TW201932024A - A cream composition comprising allulose - Google Patents

A cream composition comprising allulose Download PDF

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TW201932024A
TW201932024A TW107138795A TW107138795A TW201932024A TW 201932024 A TW201932024 A TW 201932024A TW 107138795 A TW107138795 A TW 107138795A TW 107138795 A TW107138795 A TW 107138795A TW 201932024 A TW201932024 A TW 201932024A
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emulsifiable concentrate
parts
weight
concentrate composition
psicose
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TW107138795A
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TWI698188B (en
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金元哲
崔鍾珉
朱恩英
金澈進
鄭東澈
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南韓商Cj第一製糖股份有限公司
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C13/00Cream; Cream preparations; Making thereof
    • A23C13/12Cream preparations
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2200/00Function of food ingredients
    • A23V2200/12Replacer
    • A23V2200/132Sugar replacer
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2250/00Food ingredients
    • A23V2250/60Sugars, e.g. mono-, di-, tri-, tetra-saccharides
    • A23V2250/606Fructose
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2250/00Food ingredients
    • A23V2250/60Sugars, e.g. mono-, di-, tri-, tetra-saccharides
    • A23V2250/628Saccharose, sucrose

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Dairy Products (AREA)
  • Grain Derivatives (AREA)
  • Confectionery (AREA)
  • Cosmetics (AREA)
  • Medicinal Preparation (AREA)

Abstract

The present disclosure relates to a cream composition including allulose and a preparation method thereof.

Description

包含阿洛酮糖的乳油組成物 Emulsion composition containing psicose

本發明是關於包含植物性油脂及阿洛酮糖的乳油組成物,包含混合及打發植物性油脂及阿洛酮糖的製程的乳油製造方法,及抑制在乳油產生裂紋的方法,該抑製方法包含混合植物性油脂及阿洛酮糖的製程而製造乳油。(本文中的乳油係指cream) The present invention relates to an emulsifiable concentrate composition comprising vegetable oils and fats and psicose, a method for producing an emulsifiable concentrate comprising a process for mixing and emitting vegetable oils and fats and psicose, and a method for suppressing cracking in emulsifiable concentrate, the method comprising the inhibition comprising The process of mixing vegetable oils and psicose to produce emulsifiable concentrates. (The cream in this article refers to cream)

將植物油類或動物脂肪為原料而加工製得的乳油為廣泛在糕餅及焙烤食品領域中被利用,例如:糕餅、餅乾、麵包、蛋糕等。由於最近的食品飲料工業的發展,乳油被利用於例如醬汁、湯類、布丁、冰淇淋等的食品,及例如咖啡、優酪乳等的液體飲料。 Emulsifiable oils obtained by processing vegetable oils or animal fats as raw materials are widely used in the field of cakes and baked goods, such as cakes, biscuits, breads, cakes and the like. Due to the recent development of the food and beverage industry, emulsifiable concentrates are used for foods such as sauces, soups, puddings, ice creams, and the like, and liquid beverages such as coffee, yogurt, and the like.

這些乳油包含發泡乳油(whipped cream)、酸乳油(sauer cream)、卡士達糊(custard cream)、奶油淇淋(butter cream)等。視應用乳油的產品而考慮硬度、附著性、可鋪展性、水分含量、形狀等,選用合適的乳油為重要。例如,要用於調配糕餅及焙烤過程或改善食品的香味,則需要使用油中水乳液(water-in-oil emulsion)型人造奶油(magarine),其係在食用油脂添加水及乳化劑而製造。因為人造奶油含有大量的動物性脂肪酸,所以開發作為高熱量奶油的代替品。另舉一例,酥油(shortening),係 作為豬油及牛脂的代替品,在焙烤過程中用於對糕餅或麵包賦予脆酥質地。酥油是,將食用油脂迅速冷卻並拌合而成為固相或液相產品,特徵是只有食用油脂,或由食用油脂及無水添加物所組成。這種人造奶油或酥油是二次加工油脂,其係將食用油脂做為原料加工而成為具有適合於使用目的之性質及形狀,可用於添加或掺入於糕餅製造過程中。 These emulsifiable concentrates include whipped cream, sauer cream, custard cream, butter cream and the like. It is important to select a suitable emulsifiable concentrate depending on the hardness, adhesion, spreadability, moisture content, shape, etc. of the product to which the emulsifiable concentrate is applied. For example, in order to prepare a cake and baking process or to improve the flavor of a food, it is necessary to use a water-in-oil emulsion type magarine which is produced by adding water and an emulsifier to edible fats and oils. . Because margarine contains a large amount of animal fatty acids, it has been developed as a substitute for high-calorie cream. Another example is shortening, As a substitute for lard and tallow, it is used to impart crispy texture to cakes or breads during baking. The ghee is a product that is rapidly cooled and mixed to form a solid or liquid product, characterized by only edible fats or oils and anhydrous additives. Such margarine or ghee is a secondary processed fat which is processed as a raw material and has properties and shapes suitable for the purpose of use, and can be used for addition or incorporation into a pastry manufacturing process.

同時,脂肪含量10%(w/w)至35%(w/w)的植物性發泡乳油在使其發泡後,可用於糕餅及焙烤食品以及各種點心,例如乳油泡芙,及液狀飲料,例如咖啡或茶。植物性發泡乳油是二次加工的油脂,其係與人造奶油及酥油在乳液型及使用目的上有不同。這種發泡乳油是由新鮮乳油、食用油脂、水,及添加物例如乳化劑、增稠劑、防腐劑等所組成,並最近作為新鮮乳油的代替品而受注意,因為由於其水中油型態(oil-in-water),發泡乳油適合於在蛋糕加糖霜(icing)或蛋糕的精緻裝飾並可用於飲料。 At the same time, the vegetable foaming emulsifiable concentrate with a fat content of 10% (w/w) to 35% (w/w) can be used for cakes and baked goods, as well as various snacks, such as emulsifiable puffs, and liquid after foaming. A drink, such as coffee or tea. The vegetable foaming emulsifiable concentrate is a secondary processed fat which differs from the margarine and ghee in the emulsion type and the purpose of use. This foamed emulsifiable concentrate is composed of fresh emulsifiable concentrate, edible fats and oils, water, and additives such as emulsifiers, thickeners, preservatives, etc., and has recently received attention as a substitute for fresh emulsifiable concentrates because of its oily type in water. Oil-in-water, foamed emulsifiable concentrate is suitable for the delicate decoration of cakes or icing or cakes and can be used for beverages.

如上述,由於發泡乳油與高脂肪人造奶油或酥油製造的乳油在例如水分含量、質地、附著性(tackiness)、硬度等的性質上有很大的差異,為了要改善乳油的口味、可加工性、及儲藏安定性需要考慮發泡乳油的特性。 As described above, since the emulsifiable concentrate of the foamed emulsifiable concentrate and the high-fat margarine or ghee differs greatly in properties such as moisture content, texture, tackiness, hardness, etc., in order to improve the taste of the emulsifiable concentrate, it can be processed. Sex, and storage stability need to consider the characteristics of foamed emulsifiable concentrates.

通常,發泡乳油含有植物性油脂,及牛奶脂肪所成的新鮮乳油為主要成分。在這些主要成分之外,添加乳化劑、增稠劑、糖類、香料等並加工成為液態形狀,再將該液態混合物在冷藏溫度打發成為發泡乳油。這時,微細泡沫會聚集而增加發泡乳油容積,並將此性質用於裝飾、加糖霜、撒砂糖(sanding)、或填充蛋糕或麵包,特別是,液體飲料例如咖啡。 In general, foamed emulsifiable concentrates contain vegetable oils and fats, and fresh emulsifiable concentrates made from milk fat are the main components. In addition to these main components, an emulsifier, a thickener, a saccharide, a perfume, and the like are added and processed into a liquid shape, and the liquid mixture is then subjected to a refrigerating temperature to become a foaming emulsifiable concentrate. At this time, the fine foam gathers to increase the volume of the foamed emulsifiable concentrate, and this property is used for decoration, icing, sanding, or filling of a cake or bread, in particular, a liquid beverage such as coffee.

但是,當將發泡乳油長期儲存於冰箱或曝露於室溫或高溫,會產生脂肪球的再結晶而改變脂肪結晶,結果,發泡乳油的品質惡化而產品硬化或凝乳。因此,形狀維持例如裝飾、加糖霜等及可加工性惡化,生成裂紋而減低商品價值。 However, when the foamed emulsifiable concentrate is stored in a refrigerator for a long period of time or exposed to room temperature or high temperature, recrystallization of the fat globule is caused to change the fat crystallization, and as a result, the quality of the foamed emulsifiable concentrate is deteriorated and the product is hardened or cured. Therefore, the shape is maintained, for example, decoration, icing, etc., and workability is deteriorated, and cracks are generated to reduce the commercial value.

有一件先前技術,韓國專利公開10-0334735號揭示一種發泡乳油組成物,該組成物係具有低脂肪含量、抗酸性、及抗冰凍性,以及前述發泡乳油組成物的製造方法;但是,乳油組成物在打發之前有安定性減低的問題,這是因為基本上含有酪蛋白及乳清蛋白。另一有關連的先前技術,韓國專利公開10-1695832號提供“包含阿洛酮糖的焙烤食品及糕餅用乳油組成物“建議一種焙烤食品及糕餅用乳油的可加工性的改善方法。但是,所製成的乳油組成物的脂肪含量非常高,達55%(w/w),而其應用只限於卡士達糊、奶油乳油(butter creams)等。因此,乳油組成物限於焙烤食品及糕餅的使用上有差異。同樣,有介紹低脂肪人造奶油產品,其中在實現乳油的口味及質地下減低人造奶油產品的脂肪含量而減低熱量。但是,依據”食用油脂產品的知識(Song Jong-yeon著,Jinro出版公司,2014)”,低脂肪人造奶油(塗脂)通常脂肪含量為40%(w/w)至60%(w/w),與本發明的脂肪含量10%(w/w)至35%(w/w)的發泡乳油大不相同。 There is a prior art, Korean Patent Publication No. 10-0334735 discloses a foaming emulsifiable oil composition having a low fat content, acid resistance, and freeze resistance, and a method for producing the aforementioned foaming emulsifiable oil composition; The cream composition has a problem of reduced stability before it is administered because it basically contains casein and whey protein. Another related prior art, Korean Patent Publication No. 10-1695832, provides a "baked food containing psicose and a cream composition for cakes", suggesting a method for improving the workability of a baked food and a cream for cake. However, the resulting emulsifiable concentrate composition has a very high fat content of up to 55% (w/w), and its application is limited to only custard paste, butter creams and the like. Therefore, the composition of the cream is limited to the use of baked goods and cakes. Similarly, there are introduced low-fat margarine products in which the taste and quality of the cream are reduced to reduce the fat content of the margarine product and reduce the calories. However, based on the knowledge of edible fat products (Song Jong-yeon, Jinro Publishing Co., 2014), low-fat margarine (fat-coated) usually has a fat content of 40% (w/w) to 60% (w/w). It is quite different from the foaming emulsifiable concentrate of the present invention having a fat content of 10% (w/w) to 35% (w/w).

本發明者等為解決上述問題而精心研究,結果發現:以阿洛酮糖代替乳油或發泡乳油的主要成分之果糖及蔗糖,則在蛋糕製造上使用 乳油或發泡乳油的加糖霜工作可以更容易,可以減低蛋糕儲藏中的裂紋的生成,及乳油組成物應用於飲料時可以呈現優異的溶解性,而完成本發明。 The inventors of the present invention have carefully studied to solve the above problems, and have found that the use of aldose to replace fructose and sucrose, which are the main components of emulsifiable concentrates or foaming emulsifiable concentrates, is used in the manufacture of cakes. The icing operation of the emulsifiable concentrate or the foamed emulsifiable concentrate can be made easier, the crack formation in the cake storage can be reduced, and the emulsifiable concentrate composition can exhibit excellent solubility when applied to a beverage, and the present invention has been completed.

本發明提供一種含有植物性油脂及阿洛酮糖的乳油組成物。 The present invention provides an emulsifiable concentrate composition comprising vegetable oils and fats and psicose.

本發明提供一種乳油製造方法,其係包含混合及打發植物性油脂及阿洛酮糖的製程。 The invention provides a method for producing an emulsifiable concentrate, which comprises a process for mixing and spraying vegetable oils and oleose.

本發明提供一種抑制在乳油產生裂紋的方法,其係包含混合植物性油脂及阿洛酮糖而製造乳油的製程。 The present invention provides a method for inhibiting cracking in emulsifiable concentrate, which comprises a process for producing emulsifiable concentrate by mixing vegetable oils and fats and psicose.

由於本發明的乳油組成物在阿洛酮糖之外可含有蔗糖及/或果糖及/或葡萄糖,因而具有改善超多(over-run(含量過多,發泡過度,後面有說明))性質的有利效果,對加糖霜或裝飾工作上的可加工性有優異的物理性狀,在冰冷(refrigerated)後的裂紋生成也可減少。再者,由於阿洛酮的添加,本發明的乳油組成物可增進微生物安定性及顯著的減低植物性油脂,而製備低熱量乳油。 Since the cream composition of the present invention may contain sucrose and/or fructose and/or glucose in addition to psicose, it has an improved over-run property. The advantageous effect is that it has excellent physical properties for the processing property of the icing sugar or the decoration work, and the crack generation after the refrigerating can also be reduced. Furthermore, due to the addition of naloxone, the emulsifiable concentrate composition of the present invention can improve microbial stability and significantly reduce vegetable oils, thereby preparing low-calorie emulsifiable concentrates.

第1圖是表示乳油組成物的生成裂紋的照片。 Fig. 1 is a photograph showing the formation crack of the cream composition.

[最佳實施方式] [Best implementation]

茲將本發明詳細說明如下。一方面,在這裡揭示的說明及實施例也可以應用於其他說明及實施例。換言之,在這裡揭示的各種要素的組合都包含在本發明的範圍內。再者,本發明的範圍不限定於下面所述的特定實施例。 The invention will be described in detail below. In one aspect, the descriptions and embodiments disclosed herein may be applied to other descriptions and embodiments. In other words, combinations of the various elements disclosed herein are included within the scope of the invention. Further, the scope of the invention is not limited to the specific embodiments described below.

在本發明的一種態樣是提供一種含有植物性油脂及阿洛酮糖的乳油組成物。 In one aspect of the invention, an emulsifiable concentrate composition comprising vegetable oils and psicose is provided.

這裡所用的術語“乳油”係指處理植物油類或動物脂肪為原料而得的產品。乳油係包括發泡乳油、酸乳油、卡士達糊、奶油淇淋等,但只要呈現本發明的組成及效果則包括任何乳油。在乳油中,發泡乳油係指將乳油在低溫攪拌生成泡沫狀的二次加工而得者而言。發泡乳油是新鮮乳油的另選,其係由新鮮乳油、食用油脂、水、及添加物例如乳化劑、增稠劑、防腐劑等組成。發泡乳油為水中油型乳液狀而主要用於糕餅、焙烤食品、及飲料(咖啡)的加工。 The term "emulsifier" as used herein refers to a product obtained by treating vegetable oils or animal fats as raw materials. The emulsifiable concentrate includes foaming emulsifiable concentrate, yoghurt oil, cassava paste, cream cream, and the like, but includes any emulsifiable concentrate as long as the composition and effects of the present invention are exhibited. In the emulsifiable concentrate, the foamed emulsifiable concentrate refers to a secondary process in which the emulsifiable concentrate is stirred at a low temperature to form a foam. Foamed emulsifiable concentrates are an alternative to fresh emulsifiable concentrates, which are composed of fresh emulsifiable concentrates, edible fats and oils, water, and additives such as emulsifiers, thickeners, preservatives, and the like. The foaming emulsifiable concentrate is an oily emulsion in water and is mainly used for the processing of cakes, baked goods, and beverages (coffee).

如本文中所用,術語”乳油組成物“係指成為液態狀的產品而言。在本文中,乳油組成物以成為液態狀提供時,該乳油組成物在糕餅裝飾、焙烤食品,尤其是飲料可提供優異的可加工性,而在食用時可能更有利於感覺到濃郁的乳油香味。再者,與固狀形態相比,儲存乳油的容器可以是多樣的,因而乳油可以更適合於加糖霜或裝飾用途。 As used herein, the term "cream composition" refers to a product that becomes liquid. In the present context, when the cream composition is provided in a liquid form, the cream composition provides excellent processability in pastry decoration, baked goods, especially beverages, and may be more beneficial to feel a rich creamy flavor when consumed. . Furthermore, the container for storing the cream can be varied compared to the solid form, so that the cream can be more suitable for icing or decorative purposes.

如本文中所用,術語“食用油脂(edible oil and fat)”係指將粗油脂製造加工成為可食用者而言,其中作為原料的粗油脂係取之於含油的植物(包括粉碎的粉末)或動物。食用油脂視其原料可以分為植物性油脂及動物性油脂。 As used herein, the term "edible oil and fat" refers to the manufacture of crude oils into edible foods, wherein the crude oil as a raw material is taken from oily plants (including pulverized powder) or animal. Edible oils and fats can be divided into vegetable oils and animal fats depending on their raw materials.

植物性油脂的特定例可包含大豆油、玉米油、菜籽油、米糠油、芝麻油、紫蘇油、紅花籽油、向日葵油、棉籽油、花生油、橄欖油、棕櫚油、椰子油、調和烹飪油、或硬化油、分餾油、及該等的酯化油等、但不限定於這些。 Specific examples of vegetable oils and fats may include soybean oil, corn oil, rapeseed oil, rice bran oil, sesame oil, perilla oil, safflower seed oil, sunflower oil, cottonseed oil, peanut oil, olive oil, palm oil, coconut oil, blended cooking oil Or, but not limited to, hardened oil, fractionated oil, and such esterified oil.

當植物性油脂添加於乳油時,可使乳油維持形狀並賦予堅果味。但是,添加過量時,乳油有容易硬化、熱量增高、口味及消化性減低,以及在嚐味時會殘留於口內而減低清爽及清淨味的問題。在本發明中,植物性油脂的使用量為可維持形成適當的乳油的範圍內的極少量,以提供有優異的可加工性及低熱量的乳油組成物。 When vegetable oils are added to the cream, the cream can be maintained in shape and imparted a nutty taste. However, when the amount is excessively added, the emulsifiable concentrate is easily hardened, the calorie is increased, the taste and digestibility are reduced, and the taste remains in the mouth during taste, thereby reducing the problem of refreshing and clear taste. In the present invention, the amount of vegetable oil and fat used is a very small amount in a range in which an appropriate emulsifiable concentrate can be maintained to provide an emulsifiable concentrate composition having excellent workability and low heat.

在本發明中,相對於乳油組成物的100重量份,植物性油脂的含有量可以在5至40重量份,5至35重量份,5至30重量份,10至35重量份,10至30重量份,15至35重量份,15至30重量份,20至30重量份,20至25重量份,或23至24重量份,但不限定於這些。本發明的乳油組成物可有用於更減少油脂含量的應用,與相對於乳油總量100重量份,含有脂肪40至60重量份的低脂人造奶油比較,或與相對於乳油組成物總量100重量份,含有脂肪55重量份的已知的乳油組成物比較,本發明的乳油組成物由於更減低脂肪含量,而有利於對減低熱量、有優異口感及質地的乳油的製造上的應用。 In the present invention, the vegetable oil and fat may be contained in an amount of 5 to 40 parts by weight, 5 to 35 parts by weight, 5 to 30 parts by weight, 10 to 35 parts by weight, 10 to 30 parts by weight based on 100 parts by weight of the cream composition. Parts by weight, 15 to 35 parts by weight, 15 to 30 parts by weight, 20 to 30 parts by weight, 20 to 25 parts by weight, or 23 to 24 parts by weight, but are not limited thereto. The emulsifiable concentrate composition of the present invention may have an application for further reducing the fat content, compared with 100 parts by weight of the total amount of the emulsifiable concentrate, 40 to 60 parts by weight of the fat-containing low-fat margarine, or 100% relative to the total amount of the emulsifiable concentrate composition. In comparison with the known cream composition containing 55 parts by weight of fat, the cream composition of the present invention is advantageous for the manufacture of an emulsifiable concentrate which has reduced heat, has excellent mouthfeel and texture because of lower fat content.

如本文中所用,阿洛酮糖(allulose)是一種糖類,其係具有化學式C6H12O6及分子量180.16,並已知在無花果、葡萄等有少量存在,也稱為假果糖(psicose)。阿洛酮糖包含D-阿洛酮糖及L-阿洛酮糖。阿洛酮 糖可以從商場購買而使用,或可使用化學方法或微生物方法製造的阿洛酮糖。 As used herein, allulose is a saccharide having the chemical formula C 6 H 12 O 6 and a molecular weight of 180.16, and is known to have a small amount in figs, grapes, etc., also known as pseudo-fructose (psicose). . The psicose contains D-psicose and L-psicose. The psicose can be purchased from a store or used, or can be produced by chemical or microbiological methods.

乳油組成物可以含有適當量的阿洛酮糖,具體而言,相對於乳油總量100重量份,含量在5至50重量份,5至40重量份,5至30重量份,5至20重量份,5至10重量份,10至50重量份,10至40重量份,10至30重量份,10至20重量份,20至50重量份,20至40重量份,20至35重量份,20至30重量份,25至50重量份,25至40重量份,25至35重量份,25至30重量份,或30重量份,但不限定於這些。 The cream composition may contain an appropriate amount of psicose, specifically, 5 to 50 parts by weight, 5 to 40 parts by weight, 5 to 30 parts by weight, and 5 to 20 parts by weight based on 100 parts by weight of the total amount of the cream. Parts, 5 to 10 parts by weight, 10 to 50 parts by weight, 10 to 40 parts by weight, 10 to 30 parts by weight, 10 to 20 parts by weight, 20 to 50 parts by weight, 20 to 40 parts by weight, 20 to 35 parts by weight, 20 to 30 parts by weight, 25 to 50 parts by weight, 25 to 40 parts by weight, 25 to 35 parts by weight, 25 to 30 parts by weight, or 30 parts by weight, but are not limited thereto.

本發明的乳油組成物在阿洛酮糖之外可以再含有或不含醣類。醣類可以是由果糖、葡萄糖、及/或蔗糖選出一種或更多種。 The cream composition of the present invention may or may not contain a saccharide in addition to psicose. The saccharide may be one or more selected from fructose, glucose, and/or sucrose.

當本發明的乳油組成物可以再含有果糖及/或蔗糖時,果糖及/或蔗糖及阿洛酮糖可以相對於乳油總量100重量份,含有5至50重量份,5至40重量份,5至30重量份,5至20重量份,5至10重量份,10至50重量份,10至40重量份,10至30重量份,10至20重量份,20至50重量份,20至40重量份,20至35重量份,20至30重量份,25至50重量份,25至40重量份,25至35重量份,25至30重量份,或30重量份,但不限定於這些。 When the emulsifiable concentrate composition of the present invention may further contain fructose and/or sucrose, fructose and/or sucrose and psicose may be contained in an amount of 5 to 50 parts by weight, 5 to 40 parts by weight, based on 100 parts by weight of the total amount of the emulsifiable concentrate. 5 to 30 parts by weight, 5 to 20 parts by weight, 5 to 10 parts by weight, 10 to 50 parts by weight, 10 to 40 parts by weight, 10 to 30 parts by weight, 10 to 20 parts by weight, 20 to 50 parts by weight, 20 to 40 parts by weight, 20 to 35 parts by weight, 20 to 30 parts by weight, 25 to 50 parts by weight, 25 to 40 parts by weight, 25 to 35 parts by weight, 25 to 30 parts by weight, or 30 parts by weight, but not limited to these .

當本發明的乳油組成物可以再含有果糖、葡萄糖、及/或蔗糖時,相對於乳油總量100重量份,可以含有果糖、葡萄糖、及/或蔗糖及阿洛酮糖5至50重量份,5至40重量份,5至30重量份,5至20重量份,5至10重量份,10至50重量份,10至40重量份,10至30重量份,10至20重量份,20至50重量份,20至40重量份,20至35重量份,20至 30重量份,25至50重量份,25至40重量份,25至35重量份,25至30重量份,或30重量份,但不限定於這些。 When the emulsifiable concentrate composition of the present invention may further contain fructose, glucose, and/or sucrose, it may contain 5 to 50 parts by weight of fructose, glucose, and/or sucrose and psicose with respect to 100 parts by weight of the total amount of the emulsifiable concentrate. 5 to 40 parts by weight, 5 to 30 parts by weight, 5 to 20 parts by weight, 5 to 10 parts by weight, 10 to 50 parts by weight, 10 to 40 parts by weight, 10 to 30 parts by weight, 10 to 20 parts by weight, 20 to 50 parts by weight, 20 to 40 parts by weight, 20 to 35 parts by weight, 20 to 30 parts by weight, 25 to 50 parts by weight, 25 to 40 parts by weight, 25 to 35 parts by weight, 25 to 30 parts by weight, or 30 parts by weight, but are not limited thereto.

當本發明的乳油組成物可以再含有果糖及/或蔗糖時,可以以混合比1:0.5至1:5,更特別是,以混合比1:1.1至1:5包含果糖及/或蔗糖的醣類、及阿洛酮糖,但不限定於這些。 When the emulsifiable concentrate composition of the present invention may further contain fructose and/or sucrose, fructose and/or sucrose may be contained in a mixing ratio of 1:0.5 to 1:5, more specifically, in a mixing ratio of 1:1.1 to 1:5. Sugars, and psicose, but are not limited to these.

當本發明的乳油組成物可以再含有果糖、葡萄糖、及/或蔗糖時,可以以混合比1:0.5至1:2,更具體而言,可以以混合比1:1至1:2包含果糖、葡萄糖、及/或蔗糖的醣類及阿洛酮糖,但不限定於這些。 When the cream composition of the present invention may further contain fructose, glucose, and/or sucrose, the ratio may be 1:0.5 to 1:2, and more specifically, the fructose may be contained at a mixing ratio of 1:1 to 1:2. Glucose, and/or sucrose saccharides and psicose, but are not limited thereto.

本發明的乳油組成物可以不含果糖、葡萄糖、及/或蔗糖。 The cream composition of the present invention may be free of fructose, glucose, and/or sucrose.

本發明確認當單獨使用阿洛酮糖時,或混合果糖、葡萄糖、及/或蔗糖及阿洛酮糖而使用時,可以改善乳油的物理性質,可以減少加糖霜後的裂紋生成。 The present invention confirms that when psicose is used alone, or when fructose, glucose, and/or sucrose and psicose are mixed, the physical properties of the emulsifiable concentrate can be improved, and crack formation after icing can be reduced.

本發明的乳油組成物或由其製造的乳油可以有改善的黏度。黏度係指物體的黏力的大小而言。當物體有較低的黏度時,其流動性較高並更接近於液相。當物體有較高的黏度時,具有較低流動性並較接近於固相。由於使用本發明的乳油組成物製造的乳油有較低的植物性油脂含量,因而比已知乳油有較低的黏度,而具有液相。使用本發明的乳油組成物製造的乳油的黏度值是將試料密實接觸於探頭(probe)(40mm平行盤)並將探頭在冰箱溫度或7℃以10s-1的剪率(剪切速率(shear rate)旋轉一分鐘的時點測定。代表性的黏度值可以是0.01Pa.s至0.1Pa.s,更具體而言是0.02Pa.s至0.06Pa.s,但不限定於這些。 The emulsifiable concentrate composition of the present invention or the emulsifiable concentrate produced therefrom may have an improved viscosity. Viscosity is the size of the object's viscosity. When the object has a lower viscosity, its fluidity is higher and closer to the liquid phase. When the object has a higher viscosity, it has a lower fluidity and is closer to the solid phase. Since the emulsifiable concentrate produced using the emulsifiable concentrate composition of the present invention has a lower vegetable oil content, it has a lower viscosity than the known emulsifiable concentrate and has a liquid phase. The viscosity of the emulsifiable concentrate produced using the emulsifiable concentrate composition of the present invention is that the sample is densely contacted with a probe (40 mm parallel disk) and the probe is at a refrigerator temperature or 7 ° C at a shear rate of 10 s -1 (shear rate (shear The rate of rotation is one minute. The representative viscosity value may be from 0.01 Pa.s to 0.1 Pa.s, more specifically from 0.02 Pa.s to 0.06 Pa.s, but is not limited thereto.

本發明的乳油組成物或由其製造的乳油可以有改善的超多值(over-run value)。超多(over-run)係指相對於初始值的打發後的體積膨脹度而言。較高的超多值表示較高的乳油體積膨脹度,對可加工性有利。由本發明的乳油組成物製造的乳油可以有超多值具體而言在190%至250%,更具體而言在200%至240%,但不限定於這些。再者,由本發明的乳油組成物製造的乳油相對於由只含醣類是蔗糖的乳油組成物製造的乳油,可以有相對超多值在1.05至1.5,更具體而言在1.1至1.4,再更具體而言是在1.1至1.3,但不限定於這些。 The cream composition of the present invention or the cream produced therefrom may have an improved over-run value. Over-run refers to the volumetric expansion after firing relative to the initial value. A higher super multi-value indicates a higher emulsion volume expansion, which is advantageous for workability. The emulsifiable concentrate produced from the emulsifiable concentrate composition of the present invention may have an ultra-multiple value of specifically from 190% to 250%, more specifically from 200% to 240%, but is not limited thereto. Further, the emulsifiable concentrate produced from the emulsifiable concentrate composition of the present invention may have a relative supermultiple value of from 1.05 to 1.5, more specifically from 1.1 to 1.4, relative to an emulsifiable concentrate made of an emulsifiable concentrate composition containing only saccharide. More specifically, it is 1.1 to 1.3, but is not limited to these.

本發明的乳油組成物或由其製造的乳油可以具有改善的可加工性。乳油是用在加糖霜或裝飾蛋糕及裝飾飲料。在此情況中,加糖霜或裝飾的加工效率會視物理性質例如硬度、可鋪展性、及乳油的黏結性而變化。 The emulsifiable concentrate composition of the present invention or the emulsifiable concentrate produced therefrom may have improved processability. Emulsifiable oil is used in icing or decorating cakes and decorative drinks. In this case, the processing efficiency of the frosting or decoration varies depending on physical properties such as hardness, spreadability, and adhesion of the cream.

硬度表示物體的堅固度(solidity)。乳油有較高的硬度時,會變硬,其可加工性會變不好。相反的,乳油有較低的硬度時有利於加糖霜或裝飾並呈現柔軟的質地。本發明的乳油組成物經由阿洛酮糖及植物性油脂的組合可以顯著的減低硬度,用於加糖霜或裝飾目的時可以表現優異的效果。本發明的乳油組成物或由其製造的乳油的硬度可以在70g至220g,80g至210g,80g至160g,80g至150g,或80g至120g,但不限定於這些。 Hardness indicates the solidity of the object. When the emulsifiable concentrate has a high hardness, it will become hard and its workability will become poor. Conversely, when the cream has a lower hardness, it is advantageous for adding frosting or decoration and exhibiting a soft texture. The cream composition of the present invention can remarkably reduce hardness by a combination of psicose and vegetable oil, and can exhibit excellent effects when added for icing or decorative purposes. The cream composition of the present invention or the cream produced therefrom may have a hardness of 70 g to 220 g, 80 g to 210 g, 80 g to 160 g, 80 g to 150 g, or 80 g to 120 g, but is not limited thereto.

可鋪展性(spreadability)是指當液體例如乳油施用於固形物體時表現的施用的容易性而言。乳油有低可鋪展性時,其阻力低,有利於加糖霜或裝飾。本發明的乳油組成物或由其製造的乳油的可鋪展性是,將 探頭(TTC可鋪展性裝置(TTC Spreadability Rig))以一定的力及速度(測試速度及後測試速度(Post Test Speed 1.0mm/sec))移動,從探頭與試料表面接觸點加壓到85%深度時測定的值。可鋪展性可以是在2至9g/sec,更具體而言在3至8g/sec,再更具體而言在3至6g/sec,但不限定於這些。 Spreadability refers to the ease of application that is exhibited when a liquid, such as emulsifiable concentrate, is applied to a solid object. When the cream has low spreadability, its resistance is low, which is good for adding frosting or decoration. The spreadability of the emulsifiable concentrate composition of the present invention or the emulsifiable concentrate produced therefrom is The probe (TTC Spreadability Rig) is moved at a certain force and speed (test speed and post test speed (Post Test Speed 1.0mm/sec)), and is pressurized from the contact point of the probe to the sample surface to 85%. The value measured at depth. The spreadability may be from 2 to 9 g/sec, more specifically from 3 to 8 g/sec, still more specifically from 3 to 6 g/sec, but is not limited thereto.

黏結性(cohesiveness)是指維持產品形狀所需的內部結合力,即,對變形的復原力而言。當乳油的黏結性的絕對值較小時,在加糖霜或裝飾工作時表面變成更平滑,因而可得優異的可加工性。反過來,當黏結性的絕對值較大時,乳油相對性的強黏在用於施用乳油的工具上,對可加工性不利。通常,黏結性(g/sec)是,當將探頭(TTC可鋪展性裝置)以一定的力及速度(測試速度及後測試速度1.0mm/sec)移動,從探頭與試料表面接觸加壓到85%深度後,探頭回復到初始的位置時測定的阻力值。本發明的乳油組成物或由其製造的乳油的黏結性可以是在150至310g/sec,更具體而言是在150至260g/sec,但不限定於這些。 Cohesiveness refers to the internal bonding force required to maintain the shape of the product, that is, the resilience to deformation. When the absolute value of the adhesiveness of the cream is small, the surface becomes smoother when the frosting or decorating work is performed, and excellent workability can be obtained. Conversely, when the absolute value of the adhesiveness is large, the relative strong adhesion of the emulsifiable concentrate on the tool for applying the emulsifiable concentrate is unfavorable for workability. Usually, the adhesion (g/sec) is when the probe (TTC spreadable device) is moved with a certain force and speed (test speed and post-test speed 1.0 mm/sec), and the probe is pressed against the surface of the sample to the pressure. The resistance value measured when the probe returns to the initial position after 85% depth. The adhesiveness of the emulsifiable concentrate composition of the present invention or the emulsifiable concentrate produced therefrom may be from 150 to 310 g/sec, more specifically from 150 to 260 g/sec, but is not limited thereto.

本發明的乳油組成物或由其製造的乳油可以減少裂紋生成。具體而言,本發明的乳油組成物或由其製造的乳油,與只含有蔗糖或果糖或由該等製造的乳油的乳油組成物相較,可減少在5℃儲存時的裂紋的生成。 The emulsifiable concentrate composition of the present invention or the emulsifiable concentrate produced therefrom can reduce crack generation. Specifically, the emulsifiable concentrate composition of the present invention or the emulsifiable concentrate produced therefrom can reduce the generation of cracks at the time of storage at 5 ° C as compared with the emulsifiable concentrate containing only sucrose or fructose or the emulsifiable concentrate.

本發明的乳油組成物可用於加糖霜、裝飾、及飲料,特別是飲料。飲料可包括咖啡、咖啡飲料、果汁等,但不限定於這些。當本發明的乳油組成物應用於飲料時,為了加強飲料的香味,乳油需要迅速溶解於飲料。乳油溶解得更迅速,對液體飲料的感官偏好(sensory preference)有利。 The emulsifiable concentrate composition of the present invention can be used for icing sugar, decoration, and beverages, particularly beverages. The beverage may include coffee, coffee beverage, juice, etc., but is not limited thereto. When the emulsifiable concentrate composition of the present invention is applied to a beverage, in order to enhance the flavor of the beverage, the emulsifiable concentrate needs to be quickly dissolved in the beverage. The emulsifiable concentrate dissolves more rapidly and is advantageous for the sensory preference of liquid beverages.

本發明的乳油組成物可以改善微生物安定性。如本文中所用,術語“微生物安定性(microbial stability)”是指在乳油製造、儲藏、或使用階段,或在使用後的有害微生物的發生及生長而言。由於通常將醣類例如蔗糖加入於乳油,則乳油容易受微生物汙染及損壞。但是,在本發明的乳油組成物中,全部或一部分醣類例如蔗糖或果糖以阿洛酮糖取代,如此乳油組成物對有害微生物在乳油中發生及成長有優異的抑制作用。 The emulsifiable concentrate composition of the present invention can improve microbial stability. As used herein, the term "microbial stability" refers to the occurrence and growth of harmful microorganisms during the manufacture, storage, or use phase of the cream, or after use. Since a saccharide such as sucrose is usually added to the emulsifiable concentrate, the emulsifiable concentrate is easily contaminated and damaged by microorganisms. However, in the emulsifiable concentrate composition of the present invention, all or a part of the saccharides such as sucrose or fructose are substituted with psicose, and thus the emulsifiable concentrate composition has an excellent inhibitory effect on the occurrence and growth of harmful microorganisms in the emulsifiable concentrate.

本發明的乳油組成物除了植物性油脂、阿洛酮糖、果糖、或蔗糖之外可以再含有乳化劑、安定劑、酪蛋白鈉、酸度調整劑、精製鹽、調味劑、鹽、著色劑、或水。加之,本發明的乳油組成物可以再含有通常用於乳油的製造的已知材料。鹽類的具體例可包括氯化鈉(鹽)、氯化鎂、氯化鉀、磷酸鹽等,但不限定於這些。本發明的乳油組成物可以再含有可用於製造乳油的鹽類。 The emulsifiable concentrate composition of the present invention may further contain an emulsifier, a stabilizer, sodium caseinate, an acidity adjuster, a refined salt, a flavoring agent, a salt, a coloring agent, in addition to vegetable oil, naloxose, fructose, or sucrose. Or water. Additionally, the emulsifiable concentrate composition of the present invention may further contain known materials commonly used in the manufacture of emulsifiable concentrates. Specific examples of the salt may include, but are not limited to, sodium chloride (salt), magnesium chloride, potassium chloride, phosphate, and the like. The emulsifiable concentrate composition of the present invention may further contain a salt which can be used in the manufacture of emulsifiable concentrate.

本發明的乳油組成物可以含有乳化劑、乳液安定劑、及/或適當量的安定劑,具體而言相對於乳油組成物總量100重量份,含量在0.01至10重量份,0.1至5重量份,0.3至3重量份,0.2至2重量份,或0.4至1重量份。乳化劑是指可讓2種或更多種的互不相混合的液體混合成為穩定混合物的物質,安定劑是指用於防止食品的物理性或化學性變化的物質。 The emulsifiable concentrate composition of the present invention may contain an emulsifier, an emulsion stabilizer, and/or a suitable amount of a stabilizer, specifically, in an amount of 0.01 to 10 parts by weight, 0.1 to 5 parts by weight based on 100 parts by weight based on the total amount of the emulsifiable composition. Parts, 0.3 to 3 parts by weight, 0.2 to 2 parts by weight, or 0.4 to 1 part by weight. The emulsifier refers to a substance which can mix two or more mutually miscible liquids into a stable mixture, and the stabilizer is a substance for preventing physical or chemical changes of foods.

乳化劑、乳液安定劑、或安定劑的具體例,可包含非離子性界面活性劑例如脂肪酸單甘油酯、去水山梨醇脂肪酸酯(例如Spans等。)、蔗糖的脂肪酸酯等、卵磷酯、阿拉伯樹膠、卵黃、明膠、刺槐豆膠、瓜爾 膠、三仙膠、海藻酸鈉、果膠、CMC、酪蛋白鈉、白蛋白、磷酸酯、檸檬酸酯、羥丙基甲基纖維素等,但不限定於這些。 Specific examples of the emulsifier, the emulsion stabilizer, or the stabilizer may include a nonionic surfactant such as a fatty acid monoglyceride, a sorbitan fatty acid ester (for example, Spans, etc.), a fatty acid ester of sucrose, or the like. Phosphate ester, gum arabic, egg yolk, gelatin, locust bean gum, guar Gum, Sanxian gum, sodium alginate, pectin, CMC, casein sodium, albumin, phosphate, citrate, hydroxypropyl methylcellulose, etc., but are not limited thereto.

為了達成上述目標,本發明另一態樣是提供一種乳油製造方法,其係包含混合及打發植物性油脂,及阿洛酮糖的製程。 In order to achieve the above object, another aspect of the present invention provides a method for producing an emulsifiable concentrate comprising the steps of mixing and dispensing vegetable oils and fats, and psicose.

為了達成上述目標,本發明的再另一個態樣是提供抑制在乳油產生裂紋的方法,其係包含混合植物性油脂、及阿洛酮糖而製造乳油的製程。 In order to achieve the above object, still another aspect of the present invention provides a method for suppressing cracking in an emulsifiable concentrate, which comprises a process of mixing a vegetable oil and fat and naloxone to produce an emulsifiable concentrate.

植物性油脂、阿洛酮糖、及乳油與上述者相同。 Vegetable oils, psicose, and emulsifiable concentrates are the same as described above.

本發明的製造乳油或抑制乳油產生裂紋的方法可以再含有與蔗糖或果糖混合的製程。 The method of producing an emulsifiable concentrate or inhibiting the generation of cracks in the emulsifiable concentrate of the present invention may further comprise a process of mixing with sucrose or fructose.

[實施方式] [Embodiment]

以下,舉例而更詳細說明本發明。但是,這些例只是用於說明之目的,本發明的範圍並不受這些例所限定。 Hereinafter, the present invention will be described in more detail by way of examples. However, these examples are for illustrative purposes only, and the scope of the invention is not limited by these examples.

實例1:乳油組成物的製造 Example 1: Manufacture of emulsifiable concentrate

依照下述第1表的組成製造T-1至T-7的乳油組成物。尤其是,依照第1表的條件在乳油組成物混合進去的醣類[蔗糖(第一製糖股份公司(CJ CheilJedang),純度98%或更高)、果糖(第一製糖股份公司(CJ CheilJedang),純度42%或更高,果糖及葡萄糖的混合物(第一製糖股份公司)、及阿洛酮糖(第一製糖股份公司,純度95%或更高)]含量是依照第1表所示改變。作為果糖及葡萄糖的混合物係使用果糖(42%)及葡萄糖組成的產品。在第1表及下面的各例中的果糖係表示果糖及葡萄糖的混合物。 The cream compositions of T-1 to T-7 were produced in accordance with the composition of Table 1 below. In particular, sugars (sucrose (CJ CheilJedang, purity 98% or higher), fructose (CJ CheilJedang) mixed in the emulsifiable concentrate according to the conditions of Table 1. , purity 42% or higher, a mixture of fructose and glucose (first sugar company), and psicose (first sugar company, purity 95% or higher)] content is changed according to the table 1 As a mixture of fructose and glucose, a product consisting of fructose (42%) and glucose was used. The fructose in the first table and the following examples represents a mixture of fructose and glucose.

試驗例1:乳油組成物的黏度測定 Test Example 1: Determination of viscosity of emulsifiable concentrate

實例1所製造的乳油組成物的黏度是與蒸餾水(單次蒸餾水)及低脂人造奶油(聯合利華(Unilever),脂肪含量45%(w/w))比較而測定。黏度係指物體的黏力大小。當物體有較低黏度時,具有較高的流動性而較接近於液相。當體有較高的黏度時,具有較低流動性及較接近於固相。詳細的說,將每3g的實例1中製造的乳油、蒸餾水、及低脂人造奶油在黏度計(AR 1500ex,TA Instruments,USA)的測定位置中心測重,然後將探頭(40mm平行盤)移動到測定位置中心高1mm的位置,使試料及探頭均勻密實互相接觸,使探頭在7℃以10s-1的剪切速率旋轉。在1分鐘的時點,測定黏度,結果示於下述第2表。 The viscosity of the cream composition produced in Example 1 was determined in comparison with distilled water (single distilled water) and low fat margarine (Unilever, fat content 45% (w/w)). Viscosity is the amount of adhesion of an object. When the object has a lower viscosity, it has a higher fluidity and is closer to the liquid phase. When the body has a higher viscosity, it has lower fluidity and is closer to the solid phase. In detail, each 3 g of the emulsifiable concentrate, distilled water, and low-fat margarine produced in Example 1 was weighed at the center of the measurement position of the viscometer (AR 1500ex, TA Instruments, USA), and then the probe (40 mm parallel disk) was moved. To the position 1 mm higher at the center of the measurement position, the sample and the probe were uniformly and closely contacted with each other, and the probe was rotated at 7 ° C at a shear rate of 10 s -1 . The viscosity was measured at the time of 1 minute, and the results are shown in the second table below.

結果,確認實例1製造的乳油組成物表現與在冰箱溫度7℃的蒸餾水相似的黏度,有高流動性的液相,而低脂人造奶油呈現高黏度,與蒸餾水及乳油組成物不同,在冰箱溫度儲存時成為固相存在。 As a result, it was confirmed that the emulsifiable concentrate composition produced in Example 1 exhibited a viscosity similar to that of distilled water at a refrigerator temperature of 7 ° C, and had a high fluidity liquid phase, while the low fat margarine exhibited a high viscosity unlike the distilled water and emulsifiable concentrate composition in the refrigerator. When the temperature is stored, it becomes a solid phase.

試驗例2:乳油組成物的超多(over-run)的測定 Test Example 2: Measurement of over-run of emulsifiable concentrate composition

測定實例1製造的各種乳油組成物的超多的程度。超多係指在打發後相對於初始值的體積膨脹的程度而言。較高的超多值表示較高的乳油體積膨脹度的意思,是對可加工性有利。 The degree of excess of the various cream compositions made in Example 1 was determined. Ultra-multiple refers to the extent of volume expansion relative to the initial value after firing. A higher super multi-value means a higher emulsion volume expansion, which is advantageous for workability.

詳細而言,將每0.6L的實例1製造的乳油組成物使用廚房幫手攪拌機(USA,KITCHEN AID)高速(8階段)打發至打發終點,將使用100mL比重杯測定的體積依據下述式決定超多。再者,T-2至T-7的超多是相對於T-1的超多表示,具體而言,將計算值的小數點下第二位四捨五入,結果示於下述第3表。 Specifically, each 0.6 L of the emulsifiable concentrate composition produced in Example 1 was sent to the end of the firing using a kitchen hand mixer (USA, KITCHEN AID) at a high speed (8 stages), and the volume measured using a 100 mL PCT cup was determined according to the following formula. many. Further, the excess of T-2 to T-7 is a super-multiple representation with respect to T-1. Specifically, the second decimal place of the calculated value is rounded off, and the results are shown in Table 3 below.

[式1]超多(%)=(打發後體積-打發前體積)÷打發前體積×100 [Formula 1] Super (%) = (volume after firing - volume before firing) 体积 volume before firing × 100

結果,確認含有重量30%蔗糖的T-1呈現最低超多178%,全部或部分蔗糖以阿洛酮糖取代的T-3至T-5,或混合果糖及阿洛酮糖的T-6及T-7呈現更高的超多200%,顯示超多有增加。尤其是,含有30%(w/w)的阿洛酮糖,其中全部的蔗糖或果糖以阿洛酮糖取代的T-3,呈現最高的超多239%。其中,當超多是以相對值表示時,T-3至T-7對做為醣類而只含有蔗糖的T-1的相對超多值為1.1至1.3。 As a result, it was confirmed that T-1 containing 30% by weight of sucrose exhibited the lowest over 178%, T-3 to T-5 in which all or part of sucrose was substituted with psicose, or T-6 mixed with fructose and psicose. And T-7 showed a higher than 200% higher, showing an increase of more than a lot. In particular, T-3 containing 30% (w/w) of psicose, in which all of the sucrose or fructose was replaced by psicose, showed the highest excess of 239%. Among them, when the super-multiple is expressed as a relative value, the relative super-value of T-1 to T-7 as a saccharide and only sucrose-containing T-1 is 1.1 to 1.3.

因此,可見當使用蔗糖及阿洛酮糖的混合物或只使用阿洛酮糖代替蔗糖時,乳油組成物的超多性質有改善,對體積膨脹更有利。 Thus, it can be seen that when a mixture of sucrose and psicose is used or only oseose is used instead of sucrose, the super-mass properties of the cream composition are improved and are more advantageous for volume expansion.

試驗例3:由乳油組成物的物理性質測定探討加糖霜可加工性 Test Example 3: Determination of physical properties of emulsifiable concentrates

使用TA(質地解析儀)測定實例1製造的各種乳油組成物的特定的物理性質。 The specific physical properties of the various emulsifiable concentrate compositions produced in Example 1 were determined using TA (Texture Resolver).

具體而言,將實例1製造的乳油組成物的各相同體積密實的放置於質地解析儀(STABLE MICRO SYSTEMS,TAXT plus)的試料支持台,由與表面的接觸點以固定的力及速度(測試速度及測試後速度1.0mm/sec)移動探頭(TTC鋪展性裝置)(放在離每一試料表面30cm處)加壓至85%深度。在加壓到由與表面的接觸點以固定的力及速度(測試速度及測試後速度1.0mm/sec)移動探頭(TTC鋪展性裝置)加壓至85%深度後,當探頭回到原位時測定阻力值。將所測定值定義為黏結性(g/sec)。 Specifically, the same volume of the emulsifiable concentrate composition produced in Example 1 was densely placed on a sample support stand of a texture analyzer (TAXT plus), and the contact point with the surface was fixed at a constant force and speed (test Speed and post-test speed 1.0 mm/sec) The mobile probe (TTC spreader) was placed at a depth of 85% from the surface of each sample. After the pressure is applied to the contact point with the surface at a fixed force and speed (test speed and test speed 1.0mm/sec), the probe (TTC spread device) is pressurized to 85% depth, when the probe returns to the original position The resistance value is measured. The measured value was defined as the adhesion (g/sec).

關於這一點,探頭加於試料的最大強度的推力表示硬度(力),而當試料被連續加壓時產生的阻力值的比定義為可鋪展性。 In this regard, the thrust of the maximum intensity of the probe applied to the sample indicates hardness (force), and the ratio of the resistance value generated when the sample is continuously pressurized is defined as spreadability.

再者,由上述方法所測得的綜合示於下述第4表。較高的硬度(gf)值表示乳油組成物較硬,而較低的可鋪展性[梯度(g/sec)]值表示乳油組成物有較低阻力而具有優異的可鋪展性。 Further, the combination measured by the above method is shown in Table 4 below. A higher hardness (gf) value indicates that the cream composition is harder, while a lower spreadability [gradient (g/sec)] value indicates that the cream composition has lower resistance and excellent spreadability.

結果,如第4表所示,只含有蔗糖的T-1有高硬度、可鋪展性、及黏結性值,表示非常差的可加工性,而以阿洛酮糖取代全部或一部分蔗糖的T-3至T-5有低硬度、可鋪展性、及黏結性值,表示有非常改善的可加工性。再者,與只含有果糖的T-2比較,以阿洛酮糖取代一部分的蔗糖的T-6及T-7顯示有顯著改善的可加工性。尤其是,以阿洛酮糖取代全部的蔗糖或果糖的含有30%(w/w)阿洛酮糖的T-3有最低的硬度、可鋪展性、及黏結性值,表示有最優異的可加工性。 As a result, as shown in the fourth table, T-1 containing only sucrose has high hardness, spreadability, and adhesion value, indicating very poor processability, and replacing all or a part of sucrose with psicose. -3 to T-5 have low hardness, spreadability, and adhesion values, indicating a very improved processability. Furthermore, T-6 and T-7, which partially replace sucrose with psicose, showed significantly improved processability compared to T-2 containing only fructose. In particular, T-3 containing 30% (w/w) psicose, which replaces all sucrose or fructose with psicose, has the lowest hardness, spreadability, and adhesion value, indicating the best Machinability.

因此,確認當代替蔗糖或果糖而添加阿洛酮糖時,乳油組成物的硬度及可鋪展性減低,乳油的加糖霜工作可容易以較小的力實施,而改善工作效率,並可提供柔軟的質地,有利於偏好。 Therefore, it was confirmed that when naloxone was added instead of sucrose or fructose, the hardness and spreadability of the emulsifiable concentrate were reduced, and the icing operation of the emulsifiable concentrate was easily carried out with less force, and the work efficiency was improved, and the softness was provided. The texture is good for preference.

試驗例4:乳油組成物的裂紋生成的探討 Test Example 4: Discussion on crack formation of emulsion composition

探討使用實例1製造的各種乳油組成物時是否會生成裂紋。當使用乳油實施蛋糕加糖霜或裝飾工作時,由於在低溫儲藏時水分的移動其質地變成弱,其結果,有產生裂紋而減低商品價值的問題。由於此,探討改善此問題的效果。 Whether cracks were generated when using the various emulsifiable compositions produced in Example 1 was investigated. When the cake is added with icing or decoration work using emulsifiable oil, the texture becomes weak due to the movement of moisture at the time of low-temperature storage, and as a result, there is a problem that cracks are generated to reduce the commercial value. Because of this, explore the effect of improving this problem.

具體而言,乳油組成物的加糖霜是以1cm厚度在培養皿上實施,在5℃儲存而由肉眼檢查裂紋的生成。將裂紋的程度示於第1圖,並依據下述基準(無裂紋:X,裂紋:○,很多裂紋:◎)示於第5表。 Specifically, the icing sugar of the cream composition was applied to a petri dish at a thickness of 1 cm, and stored at 5 ° C to visually examine the generation of cracks. The degree of the crack is shown in Fig. 1, and is shown in the fifth table in accordance with the following criteria (no crack: X, crack: ○, many cracks: ◎).

結果如示於第5表,只含有蔗糖的T-1在第2日顯示裂紋,而只含有果糖的T-2在第4天產生若干數目的裂紋。 As a result, as shown in the fifth table, T-1 containing only sucrose showed cracks on the 2nd day, and T-2 containing only fructose produced a number of cracks on the 4th day.

與此對照,全部或一部分蔗糖或果糖以阿洛酮糖取代的T-3至T-7在低溫也只到加糖霜後第3天才顯示裂紋。尤其是,當蔗糖及阿洛酮糖以混合比2:1或1:2添加時,或果糖及阿洛酮糖以混合比1:2添加時,更顯著的抑制裂紋的生成。 In contrast, T-3 to T-7, in which all or a portion of sucrose or fructose was replaced by psicose, showed cracks only at the low temperature only on the third day after the addition of the frosting. In particular, when sucrose and psicose are added at a mixing ratio of 2:1 or 1:2, or when fructose and psicose are added at a mixing ratio of 1:2, crack formation is more significantly inhibited.

因此,可見當以阿洛酮糖取代全部或一部分蔗糖或果糖時,將乳油加糖霜後雖在低溫下儲存裂紋生成也可受到抑制,裂紋生成時間可更延後。 Therefore, it can be seen that when all or a part of sucrose or fructose is replaced by psicose, the generation of cracks at the low temperature after the emulsified icing cream can be suppressed, and the crack generation time can be further delayed.

試驗例5:乳油組成物應用於液體飲料的效果的探討 Test Example 5: Discussion on the effect of emulsifiable concentrate composition on liquid beverage

探討實例1製造的各種乳油組成物在液體飲料例如咖啡使用時是否表現同樣的效果。在此情況中,為了要加強咖啡的香氣乳油需要迅速溶解於咖啡。具體而言,秤取乳油組成物各50g放在75℃的270g的咖啡上面。測定乳油完全溶解於咖啡的時間而示於下述第6表。 It was investigated whether the various emulsifiable compositions produced in Example 1 exhibited the same effect when used in a liquid beverage such as coffee. In this case, in order to strengthen the aroma of the coffee, the cream needs to be quickly dissolved in the coffee. Specifically, 50 g of each of the cream compositions was placed on top of 270 g of coffee at 75 °C. The time when the cream was completely dissolved in the coffee was measured and shown in Table 6 below.

結果,當全部或一部分蔗糖或果糖以阿洛酮糖取代時,乳油溶解的時間有縮短。尤其是,只有添加阿洛酮糖的T-3,及果糖及阿洛酮糖以混合比1:2添加的T-7顯示最大的溶解速率。 As a result, when all or a part of sucrose or fructose is substituted with psicose, the time for the emulsification to dissolve is shortened. In particular, only T-3 with psicose added, and fructose and psicose showed a maximum dissolution rate with T-7 added at a mixing ratio of 1:2.

因此,可見當蔗糖或果糖之外在乳油製造時使用阿洛酮糖,則可以改善乳油的溶解速率,更有利於液體飲料的感官偏好。 Therefore, it can be seen that when aldose is used in the manufacture of emulsifiable concentrates other than sucrose or fructose, the dissolution rate of the emulsifiable concentrate can be improved, and the sensory preference of the liquid beverage is more favored.

由上述說明,具有本行業技術者可理解本發明在不改變其技術精神或基本特性下可以不同特定形式實施。因此,應瞭解上述實施例並非限定性的,是在各方面說明用的。本發明的範圍係由所附帶的請求項所定義,而不是之前的說明所定義,因此,在請求項範圍內的所有變化和修改,或與這些範圍及界限的同等者,都應被包含在請求項中。 From the above description, it will be understood by those skilled in the art that the present invention may be embodied in various specific forms without departing from the spirit of the invention. Therefore, it should be understood that the above-described embodiments are not limiting, and are described in various aspects. The scope of the present invention is defined by the appended claims, and is not defined by the foregoing description, therefore, all changes and modifications within the scope of the claims, or equivalents In the request item.

Claims (17)

一種乳油組成物,包含植物性油脂,及阿洛酮糖,使用前述乳油組成物製造的油脂的硬度為70至220。 An emulsifiable concentrate composition comprising vegetable oils and fats and psicose, wherein the fats and oils produced using the aforementioned emulsifiable concentrates have a hardness of 70 to 220. 如申請專利範圍第1項所述的乳油組成物,其中,相對於乳油組成物總量100重量份,阿洛酮糖的含有量為5至40重量份。 The emulsifiable concentrate composition according to claim 1, wherein the aldose content is 5 to 40 parts by weight based on 100 parts by weight of the total amount of the emulsifiable concentrate composition. 如申請專利範圍第1項所述的乳油組成物,其中,相對於乳油組成物總量100重量份,植物性油脂的含有量為10至35重量份。 The emulsifiable concentrate composition according to claim 1, wherein the vegetable oil and fat is contained in an amount of 10 to 35 parts by weight based on 100 parts by weight of the total amount of the emulsifiable concentrate composition. 如申請專利範圍第1項所述的乳油組成物,該乳油組成物再含有果糖,相對於乳油組成物總量100重量份,果糖及阿洛酮糖的含有量為5至40重量份。 The cream composition according to claim 1, wherein the cream composition further contains fructose, and the content of fructose and psicose is 5 to 40 parts by weight based on 100 parts by weight of the total amount of the cream composition. 如申請專利範圍第4項所述的乳油組成物,該乳油組成物再含有葡萄糖,其中,相對於乳油組成物總量100重量份,果糖、葡萄糖、及阿洛酮糖的含量為5至40重量份。 The emulsifiable concentrate composition according to claim 4, wherein the emulsifiable concentrate composition further contains glucose, wherein the content of fructose, glucose, and psicose is 5 to 40 with respect to 100 parts by weight of the total amount of the emulsifiable concentrate composition. Parts by weight. 如申請專利範圍第4項所述的乳油組成物,其中,所含果糖及阿洛酮糖的混合比為1:0.5至1:5。 The emulsifiable concentrate composition according to claim 4, wherein the mixing ratio of fructose and psicose contained is from 1:0.5 to 1:5. 如申請專利範圍第5項所述的乳油組成物,其中,所含果糖/葡萄糖及阿洛酮糖的混合比為1:0.5至1:2。 The cream composition according to claim 5, wherein the fructose/glucose and psicose are mixed in a ratio of 1:0.5 to 1:2. 如申請專利範圍第1項所述的乳油組成物,該乳油組成物再含有蔗糖,其中,相對於乳油組成物總量100重量份,蔗糖及阿洛酮糖的含有量為5至40重量份。 The emulsifiable concentrate composition according to claim 1, wherein the emulsifiable concentrate composition further comprises sucrose, wherein the sucrose and psicose are contained in an amount of 5 to 40 parts by weight based on 100 parts by weight of the total amount of the emulsifiable concentrate composition. . 如申請專利範圍第8項所述的乳油組成物,其中,所含蔗糖及阿洛酮糖的混合比為1:0.5至1:2。 The emulsifiable concentrate composition according to claim 8, wherein the mixture ratio of sucrose and psicose is 1:0.5 to 1:2. 如申請專利範圍第1項所述的乳油組成物,其中,使用前述乳油組成物所製造的乳油的黏度為0.02Pa.s至0.06Pa.s。 The emulsifiable concentrate composition according to claim 1, wherein the emulsifiable concentrate produced by using the emulsifiable concentrate composition has a viscosity of 0.02 Pa. s to 0.06Pa. s. 如申請專利範圍第1項所述的乳油組成物,其中,相對於使用只含有蔗糖作為醣類的乳油組成物所製造的乳油的超多值,使用前述乳油組成物所製造的乳油的相對超多值為1.1至1.3。 The emulsifiable concentrate composition according to claim 1, wherein the emulsifiable concentrate produced by using the emulsifiable concentrate composition is relatively super-extra value with respect to the emulsifiable concentrate produced using the emulsifiable concentrate composition containing only sucrose as a saccharide. The multi value is 1.1 to 1.3. 如申請專利範圍第1項所述的乳油組成物,其中,使用前述乳油組成物所製造的乳油的可鋪展性為3g/sec至8g/sec。 The emulsifiable concentrate composition according to claim 1, wherein the emulsifiable concentrate produced using the emulsifiable concentrate composition has a spreadability of from 3 g/sec to 8 g/sec. 如申請專利範圍第1項所述的乳油組成物,其中,使用前述乳油組成物所製造的乳油的黏結性為150g/sec至310g/sec。 The emulsifiable concentrate composition according to claim 1, wherein the emulsifiable concentrate produced by using the emulsifiable concentrate composition has a viscosity of from 150 g/sec to 310 g/sec. 如申請專利範圍第1項所述的乳油組成物,該乳油組成物再含有酪蛋白鈉、酸度調節劑、精製鹽、調味劑、鹽、著色劑、或水。 The cream composition according to claim 1, wherein the cream composition further comprises casein sodium, an acidity adjuster, a refined salt, a flavoring agent, a salt, a coloring agent, or water. 一種乳油,係含有如申請專利範圍的第1項至第14項中任一項所述的乳油組成物。 An emulsifiable concentrate comprising the emulsifiable concentrate composition according to any one of the items 1 to 14 of the patent application. 一種乳油的製造方法,該方法包含混合並打發植物性油脂及阿洛酮糖的製程。 A method for producing an emulsifiable concentrate, which comprises a process of mixing and delivering vegetable oils and naloxones. 一種抑制乳油產生裂紋的方法,該方法包含混合植物性油脂及阿洛酮糖而製造乳油的製程。 A method for inhibiting cracking of an emulsifiable concentrate, the method comprising the steps of mixing vegetable oils and psicose to produce emulsifiable concentrates.
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