TW201930187A - Carbon nanotube structure as a double-sided adhesive application - Google Patents

Carbon nanotube structure as a double-sided adhesive application Download PDF

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TW201930187A
TW201930187A TW107100826A TW107100826A TW201930187A TW 201930187 A TW201930187 A TW 201930187A TW 107100826 A TW107100826 A TW 107100826A TW 107100826 A TW107100826 A TW 107100826A TW 201930187 A TW201930187 A TW 201930187A
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carbon tube
carbon
double
tube structure
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TWI700247B (en
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金翔
巫梓鵬
苗文韜
姜開利
范守善
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鴻海精密工業股份有限公司
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/03—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers with respect to the orientation of features
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
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    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/16—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
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    • B32B9/007—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
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    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
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    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/047—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of fibres or filaments
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C08K3/041—Carbon nanotubes
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    • C09J1/00—Adhesives based on inorganic constituents
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    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/05—5 or more layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2405/00—Adhesive articles, e.g. adhesive tapes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00—Electrical equipment
    • B32B2457/14—Semiconductor wafers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/31—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive effect being based on a Gecko structure
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Abstract

The present disclosure relates to an application of a carbon nanotube structure as a double-sided adhesive. The carbon nanotube structure is used to bond two objects together. The carbon nanotube structure includes a first bonding surface and a second bonding surface. The first bonding surface and the second bonding surface are oppositely disposed. The carbon nanotube structure consists of at least one super-aligned carbon nanotube film. The at least one super-aligned carbon nanotube film includes a plurality of carbon nanotubes. The plurality of carbon nanotubes extend substantially in the same direction and are connected to each other by van der Waals attractive force. The extending direction of the plurality of carbon nanotubes is parallel to the first bonding surface and the second bonding surface.

Description

奈米碳管結構作為雙面膠的應用Application of carbon nanotube structure as double-sided adhesive

本發明涉及一種奈米碳管結構的應用，尤其是一種奈米碳管結構作為雙面膠的應用。The invention relates to the application of a nano carbon tube structure, in particular to the application of a nano carbon tube structure as a double-sided adhesive.

在日常生活以及工業生產中，雙面膠被普遍用於物體之間的黏結和固定。然而，先前的雙面膠一般適用的溫度範圍很窄，在高溫（例如高於70℃）和低溫（例如低於0℃）下黏性顯著降低甚至失去黏性。當不需要黏結時，很難將物體分開，即使分開，雙面膠也會在物體的表面殘留難以去除或者會對物體造成破壞。而且先前的雙面膠中大多含有有機溶劑，污染環境且不利於使用者的身體健康。In daily life and industrial production, double-sided tape is commonly used for bonding and fixing objects. However, the previous double-sided tape is generally applicable to a narrow temperature range, and the viscosity is significantly reduced or even lost at high temperature (for example, higher than 70 ° C) and low temperature (for example, lower than 0 ° C). When no adhesion is required, it is difficult to separate objects. Even if they are separated, double-sided tape will remain on the surface of the object, which is difficult to remove or cause damage to the object. Moreover, most of the previous double-sided adhesives contained organic solvents, which polluted the environment and were not good for the user's health.

有鑑於此，確有必要提供一種奈米碳管結構作為雙面膠的應用，該奈米碳管結構作為雙面膠應用時，可以在高溫和低溫下使用，當不需要黏結時，分開物體比較容易，不會在物體表面殘留，且不含有有機溶劑。In view of this, it is indeed necessary to provide a nano carbon tube structure as a double-sided adhesive. When the nano carbon tube structure is used as a double-sided adhesive, it can be used at high and low temperatures, and when no adhesion is required, separate objects It is relatively easy, does not remain on the surface of the object, and does not contain organic solvents.

一種奈米碳管結構作為雙面膠的應用，該奈米碳管結構用於將兩個物體黏結於一體，該奈米碳管結構包括一第一黏結面及一第二黏結面，第一黏結面和第二黏結面相對設置；該奈米碳管結構由至少一層超順排奈米碳管膜組成，該至少一層超順排奈米碳管膜包括複數個奈米碳管，該複數個奈米碳管的延伸方向基本相同且通過凡得瓦力相互連接，該延伸方向平行於所述第一黏結面和第二黏結面。A nano carbon tube structure is used as double-sided adhesive. The nano carbon tube structure is used to bond two objects together. The nano carbon tube structure includes a first bonding surface and a second bonding surface. The bonding surface and the second bonding surface are oppositely arranged; the nano carbon tube structure is composed of at least one super-row nano carbon tube film, and the at least one super-row nano carbon tube film includes a plurality of nano carbon tubes, the plurality The extension directions of the nano carbon tubes are substantially the same and are connected to each other by Van der Waals force. The extension directions are parallel to the first bonding surface and the second bonding surface.

一種奈米碳管結構作為雙面膠的應用，該奈米碳管結構用於將兩個物體黏結於一體，該奈米碳管結構由複數個奈米碳管組成，該複數個奈米碳管首尾相連且沿同一方向延伸，且延伸方向平行於雙面膠的長度方向，所述複數個奈米碳管通過凡得瓦力相互連接。Application of a nano carbon tube structure as a double-sided adhesive. The nano carbon tube structure is used to bond two objects together. The nano carbon tube structure is composed of a plurality of nano carbon tubes, the plurality of nano carbons. The tubes are connected end to end and extend in the same direction, and the extending direction is parallel to the length direction of the double-sided tape, and the plurality of nano carbon tubes are connected to each other by Van der Waals force.

與先前技術相比較，由本發明提供的奈米碳管結構作為雙面膠的應用具有以下優點，該奈米碳管結構作為雙面膠應用時，與物體之間僅通過凡得瓦力黏結，凡得瓦力基本上不受溫度的影響，因此，所述奈米碳管結構作為雙面膠的應用溫度範圍較大，例如，在-196℃～1000℃的範圍內均具有較大的黏性；而且當不需要黏結時，可以僅通過一定的外力就能將物體分開，不會對物體造成損傷，而且奈米碳管結構在物體上基本沒有殘留；另外，所述奈米碳管結構僅由超順排奈米碳管膜組成，不含有有機溶劑，對環境污染較小。Compared with the prior art, the application of the nano-carbon tube structure provided by the present invention as a double-sided adhesive has the following advantages. When the nano-carbon tube structure is applied as a double-sided adhesive, it is bonded with objects only by Van der Waals force. Van der Waals force is basically not affected by temperature. Therefore, the application range of the carbon nanotube structure as double-sided adhesive is large, for example, it has a large viscosity in the range of -196 ° C to 1000 ° C. And when the adhesion is not needed, the object can be separated only by a certain external force without causing damage to the object, and the carbon nanotube structure of the object has almost no residue on the object; in addition, the carbon nanotube structure It only consists of super-semi-row carbon nanotube film, contains no organic solvents, and has less environmental pollution.

下麵將結合附圖及具體實施例對本發明作進一步的詳細說明。The present invention will be further described in detail below with reference to the drawings and specific embodiments.

請參閱圖1，本發明第一實施例提供一種第一奈米碳管結構作為雙面膠的應用，該第一奈米碳管結構用於將兩個物體黏結於一體。該第一奈米碳管結構由至少一層超順排奈米碳管膜10組成。該超順排奈米碳管膜10包括複數個奈米碳管100，該複數個奈米碳管100基本朝同一方向延伸，且該複數個奈米碳管100的延伸方向基本平行於超順排奈米碳管膜10的表面。所述第一奈米碳管結構作為雙面膠應用時，該第一奈米碳管結構包括一第一黏結面及一第二黏結面，該第一黏結面和第二黏結面相對設置，所述複數個奈米碳管100的延伸方向平行於所述第一黏結面和第二黏結面。Referring to FIG. 1, a first embodiment of the present invention provides a first nano carbon tube structure as a double-sided adhesive. The first nano carbon tube structure is used to bond two objects together. The first carbon nanotube structure is composed of at least one super-sequential carbon nanotube film 10. The nano carbon nanotube film 10 includes a plurality of carbon nanotubes 100, the carbon nanotubes 100 extend substantially in the same direction, and the extending direction of the carbon nanotubes 100 is substantially parallel to the super carbon. The surface of the carbon nanotube film 10 is lined up. When the first carbon nanotube structure is applied as a double-sided adhesive, the first carbon nanotube structure includes a first bonding surface and a second bonding surface, and the first bonding surface and the second bonding surface are opposite to each other. The extending direction of the plurality of nano carbon tubes 100 is parallel to the first bonding surface and the second bonding surface.

請一併參閱圖2，所述複數個奈米碳管100基本朝同一方向延伸是指超順排奈米碳管膜10中大多數奈米碳管的延伸方向朝同一方向，僅存在少數隨機排列的奈米碳管，這些奈米碳管不會對超順排奈米碳管膜10中大多數奈米碳管的整體延伸方向構成明顯影響，該少數隨機排列的奈米碳管可以忽略。所述超順排奈米碳管膜10中的複數個奈米碳管100是通過凡得瓦力首尾相連。進一步地，所述超順排奈米碳管膜10中每一奈米碳管100與在延伸方向上相鄰的奈米碳管通過凡得瓦力首尾相連。Please refer to FIG. 2 together. The fact that the plurality of carbon nanotubes 100 extend in the same direction means that most of the carbon nanotubes in the super-row carbon nanotube film 10 extend in the same direction, and there are only a few random ones. Aligned carbon nanotubes. These carbon nanotubes will not significantly affect the overall extension direction of most of the carbon nanotubes in the super-sequential carbon nanotube film 10. The few randomly arranged carbon nanotubes can be ignored. . The plurality of nano carbon tubes 100 in the super-sequential nano carbon tube film 10 are connected end-to-end by Van der Waals. Further, each of the carbon nanotubes 100 in the super-sequential carbon nanotube film 10 is connected end-to-end with a carbon nanotube adjacent to the carbon nanotubes in the extending direction.

所述超順排奈米碳管膜10中的複數個奈米碳管100為純奈米碳管，純奈米碳管是指奈米碳管未經過任何物理、化學等修飾，奈米碳管的表面純淨（純淨度達到99.9%以上），基本不含有雜質，如無定型碳或殘留的催化劑金屬顆粒等。因此，所述奈米碳管結構作為雙面膠應用可以使雙面膠中不含有有機溶劑，對環境污染較小。The plurality of nano carbon tubes 100 in the super-sequential nano carbon tube film 10 are pure nano carbon tubes. Pure nano carbon tubes refer to the nano carbon tubes without any physical or chemical modification. The surface of the tube is pure (purity is above 99.9%), and basically contains no impurities, such as amorphous carbon or residual catalyst metal particles. Therefore, the application of the nanometer carbon tube structure as a double-sided tape can make the double-sided tape not contain an organic solvent and have less environmental pollution.

由於超順排奈米碳管膜10中的奈米碳管100非常純淨，且由於奈米碳管本身的比表面積非常大，所以該超順排奈米碳管膜10本身具有較強的黏性，由其形成的第一奈米碳管結構也具有很強的黏性，當該第一奈米碳管結構作為雙面膠應用時可以很好的將兩個物體黏結於一體。由於所述超順排奈米碳管膜10中的奈米碳管的表面純淨，基本不含有無定型碳或殘留的催化劑金屬顆粒等，所以該超順排奈米碳管膜10具有很高的熱穩定性，即使在很高的溫度下也不易氧化。另外，當所述第一奈米碳管結構作為雙面膠應用時，所述第一奈米碳管結構僅通過凡得瓦力與待黏結物黏結，溫度對凡得瓦力的影響很小，因此，當所述第一奈米碳管結構作為雙面膠應用時，雙面膠在高溫和低溫下仍然具有很好的黏性，進而使所述第一奈米碳管結構作為雙面膠的應用溫度範圍較廣。優選的，所述第一奈米碳管結構作為雙面膠的應用溫度範圍為-196℃～1000℃。Since the nano carbon tube 100 in the super-sequential nano carbon tube film 10 is very pure, and because the specific surface area of the nano carbon tube itself is very large, the super-sequential nano carbon tube film 10 itself has a strong viscosity. The first nano carbon tube structure formed by it also has strong adhesiveness. When the first nano carbon tube structure is applied as a double-sided adhesive, two objects can be well bonded together. Since the surface of the nano carbon nanotubes in the super-sequential nano carbon tube film 10 is pure and contains substantially no amorphous carbon or residual catalyst metal particles, etc., the super-sequential nano carbon tube film 10 has a high Thermal stability, not easily oxidized even at very high temperatures. In addition, when the first nano carbon tube structure is applied as a double-sided adhesive, the first nano carbon tube structure is bonded to the to-be-adhered body only by Van der Waals force, and the influence of temperature on the Van DeWor force is small. Therefore, when the first nano carbon tube structure is applied as a double-sided adhesive, the double-sided adhesive still has good adhesion at high and low temperatures, thereby making the first nano carbon tube structure as a double-sided adhesive. The application temperature range of glue is wide. Preferably, the application temperature range of the first carbon nanotube structure as double-sided adhesive is -196 ° C to 1000 ° C.

所述超順排奈米碳管膜10為一自支撐結構，所謂自支撐是指超順排奈米碳管膜10無需其它基體支撐，可自支撐保持一膜的形態。因此，所述超順排奈米碳管膜10可直接鋪設於待黏結物的待黏結表面上，並與該待黏結表面貼合設置。The super-sequential nano carbon nanotube film 10 is a self-supporting structure. The so-called self-supporting means that the super-sequential nano carbon tube film 10 does not need to be supported by other substrates, and can maintain the shape of a film by itself. Therefore, the nano carbon nanotube film 10 can be directly laid on the surface to be bonded, and can be attached to the surface to be bonded.

所述超順排奈米碳管膜10可以從一超順排奈米碳管陣列中直接拉取獲得。該超順排奈米碳管膜10中奈米碳管的排列方向基本平行於超順排奈米碳管膜10的拉伸方向。該超順排奈米碳管陣列中的奈米碳管純淨且奈米碳管長度較長，一般大於300微米。所述超順排奈米碳管陣列的製備方法不限，可以為化學氣相沉積法、電弧放電製備方法或氣溶膠製備方法等。本實施例中，所述超順排奈米碳管陣列的製備方法採用化學氣相沉積法，其具體步驟包括：（a）提供一基底，該基底可選用P型矽基底、N型矽基底或形成有氧化層的矽基底等；（b）在基底表面均勻形成一催化劑層，該催化劑層材料可選用鐵（Fe）、鈷（Co）、鎳（Ni）或其任意組合的合金之一；（c）將上述形成有催化劑層的基底在700~900℃的空氣中退火約30分鐘~90分鐘；（d）將處理過的基底置於反應爐中，在保護氣體環境下加熱到500~740℃，然後通入碳源氣體反應約5~30分鐘，生長得到超順排奈米碳管陣列，其高度為200~400微米。本實施例中碳源氣可選用乙炔等化學性質較活潑的碳氫化合物，保護氣體可選用氮氣、氨氣或惰性氣體。The super-sequential nano carbon tube film 10 can be directly obtained by pulling from a super-sequential nano carbon tube array. The arrangement direction of the nano carbon nanotubes in the super-sequential nano carbon tube film 10 is substantially parallel to the stretching direction of the super-sequential nano carbon tube film 10. The carbon nanotubes in the super-sequential carbon nanotube array are pure and the carbon nanotubes have a longer length, generally greater than 300 microns. The method for preparing the super-sequential nano carbon tube array is not limited, and may be a chemical vapor deposition method, an arc discharge preparation method, or an aerosol preparation method. In this embodiment, the method for preparing the super-sequential nano-carbon tube array adopts a chemical vapor deposition method, and the specific steps include: (a) providing a substrate, which may be a P-type silicon substrate or an N-type silicon substrate; Or a silicon substrate with an oxidized layer, etc .; (b) a catalyst layer is uniformly formed on the surface of the substrate, and the material of the catalyst layer can be one of iron (Fe), cobalt (Co), nickel (Ni), or any combination thereof (C) annealing the substrate with the catalyst layer formed in the air at 700-900 ° C for about 30 minutes to 90 minutes; (d) placing the treated substrate in a reaction furnace and heating it to 500 in a protective gas environment ~ 740 ℃, and then pass in a carbon source gas to react for about 5 ~ 30 minutes, and grow a super-row nano carbon tube array with a height of 200 ~ 400 microns. In this embodiment, a more active hydrocarbon such as acetylene may be used as the carbon source gas, and nitrogen, ammonia, or an inert gas may be used as the protective gas.

從所述超順排奈米碳管陣列中拉取獲得所述超順排奈米碳管膜10具體包括以下步驟：從上述超順排奈米碳管陣列中選定一定寬度的複數個奈米碳管片斷；以一定速度沿基本垂直於超順排奈米碳管陣列生長方向拉伸該複數個奈米碳管片斷，以形成一連續的所述超順排奈米碳管膜10。Pulling the super-sequential nano carbon tube array to obtain the super-sequential nano carbon tube film 10 specifically includes the following steps: selecting a plurality of nanometers of a certain width from the super-sequential nano-carbon tube array. Carbon tube segments; the plurality of nano carbon tube segments are stretched at a certain speed in a direction substantially perpendicular to the growth direction of the super-row nano-carbon tube array to form a continuous super-row nano-carbon tube film 10.

請參閱圖3~5，當所述第一奈米碳管結構由至少兩層超順排奈米碳管膜10組成時，該至少兩層超順排奈米碳管膜10重疊且平行設置，相鄰兩個超順排奈米碳管膜10之間通過凡得瓦力緊密連接。該至少兩層超順排奈米碳管膜10中每層超順排奈米碳管膜10中奈米碳管的延伸方向與其它層超順排奈米碳管膜10中奈米碳管的延伸方向基本相同，基本相同是指大多數奈米碳管的延伸方向朝同一方向，僅存在少數隨機排列的奈米碳管，這些奈米碳管不會對超順排奈米碳管膜10中大多數奈米碳管的整體延伸方向構成明顯影響，可以忽略。Please refer to FIGS. 3 to 5, when the first nano carbon tube structure is composed of at least two super-sequential nano carbon tube films 10, the at least two super-sequential nano carbon tube films 10 are overlapped and arranged in parallel. The two adjacent super carbon nanotube films 10 are closely connected by Van der Waals force. The extending direction of the carbon nanotubes in each of the at least two layers of the super-sequential carbon nanotube film 10 and the carbon nanotubes in the other layers of the super-sequential carbon nanotube film 10 The extension direction of is basically the same, which means that most of the carbon nanotubes extend in the same direction, and there are only a few randomly arranged carbon nanotubes. These carbon nanotubes will not affect the super-sequence carbon nanotube film. The overall extension direction of most of the carbon nanotubes in 10 constitutes a significant influence and can be ignored.

所述第一奈米碳管結構作為雙面膠應用時，該第一奈米碳管結構中超順排奈米碳管膜10的層數不限，可以根據實際需要進行選擇。優選的，所述第一奈米碳管結構由5～30層超順排奈米碳管膜重疊且平行組成。更優選的，所述第一奈米碳管結構由10～15層超順排奈米碳管膜重疊且平行組成。請參閱圖6，分別採用由1層、2層、4層、6層、8層、10層、12層、15層、30層超順排奈米碳管膜10組成的第一奈米碳管結構作為雙面膠黏結兩個邊長為7毫米的正方形矽片，從圖中可以看出，當兩個矽片之間沒有第一奈米碳管結構時，兩個矽片完全沒有黏結力；隨著第一奈米碳管結構中超順排奈米碳管膜10的層數增加，兩個矽片之間的黏結力增加，當第一奈米碳管結構中超順排奈米碳管膜層數大於15層之後，黏結力隨超順排奈米碳管膜10的層數增加的速率減慢。請參閱圖7，分別採用由4層、6層、15層、20層超順排奈米碳管膜10組成的第一奈米碳管結構作為雙面膠黏結矽片和熱氧化矽片（SiO2 ），從圖中可以看出，隨著第一奈米碳管結構中超順排奈米碳管膜10的層數增加，矽片和熱氧化矽片之間的黏結力增加，當第一奈米碳管結構中超順排奈米碳管膜層數大於15層之後，黏結力隨超順排奈米碳管膜10的層數增加的速率減慢。本實施例中，所述第一奈米碳管結構包括10層超順排奈米碳管膜重疊且平行設置。When the first carbon nanotube structure is applied as a double-sided tape, the number of layers of the super-sequential carbon nanotube film 10 in the first carbon nanotube structure is not limited, and can be selected according to actual needs. Preferably, the first nano carbon tube structure is composed of 5-30 super-sequential nano carbon tube films overlapping and parallel. More preferably, the first nano carbon tube structure is composed of 10 to 15 super-sequential nano carbon tube films overlapping and parallel. Please refer to FIG. 6, the first nano carbon composed of 1-layer, 2-layer, 4-layer, 6-layer, 8-layer, 10-layer, 12-layer, 15-layer, and 30-layer super-nano-carbon nanotube film 10 is used, respectively. The tube structure is used as a double-sided adhesive to bond two square silicon wafers with a length of 7 mm. As can be seen from the figure, when there is no first carbon nanotube structure between the two silicon wafers, the two silicon wafers are not bonded at all. With the increase in the number of layers of the super-semi-row carbon nanotube film 10 in the first nano-carbon tube structure, the adhesion between the two silicon wafers increases. After the number of tube film layers is greater than 15 layers, the rate of adhesion decreases with the increase of the number of layers of the super-sequential nano carbon tube film 10. Referring to FIG. 7, the first carbon nanotube structure composed of four, six, fifteen, and twenty layers of super-sequential carbon nanotube films 10 is used as a double-sided adhesive bonded silicon wafer and a thermally oxidized silicon wafer ( SiO 2 ), it can be seen from the figure that as the number of layers of the super-semi-nano carbon nanotube film 10 in the first nano carbon tube structure increases, the adhesion between the silicon wafer and the thermally oxidized silicon wafer increases. After the number of super-sequential carbon nanotube film layers in a one-nanometer carbon tube structure is greater than 15 layers, the rate of adhesion decreases as the number of super-sequential nano-carbon tube films 10 increases. In this embodiment, the first nano-carbon tube structure includes 10 layers of super-sequential nano-carbon tube films that are overlapped and arranged in parallel.

本發明中的所述第一奈米碳管結構作為雙面膠應用時僅通過凡得瓦力與待黏結物黏結，如果待黏結物表面太粗糙或者表面不乾淨，會降低第一奈米碳管結構與待黏結物之間的凡得瓦力，進而影響雙面膠與待黏結物之間的黏結力。所述第一奈米碳管結構作為雙面膠應用時，優選用於黏結具有乾淨平滑表面的物體，即所述待黏結物的待黏結表面為乾淨平滑的表面。所述乾淨平滑表面是指表面基本不含有雜質且表面粗糙度較小，優選的，所述乾淨平滑表面的表面粗糙度小於等於1.0微米。所述待黏結物可以為乾淨平滑的玻璃、石英片、矽片、PET片等。由於所述第一奈米碳管結構作為雙面膠時僅通過凡得瓦力將物體黏結在一起，當黏結在一起的物體之間需要分開時，只需要施加一定的力即可，該第一奈米碳管結構可以從物體表面去除乾淨，不會對物體表面造成傷害；而且當採用所述第一奈米碳管結構作為雙面膠黏結物體時，如果黏結的位置不是很準確可以隨時進行調整。When the first nano carbon tube structure in the present invention is applied as double-sided adhesive, it is only bonded with the to-be-adhered material by van der Waals force. If the surface of the to-be-adhered material is too rough or the surface is not clean, the first nano carbon will be reduced The van der Waals force between the tube structure and the object to be bonded, which in turn affects the adhesive force between the double-sided tape and the object to be bonded. When the first carbon nanotube structure is applied as a double-sided tape, it is preferably used for bonding objects having a clean and smooth surface, that is, the surface to be bonded of the object to be bonded is a clean and smooth surface. The clean and smooth surface means that the surface contains substantially no impurities and has a small surface roughness. Preferably, the clean and smooth surface has a surface roughness of 1.0 micrometer or less. The object to be bonded may be clean and smooth glass, quartz, silicon, PET, and the like. Since the first carbon nanotube structure is used as double-sided adhesive, the objects are bonded together only by van der Waals force. When the bonded objects need to be separated, only a certain force is required. One nanometer carbon tube structure can be cleaned from the surface of the object without causing damage to the surface of the object; and when the first nanometer carbon tube structure is used as a double-sided adhesive bonding object, if the bonding position is not very accurate, it can be at any time Make adjustments.

本發明第二實施例提供一種第二奈米碳管結構作為雙面膠的應用，該第二奈米碳管結構用於將兩個物體黏結於一體。本實施例中的第二奈米碳管結構與第一實施例中的第一奈米碳管結構基本相同，其不同僅在於，本實施例中的超順排奈米碳管膜由複數個基本朝同一方向延伸的奈米碳管組成，該複數個奈米碳管在其延伸方向上首尾相連。The second embodiment of the present invention provides an application of a second nano carbon tube structure as a double-sided adhesive. The second nano carbon tube structure is used to bond two objects together. The structure of the second carbon nanotube in this embodiment is basically the same as the structure of the first carbon nanotube in the first embodiment. The only difference is that the super-narrow carbon nanotube film in this embodiment consists of a plurality of carbon nanotube films. The carbon nanotubes extend in the same direction, and the carbon nanotubes are connected end to end in the extending direction.

本實施例中的複數個奈米碳管為純奈米碳管，純奈米碳管是指奈米碳管未經過任何物理、化學等修飾，奈米碳管的表面純淨（純淨度達到99.9%以上），基本不含有雜質，如無定型碳或殘留的催化劑金屬顆粒等。The plurality of carbon nanotubes in this embodiment are pure carbon nanotubes. Pure carbon nanotubes refer to the carbon nanotubes without any physical or chemical modification. The surface of the carbon nanotubes is pure (purity of 99.9%). % Or more), basically contains no impurities, such as amorphous carbon or residual catalyst metal particles.

本發明第三實施例提供一第三奈米碳管結構作為雙面膠的應用，該第三奈米碳管結構用於將兩個物體黏結於一體。本實施例中的第三奈米碳管結構與第一實施例中的第一奈米碳管結構基本上相同，其不同僅在於，該第三奈米碳管結構由複數個奈米碳管組成，該複數個奈米碳管首尾相連且沿同一方向延伸，且延伸方向平行於雙面膠的長度方向，所述複數個奈米碳管通過凡得瓦力相互連接。The third embodiment of the present invention provides a third nano carbon tube structure as a double-sided adhesive. The third nano carbon tube structure is used to bond two objects together. The structure of the third carbon nanotube in this embodiment is basically the same as the structure of the first carbon nanotube in the first embodiment, except that the structure of the third carbon nanotube is composed of a plurality of carbon nanotubes. The plurality of nano carbon tubes are connected end to end and extend in the same direction, and the extending direction is parallel to the length direction of the double-sided tape, and the plurality of nano carbon tubes are connected to each other by Van der Waals force.

本實施例中的複數個奈米碳管為純奈米碳管，純奈米碳管是指奈米碳管未經過任何物理、化學等修飾，奈米碳管的表面純淨（純淨度達到99.9%以上），基本不含有雜質，如無定型碳或殘留的催化劑金屬顆粒等。The plurality of carbon nanotubes in this embodiment are pure carbon nanotubes. Pure carbon nanotubes refer to the carbon nanotubes without any physical or chemical modification. The surface of the carbon nanotubes is pure (purity of 99.9%). % Or more), basically contains no impurities, such as amorphous carbon or residual catalyst metal particles.

綜上所述，本發明確已符合發明專利之要件，遂依法提出專利申請。惟，以上所述者僅為本發明之較佳實施例，自不能以此限制本案之申請專利範圍。舉凡習知本案技藝之人士援依本發明之精神所作之等效修飾或變化，皆應涵蓋於以下申請專利範圍內。In summary, the present invention has indeed met the requirements for an invention patent, and a patent application was filed in accordance with the law. However, the above is only a preferred embodiment of the present invention, and it cannot be used to limit the scope of patent application in this case. Any equivalent modification or change made by those who are familiar with the skills of this case with the aid of the spirit of the present invention shall be covered by the scope of the following patent applications.

10‧‧‧超順排奈米碳管膜 10‧‧‧Nano Carbon Tube Film

100‧‧‧奈米碳管 100‧‧‧nanometer carbon tube

圖1為為本發明實施例提供的超順排奈米碳管膜的俯視結構示意圖。FIG. 1 is a schematic plan view of a super-semi-nano-carbon nanotube film according to an embodiment of the present invention.

圖2為本發明實施例提供的超順排奈米碳管膜的掃描電子顯微鏡照片。FIG. 2 is a scanning electron microscope photograph of a super-sequential nano carbon tube film provided by an embodiment of the present invention.

圖3為本發明實施例提供的奈米碳管結構包括8層超順排奈米碳管膜時的掃描電子顯微鏡照片。FIG. 3 is a scanning electron microscope photograph when the structure of the nano carbon tube provided in the embodiment of the present invention includes eight super-sequential nano carbon tube films.

圖4為本發明實施例提供的奈米碳管結構包括50層超順排奈米碳管膜時的掃描電子顯微鏡照片。FIG. 4 is a scanning electron microscope photograph when the structure of the nano-carbon tube provided by the embodiment of the present invention includes 50 layers of super-sequential nano-carbon tube film.

圖5為本發明實施例提供的奈米碳管結構包括至少兩層超順排奈米碳管膜時的結構示意圖。FIG. 5 is a schematic structural diagram when a nano carbon tube structure according to an embodiment of the present invention includes at least two super-sequential nano carbon tube films.

圖6為本發明實施例提供的矽片表面張力隨奈米碳管結構中超順排奈米碳管層數的變化曲線。FIG. 6 is a variation curve of the surface tension of a silicon wafer according to the embodiment of the present invention as a function of the number of super-sequential nano-carbon tubes in a nano-carbon tube structure.

圖7為本發明實施例提供的熱氧化矽片表面張力隨奈米碳管結構中超順排奈米碳管層數的變化曲線。FIG. 7 is a variation curve of the surface tension of the thermally oxidized silicon wafer according to the embodiment of the present invention as a function of the number of super-sequential carbon nanotube layers in the carbon nanotube structure.

無no

Claims (10)

一種奈米碳管結構作為雙面膠的應用，其中，該奈米碳管結構用於將兩個物體黏結於一體，該奈米碳管結構包括一第一黏結面及一第二黏結面，第一黏結面和第二黏結面相對設置；該奈米碳管結構由至少一層超順排奈米碳管膜組成，該至少一層超順排奈米碳管膜包括複數個奈米碳管，該複數個奈米碳管的延伸方向基本相同且通過范德華力相互連接，該延伸方向平行於所述第一黏結面和第二黏結面。A nano carbon tube structure is used as a double-sided adhesive. The nano carbon tube structure is used to bond two objects together. The nano carbon tube structure includes a first bonding surface and a second bonding surface. The first bonding surface and the second bonding surface are oppositely arranged; the nano-carbon tube structure is composed of at least one super-row nano-carbon tube film, and the at least one super-row nano-carbon tube film includes a plurality of nano-carbon tubes, The extending directions of the plurality of nano carbon tubes are substantially the same and are connected to each other by Van der Waals force. The extending directions are parallel to the first bonding surface and the second bonding surface. 如請求項1所述的奈米碳管結構作為雙面膠的應用，其中，所述奈米碳管結構作為雙面膠的應用溫度範圍為-196℃～1000℃。The application of the carbon nanotube structure as a double-sided adhesive according to claim 1, wherein the application temperature range of the carbon nanotube structure as a double-sided adhesive is -196 ° C to 1000 ° C. 如請求項1所述的奈米碳管結構作為雙面膠的應用，其中，所述奈米碳管結構由5~30層超順排奈米碳管膜重疊且平行組成。The application of the nanometer carbon tube structure according to claim 1 as a double-sided adhesive, wherein the nanometer carbon tube structure is composed of 5-30 layers of super-sequential nanometer carbon tube films overlapping and parallel. 如請求項3所述的奈米碳管結構作為雙面膠的應用，其中，所述奈米碳管結構由10~15層超順排奈米碳管膜重疊且平行組成。The application of the nanometer carbon tube structure according to claim 3 as a double-sided adhesive, wherein the nanometer carbon tube structure is composed of 10 to 15 super-sequential nanometer carbon tube films overlapping and parallel. 如請求項1所述的奈米碳管結構作為雙面膠的應用，其中，所述超順排奈米碳管膜中的複數個奈米碳管為純奈米碳管。The application of the nano carbon tube structure according to claim 1 as a double-sided adhesive, wherein the plurality of nano carbon tubes in the super-sequential nano carbon tube film are pure nano carbon tubes. 如請求項1所述的奈米碳管結構作為雙面膠的應用，其中，所述第一黏結面以及第二黏結面僅通過范德華力與物體黏結。The application of the nano-carbon tube structure according to claim 1 as a double-sided adhesive, wherein the first bonding surface and the second bonding surface are bonded to the object only by Van der Waals force. 如請求項1所述的奈米碳管結構作為雙面膠的應用，其中，所述超順排奈米碳管膜由複數個基本朝同一方向延伸的奈米碳管組成，該複數個奈米碳管在其延伸方向上首尾相連。The application of the nano carbon tube structure according to claim 1 as a double-sided adhesive, wherein the super-sequential nano carbon tube film is composed of a plurality of nano carbon tubes extending substantially in the same direction, and the plurality of carbon nanotubes The carbon tube is connected end to end in its extension direction. 如請求項1所述的奈米碳管結構作為雙面膠的應用，其中，對黏結於一體的兩個物體施加一外力，該黏結於一體的兩個物體分開，且所述奈米碳管結構從物體表面去除乾淨。The application of the nano carbon tube structure according to claim 1 as a double-sided adhesive, wherein an external force is applied to two objects bonded together, the two objects bonded together are separated, and the nano carbon tube is The structure is removed from the surface of the object. 如請求項1所述的奈米碳管結構作為雙面膠的應用，其中，用於黏結待黏結表面為乾淨平滑表面的物體。The application of the nano-carbon tube structure as described in claim 1 as a double-sided adhesive, wherein the nano-carbon tube structure is used for bonding objects with a clean and smooth surface to be bonded. 一種奈米碳管結構作為雙面膠的應用，其中，該奈米碳管結構用於將兩個物體黏結於一體，該奈米碳管結構由複數個奈米碳管組成，該複數個奈米碳管首尾相連且沿同一方向延伸，且延伸方向平行於雙面膠的長度方向，所述複數個奈米碳管通過范德華力相互連接。An application of a nano carbon tube structure as double-sided adhesive, wherein the nano carbon tube structure is used to bond two objects together, the nano carbon tube structure is composed of a plurality of nano carbon tubes, and the plurality of carbon nanotubes are The carbon nanotubes are connected end to end and extend in the same direction, and the extending direction is parallel to the length direction of the double-sided tape. The plurality of nano carbon tubes are connected to each other by Van der Waals force.
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