlorodiuron Chloroxynil, chlorprocarb, chlorphtalim, chlorpropham (IPC), chlorsulfuron, chlorthal (TCTP), esters of gram grass (chlorthal-esters), chlorthiamid (DCBN), cinidon-ethyl, cinmethylin, cinmethylin, cinosulfuron, cisanilide, chloranilide Clacyfos, clethodim, cliodinate, clodinafop, clodinafop-propargyl, clofop, isobutyl chloride Clofop-isobutyl, clomazone, clomeprop, cloprop, cloproxydim, clopyralid, methylpyrrolidone (clopyralid) clopyralid-methyl), clopyralid-salts, cloransulam, cloransulam-methyl, copper sulfate (copper sulfate), CPMF (CPMF), CPPC (CPPC), Cremazine (credazine), cresol (cresol), cumyluron (cumyluron), cyanatryn (cyanatryn), cyanamide (cyanamide), cyanamide (cyanazine), cyclic grass Cycloate, cyclopyranil, cyclopyrimorate, cyclosulfamuron, cyclooxydim, cyclourdim, cyclouron (COMU), sambucus ( cyhalofop), cyhalofop-butyl, cyperquat, cyperquat-chloride, cyprazine, cyprazole, cyprazole, cyprochlor cypromid), vanilla long (daimuron, dymron), dalapon (dalapon), dalapon-salts, dazomet, dazomet-sodium, different Delachlor, desmedipham, desmetryn, di-allate, dicamba (MDBA), dicamba-salts, dicamba (dicamba-esters), dichlobenil (DBN), dichloraurea (DCU), dichlormate (dichlormate), o-dichlorobenzene (DCB), 2,4-dipropionic acid (dichlorprop), dichlorprop-salts, dichlorprop-esters, dichlorprop-ester 2, dichlorprop-P, 2, Dichlorprop-P-salts, dichlorprop-P-esters, dichlorprop-P-esters, diclofop, diclofop-methyl ), diclofop-P, diclofop-P-methyl, diclofop-D-diclosulam, diethamquat, diethamquat dichloride dichloride), diethatyl, diethatyl-ethyl, difenopenten, difenopenten-ethyl, diuron (difenoxuron), difenzoquat, difenzoquat metilsulfate, diflufenican, diflufenzopyr, diflufenzopyr-sodium, dimefuron, Dimepiperate, dimethachlor, dimethametryn, dimethenamid, dimethenamid-p, dimexano, dimidazon ), dimethyl disulfide, dinitramine, dinofenate, dinoprop, dinosam, dinoseb, DNBP Teraphenol Dinoseb-salts, dinoseb-esters, dinoterb, dinoterb-salts, dinoterb-esters, dibenzoyl esters Diphenamid, dipropalin, dipropetryn, diquqt, diquqt, diquqt dibromide, 2,4-sodium thiosulfate (disul, 2, 4-PS), 2,4-Dulsodium sodium (disul-sodium), dithiopyr (dithiopyr), diuron (DCMU), DMPA (DMPA), DNOC (DNOC), DNOC salt ( DNOC-salts), EBEP (EBEP), glycyrrhizin (eglinazine), ethyl glycyrrhizin (eglinazine-ethyl), endothal, endothal-salts, epronaz , EPTC (EPTC), erpropan (erbon), esprocarb, ethachlor, ethalfluralin, ethametsulfuron, ethametsulfuron, ethametsulfuron -methyl), ethaprochlor, ethidimuron, ethiolate, ethiozin, ethofumesate, ethoxyfen, ethyl Ethoxyfen-ethyl, ethoxysulfuron, etinofen, etnipromid, etobenzanid, EXD (EXD), benzene Fenasulam, fenoprop, 2,4,5-TP, silvex, fenoprop-salts, fenoprop-esters, fenoxaprop ), fenoxaprop-ethyl, fenoxaprop-p, fenoxaprop-p, fenoxaprop-p-ethyl, fenoxasulfone, fenquin Fenquinotrione, Fenteracol, Fenthiaprop, Ethylazole Fenthiaprop-ethyl, fentrazamide, ferric sulfate, fenuron, fenuron-TCA, flamprop , Flamprop-esters, flamprop-M, flamprop-M-esters, flazasulfuron, flosulam, Florpyrauxifen, florpyrauxifen-benzyl, fluazifop, fluazifop-esters, fluazifop-esters -P), fluazifop-p-esters, fluazolate, fluazolate, flucarbazone, flucarbazone-sodium, fluopyril Flucetosulfuron, fluchloralin, flufenacet, flufenican, flufenpyr, flufenpyr-ethyl, Flumetsulam, Flumezin, Flumiclorac, Flumiclorac-pentyl, Flumioxazin, Flumipropyn, Fluvo Fluometuron, fluorodifen, fluoroglycofen, fluoroglycofen-ethyl, fluoromidine, fluoronitrofen (CFNP) , Fluothiuron, flupoxam, flupropacil, flupropanate, tetrapion, flupropanate-sodium, fluazinum (flupyrsulfuron), methylpyrsulfuron-methyl, flupyrsulfuron-sodium, flupyrsulfuron-sodium n-methyl-sodium), fluridone, flurochloridone, fluroxypyr, fluroxypyr-esters, flurtamone ), fluthiacet, fluthiacet-methyl, fomesafen, fomesafen-sodium, foramsulfuron, formazan Fosamine, fosamine-ammonium, furyloxyfen, glufosinate, glufosinate-salts, glufosinate-P , Glufosinate P salt (glufosinate-P-salts), glyphosate (glyphosate), glyphosate salt (glyphosate-salts), haloxifen (halauxifen), fluorochloropyridine (halauxifen-methyl) , Halosafen, halosulfuron, halosulfuron-methyl, haloxydine, haloxydine, haloxyfop, haloxyfop-sodium, Haloxyfop-esters, haloxyfop-P, haloxyfop-p-esters, herbimycin, hexachloroacetone, HCA ), hexazinone, imazamethabenz, imazamethabenz-methyl, imazamox, imazamox-ammonium, imazapic nicotinic acid (imazapic ), imazapic-ammonium, imazapyr, imazapyr-isopropylammonium, imazaquin, imazaquin-methyl, Imazaquin-salts, imazethapyr, imazethapyr-ammonium, and imazosulf uron, indanofan, indaziflam, iodobonil, iodosulfuron, iodosulfuron-sodium, methyl iodosulfuron-sodium iodosulfuron-methyl), iodosulfuron-methyl-sodium, iofensulfuron, iofensulfuron-sodium, ioxynil, iodobenzene Ioxynil-salts, ioxynil-esters, ipazine, ipfencarbazone, iprymidam, isocarbamid, isocarbidine (isocil, isoprocil), isomethiozin, isoruron, isopolinate, isopropalin, isoproturon, isouron ), isoxaben, isoxachlortole, isoxaflutole, isoxaflutole, isoxapyrifop, karbutilate, ketospiradox, ketospira Ketospiradox-potassium, lactofen, lancotrione, lancotrione-sodium, lenacil, linuron, MCPA (MCPA), MCPA salt (MCPA-salts), MCPA ester (MCPA-esters), MCPB (MCPB), MCPB salt (MCPB-salts), MCPB salt ester (MCPB-esters), 2-A -4-chloropropionic acid (mecoprop, MCPP), 2-methyl-4-chloropropionic acid salts (mecoprop-salts), 2-methyl-4-chloropropionic acid esters (mecoprop-esters), 2-methyl- 4-chloropropionic acid P (mecoprop-P), 2-methyl-4-chloropropionic acid P salt (mecoprop-P-salts), 2-methyl-4-chloropropionic acid P ester (mecoprop-P-esters ), medinoterb, medinoterb actate , Mefenacet, mefluidide, mefluidide-salts, mesoprazine, mesosulfuron, mesosulfuron-methyl, Mesotrione, metam, carbam, metam-salts, metamifop, metamitron, metazachlor, Dizoclosulfuron (metazosulfuron), metflurazon (metflurazon), methathione (methabenzthiazuron, methibenzuron), methaloprolin (methalpropalin), methazole (methazole), methadan (methiobencarb), methiuron, methometon, methoprotryne, methoprotryn, methoxyphenone, methiopyrisulfuron, meclizine (methiopyrisulfuron) methiozolin), methyl azide, methyl bromide, methyl dymron, methyl iodide, methyl isothiocyanate, Metobenzuron, metobromuron, metolachlor, S-metolachlor, metosulam, metoxuron, metbichlor ( metribuzin), metsulfuron, metsulfuron-methyl, molinate, molinate, monalide, monisouron, monolinuron, mono Monosulfuron (monosulfuron), methyl monosulfuron-methyl (monosulfuron-methyl), chlorsulfuron (monuron, CMU), chlorsulfuron TCA (monuron-TCA), morfamquat (morfamquat), chlorfenuron dichloride (Morfamquat dichloride), naproanilide (naproanilide), napropamide (napropamide), napropamide M (napropamide-M), naptalam (NPA), naptalam-sodium, neburon, nicosulfuron, nipyraclofen, nimepyramine (nipyraclofen) nitralin, nitrofen, NIP, niclofen, nitrofluorfen, norflurazon, noruron, norea, OCH (OCH), oleic acid, Orbencarb, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxapyrazon, salt of oxapyrazon ( oxapyrazon-salts), oxasulfuron, oxaziclomefone, oxyfluorfen, parafluron, paraquat, paraquat dichloride , Paraquat dimetilsulfate, pebulate, pelargonic acid, nonanoic acid, pendimethalin, penoxsulam, pentachlorophenol, Sodium pentachlorophenoxide, pentachlorophenyl laurate, pentanochlor, solan (CMMP), pentoxazone, perfluidone, pethoxamid ), phenisopham, phenmedipham, phenmedipham-ethyl, phenobenzuron, picloram, picloram-salts, Picloram-esters, picolinafen, pinoxaden, piperophos, potassium azide, potassium cyanate ),general Pretilachlor, primisulfuron, primisulfuron-methyl, procyazine, prodiazine, prodiamine, profluazol, Profluralin, profoxydim, proglinazine, proglinazine-ethyl, prometon, prometryn, prometryne, Propachlor, propanil (DCPA), propaquizafop, propazine, propham, propisochlor, propoxycarbazone, Propoxycarbazone-sodium, propyrisulfuron, propyzamide, pronamide, prosulfalin, prosulfocarb, trifluorosulfuron (prosulfocarb) prosulfuron), proxan (IPX), proxan-sodium, prynachlor, pydanon, pyraclonil, pyraflufen, beta Pyraflufen-ethyl, pyrasulfotole, pyrazolynate, pyrazolate, pyrazosulfuron, pyrazosulfuron-ethyl, pyrazolone (pyrazosulfuron-ethyl) pyrazoxyfen), pyrribambenz-isopropyl, pyribambenz-propyl, pyribenzoxim, pyributicarb, pyriclor , Pyridafol, pyridate, pyriftalid, pyriminobac, pyriminobac-methyl, pyrimsulfan, pyrimidine Pyrithiobac, pyrithiobac-sodi um), pyroxasulfone, pyroxsulam, quinclorac, quinclorac-dimethylammonium, quinclorac-methyl, Quinmerac, quinoclamine (ACN), quinonamid, quinonamid, quizalofop, quizalofop-esters, quizalofop-esters P), quizalofop-P-esters (quizalofop-P-esters), rhodethanil, rimsulfuron, saflufenacil, sebuthylazine ), secbumeton, secthoxydim, siduron, simazine (CAT), simeton, simetryn, simetryne, azide Sodium azide, sodium chlorate, sulcotrione, sulfallate (CDEC), sulfentrazone (sulfentrazone), sulfometuron (sulfometuron), methyl pyrimidine Sulfometuron-methyl, sulfosulfuron, sulfuric acid, sulglycapin, sweglycapin, swep (MCC), tavron, TCA (TCA, trichloroacetic acid), TCA-salts, TCA-ethadyl, TCA-ethadyl, tebutam, butam, tebuthiuron, tefuryltrione, Tianbao trione ( tembotrione), tepraloxydim, terbacil, terbucarb, terbutol, MPMC, terbuchlor, terbumeton, terbuthylazine, Terbutryn, tetrafluron, thenylchlor, thiazafluron ), thiazopyr, thidiazimin, thidiazuron, thiencarbazone, thiencarbazone-methyl, thifensulfuron , Thifensulfuron-methyl, thiobencarb, benthiocarb, tiafenacil, tiocarbazil, tioclorim, tolpyralate, pyridine Topramezone, tralkoxydim, triafamone, triallate, tri-allate, triasulfuron, triaziflam, trisulfuron (tribenuron), tribenuron-methyl, tribenuron-methyl, tricamba, triclopyr, triclopyr-salts, triclopyr-esters , Tridiphane, trietazine, trifloxysulfuron, trifloxysulfuron-sodium, trifludimoxadin, trifluralin ), triflusulfuron, triflusulfuron-methyl, trifop, trifop-methyl, trifopsime, trihydroxytrimethyl Trihydroxytriazine, cyanuric acid, trimeturon, tripropindan, tritac, tritosulfuron, trinosulfuron, vernolate, xylachlor ), 6-{(difluoromethyl)thio}-N2,N4-diisopropyl-1,3,5-triazine-2,4-diamine (CAS 103427-73-2), (R )-2-[{7-(2-chloro-4-(trifluoromethyl)phenoxy)naphthalen-2-yl}oxy]propionic acid methyl ester (CAS 103055-25-0), propane-2 -Keto O-(12H-dibenzo[d,g][1,3]dioxin) -6-carbonyl)oxime (CAS 503819-68-9), [{(2-(N-methylmethylsulfonamide)-2-oxoethyl)amino}methyl]phosphonic acid (CAS 98565 -18-5), 2-[{2-(4-((6-chloroquinoxalin-2-yl)oxy)phenoxy)propanyl}oxy]-3-methyl-3-butan Ethyl enoate (CAS 1191932-79-2), O-(2,4-dimethyl-6-nitrophenyl) O-methylisopropylphosphoramide thioester (CAS 189517-75- 7), 5-[N-{(4,6-Dimethylpyrimidin-2-yl)amine, formamide}, sulfamoyl]-1-(pyridin-2-yl)-1H-pyrazole-4 -Methyl carboxylate (CAS 104770-29-8), 4-[2-chloro-3-{(3,5-dimethyl-1H-pyrazol-1-yl)methyl}-4-(methyl Sulfamoyl)benzyl]-1,3-dimethyl-1H-pyrazol-5-yl 1,3-dimethyl-1H-pyrazole-4-carboxylate (CAS 1911613-97 -2), 4-[2-chloro-4-(methylsulfonyl)-3-{(2,2,2-trifluoroethoxy)methyl}benzyl]-1-ethyl -1H-pyrazol-5-yl 1,3-dimethyl-1H-pyrazole-4-carboxylate (CAS 1992017-55-6), 1-{2-chloro-3-(3-cyclopropane 5-hydroxy-1-methyl-1H-pyrazole-4-carbonyl)-6-(trifluoromethyl)phenyl)piperidin-2-one (CAS 1855929-45-1), 1,3 -Dimethyl-4-{2-(methylsulfonyl)-4-(trifluoromethyl)benzyl}-1H-pyrazol-5-yl 1,3-dimethyl-1H- Pyrazole-4-carboxylate (CAS 1622908-18-2), 2-[{3-(2-chloro-4-fluoro-5-(3-methyl-2,6-dioxo-4- (Trifluoromethyl)-3,6-dihydropyrimidin-1(2H)-yl)phenoxy)pyridin-2-yl)oxy) ethyl acetate (CAS 353292-31-6), 2-methyl -N-(5-methyl-1,3,4-oxadiazol-2-yl)-3-(methylsulfonyl)-4-(trifluoromethyl)benzamide (CAS 1400904 -50-8), 2-chloro-N-(1-methyl-1H-tetrazol-5-yl)-3-(methylthio)-4-(trifluoromethyl)benzamide (CAS 1361139-71-0), 2-chloro-N-(1-methyl-1H-tetrazol-5-yl)-3-(methylsulfonyl)-4-(trifluoromethyl) Benzoamide (CAS 1361139-73-2), F4050 (test name), F9600 (test name), F9960 (test name), OK-701 (test name), SL-1201 (test name), etc.

(a)農藥活性成分當中，選自氟米塔麥(fluxametamide)、畢達本、安美速及快伏草中之至少1種的含量係本發明之農藥乳化性組成物中通常為0.05～25質量%。含量的下限較佳為0.1質量%以上，更佳為1質量%以上，再更佳為2質量%以上，又再更佳為3質量%以上。含量的上限較佳為20質量%以下，更佳為18質量%以下，再更佳為17質量%以下，又再更佳為15質量%以下。(a) Among the active ingredients of pesticides, the content of at least one selected from the group consisting of fluxametamide, Pidaben, Amethicone, and Fulv grass is generally 0.05 to 25 in the pesticide emulsifiable composition of the present invention quality%. The lower limit of the content is preferably 0.1% by mass or more, more preferably 1% by mass or more, still more preferably 2% by mass or more, and still more preferably 3% by mass or more. The upper limit of the content is preferably 20% by mass or less, more preferably 18% by mass or less, even more preferably 17% by mass or less, and still more preferably 15% by mass or less.

包含前述其他農藥活性成分時，其含量只要不損害本發明之效果雖為任意，但通常本發明之組成物中通常為0.01～20質量%左右，較佳為0.05～15質量%左右。惟，作為(a)農藥活性成分全體，較佳為本發明之組成物中為25質量%以下。尚，其他農藥活性成分可1種單獨使用，亦可組合2種以上使用。When the aforementioned other pesticide active ingredient is included, its content is arbitrary as long as it does not impair the effect of the present invention, but it is usually about 0.01 to 20% by mass in the composition of the present invention, preferably about 0.05 to 15% by mass. However, as (a) the entire pesticide active ingredient, it is preferably 25% by mass or less in the composition of the present invention. Still, other pesticide active ingredients can be used alone or in combination of two or more.

[(b)混合溶劑] (b)成分之混合溶劑係包含 (b-1)包含3-甲氧基-N,N-二甲基丙醯胺之極性溶劑及 (b-2)非極性溶劑。[(b) Mixed solvent] (b) The mixed solvent of components contains (b-1) Polar solvent containing 3-methoxy-N,N-dimethylpropionamide and (b-2) Non-polar solvent.

(b-1)極性溶劑於不損害本發明之效果的範圍，可進一步包含其他極性溶劑。尚，在本發明，所謂極性溶劑，雖係意指在20℃之水溶解度為1g/L以上者，但較佳為2g/L以上者，更佳為4g/L以上者。作為其他極性溶劑之例，可列舉酮、N-烷基吡咯烷酮、環狀脲、3-甲氧基-N,N-二甲基丙醯胺以外之羧酸醯胺、內酯、含氮芳香族化合物、環狀胺、二甲基亞碸、碳酸酯等。(b-1) The polar solvent may further contain other polar solvents as long as the effect of the present invention is not impaired. In addition, in the present invention, the polar solvent means a water solubility at 20°C of 1 g/L or more, but preferably 2 g/L or more, and more preferably 4 g/L or more. Examples of other polar solvents include ketones, N-alkylpyrrolidone, cyclic urea, 3-methoxy-N,N-dimethylpropylamide, carboxylic acid amides, lactones, and nitrogen-containing aromatics. Group compounds, cyclic amines, dimethyl sulfoxide, carbonates, etc.

作為酮，可列舉丙酮、甲基乙基酮、甲基n-丙基酮、甲基n-丁基酮、甲基異丁基酮、甲基n-戊基酮、甲基n-己基酮、甲基n-庚基酮、二乙基酮、乙基n-丁基酮、二-n-丙基酮、二異丙基酮、二異丁基酮、二丙酮醇、乙醯基丙酮、丙酮基丙酮、亞異丙基丙酮(mesityl oxide)、苯乙酮、佛爾酮等之C3 ～ 9 直鏈狀或分枝狀酮、環戊酮、環己酮、甲基環己酮、環庚酮、異佛爾酮等之5～7員環的環狀酮等。尚，「Cm ～ n 」係意指碳原子數為m～n (以下相同)。Examples of ketones include acetone, methyl ethyl ketone, methyl n-propyl ketone, methyl n-butyl ketone, methyl isobutyl ketone, methyl n-pentyl ketone, and methyl n-hexyl ketone. , Methyl n-heptyl ketone, diethyl ketone, ethyl n-butyl ketone, di-n-propyl ketone, diisopropyl ketone, diisobutyl ketone, diacetone alcohol, acetone acetone , acetonyl acetone, mesityl (mesityl oxide), acetophenone, isophorone, etc. C 3 ~ 9 linear or branched ketone, cyclopentanone, cyclohexanone, methyl cyclohexanone , Cycloheptanone, isophorone and other 5- to 7-membered cyclic ketones. Still, "C m ~ n "means that the number of carbon atoms is m ~ n (the same applies hereinafter).

作為N-烷基吡咯烷酮，可列舉N-甲基-2-吡咯烷酮、N-乙基-2-吡咯烷酮、N-丁基-2-吡咯烷酮、N-辛基-2-吡咯烷酮、N-十二烷基-2-吡咯烷酮等之N-C1 ～ 12 烷基-2-吡咯烷酮等。Examples of N-alkylpyrrolidone include N-methyl-2-pyrrolidone, N-ethyl-2-pyrrolidone, N-butyl-2-pyrrolidone, N-octyl-2-pyrrolidone, and N-dodecane NC 1 to 12 alkyl-2-pyrrolidone, etc.

作為環狀脲，可列舉1,3-二甲基-2-咪唑酮、N,N’-二甲基丙烯脲等之5～6員環的環狀脲等。Examples of the cyclic urea include a 5- to 6-membered cyclic urea such as 1,3-dimethyl-2-imidazolidone and N,N'-dimethylacrylurea.

作為3-甲氧基-N,N-二甲基丙醯胺以外之羧酸醯胺，可列舉N,N-二甲基甲醯胺、N,N-二甲基乙醯胺、N,N-二甲基乳酸醯胺、N,N-二甲基辛烷醯胺、N,N-二甲基-9-癸烯醯胺、N,N-二甲基癸烷醯胺、N,N-二甲基十二烷醯胺、N,N-二甲基十四烷醯胺、3-丁氧基-N,N-二甲基丙醯胺等之C1 ～ 14 羧酸醯胺等。尚，羧酸之碳數較佳為1～14，以羧酸為脂肪族羧酸較佳。Examples of the carboxylic acid amides other than 3-methoxy-N,N-dimethylpropylamide include N,N-dimethylformamide, N,N-dimethylacetamide, and N, N-dimethyllactamide, N,N-dimethyloctanamide, N,N-dimethyl-9-decenamide, N,N-dimethyldecaneamide, N, C 1 ～ 14 carboxylic acid amides such as N-dimethyldodecylamide, N,N-dimethyltetradecylamide, 3-butoxy-N,N-dimethylpropylamide, etc. Wait. In addition, the carbon number of the carboxylic acid is preferably 1 to 14, and the carboxylic acid is preferably an aliphatic carboxylic acid.

作為內酯，可列舉β-丙內酯、β-丁內酯、γ-丁內酯、γ-戊內酯、δ-戊內酯、γ-己內酯、δ-己內酯、ε-己內酯、γ-庚內酯、γ-辛內酯、δ-辛內酯等之4～7員環狀內酯等。Examples of lactones include β-propiolactone, β-butyrolactone, γ-butyrolactone, γ-valerolactone, δ-valerolactone, γ-caprolactone, δ-caprolactone, ε- 4 to 7-membered cyclic lactones such as caprolactone, γ-heptanolide, γ-octanolactone, δ-octanolactone, etc.

作為含氮芳香族化合物，可列舉吡咯、1-甲基吡咯、3-甲基吡咯、1-乙基吡咯、2-乙基吡咯、2,4-二甲基吡咯、2,5-二甲基吡咯、1-甲基吡唑、3-甲基吡唑、1-甲基咪唑、1-乙基咪唑、1-異丙基咪唑、吡啶、2-甲基吡啶、3-甲基吡啶、4-甲基吡啶、2-乙基吡啶、3-乙基吡啶、4-乙基吡啶、2,3-二甲基吡啶、2,4-二甲基吡啶、2,5-二甲基吡啶、2,6-二甲基吡啶、3,4-二甲基吡啶、3,5-二甲基吡啶、2-甲醯基吡啶、3-甲醯基吡啶、4-甲醯基吡啶、2-乙醯基吡啶、3-乙醯基吡啶、4-乙醯基吡啶、噠嗪、3-甲基噠嗪、4-甲基噠嗪、嘧啶、4-甲基嘧啶、2-甲基吡嗪、2,3-二甲基吡嗪、2,5-二甲基吡嗪、2-乙基吡嗪等之包含1個以上之氮原子的5～6員環之環式芳香族化合物等。Examples of nitrogen-containing aromatic compounds include pyrrole, 1-methylpyrrole, 3-methylpyrrole, 1-ethylpyrrole, 2-ethylpyrrole, 2,4-dimethylpyrrole, and 2,5-dimethyl Pyrrole, 1-methylpyrazole, 3-methylpyrazole, 1-methylimidazole, 1-ethylimidazole, 1-isopropylimidazole, pyridine, 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, 2-ethylpyridine, 3-ethylpyridine, 4-ethylpyridine, 2,3-lutidine, 2,4-lutidine, 2,5-lutidine , 2,6-Dimethylpyridine, 3,4-Dimethylpyridine, 3,5-Dimethylpyridine, 2-Methylpyridine, 3-Methylpyridine, 4-Methylpyridine, 2 -Ethylpyridine, 3-ethypyridine, 4-ethypyridine, pyridazine, 3-methylpyridazine, 4-methylpyridazine, pyrimidine, 4-methylpyrimidine, 2-methylpyridine 5-6 ring cyclic aromatic compounds containing more than one nitrogen atom, such as azine, 2,3-dimethylpyrazine, 2,5-dimethylpyrazine, 2-ethylpyrazine, etc. .

作為環狀胺，可列舉吡咯啶、1-甲基吡咯啶、1-乙基吡咯啶、1-乙醯基吡咯啶、哌啶、1-甲基哌啶、2,6-二甲基哌啶、3,5-二甲基哌啶、1-乙基哌啶、1-甲醯基哌啶、1-乙醯基哌啶、嗎啉、4-甲基嗎啉、2,6-二甲基嗎啉、4-乙基嗎啉、4-醯基嗎啉(4-甲醯基嗎啉、4-乙醯基嗎啉、4-丙醯基嗎啉、4-丁醯基嗎啉、4-戊醯基嗎啉、4-己醯基嗎啉、4-庚醯基嗎啉、4-辛醯基嗎啉、4-壬醯基嗎啉、4-癸醯基嗎啉、4-十一醯基嗎啉、4-十二醯基嗎啉等)、1-甲基哌嗪、1,4-二甲基哌嗪、1-乙基哌嗪、1-甲醯基哌嗪等之包含1個以上之氮原子的5～6員環之飽和環狀胺等。Examples of cyclic amines include pyrrolidine, 1-methylpyrrolidine, 1-ethylpyrrolidine, 1-ethypyridine, piperidine, 1-methylpiperidine, 2,6-dimethylpiperidine Pyridine, 3,5-dimethylpiperidine, 1-ethylpiperidine, 1-methyl acetylpiperidine, 1-ethyl acetylpiperidine, morpholine, 4-methylmorpholine, 2,6-di Methylmorpholine, 4-ethylmorpholine, 4-acylmorpholine (4-methylacrylomorpholine, 4-ethylacrylomorpholine, 4-propionylmorpholine, 4-butanoylmorpholine, 4 -Pentyl morpholine, 4-hexyl morpholine, 4-heptanoyl morpholine, 4-octyl morpholine, 4-nonyl morpholine, 4-decyl morpholine, 4-decyl morpholine, 4-undecylo morpholine Morpholine, 4-dodecylmorpholine, etc.), 1-methylpiperazine, 1,4-dimethylpiperazine, 1-ethylpiperazine, 1-methylpyrazine, etc. Saturated cyclic amines with 5 to 6 member rings of more than one nitrogen atom.

作為碳酸酯，可列舉碳酸乙烯酯、碳酸丙烯酯、碳酸1,2-丁烯酯、碳酸三亞甲酯等之碳酸C2 ～ 4 伸烷酯等。Examples of carbonates include C 2 to 4 alkylene carbonates such as ethylene carbonate, propylene carbonate, 1,2-butylene carbonate, and trimethylene carbonate.

3-甲氧基-N,N-二甲基丙醯胺以外之極性溶劑的含量，只要不損害本發明之效果雖為任意，但通常(b)極性溶劑中為0～50質量%左右，較佳為0～40質量%，更佳為0～30質量%。其他極性溶劑可1種單獨使用，亦可混合2種以上使用。The content of the polar solvent other than 3-methoxy-N,N-dimethylpropylamide is arbitrary as long as it does not impair the effect of the present invention, but it is usually about 0 to 50% by mass in (b) polar solvents, It is preferably 0 to 40% by mass, and more preferably 0 to 30% by mass. Other polar solvents can be used alone or in combination of two or more.

(b-2)非極性溶劑雖並未特別限定，但通常為在20℃之水溶解度未滿1g/L者，較佳為未滿0.7g/L者，更佳為未滿0.5g/L者。作為非極性溶劑之例，可列舉二甲苯、烷基(C9 ～ 13 等)苯、苯基二甲苯基乙烷、二甲基萘、烷基(C1 、C3 或C12 ～ 14 等)萘、烷基聯苯、烷基二苯基烷烴、沸點為150～350℃之芳香族烴等之芳香族烴；機油、正石蠟、異烷烴(Isoparaffin)、環烷酸等之脂肪族烴；煤油等之芳香族烴與脂肪族烴的混合物；芳香族羧酸酯(苯甲酸、鄰苯二甲酸、間苯二甲酸、對苯二甲酸、偏苯三酸、苯均四酸等之芳香族羧酸、與甲醇、乙醇、丙醇、異丙醇、丁醇、異丁醇、己醇、己醇、2-乙基己醇、異壬基醇、癸基醇、異癸基醇、十三烷基醇、苄基醇等之碳數1～13之醇的酯)；二元酸酯(草酸、丙二酸、琥珀酸、戊二酸、2-甲基戊二酸、己二酸、庚二酸、辛二酸、壬二酸、癸二酸等之碳數2～10之二羧酸、與甲醇、乙醇、丙醇、異丙醇、丁醇、異丁醇、己醇、己醇、2-乙基己醇、異壬基醇、癸基醇、異癸基醇等之碳數1～10之醇的酯)；脂肪酸酯(蟻酸、乙酸、乳酸、丙酸、丁酸、戊酸、己酸、辛酸、2-乙基己酸、癸酸、月桂酸、肉荳蔻酸、棕櫚酸、硬脂酸、油酸等之碳數1～18之脂肪酸、與甲醇、乙醇、丙醇、異丙醇、丁醇、異丁醇、己醇、己醇、2-乙基己醇、癸基醇、異癸基醇、月桂基醇、十三烷基醇、異十三烷基醇、肉荳蔻基醇、十六烷基醇、硬脂基醇、油基醇等之碳數1～18之醇或乙二醇、丙二醇、甘油、山梨糖醇、季戊四醇等之多元醇的酯、大豆油、亞麻籽油、蓖麻油、椰子油、菜籽油、棉籽油等之源自植物油之脂肪酸酯)等。此等當中，較佳為芳香族烴。(b-2) Although the non-polar solvent is not particularly limited, it is generally one having a water solubility of less than 1 g/L at 20°C, preferably less than 0.7 g/L, and more preferably less than 0.5 g/L By. Examples of non-polar solvents include xylene, alkyl (C 9 to 13 etc.) benzene, phenyl xylyl ethane, dimethyl naphthalene, alkyl (C 1 , C 3 or C 12 to 14 etc.) ) Aromatic hydrocarbons such as naphthalene, alkyl biphenyls, alkyl diphenyl alkanes, aromatic hydrocarbons with a boiling point of 150-350°C; aliphatic hydrocarbons such as engine oil, normal paraffin, isoparaffin, naphthenic acid, etc. ; A mixture of aromatic hydrocarbons and aliphatic hydrocarbons such as kerosene; aromatic carboxylic acid esters (benzoic acid, phthalic acid, isophthalic acid, terephthalic acid, trimellitic acid, pyromellitic acid, etc. aromatic Group carboxylic acids, with methanol, ethanol, propanol, isopropanol, butanol, isobutanol, hexanol, hexanol, 2-ethylhexanol, isononyl alcohol, decyl alcohol, isodecyl alcohol, Esters of C1-C13 alcohols such as tridecyl alcohol and benzyl alcohol); dibasic acid esters (oxalic acid, malonic acid, succinic acid, glutaric acid, 2-methylglutaric acid, adipic acid) Acid, pimelic acid, suberic acid, azelaic acid, sebacic acid and other C 2-10 dicarboxylic acids, and methanol, ethanol, propanol, isopropanol, butanol, isobutanol, hexanol , Hexanol, 2-ethylhexanol, isononyl alcohol, decyl alcohol, isodecyl alcohol and other C 1-10 alcohol esters); fatty acid esters (formic acid, acetic acid, lactic acid, propionic acid, Butyric acid, valeric acid, caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid and other fatty acids with 1 to 18 carbon atoms, and methanol, Ethanol, propanol, isopropanol, butanol, isobutanol, hexanol, hexanol, 2-ethylhexanol, decyl alcohol, isodecyl alcohol, lauryl alcohol, tridecyl alcohol, isodecyl alcohol C1-C18 alcohols such as trialkyl alcohols, myristyl alcohols, cetyl alcohols, stearyl alcohols, oleyl alcohols, or polyhydric alcohols such as ethylene glycol, propylene glycol, glycerin, sorbitol, and pentaerythritol Fatty acid esters derived from vegetable oils such as alcohol esters, soybean oil, linseed oil, castor oil, coconut oil, rapeseed oil, cottonseed oil, etc.). Among these, aromatic hydrocarbons are preferred.

(b-1)極性溶劑及(b-2)非極性溶劑的混合比，從防止(a)農藥活性成分之結晶析出的觀點來看，較佳為以質量比為極性溶劑：非極性溶劑=15：85～65：35，更佳為20：80～60：40，再更佳為30：70～55：45。(b-1) The mixing ratio of the polar solvent and (b-2) non-polar solvent is preferably the polar solvent with the mass ratio as the polar solvent from the viewpoint of preventing (a) the crystal precipitation of the pesticide active ingredient: non-polar solvent = 15:85 to 65:35, more preferably 20:80 to 60:40, and even more preferably 30:70 to 55:45.

(b)混合溶劑的含量於本發明之組成物中通常為45～97.95質量%。含量的下限較佳為55質量%以上，更佳為62質量%以上，再更佳為65質量%以上，又再更佳為70質量%以上。含量的上限較佳為96.9質量%以下，更佳為95質量%以下，再更佳為93質量%以下，又再更佳為91質量%以下。(b) The content of the mixed solvent is usually 45 to 97.95% by mass in the composition of the present invention. The lower limit of the content is preferably 55 mass% or more, more preferably 62 mass% or more, even more preferably 65 mass% or more, and still more preferably 70 mass% or more. The upper limit of the content is preferably 96.9% by mass or less, more preferably 95% by mass or less, even more preferably 93% by mass or less, and still more preferably 91% by mass or less.

[(c)界面活性劑] 作為(c)成分之界面活性劑，可列舉以下之(A)～(E)所示者。[(c) Surfactant] Examples of the surfactant of the component (c) include the following (A) to (E).

(A)非離子性界面活性劑： (A-1)聚乙二醇型界面活性劑：例如可列舉聚氧乙烯烷基(C12 ～ 18 )醚、烷基萘酚之氧化乙烯加成物、聚氧乙烯(單或二)烷基(C8 ～ 12 )苯基醚、聚氧乙烯(單或二)烷基(C8 ～ 12 )苯基醚之福馬林縮合物、聚氧乙烯(單、二或三)苯基苯基醚、聚氧乙烯(單、二或三)苄基苯基醚、聚氧丙烯(單、二或三)苄基苯基醚、聚氧乙烯(單、二或三)苯乙烯基苯基醚、聚氧丙烯(單、二或三)苯基苯基醚、聚氧丙烯(單、二或三)苯乙烯基苯基醚、聚氧乙烯(單、二或三)苯乙烯基苯基醚之福馬林縮合物、聚氧丙烯(單、二或三)苯乙烯基苯基醚甲醛縮合物、聚氧乙烯聚氧丙烯嵌段聚合物、烷基(C12 ～ 18 )聚氧乙烯聚氧丙烯嵌段聚合物醚、烷基(C8 ～ 12 )苯基聚氧乙烯聚氧丙烯嵌段聚合物醚、聚氧乙烯雙苯基醚、聚氧乙烯樹脂酸酯、聚氧乙烯脂肪酸(C12 ～ 18 )單酯、聚氧乙烯脂肪酸(C12 ～ 18 )二酯、聚氧乙烯山梨糖醇脂肪酸(C12 ～ 18 )酯、丙三醇脂肪酸酯氧化乙烯加成物、聚氧化烯基植物油(聚氧乙烯蓖麻油醚、聚氧乙烯硬化蓖麻油醚、聚氧丙烯蓖麻油醚、聚氧丙烯硬化蓖麻油醚、聚氧乙烯菜籽油醚等)、烷基(C12 ～ 18 )胺氧化乙烯加成物、脂肪酸(C12 ～ 18 )醯胺氧化乙烯加成物等。(A) Nonionic surfactant: (A-1) Polyethylene glycol type surfactant: for example, ethylene oxide adducts of polyoxyethylene alkyl (C 12 to 18 ) ether, alkyl naphthol , Polyoxyethylene (mono or di) alkyl (C 8 ～ 12 ) phenyl ether, polyoxyethylene (mono or di) alkyl (C 8 ～ 12 ) phenyl ether formalin condensate, polyoxyethylene ( Mono-, di- or tri) phenyl phenyl ether, polyoxyethylene (mono, di or tri) benzyl phenyl ether, polyoxypropylene (mono, di or tri) benzyl phenyl ether, polyoxyethylene (mono, Di or tri) styryl phenyl ether, polyoxypropylene (mono, di or tri) phenyl phenyl ether, polyoxypropylene (mono, di or tri) styryl phenyl ether, polyoxyethylene (mono, Two or three) formalin condensate of styryl phenyl ether, polyoxypropylene (mono, di or tri) styryl phenyl ether formaldehyde condensate, polyoxyethylene polyoxypropylene block polymer, alkyl ( C 12 ～ 18 ) polyoxyethylene polyoxypropylene block polymer ether, alkyl (C 8 ～ 12 ) phenyl polyoxyethylene polyoxypropylene block polymer ether, polyoxyethylene bisphenyl ether, polyoxyethylene resin acid esters, polyoxyethylene fatty acid (C 12 ~ 18) monoesters, polyoxyethylene fatty acid (C 12 ~ 18) diesters, polyoxyethylene sorbitol fatty acid (C 12 ~ 18) esters, glycerin fatty acid Ethylene oxide adducts, polyoxyalkylene-based vegetable oils (polyoxyethylene castor oil ether, polyoxyethylene hardened castor oil ether, polyoxypropylene castor oil ether, polyoxypropylene hardened castor oil ether, polyoxyethylene rapeseed oil ether Etc.), alkyl (C 12 to 18 ) amine ethylene oxide adducts, fatty acid (C 12 to 18 ) amide ethylene oxide adducts, etc.

(A-2)多元醇型界面活性劑：例如可列舉丙三醇脂肪酸酯、聚甘油脂肪酸酯、季戊四醇脂肪酸酯、山梨醇(Sorbitol)脂肪酸(C12 ～ 18 )酯、山梨糖醇脂肪酸(C12 ～ 18 )酯、蔗糖脂肪酸酯、多元醇烷基醚、脂肪酸烷醇醯胺等。(A-2) Polyol type surfactants: for example, glycerin fatty acid esters, polyglycerin fatty acid esters, pentaerythritol fatty acid esters, sorbitol (Sorbitol) fatty acid (C 12 to 18 ) esters, sorbitol Fatty acid (C 12 to 18 ) ester, sucrose fatty acid ester, polyhydric alcohol alkyl ether, fatty acid alkanolamide, etc.

(A-3)乙炔系界面活性劑：例如可列舉乙炔二醇、乙炔醇、乙炔二醇之氧化乙烯加成物、乙炔醇之氧化乙烯加成物等。(A-3) Acetylene-based surfactant: For example, acetylene glycol, acetylene alcohol, ethylene oxide adducts of acetylene glycol, ethylene oxide adducts of acetylene alcohol, etc. may be mentioned.

(A-4)其他界面活性劑：例如可列舉烷基烷基糖苷等。(A-4) Other surfactants: Examples include alkyl alkyl glycosides.

(B)陰離子性界面活性劑： (B-1)羧酸型界面活性劑：例如可列舉聚丙烯酸、聚甲基丙烯酸、聚馬來酸、馬來酸與烯烴(異丙烯、二異丁烯等)的共聚物、丙烯酸與衣康酸的共聚物、甲基丙烯酸與衣康酸的共聚物、馬來酸與苯乙烯的共聚物、丙烯酸與甲基丙烯酸的共聚物、丙烯酸與丙烯酸甲基酯的共聚物、丙烯酸與乙酸乙烯酯的共聚物、丙烯酸與馬來酸的共聚物、N-甲基-脂肪酸(C12 ～ 18 )肌氨酸酯、樹脂酸、脂肪酸(C12 ～ 18 )等之羧酸、此等之羧酸之鹽。(B) Anionic surfactant: (B-1) Carboxylic acid type surfactant: for example, polyacrylic acid, polymethacrylic acid, polymaleic acid, maleic acid and olefins (isopropylene, diisobutylene, etc.) Copolymer, acrylic acid and itaconic acid copolymer, methacrylic acid and itaconic acid copolymer, maleic acid and styrene copolymer, acrylic acid and methacrylic acid copolymer, acrylic acid and methyl acrylate Copolymer, copolymer of acrylic acid and vinyl acetate, copolymer of acrylic acid and maleic acid, N-methyl-fatty acid (C 12 ～ 18 ) sarcosinate, resin acid, fatty acid (C 12 ～ 18 ), etc. Carboxylic acids, salts of these carboxylic acids.

(B-2)硫酸酯型界面活性劑：例如可列舉烷基(C12 ～ 18 )硫酸酯、聚氧乙烯烷基(C12 ～ 18 )醚硫酸酯、聚氧乙烯(單或二)烷基(C8 ～ 12 )苯基醚硫酸酯、聚氧乙烯(單或二)烷基(C8 ～ 12 )苯基醚之聚合物的硫酸酯、聚氧乙烯(單、二或三)苯基苯基醚硫酸酯、聚氧乙烯(單、二或三)苄基苯基醚硫酸酯、聚氧乙烯(單、二或三)苯乙烯基苯基醚硫酸酯、聚氧乙烯(單、二或三)苯乙烯基苯基醚之聚合物的硫酸酯、聚氧乙烯聚氧丙烯嵌段聚合物的硫酸酯、硫酸化油、硫酸化脂肪酸酯、硫酸化脂肪酸、硫酸化烯烴等之硫酸酯、此等之硫酸酯之鹽。(B-2) Sulfate type surfactant: for example, alkyl (C 12 to 18 ) sulfate, polyoxyethylene alkyl (C 12 to 18 ) ether sulfate, polyoxyethylene (mono or di) alkyl (C 8 ～ 12 ) phenyl ether sulfate, polyoxyethylene (mono or di) alkyl (C 8 ～ 12 ) phenyl ether polymer sulfate, polyoxyethylene (mono, di or tri) benzene Phenyl phenyl ether sulfate, polyoxyethylene (mono, di or tri) benzyl phenyl ether sulfate, polyoxyethylene (mono, di or tri) styryl phenyl ether sulfate, polyoxyethylene (mono, Two or three) sulfate ester of polymer of styryl phenyl ether, sulfate ester of polyoxyethylene polyoxypropylene block polymer, sulfated oil, sulfated fatty acid ester, sulfated fatty acid, sulfated olefin, etc. Sulfates, salts of these sulfates.

(B-3)磺酸型界面活性劑：例如可列舉石蠟(C12 ～ 22 )磺酸、烷基(C8 ～ 12 )苯磺酸、烷基(C8 ～ 12 )苯磺酸之福馬林縮合物、甲酚磺酸之福馬林縮合物、α-烯烴(C14 ～ 16 )磺酸、二烷基(C8 ～ 12 )磺基琥珀酸、木質素磺酸、聚氧乙烯(單或二)烷基(C8 ～ 12 )苯基醚磺酸、聚氧乙烯烷基(C12 ～ 18 )醚磺基琥珀酸半酯、萘磺酸、(單或二)烷基(C1 ～ 6 )萘磺酸、萘磺酸之福馬林縮合物、(單或二)烷基(C1 ～ 6 )萘磺酸之福馬林縮合物、雜酚油磺酸之福馬林縮合物、烷基(C8 ～ 12 )二苯基醚二磺酸、IGEPON T(商品名)、聚苯乙烯磺酸、苯乙烯磺酸與甲基丙烯酸的共聚物等之磺酸、此等之磺酸之鹽。(B-3) a sulfonic acid type surfactant: for example include paraffin (C 12 ~ 22) sulfonic acids, alkyl (C 8 ~ 12) sulfonic acid, alkyl (C 8 ~ 12) of benzenesulfonic Fuma Lin condensate, formalin condensate of cresol sulfonic acid, α-olefin (C 14 ～ 16 ) sulfonic acid, dialkyl (C 8 ～ 12 ) sulfosuccinic acid, lignin sulfonic acid, polyoxyethylene (single Or di) alkyl (C 8 ～ 12 ) phenyl ether sulfonic acid, polyoxyethylene alkyl (C 12 ～ 18 ) ether sulfosuccinic acid half ester, naphthalene sulfonic acid, (mono or di) alkyl (C 1 ～ 6 ) Naphthalene sulfonic acid, formalin condensate of naphthalene sulfonic acid, (mono or di) alkyl (C 1 ～ 6 ) formalin condensate of naphthalene sulfonic acid, formalin condensate of creosote sulfonic acid, alkyl Sulfonic acid based on (C 8 ～ 12 ) diphenyl ether disulfonic acid, IGEPON T (trade name), polystyrene sulfonic acid, copolymer of styrene sulfonic acid and methacrylic acid, etc. salt.

(B-4)磷酸酯型界面活性劑：例如可列舉烷基(C8 ～ 12 )磷酸酯、聚氧乙烯烷基(C12 ～ 18 )醚磷酸酯、聚氧乙烯(單或二)烷基(C8 ～ 12 )苯基醚磷酸酯、聚氧乙烯(單、二或三)烷基(C8 ～ 12 )苯基醚之聚合物的磷酸酯、聚氧乙烯(單、二或三)苯基苯基醚磷酸酯、聚氧乙烯(單、二或三)苄基苯基醚磷酸酯、聚氧乙烯(單、二或三)苯乙烯基苯基醚磷酸酯、聚氧乙烯(單、二或三)苯乙烯基苯基醚之聚合物的磷酸酯、聚氧乙烯聚氧丙烯嵌段聚合物的磷酸酯、膽鹼磷脂、磷脂醯基乙醇亞胺、縮合磷酸(三聚磷酸等)等之磷酸酯、此等之磷酸酯之鹽。(B-4) Phosphate type surfactant: for example, alkyl (C 8 to 12 ) phosphate, polyoxyethylene alkyl (C 12 to 18 ) ether phosphate, polyoxyethylene (mono or di) alkane (C 8 ～ 12 ) phenyl ether phosphate, polyoxyethylene (mono, di or tri) alkyl (C 8 ～ 12 ) phenyl ether polymer phosphate, polyoxyethylene (mono, di or tri) ) Phenyl phenyl ether phosphate, polyoxyethylene (mono, di or tri) benzyl phenyl ether phosphate, polyoxyethylene (mono, di or tri) styryl phenyl ether phosphate, polyoxyethylene ( Mono-, di- or tri) phosphate esters of polymers of styryl phenyl ether, phosphate esters of polyoxyethylene polyoxypropylene block polymers, choline phospholipids, phospholipid acetylethanolimines, condensed phosphoric acid (tripolyphosphoric acid Etc.) phosphate esters, etc. phosphate salts.

作為在(B-1)～(B-4)之鹽，可列舉鹼金屬(鋰、鈉、鉀等)、鹼土類金屬(鈣、鎂等)、銨、各種胺(烷基胺、環烷基胺、烷醇胺等)等之鹽。Examples of salts in (B-1) to (B-4) include alkali metals (lithium, sodium, potassium, etc.), alkaline earth metals (calcium, magnesium, etc.), ammonium, and various amines (alkylamines, naphthenes) Base amines, alkanolamines, etc.).

(C)陽離子性界面活性劑：例如可列舉烷基胺鹽、烷基4級銨鹽等。(C) Cationic surfactants: for example, alkylamine salts, alkyl quaternary ammonium salts, etc. may be mentioned.

(D)兩性界面活性劑：例如可列舉甜菜鹼型界面活性劑、胺基酸型界面活性劑等。(D) Amphoteric surfactant: For example, betaine-type surfactant, amino acid-type surfactant, etc. may be mentioned.

(E)其他界面活性劑：例如可列舉聚矽氧系界面活性劑、氟系界面活性劑等。(E) Other surfactants: For example, polysiloxane-based surfactants, fluorine-based surfactants, etc. may be mentioned.

此等之界面活性劑當中，較佳為使用以下之(1)～(4)之非離子性界面活性劑。 (1)聚氧化烯基芳基苯基醚：例如較佳為聚氧乙烯(單、二或三)苯基苯基醚、聚氧乙烯(單、二或三)苄基苯基醚、聚氧乙烯(單、二或三)苯乙烯基苯基醚、聚氧丙烯(單、二或三)苯基苯基醚、聚氧丙烯(單、二或三)苄基苯基醚及聚氧丙烯(單、二或三)苯乙烯基苯基醚。Among these surfactants, the following nonionic surfactants (1) to (4) are preferably used. (1) Polyoxyalkylene aryl phenyl ether: for example, preferably polyoxyethylene (mono, di or tri) phenyl phenyl ether, polyoxyethylene (mono, di or tri) benzyl phenyl ether, poly Oxyethylene (mono, di or tri) styryl phenyl ether, polyoxypropylene (mono, di or tri) phenyl phenyl ether, polyoxypropylene (mono, di or tri) benzyl phenyl ether and polyoxypropylene Propylene (mono, di or tri) styryl phenyl ether.

(2)聚氧化烯基芳基苯基醚之福馬林縮合物：例如較佳為聚氧乙烯(單、二或三)苯乙烯基苯基醚之福馬林縮合物及聚氧丙烯(單、二或三)苯乙烯基苯基醚甲醛縮合物。(2) Formalin condensate of polyoxyalkylene aryl phenyl ether: for example, preferred are formalin condensate of polyoxyethylene (mono, di or tri) styryl phenyl ether and polyoxypropylene (mono, Two or three) Styryl phenyl ether formaldehyde condensate.

(3)聚氧化烯基植物油：例如較佳為聚氧乙烯蓖麻油醚、聚氧乙烯硬化蓖麻油醚、聚氧丙烯蓖麻油醚、聚氧丙烯硬化蓖麻油醚及聚氧乙烯菜籽油醚。(3) Polyoxyalkylene-based vegetable oils: for example, polyoxyethylene castor oil ether, polyoxyethylene hardened castor oil ether, polyoxypropylene castor oil ether, polyoxypropylene hardened castor oil ether and polyoxyethylene rapeseed oil ether .

(4)聚氧乙烯聚氧丙烯嵌段聚合物：例如分子量為1,500～20,000，較佳為相對於分子全體之氧化乙烯部分的含量為10～85%者。更具體而言，例如可列舉EPAN(註冊商標)410、EPAN 420、EPAN 450、EPAN 485、EPAN 610、EPAN 680、EPAN 710、EPAN 720、EPAN 740、EPAN 750、EPAN 785、EPAN U103、EPAN U105、EPAN U108(以上為第一工業製藥(股)製)；TOXANON (註冊商標)PE-61、TOXANON PE-62、TOXANON PE-64、TOXANON PE-68、TOXANON PE-71、TOXANON PE-74、TOXANON PE-75、TOXANON PE-78、TOXANON PE-108、TOXANON PE-128(以上為三洋化成工業(股)製)；Pluronic(註冊商標)PE3100、Pluronic PE4300、Pluronic PE6100、Pluronic PE6200、Pluronic PE6400、Pluronic PE6800、Pluronic PE8100、Pluronic PE9200、Pluronic PE9400、Pluronic PE10100、Pluronic PE10500、Pluronic RPE2520、Pluronic RPE3110(以上為BASF公司製)；NEWKALGEN 5050PB、NEWKALGEN 70100PB(以上為竹本油脂(股)製)、PEPOL (註冊商標)B-182、PEPOL B-184、PEPOL B-188(以上為東邦化學工業(股)製)等。(4) Polyoxyethylene polyoxypropylene block polymer: for example, a molecular weight of 1,500 to 20,000, preferably a content of 10 to 85% of the ethylene oxide portion of the entire molecule. More specifically, for example, EPAN (registered trademark) 410, EPAN 420, EPAN 450, EPAN 485, EPAN 610, EPAN 680, EPAN 710, EPAN 720, EPAN 740, EPAN 750, EPAN 785, EPAN U103, EPAN U105 , EPAN U108 (the above is the first industrial pharmaceutical (stock) system); TOXANON (registered trademark) PE-61, TOXANON PE-62, TOXANON PE-64, TOXANON PE-68, TOXANON PE-71, TOXANON PE-74, TOXANON PE-75, TOXANON PE-78, TOXANON PE-108, TOXANON PE-128 (the above are manufactured by Sanyo Chemical Industry Co., Ltd); Pluronic (registered trademark) PE3100, Pluronic PE4300, Pluronic PE6100, Pluronic PE6200, Pluronic PE6400 Pluronic PE6800, Pluronic PE8100, Pluronic PE9200, Pluronic PE9400, Pluronic PE10100, Pluronic PE10500, Pluronic RPE2520, Pluronic RPE3110 (above are made by BASF); NEWKALGEN 5050PB, NEWKALGEN 70100PB (above are made by bamboo oil (share)), PEPOL Trademarks) B-182, PEPOL B-184, PEPOL B-188 (above is Toho Chemical Industry Co., Ltd.), etc.

前述(1)～(4)之界面活性劑當中，更佳為聚氧化烯基芳基苯基醚或聚氧化烯基植物油，再更佳為聚氧乙烯單苯乙烯基苯基醚、聚氧乙烯二苯乙烯基苯基醚、聚氧乙烯三苯乙烯基苯基醚、聚氧乙烯蓖麻油醚或聚氧乙烯硬化蓖麻油醚。Among the aforementioned surfactants (1) to (4), polyoxyalkylene aryl phenyl ether or polyoxyalkylene vegetable oil is more preferred, and polyoxyethylene monostyryl phenyl ether, polyoxyethylene Ethylene distyryl phenyl ether, polyoxyethylene tristyryl phenyl ether, polyoxyethylene castor oil ether or polyoxyethylene hardened castor oil ether.

此等之非離子性界面活性劑可為1種單獨使用，亦可組合2種以上使用。These nonionic surfactants may be used alone or in combination of two or more.

(c)成分之界面活性劑，較佳為組合非離子性界面活性劑與陰離子性界面活性劑使用，特佳為以下之(5)～(8)的組合。 (5)聚氧化烯基芳基苯基醚、與烷基(C8 ～ 12 )苯磺酸鹽的組合。 (6)聚氧化烯基芳基苯基醚之福馬林縮合物、與烷基(C8 ～ 12 )苯磺酸鹽的組合。 (7)聚氧化烯基植物油、與烷基(C8 ～ 12 )苯磺酸鹽的組合。 (8)聚氧乙烯聚氧丙烯嵌段共聚物、與烷基(C8 ～ 12 )苯磺酸鹽的組合。(c) The surfactant of the component is preferably used in combination with a nonionic surfactant and an anionic surfactant, and the combination of the following (5) to (8) is particularly preferable. (5) a polyoxyalkylene aryl phenyl ether, and combinations of alkyl benzenesulfonate (C 8 ~ 12). (6) a polyoxyalkylene aryl phenyl ether formalin condensate of, with a combination of alkyl benzenesulfonate (C 8 ~ 12). (7) Combination of polyoxyalkylene-based vegetable oil and alkyl (C 8 to 12 ) benzenesulfonate. (8) a polyoxyethylene polyoxypropylene block copolymers, in combination with an alkyl (C 8 ~ 12) benzenesulfonate.

以上之組合當中，更佳為以下之(9)～(13)之組合。 (9)聚氧乙烯(單、二或三)苯乙烯基苯基醚、與十二烷基苯磺酸鈣鹽的組合。 (10)聚氧乙烯(單、二或三)苯乙烯基苯基醚之福馬林縮合物、與十二烷基苯磺酸鈣鹽的組合。 (11)聚氧乙烯蓖麻油醚、與十二烷基苯磺酸鈣鹽的組合。 (12)聚氧乙烯硬化蓖麻油醚、與十二烷基苯磺酸鈣鹽的組合。 (13)聚氧乙烯聚氧丙烯嵌段共聚物、與十二烷基苯磺酸鈣鹽的組合。Among the above combinations, the following combinations (9) to (13) are more preferable. (9) Combination of polyoxyethylene (mono, di or tri) styryl phenyl ether and calcium salt of dodecylbenzene sulfonic acid. (10) Combination of formalin condensate of polyoxyethylene (mono-, di- or tri) styryl phenyl ether and calcium salt of dodecylbenzenesulfonic acid. (11) Combination of polyoxyethylene castor oil ether and calcium salt of dodecylbenzenesulfonic acid. (12) Combination of polyoxyethylene hardened castor oil ether and calcium salt of dodecylbenzenesulfonic acid. (13) Combination of polyoxyethylene polyoxypropylene block copolymer and calcium salt of dodecylbenzenesulfonic acid.

組合非離子性界面活性劑與陰離子性界面活性劑使用時，其摻合比較佳為以質量比，以成為非離子性界面活性劑：陰離子性界面活性劑=10：90～90：10的方式進行摻合，更佳為以成為20：80～80：20的方式進行摻合。When using a combination of a nonionic surfactant and an anionic surfactant, the blending ratio is preferably a mass ratio to become a nonionic surfactant: anionic surfactant=10:90～90:10 The blending is more preferably carried out so as to become 20:80 to 80:20.

(c)界面活性劑的含量係本發明之組成物中通常為2～30質量%。含量的下限較佳為3質量%以上，更佳為4質量%以上，再更佳為5質量%以上，又再更佳為6質量%以上。含量的上限較佳為25質量%以下，更佳為20質量%以下，再更佳為18質量%以下，又再更佳為16質量%以下。(c) The content of the surfactant is usually 2 to 30% by mass in the composition of the present invention. The lower limit of the content is preferably 3% by mass or more, more preferably 4% by mass or more, even more preferably 5% by mass or more, and still more preferably 6% by mass or more. The upper limit of the content is preferably 25% by mass or less, more preferably 20% by mass or less, still more preferably 18% by mass or less, and still more preferably 16% by mass or less.

又，界面活性劑以增強本發明之組成物之殺蟲或殺蟎活性為目的，亦可作為佐劑使用。又，作為其他佐劑，可列舉植物油及礦物油。此等之佐劑可提前含有農藥乳化性組成物中使用，亦可混合在該農藥乳化性組成物之稀釋液使用。In addition, the surfactant can be used as an adjuvant for the purpose of enhancing the insecticidal or acaricidal activity of the composition of the present invention. In addition, as other adjuvants, vegetable oils and mineral oils may be mentioned. These adjuvants may be used in advance containing the pesticide emulsified composition, or may be mixed in the diluent of the pesticide emulsifiable composition.

作為可進一步使用在本發明之組成物之補助成分，例如可列舉防凍劑、pH調整劑、抗分解劑、消泡劑、防腐劑等。Examples of auxiliary components that can be further used in the composition of the present invention include antifreeze agents, pH adjusting agents, anti-decomposition agents, antifoaming agents, and preservatives.

本發明之農藥乳化性組成物，例如可藉由將(a)成分、(c)成分及如有必要之補助成分溶解在極性溶劑及非極性溶劑之混合溶劑來製造。The pesticide emulsifiable composition of the present invention can be produced, for example, by dissolving (a) component, (c) component and, if necessary, auxiliary components in a mixed solvent of a polar solvent and a non-polar solvent.

本發明之農藥乳化性組成物，例如可用以水稀釋成10～5,000倍左右，使用噴霧機等散布在作物或樹木或生育其之土壤之方法、從空中使用直升機等，以水稀釋成2～100倍左右進行散布之方法施用。 [實施例]The pesticide emulsifiable composition of the present invention can be diluted to about 10 to 5,000 times with water, for example, it can be sprayed on crops or trees or the soil that grows it, using a sprayer, etc., and it can be diluted with water to 2 to 2 to use water. The method of application is about 100 times. [Example]

以下，雖列舉實施例及比較例，更具體說明本發明，但本發明並非被限定於下述實施例。Although the following examples and comparative examples are used to explain the present invention more specifically, the present invention is not limited to the following examples.

[1]農藥乳化性組成物的調製 [實施例1-1] 混合氟米塔麥(fluxametamide)原體(純度94.0%)10.64質量份、3-甲氧基-N,N-二甲基丙醯胺(KJCMPA(註冊商標)-100、KJChemicals(股)製)35質量份、聚氧乙烯蓖麻油醚(Sorpol (註冊商標)CA-42、東邦化學工業(股)製)4質量份、十二烷基苯磺酸鈣(Sorpol EX-15、東邦化學工業(股)製)4質量份及芳香族烴(Solvesso(註冊商標)200、ExxonMobil Chemical公司製)46.36質量份，來調製農藥乳化性組成物A1。[1] Preparation of pesticide emulsified composition [Example 1-1] Fluxametamide original (purity 94.0%) 10.64 parts by mass, 3-methoxy-N,N-dimethylpropionamide (KJCMPA (registered trademark)-100, KJ Chemicals Co., Ltd.) 35 parts by mass, polyoxyethylene castor oil ether (Sorpol (registered trademark) CA-42, Toho Chemical Industry Co., Ltd.) 4 parts by mass, calcium dodecylbenzenesulfonate (Sorpol EX-15, Toho Chemical Industry ( Co., Ltd.) 4 parts by mass and 46.36 parts by mass of aromatic hydrocarbons (Solvesso (registered trademark) 200, manufactured by ExxonMobil Chemical Co., Ltd.) to prepare the pesticide emulsifiable composition A1.

[實施例1-2] 除了將3-甲氧基-N,N-二甲基丙醯胺35質量份變更為40質量份，將芳香族烴46.36質量份變更為41.36質量份之外，其他以與實施例1-1相同的方法，來調製農藥乳化性組成物A2。[Example 1-2] Except that 35 parts by mass of 3-methoxy-N,N-dimethylpropionamide was changed to 40 parts by mass, and 46.36 parts by mass of aromatic hydrocarbon was changed to 41.36 parts by mass, the others were the same as those of Example 1-1 The same method is used to prepare pesticide emulsifiable composition A2.

[實施例1-3] 除了將3-甲氧基-N,N-二甲基丙醯胺35質量份變更為50質量份，芳香族烴46.36質量份變更為31.36質量份之外，其他以與實施例1-1相同的方法，來調製農藥乳化性組成物A3。[Example 1-3] It is the same as Example 1-1 except that 35 parts by mass of 3-methoxy-N,N-dimethylpropionamide is changed to 50 parts by mass and 46.36 parts by mass of aromatic hydrocarbon is changed to 31.36 parts by mass. Method to prepare pesticide emulsifiable composition A3.

[實施例1-4] 除了將聚氧乙烯蓖麻油醚4質量份變更為聚氧乙烯苯乙烯基苯基醚(Sorpol T-26、東邦化學工業(股)製)4質量份之外，其他以與實施例1-1相同的方法，來調製農藥乳化性組成物A4。[Example 1-4] Except for changing 4 parts by mass of polyoxyethylene castor oil ether to 4 parts by mass of polyoxyethylene styryl phenyl ether (Sorpol T-26, manufactured by Toho Chemical Industry Co., Ltd.), the other The same method is used to prepare pesticide emulsifiable composition A4.

[實施例1-5] 除了將聚氧乙烯蓖麻油醚4質量份變更為聚氧乙烯硬化蓖麻油醚(Sorpol HC-40、東邦化學工業(股)製)4質量份之外，其他以與實施例1-1相同的方法，來調製農藥乳化性組成物A5。[Example 1-5] Except that 4 parts by mass of polyoxyethylene castor oil ether was changed to 4 parts by mass of polyoxyethylene hardened castor oil ether (Sorpol HC-40, manufactured by Toho Chemical Industry Co., Ltd.), the rest was the same as Example 1-1. Method to prepare pesticide emulsifiable composition A5.

[實施例1-6] 混合氟米塔麥(fluxametamide)原體(純度94.0%)3.0質量份、3-甲氧基-N,N-二甲基丙醯胺(KJCMPA-100、KJChemicals(股)製)15質量份、非離子性界面活性劑與陰離子性界面活性劑的混合物(Sorpol 2680、東邦化學工業(股)製)15質量份及二甲苯(純正化學(股)製)75質量份，來調製農藥乳化性組成物A6。[Example 1-6] Fluoxametamide (fluxametamide) original (purity 94.0%) 3.0 parts by mass, 3-methoxy-N,N-dimethylpropionamide (KJCMPA-100, KJ Chemicals (made)) 15 parts by mass, A mixture of nonionic surfactant and anionic surfactant (Sorpol 2680, manufactured by Toho Chemical Industry Co., Ltd.) 15 parts by mass and xylene (made by Pure Chemicals Co., Ltd.) 75 parts by mass to prepare the emulsifiable composition of pesticides物A6.

[實施例1-7] 除了將氟米塔麥(fluxametamide)原體10.64質量份變更為畢達本原體(純度99.5%)10.05質量份，芳香族烴46.36質量份變更為46.95質量份之外，其他以與實施例1-1相同的方法，來調製農藥乳化性組成物A7。[Example 1-7] Except that 10.64 parts by mass of the original fluxametamide was changed to 10.05 parts by mass of the Pythagorium (purity 99.5%) and 46.36 parts by mass of the aromatic hydrocarbon was changed to 46.95 parts by mass, the other -1 Prepare the pesticide emulsifiable composition A7 in the same way.

[實施例1-8] 除了將氟米塔麥(fluxametamide)原體10.64質量份變更為安美速原體(純度99.5%)10.05質量份，芳香族烴46.36質量份變更為46.95質量份之外，其他以與實施例1-1相同的方法，來調製農藥乳化性組成物A8。[Example 1-8] Except that 10.64 parts by mass of the original fluxametamide was changed to 10.05 parts by mass of the original Amethyst (purity 99.5%), and 46.36 parts by mass of the aromatic hydrocarbon was changed to 46.95 parts by mass. 1 Prepare the pesticide emulsifiable composition A8 in the same way.

[實施例1-9] 除了將氟米塔麥(fluxametamide)原體10.64質量份變更為快伏草原體(純度98%)10.20質量份，芳香族烴46.36質量份變更為46.80質量份之外，其他以與實施例1-1相同的方法，來調製農藥乳化性組成物A9。[Example 1-9] Except that 10.64 parts by mass of the original fluxametamide was changed to 10.20 parts by mass of the fast grassland (purity 98%) and 46.36 parts by mass of the aromatic hydrocarbon was changed to 46.80 parts by mass. 1 Prepare pesticide emulsifiable composition A9 in the same way.

[實施例1-10] 除了將聚氧乙烯蓖麻油醚4質量份變更為2質量份，十二烷基苯磺酸鈣4質量份變更為2質量份，芳香族烴46.36質量份變更為50.36質量份之外，其他以與實施例1-1相同的方法，來調製農藥乳化性組成物A10。[Example 1-10] In addition to changing 4 parts by mass of polyoxyethylene castor oil ether to 2 parts by mass, 4 parts by mass of calcium dodecylbenzenesulfonate to 2 parts by mass, and 46.36 parts by mass of aromatic hydrocarbons to 50.36 parts by mass, other The pesticide emulsifiable composition A10 was prepared in the same manner as in Example 1-1.

[實施例1-11] 除了將聚氧乙烯蓖麻油醚4質量份變更為6質量份，十二烷基苯磺酸鈣4質量份變更為6質量份，芳香族烴46.36質量份變更為42.36質量份之外，其他以與實施例1-1相同的方法，來調製農藥乳化性組成物A11。[Example 1-11] In addition to changing 4 parts by mass of polyoxyethylene castor oil ether to 6 parts by mass, 4 parts by mass of calcium dodecylbenzenesulfonate to 6 parts by mass, and 46.36 parts by mass of aromatic hydrocarbon to 42.36 parts by mass, other The pesticide emulsifiable composition A11 was prepared in the same manner as in Example 1-1.

[實施例1-12] 除了將聚氧乙烯蓖麻油醚4質量份變更為8質量份，十二烷基苯磺酸鈣4質量份變更為8質量份，芳香族烴46.36質量份變更為38.36質量份之外，其他以與實施例1-1相同的方法，來調製農藥乳化性組成物A12。[Example 1-12] In addition to changing 4 parts by mass of polyoxyethylene castor oil ether to 8 parts by mass, 4 parts by mass of calcium dodecylbenzenesulfonate to 8 parts by mass, and 46.36 parts by mass of aromatic hydrocarbons to 38.36 parts by mass, other The pesticide emulsifiable composition A12 was prepared in the same manner as in Example 1-1.

[實施例1-13] 除了將聚氧乙烯蓖麻油醚4質量份變更為聚氧乙烯苯乙烯基苯基醚之福馬林縮合物(Sorpol F-19、東邦化學工業(股)製)4質量份之外，其他以與實施例1-1相同的方法，來調製農藥乳化性組成物A13。[Example 1-13] In addition to changing 4 parts by mass of polyoxyethylene castor oil ether to 4 parts by mass of formalin condensate (Sorpol F-19, manufactured by Toho Chemical Industry Co., Ltd.) of polyoxyethylene styryl phenyl ether, other The pesticide emulsifiable composition A13 was prepared in the same manner as in Example 1-1.

[比較例1-1] 除了將3-甲氧基-N,N-二甲基丙醯胺35質量份變更為N,N-二甲基甲醯胺(和光純藥工業(股)製)35質量份之外，其他以與實施例1-1相同的方法，來調製農藥乳化性組成物B1。[Comparative Example 1-1] In addition to changing 35 parts by mass of 3-methoxy-N,N-dimethylpropionamide to 35 parts by mass of N,N-dimethylformamide (manufactured by Wako Pure Chemical Industries, Ltd.), other The pesticide emulsifiable composition B1 was prepared in the same manner as in Example 1-1.

[比較例1-2] 除了將3-甲氧基-N,N-二甲基丙醯胺40質量份變更為N,N-二甲基甲醯胺(和光純藥工業(股)製)40質量份之外，其他以與實施例1-2相同的方法，來調製農藥乳化性組成物B2。[Comparative Example 1-2] In addition to changing 40 parts by mass of 3-methoxy-N,N-dimethylpropionamide to 40 parts by mass of N,N-dimethylformamide (manufactured by Wako Pure Chemical Industries, Ltd.), other The pesticide emulsifiable composition B2 was prepared in the same manner as in Example 1-2.

[比較例1-3] 除了將3-甲氧基-N,N-二甲基丙醯胺50質量份變更為N,N-二甲基甲醯胺(和光純藥工業(股)製)50質量份之外，其他以與實施例1-3相同的方法，來調製農藥乳化性組成物B3。[Comparative Example 1-3] In addition to changing 50 parts by mass of 3-methoxy-N,N-dimethylpropionamide to 50 parts by mass of N,N-dimethylformamide (manufactured by Wako Pure Chemical Industries, Ltd.), other The pesticide emulsifiable composition B3 was prepared in the same manner as in Examples 1-3.

[比較例1-4] 除了將3-甲氧基-N,N-二甲基丙醯胺35質量份變更為N,N-二甲基甲醯胺(和光純藥工業(股)製)35質量份之外，其他以與實施例1-4相同的方法，來調製農藥乳化性組成物B4。[Comparative Example 1-4] In addition to changing 35 parts by mass of 3-methoxy-N,N-dimethylpropionamide to 35 parts by mass of N,N-dimethylformamide (manufactured by Wako Pure Chemical Industries, Ltd.), other The pesticide emulsifiable composition B4 was prepared in the same manner as in Example 1-4.

[比較例1-5] 除了將3-甲氧基-N,N-二甲基丙醯胺35質量份變更為N,N-二甲基甲醯胺(和光純藥工業(股)製)35質量份之外，其他以與實施例1-5相同的方法，來調製農藥乳化性組成物B5。[Comparative Example 1-5] In addition to changing 35 parts by mass of 3-methoxy-N,N-dimethylpropionamide to 35 parts by mass of N,N-dimethylformamide (manufactured by Wako Pure Chemical Industries, Ltd.), other The pesticide emulsifiable composition B5 was prepared in the same manner as in Example 1-5.

[比較例1-6] 除了將3-甲氧基-N,N-二甲基丙醯胺35質量份變更為3-n-丁氧基-N,N-二甲基丙醯胺(KJCBPA(註冊商標)-100、KJChemicals(股)製)35質量份之外，其他以與實施例1-1相同的方法，來調製農藥乳化性組成物B6。[Comparative Example 1-6] In addition to changing 35 parts by mass of 3-methoxy-N,N-dimethylpropionamide to 3-n-butoxy-N,N-dimethylpropionamide (KJCBPA (registered trademark)-100, KJ Chemicals (manufactured by KJ Chemicals) except for 35 parts by mass, the pesticide emulsifiable composition B6 was prepared in the same manner as in Example 1-1.

[比較例1-7] 除了將3-甲氧基-N,N-二甲基丙醯胺40質量份變更為3-n-丁氧基-N,N-二甲基丙醯胺(KJCBPA-100、KJChemicals (股)製)40質量份之外，其他以與實施例1-2相同的方法，來調製農藥乳化性組成物B7。[Comparative Example 1-7] In addition to changing 40 parts by mass of 3-methoxy-N,N-dimethylpropylamide to 3-n-butoxy-N,N-dimethylpropylamide (KJCBPA-100, KJ Chemicals (shares) Except for 40 parts by mass, the pesticide emulsifiable composition B7 was prepared in the same manner as in Example 1-2.

[比較例1-8] 除了將3-甲氧基-N,N-二甲基丙醯胺50質量份變更為3-n-丁氧基-N,N-二甲基丙醯胺(KJCBPA-100、KJChemicals (股)製)50質量份之外，其他以與實施例1-3相同的方法，來調製農藥乳化性組成物B8。[Comparative Example 1-8] In addition to changing 50 parts by mass of 3-methoxy-N,N-dimethylpropylamide to 3-n-butoxy-N,N-dimethylpropylamide (KJCBPA-100, KJ Chemicals (shares) Except for 50 parts by mass, the pesticide emulsifiable composition B8 was prepared in the same manner as in Example 1-3.

[比較例1-9] 除了將3-甲氧基-N,N-二甲基丙醯胺35質量份變更為3-n-丁氧基-N,N-二甲基丙醯胺(KJCBPA-100、KJChemicals (股)製)35質量份之外，其他以與實施例1-4相同的方法，來調製農藥乳化性組成物B9。[Comparative Example 1-9] In addition to changing 35 parts by mass of 3-methoxy-N,N-dimethylpropylamide to 3-n-butoxy-N,N-dimethylpropylamide (KJCBPA-100, KJ Chemicals (shares) Except for 35 parts by mass, the pesticide emulsifiable composition B9 was prepared in the same manner as in Example 1-4.

[比較例1-10] 除了將3-甲氧基-N,N-二甲基丙醯胺35質量份變更為3-n-丁氧基-N,N-二甲基丙醯胺(KJCBPA-100、KJChemicals (股)製)35質量份之外，其他以與實施例1-5相同的方法，來調製農藥乳化性組成物B10。[Comparative Example 1-10] In addition to changing 35 parts by mass of 3-methoxy-N,N-dimethylpropylamide to 3-n-butoxy-N,N-dimethylpropylamide (KJCBPA-100, KJ Chemicals (shares) Except for 35 parts by mass, the pesticide emulsifiable composition B10 was prepared in the same manner as in Example 1-5.

[比較例1-11] 除了將3-甲氧基-N,N-二甲基丙醯胺35質量份變更為N,N-二甲基乙醯胺(純正化學(股)製)35質量份之外，其他以與實施例1-1相同的方法，來調製農藥乳化性組成物B11。[Comparative Example 1-11] In addition to changing 35 parts by mass of 3-methoxy-N,N-dimethylpropylamide to 35 parts by mass of N,N-dimethylacetamide (made by Pure Chemicals Co., Ltd.), other In the same manner as in Example 1-1, a pesticide emulsifiable composition B11 was prepared.

[比較例1-12] 除了將3-甲氧基-N,N-二甲基丙醯胺40質量份變更為N,N-二甲基乙醯胺(純正化學(股)製)40質量份之外，其他以與實施例1-2相同的方法，來調製農藥乳化性組成物B12。[Comparative Example 1-12] In addition to changing 40 parts by mass of 3-methoxy-N,N-dimethylpropionamide to 40 parts by mass of N,N-dimethylacetamide (made by a pure chemical company), other In the same manner as in Example 1-2, a pesticide emulsifiable composition B12 was prepared.

[比較例1-13] 除了將3-甲氧基-N,N-二甲基丙醯胺50質量份變更為N,N-二甲基乙醯胺(純正化學(股)製)50質量份之外，其他以與實施例1-3相同的方法，來調製農藥乳化性組成物B13。[Comparative Example 1-13] In addition to changing 50 parts by mass of 3-methoxy-N,N-dimethylpropionamide to 50 parts by mass of N,N-dimethylacetamide (made by a pure chemical company), other The pesticide emulsifiable composition B13 was prepared in the same manner as in Example 1-3.

[2]沉澱物量之測定 [實施例2-1～2-13、比較例2-1～2-13] 於100mL量筒放入100mL之3度硬水或19.2度硬水，對於加入1mL之各農藥乳化性組成物，轉倒該量筒使其均勻乳化。將該稀釋液於30℃之恆溫水槽內靜置24小時後，藉由將底部之沉澱物量讀取量筒的刻度測定。將結果示於表1。尚，所謂「極微量」係意指並非不足以讀取量筒的刻度的沉澱量，但確認沉澱物淡淡沉在底部的狀態。[2] Determination of the amount of sediment [Examples 2-1 to 2-13, Comparative Examples 2-1 to 2-13] Put 100 mL of 3 degree hard water or 19.2 degree hard water in a 100 mL measuring cylinder, and for the addition of 1 mL of each pesticide emulsifiable composition, turn over the measuring cylinder to emulsify evenly. After this diluent was allowed to stand in a thermostatic water bath at 30°C for 24 hours, it was measured by reading the amount of sediment at the bottom by reading the scale of the measuring cylinder. The results are shown in Table 1. Still, the so-called "very trace amount" refers to a state where the amount of precipitation that is not enough to read the scale of the graduated cylinder, but confirms that the sediment is lightly sinking to the bottom.

Figure 02_image001
Figure 02_image001

[3]結晶析出率之評估 [實施例3-1～3-13、比較例3-1～3-13] 將實施例2-1～2-13及比較例2-1～2-13再度轉倒實施後之量筒，於恆溫水槽內進一步靜置30分鐘。將靜置後之稀釋液以膜過濾器(孔徑1.0μm)過濾。將過濾器與過濾殘渣於設定在60℃之乾燥機內靜置2小時使其乾燥。將乾燥後之過濾器上殘渣的質量A(mg)及農藥乳化組成物1mL中所包含之農藥原體的質量B(mg)為基礎，藉由下述式算出結晶析出率。 結晶析出率(%)=A/B×100 將結果示於表2。[3] Evaluation of crystal precipitation rate [Examples 3-1 to 3-13, Comparative Examples 3-1 to 3-13] The measuring cylinders of Examples 2-1 to 2-13 and Comparative Examples 2-1 to 2-13 were turned upside down again and allowed to stand still in a constant temperature water tank for 30 minutes. The diluted solution after standing was filtered with a membrane filter (pore size 1.0 μm). The filter and filter residue were allowed to stand in a dryer set at 60°C for 2 hours to dry. Based on the mass A (mg) of the residue on the filter after drying and the mass B (mg) of the pesticide precursor contained in 1 mL of the pesticide emulsified composition, the crystal precipitation rate was calculated by the following formula. Crystal precipitation rate (%)=A/B×100 The results are shown in Table 2.

Figure 02_image003
Figure 02_image003

由以上之結果，瞭解到本發明之農藥乳化性組成物即使以3度硬水及19.2度硬水之任一者稀釋後，由於沉澱物量少，結晶析出率亦小，故亦可大幅改善乳化安定性。From the above results, it is understood that even if the pesticide emulsifiable composition of the present invention is diluted with either 3 degree hard water or 19.2 degree hard water, since the amount of precipitate is small, the crystal precipitation rate is also small, so the emulsion stability can be greatly improved Sex.

Claims (6)

一種農藥乳化性組成物，其係包含： (a)選自氟米塔麥(fluxametamide)、畢達本、安美速及快伏草中之至少1種的農藥活性物質、 (b)包含(b-1)包含3-甲氧基-N,N-二甲基丙醯胺之極性溶劑及(b-2)非極性溶劑之混合溶劑、以及 (c)界面活性劑。A pesticide emulsifiable composition, which includes: (a) At least one pesticide active substance selected from the group consisting of fluxametamide, Pidaben, Amethicone, and fast Fu grass, (b) a mixed solvent containing (b-1) a polar solvent containing 3-methoxy-N,N-dimethylpropylamide and (b-2) a non-polar solvent, and (c) Surfactant. 如請求項1之農藥乳化性組成物，其中，(b-2)非極性溶劑為芳香族烴。The pesticide emulsifiable composition according to claim 1, wherein (b-2) the non-polar solvent is an aromatic hydrocarbon. 如請求項1或2之農藥乳化性組成物，其中，(b-1)極性溶劑及(b-2)非極性溶劑的混合比以質量比為極性溶劑：非極性溶劑=15：85～65：35。The pesticide emulsified composition as claimed in claim 1 or 2, wherein the mixing ratio of (b-1) polar solvent and (b-2) non-polar solvent is the mass ratio of polar solvent: non-polar solvent = 15: 85 ~ 65 : 35. 如請求項1～3中任一項之農藥乳化性組成物，其中，(c)界面活性劑係包含非離子性界面活性劑。The pesticide emulsifiable composition according to any one of claims 1 to 3, wherein (c) the surfactant system contains a nonionic surfactant. 請求項4之農藥乳化性組成物，其中，前述非離子性界面活性劑係包含選自由聚氧化烯基芳基苯基醚、聚氧化烯基芳基苯基醚之福馬林縮合物、聚氧化烯基植物油及聚氧乙烯聚氧丙烯嵌段聚合物所構成之群組中之至少1種。The pesticide emulsifiable composition of claim 4, wherein the nonionic surfactant contains a formalin condensate selected from polyoxyalkylene aryl phenyl ether, polyoxyalkylene aryl phenyl ether, polyoxyalkylene At least one of the group consisting of alkenyl vegetable oil and polyoxyethylene polyoxypropylene block polymer. 如請求項4或5之農藥乳化性組成物，其中，(c)界面活性劑係進一步包含陰離子性界面活性劑。The pesticide emulsifiable composition according to claim 4 or 5, wherein (c) the surfactant system further contains an anionic surfactant.
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JP7287392B2 (en) 2023-06-06
JPWO2019230621A1 (en) 2021-06-24

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