TW201947685A - Apparatus for gaseous byproduct abatement and foreline cleaning - Google Patents

Apparatus for gaseous byproduct abatement and foreline cleaning Download PDF

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TW201947685A
TW201947685A TW108113169A TW108113169A TW201947685A TW 201947685 A TW201947685 A TW 201947685A TW 108113169 A TW108113169 A TW 108113169A TW 108113169 A TW108113169 A TW 108113169A TW 201947685 A TW201947685 A TW 201947685A
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exhaust
plasma source
remote plasma
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gas
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TWI800637B (en
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詹姆士 勒荷
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美商應用材料股份有限公司
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/68Halogens or halogen compounds
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/4401Means for minimising impurities, e.g. dust, moisture or residual gas, in the reaction chamber
    • C23C16/4405Cleaning of reactor or parts inside the reactor by using reactive gases
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/4412Details relating to the exhausts, e.g. pumps, filters, scrubbers, particle traps
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32009Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32431Constructional details of the reactor
    • H01J37/32798Further details of plasma apparatus not provided for in groups H01J37/3244 - H01J37/32788; special provisions for cleaning or maintenance of the apparatus
    • H01J37/32816Pressure
    • H01J37/32834Exhausting
    • H01J37/32844Treating effluent gases
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32431Constructional details of the reactor
    • H01J37/32798Further details of plasma apparatus not provided for in groups H01J37/3244 - H01J37/32788; special provisions for cleaning or maintenance of the apparatus
    • H01J37/32853Hygiene
    • H01J37/32862In situ cleaning of vessels and/or internal parts
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32431Constructional details of the reactor
    • H01J37/32798Further details of plasma apparatus not provided for in groups H01J37/3244 - H01J37/32788; special provisions for cleaning or maintenance of the apparatus
    • H01J37/32853Hygiene
    • H01J37/32871Means for trapping or directing unwanted particles
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67011Apparatus for manufacture or treatment
    • H01L21/67017Apparatus for fluid treatment
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67011Apparatus for manufacture or treatment
    • H01L21/67098Apparatus for thermal treatment
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67242Apparatus for monitoring, sorting or marking
    • H01L21/67253Process monitoring, e.g. flow or thickness monitoring
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67242Apparatus for monitoring, sorting or marking
    • H01L21/67276Production flow monitoring, e.g. for increasing throughput
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/46Generating plasma using applied electromagnetic fields, e.g. high frequency or microwave energy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/55Compounds of silicon, phosphorus, germanium or arsenic
    • B01D2257/553Compounds comprising hydrogen, e.g. silanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/55Compounds of silicon, phosphorus, germanium or arsenic
    • B01D2257/556Organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0216Other waste gases from CVD treatment or semi-conductor manufacturing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/30Capture or disposal of greenhouse gases of perfluorocarbons [PFC], hydrofluorocarbons [HFC] or sulfur hexafluoride [SF6]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

Embodiments disclosed herein include an abatement system and method for abating compounds produced in semiconductor processes. The abatement system includes a remote plasma source for generating an oxidizing plasma for treating exhaust gases from a deposition process performed in the processing chamber, the treatment assisting with the trapping particles in an exhaust cooling apparatus. The remote plasma source then generates a cleaning plasma for treating exhaust gases from a cleaning process performed in the processing chamber, the cleaning plasma reacting with the trapped particles in the exhaust cooling apparatus and cleaning the exhaust cooling apparatus.

Description

用於氣體副產品消除和前級管線清潔的設備Equipment for gas byproduct elimination and foreline line cleaning

本揭示的實施例通常係關於半導體處理設備。更特定而言,本揭示的實施例係關於用於移除在半導體製程期間產生的不期望化合物的消除系統及真空處理系統。Embodiments of the present disclosure relate generally to semiconductor processing equipment. More specifically, embodiments of the present disclosure relate to an elimination system and a vacuum processing system for removing undesired compounds generated during a semiconductor process.

由半導體處理設施使用的處理氣體包括歸因於規定要求及環境與安全考慮在處置之前必須消除或處理的眾多化合物,諸如TEOS、SiH4 。習知的消除技術可以導致在處理腔室下游的設備(諸如排氣管線及泵)中形成固體粒子。若未適當地控制在處理腔室下游的設備(諸如排氣管線及泵)中形成的固體粒子,則可以發生對泵送系統中的硬體的損壞。Process gases used by semiconductor processing facilities include numerous compounds such as TEOS, SiH 4 that must be eliminated or processed due to regulatory requirements and environmental and safety considerations. Conventional elimination techniques can lead to the formation of solid particles in equipment downstream of the processing chamber, such as exhaust lines and pumps. If solid particles formed in equipment downstream of the processing chamber, such as exhaust lines and pumps, are not properly controlled, damage to the hardware in the pumping system can occur.

由此,在本領域中需要用於消除在半導體製程中產生的化合物的改進的消除系統。Therefore, there is a need in the art for an improved elimination system for eliminating compounds generated in a semiconductor process.

在一實施例中,將試劑注入電漿源中以輔助化合物的消除。電漿用作改變來自腔室的化合物的組成的能源,將化合物的組成改變為不同化合物,該等化合物更好地滿足規定限制、改進安全性並且提供改進的排氣泵以及下游消除部件的壽命及維護間隔。In one embodiment, a reagent is injected into the plasma source to assist in the elimination of the compound. Plasma is used as an energy source to change the composition of the compounds from the chamber, changing the composition of the compounds to different compounds that better meet regulatory limits, improve safety, and provide improved life of the exhaust pump and downstream elimination components And maintenance intervals.

在一實施例中,提供了一種用於處理腔室的消除系統。消除系統包含:排氣系統,包括耦合到處理腔室的真空泵;排氣冷卻設備,耦合到在處理腔室與真空泵之間的排氣系統;以及遠端電漿源,具有用於將電漿供應到在處理腔室下游並且在排氣冷卻設備之前的排氣系統的出口。遠端電漿源連接到氧氣源、清潔氣體源及惰性氣體源,其中遠端電漿源的出口流體連接以在鄰近排氣冷卻設備連接到前級管線的入口的位置處進入排氣前級管線。In one embodiment, an elimination system for a processing chamber is provided. The elimination system includes: an exhaust system including a vacuum pump coupled to the processing chamber; an exhaust cooling device coupled to the exhaust system between the processing chamber and the vacuum pump; and a remote plasma source having a plasma Supply to the outlet of the exhaust system downstream of the processing chamber and before the exhaust cooling device. The remote plasma source is connected to an oxygen source, a clean gas source, and an inert gas source, wherein the outlet of the remote plasma source is fluidly connected to enter the exhaust fore stage at a position adjacent to the exhaust cooling device connected to the inlet of the foreline line. Pipeline.

在一實施例中,提供了一種處理系統。處理系統包含:處理腔室;排氣系統,包括耦合到處理腔室的真空泵;排氣冷卻設備,耦合到在處理腔室與真空泵之間的排氣系統;以及遠端電漿源,用於將電漿供應到在處理腔室下游並且在排氣冷卻設備之前的排氣系統。遠端電漿源連接到氧氣源、清潔氣體源及惰性氣體源,其中遠端電漿源的出口流體連接以在鄰近排氣冷卻設備連接到前級管線的入口的位置處進入排氣前級管線。In one embodiment, a processing system is provided. The processing system includes: a processing chamber; an exhaust system including a vacuum pump coupled to the processing chamber; an exhaust cooling device coupled to the exhaust system between the processing chamber and the vacuum pump; and a remote plasma source for The plasma is supplied to an exhaust system downstream of the processing chamber and before the exhaust cooling device. The remote plasma source is connected to an oxygen source, a clean gas source, and an inert gas source, wherein the outlet of the remote plasma source is fluidly connected to enter the exhaust front stage at a position adjacent to the exhaust cooling device connected to the inlet of the foreline Pipeline.

在一實施例中,提供了一種用於在處理腔室的排氣系統中處理氣體的方法。該方法包含:使用由遠端電漿源產生的氧化電漿處理來自在處理腔室中執行的沉積製程的排放氣體;在排氣冷卻設備中捕獲粒子;以及使用由遠端電漿源產生的清潔電漿處理來自在處理腔室中執行的清潔製程的排放氣體。清潔電漿在排氣冷卻設備中與所捕獲粒子反應並且清潔排氣冷卻設備。In one embodiment, a method for processing a gas in an exhaust system of a processing chamber is provided. The method includes: using an oxidizing plasma generated by a remote plasma source to treat exhaust gas from a deposition process performed in a processing chamber; capturing particles in an exhaust cooling device; and using a remote plasma source The cleaning plasma processes exhaust gases from a cleaning process performed in a processing chamber. The cleaning plasma reacts with the captured particles in the exhaust cooling device and cleans the exhaust cooling device.

第1圖為將遠端電漿源100併入到消除系統102中的真空處理系統170的示意性側視圖。真空處理系統170至少包括真空處理腔室190及消除系統102。消除系統102至少包括電漿源100、排氣冷卻設備117、及處理真空泵196。真空處理腔室190通常經配置以執行至少一種積體電路製造製程,諸如沉積製程、蝕刻製程、電漿處理製程、預清潔製程、離子佈植製程、及/或其他積體電路製造製程。在一些實施例中,真空處理腔室190經配置以處理基板,用於裝置製造、顯示器或太陽能應用。在真空處理腔室190中執行的製程可為電漿輔助的,諸如能夠執行電漿增強沉積製程的電漿輔助化學氣相沉積腔室。例如,在真空處理腔室190中執行的製程能夠執行用於使用含矽氣體(例如,矽烷、二矽烷)沉積矽基材料的電漿增強沉積製程或用於移除矽基材料的電漿蝕刻製程。FIG. 1 is a schematic side view of a vacuum processing system 170 incorporating a remote plasma source 100 into a removal system 102. The vacuum processing system 170 includes at least a vacuum processing chamber 190 and a removal system 102. The elimination system 102 includes at least a plasma source 100, an exhaust cooling device 117, and a processing vacuum pump 196. The vacuum processing chamber 190 is generally configured to perform at least one integrated circuit manufacturing process, such as a deposition process, an etching process, a plasma processing process, a pre-cleaning process, an ion implantation process, and / or other integrated circuit manufacturing processes. In some embodiments, the vacuum processing chamber 190 is configured to process substrates for device manufacturing, display or solar applications. The processes performed in the vacuum processing chamber 190 may be plasma assisted, such as a plasma assisted chemical vapor deposition chamber capable of performing a plasma enhanced deposition process. For example, a process performed in the vacuum processing chamber 190 can perform a plasma enhanced deposition process for depositing a silicon-based material using a silicon-containing gas (eg, silane, disilane) or a plasma etch for removing the silicon-based material. Process.

真空處理腔室190具有腔室排氣埠191,該腔室排氣埠經由排氣前級管線192耦合到消除系統102的排氣冷卻設備117。排氣冷卻設備117耦合到真空處理腔室190,以便冷卻離開電漿源100的排氣並且收集從真空處理腔室190離開的在排氣前級管線中形成的粒子,諸如二氧化矽粒子。排氣冷卻設備117耦合到排氣管道193並且耦合到處理真空泵196。排氣管道194將真空泵196耦合到燃燒/濕消除子系統198。處理真空泵196通常用於抽空真空處理腔室190,而燃燒/濕消除子系統198通常包括洗滌器或用於製備真空處理腔室190的流出物以進入大氣的其他排氣清潔設備。The vacuum processing chamber 190 has a chamber exhaust port 191, which is coupled to an exhaust cooling device 117 of the elimination system 102 via an exhaust foreline 192. The exhaust gas cooling device 117 is coupled to the vacuum processing chamber 190 so as to cool the exhaust gas leaving the plasma source 100 and collect particles formed in the exhaust gas foreline from the vacuum processing chamber 190, such as silicon dioxide particles. An exhaust cooling device 117 is coupled to the exhaust duct 193 and to the processing vacuum pump 196. Exhaust duct 194 couples a vacuum pump 196 to a combustion / humidification subsystem 198. The processing vacuum pump 196 is typically used to evacuate the vacuum processing chamber 190, while the combustion / humidification subsystem 198 typically includes a scrubber or other exhaust cleaning equipment for preparing the effluent of the vacuum processing chamber 190 to enter the atmosphere.

排氣冷卻設備117在真空處理腔室190與處理真空泵196之間耦合,用於降低在排氣前級管線192中的排氣的溫度,並且用於收集在排氣前級管線192中形成的粒子。在一實例中,排氣冷卻設備117係消除系統102的一部分。離開真空處理腔室190的排氣可在排氣冷卻設備117內部的冷表面(具有實質上低於排氣溫度的溫度的表面)上沉積。可在排氣冷卻設備中收集的材料的實例係二氧化矽。The exhaust gas cooling device 117 is coupled between the vacuum processing chamber 190 and the processing vacuum pump 196 for reducing the temperature of the exhaust gas in the exhaust foreline 192 and for collecting the exhaust gas formed in the exhaust foreline 192. particle. In one example, the exhaust cooling device 117 is part of the elimination system 102. The exhaust gas leaving the vacuum processing chamber 190 may be deposited on a cold surface (surface having a temperature substantially lower than the temperature of the exhaust gas) inside the exhaust gas cooling device 117. An example of a material that can be collected in an exhaust cooling device is silicon dioxide.

在一些實施例中,真空處理腔室190包括用於產生清潔自由基(諸如氟自由基)的遠端電漿源185,該等清潔自由基流入真空處理腔室190的處理區域189中以清潔真空處理腔室190。未反應的清潔自由基可離開真空處理腔室190並且進入排氣前級管線192及排氣冷卻設備117,從而移除先前在積體電路製造製程期間於排氣前級管線192及排氣冷卻設備117中沉積的材料。在一些實施例中,有效地執行在真空處理腔室190內執行的清潔製程,這導致最小量的未反應的清潔自由基離開真空處理腔室190並且進入排氣前級管線192。有效地清潔真空處理腔室190的清潔製程將通常不提供足夠的清潔自由基以在正常使用期間有效清潔排氣冷卻設備117。In some embodiments, the vacuum processing chamber 190 includes a remote plasma source 185 for generating clean radicals, such as fluorine radicals, which flow into the processing region 189 of the vacuum processing chamber 190 for cleaning Vacuum processing chamber 190. Unreacted clean radicals can leave the vacuum processing chamber 190 and enter the exhaust foreline 192 and exhaust cooling equipment 117, thereby removing the cooling of the exhaust foreline 192 and exhaust previously during the integrated circuit manufacturing process Material deposited in the device 117. In some embodiments, the cleaning process performed within the vacuum processing chamber 190 is effectively performed, which results in a minimal amount of unreacted cleaning free radicals leaving the vacuum processing chamber 190 and entering the exhaust foreline 192. The cleaning process that effectively cleans the vacuum processing chamber 190 will typically not provide enough cleaning radicals to effectively clean the exhaust cooling device 117 during normal use.

由此,為了確保足夠的未反應的清潔自由基到達並且有效地清潔排氣冷卻設備117,消除系統102包括遠端電漿源100,該遠端電漿源可用於提供清潔電漿以清潔排氣冷卻設備117。遠端電漿源100用於對離開真空處理腔室190的氣體及/或其他材料執行消除製程,使得此種氣體及/或其他材料可隨後被捕獲或轉化為更環保及/或處理設備友好的組成。例如,遠端電漿源可能為電感耦合電漿源、電容耦合電漿源、直流電漿源、或微波電漿源。遠端電漿源100可耦合到消除系統102,以離子化、清潔、淨化載體或其他處理氣體,並且將離子化的氣體提供到消除系統102,以及產生清潔自由基來清潔排氣冷卻設備117。例如,第一氣體供應源104可耦合到遠端電漿源100以將惰性或非反應性氣體(諸如氬(Ar))經由其中提供到消除系統102。第二氣體供應源106可耦合到遠端電漿源100以將清潔氣體(諸如NF3 )經由其中提供到消除系統102。其他預期的清潔氣體包括氟碳及/或含鹵素氣體,諸如NF2 H、CHF3 、CF4 、F2 、HCl、Cl2 及SF6 以及類似者。另外,第三氣體供應源108可耦合到遠端電漿源100以將反應性試劑(諸如O2 )經由其中提供到消除系統102。如第1圖所示,遠端電漿源100可經由管道112耦合到排氣前級管線192。反應性氣體促進從消除系統102的內部體積移除累積的沉積物,因此減少或除去對消除系統102拆卸以用於清潔的需求。在一個實施例中,在電漿源100中產生的清潔自由基(諸如NF3 電漿)可流入排氣前級管線192中並且流入排氣冷卻設備117中以移除在排氣冷卻設備117中形成或收集的固體副產物材料或粒子。Thus, in order to ensure that sufficient unreacted clean radicals reach and effectively clean the exhaust cooling device 117, the elimination system 102 includes a remote plasma source 100, which can be used to provide a clean plasma to clean the exhaust气冷 设备 117。 Gas cooling equipment 117. The remote plasma source 100 is used to perform a elimination process on the gas and / or other materials leaving the vacuum processing chamber 190, so that such gases and / or other materials can be subsequently captured or converted into more environmentally friendly and / or processing equipment friendly Composition. For example, the remote plasma source may be an inductively coupled plasma source, a capacitively coupled plasma source, a DC plasma source, or a microwave plasma source. The remote plasma source 100 may be coupled to the elimination system 102 to ionize, clean, purify a carrier or other process gas, and provide the ionized gas to the elimination system 102, and generate clean radicals to clean the exhaust cooling device 117 . For example, the first gas supply source 104 may be coupled to a remote plasma source 100 to provide an inert or non-reactive gas, such as argon (Ar), to the elimination system 102 therethrough. A second gas supply source 106 may be coupled to the remote plasma source 100 to provide a cleaning gas (such as NF 3 ) therethrough to the elimination system 102. Other contemplated cleaning gases include fluorocarbon and / or halogen-containing gases such as NF 2 H, CHF 3 , CF 4 , F 2 , HCl, Cl 2 and SF 6 and the like. Additionally, a third gas supply source 108 may be coupled to the remote plasma source 100 to provide a reactive reagent (such as O 2 ) therethrough to the elimination system 102. As shown in FIG. 1, the remote plasma source 100 may be coupled to the exhaust foreline 192 via a pipe 112. The reactive gas facilitates the removal of accumulated deposits from the internal volume of the elimination system 102, thereby reducing or removing the need for disassembly of the elimination system 102 for cleaning. In one embodiment, clean radicals (such as NF 3 plasma) generated in the plasma source 100 may flow into the exhaust foreline 192 and into the exhaust cooling device 117 to remove the exhaust cooling device 117 Solid by-product materials or particles that are formed or collected.

在一個實施例中,在遠端電漿源100中產生的氧化試劑(諸如O2 電漿)可從遠端電漿源100遞送到排氣前級管線192中以在沉積處理期間與從真空處理腔室190流到處理真空泵196的前驅物產物反應。氧化試劑與來自沉積製程的前驅物副產物反應,並且促進前驅物氣體副產物轉化為固體副產物或粒子以增強在排氣冷卻設備117中捕獲的固體副產物或粒子的量。增加在排氣冷卻設備117中捕獲的固體副產物的量減少流過排氣冷卻設備117並且流入處理真空泵196中、流過排氣管道194並且流到燃燒/濕消除子系統198的反應物副產物氣體的量,由此增加處理真空泵196及燃燒/濕消除子系統198的期望壽命,並且亦減少在維護處理真空泵196及燃燒/濕消除子系統198之間的時間,從而有助於增加工具運行時間。In one embodiment, an oxidizing agent (such as an O 2 plasma) generated in the remote plasma source 100 may be delivered from the remote plasma source 100 into the exhaust foreline 192 to communicate with the vacuum during the deposition process. The processing chamber 190 flows to the precursor product of the processing vacuum pump 196 for reaction. The oxidizing reagent reacts with precursor by-products from the deposition process and promotes the conversion of the precursor gas by-products into solid by-products or particles to enhance the amount of solid by-products or particles captured in the exhaust cooling device 117. Increasing the amount of solid by-products captured in the exhaust cooling device 117 Reduces reactant by-products flowing through the exhaust cooling device 117 and into the process vacuum pump 196, through the exhaust duct 194, and to the combustion / humidification subsystem 198 The amount of product gas, thereby increasing the expected life of the processing vacuum pump 196 and the combustion / humidification subsystem 198, and also reducing the time between maintenance processing of the vacuum pump 196 and the combustion / humidification subsystem 198, thereby helping to increase tools operation hours.

排氣冷卻設備117可在製造設施的子晶圓廠位置中位於距處理腔室190為距離DF (諸如至少10-40呎或更多)處,並且可由設施壁或地面301分開。消除系統102的遠端電漿源100的出口可在排氣前級管線中的位置195處流入排氣前級管線192中,該位置實質上鄰近排氣冷卻設備117的入口。在一個實例中,在排氣前級管線192進入排氣冷卻設備117之前,位置195位於距離DR 處,諸如在6英吋與18英吋之間或約12英吋的距離。已經發現,當將在距離DR (在6英吋與18英吋之間)處由遠端電漿源100產生的O2 電漿從到排氣冷卻設備117的入口引入排氣前級管線192中時,排氣冷卻設備117捕捉更多的固體副產物材料。The exhaust cooling device 117 may be located at a distance D F (such as at least 10-40 feet or more) from the processing chamber 190 in the sub-fab location of the manufacturing facility, and may be separated by the facility wall or floor 301. The exit of the remote plasma source 100 of the elimination system 102 may flow into the exhaust foreline 192 at a location 195 in the exhaust foreline, which is substantially adjacent to the inlet of the exhaust cooling device 117. In one example, the exhaust foreline 192 before entering the exhaust cooling apparatus 117, a position located at a distance D R at 195, such as 12 inches, or about 6 inches and a distance between 18 inches. It has been found that when the O 2 plasma generated by the remote plasma source 100 at a distance D R (between 6 inches and 18 inches) is introduced into the exhaust foreline from the inlet to the exhaust cooling device 117 At 192, exhaust cooling equipment 117 captures more solid by-product material.

排氣管道194允許氣體從處理真空泵196流到燃燒/濕消除子系統198。例如,排氣前級管線192、排氣管道193、真空泵196及排氣管道194、以及相關聯的硬體可由一或多種製程相容材料來形成,諸如鋁、陽極化鋁、鍍鎳鋁、不鏽鋼、以及其組合及合金。例如,排氣冷卻設備117可由類似的製程相容材料形成或由有助於凝結排放氣體的材料製成。燃燒/濕消除子系統198可為如在半導體製造工業中已知的燃燒/濕消除子系統。例如,消除系統102可在製造設施內與真空處理腔室190分開的位置中提供,並且與真空處理腔室190由壁或地面301分離。消除系統102與真空處理腔室分離允許在不需要為嚴格的潔淨室空氣純度分類要求的環境中維護消除系統。The exhaust duct 194 allows gas to flow from the processing vacuum pump 196 to the combustion / humidification subsystem 198. For example, exhaust foreline 192, exhaust pipe 193, vacuum pump 196 and exhaust pipe 194, and associated hardware may be formed from one or more process compatible materials, such as aluminum, anodized aluminum, nickel-plated aluminum, Stainless steel, and combinations and alloys thereof. For example, the exhaust cooling device 117 may be formed of a similar process compatible material or made of a material that helps condense the exhaust gases. The combustion / wet elimination subsystem 198 may be a combustion / wet elimination subsystem as known in the semiconductor manufacturing industry. For example, the elimination system 102 may be provided in a location separate from the vacuum processing chamber 190 within the manufacturing facility and separated from the vacuum processing chamber 190 by a wall or floor 301. The separation of the elimination system 102 from the vacuum processing chamber allows the elimination system to be maintained in environments that do not require strict clean room air purity classification requirements.

包括遠端電漿源100、第一氣體供應源104、第二氣體供應源106、第三氣體供應源108及排氣冷卻設備117的消除系統102可與控制器199連通。控制器199亦可與真空處理腔室190及處理真空泵196連通。The elimination system 102 including the remote plasma source 100, the first gas supply source 104, the second gas supply source 106, the third gas supply source 108, and the exhaust cooling device 117 may communicate with the controller 199. The controller 199 may also communicate with the vacuum processing chamber 190 and the processing vacuum pump 196.

控制器199可包括中央處理單元(CPU)199A、記憶體199B、及支援電路(或I/O)199C。CPU可為任何形式的電腦處理器中之一者,該等電腦處理器在工業設置中用於控制各種製程及硬體(例如,馬達、閥門、功率遞送部件及其他相關硬體)並且監控製程(例如,處理時間及基板定位或位置)。記憶體(未圖示)連接到CPU,並且可為容易獲得的記憶體中的一或多個,諸如隨機存取記憶體(RAM)、唯讀記憶體(ROM)、軟碟、硬碟、或任何其他形式的數位儲存(本端或遠端)。軟體指令、演算法及資料可以在記憶體內編碼及儲存用於指示CPU。支援電路(未圖示)亦連接到CPU,用於以習知方式支援處理器。支援電路可包括習知的快取記憶體、電源供應器、時鐘電路、輸入/輸出電路、子系統、以及類似者。由控制器可讀取的程式(或電腦指令)決定可由消除系統102執行哪些任務。程式可為由控制器可讀取的軟體,並且可包括用於監控及控制(例如)處理時間及消除系統製程變數及處理動作的代碼。The controller 199 may include a central processing unit (CPU) 199A, a memory 199B, and a supporting circuit (or I / O) 199C. The CPU may be one of any form of computer processor that is used in industrial settings to control various processes and hardware (eg, motors, valves, power delivery components, and other related hardware) and monitor the process (For example, processing time and substrate positioning or location). Memory (not shown) is connected to the CPU and may be one or more of easily accessible memories, such as random access memory (RAM), read-only memory (ROM), floppy disks, hard disks, Or any other form of digital storage (local or remote). Software instructions, algorithms and data can be encoded and stored in memory to instruct the CPU. A support circuit (not shown) is also connected to the CPU to support the processor in a conventional manner. Supporting circuits may include conventional cache memory, power supplies, clock circuits, input / output circuits, subsystems, and the like. Programs (or computer instructions) readable by the controller determine which tasks can be performed by the elimination system 102. The program may be software readable by a controller, and may include code for monitoring and controlling, for example, processing time and eliminating system process variables and processing actions.

在操作中,控制器199偵測在真空處理腔室190中何時發生沉積並且致使在遠端電漿源100中產生的氧化試劑將遞送到排氣前級管線192以與從真空處理腔室190流動的前驅物產品反應。控制器199亦偵測處理系統的效能何時由在排氣冷卻設備117中累積的大量粒子妨礙,並且控制器199可致使使用遠端電漿源100產生清潔電漿,將清潔電漿引導至排氣冷卻設備以與在排氣冷卻設備中沉積的粒子反應並且移除該等粒子。In operation, the controller 199 detects when deposition occurs in the vacuum processing chamber 190 and causes the oxidizing agent generated in the remote plasma source 100 to be delivered to the exhaust foreline 192 to communicate with the vacuum processing chamber 190 The reaction of the flowing precursor product. The controller 199 also detects when the performance of the processing system is hindered by the large number of particles accumulated in the exhaust cooling device 117, and the controller 199 can cause the use of a remote plasma source 100 to generate a cleaning plasma to direct the cleaning plasma to the exhaust The air cooling device reacts with particles deposited in the exhaust cooling device and removes the particles.

第2圖示出使用反應性電漿增強氣體與在排氣前級管線中流動的前驅物副產物反應、形成固體副產物以及隨後在排氣冷卻設備中捕獲固體副產物的方法。根據本揭示的某些態樣,後續的含有清潔氣體的電漿與捕獲的固體副產物反應以形成可蒸發材料。如在操作方塊202處所示,基板沉積製程係在真空處理腔室中執行,進而形成排放氣體。例如,參考第1圖,使用前驅物氣體(諸如TEOS或其他基於矽烷的前驅物)的電漿沉積製程在真空處理腔室190的處理區域189中執行以在其中設置的基板上沉積膜。製程產生包括未處理的前驅物氣體的排放氣體,該等排放氣體穿過腔室排氣埠191離開腔室,並且作為排放氣流進入排氣前級管線192。FIG. 2 illustrates a method of using a reactive plasma enhanced gas to react with precursor by-products flowing in an exhaust foreline, forming a solid by-product, and subsequently capturing the solid by-product in an exhaust cooling device. According to certain aspects of the present disclosure, a subsequent plasma containing clean gas reacts with the captured solid by-products to form an evaporable material. As shown at operation block 202, the substrate deposition process is performed in a vacuum processing chamber to form an exhaust gas. For example, referring to FIG. 1, a plasma deposition process using a precursor gas such as TEOS or other silane-based precursors is performed in a processing region 189 of a vacuum processing chamber 190 to deposit a film on a substrate disposed therein. The process generates exhaust gas including unprocessed precursor gas, the exhaust gas exits the chamber through the chamber exhaust port 191, and enters the exhaust foreline line 192 as an exhaust gas stream.

操作在操作方塊204處繼續,使用遠端電漿源100在消除系統中產生反應性電漿並且將電漿增強的反應性氣體與從處理腔室190遞送的排放氣流混合。例如,參考第1圖,在電漿沉積製程期間,使用氧的反應性電漿在遠端電漿源100中產生,從而產生氧化電漿。氧化電漿在前級管線中的位置195處(距排氣冷卻設備117在6與18英吋之間的距離)經由管道112進入排氣前級管線192。氧化電漿與在排放氣流中發現的反應性、易燃及/或易爆氣體反應,從而減少進入處理真空泵196並且進入燃燒/濕消除子系統198以及其他設施洗滌器排氣泵的進一步下游的易燃或易爆氣體的量。在一個實例中,在氧化電漿與排放氣流中的副產物氣體之間的反應促進將前驅物副產物轉化為固體副產物或粒子,例如,二氧化矽。Operation continues at operation block 204, where a remote plasma source 100 is used to generate a reactive plasma in the elimination system and mix the plasma-enhanced reactive gas with the exhaust gas stream delivered from the processing chamber 190. For example, referring to FIG. 1, during a plasma deposition process, a reactive plasma using oxygen is generated in a remote plasma source 100 to generate an oxidized plasma. The oxidation plasma enters the exhaust foreline 192 at a location 195 in the foreline (a distance between 6 and 18 inches from the exhaust cooling device 117) via the pipe 112. Oxidation plasma reacts with reactive, flammable and / or explosive gases found in the exhaust gas stream, thereby reducing entry into the process vacuum pump 196 and further downstream of the combustion / humidification subsystem 198 and scrubber exhaust pumps of other facilities The amount of flammable or explosive gas. In one example, the reaction between the oxidation plasma and a by-product gas in the exhaust gas stream promotes the conversion of precursor by-products into solid by-products or particles, such as silicon dioxide.

在操作方塊206處,操作藉由以下步驟繼續:在排氣管線的區域(例如,排氣冷卻設備117)中捕獲粒子。作為實例,(並且參看第1圖),由在前驅物副產物氣體與氧化電漿之間的反應產生的粒子在真空處理腔室190與真空泵196之間連接的排氣冷卻設備117中捕獲。產生粒子的反應減少在排放氣流中易燃或易爆氣體的量。進入泵196以及燃燒/濕消除子系統198的易燃或易爆氣體的減少量延長此等部件的壽命、減少維護間隔並且亦增加工具運行時間。At operation block 206, operation continues by capturing particles in a region of the exhaust line (eg, exhaust cooling device 117). As an example (and see FIG. 1), particles generated by the reaction between the precursor byproduct gas and the oxidation plasma are captured in an exhaust cooling device 117 connected between the vacuum processing chamber 190 and the vacuum pump 196. The particle-generating reaction reduces the amount of flammable or explosive gas in the exhaust gas stream. The reduction in the amount of flammable or explosive gases entering the pump 196 and the combustion / humidification subsystem 198 extends the life of these components, reduces maintenance intervals, and also increases tool uptime.

操作方塊208係用於在後續的腔室清潔操作方塊210之前從排氣冷卻設備移除粒子的可選清潔操作。在處理系統的效能由在排氣冷卻設備中累積的大量粒子妨礙的情況下,可執行可選操作方塊208。在操作方塊208處,清潔電漿係使用遠端電漿源100並且將清潔電漿引導至排氣前級管線192並且至排氣冷卻設備117中而在消除系統102中產生。例如,在做出在排氣冷卻設備中的粒子量正負面影響真空處理系統170的效能的決定之後,清潔電漿(諸如產生清潔自由基的氟電漿)在消除系統102內的遠端電漿源100中產生。清潔電漿經由管道112在位置195處進入排氣前級管線192,並且進入排氣冷卻設備117以及與所沉積的粒子反應且移除該等粒子。在一實例中,NF3 用作形成清潔電漿的清潔氣體。其他預期的清潔氣體包括氟碳及含鹵素氣體,諸如NF2 H、CHF3 、CF4 、F2 、HCl、Cl2 及SF6 以及類似者。The operation block 208 is an optional cleaning operation for removing particles from the exhaust cooling device before the subsequent chamber cleaning operation block 210. Where the effectiveness of the processing system is hindered by the large number of particles accumulated in the exhaust cooling equipment, optional operation block 208 may be performed. At operation block 208, the cleaning plasma is generated in the elimination system 102 using the remote plasma source 100 and directing the cleaning plasma to the exhaust foreline 192 and into the exhaust cooling device 117. For example, after a decision is made that the amount of particles in the exhaust cooling equipment positively and negatively affects the performance of the vacuum processing system 170, a clean plasma (such as a fluorine plasma that generates clean radicals) eliminates the remote electricity in the system 102. Produced in pulp source 100. The cleaning plasma enters the exhaust foreline 192 at location 195 via the pipe 112 and enters the exhaust cooling device 117 and reacts with the particles deposited and removes them. In one example, NF 3 is used as a cleaning gas to form a cleaning plasma. Other contemplated cleaning gases include fluorocarbons and halogen-containing gases such as NF 2 H, CHF 3 , CF 4 , F 2 , HCl, Cl 2 and SF 6 and the like.

操作在操作方塊210處藉由在真空處理腔室190中執行腔室清潔製程而重新開始。例如,(參見第1圖)一旦完成沉積製程或沉積製程系列,並且在處理基板之間,流體連接到真空處理腔室的遠端電漿源185產生清潔電漿,諸如產生清潔自由基的氟電漿。清潔自由基流入真空處理腔室190的處理區域189中以與從沉積製程餘留在內部腔室壁及處理腔室部件上的所沉積的材料反應並且移除該等材料。適宜的清潔氣體包括氟碳及含鹵素氣體,諸如NF3 、NF2 H、CHF3 、CF4 、F2 、HCl、Cl2 及SF6 以及類似者。包括未反應的清潔自由基的所得清潔製程排放氣體進入排氣前級管線192及消除系統102。Operation resumes at operation block 210 by performing a chamber cleaning process in the vacuum processing chamber 190. For example, (see Figure 1) Once the deposition process or series of deposition processes is completed, and between the processing substrates, a remote plasma source 185 fluidly connected to the vacuum processing chamber generates a clean plasma, such as fluorine that generates clean free radicals. Plasma. The clean radicals flow into the processing region 189 of the vacuum processing chamber 190 to react with and remove the deposited materials remaining on the internal chamber walls and the processing chamber components from the deposition process. Suitable cleaning gases include fluorocarbons and halogen-containing gases such as NF 3 , NF 2 H, CHF 3 , CF 4 , F 2 , HCl, Cl 2 and SF 6 and the like. The resulting cleaning process exhaust gas including unreacted clean radicals enters the exhaust foreline 192 and the elimination system 102.

在操作方塊212處,操作藉由以下步驟繼續:使用遠端電漿源100在消除系統102中產生清潔電漿並且將清潔電漿與由處理腔室清潔製程產生的排放氣流混合。例如,在真空處理腔室190內的腔室清潔製程期間,清潔電漿(諸如產生清潔自由基的氟電漿)在消除系統102內的遠端電漿源100中產生。清潔電漿經由管道112在位置195處進入排氣前級管線192,並且與排氣前級管線192中的排放氣體混合。清潔電漿進入排氣冷卻設備117並且與在沉積製程期間保持捕獲在排氣冷卻設備117中的所沉積的粒子材料反應且移除該等材料。所沉積的材料與產生非反應性氣體副產物的清潔電漿反應,該等氣體副產物繼續沿著排氣管道193並且進入處理真空泵196並且進入燃燒/濕消除子系統198及其他設施洗滌器排氣泵的進一步下游。在一個實例中,NF3 用作形成清潔電漿的清潔氣體。用於產生清潔電漿的適宜清潔氣體包括,但不限於,氟碳及/或含鹵素氣體,諸如NF3 、NF2 H、CHF3 、CF4 、F2 、HCl、Cl2 及SF6 以及類似者。在一個實例中,NF3 清潔電漿與所沉積粒子(諸如二氧化矽)反應,以形成非反應劑氣體SiF4 。非反應性SiF4 流過處理真空泵196並且流入燃燒/濕消除子系統中,其中SiF4 再次轉化為粒子材料(諸如二氧化矽),其中該粒子材料可以容易地從燃燒/濕子系統移除。At operation block 212, operation continues by using the remote plasma source 100 to generate a cleaning plasma in the elimination system 102 and mixing the cleaning plasma with an exhaust gas stream generated by a process chamber cleaning process. For example, during a chamber cleaning process within the vacuum processing chamber 190, a cleaning plasma, such as a fluorine plasma that generates clean radicals, is generated in the remote plasma source 100 within the elimination system 102. The cleaning plasma enters the exhaust foreline 192 at position 195 via the pipe 112 and is mixed with the exhaust gas in the exhaust foreline 192. The cleaning plasma enters the exhaust cooling device 117 and reacts with and removes the deposited particulate material that remains trapped in the exhaust cooling device 117 during the deposition process. The deposited material reacts with a clean plasma that produces non-reactive gas by-products that continue along the exhaust duct 193 and enter the processing vacuum pump 196 and into the combustion / humidification subsystem 198 and other facility scrubber rows. Further downstream of the air pump. In one example, NF 3 is used as a cleaning gas to form a cleaning plasma. Suitable cleaning gases for generating a cleaning plasma include, but are not limited to, fluorocarbon and / or halogen-containing gases such as NF 3 , NF 2 H, CHF 3 , CF 4 , F 2 , HCl, Cl 2 and SF 6 and Similar. In one example, the NF 3 cleaning plasma reacts with the deposited particles, such as silicon dioxide, to form a non-reactive gas SiF 4 . The non-reactive SiF 4 flows through the processing vacuum pump 196 and into the combustion / wet elimination subsystem, where SiF 4 is again converted into a particulate material, such as silicon dioxide, where the particulate material can be easily removed from the combustion / wet subsystem .

因此,提供了用於處理易燃或易爆副產物氣體並且防止在沉積系統的真空前級管線中堆積粒子的設備及方法。來自沉積製程的排放氣體可用反應性電漿處理以促進對反應物氣體的處理並且促進在排氣冷卻設備中捕獲的副產物粒子的產生。來自後續處理腔室清潔製程的排放氣體用使用清潔氣體(諸如NF3 )的清潔電漿處理,以與排氣冷卻設備中的副產物材料反應,從而形成非反應性SiF4 ,SiF4 流出排氣冷卻設備並且流入排放氣流中,且朝向真空泵以及其他設施消除子系統及排氣洗滌器流動。Accordingly, apparatus and methods are provided for processing flammable or explosive by-product gases and preventing the accumulation of particles in the vacuum foreline of the deposition system. The exhaust gas from the deposition process can be treated with a reactive plasma to facilitate the processing of the reactant gas and to promote the production of by-product particles captured in the exhaust cooling equipment. The exhaust gas from the cleaning process of the subsequent processing chamber is treated with a clean plasma using a clean gas (such as NF 3 ) to react with by-product materials in the exhaust cooling equipment to form non-reactive SiF 4 , and SiF 4 flows out of the exhaust The air cooling equipment flows into the exhaust air stream and flows towards the vacuum pump and other facilities to eliminate the subsystem and exhaust scrubber.

本文描述的態樣的益處包括更安全且更快地清潔排氣系統。本文描述的態樣可減少包括真空泵及燃燒/濕消除單元的消除部件的清潔時間。另外,在時間及成本防止性維護之間的持續時間可得以延長,從而改進工具運行時間以及降低維護成本。Benefits of the aspects described herein include safer and faster cleaning of the exhaust system. The aspects described herein can reduce the cleaning time of the abatement components including the vacuum pump and the combustion / wet abatement unit. In addition, the duration between time and cost preventive maintenance can be extended, improving tool uptime and reducing maintenance costs.

儘管上述內容涉及本揭示的態樣,本揭示的其他及進一步態樣可在不脫離其基本範疇的情況下設計,並且其範疇係由以下申請專利範圍決定。Although the above content relates to aspects of the present disclosure, other and further aspects of the present disclosure can be designed without departing from its basic scope, and its scope is determined by the scope of the following patent applications.

100‧‧‧遠端電漿源100‧‧‧Remote Plasma Source

102‧‧‧消除系統 102‧‧‧ Elimination system

104‧‧‧第一氣體供應源 104‧‧‧The first gas supply source

106‧‧‧第二氣體供應源 106‧‧‧Second gas supply source

108‧‧‧第三氣體供應源 108‧‧‧Third gas supply source

112‧‧‧管道 112‧‧‧pipe

117‧‧‧排氣冷卻設備 117‧‧‧Exhaust cooling equipment

170‧‧‧真空處理系統 170‧‧‧Vacuum processing system

185‧‧‧遠端電漿源 185‧‧‧Remote Plasma Source

189‧‧‧處理區域 189‧‧‧ processing area

190‧‧‧真空處理腔室 190‧‧‧Vacuum processing chamber

191‧‧‧腔室排氣埠 191‧‧‧ Chamber exhaust port

192‧‧‧排氣前級管線 192‧‧‧Exhaust Foreline

193‧‧‧排氣管道 193‧‧‧Exhaust duct

194‧‧‧排氣管道 194‧‧‧Exhaust duct

195‧‧‧位置 195‧‧‧Location

196‧‧‧處理真空泵 196‧‧‧handling vacuum pump

198‧‧‧燃燒/濕消除子系統 198‧‧‧Combustion / wet removal subsystem

199‧‧‧控制器 199‧‧‧controller

199A‧‧‧中央處理單元(CPU) 199A‧‧‧Central Processing Unit (CPU)

199B‧‧‧記憶體 199B‧‧‧Memory

199C‧‧‧支援電路(或I/O) 199C‧‧‧Support circuit (or I / O)

202‧‧‧操作方塊 202‧‧‧Operation Block

204‧‧‧操作方塊 204‧‧‧Operation Block

206‧‧‧操作方塊 206‧‧‧Operation Block

208‧‧‧操作方塊 208‧‧‧Operation Block

210‧‧‧後續腔室清潔操作方塊 210‧‧‧Subsequent chamber cleaning operation block

212‧‧‧操作方塊 212‧‧‧Operation Block

301‧‧‧地面 301‧‧‧ ground

DF、DR‧‧‧距離D F , D R ‧‧‧ Distance

為了能夠詳細理解本揭示的上述特徵所用方式,可參考實施例進行對上文簡要概述的本揭示的更特定描述,一些實施例在附圖中示出。然而,將注意,附圖僅示出本揭示的典型實施例,並且因此不被認為限制其範疇,因為本揭示可允許其他等同有效的實施例。In order to be able to understand the manner in which the above features of the present disclosure are used in detail, a more specific description of the present disclosure briefly summarized above may be made with reference to embodiments, some of which are illustrated in the accompanying drawings. It will be noted, however, that the drawings show only typical embodiments of the disclosure and are therefore not to be considered limiting of its scope, as the disclosure may allow other equally effective embodiments.

第1圖係根據本文描述的一實施例的處理腔室及包括遠端電漿源及排氣冷卻設備的消除系統的示意性圖示。FIG. 1 is a schematic illustration of a processing chamber and an elimination system including a remote plasma source and exhaust cooling equipment according to an embodiment described herein.

第2圖描繪了根據本文描述的一實施例的用於處理排放氣體的方法的流程圖。FIG. 2 depicts a flowchart of a method for processing exhaust gas according to an embodiment described herein.

Claims (20)

一種用於一處理腔室的消除系統,包含: 一排氣系統,包含耦合到該處理腔室的一真空泵;一排氣冷卻設備,耦合到在該處理腔室與該真空泵之間的該排氣系統;以及一遠端電漿源,具有用於將一電漿供應到在該處理腔室下游並且在該排氣冷卻設備之前的該排氣系統的一出口,並且該遠端電漿源連接到一氧氣源、一清潔氣體源及一惰性氣體源,其中該遠端電漿源的該出口流體連接以在鄰近到該排氣冷卻設備連接至該前級管線的一入口的位置處進入一排氣前級管線。An elimination system for a processing chamber, comprising: An exhaust system including a vacuum pump coupled to the processing chamber; an exhaust cooling device coupled to the exhaust system between the processing chamber and the vacuum pump; and a remote plasma source having a An electric plasma is supplied to an outlet of the exhaust system downstream of the processing chamber and before the exhaust cooling device, and the remote plasma source is connected to an oxygen source, a clean gas source, and an inert gas. A gas source, wherein the outlet of the remote plasma source is fluidly connected to enter an exhaust foreline at a location adjacent to an exhaust cooling device connected to an inlet of the foreline. 如請求項1所述之消除系統,進一步包含一控制器,其中該控制器致使該遠端電漿源進一步將一解離氣體供應到該排氣系統。The elimination system of claim 1, further comprising a controller, wherein the controller causes the remote plasma source to further supply a dissociated gas to the exhaust system. 如請求項1所述之消除系統,其中該清潔氣體源將NF3 、NF2 H、CHF3 或CF4 供應到該遠端電漿源。The elimination system of claim 1, wherein the clean gas source supplies NF 3 , NF 2 H, CHF 3 or CF 4 to the remote plasma source. 如請求項1所述之消除系統,其中該惰性氣體源將氬供應到該遠端電漿源。The elimination system of claim 1, wherein the inert gas source supplies argon to the remote plasma source. 如請求項1所述之消除系統,其中該遠端電漿源的該出口流體連接以在從該入口上游到該排氣冷卻設備在6英吋與18英吋之間的一位置處進入該排氣前級管線。The elimination system of claim 1, wherein the outlet of the remote plasma source is fluidly connected to enter the location upstream of the inlet to the exhaust cooling device at a location between 6 inches and 18 inches Exhaust foreline. 如請求項1所述之消除系統,其中該遠端電漿源係下列中的一者:一電感耦合電漿源、一電容耦合電漿源、一直流電漿源或一微波電漿源。The elimination system according to claim 1, wherein the remote plasma source is one of the following: an inductively coupled plasma source, a capacitively coupled plasma source, a DC plasma source, or a microwave plasma source. 如請求項1所述之消除系統,其中該遠端電漿源的該出口位於距該前級管線耦合到一腔室排氣埠的該位置至少10呎的該前級管線中。The elimination system of claim 1, wherein the outlet of the remote plasma source is located in the foreline at least 10 feet from the location where the foreline is coupled to a chamber exhaust port. 一種處理系統,包含: 一處理腔室;一排氣系統,包含耦合到該處理腔室的一真空泵;一排氣冷卻設備,耦合到在該處理腔室與該真空泵之間的該排氣系統;以及一遠端電漿源,用於將一電漿供應到在該處理腔室下游並且在該排氣冷卻設備之前的該排氣系統,該遠端電漿源連接到一氧氣源、一清潔氣體源及一惰性氣體源,其中該遠端電漿源的該出口流體連接以在鄰近到該排氣冷卻設備連接至該前級管線的一入口的位置處進入一排氣前級管線。A processing system including: A processing chamber; an exhaust system including a vacuum pump coupled to the processing chamber; an exhaust cooling device coupled to the exhaust system between the processing chamber and the vacuum pump; and a remote electrical A plasma source for supplying a plasma to the exhaust system downstream of the processing chamber and before the exhaust cooling device, the remote plasma source is connected to an oxygen source, a clean gas source, and an inert gas A gas source, wherein the outlet of the remote plasma source is fluidly connected to enter an exhaust foreline at a location adjacent to an exhaust cooling device connected to an inlet of the foreline. 如請求項8所述之處理系統,進一步包含一控制器,其中該控制器致使該遠端電漿源將一解離氣體進一步供應到該排氣系統。The processing system according to claim 8, further comprising a controller, wherein the controller causes the remote plasma source to further supply a dissociated gas to the exhaust system. 如請求項8所述之處理系統,其中該清潔氣體源將NF3 、NF2 H、CHF3 或CF4 供應到該遠端電漿源。The processing system according to claim 8, wherein the clean gas source supplies NF 3 , NF 2 H, CHF 3 or CF 4 to the remote plasma source. 如請求項8所述之處理系統,其中該遠端電漿源的該出口流體連接以在從該入口上游到該排氣冷卻設備在6英吋與18英吋之間的一位置處進入該排氣前級管線。The processing system of claim 8, wherein the outlet of the remote plasma source is fluidly connected to enter the location upstream of the inlet to the exhaust cooling device at a location between 6 inches and 18 inches Exhaust foreline. 如請求項8所述之處理系統,其中該遠端電漿源的該出口流體連接以在從該入口上游到該排氣冷卻設備在6英吋與18英吋之間的一位置處進入該排氣前級管線。The processing system of claim 8, wherein the outlet of the remote plasma source is fluidly connected to enter the location upstream of the inlet to the exhaust cooling device at a location between 6 inches and 18 inches Exhaust foreline. 如請求項8所述之處理系統,其中該遠端電漿源係下列中的一者:一電感耦合電漿源、一電容耦合電漿源、一直流電漿源或一微波電漿源。The processing system according to claim 8, wherein the remote plasma source is one of the following: an inductively coupled plasma source, a capacitively coupled plasma source, a DC plasma source, or a microwave plasma source. 如請求項8所述之處理系統,其中該遠端電漿源的該出口位於距該前級管線耦合到一腔室排氣埠的位置至少10呎的該排氣前級管線中。The processing system of claim 8, wherein the outlet of the remote plasma source is located in the exhaust foreline at least 10 feet from a location where the foreline is coupled to a chamber exhaust port. 一種系統,包含一控制器,其中該控制器包含一中央處理單元及一記憶體,並且該記憶體進一步包括當由該中央處理單元執行時致使執行該等以下操作的軟體: 使用由一遠端電漿源產生的一氧化電漿處理來自在該處理系統的一處理腔室中執行的一沉積製程的排放氣體,其中該氧化電漿包含一氧化氣體;以及使用由該遠端電漿源產生的一清潔電漿處理來自在該處理系統的該處理腔室中執行的一清潔製程的排放氣體,其中該清潔電漿包含一清潔氣體。A system includes a controller, wherein the controller includes a central processing unit and a memory, and the memory further includes software that, when executed by the central processing unit, causes the following operations to be performed: Using an oxidation plasma generated by a remote plasma source to treat exhaust gases from a deposition process performed in a processing chamber of the processing system, wherein the oxidation plasma includes an oxidation gas; and using the remote plasma source; A clean plasma generated by the end-plasma source processes exhaust gas from a cleaning process performed in the processing chamber of the processing system, wherein the clean plasma includes a clean gas. 一種用於在一處理腔室的一排氣系統中處理氣體的方法,該方法包含以下步驟: 使用從一遠端電漿源產生的一氧化電漿處理來自在該處理腔室中執行的一沉積製程的排放氣體;捕獲一排氣冷卻設備中的粒子;以及使用由一遠端電漿源產生的一清潔電漿處理來自在該處理腔室中執行的一清潔製程的排放氣體,該清潔電漿與該排氣冷卻設備中的該等捕獲粒子反應並且清潔該排氣冷卻設備。A method for processing a gas in an exhaust system of a processing chamber, the method comprising the following steps: Using an oxidation plasma generated from a remote plasma source to treat exhaust gas from a deposition process performed in the processing chamber; capturing particles in an exhaust cooling device; and using a remote plasma source A generated cleaning plasma processes the exhaust gas from a cleaning process performed in the processing chamber, the cleaning plasma reacts with the trapped particles in the exhaust cooling equipment and cleans the exhaust cooling equipment. 如請求項16所述之方法,其中該遠端電漿源流體耦合到一清潔氣體源,該清潔氣體源將NF3 、NF2 H、CHF3 或CF4 供應到該遠端電漿源。The method of claim 16, wherein the remote plasma source is fluidly coupled to a clean gas source that supplies NF 3 , NF 2 H, CHF 3 or CF 4 to the remote plasma source. 如請求項16所述之方法,其中該遠端電漿源流體連接以在從一前級管線入口上游到該排氣冷卻設備在6與18英吋之間的一位置處進入一排氣前級管線。The method of claim 16, wherein the remote plasma source is fluidly connected to enter an exhaust gas from upstream of a foreline line inlet to the exhaust cooling device at a location between 6 and 18 inches Stage pipeline. 如請求項16所述之方法,其中該遠端電漿源流體連接以在距該排氣前級管線耦合到一腔室排氣埠的該位置至少10呎的一位置處進入一排氣前級管線。The method of claim 16, wherein the remote plasma source is fluidly connected to enter an exhaust at a location at least 10 feet from the location where the exhaust foreline is coupled to a chamber exhaust port. Stage pipeline. 如請求項16所述之方法,其中該沉積製程係一TEOS製程。The method of claim 16, wherein the deposition process is a TEOS process.
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