TW201920692A - Top-blowing lance for converter blowing and molten iron refining method - Google Patents

Top-blowing lance for converter blowing and molten iron refining method Download PDF

Info

Publication number
TW201920692A
TW201920692A TW107128299A TW107128299A TW201920692A TW 201920692 A TW201920692 A TW 201920692A TW 107128299 A TW107128299 A TW 107128299A TW 107128299 A TW107128299 A TW 107128299A TW 201920692 A TW201920692 A TW 201920692A
Authority
TW
Taiwan
Prior art keywords
blowing
spray gun
nozzle
flow path
molten iron
Prior art date
Application number
TW107128299A
Other languages
Chinese (zh)
Other versions
TWI665308B (en
Inventor
田村鐵平
小野慎平
Original Assignee
日商新日鐵住金股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日商新日鐵住金股份有限公司 filed Critical 日商新日鐵住金股份有限公司
Publication of TW201920692A publication Critical patent/TW201920692A/en
Application granted granted Critical
Publication of TWI665308B publication Critical patent/TWI665308B/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • C21C5/42Constructional features of converters
    • C21C5/46Details or accessories
    • C21C5/4606Lances or injectors
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • C21C5/30Regulating or controlling the blowing
    • C21C5/35Blowing from above and through the bath
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • C21C5/42Constructional features of converters
    • C21C5/46Details or accessories
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)
  • Furnace Charging Or Discharging (AREA)

Abstract

The present invention satisfies 0.19 ≤ L/L0 ≤ 0.82, where L0, given a cross section including the center axis of a lance and bisecting a boundary plane between a flow path of a lance inner tube and a nozzle hole, is the length of a line segment which passes through the most downstream point of the lance on the boundary plane and traverses the nozzle hole on a straight line perpendicular to the lance center axis, and L is the length of said traversing line segment when projected within the range of the flow path of the lance inner tube on a horizontal cross section taken perpendicular to the lance center axis.

Description

轉爐吹煉用頂吹噴槍及熔鐵的精煉方法Top-blowing spray gun for converter blowing and refining method of molten iron

發明領域 本發明是有關於一種在製鋼用轉爐中,將精煉用氣體及粉體噴灑到熔鐵浴面以進行吹煉時所使用的轉爐吹煉用頂吹噴槍、及使用該轉爐吹煉用頂吹噴槍之熔鐵的精煉方法。FIELD OF THE INVENTION The present invention relates to a top-blowing spray gun for converter blowing used for spraying refining gas and powder onto a molten iron bath surface in a steel-making converter, and to use the converter for blowing Refining method of molten iron for top-blowing lances.

發明背景 例如,在氧氣頂吹轉爐製鋼法中之預備脫磷精煉中,使用了將生石灰等之粉體與氧氣射流一起噴灑至溶鐵的表面的方法。此時,將粉體噴入至氧氣射流與熔鐵的碰撞面、所謂的火點,促進渣化並且提高反應效率。因此,該方法中,必須盡可能以高速度噴入粉體,確實地到達火點。BACKGROUND OF THE INVENTION For example, in the preliminary dephosphorization refining in an oxygen top-blown converter steelmaking method, a method in which powder of quicklime or the like is sprayed on the surface of molten iron together with an oxygen jet is used. At this time, the powder is sprayed into the collision surface of the oxygen jet and the molten iron, the so-called fire point, to promote slagging and improve the reaction efficiency. Therefore, in this method, it is necessary to inject the powder at a high speed as much as possible to reach the fire point reliably.

但是,使粉體噴入速度增加時,則粉體造成噴嘴的磨耗成為問題。噴嘴磨耗持續進行而在用以冷卻噴嘴之冷卻水的流路開孔,引起冷卻水漏水時,會成為重大的操作阻害,招致生產性的降低。又,噴嘴的磨耗變得顯著時,也會有精煉行為變化且吹煉控制變困難的問題。不僅是預備脫磷精煉,在對未施行預備脫磷精煉之熔鐵或已經施行預備脫磷精煉之熔鐵施行脫碳精煉時,從頂吹噴槍噴入生石灰或礦物等之粉體時有同樣的課題。However, when the powder injection speed is increased, abrasion of the nozzle by the powder becomes a problem. Nozzle abrasion continues, and openings in the flow path of the cooling water used to cool the nozzles cause leakage of the cooling water, which will become a major operational obstacle, resulting in a reduction in productivity. Moreover, when the abrasion of a nozzle becomes remarkable, there exists a problem that a refining behavior changes and a blowing control becomes difficult. Not only for preliminary dephosphorization refining, but also for decarburization refining of molten iron that has not been subjected to preliminary dephosphorization refining or molten iron that has been subjected to preliminary dephosphorization refining, the same applies when spraying powder of quicklime or minerals from a top-blowing lance. Subject.

因此,為了解決該課題,例如,在專利文獻1中,已經揭示了在噴嘴孔之內表面施行利用電鍍之鍍硬鉻,以抑制磨耗的方法。然而,在此揭示的方法雖然可提高噴嘴之耐磨耗性,但無法抑制粉體往噴嘴孔內表面碰撞本身。又,往噴嘴孔內施行鍍硬鉻難以說是簡易的方法。Therefore, in order to solve this problem, for example, in Patent Document 1, a method has been disclosed in which hard chromium plating by electroplating is performed on the inner surface of the nozzle hole to suppress wear. However, although the method disclosed herein can improve the abrasion resistance of the nozzle, it cannot prevent the powder from colliding with the inner surface of the nozzle hole. In addition, it is difficult to say that it is easy to apply hard chromium plating to the nozzle holes.

進而,從在實際操作中抑制噴渣的觀點,由於使射流之動壓分散,一般對噴嘴賦予傾斜角而多孔化。因此,認為是粉體所致之噴嘴的磨耗也與噴嘴之配置或噴嘴傾斜角度息息相關。例如,若使用單孔噴嘴,與氧氣一起通過噴嘴內的粉體大部分可推定為即使粉體未順著氣流而直線前進,也不會衝撞到噴嘴內壁,難以磨耗。另一方面,若是多孔噴嘴的情況,由於噴嘴內壁相對於噴槍內管之軸方向成角度,因此若粉體沒有順著氣流,則會確實地碰撞到噴嘴內壁,故容易磨耗。因此,不論噴嘴的材質為何,都需要以多孔噴槍構造為前提以抑制粉體所致之噴嘴磨耗的技術。Furthermore, from the viewpoint of suppressing slag blasting in actual operation, since the dynamic pressure of the jet flow is dispersed, an inclination angle is generally given to the nozzle to make it porous. Therefore, it is thought that the wear of the nozzle caused by the powder is also closely related to the arrangement of the nozzle or the tilt angle of the nozzle. For example, if a single-hole nozzle is used, most of the powder passing through the nozzle with oxygen can be estimated to prevent the powder from colliding with the inner wall of the nozzle even if it does not follow the air flow, making it difficult to wear. On the other hand, in the case of a porous nozzle, the inner wall of the nozzle is angled with respect to the axial direction of the inner tube of the spray gun. Therefore, if the powder does not follow the air flow, it will definitely collide with the inner wall of the nozzle, which is easy to wear. Therefore, regardless of the material of the nozzle, a technology based on a porous spray gun structure to suppress nozzle wear caused by powder is required.

以多孔噴槍構造為前提的技術,例如,在專利文獻2記載了方法如下:在從頂吹噴槍噴入粉體時,調整噴嘴喉部之橫截面積之總和與噴槍內管流路之橫截面積的比,以改變粉體通過噴嘴部時的分布。可是,該方法是以抑制噴渣為目的,並未記載與抑制噴嘴磨耗的關係。又,由於噴嘴內壁相對於噴槍內管之軸方向具有角度,因此即使可改變粉體通過噴嘴部時的分布,還是會如前所述,粉體碰撞到噴嘴內壁的可能性高,難以抑制噴嘴孔的磨耗。 先行技術文獻 專利文獻The technology premised on the structure of a porous spray gun, for example, describes in Patent Document 2 that when spraying powder from a top-blown spray gun, the sum of the cross-sectional area of the throat of the nozzle and the cross-section of the inner tube flow path of the spray gun are adjusted. Area ratio to change the distribution of powder as it passes through the nozzle. However, this method is for the purpose of suppressing slag blasting, and the relationship with suppressing nozzle wear is not described. In addition, since the inner wall of the nozzle has an angle with respect to the axial direction of the inner tube of the spray gun, even if the distribution of the powder passing through the nozzle portion can be changed, as described above, the possibility of the powder colliding with the inner wall of the nozzle is high and it is difficult Suppress wear of nozzle holes. Prior technical literature Patent literature

[專利文獻1]特開2003-213318號公報 [專利文獻2]特開2012-251199號公報[Patent Document 1] JP 2003-213318 [Patent Document 2] JP 2012-251199

發明概要 發明欲解決之課題 本發明是有鑑於前述的問題點,目的在於提供一種噴嘴內壁相對於噴槍內管之軸方向具有角度且具有多孔噴嘴,可抑制該等噴嘴孔之磨耗的轉爐吹煉用頂吹噴槍及使用該轉爐吹煉用頂吹噴槍之熔鐵的精煉方法。 用以解決課題之手段SUMMARY OF THE INVENTION Problems to be Solved by the Invention The present invention has been made in view of the foregoing problems, and an object thereof is to provide a converter blower having an inner wall of a nozzle having an angle with respect to the axial direction of the inner tube of the spray gun and having a porous nozzle, which can suppress the wear of these nozzle holes Refining top-blowing lance and method for refining molten iron using the converter-blowing top-blowing lance. Means to solve the problem

從頂吹噴槍將粉體副原料與含氧氣體一起頂吹時,通常,在頂吹噴槍之上端部連接有含氧氣體之配管與粉體副原料之配管,因此含氧氣體與粉體副原料會混合。而且,含氧氣體及粉體副原料之混合體通過1支噴槍內管的內部,從連接於噴槍內管之前端的噴嘴部之1個或2個以上的噴出孔(噴嘴孔)噴出。When the powder sub-material is top-blown with an oxygen-containing gas from a top-blowing lance, usually, an oxygen-containing gas pipe and a powder sub-material piping are connected to the upper end of the top-blowing lance. The ingredients are mixed. In addition, the mixture of the oxygen-containing gas and the powder auxiliary material passes through one of the inner tubes of the spray gun, and is sprayed from one or more nozzle holes (nozzle holes) connected to the front end of the nozzle inner tube.

本發明人們檢討如下:使用具有如後述之多孔噴嘴、即噴嘴內壁相對於噴槍內管之軸方向具有角度的多孔噴嘴、也就是噴嘴孔之中心軸相對於噴槍內管具有之含氧氣體及粉體副原料之流路的中心軸而傾斜的多孔噴嘴的頂吹噴槍時,藉由噴嘴孔與噴槍內管之流路的接合位置來控制粉體行為,抑制噴嘴磨耗。以下,在噴槍內管流路之內壁面中,將噴槍內管之流路與噴嘴孔之邊界部所區隔出之假想的噴槍內管之流路的內壁面表現為「邊界面」。The present inventors reviewed as follows: the use of a porous nozzle having a porous nozzle as described later, that is, an inner wall of the nozzle having an angle with respect to the axial direction of the inner tube of the spray gun, that is, a central axis of the nozzle hole with respect to the oxygen-containing gas and In the case of a top-blowing spray gun with a porous nozzle inclined by the central axis of the flow path of the powder auxiliary material, the powder behavior is controlled by the joint position of the nozzle hole and the flow path of the inner tube of the spray gun to suppress nozzle wear. In the following, the inner wall surface of the imaginary spray gun inner tube flow path which separates the spray gun inner tube flow path from the boundary portion of the nozzle hole in the inner wall surface of the spray gun inner tube flow path will be referred to as a "boundary surface".

圖1顯示了相對於1個噴嘴,含有噴槍中心軸,且將上述之邊界面二等分的截面。圖1中,將在邊界面上通過噴槍之最下游側的點,與噴槍中心軸垂直的直線定義為直線A。而且,將在該直線A上橫截噴嘴孔的線段定義為橫截線段B。進而,將橫截線段B在噴槍內管之流路的範圍內往與噴槍中心軸垂直的橫截面投影時投影在橫截面上的線段定義為線段C。本發明人們發現,藉由橫截線段B之長度L0 與線段C之長度L的比L/L0 滿足述式(1),可抑制噴嘴磨耗。又,若是具有多孔噴嘴之頂吹噴槍的情況,由噴槍中心軸傾斜之所有的噴嘴滿足下述式(1)。 0.19≦L/L0 ≦0.82   ・・・(1)FIG. 1 shows a cross section that includes the center axis of the spray gun and bisects the above-mentioned boundary surface with respect to one nozzle. In FIG. 1, a straight line passing through a point on the boundary surface of the spray gun at the most downstream side and perpendicular to the central axis of the spray gun is defined as a straight line A. Further, a line segment that crosses the nozzle hole on the straight line A is defined as a cross-section line segment B. Further, a line segment projected on the cross-section when the cross-section line segment B is projected on a cross-section perpendicular to the center axis of the spray gun within the range of the flow path of the inner pipe of the spray gun is defined as a line segment C. The inventors have found that nozzle wear can be suppressed by the ratio L / L 0 of the length L 0 of the cross-sectional line segment B and the length L of the line segment C satisfying the expression (1). In the case of a top-blowing spray gun having a perforated nozzle, all the nozzles inclined from the center axis of the spray gun satisfy the following formula (1). 0.19 ≦ L / L 0 ≦ 0.82 ・ ・ ・ (1)

本發明如下。 [1]一種轉爐吹煉用頂吹噴槍,是在將熔鐵裝入至頂底吹轉爐,並從頂吹噴槍將粉體副原料與含氧氣體一起噴附於熔鐵而進行吹煉時所使用的轉爐吹煉用頂吹噴槍,其特徵在於具備: 噴槍內管,具有前述含氧氣體及前述粉體副原料之流路;及 噴嘴部,連通於該噴槍內管之前述流路而延伸設置,且具有2孔以上之噴嘴孔, 前述噴嘴孔之噴嘴中心軸是相對於前述流路之噴槍中心軸傾斜,且前述噴嘴孔分別滿足以下之式(1): 0.19≦L/L0 ≦0.82   ...(1) 在此,L0 :在包含前述噴槍中心軸,且將前述噴槍內管之流路與前述噴嘴孔之邊界面二等分的截面中,在前述邊界面上通過噴槍之最下游側之點,且在垂直於前述噴槍中心軸的直線上將前述噴嘴孔橫截之線段的長度, L:在前述噴槍內管之流路的範圍內,將前述橫截之線段往垂直於前述噴槍中心軸的橫截面投影時,投影到前述橫截面上之線段的長度。 [2]一種熔鐵的精煉方法,是使用上述[1]記載之轉爐吹煉用頂吹噴槍進行吹煉之熔鐵的精煉方法,其特徵在於: 將熔鐵裝入至頂底吹轉爐,並從前述轉爐吹煉用頂吹噴槍將粉體副原料與含氧氣體一起噴附於前述熔鐵而進行吹煉。 發明效果The present invention is as follows. [1] A top-blowing spray gun for converter blowing is performed when the molten iron is charged into the top-bottom blowing converter, and the powdery raw materials are sprayed together with the oxygen-containing gas from the top-blowing spray gun to the molten iron for blowing. The top-blowing spray gun used for converter blowing is characterized by comprising: an inner tube of the spray gun, which has a flow path for the oxygen-containing gas and the powder auxiliary material; and a nozzle section, which communicates with the aforementioned flow path for the inner tube of the spray gun. It is extended and has two or more nozzle holes. The nozzle central axis of the nozzle hole is inclined with respect to the central axis of the spray gun of the flow path, and the nozzle holes respectively satisfy the following formula (1): 0.19 ≦ L / L 0 ≦ 0.82 ... (1) Here, L 0 : A cross section including the central axis of the spray gun and bisecting the flow path of the inner tube of the spray gun and the boundary surface of the nozzle hole is passed on the boundary surface The point of the most downstream side of the spray gun, and the length of the line segment crossing the nozzle hole on a straight line perpendicular to the center axis of the spray gun, L: within the range of the flow path of the inner pipe of the spray gun, Projected into a cross section perpendicular to the central axis of the aforementioned spray gun , The projected length of the segment of the cross section. [2] A method for refining molten iron, which is a method for refining molten iron using a top-blowing spray gun for converter blowing described in the above [1], characterized in that: the molten iron is charged into a top-bottom blowing converter, Then, the powdery raw material and the oxygen-containing gas are sprayed onto the molten iron from the top-blowing spray gun for converter blowing, and the blowing is performed. Invention effect

根據本發明,可抑制將含氧氣體及粉體副原料進行頂吹所致之噴嘴的磨耗,可加長精煉用噴槍的耐磨耗壽命。According to the present invention, it is possible to suppress the abrasion of the nozzle caused by the oxygen-containing gas and the powder auxiliary material being subjected to top blowing, and to extend the wear life of the refining spray gun.

較佳實施例之詳細說明 以下,就本發明之實施形態,一面參照圖式一面進行說明。本發明之轉爐吹煉用頂吹噴槍是在將含氧氣體與粉體副原料一起噴附到裝入轉爐之熔鐵而進行吹煉時使用。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT Hereinafter, an embodiment of the present invention will be described with reference to the drawings. The top-blowing lance for converter blowing of the present invention is used when spraying an oxygen-containing gas together with a powder auxiliary material to molten iron which is charged into the converter for blowing.

圖2是多孔噴槍之前端部分的截面概略圖。例202是本發明之頂吹噴槍1之前端部分的截面概略圖,與圖1之例102對應。也就是說,例202所示之截面是包含噴槍中心軸2d,且將邊界面4二等分的截面。另一方面,圖2之例201是第1比較例即頂吹噴槍5之前端部分的截面概略圖,與圖1之例101對應。也就是說,圖2之例201所示的截面是包含噴槍中心軸6d,且將邊界面8二等分的截面。進而,圖2之例203是第2比較例即頂吹噴槍9之前端部分的截面概略圖,與圖1之例103對應。也就是說,圖2之例203所示之截面是包含噴槍中心軸10d,且將邊界面12二等分的截面。再者,在圖2所示之例中,為了易於說明,就2孔的多孔噴槍,省略其中一方的孔來圖示。又,圖2之例204~206是分別顯示了圖2之例201~203之噴槍內管之流路之範圍內的A-A截面圖。又,圖2所示之例中,為了簡化說明,圖2之例202之噴嘴中心軸3c、圖2之例201之噴嘴中心軸7c及圖2之例203之噴嘴中心軸11c的傾斜角θ是相同的。又,圖2所示之例中,雖然沒有圖示,但在頂吹噴槍(噴槍內管及噴嘴部)之內壁面與外壁面之間,設置有用以冷卻頂吹噴槍之冷卻水的流路。Fig. 2 is a schematic cross-sectional view of a front end portion of the porous spray gun. Example 202 is a schematic cross-sectional view of the front end portion of the top-blowing lance 1 of the present invention, and corresponds to Example 102 of FIG. 1. That is, the cross section shown in Example 202 is a cross section including the center axis 2d of the spray gun and dividing the boundary surface 4 in half. On the other hand, the example 201 of FIG. 2 is a schematic cross-sectional view of the front end portion of the top blowing spray gun 5 as the first comparative example, and corresponds to the example 101 of FIG. 1. That is, the cross section shown in the example 201 of FIG. 2 is a cross section including the spray gun central axis 6d and dividing the boundary surface 8 in half. Furthermore, the example 203 of FIG. 2 is a schematic cross-sectional view of the front end portion of the top-blowing lance 9 as the second comparative example, and corresponds to the example 103 of FIG. 1. That is, the cross section shown in Example 203 of FIG. 2 is a cross section including the center axis 10d of the spray gun and dividing the boundary surface 12 in half. In addition, in the example shown in FIG. 2, for ease of explanation, a two-hole multi-hole spray gun is omitted for illustration. In addition, the examples 204 to 206 in FIG. 2 are A-A cross-sectional views showing the ranges of the flow paths of the inner tubes of the spray guns in the examples 201 to 203 in FIG. 2, respectively. In the example shown in FIG. 2, for the sake of simplicity, the inclination angle θ of the nozzle central axis 3c of the example 202 of FIG. 2, the nozzle central axis 7c of the example 201 of FIG. 2, and the nozzle central axis 11c of the example 203 of FIG. 2. Are the same. In the example shown in FIG. 2, although not shown, a flow path for cooling water for cooling the top-blowing lance is provided between the inner wall surface and the outer wall surface of the top-blowing lance (inner tube and nozzle portion of the lance). .

如圖2之例202所示,頂吹噴槍1具備噴槍內管2及噴嘴部3。 噴槍內管2主要是鐵製,具有噴附到容置於轉爐型精煉容器之熔鐵的含氧氣體(以下,有時候單稱為「氣體」。)及粉體副原料(以下,有時候單稱為「粉體」。)之混合體的流路2a。流路2a到噴嘴部3為止,呈具有大略均一之內徑的管狀,且呈相對於氣體及粉體的進行方向,流路2a之截面積不急遽變化的形狀。As shown in Example 202 of FIG. 2, the top-blowing spray gun 1 includes a spray gun inner tube 2 and a nozzle portion 3. The inner tube 2 of the spray gun is mainly made of iron, and has an oxygen-containing gas (hereinafter, sometimes simply referred to as "gas") sprayed into molten iron contained in a converter-type refining container, and a powder auxiliary material (hereinafter, sometimes It is simply referred to as "powder".) Of the mixed flow path 2a. The flow path 2a to the nozzle portion 3 has a tubular shape having a substantially uniform inner diameter, and has a shape in which the cross-sectional area of the flow path 2a does not change rapidly with respect to the direction of the gas and powder.

再者,如圖2之例202所示,邊界面4是在流路2a之內壁面2b中,以流路2a與噴嘴孔3a之邊界部2c所區隔之假想的噴槍內管2之流路2a的內壁面。又,如圖2之例205所示,在噴槍內管2之流路2a之範圍內將邊界面4投影至垂直於噴槍中心軸2d的橫截面13時,形成以邊界線2c’所包圍的投影面14。邊界線2c’是將邊界部2c投影到橫截面13的線。Furthermore, as shown in Example 202 of FIG. 2, the boundary surface 4 is the flow of a hypothetical inner tube 2 of the inner wall surface 2 b of the flow path 2 a separated by the boundary portion 2 c of the flow path 2 a and the nozzle hole 3 a. The inner wall surface of the road 2a. As shown in Example 205 of FIG. 2, when the boundary surface 4 is projected onto the cross section 13 perpendicular to the central axis 2d of the spray gun within the range of the flow path 2a of the inner pipe 2 of the spray gun, a boundary surrounded by a boundary line 2c ′ is formed. Projection surface 14. The boundary line 2c 'is a line that projects the boundary portion 2c onto the cross section 13.

噴嘴部3主要是銅製,具有噴嘴孔3a。噴嘴孔3a的形狀亦可為圓筒形(直管噴嘴),亦可為所謂的拉瓦形(拉瓦噴嘴(Laval nozzle)。噴嘴孔3a是如圖2之例202所示,在噴槍內管2之流路2a的端部,隔著邊界部2c而與流路2a連通延伸設置。流路2a與噴嘴孔3a接合的位置是如圖1所示之線段C的長度L與橫截線段B的長度L0 之關係滿足了前述式(1)的位置。這是根據如下的構思所得的看法。The nozzle portion 3 is mainly made of copper and has a nozzle hole 3a. The shape of the nozzle hole 3a may be a cylindrical shape (straight tube nozzle) or a so-called laval nozzle (Laval nozzle). The nozzle hole 3a is shown in Example 202 in FIG. The end of the flow path 2a of the tube 2 is extended to communicate with the flow path 2a through the boundary portion 2c. The position where the flow path 2a and the nozzle hole 3a are joined is the length L and the cross-section of the line segment C shown in FIG. The relationship of the length L 0 of B satisfies the position of the aforementioned formula (1). This is a view based on the following concept.

與氣體一起通過噴槍內管之流路並從噴嘴孔噴出的粉體大致區分的話,是分成「在侵入到噴嘴孔內以前與流路之內壁面碰撞的粉體」與「不與流路之內壁面碰撞而直接侵入到噴嘴孔內的粉體」。本發明人們將2.5t規模之轉爐進行之粉體頂吹實驗時的噴槍磨耗實態、與藉由流動分析所得之氣體及粉體行為對照的結果,「不與流路之內壁面碰撞而直接侵入到噴嘴孔內之粉體」的行為與磨耗行為是類似的。根據以上,本發明人們認為若藉由變更噴嘴部的形狀,使「不與流路之內壁面碰撞而直接侵入到噴嘴孔內的粉體」的比例減少,可抑制粉體造成之噴嘴內壁面的磨耗。The powder that passes through the flow path of the inner tube of the gun with the gas and is ejected from the nozzle hole is roughly divided into "powder that collided with the inner wall surface of the flow path before entering the nozzle hole" and "not in the flow path." The powder that collides with the inner wall surface and directly penetrates into the nozzle hole. " The present inventors compared the actual results of the abrasion of the spray gun during a 2.5t-scale converter top-blown experiment with the behavior of the gas and powder obtained by flow analysis. "It does not directly collide with the inner wall surface of the flow path. The behavior of the powder intruding into the nozzle hole is similar to that of abrasion. Based on the above, the present inventors believe that by changing the shape of the nozzle portion, the proportion of "powder that directly penetrates into the nozzle hole without colliding with the inner wall surface of the flow path" can be reduced, and the inner wall surface of the nozzle caused by the powder can be suppressed. Abrasion.

首先,假設氣體與粉體相對於流路之中心軸方向均一地在噴槍內管之流路流動。此種情況下,將噴槍內管之流路與噴嘴部之噴嘴孔的邊界面往噴槍內管之流路之橫截面投影時,若縮小其投影面上之線段C的長度L,則在通過噴嘴孔之全粉體內所占的「不碰撞到流路的內壁面而直接侵入到噴嘴孔內的粉體」的比例會減少,並且碰撞到噴嘴孔之內壁面的粉體量降低,因此有抑制噴嘴磨耗的可能性。First, it is assumed that the gas and powder flow uniformly in the flow path of the inner tube of the spray gun with respect to the center axis direction of the flow path. In this case, when the boundary surface of the flow path of the inner tube of the spray gun and the nozzle hole of the nozzle section is projected to the cross section of the flow path of the inner tube of the spray gun, if the length L of the line segment C on the projection surface is reduced, The proportion of "powder that directly penetrates into the nozzle hole without colliding with the inner wall surface of the flow path" in the entire powder body of the nozzle hole will decrease, and the amount of powder that hits the inner wall surface of the nozzle hole will decrease. Suppresses nozzle wear.

另一方面,當投影面上之線段C之長度L為0或者過小時,線段C的長度L變得遠小於噴嘴孔3a中之橫截線段B的長度L0 。其結果可能是在氣體及粉體之流動產生偏流,「不碰撞到流路的內壁面而直接侵入到噴嘴孔內的粉體」碰撞到噴嘴孔之內壁面,反而招致磨耗。On the other hand, when the length L of the line segment C on the projection plane is 0 or too small, the length L of the line segment C becomes much smaller than the length L 0 of the cross-sectional line segment B in the nozzle hole 3a. As a result, a biased flow may occur in the flow of gas and powder. "Powder that directly invades into the nozzle hole without colliding with the inner wall surface of the flow path" collides with the inner wall surface of the nozzle hole, causing wear.

例如,在圖2之例201所示之頂吹噴槍5中,噴嘴孔7a與流路6a的邊界面8位於流路6a的側面。因此,如圖2之例204所示,往垂直於噴槍中心軸6d的橫截面15,投影邊界面8時,投影面的面積幾乎為0。也就是說,如圖1之例101所示,線段C本身不存在,因此L=0。此種情況下,雖然「不碰撞到流路的內壁面而直接侵入到噴嘴孔內的粉體」的比例降低,但產生如圖2之例201所示之偏流,如圖2之例201因與圖2之例203不同的機制,噴嘴孔之上側的內壁面7b會磨耗。也就是說,藉由產生偏流,在噴嘴孔7a內,氣體及粉體之速度加速,特別是在噴嘴孔7a之出口附近,內壁面7b變得容易磨耗。For example, in the top-blowing lance 5 shown in Example 201 in FIG. 2, the boundary surface 8 between the nozzle hole 7 a and the flow path 6 a is located on the side of the flow path 6 a. Therefore, as shown in Example 204 of FIG. 2, when the boundary surface 8 is projected to the cross section 15 perpendicular to the central axis 6d of the spray gun, the area of the projection surface is almost zero. That is, as shown in Example 101 of FIG. 1, since the line segment C itself does not exist, L = 0. In this case, although the proportion of "powder that directly penetrates into the nozzle hole without colliding with the inner wall surface of the flow path" is reduced, a biased flow as shown in Example 201 of Fig. 2 is caused, The mechanism different from the example 203 in FIG. 2 causes the inner wall surface 7b on the upper side of the nozzle hole to wear. That is, by generating a bias flow, the velocity of the gas and the powder is accelerated in the nozzle hole 7a, and particularly, the inner wall surface 7b is easily worn away near the exit of the nozzle hole 7a.

又,在圖2之例203所示之頂吹噴槍9中,由流路10a與噴嘴孔11a之邊界部10c所區劃出之邊界面12是位於流路10a之最下游側的內壁面10b。因此,邊界面12投影至與噴槍中心軸10d垂直的橫截面16時,被邊界線10c’包圍的投影面17呈楕圓形。再者,邊界線10c’是將邊界部10c投影至橫截面16的線。因此,「不碰撞到噴槍內管之流路的內壁面而直接侵入到噴嘴孔內的粉體」大量地進入到噴嘴孔11a。由於已進入之粉體碰撞於噴嘴孔11a的內壁面11b,故內壁面11b容易磨耗。In the top-blowing lance 9 shown in Example 203 in FIG. 2, the boundary surface 12 defined by the boundary portion 10 c between the flow path 10 a and the nozzle hole 11 a is an inner wall surface 10 b located on the most downstream side of the flow path 10 a. Therefore, when the boundary surface 12 is projected onto the cross-section 16 perpendicular to the central axis 10d of the spray gun, the projection surface 17 surrounded by the boundary line 10c 'is rounded. The boundary line 10c 'is a line that projects the boundary portion 10c to the cross section 16. Therefore, "the powder that directly penetrates into the nozzle hole without colliding with the inner wall surface of the flow path of the inner pipe of the spray gun" enters into the nozzle hole 11a in large quantities. Since the entered powder collides with the inner wall surface 11b of the nozzle hole 11a, the inner wall surface 11b is easy to wear.

如此,本實施形態之頂吹噴槍1的情況是投影面14的面積小圖2之例203所示之頂吹噴槍9之投影面17的面積,且線段C的長度L短。因此,如圖2之例202所示之頂吹噴槍1,噴嘴孔3a與流路2a連通時,「不碰撞到流路的內壁面而直接侵入到噴嘴孔內的粉體」的比例則比圖2之例203所示之頂吹噴槍9少。Thus, in the case of the top-blowing lance 1 of this embodiment, the area of the projection surface 14 is smaller than the area of the projection surface 17 of the top-blowing lance 9 shown in Example 203 in FIG. 2, and the length L of the line segment C is short. Therefore, in the top-blowing lance 1 shown in Example 202 of FIG. 2, when the nozzle hole 3a communicates with the flow path 2a, the ratio of "powder that directly penetrates into the nozzle hole without colliding with the inner wall surface of the flow path" is greater than There are few top-blowing lances 9 shown in Example 203 of FIG. 2.

又,圖2之例202所示之噴嘴孔3a是以噴嘴中心軸3c相對於流路2a之噴槍中心軸2d傾斜的方式,連通於噴槍內管2的流路2a。傾斜角θ小於10°時,從噴槍噴出之射流之間變得容易合體而容易增加噴渣,又,傾斜角θ超出30°時,火點與爐壁間距離過短,而促進爐壁耐火物的腐蝕,因此傾斜角θ宜為10~30°。又,亦可為:在設定為噴槍內管2之噴槍中心軸2d在Z軸上、噴嘴孔3a之出口位置在X軸上的XYZ正交座標系中,設置相當於噴嘴孔3a之扭矩之噴嘴軸往YZ平面之投影與Z軸所成之角度、及相當於噴嘴之外側方向的傾斜之噴嘴軸往XZ平面投影與Z所成之角度,噴嘴孔3a之噴嘴中心軸3c朝對噴槍中心軸2d扭轉之方向傾斜。The nozzle hole 3a shown in the example 202 in FIG. 2 communicates with the flow path 2a of the inner tube 2 of the spray gun so that the nozzle center axis 3c is inclined with respect to the spray gun center axis 2d of the flow path 2a. When the inclination angle θ is less than 10 °, the jets from the spray gun become easy to fit and increase the slag blasting. When the inclination angle θ exceeds 30 °, the distance between the fire point and the furnace wall is too short, which promotes the furnace wall fire resistance Corrosion of materials, so the inclination angle θ should be 10 ~ 30 °. In addition, in the XYZ orthogonal coordinate system of the center axis 2d of the spray gun set as the inner tube 2 of the spray gun on the Z axis and the exit position of the nozzle hole 3a on the X axis, a torque equivalent to the torque of the nozzle hole 3a may be set. The angle formed by the projection of the nozzle axis to the YZ plane and the Z axis, and the angle of the nozzle axis corresponding to the inclination of the outer direction of the nozzle to the angle formed by the ZZ plane, the nozzle central axis 3c of the nozzle hole 3a faces the center of the spray gun. The direction in which the shaft 2d is twisted is inclined.

其次,本發明人們,根據前述的假說,為了找出L/L0 之較佳範圍,就以抑制粉體磨耗為需求的噴嘴形狀,進行了抗磨試驗。Next, the present inventors conducted an abrasion resistance test in accordance with the foregoing hypothesis to find a preferable range of L / L 0 by using a nozzle shape with a requirement for suppressing powder wear.

(1)共通的調査條件 本發明人們,令噴槍內管之徑為20mm,令噴嘴孔數為4,令喉徑為5.1mm,令噴嘴傾斜角為20°,且在包含噴槍中心軸,將邊界面二等分的截面中,橫截線段B的長度L0 設定為固定值,前述橫截線段B是在邊界面上通過噴槍之最下游側之點,且在與噴槍中心軸垂直之直線上橫截噴嘴孔的橫截線段。另一方面,變更線段C之長度L,來評價粉體造成噴嘴孔之內壁面的磨耗,線段C是在噴槍內管之流路之範圍內往與噴槍中心軸垂直之橫截面投影橫截線段B時投影在橫截面上的線段。所謂喉徑,是在噴嘴部之噴嘴孔中截面積為最小時的直徑,並且使用氧氣作為含氧氣體,使用生石灰粉作為粉體副原料。在氧氣流量為3.0Nm3 /min的條件下,實施了將粒徑5~200μm之生石灰粉以5.5kg/min斷續地供給總計20小時,使氣體及粉體通過噴嘴孔的試驗。(1) Common survey conditions The inventors set the diameter of the inner tube of the spray gun to 20 mm, the number of nozzle holes to 4, the throat diameter to 5.1 mm, and the inclination angle of the nozzle to 20 °. In the bisected section of the boundary surface, the length L 0 of the cross-section line segment B is set to a fixed value. The aforementioned cross-section line segment B is a point that passes through the most downstream side of the spray gun on the boundary plane and is a straight line perpendicular to the central axis of the spray gun. The upper cross section of the nozzle hole. On the other hand, the length L of the line segment C was changed to evaluate the abrasion of the inner wall surface of the nozzle hole caused by the powder. The line segment C is a cross-section projected on the cross-section perpendicular to the center axis of the spray gun within the range of the flow path of the inner tube of the spray gun. Line B projected on the cross section. The so-called throat diameter is the diameter when the cross-sectional area of the nozzle hole of the nozzle portion is the smallest, and oxygen is used as the oxygen-containing gas, and quicklime powder is used as the powder raw material. A test was performed in which the quicklime powder having a particle size of 5 to 200 μm was intermittently supplied at a rate of 3.0 Nm 3 / min at a rate of 5.5 kg / min for a total of 20 hours to pass the gas and powder through the nozzle holes.

(2)L/L0 與磨耗試驗後之噴嘴磨耗量的關係 於圖3顯示各噴嘴中之L/L0 與磨耗試驗後之噴嘴磨耗量的關係。L/L0 愈小,則噴嘴磨耗量愈減少,但特別是在L/L0 <0.2的區域中,L/L0 愈小,則相反方位之噴嘴孔之內壁面的磨耗量增加。約為0.19≦L/L0 ≦0.82的情況時,相較於L/L0 =1.0的情況,噴嘴的磨耗量在一半以下。藉由以上的檢討,對於實施本發明之較佳的範圍是如式(1)所示,可知為0.19≦L/L0 ≦0.82。又,為了更確實地抑制磨耗,宜為0.35≦L/L0 ≦0.70。(2) L / L 0 and the relationship between the amount of wear of the abrasion test shows the relationship of the nozzle in each nozzle of L / L 0 and the amount of wear of the nozzle after the abrasion test in FIG. The smaller the L / L 0 is, the smaller the nozzle wear is, but especially in the area of L / L 0 <0.2, the smaller the L / L 0 is, the larger the wear of the inner wall surface of the nozzle hole in the opposite direction is. When it is about 0.19 ≦ L / L 0 ≦ 0.82, compared with the case where L / L 0 = 1.0, the wear amount of the nozzle is less than half. Based on the above review, the preferred range for implementing the present invention is as shown in formula (1), which is 0.19 ≦ L / L 0 ≦ 0.82. In addition, in order to more surely suppress abrasion, 0.35 ≦ L / L 0 ≦ 0.70 is preferable.

其次,就熔鐵的精煉方法進行說明。 本發明之熔鐵的精煉方法主要是在將粉體副原料與純氧氣即含氧氣體一起噴附到裝入至轉爐之熔鐵而進行熔鐵精煉時,使用前述之本發明的轉爐吹煉用頂吹噴槍。本發明之熔鐵的精煉方法中,裝入至轉爐之熔鐵不論是否已經予備處理。又,也不論精煉實施後之熔鐵的成分,其精煉亦可為所謂的熔鐵予備脫磷處理,亦可藉由其精煉而製造熔鋼。進而,粉體副原料不限定於生石灰、石灰石、鐵酸鈣(Calcium ferrite)等的脫磷劑,亦可為鋁礬土(bauxite)或金紅石(rutile)礦物等之渣化促進材、鐵礦物或Mn礦物等之礦物類、或者該等之混合物。Next, a method for refining molten iron will be described. The method for refining molten iron according to the present invention is mainly carried out by using the converter of the present invention for refining when the powder auxiliary material is sprayed together with pure oxygen, that is, an oxygen-containing gas, into the molten iron loaded into the converter to perform molten iron refining. Use a top blow spray gun. In the method for refining molten iron according to the present invention, the molten iron charged into the converter is prepared whether or not it has been prepared. In addition, regardless of the components of the molten iron after the refining is performed, the refining may be a so-called molten iron pre-dephosphorization treatment, or molten steel may be manufactured by the refining. Furthermore, the powder by-products are not limited to dephosphorizing agents such as quicklime, limestone, and calcium ferrite, and may be slag-promoting materials such as bauxite or rutile minerals, and iron. Minerals, minerals such as Mn minerals, or mixtures of these.

含氧氣體之噴附流量及粉體副原料之粒徑、添加量只要可因應於該熔鐵的精煉目的而穩定進行粉體副原料之搬送及噴附即可。 本發明之轉爐吹煉用頂吹噴槍在任何的條件中都可以比使用習知之頂吹噴槍更抑制供給粉體所伴隨之噴嘴磨耗的問題,有助於穩定操作並且可降低噴槍更換的頻率,而對生產性提高有所貢獻。 [實施例]The spraying flow rate of the oxygen-containing gas, the particle size and the addition amount of the powder auxiliary raw materials may be carried and stably carried out and sprayed according to the purpose of refining the molten iron. The top-blowing spray gun for converter blowing in the present invention can suppress the problem of nozzle wear associated with the supply of powder more than the conventional top-blowing spray gun in any condition, which helps stabilize the operation and reduces the frequency of spray gun replacement. And contribute to the improvement of productivity. [Example]

其次,雖然是就本發明之實施例進行說明,但在實施例的條件是為了確認本發明之可實施性及效果所採用的一條件例,本發明並不受限於該一條件例。本發明是只要不脫離本發明之要旨,可在達成本發明之目的之下,採用各種條件。Next, although the embodiment of the present invention is described, the conditions in the embodiment are an example of a condition adopted for confirming the feasibility and effect of the present invention, and the present invention is not limited to the example of the condition. As long as the present invention is not deviated from the gist of the present invention, various conditions can be adopted while achieving the purpose of the present invention.

以300t規模之頂底吹轉爐進行了熔鐵預備脫磷吹煉。此時的主原料中,使用了質量濃度含有C:4.4~4.5%、Si:0.2~0.5%、Mn:0.2~0.4%、P:0.100~0.130%的熔鐵約260t,使用了廢料約20t。令頂吹氧流量為每熔鐵1t則為3.0Nm3 /min,粉體副原料是令粒徑5~200μm之生石灰粉體為頂吹速度900kg/min,令底吹CO2 流量為0.25Nm3 /min。藉由該脫磷吹煉,製造了質量濃度為C:3.6~3.8%、Si≦0.01%、Mn:0.1~0.2%、P:0.015~0.025%的熔鐵。在該試驗中,調查了因為噴嘴磨耗,噴槍內部之冷卻水的流路開孔,直到產生漏水的吹煉次數與L/L0 的關係。A 300t top-to-bottom blowing converter was used for preliminary dephosphorization melting of molten iron. At this time, the main raw materials used about 260 tons of molten iron containing C: 4.4 to 4.5%, Si: 0.2 to 0.5%, Mn: 0.2 to 0.4%, and P: 0.100 to 0.130%, and about 20 tons of waste materials were used. . Let the top-blown oxygen flow rate be 3.0Nm 3 / min per 1t of molten iron. The powder raw material is to make a quick lime powder with a particle size of 5 ~ 200μm as the top-blown speed of 900kg / min, and the bottom-blown CO 2 flow rate is 0.25Nm. 3 / min. By this dephosphorization blowing, molten iron having a mass concentration of C: 3.6 to 3.8%, Si ≦ 0.01%, Mn: 0.1 to 0.2%, and P: 0.015 to 0.025% was produced. In this test, the relationship between the number of blows and the L / L 0 that caused the leakage of the cooling water flow path inside the spray gun due to nozzle wear was investigated.

頂吹噴槍的條件是令噴槍內管之徑為180mm、令喉徑為45mm、令噴嘴孔數為4、將噴嘴傾斜角固定為20°,製作改變了L/L0 的頂吹噴槍,使用於吹煉。在以下的表1,顯示L/L0 及磨耗指數。在此,所謂磨耗指數,是令比較例1之頂吹噴槍使用於吹煉直到產生前述之漏水的吹煉次數為1而經過指數化的值。Top-blowing lance condition is to make the diameter within the barrel of of 180mm, so that the throat diameter of 45mm, so that the number of holes of the nozzle 4, the nozzle inclination angle is fixed at 20 °, making change L / L top-0-blown lance, using Yu Bing. Table 1 below shows L / L 0 and abrasion index. Here, the abrasion index is an indexed value when the top-blowing lance of Comparative Example 1 is used for blowing until the number of blows for which the aforementioned water leakage occurs is 1.

[表1] [Table 1]

首先,敘述比較例1及2。相較於比較例1,比較例2的磨耗指數較小。這是因為比較例2之頂吹噴槍的L/L0 較小之故。其次,敘述實施例1~4。實施例1~4之磨耗指數相較於比較例1為一半以下。這是因為滿足L/L0 ≦0.82,且「不碰撞到噴槍內管壁面而直接侵入到噴嘴孔內的粉體」的比例已減少之故。又,實施例2的L/L0 比實施例1還小,但看不到與實施例1之磨耗指數有大的差異。又,實施例1及2分別比實施例3及4還更為抑制磨耗。First, Comparative Examples 1 and 2 will be described. Compared with Comparative Example 1, the wear index of Comparative Example 2 is smaller. This is because the L / L 0 of the top-blowing lance of Comparative Example 2 is small. Next, Examples 1 to 4 will be described. The wear index of Examples 1 to 4 was less than half as compared with Comparative Example 1. This is because L / L 0 ≦ 0.82 is satisfied, and the proportion of “powder that directly penetrates into the nozzle hole without colliding with the wall of the inner tube of the spray gun” has been reduced. In addition, the L / L 0 of Example 2 is smaller than that of Example 1, but no significant difference from the abrasion index of Example 1 is observed. In addition, Examples 1 and 2 suppress wear more than Examples 3 and 4, respectively.

另一方面,比較例3的磨耗指數比實施例1~4還大。這是因為藉由令L/L0 比0.19還小,在噴嘴孔內之氣體及粉體之流動產生了偏離之故。 由以上可確認,藉由設定為0.19≦L/L0 ≦0.82,可抑制因粉體造成之噴嘴孔之內壁面的磨耗,進而藉由設定為0.35≦L/L0 ≦0.70,可更抑制內壁面的磨耗。 產業上之可利用性On the other hand, the wear index of Comparative Example 3 is larger than that of Examples 1 to 4. This is because by making L / L 0 smaller than 0.19, the flow of gas and powder in the nozzle hole is deviated. From the above, it can be confirmed that by setting 0.19 ≦ L / L 0 ≦ 0.82, the abrasion of the inner wall surface of the nozzle hole caused by powder can be suppressed, and further by setting 0.35 ≦ L / L 0 ≦ 0.70, it can be more suppressed Wear of the inner wall surface. Industrial availability

根據本發明,可抑制將含氧氣體及粉體副原料進行頂吹所致之噴嘴的磨耗,並可加長精煉用噴槍之耐磨耗壽命。因此,工業的價值大。According to the present invention, it is possible to suppress abrasion of the nozzle caused by the top blowing of the oxygen-containing gas and the powder auxiliary material, and to lengthen the wear-resistant life of the refining spray gun. Therefore, the value of industry is great.

1‧‧‧頂吹噴槍1‧‧‧Top Blow Gun

2‧‧‧噴槍內管2‧‧‧Inner tube of spray gun

2a‧‧‧流路2a‧‧‧flow

2b‧‧‧內壁面2b‧‧‧Inner wall surface

2c‧‧‧邊界部2c‧‧‧Border

2c’‧‧‧邊界線2c’‧‧‧ boundary

2d‧‧‧噴槍中心軸2d‧‧‧ spray gun central axis

3‧‧‧噴嘴部3‧‧‧ Nozzle section

3a‧‧‧噴嘴孔3a‧‧‧Nozzle hole

3c‧‧‧噴嘴中心軸3c‧‧‧Nozzle central axis

4‧‧‧邊界面4‧‧‧ boundary surface

5‧‧‧頂吹噴槍5‧‧‧Top blowing spray gun

6a‧‧‧流路6a‧‧‧flow

6d‧‧‧噴槍中心軸6d‧‧‧ spray gun central axis

7a‧‧‧噴嘴孔7a‧‧‧Nozzle hole

7b‧‧‧內壁面7b‧‧‧Inner wall surface

7c‧‧‧噴嘴中心軸7c‧‧‧Nozzle central axis

8‧‧‧邊界面8‧‧‧ boundary surface

9‧‧‧頂吹噴槍9‧‧‧Top Blow Gun

10a‧‧‧流路10a‧‧‧flow

10b‧‧‧內壁面10b‧‧‧Inner wall surface

10c‧‧‧邊界部10c‧‧‧Border

10c’‧‧‧邊界線10c’‧‧‧ boundary

10d‧‧‧噴槍中心軸10d‧‧‧ spray gun central axis

11a‧‧‧噴嘴孔11a‧‧‧Nozzle hole

11b‧‧‧內壁面11b‧‧‧Inner wall surface

11c‧‧‧噴嘴中心軸11c‧‧‧Nozzle central axis

13‧‧‧橫截面13‧‧‧ cross section

14‧‧‧投影面14‧‧‧ projection surface

15‧‧‧橫截面15‧‧‧ cross section

16‧‧‧橫截面16‧‧‧ cross section

17‧‧‧投影面17‧‧‧ projection surface

A‧‧‧直線A‧‧‧Straight

B‧‧‧橫截線段B‧‧‧ cross section

C‧‧‧線段C‧‧‧Segment

L‧‧‧長度L‧‧‧ length

L0‧‧‧長度L 0 ‧‧‧ length

圖1是用以說明橫截線段B之長度L0 與線段C之長度L的圖。 圖2是多孔噴槍之前端部分的截面概略圖。 圖3是顯示L/L0 之差異所致之磨耗係數的變化之圖。FIG. 1 is a diagram for explaining the length L 0 of the cross-sectional line segment B and the length L of the line segment C. FIG. Fig. 2 is a schematic cross-sectional view of a front end portion of the porous spray gun. FIG. 3 is a graph showing changes in abrasion coefficients due to differences in L / L 0 .

Claims (2)

一種轉爐吹煉用頂吹噴槍,是在將熔鐵裝入至頂底吹轉爐,並從頂吹噴槍將粉體副原料與含氧氣體一起噴附於熔鐵而進行吹煉時所使用的轉爐吹煉用頂吹噴槍,其特徵在於具備: 噴槍內管,具有前述含氧氣體及前述粉體副原料之流路;及 噴嘴部,連通於該噴槍內管之前述流路而延伸設置,且具有2孔以上之噴嘴孔, 前述噴嘴孔之噴嘴中心軸是相對於前述流路之噴槍中心軸傾斜,且前述噴嘴孔分別滿足以下之式(1): 0.19≦L/L0 ≦0.82   ...(1), 在此,L0 :在包含前述噴槍中心軸且將前述噴槍內管之流路與前述噴嘴孔之邊界面二等分的截面中,在前述邊界面上通過噴槍之最下游側之點,且在垂直於前述噴槍中心軸的直線上將前述噴嘴孔橫截之線段的長度, L:在前述噴槍內管之流路的範圍內,將前述橫截之線段往垂直於前述噴槍中心軸的橫截面投影時,投影到前述橫截面上之線段的長度。A top-blowing spray gun for converter blowing is used when a molten iron is charged into a top-bottom blowing converter, and a powder auxiliary material is sprayed together with an oxygen-containing gas from the top-blowing spray gun to the molten iron for blowing. The top-blowing spray gun for converter blowing is characterized in that: the inner tube of the spray gun has the flow path of the oxygen-containing gas and the powder auxiliary raw material; and a nozzle portion is extended to communicate with the flow path of the inner tube of the spray gun, And there are nozzle holes with more than 2 holes, the nozzle central axis of the nozzle hole is inclined with respect to the central axis of the spray path of the flow path, and the nozzle holes respectively satisfy the following formula (1): 0.19 ≦ L / L 0 ≦ 0.82. .. (1) Here, L 0 : In a cross section that includes the central axis of the spray gun and bisects the boundary surface of the spray gun inner tube and the boundary surface of the nozzle hole, passes the most of the spray gun on the boundary surface. The point of the downstream side and the length of the line segment of the nozzle hole on a straight line perpendicular to the central axis of the spray gun, L: within the range of the flow path of the inner pipe of the spray gun, the line segment of the cross section is perpendicular to When the cross section of the central axis of the spray gun is projected, The length of the line segment shadowed to the aforementioned cross section. 一種熔鐵的精煉方法,是使用如請求項1之轉爐吹煉用頂吹噴槍進行吹煉之熔鐵的精煉方法,其特徵在於: 將熔鐵裝入至頂底吹轉爐,並從前述轉爐吹煉用頂吹噴槍將粉體副原料與含氧氣體一起噴附於前述熔鐵而進行吹煉。A method for refining molten iron is a method for refining molten iron that is blown with a top-blowing lance using a top-blowing lance for converter blowing according to claim 1, characterized in that: the molten iron is charged into a top-bottom blowing converter, and from the foregoing converter The top-blowing lance for blowing sprays powder auxiliary materials together with oxygen-containing gas onto the molten iron to perform blowing.
TW107128299A 2017-08-21 2018-08-14 Top-blowing spray gun for converter blowing and refining method of molten iron TWI665308B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2017-158736 2017-08-21
JP2017158736 2017-08-21

Publications (2)

Publication Number Publication Date
TW201920692A true TW201920692A (en) 2019-06-01
TWI665308B TWI665308B (en) 2019-07-11

Family

ID=65438715

Family Applications (1)

Application Number Title Priority Date Filing Date
TW107128299A TWI665308B (en) 2017-08-21 2018-08-14 Top-blowing spray gun for converter blowing and refining method of molten iron

Country Status (5)

Country Link
JP (1) JP6721129B2 (en)
KR (1) KR20200003114A (en)
CN (1) CN110621792A (en)
TW (1) TWI665308B (en)
WO (1) WO2019039285A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7380444B2 (en) * 2020-06-24 2023-11-15 Jfeスチール株式会社 Top blowing lance for converter dephosphorization treatment and converter blowing method

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2903211A1 (en) * 1979-01-27 1980-07-31 Stiftelsen Metallurg Forsk Powder and gas injection lance - has outward inclined exit ports close to support point
US4426224A (en) * 1981-12-25 1984-01-17 Sumitomo Kinzoku Kogyo Kabushiki Gaisha Lance for powder top-blow refining and process for decarburizing and refining steel by using the lance
JPH0626758B2 (en) * 1990-03-01 1994-04-13 新日本製鐵株式会社 Equipment for removing mold deposits in continuous casting equipment
CN1059470C (en) * 1995-01-06 2000-12-13 新日本制铁株式会社 Converter top-blow refining method having excellent decarburization characteristics and top-blow lance for converter
JPH10287909A (en) * 1997-04-15 1998-10-27 Sumitomo Metal Ind Ltd Top-blown lance for blowing gas into converter and also melting skull stuck to nose
JP2001280608A (en) * 2000-03-31 2001-10-10 Sumitomo Heavy Ind Ltd Lance and method for controlling combustion flame
JP4448231B2 (en) * 2000-05-10 2010-04-07 新日本製鐵株式会社 Top blowing lance for blowing with expansion control laval nozzle
JP3772750B2 (en) 2002-01-28 2006-05-10 住友金属工業株式会社 Refining lance
JP3849571B2 (en) * 2002-05-14 2006-11-22 Jfeスチール株式会社 Converter blowing method
US6773484B2 (en) * 2002-06-26 2004-08-10 Praxair Technology, Inc. Extensionless coherent jet system with aligned flame envelope ports
JP5353463B2 (en) * 2009-06-17 2013-11-27 新日鐵住金株式会社 How to remove hot metal
JP5516375B2 (en) * 2010-12-02 2014-06-11 新日鐵住金株式会社 Hot metal refining method
JP2012251199A (en) 2011-06-02 2012-12-20 Sumitomo Metal Ind Ltd Refining method of molten iron
WO2013057927A1 (en) * 2011-10-17 2013-04-25 Jfeスチール株式会社 Powder injection lance and method of refining molten iron using said powder injection lance
IN2014KN01258A (en) * 2011-12-20 2015-10-16 Jfe Steel Corp
CN202595160U (en) * 2012-04-13 2012-12-12 张昭贵 Coal powder nozzle
JP6451364B2 (en) * 2015-02-04 2019-01-16 新日鐵住金株式会社 Top blowing lance for molten metal refining
JP6515335B2 (en) * 2015-07-10 2019-05-22 日本製鉄株式会社 Converter melting method of iron containing materials
JP6421731B2 (en) * 2015-09-17 2018-11-14 Jfeスチール株式会社 Converter operation method
JP6421732B2 (en) * 2015-09-17 2018-11-14 Jfeスチール株式会社 Converter operation method

Also Published As

Publication number Publication date
JP6721129B2 (en) 2020-07-08
KR20200003114A (en) 2020-01-08
TWI665308B (en) 2019-07-11
JPWO2019039285A1 (en) 2019-11-21
WO2019039285A1 (en) 2019-02-28
CN110621792A (en) 2019-12-27

Similar Documents

Publication Publication Date Title
KR101346726B1 (en) Method for refining molten iron
JP4901132B2 (en) Converter blowing method and top blowing lance for converter blowing
TWI665308B (en) Top-blowing spray gun for converter blowing and refining method of molten iron
TWI664295B (en) Dephosphorization treatment device and dephosphorization method using molten pig iron
JPH1180825A (en) Top-blown lance for converter refining and converter refining method by using this
JP2009091617A (en) Method for dephosphorizing molten iron
CN107429303B (en) Operation method of top-bottom simultaneous blowing converter
CN108251596B (en) Fixed converter tapping hole double-nozzle structure
JP2007239082A (en) Method for oxidize-refining molten metal and top-blown lance for refining
JP6658678B2 (en) Top blowing lance for refining and method for refining hot metal
JP2011074411A (en) Top-blowing lance for refining, and converter refining method
JP6870450B2 (en) Top-blown lance and converter blowing method using it
JP6451364B2 (en) Top blowing lance for molten metal refining
JP2012082492A (en) Converter refining method
JP7410393B2 (en) Hot metal pretreatment method and hot metal pretreatment lance
JP2001131629A (en) Top-blown lance for dephosphorizing molten iron and dephosphorizing method of molten iron
JP7380444B2 (en) Top blowing lance for converter dephosphorization treatment and converter blowing method
JP7298649B2 (en) Top-blowing lance for converter refining and molten iron refining method using the lance
JP7036147B2 (en) Top-blown lance and refining method of molten iron using it
JP6888492B2 (en) Molten steel refining equipment and molten steel refining method
JP2009052090A (en) Lance for refining molten iron and method for refining molten iron
JP6747100B2 (en) Oxygen blowing lance and oxygen blowing method
JPS58207313A (en) Refining method of steel
KR20100076115A (en) Lance for blowing-in microstructural particle
JP2018131675A (en) Decarbonization blowing lance tip

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees